SCIENTIFIC ABSTRACT ARBUZOV, A. Y. - ARBUZOV, A. Y.

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• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

:~,issk/chemistry Organ6phosphorus .21
May 5 2
Compounds
Vsome Complex Compounds of Complete
Phosphorous
Acid Efters; With Copper, Silver and Gold
Salts,"
Acad A. Ye. Arbuzo'v, V. M. Zoroastrovi,
Sci Res
Chem.Inst imeni A. M. Butlerov, Kazan
State U imeni
V. I.'Lenin
"Dok Ak Nauk SSSR" Vol IXKXIV, No 3, PP
503-506
A. Ye. Arbu'zov indicated that the
reaction of com-
plete esters of phosphorous acid with
cuprous salts
resulted in'complex compds like CuX-P(OR)
and
CuX-2P(OR)3- These same esters also reald
with
225T1
silver halide, producing complex compds
like
AgX-P(OR)3- CuX-P(OR)3 and similar
complex compds,,
were found Iwo have a triple,mol wt. On
the other
hand, the mol wts of compds
3.ike*CuX-2P(OR)3 were
not detd. The complex compds, however,
resulting
from the reaction of phosphorous acid
esters with
silver halide also produced a triple mol.
Finally$
the. action of triphenylphosphite on
AuCl-PC13
brought forth the complex comPd,
(C6H50)3P-AtLC1'
225T1
10

,ARBUZOY. A.Ye., akademilc; KAZANSKIY, B.A., akademik; PBTROV, A.D.,
chlon-korrespon-
'"~Vrrf'~"WSSSH; NIKITIN, N.I., chlon-korrespondent AN SSSR;
FIGUROVSKIT, N.A.,
piofessor, otvatstvennyy redaktor: POGODIN, B.A., professor;
ZVTAGINMV,
O.Ye., professor; YZV7MVA,P.X., uchenyy askratarl.
[Materials on the history of Soviet chemistry; reports given at the
2nd
All-Union Conference on the History of Soviet Chemistry, 21-26 April
19511
Katerialy po istorli otachostyannoi khimii; abornik dokladov n&
Ttorom
Voesoiusnom soveshchanii po istorii otechestyennoi khimii, 21-26
aprelia
1951 g. Moskva, Isd-vo Akademii nauk SSSR, 19$3. 318 p. (KLRA- 7:4)
(Chemistry-;-History)

.ARBUZOV, A.YW. VALITOVA, F.G.
Studying the phosphorus containing products of the reaction
producing
free radicals by the method of A.E.Arbuzov, and B.A.Arbuzov.
Soob.o
naach.rab.chl.VIKHO no.2,21 153. (MIRA 10:10)
(Phosphorus) (Radicals (Chemistry))

. ! , - i

v v- i r I V 1. 4b:Z
7?+,0 bW. AV Ir s D'3' r.
4~C-'

PMROV, A.A.; -A-31-1 akademdk. PORrIR'YSVA, TU.I.
Order of addition of alkylhypobalogenides to vinylacetylene homologa.
Dokl.AN SSSR 90 no-4:561-564 je 153. (MLEA 60)
I* Akademiya Nauk SSSR (for Arbuzov). (Ralogenides) (Vinylacetylene)

-- -
-,KWVIK,--A.N.-;---IEBEDIVAi-N~M-.-;-ARBLTZOVI-A:.-Ye.,-akaddt
ik-.---- -- -
Reaction of addition and condensation of phosphonoacetone and
phosphono-
acetic ester. Dokl.AN SSSR 90 no.5:799-802 Je '53. (KY-RA 6:5)
1. Khimicheakiy Inatitut im. A.Ye. Arbuzova Kazanskogo
filiala Akademii
nauk SSSR (for Padovik, Lebadeva). 2. Akademiya nauk SSSR
(for Arbuzov).
(Phosphonium compounds)

BARDYSBEV, I.I.; ARBUZOV, A.Ye., akademik.
Properties of sylvestrene. Dok-1. AN SSSR 90
no.6:1035-1037 Je '53.
(KIX& 6:6)
1. Tsentrallnyv nauchno-issledovateltakiy le8okhimicheakiy
institut (for
Bardyshev). 2. Akademlya nauk SSSR (for Arbuzov).
(Sylvestrene)

RMMOV, A.I.-, HUMMVA, 0,A,.;,,ARMOVf,,A.Ye.. akademik.
Simplest asters of the diethylphosphinic acid. Dokl. AN SSSR
91 no.2.-2n-
272 JI 153. (MLHA 6:6)
1. Kazanskiy khimiko-tekhnologicheskiy institut im.
S.M.Kirovas 2. Akedemiya
nauk SSSR (for Arbuzov). (Vetere) (Phoophinic acids)

XAMAY. MOM.; XMTINI IA. ARBUZOV. k.Te.. akademik.
Reaction of the interaction of neutral and acid asters
of4hosphorus
acid, with eaters of halide substituted aliphatic acids.
Dokl.AN SM
91 no.4,.837-839 Ag *53- (M~A 628)
1. Akademi7a nuak GMR (for Arbuzov). 2.
Irazansi"imiko-tekbuologi-,
cheBk-ly institut im. S.K.Kirova (for Xamy and Mikhtin).
(Natera) (Phosphorus organic compounds)

ABRAMOV, V.; VAR G.; ARBUZOV, A.Ye., akademik.
Mechanism of the Arbuzov rearrangement. Dokl.AN WSR 91
no-5:1095-1098 Ag
153, (KLHA 6:8)
1. Akademiya nauk SSSR (for Arbuzov). 2. Kavauskiy
khimiko-tekhnologiche-
skiy institut im. S..M.Kirova. (Isomerism) (Esters)

-5.39 '2 C
, p -'j'?

kPAV),P.' I CH, CH Afc,. Gh, I N

Phop(om')"

. 21'
.d:,-7 /9. 1 1:11;7
!21
1.5
6M) 11,
.19m/ "'0'. bt ~I rx,, wtTt, 31h)"t-d
t"
-ct It th,
-hd- A

Iq rfthiz- thr i-mmimt6ii rat, 11, sume 3(~ 40 fold;
.1 at, f~drr'l 6' V-
J0.1 k;:w'.g .1. h'!!:!,- 'IuJim Plfi~'11!1
fa 16

I ~t h- i-s; -Juctwn pffuxi Th,
or, th, arr If
ki
h4 h ,;f
M n-T .-
-in., and in 315 mui~; .1th pho-
phonate added it was 2Z-_ cu;np)rtc in 19 nin. in 71
non., 75% in 110 inin , anti liP, , ' in 2W inni- -11, i~ !,
-olt phoilphointic taddrid thr frarit-1; ~., ~~:" , --pirt~ in
" I =i,,, -r-056 in fr rain-o 767W in W? min , ,and 100% is)
23D
min.: vrith I ustole phosphorsate the reaction VMS vi ~M corn-
plac in 32min., 50501109 min., 75% In 105 min., and IW/
niteiraflon of the re-jetion medium can
\be ii;W.etive factor. G. M. KOSDInpuff-

KARAY, Gillm; KHISHATULLINA. L.; ARBUZOV, A.Ye., akademik.
Separation of asymmetric tetracovalent phosphonium compounds into
optically
active components. Dokl.AN SSSR 92 no.1;69-71 S '53. (MLRA 6:8)
1. Akademiya rauk SSSR (for Arbuzov). 2. Khimicheskiy institut im.
A.Ye.
Arbusova Kazanskogo filiala Akademii nauk SSSR (for lAmay and
Khiamatullina).
(Phosphonium. compounds)

YURZHMO, T.I., FWHIN, V.A.; GRIGOROYEVA, I.S.; ARBUZOV. A.M.,
akademik.
Peculiarities of the initiating action of tertiary hydrogen
peroxides during
emulsion polymerization. Dokl.AN SSSR 92 no.1:97-100 S 153.
(MLEtA 6:8)
1. A,kademiya nauk SSSR (for Arbuzov). 2. Llvovskiy
politekhnicheskiy insti-
tut (for Turzbenko, Pitchin and Grigorlyeva).
(Polymer& and polymerization) (Peroxides)

PUDOVIK, A.N.; ARBUZOV, A.Ye., akademik.
Synthesis of amino phosphinic and amino thiophosphinic
esters. Dokl.Aff SSSR
92 no.4:773-776 0 153- NT;RA 6:9)
1. Akademiya nauk SSSR (for Arbuzov). 2. KhImicheskiy
institut im. A.Te.Arbu-
zova Kazanskogo filiala Akademii nauk SSSR (for Padovik).
(39ters) (Aminophosphinic acid)

ARBUZOV, 1-ye., laureat Stalinckoy premii.
EiL.M.Butlerov,lgreat Russian chenist] A.M.Butleroy -
velikii
rueskii khtmik. Moo)rm, Izd-vo "Znante.0 1954. 36 P.
(Voesoiuz-
nbe obohcheotv~ po rasprostrananiiu politichaskikh i
nsuchnyk-h
manil. Ser. 3 no-5) (MLRA 7:5)
(Butleroy. Aleksandr Mikhailovich, 1828-1886)

otyetetvennyy redaktor; SIMIYXNXO, S.R., professor,
otvetstienny7 redaktor; IOKTXT, S.M., redaktor; SIKKnU, Ye.j.,
tekh1hichaskly redaktor.
(Academician Sergei Vasillevich lebedev; for hie
eightieth'birthdayl
Akademik SergeiJasillevich lebadev; k voelmidesiatiletHu so dnia
rozhdaniia. Moskva, Is&-vo Akademii usuk SSSR, 1954. 263 p.(KLRA
7:11)
1. Akademlya nauk SSSR.
(Lebedev. Sergei Vasillevich, 1874-1934)

-Wo/~-Chemistry-
----l-'-Isomerization-:7
-Card:

Autb~re
Arbitzov A,
',E*1:1: and liester6v, L. iv._

..Title
Sizdl and stme ture
of:~radicals and their effect on the rate of' isomeriza_:

tio6 of.
phosphorous acid - esters,
Perlodicaa

AN SSSR uk. 3., 427 435~ ~by June, 1954
z N~
-Abstra t
Datai are presented:
regardihg the rate of isomerization of new mixed phos-

phorous acid
esters - (phosphites) the addition of alkyl iodides to

triphenyl
phosphitel:,th6rmal decomposition of addition.*pn~dudts and the

rate,
of all mentionadtonversions. It was established that the products.

obtained from phosphite-isoirierization actually accelerate the is
riza-
ome

tion process,thals chabging the isomerization reaction into
anauto-

catalytic reaction' The effect of size and structure of
radicals on the-

ra-telof isomerization is,explained. Eleven
references: 5 USSRJR 2 USA)

1 Oernan 2 Polish$ I.-French, Tables.
Institation
The S. M.~Kiroir Chem-Technological Institute Kazan
Submitted
June19,,1953

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-- "K~, -11 g
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A -HE"R k a
1. RR
ROOM -~ MI-Imi mllw I., ~
Iffiffill,

BLUDOROV, A.P.; KIRSAWOV. N.Y.; DISTANOV, U.G.; TUZOVA, L.S.; OT A T
LOF 4 1
akademik, redaktor,: HIROPOLISKIT, L.M., redaktor; SHA PANX.Y.
redaktor; PAVLOVSKIY, A.A#, takhnicheakiy redaktor.
[Tertiary coal-bearinx deposits of the central And southern regions
of Bashkiria) Tratichnve vglenoonys otlozheniia-teentrallnykh i
iuzhnykh
rmionov Bashkirii. MoskvmL, Izd-vo Akademii nauk SSSR, 1956, 138 P.
(Akadeniia nauk SSSR. XR2anskil filial, Kazan. Geologicheskii
insitut.
Trudy. no-3) (M1RA 9:10)
(Bashkiria-Coal geology)

i,
luik
OEM w! mg mm,

A P90--IC" 2.4,
F2,7L 00 S"B cx)DE.
soy 00

- . 7 ""'' ~~' '' ~ --
611,2!z-,~ :C, 4~ - 4 .

AAMT A To akademik.
IjAftzuz- ull"?=,- ~
A.M.Butlerov, the groat Rassian chemist; e& the 70th
amiversarv of
his death. Khim.*&Wm i prom. 1 ne.3:-345-351 156. ()MA
9: 9)
(BWorov, AlekvaRdr Mikhailevich, 1828-1W)

- -
Properties and ReactiOns of Alkyl and Aryl Propylene
Phosphites.
Comunication 1. Addition Reactidns. -
Iz. Ak Nauk, S M . Otdol) Xhim
Nauk, No. 2, 1956, pp 179
Translation 564938c

12=70V ~-~ RAZUMDVA, N.A.
Proportion and conversions of proprleneglycolphosphorgue acid
asters.
Part 1. Addition reactions. Isv.AN SSSR Otd. khimo nauk no.2:187-192
1 156. (MI-RA 9:7)
l.Kax4askly khimike-takhnologicheakiy institut imeni S.M.Kirova.
(Phosphorous acid)

-7
L L
USSR/'Organic Chemistry - Synthetic organic chemistry E-2
Abs Jour Referat Zhur - Khimiya, No 4, 1957, 11795
Author Arbuzov A.Ye., Valitova F.G.
Inst '~e~~
rtment of Chemical Sciences, Academy of Sciences USSR
Title On Pyrocatechol Esters of Pyrophosphorous Acid
Orig Pub Izv.. AN SSSR, Otd. khim. n., 1956, No 6, 681-683
Abstract On reaction of pyrocatechol chlorophosphite C6H402 PC1
(I). or C6H402PBr
with (C2H50)2PONa (II) there are obtained the pyrophosphites
C64402pop-
C (III) and (C CuBr and CuI III forms
0 2H5)2 6H402P)20 (IV)' With CuCl,
(
resins while IV yields solid addition products.vhich could
not.be puri-
fied. From (C~H50)2 PSONa and I was obtained C6H402POPS (OC2H5)2
M.
To II (from 27 g.-(.C2H 0)2POH and 4.1 g Na in 250 ml ether) are
added
5
32 g I and the mixture is heated for 1 hour, yield of 111 13-79%,
Card 1/2

TJSSR/ Organic Chemistry - Synthetic organic chemistry E-2
Abs Jour Referat Zhur - Khimiya, No 4, 1957) 11795
BP 115-1160/1 mm, n2OD 1.4800, d201.1816. Yield of IV 14.8%,
BP 170-
4
20~
1720/1 Mm, n20D 1.5502, d4 1.3107. On saponification of IV at
1W0
is obtained,pyrocatechol (VI). On heating 1 g III and 1.17 9
(C6H
5
CBr (170-1750) and saponification with HU acid there are
obtained
PO and VI. Yield of V (in benzene) lo.6%, BP 145-
(C05)31C (0H)2 1
1470/ mm, n20 D 1.52219 d20 1 2846.
4
Card 2/2

.-, e_-,- ::~ . . 1. ~ - - - !I - I . I : . I
I - ~ ` 7 -4 . ~ - ~~7 ., -- ~ I ..- . 1, : : 1 - . ,
-- -Y - z 1. .

-,ABI~UZ.O.Vv...,As*lo.ppakademik, otvatetvannyy redaktor;
KATRENKO, D.A., rodaktor
izdatelletva; IUZAH, N.I., takhaichaskiy redektor
[The chemistry and us e of phosphorus organic compounds;
proceedings
of the first conference) Khimiia i primenenis
foafororganApheekikh
soadinsaii; trudy-pervoy konferentsii, 8-10 dekabria 1955 9.
Moskva, 1957. 526 P. (HIMA 10:3)
1. Ak-demiya nauk SSSR. Kazanskiy filial.
(Phosphorus organic compounds)

I~z , - -
, S~r
, 'I
A a . E .
I-RIFIT-210V f
I
! I

-md

-ARBUZOV,----A. fi;~~ lyl -' ',- r7 "'
"In One Day the Future has Become the Present," The Soviet
Artificial Earth
Satellite, 1957 , P. 3(!),

FIGUROVSKIY, Nikolay Aleksandrovich; SOIA)VIYXV, Yurty
Iva novi ch;,4RAQQZ..,
A-Ye. akademik, otvatetvannyy red.; TSURY.BMN, A.M.,
red. izd-va;
I:=
--TWINA, U.N., tekhn.red.
Ellikolai Nikoleevich 2juin; a biography] Nikolai
Nikolaevich Zints;
biografiebaskii ocherk. *Koskva, Izd-vo Akmd.nauk SSSR,
1957. 215-P.
(HIBA 11:2)
(Zinin, likolai Niko.1sevich, 1812-1880)

.- -, - W,
I ~ I
- - -111- ~?~ - , I -- - .-- -. -- - -'I-- --
. -- r I -

W-w-- "m

/'A
LANDSBERG, G.S., [deceased]. almdemik; L7KBYMV,'A.A., ak-Rdemik;
RCUKI, VASKO
[Ronchl, Vqscol- ARIBUZOV A.Ya.; TOLSTOY, N.A.; VIFTM, A.V.,
akademik;
BARDIN , I.P., 4~
Recollections about Sergei Ivanovich V,,vilov. Trudy Inst.ist.
est.i tekh. 17:137-153 '57. (MM 10:7)
1. Direktor Natsionalinogo optinhaqkogo inatituta, Archetri
(Florentsiya) (for Ronki).
(Vavil0v, Sergei Ivanovich, 1891-1951)

of PlIN
MIX
D! str. 4E4 4F,2 c

React of transbvdwouttim c
Yu- Icy
_k; M,
s tr
E ~ In. Ove CM cuci~
C-Nfe'. rr, 2.~---; ~' Rtfluxing - ,-- - -I,: , 4 1 -.11H -
bc, mi Acuil V.1 hr pi,c ii_ei
c-ling. 4r,( dilil

Yu 1, -,r-
5-7
dh6ssed ~~Rt jeulth with ;3umeMU3 relemnets.
al PhIN
Tk-
2,s,
0 piwrvem
N

ARBUZOV, A.Ye.; KITAYEV, Tu.P.
z
Synthesis of heterocyclic compounds on the basis of E. Fischer's
reaction. Part 2: Abnormal course of E. Fischer's reaction. Zhur.
ob. khim. 27 no.9:2341-2354 S '57. (MIRA 11:3)
l.Kazanskiy khimiko-tekhnologicheskiy institut.
(Chemical reaction-Mechanism)

ARBMOV, A.Ye.; VALITOVA. F.G.
0-`-1. 1 ~
Obtaining the free radical
dlicy--diphenyl-~l-trinitrophenvlhydraz3rl.
Zh'ur, ob. khim. 27 no,9:2354-2356 S 157. (MIRA 11:3)
- l.Khimicheskiy institut Kazanskogo filiale. AN SSSR.
(Hydrasyl) (Chemistry, Organic-47nthesis)

qw,

~ 3 f j'j D C. 921 X P I -~~
MHIW~n Mal III, ti vcry'~'nkple-x ~11~
n-t 10 '~cler t~~r "X,
i'yc only 1

si
-Y~ '41

pr

o,rupanird hy f-h-

4-C

71
ni I",
J-uH. L's W-4 1 iL~ iv, v
ir~, kj*Ft)grju(;)rujj.
t~,
1.4210, 0 Q-;LM

AUTHOR AKBUZOV A.Ye.,Member of-the Academy, KITAYzV xu..?. FA -
31146
TITLE Arolarographic Study of the Tautomerism And Geometrical
Isomerism of
Some Ary1hydrazones.
(Izucheniye tautomerii i Zroometrich"koy i%omerii nekotorykh
arilgidra-
tonov polyarograficheakim-metodom. Zussiati)
P&lOD1CAL Doklady Akademii.Mauk SSSR,, 1~57, Vol 123, Nr 3, pp 577
-58o (U-S,b-R-)
Received 6/1957 Reviewed 7/1957
ABSTRACT As it, is kno wn that tautomeric forms and stereoisomers
regtinerate at di.C-
ltzrcint, potentials on a mercury.!.drop electrode, the
polarographic method.
was chosen in the present case, by means of which the
modifications taking
place on the occasion of the dissolution of ary1hydrazones in
alcohol we-
re controlled.Polarograms were recorded during storave in the dark
of the
methanol solutions of phenyl hydrazones of acetone, of methyl.
ethyl ketone,
of methyl iaopropylketone, of cyclohexanon, of acetop6non, of n-
cholri-'
ne acetophenon, of vinegar- and benzone aldehydes. A borate buffer
with
PH'~ 7.2 was used. The concentration of the solutions investigated
was.
0 - 1,2.1o-A mol. There follows the descriptio" of the deiphering
of
the polarograma. By means of polarography it was found that the
forms of the
pnenylhydrasone of acetaldehyde are not stereoisomers but
tautomers..Tho
substance with the melting point at 570 which is obtained by th5
int4wao-
tion of the component in ether in the cold or from the second form
by treat-
ment with a SOR alcohol solution is an antilsomer-phenylhydrazone,
whilst
the suostance with the meliing point at 98 - loll' was found to be
a 2-phenyl-
Card 1/2 hydrazone ethylene. besides, two isomers of
phenylhydrazone neb%oe+a1dehyde

AUTHOR:
ARBUZOV,Atff"_Member of the Academy of Science, FA - 2742

X1, V'YU.P.
TITLE:
On the Mechanism and Abnormal Course of
E.FISCHERIS Reaction.

(0 mekhanizme reaktaii E.Fishera i
anormallnom protekanii t,Russian)
O

PERIODICAL:
.S.S.R.)
uk SSSR, 1957, Vol 113, Nr )+, pp 7-8io
Doklady Akadendi Na 80 M

Received: 6 / 1957 Reviewed: 7/ 1957
ABSTRACT:
The authors showed previously that the ary1hydrazones
may exist in the

three tautomeric forms. The polargraphic
activity of all three forms

proves the existence of conjunctions
of bindings in their molecules.

This paper is intended to ahovr
the nature of the intermediary effect

of bindings in the
enbydrazine form. The moleaules of these oompounds

contaLn two
double bindings which are separated by nitrogen atoms, i.e.

there
exist two groups with Ap-cowJugations in each of them. In so

far
as ary1hydrazone compounds are of a basic nature, their state is
con-

siaerably influenced by the add medium. Thus, hyarazine of
the one

group may bring about a 1,4 connection of an acid
according to a

it d -conjugated system. By this a more basic
hydrazine is produced,

vdiich becomes an anion. In this
connection the effect produced by

catalyzers in FISCHER' 40
reaction becomes understandable. They shift

-the tautomerlo
equilibvium in the direction of enhydrazine and aoti-

vate the
bindings. The most characteristic -feature of I o4-conjugated

systems is their ability of entering into reactions of the Dien
Card 1/2

-L-1:z Ci \;14-T ~T k~: ,
AUTHORS: Arbuzov) A. AcadaticiM. 2o-6-18
Pq /48
wd-S-azonova, N. N.
TITLE; The Int*raction of the Intermediate Products-of Arbuzov's
Rearrangement with Amines (Vzaimod%s;tviye.promezhutochnykh
produktov arbuzovskoy peregruppirovki s aminami).
PERIODICAL: Doklady AN SSSRp 1957, Voks 115, Nr 6, pp. 1119-1121
(USSR).
ABSTRACT: In 1905 thefirst author discovered a rearrangement which
later on
was given the name "Arbuzov's rearrangement". Its general scheme is
given. The,intirmediae complexes of phosphites behave differently
according.to the fact whether they contain an aliphatic or an aroma-
tic radical. In the case of aliphatic radicals the complex is unstabs
1e; In the caaeof aromatic radicals) however) the complex can be
isolated in an ana%vtically pus formo The above-mentioned intermew
diate productor are substances-capable of reaction. They show an enere
g4ic, interaction.with water and various alcohols. A reaction scheme
of the intermediate complexes with alcohols (according to Landauer
and Ridon) is,give. As far as the first phase-of this reaction, sea
cording.to a3aLPrQbabijjty.L takes plaee at the expense of the active
hydrogen of the alcoholL., a similar reaction might be expected with
Card 113 other substances containing active hydrogen, Instead of
alcohol.the
_WWAZW~Uuvu V-W V42M
Card 2/) in product no* I is-connected with phosphorus. Iodine is
here prew

20-6-18/4! ,
The Interaction of the Intermediate Products of Arbuzov's
Rearrangement with
Aminese
sent as ion. only ba this structure the non-oocurring
reaction ace
cording to schemes (1) and (2) can be explained. The
scheme of the
formation of the products no. ", suggested here, is
confirmed by
a number of works by other authors concerning,the
isomerization of
amidophosphites by haloidalkyls in contrast to the
isomerization of
diamidopbosphites. In this latter case a normally
*c;omerized pro=
duct, a non-distillable mass and a dialkylamine ialt
dL-velop,
There are 3 tables and 6 Slavic references.
SUBMITTED'. April 29,, 1957-
AVAILABLE: Library of Congress*
Card 313

1-1 V1
50) PHASE I BOOK EXPLOITATION SOV/1589
Akademiya nauk SSSR.
Kj'iimiya bol'shikh molekul; sbornik statey (Chemistry of Large
Molecules; Collection of Articles) Moscow, Izd-vo AN SSSR, 1958.
299 P. (series: Akademiya nauk SSSR. Nauchno-populyarnaya
seriya) 30,00,0 copies printed.
Compiler: G.V. Sklovskiy; Resp. Ed.: A.V. Topchiyev, Academician;
Ed. of Publishing House: V.A. Boyarskiy; Tech. Ed.:
I.N. Guseva.
PURPOSE: This book is intended for a wide circle of readers
including those who have had no training in chemistry. It can
also serve as amanual for propagandists, teachers, and'
journalists.
Card l/ 8

Chemistry of Large Molecules (Cont.)
PART I
SOV/1589
CHEMISTRY AND THE PROGRESS OF SOCIALIST SCIENCES AND
TECHNOLOGY
Nesmeyanov, A.N. Acceleration of the Development of the Chemical
Industry, Particularly the Production of Synthetics for
Consumers' Goods and for the National Economyp and the
Tasks of the Academy of Sciences of the USSR 7
Topchiyev, A.V. Chemistry in the Service of Socialist
Production
Semenov, N.N. The Era of Polymers Has Begun
Arbuzov, A.Ye. The Cradle of Russian Chemistry
Knunyants, I.L. Competing With Nature
Card 3/8
31~
53
64
69

Che.mistry of Large Molecules (Cont.) SOV/1589
Krentsell,' B.A. Fundamentals of Organic Synthpsip 128
Berlin, A.A. Chemistry of the Macromolecules 140
Losev., Ij. Chemistry of Plastics 156
Dintses, A.I., V. Monastyrskiy, and L. Lozhkin. Polyethylene,
Its Manufacture and Use 165
Rogovin, Z.A. Miraculous Fibers 161
Ryabchikov, D.I. Ion-exdhange Resins 179
Bobrovskly, P.A. Role of the Chemical Industry in the Economy
of the USSR 183
Mirotvoretsev, N.N. Gigantic Program for the Manufacture
of~Consumersl Goods 193
Card 5/8

Chemistry of Large Molecules (Cont.) SOV/1589
Akutin, M.S. Plastics in Agriculture 199
Revzin, I.I.,and V.A. Marskiy. Use.of Plastics in Medicine 204
Iofan, B.M. Such Will Be a Plastic House 120
Sapozhnikov, M.M. Plastic-Tubes Instead of Metallic 214'
PART III
RESOURCES FOR THE PREPARATION OF SYNTHETICS
Antropov, P.Ya. A Powerful Raw-materials,.Base for the
-Chemical Industry 221
Bardin, I.P. The Indu6trialization of Socialism Expands
Eastwards 227
Mamedaliyev, Yu. G. Sciences and the Chemistry Industry 'R35
Satpayev., K.I., Basic Problems of the Development of the
Chemical Industry In Kazakhstan 248
Card 6/ 8

Chemistry of Large Molecules SOV/1589
Demenev, P.V. Scientists From the Urals in the Struggle for
Progress In Technology 286
Shakhray, F.V. An Inexhaustible Source for the Production of
Valuable Materials 290
Shur, A.M. Unlimited Possibilities
AV,kILABLE: Library of Congress
TM/Jmr
6-1-59
295
Card 8/8

.ARBY,,'07, A. Ye.
"The Problem of Proper Asolgrmnt of Scientific Staff."
report presented at the dession of the Presidium of the
Council for Cc-ordination
of Scientific Work of the Academies of Soiencon of Union
Republics and Branobes
(on IlDvelopment of Researobse on Highlv Molecular
Compounds) 21 June 1958.
(Vest * Ak Nauk SMR, 1W, No. 9, pp * 101-104)
Chalrwn of the Kazan' Branch of AS U38R

AUTHORS: Arbuzov, A. Ye., Razumova, N. A. SOV/62-58-9-7/26
TITLE: The Esters of Propyleneglycol Phosphorous Acid and
Their
Transformation Reactions (Ob efirakh propilenglikoll-
fosforistoy kisloty i ikh prevrashcheniyakh)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye
khimicheskikh nauk,
1958, Nr 91 pp lo61 - 1o69 (USSR)
ABSTRACT: The properties of the alkyl and aryl cyclic
esters of
phosphorous acid are different from those of the
corresponding open-chain esters by their group
rearrangements.
The chemical behavior of the cyclic esters of phosphorous
acid is described in detail in various papers by Arbuzov
and others (Refs 2-5). As previous papers by the authors
of this paper and by other authors have shown (Refs 2-5,
7-9), the cyclic esters can react in two different ways. To
explain this reaction and the reaction of the open-chain
esters with alkyl halides the authors carried out various
experiments. They studied the reaction between the cyclic
esters of propyleneglycol phosphorous acid and alkyl
Card 1/4 halides (group rearrangements according to
Arbuzov).

The Esters of Propyleneglycol Phohphorous Acid and Their
SOV/62-58-9-7/26
Transformation Reactions
Two kinds of compounds were found to be formed
in this reaction: cyclic propyleneglycol esters of
alkyl phosphinic acids and halogen esters of alkyl
phosphinic acids (with open chain). As a result of the
study on this rearrangement process the following mechanism
was suggested:
CH 3 -C H - 0 CH 3 - CH 0. OR
I POR+R'Hal -4 i \ P, \*- Hal --4
CH2 - Oz CH2 / . R'
CH 3 -CH - 011\P / R1 CH 3 -CH - 0 F R1 + RHal.
CH2Hal 0 OR CH2- 0 0
It was further found that this process can be stopped
Card 2/4 with the step in which the halogen eater of the alkyl

ior A
The Eaters of Propyleneglycol Phosphorous kcid~and Their
SOV/62-58-9-7/26
Transformation Reactions
phosphinic acid is formed. This depends, however, upon
the temperature at which the experiment is carried out.
It is not entirely out of the question that the group re-
arrangement of the alkyl cyclic esters may take place
in some cases in two parallel ways: either according
to the diagram given, which is accepted for the trialkyl
ester of phosphorous acid, or through intermediate
steps involving the opening of the ring. There are 4 tables
and 10 references, 9 of which are Soviet.
ASSOCIATION- Kazanskiy khimiko-tekhnologicheskiy institut
im.5.114'.Kirova
(Kazan' Chemical Technological Institute imeni S.M.Kirov)
SUBMITTED: January 29, 1957
Card 3/4

SEMENOV. N.N., akadamik~-~.UZOV,--A.Te., ak-ademik; MAMEDALIM.
Tu.G.;
KARGIN, V.A., akademik; TITOV, N.G., doktor khim.nauk; OBOLINTSW,
R.D., doktor khim.nauk; IMSHZRTSKIY, A.A.; SISAKYAII. N.M.
Discussion of the report. Vest. AN SSSR 28 no.8:19-26 Ag 158.
(MIRL 11-9)
1. Cblen-korrespondent AN SSSR (for Xamedaliyev, Imshenotski7,
Sisakyan).
(Ohamistry, Organic--Syntheais)

KUZURTSOV, Vladimir Ivanoviclfl,."UZOV, A.Ye.,
akademik, otv.red.;
POVAROV, L.S., red.izd-va;-A5TAFLMA, G.A., tekhn.red.
[Development of studies in the U.S.S.R. in the field
of the
polymerization of unsaturated compounds; on the 100th
anniversary of the birth of A.Z.Favorskii] Razvitie
issledo-
vauli polimerizataii nopredelinykh soadinenii v
SSSR; k 100-
latiiu so dnia rozhdaniia A.M.Favorskogo. Moskva,
Izd-vo Akad.
nauk SSSR, 1959. 274 p. (HIRA 13:1)
(Polymerization) (Unsaturated compounds)

50) SOV/62-59-1-5/38
MYTHORS: Arbuzov, A. Ye., Krasillnikova, Ye. A.
TITLE: On the Ef f ect of Triarylmethyl Halides on ibe Silver Salts
of Dialkyl Phosphites (0 deystvii galoidnykh triarilmetilov
na serebryanyye soli dialkilfosforistykh kislot)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh
nauk,
1959, Nr 1, pp 30 - 34 (USSR)
ABSTRACT: In the investigation of the reaction of triphonyl-methyl
chloride and triphemyl-methyl bromide with nilver dialkyl
phosphite A. Ye. Arbuzov (Ref 1) found in 1939 that the
reaction takes place as a rule in two different directions,
depending on the nature of the halogen. I. The reaction
with triphenyl-methyl chloride takes place according to
the scheme:
(RO )2 POAg +ClC(C6H5)3 -4 AgCl + (R0 )2poC(C6H5)3 (1)
R= CH - C H - n-C H
3f 2 59 3 7; '-C3H79- '-C4H9'
Card 1/4 11. The reaction with triphenyl bromide takes place to the

On the Effect of Triarylmethyl Halideaaatba-Silve:r Salts
SOV/62-59~1-5/38
of Dialkyl'Phosphites
scheme:
(R0) 2POAg + BrC(C 6if5)3-4 AgBr + (RO)P .40 - C.(C6H03 (2)
R-CH 3; C2H5 ; n-C 3H7; i-C4H9'
In the present paper the behavior of silver dialkyl
phosphites
with other secondary radicals was investigated. The reactions
with chlorine and bromine derivatives on the one hand and
with the triarylmethyl halides substituted in the nucleus
oii the other hand have shown that silver di-secondary-butyl
phosphite reacts according to equation (1)(Table 1). Thus,
salts of acids containing secondary.radicals react in
another way than those containing primary radicals. The sub-
stituent (chlorine) in the aromatic nucleus of the halogen
derivative apparently does not change the reaction course.
It is quite different with the reaction of silver dialkyl
phosphites which contain primary radicals, such as silver
Card 2/4 diethyl phosphite and silver diisobutyl phosphite.
The

On the Effect of Triarylmethyl Hal idea on the Silver Salts
SOV/62-59~-1~~5/38
of Dialkyl Phosphites I
course of reaction depends on thestructure of the aromatic
radicals of the halogen derivatives (Table 2). In the
presence of the chlorine substituent in the aromatic nucleus
of the halogen derivative the reaction takes place both for
chlorine- and bromine tritans according to scheme (1) and
forms mixed eaters of the phoophite. If the substituent in
the nucleus is a methyl radical, the reaction takes place
according to scheme (2), i.e. diesters of the
alkylphosphinic
acid are formed as derivatives of 5-valent phosphorus. It
is most difficult to in ves tigate the reaction course
accord-
ing to scheme (1) because the separation of the reaction
product is very complicated. Complexjeompounds of triethyl
phosphite and some others with silver haloids were already
earlier obtained (Refs 2 and 3). By adding silver dimethyl
phosphite to the molten triphenyl methane the dimethyl ester
of triphenyl-methyl phosphinic acid was obtained. A number
of experiments were carried out in order to investigate the
effect of temperature and the solvent upon the reaction
card 3/4 course. The experiments were performed in sealed
tubes in

On the Effect of Triarylmethyl Halides ontheSilver Salts
SOV/62-59-1-5/38
of Dialkyl Phosphites
benzene solution without heating. It was found that the
reaction without heating has the same effect as on heating.
By use of ether instead of benzene the reaction took the
same direction. There are 3 tables and 11 references, 7 of
which are Soviet.
ASSOCIATION: Kazanskiy khimiko-tekhnologicheskiy inatitut (Kazant
In-
stitute of Chemical Technology)
SUBMITTED: April 29, 1957
Card 4/4

.50) SOV/62-59-1-6/38
AUTHORS: Arbuzov, A. Ye., Abramov, V. S.
TITLE: The Problem of the Effect of Halogen-Substituted Ethers
on the Salts of Dialkyl Phosphites (K voprosu o deystvii
galoidozameshchennykh prostykh efirov na soli dialkilfos-
foristykh kislot)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye
khimicheskikh nauk,
1959, Nr 1, pp 35 - 40 (USSR)
ABSTRACT: The experimental investigations carried out by the
authors
have shown that the monochloro-methyl ether reacts regularly
with sodium diethyl phosphite and forms ethyl ethers of the
methoxy-methyl phosphinic acid. Sodium dimethyl phosphite
reacts with monochloro- and monobromo-methyl ether in a
similar way as sodium diethyl phosphite and yields the
methyl ester of the methoxy-methyl phosphinic acid. In the
distillation of reaction products of the bromo-methyl ether
with sodium dialkyl phosphite a reaction takes place without
separation of the sodium bromide formed in the reaction in
which salts of acid esters of the methoxy-methyl phosphinic
Card 1/3 acid ar-e formed. ]Aonobromo-methyl ether reacts
with silver

The Problem of the Effect of Halogen-Substituted Ethers
SOV/162-59-i-6/1z8
on the Salts of Dialkyl Phosphites
dialkyl phosphites in the same way as with sodium salts and
forms corresponding esters of the methoxy-methyl phosphinic
acid. The reaction in benzene takes place rith a preliminary
dissolution of silver salt and apparently forms an adduct
of the halogen-substituted other at silver dialkyl phosphite.
In the reaction of chloro-methyl other with silver dialkyl
phosphites the silver salt is equally dissolved and an adduct
is presumably formed. On heating the product obtained
separates silver chloride and apparently mixed esters of the
phosphite. They are disproportionated in the distillation
and yield phosphites which contain the same radicals as the
silver salts. By the influence of triphenyl me-thane upon
adducts of the chloro-methyl ethers at silver diethyl
phosphite the triphenyl-methyl phosphinic acid is formed
after saponification. The same reaction with the adduct
of the bromo-methyl ether at silver diethyl phosphite, hor-
ever, yields triphenyl carbinol. This indicates a different
course of both reactions. There are 12 references, 10 of
which are Soviet.
Card 2/3

The Problem of the Effect of Halogen-Substituted Ethers
SOV162-59-,1-6138
on the Salts of Dialkyl Phosphites
ASSOCIATION: Kazanskiy khimiko-tekhnologicheskiy institut (Kazan, In-
stitute of Chemical Technology)
SUBMITTED: April 29, 1957
Card 3/3

50) SOV/62-59-1-31/36
AUTHORS: Arbuzov, A. Ye., Imayev, M. G.
TITLE: On the prepardim of Diphenyl Phosphite (0 poluchenii di-
fenilfosfita)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye
khimicheskikh nauk,
1959, Nr 1, PP 171 - 171 (USSR)
ADSTRACT: In the present comminication- a simple method of
synthesi2ing
diphenyl phosphite is sugCosted. There are 2 references in
publications available (Refs 1 and 2). Recently (Ref 3)
diphenyl phosphite was obtained by careful saponification
of the chloric acid anhydride of diphenyl phosphite by an
equivalent quantity of water in ether according to the
following equation:
(C6H50)2 PC1+H 20 -4 (C6H 50)2 POH+HC1. The authors investigated
the saponification reaction of triphenyl phosphite, and
stated that this reaction may be applied for the synthesis
of diphenyl phosphite which so far has been very difficult
to produce. Diphenyl phosphite was obtained in a quantitative
yield (as compared to the raw product) by saponification
Card 1/2 of triphenyl phosphite with an equivalent quantity of
water

On the Preparation of Diphenyl Phosphite SOV/62-153-1-31/38
and by subsequent removal of phenol in vacuum:
(C 6H56)3P+H26 --4 (c6H50)2 POH+C6115OH. Diphenyl phosphite
synthesized in this way may be used for purposes of-
synthesis
without further purification. There are 3 references, I of
which is Soviet.
ASSOCIATION: Kazanskiy khimiko-tekhnologicheskiy institut
im. S. M. Kirova
(Kazan' Institute of Chemical Technology imeni S. IA. Kirov)
SUBMITTED: June 16, 1958
Card 2/2

5 (3, A)
AUTHORS: Arbuzov, A. Ye., Academician, SON'/20-126-4-23/62
Iyanov, N. S. , Kozyrev, B. 14.
TITLE:
Paramagnetic Resonance of tcc-Diphenyl-(~-picryl-hydrazyI

Obtained From Different Solvents (0 paramagnitnom rezonanse

c4
oL-aifenil-if~-pikri,lgidrazila, poluchennogo iz razlichnykh

rastvoriteley)
PERIODICAL:
Doklady Akademii nauk SSSR, 1959, Vol
126, Nr 4,

PP 774-776 (USSR)
ABSTRACTs
The data given by various
authors on the width of-the line

of the paramagnetic resonance of
the compound (DPIIPH)

mentioned in the title, vary considerably:
from v 1 to "6 Oersted.

In order to explain this fact, the first
author suggested to

deal with the subject mentioned in the title.
DPhPK was

produced according to the method described in reference
3

which differs from the Goldschmidt method (Ref 4). The solvents

used were: benzene, toluene, xylene (isomeric mixture),

pyridene,
bromoform, carbon tetrachloride, chloroform and

carbon disulfide.
For the method of measuring the resonance

see reference 5. The
values of the width of the lines of the
Card 1/4
paramagnetic
absorption (,& H)1/2 mentioned in,the title, show

Paramagnetic Resonance of o4#-Diphenyl-A-picryl-
SOV/20-126-4-23/62
hydrazyl Obtained From Different Solvents
that the nature of the solvent has a considerable influence
on the width of the line. Naturally this leads to the
conclusion that the molecules of the solvent form part of the
crystalline lattice of the DPhPH (Refs 6-9). In no case
however, there ii a guarantee that the experimenter dealt
with chemically pure compounds. The data of table 1 show that
the solvents used here, are divided into two groups, according
to their influence on the width of the line: a. compounds of
the cyclic type, b. compounds containing no cycles. In
DPhPH specimens of the group a. a narrowing of the absorption
line takes place, in consequence of cooling and of an increase
of their frequency. Group b. in such cases shows a widening
of this line. On the.,whole it may be said that the specimens
of group a. despite of their broader lines, are more
magnetically isotropic than the specimens of group b. All this
has to be considered as something more or less provisional.
The observed dependences"oan only be explained after further
investigation. Furthermore both DPhPH groups show a different
influence of the atmospheric oxygen on the breadth of line.
Card 2/4 On-the whole widening of the line by means of 0 2 is
reversible.

Para magnetic Resonance of ac,ce-Diphenyl-fw.-picryl-
SOV/20-126-4-23/62
hydrazyl Obtained From Different Solvents
Finally experiments of the authors are described in which
one solvent (chloroform) was replaced by another (benzene).
The crystals developed by chloroform, showed wider lines after
they had been recrystallized with benzene. With a reverse
sequence of the solvents used, the crystals maintained the
line of a benzene specimen. Thus it seems that the affinity
of benzene and DPhPH is stronger than that of chloroform. if
DPhPH is used as'a standard for defining the number of
paramagnetic centres in different substances, it has to be
done very carefully. Only a DPhPH preparation from a certain
solvent may be used. In the case of a DPhPH synthesis from
other solventsp the exaot details of the experiment have to
be given, or the experimenter will get various results.
There are 1 table and 13 references, 3 of which are Soviet.
Card.3/4

Paramagnetic Resonance of oe,,oL-Dipheny1-(~-picryl-**
SOV120-126-4-23162
hydrazyl. Obtained From Different Solvents
ASSOCIATION: Fiziko-tekhnicheskiy institut Kazanskogo
filiala Akademii
nauk SSSR (Institute of Physics ancl Technology of the
KazanI Branch of the Academy of Sciences, USSR)
Khimicheskiy institut Kazanskogo filiala Akademii nauk SSSR
(Institute of Chemistry of the Kazan' Branch of the Academy
of Sciences, USSR)
SUBMITTED: May 13, 1959
Card 4/4

o V
5(3)95(4 SOV/20-1,27-4-25/60
JAUITHORS: Kitayev, Yu. P.f Budnikov, G. K.. Arbuzov. A. Ye.,
Academician
TITLE% PolarogT-~,jphio Investigation of the Tautomerism of Some
Semi-
and Thiosemicarbazones in Solutions
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 127, Nr 4P pp
818-821
(USSR)
ABSTRACT: As the problem of the structure and tautomerism of semi-
and
thiosemicarbazones has not yet been fully solved, the authors
started with this article a systematic investigation of the
structure and behavior of the representatives of this type of
compounds, At first# the polarographio method was used. The
semi- and thiosemicarbazones of aeotone, methyl-ethyl ketoneg
acetaldehyde, propionaldehyde, eyolopentane, benzaldehydef and
acetophenono as well as the thiosemioarbazone, of para- and
isopropylbenzaldehyde were investigated by means of an LP-55
polarograph (Iieyrovskiy system) with photographic recording of
polarograms. The polarograms were recorded for buffer solutions
of the above compounds with the pH-val.ues 5.7, 7-3p 9.3 at 200t
and a molar concentration of the semi- and thiosemicarbazones of
Card 1/3 500-4 -5-10-3. A family of curves was obtained for every

Po'laiogTaphic Investigation of the Tautomerism of
SOV/20-127-4-25/60
Some Semi- and ThiosemicarbazoneB in Solutions
solution with a certain pH-value. The polarograms show the
high similarity in the behavior and, consequently, in the
structures of the individual oompounds. Certalp. rules for the
polarograms of the aliphatic aldehydes and ketones as well as
of the alicyclic ketones of semi- and thiosemicarbazones were
found in the change of polarograms (Fig 11); the waves with an
E1/2 -1-4 to -1-55 v fi=st become smaller with the time; grow
again, and finally disappear completely. The aliphatiz and
aliolyclic omo-compounds had - as they o~,ca,,r In two
tautoiat-t.riu
forms .. txvo waves at E1/2--l-5 v and El/2 76
Comparative polarograms of the aqueous alcobel solutions of
S-methylthiosemicarbazone were rezorded whi4ah also show the
two waves corresponding to the two tautomerle forms
(E 1/2 ~ -0.8 and -1-15 v). An analysis of the polarograms
led to the following results; All compounds investigated had an
ensemi- and enthiosemicarbazone structure in aqNaeous and
aqueous-alcoholic solutions. There is no transition of the
Card 2/3 double bond from the azomethin group into the
carbonyl group.

Po'Lar3graphic Investigation of the Tautomerism of
SOV/20~127-4_25/60
-Some Semi- and.Thiosemicarbazones in Solutions
The polarograms of the benzalsemi- and(acetoplienonethiosemi-
carbazones again showad only one wave E,/2^0-1.15)(Pig 13).
In the general cases the polarograms pointed to 4 possible
tautomers of the semi- and thiosemicarbazones. They permit
the following transitions:
'R 0 li-NE-0 NHr*--+ H -on - 0 NN - IM-0 NH
1-CH 2-1 1 - 1 1 2
R 0 R 0
t I '(S) t ~ '(S)
RI _CR2_C N-1.0 R -OR - C IM - N- C VH
2
ROO OH(SH) k11) WS11)
There are 3 figures and 6 references, 4 of vrhich are Soviet.
ASSOCIATIONt Xhimioheakiy institut im. A, Yet Arbuzova
Kazanskogo filiala
Ak-ademii nauk SSSR (Chemical Institute of the Kazant Branoh
of the Academy of Sciences, USSR)
SUBMITTED: May 21l 1959
Card 3/3

5W., SOV/20-127-5-30/58
AUTHORS: Kitayer, Yu.. P., Budnikov$ G. K.9 Lrbuzov, A. Ye.,
Academician
TITLE: The P.Qlarographic Investigation of the Stereoisomeric
Trans-
formation of Some Semi- and Thiosemicarbazones in Solutions
PERIODICAL: Doklady Akademii nauk SSSR9 19599 Vol 127g Nr 5s PP
1041-1043
(USSR)
ABSTRACT: The authors Point out that the stereoisomerism of semi-
and
thiosemicaxbazoiies has not yet been sufficiently well investi-
gated, and that there are many discrepancies in published data
(Refs 2-4)- Investigations were carried out of the semi- and
thiosemioarbazones of methyl ketone, diethyl ketone, cyclo-
pentanone, cyclohexanorLe, benzaldehyde, acetophenone, and thio-
seminarbazone.of p-isopropylbenzaldehyde in a 20~. solution of
methanol in water with PH - 5-7 under irradiation with ultra-
violet light. The measurements were carried out by means of the
photorecording polarograph LR-55- In the case of alicyclic
aldehydes and ketones the stereoisomeric transformation of the
corresponding semi- and thiosemicarbazones occurs easily. Under
irradiation by ultraviolet light the polarogram shows a new
Card 1/3 wave with positive E
1/2* An exception is formed by the thiosemi-

SOV/20-127-5-30/58
The Polarographic Investigation of the Stereoisomeric
Transformation of Some
Semi- and Thiosemicarbazones in Solutions
carbazone of cyclopentanone, which decays by irradiation. The
production of the second wave, the height of which increases
with the duration.of theIrradiation, is explained by the
production of a labile form. In the case of cyclic derivatives
isomerism is based on the cis- and trans-form with respect to
the ring. In aromatic derivatives stereoisomerism may be ex-
plained by the group R I \
R(HY
Table I gives the measured potentlials of the semiwaves of the
stereoisomers.and the transformation energies. Even though the
polarographioal data alone do not suffice for the purpose of
explaining.the-structure of stereoisomers, they may, in con-
junction with-ohemical and physical methodsp nevertheless make
a valuable contribution. The labile forms found will as a rule
be the cis- (or syn-) forms, though there are exceptions.
Therefore a further investigation of the structure of these
atereoisomers is necessary. There are 2 figures, I table and
Card 2/3 9 references, 7 of which are Soviet.

SOV/120-127-5-30/58
The Polarographic Investigation of the Stereoisomer-4c
Transformation of Some
Semi- and Thiosemioarbazones in Solutions
ASSOCIATION: Khimioheskiy institut im. A. Ye. Arbuzo*ra Kazanskogo
filiala
Akademii nauk SSSR (Chemical Institute imeni A. Ye. Arbuzoy
of the Kazan' Branch of the Academy of Sciences, USSR)
SUBMITTED: May 22, 1959
Card 3/3

KITAYEV, Yu.F.; ARBUZOV.. A.D.
Study of tautomerism and geometric isomerism of
nitrogen-
containing derivatives of carbonyl compounds. Report
No*2:
Polarographic study of transformations of
pheny3.hydrazones of
some aldehydes and fatty aromatic ketones in methanol*
Izv,AN
SSSR Otd.khim.nauk no.S.*1405-= Ag 160. 15:5)
1. Khimicheskiy institut im. A.Te.Arbuzova., Ka2aMkiy
filial AN SSSR.
(Hydrazones) (Polarography) (Isomerism)

ARBUZOV, Aleksandr Yerminingelldovich; GUSIKOVA,
O.M.., tekhn. red.;
(A.I,',.Butlerov, the great Russian chemist;
anniversary of the
theory of chemical structure] A.M.Butlerov velikii
russkii khi-
mik; k 100-letiiu teorii.khimicheskogo stroeniia.
Moskva.. Izd-
vo Akad.nauk SS91, 1961. 42 p. (MIRA 15:1)
(Butlerov, Aleksandr Mikhai-lavich) 1828-1886)
(Chemical structure)

ARBUZOV A Ye . akad.; VAULOV, S.I., akad.;- VOLIFKOVICH, S.I.,
aked.;
KOCHINA, F.Ya., W-rad.; LANDSIBERG, G.S.,, akad.; LEYBENZON,
L.S.p
akad.,- PORM-KOSPITS, A.Ye.,, akad.; SMIRNOV, V.I., akad.,-,
FESENKOV,
V.G., akad.,~ CHMaAYEV,-V.I., akad.,- KAPUSTUSKn, A.F.; KORSW~
V.V.; KRAVKOV, S.V.; NIKIFOROV, P.M.; PETROV) A.D.j:
PRMVODITELBV,
A.S.; FRISH, S.E.j CHETAYEV, N.G.; CINUTOV,
V.K.;,,11)'HOSTAKOVSKIY, M.F.;
KUZNETSOVJ, I.V., red.; MIKULINSKIY, S.R., red.; MURASHOVA,
N.Ya...
tekbn.red,
[Man of Russian science; essays on prominent persons in natural
soience and technology: Mathematics, mechanics, astrononq,
physics,
chemistry) Liudi 3-USskoi nauki; ocherki o vydaiushchikhsia
deiate-
liakh estestvoznardia i tekhniki. matematika, mekhanika,
astronomiia,
fizika, khiniia. Moskva, Goa. iod-vo fiziko-matem. lit-i7, 1961.
599 P. (MIRA 14-10)
1, Obleny-korrespondenty AN SSSR (for Kapustinskiy, Korshak,,
Kravkov,
Nikiforov, Petrov, Predvoditelev, Frishp Cbetayev, Chmutov,
Shostakovskiy).
(Sc ientists)

KUZMSOV, Vladimir Ivanovich; ARBUZOV A Ye akademik., otv.
red.; PO-
VAROV, L.S., 'red. izd Va-; tekhn. red.; VAKOGCNOVA,
I,A., tekhn, red,
[Origin and development of the chemistry of a3.ioyo:Lio
compoundsl
V07,niknovenie khbaii, alitsiklicheskikh soedinenii. Moskva,
Izd-vo,
Akad. nauk SSSR., 1961. 185 p. (miRA i4:ja)
(A3Aoyolic compounds)

BERG, Lev Germanoirich)--ARBUZOV, A.Ye., akademik,, otv.
red.; YEGGROV, N.G.p
red. izd-va; ASfiftlYLT!-,-G4-.-)--tekhn-q-- red.
[Introduction to thermograpby] Vvedenie v termograftiu.
Moskvaj Izd-
vo Akad. nauk SSSR, 196 367 P. (MIRA 14:U)
thermal ana3ysis)

KITAYEV, Yu.F.; BUDNIKOV, G.K.; ARBUZOV, A.Ye.
Study of tautomerism and geometric isomerism of
nitrogen- containing
' -- P
derivatives of carbonyl compounds. Report No.3:
Folarographic study
of some semi- and UJ~Iemichrbazones in water-alcohol
solutions. Izv.
SSSR.Otd.khJTn.n&uk-no.5:824-831 MY 161. (MIPA 14:5)
1. Khimicheskiy institut im. A.Ye.Arbuzova
Akademii -nAuIr SSSR.
(Semicarbzaoneo)
Kazanskogo filials,
(Polarography)

KITAYEV, Yu.P.; BUDNIKOV, G.K.; ARBUZOV, A.Ye.
Tautomerism, and gecmetrical isomerism of
nitrogen-containing
carbo nyl compouilds. Report No.4: Polarographic study of
transformations of some semi- and-thiosemicarbazones in
Fater - al-cQhol solutions. Izv, A9 SSSR. Otd.khim.nauk
no.7:
1222-1227 J1~161. (KIRA 14-7)
1. Khimicheskiy institut im. A.Ye. Arbuzova Kazanskogo,
filiala.
Akademii neuk SSSR.
(Semicarbazones)

KITAYEV9 114.P.; BUDNIKOVS G.K.;
Study of tautomerism and geometrical isomerism of
nitrogen-
containing derivatives-of carbonyl compounds. Report
Ho.5:
Polarographic study of semi- and thioeemicarbazonee of
aromatic
aldehydes, Izv.AN SSSR.Otd.khim.nauk no.'10.-1772-1780 0
1619
(MM 14-
1. KhImicheskiy JliBtitut im. A.Ye.Arbuzova Kazanskogo
filiala
AN SSSR.
(Semicarbazones) (Pblarographv)

ARBUZOV, A.Ye.9 akademik
What is going to bappen to the sky? -This problem
worries the
volentists today. Tekh,.mol* 29' no#4:4-25 Ap, 161.
(MIRA 14:5)
(Photosynthesis') (Air-Pollution)

ARBUZOV, A-Ye., akademik
A.M.Butlero,r, a rreat Russian chemist. Zhur.ob.khim. 31
no.9:2797-2811 3 '61. (MIRA 14:9)
(Butlerov, Aleksandr Mikhailovich, 1828-1886)

ARBUZOV) A. Ye... akademdk
4 great Russian chemist; one hundred years of
A.M. Butlerav's
Utory of the chemical structure. Priroda 50
no.9:22-23 S
161. (MIRA 14-.8)
(Butlerov., jaekamdr Ydich-novich,, am&iw)
(Chemistry, Organ:Lc)

KITAYLV, Yu.P.; BUDNIKOVj, G.K.; TROYEFOLISKAYA, T.V.j
AF-J3UZOV, A,. Ye,s-
akademik
Quantitative evaluation of the effect of substituents on the
polarographic reduction of certain az6methine, compounds. Dok1
AN SSSR 137 no./+:862-865 Ap 161. (MIRA 14:3)
1. yhimicheskiy institut im.A. Ye. Arbuzova Kazan4kogo filiala
A,N SSSR.
(Schiff bases) (Hammett ejuation)

ARBUZOV, -.Ye... ah-adcldh; ':'T,13'7-T': ) V.Ye.
............
Sore :,oir i-midoother derivatives. Do]-11. -*-" SSSP 141 no.I:Cl-
83 1-1 161. (mIRA A: 11)
1. Kananskiy 'A-hiriko-tekhnologichaskiy inatitut im. S.M. Kirova.
(Ethers)
(Chemistry)