OC-GLYCOL ESTERS OF P-NITROPHENYLARSENOUS AND OC-NAPHTHYLARSENOUS ACIDS

• Document Type: CREST
• Collection: General CIA Records
• Document Number (FOIA) /ESDN (CREST): CIA-RDP80-00809A000700160157-9
• Release Decision: RIPPUB
• Original Classification: C
• Document Page Count: 2
• Document Creation Date: December 22, 2016
• Document Release Date: September 8, 2011
• Sequence Number: 157
• Publication Date: January 29, 1954
• Content Type: REPORT

Sanitized Copy Approved for Release 2011/09/08 :CIA-RDP80-00809A000700160157-9
CLASSIFICATION CONFIDIIdTLAL
CENTRAL INTELLIGENCE AGENCY
INFORMATION FROM
FOREIGN DOCUMENTS OR RADIO BROADCASTS
REPORT
CD N0.
DATE GF
DATE DIST. 1`! .Tan 1954
SUPPLEMENT TO ~~
LANGUAGE Russian REPORT NO.
COUNTRY USSR
SUBJECT Scientific -Chemistry, toxic compounds
HOW
PUBLISHED Monthly periodical
WHERE
PUBLISHED Leningrad
DATE
PUBLISHED Aug 1953
'.. '"'? " ?" ~???? ' ~'~~??r?e ~~ ????'a~ ~'?" ~ o"~^~~ THIS IS hDJEVALUATED INFORMATION
SOURCE Zhurnal Obehchey Khimii, Vol ..^3, Ao 8, pp 1431, :}+32
a-GLYCOL ^nSTr"'ii S OF p-NITROPHS't~IYLARSEtiOUS AND a ~NAPRTHYLARSENOUS ACIDS
Gi1'm Kamay and ti. A. Chadayeva
Chem Inst im Acad A. Ye. Arbuzov
Kazan' Affiliate, Acad Sci USSR
~he experimental part of this article has been omitted_~
m},e present short work is a further de~?eJ.spment of our investigations in
the field of cyclic g).ycol esters of arsenous and arylarsenous acids. Rere
we undertook the study ~f the methodr n_^ obtaining several cyclic a-glycol
esters of p-nitrophenylarsenous and a-naphthylarsenous acids.
By `,he action of nn equimolecular quantity of p-nitrophenylarsenous acid
on various oc?glycols (with heating), the a glycol esters of p-nitrophenylarse-
nous acid were synthesized according to tue following scheme:
02f7 ~ \ -As\ t I ~ 02fi / ~ -A / I i- H02
\
OH HO-CH
0-CH
R R
where: R = R, CH2CCA3, or CH2OC2H5.
- 1 -
CLASSIFICATION CONFID:?N'fh1L
~" STATE NAVY NSRB DISTRIBUTIDII
ARMY AIR Fal i _r~-J-~_~- - I ~~
I
Sanitized Copy Approved for Release 2011/09/08 :CIA-RDP80-00809A00(
 Sanitized Copy Approved for Release 2011/09/08: CIA-RDP80-00809A000700160157-9
In this way, the ethyleneglycol, a?methoxypropyleneglycol, and a-ethoxy-
p^opylene~lycol esters of p-nitrophenylarsenous acid were prepared and then
isolated. The esters readily saponify in water.
We prepared the a-glycol eaters of a?naphthylarsenous acid by the reac-
tion betxeen a-naphthyldichloroarsine and the corresponding a-glycol in the
presence of a~ihydrous pyridine. The reaction was carried ouc in absolute
ether according to the follaxing scheme:
The a?clycol esters of a?naphthylarsenous acid which are thus obtained
Pre thick, transparent liquids unstable in air. They hydrolyze to form
co-naphthylarsine oxide.
Conclusions: Various a-glycol esters of p-nitrophenylarsenous and
a-naphthylarsenous acids have been synthesized and their properties studied.
1.
Gil'm Kamsy and Z. L. Khisamova, DAN SSSR, Vol 46, p 535
(1951)
2.
Gil'm Kamay and N. A. Chadayeva, DAN SSSR, Vol 87., p 71
Iz Ak Nauk SSC;R, OTN, 908 (1y52)
(1952};
3.
Gil'm Kamay, Z. L. Khisamova, and N. A. Chadayeva, DAN SSSR, Vol 89,
1051 (1953)
Sanitized Copy Approved for Release 2011/09/08: CIA-RDP80-00809A000700160157-9