SCIENTIFIC ABSTRACT ANISIMOV, I - ANISIMOV, K.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000101620016-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: April 3, 2001
• Sequence Number: 16
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

ANISIMOV. I.
Truck for transporting bottled gas. Zhil.-kom. khoz. 8 no.12:22
158. (MIRA 13:1)
1,Direktor treata, "Kaliningorgas.*
(Idquefied petroleum gas--Transportation)

ANISIMOV, 1.
Do not lower the tempo or quality of work. Zhila-komokhov, 4 no.2:
6-8 154. (KLRA 7:5)
1. Upravlyayushchiy Xalininskla trestom "Todokanal".
(Xalinin-Water supply) (Water supply--rLalinin)

ARDBDVICH. V.Y. (Moskva); ANISINDY. LA. (Moskva); LYUDMIRSKIT, H.I.
(Koskya); PATUSHINSKATA, R.S. (Moskva)
(bmlity control of some processes in the chemical industries.
Aytom.A telem. 21 no,6jB21-832 Je 160. OURA 1317)
(Automtio control) (Chemical engineering)

--ANlSIMOV.-I,A,
intersections in city triangulation. Geod.i kart. no.6:53--56 1e
161. (MA 14:6)
(Triangulation)

ANISIMV, I.A.; PINYAGI?4, N.B.; RYKOVA, S.S.
~ I
Role played by the petroleum refining industry in the creation of
Iajor industrial chemical complexes. Khim.i takh.topl.i masel 8
no.800-31 Ag 163. (MIRA 16:9)
(Petroleum-Refining) (Chemical industries)

ANISIMOT, I.I.; SHNNYANSKIT, K.A.; RUDIX, G.T.
Specific prophylaxis of brucallosis in cattle on collective
and state farms in Stalin* Province. Vaterinarlia 32 n#.5:
25-29 My '55. (K"gk 8:7)
l.Nachallulk vatotdela Stalinakey oblasti (for Anisimov).
2.Direktor mazhoovkhoznoy labornt6ril (for Shanyanskijr).
3.StarshiT vetvroch sovkhoza imeni Oktyalbflskok revelyutsil
(for Jbid1k).
(STALINO PROVINCE-BRUCRIMSIS IN CATTLE-PREVENTIVE INOGULA-
TION)

ARZUMANYAN, A.A., akademik; BERG, A.I., akademik; ZIIUKOV, Ye.M., akadem1k;
SV-WOV, N.M., akademik; VINOGRADOV, V.V., akademik; FRANTSEV, Yu.P.;
SHCHMUMOVY D.I., akademik; ANISINOV, I.I.; GATOVSKIY, L.M.;
IOVCfIUK, K.T.; FEDOSEMT, P.N.',* akaae~nq Ra4ASIKIN, P.S.; KWSTANTINOV,
F.V.; MITIN, M.D., akademik; YELYUT171, V.P.; PLOTHKOV, K.N.,
nUDENSKIY, G.A.; YUDD;, P.F., akademik; RYBAKOV.. B.A., akadmnik;
KOVISTANTINOV, B.P., akademik; KHVOSTOV, V.M.; KEDROV, B.M.; MARKOV,
A.A.; BAISBEV, S.B., akadmik; ALEKSKYEV, M.N., Prof.; SKAZK114, S.D.,
akademik; ALEKSANDROVP A.D.) POSPEWV, P.N., akadernik
Discussion of L.F. Wichev's rreport. Vest. AN SSSR 32 no.12.,19-50
D 162. (MM 15:U)
1. Chlen)-korrespondenty AN SSSR (for Aleksandrov, Frantsev,
Anisimov, Gmtovskiy,, Iovchuk, RomaslJc1n, Konstantinov, Yelyutin,
Plotnikov, Prudenskiy, Khvostov, Kedrovp Harkov). 2. AN Kazakhskoy
SSR (for Bmisherv).
(Research)

A 1: 13 1, 'r . 1%
.1
I ' T -, f e, x " ; 1 , ~ 1 n i) V r, v, 10 1 ron., I p'.
.1*0"'dov ~. 1). -n,' Anin~-ovp . ". ll~'alcllja! lorl:1 , . ,
c-.mensators with etlectronic vnifare. rer,lators," In ,'nr' Riill~nr -
Anisi,ov, N, 7. -Irlrly T.nvocl-erkann. polljff~'!-hn. in-'!, i-.
Vnl. VI'll, YV,~', n. 17-l'
SO: 16 Jime 53, (leto-i!l I-,v'li ~iaf-y,
- . r., . . I

ANISIMOV, I., zaaluzhennyy vetvrach USSR.
Use of antibiotics in poultry farming. Ptitsevodstvo 8 no.6:33-35
Je '58. WRA 11:6)
1.11achallnik veterinarnogo otdela Stalinskoge obleallkhozapravleniya.
(Stalino Province- Poultry) (Antibiotics)

ANISIMOV, I._11.,_mnsluzhennyy vetvrnch USSR.
Results of warble fly control In Stalino Province. Yeterinarila
35 no.3:67-69 Mr 158. (MIRA 11:1)
1. Nachallnik vetotdela oblaellkhozuprAvleniyn Stnlinckoy oblesti.
USSR.
(Stalino Province--Warble flies)

ANISIMDV, I.M.
Disoasea of tho respiratox7 organn in yom4; poultx7.
Vaterinnrila 36 no.10:2)-25 0 '59. (HIJU, 13: 1)
1. Nachallnik votorinariingo otdola Stulinqkogo oblsollkho-m1pruvle-
niya.
(Poultry-Diseases and posts)

ANTSIMOV, 1. N. Head of the Veterinary Department of the Stalinsk Oblast'
Agricultural Administration, Honored Veterinary Surgeon of
the Ukrainian SSR.
Effective means (sources) for the rise of the productiveness in animal husbandry
M-se of feed antibiotics7,Veterimriya, Vol. 37, No. 11, p. 27, 1960.

.ANISIMOVp I.N., zaaluzhennyy veterinarnyy vrach 1UkrSSR
Possibilities for the increase of productivity in animal husbandry,
Veterinarlia 37 no.11227-30 N 160. (MIRA 16925
1. Raobaltnik veterinarnogo otdela Stalinakogo oblastnogo vel'sko-
khozyaystvennogo upravleniya.
(Donetsk Rrovinee-Stook and stockbreeding)

R~~';T~-
IM"
'm2
'i 81
'at.
51V

/04 /3 11))i J" .-I
ANISIMOV, I.T., podpolkovnik tueditsinukoy
~- .
Prevention of auppuration in surgery of infected tissue. Voen.-
mod.7.hur. no.7:58-61 A 157. (MIRA 11:1)
(WOUNDS Atli) INJUIUBS. Burg.
prev. of suppuration)

ANISIKOV, I.T.
Perforating gastric ulcer complicated by a biliary fistula which was
cloned with a paraffin seal. Sov.med. 21 Suppleinent.21 157,
(PXKIG ULCER) (MIRA 11:2)
(FISTUIA)
(GALL BIADDER-DISUSIS)

(jNISIMOV, I.T.
Prevention and treatment of,acuto purulent peritonitis@ Sovemodf*
22 no,711.14-117 J1158 (MDU 11110)
(PZRrPOIIITISI
-purulent postopt, prove & there (Rue))

i. V.
I. V.: III-Iatfrial on f1he r-,,or- holo-~Ivl of i.erlph rtl blood
bone-marrov. -unctate of cattlo under nor:a6l and anenic conditions". Troitsk,
PLin Iii-her EdiicAion U-T;R. Kazan' "itatf, Veterinary In-t. imcni N. E.
Bmiman. (Dlsqertations for the degree of Cinlldaf..~ of Veterinary 3ci~ilcp.)
SO: Knizhna,-,a Letoris' No. 50 10 Decenib~?r 1955. -'."OSCV.7.

AWSIMOV~ I.V.; KRINSUNCIV, V.N.
Characteristics of the trmicient condAtf,m of *~(;-Prs.
Khim. i tekh. topl. I mRsel 10 no.3!45-5,) Xr '65,
(MIPA 78:1) )
1. Monkovskiy ir-stitut khim5chenkogo njqhInoqtrcycn-.Ir., j,
Sevcrodonetskiy filial Oryytn(~.-),c-.nqtrul,.i-.orrkog~; b~v,-O

X., !. V., D16'r.
,i ('r !,I, i-n-duct'i"ll of,
, I :0~-,Ccw III.A. n.
,c A "', 11. 1'061 'Cl ..
Chc:-Ac~.l llach'.no aiil-.i'n- U -
. - , 1' 54. M', u --~- 54)
L;O: ."32, 2) 1.',r 55

HA1151nor, I-K
USSR/Chemistry Acetic acid production
Card 1/1 Pub. 50-5/18
FD-264o
Author Anisimov, L V.
-- -manoww3m.,
Title Automatization of the production of acetic acid from acetaldehyde
Periodical Khim. prom. No 3, 145-150, Apr-May 1955
Abstract Outlines automatic control procedures used in the production of
acetic acid by the liquid phase oxidation of acetaldehyde In the
presence of manganese acetate. Five figures.

USSR/Chemistry Chemical engineering, Control instruments
Card 1/1 Pub. 50 - 7/20
FD-3363
Author Anisimov, I. V.
....................
Title Determination of the dynamic characteristics of automatic control
systems by means of industrial instruments and controllers
Periodical Khim. prom. No 7, 4oB-414, oct-Nov 19qr-,
Abstract Developed a method of determining the characteristics of automatic
control systems applied in the chemical industry by using industrial
recorders and controllers which record data on a magnified scale.
Propose a method of introducing disturbances into the input in such
a manner that the fluctuations of the parameter being regulated will
not exceed the set limits. The calculation of the amplitude-phase
characteristics according to "dispersal curves" (error curves]
yielded values which agreed well with those calculated from fre-
quency curves. Ten references, all USSR, all since 1940. Two fig-
ures, 6 graphs, 3 tables.
Institution
Submitted

)mndidat tekhnicheskikh nax0c.
Experimental -determination of the dynamic chArncteristics of industrial
pneumati~-.rogtil'at'ors..Xhim.prom.no.8.-476-482 D '56. (HLRA 10: 1)
(Thermostat) (Phoumatic control)

ANISIMOV, Igor$ Vasillyevich, kandidat takhnicheakikh nauk; OMOVA, A.A..
- ` ?"' -1-azherneri vedUshebty'redaktor; XHLIBNIKOVA, L.A., tekhnicheskiy
redaktor
[Automatic control in rectification processes) Avtomaticheskoe
regulirovanie protsessa rektifilmteii. Moskva. Goo.nauchno-takha.
izd-vo neft. L gorno-toplivaii lit-ry, 1957. 102 p. (HLRA 10:7)
(Distillation) (Automatic control)

ANISIMOV, I.V., kand.takhn.nauk.
Considering the automatic regulation of oxidation tovers as
standard control type in chemistry industries. Priborostroanie
no.9:4-8 S '57. (MIRA 10:10)
(Automatic control) (Oxidation)

28 (5) 3/064/59/000/07/019/035
AUTHORs Aniaimov, I. V. B0050123
TITLE: Methods of Optimum Adjustment of Regulators Based on the
Dynamic Characteristics of the System to Be Regulated as
Obtained by Experiments
PERIODICAL: Xhimicheskaya promyshlennost', 1959, Nr 7, pp 612 - 619 (USSR)
ABSTRACTs In the paper by Ye. G. Dudnikov (Ref 1), a method is des-
cribed for computing the adjustment of regulators from dynamic
characteristics of the system that were obtained experimental-
ly. In the present paper it is shown that this method can also
be used for computing optimum adjustments of serially manu-
factured automatic regulators in the chemical industry. Be-
sides, correction factors for the changes in working con-
ditions of the system are given. Moreover, the author worked
out a procedure by which the adjustment of the rQgulator can
be solected according to the conditions of the changing load
of the system. The author's calculations are given in the
paper. Table 1 shows the values of two power exponents that
Card 1/3 were necessary for the calculation. As an example the com-

Methods of Optimum Adjustment of Regulators Based on slo6 59/000/07/019/035
the Dynamic Characteristics of the System to Be Rs- B005YB123
gulated as Obtained by Experiments
putation of the optimum adjustment for a manometric , ;Gmpera-
ture regulator, type 04-TG-61OVis given, which is us4d in
the oxidation column in the production of acetic acids: This
regulation system is reproduced schematically and accurately
described. Table 2 gives the data necessary for the computation
obtained by expuriment, tables 3 to 5 show intermediate results
obtained in the course of calculations. A method was suggested
by V. V. Solodovnikov (Refs 4, 5) for drawing a diagram of the,
anticipated transition process of regulation with an optimum
adjustment of the regulator. In the present paper the
following industrial standard measuring apparatus with pneu-
matic transmission of indications are recommended: Float-mano-
meter (consumption-metert level-meter, extensometer), type
Ii IMP-28 , spiral spring-manometer, kpe MV.P_ jj~~bel lows -sealed
"land a riiig balance with universal
vacuometer, type VSP-270t
pneumatic transmitter, type-UDKVAIn a special section of the
paper the preparatory work for adjusting and determining the
correction coefficients during the calculation of optimum ad-
Card 2/3 justment is discussed in detail. There are 9 figures, 5 tables,

V~-~
Methods of Optimum Adjustment of Rcaulatoro Based
on the Dynamic Charactoriatics of the Systein to Be
Regulated as Obtained by Experimenti,
and 5 Soviet referenc,-o.
S/064/59/000/07/019/035
B005/B123
Card 3/3

A11IS114OV, Igor' Vasillyevich-, GORIKOVA, A.A., vecl. red.; POILSINA, A.S.,
I teld-m. red.
[Automatic control of rectifi--ation] Avtori;aticheskoe regulirovanie
protsessa rektifikatell. 2. izd., dop. Mloskva~ Goo.navokinc-tekbn.
izd-vo neft.1 gorno-toplivnoi lit-.ry,, i961. 1789 p. (MIRA 1/4-12)
(Distillation, Fractional) (Automatic control)

e- A14I-SIMOV,_I_,V.; KRIVSUROV, V.h.
Mathematical description of the static charactcriaties of
a tray rectification colural. Khim.prom. no.9:572-575 Ag 162.
(IrE RA 15:9)
(Plate towors)

KRIVSUNOVP V. N. j ANISIMOV I. V.
- ~~p
Static characteristics of plate rectification columns. Khim.
prom. no.3:219-227 Mr 163. (MIRA 16:4)
(Plate towers)

ANISIMOV, I,V.; SMOLINIKOV, P.V.
Development of the combined inv4riant system for the control of
rectification. Khim.prom. no.l2t895-902 D 163. (MIRA 17:3)

14ic, of c., I (-.c tron ura'~., g c r rr I -,rc of the
ructificaticn of bliulry .Tom. Je
8 : 7

ElectronAr -nmpui.nr ralculnt!on of I-hf,
ParnmPters --)F '.hp vlqtt- rectifictition ~*Ijmns for the qeparat.tnn
c)f' binary -rixt,~t,or, pr(,-Ln. 40 no.30:776-782 (' 161'.
I. M

ANISIMOV, I.V.
Y,ftndrel for turning grooves. Mashinostroitell nQ5%18 My 165.
(MIRA 18:5)

1.
%T V , V S. ; , J V. ; S~ ?.,, j L! .!I,, Yll .,f.
St;~: ti st ~ metlic,lis f- T, ~,hr:,. ric., r~, nu* r)f
- i 11 .. I
diarac; les ('r 1-( c ~ I f1cf, t L,, co ll~mj I-.,, - D I I tri. 41 no . i.,
49-54 Ja '65- (1-:IRA IF:3)

ANISIMOVO, I.Te. (Moscow).
Strapless folding apparatus for newspaper rotary presses. Poligr. proiz.
no.5:14-15 My 153. NLRA 6:6)
press)
(Printing

.&NISIMOV, K._
This demands an urgent decision. I-rom.koop. 14 no.8:28 Ag
16o. (MIRL 13:8)
1. PredesdAtell pravleniya arteli invalidov "Kartonazn,"
Leningrad.
(Leningrad--Physically handicapped--Rehabilitation)

ANISIMOV, Kb.; ADRATKIN. P.
Oar bearers of decorations. Prom.koop. 14 no.6:27
Je 160. (MIRA 13'-?)
1. Starshiy inspektor orgrovizionnogo otdola promsovets,
Dagestanskoy ASSR, g. Makhachkala (for Anisioov).
2. Haeballnik otdola orgmassovoy, raboty i kadrov oblprom-
soveta, g. Irkutsk (for Admaykin).
(Decorations of honor)

KOTTELI, Yu.; METKIN, A.;._ANISIMOV, K.
This Is what conveyers contribute. Prom.koaps 14
no.7:6-7 Jl 160. (MIRA 13:8)
1. Tekhnoruk arteli "Kulttkhim," Kiyev(for Kottell).
2. Tekhnoruk arteli invalidov "KollektivrVy trud," g.Kimry,
Kalininskoy oblasti (for Metkin). 3. Predeedatell pravleniya
arteli invalidov "Kartonazh," Leningrad (for Anisimov).
(Kiev--Pi ente) (Kimr7-Shoe industry)
rieningrad-Paper box indust-ry)

ANISIMCOV, K. -.--
Electron-tube voltmeter. Radio no-3:53P54 Mr '61. (MIRA 14:8)
(Electron-tube voltmeter)

ANlSIMUV, K. (g. Leningrad)
Audio generator. Radio no.5s.47-0 Yq 161. MMA 14:7)
(Oscillators, Electric)

ANISIMOV, K. (Leningrad)
Wobbulator. Radio no.5:52-54 My 163. (KRA 16:5)
(Oscillators, Electron-tube)

27
Autborm i Aniiisov,, L, Ni'O4hd.N6siaq*nov,: A,')(*
Tltu I Inves4gation. 0t- phoop)4nic acid derivati4es, Part l.- syu~hesio-IC4
-ohlorideb
beta-alkoxy (ObOwW)~-phoophinio acid
Perlodlua. I Isy.:-ANSMO Otd*'o"Idlitif nauk 4t- 610 - 6133, July - August 1954.
AUtmat, s, The addition of:pb6sphapputabbloride' to, aDyl(az7l)vlnyl-,O'thero in~..

chemical Al - ~f the addit .:i~ oil
the -Pr". ej~' 4 lou proftoto obtalned- 'i4relm
'
ut method for, the opthesix of dicbl6i
jated,: A 91MIs and-co~ie4ls
bTdrldee~of:batai4ai~~ .(pbonM)~virqlphosphinio acid*: is'doi6ribed.-'.
TW7~effeot'of oarb~Wl o::aoida andwater on the
yield,of Witt
:3 - Gormu-:
Proftote . is,. w[plajn6di; Nine references l.'2 USSR) 4 USA and
(1876 "-.:1948
'
lnmltli~iiou ~ 'I'
Acidt"Of Booltsm0
~iut 4fomanio.chemistry
Subidttod :
iAupA 23., 1953;

romn
. . . . . . .. . . . . u
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bot'tQ U*
V.44'. it o"
Of a
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He CWTO beet
In AM mli'vs
-;ffli CDC114 the
lay6o;

qt~
0 t he prodOtt heated the toll iii
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aid
m
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obt*ed tba fo
4 dw Nil

ANISIMOV. K.N.; KOLOBOVA, N.Te.1 NESHEYANOV, A.N.
Investigation in the field of derivatives of unsaturated phosphinic
acids. Report no-3- ~-alkovethoxyvinylphosphinyl and P-alkoxy-
ethox"in.vlthiophoaphinyl chlorides. Izv.AN SSSR Otd.khim. nauk
no.5:799-802 S--O '54. (MLRA 8:3)
1, Institut organichesko7 khimii im. N.D.Zelinskogo Akademii
nauk SM.
(Phosphinic acid) (Chlorides)

ANISIMOV ~~*
Investigation in the field of derivatives of unsaturated phosphinic
acids. Report no.4. Arv1vinv1phosphinyl chlorides. Izv. AN SSSR
Otd.khim. nauk no-5:803-805 S-0 154. (ML'RA 80)
1. Institut organicheskoy khimii im V.D.Zelinskogo, Akademii nauuk
S=.
(Phosphinic acid) (Chlorides)

Z;'Yz:.

ANISIMOV,K.N.; KOL09MA,N.Ye.; liESMANOV,A.S.
Research in the field of unsaturated-phosphinic acids. Report
no.7- Esters of (-~-phenoxyvinylphosvhinlc acid. Iz,,,.AN SSSR.
Otd.khim.nauk no.1:432-434 My-Je '55. (KLRA 8:9)
1. Inatitut elementoorranicheskikh soyedineniy Akademii nauk
SSSR.
(Phosphinic acid)

I
. I
I ~ -'

ANISIMOV, K.N.; KOLOBOVA, N.Ye.; NESMNYANOV, A.N.
Research in thm field of unsaturated phssphizic acids. Report zo.g.
Complete eaters of,,b-alkoxy(phe*wW)visylthisphosphisic acids.
Izv.AN SSSR.Otd.khim.xsuk xo.4:669-~671 JI-Ag 155- OM 9:1)
1.1istitut alemostoorgnichookikh seyedimeniy Akademii usuk SSSR.
(Phosphisic acids)

I
. . 1 0
t.
k
N .
. .
. --I ., i

ANISIMOV, K.N.;KOLOBCVA. N.Te; NISHMANOT, A.N.
--- - ---ftwlb~,~
Investigation into the unsaturated phosphinic acids. Part 11.
The complete astern of,.~ -alkoxyethozyvinylphosphinic acids.
Izv.AW SSSR.Otd.khim.n&uk no.3:827-833 S-0 155- (KIRA 9:1)
1.1natitut elementoorganicheakfth soyedinenty Akademii nauk
SSSR. (Phosphinic acid)

ANISINOT, K,N*; KOLOBOVA, N.Ye; NISKEYANOV, A.N.
Investigation into the unsaturated phoephinic acids. Part 12.
The totraalkyldiamides of-the ~-alkoxyethoxyvlnylphosphinic
acids, INT,AN 36BR,Otd&khlz*nauk ng*3:834-837 5-0 '53.
(MIRA 9:1)
'I.Institut elementoorganichookikh soyedineniy Akademii nank
(Phosphinic acid) (Amides) SSSR,

_VT,
IV,
VA-. %. A
_171
A-s
4 11 I~
e
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14
MORE,

71
---a 'AY
.7r h*,.-~'~
It
Z t FIN,
p I I I
wk -

ANISIMOV, KeN.; NESMEYANOV, Aefi.
Investigation into the derivatives of unsaturated phosphonic
acids. Part 14. The complete eaters of P -phenylvinyl phospho-
nie acids. Izv.AN SSSR Otd.khim.nauk 86 ne.6:1003-1005 M7 155.
l.Inatitut elemenloorganicheakikh soyedineni7 Akademii neuk
SSSR. (Phosphouic acid)

AHISIMOV, K.N.; MESKHYANOV, A.N.
- ~
Investigation Into the derivatives of unsaturatod phosphonin
acids. Part 15. Tho complete esters of 0, 01-phanylchlorovinyl
phosphanic and P-pharqlacety-lene phoaphanic acids. Izv.AN SSSR
Otd.khim.nauk 86 no.6:loo6-lon Mr 155. WaA 9:4)
l.Institut olementoorganichaskikh sayedinaniy Akademit nauk
SSSR. (Phosphonic acid)

-T-T"
tTn
Der. 51

ANISD(QV~ K.W.;KOLOWVA. N.Ts.
-- - * ~
Research in the field of uneaturqted phosphint& Acids. Part 2D.
Raters of (3-chloro-2-mothvlbutene-2)-4-phosphinte and (2-methyl~
butadione-20)-4-phosphinic Acids. Izv.AN SSSR. Otd.khim.nauk no.
8:927-931 Ag 156. (MM 01:10)
1. Institut elementoorl-,anicheakikh soyedineniV Akndemii nauk SSSR.
(Phosphinic acid)

ANISIMOV) K. N.; KOLOBOVAt N. Ye, (Inst, Elementary Organ. Compounds AS USSR)
"Research in the Field of Derivatives of Unsaturated Phosphinic Acids!' (Issledovaniye
v oblasti proizbodnykh nepredel*Vkh foofinovykh kislot)
CherliStry and uses of Oraanophosphorous CorTounds
"IaLL,jiya i primenenlye fosforor[;anichcsI:'L'kh s'-0j0dnc"Tiiy)I
k 8-10 Decenber 3955, Kaz",
Truly of First. ConfL,,.enc,, . As ussR, 1957
P lished by Kazan Affil
I -ab
Report discussed by A. N. PulLovik (Chem. Inst. im. Acad. A. Ye. Arbuzov, Kazan Aff. AS
USSR)$ G. V. Vinogradov (Inst. of Petroleum im. Acad. S. S. Nametkin AS USSR), B. A.
Arbuzov (Chem. Inst. im. Aced. A. Ye. Arbuzov, Kazan Aff. AS USSR)

TAROSH, A.Ta.: ANSIM079 K.N.; POLYAKOT, A&B.
~
Using gravitational prospeoting for studying deep pyrite layers.
Trudy Wer gor. inst. no'30155-63 '57. (MIR& 11:4)
(Ural ;~untains--F~rit;s) (Pro"oting-Goophysical methods)

SOV/78-3-11-1/23
AU72ORS: Volkov, V. L., Mikheyev, Ye. P., Anisimov, K. N., Yeliseyeva,
L. Ye., Valuyeva, Z. P.
TITLE: The Production of the Carbonyl Compounds of Molybdenum and
Tungsten (Polucheniye karbonilov molibdena i vollframa)
PERIODICAL: Zhurnal neorganicheskoy khimii, 1958, Vol 3, Nr 11, pp 2433-2436
(USSR)
ABSTRACT: In the present paper the authors investigated the reaction
velocity, the impurities, the time, as well as the temperature
and the pressure of the reaction gases, and the nature of the
solvents on the course of the synthesis and the yield of the
carbonyl compounds of molybdenum and tungsten. The synthesis
of molybdenum carbonyl lasted 2-3 hours, the synthesis of
tungsten carbonyl 1-1,5 hours. Tungsten carbonyl Is produced
with a yield of 81-85% at a reaction temperature of 32-670. The
production of the carbonyl compounds of tungsten and molybdenum
is usually carried out at 50 atmospheres absolute pressure.
Experiments were carried out to produce molybdenum carbonyl
under a pressure of 20-30 atmospheres excess CO-pressure. Zinc
Card 1/2 powder and aluminum powder were used as reducing agents. If

SOV/78-3-11-1/23
The. Production of the Carbonyl Compounds of Molybdenum and Tungsten
aluminum in uned an reducing agent, the yield of molybdenum
carbonyl amounts to 0,6% at 180C, 1,3% at 1000C, 9% at 1500C
and 100 atmospheres excess pressure. If iron powder is used
as reducing agent, the yield of molybdenum carbonyl amounts to
1,5% at 1000C. If zinc is used as reducing agent, the yield of
molybdenum carbonyl is not higher than 6,6%. Mainly zinc powder
is used as reducing agent for the production of tungsten carbonyl.
The yield amounts to 85%. It was shown that for the production
of carbonyl compounds ether in a quantity of not more than
2 g-mol to 1 g-mol metal chloride is necessary.
There are 2 tables and 3 references, 2 of which are Soviet.
SUBMITTED: October 2, 1957
Card 212

AUTHORS: Anisimov, K. N., Raysbaum, B. V. SOV/62-58-10-8/25
tITLE: Investiga:tion in the Field of the Derivatives
of Unsaturated Phosphinic Acids
(Issledovaniya v oblasti proizvodnykh nepredellnykh
foafinovykh kislot)
Communication 21: Esters and Amides of
~ -Isooctyl-oxy-V42~yl
Phosphinic Acid
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdoleniye khimicheskikh nauk,
1958, Nr 10, pp 1208-1211 (USSR) I
ABSTRACT: This paper is a part in the series of investigations of
phosphinic acids and their derivatives produced on the basis
of combination reactions of phosphorus pentachloride with
unsaturated compounds. Acid chloride of the 5 -isooctyl-oxy-
vinyl phosphinic acid was synthesized according to the method
described already earlier (Ref 1) by the action of PC15 on
vinyl-isooctyl ether. For synthesizing complete esters of the
0 -isooetyl-oxy-vinyl phosphinic acid by the interaction of
acid chloride with alcohols in benzene medium the method by
Milobendzki and SachwWaki (Ref 2) was employed. In the
Card 1/2 present paper the authors report on the synthesis of acid

Investigation in the Field of the Derivatives of SOY/62-56-10-6/25
Unsaturated Phosphinic Acids. Communication 21:
Eaters and Amides of 0 - Isooctyl-oxy-Vinyl Phosphinic Acid
chloride of the ~ -isooctyl-oxy-vinyl phosphinic acid, diethyl,
dipropylt dibutyl, diisobutyl, diisoamyl, dihexyl, diisooetyl,
dimethoxy-ethyl eater of the ~ -isooctyl-oxy-vinyl phosphinic
acid and tatramethyl diamide,tatraethyl diamide and piperidide
of the A -isoootyl-oxy-vinyl phosphinic acid. The synthesis of
tAtramethyl diamide, tetraethyl diamide and dipiperidide of the
-isoootyl-oxy-vinyl phosphinic acid was carried out according
to the method by Michaelis (Ref 3).There are I table and
4 references, 2 of which are Soviet.
ASSOCIATIONs Institut elementoorganicheakikh soyedineniy Akademii nauk SSSR
(Institute of Elementary OrSanic Compounds, Academy of
Sciencesp USSRI)
SUBMITTED: March 6, 1957
Card 2/2

liov/60-59-1-2q/44
11 U 'J' HO Papok, K.],';, Anisimuv, 11%I,., ",useva, 73.'J. ;-n-' Kolobova, 1'.Ye.
"f"ect of E~;tero of ~cijs or. ' e .!.nti-
c.~-A-A,-;tiwi ?rop~rtiec~ cf 'ireriil Cill ~%-IiYani,.-c r?firov reprc-
lellnykh fo3fl:~ovyl,', 'I-iolot svoystwa
o ra 11 n c., o la
7hurr.,~~l prikla,lro~ :.'r 1, pj: )bC-166 OSSP)
7 f C I'll 11:ior-u~, -')r- 11-d-C t! - 1-0, ortio!; lu-rl-
ut~ting oil.s. In t.'-V tl,~. authors describe the
ef.'ect of esters of unsatur:A4L~d .1-ic-sil.inous acills on the
antioxidizin~, troyerties of t-'-,c :-;C-21- L-.'xeral oi 1. Th e
C)ILIluatior of the-;e 1.roycrtici; ,i ,erformud by the four
n,etho as -. 1. thermc~: oxillivir-- volatilit:,Y,
3. txrkin6~ fr-action and 4. varnish for::~.-ttior, (GOST
and the results nere compi2ed irto t~.bles. Their analysis
leads to the follo-ainlir concluoions. 1. The antioxidizing
properties of uns-i-Aurated p~icrr'-irous acid esters are in.-
T rovcni ; it. -Ath the introl-:cAicn o,-' "lie phenyl ;~.-oup in
qictliyl, diallyl and ~Iihex~-I est,~rc; ',). -..ritl-, the prenc!rcc
cf tho indenyl group in dilethyl and diallyl o,,~tcrq; c. v:itil
an
increase In Cie len~~th of' tlic 1,,~-drocnrbon ra6ioal
~frcm C2 to C6) in diallyl and dihoxyl coters; 6. ait*h an
increase in the Ienkrth of the chain oft' the ester groupin.-
--A~cal (from C-.~ to C6) in e--ters of the -butoxivilly 1

ed Pho3i,'ji r:c,.::j Ar, i--7:- - r; t- t,- Antioxi,.; at ion ?r,)-
ID-Itiez of
/9-phenylvinyl,.~,,cspi;,*.!.~l"s
~,,,;cnF; titc., uu:q, 'and i i i-. tt ed i -
2.
of un:;at-urate.1 t",v
,AJ,..2-t antioxj~,izin:,-
-:1 r. Ic-re 5 t-bles al~d r~,FcrencQ:;, I o~` in Soviet
ar.:11 1 American.
J.~,TIOTI Institut olpmeni yedineniy AN SSSR (Insti-
oorganichauld1rh so
tute of Elemental Organic Comyou.,AL oi' the AS USSIZ)
J Z'; D t'l a y 21 5 7
Card 2/2

P
5(2) SOV/78-4-2-1/40
AUTHORS: Nesmeyanov, A. N., Anis-imr--v K. N., Mikheyev, Ye. P.,
Volkov, V. L., Valify~ea, i. P.
.paration af Tungsten Carbonyl by the Interacticn of
TITLE: ?Z,3'
Iron Pentacarbonyl With Tangster. Hexachloride (Polucheniye
karbonila vollframa vzaimodoy9"viyom pontakarbonil.a. zheleza
a shestikhloristym vollfrwaom)
PERIODICAL: Zhurnal neorganicheskoy khimii, '1959, Vol 4, Nr 2,
pp 249-252 (USSR)
ABSTRACT: The intera.-tion of tungsten-6-ch1oride with iron pentacarbonyl
in an ethyl other medium was investigated. The tests in the
autoolave overe carried out at the following molar ratios of
the individual oomponentu: WC1 6 : Fe(CO) 5 ' 1 : 2.25 and
1 : 3.25. The temperatures during the tr;,,%ts were: '10, 90, -.10;
130, 150, 170 and 1903. At the molar ratio Fe(CO) 5 , WC1 6
= 5.25 : 1 the yield of W (CO)6 increases with temperature;
it shows an increase of 29-31% at 200, of 36-42% at 700, and
Card 112 of 72-75% at 900. The ooxi~rse of the reaction is shown in the

SOV/78-4-2-1/40
Prepm,e4ion of Tungsten Carbcnyl by the Inte"ar;-ion of Izon Pentacarbonyl
With Tungsten Hexachloride
following ,quaticn: WCI 6 ':- 3Fc (CO) 3FcCl, 4 9CO.
5 -1" W (CO) 6 +
The supply of hydrogen tc the reaction mixture after, +he
conclusion of the reaction, ~.nireases the W(CO4 yipld to
85%. This react'-on _correeponds -to the following Pquiltion:
Wol 6 + 2Fe(CO)~, ~ H2-.9- W(CO)6 + 2Fo C12 + 2HL + 4CO.
The production of tungsten hexacarbony- is descr-i.bed i'r. dr-tail,,
'L
Results which are well reprodiicible are c~bta-_'ned by This
method. There are 2 tableg zLad 'I references, 3 of which are
Soyipt.
SUBMITTED: De,:;ember 9, 1957
Card 211,

5(2) SOV/78-4- -34
AUTHORS: Neameyanov, A. N., Mikheyev, Ye. P.
Volkov, V. L., Valuyeva, Z. P.
TITLE: The Synthesis of Molybdenum Carbonyl by Interaction Between
Iron Pentaoarbonyl and Molybdenum Pentachloride (Sintez
karbonila molibdena Vzaimodeystviyem pentakarbonila zheleza a
pyatikhloristym molibdenom)
PERIODICAL: Zhurnal neorganicheskoy khimii, 1959, Vol 4, Nr 3,
Pp 503-505 ('USSR)
ABSTRACT: It has been found that molybdenum hexacarbonyl is formed in a
maximum yield of 28-5~ by the interaction between iron penta-
carbonyl and molybdenum pentachloride in the presence of
hydrogen chloride under a carbon monoxide pressure in an ether
medium. Molybdenum hexacarbonyl is formed in a 15% yield at
1750 in the presence of compressed hydrogen in an ethyl ether
medium. Molybdenum carbonyl is formod in a yield of 23.4% at
1750 when the reaction is performed in an autoclave with
hydrogen (initial pressure 100 atmospheres) and carbon monoxide
(initial pressure 50 atmospheres). There are 2 tables and
Q-Wr~=tp 1 Soviet reference.

5(2) SOY/78-4-8-19/43
AUTHORS: Nesneyanov, A. N., AnisimovI.K.-N.., Yolkov, V. L.t
Fridenberg, A. E., MlMe-y-el, fee i., Medvedeva, A. V.
T12LE: The Synthesis of Chromium Hexacarbonyl by the Reaction of
Chromium Triahlorido With Lithium Aluminum Hydride and Carbon
Oxide Under Pressure (Sintez geksakarbonila khroma vzaimodeyst-
viyem trekhkhloristogo khroma 9 litiyalyuminiygidridom i
okislyu ugleroda pod davleniyem)
PERIODICAL: Zhurnal neorganicheskoy khimii, 1959, Vol 4, Nr 8, pp 1827-1828
(USSR)
ABSTRACT: If the reaction mentioned in the title is carried out at a
ratio of 1 mole CrCl-3 : 3 mole LiAlH4 in etheric solution at
650C and a pressure of 100 at, Cr (CO)6 is obtained in a 65%
yield. The hitherto published data (Refs 1-6) show lower
yields. A lower content of lithium aluminum hydride in the
reaction mixture and lower temperatures strongly reduce the
yields (Table 1). There are 1 table and 7 references, 3 of
which are Soviet.

5(g) SOV/78-4-9-3/44
AUTHORS: Nesmeyanov, A. N., Mikheyev, Ye. P., Anisimov, K. if.,
Filimonova, N. P. V-- ------------------~
TITLE: The Synthesis of the Chromium Hexacarbonyl With Participation
of Metallic Reducing Agents
PERIODICAL: Zhurnal neorgenicheekoy khimii, 1959, Vol 4, Nr 9,
pp 1958-1960 (USSR)
ABSTRACT: Reference is made to the studies on Cr (CO)6 described in
publications (Refs 1-5, 7, 8). The difficulty encountered
in synthesizing this substance lies in the high electrode
potential of chromium trichloride, as this makes the use
of strongly reducing metals necessary, which simultaneously
give side reactions with the solvent . The only comparatively
indifferent solvent was stated to be pyridine, which does
not react with the alkali metals and forms complex compounds
with Cr (CO)6' CrCl3 was dissolved in pyridine and reacted with
CO 8nder higher pressure after addition of zinc powder at
175 and yielded 10.8% Cr (CO)6 . The authors obtained a 35%
yield of the same substanoet by applying 50/1t excess magnesium
activated by a crystal of iodine. Without activatkon by iodine
Card 1/2 the yield sank to 4%, as the magnesium did not react. An

SOV/78-4-9-3/44
The Synthesis of the Chromium Hexacarbonyl With Participation of Metallic
Reducing Agents
increase in the CO pressure to 220 atm also passivated the
magnesium (only 1-7% yieli). Appreciable yields were obtained
with sodium (150%0 theoretical amount) at 20-25 .Raising the
temperature to 50 lowered the yield. Howevert a rise in
pressure to 220 atm increased the yield to 37%. The same yield
was obtained by using lithium instead at a pressure of only
70 atm, but a further rise in the CO pressure had no effect
on the yield. There are 9 references, 2 of which are Soviet.
SUBMITTED: May 28, 1958
Card 2/2

PAPOK. K.K.; ANISIHOV, R.N.; ZUSHVA, B.S.; KOLOBOVA, N-Ye.
Effect, of estera of unsaturated phosphinic acids on the
tuitioxidizing properties of mineral oil. Zhur.prikl.khim.
32 no.1:180-186 Ja 159. (MIRA 12:4)
1. Inatitut eleme ntoorganichaskikh soyedineniy AN SSSR-
(Mineral oils) (Phosphinic acid) (Oxidation)

' ;C - 3 2 -2 - 22/5 6
AUTHOPS: Papok, IX-K., Anisimov, K.N., Zuseva, B.S., Kolobova, N.Ye.
TITLE: Effect of Tetranlkyldiamidos and Dipiperidides of Unsaturated
Phosphine Acids on the Antioxidation Properties of 1.,inc~ral
Oil (Vliyaniye tetraalkildiamidov i diPiperididov nel-reLlell-
nykh fosfinovykh kislot na antiokislitel'nyye svoystva rinerall-
nogo nasla)
KRIODICAL: Zhurnal prikladnoy khimii, 1959, Vol XXXII, 11r 2,
PP 358-363 (USSR)
ABSTRACT: The effeat of diamides and (lipil,oridides of unoaturnted phoD-
phinic acids on the antioxidizing properties of the oil MS-20 is
investigated here. The dipiperidide radical in the compounds
increases their anticxidizinf; property. Phenyl and phenoxy
aroups increase the antioxidation properties only in tetraothyl-
diamides, but not in other comyounds. The lengthening of the
carbon radical in the group (l.,R2)2 from C to C reduces anti-
oxidution in tetraethyidiamidon and totVaLtyidlamides. Tetra-
Card 1/2 alkyldianidc-3 and piperidide3 of unsatur~-;ted phosi,hinic acids

SOV/eC-72-2-22/56
"ffect of Tetraalky1diamidQs and Dij4peridides of Unanturated Phosphine Acids
on the Antioxidation Properties of Mineral Oil
bave higher antioxidizing properties than the esters of unsatur-
ated phosphinic acids.
There are 4 tables and I Soviet reference.
ASSOCIATION: Institut clementoorganiclieskikh soyedineniy All SSSR (Institute
of Element-Organic Compounds of the USSR Academy of Sciences)
SUB11PIVED: May 23, IM
C-11rd 2/2

5(3)
Papok, K.K., Anisi..ov, K.11.,

'P'ITL-,: The Lffact of Thio-Cmiliounds of
on the Anti-Oxidation I~ropertios of I Oil .,niye
tiosoyedinvidy nepreciel Irjykh foz3fimc ':~j lot :,;:;Ii
c
t,1 I nyyc s,.,( ystva :7, ~ ti(-.rf.1 I no,,,(, vash,.
L'burnal ijrikladnoy k1da.;-J, Ic.,59, YA ::1-
u Cis, 2
ATISTRACT: ',"hc, efi-eci. ctler:- 01-

c u:, t h, i:~
C C,

homphinic a-vias ~,n ztnti,)xi,:CLtic!. t~'V 61 L
here. Tri c, u., i j t,

1:j

AVISIMOV, X.N. (Anisimov, K.H.]; FI=OVA, G.K. CIFederova, H.K.3
Rep?:tl.on of phosphorus pantachloride and vinylacetylone. Dop.AN
1". UP,:3-*,' no.9:1243-1230 )60o (MIRA 13110)
1. Inatitut organichaskay khimii AN USSR. Predstavleno akademikom
AN USSR A.I.Kiprianovym.
(Phosphorus chlorides) (Butenne)

1MZ!TSK;,YAv G.N.; SLOVQ.*LIiOTOVA, P.A.
,,-Y, a. ;
Unsaturated phosphonic acids. I-Report Fo. 22: dd--'.ion of
phosphorus pentachloride to isopropanylace-l,yIene. Izv. Ali
SSSR. Otd. khim.n-u!z no. 1:64~-71 Ja 161. ('11i'lul 14:2)
1. Institut Olenentoorganichoskikh, soyedinaniy Z SSS"3 i
Fizikokhimicheskiy institut im. L.Ya. Karpova.
(13utenyne) (Phosphorus chloride)

S/062/61/000/001/006/016
B100220
AUTHORS: Slovokhotova, N. A., Kc N,, Kunitakaya, 0. It.,
and Kolobova, N, Ye.
TITLE: Infra-red spectra of some deriiatives of unsaturated
phosphinic acids
PERIODICAL: Izvestiya Akademii nauk SSSR, Otdeleniye khimicheskikh nauk,
no. 1, 1961, 71-76
TEXT: The pxpose of the present paper was to verify the structural
formulas of various previously (Ref.l)syntheslzed derivatives of unsaturat-
ed phosphinic acids based on their infra-red spectra, as well as to study
the mutual influence of atoms and groups Inaide their molecules. The
spectra were taken by means of a Hilger A -209 (D-209) infra-red spectro-
meter. A table indicates those absorption bands from which conclusions
were drawn as to thestructure of the analyzed substances, In detail, the
following has been found: The chlorine atom bound to the C-atom neigh-
boring the C-C bond (aster 11) increases the frequency of stretching
vibrations of the C-C bond. The absorption bands 870-910 em"i correspond-
Card 1/4

Infra-red spectra of some derivatives... S/062/61/000/001/006/016
B100220
ing to deformation vibrations of the CH group at the C-C bond confirm the
existence of vinyl groups in IV and of vinylidene groups in I, II, III.
The shift of these bands in II is also attributed to the neighboring
chlorine atom. In relation to IV where the phosphorus group is not
conjugated with the C-0 group, frequency in V is reduced by 40 cm-1. Since,
however, the P-0 group, due to its different configuration, cannot be
located in the same plane as the C-C group, this effect is attributed to
the phosphorus atom. In the esters VII to IX, a similarity with the
spectra of pentadiene and isoprene was found in the range
1
1640-1585 cm- , which is attributed to the corresponding bands of
symmetrical and antisymmetrical vibrations of the conjugate double bonds.
The band shift is attributed to the neighboring phosphorus1atom. All
compounds show intensive bands in the range 1250-1270 cm I these bands
correspond to the P-Obond,andinthe case of acid chlorides, they are shifted
by 20 cm-1 toward higher frequencies, owing to thT action of the chlorine
atoms. The intensive doublet bands 1060-1000 cm-' are attributed to
vibrations of the O-C bond in the P-0-C groups. There are 3 figures,
1 table, and 10 references: 3 Soviet-bloc and 8 non.-Soviet-bloc.
Card 214 -~

Infra-red spectra of some derivatives... S106 611000100110061016
B101Y3220
ASSOCIATION: Fiziko-khimicheakiy institut im. L. Ya. Karpova
(Physicochemioal Institute imeni L. Ya. Karpov).
Institut elementoorganicheskikh soyedineniy ~kademii nauk
SSSR (Institute of Elemental-organic Compounds,Academy
of Sciences 'USSR)
SUBMITTED: July 23, 1955
Card 3/413

gk-)?
3/062/6ljOOO/OD2/OO5/01-2-'
22()~, B115/11207
AUTHORS: Anisimov, K. N. and Kunitakaya, G. M.
TLTLE: Study of unsaturated phosphonic acids. Report no. 23.
Addition of phosphorus pentachlorideto ethynyl
oyclohexene-1
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh
naukl,noo 2t 1961, 274-277
TEXT: In continuation of their studies of unsaturated phosphonic acids,
the authors describe the addition of phosphorus pentachloride to ethynyl
cyclohexene-1:
C=CH ===,---CCI=CIIPCI, - PCI, -
+ PCI, PC-I.
SO. ~\M=CVIPOCI,
Card

89909
S/062/61/000/00W005/671',
Study of unsaturated phosphonic ... B115/3207
The acid chloride obtained reacts readily with alcohols:
-CHPOCI,
+ ROH + --C,YI,Nl
CD
N . \ CC1=C1-1PO(OR),
C/ -' 2CsHiN - FICI
In accordance with this reaction, the authors separated ethyl- and
n-propyl esters of P,pl-cyclohexenyl chloro vinyl phosphonic acid
(CCVP). The table shows the constants of the compounds obtained.
The infrared spectra of the acid chloride and the esters of (CCVP)
facilitated the study of the structure of these substances. In the
range of the stretching vibrations of the C-C bond, two bands appear
in the spectrum of these compounds: 1625, 1620 cm-1 and 1570, 1558 cm-1f
which confirms the existence of double bonds in the molecules of the
.conjugate system. The absorption bands 1275, 126 0 cm-1 are stretching
Card 2/,5r-~

89909
Study of unsaturated phosphonic ...
sA62/61/000/002/00-5/01-2
B115/B207
vibrations of the P-0 bond (according to A. Yo. Arbuzov, 111. 1. Batuyev,
- S. Vinogradovv., Do'-l. Ali' &33'11 54, 60-~ (1946)). in conclut-iont
and V r~ I
the authors summarize a:s follows: 1) The acid chloride of (CCVP) was
obtained. 2) Dicthyl- and di-n-propyl c2ter,,', of (CCVP) -.xre
synthesized. 3) The structure of the -.ubstancco obtained was studied
by means of infrared spectroscopy. There are 2 fijare3, 1 table, and
6 references: 3 Soviet-bloc and 2 non-Soviet-bloc.
ASSOCIATION: Institut elementoorganicheskikh soyed,-neniy Akademii nauk
SSSR (Institute of Elemental-organic Compounds of the
Academy of Sciences USSR)
SUB1.11ITTED: July 23, 1959
Card 3/4
3

8 9 "~ ".!~
S10621611000100210061012
2 2 OC3, 12.A 71 B115/B207
AUTHORS: Anisimov# K. N. and Kopylova, B. V.
TITLE: Studies in the field of unsaturated phosphonic acid
derivatives. Report no. 24. Interaction of phosphorus
pentachloride with alkoxy acetylenes
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh
nauk, no. 2, 1961, 277-280
TEXT: In the present paper, the authors report on the addition of
phosphorus pentachloride to 5-phenoxy pentyne-1 and 5-ethoxy pentyne-1.
After having treated the addition products with sulfur dioxide, the
authors obtained the aoid chloride of 2-chloro-5-phenoxy pentene-1-
phosphonic acid (I), and of 2-chloro-5-ethoxy pentene-1-phosphonic
acid (11), respectively - f - S02
RO(CH2'5C = CH + 2PCl+PC16 ----* RO(CH2)3 CCI - CHPC1 PC16 0
4 3
RO(CH2)3 CC1 - CHPOC12 -t POC13 + SOC12- Dimethyl-, diethyl-, and
Card 1/3

69M
S/062/61/000/002/006/012
Studies in the field of unsaturated ... B115/B207
dibutyl esters were obtained from (1) by the usual method. By
hydrolyzing the acid chloride, the corresponding acid was obtained.
From (II), the authors obtained the diethyl eater (boiling point
'158-16orC at 3 mm Hg). V. N. Smorchkov recorded infrared spectra of
diethyl.- and dibutyl esters of 2-chloro-5-phenoxy pentene-l-phosphonic
acid in I. V. Obreimov's laboratory. An absorption band in the range
i6eo-1620 cm- is characteristic of compounds containing an isolated
double bond., In the case of C6H5O(CH 2) 3CC1 - CHFO(OR)2' the
absorption band lies in the region of 1580 cm-". This shift is
explained by the action of the chlorine atom at the double bond. The
absorption band in the range 1250-1300 Om'_Iis characteristic of the
P - 0 group; it also holds for the two cases investigated. (I) 'q a
white, crystalline, extremely hygroscopic substance readily solublo in
benzene, less readily in petroleum ether, and inHoluble in sulfur
ether. 2-Chloro-5-phenexy pentene-I phosphonic acid (III) is a
silvery-white, crystalline subst%n~-,e poorly soluble in water and
Card 2/3

89910
S/062/61/000/002/006/012
Studies in the field of unsaturated ... B115/B207
easily in alcohol. The eaters of this acid are thick, yellowish liquids
soluble in organic solvents. Under the action of a calculated amount
of KOH alcohol solution upon the dimethyl and diethyl ester of (III),
corresponding esters of 5-phenoxy pentyne-1-phosphonic acid were obtained
C H O(CH ~ CHPO(OR KOH C H O(CH -
6 5 2)3CCl )2 C 2H5OH 6 5 2)3C==CPO(OR)2'
The authors failed to obtain these esters by interaction of (1) with
alcohol and a calculated amount of triethylamine. The corresponding
esters of (III) were thus obtained. Papers by M. F. Shostakovskiy and
L. I. Antsus are mentioned. There are 2 figures, 2 tables, and 5 refer-
ences; 4 Soviet-bloc and 1 non-Soviet-bloc.
ASSOCIATION: Institut elementoorganicheskikh soyedineniy Akademii
nauk SSSR (Institute of Elemental-organic Compounds of
the Academy of Sciences USSR)
SUBMITTED: August 4, 1959
Card 3/3

YW4.5 / m 6 Vk Al.
NESMEYANOV, A.N.; ANI~~, K.Nt;.-VALUYEVA, Z.P.
Preparation of ethyloyclopentadienyltricarbonylmanganese.
Izv.AN SSSR.Otd.khim.nauk no.10:1780-1783 0 61. (MIRA 14:10)
1. Institut elementoorganicheskikh soyedineniy AN SS"FR.
(Manganese)

ANISIMVI K.N.; KOLOBOVAp N.Ye.
Chlorides of unsaturated ncids. Izv.AN SSSR.Otd.khim.nauk
no.3:442-"3 Mr 162. (MA 15:3)
1. Institut elementoorganicheskikh aoyedineniy AN SSSR.
(Phosphinous chloride)