SCIENTIFIC ABSTRACT ANDRIANOV, K.A. - ANDRIANOV, K. A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000101420005-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 20, 2001
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

ANDRIANOV, K.A.
Synthesis and spectra of trimethyla~;~-,.
2,6-disilacyclohexano6. Dokl. AN 11~14~7
4

-L-37o3o-6-s- EPA(s)-2/EWT(m)/EPF(c)/EWP(v)/EPR/EPA(w)-2/EWT(J)/T
PC_14,-/Pab_ 0/Pr-4/Ps_4/Pt_10 WW/RM
ACCESSION HR: AP3009222 S/0020/651161/00110099/01 2
AUTHORt Andrianov, K. A,,_(Academician): Yemel_'yanov, V. N.;
lukhareva,"V-.-A.i- Smirnova, Yu. P.; Zubov, P. I-
TITLE: Synthesis and physical and mechanical properties of films
.from polymers vith regular structure
~SOURCEs AN SSSR. Voklady, v. 1616 no. 1# 196~, 99-102
.TOPIC TAGS3 polymer, regular structure, regular structure polymer,-I.-I
i ~-
epoxy polymer, polyesteroepoxy polymer, silicon containing poly-
esteroarildoepoxy polymer
ABSTRACT: e purpose of the work was to synthesize and study oly-"---'
esteroevo3yrand silicon-containina polZesteroamidoeRox-v Eolymers of
a regular dyclonet ructure, whio could be used for coatin
gs
electric Insulatio or as bindersPfor glass-reinforced plasticsX9
Polyeateroepoxy polymers were oUtained by reacting pent'aer, itol
tatraadipate with glycidol-hydroquinone or wLth glycidol-diphenylol-
propane ("Bisphenol A") (See I below) diethers. Silicon-containing

L P030-65
-ACCESSION NRt AP5009222
p i~polyevteroamidoepoxy polymer* of regular structure were prepared In
two stagest in the first st:age, pentaerythritol tetraadipate was
condensed with bis-(phenylaninomethyl)-tetramethyldisiloxane; in the
second stage, the resulting polymer which contained phenylamino and
carboxyl groups was reacted with a glycidol diether, as In the pre-
paration of to resulting In polymer (11)6 Reactions were carried
out in CH,
0 0 'OH OH 0 0
eirsoi(CH*)&~OCHtH9clt.Oo~OOCH.AHCH~09(clit)46HI
-,CH*OC (Clls)t C - NCII*Sl (CHs)s 081 (Clls)s CHjN -
0 0
off Clio
Oil
0 0
Ca~j 2/4
...... .. . ..

L 37030-65
ACCESSION NRs
AP5009222
films on &.metal surface. Polymer (111) with an irregular structure
vas obtained b7 simultaneous condensation of pentacrythritolI, adipicl
acid and glycidol-Bisphencl A diether. Mechanical and electrical
properties of ;1;.and UT. were studied to determine the effect of the'
structure on these properties. The dependence of inner stresses,
adhesion,and elastic modulus on the thickness of the film was found.'
The above mechanical properties and the tensile strength of 1, n, anA
III and of a commercially used epoxy resin (ED-5) Peured with poly-
ethylenepolyamine, were compared. It wan found hat the tensile
attength of polymers with the regular structure is 20-50% higher
than that of the irregular polymer, but 1.5-2 times lower than that~
J
of the commercially used epoxy resins, However. inner stresses In
the coatings from the new film-forming regular polymers are con-
siderably Vower. The best physical and mechanical properties are
displayed by 11 films, which have the maxitnum curing rate, minimum
innez stresses and a high tensile strength and adhesion. Films from!
polymers with the regular structure are moisturc proof. Thermal
stability f I at 200C to 3
Ak

-L-37030-65-
ACCESSION Nftt APS009222
Test duration, hr 24 100 500 900 1500
weight logo# x 0,76 0,95 3.60 4.20 6.32
Electric properties were d'etermLned for I and for a glase_reinforcedl~_
~.plastlc, in which I was used an a binder* Orige arte hast 4 for-
tiulas, 3 graphat and 2 tables. JBNJ
ASSOCIATION9 Institut elementoorga6icheakikh soyedineniy Aka~emti
asuk OsSlt (Instituto of Orstaftoe,lemental Compounds, Academy of
SUBHITTEDi 29Sep64
-NO REP SOV-t 001
HHCL: 00
-OTHERt 000

L 4q9 ' 11
.j7A5 EVIr 'm)/EPF (c )/EVIP PC-4/Pr-4 RM
ACCESSION NR: AP5006418 S/0062/6S/000/001/0167/OIL69
AUTHOR: Andrianov, K. A.; Sidorov, V. I.; Khananashvili L. M.; Kuznetsova, N.
to
TITLE: Reaction of the addition of nethyldichloro- and dimethyl-chlorosilanes,
vinyl-derivatives of organocyclosiloxanes
SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 1, 1965, 167-169
TOPIC TAGS- silanf, organosilicon compound, methyldichlcrosilane, dimethylchloro-
silane
ABSTRACT: The reactions of the addition of methylchloro- and dimethylchlorosilailes
to vinylheptamethyl- and divinylht-xamethylcyclotetrasiloxanes in the presence of an
H2PtC16 catalyst occur relatively easily and with good yields of the desired prod-
ucts. The Si(CH2)Cl2 and Si(CH3)2Cl groups are joined to the B-carbon atom of the
vinyl group of cyclosiloxane. Five new compounds were synthesized. "The authors
express their deep gratitude to M. G. Z2xtseva for taking the Infrared absorption
spectra," Orig. art. has: I tables, 1 equation.

Card 212

L 40978-6!~ EVIT (m)/[Pr, (c)AP R /E I'M (j Pc-4/Pr-4/`0s-4 RPL
ACCESSION NR: AP50061422 S/0062/65/000/001/0187/0189
Shapatin, A. S.; Ponomarev, V. V.
Formation reactions and properties of aluminum salts of ethoxymethylphos-
and diethylphosphoric acids
so ukcjs~. I -_-A e--s ka- pa ino. 1, 1965$ 187-189-
iTOPIC MS.- alumimim_, a-bamin-u-m --compound.' pbosphonic acid, phosphoric acid, polymer
-:-ABSTRACT-. -A1xmdnum diisopmpoxy(e-thoxymet~ylphosphinate), aluminum isopropoxymbis~
.(ethoxymethylphosphinate), and aluminum tris-(ethoxymethylphosphinate) were synthe-
sized. The interaction of aluminum isopropylatel~iith triethylphosphate was studied
in niolar ratios of 1: 1, 1: 2_._a_n_J71_-3. The reaction of aluminum isopropylate with
ethyl ethers of methylphosphinic and phosphoric acids yields aluminum tris-(ethoxy-
methylphosphinate) and aluminum tris-(diethylphosphate). Aluminum isopropoxy-bis-
(ethoxymethylphosphinate), and aluminum tris-(ethoxymethylphosphinate) have a poly-
meric structure. Orig. art.,has: 1 figure, 4 equations.

L 40978-W
ACCESSION NR: AP5006422
ASSOCIATION: Moskovskiy institut tonkoy khimicheskoy tekhnologii im. M. V.
Lomonosova (Moscow Institute of Fine Chemical Technoloarv)
,SUBMITTED: 03Jun64 ENCL; 00 SUB CODE; GC, OC
REF SOV: 002
OTHER: 000
Card.

L 4157~~ Fc-4/Pr-4. - In '~2
,ACCESSION MR: AP5008641 7
S/0079/65/035/003/0524
AUTHOR: AndriaT!qvj K, Sidor-ov. V. 1. -, Khanan vill M.; Kuznetsova, N. V.-B
TITLEt Cohydrolysis of met-hvl_v~Ln_X-Idichlorosilanelwith various alkylehlorosilanes
SOURCEt Zhurnal. obshchey khimii, v. 3S, no. 3, 1965, 524-527
TOPIC TAGSt. silans, silicon organic compounds, hydrolysis, organic synthesis
ABSTRACT: The cohydrolysis reaction of methylvinyldichlorosilane with different
alkylchlorosilanes was studied according to the following scheme:
C11 + III CIO 11'o
>S
ClItURCH, n
S10
+ 11C1 + polymers
1-mothyl-i-vinyl-3,3,5,5-tetraethyleyclotrililoxane and 1,1-diethyl-3,5-dimethyl-
- 1/2

I - 41575-65,
ACCESSION NR: APS008841
3,5-divinylcyclotrisiloxane were proLced by cohydrolysis of methylvinyldichloro-
I
silane with diethyldichlorosilane. Cohydrolysis of methy1viny1dichlorosilane with
methyldichlor,osilane produced A,3,5,7-tetrameth-il-~l-vi-.iylcyclatettwiloxane and
1.31517-tetramethyl-1,5-divinylcyclotet:rasiloxane. I-Methyl-l-vinyl-3.5.7-tri-
ethylcyclotetrasiloxane, 1. 5-d imethyl- 1, 5-diviny l- 2, ' - u.Le tiiy.L cy c.Lu tetras i loxane
and 1-ethyl-3,5,7-trimethyl-3,5,7-trivinylsiloxane were produccd by cohydrolysis of
methylvinyldichlor,osilane with ethyldichlorosilane. Orig. art. has: 1 table.
ASSOC IOP: H6s,k6viki~-li~atitut--tonko~~-khimicheakoy tekhno1og1L-im*--M*
Lommosova (Moscow Instititte of rine Chemical Technology)
SUBMITMDi 02Jan64
ENCL: 00 SUB CODE: 0C
NO REr sov: ou OTHERt 000

L 54445-65 EWr(m)/EPF(c)/EPR/EWP(.j)/T Pr,-4/Pr-4/Ps-4 MVIRY.
ACCESSION NRi AP5012450 UR/0062/65/OGO/004/0660/066
546.287
AT)THORSt Fromborg, M. B.; PetraBhko., Yu. K.; Vozhova, V. D.j Andrianov, Ks A.
TITLE: Double decomp ion'lof al~x anes ~nd mothylphenyl
dichlorosilane ?sit (aal)trisodium oxysil
SOURGE: AN SSSR. Izvostiya. Seriya khimichaskaya, no. 4, 1965p 660-665
TOPIC TAGSt silane, IR absorption spectrum, P.012erizationy polycondensation,
oodiun compound
ABSTRACT: The double decomposition of trisodium salts of allgl(aryl) silantriols
and methylphanyl, dichlorosilane was studied. In order to use the roaction for
obtaining trifunctional splitting of oligomers vitli functi,)nal groups at the ends
of the branches, the synthesis was carried out With 1 mole of alkyl(aryl) tri-
sodium oVailano for 3 lwles of raothylphenyl dichlorooilane. Sodium salts (ob-
tained by treating alkyl(aryl)polys-iloxanos with an alcohol solution of caustic
Goda) were used. The double decomposition reaction was carried out below 40C
with gradual introduction Into a volution of mothylphenyl dichlorosilane of a
suspension of the trisodium salt in toluene. Analysis of the reau.1ting products

L 54445-65
ACCESSION KR: AP5012450
shows them to contain but an insignificant amount of functional groups. The
chlorine content was but 0,1% as against an expected 17.17%, on the assumption
of the course the reaction would follow. Only traces of the hydroxyl group were
detected after treatment with water. These data indicate that the double de-
composition does not follow the expected pattern, but that it is apparently accom-
panied by hydrolytic processes that lead to the formation of cyclic compounds of
complex structure. This view is supported by the presence of crystallization
water in allVl(aryl) silantriols. For the double decomposition reactions, sodium
snlts of methyl, ethyl, and phonyl silantriola were used. These yielded 1,7-
dimethyl-3,5,9,11,14,1.6-hoxnmothylhoxipherWI bicyclo (5 5 5) octasiloxano; 1,7-
diethyl '5, octasiloxane; and
-3,5,9,11,14,16-he3cnmetli.vlhoxaplionyl b1cycla (5,5' ~
1,7-diption.,,rl-3,5,9,11,16-boxarnothylhoxali)iGnyl bicyclo octasil,)XnTle.
These compounds aro lcw-viscosity liquids, soluble in benzone, toluene, and car-
bon tetrachloride) and insoluble in-ethyl and mathyl alcohols. M~ compoaltionj 1
structure, and properties or the compounds are tabulated. Infrared apectra of
all compounds exhibit an absorption band In the 1080-10"?o CM-1 regionp corre-
aponding to vibration of the Si-O bond in-oight-member rings. No characteristic
bond for Si--OH was detected. Supplementary experiments on catalytic polymoriza-
tion and thermal polycondeneation demonstrated that the compounds are polymerized
by means of 1% NaOli at 800 and that thermal polycondeneation, which was
Card 2/3-

ANDRIANOV, K.A.; LAVYGIII, I.A.; Yu.A.
Synthesis and properties of branched 9-hydroxy quinollne titanium
dimethylsiloxane oligomers. Vhur. ob. khim. 35 no.4:689-693 Ap 165.
(Ml I'l 18 - 5)

1,M)RIANOVO K.A,,; ;
------
the cohydrolysis of methylallyldichlorosilane with
ethy1dichlorosilanes. Zhur. ob, khim. 35 no.4:698-700
(IMIRA 18: 5)

ZHINKIN., D.Ya.; MALINOVA, G.N.; POLONSKAYA, A.P.; A-?,MRIANOV, K.A.
Simultaneous bydrolytic condensation of trimetbyl-,
tr4ethylehlorosilanes, and phenvltrichlorusliane. Zhur. ob.
khim. 35 no.5009-911 My 165. (MIRA 18W

tNTRIANOV,, K.k.,- ZPDANOV, A.A.- YJTHC.F-'-NAj E.A.
Synthas�s and study cf the properties of polydimethylsi2oxanes
contp~ining carboxyl groups An organ-54c end radicals. MI-r. ob.
khir- 35 no.621037-1040 Je '65. (MIRA 18:6)

ANDRIANOV, K.A., TZIMAYLOV, B.A.-
Reaotion of higher alkylahlarosilanes with ethyl alcohol. Zhur.
ob. khlm. 35 no.6xlO4l-lO44 Je 165. (MIRA IM)

IL 42147-65 EPF(c)/EWP(j),/EWT(m)/7 Pc-~/Pr-4 RM
ACCESSION NR: APW659 B/0020/651160/000300510:
AUTHORS: Andrianovi K* A"(AORAWACianji Delazarl N. V.1 Volkovap
Tlfiji.- Syn esie spectra of trimethylalkll-(phenyl, chlor)-i-oxa-2t6-
'disilacyclobexanes
SOURCEs AF SSSR. Dokladyy V. 16o, no. 6, 1965, 1307-1310
TOPIC TAGS% oyclohexamet IR absorption spectrum, speatrophotometer/ VIKS M
apectrophotometer, IKS 14 opeotrophotometer
1ABSTRACTt The authors have produced new trivetby1a1Ry'1-(phenyl0 chlor)-l-oxa-.2,6
'disilacyolohexanes, with a yield of 60-00~, during hy4rolysis of bis(alkylohlorsilA
propanes by an oLqueoua solution of caustic potash. On heating an ether molution of
1-dimethylahlorailyl-3-mothyldichlorsilyI propane with bicarbonate of soda, a
bicyclic compound was obtained according to
CHI CHI
Ct(&\CHs cl~& \Clio
(CH43 11 A -~-o J1 A (CHI),.
PHI... CHI
.~Card

42147-65-,
L
tAccEssioN at'-Ar5w7659
ISi3-(alkylohlorsilyl) propanes were obtained according to reacti*r*ms (a)p (b), and
I(o
. . * .CHISICIA +- RAgBr --' CH~R)SICIS'
CHIRSICIs + CH% - CHCR%MgDr - CIIj(R"SiCH4H = CHII~ b~
CH#(R)CISICH*CH = CHS + HSt(CH&)jCIH
C&H.#,. C;118, C1.
iThe properties of the newly synthesized substancPs are given in a tabl-e. The IR
spectra were obtained and compared with other compounds. These spectra were studied
on two spectrophotometere: a VIKS M-3 with an NaCI prism (700-1500 am-1) and an
ILS-14 with a KBr pricm (400-700 cm-1). The spectra are illustrated in Fig. 1 on
the 'Enclosure. Orig. art. hast 1 table and 1 figure.
ASSOCIATIONs Institut elementoorganicheakikh soyedinenV, Akademii nauk SSSR
(Institute of Retero-Orgmio Compounds, Academy of Sciences SSSR)
dpl,'
ISMDUTTEDt ~-2600%4- EXCL t 01
NO RV SM 001 W7

_L 49286-65 Pc-4/Pr-4 IJP(c) JD/R11
ACCESSION KR: AP013754- UR/.0020/65/162/002/0335/0338
AUTHOIR: Zhd_ ov. A. A.; Andrianov, K. A. (Academician); Odinets, V. A., lc!~~Va
i
ill. V.
TITLE: Synthesis and,291~Merizatiolf cyclotetr siloxanes~hich contain hetero-
cyclic radicals with a silicon atom
SOURCE: AN SSSR. Doklady, v. 162, -no. 2, 1965, 335-338
TOPIC TAGS: organosilicon compound, cyclosiloxane, silahexyl substituted cyclotetra-
--Isiloxane, organosilicon compound polymerization
ABSTRACT: -An attempt was m%de:to,.synthes-izel.an.d.-,polynierize.cyclosiloxane's fringed
with heterocyclic groups in which silicon atoms belonged simultaneously to the hetei-
__~ocyclic groups and to sJ.loxane closed chains. No literature data were available on
!tbe couipbunds in question. To.synthesize silacyclohexyl derivativcs of cyclosilo-
;xanes, 1,1-dichloro-3,b-benzo-l-silacyclohexane was hydrolyzed either alone or with
IditieLhyldichloronilane in from '3:1 to -1:,3. - Mono-, di-, tri-,
and tetra-(3,11-benzo-I.-ailahexyl)-cyclotetrasiloxanes were obtained. The properties
of these compounds are tabulhted in the original. The compounds obtained were
polymerized in the presence of an al1taline catalyst, either 0.3% KOH or 0.3% tetra-

r 49286-65
ACCtSSION HR: AP5013754
Imethylarmonium hydroxide, at various temperatures. Concentrated H2804 waa ineffec-~
!tive as a catalyst. Formation of an insoluble product was observed in all cases of
ipolYmerization and was ascribed to the cross-linking effect of the alkaline agent,
.which either splits off organic radicals or opens the silahexyl rings. it was found
':that tetramethylammonixua hydroxide is more effective as a polymerization catalyst
,than KOHi the reactivity of the cyclosiloxanes studied decreases with an increase
I!in the number of heterocyclic radicals in the molecule. Orig. art. has: 2 formulas,
11 table and 3 graphs. LBN]
ASSOCIATION,, InStitut elementoorgazivbeskikh soyedineniy Akademii nauk SBSR
(Institute of Heteroorganic Compounds~ Academy of Sciences,SSSR)
lsmiTTED: njan65 ENCL: 00 SUB CODE: OCIG'C'
No RFX SOV 1 004 OTHPR 1 003 ATD PRESS h004
~qrd 2/2-:

L 51,9R7-65 Evrr (m)/EPF (c )/EPft/ffvjP (j )/T/L;TC (1~) Pc-h/Pr-h/Ps-4 VAI/Am
ACCESSION NR! APS011919 UR/0363/65/001/003/0294/03N
541.6.542. ~i 9
3.11
Kurasheva, N. A.% Manuch rova, 1. F.- Berlin-r Ye. M
AUTHOR: Andrianov, K. A., a
TITLE: Polymers with inorganic molecule chains, po titanodimethylsiloxanes
iSOURCE: AN SSSR. Izvestiya. Neorganicheskiye materialy, v. 1, no. 3, 1965, 2Z-300,
TOPIC TAGS: polymer, inorganic polymer, titanium organic cwpound, dimethylsiloxane
,rubber, polymethylsiloxane
,ABSTRACT: Kinetics of cross-linking of polytitanodimethylsiloxanes, (product hav-
ing a reticular structure), was studied using oligomers of general formula
CHI'
;as a model compound (where ?I is 2, 3, 23, 34, 52. and 128). The oligomer condensa-,
reactions and cross-linking process took place simultaneously. The yield of
the reticular product (gel) is directly proportional to the reaction duration. The
lCard 1/2

_L 54987-65.-
ACCESSION NR: APS011919
crate of the cross-linking reaction is inversely proportional to the magnitude of n.j.
:In general, the polytitanodimethylsiloxanes are slightly more thermally stable than!'
the corresponding polymethylsiloxanes. Orig. art. has: 3 tables and 8 fiFr-es.
!ASSOCIATION: Institut elementoorganicheskikh soyedineniy Akademii nauk SSSR
(institute of Or~anoelemental Compounds. Academy of Sciences.SSSR); Institut ob-
shchey i n organicheskoy khimil Akademii nauk SSSR (Institute of General and In-
SS R)
-organic Chemistry, Academy of Sciences,
FSUBMITTED- 04Dec64 ENCL: 00 SUB CODE Ge
NO REF SOV: 005 OTHER- 000,
-7 -7~

tetramonotima t 1
tiutoxidc-liads to' a L
titanium --~tri`-Mbn
methYlphqsp*hate- reacts -ikith -,tiAothylbut(
-and- di-.triethyloi-loxy--ester---otim,at4hylvh
ph
an, th
lUblCwMM(;t_of.. -formilu" -
groups split- off, readily
pou S'--&wL
tvo psp IL
.0003
as. 1 f
SSR)
teW
;7; 71,
WC
T T.
I'A

Out -.8 v
.g
1965
i~-- Obabohi no
Zhit
100
t
09 !,11.40ON
An .0-0 M-2 01-
liqxd ar
ang.- 6
.nithyiiiiloUn*L --are yn 48 a--
Ah6
66~W ldbindeU
VC16. IDMCi
y ro)W---'--
M-_ -omegt4rimstby -w imetb7likiloxahoo Thin yieldal ioligomera in-
-po 46~ti~~ W-f --th,-
gree--.-O:t _0 -0
30,' 98# _ors,is-in,ths-~utorval_ -0
t 'iM-' 'I A
~Ilhriefrio , ~-. ibbrOS6~-Iil. egree,
,n
lygori ---Th 34 1 t t difId IR 6*0
tr VaSTA u '~Oowo.
'NO-

lin-Ah"veiiiigateaA t i ratbr
20-1300-rangoa-Trom-4059 kcal/bo e
rapidly at first, then levels ofT7
j
n1ug that the 84ydroquinblihe t1tabium oxane group
at higher values of ni. mea,
great meas ion.~ The rolation,ot4etiva-i-
determines in ure AI)6'btarmolecular react
tion energy, to 'degree-, of bi4no~-.u_ normal -for linear polydimethylailoxaneV,
containing polar group# at tU ends, of the chains. A tabWAtion is- given for tbe
compositions and properties of the synthesized polymers. Orig. art. hass -5
f igures and 3 tables.
ASSOCIATIONs none
SIUBMTTED i 05Fob64 ENCL: 00 SUB CODE: GC, OC
NO REF SOV% 009 OTHER: 006
4

7;
52~66-65 EPF -e
LIR/0020/65/161/004/06SUM,5
7ACCESSION HR; AP5010831
AUMOR: Andrianov
A (Academician); Makarova, L.
TITLXt Synthesillof
S 0
SOURCE: AN SSSR. Doklady-,-v. 161, no. 4, 1965, 833-835
TOPIC TAGS: organosilicon, alcohol, polyhydric alcohol, eth6r alcobol
A~,1~7FACTA: T-i- and tetranydric ether alcohols containing B-oxyethoxymethyl groups
t
~-~iZed with yields of 94 to 99~ of thear~_ticjj. Synthetic procedur-es and
ir~- given in det~)i!. Synthesized were-:
-'(7H 2 (H 2 ()H j
Dy"
I'-Ie t t xv
V" -
xynielhylci~w (tit; lsi,' x,~,
was don- t)y
'i(-xy(.v lohexane wish mthyll-, r; pt I --;s ii r-3 e t n
F tI~ the general schem:
Rsi I Osi (C)IS).1 C litOCHICH 10 If is + ac, If 60 H.
Co,d I

,L 52266-65
ACCESSION NR: AT5010831
:n the case of t(~traethoxysilane a corresponding tetrahydric ether alcohol,
S'10Si(CH3)2CH2C)0H7CH20H14, was obtained. It i~, ;n the ini-i-modiate
:~t,ige of hydrolysis of rrespond:-,
'-:w formr-d wh,*~h, ir, lijrn, enters into .-3 c ond:, n ~a t i ot t,,- --)n with lioxv-
f rrtltif~n of vl:ly
cb xa: I eis Qxcluulad SIDQe I.,
~~qE~,CIATION: none
ENCL: 00 S!T' ~'ODE: OC,
NO REF SOV: 002 OTHER: 005
Cord 2/2

L 56662-6.5 EviT(m)/h?F(c)/EP4/a1F(J)/T Pc-4/Fr-4/Ps-4 '4001
ArrrssjoN NP- AP5017840 LIR/0286/65/000011/0078/0078
676.84
AUTHOR: Andrianov, K. A.; Pakhomov, V. I.; Lapteva, N. Ye. IG-
TITLE: A method for producing oi:ganosiliLo~_re2,ins. Class 39, No. 171565
SOURCE: Byulleten' izobreteniy i tovarnykh znakov, no. 11, 1965, 78
TOPIC TAGS: organosillcon resia, hydrolysir,, catalysis
ABSTRACT: This Author's Certificate introduces a imthod for producing organosilicon
resins by cohydrolysis of methyltrimetboxysilane and phenyltrimethoxysilane and then
hardening them in the presence of a hardening catalyst. Pesins with high thermal
stability4nd improved mechanical characteristics a'rk- produced by car-r-YTn-9 out the
with,o_qphenylpropylsilane and using aidehydes or aldehyde deri-
vat I, ~ a's n
ASSOCI TION: ar-.hno-issledovatePskly institut plastichos-kikh M-assj8a
Research In tute of Plastic)
[card 1/2

L FC!-4/Fr-4
UR/0206/65/000/011/0080/0080-
678.84+678.643
AUTHOR: Prutkov,, L. M.; Andrian' -K A '-polikanini N. A#; Asi2ovich,
0v, 4
TITLE: A method for producing molding compounds. Class 39, No. 171577
SOURCE: Byulleten' izobreteniy i tovarnykh znakov, no. 11, 1965, 80
!TOPIC TAGS: molding material, plastic, graft copolymer
ABSTRAC
'TV/This Author's Certificate introduces a method for producing molding
cowoundg based on a filler and binders --synthetic resi-ir. The useful 'properties
of the molding compounds are improved by using binders consisting of graft copoly-
mers of apoxy resin/and a polyorganosiloxane ich contains a secondary amino groupi
in the siae- chain.1b
ASSOCIATION: none
SUBMITTED: 24Mar62
NO REF SOV: 000
Card
ENCLi 00
OTHER: 000
SUB CODE: MT-pW

ANDRIANOV, K.A.; XHANANASHVILI, L.M.; TE~MtVA, N.A.; TIKHOIJOV, V.S.
Reactions of dimthyloyclosilazanes ith -butyl alcohol and
n-butyl borate. In. AN SSSR. Ser. A s \no'~446-449 165.
(FJRA 18: 5)
1. Institut tonkoy khimiohpskoy tekbnofogii im'.'M.V.Lomonosova.

ANDRIANOV) K.A.; TSOMkYA, N.I.; KHAnANASHVILI, L.M.
Synth6sis of glycerol derivatives of oligomers with functional
groups at the ends of molecules. Izv. AN SSSR. Ser. khim. no.6:
1022-1025 165. (MIRA 18:6)
1. Moskovskiy institut tonkoy khimicheskoy tekhnologii imeni
Lomonosova.

L 0852-65 EPA(s)-2/EWT(m)/EPP(c)/EWP(J)/T WW/DJ/RH
ACMSI03 M AP5019675 UR/0064/65/C)OO/008/0570/0572
662-967-91547.1#128
:AUTHORSt Andrianov, K. A.; Ovchirmikov, V. A. 1 Khananashvi I i, L. M.61-1-~4
ITITLEt orgnosilicon coolants
iSOURC-Es Khimicheakaya pronVehlennost', no. 8, 1965, 570-572
TOPIC TAGS: organosilioon compound, coolant, silane, siloxane/AMT 300 oil,
Ithobiltern 6oo
ABSTRAM T~p purpose of the inveatigatjort was the synthesis oAiquid grganosili-
oon ooolants\NoS,~ I stability.0 The following compoundejere synthesized:
Lrnylphenoyydiphenoxys i lane II),
phenoVdiphenoxysi lane (III), and dj-(pheny1pbenoxYdipbenoYY) disiloxme (IV). The
synthesis of I,'II, md*Ill was -carried out at 220-240C aooording-to
~4H4!kl' + nCoHlOll + (3 - a) CHCoH,OH
C'%V(0C6Hj)x(0CACH&4 + SHCJ
where -49;1
Card l/

L 60852-65
ACUSSION NRs AP5019675
+
+ 3HC1
where
+ (4 - n) CHCVfD
Sj(OCgH6)R(OCOH&CgHj)&_,j+ MCI
where
respectively. Comppl~d JV i;as obta'ined by, treatment of phenyl tri chlorosi lane with a
mixture of phenol, o-hyft.-,~,tdplfenyl, and water in the ratio of 1 : 1.65 1 0.45 t 0.5-
The formula of the product obtained was
where
!The yields of 1, 11, 111, and'IV,were 96-5t 94-5, 85, and 81%, respectively. The
,refractive index, density, heat capac~:Lty, and viscosity of the synthesized compounds
vere determined and are presented in tabular - form. The temperature dependence
of viscosity and vapor pressure of-the aryloxysilanes synthesized are shown
graphically (see Figs. I and 2 of the Enclosure). It is concluded that the
aryloxysilanes synthesized have a greater thermal stability than either of the
Andustrial coolants, the aromatized oil AMT-300 or mobiltern-600. Orig. art. hast
13 tables and 2 fl-gur--s. (o4l
-2
_J

L 6085a-65
iACCMION Ms AP5019675
ASSOCIATIONt none
sumavmt Oo
;NO REP SM 000
ENCLt 02 SUB CODEi OC
063
OTM 035 ATD PRESS:4

L 6085-2-65
ACCESSION NRi AP5019675
EVLOSURE: 01
Tempers6twe C
Temp#Attiie*de~6e-.euoe %V*e--vieciosity of
3 - phoyip,fienoi-y
--disiloxane.
4 -di(phenylphenoxy-di--p--h--e-no-x-y-
Jl-

L 60352-75"'
ACCESSIOW N16 AP5019675
Temperature, 0C
Fig. 2. Saturation vapor pr6sBure of aryloxysilanes as a
function of temperatwe
I - Pbenoxydiphenoxysilane; 2 - phenylphenoxy-m-cresoxy-
silane; 3 - phenylphenoxydiphenoxy silane; 4 di(phenyl-
Card phenox.-diphenoxy)-disiloxane.

FROMRGP M.B.; FEMASHKO, Yu.K.; VOZHOVA, V.D.; ANI)RIANOV, K.A.
~-- - -
yl.) tri*"-" iu'm-
Exchange decomposition ~ reaction betwoein alkyl (ar sod ~ '
hydroxysilanes and methylphenyldichlorosilane. Izv. AN SSSR. Ser.
khim. no.4:660-665 165. (MIRA 180)
1. Blektrotekhnicheskiy Institut im. V.I.Lenina.

NO;j m5 c)MWP(j) ~4/1`r--4
(7 N M Aj
A 0 UR/007 J901035 A) 0 6/1037 /1040
P 1j
546.287: 547.463
AUTHOIR: Andrianov, K.A.; Zhdanov, A.A.; Kashutina, E.A.
TITLE: Synthesis and stud'~y'4 of the properties of p2jydimeth a oxanealcontainkig
carboxyl groups i n the terminal 21ganic rai#cals
SOURCE.- Zhurnalobahcheykbimfiv. 35, no. 6, 1965, 1037-1040
TOPIC TAGS: organoBibcon compound, hateroorganic polymer, polysiloxane synthesis,
terminal carboxyl group, therniornechanical property, glass temparature
ABSTRJkCT: In the catalytic polymerization of oc tam ethyleyclotetras floxane in the
presence of bis (2-carboxyethyl)tetramethyldisiloxane, linear polydimethylailoxanes with
carbolq,l groups in the tarminal organic radicals are formed:
f:113
si-o-si C113
C + M ' 4 1
0
C ')210
C11 C1i"-Si-0-~ij-Cjj3
Card ---------- ~. - (~ t

L 63J486-65 rll
-ACCI-M'WNNIk A115C16407 osf-cli'C11,C0011
C113,
The average length of the oligomer formed is determined by the molar ratio of the
reacting components. The physicochemical charactoristics (including viscosity and acti-
vi~tion energy of ViSCOAS flOAV) Of the S~Intl`IVSi70(1 011KI.A1101-9 are uibulated. As the chain
len~-Ifi increases, tile InOlVcUlar intei-action do(Ilnos lwraiiso ()f a h-(-ronse in the (-()n-
(-!ntratiwi of the car'"boxyl k-r0Uj3S per L1111t ~ ~IIWTW 'in I 0it, ur-,)pertiot~ cyf* the oligorrwrs
m~~rt~asin~;lv reqenihl(- Lhose of polydini o(hvls i 1,)\,i nos A i[1, toi-viinnl tTiniethvlqI!oX\'
gCoups, Since the influence of the tormiiL-il t.:arboxv! grl~q-~4 r-ogularlY falls off. A studv
I of the thermomechanical properties of the oligomers showed that they a] I have a glass-
trangition temperature hotweon -80 and -110C under a 30 g load. III spectra of all the
oligonners were identical in character. The operimnntal proemure employed In syntbes-
y)polvdfmvthylqiIoxLne (n = 10) is described.
izingj. Li, -bis 12-cai-b6xy(.~thyldin-tethvlsilox-
ha.
Similar compounds with n ~ 21, 28, 59, 73, and 106 were obtained. Orig. art. s:
4 figures, 2 tables and 1 formula.
ASSOCIA 770N. none
SUBMITTED: 05Feb64 ENCL- 00 SUB CODE: OC
NO REF SOV: 000 OTHER: 006
Pard '_ 0_

.L 65216-65 E-dT(m)/EPF(c)/EWP(J)/T RM
I
ACCESSION HR: APS011918 UR/0363/65/001/003/029910293
10 546.821:541.61 LA
AUTHOR,-, Andrianov, K. A Kuznetsova, I. K. Smirnov, Yu. N.
= ,,
TITLE: Reaction of tetrabutyl titanate~~ith
1:~1-2h2Mhoq~iS acid esters,
SOURCE: AN SSSR. Izvestiya. Neorganichesk-4ye materialy, v. 1, no. 3, 1965, 289-
293
TOPIC TAGS: titanate, organotitanium compound, oligomer, polycondensation
ABSTRACT: Oligomers are prepared with chains made up of alternating atoms of ti-
taniula, oxygen and phosphorus by polycondensaltio~7of n-tetrabutyl titaitate w1th
iialkyl esters of methyl-phosphonic ~Cld. the-reaction was carried out at 170-
-001C without catal,
ysts at initial component ratios of 1:1, 1:2 and 2:1. Poly-
',ondensation of n-butyl t1tanate with dibuty! ester of methyl-phosphonic acid in a
1:1 i-atio takes place with isolation of the dibutyl ester and fomation of oligo-
iners:
,C-ard-.1/4.

L 65216-65
ACMSION NRj AP5011918
n(n- (:4H#O)j Ti + n (C4H9O)2-P-CH, (2n - 1) C,H,OC,,H,
OG4H, Cli
+ CJH$- -.~O--:-Ti-O-P Oc 11
(A)
Oc4ff, C
The authors studied the effect of temperature on the rate of polycondensation.
The rate of the reaction was monicored by checkin.~4 the amount of isolated dibutyl
ester. it was found that an increase in temperature increases the completeness and
speed of the reaction as well as the oligomer yield. An increase in the duration
of isothermal holding at 2001C during the reaction increases the completeness of
the reaction and the titanium content In the reaction mixture . However, the rela-
tive viscosity of the oligomer solution during polycondensation increases very
!it-:le (from 1.11 to 1.56). The oligomer prepared by condensation at 2001C for 50
hours with subsequent removal of volatile products at 2001C and 1-0.1 :mm fig is a
resinous dark yellow substance with a molecular weight of 4000 which !;: quite solu-
Card

L 652V)--)5
ACCESSION NR: AP5011918
ble in alcohols, arontatic hydrocarbons and petroleum ether. The oligomer is
easily hydrolyzed with the isolation of butyl alcohol and the formation of an in-
-Q],3blt, pm)duct. ThLs poly-mer is deformned at 3000C, but does not flow even at
I-0 ~_, " - .~,)ridensalion of r.-tetrabutyl titanate with (11butyl e9ter of inethyl-phos-
phonic a(_id iii a 1:2 ratio takes place with the fermation of a monomer product:
C11, oc'[~f' C11,
0 k,H, 0
1i o,?;ever,.reaction of these same initial components in '2tl ratio takes place ac-
roduct and the excess (I
ccrding to scheme (A) with the formation of a P e,
iaol) Pi-tetrabutyl titanate is retuimed from the reaction. Ultimate analysis and
ey,amination of the properties of -chis polymer product indicate that it is close in
-ructure to the proluct formed from an initial component ratio of 1:1. The ex-
work Is JescribF-d in detail. Orig. ar* ha5: 4 fiRum~s, 2for-m-ulas,
2 tables.
'Ca!-d 3/4

L 65216-65
ACCESSION M AP501.1918
AGSOCIATION: Institut elementoorganicheskikh sovedineniv Akademll nauk SSSR
(Institute of Hatero-organic Cootmounds, Academy of Sciences SSSR),
S-TMITTED: 2OOct64 ENCL: 00 SUP CODE: GC, OC
NO REr SOV: 001 OTHER: 000
~4 ",
Cord 4/4

L 62696-65 WT(m)/EF11(C)/EWP(J)/T RM
ACCESSION M'., AP5014073 UR!0363/65/001/004/0460/0463
541.6:543.422.4
AUMOR: Andrianov. K. A.; Gashnikova 'o's~r " 4, Sir
I N. P.; Kuznet-sova,-I. K.
TITIE: Polymers with inorganic molecular chains. Infrared spectra of poly-
r)hosphonyltitanoxanes
SOURCE: AN SSSR. Izvj.,tiya. Neorganicheskiye materialy, v. 1, no. 4, 1965,
460-463
TOPIC TAGS: infrared spectrum, titanium containingip2inmer/ inorganic polymer,
titanium compaund, phosphorus ccxapound
ABSTRACT: Infrared absorption spectra of polydiphosphonyltitanoxanes of various
degrees of polymerization were studied. Polymers having the general formula
0- -P
-0- -0C4110
~-P(CH2)j
Card 1/3

L 62696-65
ACCE11108 NR: AP1014011
were prepared by condeftsation of dimethylphosphinic acid with n-tetrabutyl
titanate, followed by hydrolysis. A similarity in the spectra of the polymers
wa
s established in regard to the positions and number of bands in the region of
stretching and bending vibrations of the 012 and C'13 groups and stretching
vibrations of the P--O and P-0 groups, and also in the 400100 cm- region, in
which for all polymers only two bands, 760 and 453-500 cm were observed (i
n
contrast to bisdimethylphosphonyldibutoxytitanium, which in this region has three
bands: 760 cm-1, 618-620 cm-1, and 450-500 cm-1). The similarity in the spectra
indicates a similarity in the molecular chains forming the polymers. A lowering
of the stretching vibration frequency of P=O was observed in the spectra of big-
dimethylphosphonyldibutoxytitanium and polybisdimethylphosphonyltitan.),xanes; it
is attributed to the intramolecular interaction of P=O with the tttan,.um, atom,
as follows:

L 62696-65
ACCESSION NR: AP5014073
Orig. art. has: 2 figures, 2 formulas and 1 table.
ASSOCIATION: Institut elementoorganIcheskikh soyedinenly Akalemii nauk SISR
Institute of Organometallic Compounds, Academy of Sciences SSSR) Li,,
StMMITTED.- 22Dec64 ENCL! 00 SUB CODE, 0-PjOC
NO RU SOVt 003 OTRER: 013
A
,Card 3/3

.'N'*,RI;'40V, K~2,,5 YEWL'YANM, V-N.
: . -
Three dimensional polyconden3ation. Plast. massy no.2s22-26 165.
(MIRA 18s7)

ANDRLILNOV., K.A.; KUZNETSOVA,, I.K.
..
Reactions of formation of dimethylphosphonyltitanoxane oligomers.
Izv. AN SSSR. Ser. khim. no*6:945-949 165.
(MIRA 18:6)
lo Institut alementoorganichookikh soyedineniy AN SSSR#

-4 1'~,T -,I
JA J/;I!-~
ACCESSION MR: AP501SO36 TTR/019 !6~/O()0/007 /0023/0026
678,84
AUTHOR! Andrianov., K. A., Yemel'yanov, V, N.; Ravgorodakiy, 1. M.
-7 11-.~ev-dimp,ieional condentintion of sflicnn-co,~talnln~ dismines\With
tetras' ufkeL LQ~"11 gv~e_r. aci_dfi
SOURCE: Plasticheskiye tm say, no. 7. 1965, 23-26
TOPTC TAGS: organostlicon compound, eater acid, condensation reaction, poly-
amide, dismine
ABSTRACT: The article presents the results of a study of three-dimensional con.
densetion of tetrafanctional eater acids with organocilicon diaminee. The re-
cl 1. Ci L
--tr -AMP AIWWW~~
T
LT
Q__ b0c(CHOAM _AV
oisl
al, C11,
W10C(CH&C-NCH~S10)._~CH,N
C(CH&CO"
_~4

"L, 60045-65
SSION NR: AP5018036 V;
CCE
A
ho synthesis of such silicon..containing polyester amidas having a apaciew lattice"
structure was studied by condensing pentaerythritol tetrasebacate, pentaerythri-
tol tetraadipate, and pentalerythrito! tetra-succinate trith blis(phenylaminomethyl) I
tetramethyldisiloxane and bis(plienylaminomettiyl)ticxadecametliyloctasiloxane. It
was found that the rate of polycondensation of the tetramethyldisilaxane with
the tetrafunctional ester acids up to the gel point of the polymers and also
after the start of galling decreases with increasing distance between the car-
boxyl groups of the tetrafunctional ester acids. Condensation of adipic acid
with bis(phonylaminouethyl)t(,,tramethyldit;iloxane produced linear polyamides. The
reaction, carried out at 160C, is not accompanied by degradation of the rompo-
nents. ne new compoundso\, Uj-bis (ch lorome thy I)hexadecametby loc tas i loxane and
k, Lirbis(phenylaminomethyl)hexadecatmthyloctasiloxane were synthesized. Con-
densation of the latter compound with tetrafunctional ester acids at 160C occurs
in a heterogeneous medium and yields inhomogeneous products forming fibers. Orig. I
art. has: It. figures, 3 formulas and 1 table.
ASSOCIATC1014: None
SUBMITTFt- 00
ENCL: 00 SUB CODF- DC
t'
ift.
NO REF SOV, 004 OTHER- 002
Card 2/2
A

ANDRIANOV, ~.A.; YEMELIYANOV, V.N.
Three-dimensional condensation of silicon-containing alcohols
with tetrafUnctionalacid eaterv. Vysokom. soed. 7 no.3017-
522 Mr 165- (MIRA 18:7)
1. Institut alementoorganicheakikh soyedinenly AN SSSR.

ANDRIANOV, K.A.; GOIJJBKOV, G.Ye.; YELINEK, V.I.; KURASHEVA, N.A.;
' -,--,--MANUCHAROVA, I.F.; LITVINOVA, L.F.; ARTEMlYFV, D.K.
Synthesis and properties of polytitanodimethylailoxanes.
Vysokom. soed. 7 no.4-680-687 Ap 165.
X-ray diffrantion study of Dolytitanodimethylsiloxanes. Ibid.:
688-695 (RIRA 18-o)
1. Institut elementoorganicheskikh soyedineniy AN SSBR, Inatitut
obshchey i neorganicheskoy khimii Imeni KurnFikova i Vqesnyuznyy
elektrotekhnicheskiy institut imeni Lenina.

- -- --------
L 62479-65 WTW/&"F(c)/WP(J)/T RM
C F f) NN' R A r 10 r) 4 7 7 114 7 7
4
A U THCF Andriannv F A Vurakov, F V 11v k
V. A. ,A v
TITLF- Polymerization tf cyclic phenylsilsesquioxaneal
SOURCE- Vysokomolokulyarnyye soyedineniya, v. 7, no. 8,~1965. 147"
TOPIC TAGS: organosilicon polymer, silicone. phenvlsilsesquioxane
ABSTRAM High-molecular-weight, benzene-soluble polymers having a
Rlasq transition temperature of above 300C have been prepared f rom
%_ - it is noted
lithe cyclic pbenylallsesquioxisine ocLarua i ' "b""!IL
fthet previdus attemptt-,at polymerizing the octamer were unsucceqsfuls~
:The polymerization was carried out in two steps: first, in a high-
!boiling solvent (preferably. dimethylformamidp) in the presence of
pn alkali to complete dissolution of the starting material, and then
Wj~hout solvent at 250-270C. S M
ASSOCIATIONi none
Card

... ACCESSION HRs A F ~ vr'&" un a, 11 -6
5
I UBMITTEDs OLApY65
No REF SOVi 000
L-
2 i2- --- ~
/1~1,
SUB CODE-1*13C� Gd
ATD PRESS: ~47a ;

ANDRIANOV, K.A.; MANEVICH, I.Ya.; BUSLAYEV, Yu.A.; MATRCS)V, Ye.l.
Acid salts of methylphosphir-'Le acid. Zhur. neorg. khim. 10
no.3.-596-600 Mr 165. (MIRA 18:7)
1. Institut elementoorganicheskikh soyedineniy AN SSSR
Institut obshchey i noorganichoskoy khimii imeni N.S.
Kurnakova AN SSSR-

ANWRIANOV, K.A., uhAdeiiik; "fI",.'v:~A,'YANGV, SUKiU-,i'Ii;Vj" YI-I.P.;
-., 20~6v', P.1,
SynthesJs and physicomechtirdeal, proporties of fiIns of polymers
or regular structure. bokI. All J-SSH 101 Mr 65.
(MBIA 18:3)
1. Iristitut 3olyedinerdy AN

ANDRILANOV, K.A., akademik; PAKHOMOV., V.I.; CIELIPPRIN.,I, V.M.
......................
Disproporticnation reaction used'as a new method for synthesizing
organosillcon polymers. Synthesis of polyphenylenesilanes. Dokl.
AN SSSR 162 no.109-81 My t65. (MIRA 180)
1. Natichno-issladovatellskiy Institut plasticheskikh mass.

ZHDANOV, A.A.; ANDRIANOV, K.A., akademik; ODINETS, V.A.; KAIUOVA, I.V.
Synthesis and polymerization of cyclotetrasiloxanes containing
heterocyclic radicals with a silicon atom. Dokl. AN SSSR 162
no.2s335-338 Yq 165. x\ (MIRA 180)
1. Institut elementoorganichoskikh soyedinenly AN SSSR.
W

AN! 11 i 1 '~ NOV K -,I. . Kadi--inLk j G , M"Ill(II(NA, Yi- F. . 1-11Y, I YANOVA,
, I
G,.m. , N.V.
Themal dogridation of the polyiTmn of a-.1d ontorg.
Dokl. AN SB~')R 163 nt).l-.97-99 JI 165. (MIRA 180)
I . Institut, soy,~,ilnonly AN S33R i Voskovskiy
inititut. im. D.TJILin,lelt,yeva.

AITDR F!-t I -1-V - ~k ~kskjvjnll:; 1 01114$ RU!'RELEV, G.V.; GOItSEAYA, I.V.
I
--l- .
liti-,li-resc-Oution proton riagrietici nevonance of organocyolosilazanell.
DoIll. AN SSSR 163 no,4:877-670 Ag 165, (MIRA 18:8)
1. In3tifixt elertc-iii.r)(,wrr,,inielieskikh soyedirieni.y AN SSSR.

L�g'%4 &5 E'.'iT(m)/1-PF (c)/E;iP(j I/T Pc-4/Pr-4 JAJ/RM
ACCESSION NR: AP5017960 UR/0062/65/000/006/1022/1025
I AUTWR:
TITLE:
groups
542.91
Andrianov, K, A.; Tsomaya, N. I.; Khananashvili, L. M.
Synthesig of glycerol erivatives of oligomers with terminal functional
SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 6, 1965, 1022-1025
TOPIC TAGS: glycerol, glycol, hexametbylenediamine,\oligomer, adipic acid,
sebacic acid
ABSTRACT: The development of methods for preparing polymers via oligomers in-
volvee the development of a synthesis of oligomers with terminal reactive gz--F.O,
The article presents data on the synthesis of eateril'from glycerol and various
dibasic acids, as well as data on the synthesis of-cligoniers from the glycerides
of dibasic acids and hexamethylenediamine or a glycol. A study of the reaction
between glycerol and dib-saic acids showed thalt the reaction rmist be carried oxit
i in the preaeate of a lArge ex-cess of acid Lo permit tlie formation of trib-asic
I glyceroacide. The reaction follows the equa tion
1 Card 113 C I 1'0-co (Ciii).C0011

FL. 60CA7-65 AP5017960 -CO (CRA). C0011 + 31110
AWESSION NR- d11011 4
C112011 61~0-co (CH')"COO11
only if the molar ratio of glycerol to acid is 1-5, so that no Polymers are
formed. Esters of adipic and sebacic acid were thus obtained and identified.
The oligomrs were synthesized by condensing tribasic glyceroacide with hexa-
methylenediamine and. glycols. It was found that also in this case, when the
ratio of glyceroacids to the other component is 1:5, the reaction proceeds with I
the formation of oligomers as follaws:
1) c1linco (C112). C0011 C1110CO (CA12)XONH (Cli,)614113
COO 11
I't 11A) (1, 11'). GOO 11 Lti.t)(:O(Gll,),CoNIlfCii,).Nii,
2) 1 1j)(-.0 (c I l'), coo it Ul I I 10C 0 (C I 11) 0 0
I sO ~ GOO H 4- Ail 0 (Gil s), 0 11 - - (.11OCO V.11.), OW) OH + 31120
cooli
4,8, 2.4
Card 2/3

~'L 60047-65 i.*
ACCESSION KR- APS017960
These oligamers were separated by removing excess hexamethylenediamine or glycol
by extraction with water. The properties of the synthesized oligoriers are given,
and the experimental procedure followed for each compound is deecriht~d. Orig.
art. has: 2 tables and 3 formilas.
ASSOCIATION- Most-ovskiy inatitut tonkoy khtmicheskoy tekhnologii iffl. M. V.
Lomonosove (Moaccrw Institute-of Fine Chemical Technology)
SUEKIMD- 201-ia)-63 ENCL: 00 SUB CODE, OC
NO RZF SOV: 000
Ct7rd 3/3

~L 60953-65 E'dT(m)/EPF(c)/EWP(j)/T/EWA(c) Pc-4/Pr-4/Ps-L RPL WW/JW/RM
ACCESSION NR: AP5018911 UR/0363/66/001/006/0825/0829
541.64
AUTHOR: ADdrianov K. A Yermakova, M. N.
TITLE: Polymern wiLb InorpWo molecular chains - polyborome omethyl-
jy~~t~hl
Biloxanes
SOURCE- AN SSSR. Izveaflya. Neorganicbesidye matertaly, v. 1, no. 6, 1965, 825-829
TOPIC TAGS: boron organic compound, polyallaxane, silicon organic polymier
ABSTRACT: In a study of the formation of polyhorodimethylstioxane olippleris with a
branched structure, an attempt wms made to raise the hydrol~~c stabilit30-W these oll-
gomers by intro-rItcLng Into the inorg-anic rhnin ~-IoxanvTFT,.~.-i gurrmindmi by orgo-nic
radicals having donor proper'Lles. To this end, Use was Made of the phenylAML-IonicthYl-
methylaxane group, which was hitroduced Into the molecules in small amounts by conden-
satioat of A, U) --dilt ydrnxydi meth~'sil ox&ne s urith pheny lam inometlii), I methy1diethoxystlane
osi),-011 + cotso'41-Kslls - 2G21hOll 4- CsHsO- i-40.(;1).-0Si-0C4114
R, It
I-Card 1/3

L 60953-65
ACCESSION NR: AP6018911
H . Thereaction, associated with a quantitative
where R - CH and RI --CH;~MC6
evolution of ;1;1 alcohol, w us-ed%D control both the number of methylphenylamino- I
methyloiloxane groups and their position relative to the siloxane bond. The reaction
of polycondensation of ck , W-dihydroxydimethylsilmxanes with phenylan'dnomethy1dieffinoxy-'
silane was studied with oligomers of various degrees of polymerization. Oligomers of
the general formula
11 R R
(A)
wore obtained; where R CH3 and R' CH2NHC 6H with functional ethoxy groups at the
ends of the inorganic chain of molecules, and n = 1TP' 251 46P 74, and 188. The pro-
pertiep of these oligomers were determined. Branched borophenylaminometliylmethyl-
afloxanes with a regular distribution of boron in the inorganic chain were prepared by
condensing the synthesized oligomers with boric acid. The kinetics of the croBs-linking
reaction of the polymer obtained from the various oligomerE; were studied. The rate
constmt of this reaction decreasee with the degree of polymerization of the oligomer.
[;Oro---

L 60953--b5
MROCIATIONto luoUtut olemantoorgraicheddkb soyedinenly Akademli nauk &-sn (in-
stitute of OrganametaWe Compounds, Academy of Sctence
STJBMITTED: MebGS ENC L: 00 SUB CODE: OCI X c

ENT'~.m~/E PF(n ./EVIP(j)/T Pr_-4/Pr-4 R M
ACCESSION IT.Rt A.P5011249 VR/0150/69,/007/004/66801C~87
AUTHORS: And~ig v KI..=A., Golu 0v 0. Ye.; Yellnek, V. I.; Kurasheva, F. A.;
no , I
Manucharova, L F.; Lirv7xova, 7. F.; A
TTTLFi Synthesis and properties of polytitanodLmethylsiloxanes'l
SIOURCE: Vysokomolel-alyarrVye aoy~-_dineniyft, V. 7, no. 41 M65, 690-687
TOPIC TAG3j organic eynthesie, thermographic analysis, glass transition teinperi-
ture, polyoondeneation
ABSTRACTi The authors synthesized titanodi-methylailoxane 31igomers of the general
CHO
'formulu Tij(06_).0W, in which n may equal 99 18, 25, 34P 42, 52, 80, pr 1'_Lj. Poly-
condensation W~s earried out -at 200G. Thermographic analynes were made of tb:6 -7-
titanGdimethylsiloxana oligomers and polymers, and the heat of funior of the
crysta-IlLne phase was determined; tboup data Pore tabnlatpd. Electrical obidips
show that an increase in content of the hydroxyl group in the
~) I igomern leads to an increase In rigidity, a retKrdation in ar~yn tall ization, and an
increase in polarl mbillty and dielectric loss. It is concli-HoA that the relaxation
Card 112

.L 51393-65
ACCESSION NR, AP5011249
reaction of the comj)ounds in an electric field io determined by the presence of the
anorphous phase. The time of relaxati.)n wan foiind tn bo indppendent of thr, length
polydimet*lMlo,wie 'branches. Tho glass nt for the ntudie~. compounds waB
of the
found to liq within the range from -120 to ig. Last
itables.
4SSOCIATTONt Inatitut elementoorfvmicheski'kh soyedineniy AN SSSIR (Institute of
Eeteru-Organic Compo=dq, AN MR); Inatitut obahchey i neorganicheskoy khizil in.
.3. Xi=,-ia-kovn ('Instituto of General and -Tnore~lo Chemstra
!--- -L
No Rff SOVI 0% Orml WO
Cori - 2/2

L 5139 .k E!t1T(m)/EPF(c;)/'F_WP(j)/T PC-4//~T-4 RM
ACCESSION HRs AP5011250
UR/01 90/65/007/000688/0635
J:~'
3t
AUTHORSi Andrilanov, K. A.; Golubkov G. Ye.; Yelinik, V, 1.1 Kurasheva, K. A.;
Manucharo-ra, 1. F.; Litvinova, L. V.; Mem'Yev'-B. K. L
:TITLEt X-ray studies of R?l xanes
.1titanodim=xlsilo
.SOURCE: 'Iyookomolekulyarnyye soyedineniya, v. 7, no. 4, 19659 688-695, and insert
facing p. 688
TOPIC TAGSt x ray study, polymer, titanium compound, structure analysis
kBS'7tACT: The structure of polytitanodimethylsiloxane.; was studied by means of
Y-,---r,y stnicture analysis 3t room temperatFe and at -1:'0 7he. x-ray photographs
were takon with CuK radiation 1.54 A), and tb~ anar dgtances vvere
L;,mpu ted by the Braggg-'Nul f f f o-nila. The da ta qr,- tabu ! i to R~.4sti 1 t s show that the
of -10-lemaarchains- in polyme*16il-0-i-ah-ee, ~-h Was Toxind -tYAt-- titario -aimetbLylbil-0-Xim-e-t-
oligoners with to,-minal bjrdroxffl groups for n Z 42t polymers with n > 361 and
i
oligo-mers with terminal trimethylailane group~_vith n Z 23 arystalliv; in approxi-
mat6i. the same temperature range as polydi-methylailoxi-~.-ien, and the structures of
corcl 1/2

L 51394-65
:ACC MTIOV NH: AP5011250
the crystalline phnues are identlca,3. Orig. art. haB, 4 figures and 2 tables.
ASSOCIATTOI.'~ -~ngtitut elementoorpnichegkikh eoyodineniy AN SSSR (institute of
-Ir, .4-11 SSSR)-, Inatitut obahahe.,,, nooi~vrtrir-heakikh khimli im.
'h-m L3
o. -inoral Pz,.2
hhgineer ixig
9'- tu L E-',
b-UBMITTKD: 27jun64 ERCLi 00 SUB COM OC, OF
NO REF 8071 002 OTHERt 000

~~-L 2267---66:----EWT(-&)/E;PF(-C-)/EWP(-J-)---RM---
_M~TMOWWR: AP5022223 UR/0191/65/000/009/0020/0022
67/8.842
AUTHOR: Andrianov, K. A.; Pakhomov, V. I.; Lapteva, N. Ye.
TITIE: Reactions of chloromethylsilanes 'and siloxanes vith dihydric ehenol
SOURCE: Plasticheskiye massy,, no. 9,,1965, 20-22
TOPIC TAGS: organosilicon compoundi resorcinol, hydroquinone, condensation
reaction, silans esterification
ABSTRACT: The object of the work was to synthesize monomeric hydroxyphenoxy-
methylailoxanes and monomeric products with completely esterified phenol
hydroxyls by the reaction of chloromethylalkoxysilanes and siloxanes with mono-
and diosodium derivatives of dihydric, phenols. As a result of the reaction)
the chlorine in the methyl radical was replaced by the residue of the dihydric
phenol containing a free or eaterified,hydroxyl group. Reactions of bis(chloro-
methyl)tetramethyldisiloxane and chloromethyldimethylbutoxysilane with resercinoll,
hydroquLnone, or dihydroxydiphenylpropane (diana) were carried out in absolute
butanol under nitrogen. The conditions and results of these reactions are
tabulated. The 43ilanols obtained were subjected to condensation reactions, and
Cwd 1/2

L~Ord- 2/1

L 2168_66-,.._ EwT(m)/EPF-(a)/EWP(j)- - RM
ACCESSION NR: AP5024501 .4< UR/019.1/65/000101010015/0016
Ice,
AUTHORi Semenova, Ye. A.; ?4akovskaya, T. 0,'ihinkin, D. Ya.; Andriano
YAL
K. A.
LE: earrangements of methylcyclosilazanes
SOURCE:- Plasticheskiye massy, no. 10, 1965, 15LB.
TOPIC TAGS: organosilicon compound, 'chemical reaction, chemical equilibrium
recombination reaction, chemical reaction kinetics, catalytic polymerization,
catalysis
ABSTRA
CT: The 6ffect of electrophilic catalystalat different temperatures on
the mutual rearrangements of methyloycloollazanes was investigated to explain
previously obtained data. The conversion of hexamethylcyclotrisilazane (A) and
octamethylcyclotetrasilazane (B) by the action of 216 ammonium sulfate of 11o
concentrated sulfuric acid was studied in the 25-245 C range. Mutual rearrange-
ment of the two cyclosilazanes occurred, and at temperatures above 150 C
polymethyloilazanes were formed. The latter polymers were viscous yellow
liquids having a cyclo-linear structure, Ammonium sulfate was most active In, th
1/2-
A

IS

ANDRIANOVI K.A.; KUZNETSOVA, I.K.; SMIRNOV, Yu.N.
Reaction of tetrabutyl titanate:with methylphospbinlc sold
esters. Izv. AN SSSR. Neorg. riat. 1 no,3t289-29) Mr 165-
Reactions of n-tetrabutyl titanate with phosphinic acids.
lbid.001-306 (MIRA 18t6)
1, Institut elementoorganichoDkikh soyedineniy AN SSSR.

ANDFIANOVII N.A., MANUC,'HAROVAP
Polymore with ln~rganic chainv of molecules
poly ti banodime f,-hylrdloxanes. Iziy~ AN SSAR. Neorg. ma..
no.3t294-300 M.- 165. (MMA 18s6)
1. lns"Lhut elementoorganicheakith qoyedInen'.y AN SSSR i
Inat4-tulv obsh~!hfjy i neorganichnskoy imerd, Kiznakova
AN FSSR.

ANDPIANO'll, Y..h.j YITMAKOVA, M.N.
Polyboronmethylpherylaminomethylsiloxanes, polymers with
inorganic molecular chains. Izv. AN SSSR. Neorg. mat. 1
no.6:825429 Je 165. (MIRA 18:8)
1. Institut elementoorganicheskikh noyedineniy AN SSSR.

ynthosi3 o~ rit,..hy'! riPil:,e Jr., i, tv:d by Muhllp Of
vilb.-ation. Knix-,.Frcm.

OVCIII14NIKDV
ANDRIANOV? V.A.; KMNAINASHVEW L.M.
Organosilicon heat carriers. Rhin. plWm. 41 no.8:570-572
Ag 165. (MIRA 18:9)

~kc r
_7
ACCF-SSION NR: A.P5016503 tTR/Ol')0/05/007/006/1000/1004
5 41 . 64
AUTHORSt Andrianov K. A*j gin I. A.
TITLEt Formation of three-dimensionnl B-hydro)7-,tiinoll~no~itanapolydi-mothy'lloilox-
ane polymers
SOURCEi Vysokomo*19kWyariV7e xoyedineniya, v. 7, no. 6, 2965, 1000-1004
TOPIC TAGSt silomne, organoollicon com ~polymer, resin, oligomer, ' ans'-
pound vr J.
tion meta3,qcompleic, regetion mechanism
IT-
ABSTRACT: The vork was initiated to elucidate tho mechanism of oligomer Y-
10-1z:
merization. The Invostigation is an extension of the work of K. A. Adrianov a~_cT__
__i_.A._~~,Janov (Izir. A14 SSSR. Otd. khim. n.p 1962 F?"). 711,e oiii7omars studied
had the general formula (C NO')Ti - O(Si(CH ) 0)1111 I(T). "11.e polymerization of
06 3 2
these substances irith themselves and with 8-hydro-Vqiiinoli.tietributoxytitaniun
(H) was investigatod at 200C in vacuum. lt wa.~ four),--! that polymerI7.ation of I
and II was of firat and second order, respectively, and that the rate of poly-
merization reaction decreased with increase in the degree of polymerization of
the initial oligozae:% The specific viscosity, yield of gel fraction, and
Card 1/2

L 60137-65
ACCESSION NR: AP5016503
thermodynamic properties for the systems studled are given an functions of con-
densation timo. A reaction mechanism is proposed. Orijz. art. haoi 1 table,
5 graphs, and 2 illustrations.
ASSOCIATIONt Inatitut elementoorganichoskikh soyedinoniy KN 53SR (Inatituto
Hetero-Organic Compounds, AN SSSR),A
SUBINUTTEDt OWuI64 ENGLi 00 SUB GODE: OC
NC REY C05 OT HF R 000
Card 2/2

L 3.128-66 EWT(M)1EPF(C)1EWP(j) RPL WW/RK -
ACCESSION Us APS022931 UR/0062/65/000/008/1396/1402
546.287
AUTHOR: Tkeshelashvili, R. Sh.;.Apdrianovt__K, Aoj~'No A. I.
TITLE: Reaction of dimethyl- and phenylueth ldichloresilan6h with 114-dilithius-.-
-1.4-dihydronaphthalens
SOURCE:
AN SSSR. Izves a. Seriya khimicheskaya, no. 8, 1965, 1396-1402
TOPIC TAGS: dimethyidichlomailanoo condensation reaction
ABSTRACT: The reaction of dimethyl- and phenylmethylchlorosilanes with dilithium
derivatives of naphthane was studied to deteruine, its usefulness in the synthesis
of oligomers. The condensation reaction of 1,4-dilithium-1,4-dihydrmaphthalene
with dimethyleblorosilane proceeds according to the following scheme
H Ll
CHI
CH CHI
CH CH, CHI
He
-,o
cl
8HO, Its lh
LI
fit
Lcordl./3

L 3.128-66
ACCESSION NR: APS022931
The reaction product Is a tatramer with a boiling temperature of 218-22006 (at.1 M
Hg), In the absence of moisture this reaction proceeds according to-
I C
C116 -11 It Clio 118 110
1 11 H
CIA. 1.~~ C1 + L01 LLI + CI-41 -
- JH
Ho J11o' .&
CHI H' HCHIH H C11& H -11 CH,
C1 V
JH, 'JH. Its
This scheme was followed also in the case of condensation with phenylmethyldichloro-..
silane, In this case the products were: a dimer boiling at 200-2050C (I MM Hg) and*' .
a tetramer boiling at 245-2500C Umm Hg). Boiling temperatures at reduced press
refractive indices, and molecular weights (elemental analysis) were determined for
ail reaction products. 'In order to confirm the structure, the reaction products*
were hydrolyzed to the corresponding dihydroxy-derivatives with various degrees of
Card 2/3

ACCESSION NR: AP5022931

11 00752-66 _~Ellk(s)-?lj
-ACCESSION NR: APS020974 IJR/0190/65/007/000/1456;/1462
K. A.; Fromberg, M. B.; Belkina, T. M.
AUTHOR: Andrianov
----------
TITLE: Synthesis of trifunctional crosslike ester acids and of p2jLqsters having
a regular lattice structure
-SOURCE: Vysokomolekulyarnyye soyedineniya, v. 7, no. 8, 1963, 1456-1462
TOPIC TAGS: ester,- polyester plastic, polycondensation, adipic acid, dielectr c.
ru
joss synthesis, polymer'st cture
ABSTRACf: Trifunctional ester acids were synthesized by reacting trimethylol-
ethane or trimethylolpropane with a two-fold excess of adipic lazelaic or sebacic,
acid. Their. properties were determined, The kinetics of the Oolycondensati
d'adipic acid in 1: 1. tigated.
of trimethylolethane 'an 5 and 1:6 ratios were inves
In the first case the reaction is of the second order and in the case with excess
adipic acid the rilpaction Islirst order, The reaction rate constants and the energy
d'activati-on of these pol tondenbations: were calculated: Ec 20,600 cal/mol -
y
card 1/ 2
4
2/2

AM)RIANOIF K A - KURAKOVI G.A. -.r.; - , .
-1-1.1- - I- -? . '. , .,--u ~",. , N- ,
I..
Polymerization of cyclic VvS01"OM, soca.
7 no.8:1477 Ag 165. (I'4FRtA 18:9)

ANDRIANOV, K.A.; KURASHEVA, N.A.; AVILOV, V.A. '
Condensation of 6,4)-dihydroxydimethylailaxanes with
tatrabutoxytitanium. Izv. AN SSSR Ser. khim. no.Qtl6l6-
1619 165. (MMA 1839)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.

~ . -, FES I I I-ir It. 5. ; A Nil) I i ~ A NOV11: A.
Sv- ,the3is of ramlifted c)lge.)u,.r-r:, wlldh the ~,f~!ntral 9-fhcon at~;vi
S~ld hydroxyl. groups at the ends of brfinching. Izv. AN SSSR.
Ser. khlm. no.9t1709-1711 165. O'C RA 18 A 9)
1. Flektrotehhnicheskly imst'Atn!. dm. V..). Lenina.

Y~)/E c
2929 __?E~ JZ RM
AcawioN mRt Ap5c)226o5 UR/0190/65/007/009/156~/l
678.olt53+678-84
1avyginj I* A.
-AUTHORSt Andrianovp Ke Aij
TI TLM The structure and properties of linear and branched Rolych ate
titanodimethylsiloxmanes
'SOURGEt VysokomolekulyarWe soyedineniya, ve 7s no. 9, 1965., 1585-1591
TOPIC TAGSi linear polymer,, branched polymer, dimethylsiloxanep titanium
ABSTRAM The physicachemical properties of two polymerohomologous series of
linear and branchea polychelate titanosiloxanes of the general formulas
(.GqH6NO)ei- 65(S1(OH3)jO),Si)(CH3).,,.7., and (C06NO) Ti C0(Si(CH3)2O)nSi(CH3)_tJ3
were investigated and-their properties were compared with those of linear
polydimethylsiloxaaes. Xt was found that the introduction of titanium atoms
surrounded by 8-hydroxyqdnoline grouping into the siloxano chain increases
the molecular-interaction and influences the physicochemical properties or them
investigated compourk1s., Specific gravity and activation energy were found to vary
with temperature in ~he ranae of 20-700o A linear relationship between specific
weight and temperature was noted for both compounds. It was demonstrated that the
I Card 1/2

2929-66
V
505
Acomm Na a AP5o2
specific gravitypactivatign energy of viscous flow., and tho refractive index for.
polychelate titanosiloxanes decrease with increasing moleculAr weight (an inverse
relationship is true -for polydimethylsiloxanes). The free volume of polychelate
titanosiloxanes in the range of lower molecular weights is lower than that of
polydimethyl siloxanes. The various relationships are plotted and interpreted,
and the physicomechanioal constants of polychelate titanodimethylsiloxaties and
polydimetbVisi-Loxanes are tabulated. The viscosity of polychelate titanodimethyl-I
ailoxanes and polydimethyl siloxanes is shown to increase with increasing molecular,
i weight. For molecular weights up to 16000 the viscosity of polychelate
titanodimethylsiloxanes is higher than for,polydimethylailaxanes. With an
increase'in i~hlicular weight th&viscosity of branched polychelate titanodimetbyl-
siloxanes becomes lower than for linear ones and for dimethyl siloxanes, Orige
art. hass 6 figures'and 1 table,
ASSOCIATION i Institut elementoorgaacheakikh. ooy?dinenivj AN SSSR (Institute
of Organometallio Compoundep AN ISSR)
j (US W
SUBMTTEDs lsootA ENOLF 00 M CODE
OTHER -:00V
NO PM BOV
Card 2/2

L1255-66
ACCESSION NR: AP5021674 UR/0080/65/038/008/1887/1889
'14,0547. 21112221245 _;C 4D
AUTHOP Andr Val
Lobusevich, N. P.; Trofimova, I. V. ianov, K.A.: Golubtso
S. A. AAP
TITLE: Effect of methyl chloride and vinyl chloride on the synthesis of melhyl-
chlorosilanes&qq,;,
SQURCE: Zhu al prikladnoy khimii,, v. 38, no. 8, 1965, 1887-1889
TOPIC TAGS: chloride, silane, methylene chloride, vinyl chloride catalysis,
copper, silicon, aluminum, antimony
ABSTRACT: Methyl chloride obtained by chlorination of natural gas contains
up to 1. 7 vol. % methylene chloride and 0. 2- 3. 016 vinyl chloride. It is known
that at temperatures of 300-350C methylene chloride reacts with silicon copper
catalysts with formation of hexachlorodisilane methane and also of hydrogen con-
taining chlorosilanes. Under the conditions of the reaction of methyl chloride
with silicon-copper catalysts, the methylene chloride can react with the silicon
with information of analogous compounds, and can undergo decomposition with
the formation of carbon, which deactivates the catalyst. Carbonization of the
ca a
1 st was observed even after short term synthesis, with the introduction of
112.

L 1255-66
'ACCESSION NR: AP
5021674
6- 7% of methylene chloride into the methyl chloride. In experiments in a pressur,-
ized fluidized bed on an alloy promoted with antimony, an investigation was made
of the effect of vinyl chloride, whose concentration in the mixture'with methyl
chloride was varied from 0. 16 to 4. 0 vol. %. No adverse effect on the process was
observed at concentrations up to 0. 216. In the reaction of methyl chloride with,
an alloy of the composition Cu3Si, vinyl chloride in concentrations higher than
0. 1616 sharply lowers -overall activity and slightly lowers selective activity. For
Cu3Si alloys and mixtures of copper and silicon powders with addition of 0. 514
aluminum, the introduction of more than 0. 16% vinyl chloride causes a greater
decrease in overall activity than for catalysts-with an antimony additive. In this
case, large amounts of still residues are formed (15-40%). In general, it is
concluded that under the conditions of the synthesis, vinyl chloride reacts with
silicon with the formation'of vinyl:; trichlorosilane, . ethyl dichlorosilane, and
dimethyl vinyl chlorosilane, and that this inhibits the separation of dimethylehloro-
silane from the mixture of methylchlorosilanes. Orig. art. has: 3 figures and
I table
SUBMITTED: 17Jun63 ENCL: 00 SU34 CODE: MM, ac
NR REF SOV: 003 OTHER: 002
Card 2/ 2

ACC- NRi_ - AP5027692 PURCE CODE: uFt/oo62/65/000/010/1895/189T j
IN,
'Kid'
AUTHOR: Andriang ,K.,,A.; Lavygin, I. A.
ORG: Institute of Heteroorgani6 Compounds, AcadeM of Sciences SSSR (Institut
elementoorganicheskikh soyedineniy x4-)
Akademiy a,nauk SSSR)
TITLE: The reaction of Vis-(B-hydro)wquinoline)dibuto&vtitaniu~l'with a-hydroxy-w-
(trimethylsilyl)dimetbylsiloyme
SOURCE: AN SSSR. Izvesti~&. Sejiya khimicheskaya, no. lo, 1965, 1895-189T.~
TOPIC TAGS: titanium compoundt titanium organic compound, siloxame, titanosiloxane,
8 hydroxyquinoline
ABSTRACT: The condensation of bia(B-hydroxyquinolyl)dibutoxytitanium with a-hydroxy-
w-(trimethylsilyl)dimethylsiloxane resulted in the formation of linear oligomers with
the structure:
sl(C"3)
(CS 113). .12
where.n was 15, 60, 98, 1TOS*or 350. 'The co ndensation was performed in benzene solu-
tion at 80C for 3-4 hours. Butanol vas split off. The oligomers obtained were via-
Card 1/2 UDC: 542.952+546.821
0701 00;- 7

L 00265-66 ._'EFF(cj/94P(J)/wT(m)/T
ACCESSION XR: AP5013444 UR/0020/65/162/001/0079/0001
AUTHORt Andrianov. K. A. (Academician); Pakhomov, V. I.; Cellperina, V. M. . 119
TITLE: Disproportion reaction-a new method of qjRjhhesispf silicoorganic poly-
mers. Synthesis of.polyphonylonesilanes
SOURCE: AN SSSR. Dokladys ve 162, no, 19 19659 79-81
TOPIC TAM disproportion reaction, silicoorganic polymer, synthesis, polyphenyl-
enesilane
ABSTRACT: Base catalyzed disproportionation of several bis-Wimethylethoxysilyl) I
benzenes is studied'in an attempt to find new routes to the synthesis of poly-
phenyleneallanes. The ionic mechanism of this reaction is:
Card