SCIENTIFIC ABSTRACT ARBUZOV, B. A. - ARBUZOV, B. A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000101920005-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 5, 2000
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

L L. L i i
a ac on Of D5PAO_rM_W&hlQ_ftddzon eth qrthopro-1~)______
N. P. - cf!
lonate and is. A;, A M.and Et oEt gave -&__c_o_niV_,bI. Plit
nig-4-MV-704211. Nauk 112 g. gtopCis, b. 116-1
9JUSP mile EtCO113t an' Lhe reactions with vark
S.S..Y.K.. UMa-.WVsM. lVauk 1953, 4WV.-Addn. of 10.6, mq 1.4760. Thus
I own as: Et Et),
PCI4 to 40 & EtC(08t), led to much heat evolution with Of _Ctauts
COMM be 5h, 1%100
JPCII; 2 13t RO
temporary formation of a colorless ppt. After 2 hrs. on a Co'Et + Eta
+ Et, 101
t Htcl + (Rto),PCI + 2 EtCChHt; a Et
earn bath the reaction Ixt (elded 10.1 ff. RtC0.9t. C, + p(oEt), A51d
9.8 1. and 9.07 u )M P OMM)v M, bit utcoxt 4- 3 Et
C
0
140- 0 d'0 10353. 06 trea w th HO and a _Uon of PCU with
S. MOV iAMP .1,12 , -~199)j described Q -L Etc
I little jj&*,I~wly h;&lyzed and after 2 weeks gave' a OHOI, which
4rmably gave s=e
EtCl and HC Bt- Bassett [Chem. 9 CW
Et.
holnogonedds soln. which on distu. yielded a product, bit t ratio and
claimed C
108-401,~ my 1.4203, which formed a semicaroazoue, in. used the 1:3
resr~ pot priedel and I
160-3% In very low yield (this Is used as a confirmation of monti-Et
ester 0 C'
it, Kith Ut sulcovol
I the above structure). (StONIP (28 S.) slowly treated with 13
17(187011 fron I
from which no Individil
'15.5 It. RtCOCI and the mixt. distd. gave 14.5 g. JUCOPO- A'mixt. b.
I!ft~ Vest jChMjj% (if AHP
(OEjh, bs IOD.5-2.5', d I.OM, my 1.4230; the residue (the statement a
I was a water-tot. solid. Repeated dbtn. of the above prod- Ig,43. p.
e4 ~C.A. 37.440,14)) is in Itaidinfil,
~ioHt~ sho-
uct gave an extended fmctlon (bi, 67-1211) from which only with So g.
S d visible action
tCl.
!uct, b, 100.5-2.5", d, di-tri. Kit the 11
sonic 30% ptod 111.0801 my 1.4201, steam bath y elded 13,60 14 g.
was obtain-, and further distn. was similarly unsatisfac- EtopCl,, b.
116-19 -
tory. This product treated In aq. soln. with Na nitro- - d:0 1,1290,
121.1 g. (9t0 'SICII.
137-8 ' J)" 4* 1
pruisside and t1q. NxOH gave a red color. With aq. EtOH, 10460 7.2 g.
intermediate cut.
NaOAe, and H,NCONHNHo.HCI It slowly gave the semi- No (Eto),P could
be isol
Carbazone, Tn. 100-2'. Identical with that cited above. netant
PrOP001003 Me even lesl well'
Letting EtCOPO(ORt), stand overnight with IFIC(OIR)a In The anal rse,
for P in the presence 01611"
abs. ELOH failed to yield any 1, and only the essentially metric
t1tratlou (el. SaIkIna and Tot
univActed ester, his 118-10.51, d!O. 1.0715. my 1.4170, was 1989h). 0
recovered. Extuation of I Lt represented by initial addn. of
the components to yield EtC(OHt)tCI and ZtOPCIj; the
form;r product then reacts with P(OEt)l that Is fonued in
the mixt. by the Aibuzov reaction and yields I and EtCl.
PCI, (15.7 j.) and 40 g. EtC(09t)~ kept 2.5 hirs. an a steam
Uth Hit e ppt. formed) and the mixt. distd. gave 21.5
1380111t an 5.5 g. (Et%PCI, ba IN24", dl,' 1,0871,
1.4344. Similar reaction with 39.17 g. PC4 and 50 R.
34 g
i1.2373.
Et-
2
Cl, -
t4o, 194,
of TIC-
"g with'
8(1863)
tion )5
is
lBer
'.%t.In;d
D Isolated
'thocurs
(44.19)
brs. on a
ve 27.5
g. MIYt*.,
other re
nets.
prod
ly Ampere-
C.A. 48.:
M japoll

9 R

&AcUO2 of coadou"tIOU of 3

-cam
sketwous

LI

0
:
;

02i

ARBUZOV, B.A.; KATAYRVA, L.M.
"'
The structure of molecules of secondary amines. Soob.o
nauch.rab.
chl.VKHO no-1:34-36 153. (MIRA 10:10)
(Stereochemistry) (Amines)

A k

V
,

J
a( the acid gave 7.6 g. di-Br eferip,, 1G. 330. 1 ~Ia 1.) Wi

M,
i
65

-
n. to
P" heated 15 ra
1
i 'gave
W20 do* 0 OM (heated w
ixuio I hr
tt

.
,
e' 1*4'h 8 g. AW in sealeV Wbe I hr. at
. t
athig 5

ave ter a length DO% of the OxAydridp
1
I IBD-Doo g I Y evapp., ~

-
of 1, re. 47."' (from dry Ut3O) (this beated I hr. with dil.,*
Toila
add. B. A. ATbuzov and B. P, Lugov
NaOH readily gave 1); 1 g. anhydride
with 0.7 9. Br to
M 1. UI,YaRDvrRrM-,-W11r_~.1 Kazan).. -%i)prjik
CHC4
gave the 1drabrornide, m. 33.5',' 1 chloride M3 0.)
Statel Obskzhel
Xhim., Akad. Nauk S.S.S~R. 1, 419-24
added to concd. NHOH with coolie?
pvt M.7% 41hiidf
(1953); cf. Arnaud, CowPl- rtxd. 114, 79,F1892); ja4.
-(XI), m. 8B' ffrou abs. E1OH), whic (6- g.) in CHM
'
473(1W2) -To 60.7 g. Petmsellxiic add in dry CHCL tva!i
g. Ur gave the
di-Br amide ol 1, in. 8040.60-
treated with 4
sloWlY added 80 g. Dr in Q all, CHCls with good cottling;
(from RIOR). 11 (16.7 g.) and 8.5 g. PjOh hwed it about
Afttr evaPu- Of
the solvent there was obtained 7 6,7.
7
I
dibrow0wric acid
87-89 (f
R
0
T
l
U
3 rnin. to 180, ga%,e 18.6% nithis. bs 158 9', Wu-1.47A

dl
WWI with
4
xln
Jin20
abs
8790
R
fJ
l0
0
, m.
rom
4
).
h
s (
lit
s
15D ml
abs
RtOH and 20
Po
d
KOH
d h
5
h
.,
.
e
,
u
g.
,
g.
g
'
a
"0
N 167-81
b
9-
6 hr%
ave 02
2% 1 Mc ester

.
.
,
9.
w
w33
eate
is.
.
On 4 $tenet bath, then treated with 24 g. polvd. KOHaud
.
,
S
. g
,
,
.
nq 1.48d0. d,141 0.81,17.. which with I1r In CHCI, gave the Lit-
ljtAle4
6 his. lopler; after dila, with 5W. all. RIO and
Br drrip,, m. 27-7.5'
(frout EtOH-PtO) almilarlt WA3
*
neutrallsuvion with d1l. HgSOj tbtrc was formed 8550
j

, bi 202-4 , 16V
prtPd. 01.6% 1 M eilt-P (111), bt 10-4
t
acid) (1), aj, 8U.4
2W-7~
19S'
1,
(Irmn VtOn)
t
h 3
i
C
1.4640, d,1#' O.W5, d;o 0.9921 (hydrolysis with a
" N;49H
Ii
h
dib
id
kt
i
1
5 f
1
dl
oo
t
,
,
; w
S. fit In CH
1
lb, 5 S,
polls
.
aw
n
e
e~ it )f
irs. gave
). gave t
qu
,
~
do 1
h
h
1
III i
Oll
4773
1 M
5
l
A

cat
.
n
,
c
.
1.
ig
C.
o tu
.;
,
111t) a hu, at 70-L10* gave the di-todide, in ~ 21) *.S'

("Mob' E1019.
To 204 s. III Ia 100 mi. dvY htsOll

uddea 7 g, Na, after ft~~ting 16-20
odit. to cinill,10c,

the "actio i. Lite inixt. was dild. with 1110 (35
till.),

A with 140, sultial out with N I
tit 100-D00 I br., washt:

41"-
0
l
1A
1
104h
7
d

~:4011
.
ej
c.)na
. Y
the W9.)4Ytr OVAe
is
-.Crystni from 'AcOf - cbanW this iliatelfal
*
-

yielding sunte'
. lit, TM
I Und ii Sub4tflnCe,

it of tho liroduct, id. e,.~

40 X C111011, hi I W
-4', ni, 2 jot.~
Cf'
H
l

it
r

an Ity If( 0411ide, 1P.- G.

W_
71

N MI.
M2 ON
St

fto
Tz.-RN-

!:mt_ .6

S, , - -
I, ~ - L. - , I - - Y- , - -- - -- - --- - --
WGOVKIN, B.P.; ARBUZOV, B.I.
Alkylating amines with acid chloride of dialkylphosphoric acid..
Soob.o nauch.rab.chi.VKHO no.2:22-23 153. (MIRA 10:10)
(Allwlation) (Amines) (Phosphoric acid)

'4u')-ZCa Mtb I ic~ ,!I:'- M
19-4i,'
flk~ 11 r, U
1.4965-1 hyd,,j '31'. , - L~,
~ gave
S-1y. , , I dZ 1-12w, V
Eton) NUW,. '. - *P,4' U". m
169-70.
the 38M, Metum Trith pbell,gr
. (from
;k csttt. bil 153-50. d.9
1-1189 Pvc 44% yjtqd 01
CH, 1EV12 1
"-I !" % Yidd Of th. wwa Ph.

ARBUZOV, B.A.; BOGONOSTSEVA, X.P.
t
---W21 ~,~j~ractlon of certain derivatives of
chlorine and bromine with
sodium diethylphosphide. Soob.o nauch.reb.chl.VXHO
no.4:39-42
'53. (MIRA 10:10)
(Chlorine) (Bromine) (Sodium phosphides)

ARBUZOV, B.A., akademik.
Paris Conference on the Study of Molecular Structure. Vest.AN SM
23 no.10:
90-93 0 '53. (MLRA 6:11)
(Paris--Molecular theory--Congresses) (Congresaes-golecular
theory-
Paris)

G/ io" A

Olt

",
0
Ora 0 Iih a c an
am FIE
a
C
i

-
acids. . Y~I=
k W
45
N

.
" Is. Khm. 27, 713-18
A, .
-
I
20*
d
4
(d
~
/
r
Va"
/
f

t Sur Sem en an
,.,
y
y
"
.
'
)ncs
was
cm.) at
or
Y (
Me Tp.
Mep thalate (Mc3R) 41.85, 1141137.38, PriR 35.25, Built

23.40,
(CHis)zR 32M. (C&Hjj):R 22.00, (CpHjm)jR 31.52-

and (C,oHn)3R
31.75. It was for Et temphthalate (Etjlt~

82.89 at 55*, Pr.RI
34.68 at 20% Bu$R' 33.7121 at 20',

W1,6111 29-90 at 55*,
(Cslfn)iR' (in. 41-42.5*) 30.0 at

85'. (Cil-fu)311' (in.
44-4SI) 29.75 at M*, (ClefflJoR' (in.

55-57') 29M at W. A, 20',
-y of benzoatts wtLs-. hexyl

32.92, octyl 32.66. nony) 32.59,
and decyl 32.70. The
taled. parathors, with (C)Cj I d(C) 174.8, (C)COO(C) -

66.4,
ortho - - 2.7. cormcdon - 4.0. are greater than

the expti.
values, and the difference Increases with the no. of
*
carbons in the alk
l radi6l
The diff
b
t
th

.
erence
ween
e
e
y
next hamologs is 4.4 for plithalates, !l2 for terephthal:Ltes,
A%

and 1.1 for benzoates. J. 1. Dikeman

cturt of esters of phthelic atidT., 11. A.
Arhumv wid Z., Z. Vakvva (NI. I . I
-Lenin 1 in
Zhur.* Fis. Xhim, 27,
1953); cf. C.A.
48, l3b-The viscosities were measured at 20' of benzene
tinins. of hu-yl tereplithalme, I terephthalate, nouyl
nonyl m-plithalatt
(1), nonyl terephtlialate.
dt:TSI m-plithalate (11), decyl terephthalete, hExyl enrlionatt
(111), octyl carbonate (IV), decyl carbonate (V). heryl
orthopropionate (VI), and octyl orthopropionate (VII)
(concils. 1-10%). By Inca! S' of the tabulawd CKPti. data,
these,estus wei-e shown to have an dangated ftracture in
benzene w1n. Tire plithalates; were preid. by reaction of
the ell-yl plitlialate witij the appropriateale. in the pres Ce
a
"it, and the remaining esters %vere: prelid. 63, the
f N inethod
~_of ArbuzovaticiVutdashet-a(C.~1.44,37Zigc),.Ln(tYLIdastttva
(cf. llch"y, Zapiski Kazan. Gosudaysi. Univ. im. V. r
'2)). The d..*:
_W'yanom-Lenina 112, 35(19. b'p_' "2"', 1 1 . ...
~:aud turf&ce tension (-r) at n' in dynea/cm. it, that order
are for 1, Z33-41.5' (I mm.). 1AMI, 0.9711, 32.23; for Ul.
128' (3
into.), 1.42W, 0.0036, 28.05; for IV l(W-8 3'
L 1.43W, OATM, 'D.03; for V, 204-4.51 M m
4.44265, 0.81,39, 30.21; for VI, 172.5-3.5'
A.43500, 0.8099. 27.35; for Nill, 207-3' (2.5 min.), .4
O.SW4, 28.85. For 11 the ra.p., b.p., d4,1, art,] at 86&
W
are 5 253.5 .5' 1.5 mar.), OAM, and 21, . :,, ~'~Sp
J. W, Lom-h-trg, jr.
7-
7_

-.7
AR, f3l)7~C-v
~,"pl ziLaw pyrr
-1-,4 q BUN in a" b.W una 2 CO, atm Tae i~uvwirj
'Dad siriviltng !iquW, in air :h,
derr, estt-,~
d..
~. 87--9*, Lvv V" N t4,
:. 4320: Bu. t,,. 54 ~A 44 i
,430. 1 43.5. C.H.. G &503. 1 "49;
0 Pq 444E: Cj,%, k'- -3 ~ A,' 71~~ 4~Z
14 tN jL),
3 A
1 1 4&1. 7 u ' S g FLK)E~u -as ~dde-~ the th~
Ier i- I aw-E. of 66. -hk,-h I ed to -einp. rim to IW*, indicating
vlow virmoiii zddln.; dista. gave rhnS';OBs, th 74-4.5'.
0.9779. IAMS. To 2 7 1 EtPaBu was &&IH (1.2 j
Bul; with; 4 tnin- the temp ~l thr Inixt r-m 1. 141'
ielding F~,B. P.-, 4,-O~ RTCH,
adds 8 in thL wence of AICI, mWyst and PtvPCI adds
Stather enerpticalty. )-i0ding EI-PSC- b- 90-90 V, 1. 1438.
1.5294. For the papn -f EtzPCI, Beeb- 2nd Nl.nn
CA. 415. rx),U~ K"IWF7
7:

-P
.j!
and
T~
A -
a-1
0- XxTi-
vNA
am
With
a0'9. JMV0 the tc4
J.090D 144
MCM
XM VIR cff. 87, c
cAr W 00: (
.)i, b, 102-8
PII- FN'
0 C1zp%gfiw, fn. 4OL-I*; JVC.
C4;41.
Civ)
1.4 P_
#,-- 1', '~R C&q
I DOE b4 20S-I()
b
b, 2. 21a~-23-
Cir, c N 72:
1h 0 74-6- 0 a?
b. 151- -ass'),
ted over X,, 0.0m , -0214 0
14480 .4&).q;
at jb" -
ThCSC "re hydr
b, p2-4. at
0 0 Ile dix-j..:
'ID-9904, I 4B,-O (Cliwcg ely, yWAr, ' 4W (dka,
1 2 30 x)~ b,
C-V2 E (2BI d,,
bs 12&-30. , L 23-7*); (C~j,
41-2')- C'u, _ 01)
I 4d=' MCHICH,C~j JA53D(d1--.BZji
di-Bs di, b. 118-25.
Cq 0.90,8
40.5-); 0,
Cq C 0 om
Z~6be,~ C, - 1_4W (di-B. CH,CfT;
(di-B, .v 1 71, ~~l , vi/ ~ b M. 5
C149 C11, Cjr, ' - - 'n -38 &-7,5 ' ' - - 109- 1 S
1 0785 iocHejjo6. - ); 11'scii C), , 1.3110
~Kvk 1.4ulo (di-Bid - 1-C14CArAPjj ll,)CftOC~j:
A,:~p ON'th77-8. "F,M ~75_qo.')' j,, 146,M
,),b3&5_60. og~~OROJ7,144&)- - , * C C
b,7&_,jd. OWi - . 1_44,1.0. pi p,hmC7 c
0.9106, .1.4W; '~ C111 C* - ffr.
CN,)V.Y,
c1. , th ol

I grmvWtospborpus add. &kUTov
21
Z. shi--hova
iTokiddy Al&-d.--Wmuk ~.S..SJC 91. -Slow
.-ddu, of the calvd. amt. of HvO and a buse (rj~-ridine.
r----------- I
hfe,Nllh, or EtlN) to 2 moles O.CH2lCH3,0.PCI dfld, with
.~-S parts MIO at abowt P oith stirring, filt-ring
after 3 CH.Ale H~ 0. PO P(O R 4; Ei z, 7.; 4

Ia
Distr. 4E4J
vo,Parachor and aagmiltioll 0 1 1 and
Uc&-n>v
Xkim. 113, No. 8,
ULM. of pararhors for 16 arnines (no data on surface ten
sion or d. are sbow-n) indicates that primary and secondary
aramalic amines may be asiocd., since the deviation of ob
Served from calrd. v;dues rungt-s from I% to 2.8%, whereas
tertiary amines peld dtviutij-as d less thu-n 0.71/c.
Antong
the aliphatic aming,,,,,11 primary amines aluo are
as!~ocd.. the
demp of ass"M. Casing wiih inrreasing inal wt. Only
MeINH and Et,N11 show assnrn. aniong the swondary
aliphatic am.,nes. Terdury Bmines are not assTx-d The re~
suits are based an Giblin ' th r tical cunsiderafiDm of the
a IDIM 5 Co V
pa!aehor (C-A. 3~~,)- G. M. RO&Wq)aff,

7"

j

V-Zav,ntbesid or extorg-of 009pborite acids containing hotivd~
-
l
l

da w
tit itonty.011D
WOOL IV,
Vktrro tit phowphonk4ia

1101, 111noxalino radlcafi;~' 11. A. Atbuzov
awl V. M. Zotlm-

strova (%,. 1. UPpinov-L64a"S lVea ~, M,xan). lzr~esl,
i
Xh
N
1
k

im.
1954, %6 -
Akad. Xazik S.S.S.R.. OWL
au
1,
t
o
V
10
d
1
b

0
c.-
rate
t
to
cf. C.A.. 47, 487
),
g-) pre
.

all()
treated dropi
.
e 69
di
F
i
6
d

-
t
qt
ruixt, hoted I hr, Lu 4jv-
and d
. gav
the
71,

1100 4A8-'0;- similarly ims obtaitul! 211,',o' di-Me esler, b,

3.27447,- uj~- 1A670 (d6tji. 't3f a-larger- amt. of

as
thc produbt lvas pmveoted by sevcre decoutpu.), as WV11

#35.40-' di-Pr
ester 160~2% dP 1.111AI n2p, 1-407B, and
-15.6f. di-flu IM4-. dt-- 1.0750: tsi? IA575 (the

reaction %Yws run
ally, (tt Isi-P5. The
at IM41W, und hit
d I-E ( ester wa q obtained In 17% yfelo from the

IntthyINSUmZ010 and
(E1O)jPONa in rt.O. - lieu ng the

di-Ft ester5 hrs. to 120-5' with dil.
HCI gave an uncrys-

7
utilizable tarry product. .-The di-Et ester (1.9
g.) tefluxed

4.5 fin. %ith Ug. KnOff in 60 ml. 11--0, neutralf7cd with

HCI, evapd., t-its). with abs. RtOH, the ext. evapd., ard

the residue
bailed With BaC01 9aYe a YCIJOWiSh B4 $011,

P4H,04NPLIat of the free

which lids anaI3
wd (the product 0 Itigh in Da).

'Id
Condmu-ItIon,of (UTCHICO)l 'A h VHh In MOU

-gave m. 351-2'. This.(2

g.)
sutd:1.65 1c. (MeO)aP reflaxod 1.5 Itts. In 10 ml. Colls
'
'
R

5i min. to 130
. then cwled and rubbcd w
concd.~ hented

pdrvet1tr gave 70.6% !dra-Afe yf.

phosphanald), m.
115-101 (front Bt,O),aahin HIO; hydrolysis

entq oi some jt~!:v~rires
inom.
On,

rl.;;.'OT~Vropylcue glycal"pbosis' 46do,00a froglent i:iYcol"-
-
'
-
F
u
v

It
. A, AtN
t
il Ni
K
N
-
l
nelt,
X"Mrft'
l3r
K
ShbWor4 r
;
1~4
Z

lu
.
.;-
trs
l
'A'
a
:
i G. '
--ru. Akad. 1V'1stkS.S.S;x Old q
-Acad. SO: It.

Kbitq. Kvt.4 10%,:,23-~5-Addu. of 46.1135 t. POCI, ut
m-3

t, wid " .2.3 g. WcCH(OH)CH,011
in 2 lirs. to SIA g. PhNr

(1) in.Ftj0j followed by 2.6-3 Ists. at
romrk ternp.. gave after

filtratims and distit. 21" 7ci4 C1111ti-1.0.110)x (11, x -
0

CO (111), N 102-5', tl:~ L-12ta. "J*' I.-IMIG, siasllarreactlou~

s,f
68 c, I'SCI& mid 63.5 g. pyridine Its EW with 304 g.. I

addcd over
1hr. at -S*, lollowtd by 2 hrs.* at 25% gave

43,5% of Ott- (IV) of
111, b4 A2-4*, an I.M.,

tsjb~ 1.6000,-* Iff (25 g;) added to UtONa
(front 3.07 f. Nlai

mispetided lit J7t,Oat 0-2*i followed byseverul
hrs. Ftt roont
'

temp. gave 2,171 - 0131), bs 10-5-8% do 1.208, tito
11 (X
i
i
l
I
e
il
l
f
h

low
t wer
ar
c
e fo
sim
1.4205. T
d,
ns
y trepel. M %y
to
114-18% 1
273
lv
t
d
M
O
33
b
d
)

.
is
c
t
e
.
.p.,
p, nn
,
,
, j
g
1,42-3oj rro. 34.8, b, 116-18% 1,1023, 3.4290: BjiO. 32.2,

bo 127-3D*,
1.121, 1,4312; isa-DvO, 32.9, bi 122-4% 1,133. i
'Itt
ridine
ith ROJI I
rtsence
ol
O I
th
4310
IV
1

.
.
n
.
.
w
n
e p
s
py
*01, 41.8, bit 121-30,1,2639,11,4M, ElO, 55, b. 107-

1.209, IAM; PrO, 01, ba 110-12', 1.187.1.4741, iso-
8

PtO, 38 bs 11)4-0o, 1 188, 1.4740; BuO, 52.4, bi 114-16%
1.1435.1,4730; i.,o-B;O, 38, b, 112-15*11,08,1.4720. All

the esters
were tested as Insecticides ngainst the floar weevil;

all were ramh Im
effective Ilum teirp-Et pyropho5?hatt or
thlonopyr6plosphatc (no specific activities are cited,.

u

-,
77 -7
tW 'at '&*#I -balides on 04 of- ant
'A. Arlyutiy'
Wait Acids, ~ B;
and 0-1).Saitioucivii

auk S
Olde)
S
S
R
WNW Mllk- IPS4 8304, d

.
.
.
.,
.
45, 751fb; 48, -IbM06-Heating. 7'g. (Et6),~%
*'7
"
'
1k
I-
;ftl
110
6
OJI
2

-
A-.
l
.
in
to
0
yielded 3.0 g. FCtOlI aud
C.

7.3 g. (j3o-vlmOhSb, 6, dn'I.IFD, mj? 1.47C4,*

11caMullS C.
(13tO),Gb uud 8.3 g. Met in "10 t-j" 3 hri.
*
t I .
OIZ
MO
Sbl
72
d

-.G
a
gove
. m.
6.1 C. ttn-
, an
)~
;O J
reacted (IROV%. It shnilirly gave in 2.8 hirs. At 170-

_
I -Willi Eto, mine-Sli, hx3ftie,and
7

4 hm pt'IW-
t r lit a Arm tar i Ed
i v3dion VV n

48 V),SbBi'm GG4', and mine Et,C), Sb, hxlfnt~, ~nd!
,
00
f

.
prDI In 6 lim at
Slh 1;; (Rto)~S
l (1
15 X.) and 7.2 -
(lIt0I
SbJ;r
s
u
a
d
S and 297
4
6
m
(FtO)

t
.
.
n
a
ave
S.
t
c
,
s
j,
RtOPr and sojn~- Sb
mtin
with 2A
16 g
long
%

,
.
.
a
g.
j
g
(DuO),Sb with 6.2 Met 3.0 hrm. at 185-W0 guVe 2.9 1(.

-101 strailAfly
gave
SthO, arid lodni. EtBr in 12 hro. at 20D

49.9% (Burl),SbIle.
bs'149-M', dy, 1,5931. 2.1 g. BuORL

and swnt SbA. (Lqo-AniO)3Sb hud
Mel in 6 hm. at 185-

2D0! gave sme MeOCtl,CH,CHVN ninni; with 43.217,

(is*-AmO)23bI. b4'l&`i,-V. do 1.0315. sortie iodire, %b atid

%0&1 With
EtDr the prodocts utter 0 lire fit IM-210*
I
W19
owAmOhAB~
Sb
b
I
O
d 42
(i

.
.
j
mrm
s an
,
r
,
, b
421 i
8
N
ti
ct
t
(13tONSl
d CM
r
r
k

i an
n
o
eac
ori too
e
e
ween
1,
li
*

firis., at 20D-15
. Heating 10 S. (L?1!3),Sb and 4.8 g. Mel

2.6-hn. at SD-50 gave 3me
Sli, S,und iodine along with
MeSRt 6d 20.4% (Etsy%r, b. IU2,1', dn 22M0. RL-'

action with EtI lit
1.5 hro. at 76-800 pvo-46h (RJS)IW
1
h*R
Iq
RtS Ob
l
I
10
5
d

N 161-2
ong w
t
t
.
s. 22M. a
. (
,
(
and 3.0 g. Etlir in 3 bra. at 7040 rive 2A X. RtjS nnd 46.8%

0 r

'k IR I? I 'RIM
0
=0011= 101F&, RIPON

"SynObtFiE of Som. v:z-.
MA,
-:119 Q~
"ENT

I I f . . . .

A

hemistry.-;------Phyt1ca1, b
e
t
UM/7. ry,

27:
vi~
v Shavsha-Tolkacheta,~~ T.

.title

11 16~1- M U 6Ah Ind
opi --an th f
*n esi~i re
PO -c a or o o c ac
opropi

Peft.
-611~' 6 1954%-
Au 9k

Al~
Ths,

di OP i'O~fpnia and" fort-dc acid
'

'esters wore_;6e
&vt tn~d and.Ahe:..results.are- shown table

te of Ahe abo v*e mentioned estert "are much
ntAhat~ihe AJ~6,e momen

higher' thaW the moments , of- vrthoc6rbonic
acUesters An:

:anslogy Im en.phdaphorous: acid esters and or opionic aoid.esters- -
thopr

-of individuiLl
waw established b 1&6-di6positi
, y. ~ . on of the dipole-Momentsi

le; int
bonds. 12 eratomic spaces of various moletular ester modele,were
'

caicxilat~.,Cl with consideration- of-the~affec
tive -radius- of

..Usk
fes. eas- 6-USSR-_'2:Ge (i929, -
a C 'Xi re TIC raian. a~d

0 195 es

~Inetitution

the VO I* Bu
Lenin Aite 'Unkv6rsity...The -A. M. tlerov Scientifi6 Research

Institute Kazan

'Submitted

he 1
Ju 25j 953
wo

Cbeidit27~ synthemis

Cara
fl/l" Pabo 41~_' V27
'UtUars
'Olmsov B A Rizpdlozhenskl~rs
N 1,

fit"

d,'~,!Rstera and acme of -.their conversion,,
I'VIFt 40

bYutheils 'of
othyidlit4ijimido.forlilKphdophinid acid eaters
"r1odical

AN SM 'Otd
Isy
..kbim nauk'4 631 6350 ja3,v August,1954
Abstract
1 716 apthevis,of.
:qtbYjdjethY_Jamjdofor*j&

osphinio acid eaters"
thiough
0

tba,reaction-~f-dietbrlca~rbamio- acidehloride.urith sodium salts of~

ethylphosphinia acid seters',is desoribede The yield of the reaction

product in
this, i3aae was found to be mch lower than the *yisld cbtained

during
regroupiAg.of absoluto.etbylphosphinic acid eaters. Tho

pbyeical rtiei., of the
eaters obtained,.are shown in a table.
prope

Seven references I 'USSR; 1 USA and 1 German (1897.- 1952),
Inatifttion
uAcad. of See USM~ Usan Branoh The A, Be Arbuzov-cbemica institute

Jws'199- 1953

AUTIZOV. B.A.; BOGONOSTSEVA. N.P.
- Ommm
Abnormal reactions of sodim diethylphoophide and
triethylphos-
phite with certain halogen derivatives. Izv.AN SM
Otd.khim.
nauk no.5-.837-845 -.0-0 154. (MLRA 8:3)
1. Bauohno-iseledovatellskir IchimicheskiT
Institut im.A.H.
Butlerova, Kazanskogo gosudarstvannogo
universiteta, im. V.1.
M lyanova-Lenina.
(Phosphides)(Ithyl phosphites)(Haides)

Periodical Izv. AIN S~SH. Otd. khir., nauk 6, Nov-Dec 1954
Card 2/2 Pub. 40 - 13/27
Abstract The synthesis of ethyl ethers, mixed aLk-yl ethera and
ether-amides of
monothl anr! di".HopyropLiosphorlc ac-;~ described. The
effectiveness

, f w'!mp-ate,
fz-,!,-~s~;-.,~.,~~~,~Z.'~--,-$T,.~K------~i,~;~ArmIE5---~Q--
-

US"R/Chemistry 3ynthesis
Card 1/1 Pub. 40 - 15/27
Authors I Arbuzov, B. A.; 11imov, ?. Zvtreva, A.; N~-klescva,
D.- and
Title I Svnth~ s4.5 of am-eEs of
Periodical t 1-.v. AN S,5,03R. Ctd 'Khly,-,. rw-.,~-.
AbstraiDt I The derivation of numerous oreano-phosphorous
compounds is annoimcf~d and
snme tl,-r
Rnalv-4- of t!
0 r 7A f. 00 t
Institution Acad. of 1,11; Kpzari 'Eranch, Tne A. E. Azrt~uzov
Chvmlc~l InstiL.
Subrd tted January 1~54

ARBUZOV. B.A., akademik.
.The A.M.Butlerov Chemical Research Institut. Uch.zap.Kaz.un.114
no.9153-76 1 54. j (MLRA 1013)
(Knau-Chemistry-Study and teaching_

ARBUZOV, B.A., akademik.
__ --.1
I
Basic trends in the activity of the Department of
Organic Chemistry
of Kazan University from 1917to 1954..Uch.,zap.Kaz.un.
114 no.91-77-
86 '54. (MLRA 10:3)
(Xuan-Ghemistry, Organic--Study and teaching)

- ,zzl-~------,-.--=,=
I -'i- - j~,~ ~ ~ ...- -.- . . ~ ~. .
"- f - - - -,
T~. -~,- I;,-,- l------
.~L~~ .1,
I ~- - .. . - I I . .

--- -.;., ;~ _.,, btCC& I t~i:' ; .- - - - ; - :: -
-V" ,
'A -f . .71 ~
! .1 vrXI. .,.. . - , - . . , , . 11 --%;.t !I I
4 -" -1 --

a3-Imtst I ril
=

'TD 3.d
M - Vinnkumya
ib

",!-f W !"i at ll,) vho

A,11. thr t-,* p.,..

;P. i !-

12.1 2i, i~
trtl_~,j.

Ojr I iO_~, -btmnol

La 73-Y :-Ad. t:uttld ..1 1), dwd
~Itho%st d--q...
, 'I a_t ! ~ . J! It, I *u
d[, Ilabl't w 1,!1u! I,,

M,

m-~lizvA.1 -q-,t ;t,.

aft 2 3 1, y
zzpcx4j-zi the othet itite" wtft my istuch

G. 111.

vi
'i`~~Ogang OAXAWXd stutimonous acid. li~ A.
(V
310. illrtif. 144. Alauk 9-S.S.R., Oldel. Khim. Nawk
Sami
iNS5,67440- di CX, 49, IM M w-Addn. of 7.5 g C),
IvIt. I Intl) Ing to
in C110, witil g( .uxi pmtvv~
www' antst- Iarcm; U moistum gave afivr evaiml. of flic."
solvcui~ (M))3sbC1t. -in. zo~-3* (froin litiOl. lltzItiug to
IM, foiltif t4yieltUatty volatife ps-Wucts. (im c%V M'eW
in,' 'vidding sonir 7% MICI ami,
218% Rt,O W tilt (16tilhate, wljiilt~ tilt, rLsidu
-.ulid' o1iiijusited to on distil glive 8.6%.51)ch'
m.- 70-21'. Situitirly adilti. of MAI R. lirs III
r. (A.'to)L"~b its C110,.with 'vs)Oog,g:%vv (r[O),SMr,,
13441, 45 g~ of whidt dmomp.. vigorotmiy. at. 130-5%
yielding 5 4 Fg. M011, and 2,'_1 g,
~);l g. EtUr, 3 g. L
Breff C H
t 't, Addp.'of r,.2 C14 10 cu"Ied 0110)X%1k (25
B.). gave"A."dollt; 141ttid (13110)sSb Gl-'o d-v L'UrIA " this (27
S.) Itcatild to 13U-5* decompti. vig1wrousiy, yiebli!)g soule
(NAtted by ditil. of III
rv,'Muc), -7
7A g. hji:~O. Simil:10%. wn!s ptel (Bit()),-
N61Jr,, dAIL,05., PtLat M11,30, Yielding
2- 0 lIrt'.110. Itnj3r:_ 2x 111,011, fill (I
~O'Bu.~alvj :1 T f;oyll 'wbich wille 'SbOrl
t6rjuld be (16td~' J1vtijjxjtq,; Ett)JI of IWI willi
I
T
I gjve 2.1" g. ppl.j. Avilitv sx.fift, Nyllile
the gave AV'T':~" ttuclmng,~d Dr.11, 11.2~'/v
Phe W1 F mid Ait'~" I lKs 13t; t ]w it-i4i lit-, di a I st th'An. Was
In. 63 4 l'i-I'tC110 -.Intl 5 g. (1410j's
I)fIrt
a wCaled tilbea rv'wtioll k1ollialk-ace'd ut r(K-Itt
Ivillp., ufj(~ SVIKJ. -.314d 1110
0 h(S. Ill OW PIA. '%~tl
filtrate g;M~31.2 t"' ii1j-1*r ,C110. I PS g. h"14401t' and 141 g.
AWIlixistg, E
'WN Solo. tq UZ11
uIld (11tio)'ShC1, 25 111,,;. failtJ Io mule ally detceiithk- rt,.--
acticill,
4M
-A.

-F-7-
VIALhois ca lboubwo uld egan WIM hateroonno "At-ILIL
V. Phwpbjouk &Aa estwo w1sh dibydroeoumarin radleLls.
Xrbuzav &ad V NI Zoroa-,tr,;%a ~Jnv A A ad
pbar,,
ph-%m, -t., 2
obtamed ' 3 4 A a-
dibuty: d~t.Q;6 kn d 1*1 J !L.
Corm-W-Z-A -.-ipbc :Jid
ezd th,,~ '41-thyl 3
pbomic aczd. A 1- 14

fAIS; PF~ 65. -13--4'/ 10, 0 1,44:30:
O.W,)6, 1.4569. EtP.\'Rt,Cl failed 'to react %,i1r) ~'tt
120', bu! if a !ittle AIICI:
1,22-t~- IILI,1 IAC~'A'2; E-1. 73, iB
G5. 9-4-5*/1, 0.9899, 1.4ROI; iv-P,.

131-7.5 12, 0.4 7S. 1 .47,1~9; M-4, 144-4n'
IP 2~ l7tY 2'j I. U:-440, I ASoO F! Pk t
d. O.W 0. f,V J.C'L5, QDd TA,Nll.llU- I ne :41 r,"nt"-
4.78 -o -,~l
for thr " wom in the thiod.e.iivs. 7/Z

1-1-4 -- -- --I1 .-0. - :---- :-'-i-
, . -i-l- -.--
, --I"

ZVI
F.RR R,

ARBUZOV, B.A.; GRECHKIN, N.P.
-PIM
Synt)10808 in the flold of pyrene derivatives. Izv.Xazan.fil.AN
SSSR Ser.)chim.nauk, no.2:31-37 '55. (MLRA 10:5)
("no)

-A~
USSR/Organic Chemistx-y Synthetic Organic Chemistry, E-2
Abet Journals Referat Zhur - Khimiya, No 1, 1957, 962
Authort- Arbuzov,-B. AA,.and Samoylova, 0. D.
Institutions Acaa%W of Sciences USSR
Titles Action of Some Trialkoxy- and Dialkoxyotibine
Derivatives
Original
Periodicals Izv. AN SSSR., 1955, No 3~ 435-"0
Abstracts The partial transesterification of Sb(oc2H5)3 (i)
with equimolar,
amounts of higher al, aohols H10H (not higher than C6HI30H)
yields '
Sb(OC H )20R' and Sb(OC2H5)(OR')2. Transesterification also
results
2u
Lp reaciJon with RCOORI and glacial CH3COOH* When
dialkoxychloro-
stibines are reacted with higher alcohole an exchange of
alkoxy
groups taken place. All experlmate Wore carrtqd out in an
Arbuzov
dist,111fition flock with the a 11catlon of heatj 18 ps I sod
4-5 $me
D-C4 OR (at 110-1150) yleld-~.9 90 Sb(QC2#5)2()3'0C4H9) (11),
bp
00/7 1 1 D -
mn n2O 1 4902 d!d~~-3990, 3.2 -021
bp-129 130/7 mm, 20 1.48k 1.3051, angdmhb(OC2'~)(OC4~,
nB (OC4H9'n)3 (I,
Card 1/3

USSR/Organic Chemistry - Synthetic Organic Chemistry, E-2
Abst Journal: Reforat Zhur - Khimiya, No 1, 1957, 962
Abstract: bp 140-141/7 mm. The following have als o beip
prepared by a similar
method (the ester, bp in o C/~mm n20 d du are indicated).
Sb(OC2H )2(0C Hil-J) 120-121/6,'3185'671 .3452; Sb(OC2Hj)(OC
N-iso)2
(IV), 1-137R 1.4815, 1.2630; Sb(OC2"5)2(OC H I ), 51-1~2
1.484o, 1.3313; Sb(OC2H5)(OC6H 171-172/t,11.4743, 1.1982.' When
4.9 gms 11 are heated to 150-1~80_11for 20 minutes, 2.9 gms I
and 1.6
gms Ill. A similar disproportionation is obtained with IV.
Reaction
of 4 gms I with 6 gms CH3C00C4Hq-n (V) (one hour at 110-1150),
o.6 gms
III are produced, Under the same conditions, 5 gms I and 8 gms
CH CO~ H 1-iso give Sb(OC5Hll-iso) in 82.4% yield, bP
156-1570/6 mm,
r;-!. A 1
85, with the evolution of CH3COOC2H5 (VI), Reaction of I
vith C6H5C00C6 in 77.4%
2% (30 minutes at 140-1500) yields Sb(OC6H5)3
yield, bp 238-2 0/k mm, mp 99-1010, and C6H5COOC2H5' Ten grams I
are reacted with 2-3 gms glacial CH3COOR and distilled at
30-400/90
mm in alcohol. The residue is wasMd with Sb(OC2H5)(OCOCH3); mp
50-
510. At 100-1100 decomposition takes placa with the evolution
of VI.
Heating of 12 gms Sb(OC2Hr,)2Cl with 6.8 gmB V at 110-1150 gives
Sb(OC4H9-n) Cl in 9C% yield, bp 147-1480/10 mm, d~O 1.5o66. A
simi-
lar procedure can be used in the preparation of
Sb(OC5Hll-iso)Cl in
Card 2/3

ARBuzov, BoA.; SAMOYLOVA, O.D.
Acties ef halides *u, astimosous acid soters. Isv.AN
SSSR.Otd.khise
sackno.4:676-6ft JI-Ag '55. (.Km 9:1)
.i
1.1auchao-isslodevatelfskly institut inexi A.M.Butlereve,
4smakoge
geou"rotyessege usiversiteta imaiki V,I.Mlynera-Lexiss.
(Ant Isonous &4d)

ARBUZOV, B,A~; ZOROASTROVA, Y.M.
Synthesis of phosp~ixic acid eaters coataisiRg heterocyclic
radical@
Report me.5. Pbosphinic acid eaters with a dihydrocaumarts
radical.
IzvwAN SSSR.Otd.khim.jkauk a*4:681-"688-JI-Ag 155- (Km 9:1)
1,Xhimichaskiy sauchme-issledovatel'skly institut imeat
A.M.Butlereva
Kazanskego universitets, imeni Ullyaneva-Lezina.
(Phosphiale acid) (Hydreemmarim)
%U~ ~K~m -

AIRBUZOT, B.A., akademik (g. Kassa').
V
"MOMMOMMM14
Kazan school of chemists. Xhim. v shkele
lono.6:10-17K-D '55.
(Kazan-Chimis try--Hi story) (KLU 9: 1)

ARBUZOV, B.A.; VILNOGRAWVA, V.S.
~
Parachers of methyltrialkyloilause. IZV-AN SSSR
Otd.khim-sauk 86 ne.6
1031-1036 MY 155. (MLRA 9:4)
1JDdmicheski7 inatitut imeni A.M.Butlereva, Kazanskogs
gesudarstven-
nogs universitsta imeni V.I.Ullyanova-Leniia.
(Silane) (Paracher)

-2 -0
v

nds
XMR/Ohemiatry ithiesis 6t.orgv,,no*ajhor6uS coqxra

Ribo, 22* 24/52

hithore:

Arbjjzo~- B 'A' c
Acadevi ian
P and,.Yaruxk1wwtova,, D. Kh

Title i
Esteirs'of
dinethylamidophosphorous and divethylamidothiophosphoric-

acids

Pealwical I.
Dok., AN SWR 101A 675-677s Apr 1955~

Abstraolt
mater.'
Al i
:.'on the synthesis of two-new ,

organophosph~oioui esters
of-dimethylamidophosphorous

esa.
aci& and bers of dimthylamidothiophosphoric acid (in abbrev.

dimthylamido- and dimthyl-amidothiophosphates), The physico.-

cher-cleal constant's of,the P-conpounds are presented in tables.

Exper-Iment.-3 were conducted to determine the effect of metbyl and

ethyl iodides on dimethylamidophosphates and the results obtained are

listed. The derivation of other phosphor-base by-products is briefly

described, Two references.* I German and I USA (1903 and 1950).
Tables.

Institution t
Aced. of So.,, USSR., Kazan' Branch, The A. E.
Arbuzov Chem. Institute

Submitted
Jamitary 1) 2.955

ARBUZOV, B.A. (Kazan'); ISAYEVA, Z.G. (Kazan')
Isomeric conversions in the series of terpene oxides.
Uch.z&p.Kaz.
un. 115 no.10:32-35 155. (MI.RA 10:5)
(Isomerism)
(Terpenes)

ARBUZOV, B.A. (Kazan); VINOGRAIDOVA, V.S. (Kazan')
Ksio-:Wn-ol tautomeriew of some phosphorus organic
compounds. Uch.zap.
Kaz.un. 115 no.10:36-37 155. (MLU 10-5)
(Phosphorus organic compounds)
(Ta4tom'erism) -

ZOROASTROVA, V.M. (Kazan')
Eaters of phosphinic acid with heterocyclic radicals.
Uch,zap,xa%,Un,
115 no.10 ;37-40 155. (MM 10:5)
(rhos Vcia)
(Radicals (Chemistry))

ARB'UZOV, B, -L. and V1110GRADOVA, V. So
"Esters of Ket-ophosphonic Acids and Some of Their Properties"
paper presented at Nn First Conference on Phosphorous
Gompounds, Kazan,
8-10 Dee 56
SO: B-3,084,841

AIZ !-',I A! . 11. A.
aths of Develourment. of Orimnic Derivntive,~, -,)f
Illics!,horus"
n-aT-.er !-..rc.~~ented it ',,In First boniperence on
T'hosl,lilnvous Co:::-omids,
Ka,~:M, 8-10 Dec 5A
B-3,081,,81,1

7-
RWINZOV, Te.A.; ARBU OV 4., akademik, otvetetvanW
rodaktor; XOVSSC-
ROT, K. G. *"Vmot '4z
, rel'Rtrw Lddpatel'stva; KLIUNI, Te.T., tekhnicheekly
redaktor.
[Pbtroleum of the Tatar A.S.S.R.] Nefti Tatarskoi AM.
Moskva,
Izd-vo AWsnii nauk SM, 1956. 157 P- (AWsmila nauk SM.
Taianskil filial, lazan.-Trudy. SorRa khimicheskikh
nauk, no.1)
(Tatar A.S.S.R.- Petroleum) I(MLU 9:12)

i "

- so a P, - - wo- -a sm-

" . - ~ ~ 1- -1 1 - I ~ I .
. .~ I IV.1 - -~-- :,-- -1 + a : , !
I.- . ;
... . I - . . ~ i . I , .. - '-.
i

Esters- of Beta-~X6tO"P"jjo'sthordc Acids P'Communication 1.
'Phospho-
acetic Ester, Phosphonacetone, and Their Homologs," by B. A.
Arbuzov and V. S. Vinogradova, Chemical Institute imeni -A. M
*'-~a e~~Y ime
-fu-t-lerov, Kazan ni V. I. Lenin, Izvestiva
Akademil Nau
cheskikh Nauk, NO 1, Jan
56, PP
This article outlines material indicating an analogy between
carbox-
.-~';Ylic acids and beta-keto and beta-carbalkoxy derivatives t
of phosphonic
--Acid esters. The phosphonacetic a
nd methYl phosphonacetic esters do n
0
~vqontain noticeable amounts of the enol form. Both
phosphonacetone and
thyl phosphonacetone contain small amounts of the enol form, as
deter-
ned bromine titration. Considerable enolization was found to take
place
an alkaline medium. Esters of beta-ketophosphouic acids as prepared
gepent,-
-*,.Arbuzov, I a.-..rearran -.4ve..-.,prpl)erties..differ~ng -fr=
those-as~-iDrllk7
-Vift
,Pare WIR d

C7 -f
USSR/Chemical Technology - Chemical Products and 1-7
Their Applications -- Pesticides
Abs Jour : Ref Zhur - Khimiya, No 31 1957, 8838
Author : -Arbuzov, B.A.
Inst
Title Applications of Organophosphorus Compounds.
Orig Pub Rhim. nauka i prom-st, 1956, 1, No 1, log.
Abstract A short communication on the conference on
organophosphorus compounds (Kazan, December
1955).
Card 1/1

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BUIN~Iv3z"MPY
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J
USSR/Organic Chemistry Synthetic Organic Chemistry, E-2
Abst Journal: Referat Zhur - Khimiya,, No 1, 1957, 956
Author: Arbuzov, B. A., and Grechkin, N. P.
Institution: Acaaemy of Sciences USSR
Title: 'On the Structure of Phosphorus-Containing Organolead.
Compounds
Original
Periodical: Izv. AN SSSRY Section on Chemical Sciences,, 1956,
No 4, 440-442
Abstract: The formation of RP(O)(OR)(O&R~) (I) from the
reaction of (R03)P
(11) and RjSnI (111) is confirmed (L. Malatesta, Gazz. Chim.
Ital.,
1950) 80~ 527), and not that of RASnP(O)(OR)2 (Dokl. AN SSSR,
1947,
Vol 57, 353). 11 undergoes the Arbuzov rearrangement, and forms
RP(O)(OR)2 (IV), which with III yields I and RI. One mole
(C2~5)2&12 (V) reacts 'with 2 moles IV P = C2H5) at 1250 to
give
C2H I (yield 72%) and CC6H5P(O)(OC2qH5)Y2SD(C2115)2 (V11)
(yield 78%,
MP ~292-2940); the latter empound can also be prepared from
C611r1P(OC21'5)2 and V. The hydrolysis of VII with
concentrated HCl
yieids C0~005)POH. When 2 moles of (C6H5)2POC2H5 (VIII) are
Card 1/2

USSR/Organic Chemistry - Synthetic Organic Chemistry, E-2
Abst Journal: Referat Zhur - Xhimiya, No 1, 1957, 956
Abstract: heated to 2100 with one mole (C2H 5)2SnC'21 LTq H )
P(0)92Sn(C2H5)2
'33 PO. The forma
(IK) is obtained (mp 346-3490) together with (Kk
tion of IX is apparently related to am intramoleculAr
oxidation reac-
tion of VIII; this, however, is unestablished. The hydrolysis
of IX
yields (C6H5)2POH; the reaction is quantitative.
Card 2/2

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'r " V - /
u / J? 17; -
I
~71-

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f
Ultraviolet absorption spectra 0 orpil AP)
. . . . . . . . . . . .at M v unit
oule fin
o a
NaskSASX. lit, V U50). productions ultra
VMM
Awet Ab9mO xim ~iuv xiveil I Soins. of myclul cSters
n
Akenji (Uphate
of. ktio th" rioXc 4cids and of their' I
anakso 11011andlaROH-RONa. (HIO~JOVIIAIn
Lw a spectruin sintiLar to that of Ac 11,COBt Ito
MCDH
_M 0
1110, inwead ig -very .1ittli enal form; in MeMa~
soln.Abere is: a-max, ~C2400 A.', Indicative of cousicici,
concu. of enolate Ions-, (Hto~P(O)CIISCOI:t gives a SIM11
spectnun whitih is similar. to that of BuSO~CH%Ac (ci. Felmil
1; and Carmucki C.A., 43;- 4215i). MeOH, hexane. or- Iho
solvents iveoubstantially the mime spectrum of jO),P(O)_
~7 'The spoctrisin of (Etp:
CHA a
Possible coniazalaanCaf: the abovq,*sliows 4 m4x. 2500
A., In the. Io6atlew in iwhkh I has it min_ MeMia merely
;-enhances the 2500 ba~&. The'above remits were obtained
o -and.XCH,Ac. from
iiifr m (HtONF - prejA.
'(MON Ni, CHAc has ttstfi6other obabiptiodcurve
; t Bt
and )ads thb, max. -at M A.;'In WONuAb8% specimen
also has,the enolate band at 2400 A. -(]3tOhP( ~ChfcAe.
L PiNVA.- (mv has less than I iten with Dry.
(M~P01qa
7,,-_--.,unchanScd:'-by. MeONa. (BtW(O)C1-I,COPh, prctxl.
linstlyoull
from I -Unt.
sad; materiul; its spectruin In_ McOll duplle~tts Oat of
4
10,v
_7

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W.

24

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IS,
aife if
Ulf.
o
3
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eoll lfl~ 245f) 2&'9)w
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a
jarI
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it
mlid
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pe of. tile
"'Cake"
ens, fil )q
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tilli and
, "9 - Io
fr
e

l
V
or sell
An -ft? A "IN it
ann
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1t.24,jo'A
143
, M; lint
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er. I,

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pectrut'l,
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- Uamir

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<
Addition Of PLhc!nol-!c,

Ad.

the j).
Wm
et 2wfl-I of t"w CO
group. I'm tiler clavlm of I -ho-O O!'r it NO-d t., mact
c-I
wt with Br but Tvith thc 00
group ivith interale(Hate ~vtmntion of 13rCH-CNIc(ONa)I'-

"f;.7,t
law
rlehr at 171
9 ecimen r;3
, '-d-

LTIBUZOV,.B.A.; ISKHAKOVA, I.Kh.
"ft*I0_ft"bft_'.~
1.11"MwWathesis of anthracene with acrolein and acrylic acid
nitrile. Uch.zap.Kaz.un. 116 n0-5--113-116 '56. (ULR& 10W
1. lafedra organicheekoy khimii.
(Acrolein) (Chemistry, Organic--Synthesis)

-IBU7
J
U
USS'j
"A Stildy of T3,~~
PIlyziochem-Str'! I. a0lipingr Jjc(:Orajjj,3 t. h.
E. llrbuzo~,' Usin,3
roper stfumittea
u
ClIlGrOss of Pure and AIDDlied Chemis at thL'
.16th Interna-ujoral
,try, Paris, 18-24 lp',T.