SCIENTIFIC ABSTRACT ANDREYEVA, L.P. - ANDREYEVA, M. G.
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ORFSHKINP P.T.; ANDRLTE7Ay L.P.
Relaxation effects of alectroconductivity in industrial rafractorle3
at high temperatures. Izv. vys. ucheb. zav.; fiz. 8 no.lsl55-
161 165. (MIRA 180)
1. Slbirskiy metallurgicheskly Institut imeni Ordzhonikidze.
- . - I I.-II.. I-- I FIT..
ORESHKIN, P.T.; KHRAMMIVA, M.Nj ABDREYWA, L.P.
Electric conductivity of cocide refractories at high
temperatures. Izv, v7s. ucheb. zav.; chern. met.
6 no.2:3.42-149 163. (MIRA 16-3)
1. Sibirakiy metallurgichookiy instituto
(Refractory materials-Electric properties)
VISIUUAKOVA~ Ye.S.., in2h.; RIft4fAIITSVA,, N.F.., inzh.; 130ROIVICHEV, G.A.,
inzh.; PITMOVA, L.V., Inzh.; FMAUNIN, N.I., inzb.; IAESXTI-lp
I.M... inzh.; AIIDIMYEVA, L.P., inzh.; BIS)ILIIKEVICI!, G.V., inzh.,-
RYABIDIIIIA, A.I.,inzh.,- VIOSMID, N.S., red. Gazety; K0111MOV,
A.Lp otv. red.; ITNITSKIY, V.P., red.; FLIGELIMAN, S.M., red.;
ROZEDAYKIIIAs V., tekhn. red.
(Kalinin Artificial Fiber Combine] Kalininskii korbinat islms-
tvannogo vololma. Kalinin, Kalininskoe hnizhnoe izd-vo, 1960.
92 P. (MIRA 15:8)
1. Kalininskiy kombinat isk-usstvennogo vololma (for an except
Komkcnr, Yunitskiy, Fligellman, Rozhdaykina).
(Kalinin-Textile fibers, Synthetic)
Coefficients of
iron silicides.
117 165.
politekhnicheskiy
-ACCESSION'01 ~ ---A?5010202-- 7- UlVIO43/65/000/003/
-0061/0068
iAUMORi Andreyevag Le Pa
TITLE: Concerning the practical.Wlication of the orthogonal power-series meth
:SOURCEI Mosc~m_& - -Uav'er-isitet'.-.Vyohi'bliteltMy.- teentr. Sbornik rabot, no 3i 1965i
;Vyc1Asl1tel1xWyemeto4V i programairovwAye (Computing methods and progr
t TOPIC TAGSt power series method,~numerical calculation,, mtrix diagonalization,
subprogram.. amputer programing
order 38 inclusive. The-set consists of three-subprograms, each of which-its
standard and can be used independent4 in the presence of available information.
The computation algorithm realized by the subprograms is based on the power-series
method,, Each subprogram is described and the use of subprograms is illustrated
'with examples of the diagonalization of a 10-th order matrix,, the determination of
the eigenvalues and eigenvectors of a 14-th order matrix, the determination of the
1_Ca,d 1/2
ANDREYEVA, L.P.
Adopt the work practices of the brigades of communist labor
of the Winin Combine. Dim. volok. no.l126-27 165.
(MIn 18 t 2)
1. Kalininskiy kombinat iskuastvennogo volokna.
BOGUN, A.Fe; RUSNAKp N.Te; ANERMVA, L.S., red.; LAVPY.NOVA, H.B.,
tekhn.red.
[Organization and mechanization of docking operational
Opyt organizataii i mokhanizateii dokovvkh rabot, Koskva,
Izd-vo "Morskoi tranuport9l 1959. 100 p. (MIRA 13:2)
(Ships--Maintenance and repair) (Dry docks)
CMWCHENKO, Ivan Ivanovich; GKOBELIN, L.T., red.; 4~P~~ -
rad.1 LAYRENOTA, N.B., takha.red.
[Internal combustion marine engines] Sudovye dvigateli vnutrannago
agorantia. Izd.2., perer..i dop. Moskva, 1zd-vo "Horskol transport,"
1960. 673 p. (xiRA 14:3)
(Marine engines) (Gas and oil engines)
N"
CHUMACHENKO, Ivan Ivanovich; SKOBELING, L.V., red.; ANDIWEVA, L.S.,-red.1
IAVFMOVA, N.B.p tekhn. red. t-~~
[Marine internal-combustion engines] Sudovve dvigateli vrAxtrennego
sgoraniia. Izd.2. perer. i dop. Moskva, Izd-vo "Morksoi transportf"
1960. 675 P. (Marine engines) (YMA 140)
SUSHKOV$ Boris Borisovich; ANDPMEVA, L.S., red.; TIKHONOVA, Te.A.9 tekhn,
red.
(Marine separators and shore installations for separating water from
petroleum products] Sudovye separatory i beregovye ustanoyki dlia ot-
deleniia Tody ot neflteproduktov. Moskva., izd-vo *Morskou transports"
1961. 336 p. (MIU 14:10
(Oil pollution of rivers, harbors, etc.)
(Separatora (Machines))
ELITSOV, Stepan Petrovich; NOVIKOV, Teodor Nikitovich; NEDZVEDSKIY,
Pavel Ivanovich; ANDMEVA, L.S. red.; LAVREHOVA) N.D.,
toklin. red.,. ~f -- ------
[Working t and rest perioids,of the workers of marine
transportation)llabochee vremia i vremia otdykha rabotnikov ror-
skogo transporta. Moskva., Izd-vo "Morskoi transport," 1961.
174 P. (MIRA 15:8)
(Merchant marine)
KRUCHININ, Yuriy Aleksandrovich; ANDREYEVA.-Lj9., red.; USANOVA,
N.B., takhn. red.
(Trip into the ice age] Putashestvis v lednikovyi period.
Moskva, Izd-vo "Morskoi transport," 1963. 134 p.
(MIRA 16:7)
(Queen Maud Land)
CHEREVICRNYY, Ivan Ivanovich, polyarnyy letchik, Geroy Sovetskogo
Soyuza; ANDREYEVA, L.S,red.; USANOVA, N.B., tekhn. red.
[In the Antarctic sky] V nebe Antarkidy. Moskva, Izd-vo
"Morskoi transport," 1963. 147 P. (MIRA 16:5)
(Antarctic regions--Aerial exploration)
ITSKOVICH, Yuriy Leonidovich; SKOBELING, L.V., red.; ANDREYEVA,
L.S., red.
rElectric drives on ships] Sudovye eloktricheskie privody.
Moskva, Izd-vo "Morskoi transport," 190. 583 p.
(MIRA 17:5)
y,UF,c)FATKjj,,', Fatr Vasillyevich; AEM1EYEVA) L.S., red.;
L.V. . red.
[Automation of electric ship propulsion systew-o] Avtoma-
tizatAin grobnykh olektrichookikh ustanovok. Moz;kva,
Transport, 19(d.. 202 p. (NIRA 17:9)
BROYTW, A.A.1 DEREVICH, V.A.; SEDOR, A.Ml.j EDL11~LML,_~* S.S,
red.j SKOBELINGp L.V., red.
[Load--hoisting machines and arrangements on ships] Sudovye
gruzopod"emnyo mashirq i ustrointva. Moskva, Transport.
1964. 298 p. (MIRA 17*-.12)
Sh'UB114SKr-,'- Aleksandr rosifuvioh,; KA,,jAI,Cj'V, Yurly Nikolayevich;
red.; ZARE"11,', I.V.; rea.
,~~IIE4ANA, i~
[Electrician in hdrbor mo~,heaiizatlonj Eloktromonter
portovoi mekhanivitsii. Mloskvap Transportt 1965. 183 p -
(PIRA 18:9)
F i T I I , ~j: ~
. -1 Aloiz Alnizovich; Al,.:1.1'4E,FVA, I r
I ""A rol -, 1
(On streets; port ~-litles of "
,e gorodn --'vr-,,,y.
Illa chuzhikh ulitsakli, pwtov- V, I ~ n .1
Moskva, Transport, 1965. 229 P. (:,"RA W!~ 11
51111101w, vT; ~~4A
TURBAKOV, A.A.;
[Electrical engineering and the electrical equipment of
ships) Elelctroteklinika I alektrooborudovanie sudov. Mo-
skva, Transports 1965. 446 p. (MIRA 18:9)
BARTOSHEVICHp Ye.N.;
MARTYNEHKO,
Pblioqrelitislike
with live Sabin v
M.B.; LESHCHINSKAYA., Ye.V.;
ANDREYKVAjJL~�_t; ASHMMNA,
children inoculated
18 no.6:16-.;-l 163.
(MIRA 17: 1)
SYCHEV, Konstantin Arsentlyevich; ANDREYLIVAI_L.S., red,; LAVRENOVA, N.B.y
tekbn. red.
[On a drifting ice flool Na dreifuiushchem ledianom ostrove. Mo-
skva, Izd-vo UMorskoi transport,," 1961. 112 P. (MIRA 1012)
(Arctic regiono-Russian exploration)
m
MAKSNOVp Ivan Georgiyevioh; POZNYAKOVA, Go
- L.S., red.; LAVRENOVA, N.B.# tekhn.
Yurlyevna-; ANDREYEVA)._
[Workdays in a large port) Budni bollsbogo
vo "Morskoi transport," 1961. 38 p.
(Leningrad-Harbor) (Cargo
ABREMA, L. S.
Introduce public control in building achoolhouass. Sell.stroi.
14 no.8:4-5 Ag '59. (14IRA 12:12)
1. Zaveduyushchiy Moskovskim oblastnym otdelom narodnogo
obrazovaniya. (SchoolhOUBOO)
~O
ANERFYV,VA, L. V.
Andreyeva, L. V.-"The nir-stern methoe f burning out -~cke in tube f-jrnaces," Irl th(,
Tn-uc-h
symposium: . mboty studentov gorno-metvllur~. In--tov Plorkvy, ll~scow, 1969,
'20-L2
P. I-
I, .
SO: U-I.'--31;, 20- Oct 5?, (LetOTis '~hurnl njvkh Statey, No. 10'. l9h9).
f 7777n~7
im Nlroyt*,- ~
--v . - --Nilm ~ 4 --- - --
. - . ~e. 'r. . -,= t::, te'l- ..~
T
KQMUKHC A
IV , L.I., inzh., SUDIANOV.~, T.A., inzh.,, 1L.V. inzh.
Methodology for calculating r.*--* material eypenditmre for krdt
outerwar garment pieces. Nauch.-issl.trudy V'N11TP no.4:71-117
'63. 1 (KRA 17:4)
SARANCHAj Ye.T.;. ABRDSIMOVAv A.M.; ANDR"EVA, L.V.
Production of concentrated liquid ammoniate salts of carbon
dioxide based on ammonium carbonate and urea. Khim. prom. 41
no.5083-384 YV 165. (KM 18s6)
ANDREYEVA, L. Yo.
"Calculation for the Rigidity of Diaphragns and Diaphragm Boxes." Sub 17 Sep 51,
Yoscovr Order of the Labor Red Banner Higher Technical School imeni Bauman.
Dissertations presented for science and engineerinp derrees in Moscow during 1951.
SO: Sim. No. hOOp 9 May 55.
ANDRMVA, L. Ys., kandidat teklinicheakikh nauk.
Compu--ation of serrate profiled membranes; rigidity calculation. LTrudy)
MVTU no.16:55-75 152. (MLEA 6-.6)
(Slastic plates and shells)
I
i
i
I
I
I
ANDRMVA, L.Ye., kandidat tekhnicheskikh nauk.
Computution of membrunes with linear characteristics under pressure. tTrudv)
MVTU no.16:76-89 152. (MLRA 6:6)
(Slastic plates and shells) -
AMMUTA, L.Ya.. kandidat tekhnicheskikh nauk.
-----------
Calculation of sloped trapezoidal corrugated membranes. [TrudyJ XYTU
no.26:123-141 133. (MLRA 7:3)
(21astic plates and shall@)
ANDREMA, L.Ye., kandidat takhnichaskikh nauk.
....... ,
Calculation of conical and spharical corrugated membranes. [TrtIdyj
KTTU no.26:143-150 153. OMU 7:5)
(Elastic plate* and shells)
ANDRXYNVA,L.Ye.
- 1.
i concerning corrugated diaphrAgMS
plates. Inzh.sbor. no.21:128-lbl
(Elastic plates and shells)
ANMTEVA, L.Ye.,
Calculation of
155. (Slastic
ANDREYXVA, L. Ye.
~ - -
,
Calculating corrugated diaphragm characteristics. Priborostroenie
no.3;11-17 Mr 156. (MM 9-8)
(Elastic plates and shells)
ANDWEVA, L.Ye., dote.. kanA.tekhn.nauk
, .
Determining characteristics and effective areas of corrugated
membranes with rigid centers. Naucb.dokl.vys.shkoly; maeb.i
prib, no.1:218-227 1,58. (MIRA 12:1)
1. Predstavleno kafodroy "Soprotivienlye materialov" Moskovekogo
vy8abego tokhnicheskopp uchilisbeba iteni N.M. Baumana.
(Elastic plates and shells)
ANDREYEVA L Ye - FEDDOSIYEV, V.I., doktor tekhn. nauk, prof... red.;
===RTiaftP G.O.p dok-tor tekhn.naukv retsenzent; AKIMOVA,
A.G., red. izd-va; ELIKIND, V.D., tekhn. red.
(Elastic elements of instruments]Uprugie elementy priborov. Pod
red. V.I.Feodooleva. Moskvap Mashgizv 1962. 254 pe
(MIRA 15:9)
(Measuring instruments)
AGPWIROV., V.L., kand. tekhn. nauk; AMEWYA11CHIR, A.V., inzb.;
ANDREYEVA L.Yeej kand. tekhn. nauk; BIDER[W1, V.L., doktor
'T4 hn. -;;ik
nauk; BOYARSHINOV, S.V., kand. tekhn. nauk; VOLTIR,
A.S., prof., doktor tekhn. nauk; DIMENTBERG, F.M., doktor
tekhn. nauk$ KOSWUK, A.G., kand. tekhn. nauk; MAKUSHIN, V.M...
kand. tekhn. nauk; MASLOV, G.S., kand. tekhn. nauk; MALININ,
N.N., prof., doktor tekhn. nauk; PONOMAREV, S.D., prof. doktor
tekhn. naukj PRIGOROVSK171 N.I.p prof., doktor takhn. nauk;
SERENSElt S.V.9 akademik; STEPANOVA, V.S.0 inzh.; STRELYAYEVy
V.S.j, inzb.,- TRAPEZIN, I.I., prof., doktor tekhn. nauk;
UMANSKIY~ A.A., prof.) doktor tekhn. nauk; FEODOS'Yb"QT) V.I.)
prof., doktor tekhn. nauk; SHATALOV, K.T., doktortDkhn.nauk;
YUMATOVp V.F.p kand. tekhn. nauk; BLAGOSKLONOVAI NvYuop red*
izd-va,- YEVSTRATIYEV, A.I., red. izd-va; SOKOWVA, T.F.0
tekhn. red.
(Manual for a mechanical engineer in six volumes] Spravochnik
mashinistroitelia v shesti tomakh. Red. sovet N.S.Acherkan i
dre Izd-3.j ispr. i dop. Moskva) Mashgiz. Vol-3. 1962. 651 P-
(MIRA 15:4)
1. Akademiya nauk USSR (for Serensen).
(Machinery-Design)
ANDREMA... M.; K11HYFETS, L.S.; GOLISKAYA, I.F., inzh.-metodist;
VODYANITSKAYA, Zh.I.; KOZHEVNIKOVA, E.I., starshiy nauchnyy
sotrudnik; BLIDMAN, A.I.; VORONOV, B.V.
Echibitions and displays. Infom. biul. VDNKH no.11 110-llpl5-18.,
26-27,31-32 N 163 (MIRA 18:1-)
I*Starshiy ekskursovod pavillona "nimicheskaya promyshlennost,"
na Vystavke dostizhaniy narodnogo khozyay8tva SSSR (for Andreyeva).
2. GlavnyY inzh. pavilions. "Stroitellnyye materialy* na Vystavke
dostizhaniy narodnogo khozyaystva, SSSR (for Kheyfets). 3. Pav!"on
"Ehorgeticheskoye stroitellstv-o* na Vystavke dostizheniy narodnogo
khozyaystva SSSR (for Gollskaya). 4. Direktor pavillona "Sellikoye
stroitellstvol"na Vystavke dostizheniy narodnogo khozyaystva
SSSR (for Vodyanitskaya). 5. Pavil(on "Sellskoye stroitel'stvo*
na Vystavke dostizheniy narodnogo khozyaystva SSSR (for Kozhev-
nikova). 6. Starshiy inzh.-metodist po khraneniyu i pererabotke
zerma paviltona. 'qMraneniye i pererabotka merna" na Vystavke
cinntizhen1v nn--,4noeo khoz-yaystva SSSR (for Midman)e 7. Glavnyy
metodist Pavillona "Professiorallnotakhnicheskoys obrazovaniye-*
na Vystavke dostizheniy narodnogo khozyayetva SSSR (for Voronov).
ANDRMTA, H.
On the rivers of Kamchatka. Vokrug ovate no.8:46-47 Ag 134.
(HLRA 7:9)
(Kamchatka--Fisheries) (7isheries--Xamchatka)
k ~ ij ~ ~,2( ~ "i 4'L ,,'t .
"Iflie Installaticii of' ;WrJi FroA-mvC Unin-s on 11*
.1
ConotriicLocl oil 1111.1aY Filterin., quaternary Depo~;A,3 In the
Central Blac',-Earth Rc,"ions." C,,nI Geol-I.An J`ci, Iloscow 3tate
U ii--icni 1'.. V. Lomonosov, '-' Oct 54. (VI4, 2/+ Jej) 54)
30: Skri 432, 2'-.' I'lar 55
-4-
,7q~:
212131 "OtlCAL-v 01 Fo Illil Cu Coulpits in .0indepwr Vajwr
tin the Quality nf CQtj~tr %,,, VIllanle sode.6houlla 'ilaplera
I snedl v k -('jj~g
unflcn%~lorlno "majet nn k8chesivo kondenaft(a.
ruv. (Rusm'an'.) and
Bitmathnala vml entiml, no. k Aug.
A tulal Fe and Cu vontent exemling 0.02~ vallb" a"re"' 4 (if
weAtiess in thu izondensti dielechic. 'fables, graphs,
with
1) Wnitwition of s. p
48, 5710g.-Cu was -jtmt,,l wk1b in mi m
r1l"uIn Ill tim presen" of KIQ,, KCrO,, NabrO,
or KCIOx. Gcod results wtre obtained when N
tAdded to the CL- sola. ill cillon"itie.1 imufficient vn completc)v
dbWvc tbo Qu ppi. and w1wrl titratloil Stoll-d whHe SmIlu
of thn ppt, was pteftht. The Tyresenct c4 NH,4 ill solu n
USSR / General Problems of Pathology. Experimental Treatment. U-5
Abs Jour : Rof Zhur - Biol., No. 10~ 1958, No. 47010
Author : Andr M Rozin., D. L.
Inst t-Wo-f Given
Title The Uae of Rndloactive Phosphorus for the DiaGnosis of
Breast Tumors and Their Complications.
Orig Pub Tr. 1-y Zakavkazek. konforentaii po mod. radiol, Tbilisi,
Gruzmedgiz, 1956, 273-279.
Abstract The distribution of p32 was studied in 55 patients with
malignant and benign tumors of the mammary gland. The
patients were treated with isotopes in the foii3 of
bisubstituted sodium phosphate in a dosis of 0.12 mu curie
In a 40 percent glucose solution, The accumulation of
p32 in the afflicted mammary Gland and in the symmetri-
cally located area of the intact gland was detertined
Card 1/2
, 11 A.
.-TA T-A
USSR/ClEMISTRY - FRIEDEL-CRAFTS
RFACTION
BENZENE
Apr 49
"Mechanism of the Friedel-Crafts Reaction: IX, The Reaction of Trichloroethylene Wigh
Benzene," V. V. Xorshak, K. K. Samplavskaya, M. A. Andreyeva, Moscow Chemicotachnol
Inst imeni D. I. Mendeleyev) 5 3/4 pp
"Zhur Obshch Khim" Vol XIX, No 4
study of subject reaction in the presence of aluminum chloride shows that polynuclear
products of the condensation are similar to those formed when 1., 1-diphenyle-2-
chloroethylene is substituted for the trichloroethylene. In the case of the latter,
they are diphony1methane, triphenylmethane, and anthracens. Sz-bmitted 30 Dec 47.
PA 65/49T24
1 ra d qs, LXWvrff mliia-
:
a
w writ
ts c0 lit t nor due"
the-xv-4
Y
y
it, J,
19"o, t13 w 1, it 50
-Cruimw Do] tly EfAld-s, xylliell readilyfef1w
fir)m iand arv I it Phol I and rill-Tul acids: the -.1 ly - and
m.p art, mhav, lit t1ii... tr,mi, 'nic m ps of tile
JIVII(JUO.' All lolo A ~b-'Lll 0 r1 O.S 11114C fr-tiOn of tile
acid in 0- Thc lit -,~,mqm vur,cs ore
-L I. I-,,, ttt -~rd-
!W7i ';' IL 1~' 1;; it. tjll' 11111 1 Of fill'
it: Th, 11
%
1--4 127-30', nd Fbe Ist ivus sot. in
cl-11 aild UO 4!l1tHl4t. litolir, tht; ?t-Ld ~(--l III If C) uljd
wvre H and f, Ight]
-'UA
FR , 1- .
'I'ili~it"~"- 'nit ether III'L. 1, 11-14. etlectil". In
t It, -:1"cr ".ht 1, it k 1, wn tcd in the avid r rqidui at 1wr t 1
it) t d a nine. Copulynturit wt:re prept. fTLI[l)
find I in " "T ious proportinl;N; th~e ~illilj 11-11V q1th'tRu",
:11!- (-,Ill f"r"l f1hrr,i ('It qrrtching in Ott Cold %lall l1w lit 1,
"1 111. :11,' 1 1-0- t O""'I'l wil, it
Onwouell, sy6ituni of tabled polymninies Irldlidilig ii-Ilittlo
acids. V. V. Romhak, T. M. Frunze, and L it. Dikartyu.
In-rij Akad. Nalsk. S.S.S-R., Oidd 1, li,,7775-uT-)W,
108- 13; Bull. Acad. Sci. U-S.S.R.. Mr. Chrin SIN.
19S6, 101-105(Engl. transhition).-Ternitry systcrn dia-
~rnrrts are preimutir.-d far tnixf%d paly-tniidew pri pA fl-ilm -m-
onlLii,ms -J
an.in,lurld-arloic %cids, and
adipi, , a2elaic, cir sc;x%--ic acid.- 4)T c-.-pruI:),-l-n ',It( Ii- 1 t
ni.ps. and highest soly. are found in products near the cmter~
of the terna-ry diagrants. XC. Polycoridepration of 1,2-
41thlorcietbane -wHh TotrdW- - G. S. K -QV, V. V.
Rmhak, M. MA: And A-7-Rit I 'rQlt"-U' 4-
Test A kad. a Otdtl.-i 1956, 114 -
:19; Bull. Acad. Sci. U.S-S.R., Div, Chem. Sri. 1956, 107-
'111(Engl. tratLdaticit).-Polyc4xidcjLq:Ltion of (CILM4 with
letTuhydronaphthalerie in the pre:~encv of AICIa was studwd
in inixt, 4 vatioui ~itnpns. treatoi 4 hr~. tkt ItK)'. With
-I'm y. 4d 4D.1 P49~wiairia H4L t &~ QW16t. ~nd
in, 4 wt. in formed with ! I !1 0 imici rI Tcualm 1~~ ~( It,
CI .1 DIC IE'. Infil %V( . 1q I
X!6M
jv.~ -6; - payee Irmp nvi CIL;
Z - 2 M inalt edl. lhto tridimensiona) pWyvier &rrns in
this reacti-on. The p,4)mjozk product dries nut slinw ass'Lwo,
.i- C.H. Until th~ ~~h% rr~zchei about 10% volicn. XCI.
Trangarylation of 11,2-dipbertylethene at varfous tempera-
tures. G. S K nl~nikx- and V. V. Karshak. lirveit. A kid.
Allyuk S.S.S R , ()Uej. AAim, A~zvk 1056, '-132 9, B.11
Aead Sm U S.S. R., D.m. JQ56. =J- 7( J~s)gj
uanAafiml ' f C 4 4f . 7.1~'?U qpe~cimr- , 4 ~ t' .
IIP~OPI! M -11,t 11-1, -th AICI., .111. L--V I',
.""I and 11- ..'t If ~V" vVil C.H. detd. Vs (III], Pic T,
m-lual tolyp;ievvl~thyl ",,s i,~,Iatt,l as --Lwal I'b( F-mit
sh,mn graphi'-WY Ind$,-aft that in the trinp. rung.
the tranw0mim it-actn,n is with ;,ki~vmwn
energy 11,400 cal. per mole. The chain gn-i-th !if thr
P'4yrner rm-Ults I-th from inteniction of the rytIviner mols
ami from reactiim >I the monirrurr with a glowITIR Chain-
The mol, wt. of time polyrrwr lnaewso with jising tcmv- IIRL
I Mim: lots fter-
mbout -25.0W-m
i shown initim. -mof. wt. of K7150
fect of CA141YISt concentration on tranSiVylallon Of
pbemylethane. fxvojj. Akad. Nauk S.S.S.R., Odd, Khirn-
Nauk 1036, 2" 42; Bull. Acad. 'q'i V S.S R., DIV Chr"I
Srs 1054, =~-,31(Rngl trans!ation) -lncYvA%e uf concil id
AIC13 us;ed in the reaction (cl part ),CI ~ m,,ults, in grad- &II-N
incmaFirtg yield of the polymer up to 13.0 mole-70 AICII; the
Mte of reaction rises linearly with corim. of AICJ#. The Yiel(l
of tridirrimsiornil polynirr riv-swith increa4,,d A11C), concri in
I Cild S t" I 1v kt, im ".d " 'lit u of t h, o-1 I
dimemional j;,Aymu fOT111% ItTitILUily fl(A!1 OIL
"t . "Xilf Pf.pertiea (d polyesters of
mjiL~L \1 V. K,w~~w!, at,d
enz nd 1,3-butLp
-26, '539-1-109513"~
. pe glycol or 1,3-Ijut 111tiloffic, vuc-
VIC with oxalic,
Ciatt'. Afliflic, rhitllic, pill,elir, arelaic, ~cLiacic, and dc-c-
itTledlic."11-bo-, ylit, acid'. Tht. polycStus IT0111 tC%Tvcn-.eT11Y I I'll-
glycol 11-cre lmolalN wj)('~-u 11t.pq. "I'muo ibv Fisw-t(.1111 ilit( I
nation ; I ~11 mala-'r, III- 1113-h" 111(frm'Itt" til --,',0' lit
-:.A"
111~ 58 110" 41. as'. 41" pittic1itc, m 4~i 01".
ealc,' in 1A 7". 1 lie polycitc-rs (,1 1. wtic
liq1ti(N wifh ~-Ihfirw~Ltklfl tv-mps'. in tile -.I' rjupr
whicl~ .' cimd it allo-ax"'11, Lut i'laich t'..; li--
pronk-1111, v'l I-11, ul.p~ of I,,: ~'OY-1,:1 1; w1im;'
'k-.' LI-1 1~ 1(
lion -wall 11"-A. ".~ KCIV
one and PCtit-1~t~i-13-ler- OYCOir.
of Wjlj))~014)3 and (CII2).(0II)T wem jurlid. %ith dic~ir-
1:-Ylicadd-~Jro.m -x~djc Tbitse wvii
low-McIting ,iilids, gcntj~illy ~ji('.wing a rj,,insi m.p. pa5t. ,it,
dnic acid e!;:VF; the est~15! Milt maIrmii: ~Itid %Vcfc litillidl.,
1-it. ukint which mm~' -.eiltcll a mict T1-
.wC'A;1atzL lut1tra abovi: 111~ rhaatatr'. Tht
I-M givenIs tkith al (xid tti,. n! C Rtotw. deAwY flu lat ti)r
o: -,,vcu~dd scqutuee, beginning Nrim i , ,it, ,
wition uf intmiuj! tttf.p 6jjjt!ity ~mi~ ,,Iy. it, 1w,p-i
.Cxhu.. G' M. Kw~[Aqmll
ILW Chnistr7 - Molecular ac"ounds,
Oftmd 1A Pub- 40- 20/25
Authm j Kolesnikov, Go S.; Korshaki V. V.; !'nj~!yeva, M. A.; and Kitaygorodekvv ~AeL
Title IHigh molecular compounds* Part 90o Polycondenaation of lj2-dichloroothane
with tetralin
Nriodical IIsy. AN SSSR. Otd. khim, nauk 1. 114-119, Jan 1956
Abstraot iThe polycondensation of 102-dichloroathans with tetralin %as investigated in
the presence of aluminum chloride and the basie laws governing thin pol7c*6-
densation process wers.,establi shed, On the bi-'Aa of x-ray, amlyals-it
at-1;2Ldi4 t - -ilyl) othan 4 is ~ the
product
-stages.- 'Me formation of threel~fiiii~aa
polycondeneation products was observed in spite of the fact that the potential
functien of tetralin is only 4.- The effect of benzene-solution concentrations
of polytetralylenethyl, on the polymer moleculv aesociation is.diecuseed.
Seven referencesi 5 USM and 2 Gem. (1921-1955). Tables; graph.
Institution t Aced. of So.# USSR, Inst. of Organoolemental Ccepounds
Slamitted iNovember l8j l954
tj
I'Ap-l-rizaduai A
CM ~Vv;iiiy ~Pilt tkj-yjpktmpbvTIIr addij. V. L,,,~e ~4-
C-IjLjl~1~4 4TfjI kI A. ~Irist. lf-7-77R;
a-d ,Id" f :1 L
7 07
I iflAt
L4
Rl-)Vt ilh Na -, Il
Lit 140' pvt!
Pvc IS 40e P4
10 Lit
tier (I)i.
'.1-- 1 0 1,,
4-1 A-
LIP,
tip
Ilottlit, ut
- wi
LUTHORS: Korshak~ V. V., Gribova, I. A, SOV/62-58-7-14/20'
TITLE: An Investigation Within the Field of Organophosphorus Folymern
(Issledovaniye v oblasti fosfororganicheskikh polimerov)
Communication 4: On the Polyesters of Some Phosphinic Acids and
of Hydroquinone(Soobshcheniye 4. 0 poliefirakh nekotorykh fos-
finovykh kislot i gidrokhinona)
PERIODICAL: Izvestiya Akademii nauk SSSR, Otdeleniye khimicheskikh nauk,
1958, Nr 7, Pp 880 - 885 (USSR)
ABSTRACT: Already earlier the authors showed that after the interaction
between dichloranhydrides of the alkyl and aryl phosphinic
acids with glycols in the presence of hydrogen chloride binding
substances the formation of polymer esters takes place. In the
present paper the authors describe the synthesis of polyesters
of various phosphinic acids and of hydroquinone. It was found
that -the nature of the substituents at the phosphorus atom
exerts a considerable influence on the properties of the poly-
esters. The introduction of an aromatic residue into the poly-
Card 1/Z mer chain leads to the production of solid products (in con-
An Investigation Within the Field of Organophosphorus SOV/62-58-7-14/26
Polymers. Communication 4: On the Polyesters of Some Phosphinic Acids and
of Hydroquinone
trast to similar polymera being produced from aliphatic
glycols). The polyesters produced were formed by the con-
densation of the chlorine anhydrides of the corresponding
acids and of hydroquinone in the presence of metallic tin. The
investigation of the binary system within the entire structural
range (diapazon sostava) showed that a minimum of the melting
temperature is exhibited by the copolymer (of a certain
structure). There are 2 figures, 4 tables, and 7 references,
3 of which are Soviet.
ASSOCIATION: Tnqtitut elementoorganicheskikh soyedineniy Akademii nauk SSSR
(Institut,,, of Element&l-organic~ompounds AS USSR)
SUBMITTED: December 21, 1956
Card 2/?-
STEPANOV, B.I.; ANDMYEVA. N.A.
Substitntion of halogen into azo compounds. Part 3: Preparation
of o-arylalkoxyaniline derivatives. Zhur.ob.khim. 28 no.9:
2490-2191 S 158. (HIRA 11:11)
1. Notkovskiy khimilco-takhnologicheakly institut imini D.I. Vende-
leyeva.
(.Aniline)
Andreyeva, U. A., Stlepanov,
SOV/79-28-11-14/515
On the Substitution of the Halogen in Azo Compounds
(0 zameshchenii calogena, v azosoyedineniyakh) V.
Reaction of the Copper Complex of 2-Chloro-Benzene Azo-21-
Naphthol With Alcoholates (V. Vzaimodeystviye mednogo
kompleksa 2-khlorbenzolazo-21-naftola s alkogolyatami)
Zhurnal obshchey khimii,
pp 2966 - 2967 (USSR)
To explain the mechanism of the substitution of the
halogen atoms in o-halogen-ol-oxy-azo dyes in the
presence of copper salts (Ref 1) it was important
to carry out this reaction using the complex compound
of a halogen containing dye with copper and without
the free copper salt. First the reaction of the copper
complex of 2-chloro-benzene azo-21-naphthol (the azo
dye from 2-chloro-anilineand 2-naphthol) with alcoholates
of n-butyl and benzyl alcohol was carried out. The
copper complex of the chlorine containing dye was
obtained according to Crippa (Krippa, Ref 2) in a
somewhat modified form by the reaction with copper
On the Substitution of the Halogen in Azo Compounds. 30'1/79-26-11-14/55
V.Reaction of the Copper Complex of 2-Chloro-Benzene-Azo-,21-Naphthol
With Alcoholates
ammonia solution on its heating in acetone instead
of alcohol. According to the analysis this.complex
contains one copper atom per two dye molecules,
and apparently has the mentioned structure (I).
The reaction of the~complex with sodium butylate and
sodium benzylate in the solution of the corresponding
alcohol was carried out at 100-1o30 within 8 hours.
From the reaction products dyes were separated that
turned out to be the products of the substitution
of the chlorine atom by the corresponding butoxy and
phenyl methoxy group (94.3 and 95-06). Thus, the
chlorine atom in the copper complex was substituted
practically quantitativelybjltbealkoxy groups in the
presence of the free copper salt. The dyes were identified
according to the melting point of the mixed sample with
the corresponding alkoxy substituted dyes. There are
3 references, 2 Soviet references.
Card 2/3
On tho Subatitution of the-Halogen in Azo Compounde. SOV/79-28-11-14/55
V.'~eaction of the Copper Complex of 2-Chloro-Benzene-.'ftzo-21-HaphthoI
With Alcoholatos
ASSOCIATION: Moskovokiy khimiko- Vtekhnologicheskiy institut imeni
D.I.Mendeleyeva (Moccow Chemotechnolojical Institute
imeni D.I.Mendeleyev)
SUBIZITTED: Aug"St 31, 1957
Card 3/3
AUTHIOR. V, V, Formin) So Po Vorobov) M. A. Androova
TITLE: The Investigation of Complex Plutonium Oxalates by the Polaro-
graphic Method
PMIUL:OAL: Y~an Tzii Neng, 1958, Vol 3, Nr 5, pp 450-456
ABSTRACT: The composition and stability of complex ions of tri-and tetra-
valent plutonium in oxalate solution wore investigated by the
authors using the polarographic method. The process is described,
The ions of Pu (02 04) 1~4 (predonderant) and Pu (C2 04)4 -5 were
f ormod in potassium oxalate solution with PH 3.5-6. Pu#4 gave
a well reverse reaction wave which is suitable fo., the quanti-
tative determination of plutonium by the polarographic method.
In 1M potassium oxalate solution, the oxidation-reduction poten-
tial of the above reaction is 0.205V (corresponding to a saturated
calomel electrode at 25 0). At pH 6-8, the authors discovered
that two Put4 con. plexes were simultaneously present. The authors
determined the instability constants of Pu (C. 0 ) -5 from the
data on the solubility of Pu 02 Ok)3 and the i~~ographic method
Card 1/2 is: Kp'u -5= 2-4 x i6-~O 2.2 x 10-1-1,
(02 0404 PU (C204)3
/
Y
AUTHORS; Fominj V. Vol Vorobtyevs So P,s Andreyevas Me As 89.0.7/29
TITLE; Imreatigation of Complex Plutonium oxalate Compounds by the
Polarographic Method (Isuoheniya komplakarqkh ok9alatav plutoniya
polyarografioheakim metodom).
FERINICAL: Atomnaya Energiya, 1958., Vol, 4. Nr 1, pp. 57 - 62 (USSR).
ABSTRACTt The composition and constancy for tri. and quadrivalent complex plu-
tonium ions in oxalate solutions was determined by the polarographic
method. In a solution of potassium oxalate with a pH value of from
3~5 to 6s,0 mainly (C P 4) 41 4 and also EFU(C204 Q -5 are formed.
Conditions being as they are give% there exists for Pu+4 a well de-
veloped reversible reaction-waves which suffices for the qualitative
polarographic determination of plutonium*
The oxidation reduction potential for this reaction in a 1 M solum
tion of potassium oxalate is 01205 V- +4
If the solutions have a pfi valud between 6 and 81 then two Pu Comm
plexes exist at one and the same time.
From the data for the solubility of [Pa(C20033 the instability cons
Card 1/2 stants for the complex ions [Pu(C204)3) 3 and Lpu(C204) 4)"~ and from
Card 2/2
'r
ANDRKYh'VA, M. As Cand Chem Soi -- (dies) "On the mobility of halogen in certain
halogenoxyazo-oompoundae" Mos, 1959. 11 pp (Min of Higher and Secondary
Specialized Eduoation RSFSR. Mos Order of Lenin Chemiooteohnologioal Inst
im D. I. Mendeleyev), 150 copies (KL, 52-59, 116)
-14-
5(3) r.
SCV/1 56-59- 1 -36A.14
A U T 11`0 R S Ste:~,anov, B. I, , Andreyeve.,
% 1J. A.
-------
T I T ' 171 -
--------------
t! -. Sixbstitution of Atom~s in o,o-Dihaloacn-ol-
oxyazo-dyos (0 atomov UaloC;ciia v o,o-digaloi,-er-
o I -ok"da-zol-rasi tolyalch)
P11 :1'~DICAL: Nauchnyyc doklady vysshey s hkoly. ".himiya i Ichimic:.0skaya
tek-hriol(q;iya, 19511, 11.r 1, p p 1111 - 1,12 /us-p
A T; co 2AL: Por the investi--ation into the mobility of 1,alo-cri atoms in
o-halo~;on-ol-oxy compound.- (Relfs 1,2,3), 2, 6-dichlorobenz one-
(1-azo-11).-naphtlicl-21, an azo-dye from 2,6-dichlt.ro-aniline
and 2-naphthol, vias used as an initial This
o.-oxyazo compouivt thuL cont ained t.-:cj halcj~,,n atom.,:. in an
ortho-position with r(-,Lard to the azo-grou.,,. It was found that
on the reaction of this sub staiice with alcoholates (scdium-
n-butylate) and phenolates P--4-Phenyl-pl~c-olate) in the
presence of copPer salts a praclically quantita'.ive substitu-
tion by the respective alko xy- or phenoxy-t;roup of the two
halo.gen atoms ta-c~ place. This substitution occurs far more
readill, than it does in the anal(,gous compounds containing
Card 1 2 only one halcL-en atom. The experimental part [:ives instructions
KORSHAK, '7.V.; GRIBOVA, I.A.-, ANMYEVA. M.A...
6.4 WUWA. 0L., - fivie-;Nk -,I ~ ~,
Organophosphorus pol7mers. -Part 8: Nlyesters of phosphonic acids
and of some aromatic dioxycompounds. Vysokom. aced. 1 no.6:825-828
j6 159. (MIRA - 12: 10)
l.Inatitut alementoorganichookikh soyedineniy AN SSSR.
(Pol7mers) (Phosphorus organic compounds)
S7,34,70
0
81586
3/190/60/0,02/03 1-7. 'f%
B020/BO66
AUTHORS: Korshak, V. V., Gribova, I. A,., Andreyeve.,-,M. A.
ai~
TITLE: Investigation in the Field of Organophosphorus Polymers.l.
Jof the Dichlorides of Phosphinic
Ix. Polveondeneation.
Acids With Dioxy Compounds
PERIODICAL: Vysokomolekulyarnyye soyedineniya, 1960, Vol. 29 No. 39
pp. 427-432
TEXT: The objective of the present paper was an investigation of the
influence of various factors upon the polycondensation of the di-
chlorides of phoaphinic acids with dioxy compounds as well as a kinetic
investigation of this reaction which proceeds according to the scheme
0 0
11 11
C1 - P - Cl + HOROR P - ORO- + 2RC1.
R'
Card 1/4
Investigation in the Field of
Organophosphorus Polymers. IX. Poly-
condensation of the Dichlorides of
Phosphinic Acids With Dioxy Compounds
81586
S/190/60/002/03/0,~.'r
B020/BO66
glycol, diethylene glycol, and triethylene glycol) upon polycondeneation
with diohlorides of phosphinic acids. The polyester yield was found to
increase. Fig- 3 shows the influence of the reaction temperature of
methyl phosphinio acid dichloride with hydroquinone upon the yield and
reduced viscosity of the polyester. A considerable effect on the reaction
rate is exerted by the reaction temperature and the concentration of the
initial reagents. Fig. 4 is a graphical representation of the degree of
completeness of the reaction of methyl phosphinic acid dichloridep and
Fig. 5 shows the temperature dependence of the reaction rate constants
of methyl phoophinio acid diohloride with hydroquinone and diethylene
glycol. The reaction rate constants are given in Table 2. The conditions
of the reaction of methyl phosphinic acid diohloride with hydroquinone
and the results obtained from this reaction are represented in Table 3.
There are 5 figuresq 3 tables,and 9 references: 6 Soviet, 2 British,
and I Dutch.
Card 3/4
S/079/60/030/04/69/080
BOO1/BO1 1
AUTHORS% Andreyeva, M. A., Stepanov, B. 1.
TITLEs On the Substitution of Halogen in Azo Compoundel, IX. Influence
of the Position of Halogen and of Nucleophilic Substituentep
and of the Nature of Nucleophilic Substituents
PERIODICALs Zhurnal obshchey khimiij 1960p Vol- 30~# No. 4, pp. 1350-1356
TEXTt With a view to determin-.6 the limits of applicability of the substi-
tution of the halogen atom in azo compounds# the 6uthors of the present paper
carried out the reaction of n.-sodiuih butylate with chlorine-containing azo L-1"
compounds in the presence of copper salts differing by the position of the
chlorine atom and of the nuoleophilic substituents in relation to the azo
group, and also by- the character of nucleophilic substituents. The substi-
tution of the halogen atom in azo compounds was found to take place only in
the case of the vicinity (ortho-position) of-the halogen atom and of the
nucleophilic substituents to the azo groupt as well as in the presence of a
mobile hydrogen in the structure of the nucleophilic substituent. The reaction
is the easier, the easier hydrogen is replaced by metal. It was found that
Card 1/2
On the Substitution of Halogen in Azo Compounds. S/079/60/030/04/69/oao
IX. Influence of the Position of Halogen and of B001/BO11
Nucleophilic Substituents, and of the Nature of Nucleophilic Substituents
V~5
the halogen atom in qM dves can be replaced by arylides of A-keto acids and
amines as the azo components. The halogen atom was found to be replaced by.
the alkoxy group on the reaction of the copper complex of o-lialogen-ol-amino
dye with alcoholates, without free copper salt. On heating the azo dye, which
contains a methoxy group in the naphthalene ring in the ortho-position to the
azo group, with sodium butylate in the presence of a copper calt, the methyl
residue in the eater group is replaced by the butyl g-roup, There are 2 tables
and 12 references, 6 of which are Soviet.
ASSOCIATIONs Moskovskiy khimiko-tekhnologicheskiy institut imoni D. 1,
Mendeleyeve, (Ijoscow Institute of Chemical Technology imeni
D. 1. MendeleyevT-
SUBMITTEDs March 14, 1959
Card 212
STEPANOV, B.I.; AITDIRMXTA, M.A.
Substitution of the halogen in azo compounds. Fart 11: Significance
of certain space factors. Zhur.ob.khim- 30 to.8:2748-2754 Ag
,6o. (KIRA 13:8)
1. Moskovskly khimiko-tokhnologichookly institut imeni D,I,
Mendeleyeva,.
(Azo compounds) (Substitution (Chemistry))
ANDREYEVA, M,A.; STXPANOV, B.I.
Substitution of the halogen in azo compounds. Part 12: Influence
of the nature of the halogen. Zhur.ob.khlm. 30 no.8:2768-2771
Ag 160. (MIRA 13:8)
1. Hookovskiy khimiko-tekhnologichaskiy institut imeni D.I.
Mendeleyeva.
(Azo compounds) (Substitution (Chemistry))
1-7
T,' r- L
IW;F
A. V. K'rtl,,ov ct 1.
. . . . . . . . . . . . . . . . . . .
Ma
27: 1.3. 1. N. . . . . . . . . . I . . . . . . . . I . . 1'.*5
2ti. bl,'=ION OF All.-i'l. 1AIIII-ES. K. S. 1,-vct.,-nko et %I . . . . . . WIG
1:9. 01' CARBOXYlaC ACIDJ comwom-').3).
'
G. 1. 1),~rhach . . . . . . . . . . . . . . . . . .
*
'
'
*
*
* 64
30. ;A
al
M'.CT!C:;3 OF MWJT;iO-':Y:;6JRU3 C)!Uj:UDy.3 W17,1 ACII) AXIIJE3. I
htvc
,o
et
.
hc
31. OF DIAIK(TJT0.;* 1i'!oT-!: ACT Z!:',. E. 11. TLivet-kcIv . . . . . . . . . . . . . . . . .
K. A. retriw and A. 1. Onyrt lopt . . . . . . . . . . . 197
34. I -CY L I S. n
RKA~ITON 01' Dill-, :'J I i*"'.; V
1 0 C-7
35.
(~Y )'.~U Xl' RIC AM) ACOM.
IX4 0' 11
F. at, 1 !1. L;. . . . . . . . . . . . . . . . . . . . . . . . . . 212
L:.Tj~Z OF D-',!i"'*,T'- ~'j AC!). G.
f;tykn , . . % 17
37. ACT-01. 0" CA],'"1% A:I:~:- i-~I-'.--'!-'. OF AC"D.
G. t-' al . . . . . . . . . . . . . . . . . . . . . . . . . I . . . . . . .
;I'n I ~.FIIIMICN OF M711-~-:TC `r7! 7~ :: ":z :-, "t-J;; C. L. V. N~~ ;--rev -A ~'.A.
39. RUZ;ION OF 1 - 1: 1,7 1: 1,; 1', ~ i A' t :C CCIM.; A. F. Gr ~',-,v . . .
'o. I j::L;~"'~ ACID V;Y.~: CiIIrNM'F. L. Z.
REACTX!;
r, v a
41.
ACK71VIIEj. I.F. 11AIL."E.n."o ~. I 'k". Y"
-,37
42. s;7:AY-; 0.0 0: 1., YI5;'KR.;. V. V. xonl:n!'. ot Ell. . . . . . . . . . ;-V.,
43. S-14n'3131 G-F 11*.Cj"~.10).Y1.1c AMS V;) C'
I-Rim V. V. Korzi::,i~ --L al . . . . . . . . . . . . . . . . . . . . . . . . .
44. SYN-11:1-1~3, O~ OF VII."!'L::':).'.i':-'-. T." C
r. ~% 1'. Ill . . . . . . . . . . . . .
45. 1.::'; OF NI-4 ('P,
3
46. 5-.WN~EJIS OF IM'UNC4 1' %"Ij, A.
47. SYNT;M~L-, A! N 'C'Vi"O'.'; or, 6:~ 0U.N.Y.; N j'I-"iC3
1'. A. "t .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
tn. I)li3~';I');-":",I"-Co:""",:;II.L; J"~:: K. A. Yot-roi et ill . . . . . . .
49. "'PTLICIVII ION OF
lc~:tica
of Yo. 17i1. pvbl. Izr L'It"n' lc:i-a. Eel.
tVwIZ,
Conection of cm-plotc rrj--~rs Iwunciated at t1o 1959 JZazrm CQrTc,rcnco on CLnullutry of
Ori;emophoophoms Coc.NwLdo.
KORSHM VS., GRIBOVA, I-i-, AWDREYEVA, M.A.
Research in the field of phosphorus-containing polyesters.
Khimiya i Primene-niye Fosfororganicheskikb loyedineniy (Chemistry and
ap,)Ucation of organoohost)h:)rus cormun('!s) A. Y+,. Ed.
Omi)IQ by Kazan Affil. Acad. . leis USS?, Moacow 1902, 032 m).
Collection of covm'_et4~ nawra L)rnsanted at the 191-',,9 Kazars ~-Onforence Om
Chemistry of :Tganorhonphonin Gorwounas.
AND.TizyEvA M. A.
PHASE I BOOK EXPLOITATION SOV/6034
Konferentstya po khtmit i primeneniyu foefororganicheakikh soyedinenly. 2d,
Kazan!, 1959.
Khimiya i prime6entye foefororganicheskM soyedineniy; trudy (Chbmistry
suid use of 01-19anophosphorus Compounds; Conference Transactions) Moscow,
SS
Izd-vo AN S R, 196Z 630 p. Errata slip Inserted. 2800 copies printed.,
Sponsoring Age y: Akademiya nauk SSSR. Hazanskly filial.
esp. Ed. -. A. e. Arbuzov, Academician; Ed. of Publishing House: L. S.
Povarov; Te h. Ed. - S. G. Tikhomirova.
PURPOSE: This collection of conference transactions is intended for chemists,
process engineers, physiologists, pharmacists. physicians, veterinarians,
and agricultural scientists.
COVERAGE: The transactions include the full texts of most of the scientific
resented at the Second Conference on the Chemistry and Use of
-rs
C~rd IIJ
Chemistry and the Use of Organophosphorus (Cont.) SOV/6034
Organophosphorus Compounds held at Kazan' from 2 Nov through I Dec 1959.
The material is divided into three sections: Chemistry, containing 67 arti-
cles; Physiological Activity of Organophosphorus Compounds, containing 26
articles: and Plant Protection. containing 12 articles. The reports reflect
the strong interest of Soviet scientists in the chemistry and application of
organophosphorus compounds. References accompany individual reports.
IShort summaries of some of the listed reports have been made and are given
'below.,
TABLE Or CONT ENTS: (Abridged):
Introduction (Academician A. Ye. A buzov) 3
TRANSACTIONS OF THE CHEMISTRY SEC~ION
Getter, Ye. I- INU plastmass (Scientific Research Institute of Plastics.
Moscow]. Some Prospects for the Industrial Use of Organophosphorus
Compounds 46
Card
70A
Chemistry and the Use of Organophosphorus (Cont.) SOV/6034
triorganosilanols (113SM) with acids of phosphorus under condi-
tions of azeotropic distillation of water in the presence of inert
solvents. Another is based on the interaction of triorganosi lanes
with orthophosphoric and methylphosphonic acids in the presence
of active colloidal nickel.
Korshak, V. V., 1. A. Gribova, and A. Andj~~va [Institut ele-
mentoorganicheskikh soyedineniy (Institute of Organoelemental Com-
pounds, Academy of Sciences USSR, Moscow)]. Study of Phosphorus-
Containing Compounds 242
The polycondensation of dichlorides of phosphonic acids with diols
has been studied by following the interaction of m ethylphos phonic
dichloride with hydroquinone in a nitrobenzene solution at a tempera-
ture of 140 to 170*C. The properties of polyesters of phosplionic acid
have also been studied.
Card 4(Zq~ -3V,~
S/081/62/000/023/120/120
B117/B186
AUTHORSo Korshak, V. V., Gribova, I. A., Andreyeva, M. A.
TITLEr Study in the field of phosphorue-containing polyesters
PERIODICALt Referativnyy zhurnal. Khimiya, no. 23, 1962, 617, abstract
23R60 (In colleotiont Khimiya I primeneniye foafororgan.
soyedineniy. M., AN SSSR, 1962, 242 - 246)
TEXT3 Phosphorus-containing polymers (PM) with heterogeneous chains were
synthesized by poly condensation of methyl phosphinic dichloride (I) with
aliphatic and aromatic dihydroxy compounds. The second-order reaction
occurs between (I) and hydroquinone (in nitro-benzene at 140 - 1700C), UP
and diethylene glycol (in dichloro ethane &t 40 - 800C) with activation
energies of 10.5 t 0971 and 7-5 t 1.0 kcal/mole, respectively. Yield and
molecular weight of PM Increase considerably with increasing temperature.
The formation of cyclic eaters occurs as a side reaction, mainly in the
case of the lower glycols. Based on aliphatic glycols, the PM are thick and
viscous liquids; in the case of aroaRtio dihydroxy compounds, they are solid
transparent substances. The PM are soluble in CHCl 3 , dichloro ethane, and
Card 1/2
3/001/62/000/023/119/120
B117/B166
AUTHORSi Gribova, I. A. , Kabachnik, M. I.
Koleanikov, G. S., Korshak, V. V., Medved', T. Ya.:
Polikarpov, Yu. M., Rodionova, Ye. F., Pedorova, L. S.
TITLEt Some methods of synthesizing new organophosphorus monomers
and polymers
PERIODICALt Referativnyy zhurnal. Khimiya, no. 23, 1962, 816, abstract
23R58 (In collections Khimiya i primeneniye foefororgan.
soyedineniy. YI., AN SSSR, 1962, 263 - 271)
TEXTt This is a review of the authors' papers on synthesizing vinyl oom-
pounds of quinquevalent P and polymers based oh them. Syntheses of varioup
derivatives of vinyl phosphinio and vinyl thiophosphinic acid, and of
diethyl vinyl phosphinic oxide, have been described. The production of some
new phosphorus -containing polymers and copolymers with carbo-chains'and
heterogeneous chains is described. 13 references. EAbstracter's notes
Complete tran8lation.3
Card 1/1
.-ABTMVA, M.A.9 GPJUDVAI I.A.9 UMCHNIK, M-I-9 KOLFSNIKOVi Gz5-j,
KORSHAK;-V-.V-.,,-MDVED's T.YA., POLIKkRPOV9 YU-M-s, RODIONDVAO YE.F.,O
FEDOMVAq L.S.
"Some means of synthesizing new organophosphorus monomers and polinners."
Khimiya i hImeneniye Foafororgutichaskikh Soyedimniy (Chemistry aM
application of organophosphorus com)ounds) A. TR. ARHAW, No
Publ. by Kazan Lffil. Acad. Sci. USSR,, Moscow 1962, 632 pp.
Collection of comolets papers presented at the 1959 Kazan 'Conforvnee an
Chemistry of Organc,--~,hosphorus ComoourAa.
STEPANOV, B.I.; VOROBIXEVAj I.I.; ANDREYEVA, M.A.
Substitution of halogen in azo compounds. Part 14:
Substitution of chlorine in the azo dye of
3-chloro-3-aminoanthraquinons and 2-naphthol. Zhur.ob.khim.
32 no.10:3281-3283 0 162. (MIRA 1511l)
1. Mookovskiy kbimi o-tekhnologioheokiy inotitut imeni
D.I. Mendele va.
(Ayz'ao dy.-,a) (Chlorine)
(Substitution (Chemistry))
AWYEVA, M.A.1 VOROZHTSOV, N.N., mladshiy; -OIZIIECIIKOVSKAYA, N.I.,
STSPANOV~ B.Io; YAKOBSON, G.G. 910.
N,~ , 1 "
Substitution of halogen in azo compounds. Part 17:
Reactions of polyhaloazo compounds. Using the reaction
for establishing the structure of some aromatic
halogen-containing compounds. Zhur.ob.khim. 33 no.30"91
Mr 163. (mm 160)
1. Mookovskiy khimiko-tokhnologichoskiy institut imeni
D.I, Mendeleyeva i Novosibirskiy institut organiehoskoy
kbirnii Sibirskogo otdeleniya AN SSSR.
(Azo compounds)
(Halogen)
KCRSHAK, V.V.; GRIBOVA, I.A.; ANDi~'EEVA, M.A.
Phosphorus-containing thermosetting resins. Plast.masay no.10i
1-1-12 163. (HIRA 16:10)
STEPANOV, B.I.; ANDREYEVA, M.A.
Interaction of 2-chlorobenzene-(I-azo-It)-21-naphthol
with fluorene. Zhur. VKHO 8 no-5:577 163. (MIRA 17:1)
1. Moskovskiy khimiko-tekhnologichooldy institut imeni
Mendeleyevao
ANDRMVA, M. A.
Dissertation; *On the Changes in the Degree of Dispersion of Solutions Obtained by
Means of Colloid Solvents,* Cand Chem Sci, State Sci Res Inst of Roentgenology and
Radiology, Baku 1953
W-30928
SO: Referativnyy Zhurnal, No. 5, Dec. 1953, Moscow, AN USSR (X4*M)
ANDREYNTA, M.A.
Dissolving essential oils by complex colloidal solvents* Uch,
zap. AOU no.7:35-40 157- . (MIRA 11:11)
(Zesences and essential oils) (Solvents)
1~11D
362)40/62/004/001 /009/020
B1O1/B1 10
AUTHORS: Korshak, V. V., Gribova, I. A., Andreyeva, M. A., Popoval
G. M. ----------
TITLE: Polymers containing phosphorus. XXVII. Heterochained
polyesters of vinyl phosphinic acid with some dihydroxy
compounds
PERIODICAL: Vysokomolekulyarnyye soyedineniya, v. 4, no. 1, 1962, 58-63
TEXT: The authors report on the properties of eaters of diethylene glycol
(1) and 4,41-dihydroxy-2,2-diphenyl propane (II) with mixtures of vinyl
and methyl phosphinic acids. The syntheses of these esters have already
been described (Vysokomolek. soyed., 2, 427, 1960; Izv. AN SSSR, Otd.
khim. n., 1958, 880). Eaters with I -are colorless, viscous liquids. Their
freezirg point drops from -390C (104 CH 3POC12) to -5100 with 100%
CH2-CHPOC12 in the initial mixture. Eaters with II are transparent, brittle
solids soluble in dichloro, ethane, chloroform, and tricresol, insoluble in
ethar, benzene, and dioxane. Their softening points drop from 55-560C to
Card 1/2
8/1932 47
BJOJF6~2/004/001/009/020
Polymers containing phosphorus. BI 10
41-420C (- 100% vinyl phosphinic acid) as the content of vinyl phosphinic
acid increases. Struoturization of the eater of I (in sealed ampuls, N2
atmosphere, at 600C for 15 hre, or in an open test tube and in C2H 4C12
solution) by benzoyl peroxide, tert-butyl peroxide, azoisobutyrie dinitrile,
tert-butyl hydroperoxide, or cumene hydroperoxide, only occurred with a
vinyl phospbinic acid content :-'- 40% (gelatinous substances# softening
points: 150-2000C the latter value with 100% CH2-CHPO-). Eaters with II
could not be structurized under the experimental conditions, applied. There
are 2 figures, 4 tables, and 4 Soviet references.
ASSOCIATION:
SUBMITTED:
Institut elementoorganicheskikh soyedineniye AN 999R
(Institute of Elemental Organic Compounds AS USSR)
January 26, 1961
Card 2/2
L 12725--63 EPF(c)1iwP6)1swT(mYbw, Ao Pr-Vpc-~4 Rm/ww
ACCESSION NRs AP3002.291 51006210100010061109313200
45
AUTHOR: Korshakt-V. V.; Grii*va, I. A.;4ndreyeva, K. A.
TITM Research on manophosp,hor,ous" R21~mers. Report 28. Transesterification of~
diallcyl esters of phosphinic acids with various glycols
SOURCE; AN SSSR. Izv. OtdolenVe khimich skikh nauk, no. 6, 1963, 1095-1100
TOPIC TAM transesterification, organophosphorous polymers. dialkyl aster phos-
phinic acid, dibutyl methanephosphinate, dimethyl mothanaphosphinate, sicosa-
rethylene glycol
AB5'.MGTs Dibutyl and dimethyl methanephosphinate -were synthesized from the acid
chloride and transesterified-with diethylene, hexametliylene, and eicosamethylene
glycol. A-number of acidic and basic catalysts were Ltried. Metallic' sodium gave
the be3t results. The effect of variations in temperature and length of heating
was studied. At the tomperature, required for the reaction to proceed, some dacom.
position, contaminating the:pr6Auct with an acidic impurity, was unavoidable. The
products obtained with diethylene and hexamethylene glycol are dense, viswus
liquids composed mainly of trimers and tetramers, soluble in c1loroform, cresol,
and acetic acid, and insoluble in benzene, dichloroethane, carbon tetrachloride,
Card
ACCESSION NR: AT4033994 8/0000/63/000/000/0117/0122
AUTHOR: Korshak, V. V. ; Gribova, 1. A. ; Andreyeva, M. A. ; Kabachnik, M. 1.
Medved'$ To Yas
TITLE: Polymers containing phosphorus. X=. Heterocyclic polyesters of vinly-
phosphinio acid and some glycols t
SOURCE. Geterotsepny*yo vy*sokomolokulyarny*yo soyedineniya (Hoterochain macro-
molcc~lar compounds); abornik statoy. Moscow, Izd-vo "NaWca, 111963, 117-122
TOPIC TAGS: vinylphosphinic acid, ethylene glycol, propyleno glycol, diethylene glycol. s.,
trimethylene glycol, butylene glycol, polymer, cyclic polyester, polymerization, polymeri-p'
zation catalyst, metallic sodium, linear polymerization, radical polymerizattlon, benzoyl
peroxide, tort. -butyl peroxide, tort. -butyl hydroperoxide
ABSTRACT: The authors synthesized the cyclic eaters of vinylphosphinio acid (I) and
ethylene glycol (U), 1, 2-propylene glycol (E[l), trimothyleno glycol (W), 1, 4-butylene
glycol (V) or diethylenq glycol (VI) and determined some of their phy8toochomical'pro-
perties (see Table .1 in~ the Enclosure). These esters were then polymerized linearly in
the presence of water (3% by welght~ 140C, from i6 hours for III to 83 hours for
Card 1/3
ACCESSION NRs AT4033994 - Cyallo "term of vinylphosphinto acid
Chemical
11"C110
M
IV
CHOMCII
Col
6ard 3/3
TA13LE 1 '!RD COV H'% p0%
B.P., 20 20 Calcu- Cal- Calcu- Calcu-
formula 'C/mm nD d4 tated oula- lated lated
ted
0016
U
CUP fV/4'i
4701
1
1.30i9
U.63
Ms'97
355
5
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5.8
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40,4 404
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47
to
L .-XPA,(s).2/EWT(m)/EPP(c)/~WP(J)/!/FTC(m) -
IMSSION NRI A?5024495 UR/0191/65/000/010/0001/0003
678.673-4:P8.029.h4
~q
ak
AUTHOR: Vinogra4ova, S. V.; Andreyeva, IN. A.t Davydova, V. F.11 kah V. V.
TITLE: Study of the feasibility of curing and converting thermosetting ts4aryl...
aster to end products
SOURCE: Plasticbeskiye massy, no* lo, 1965, 1-3
TOPIC TAGS: polyaryl eater, heat resistant plastic, polyaryl plastic _'q
ABSTRACT: A study has.shown that unfilled or quartz-filledlt~roes-linked D-5, Poly I--
s~
ester can be.processed into end products by molAing. D-5 repared from:terephth. (7~
al
chlorideo bisphenol A, and l,lil-trimethylblpropane TlM/O,5;m6l&k.r&ti6)j is--p W r-,,
cross-linked~(38% insoluble'in chloroform) at-the outdet~ Study of-furtherlbrbhs
linking by various,-curing agents-revealed'that mdleic and endic (cis-'3fi'-endomethy-~
lene-1,2,3j6-tetrah kiveithb best
.ydrophthalic)ahhydride or tetrabittoxytitanium 4e., -.7r
sults., Cross,-linking occuts as follows:
L 1868-66
ACCESSION:MR! AP5024495 "T
CHA
AqIN-COOCK-4-4311O."... R<
-4:
C4
CW
CA
-OOC-
0 7.AWCHV
R
CH~
16
d-T
-'0
Study of D-5 polding shoved the' expOdiehey.of using a croes-linked polymersoftenW
at 200-210C and 6a-70% insoluble& Such a polymer is rapidly molded (at llo-16od
into solid products. Fig.,l of the-Enclosure shows the thermomechanical properties
of D-5 andi for comparison, of D-2 J)olyaryl eater (from terephthalic acid and big-
phenol A) As. Pig 1 indicatesi 'Prioss~linking considerably improven heat resistancdv'
CarJ 2/h
1868-66_
1
ACCESSION HH: AP5024h95
Cross-linked D-
5 withstands
I temperature cycling from -60 to 250C and exhibits goo&
1
dielectric properties. Orig. art ihad: l'table and 4~'figures. [SM)
v
ASSOCIATION:z none
8UBMITTED., 00
01-
ENCL.$. suB com ur
NO REF SOVz 002 .
COTIM 000
ATD
:tj
PRESS.
,
card 3/4,
EWT(m)/ZPF(c)/EWP
L 2324-6 Q)/T/ZTa(M) WW/RH
ACCESSION NR: AP5022222 UR/0191/(55/ooo/009/0016/0019
678.673 01-536.4503T.311
ATMOR: Vinogradova, S. V.; Kqrshak, V. V.; Fridman, Ye. I.; Andreyeval H. A.
Bnraboshkina, h. N.qA
I-- 11~ - /
P 16 X~7
rITLE, fleat-resistant eleetroinaulating polyaryInte'rInnfif, material
SOURM Plasticheskiye massy, no. 9, 1965, A_iq
.,,,,ToriC TAGS: plasticizer, heat resistant plastic, heat resistant material, polyaryl I
plastic, terephthalic acid, electric insulator, plastic , heat -resistance, polyaryla:tei
phenolphtlialein, biaphenol A, laophthalic acid, softening point
ABSTRACT: The possibility of preparing heat-resistant plastics suitable for electrib
insulators and capable of being compression molded was studied by preparing neat and
mixed compositions from phenolphtiialein is;,% ithalate or terephtbalate based polyalyj.L
h
.,Aes. (i.e. ~ aromatic polyesters) It was also. atte ted to prepare polpae ' :whi
MP rs c
had to be kept at their melting temperature during compression molding fora minimum,
'time. Thus, powdered poly(phenolphthalein ieophthalate) could be compression molded
i
at 270-300C into semitransparent light-brown samples of plastic designated as F 1 ~ VJ~
vhile the poly(phenolphthaleia terephthalato), designated as-plastic F-2, crackle__3~~j
tord 1/2
L 2~24_66-.
ACCESSION MR.- AP5022222
and disintegrated after being taken out of the molds. The addition of plasticizers,:
I'Sovoll, [biphenol dichloridel, a polysiloxane and some other palyarylates.based on
either-bisphenol. A or phenolphthalein sebacate, made it possible to prepare compres-
sion molded.samples from F-2 with softening points from 255 to 340C. The addition of
fBovol in varying amounts or the seine polysiloxane to F-1 produced plastics with soft-
Aning points between 250 and 285C. Even the sample with 10% Sovol still had a soft-'
~ening point of 230C, which was considered to be sufficiently high, combined with good
workability of the material. The introduction of fillers (up to 40%.by weight of the
composition) was also studied for the purpose of reducing cracking of the p1h3tic
and to save polymer materials, Good results were obtained with quartz flour or tal-:~,
cum, whilealuminum oxide or silica gel were ineffective. The filled F-2 polyarylatjo
samples were rtsistant to.themal shock; they withstood repeated sharp temperature
'phange from 60 tq 250C, The polyarylate compositions obtained had high dielectric
-properties'fn a rather Vide range of temperatures. Orig. art. has: 4 figures and
tables.' [BNI t
AASOCIATIONt none
6UBMITTEDi 00. ENCL: 00 SUB CODE: (M*r, 66
NO REP SOVI~ 06h OMM 000 ATD PRES~I
Card, , 2/2,44
OFENGENDEN. N.Ye.; SVYATSKAYA,
Crushing of coal caused by hydraulic mining and conveying. Sbor.-
DonUGI no.22s69-90 161. (MIRA 15:6)
. (Hydraulic mining)
SVTATSKAYAp M. 0.j ANDREYEVAO M. F.; SHALYOINA, V. T.
Clarification of alime waters. Sbor. DonUGI no 22t121-128 161*
(Coal preparation plants--Equipment and guppli -68) (MIRA l5z6)
SOV/1 20- .58-2-14/37
AUTHOR: A3~dre~L~~. G.
TITLE: Application of an Electron Multiplier to Increase the
Sensitivity of a Mass Spectrometer (Primeneniye elektronnogo
umnozhitelya dlya. povysheniya chuvstvitellnc)sti mass-
spektrometra)
PERIODICAL: Pribory i Tekhnika Eksperimenta, 1958, Nr 2, pp 53-56
(USSR)
ABSTRACT: In a nxLriber of studies it is necessary to carry out mass
spectrometric analysis with very,small amounts of material so
that the usual sensitivity (10-14 - lo-15 anip) is insuffic-
ient. Recently, various methods of recording masq spectre-
metric ion beams have been devised . using Geiger count'ers,
photoelectron multipliers, ionisation chambers, and electron
multipliers as DC amplifiers or ion counters. In the present
work, in order to increase the sensitivity of the mass
spectrometer MS-3, an electron multiplier Was used, particular
attention being paid to the method of counting. An eleven
stage electron multiplier with beryllium bronze electrodes
was used. The multiplier was specially activated and worked
with a negative voltage of 4.3-4.5 kv on the first electrode.
The ener- of the ions detected by the multiplier was 6.8-
0y
Lev, The block diagram of the recording apparatus is shown
Card 1Y3