SCIENTIFIC ABSTRACT ANDREYEV, V. I. - ANDREYEV, V. M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000101520013-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 20, 2001
• Sequence Number: 13
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

3(4)
AUTHORt Andreyev, V. 1. SOV/6-59-4-2/20
TITLE: Metallic Stnnds on the Mountain Summits of the Altay
(Metallicheskiye slitativy na gornykh vershinakh Altaya)
PER10'DICAL: Geodeziya i karto,-rnfiya. !Q1,9: Nr 4. pp 10-13 (USSi)
ABSTRACT: This is a report on the use of metallic stands instead of
concrete towors on the mo-antain sum:-.iits in the Altay-Range.
The relative sufaestion was made by K. R. Lebedev, Head of the
Construction Departm~nt, Duralumin stands were made for this
purpose in the Novosibirskoye AGF (Novosibirsk AGP). The height
of these tripod stands was about 2 m and the weight about 16 kg.
The sir
,htinp, drum via3 made of narrow metal plates or wood laths.
Experience tauKht that as a rule it is sufficient to increase
the working brigade by one or two workers, and that these
tripcds can be erected by any reconnaissance brigade. Camp Nr I
%yaq tit first establishod at the foot of the mountain, and then
Camp Nr 2 not very far from the summit. SleepinE and cooking
was done in Camp Nr 2. Spots where the rock forms the surface
were clioser. for erecting the tripod. Holes about 30 cm deep
were chiseled out with a steel chisel. The tripod was mounted
Card 1/2 in such way that tho tripod table was about 1.2 - 1.3 m above

Metallic Starids on the Mountain Suinzits of the SOV16-59-4-2120
Altay
the ground. The table wase aligned in strictly horizontp~l-,
and the sighting drum in strictly perpendicular direction,
and the feet of the tripod Yvere then embedded in concrete.
It is shown that by the use of metal tripods instead of
concrete towers about 2100 rubles can he-aaved in any place.
The first metal stands were erected in summer 1958- Some
shortcomings of construction are pointed out. Because of the
short field season, observations v~ere only made on one metal
stand. Engineer Podskrebayev is of opinion that in spite of
unfavorable conditions during observfttions it is convenient
to use the inetal stands. In summer 1959, more such tripods
will be erected on the summits of the Altay. There are
2 figures.
Card 212

ussit/ Physics.,- Physidal'chemistry
ftb. 147 -.18/29:
N. No; Che.rneva, E. P.; and Andreyev, V. I.
AuthOs 3 Tunitskiy-
t On the theory of the dyn-nmAcs of sorption and chromatoLraphy. Fart 30-
Title
4:
The dynaraics of ion-exch ,anr_e sorption durinC iiiradiffusion idnewics.
,him, 2006-2020) Novei:iber 1954
Periodical t Zhur& fiz, 1% 28/.U
of ion-axchange sorption was investiry~ted to dete c. the.
Abstract, The rmn
-Uning the sorption substemcc
behavi 'or of the sorbent layer in a flow cont. U
The c ondii tions f,
avorable for parallel tromisfer for ion-oxchan&e sorption
amindicated. The term ggyressing the -Lime loss of the protective effect':
is, introduced. TWrolo of internal diffusion wnd hydrodynciiiie- factors. an
the, sorption dynaAiQs',, ~ in explai-lod Tho exper:Lnontal dita, obt,-A:~ed for
%~al6iim I sorption with cationito in 4-fom, hydrogrcii soij)t ion vith c.- UorA-Le
in Ca-form md sorption of radioactive c-_~lciuni -t!-J_th catioi-ii, te in Ca-foiymi.'
were found to. be in'excellent confomiity with the. thoor.etical untr..
USSR references (109-1953). Tables; Iyaphs,
.Institution The~ L. Ya. Karpov Physico.-Cbe.-dazil Instituto, lloscow
Sulxnittod JLLrch 26, iq5i~

24 (4)
AUTHOR: Andreyev, V. I. SOV/32-125-5-41/56
----------
TITLE: Use of the Instrument "Tiss" as Signal Dosimetric Device in
Working With Gamma Rays (Ispcl1zovan1y6 pribora "Ties" v
kaeliestve signallnodozimetricheskoy ustanovki pri rabote 8
Gamma-izlucheniyem)
PERIODICAL: Zavodskaya Laboratoriya, 1950., Vol 91-., Nr 5, pp 622 - 623 (USSR)
ABSTRACT: For the purpose of dosine Gamma rays, smalier laboratories use
radiometers which in this case are provided with small counters
of gamma quanta. A correspondin- unit for Mlo radiometer "Ties"
U
is described here (Fi-). The unit contains se-.eral counters of
the type STS-1 which are erclosed in a cylindrical envelope and
connected with a coaxial cable. The counters are fed by a high-
-tension rectifier. An amplifier secures Cood.impulse recording
even if the coaxial ca le of the type RK-50 is 100 m long. The
test of a unit with CoH of an activity of 1 mC showed that this
type of dosimeter all0173 to measure the capacity of a dose of
Card 1/2

Use of the Instrument "Tiss" as Signal Dosimetric SOV/32-25-5-41/56
Device in Working With Gamma Rays
50-60 microroentgens/sec. There is 1 figure.
ASSOCIATION: Fizicheskiy institut im. P. N. Lebedeva Akademii nauk SSSR
(Physics Institute imeni P. 11. Lebedev of the Academy of
Sciences, USSR)
Card 2/2

1 .VOLIFE44SHTEYII, A-. A-., iN~MW, i. i.. ISLYWO, V. 1.
2. USM (600)
4. Photometry
7. Optical method of measuring the intensity, brightness and flow of light.
Zhur, tekh. fiz. 22 No. 12, 1952.
May 1953. Unclassified.
9. Monthly List of Russian Accessions, Library of Congress, -

IMMV. V.I., inah.
New plows. Trakt.
1. Altaystiy zavod
(Altaysel, mash).
(Plows)
oellkhoamash. no-11:32-34 ff 159. (miBA 13:3)
sellskokhozvavstvennogo mashinostroyeniya
-

AIMEYEV. V.I.
-
The P5-35A light-weight five-bottom tractor plow. Biul.tekh.-ekon.
inform. no.2:53-54 158. (MIRA 11:4)
(Plows)

ANDRXM, V.I.
-~,
Refrigeration in alcohol plants. Spirt. prom 22 no.3:29 156.
(KRA 9: 11)
1. Kuybyshavskly spirtoyyy treat.
(Refrigeration and refrigerating machinery)

ANDREYEV, V. I.
Applying the graphical Integration method to the calculation of
induced moments. Trud7 MITI no.14:81-87 149.
(MIRA 12:11)
l.Kafodra fiziki Kazanskogo khimiko-tel-linologicheakogo instituta
im. S.M. Korova.
(Molecules--Dipole momentr)

1:10)
AUTHOR: Andreyev, V. K. SC7164- 1/24
TITLEz Tasks of the Chemical Industry in the LiSht of
the Resolutions of the XXI Congress of the CPSS
(Zadachi khimicheskoy prom~4shlennosti Y svete resheriy
XXI s"yezda KPSS)
PERIODICALt )
Khimicheskaya promyshlennost', 1,050, Nr 1, pp 1-5 (UZ;Si
.
ABSTRACT: The Seven-year Plan 1959-65 provides a general increase
in the capacity of the chemical industry in 'the USSi bY 3.
Production of synthetic fibers is to be increased by 4
(the most valuable fibers by 12 - 13), and production of
synthetic materials and resins by more than 7. The
production of synthetic rubber is to be 4 times larger than
during the preceding Seven-year Plan, that of mineral
fertilizers 3.6 times, of a.=oni'a 3 ti_zes: of sulphuric
acid 2. 6 times, of anhydrous sodium carbonate 2.1 times
and of car tires 2.2 times. In 196;5 the prorductior. of
mineral
fe-rtilizers will amount to 35 million tons. In the
%
new Seven-year Plan, capital investment will be 4.6 times
larger (50 ~o' for the synthetic industry)i mcre than 140
Card 1/5 new large chemical factories are to be built ands -ore khan

Tasks of' the Chemical Industry in the Light of the S011164-59-1-.1124
Resolutions of the XXI Congress oi the CPSS
130 reorganized and extended. The most rapid development
will occur in the chemical industry in the Eastern repions
of the country. ~n the Vol;.-,a Area, a-J ::-. tl-.o U~ral -.0110re
the largest raw Laterial (Ileposits are situated. As comipared
with the Seneral capital investment -Nh5ch will increase by
4.6, investments in Siberia and the Soviet Faz, East wa.'Al
increase by 5.6, in Central Asia and Kazakhstan by 5.5, and
in the Volga Area and Ural by almost 5. In the RSFSR, only
the development of the chemical industry will be
intensified. The total production of the -he.-,-;cal plants
in the Kuybyshev Economic District -is to be increased lb:~
11, that in Saratov by 17. In Bashkiriya, 1;--r~e chemical
factories for the production of new types of 23.,rnthletic
rubber and products of orr
ganic synthesis wili be built. and
the total production will, increase by S. For vari~,-,s
areas in the Ural a production of synthetic materials is
provided as well as a strong intensification of the
production of potash fertilizers -;,.e Solika-msk- and
Berezniki Potassium Kombin&ts. !r, West Siberia. a nu:-.4ber
Card 2/5 of factories are to be built or, the basis of pe'troleur,

Tasks of the Chemical Industry in the Light of SOV/0'4-59-1-1/24
the Resolutions of the XXI Congress of the CPSS
processing gases, while the water power of the
Irkutsk GES (Gidro-elektricheskaya Stantsiya) is to be
used for the same purpose in East Siberia. In the
Ukrainskaya SSR production is to be especially
intensified by use of natural and waste gases of the
coke production, and three new large chemical factories
are to be built, and the building of the factories for
viscose and caprone fibers, as well as of the potassium
Kombinat, is to be completed. A strong intensification
of the chemical industry will also take place in the
Uzbekskaya, Kazakhskaya, Tadzhikskaya, Turkmenskaya,
Gruzinskaya, Azerbaydzhanskaya, Armyanskaya, Belorusskaya
SSR and other Soviet Republics. To solve all these tasks
successfully, an organized control and cooperation of the
results of scientific and research work in the experimental
plants of the Goskhimkomitet and the chemical plants of the
various economic districts will have to be carried out.
By a suitable control of more than 50 projects, a. saving of
2 billion rubles could already be attained. Within the
Card 3/5 general increase in production, the capacity of acetylene

Tasks of the Chemical industry in the Light of .50V1,-',' '24
4 -
the Resolutions of the XXI Congress of the CPSS
production should increase tc 15-000, 20.000 and 40.000
tons a year, of acetic anhydrides to 25-50.00C tons/year.
of polyethylene to 24-50,000 tonsh'ear, of poly-cro-pyllene
to 25-50-000 tons/year, of polychloro-viny! resins to
30-50.000 tons/year, for wh 4ch purpose the corresponding
plants will have to be built too as, for instance, gas
separators with a capacity of 30-60.000 tons of ethylene
a year, and - in a near future - cf 150-170-000 tons a year,
In this coftnection, already in 1950, about 1.000 new types
of equipment and devices will have to be developed
including 170 types of chemical apparatus, 59 types of
compressors, 7 types of refrigerators, 133 types of pumps.
34 types of machines for the manufacture of synthetic
fibers, and more than 600 types of ineasurin.6 instruments.
The TsK F.PSS and the Sovet Ministrov SSSR ~Council of
Ministero of the USSR) raise capital investments for the
building of the chemical industry from year to year. Thus,
an increase of 39 %a took place between 1957 and 1958, while
it will be 70% between 1958 and 1959. Th~ following large
Card 4/5 factories will start working in 19591 Sterlitamakskiy

Tasks of the Chemical industry in the Lipht of 507/64-59-1-1/24
the Resolution; of the XXI Congress of the'CPSS
zavod SK (Sterlitamak Works SK (synthetic rubber)
the production of synthetic rubber at the Karagandinskiy
zavod (Karaganda Works), the production of synthetic rubber
from butane at the Sumgaitskiy zavod (Stungait Torks). the
factories for car tires in Krasnoyarsk and Baku, the
factories for the production of synthetic fibers in
Ryazan', Engel's and several other factories. 10 new large
chemical factories will be built, in 1959.
Card 5/5

L 7791-66 ZWT(l)/SEC(k)-2/EWA(h)
ACCESSION NRt AP5027623 UR/0109/65/010/011/2010/202D
621.396.622..029.64.001.24
V. K. I Lomize L. G.
AUTHORs Andrge Lyudmirakiy, V. I ; Filkohikov, Le L
'TITLEt Calculation of frequency conversion in high-speed,serrodyne shf
~phasemeters with delay lines
25-
iSOURCH: Radiotekhnika i elektronika, v..,10, no. 11, 1965, 200-202D
TOPIC TAOS: shf phase motor, W-WU4- ; CZICAA.:r SLC41 ez.-IL
;ABSTRACT: The theory is presented and the formulas are developed for amplitudes
band phases in a serrodyne shf phasemeterl the conditions of maximum phase
;deviation at the mixer input are ana3jyzedl the role of the nonlinear-forward and
rudze-return motimw in serrated modulation is clarified.L These conclusions
and practical recommendations are offered: 1) The maxi=rm modulation frequency
tcan be determined from T >, 5 -r vhere T is the modulation period and-i is the
delay time of the long line involved; thus, the maxinum speed (or maximum
Dop~ler frequency) is &Zout 0.1/ T ; the IF corresponds to the 4th or
5th harmonic of the modulation frequency. 2) With the return motion of the
~modulating voltage, or vhen the delay time is commensurate with the modulation
Card 1/2

L-7791-66 EWT(l)/EEC(k)-2/EWA(h)
4CCESSION NR.- AP5027623
,period, the maxixum phase deviation is 2w n(I -+ 0) for operation on the first
.2-3 harmonics and is 2,na (1- 0) for operation on higher harmonica, where
is the ratio of the return time' to the phase -modulation period., 3) 'Strict.
~linearity of the modulating voltage and the frequency characteristic of the shr
oscillator is not needed; a 20.-30$ nonlinearity is tolerable., "In conclqsion,
the authors wish to thank N. I, - Malykh and Ye. S. Tmoll skly for a useful
,discussion." Orig. art. has$ T fignres and
42 fonsulaB . [031!
':ASSOCIATIDN: none
:SUBMITTED: 28Jul64 EXCL: 00 SUB COM 09
OTEM 1 005
NO REF SOVt 003 ATD
nw
Card

KORNEVA, N.K.; ANDREYEV, V.L.; DOhOFEYEV, G.A.; GRINFVICH, I.F,j VINOKIMOV,
Ye.B.; TRACHFNKO, V.A.
Study of the operation of ports in heavy duty open-hearth
furnaces. Stall 25 no.4:324-325 Ap 165, (MIRA 18:11)
1. Donetskiy institut chernoy metallurgii.

KULIKOV, V.O.; BORNATSKIY, I.I.; ZARUBIN, N.G.; DOROFFY!'X, G.A.;
YJiLUZHSKIY, Ye.A.; KA7AKOV, A.A.; ~OVALI -.F.;
TRETIYAKOV, Ye.V.; TRUNOV, Ye.A.; Prinimali u c h a s t --' y e
GORDIYENKO, V.V.; GRINEVICII, I.P.; GUBARI , V.F.; DOLINENKO, V.I.;
ZHEFTIOVSKIYI V.S.; ZIIIGALOVA, Z.I.; KOMOV, N.G.; KURAPIN, B.S.;
01ESHKINICII, T.I.; PRIhI10,71IFNKO, Ye.
Mastering the operations of 650- and 900-ton (mega - gram) capac;ty
open-hearth fiu-naces at the Illich motallurf-Icit.1 plant. St,-Ill .111
no.8:805-807 S 165. (,MII3.',. 18:9)
1. DONN 11CIII-I'll-T, T i Zhdanovskiy metallurf-icheski-; zavcd imEnl- Illicha.

1. ANDREYEV, V. M.
2. USSR (600)
4. Geography
7. Discussion of a series of pamphlets "Maps of the world." Reviewed by V. H.
Andreyev. Izv AN SSSR. Ser. geog. no. 5, 1952
9. Monthly List of Russian Accessions, Library of Congress, j,,njj,,rx 1953. Unclassified.

SAKOVICH, V.P.; AVDRKYEV, V.11., kand.med.riauk
Batadione treatanent in rhewnstism. Vauch.trudy Llvov.obi.terap,
ob-va no.1:252-254 161. (MTRA 16:5)
1, Kafedra fakulltetskoy terapii I.echebnogo fakullteta Llvovskogo
meditsinskogo instituta (zav. kafedroy - prof. S.F. Cleynik).
(RIIMIATIC FE-M) (BLITADIONE)

KMANUELI, N.M.;-U1AM1%V, T.M.; YEVSEYXNEO, L.S.; KOIWN, D.B.;
OBUKHGVA, L,K,
Kinetic criterion of ths effeutiveneS3 of stomach cancer
treatment in man. DoU, AN SSSR 165 no.2:461-46,4 N 165.
(MIRA 18:11)
1. Chlon-korrespondent AN SSSR (for Emanuel).

HAWN, 1'.*~.: TOROU, ZARETSKAYA, I.K. VMHOLETOVA, G.F.; AWCHMO, S. N.;
METWI V. M.
Steroids
Synthesis of steroids and related substances. Part 16. Uondensation of 1-methyl
cyclohexene-6-one with 2-methoxyl-ll 3-butadiene. Synthesis of 9-methyl-l-vinyl--9--
octalone-6 and 9-methyl-l-vinyl- ~~ octalone-7. Isv. AN SSSR. Otd. Khim. nawk no. 1,
1953.
9. Monthly List of Russian Accessions, Library of Congress, June 1953. Unclassified.

AINDREYEV, V. M. ; NAZAROV, 1. N.; TORGOV, I. V.; ZARETSKAYA, 1. 1.; VERKIIOLEMVA, 0. P.;
and ANANCHMO., S. N.
"Synthesis of Polycyclic Compounds Related to Steroidn. XVI. Condensation of
1-i-ethyl-l-cyclohexon-6-one with 2-nethoxy-1,3-butadiene. S~mthesis of 8a-rethyl-
1-vinyl- -octahydro-7-naphtlialene," Bull. Acad. Sci.,USSR, Div. Chem. Sci., 1953
69-80 (Eng translatloh). - See C.A. 48, 3324h. II.L.H.

AIMRMV, V. M.
Dissertation: "Diene Reactions of I-Vinyl - 4'-Cyclohexane. Bicyclic OrViodicar-
boxylic Acids, Their Transformation and Stsreochemiatry." Cand Chem Sci, Inst of
Organic Chemistry, Acad Sci USSR, Department of Chemical Sciences. Moscow 1953.
W-30928
SO: Referativnyy Zhurnal, No. 5, Dec 1953, Moscow, AN WSR (N42U%W

cut Vi Pub. 40~ - 13/26
Authors s Nazarov, I. N, j Nucherovo, V. F11 jand Andreyev# V. M,
Title sThe:stereochemistryof,cyclic compounos"-,"P=~ ionization of cis-and
a- A4-ootal
t
ran in_l,2-4icarb6xyl1.P so ids
Pariodiwa i I Izv, AN SSSR. Otd. Idili. -nauk 2p'. 289 - 297, Mar-Apr 1955
Abstraot I Investigations were conduated.to determine the laotonization of-ais-methyl-
A4-00talin-1,2-dicarbo~yhc acid and.to obtain data regarding the.atructure
of the cis-lactomacids which 'are formed-during the lactonization. ''process.
;It was found that of, all the spimeric.-trans-.4cids only a certain group of
trans-acids is capable:of laotonization. Trans-aoids of..other groups having
double,bondsbetween themclesare not lactonizable. Experimental facts-
redarding sterio,11ndrinces observed* during the lactonizationate explained.~
Seven referencest 2 USSR$, 1,German...l*Swiss,~ 2 USA and 1 Fronch.(1932-1955)...
USISR9 .The H. D. Zelinskiy Inst, of Organ. Chem
~Institution,l Acad of Se.,
Submitted April 6y 1954-

Subject
Card 1/1
Authors
Title
Periodical
AID P - 3582
USSR/Chemistry
Pub. 152 - 19/20
Yurlyev, Yu. K., A. V. Arbatskiy, I. K. Korobitsyna,
and V. M. Andreyev
Prea-r-~t-i-o'n--~6?-'~--61~6nylpyrrolidine from 1,4-butanediol
and aniline in the presence of aluminosilicate
Zhur. prikl. khim., 28, 7, 781-782, 1955
Abstract Under optimum reaction conditions the yield of
N-phenypyrrolidine obtained was 66.1%. The prepara-
tion is described in detail. One table, 5 references,
all Russian (1937-1950).
Inatitution None
Submitted Je 30, 1954

'trie
tsu [100cuors. of 404h in., 163" (auhAide m. 1281-- di-Ate giier, 'It
rmt to~P. _741cer
W od tiad their Wool* face Is pe~ to the It COW!
od "7d le
and V. M. Andretv figurationatthe'land0carbons..
V
. iLv, -
&F'U:A-8 R bi --poklely lidridtoftitedecohydroac;d.tn.76*.to2M pveuncw4xAy-"'
:4 '411C, 1U.1 i1x(-0 dtido, m, 00". which ptubably has the eh~axti-o* coua
-tWU* 'lt%hYIe4WY%i Yt the cwtspoudins'dicarboxyUk4M
.4 tr. don -of I.Vinylty chextue, *1 S
- *,b,
Pve ~lsomi~x of ta - 1W which with &N', savtdi-Afteskr, RqWd TU 411-0.1
a h;dride'with McOll gave the
ridu (1) tn. 54* and a Uquid; "bkh'hjdro-~,'- anti-do
-1 and m, 030 ~:wkkh
d y~_drql P reap- tathe-dicakydrooWir.tio coa uration etterified at 3-carboxi
rig d, na. y-, , , -- and traus4Z withl"Na save tbeffet ". m. 203'. while"C"tiftal
IbSO, which am the ri"yx-cjs
Moto-Aft #skis 0 1 were %(Qtd4tQ bam- tuertax of thala kagth, at'tht 1-casboxyl juvn the 6vft~
2-4
Thul the *~-W. di vrboxydewA)tkottapkikakne-l-acelic deid.
trixaft by he&U4 %ith MeONA m
Isomer give syx-ds ester esterified at the 2-ftrb=yl, while. 182% which deby4rogenated and decarbuylitad. to.. I-
SAP-QuIficadw, of -tht:0*-_M di-Me it*wlth KOH' gave "Me.01 III rization-ol the mano-lie ester (m4 030),
'Impinly the syn4a' ima"s akr estetilled atIwboxyl. with WON& pvt the previously described d*4xii-tt"S
M. 1399. the latto., M. 12110., It'
the fortatt ester dkwbo%yUc acid, m. 2D3'. lb**AS of thb di-Me ester
fl= gave the keekto asdiess, mo 144&p,&nd 10%iexp; ;with I mole KOH gave the mm-Yeaterat the I-carbaxgl
(m. (m. 980) and the mixed isetnerisai p
Treatment With eONa:lwmeAze4 the.utd. ester o* ralud. ra. 168
144*) yielding CiPs -&4*S-dM 3kat-144kor. The , former, Isomerized with MeON%, gave the kww;i
'p, i cit
boxAs ", w. 218, (a 76 tAkt, M.- -jy*0axs dkarbwr,,.4k acid. tn. 2181, while the liom
mQua C tsterlsomer-130merizedivith mao"a eater save (after treatment Vri
The other th CHSI S 4"W-,
WON& and b ,fr*xs&JI*e$krm.44'. Aradt-Elstertmethod for chalu
Askat.-I,"ica (.MZoss. 11111.; 1 Increase gave'. from this Mono-ester.
Sluillarly were trtated the mOn- - *aPUWs*r-2-w)iC acid, in. 1990, which dehydrogenated
Mer, ut., - liquid Isconer of J (arti- '-and. deearboxylated to 2-MeCipHy. Thin of 8 puufl*lm-.
ea#ersofouli-eiscoafturation. 7%c
with Uton pya the mono-1170 istcr. m. 1870 (tateiMed I tners of decahydranaphthalcut-I j2-dlcarbQjyUC acid, 6 Were
malply at I-Pasifiax =owhich hydrazenated to the frost- isolated and Identl6ed; 4 am ot the ds series and 2 of ISMIS
W oerlft~, ~~.Ttuve of the iii Ismers heated to 2600 are nearly
Mar, us. 34P. toomeriied with MeONn. to the itist-auti- qu"titativel converted In I hr. to cis,4*0"s ocries;'. the
':m~ 55* 3 YW& ft"tk* acid
Aram isonsir of the Pee "U, to. 200!. (di-Aff ukr, anhydride),
-'HydrtAysis of dl-ut cater t"M the Unit the most stabla U the anti configuration at C StOiD2 I
.;,HquId anhydride jjrith 1 mole KOH gave a wo-Afe esto,
f and 9 with cls configuration of the anhydride Tin (5 atomic).
It*41; lo tionot this save the correeponding"p-, 17t6 Unknown 19mers of tka trans oesies- (boxi-eyWraw
oxg.,* is~=the AtmAydro 8!0*69 which bW t0 hOmtr~ and lraxs4y*Ness aft rather Imst"
ROW
jqtvftWcPNk idw-d alu as and Walker, CA
I~q
Arm .77~v

NAUROV, I.N.; KUCHEROV. V.F.LAND4~~V, VOM.
- WN 0 ~
Research in the field of stersochenistry of c7clic compounds. Part 10
Stereschmnistry of the diene condensation of 1-vinSrl- d-cyclehexame
with malaic anhydride. Izv.AN SSSR Otd.khic.nauk n9.6:715-722 J6 156.
(MLRA 9:9)
1.Institut rganichaskey khimii imerd N.D.Zmlinskogo Akadenli nauk SSSR.
(Cycloh6xax:) (Maleic anhydride) (Stereochanistry)

~11 We
VV
IN
t;tv
n b
Tilol 9;1,1~~V
1. ~, LIM ~,w AvO
V!
gs
ON
~g w
.1 ll~i5
MR
IN,
M. P

HAZARM, I.N.; KUCIMOV, V.P.; ANDRNM." V.)(.
Research in the attroochomistry of cyclic compounds. Part 11.
Stersochemistry oft'ly -ectalln-1,2-dicarboxyllc acids. Izv.
AN SSSR Otd.khtm.nank no-7:817-826 J1 156. (MLRA 9:10)
l.Institut erganichaskey khtmii imeni H.D.Zalin5koge Akskdemii
nauk SSSR.
(Acids, PattV) (Storeachemistry)

4 v
10
J.k
1"g 6,
N

Vfi
lit;

Vi~
IWWRIM-1,
Eta

~ V-11, ~- I "T-~
u,-,~,,zz
w
U7

k~R
1,"'N A-

'"t.
k ,

ILAZAROV, I.Ii.;KUCHEROVO V.F.;ANDHEYBV, Y.M.
-. , 1. ~
Research in the Btereochemistry of cyclic compounds. Part 1). Synthesis
and stereochemistry of isomeric decalin-1.2-dicarboxylic acids. Izv.
AN SSSR. Otd.khim.nauk no.9:1091-1101 3 136. (MLHA 9:11)
1. Inutitut organichenkoy khimii imeni N.D.Zelinakogo Lkademii nauk
SSSR.
(Naphthalenedicarboxylic acid)

10
11~ Ve~: e4
1 7 V',
t4&45' "e A%-,~
;T'4~ o',
A 14~
I -- MOR-111,111.1

4.
R -Alf V144"',
-7,~j 7
onw"M t
-R,.At,4 -i/ -0
a
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orl. -A
ow.
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j.
=7'
", M'.A"

0... ~
I

n N.1))~ F- y C- v
YUGOSLAVIA/Organic Chemistry. Synthetic Organic Chemistry. G
Abs Jour: Ref Zhur-KMmlya, No 221 73969.
Author I.N. Nazarov, V.F. Kucherav, V.M. Andreyev, G-14.
Segall.
Inst
Title Upon the Spatial Directivity of Diene Condensations
and Stereochemistry of Cyclic Carboxylic Acids.
Orig Pub; Croat. chem. acts, 1957, 29t No 3-4, 369-392.
Abstract: Trans-1,2-dimetbylbutadiene-1,3 (I) was prepared
by the dehydration of methylethylvinylcarbinol at
2
300 to 210,', 0~.MgSOI, yield - 50 to 605, boil. p. -
76.5 to 78% n D - 1.4515. Boiling (4 hours) 51.5 9
of I with 56 g of malein anhydride in C;14resu~ted
in anhydride (III) of cis-cis-3,4-dimethyl-6
cyclohexenedicarboxylic-1,2 acid (IV), yield - 56.5 9,
Card V14
YUGOSLAVIA/Organic Chemistry. synthetic Organic Chemistry. a
Abs Jour: Ref Zhur-Xhimiyal No 22, 73969-
melt. P. - 67 to 68 (from,ether - petroleum ether).
17.3 g of IV, melt. p. 172 to 173"(dinsociates, from
vater) was obtained from the mother liquor by sapoai-
fication after separation Of III. The boil. P. Of
dimethyl ester of IV (V) is 122 to 123'/5 mm, n~'D
- 1.4750 d f to . 1 0987- The therml isomerization
of III (~,; to 215c; 4 hours, VL flow) in the pre-
sence of diethylaniline led to a mixture of substances,
boil. p. - 186 to 188'/35 zm, n LOD - 1.4950, from
which ciB-trans-3,4-dimethyl- 6~ -cyclohexanedicar-
boxylic-1,2 acid (VI) was separated after saponifica-
tion, yield - 64) melt. P. - 3-60 to ift' (from water);
anhydride of vi (vii), melt. y. - 46 to 4T ~from
petroleum ether); di" tVl eater of VI (vv '~Oil-
p. 116 to U71/5 mm, n4 D - 1-47A d 1.0921.
Card 2/ 111

YUGOSLAVTA/Orsozie Chemistry. Synthetic Organic Chemistry.
A~s Jour: Ref Zhur-Xhimlys) No 22) 73969-
correspondingly. cis_cie-,lj4-Iacto-3P4-dimethYl-
cyclobemecarbWlic-2 &0iA (XIII) was obtaited by
heating 5 g of W (I hour, 661) in glacial CHI-COOH
saturated vith MI (W), yield 3A g, melt. P*.
186 to 1870 (vater), the zeIt. p. of the methyl aster
thereof vas 3.09 to 1100 (from 70%-ual CHSOH)~ Under
these conditions, XII (0-9 a) undergoes a preliminary
cycle conversion producing trans-cis.1j.4-lacto-3,4-ft-
methylcyachexame-carbwWlic-9 acid (XIV) in the re-
sult of a following lactanitation) yield 0.55 9.,
melt. P. 154 to 1550 (from 20%-ual aqueous acatone).
Methyl ester of XIV,, melt. p. 57 to 58 " (from yetro-
Itum ether + ether) produced XIII by isomerization
with CH3ON& and following saponification. Similarly,
Card 4/14

yuGOSIAVTA/Organic Chemistry. Synthetic Organic Chemistry.
Abs Jour: Ref Zhur-Khimiyap No 22, 73969.
selectively from the side optosite to COOH groups
and led to cis-cis-cis-3,4-al thylcyclobexanedi-
carboxylic-1,2 acid (XVI), yield 2 g, nelt. p. 187
to 108 0 (dissociates, from 5*ual acetone). 10
g of III was converted into 9.6 g of anhycYide of
L
XVI (XVII), boil. p. 145 to 146,-" /5 mm, n 0D - 1.4835,
d ~- "?, 0s 1.1435 in a similar way (but in CkHj,).
Boiling of 5.9 g of XVII in absolute CH~OH led to
1-manomethyl ester of XVI, yield 4.25 'i, melt. P.
ilo to luo (from 6o%,ual CH60H) 1-5 9 of which
yielded 1.2 g of trano-cia-cia-3,~-dimethylcyclo-
hexinedicarboxylic-1,2 acid (MIM melt- P- 183 to
1840 (from water) by isomerization with CkONa and
following saponification; anhydride of XVIII, melting
Card 6/ 14

YUGOSLAVIA/Organic Chemistry. Synthetic Organic Chemistry. G
Abs Jcur: Ref Zhur-Ehimiya, No 22, 73969.
d.imethylcyclobannedicarboxylia-1,2 acid (XXI
acid), melt. p. 69 to 700 (fram petroleum ether
+ ether), together with 0.35 g of XIK was pro4uced
by hydrogenation Of 7.3 g of VII on Pt in C6H(,.
1.3 g more of XX was produced from the residue
after XIX and XKI separation and saponification.
XXI was produced by hydrolizing the anhydride, melt.
P. 113 to 1140 (from lvp'-ual acetone)p it produced
dimethy,l eater with the boi, p. of 108 to 109C'13.5
mm, n D - 1.4595p and d~" u 1.0722. The latter
(1-3 g)was converted by the action of CHjONa into
trano-trnns-trans-3,4-dimethyleyelohexan'edicarbo.Vl.ic-
1,2 acid (XXII), melt. P- 158 to 159' (from water),
which produced its anhydride of melt. P. 95 to 960
(from ether + petroleum ether). The spatial direct-
Card 8/ 14
YUGOSLAVIA/Organic Chemistry. Synthetic Organic Chemistry. G
Abs Jour: Ref Zhur-Kbimiya, No 22, 73969.
ivity of oxidation of diene synthesis products with
peracetic acid and osmic anhydride was also studied.
Yhe oxidation of 5 g of syn- 4 ~ -octalenecarboxylic-
1-acid (XXIII) (-10 , 12 hours) with 9V~-ual CH COOOH
in CHC13 resulted only in O~ -oxide (MV), yield 4.9 g
melt. j. 125 to 126 0 (from ether), the configuration
of which was proved in the following way. XXIV was
converted into syn-1)10-lactodecaloi.-4 (XXV) by the
action of HCl (gas) in CjHb or by boIling in CH OH)
the yield was quantitative,melt. p. 90 to 910 Xom
ether + petroleum ether, 1 : 1). Acetate of XXV,
melt. p. 129 to 1306. Oxidation of 5 g of XXV with
Cr,O~j In CH3COOH led to syn-1)IO-lactodecalone-4 (xXVI),
yield 4-5 9, melt. p. 108 to 110" (from acetone + ether,
1 : 1),; semicarbazone of XXVI, melt. p. 222 to 2230.
Card 9/14

YUGOSIAVIA/Organic Chemistry. Sp.thetic Organic Chemistry.
Abe Jour: Ref Zhur-Khimiyal No 22, 73969-
ether)j semicarbazone of XXVIIIa, melt. p. 198 to 199
(from CHIOH). XXIII (0-3 g) was isomerized into
trans-sy~6-ketodecalincarboxylic-1 acid (0.2 g),
melt. p. 85 to 86" (from ether + petroleum ether),
by beating with 1%-ual HCl (acid (100", 10 hours);
methyl aster, melt. p. 90 to 910'. 3.9 9 of A -
oxide (XXX), melt. P. 136 to 137 9(from ether +
petroleum ether) was obtained b~ the action of 90%-
ual CHICOOOH on 5 9 of anti-L -octalinearboxylic-1
acid (XXIX). Boiling of 0-7 g of M in aqueous
dioxane in the presence of HZSO~ led to trans-trans-
anti-4,10-dioxydecalinearboxylic-1 acid, yield 0.35 9,
melt. p. 180 to 181,/ (from acetone + ether, 1 : 1);
methyl ester, melt. p. 125 to 12617 (from ether).
The latter was converted into the known methyl ester
Card ll/ 14
yuGOSIAVIA/Organic Chemistry. Synthetic organic Chemistry. 0
Abs jour: Ref Zhur-Rhimiya, No 22, 73969
of trane-anti-4-ketodecalincarboxyl-ic-1 acid
(xxxi), melt. p. 66 to 680$ by dehydration with
n-CHIC~HyS06H- 0.95 9 of cis-trans-anti-4,10-
di .decallnearboxylic-1 acidp melt. P. 190 to
uy
A10 (from acetone) was produced by hydroxylation
of 1.3 g of XXDC with 0004, methyl eater of the
product yielded XXXI at dehydration. Oxidation
of 22.5 g of III with Bep-ual CH COOOH in CHC1~
at Cc led to a mixture, from which 11.7 9 of -
tl~ -oxide (MII), melt. p. 140 to 142 9 (from
acetone), and 6.1 g of a -oxide (XXXIII)) melt.
P - 137 to 138 0 (from acetcae) were separated.
The structure of the oxides was proved by the
following conversions. 2.8 g of cis-cia-trans-cia-
2,4-lacto-3,4-dimethyl-5-oxy-cyclohexanecarboxylic-1
Card 12/14

KUCHRROV, V.F., doktor kh1m. neuk,sotrudnik. red.; RUD~NKO, V.A., sotrudnik.
red. j--AYDPJPfBY-,--"., sotr6dnik, red.; ONISHOMKO, A.S., sotrudnik,
red.; SIDAL, G.M., sotrudnik. red.; SATAROVA, M.V., red.; GRIBOVA,
M.P., tekhn. red.
(Stereochamistry of cyclohexane 4arivatives; collection of articles)
StereokhImiia proizvodnvkh taiklogeksana; sbornik statei. Mosicva,
Izd-vo inostr. lit-ry, 1958- 329 p. [Translated from the English
and French). (HIIU 11:11)
1. Institut organichoskoy khimii im. N.D.Zelinskiy AN SSSR (for
Kucheroy, Rudanko. Andreyev, Onishchenko, Segal).
(Gyclohexa ne)
(stareochemistry)

All"NO113: Nazarov, 1. N., Member, Academy of'
(Decensed Klicherov, V. F.,
Andreyov, V. M., Segall. G. M.
of the Diene-Condensation of 1-u-
'
Ac"tOxyvA?'..y!.- A'-
Vyc-1ohp-xenp With Maleic Aldrh.vve
(Sterc-Althimiya diiy,~novi%y k-n6-nlL-atsi-;
A1-t.qik!oqekt;er-F- I S m1einclTym angidridom
PERJONICAL: Doklady Akademi ~ Nauk. it, 19)8, V(A.. 119, Nr
pp.
A iTRA-':T: Tne )n the title in 'Do..' In.; hcit7.pne
(rpf v-Je!(itx rk T, whTse s-,pclni1'Acati-r, r..N,
',taciti* '.o sin all a; yi.(-.-Ld r,f indiviftial witi-cis-4-
UO P V ~ XV at~ld .11. its
.11figuration wns prov9d. (in the basis of the dats. vbte4ned
thl!- c,,-nc1us;..,n was &-tivix ihnt the above-rit-ntioned liqu-1-i
I aa wit igaiation krid that Ois
d'.UT1P-Lclnfigtirati( .,n Is under th(-se conditi(ons on the wh,.-.,fl
fr,-M~; i Ln ;'ontrast '.,% the rule of the FLccumu--,--Ltwi of
1 1 wtA~, thAn proven. thac t~jc- artduct i,-% noct
zirtividusL' and that i t .,-.ontai.ns a imal 1 quantity of
j
,"a r,1 1/4

The 9tereachemistry of the Diene-Oundensation of
I A Cti:tC,xvVillyl- &1 -Cye lohexene W I th Mnli.pj c A ldphyde
prodijot with diazomethnup, cli-gly0oi-XI-ethor wzt,3
isolated. Tne c,)nfigurmInn of' the latter correizyonds ti tni-
addition of osmium unhY(Ir: if- from the side cpy-OS_,tp to T-he
carboy 'v-L grc)iipF; ;,). Thatiks to the %xial pt)sitjon tif th.,?
tortiary hydroxv I V vri., v I ti i i, k, v - - ~-, Ip -. - , A Ii, ~~ Ii Et ~, m q , ',v
cFtpah ) 9 rl' doilyd-ml, itin tm ! wig w i I- SU ~ I -) lit A
and y Ip I de(i tncr ii~, r-or: be,! P L.)(!A e the:~ *.,*i
ms 1, , v
y
o 11 t. E. rm C., f ft.4 y!r uv 0 und
addit,on ,-)f thf~ t?ty( ;#1,4 t mugt ho stat,~d -Attt the ker i
anther producPd ~)n inft "is the main T-(f4oi~,n
prc.duct reai-'v vos.,,nffic" P, T,.
~I t t E' I- i A R S11 ff -ITL I I.V 11 Tl~` 913 on f i rm a r I c, n c, f t he
!k:rif :gui .1c,.n r-f
i~ V.7 and ii (;-i ~thc-r VT7
a iL . An ;~Ypv, Lvi,!nta'i
the ut:12al data t,(:,t I The rt,~ o
w W". c h a r 1 e T

AMILYEV, V. M.
V. 14. Andreyev and V. F. Kuche ovo IlSynthesis and Configuration of All
?ossible Isomers of 3.4-Dlmethyl-61~ -Octaline Carbo)Wlic Aclos."
report presented at the Sympcsium on Concepts of Conformation in Organic
Chemistry which took place in Moscow Pt the 1OKh AN SSSH (institute of Organic
Chenlisti-ij AS USSR) from September 30 to October 2, 195V.
Izvestiya Akademi-i nauk SSSHO Otdeleniye khimicheskikh nauk, 1959, No. 3o 561-564.

GAIWRD, Norman G.; ANDRETIV, V.M. [translator]; RUIMHKO. Y.A.Etranalatorl;
SECLAL11 G.Mv- KOCqRTKOV, H.K., red.
[Reduction with complex metal hydrides] Vosetanovlenie komplekanymi
gidridami metallov. Moakva. 12d-vo inostrannot lit-ry, 1959. 912 p.
(mmA 14:2)
(Reduction. Chemical) (Hydrides)

5 (3)
AUTHORS: Eucherov, V. F., Andreyev, V. M.P BOV/62-59-6-17/36
Nazarov, I. N.
TITLE; Investigations in the Field of Stereochemistry of Cyclic Com-
pounds (Issledovaniye v oblasti stereokhimii taiklicheakikh
soyedineniy). Communication 25. The Condensation of Trans-1,2-
dimethyn-utaaiene With Maleic Anhydride Synthesis and Configu-
ration of Four Isomers of the 394-dimet~Y144_cyclohexane-112-
dicarbm~dc Acid (Soobahcheniye 25. Kondensatsiya trans-1,2-
dimetilbutadiyena a maleinovym angidridom. Sintez i konfigura-
tsiya chetyrekh izomerov 3,4-dimetil-A4-taiklogekeen-1,2-di-
karbonovoy kisloty)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 69 pp 1056 - 1067 (USSR)
ABSTRACT: The synthesis of the diene condensation (see title) which with
stereochemical selection forms the cis-cis-configuration (IV)
was investigated. Up to now only the cis-cia-configuration
could be obtained. By further heating and in the presence of
diethylaniline (IV) may be transformed into the isomeric cis-
Card 1/4 -trans-anhydride (VII). By means of saponification (VII) may

Investigations in the Field of Stereochemistry of BOV/62-59-6-17/36
Cyclic Compounds. Communication 25. The Condensation
of Trans-1,2-dimethylbutadiene With Maleic Anhydride. Synthesis and Configu-
ration of Four Isomers of the 3P4-dimethyl-,A4_CyCl ohexane-1,2-dicarbo)~4i Icid
be transformed into the diaxially arranged carboxylic acid
(VIII). The epimeric acid (V) corresponds to (VIII); the two
latter ones form the corresponding diesters (VI and IX). In
aqueous methanol (VI) could be transformed into a cis-cia-
diester which by the action of sodium methylate isomerizes to
the trans -trans -3,4 -dimethyl -A4-cycl ohexane -1 2-dicarboiZ!ia acid
(XI). The last possible spatial isomer, the trans--cis--3,4-di-
methyl-A4-cyclohexane-1,2-dicarbo)cZ,0,1-- acid (XIV), is formed in
an analogous way. Thus, all four spatial isomers which are pos-
sible were obtained-
(V) _COOH~e~ (~III) (^~-COOH~e~ (XI)_OCOOH~e~
CH COOH a CH, 1~'? -COOH a CH COOH e
;?H 3 CH 3 'CH
3(e) 3(a) 3(e)
Card 2/4 melting point 1730 melting point 1610 melting point 150 0

Investigations in the Field of Stereochemistry of SOV/62-59-6-17/36
Cyclic Compounds. Communication 25. The Condensation
of Trans-1p2-dimethylbutadiene With Maleic knhydride. Synthesis and Configu-
ration of Four isomers of the 314-dimethyl- '64 -cyclohexane-1 2-dicarbaqdit loid.
(XIV) COOH~ej
JD -COOH e
CH31CH,(a)
melting point 185
The existing configuration was determined by means of lactoni-
zation of the different compounds. When studying the spatial
orientation of the lactonization it could be observed that with
the isomeric cis-trans- and trans-cia-aoids (VII) and (XIV)
also conversion forms take part, which are caused by repeated
isomerization of the cyclohexane ring. COOH(a)
11 CH
(G)HOOC- 6 1 1 3
(e)CH z~4
3
H_ -COOH(e) H -
C k_(a) H OOH
Card 3/4 3 XIV 0OH(a) XIV(a)

Investigations in the Field of Stereochemistry of Cyclic SOV/62-59-6-17/36
Compounds. Communication 25. The Condensation of Trans-
1,2-dimethylbutadiene With Maleic knhydride. Synthesis and Configuration of
Four Isomers of the 3t4-dimethyl-t64-cyclohexane-1,2-dicarbcxyUcAoid
H COOH 6 (O)CH CH 3 OOH(a)
~,C H OC
. , ' I -"
4 -COOH(e)
H-31 I I (e)HOOC 5
, _ ~56
CH H H
3((Z Vill V111'a
In the experimental part the different condensation- and iso-
merization processes are described in detail,
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo kkademii
nauk SSSR (Institute of Organic Chemistry imeni N. D.
Zelinskiy of the Academy of Sciences, USSR)
SUBKMD: September 24, 1957
Card 4/4

5 (3)
AUTHORS: Kucherov, V. F.t Andreyev, Vs Me, SOV/62-59-7--14/30
Nazarov, 1. 11.
TITLE: Investigation in the Field of the Stereochernistry of Cyclic
Compounds (Iseledovaniye v oblasti stereokhimji tsiklicheskikh
soyedineni.v). communication 26. Synthesis and Confi-uration
of Six Stereoisomers of the 3,4-Dimethylcyclohexane-1,2-di-
carboxylic Acid (Soobahcheniye 26. Sintez i konfiCuratsiya
shesti stereoizomerov 3,4-dimetiltsiklogelcsan-1 2-dikarbonovoy
kisloty)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 7, pp 1244 - 1252 (USSR)
ABSTRACT: In the present paper the spatial orientation of the catalytic
hydration of the anhydrides of the cis-cis- and the cis-trans-
3t4-dimethyl-4&4-cyclohexene-1,2-dicarboxylic acid (I) and
(XIX) used for the synthesis of the stereoisomeric 3,4-dimethyl-
cyclohexane-1,2-dicarboxylic acid is investif;ated. In the case
of the derivatives of the cis-cia-trans-series (1), (11), and
(V) the hydration proceeded with respect to space, the hydroC;ev
Card 1/3 was affiliated to the side opposed to that screened by carboxj!

Investigation in the Field of the Stereochemistry SOV/62-59-7-14/36
of Cyclic Compounds. Communioation 26. Synthesis and
Configuration of Six Storooisomere of the 3,4-Dimethyloyclohexane-1,2-
dicarboxylic Acid
groups. This led to the corresponding derivatives of the cis-
cis-cis-3,4-dimethyleyelohexane-1,2-dicarboxylic acid. The cis-
trans-anhydride is in contrast to the ois-cia-anhydride M
not hydrated with respect to space, since the screening effect
of the carboxyl group is leas distinctly marked in the latter.
It produces therefore both possible stereoisomers, the cis-
trans-trans- and the cis-trans-cia-anhydrides (XX) and(XV).
Furthermore, 6 stereoisomers (of 8 possible) of the 3,4-di-
methylcyclohexane-1,2-dicarboxylic acid (III~ (X), (XIII),
(XVI), (XX)f and (XXIII) were obtained by catalytic hydration
on sodium methylate and thermal transformation. The configura-
tions and structures of these stereoisomers were proved by the
internal transformations and the consideration of the model
of the molecule. There are 4 Soviet references.
Card 2/3

Investigation in the Field of the Stereochemiatry SOV/62-59-7-14/38
of Cyclic Compounds. Communication 26. Synthesis and
Configuration of Six Stereoisomers of the 3,4-Dimethylcyclohexa.'Ie-1,2-
dicarboxylic Acid
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelin8kogo Akademii
nauk SSSR (Institute of Organic Compounas imeni N. D. Zelinakl~r
of the Academy of Sciences, USSR)
SUBMITTED: September 24, 1957
Card 3/3,

5 (3)
AUTHORS: Kucherov, V. F., Andreyev, V. M., SOV/62-59--7..16/38
Nazarov, I. N.
TITLE: Investigation in the Field of the Stereochemistry of Cyclic.,
ComDounds (issiedovaniye v oblas t4 stereokhimii tsiklicheal-fl-h
soyedineniy). Communication 30. Synthesis of the Cils-cis--
trans- and Trar,*-cis-trans-3,4-dimethylcyclohexane-1,2-di-
carboxylic Acids (Soobshcheniye,4/0. Sintez Tsis-tsis-trans-
i trans-tais-trans-3,4-dimetiltsiklogaksan-1,2--dikarbonovykh
kislot)
PERIODICAL: Izvestiya Akademii naiAk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 7, pp 1262 - 1269 (USSR.)
ABSTRACT: In a previous paper (~ef 1) the authors could not obtain th(-
stereoisomeric conpounds (1) and (II) mentioned in the title
by the method used by them. Their synthesis succeeded later by
means of a series of new stereospecific transformations. These
stereospecific transformations are investiCated in the present
paper by means of peracetic acid. The stereochemical oxidation
of the anhydride of the cis-cis-3,4-dimethyl-A 1 -octaline-1,2-
Card 113 dicarboxylic acid (III) served as an example. It could be

Investigation in
Cyclic Compounds.
Cis-cis-trans- ard
Acids
the Field of the Stereochemistry of SOV/62-59-7-16/3,3
Communication 30- Synthesis of the
Trane-cia-trar,8-3,4-diincthylc,,clohL~xanc-,,2.-iica~-bcxylic
proved that this reaction proceeds in both spatial directions
possible with the fo7mation of the icomeric a- and P-oxider
(IV) and (V). The configuration of (IV) and (V) was proved
by a series of chemical transformations. Furthermore, the au-
thors succeeded in prcducing the required substance (I) the
configuration of which was proved by the transformation of its
diester (XVI) into the earlivr described trans -trans -trane -
acid (XVII), by tho reduotion of the 9-keto-r--lactcni,3 acid
(XII) according to Klemmensen. The trans-cis-trans configura-
tion (II) which was also required was obtained by the investi-
gation of the partial saponification cf the oio-trans-ois-di-
eater (XXI) and the isomerization of the mixture of -t-he oor-
responding semiesters (XXII and XXIII). Th-,s, the 8 p
,, assibl-i
steraoisomers of the 3,4-dimethyleyelohexane-1,2-dicarbrxylic
acid were obtained the configuration and transformation :!f
which correspond to the general corceptions of ccnformatlcr.
analysis. The transformation schemes are given. The nynthise3
Card 2/3 and transformationE) are described.in the. experimental part,

Investigation in the Field of the Stereochemistry of SOV/62--59-7-.16/39
Cyclic Compounds. Communication 30. Synthesis of the
Cis-cis-trans- and Trano-cio-tran3.-3,4-dinotliylcyclchexano--4,,"1-15carboxyli,.,
Acids
There are 6 Soviet referonces.
ASSOCIATION: Inatitut orCanichaskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Inotituto of Orcanic Chet,,iistry iineni N. D. Zolin.-Ikiy
of the Academy of Sciences, USSR)
SUM11TTED: October 16, 1257
Card 3/3

1114HI~6RS: Nazarov, 1. 11. (Deceased), Andreyev, V. Y.P sov/79-29-3-8/61
Torgov, I. V.
TITLE: Diene Synthesis With the Participation of Trans-a-dihydro-
muc onic Acid (Di~enovyy sintez s uchastiyem trans- a-d i Cidro-
mukonovoy kisloty
PERIODICAL: Zhurnal obshchey khimiij 1959) Vol 29) Nr 31 PP 775-776 (USSR)
ABSTRACT: The authors continued their earlier ffork (Ref 1), concerning
cyclic compounds, with a trans-arrangement of the cycles and
they further condensed dienes with a,p-tinsaturated dicarboxylic
acids, of such a structure that the forming cyclic dicarboxylic
acids could be transformed into the corresponding transindanone
derivatives by subsequent cyclizftion (Scheme 2). This scheme
would offer the possibility of avoidinG the complicated and
multiple-stage way, per reference 2, which has hitherto teen
followed in such cases. 7"he condensation of dimethyl ester
of trans-a-dihydromuconic acid I (butene-1-dicarboxyl-1,4 acid
M)] was carried out with butadiene and 1-vinyl- A,-c,,clo-
j
hexene. In the first case transdiester (II) forined at 21009
the structure of which was proven accoHin[--, to scheme 3 by
Card 1/2 conversion into the acid (III) (Ref 3). In the sv-,ne way, the

SOV/79-29-3-9/61
Diene Synthesis iVith the Participation of Trans-a-dihydromuconic Acid
condensation of compound (I) with vinyl cyclohexene led to
transdiester (IV) which, owing to the migration of the donble
bond into the o-position between the cycles, could not be
hydrogenated with catalysts. The saponification of diester (IV)
yielded the corresponding acid, which was proven accordingtD
scheme 4. Also the acid (VI), a homolocue of dihydromuconic
acid, wan synthesized according to scheme 5; it could, how-
ever, not be condensed with divinyl. There are 5 references,
1 of which is Soviet.
ASSOCIATION: In3titut organicheskoy khimii Akademii nauk SSSR
(Institute of Organic Chemistry of the Academy of Sciences,
USSR)
SUBMITTED: October 20, 1958
Card 2/2

3/062/60/000/010/021/031/XX
B002//:t',06o
-,Lill rv~. V. m. tund Lysanchuk, L. K.
-"HORS: Kucherov, V. F.,
-4-T,E: Study in the Field of Stereochemistry of Cyclic Compounds.
ljopovt 1.5. Stei-ooohomiotry anki Somo Convot-li'ono of tho
Adduct of I-Viziyl-6-mLthoxy-3,,1-311iydroilLiplitlialeile With
1.11aleic Anhydride
PERIOD10AL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1960, No. 10, PP. 1796-1803
TEXT: The adduct (II) of 1-vinyl-6-methoxy-3~4-dillydroziaplithalene (I) with
maleic anhydride, the corresponding acid (III), and the diester (IV) have
a cis-syn-configuration. The compounds of this series are readily converted
by the action of hydrogen chloride into the corresponding isomers M, (Vi)~
(VII) which contain the double bond between the rings. Catalytic hydrogena-
tion cf the two series of isomers was investigated, anl the resulting prod-
(V17') and (IX) were found to have cis-syn-cis.confijuration. The di-
(M and (VI) vere isomerized with sodium methylate, and the
rs
Card 1/5

Stud,- in the Field of Stereochemistry of Cyclic Sloc, ',olloi:)Ollolo,1021"0.zil"~::
Com-pounda. Report 33, Stereochemistry and Some 7002X_0~3
Conversions of the Adduct of 1--Vinyl.-6-methoxy-
3,4-dihydroriaphthalene With Maleic Anhydride
corresponding trans-acids (X) and (XIII) were obtained. There are 10
references. 5 Soviet, 3 USj I German, and 1 S*ias,
ASSOCIATION: Inatitut organicheskoy kh.imii im. N.. D. ~'(-Iinskogo Akademii
nauk SSSR
(Institute of Organic Chemistry imen2 N. D, Zelinskiy
of the Academy of Sciences USSR)
SUBMITTED: Maj 13, 1959
Card 2/5

s/062/60/000/01C/021/0-11
P002/3o6o
co
ccro
CH-CO,
+ it 0
CH-CO'
CH, cli,
3/5

S106 60/000/010/021/031/,'y
-co cooll COOCH,
'o
co COOH OOCH
HIO C"2N,
c1 0 cti,o CH,o
(11) Tnx '2041 N .1) T.nA.225' (IV) T
ou
0
0
u
c0, 0 00" COOCH,
c0, COOH COOCHI
Cll_.N.
cl13coct
clf,V6~ e c1l'o
CH,O
(VIO T nA 141' (V) r.nii.210* (VI) ir.nit.79'
Card 4/5

S/O 6 2160//,"D,/0 1 ~/02 1/o,~ 1/;:,.,
cooll cooli cooll
OOH ccolf ~Clooli
I, -P,
Lypdhs, Coo ,COS) j
1\1 At ~C(
CH,O CHI (Vill) CH,O M
Z
u
Coon, o0mi, -COOC112
COOCH, COOAII, COOCH,
113(pa /"COS) llj(petls,coo
clf,o~oi CHI c1l'o
(IV) (IX) VI)
T.nA. 103*
5/5

S/062/60,/000/0101'022/031/XX
BO02/BO60
A", ~'HORS: An - vev----V---U Lysanchuk, L. K., Kucherov, V. F.
TT~LL., Study in the Field of Stereochemistry of Cyclic Compounds.
Eeport 34. Conversion of Semiesters of Tricyclic Dicarboxylic
Acids, and Configuration of Cia-syn-7-methoxy-1,2,3,,"1,10,10a-
liexaliydrophenantlirene-1,2-dicarboxylic Acid
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
196o, No. 10, PP. 1804-1809
TEXT: The authcrs attempted to prove that in cis-syn diester (I) the carbo-
.!iethoxyl -,roup is axial at C and for this purpose they studied the iso-
merization of the corresponding acid esters with the carbomethoxyl group
at C1 or C2- Acid ester (III) was prepared by action of sodium methylate
!--pon the cis.-syn anhydride, acid ester (IV) by partial saponification of
.' i,
.s-syn diester (I). On treatment with dinzo methnne, (III) and (IV) again
the ini+ial oubstanco (I). The configuration of semiesters (III)
kjV) wnq proved by performing their hydrogenation to the saturated
;,rd 1/6

Str3y in the Flold of Stereochomiutry of Cycl ic S1062116010001010/02210311XX
Compounds. Report 54. Conversion of Semiesterg Boo? 1-1060
of Tricyclic Dicarboxylic Acids,' and Configuration
of Cis-syn-7-metlioxy-1,2,3,9,10,10a-
lioxaliydrol)lientint)irene-1,2-diciirboxylic Acid
semiesters (VI) and (VII). Semiester (VI) was decomposed over the acid
chloride (VIII) and tbioester (IX) to (X) by desulfurization and reduction,
to y-lactone (XI) by cyclization, and to 1-methyl-7-methoxy phenanthrene by
dehydrogenation. Tile structure of (IV) also came about in this way. (III)
yieldi the cis-syn acid (XIII) on treatment with sodium methylate, (IV) 11.1',
trans-anti acid (II). The behavior of cis-syn-7-methoxy-1,2,3,9,10,10a-lic..-~,,-
hydrophenanthrene-1 2-d icarboxy lie acid c,-,n be understood when basinG, upon
these investigations. This compound was found in forms A and B; A is able to
isomerizeanthe carboxyl group C to form the trans-anti acid (II). In contrast
therewith, form A is not able lo isomerize oil the carboxyl -roup at C,). As
only semiester (IV) is able to isomerize with the carbomethoxylgroup at
C1 , acid (XIII) is chiefly found in conversion form A, which, from the ener-
gletic viewpoint, is of greater advantage. There are 8 references: 2 Soviet,
4 Swiss, 3 US, and 2 British.
Card 2/6

1 4.
Fi-, 11 of 04ereochomistry of Cyclic
z-:) ~onvor.,;ion o" So-mipolver3 "3002/-,o "0
J C
AC id S , and 'Vonf iGiiratiozi
xv 2,3,'1,10,10u-
hre no - 1 2-dicarboxylic Acid
in~--'uittit orgnnichoskloy ki"imil' D.
-a k n I - 7 % I
k S'"SR rInstituto of Orcanic Chemi~,try ime i
n
o1 tho Acadony of Sciences USSR)
T7- D Y 131 11/1 5 9
OOCH3(*) 00110?.
OOCH3(a) OOH (e)
CH,Oe
71r,

1-10621UD/CCCO 10 100/02 210" 1 /XX
0 -) 2 /1 -C,! C, 0
c0
c0
%0
'0 OOH
CH3 No H!~Pd.)O.
J~O-CCHOION-l c
rn) MO CH30&COOH
I
M T.nit.204' (111) T.nx. 196' (VO T.nA.216*
OOH 0011
CMU13
Oc
CH COOCH3 00CH
I KO!j li, Wd)
ec-
~\, I , I
-7 - CH'O
cli, 118' CH,O (IV) TAX. 196' (VIO T."s-178,
Card 416

/ n 7
31062 !322/
,3002/
COOCH3 cooc")
COO" h, ()-Co-o-C cosc.H.
SH
'Cor-11,
1\1 CH3
C H., X"
(Vo (V 111)
COO CH3 0
CH,OH A CH,
~c:
cli
cli,
-A, 1-0
CH'o CH30 (XI) t62' CH,O (XII) f.ris
(X)
5/6

0/062160100010 1 C/0-2/03 1/:~':
2 0 0 2 /"-- C) r, 0
Bee noaylicimue 4)euallTpeuoHwe 11I)O113BOA-Hue n0 TemnepaTypa.\l 1111B-
zemisi coBnaRaiaT c COOTBeTCTDYlOllWsnt np0H3BO:jllblMll I-MeTlUlt~ellanpcin
[6-81, m 9T0 coupwentio OA]103113tillO nOATBePARM, 'ITO B INNORHOM DPC-
\1 ljllC-Cllll-UllC-TlOly3#pc (VI), a caejioi3aTe-lbllO H B URC-UH-Mly-
'INIbI10.
-3#pe (111), imeewn cuo6oxiag Kap6oxcimbitasi rpynna ilpil Ci. KaK 6b,;io
nOK23aHO DblUIC, BTOPOrl ujic-c;m-nony34)lip (IV) 31B.IneTC51 TOlbY,0 CTPYK-
TypliblM 1130Nlepom nonyq#pa H, CMCaOB3TCJ]bllO, llMeQT CBOGD;itlylO-
Kap6OKCllAbllyio rpynriy npit C,2.
"ard 6/6

KUCHRWV, V-F.; LYSAWMK,L.K.; AIWIZEV, V.M.
Stereochemistry of cyclic compounds. Report No-35: Synthesis
and configuration of the isoners of 7-methoxy-1,2,3,4,4a,q,
10,10a-octabydro-1,2-phentAnthronedicraboxylic acid havbw
cis-linked rings. Izv. AN SSSR.Otd. kbim. nalik no.ll-.2003-2008
ii 16o. (MIRA 13, 11)
1. Institut organicheskoy khimii im.N.D.Zolinskogo Ali SS&tt.
(Pbeiianthrenedicarboxylic acid)

KAZAROT, Ivan Nikolayevich [1906-19371; TORGOV, I.T., doktor khim.nauk,
otv.red.: MRMT, T.M., kand.khim.nauk, red.; GURTICH, I.A.,
kand.khim.n-aW. SHMSOY. N.I., kand.khim.nauk. red.:
TANOTEXATA, L.A., kand.khim.nauk, red.; RUDMO, V.A., red.izd-va:
POLYAKOVA, T.T., takhn.red.
(Solooted works) Isbrannye trudy. Koakva, ltd-vo Akad.nauk SSSR,
1961. 69o p. (Chemistry, Organic) (MIRA 14-.4)

ANDREYEV., V.14.; SEGAL, G.M.; KUCIIEROV, V.F.
Stereochemistry of cyclic compounds. Report No.41: Synthesis
of geometric isomers of 7-metboxyhexahydro (and octahydro)
phonanthrene- V,2-dicarboxylic acids. Izve AN SSSR. Otd.khim.
,nauk no.8:1475-1482 Ag 161. (mMA 14:8)
1. Institut organicheakoy khimii im. N.D. Zelinskogo AN SSSR.
(Phenanthrenedicarboxy.lic acid)

ANDREYEV, V.M.; NUCIIEROV, V.F.
Stereochemistry if iyclic compoundg. lir-r,7,rL and
catalytic hydroppneation of 7-methoxy-1, 2-tls -byd roxyme thy] hr x-
ahydrophenanthrenes. l7v. A14 S~'SR. Otd.lhim.nauk
s 16.1. (mmA 14-9)
1. Institut orpnicheFll~ay Hdriii im. N.D.ZelinFkof-o Z'
(F+Pnanthrene)

MCHEROVp V. F.; ANDREYEV, V. M.; LTSANCHUK, L. K.
"Synthesis of geometrical isomers of 7-mothoxykvdrophananthrenecarboxvlic
acids and the stereochemistry of their reactionx.0
report submitted for the IUPAC 2nd International Symposium on the
Chemistry of Natural Products, Prague Ciech., 27 Aug - 2 Sep 62

ANDRFYFV, V.M.; LYSANCHUX, L.K.; KUCHEROV, V.F.
Stereochemistry of cyclic compounds. Report No.47: Some laws
governing the oxidation of cis-syn-7-metboxy-1,2,3,9,10,10a.hexa-
hydr-ophenantbrene-1,2-dicarboxylic acid and its dimethyl ester with
peracetic acid. Izv. AN SSSR Otd.khim.nauk no.1:90-96 Ja 162.
(MIRA
1. Institut organicheskoy kllimii im. N.D.ZelinsRoGo A14 SSSR.
(Cyclic compounds) (Acids, Organic) (Stereocheristry)

KUCHEROV, V.F.; LYSANCIU, LA.; AtJDRFYLV, V.1-1.
Stc,-cochemistry of cyclic compounds. Report Nu.48: Oxidation of
an-bydride of cis-syn-7-netl)oxy-1,2,3,9,10,10a-boxaby6ropf)enanthrene-
1,2-dicarboxylic acid with peracetic acid, and chemical transforma-
tions of products obtained. Izv. A14 SSSR Utd.khim.nauk no.1:96-lC6
Ja 162. (MIRA 15:1)
.1. Institut orpanicheskoy khimii Im. N.D.Zelinskogo X4 SSSR.
(Cyclic compounds) (Stereochewistry) (Acids, Organic)

BARMIN, V.V.; BYSHEVA, G.K.; TMUNOV, G.K.; AGAPKIN I.I.;
1 2
VESELOV, M.A.;,_A1fDRffZV VA; GOLIDIN, L.L.; LUZIM, V.N.1
RADKEVICHJ, I.A.; SOKOLObK.-LY, V.V.; STADNIKOV, A.G.
Study and correction of -t1he horizontal component of the mag-
netic field in a proton synchrotron on low densities. Prib.
i tekh. eksp. 7 no.4122,1#-229 JI-Ag '62. (MIRA 16:4)
1. Institut teoreticheskoy i ekaperimentallnoy fiziki Gosu-
darstvenno o komiteta po ispollzovaniyu atomnoy energii SSSR.
Nagnetic measurements) (synchrotron)

S/076/62/0'z6/001/00~)/O I
BIOIlBI02
AUTHOR: Andreyev, V, M.
TITLE: Critical phenomena in open systems
PERIODICAL: Zhurnal flzicheskoy khirTii, v. 36, no 1, 1962, 42-1)2
TEXT: The biological phenomenon of IlepiCenetic homeostasis" has been
treated qi~antitatively and it has been proven that for any chemical systein
there exiit conditions undei wl'Ach several steady st8tes are present,
simultane(;usly. A wavelike surface with "valleys" representinE steady
states and with "water divides" for non-stead~- states is sut.-j'ested as a V/
model. The steady state acquired by a system depends on the nitial
state, on a chanee in parameters chajiCint- the position of the steaoy st~.,te,
and on a slight change of the parameters, which results in a loss of
stability. For the steady state of the oxidation kinetics of a hydro-
carbon in a continuous system in the presence of' an inhibitor one obtains
-k 3p + k2n - vp = 0; a + 2k 3p -k,ni - En 2 _ vn 0; - kini -4- vi0- v i = 0 ( I),
where n = concentration of peroxide radicals, p concentration of peroxde.
Card 1/4

S/07 6/62/03 6/00 1 /06:11/0 -7
Critical phencmena in open s,~stems 11101 /B 102
and i concentration of' inhibitor Elimination of p and . furnishes
3 2k k /(k + v) - v - vt,/k in 2 , (v. ~L k, k,,io - Ik X.
n A 2 3 3
- v ak I;V)n - av/Ek I= 0. 1f the factors are substituted 'by a, , a 2' a 5
this eauation can be- reduced to n3 + a n2 P, 4, a~ = 0 TL-2 oclrl 11 ~,.n
2
thqt all the roots ol' this equation be real reads >,,a
2a2 _ 4a3a 3 ~ 16a4a a 2> 0 '0; 2
1 4a - 27a a a, > 0 These -~u i
2 2 2 3 If
c.:tn be satisfied, as proved by the substitution of certia:.n values ~~n
For & / 0 and i 0 ~ i the followine relation is in een~,ral valid-
n/v v - En n c
10 Iki )[2k 2k k3 CL 11 -hen a
there occur-, a ranC,~ of' with three solut;ons it' the cond i t io-
( 1 II/v) I 2k2k 3/(k 34 V) - I > E/ ki is fulfilled Siz"I lar-ly , tile I-(- I a f
V = V expXt is derived for the open system of a liquid phase contactine
0
the surroundings throug-h diffusion and havine i vol',imp T iil s
there are several stc-idy stites with difler-~.rit r.t., of' , rovth
Card 2/4

SIO'~ 6/62,,% 1~6/uo i //w//O
Critical phenomena in open systems B I 01/B !02
the samc- kind can therefore exist in one nild the mllmv Int)(J111111 ]n il I'l,cl'ont
alternate stable steady states. Such parallel variations are fotind with
biological 9.),stems, such as Escherichia coli ',IL',;O (Ref, 20,L~ee below-,-) and
others. The question is discussed as to whether the transition from normal
to cancer cells is caused, not b,,,- mutation, but by ii tr;lnnitlon to ,~nothc-r
stable state with the same t-enes. III thiS C:jSe, SlAffiCielitiy S1.1-01it'
effects actinr or. the system must brinE.-, about a transition in the same
direction. This might be a means oi re-forming malignant cellf- Jnto norrl-.al
ones. Ya. 13. Zel'dovich and N. N. Semenov are mentioned. :~. ,~. Kzj~,rr-,~ tnfi
N. M. Emanuel' are thanked for discussions There are 4 figtires nu::
23 references: 10 5oviot ano 15 non-Soviet. The four most recent
refeie:.ces to Enj-lish-lanj_uate publications read as follows: 1). L. lianne~.
`ilicrobiolog.;, developmental Cenetics and evolution. Am. 1~aturlili~,t,
no, 87~, 1960; A. Campbell. Autocatalyt4c particles and steud; states
Nature, 186, -- 4720, 256, 1960; T. M. Sonneborn. The gene and cell
differentiation. Proc. Nat. Ac. Sci. USA, ~~, no. 2, 11107, 1960; Ref 23:
M. Cohn, K. Horibata. lnhibjt~on b.,- Clucose of the 1*nduct~d synthesis 0" th~--
;~ -, C)
P-galactosideenzyme system of E. coli. J. BacterioloE~:, 76, no. !rO 1. 1
Card 3/4

S1/07 "1 /'62, 10 56,/C0 1 /00 i;/10 i I
Critical phenomena in open o.,,stems B101"Liloc.
ASSOCIATION: Akademi,;a nauk SSSR, Institut khimich~:skoy i'izik,- (".-'cademy
of Sciences USSR, Institute of Chemical 1-1 :~:, s i c F,I:
SUB%'ITTED: May ()6,,
Card 41/4

LYSANCHUR, L.K.; ANDREYEV, V.1-I.; KUCHEROV, V.P.
Stereochemistry of cyclic compounds. Report *-52: Regularities in the
addition of hypobromous acid to dimethyl-cis-syn-7-meth -lj2j3jq*lO,l%-
hexahydrophenanthrene-1.2-dicarboxylate. Izv. AN SSSRItd.khim..- '-,
nauk no-4:706-11~ Ap 163. (MIRA 16:3)
1. Institut orgaaicheakoy khimii ime H.D.ZolinBkogo AN SSSR.
(Hypobromous acid) (Cyclic compounds) (Stereochemistry)

PELEVINA, I.I.; ANDREYEV, V.M.; LIPCHINA, L.P.; EMANUEL, N.M.
. .1.1. 1
Kinetic characteristica of the activity suppression in enzymes of
the succinic oxidase system by the inhibitors of ra~tcal processes.
Dokl. AN SSSR 148 no.611408-1411 F 163. (KRA 16:3)
1. Institut khimicheskoy fiziki AN SSSR. 2. Chlen-korrespondent
AN SSSR (for Emanuel'). (Enzymej) (Inhibition (Chemistry))

KUCHEROV, V.F.; KAZARYAN, S.A.; ANDREYEV, VX
Stereochemistry of cyclic compounds. Report No.57: Spacial
and steric course of diene condensation of 1-vinyl-,d -
cyclohexane with ethyl pseudQ-/t-formyl acrylate. Izv. AN
SSSR. Ser.-khim. no.11:1996-2002 N 163.
Stereochemistry of cyclic compounds. Report No-58: Some
transformations of isomeric &I-fornyldecalin-l-carboxylic
acids under conditions of the Knoevenagel, reaction.
Ibid.r2003-2007 (MIRA 17:1)
1. Institut organicheskoy khimii imeni N.D. Zelinskogo AN SSSR.

ACCESSION NR: A24015110 S/0136/64/000/002/0048/0051
AUTHORS: Shigina, L. N.; Andreyev,--V-.---X.
-TITLEt Hydrolysis of germanium tetrachloride
SOURCE: Tavetny*ye metally*p no. 2# 1964, 48-51
TOPIO TAGS: germanium tetrachloride, hydrolysis, hydrolysis rate,
hydrolysis oondition , germanium dioxide crystallization
ABSTRACT: The effect of temperature, reagent ratio, method of hydro-11
lysis, and agitation, on the degree of germanium tetrachloride hydro-i
lysis including additional recovery of slurry after hydrolysis with
and without agitation was Investigated. It was observed that the
degree of hydrolysis Increases during the first 1-2 hours, and that
the temperature determines the hydrolysis constant. Generally It
was found that the process rate inoreases at lower temperatures of
about'200 and that crystallization of germanium dioxide is more rapids
at the low temperatures. The temperature range Investigated was from:
-
2 to +490 and It was oonoluded that the lower the temperature the
C
ard 1/2