SCIENTIFIC ABSTRACT ANDREYEVA, L.P. - ANDREYEVA, M. G.

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ORFSHKINP P.T.; ANDRLTE7Ay L.P. Relaxation effects of alectroconductivity in industrial rafractorle3 at high temperatures. Izv. vys. ucheb. zav.; fiz. 8 no.lsl55- 161 165. (MIRA 180) 1. Slbirskiy metallurgicheskly Institut imeni Ordzhonikidze. - . - I I.-II.. I-- I FIT.. ORESHKIN, P.T.; KHRAMMIVA, M.Nj ABDREYWA, L.P. Electric conductivity of cocide refractories at high temperatures. Izv, v7s. ucheb. zav.; chern. met. 6 no.2:3.42-149 163. (MIRA 16-3) 1. Sibirakiy metallurgichookiy instituto (Refractory materials-Electric properties) VISIUUAKOVA~ Ye.S.., in2h.; RIft4fAIITSVA,, N.F.., inzh.; 130ROIVICHEV, G.A., inzh.; PITMOVA, L.V., Inzh.; FMAUNIN, N.I., inzb.; IAESXTI-lp I.M... inzh.; AIIDIMYEVA, L.P., inzh.; BIS)ILIIKEVICI!, G.V., inzh.,- RYABIDIIIIA, A.I.,inzh.,- VIOSMID, N.S., red. Gazety; K0111MOV, A.Lp otv. red.; ITNITSKIY, V.P., red.; FLIGELIMAN, S.M., red.; ROZEDAYKIIIAs V., tekhn. red. (Kalinin Artificial Fiber Combine] Kalininskii korbinat islms- tvannogo vololma. Kalinin, Kalininskoe hnizhnoe izd-vo, 1960. 92 P. (MIRA 15:8) 1. Kalininskiy kombinat isk-usstvennogo vololma (for an except Komkcnr, Yunitskiy, Fligellman, Rozhdaykina). (Kalinin-Textile fibers, Synthetic) Coefficients of iron silicides. 117 165. politekhnicheskiy -ACCESSION'01 ~ ---A?5010202-- 7- UlVIO43/65/000/003/ -0061/0068 iAUMORi Andreyevag Le Pa TITLE: Concerning the practical.Wlication of the orthogonal power-series meth :SOURCEI Mosc~m_& - -Uav'er-isitet'.-.Vyohi'bliteltMy.- teentr. Sbornik rabot, no 3i 1965i ;Vyc1Asl1tel1xWyemeto4V i programairovwAye (Computing methods and progr t TOPIC TAGSt power series method,~numerical calculation,, mtrix diagonalization, subprogram.. amputer programing order 38 inclusive. The-set consists of three-subprograms, each of which-its standard and can be used independent4 in the presence of available information. The computation algorithm realized by the subprograms is based on the power-series method,, Each subprogram is described and the use of subprograms is illustrated 'with examples of the diagonalization of a 10-th order matrix,, the determination of the eigenvalues and eigenvectors of a 14-th order matrix, the determination of the 1_Ca,d 1/2 ANDREYEVA, L.P. Adopt the work practices of the brigades of communist labor of the Winin Combine. Dim. volok. no.l126-27 165. (MIn 18 t 2) 1. Kalininskiy kombinat iskuastvennogo volokna. BOGUN, A.Fe; RUSNAKp N.Te; ANERMVA, L.S., red.; LAVPY.NOVA, H.B., tekhn.red. [Organization and mechanization of docking operational Opyt organizataii i mokhanizateii dokovvkh rabot, Koskva, Izd-vo "Morskoi tranuport9l 1959. 100 p. (MIRA 13:2) (Ships--Maintenance and repair) (Dry docks) CMWCHENKO, Ivan Ivanovich; GKOBELIN, L.T., red.; 4~P~~ - rad.1 LAYRENOTA, N.B., takha.red. [Internal combustion marine engines] Sudovye dvigateli vnutrannago agorantia. Izd.2., perer..i dop. Moskva, 1zd-vo "Horskol transport," 1960. 673 p. (xiRA 14:3) (Marine engines) (Gas and oil engines) N" CHUMACHENKO, Ivan Ivanovich; SKOBELING, L.V., red.; ANDIWEVA, L.S.,-red.1 IAVFMOVA, N.B.p tekhn. red. t-~~ [Marine internal-combustion engines] Sudovve dvigateli vrAxtrennego sgoraniia. Izd.2. perer. i dop. Moskva, Izd-vo "Morksoi transportf" 1960. 675 P. (Marine engines) (YMA 140) SUSHKOV$ Boris Borisovich; ANDPMEVA, L.S., red.; TIKHONOVA, Te.A.9 tekhn, red. (Marine separators and shore installations for separating water from petroleum products] Sudovye separatory i beregovye ustanoyki dlia ot- deleniia Tody ot neflteproduktov. Moskva., izd-vo *Morskou transports" 1961. 336 p. (MIU 14:10 (Oil pollution of rivers, harbors, etc.) (Separatora (Machines)) ELITSOV, Stepan Petrovich; NOVIKOV, Teodor Nikitovich; NEDZVEDSKIY, Pavel Ivanovich; ANDMEVA, L.S. red.; LAVREHOVA) N.D., toklin. red.,. ~f -- ------ [Working t and rest perioids,of the workers of marine transportation)llabochee vremia i vremia otdykha rabotnikov ror- skogo transporta. Moskva., Izd-vo "Morskoi transport," 1961. 174 P. (MIRA 15:8) (Merchant marine) KRUCHININ, Yuriy Aleksandrovich; ANDREYEVA.-Lj9., red.; USANOVA, N.B., takhn. red. (Trip into the ice age] Putashestvis v lednikovyi period. Moskva, Izd-vo "Morskoi transport," 1963. 134 p. (MIRA 16:7) (Queen Maud Land) CHEREVICRNYY, Ivan Ivanovich, polyarnyy letchik, Geroy Sovetskogo Soyuza; ANDREYEVA, L.S,red.; USANOVA, N.B., tekhn. red. [In the Antarctic sky] V nebe Antarkidy. Moskva, Izd-vo "Morskoi transport," 1963. 147 P. (MIRA 16:5) (Antarctic regions--Aerial exploration) ITSKOVICH, Yuriy Leonidovich; SKOBELING, L.V., red.; ANDREYEVA, L.S., red. rElectric drives on ships] Sudovye eloktricheskie privody. Moskva, Izd-vo "Morskoi transport," 190. 583 p. (MIRA 17:5) y,UF,c)FATKjj,,', Fatr Vasillyevich; AEM1EYEVA) L.S., red.; L.V. . red. [Automation of electric ship propulsion systew-o] Avtoma- tizatAin grobnykh olektrichookikh ustanovok. Moz;kva, Transport, 19(d.. 202 p. (NIRA 17:9) BROYTW, A.A.1 DEREVICH, V.A.; SEDOR, A.Ml.j EDL11~LML,_~* S.S, red.j SKOBELINGp L.V., red. [Load--hoisting machines and arrangements on ships] Sudovye gruzopod"emnyo mashirq i ustrointva. Moskva, Transport. 1964. 298 p. (MIRA 17*-.12) Sh'UB114SKr-,'- Aleksandr rosifuvioh,; KA,,jAI,Cj'V, Yurly Nikolayevich; red.; ZARE"11,', I.V.; rea. ,~~IIE4ANA, i~ [Electrician in hdrbor mo~,heaiizatlonj Eloktromonter portovoi mekhanivitsii. Mloskvap Transportt 1965. 183 p - (PIRA 18:9) F i T I I , ~j: ~ . -1 Aloiz Alnizovich; Al,.:1.1'4E,FVA, I r I ""A rol -, 1 (On streets; port ~-litles of " ,e gorodn --'vr-,,,y. Illa chuzhikh ulitsakli, pwtov- V, I ~ n .1 Moskva, Transport, 1965. 229 P. (:,"RA W!~ 11 51111101w, vT; ~~4A TURBAKOV, A.A.; [Electrical engineering and the electrical equipment of ships) Elelctroteklinika I alektrooborudovanie sudov. Mo- skva, Transports 1965. 446 p. (MIRA 18:9) BARTOSHEVICHp Ye.N.; MARTYNEHKO, Pblioqrelitislike with live Sabin v M.B.; LESHCHINSKAYA., Ye.V.; ANDREYKVAjJL~�_t; ASHMMNA, children inoculated 18 no.6:16-.;-l 163. (MIRA 17: 1) SYCHEV, Konstantin Arsentlyevich; ANDREYLIVAI_L.S., red,; LAVRENOVA, N.B.y tekbn. red. [On a drifting ice flool Na dreifuiushchem ledianom ostrove. Mo- skva, Izd-vo UMorskoi transport,," 1961. 112 P. (MIRA 1012) (Arctic regiono-Russian exploration) m MAKSNOVp Ivan Georgiyevioh; POZNYAKOVA, Go - L.S., red.; LAVRENOVA, N.B.# tekhn. Yurlyevna-; ANDREYEVA)._ [Workdays in a large port) Budni bollsbogo vo "Morskoi transport," 1961. 38 p. (Leningrad-Harbor) (Cargo ABREMA, L. S. Introduce public control in building achoolhouass. Sell.stroi. 14 no.8:4-5 Ag '59. (14IRA 12:12) 1. Zaveduyushchiy Moskovskim oblastnym otdelom narodnogo obrazovaniya. (SchoolhOUBOO) ~O ANERFYV,VA, L. V. Andreyeva, L. V.-"The nir-stern methoe f burning out -~cke in tube f-jrnaces," Irl th(, Tn-uc-h symposium: . mboty studentov gorno-metvllur~. In--tov Plorkvy, ll~scow, 1969, '20-L2 P. I- I, . SO: U-I.'--31;, 20- Oct 5?, (LetOTis '~hurnl njvkh Statey, No. 10'. l9h9). f 7777n~7 im Nlroyt*,- ~ --v . - --Nilm ~ 4 --- - -- . - . ~e. 'r. . -,= t::, te'l- ..~ T KQMUKHC A IV , L.I., inzh., SUDIANOV.~, T.A., inzh.,, 1L.V. inzh. Methodology for calculating r.*--* material eypenditmre for krdt outerwar garment pieces. Nauch.-issl.trudy V'N11TP no.4:71-117 '63. 1 (KRA 17:4) SARANCHAj Ye.T.;. ABRDSIMOVAv A.M.; ANDR"EVA, L.V. Production of concentrated liquid ammoniate salts of carbon dioxide based on ammonium carbonate and urea. Khim. prom. 41 no.5083-384 YV 165. (KM 18s6) ANDREYEVA, L. Yo. "Calculation for the Rigidity of Diaphragns and Diaphragm Boxes." Sub 17 Sep 51, Yoscovr Order of the Labor Red Banner Higher Technical School imeni Bauman. Dissertations presented for science and engineerinp derrees in Moscow during 1951. SO: Sim. No. hOOp 9 May 55. ANDRMVA, L. Ys., kandidat teklinicheakikh nauk. Compu--ation of serrate profiled membranes; rigidity calculation. LTrudy) MVTU no.16:55-75 152. (MLEA 6-.6) (Slastic plates and shells) I i i I I I ANDRMVA, L.Ye., kandidat tekhnicheskikh nauk. Computution of membrunes with linear characteristics under pressure. tTrudv) MVTU no.16:76-89 152. (MLRA 6:6) (Slastic plates and shells) - AMMUTA, L.Ya.. kandidat tekhnicheskikh nauk. ----------- Calculation of sloped trapezoidal corrugated membranes. [TrudyJ XYTU no.26:123-141 133. (MLRA 7:3) (21astic plates and shall@) ANDREMA, L.Ye., kandidat takhnichaskikh nauk. ....... , Calculation of conical and spharical corrugated membranes. [TrtIdyj KTTU no.26:143-150 153. OMU 7:5) (Elastic plate* and shells) ANDRXYNVA,L.Ye. - 1. i concerning corrugated diaphrAgMS plates. Inzh.sbor. no.21:128-lbl (Elastic plates and shells) ANMTEVA, L.Ye., Calculation of 155. (Slastic ANDREYXVA, L. Ye. ~ - - , Calculating corrugated diaphragm characteristics. Priborostroenie no.3;11-17 Mr 156. (MM 9-8) (Elastic plates and shells) ANDWEVA, L.Ye., dote.. kanA.tekhn.nauk , . Determining characteristics and effective areas of corrugated membranes with rigid centers. Naucb.dokl.vys.shkoly; maeb.i prib, no.1:218-227 1,58. (MIRA 12:1) 1. Predstavleno kafodroy "Soprotivienlye materialov" Moskovekogo vy8abego tokhnicheskopp uchilisbeba iteni N.M. Baumana. (Elastic plates and shells) ANDREYEVA L Ye - FEDDOSIYEV, V.I., doktor tekhn. nauk, prof... red.; ===RTiaftP G.O.p dok-tor tekhn.naukv retsenzent; AKIMOVA, A.G., red. izd-va; ELIKIND, V.D., tekhn. red. (Elastic elements of instruments]Uprugie elementy priborov. Pod red. V.I.Feodooleva. Moskvap Mashgizv 1962. 254 pe (MIRA 15:9) (Measuring instruments) AGPWIROV., V.L., kand. tekhn. nauk; AMEWYA11CHIR, A.V., inzb.; ANDREYEVA L.Yeej kand. tekhn. nauk; BIDER[W1, V.L., doktor 'T4 hn. -;;ik nauk; BOYARSHINOV, S.V., kand. tekhn. nauk; VOLTIR, A.S., prof., doktor tekhn. nauk; DIMENTBERG, F.M., doktor tekhn. nauk$ KOSWUK, A.G., kand. tekhn. nauk; MAKUSHIN, V.M... kand. tekhn. nauk; MASLOV, G.S., kand. tekhn. nauk; MALININ, N.N., prof., doktor tekhn. nauk; PONOMAREV, S.D., prof. doktor tekhn. naukj PRIGOROVSK171 N.I.p prof., doktor takhn. nauk; SERENSElt S.V.9 akademik; STEPANOVA, V.S.0 inzh.; STRELYAYEVy V.S.j, inzb.,- TRAPEZIN, I.I., prof., doktor tekhn. nauk; UMANSKIY~ A.A., prof.) doktor tekhn. nauk; FEODOS'Yb"QT) V.I.) prof., doktor tekhn. nauk; SHATALOV, K.T., doktortDkhn.nauk; YUMATOVp V.F.p kand. tekhn. nauk; BLAGOSKLONOVAI NvYuop red* izd-va,- YEVSTRATIYEV, A.I., red. izd-va; SOKOWVA, T.F.0 tekhn. red. (Manual for a mechanical engineer in six volumes] Spravochnik mashinistroitelia v shesti tomakh. Red. sovet N.S.Acherkan i dre Izd-3.j ispr. i dop. Moskva) Mashgiz. Vol-3. 1962. 651 P- (MIRA 15:4) 1. Akademiya nauk USSR (for Serensen). (Machinery-Design) ANDREMA... M.; K11HYFETS, L.S.; GOLISKAYA, I.F., inzh.-metodist; VODYANITSKAYA, Zh.I.; KOZHEVNIKOVA, E.I., starshiy nauchnyy sotrudnik; BLIDMAN, A.I.; VORONOV, B.V. Echibitions and displays. Infom. biul. VDNKH no.11 110-llpl5-18., 26-27,31-32 N 163 (MIRA 18:1-) I*Starshiy ekskursovod pavillona "nimicheskaya promyshlennost," na Vystavke dostizhaniy narodnogo khozyay8tva SSSR (for Andreyeva). 2. GlavnyY inzh. pavilions. "Stroitellnyye materialy* na Vystavke dostizhaniy narodnogo khozyaystva, SSSR (for Kheyfets). 3. Pav!"on "Ehorgeticheskoye stroitellstv-o* na Vystavke dostizheniy narodnogo khozyaystva SSSR (for Gollskaya). 4. Direktor pavillona "Sellikoye stroitellstvol"na Vystavke dostizheniy narodnogo khozyaystva SSSR (for Vodyanitskaya). 5. Pavil(on "Sellskoye stroitel'stvo* na Vystavke dostizheniy narodnogo khozyaystva SSSR (for Kozhev- nikova). 6. Starshiy inzh.-metodist po khraneniyu i pererabotke zerma paviltona. 'qMraneniye i pererabotka merna" na Vystavke cinntizhen1v nn--,4noeo khoz-yaystva SSSR (for Midman)e 7. Glavnyy metodist Pavillona "Professiorallnotakhnicheskoys obrazovaniye-* na Vystavke dostizheniy narodnogo khozyayetva SSSR (for Voronov). ANDRMTA, H. On the rivers of Kamchatka. Vokrug ovate no.8:46-47 Ag 134. (HLRA 7:9) (Kamchatka--Fisheries) (7isheries--Xamchatka) k ~ ij ~ ~,2( ~ "i 4'L ,,'t . "Iflie Installaticii of' ;WrJi FroA-mvC Unin-s on 11* .1 ConotriicLocl oil 1111.1aY Filterin., quaternary Depo~;A,3 In the Central Blac',-Earth Rc,"ions." C,,nI Geol-I.An J`ci, Iloscow 3tate U ii--icni 1'.. V. Lomonosov, '-' Oct 54. (VI4, 2/+ Jej) 54) 30: Skri 432, 2'-.' I'lar 55 -4- ,7q~: 212131 "OtlCAL-v 01 Fo Illil Cu Coulpits in .0indepwr Vajwr tin the Quality nf CQtj~tr %,,, VIllanle sode.6houlla 'ilaplera I snedl v k -('jj~g unflcn%~lorlno "majet nn k8chesivo kondenaft(a. ruv. (Rusm'an'.) and Bitmathnala vml entiml, no. k Aug. A tulal Fe and Cu vontent exemling 0.02~ vallb" a"re"' 4 (if weAtiess in thu izondensti dielechic. 'fables, graphs, with 1) Wnitwition of s. p 48, 5710g.-Cu was -jtmt,,l wk1b in mi m r1l"uIn Ill tim presen" of KIQ,, KCrO,, NabrO, or KCIOx. Gcod results wtre obtained when N tAdded to the CL- sola. ill cillon"itie.1 imufficient vn completc)v dbWvc tbo Qu ppi. and w1wrl titratloil Stoll-d whHe SmIlu of thn ppt, was pteftht. The Tyresenct c4 NH,4 ill solu n USSR / General Problems of Pathology. Experimental Treatment. U-5 Abs Jour : Rof Zhur - Biol., No. 10~ 1958, No. 47010 Author : Andr M Rozin., D. L. Inst t-Wo-f Given Title The Uae of Rndloactive Phosphorus for the DiaGnosis of Breast Tumors and Their Complications. Orig Pub Tr. 1-y Zakavkazek. konforentaii po mod. radiol, Tbilisi, Gruzmedgiz, 1956, 273-279. Abstract The distribution of p32 was studied in 55 patients with malignant and benign tumors of the mammary gland. The patients were treated with isotopes in the foii3 of bisubstituted sodium phosphate in a dosis of 0.12 mu curie In a 40 percent glucose solution, The accumulation of p32 in the afflicted mammary Gland and in the symmetri- cally located area of the intact gland was detertined Card 1/2 , 11 A. .-TA T-A USSR/ClEMISTRY - FRIEDEL-CRAFTS RFACTION BENZENE Apr 49 "Mechanism of the Friedel-Crafts Reaction: IX, The Reaction of Trichloroethylene Wigh Benzene," V. V. Xorshak, K. K. Samplavskaya, M. A. Andreyeva, Moscow Chemicotachnol Inst imeni D. I. Mendeleyev) 5 3/4 pp "Zhur Obshch Khim" Vol XIX, No 4 study of subject reaction in the presence of aluminum chloride shows that polynuclear products of the condensation are similar to those formed when 1., 1-diphenyle-2- chloroethylene is substituted for the trichloroethylene. In the case of the latter, they are diphony1methane, triphenylmethane, and anthracens. Sz-bmitted 30 Dec 47. PA 65/49T24 1 ra d qs, LXWvrff mliia- : a w writ ts c0 lit t nor due" the-xv-4 Y y it, J, 19"o, t13 w 1, it 50 -Cruimw Do] tly EfAld-s, xylliell readilyfef1w fir)m iand arv I it Phol I and rill-Tul acids: the -.1 ly - and m.p art, mhav, lit t1ii... tr,mi, 'nic m ps of tile JIVII(JUO.' All lolo A ~b-'Lll 0 r1 O.S 11114C fr-tiOn of tile acid in 0- Thc lit -,~,mqm vur,cs ore -L I. I-,,, ttt -~rd- !W7i ';' IL 1~' 1;; it. tjll' 11111 1 Of fill' it: Th, 11 % 1--4 127-30', nd Fbe Ist ivus sot. in cl-11 aild UO 4!l1tHl4t. litolir, tht; ?t-Ld ~(--l III If C) uljd wvre H and f, Ight] -'UA FR , 1- . 'I'ili~it"~"- 'nit ether III'L. 1, 11-14. etlectil". In t It, -:1"cr ".ht 1, it k 1, wn tcd in the avid r rqidui at 1wr t 1 it) t d a nine. Copulynturit wt:re prept. fTLI[l) find I in " "T ious proportinl;N; th~e ~illilj 11-11V q1th'tRu", :11!- (-,Ill f"r"l f1hrr,i ('It qrrtching in Ott Cold %lall l1w lit 1, "1 111. :11,' 1 1-0- t O""'I'l wil, it Onwouell, sy6ituni of tabled polymninies Irldlidilig ii-Ilittlo acids. V. V. Romhak, T. M. Frunze, and L it. Dikartyu. In-rij Akad. Nalsk. S.S.S-R., Oidd 1, li,,7775-uT-)W, 108- 13; Bull. Acad. Sci. U-S.S.R.. Mr. Chrin SIN. 19S6, 101-105(Engl. transhition).-Ternitry systcrn dia- ~rnrrts are preimutir.-d far tnixf%d paly-tniidew pri pA fl-ilm -m- onlLii,ms -J an.in,lurld-arloic %cids, and adipi, , a2elaic, cir sc;x%--ic acid.- 4)T c-.-pruI:),-l-n ',It( Ii- 1 t ni.ps. and highest soly. are found in products near the cmter~ of the terna-ry diagrants. XC. Polycoridepration of 1,2- 41thlorcietbane -wHh TotrdW- - G. S. K -QV, V. V. Rmhak, M. MA: And A-7-Rit I 'rQlt"-U' 4- Test A kad. a Otdtl.-i 1956, 114 - :19; Bull. Acad. Sci. U.S-S.R., Div, Chem. Sri. 1956, 107- '111(Engl. tratLdaticit).-Polyc4xidcjLq:Ltion of (CILM4 with letTuhydronaphthalerie in the pre:~encv of AICIa was studwd in inixt, 4 vatioui ~itnpns. treatoi 4 hr~. tkt ItK)'. With -I'm y. 4d 4D.1 P49~wiairia H4L t &~ QW16t. ~nd in, 4 wt. in formed with ! I !1 0 imici rI Tcualm 1~~ ~( It, CI .1 DIC IE'. Infil %V( . 1q I X!6M jv.~ -6; - payee Irmp nvi CIL; Z - 2 M inalt edl. lhto tridimensiona) pWyvier &rrns in this reacti-on. The p,4)mjozk product dries nut slinw ass'Lwo, .i- C.H. Until th~ ~~h% rr~zchei about 10% volicn. XCI. Trangarylation of 11,2-dipbertylethene at varfous tempera- tures. G. S K nl~nikx- and V. V. Karshak. lirveit. A kid. Allyuk S.S.S R , ()Uej. AAim, A~zvk 1056, '-132 9, B.11 Aead Sm U S.S. R., D.m. JQ56. =J- 7( J~s)gj uanAafiml ' f C 4 4f . 7.1~'?U qpe~cimr- , 4 ~ t' . IIP~OPI! M -11,t 11-1, -th AICI., .111. L--V I', .""I and 11- ..'t If ~V" vVil C.H. detd. Vs (III], Pic T, m-lual tolyp;ievvl~thyl ",,s i,~,Iatt,l as --Lwal I'b( F-mit sh,mn graphi'-WY Ind$,-aft that in the trinp. rung. the tranw0mim it-actn,n is with ;,ki~vmwn energy 11,400 cal. per mole. The chain gn-i-th !if thr P'4yrner rm-Ults I-th from inteniction of the rytIviner mols ami from reactiim >I the monirrurr with a glowITIR Chain- The mol, wt. of time polyrrwr lnaewso with jising tcmv- IIRL I Mim: lots fter- mbout -25.0W-m i shown initim. -mof. wt. of K7150 fect of CA141YISt concentration on tranSiVylallon Of pbemylethane. fxvojj. Akad. Nauk S.S.S.R., Odd, Khirn- Nauk 1036, 2" 42; Bull. Acad. 'q'i V S.S R., DIV Chr"I Srs 1054, =~-,31(Rngl trans!ation) -lncYvA%e uf concil id AIC13 us;ed in the reaction (cl part ),CI ~ m,,ults, in grad- &II-N incmaFirtg yield of the polymer up to 13.0 mole-70 AICII; the Mte of reaction rises linearly with corim. of AICJ#. The Yiel(l of tridirrimsiornil polynirr riv-swith increa4,,d A11C), concri in I Cild S t" I 1v kt, im ".d " 'lit u of t h, o-1 I dimemional j;,Aymu fOT111% ItTitILUily fl(A!1 OIL "t . "Xilf Pf.pertiea (d polyesters of mjiL~L \1 V. K,w~~w!, at,d enz nd 1,3-butLp -26, '539-1-109513"~ . pe glycol or 1,3-Ijut 111tiloffic, vuc- VIC with oxalic, Ciatt'. Afliflic, rhitllic, pill,elir, arelaic, ~cLiacic, and dc-c- itTledlic."11-bo-, ylit, acid'. Tht. polycStus IT0111 tC%Tvcn-.eT11Y I I'll- glycol 11-cre lmolalN wj)('~-u 11t.pq. "I'muo ibv Fisw-t(.1111 ilit( I nation ; I ~11 mala-'r, III- 1113-h" 111(frm'Itt" til --,',0' lit -:.A" 111~ 58 110" 41. as'. 41" pittic1itc, m 4~i 01". ealc,' in 1A 7". 1 lie polycitc-rs (,1 1. wtic liq1ti(N wifh ~-Ihfirw~Ltklfl tv-mps'. in tile -.I' rjupr whicl~ .' cimd it allo-ax"'11, Lut i'laich t'..; li-- pronk-1111, v'l I-11, ul.p~ of I,,: ~'OY-1,:1 1; w1im;' 'k-.' LI-1 1~ 1( lion -wall 11"-A. ".~ KCIV one and PCtit-1~t~i-13-ler- OYCOir. of Wjlj))~014)3 and (CII2).(0II)T wem jurlid. %ith dic~ir- 1:-Ylicadd-~Jro.m -x~djc Tbitse wvii low-McIting ,iilids, gcntj~illy ~ji('.wing a rj,,insi m.p. pa5t. ,it, dnic acid e!;:VF; the est~15! Milt maIrmii: ~Itid %Vcfc litillidl., 1-it. ukint which mm~' -.eiltcll a mict T1- .wC'A;1atzL lut1tra abovi: 111~ rhaatatr'. Tht I-M givenIs tkith al (xid tti,. n! C Rtotw. deAwY flu lat ti)r o: -,,vcu~dd scqutuee, beginning Nrim i , ,it, , wition uf intmiuj! tttf.p 6jjjt!ity ~mi~ ,,Iy. it, 1w,p-i .Cxhu.. G' M. Kw~[Aqmll ILW Chnistr7 - Molecular ac"ounds, Oftmd 1A Pub- 40- 20/25 Authm j Kolesnikov, Go S.; Korshaki V. V.; !'nj~!yeva, M. A.; and Kitaygorodekvv ~AeL Title IHigh molecular compounds* Part 90o Polycondenaation of lj2-dichloroothane with tetralin Nriodical IIsy. AN SSSR. Otd. khim, nauk 1. 114-119, Jan 1956 Abstraot iThe polycondensation of 102-dichloroathans with tetralin %as investigated in the presence of aluminum chloride and the basie laws governing thin pol7c*6- densation process wers.,establi shed, On the bi-'Aa of x-ray, amlyals-it at-1;2Ldi4 t - -ilyl) othan 4 is ~ the product -stages.- 'Me formation of threel~fiiii~aa polycondeneation products was observed in spite of the fact that the potential functien of tetralin is only 4.- The effect of benzene-solution concentrations of polytetralylenethyl, on the polymer moleculv aesociation is.diecuseed. Seven referencesi 5 USM and 2 Gem. (1921-1955). Tables; graph. Institution t Aced. of So.# USSR, Inst. of Organoolemental Ccepounds Slamitted iNovember l8j l954 tj I'Ap-l-rizaduai A CM ~Vv;iiiy ~Pilt tkj-yjpktmpbvTIIr addij. V. L,,,~e ~4- C-IjLjl~1~4 4TfjI kI A. ~Irist. lf-7-77R; a-d ,Id" f :1 L 7 07 I iflAt L4 Rl-)Vt ilh Na -, Il Lit 140' pvt! Pvc IS 40e P4 10 Lit tier (I)i. '.1-- 1 0 1,, 4-1 A- LIP, tip Ilottlit, ut - wi LUTHORS: Korshak~ V. V., Gribova, I. A, SOV/62-58-7-14/20' TITLE: An Investigation Within the Field of Organophosphorus Folymern (Issledovaniye v oblasti fosfororganicheskikh polimerov) Communication 4: On the Polyesters of Some Phosphinic Acids and of Hydroquinone(Soobshcheniye 4. 0 poliefirakh nekotorykh fos- finovykh kislot i gidrokhinona) PERIODICAL: Izvestiya Akademii nauk SSSR, Otdeleniye khimicheskikh nauk, 1958, Nr 7, Pp 880 - 885 (USSR) ABSTRACT: Already earlier the authors showed that after the interaction between dichloranhydrides of the alkyl and aryl phosphinic acids with glycols in the presence of hydrogen chloride binding substances the formation of polymer esters takes place. In the present paper the authors describe the synthesis of polyesters of various phosphinic acids and of hydroquinone. It was found that -the nature of the substituents at the phosphorus atom exerts a considerable influence on the properties of the poly- esters. The introduction of an aromatic residue into the poly- Card 1/Z mer chain leads to the production of solid products (in con- An Investigation Within the Field of Organophosphorus SOV/62-58-7-14/26 Polymers. Communication 4: On the Polyesters of Some Phosphinic Acids and of Hydroquinone trast to similar polymera being produced from aliphatic glycols). The polyesters produced were formed by the con- densation of the chlorine anhydrides of the corresponding acids and of hydroquinone in the presence of metallic tin. The investigation of the binary system within the entire structural range (diapazon sostava) showed that a minimum of the melting temperature is exhibited by the copolymer (of a certain structure). There are 2 figures, 4 tables, and 7 references, 3 of which are Soviet. ASSOCIATION: Tnqtitut elementoorganicheskikh soyedineniy Akademii nauk SSSR (Institut,,, of Element&l-organic~ompounds AS USSR) SUBMITTED: December 21, 1956 Card 2/?- STEPANOV, B.I.; ANDMYEVA. N.A. Substitntion of halogen into azo compounds. Part 3: Preparation of o-arylalkoxyaniline derivatives. Zhur.ob.khim. 28 no.9: 2490-2191 S 158. (HIRA 11:11) 1. Notkovskiy khimilco-takhnologicheakly institut imini D.I. Vende- leyeva. (.Aniline) Andreyeva, U. A., Stlepanov, SOV/79-28-11-14/515 On the Substitution of the Halogen in Azo Compounds (0 zameshchenii calogena, v azosoyedineniyakh) V. Reaction of the Copper Complex of 2-Chloro-Benzene Azo-21- Naphthol With Alcoholates (V. Vzaimodeystviye mednogo kompleksa 2-khlorbenzolazo-21-naftola s alkogolyatami) Zhurnal obshchey khimii, pp 2966 - 2967 (USSR) To explain the mechanism of the substitution of the halogen atoms in o-halogen-ol-oxy-azo dyes in the presence of copper salts (Ref 1) it was important to carry out this reaction using the complex compound of a halogen containing dye with copper and without the free copper salt. First the reaction of the copper complex of 2-chloro-benzene azo-21-naphthol (the azo dye from 2-chloro-anilineand 2-naphthol) with alcoholates of n-butyl and benzyl alcohol was carried out. The copper complex of the chlorine containing dye was obtained according to Crippa (Krippa, Ref 2) in a somewhat modified form by the reaction with copper On the Substitution of the Halogen in Azo Compounds. 30'1/79-26-11-14/55 V.Reaction of the Copper Complex of 2-Chloro-Benzene-Azo-,21-Naphthol With Alcoholates ammonia solution on its heating in acetone instead of alcohol. According to the analysis this.complex contains one copper atom per two dye molecules, and apparently has the mentioned structure (I). The reaction of the~complex with sodium butylate and sodium benzylate in the solution of the corresponding alcohol was carried out at 100-1o30 within 8 hours. From the reaction products dyes were separated that turned out to be the products of the substitution of the chlorine atom by the corresponding butoxy and phenyl methoxy group (94.3 and 95-06). Thus, the chlorine atom in the copper complex was substituted practically quantitativelybjltbealkoxy groups in the presence of the free copper salt. The dyes were identified according to the melting point of the mixed sample with the corresponding alkoxy substituted dyes. There are 3 references, 2 Soviet references. Card 2/3 On tho Subatitution of the-Halogen in Azo Compounde. SOV/79-28-11-14/55 V.'~eaction of the Copper Complex of 2-Chloro-Benzene-.'ftzo-21-HaphthoI With Alcoholatos ASSOCIATION: Moskovokiy khimiko- Vtekhnologicheskiy institut imeni D.I.Mendeleyeva (Moccow Chemotechnolojical Institute imeni D.I.Mendeleyev) SUBIZITTED: Aug"St 31, 1957 Card 3/3 AUTHIOR. V, V, Formin) So Po Vorobov) M. A. Androova TITLE: The Investigation of Complex Plutonium Oxalates by the Polaro- graphic Method PMIUL:OAL: Y~an Tzii Neng, 1958, Vol 3, Nr 5, pp 450-456 ABSTRACT: The composition and stability of complex ions of tri-and tetra- valent plutonium in oxalate solution wore investigated by the authors using the polarographic method. The process is described, The ions of Pu (02 04) 1~4 (predonderant) and Pu (C2 04)4 -5 were f ormod in potassium oxalate solution with PH 3.5-6. Pu#4 gave a well reverse reaction wave which is suitable fo., the quanti- tative determination of plutonium by the polarographic method. In 1M potassium oxalate solution, the oxidation-reduction poten- tial of the above reaction is 0.205V (corresponding to a saturated calomel electrode at 25 0). At pH 6-8, the authors discovered that two Put4 con. plexes were simultaneously present. The authors determined the instability constants of Pu (C. 0 ) -5 from the data on the solubility of Pu 02 Ok)3 and the i~~ographic method Card 1/2 is: Kp'u -5= 2-4 x i6-~O 2.2 x 10-1-1, (02 0404 PU (C204)3 / Y AUTHORS; Fominj V. Vol Vorobtyevs So P,s Andreyevas Me As 89.0.7/29 TITLE; Imreatigation of Complex Plutonium oxalate Compounds by the Polarographic Method (Isuoheniya komplakarqkh ok9alatav plutoniya polyarografioheakim metodom). FERINICAL: Atomnaya Energiya, 1958., Vol, 4. Nr 1, pp. 57 - 62 (USSR). ABSTRACTt The composition and constancy for tri. and quadrivalent complex plu- tonium ions in oxalate solutions was determined by the polarographic method. In a solution of potassium oxalate with a pH value of from 3~5 to 6s,0 mainly (C P 4) 41 4 and also EFU(C204 Q -5 are formed. Conditions being as they are give% there exists for Pu+4 a well de- veloped reversible reaction-waves which suffices for the qualitative polarographic determination of plutonium* The oxidation reduction potential for this reaction in a 1 M solum tion of potassium oxalate is 01205 V- +4 If the solutions have a pfi valud between 6 and 81 then two Pu Comm plexes exist at one and the same time. From the data for the solubility of [Pa(C20033 the instability cons Card 1/2 stants for the complex ions [Pu(C204)3) 3 and Lpu(C204) 4)"~ and from Card 2/2 'r ANDRKYh'VA, M. As Cand Chem Soi -- (dies) "On the mobility of halogen in certain halogenoxyazo-oompoundae" Mos, 1959. 11 pp (Min of Higher and Secondary Specialized Eduoation RSFSR. Mos Order of Lenin Chemiooteohnologioal Inst im D. I. Mendeleyev), 150 copies (KL, 52-59, 116) -14- 5(3) r. SCV/1 56-59- 1 -36A.14 A U T 11`0 R S Ste:~,anov, B. I, , Andreyeve., % 1J. A. ------- T I T ' 171 - -------------- t! -. Sixbstitution of Atom~s in o,o-Dihaloacn-ol- oxyazo-dyos (0 atomov UaloC;ciia v o,o-digaloi,-er- o I -ok"da-zol-rasi tolyalch) P11 :1'~DICAL: Nauchnyyc doklady vysshey s hkoly. ".himiya i Ichimic:.0skaya tek-hriol(q;iya, 19511, 11.r 1, p p 1111 - 1,12 /us-p A T; co 2AL: Por the investi--ation into the mobility of 1,alo-cri atoms in o-halo~;on-ol-oxy compound.- (Relfs 1,2,3), 2, 6-dichlorobenz one- (1-azo-11).-naphtlicl-21, an azo-dye from 2,6-dichlt.ro-aniline and 2-naphthol, vias used as an initial This o.-oxyazo compouivt thuL cont ained t.-:cj halcj~,,n atom.,:. in an ortho-position with r(-,Lard to the azo-grou.,,. It was found that on the reaction of this sub staiice with alcoholates (scdium- n-butylate) and phenolates P--4-Phenyl-pl~c-olate) in the presence of copPer salts a praclically quantita'.ive substitu- tion by the respective alko xy- or phenoxy-t;roup of the two halo.gen atoms ta-c~ place. This substitution occurs far more readill, than it does in the anal(,gous compounds containing Card 1 2 only one halcL-en atom. The experimental part [:ives instructions KORSHAK, '7.V.; GRIBOVA, I.A.-, ANMYEVA. M.A... 6.4 WUWA. 0L., - fivie-;Nk -,I ~ ~, Organophosphorus pol7mers. -Part 8: Nlyesters of phosphonic acids and of some aromatic dioxycompounds. Vysokom. aced. 1 no.6:825-828 j6 159. (MIRA - 12: 10) l.Inatitut alementoorganichookikh soyedineniy AN SSSR. (Pol7mers) (Phosphorus organic compounds) S7,34,70 0 81586 3/190/60/0,02/03 1-7. 'f% B020/BO66 AUTHORS: Korshak, V. V., Gribova, I. A,., Andreyeve.,-,M. A. ai~ TITLE: Investigation in the Field of Organophosphorus Polymers.l. Jof the Dichlorides of Phosphinic Ix. Polveondeneation. Acids With Dioxy Compounds PERIODICAL: Vysokomolekulyarnyye soyedineniya, 1960, Vol. 29 No. 39 pp. 427-432 TEXT: The objective of the present paper was an investigation of the influence of various factors upon the polycondensation of the di- chlorides of phoaphinic acids with dioxy compounds as well as a kinetic investigation of this reaction which proceeds according to the scheme 0 0 11 11 C1 - P - Cl + HOROR P - ORO- + 2RC1. R' Card 1/4 Investigation in the Field of Organophosphorus Polymers. IX. Poly- condensation of the Dichlorides of Phosphinic Acids With Dioxy Compounds 81586 S/190/60/002/03/0,~.'r B020/BO66 glycol, diethylene glycol, and triethylene glycol) upon polycondeneation with diohlorides of phosphinic acids. The polyester yield was found to increase. Fig- 3 shows the influence of the reaction temperature of methyl phosphinio acid dichloride with hydroquinone upon the yield and reduced viscosity of the polyester. A considerable effect on the reaction rate is exerted by the reaction temperature and the concentration of the initial reagents. Fig. 4 is a graphical representation of the degree of completeness of the reaction of methyl phosphinic acid dichloridep and Fig. 5 shows the temperature dependence of the reaction rate constants of methyl phoophinio acid diohloride with hydroquinone and diethylene glycol. The reaction rate constants are given in Table 2. The conditions of the reaction of methyl phosphinic acid diohloride with hydroquinone and the results obtained from this reaction are represented in Table 3. There are 5 figuresq 3 tables,and 9 references: 6 Soviet, 2 British, and I Dutch. Card 3/4 S/079/60/030/04/69/080 BOO1/BO1 1 AUTHORS% Andreyeva, M. A., Stepanov, B. 1. TITLEs On the Substitution of Halogen in Azo Compoundel, IX. Influence of the Position of Halogen and of Nucleophilic Substituentep and of the Nature of Nucleophilic Substituents PERIODICALs Zhurnal obshchey khimiij 1960p Vol- 30~# No. 4, pp. 1350-1356 TEXTt With a view to determin-.6 the limits of applicability of the substi- tution of the halogen atom in azo compounds# the 6uthors of the present paper carried out the reaction of n.-sodiuih butylate with chlorine-containing azo L-1" compounds in the presence of copper salts differing by the position of the chlorine atom and of the nuoleophilic substituents in relation to the azo group, and also by- the character of nucleophilic substituents. The substi- tution of the halogen atom in azo compounds was found to take place only in the case of the vicinity (ortho-position) of-the halogen atom and of the nucleophilic substituents to the azo groupt as well as in the presence of a mobile hydrogen in the structure of the nucleophilic substituent. The reaction is the easier, the easier hydrogen is replaced by metal. It was found that Card 1/2 On the Substitution of Halogen in Azo Compounds. S/079/60/030/04/69/oao IX. Influence of the Position of Halogen and of B001/BO11 Nucleophilic Substituents, and of the Nature of Nucleophilic Substituents V~5 the halogen atom in qM dves can be replaced by arylides of A-keto acids and amines as the azo components. The halogen atom was found to be replaced by. the alkoxy group on the reaction of the copper complex of o-lialogen-ol-amino dye with alcoholates, without free copper salt. On heating the azo dye, which contains a methoxy group in the naphthalene ring in the ortho-position to the azo group, with sodium butylate in the presence of a copper calt, the methyl residue in the eater group is replaced by the butyl g-roup, There are 2 tables and 12 references, 6 of which are Soviet. ASSOCIATIONs Moskovskiy khimiko-tekhnologicheskiy institut imoni D. 1, Mendeleyeve, (Ijoscow Institute of Chemical Technology imeni D. 1. MendeleyevT- SUBMITTEDs March 14, 1959 Card 212 STEPANOV, B.I.; AITDIRMXTA, M.A. Substitution of the halogen in azo compounds. Fart 11: Significance of certain space factors. Zhur.ob.khim- 30 to.8:2748-2754 Ag ,6o. (KIRA 13:8) 1. Moskovskly khimiko-tokhnologichookly institut imeni D,I, Mendeleyeva,. (Azo compounds) (Substitution (Chemistry)) ANDREYEVA, M,A.; STXPANOV, B.I. Substitution of the halogen in azo compounds. Part 12: Influence of the nature of the halogen. Zhur.ob.khlm. 30 no.8:2768-2771 Ag 160. (MIRA 13:8) 1. Hookovskiy khimiko-tekhnologichaskiy institut imeni D.I. Mendeleyeva. (Azo compounds) (Substitution (Chemistry)) 1-7 T,' r- L IW;F A. V. K'rtl,,ov ct 1. . . . . . . . . . . . . . . . . . . . Ma 27: 1.3. 1. N. . . . . . . . . . I . . . . . . . . I . . 1'.*5 2ti. bl,'=ION OF All.-i'l. 1AIIII-ES. K. S. 1,-vct.,-nko et %I . . . . . . WIG 1:9. 01' CARBOXYlaC ACIDJ comwom-').3). ' G. 1. 1),~rhach . . . . . . . . . . . . . . . . . . * ' ' * * * 64 30. ;A al M'.CT!C:;3 OF MWJT;iO-':Y:;6JRU3 C)!Uj:UDy.3 W17,1 ACII) AXIIJE3. I htvc ,o et . hc 31. OF DIAIK(TJT0.;* 1i'!oT-!: ACT Z!:',. E. 11. TLivet-kcIv . . . . . . . . . . . . . . . . . K. A. retriw and A. 1. Onyrt lopt . . . . . . . . . . . 197 34. I -CY L I S. n RKA~ITON 01' Dill-, :'J I i*"'.; V 1 0 C-7 35. (~Y )'.~U Xl' RIC AM) ACOM. IX4 0' 11 F. at, 1 !1. L;. . . . . . . . . . . . . . . . . . . . . . . . . . 212 L:.Tj~Z OF D-',!i"'*,T'- ~'j AC!). G. f;tykn , . . % 17 37. ACT-01. 0" CA],'"1% A:I:~:- i-~I-'.--'!-'. OF AC"D. G. t-' al . . . . . . . . . . . . . . . . . . . . . . . . . I . . . . . . . ;I'n I ~.FIIIMICN OF M711-~-:TC `r7! 7~ :: ":z :-, "t-J;; C. L. V. N~~ ;--rev -A ~'.A. 39. RUZ;ION OF 1 - 1: 1,7 1: 1,; 1', ~ i A' t :C CCIM.; A. F. Gr ~',-,v . . . 'o. I j::L;~"'~ ACID V;Y.~: CiIIrNM'F. L. Z. REACTX!; r, v a 41. ACK71VIIEj. I.F. 11AIL."E.n."o ~. I 'k". Y" -,37 42. s;7:AY-; 0.0 0: 1., YI5;'KR.;. V. V. xonl:n!'. ot Ell. . . . . . . . . . ;-V., 43. S-14n'3131 G-F 11*.Cj"~.10).Y1.1c AMS V;) C' I-Rim V. V. Korzi::,i~ --L al . . . . . . . . . . . . . . . . . . . . . . . . . 44. SYN-11:1-1~3, O~ OF VII."!'L::':).'.i':-'-. T." C r. ~% 1'. Ill . . . . . . . . . . . . . 45. 1.::'; OF NI-4 ('P, 3 46. 5-.WN~EJIS OF IM'UNC4 1' %"Ij, A. 47. SYNT;M~L-, A! N 'C'Vi"O'.'; or, 6:~ 0U.N.Y.; N j'I-"iC3 1'. A. "t .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . tn. I)li3~';I');-":",I"-Co:""",:;II.L; J"~:: K. A. Yot-roi et ill . . . . . . . 49. "'PTLICIVII ION OF lc~:tica of Yo. 17i1. pvbl. Izr L'It"n' lc:i-a. Eel. tVwIZ, Conection of cm-plotc rrj--~rs Iwunciated at t1o 1959 JZazrm CQrTc,rcnco on CLnullutry of Ori;emophoophoms Coc.NwLdo. KORSHM VS., GRIBOVA, I-i-, AWDREYEVA, M.A. Research in the field of phosphorus-containing polyesters. Khimiya i Primene-niye Fosfororganicheskikb loyedineniy (Chemistry and ap,)Ucation of organoohost)h:)rus cormun('!s) A. Y+,. Ed. Omi)IQ by Kazan Affil. Acad. . leis USS?, Moacow 1902, 032 m). Collection of covm'_et4~ nawra L)rnsanted at the 191-',,9 Kazars ~-Onforence Om Chemistry of :Tganorhonphonin Gorwounas. AND.TizyEvA M. A. PHASE I BOOK EXPLOITATION SOV/6034 Konferentstya po khtmit i primeneniyu foefororganicheakikh soyedinenly. 2d, Kazan!, 1959. Khimiya i prime6entye foefororganicheskM soyedineniy; trudy (Chbmistry suid use of 01-19anophosphorus Compounds; Conference Transactions) Moscow, SS Izd-vo AN S R, 196Z 630 p. Errata slip Inserted. 2800 copies printed., Sponsoring Age y: Akademiya nauk SSSR. Hazanskly filial. esp. Ed. -. A. e. Arbuzov, Academician; Ed. of Publishing House: L. S. Povarov; Te h. Ed. - S. G. Tikhomirova. PURPOSE: This collection of conference transactions is intended for chemists, process engineers, physiologists, pharmacists. physicians, veterinarians, and agricultural scientists. COVERAGE: The transactions include the full texts of most of the scientific resented at the Second Conference on the Chemistry and Use of -rs C~rd IIJ Chemistry and the Use of Organophosphorus (Cont.) SOV/6034 Organophosphorus Compounds held at Kazan' from 2 Nov through I Dec 1959. The material is divided into three sections: Chemistry, containing 67 arti- cles; Physiological Activity of Organophosphorus Compounds, containing 26 articles: and Plant Protection. containing 12 articles. The reports reflect the strong interest of Soviet scientists in the chemistry and application of organophosphorus compounds. References accompany individual reports. IShort summaries of some of the listed reports have been made and are given 'below., TABLE Or CONT ENTS: (Abridged): Introduction (Academician A. Ye. A buzov) 3 TRANSACTIONS OF THE CHEMISTRY SEC~ION Getter, Ye. I- INU plastmass (Scientific Research Institute of Plastics. Moscow]. Some Prospects for the Industrial Use of Organophosphorus Compounds 46 Card 70A Chemistry and the Use of Organophosphorus (Cont.) SOV/6034 triorganosilanols (113SM) with acids of phosphorus under condi- tions of azeotropic distillation of water in the presence of inert solvents. Another is based on the interaction of triorganosi lanes with orthophosphoric and methylphosphonic acids in the presence of active colloidal nickel. Korshak, V. V., 1. A. Gribova, and A. Andj~~va [Institut ele- mentoorganicheskikh soyedineniy (Institute of Organoelemental Com- pounds, Academy of Sciences USSR, Moscow)]. Study of Phosphorus- Containing Compounds 242 The polycondensation of dichlorides of phosphonic acids with diols has been studied by following the interaction of m ethylphos phonic dichloride with hydroquinone in a nitrobenzene solution at a tempera- ture of 140 to 170*C. The properties of polyesters of phosplionic acid have also been studied. Card 4(Zq~ -3V,~ S/081/62/000/023/120/120 B117/B186 AUTHORSo Korshak, V. V., Gribova, I. A., Andreyeva, M. A. TITLEr Study in the field of phosphorue-containing polyesters PERIODICALt Referativnyy zhurnal. Khimiya, no. 23, 1962, 617, abstract 23R60 (In colleotiont Khimiya I primeneniye foafororgan. soyedineniy. M., AN SSSR, 1962, 242 - 246) TEXT3 Phosphorus-containing polymers (PM) with heterogeneous chains were synthesized by poly condensation of methyl phosphinic dichloride (I) with aliphatic and aromatic dihydroxy compounds. The second-order reaction occurs between (I) and hydroquinone (in nitro-benzene at 140 - 1700C), UP and diethylene glycol (in dichloro ethane &t 40 - 800C) with activation energies of 10.5 t 0971 and 7-5 t 1.0 kcal/mole, respectively. Yield and molecular weight of PM Increase considerably with increasing temperature. The formation of cyclic eaters occurs as a side reaction, mainly in the case of the lower glycols. Based on aliphatic glycols, the PM are thick and viscous liquids; in the case of aroaRtio dihydroxy compounds, they are solid transparent substances. The PM are soluble in CHCl 3 , dichloro ethane, and Card 1/2 3/001/62/000/023/119/120 B117/B166 AUTHORSi Gribova, I. A. , Kabachnik, M. I. Koleanikov, G. S., Korshak, V. V., Medved', T. Ya.: Polikarpov, Yu. M., Rodionova, Ye. F., Pedorova, L. S. TITLEt Some methods of synthesizing new organophosphorus monomers and polymers PERIODICALt Referativnyy zhurnal. Khimiya, no. 23, 1962, 816, abstract 23R58 (In collections Khimiya i primeneniye foefororgan. soyedineniy. YI., AN SSSR, 1962, 263 - 271) TEXTt This is a review of the authors' papers on synthesizing vinyl oom- pounds of quinquevalent P and polymers based oh them. Syntheses of varioup derivatives of vinyl phosphinio and vinyl thiophosphinic acid, and of diethyl vinyl phosphinic oxide, have been described. The production of some new phosphorus -containing polymers and copolymers with carbo-chains'and heterogeneous chains is described. 13 references. EAbstracter's notes Complete tran8lation.3 Card 1/1 .-ABTMVA, M.A.9 GPJUDVAI I.A.9 UMCHNIK, M-I-9 KOLFSNIKOVi Gz5-j, KORSHAK;-V-.V-.,,-MDVED's T.YA., POLIKkRPOV9 YU-M-s, RODIONDVAO YE.F.,O FEDOMVAq L.S. "Some means of synthesizing new organophosphorus monomers and polinners." Khimiya i hImeneniye Foafororgutichaskikh Soyedimniy (Chemistry aM application of organophosphorus com)ounds) A. TR. ARHAW, No Publ. by Kazan Lffil. Acad. Sci. USSR,, Moscow 1962, 632 pp. Collection of comolets papers presented at the 1959 Kazan 'Conforvnee an Chemistry of Organc,--~,hosphorus ComoourAa. STEPANOV, B.I.; VOROBIXEVAj I.I.; ANDREYEVA, M.A. Substitution of halogen in azo compounds. Part 14: Substitution of chlorine in the azo dye of 3-chloro-3-aminoanthraquinons and 2-naphthol. Zhur.ob.khim. 32 no.10:3281-3283 0 162. (MIRA 1511l) 1. Mookovskiy kbimi o-tekhnologioheokiy inotitut imeni D.I. Mendele va. (Ayz'ao dy.-,a) (Chlorine) (Substitution (Chemistry)) AWYEVA, M.A.1 VOROZHTSOV, N.N., mladshiy; -OIZIIECIIKOVSKAYA, N.I., STSPANOV~ B.Io; YAKOBSON, G.G. 910. N,~ , 1 " Substitution of halogen in azo compounds. Part 17: Reactions of polyhaloazo compounds. Using the reaction for establishing the structure of some aromatic halogen-containing compounds. Zhur.ob.khim. 33 no.30"91 Mr 163. (mm 160) 1. Mookovskiy khimiko-tokhnologichoskiy institut imeni D.I, Mendeleyeva i Novosibirskiy institut organiehoskoy kbirnii Sibirskogo otdeleniya AN SSSR. (Azo compounds) (Halogen) KCRSHAK, V.V.; GRIBOVA, I.A.; ANDi~'EEVA, M.A. Phosphorus-containing thermosetting resins. Plast.masay no.10i 1-1-12 163. (HIRA 16:10) STEPANOV, B.I.; ANDREYEVA, M.A. Interaction of 2-chlorobenzene-(I-azo-It)-21-naphthol with fluorene. Zhur. VKHO 8 no-5:577 163. (MIRA 17:1) 1. Moskovskiy khimiko-tekhnologichooldy institut imeni Mendeleyevao ANDRMVA, M. A. Dissertation; *On the Changes in the Degree of Dispersion of Solutions Obtained by Means of Colloid Solvents,* Cand Chem Sci, State Sci Res Inst of Roentgenology and Radiology, Baku 1953 W-30928 SO: Referativnyy Zhurnal, No. 5, Dec. 1953, Moscow, AN USSR (X4*M) ANDREYNTA, M.A. Dissolving essential oils by complex colloidal solvents* Uch, zap. AOU no.7:35-40 157- . (MIRA 11:11) (Zesences and essential oils) (Solvents) 1~11D 362)40/62/004/001 /009/020 B1O1/B1 10 AUTHORS: Korshak, V. V., Gribova, I. A., Andreyeva, M. A., Popoval G. M. ---------- TITLE: Polymers containing phosphorus. XXVII. Heterochained polyesters of vinyl phosphinic acid with some dihydroxy compounds PERIODICAL: Vysokomolekulyarnyye soyedineniya, v. 4, no. 1, 1962, 58-63 TEXT: The authors report on the properties of eaters of diethylene glycol (1) and 4,41-dihydroxy-2,2-diphenyl propane (II) with mixtures of vinyl and methyl phosphinic acids. The syntheses of these esters have already been described (Vysokomolek. soyed., 2, 427, 1960; Izv. AN SSSR, Otd. khim. n., 1958, 880). Eaters with I -are colorless, viscous liquids. Their freezirg point drops from -390C (104 CH 3POC12) to -5100 with 100% CH2-CHPOC12 in the initial mixture. Eaters with II are transparent, brittle solids soluble in dichloro, ethane, chloroform, and tricresol, insoluble in ethar, benzene, and dioxane. Their softening points drop from 55-560C to Card 1/2 8/1932 47 BJOJF6~2/004/001/009/020 Polymers containing phosphorus. BI 10 41-420C (- 100% vinyl phosphinic acid) as the content of vinyl phosphinic acid increases. Struoturization of the eater of I (in sealed ampuls, N2 atmosphere, at 600C for 15 hre, or in an open test tube and in C2H 4C12 solution) by benzoyl peroxide, tert-butyl peroxide, azoisobutyrie dinitrile, tert-butyl hydroperoxide, or cumene hydroperoxide, only occurred with a vinyl phospbinic acid content :-'- 40% (gelatinous substances# softening points: 150-2000C the latter value with 100% CH2-CHPO-). Eaters with II could not be structurized under the experimental conditions, applied. There are 2 figures, 4 tables, and 4 Soviet references. ASSOCIATION: SUBMITTED: Institut elementoorganicheskikh soyedineniye AN 999R (Institute of Elemental Organic Compounds AS USSR) January 26, 1961 Card 2/2 L 12725--63 EPF(c)1iwP6)1swT(mYbw, Ao Pr-Vpc-~4 Rm/ww ACCESSION NRs AP3002.291 51006210100010061109313200 45 AUTHOR: Korshakt-V. V.; Grii*va, I. A.;4ndreyeva, K. A. TITM Research on manophosp,hor,ous" R21~mers. Report 28. Transesterification of~ diallcyl esters of phosphinic acids with various glycols SOURCE; AN SSSR. Izv. OtdolenVe khimich skikh nauk, no. 6, 1963, 1095-1100 TOPIC TAM transesterification, organophosphorous polymers. dialkyl aster phos- phinic acid, dibutyl methanephosphinate, dimethyl mothanaphosphinate, sicosa- rethylene glycol AB5'.MGTs Dibutyl and dimethyl methanephosphinate -were synthesized from the acid chloride and transesterified-with diethylene, hexametliylene, and eicosamethylene glycol. A-number of acidic and basic catalysts were Ltried. Metallic' sodium gave the be3t results. The effect of variations in temperature and length of heating was studied. At the tomperature, required for the reaction to proceed, some dacom. position, contaminating the:pr6Auct with an acidic impurity, was unavoidable. The products obtained with diethylene and hexamethylene glycol are dense, viswus liquids composed mainly of trimers and tetramers, soluble in c1loroform, cresol, and acetic acid, and insoluble in benzene, dichloroethane, carbon tetrachloride, Card ACCESSION NR: AT4033994 8/0000/63/000/000/0117/0122 AUTHOR: Korshak, V. V. ; Gribova, 1. A. ; Andreyeva, M. A. ; Kabachnik, M. 1. Medved'$ To Yas TITLE: Polymers containing phosphorus. X=. Heterocyclic polyesters of vinly- phosphinio acid and some glycols t SOURCE. Geterotsepny*yo vy*sokomolokulyarny*yo soyedineniya (Hoterochain macro- molcc~lar compounds); abornik statoy. Moscow, Izd-vo "NaWca, 111963, 117-122 TOPIC TAGS: vinylphosphinic acid, ethylene glycol, propyleno glycol, diethylene glycol. s., trimethylene glycol, butylene glycol, polymer, cyclic polyester, polymerization, polymeri-p' zation catalyst, metallic sodium, linear polymerization, radical polymerizattlon, benzoyl peroxide, tort. -butyl peroxide, tort. -butyl hydroperoxide ABSTRACT: The authors synthesized the cyclic eaters of vinylphosphinio acid (I) and ethylene glycol (U), 1, 2-propylene glycol (E[l), trimothyleno glycol (W), 1, 4-butylene glycol (V) or diethylenq glycol (VI) and determined some of their phy8toochomical'pro- perties (see Table .1 in~ the Enclosure). These esters were then polymerized linearly in the presence of water (3% by welght~ 140C, from i6 hours for III to 83 hours for Card 1/3 ACCESSION NRs AT4033994 - Cyallo "term of vinylphosphinto acid Chemical 11"C110 M IV CHOMCII Col 6ard 3/3 TA13LE 1 '!RD COV H'% p0% B.P., 20 20 Calcu- Cal- Calcu- Calcu- formula 'C/mm nD d4 tated oula- lated lated ted 0016 U CUP fV/4'i 4701 1 1.30i9 U.63 Ms'97 355 5 s 5.8 - 5 3 20 8 * 33 , 355 ' 5j . . 20 6 : , W-M/3 iH ~Q - 1,4M 1,2071 33,59 33,4 4400:7 40,6 62 02 612 204 2D:5 20,9 . - . . - its . 1 0 11 129-130/2 ~c 1.4775 1#2M 33,32 336*4 406 's 40 40-6 6,,4 6 3 8.1 2DA 2009 , i . 2D.4 C' a 001141fa 12DJ3 1.4M 1.3DU 38.10 38.11 440 44:0 44.6 70 7:0 6,9 0 1. Son. DJ12 110 3 .4D,4 40,4 404 s 612 6,2 6.2 17,5 17,4 V 4 - / ENC IMURE: 01 tp 63.' IR 33 47 to L .-XPA,(s).2/EWT(m)/EPP(c)/~WP(J)/!/FTC(m) - IMSSION NRI A?5024495 UR/0191/65/000/010/0001/0003 678.673-4:P8.029.h4 ~q ak AUTHOR: Vinogra4ova, S. V.; Andreyeva, IN. A.t Davydova, V. F.11 kah V. V. TITLE: Study of the feasibility of curing and converting thermosetting ts4aryl... aster to end products SOURCE: Plasticbeskiye massy, no* lo, 1965, 1-3 TOPIC TAGS: polyaryl eater, heat resistant plastic, polyaryl plastic _'q ABSTRACT: A study has.shown that unfilled or quartz-filledlt~roes-linked D-5, Poly I-- s~ ester can be.processed into end products by molAing. D-5 repared from:terephth. (7~ al chlorideo bisphenol A, and l,lil-trimethylblpropane TlM/O,5;m6l&k.r&ti6)j is--p W r-,, cross-linked~(38% insoluble'in chloroform) at-the outdet~ Study of-furtherlbrbhs linking by various,-curing agents-revealed'that mdleic and endic (cis-'3fi'-endomethy-~ lene-1,2,3j6-tetrah kiveithb best .ydrophthalic)ahhydride or tetrabittoxytitanium 4e., -.7r sults., Cross,-linking occuts as follows: L 1868-66 ACCESSION:MR! AP5024495 "T CHA AqIN-COOCK-4-4311O."... R< -4: C4 CW CA -OOC- 0 7.AWCHV R CH~ 16 d-T -'0 Study of D-5 polding shoved the' expOdiehey.of using a croes-linked polymersoftenW at 200-210C and 6a-70% insoluble& Such a polymer is rapidly molded (at llo-16od into solid products. Fig.,l of the-Enclosure shows the thermomechanical properties of D-5 andi for comparison, of D-2 J)olyaryl eater (from terephthalic acid and big- phenol A) As. Pig 1 indicatesi 'Prioss~linking considerably improven heat resistancdv' CarJ 2/h 1868-66_ 1 ACCESSION HH: AP5024h95 Cross-linked D- 5 withstands I temperature cycling from -60 to 250C and exhibits goo& 1 dielectric properties. Orig. art ihad: l'table and 4~'figures. [SM) v ASSOCIATION:z none 8UBMITTED., 00 01- ENCL.$. suB com ur NO REF SOVz 002 . COTIM 000 ATD :tj PRESS. , card 3/4, EWT(m)/ZPF(c)/EWP L 2324-6 Q)/T/ZTa(M) WW/RH ACCESSION NR: AP5022222 UR/0191/(55/ooo/009/0016/0019 678.673 01-536.4503T.311 ATMOR: Vinogradova, S. V.; Kqrshak, V. V.; Fridman, Ye. I.; Andreyeval H. A. Bnraboshkina, h. N.qA I-- 11~ - / P 16 X~7 rITLE, fleat-resistant eleetroinaulating polyaryInte'rInnfif, material SOURM Plasticheskiye massy, no. 9, 1965, A_iq .,,,,ToriC TAGS: plasticizer, heat resistant plastic, heat resistant material, polyaryl I plastic, terephthalic acid, electric insulator, plastic , heat -resistance, polyaryla:tei phenolphtlialein, biaphenol A, laophthalic acid, softening point ABSTRACT: The possibility of preparing heat-resistant plastics suitable for electrib insulators and capable of being compression molded was studied by preparing neat and mixed compositions from phenolphtiialein is;,% ithalate or terephtbalate based polyalyj.L h .,Aes. (i.e. ~ aromatic polyesters) It was also. atte ted to prepare polpae ' :whi MP rs c had to be kept at their melting temperature during compression molding fora minimum, 'time. Thus, powdered poly(phenolphthalein ieophthalate) could be compression molded i at 270-300C into semitransparent light-brown samples of plastic designated as F 1 ~ VJ~ vhile the poly(phenolphthaleia terephthalato), designated as-plastic F-2, crackle__3~~j tord 1/2 L 2~24_66-. ACCESSION MR.- AP5022222 and disintegrated after being taken out of the molds. The addition of plasticizers,: I'Sovoll, [biphenol dichloridel, a polysiloxane and some other palyarylates.based on either-bisphenol. A or phenolphthalein sebacate, made it possible to prepare compres- sion molded.samples from F-2 with softening points from 255 to 340C. The addition of fBovol in varying amounts or the seine polysiloxane to F-1 produced plastics with soft- Aning points between 250 and 285C. Even the sample with 10% Sovol still had a soft-' ~ening point of 230C, which was considered to be sufficiently high, combined with good workability of the material. The introduction of fillers (up to 40%.by weight of the composition) was also studied for the purpose of reducing cracking of the p1h3tic and to save polymer materials, Good results were obtained with quartz flour or tal-:~, cum, whilealuminum oxide or silica gel were ineffective. The filled F-2 polyarylatjo samples were rtsistant to.themal shock; they withstood repeated sharp temperature 'phange from 60 tq 250C, The polyarylate compositions obtained had high dielectric -properties'fn a rather Vide range of temperatures. Orig. art. has: 4 figures and tables.' [BNI t AASOCIATIONt none 6UBMITTEDi 00. ENCL: 00 SUB CODE: (M*r, 66 NO REP SOVI~ 06h OMM 000 ATD PRES~I Card, , 2/2,44 OFENGENDEN. N.Ye.; SVYATSKAYA, Crushing of coal caused by hydraulic mining and conveying. Sbor.- DonUGI no.22s69-90 161. (MIRA 15:6) . (Hydraulic mining) SVTATSKAYAp M. 0.j ANDREYEVAO M. F.; SHALYOINA, V. T. Clarification of alime waters. Sbor. DonUGI no 22t121-128 161* (Coal preparation plants--Equipment and guppli -68) (MIRA l5z6) SOV/1 20- .58-2-14/37 AUTHOR: A3~dre~L~~. G. TITLE: Application of an Electron Multiplier to Increase the Sensitivity of a Mass Spectrometer (Primeneniye elektronnogo umnozhitelya dlya. povysheniya chuvstvitellnc)sti mass- spektrometra) PERIODICAL: Pribory i Tekhnika Eksperimenta, 1958, Nr 2, pp 53-56 (USSR) ABSTRACT: In a nxLriber of studies it is necessary to carry out mass spectrometric analysis with very,small amounts of material so that the usual sensitivity (10-14 - lo-15 anip) is insuffic- ient. Recently, various methods of recording masq spectre- metric ion beams have been devised . using Geiger count'ers, photoelectron multipliers, ionisation chambers, and electron multipliers as DC amplifiers or ion counters. In the present work, in order to increase the sensitivity of the mass spectrometer MS-3, an electron multiplier Was used, particular attention being paid to the method of counting. An eleven stage electron multiplier with beryllium bronze electrodes was used. The multiplier was specially activated and worked with a negative voltage of 4.3-4.5 kv on the first electrode. The ener- of the ions detected by the multiplier was 6.8- 0y Lev, The block diagram of the recording apparatus is shown Card 1Y3