SCIENTIFIC ABSTRACT ABRAMOV, V.S. - ABRAMOV, V.S.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000100210015-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 20, 2001
• Sequence Number: 15
• Publication Date: December 31, 1967
• Content Type: SUMMARY

It it It It M a Is V 4 4, #1 it it if 4
AA A _J, i -sit 0
At
A. h. Axtxis.vv and V,
.0 Alawoov. ISWJJ. Akad.
Vdil Ndisk Ojdj. Kh,..
to 1 10"' Z'3-4'-To (VtO)WONS (from (1-4 g, Na
And 2.4 g. (9to),11011 in &j Mi. HII(j) was added slowly
vigorous action ensued
00 4 S_ JHtO#C)#CHljr in HtIO;
00 a and rapid pptn. of N&Br took place; After the a4ldn. the 1.00
13 -60
00 a 7; "*"Lt' *&A ficit" 18 Insists- On 4 water Wth. the cooled
kilt. trftted with HlO and the org layer slvao, gi%ing
4 g. cmde (1.93 X. purt~ ich(coA6111 (1) Yield).
00 Vw Of (EtO)sPOK in a similar expl. gave W ~ L When .00
0 0 Z! (hilthChOICI was used, hosrem. (EtojIPt).x& reacted X00
00-3, %lowly and required 2 his. boiling until 2.j.,P S. Nscl zoo
plitil.; in I exist. the org. 61tritte gikvr 7~, 1. in otlk-t
cipts. I could not tm "led at all. The %attic result
00,31 was obtained with (EtO),POK. No other Identifiable roe
=00
00%3 bubstancrit-sirmismislated. loan attempt lodrt. viliellur
he formation of free radicals of -*tO.C) und r
It 0 lIb.C ,06
00- (previously cilm-erved in similar rrswtion,t of PhClIr
00,111 U. Ross. Phyi.-Chrits. Ser. 61. lirLithr-ho)) prevvAm
the formation at the distrarric products or (be forrijer arise
0 'T
0
from dissocts. of the latter. the foliowing exist. was per- 0
fartutd. To (EIO)jPONa (from 0.6 g. Na and 3.7 S.
t Hio),11011) in BW was added a mist. aill 3 s. O-ANC),-
Clilir and 4.2 g. Ph,ClIr; usunediairly the guldi,n color
44 Ph,C twcaribe visal4e; after brief standing in contart
ills all, an abundant pptn. of (1111,C)M. In. JPW (hoin
be a
F1010, Ittok platv. Di,tn. of the, filtrate gavu A striall
anit. 111 1. In. 74.5-5.5* (firoul dil. FtOll). Sinsiv no
was found. it bias volh-ludi'd that the tsoo
44 the ;rackion its more cotulex thAu inere bet-it.
Coarw
L A OtIALLWA61CAL WIN, ill Xa.X and formation -of ftm milica Is. G. M. K. tioe
Wee
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00
00 Reaction of hiduz~njSaMMM& with cyclones
ud-=- Sh-hi-k-y.. Vt"t.
44*
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es l
r V6
Imir I tell splWilylvirl 1,11will adwt"Itir 1AS'd
00 14,111CO1 bral"I In a WAIrd Iulw 43 lim at 414.1 U,
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ir 1
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=0

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IICI Cvt,l,,nr I 1 :1 g.). 'I fill. CCI,:CIICI 41i'l 1.'.

f
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1.4r.A. I.Mil III Ow lit.
%%hwh In Ow I. in All ".If
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too

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K rf It it I rw 0 Of 0

0 0 * 0 0 0 0 0 0 0
0 0 0 0.0 0 0 0 0 0
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0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 00 0 000000
0 g :10 0 0 0 o 0 o o 0 0 o 0 o 0 0 lit 0 0
ill o 0

ABIWADV V. S.
UM/Chem'10try - Synthesis) Dien* I Mar 1948'
Chemistry - Cyollo Compounds
"Diene Synthesis ofCyol1o Compounds by the Dialky-
lacetylidee of Mercury," V. S. Abramov) L. A. Shap-
shinskaya, 2 pp
"Dok Akad Nauk 888H., Nova Bar" Vol LIZ, Do 7
As dienophyl) authors oboes dialk7laoetylen1doe of
mercury: First) to test whether or not they react-
with dienes, and secondly, In case the reaction takes
place) to synthesize polycyclical dimercurial organio
ompounds with their help,, wbere the atoms of mercury
stand in 0-position and the synthesis Is difTioult
other methods. Report results breifly. Submitted
Aoadmiolen A. Yo. Arbuzov) 23 Doc 1947.
TA&I. 47T7
PAJdT7

e 9 0 41 41 a a
1. it ill v 61 1. u it Vin&
ee
C'p Ditne mIntheids with cydones
Wid v Mid Xjhk.k,.N%m sp4.~.
A. Ond Ifoll fill Ow
tile I'll"611.11.1v .101
"i'lltell tv'14.15r, unit etli%lrll(.
Ilie pitmAry Alto. of ttic C I I, - vild 0 [111- Icagrilt t..
i'l tile collpigalt-1 C atolll~ I'l tile ty'.1i'lle to gl%c .1 tall.
Ill Ilk I Ilk. ill, $I'll 111 1-1 i4p. 1.1. vull C
00 hnin'. I,, it,,- lativi .4 ulli'll 1, 111,11
C st.mi .4 ih~
phir the Ill '111 ..%- 1he li"A
IM111-11,010, 111111111,X 11,1111 file 1-1 1-1 file -00
(.if I"'Ilyl bridge and II.X. The h". tit file
I lilirt aplitaf, I,, 1w a imple clitniii-itioti Ct) by 0" -
3
'the 1'~' 4 fix 40
00 Imlild..
09 iwt permit a definite comlis,ion. tit !ctijj:
AA "S .0-1r I(, yitl-l lompicir a,tdiwt, ititi,t IK- figm-Ird Ili I if 0
difftrrol light frami tile mlit-tr 4%-dmirik. st~ addmt- tit
tit, 1'. Ifult Ill 1"., 0) 1~ i"'t 1111.
1l..Iv 1W VII14.1111ril by Ow tvildri" I to ill,-
ting *11)CTTIIJI dmomp'l .'f
Its adducts in fligh-Wiling rake J
deriv. tit tricyclone. and attriulltk to pr-lucc*the I---% of
Only C( 1, 10 tic fOIIO%Cd Ilk' Ill IlOtOgel'Ation. failcil.
kvi-Lll~lll
Le 0
ctasJOKOIL.
t Fo 9
leri
it IV
0
09 00 0 00 0 06 es 0 0 00 see go
0 0 le te

Alkoxy - substituted esters of phosphorous Acid and their
reaction with holosubstituted ethers. V. S. Almamov anti
N F. Try'al-ii'vil I zhadr. OblAwkel Kkim. (J. Gen
Chrin.) A14 VIVO. -Addii lit I inol. PCL to 114 g.
.:I 11).A.1 NII,(Wif kAI:()II in 1%2 a. CI molli.) pure Me,
%'ph anti x'iii fill. with froliling, followed by stirring
0.3 lit. AIM filltili,,n, save 71'", (Men ('11, CHIMIP (1).
14 I:;M 5 Will', lij, 1.41112, i1," 11tis 12 91 was
lIcAlcil Willi L5 K. C111 (it 11111. Ilse to 45') Slid the mill.
%arturd until a ch.ir miln. finincd, 11111 "101iflit fAi1V(I 10
give a vfy,t. u-I'lott; brAtitis 7.41 g. "lit with 4 A Mc-
(WII,Cll,ltr It, hr% at 141, 'of' give fio-m`~ (4.5 x
WOCH, of I ) ('11, ('11.4 1 Ile) 1. 1), U-5 411.5" 11 j* 1.
III-JIVII 'Aith Ill 1111. ill'; IICI
r'.1 hm I:III ~W Ave an uplwr ljyrr ill Mt-thyl
"I I"s" vv 311111;11 q. lAyet IM-SAIIII.Ably ('01118. NIO )Cllr
,just) evalml. fAill-11 tu virld a cryst.
.1
pro-luct; 'AdIIII. of :1.4 11. N t(.VCII,Ilr to 's A. I g.Lve a
vijmou~ trAction mid the millt. heated 1.5 firs. to 1-511'
gAve 3.5 a. Ifei)(*It,llt)(01*11,Clt,().11,),, b, 154 6'.
Ila IM 4'. 0* 1 1:175, Ill,' 1.14-1A, which on hydrolysis
~
10111111 10'; IICI At 1~!il !ill' failud to give a cryst. acid.
A10 :1 S g. I:toCll,ltr in I.,%
Similmly. 7 ir lit%. at 150,
rave 1.2 K. Eto(*11,1'(lfo('11,('1141,itr),, 1%, PLI if V.
mjr 1.137~3. .1o,11 Aj- fAlit-tt ill fill, .1 I,jul
.16.11 Att-f 11) 111,. 'Allh III' ~ IICI At 1:01 'Of , Pff 1., 11. 111
(.',a.) all'ISC. I V.,v. ill I ,dir- .41 1.7s), 721; j1rof.71,110-
I., , 1.7.7 11 . mi? 1 Mlsl~ III, 1 1-11
SIfTIIIAI I'VAI 1111H Ill fill' 1 .11.1 1.15] a ~ I'C a lit, W I I: -
CII'mi-IIIJ 135K. %1t IN I'll ill :01 fill. Fill I ItAvr jjjrr:I
lir,, WV; 11' l" rili 9" Pill fI-*
f I IKII, ithich 11-1 1,6110 1(~ (.,fill r .)lilt (11pnins 41mlict,
.0,1111-1 '111,- r,t(r fill 14 L' K ) -'Illd :1 9 FfOC11,11.11,111f
allf-ir " lit.,. a I.,o) 1~) , r,,%,,- 7. 5 it.
010 Ill- 'I I., I.. I't I I '. " I? I - 1.172. -1:- I.f Rill, . hit 11 FAII,,1
gl%, a ".10 .4, 0 ,it "fill Ill"; IICI I III III,
at 140 4*41 '1- 11 oig .110 :3.1 K. %lit WC11,11T Kalir Aftrf
la,. at 1-*01' 65 K. lief)(71, Ill V I It Its( 10,1N)T. Ill 6
155 11', oij, 1 1:11-1, 0:1 1 (11,7, (FAI44 if) give ;I -A,hij
Acid oil li~.Illllg "lilt Ill', IICI if, 114, CAVI; mlll'!~arlv
V I"IMI'llf C.Ifte fi 5 K 1.10 ~f 00/j 714 it), I,. hit
if 1? 1.13411, 1:'- 1.072 1.11.) fAiI(A 1.) give it "Ill
acid). whilc Ill C. 1. Awl 5.1 r. PrOCIllfir rAVC ill 1.3 his
it 130-flo', 7.7 x. bi 1,14.5-
59% "V Lrgil. '11., %11101 al'o failetl togi%e R solld
A' H.

IN

AAO%Yisoptopzl esters of phosphmut acid and their
popettec 1% '. 4. Alwtill- ki-I F N NArl icV., (K41411
Stakle l1niv.), AUT. 116,kw Khlm. (J. (wit. Owni, 1 20.
lon 4-i(ION11- l(criewillOWFI, b, 1701-1 *. " I?
I VVNI. 'I.- Ow," F1011 4ml 1-topr1rilt mWe ilk It"'
pomme %4 Vkl It 1- It'% It %trl\*"-~ ""'I :ttot "I'
Foo) frevited with liv 4-1111C '11"I"Al- Wfilwl ;w it 11i"1,
X-tvr 711,; 1 (11. Ilk 1&1 8'. stir
I tX10, d" OW~I; I 'Alth IM/ fr-1001
.4 1,k V1,41. I tit I lw
1 0- A It I will, 1105 K
1'. 0? 1 1410, , . I I.-I.I. frill"
1111"I 1~k 1241, 9 It- M %
tt%IIC JAVT FJOCRICH 1, IOL2-4- (vacli'll"
"ininflY, 10 9
NJ! 11,1* 1 01~1. S - I
f(.. t1wit kert 1-2 hill.
ilf"Iftf %lowly witb 3.7 1. 14CCITiON 'mom)" t.., 101% M"
nw. 1mv 4A A. 'lei W01.1 I() C. I Atilt 4 a.
K ove 1 1W It. 11
I A31j, t 1. - 1 41441. 'A title I tit' I lit I I'l Ilk "A I -,c I 't I'lol
Ilk J."S fl.) ~ NJ, I cilo ,4114" 1 V.~I. AIM
ItOW11-cl K,Ive /:,I It'll. Vt 1~ OR ". I., '-*1,) 13% oil,,
tl'.* 1 1013 I-ToIC11:01ii Ili - It,. It I-i" S .
10711, If,* I?S_,P 111-11 1-1111101-111 IMAC. VOll. Alld
1-144111 ;k,; nlx,v~, 1.7411 6: k ,1111 o I it PCI, m flu-
.f 51 if M-S~1111 it, 11.$ ."1 1-4.11 gt%v 11~
1, , 111) ~ ~ fit. . % ., 1.1 4
-Ok V, A"tW
Alei ow-l"t $I'll,' ( 'Ib ); P. I. , I I! I Chill. I:.
I)ANNI3. HO 001.4,11-Pti. !,~, 11% ~.'l a 411.1 Ittl
X. !w%. rul F1,41 fii-,vcd tolt 622 llk'l, lit
111v l"Ll ..11, 1.1frool from 01i .1111m. 110.
ktlll~li . ,,.It
oict-, oodif V md -mc Pill ill A,Ho 4 X, IVI, ok
dw vol.t I., SO it '10 W.'llifix ..0.
-lf%- aft pik" K. (04 101,cil l[CO"PI Iff. It, 135
"1" 1 ill$!; ~IT11114f tl~c-ki 14"K PhOCIllcill-
Oll zlt,4 '33 2 S, 11CI, %.,w .1. All
limb,1111.1ble ft.,wile. all, ( I'M
('I (.Cl jj-4,vvt. ."Ijot I.,
61 gtv. 'N
G M K,-qlJ-ff

CA
Rtattion of dWkyl phorsphitoll with aldehyditil and
kistass" (a now method of synthesis of listore of hysilozy-
ailmophoo lionic acidsl. S. AWAtuoy (S. M. Kitov
Clicin -TtIllol. 11) Pokudy Akad. Veak
A A.S.R1 7.11 487 1-he ptclus. o(hydroscyalliz.1.
phl4pbouic acids I, triloc"tO And the usircharizin (it 14will-l-
tu-n of RIUOR)s trout RN and (ROYK)NA Ill diprustr&
'the bitter rfA,jitjj is Jjrjrrl-r,I it? proceed by oddii, of RX\
j,j fRo),PoNsi IlAawril oil IiiYakni P) to yield (RO)sP-
,ox,s)(Rm this view it,lulfivisfied by the formation of ktKh
Aducts with (undescribed) and 111
it,al"is of Lifir Its Lit with RM11114)(01A)s (ftho Ull-
high lenitivs. ThertAtti4gli3believelltispro-
terri by muldo. of thr. catimmul C atolls of the RX to the
unshared election lisir of 11. yielding a putsitirtly charged
cents &I Pat ors-, lit ithful, Is the sits. X son A-Lis us vanpiriks;
of the rt"tion I lot Ail-luct thell Islay fle.ve cither RX ..r
Sax. thus privillis RojN40)II(Olk (it RI1U(Okj#. live
direction of Ilse cleavage bring detil. by the nature at the
radiLAI R directly bound to 11, by the statute of the hallfir
X. Ivy Ilse mAtittle of Ilse OR radivuls, and tiv the irsilill, fluids.
ticins. Anothtir mi-ch4ni%ru thAt it ;,irmble I, shovin lit
kill
jRo)IllOx4 + R 'N - jRWAosoR
(11t0 ))R 4 Nt * t- X . Ilse 141 let Is I r lift
I "I X&
11011 k"1116 Ill live lit),-11111AY 411 frA011111% Ill M, ) )l -0
with (viliscs touiltd.. thAt 1.1utor siu,ih-gou%ly Ill RX;
isluous these tire A111111V&S Allil lIVIMIC1. III 'A blill live C 4.1
INU CO g701111 IKVUIIIV* VAI41111*1, Iwinulluis the fociust-
- of addlictil of the tyliv: (RO)lI1to)CRo Ndt', 111111411
Itll 44ciddiwil 11#0 ykl,l iRo;,P(0)Cx0)ll. The reActrivis
111' dCAIj1,1YL,1*1 I.I., illit* 111111. .1 M14,11.1 IX NICONA. M lut.11 1-
I', to be 'ilI of Ilit, dLAILyl phinphar Aud the cialitin) I
A 1,11441 thAlu IVA(tklll ill W1110i
0) of I (Cultsiteb the N.1 front the ultrFlIx-41141c
dtluc(. The yields ar,imlaoi-rd %%hii the fAwaii, ,,III.
Los the cabortyl cos it. . ancirsuir I.-Iiiii4litji of the
C
o
co groult (Ous. lizil glivi, a the~6-1 yww". Stivir :W
new C.Itts vvire Itit-I.I. Illone are 'le'llfird). it 11 ch Ate.
tz - 1 11
IL4, .431.1 Oll-PI 1.11111'All Air pirwill III file r". $:'lot, 4
jRO)jI'kO)C~OIl)X'R', Vilill" R' 11 1/ ~Jlll It' 11 rijbil H.
Ale, 1'r, or Pit; abo Invultivord We tillilittis. tA)tll R, M R, a
acre. cithcr crpi. uthill. Its %viy vu.,ou, liquids. I sk-litilt.4.
IkAl ill Ilse 1.11AUtI, 1114) %IvLl tllj~j.l. L,I,.t~ villsh- lvl,L,. -
uItful, 4-1 0 1 Ivy tilt m,ty )-"W the v,v#t-i-wdma alLox
allikutphosphunates. (~. M. K'Milalvi'll

A=on of Lakqva subsututed etb*rs oa the sodtam malft ed
16 _41karyras!t Vo*Gphwms acks Abrzrr~.- an?
I
~
A %jilstm~-ra KAZ4.-, S'.!l t...-
I f J. (-, h,rr. 2 1. J' I -! - - "',: : cf. CA 17,
.;.-P: 4 1, fir 1A PC. 9 - If "r IC
,hr
9. Me 'C;f'
ar's 14 x
4.11
E"O hcat. Th~ NA '!~nV -11h
mc C
fa--e to ri~r a-av NzC!; aO-n of ),W)oCif,lsr
-.puily ga%~ A fA %:~t aft" - 5 _-r fyn ;i sl~~m ~wh
-!wn. of *~,e ~ixl mm-4! cJ ?ht Nalir.
-_Ddje cd ' lf,,r)CIf,, , Sa,, i- 0 CiijuMo, -from
.!Ofj-F!,f~ ~ -()Cif:lir C.~e fA% cryu.
v.jpCH'Cji.-'~ Val) P10 PrOelf,ts, Ca'v
7 --, I JV,~j -( %aj il.' (P, 11- and Jiu4r)CffCJ
Z.ve 055-, :If,( He ~- ) Cj!o,jhu. K1. (M.3
1with EVocif-C-11,0:1 ri- rnc,; trojol.
CH'O.po.q. at,- 1.43f-,