COMPLEX FORMATION IN A QUATERNARY RECIPROCAL SYSTEM OF CHLORIDES SULFATES AND TUNGSTATES OF LITHIUM AND POTASSIUM.

Document Type: 
Collection: 
Document Number (FOIA) /ESDN (CREST): 
CIA-RDP80T00246A005600100012-6
Release Decision: 
RIFPUB
Original Classification: 
K
Document Page Count: 
9
Document Creation Date: 
December 21, 2016
Document Release Date: 
January 5, 2009
Sequence Number: 
12
Case Number: 
Publication Date: 
April 10, 1998
Content Type: 
REPORT
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PDF icon CIA-RDP80T00246A005600100012-6.pdf448.81 KB
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Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 IMI -W-K, T 1. .. .. .._ ':Y,~ 27r -it ae 14- Wit Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 0 pert&ft to the pure components. Sw fielft of potassium sulfate, lithium sulfate and lithlM %Woftft GM *a~ breIm up into the and modification areas Sitastat M qwwto sun W so Fig. 2). in the system the complex forming reaction on the two opy"ift SUM St Vw composition &VA&" is predominant to the double d*compoeltian rescUAL Me ". MM order to verify the stablility of the two cowlexAm (dwAae M116) vWims smctjcnm~ In particular the three lbook"* SeCtIMS (1.9 11, in, J ma as five triaingular sections, as show, in Fiw. 2. systams and thus treat then aF S.1011 In t!-Ir investigations. Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 I Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 rhe,r%ct"rized by me, tag ?IiLm chloride exhibit* 180the,,me hOMeownrph!c forms. The in ch&reCI'@r1zftw Its VIth 40crease In taw-rstur' =nA N NN&F MMIIQ Nil Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 219 Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 XULer Crystallization volumes In a E Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 I Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 41, 4- OA&UrA&17 transition Points. this IS &too Verified by the study of the JA, X // M the authors as an example. By means of a --hier of Inner mewMew, @bM jjMjjAjW_ In f1g. 2p It IS shown Uat the above system can be divided b7 4 rwh 1~ "etio" Lato five tetrahedrons each of whieh hem a quaternary euteeUe VsUA, While the fifth tetzWwAran has a quaternary transition point. 2heir Osmpwdf4j~ we listed in Table ). 1. The MW* of owelsot foniation of the quaternary reciproml x7e Lip X // CM, 1 reciprocal system Lip K // ? the quaternary system Li, K // C1, -',04, WO,, is shavn. IIL / ? ? 70% :/ M Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6 and me UAW section (50% LizW04 + 50% K004) - (50% UsW4 + %* YaNk) - Name ohm the stability of Li&WO4-KZW04 and Li2SO4-r-GW4 dGUbI4 MIU- an Slow boundaries of their crystallizatim volumes have beem deserlbeL 4. ?be inner structure of the prim LI, K, // H 904, found to have 8 voilumes of crystallization - two of the abome muntl4aft downs malts and siz of the single components. I. 1. 1 1. 1 1 iL 3. SWOM, A. C., Kialovs, A. I., Posipaiko, T. I., ILA.S. MTITL~ta Approved For Release 2009/01/05: CIA-RDP80T00246AO05600100012-6