JPRS ID: 9197 USSR REPORT MATERIALS SCIENCE AND METALLURGY
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, FOR OFFI('IAI. USF. CNLY
~PRS L/9035
16 April 1980 _
USSR Re ort ~ -
p
MATERIALS SCIENCE AND MET~?LLURGY
(FOUO 3/80)
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16 April 1980
USSR REPORT
MATERIALS SCIENCE AND METALLURGY
(FOUO 3/80)
" 7'his serial publication contains articles, abstracts of articles and news
iterns from USSR scientific and technical journals on the specific subj~.cts
reflected in the tabls of contents. -
.Photore~roductions of foreign-language sources may be obtained from the ~
Pho~.oduplication Service, Library of Congress, Washingron, D. C. 205~+~.
Requests should provide adequate identification both as to the source anc~
the individual article(s) desired.
CONTENTS PRG~
NUCLEAR SCIENCE AND TECHNOLOGY
Reactor Material Technology
(D.M. Skorov, et al; REAKTORNOYE MATER7_ALOVFDIsIJIYE,
" 1979) 1
POLYMER MATERIALS
Structure and Properties of Polymer Materials
_ (AKADEMIYA NAUK LATVIT'SKOY SSR INSTITUT M~KHANIKI
POLIMEROV, 1979) ..................................e.... 5
RUTHENIUM
Physical Chemistry of Ruthenium and Ruthenium Alloys
_ (M.V. Rayevskaya, Ye.M. Sokolovskaya; FIZIKOKHIMIXA
RUTENIYA I YEGO SPLAVOV, 1979) .11
_ SILVER
Silver and Silver-Base Alloys
_ (V. A. Mast~rov, Yu. V. Sal~sonov; SEREBRO, SPLAV~' I
BIMETALLY NA YEGO OSNOVE, 1979) 14
- a- [III - USSR 21 G~& T FOUO]
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CONTENTS (Continued) Page
TITANIUM
Corrosion Cracking of Titanium and Aluminum Alloys -
(R.K. Melekhov; KORROZIONNOYE RASTRESKIVANIYE
TITANOVYKH I ALYtJMINIYEVYKH SPLAVOV, 1979) 18
Metallurgy and Technology of Welding Titanium and its Alloys -
(METALLURGIYA I TEKHNOLOGIYA SVARKI TITANA I YEGO SPLAVOV,
1979) 21
~
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NUCLr.AR SCIENCI: AND 'TECHNOLOGY
REAGTOR MATERIAL TECI~iOLOGY
= Moscow REAICTORNOYE MATERIALOVIDIIdIYE in Russian, 1979 si~ned to press
27 Dec 78 pp3? 3~3-3~
~
_ [Foreword and table of contents from book by D. M. Skorov, Yu. F. Bychkc~v,
A. I. Dashkovskiy, Atomizdat, 2080 copiea, 34~ pages]
[Text] Foreword to second edition
The "Reactor Ma,terial Technology" mon~graph published in 1968 was sold
out rapidly which indicates reader interest in this book. an the years
after the book was published many publications appeared in the Soviet Union
and abroad that considerably expanded our concepts on the rroper-ties of
reactor meterials,and on the mechanism of the processes occ~:sri.ng in the:~e
materials during their use.
The second edition of this book was reWritten takin~ ir_to uccount the lates~
data on the ph,ysical, mechanical and nucleax properties of uranium~ plu-
tonium and thorium, as well as of their compounds. .
As before, basic attention is devoted to the description of nuclear fuo~
_ and structural ma.terials, the processes occurring in them under -the ~nflu-
e~ce of radiation and other factors related to operating conditionso A.lon~
wi'cYi this, prob~.ems are more fully considered of the change in the most im-
portant properties, identifying the pa,tterns of such changes that would .
make it possible to outline ways to improve tha operating characterist~cs
of the materials. Prc':lems axe elucidated of the life of the jacket ~struc-
~ tural) materials, in particular of the importance of streng`~h properties
and their relationship to the formation and precipitation of he:iium when
irradiated, problems of corrosion etc.
In connection with a great number of new data and the necessih.y of more
detailed treatmEnt of the ma,~erial technology and metal phy~sies aspeci;s
of reactor ma,terials, the authors considered it expedient to eliminate
sections of the book concerning phyaical and thermophysical problome of
the :ictive zone of the rea.ctor. _
1
7 -
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In the second edition being offered, the general structurP of the book~
the o~cler and titlea of several chaptera and sections ,~ere preserved;
however~ the contents axe completely renewed, the majority of chapters were
newly written taking into account new data, while the xemaining chapters
were re~rritten and amplified considerably.
CCHJ~IIITS
Page
Foreword to second edition 3
~hapter 1. Prospects and Problems of Nucleax Power 4
1. Prob~.ems of power engineering development W
2. Fisaion materials. Burn-up 5
3. TYE [F1xe1 slement] materials 7
4. TVE design 10
5. Basic types of nucleax reactors 12
~ Chapter 2. Metallic Nucleax F1.ie1 15
1. Unalloyed ur�anium 15
2. Uranium alloys ~ 29
3. Thorium and its alloys 45
4. Plutonium and its alloys 51
5. Increasing TYE efficiency 57
Chapter 3. Ceramic Nucleax F4ae1 for TVE 62
_ 1. CDcide fuel materials 63
2. Carbide nucleax fuel 109
3. Nitrides as nuelear fuel 120
4. Phosphides and sulphides as nuclear fuel 125
5. Behavior of ceramic ma.terials under radiation 128
Chapter 4. Nuclear FLiel Precipitation 138
1. Precipitation elements from uranium dioxide in the
metallic matrix 141
2. Precipitation elements from carbide and uranium
dioxide in the fuel material matrix 151
3. Precipitation elements (cermets) with carbides,
nitrides, sulphides, uranium dioxide and other
compounds in the matrix of ~~actory metals and
- ceramic materials 151
4. Coating fuel particles 161
5. Certain methods for obtaining spherical fuel paxticles 171
6. U-Mg precipitation system 176
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- CONTF~ITS
~ -
-r Yage
Chapter (Continued)
~ 7. Precipitation system with a U02, U308~ UC core and
U-A1 alloys in an aluminum and aluminum alloys ma,trix 177 _
8. Precipitation elements of LT-A1 alloys in an
aJ.uminum or aluminum alloys matrix 180 -
Chapter S, Effect of R~,diation on ~tructural Materials it32
1. Action of radiation on properties of inetals and steels 183
2. Action of radiation on zirconium ~94.
= 3. Effect of radiation on properties of refractory me~als iy7
Chapter 6. Compatibility of Core with Jacket Materials ~00
_ i. Compatibility of ur2nium with aluminum 20?
. 2. Compatibility of uranium with zirconium ?04~
3. Compatibility of uranium with stainl.ess steel 206
4. Compatibility of uranium alloys with refractory
metals 207
5. Compatibility of ceramic fuel with metallic jackQts 208
Chapt~er 7. Compatibility of Nucleax ~zel an.d Jacket
Materials with Coolant 2q1
i. Corrosion of ura.nium in water 212
2. Corrosion of aluminum alloys in water 213 =
3. Life of zirconium in water and water steam 217
4. Interaction between metals and liquid sodium,
_ potassium and cesium 223
5� Interaction between metals and liquid lithium 231 -
6. Compatibility of steels and nickel alloys i~rith water ~.nd
co2 23J -
7. Compatibility ~rith organic coolants 241 _
= 8. Corrosion of uranium and its 211oys 24~2
- Chapter 8. Certain Problems in Manufacturing and
Joining the Core to the Jacket 246
1. Methods of manufacturing the core and jackets 246
2. Nature of contact between the core and the jacket 250
3. Certain methods for joining the core to the jacket 259
4. Heat conducting interlayers 30?
5. Seali.ng the fuel elements 30r~
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C(lNT~I.'S Page
Chapter 9. Monitoring the Qua,lity and Methods for Testing
the Fl~el Elements 3i3
1. General inf.orma,tion 313
2. Phyeical bases for teating and n~onitoring methad.s 314
3. 'I'ests by radiation (reactor tests) 3i6
4. Praduction tests of fuel element parts 321
5. Teste of completed fuel elements 32~
6. Problems of standardizing tests and evaluating
their results j31
Bibliography 333
COPYRIGHT~ ATOMIZDAT, 1979
[103-2'l91]
2291
CSO~ 1842
i
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POLYMER MATERIALS
STRUCTURE AND PROPERTIES OF POLYMER MATERIAL~
Riga AKAD~MIYA NAUK LATVIYSKOY SSR INSTITUT MEKHANIKI POLIMEROV (f~cademy
of S ciences Latvian SSR Institute of Polymer Materials) in Russian, 1979
' signed to press 27 Oct 77 pp 5-8, 207-208 ~
[Foreword and table of contents fr~m the book, "Zin~atne~," 2?2 pagesJ
(Text] In the course of scientific and technical progress there is all the
more growth in requirements for structural materials. This was reflected
in the reaolutions of the 25th Congress of the CPSU where ttiey talked about
the development of new polymer materials and improved quality of existing
_ ones. Tc meet these tasks will require further development of structure
research and determination of the relationships between the structural con-
_ stit ution and a complex of physical and mechanical characteristics of polymer
materials; to control the process of polympr synthesis w~ll requize struc-
tural research at the solutions level. Determination of the correct mode
- cF m~terial application in tLrn is not possible without knowledge of struc-
t:ural tr3nsformations during the action or a varying form of external factors
on the polymer material. All of the above-listed problems were examine3 in
det ail at the Thizd All-Union Conference on the Mechanics of Polymers which
was held in 1976 in Riga and reflected in the transactions put forward to
the reader of the collection.
The content of articles in the first part of the collection encompasses a
broad circle of questions associated with the structure of a polymer material
at different structural levels. All the work on the problems and produced
results can be reduced to the following basic directions: 1) uncovering -
_ new principles of structure and property relationship and 2) development of -
new methods for controlling structure and the properties associated with it.
Mos t works have been associated with study of the structural state of polymers
at various levels.
Recently more attention is being given to properties characterizing the sys-
tem of macromolecules as a whole--like molecular mass, molecular-mass dis-
tributiun, etc. In conJunction with this exists the necessity to conduct
experimental and theoretical research, determiiie the nature of the relation-
ships between molecular distribution and individual structural elements such
5
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_ ,iy tl~e presence of vacancies, number of through molecules, etc. The work of
V.1'. I3tultov