SCIENTIFIC ABSTRACT BABKINA, N. G. - BABKO, A. K.

Document Type: 
Document Number (FOIA) /ESDN (CREST): 
CIA-RDP86-00513R000102910010-7
Release Decision: 
RIF
Original Classification: 
S
Document Page Count: 
100
Document Creation Date: 
November 2, 2016
Document Release Date: 
June 6, 2000
Sequence Number: 
10
Case Number: 
Publication Date: 
December 31, 1967
Content Type: 
SCIENCEAB
File: 
AttachmentSize
PDF icon CIA-RDP86-00513R000102910010-7.pdf3.7 MB
Body: 
MILYAYET. Arkndiy Pbvlovich; BABKINA, N.G., red.; ZUBRILIKA, Z.P., takhn.red. I- ----- [Manual on sericulturel Spravochnik po shelkovodstvu. Moskva, GoB.izd-vo sellkhos,lit-ry, 1960. 345 p. WRA 14:3) (Sericulture) M."'IENU Ili IN, , A.P., prof... dokt.o-r, -sellkhoz. natd:. --as-L'. dieyatell nauhi R-F.,-R: BABi"I"A I o red. [Effective 1ife of fam wnimalsj ~Ircki ispoil-zovaniia se-il- skokhoziaist,veiukykh zhivotny.'~:h. Miosknra, I.-A-vo "Folos," 196/4- IS2 p. 17:7 ) TOI-VE, M.F., prof., doktor sellkhoz. nauk; &4BKINA, N.G., red. [Feeds of the U.S.S.R.; composition and food value] Korma SSSR; sostav i pitaiellnost'. Izd.4. Moskva, Izd-vo "Kolos," 1964. 446 p.- (MIIbI 17:8) 1. Chlen-korrespondent Vsesoyuznoy akademil sellskokhozyaystven- nykh nauk im. V.I.Lenina (for Toiiune). ROD I ,-,NC.,V . V,,V. I- ."-;HABi--R!)Hu)V, L A.; at. i3K N.,G, . r.:-d,, [Mul-tistory beEthives and methods for beekeeping) Mn-gr- korpusayl u.'Jni A. metody pchelovoz.hdenila. Izd.2.9 pe- rer. I dop. Moskvav Kolosp. 1965. A57 1). PADUCHEVA, Aleksandra Ieonidovna; BGYKO, Dmitriy Fedorovich; BABKINAI, N.G.J* red. [Hormonal methods for increasing the fertility of farm animals] GormonalInye metody povysheniia plodovitosti sellskokhoziaistvennykh zhivotnykh. Moskva, Kolos, 1965. 302 p. (MIRk IS:4) POLYAKOV, I.I., prof., doktor biol. nauk; BARPNIOVA, K.V., dots,.,kand sellkhoz. nauk; KAZANTM, F.I.I., dots., kand. Bellkhoz. nauk; ORLOV, A.V., dots., kand. sellkhoz. nauk;.BABKnIA, N.G., red. -1- [Practical course in animl husbandry] Praktikum po zhivotno- vodstvu. Moskvaj Kolosj 1965. 222 p. (MIRA 18:7) MASLOV, V.A., lnzh., GIADYS107A, L.P., !,~7)71. Us.-Ing resistance welding c:!' 3prayers and autoclav#3s instead of gas and autoira.-~ic wqld-ing under flu-c. Svar. proizv. no.904 S 164. (M:RA 17.12) 1, Kuntovoy Wel svarki Ponetakogo soveta narodnogo khozyaystva. ,,- / - I- I( /,1" 7 /- ) -r- 1/1, A / /~ -;, ~- /, VASILOYEV, Ilikobij Aleksandrovicb; BABONA, N.T., red.; GORIKOVA, Z.D., tekhn.red. [Raising sheep on state farms] Wtsevodstva v sovkhozakh. Moskva Goo. izd-vo sellkhoz. lit-ry, 1957. 91 P. (MIRA 11:55 (Sheep breeding) B A BFMTA , 0 . I. IlRelief Forriu-na. Activity of Sna-4 on the Eya:r.:.le of Khibin, the Territory Near Moscou and the Western Caucasus." Cand Gno,g Sci, 1..oscow City Peda,-,oZical Inst imeni V. P. Potemkin, Moseaw, 1955.' (KL, No 14, Apr 55). SO: Sum. No. 704, 2 I~ov .55 - Surve:., of Scientific L-d Techmical Dissert,tiOTIS Defended at USSR HiFter Mucational lnstitutions BA3KINA, V.iL., felldsherites. -.1400--Q ~11-1-*"A - Feldsher IAkov Grigorlevich Brusko. Fel'dA akush. no.1:58-59 Ja 154. (MLRA 7:1) (Brusko. IAkov Grigorlevich, 1892- ) L 15882-66 EWP(e)IEWT(m) WH 1ACC NR: AP6002807 SOURCE CODE: UR/0237/60/000/011/0027/0031 1AUTHOR: Denikina, L. I.; Selezneva, A. M.; Shchavele 0. S.; Babkina, V. A. !ORG: none 'TITLE: The depqndence of thermooptical properties of silicate glasses 'on their composition iSOURCE: Optiko-mekhanicheskaya promyshlennost', no. 11, 1960, 27-31 TOPIC TAGS: silicate glass, temperature dependence, optic glass, glass property ABSTRACT: The present paper gives the results of Wyexperimental study of the average in-! crease in the value of the absolute index of refractioii-in glasses caused by increases ini ------ - ---The four base glasses used consisted of temperature at 643, 508, and 480 mp waveliniffis. 1) S102-80, K20-4, Na2O,3-16, and As203-0. 1; 2) S'02-80, K 0-8,- Na 0-12 and A8203-0. 1; 2 2 3) S102-75, PbO-19, K20-6, and A8203-0. 2; and 4) S102-75, B203-3, AB203-0- 2, BaO-7, ZnO-4, K 0-8, and Na20. 1 0 -3. They contained various amounts of S'02, TiO2, B 03, A 2 2 2 31 0, C aO, K 0 admixtures. Experimental d A8203', Sb203, PbO, BaO, Zn. 20, and Na2 ata orga- ARKHIPOVA, T.N.; KRYUKOVA, A.S.; BABKIIIA, V.G. "Glikasin" sizing agent. Tekst.prom. 20 no.4:54-55 Ap 160. (Melamine) (Sizing (Textile)) (MIRA 13:8) FENIKSOVA, R.V.; PETROVA, I.S.; VIIT.LSYUNAYI'-'-',, BABKIIJA, V.G.; NESTEROVA, G.A. Use of proteolytic enzymes of Actinomyces fradiae 'or removal of j wool from raw hides. Prikl. biokhim. i mikrobiol. I no.3:257-262 My-Je 165. (MLRA 18:7) 1. Institut biokhimii AN SSSR Lmeni Bak-ha. BABKINA V G ; WRABIAN Y K.M.; OSTROVSKIY, V.S.; RABINOVICII, Ya.M.; BELOTSERKOVSKIY, M.Ye. 7 Liming of pig skins 'with a reduced quantity of sodiumtsulfide. Kozh.~'Oobuv.prom. 5 no.2s2l-22 F 163. i (MIRA 16:5) (Leather) BABKINA, V.G.; DOWNIMIN, MS..,, ABRAW)VA, N.I. Change in shades taking place in some vat dyes under the effect of moisture and temperature, Zhur, prikle khim. 37 no.6:1328--1333 Ja 164. (MIRA .18:3) 1. 1.1auchno-issledovatel'skly institut organicheakikh poluproduktov i krasiteley. NUFMXHAMETOV, R.N.; BONDAREVA, L.V.; _~APKINA V.G.; DOKUNIKHIN, H.S.; ABRAMCYVA~ N. I. Study of the behavior of some vat dyes in fabrics from their fluorescence spectra. Zhur. VKHO 8 no.5:588-589 163. (mm 17:1) - 1. Nauchno-issledovatellskly institut organicheskikh polupro- vodnikov i krasiteley. KURAMSHINA, M.G.; SHIKHOVA, N.M.; GRIGORIYEEV, I.I.; KONOKOVA, Ye.I.; BABKINA, V.L. Inpunological indexes and the biological activity of streptococci in the combined treatment of rheumatic fever. Vrach. delo no.9:20- 24 s 16o. (MIRA 13--9) 1. Sochinskiy nauchno-issledovatel Iskiy institut kurortologii. (ANTIGENS AND ANTIBODIES) (STREPTOCOCCUS) (RHEUMATIC FEVER) B IRA,--S-,L Influence of factors at the Sochi-Matsesta Health Resort on the amount of cholesterol-in the blood of patients with atherosclerosis of the cerebral blood vessels. Vrach.delo no.11:85-88 N 160. (MIRA 13:11) 1. Klinika neyrorevmatizma (zav. instituta revnatizza. (C.HoLESTEROL) (SOCHI--HEALTH RESORTS,0 (ARTERIOSCLEROSIS) (BRAIN-DISEASES) - prt%.,. K.F.Nikitin) Sochinskogo WAURING PLACES, ETC.) Resistance of ornamental plants to flue gas.-Biul.Glav.bot. sada no.33:48-w-52 159. (MIRk 12:10) 1. Botanichnskiy sad Dnepropetrovakogo gosudaratvannogo universiteta. (Dnepropetrovsk-Plants. Effect of smoke on) BABKINA, V -M. ''. ~ - Flowering decorative plants for industrial sites. Naucb. zap. Dnepr. un. 78:28-38 162. Selecting he-rbaceous decorative plants for flower g!%rdens accordinr tn the time of flowering. (71-85) - - -- - I . (MIRA 16:10) KURAMSHINA, M.G.; SHIKEOVA., R.'K.; KW'OKOVA, Ye.I.;,,_A~HKIN;Aj V.L. At ~ Dynamics of immmological indices in rheumatic patients. Kaz.med. zhur. 4t7-8 Jl-Agl63 (MIRA 17:2) 1. Mikrobiologicheskaya laboratoriya ( zav. - starshiy nauch- nyy sotrudnik M.G.Kuramshlna), klinika kardlologii (zav. - dotsent N.M.Slfflchova) ~ klinika aktivnogo revmatizma (zav.- prof. M.M.Shikhov) Sochinskogo instituta kurortologii. -B;~HKINA, V,Yil.; CHUB, Yo.(I.; GA-PUNINA, --,.V.; SPIDAIII, I.K. L~', watory model of a steaminp .,ntt for corrosion tests. Zav. lab. 30 no.1:1280-1.231 164. (MIRA 18:4) 1. Nauchno-issledovatellskiy institut osnovnoy khimii. BABKINA, Ya.A., inzh. Introducing semiautomatic welding~Iin a medium of carbon dioxide in the building of petroleumi chemical enterprises in Barshkiria. Trudy BashNIIStroi no.1:122-131 162. (MIRA 17:3) ^- _ Map of the natural zones of the ocean; comments on D.V.Bogdanov's article nMap of the natural zones of the ocean". Okeanologiia 2 no.3062-563 162. (MIRA l5s7) (Oceanography--Charts, diagrams, etc.) (Bogdanov, D.V.) BABEGV, ~"l I eks~-y 1'.F ~n-~ v j i-h; KC611ECHN Ili , - Iv:,Trj,,ivi- ::13 - ~ ~ ~ ~, , ". . : .~ 1 7 1 . -- , ! . I ~ *, I V. , , f . - -a "I .7 1 -, . TfIlkinum. . Leningrad. Gi6romotenizdat, 1-),. -1 (t,11RA 1; : " .1 41111111 011111 0 0 00 0 0 0 & 0 6 66 0 ejwt ileee Gee 0 0 0 1111111111104111 64 i I A I~ . I 1 9 v III)SAW11,16 III# "XIIIJ2 13 )d 21 36 J, a ' is ifoubabisulan4l 41 W 41 a at* AIL r. a I a k__ a -IN.. p ~ a R I -_ I- v -T - 1 90 Ct 4.t b 9 It j s a, Volumebic debtrintuaboil, Cd SMdr. add Ift jlxit~ N. A. T&%AMARV di a jjApXG__LjFaixjkji Kkem. Zkar. S~ Pt. S. 71-XS(I9M)).-FinrIY Pulverized gls%!i is KI; artA concd. JICI, to ahich is added ak. to dr- treated In a I't di.%h with a mixt. of 0 crease the mt,kv. of KAN; after imrtillog OW ppt. Is filtered thepligh a paraffined funt-L.- 00 knit wAJIrd with UIrl, ale, Thv filitate tqvilirt with tile Mirk IVIvT i,% wt4rd kill ill it flask with 0 "41% oft4kit (in"olvi-It the ftwnwd F it4l toA ept )AU, 111tratt-41, %hilelk Ing .00 00 watrued oil the water bilth, with 0.5 N NaM I to the coulplete clarification of tile liquid 0 6 iver the ppt., or to change of the color of thv neutral red indicator. Tbrav.accuracy jr is About +0 3%. The applicatinii (if IfF in-tend of KF k not advi-able. am IlF Is 11 alwavii contamioated with Sitli. CIIAIL. IIII-ANC coo Of W 00 it too s I, A atlattUIT&KAL Ue* vee ti 1.1,'u U is A# 10 L% T j7-T a OW 0 too P&04KItRUtf it it it Or KLO a An I 000 0 0 0 1; ; 9 0 dfta ; 0 0 0 0 0 0 0 0 0 0 0 0.0 0 0 00 00 A as 0 4 0 9 I 11 (a C_ 2 -14 35 16 IF 31 19 a 41 a41 air* Voteminatiou of Kdkun carbonate In miscilmit, YoUnate. A. H~ t~L(Ukraiue Chem. J., in), - s l1kij. -30*. unt carbomssfw present it, SCI.I. 197 ( 'bicarbonate in exceis of 3-1% can be duermined by dw ordinary methoda. Where the content iot lower. it can W detiribliisod tolorimetrivally by compariwn of the eolow obt&iW on addition of phenolphtholvin with -00 =00 COO coo :00 $-ILA PLIALtUOMICAL LIMAT1141 CLAUPKAMN Its- I;Z at. u A, 0 ill; 1; lp iv As 8 a It a K a tz It At As a dad tsoo boo 1166 N :0010 olot see, 0 0 -9-OA-ke 0 0-0-A-0 0 0 0 WO eve 41 000 0 0 0 00 0 0 0 0 IS, 0' 1* 11 U is u It 14 if is It a 21 a n js D m V a 19 36 it u Is 34 a 36 V a 9-k -1 -L.&-.M A--AILL A- MWL 00 r-~ OfieNt.7 I L;-.,/ I)Oftfalft"Its of famic oxide, alumina, Jim#. mwnb md Ieelftft IN 1111111110. A. M, 4%lIla, 00 9 *33. No. 2. " 20-2; k-*IiPthm tit the I-chnksof tlwpe qletnt. A. 11,.A gel .01 JI SVAC.~ .1. Ott 10 r U 11 A; r1f a* 'I,; 0 Ole 0 0 % '0 0 0 0 00 0:1 9 0 e& 9es 0 0 0 0 00 00 a m L I I w 0 ~11, 1 1. IV* 0 0 Ole 0 0 0 0 0 a 0 0 0 a 0 0 0 0 0 0 0 0 0 '% 00 a * 0 0 0 0 0 0 a IS 0 *0 0 0 e *I 4 61 a a 'A a k0 -P. -L-A 00 l9 00 .00 .09 $2 11 U 1) It It I 1? 14 it J6 'I a It V 1. 6 41 .6 4v fle 1 $ v Z At all EL M it 0 0o -0 00 -09 00 00 accelerated method at detesmising R,t)., caltiun, 00 saide and inatinseluni oxide in silicates. A. k. '00 1',-s. VArnion. M. NO-sm,th /nit. 1f/4C7-'3fArinvtr-- 00 1933. N'-,. 111; J. Sm. Wals 7,,h. 19, :,',$-,A, Ih, lf"al- kii"Ilt "t ilival" tk.!l &% SIR- Willi 1114 .-1 so go 00 *0 go .. 00 00 00 A .00 xf-f- A 0 so a J ..00 go t wo 1%'.' 1 W 8, it ", 060 00 6 60 I pit ILIUM libily" 41 a a !I It Cm AT 'A 1`1 y# I'A. I * 0 Ort ~! it 00 0 ~00 000 041 , coo . 1 .7 0 0 A -11 -N- X 141.U.Jul l s 00 -LAt -AO "% VINI -- IN t)' F'Sol two 00 1y jjIp!%O I,UV .,%% 1"UJO uk4jvtu,%,"j "tik J's 11mullIlLml -%tit "I '0111W 01 . ' u I i t oba. ,l UO!PI l- . ujnw1jw - w"Juvill um pjIIbIlqI!.% ill!%% l-n vv. 0 0 00 00- 11MV 'as 'tick !ma Lot ' 11141110a I)PI40111011110 o 110 1011 1 00 - . 4 UOPMOA j 11 1 wt, ! 00 i ir 00 s0- 00 -T - go IV R It P It M'A 01 it 91 01 If a R if I qf It It AOL ~Iwr I 11 ik at I A t s 0 0 V 4-9-141-9-0-411 - . 0 411 0*0 0 41 0 0 0 Wa is0 I Ar, - 0,3 i~; 000 00, 0*- 00 4 1 0 9 60 11 ti to $0 0 It 11 0 J_LLU fk 0, p 0 go 0 o goo o!4p a m 11 it do #1 a/ it a Soo i t o oil ~'mddo. A. K. Cato. Ex- 't Nix b4i owe or &.$L I 84TALLUItGKAL UTIOATURE CLAMOKAT" 141coo mir omw 049 614AJI U ft IV _0"L a, ,,;moon $A a 0* 041: 00 00 0 0 0 0 0 0 0 0 0 0-0 0 0 0 0 0 0 0 A =00 co: see XOO goo zoo goo see es, :00 'A t it 0 t it 0 ku.- Zamilskaya Ldb. SIN-WilOW-Mg solm. i, treiated in the cold with a frembly prrpd. NaM ".a. 14 cc.ofO.1 NN*DHwW 16ce.olo.1 N 1) &M the hrown- S; black color is muipared with stantlard solos. SWIt, in the -'e anti . suln. Obutild 1* tentomf by filtration anti At, I%I n fly plim. with ftx-%hly ptvpd. HSCO.' Cba%. 1118fiv 00 SI, -00 00 90 a zoo zoo A 0 00 .00 Oe soo Do A Is '00 too fAtttI*(.k it L111441"I CI IOIPOWJV~ 60 ami ET' . q Im 1~ S a (W a a v TO u '00 (felt, mic aid Not It cc it it K stui n sr. 00000 0 0 0 * 0 0 9 0 0 0 0 0 411 0 0 00 0 0 0 0 0 O's so* 9 e 0 0 0 4 0 0 0 0 go v, CP 0 0 0 0 0 004 0090 0 0 - wip 7917 A 9 C 0 V 6 IS A L A 0 VU I I I. T.-I Oft 0% 0012 oft 0 OL: 04b 04L 00- 00. 0 0- 0 40- fee 0111100olf"T* 1 999ooot. Nil link Nil va 3-'X--Qa 0 . 6 It VI C" AV a n OF= T1 2110 "a AV- clots$ --F. "cup" 2! .013 41, -ALUMI-MA I-I%; CAT1110- FIV T119 All) OF THR OXALAt. COMPLOILK. ?4t4kl- ika>v Lab., 4 181 A114P (1935).-Alumina can be deter. 0 min ita!ion in the form of AI(Olf)a by alkalis ip ' W pZ & 00 ,. by d , USInj plurnolplithalcin; the precipitate, after solution in acid. *is I ' led t litrixtion or the excess 'u o 00 acid. To eliminate ,, ll;=,olyvis d he Al' k. It 1, boLod fly the mudate in tile presence of hjgCh. method it i d l 30 40 f ; prec se an im ta to M n. 71e odometric mr1luml 41u$ he U~I. The "Ution. after tecatruent With R.Cv()., is nrulrahad and afterward hailM with KI. K 1(h. aud CaClt; dW removing the iodine. the FrAidual The tlwthtxl is Inntrexpensivrand r 00 lets ptex-i'v but Call he IIM41 if great Tiantilk-i of hfit0and Then%Attecan w6trateduaiderimil. iuX with alumina and u%ing turthyl red until the voinplex K~IAI-(CrOt)jl ib formed. The turthod 6 rApid but not "D 11*91111agluxult tin 0o0 *0 0 0 0 0 0000 000000 00 00 !34. 111=111111YZI Ilk A n "I N I I I r It a Ilt a K a a 11 ff 61 1111 a R IS ta a It itA I I I Irv 0 0, 0 0 0 0 0 0 0 00 0 0 0 of go***** 0 0 0 0 St 0 0 0 0 0 0 0 0 9 0 111 Soo* to ? I f It U it U IS " 11 is a I it a a x a is V x )q ms' 1133 idb joij mile it &jai wd~pq A B-I P-c - I I sit -V 2.0 f.bf.% J ho '11crift'i% *it 06 *0 TitmtLon of fluesWcates anti determination of SA in 041 06 "Cates. AJ;-. k'aim. K". Zhu,. 10. 13:3 -47 h f 00 e in t titrati4m o i,frwttcr of CsCl, &I al.mit 90' j. th-mly r%s,-t ts.~Ilm.l of ' oe ~ volinnettic drin. o( Sit h in %ilwairs. At ltjw tenip. j 17 "Itti Phenol red %Ati%facit"Y fc~ultfi ste P(Kqibir only at 00 high diln. Titration curves are given at lboth Icnips. fin rOO Na.SiF. alone as well u in tbe prewrice of NaF and Cecil, coo at varying degrees of hydrolysis. G. Tolpin 3 se 0 no* t:oo ,go 1, 01 t A.11ALLUPGIC.1, 1.111-TUXI CtASSIFKAISC" too to: 4 U 0 1, a to 0' is K't 't a Ff att it of 40 0 740 : : : : : : : : : : : : : : : : 4 0 : - 0 'i : : 00 it U U -M a is 2 ii M-Ar a -M R - w --jr I'll I .4 t Jj t- a 'jMA w - A , d . 4--"- M A" "m of POCCISMS MAD Okaottlatl SIMPLIFrED nOT.MITINETRIC TITRATION, A.T. BABKO 00 a well! Zavodskays, Lab. S. 1387-8 ( 1936 I.F. Lyubimov. *0 & Ibid. 1388. -- App. for rapid titration Is illustrated and described in detail. cl'as. Blanc -00 ago so* 9*0 600 see goo Soo goo go age we* U S At 00 itv 0 a a it ft 4 a a, U, - 0 0 0 0 & * 0 0 0 0 0 0 ose 1 0 a : : 0 000000000048 11 Iluldibill like "a a a 11 a u R It M 1) a if A. 4 A A-L-4-JL-f a -1 v I I- I A- p 611111 flabl ll t K li A l - . . e. . i slife aws s TM hiblir"imspes alawi #W Chm. (t1. S. S. U.) 0, r. A 00 (110 univ. " Kim. J11mu. Pei.. PK. CUM, 1. No. 4. t ' lie ob*t was lit IM-41(im) (Ckmkan suounsfy).-I 16 ks of M-allpatin lake in wq. luvrolasts lbow 0 : = @LAU. WMA lartaulmill Ow f.4rimeric q 1"I A" 1 012). rficvI"1 , Al &w 4 0 , M.Pu&t,lr mod 11,01julo jj,'.kaA,. jb. t~ with am l 0 c'4twimorter. The rroull-I showM that In kill. milml. Sim ilml I l t h 'm I'll o 1. 'N.Illm . . Iwith a tarp viktv" III ollaouln a c j l 0 0 et C%.V- whk-b at hisher c4awsm. OW Willi a .11161 Wastrin Iscouvraid Into am allmamptkiii vuImpAl. TheAl,- (allsaria)l 6 W adowlitilin LXNUpd. Of autil. seta. At a so j! coutit. comm. cd alimdu tb quaritit of lake iDcfvaws lit a U" wA&r ratio than &be cm InLreswus rotwn' of 4L" 4 00 A.nd allsawin t1tv 4111n. 1 o1 Ion of 1 Al. At Us 61014 Pr WO ll Al k l I l i o mo . W l l lwr"m The Allit. of filhistin twAllillwi Chat. 11611C 11`9 7 No 0 At. it A t; i~;' uA'-' 71-- J.t V3701ZI.F Joe u " 0 1 A. r- , 19 U R a a a . I '- - so 0 0 el~ 06 A a 0 0 go 000 ! I AMA L I _jtD. A %D_ !_I I FiOCI~1791 A%D Pio"11.1% 1.01A oempagads. M. .,Wkwaw, Cow Tba of A wharsts is i -o x io-4. am its ~00 6061terAma" d k" "A MbMMWWA- opwinm dow not dMw fnm that of (11) or at 4*--M mo., but bus on &"tkml hand st soo- -00 . -A~KAk&bso (smu. fw. lusiv. lv*y, 1"1 3, no. 3 v~m t am Trooft or A] &&I Fa am dpkqmIW4 in the m= W, SIMI. of O.W% (1) an added to the 00 00 0 "'I"Um at ft 1 w ask a -dowk 11141 of colour (1~ boM* am a sohdke (DMMWW S-40 g. of A.I,0,+Fe,, ). f llo b N =90 , . ., WWI HMA with x -6~ 2 x 1111" Wd ir" 4 1 x 1048 o pwagi, y I UL asek of X-N&OAc and -AvO O am the , 44)r mad. is macis up to 16 ml The cog coo d A omplete at ))j 5; thk up , . PtI&M Sim 6Y UN FMWtit4 K1UUO1%, UNIX a -fift L 7 I- rog 4 above WMA it & 7III fi l er t of I other 46G.-= mp, t to detoormiod. the Fe + Al -w-t-ut, I. read fmm I stly A ksoeisted ( no OPeett"gum Of 111i III Alma* i&ut W" tW of HAI 1 11 th An emPirie4d cun-0. Fe atom 6 (letermined simfiarly, '0 0 10 e , 0 MwIlIDD-400mP.; uking a filter tranAmitting tight of x 6oo-4wo m,; A] b given kv diffmince. R. T, z0 9 A I a. % L A &EIALLWGICAL, LIMAYU111 CLAIWKAIIDN .11 o-vost u III AV I - -1g; I; g; ; A; 1111111111 Kait Igo 0 to is, Ole 0 0 * sol __ ____ *of ZOO logo t-o 0 A Z Z. too 1juslowl; a- ji. mr 0 tw 0 0 1 IN 1'1 5 i1 a 3 1 AID A I 111% dAC 0001000o0 ***be* 0000 oo::l ;i *Sol 0 4r- 0 ap OV Ow 411 0= Sep Ow *01 IM I U011411121 Nimbi A 6 c 0 v S Is A L 0 Fe 0 1 T vv .0-to MOIR 0 Nis go W! a cm AV a tocall OU311 '1q R" ptm rA amtojpxq as IN .14d 31 1 *11ovv 'film PM "N't 1114111 q.141A '011*111 AN 4PA lull-it Ag Ilve #HN "H3) I psm jjN ~~ U311.1. ql!A 93 Pull CHN qyA IV P- OA 4()tlll~ P"W`OIq _1W 01 '0011 Rita paq pus i;ONH qj~m aldill, aq, z 0,-j 'I JMvZ "Micy !n-tv It .0 M 'J"I 'If*[ 0806 rwIt"I "Joy ,13011Y to" 'd P"M OjW'vX 'V *A~rtrWE -y -K *s" iq , " P MOP --N IR P" sevow"M SIM10, at "Ma womosm 9W.-Mvp is$ powevir 0963 J, so fIL IF 041 fir til So jaI73 .11 Q., tr-r--T--1r a ii -61 I T a a it 9 K (T ?I it at it it a of 9 a jr It It of Oil 9111"till 11 4 to 0 0 0, O'w WOW 3 6 1 a I to if (I it M 16 It a is 11 X ~A B xjTxM:Hlf UZI if C if U at a M~FR LE4JL--1--t--t-j -.-L-t k j A a --A LIP 0 kD peortyl.ts ..I,. 00 The Istrestiptin of SJUMIDUM oxalatif Complests and thifir isdUndes #w the deterw1ution of Aluallnum, A. 00 K. r*' --[Sslrdm~fel- Ral,-l Kfif- a '14rMJ~121V,4. M28431WIM K hi- - Rt.'"al - Zhu,. 1, No. 7, 117.-Prm the curve of the irm and 4 1 be corn - 00, hined ams the existence of Al(CA.).- AK,04),-. 00 Ali(COi)*; A (CA)*. and Al,(C,(.).)* ... it presumed. .A In the 4em. of Al by watralisatiou, in older iqs &-id the *0 effect of hydrolysis Al b embined Into an o%alate com. .00 0 To det. Al iodometrically, 0 plex K C. A. 3D, 21321). neutralite the %oln. conig. Al in the prc~ence of the oWate .60 00 and of 11901, boil the soln. with C&CI, to remove oxalate, -00 00 add KI and a goln. of KTO~, back-titrate the excrts iodate with %0,--. A) can be drfd. a little let% acrurisfely by coo widlar to the Al call "n. an cxccx ig a siandardized coo ofs-,, K1~7, ode., neutraliting to mt-thyl red, and titrating the excritsexalate with an AIC4 vAn. Thecoloroffriethyl 00 it rrd clistrig" when all the oxaJifte is combined as At- goo W~ R. l1rim $00 %1010111) It .3.1 got 47 - -- is -islia;- . 1, 1 i i zm Od 0 0 a I v go 5 a 0 3 '0 IL4 641, 1*1 11 Klo 000 00 **go 0 0 0 0 0:6 go 0 0 09 0090 0 0 - i 4 0 * ~110 P 00 0 0 m1 1 1 4 s 1 1 s is it it it m is is ip I a IS 4 Js as it At U I' a it v a a a I it P v a . ' o n it st is a ate 4 1. a x P a I I 1_11 . - i t a cc n ail li 4 d A f A I Jj. 00. 4 of NTbfp appiludom of solid ftdwU# &puts (in auslysiel. , 00 . A. K, halika. Zatomilikaya ]Ajb, 6. In - sirtn. of Cu and So in bromcs and Rabbitt metals toy thi ntethod (C. A. 22. 2MV. the bc~t rrsuili he -400 Air by reduction with rkctrolytic Hi in strongly = -00 IICI Submit. in the Jones rovdisoctur sold duW1 m lkiletilm- 00 metric tittation o( Sn I I with 0.1 X KNInO4 Ito all in- -00 'nt yellow (CaCI, in 11CI) and that of Cut with WI t % -00 K.C,^ and dipbenylamine. The pre-sence ofq) and I'll is- harmilcm. The detn. of Fe slid Ti in itttlellitc i% see 00 'Jj- based on the reduction of the :1 elements by viectrolytic see t Zil and Cd and that of Fe by III. Ti is not rtilueed hY o0 ,i Hi in dil. HISO.contg. N&N%O,. The reduction isvilmi-t Gee 00 j its the Jones app. After the reduction with Zn or Cd in GO 0 dil. H.90. Tolls., the stairs of Fe and Ti is titrat"t with ' 00 rhe tilmied KINN04 or XjCrA and dipliessylantine. too 00 It mills. is trmt"I with 11,0 to 11K) 2(No 'V. %-W. alld 5.7 a. Nabk), tolowrr thravidily, alld 111C Fe Is triblet-11 veoll 00 z Ili alml titrated AsAbovc. lh, gee 9 taikA Ist-medurri; ate deactitmi. .1kovat rrf~tvmv.. coo Chas. Mani: goo gosll S a .L A MATALLURCKAL LITINATURI CLOSIO'KATION SIGN. S1114111 1. i 180080 it ON, Get - filial4pt 44,11 -aw"Y sit I __ U IS 10 a ; 1 0 - - 1 7 1 V 1 0 AT Ot for IF it IP a a a of K 4 it a it a S& a M., 0 a 0 1 go 0 00 o It o o Goo** 0 0 di 0 0 0 0 0 0 0 0 0 0 0 q 4 goo* Goo goo* g ***I ****,]A **Gomm 0*000000*000too 0 00 0:0 Selo go 00 0*0 0 * 09 0 0 6040606 0 CTvq W 11 u is It 15 3e v v 14 c . . .. %T C% 'y Wt-WAL11 00. 0* 00. _ojj4 pW, q IO:jrH &timjjd aq _90a 00 00 plflafr4 .(101R -ago ~ Lilpf-0 To 1) *OUKN1',VH) 00 00 SO *1% P0110,11t) 91 Uolmliv Aillpt" ot& %all ItI-) It III 0 N. , ' Ol l , 0* 9 ill Pu OWHTP 'OPA PM"l in," or. O it P- J. )JI J, *0 (M 411 ul lnjv 1"I ** . 0 1 t 111, 4m, .4*u! PUG D" K)" it% All Imitollo) p.11111V uv IJ)()jA,(tjjK) .,(Rt-tvj .-11,NNIV 'R 00 04v ON 0. Moptivilim'i luolln"Jo 00 :lu3 (ic-itt joA uxomi v m gin a6vigg.1,milia atil puge 00 IM)OW410 ll.AUI 4111 '*(Xjk . p -If 9-1 qjpA , I 0 , , I-w-"(fit IN '01 U01 00 11alp 11(d 4jifij ~)j ~ .06VOIJ*t" fit V I V . 00 -001116 OUIPJA Ad me plow Qj;mjd 10 -amoupme"a W 00 *W ews 00 1 * 1 , i , 1 0 o So o 4. 0 0 0 Ak__ _ ~ 0 0 t 0000 0 0 0 0 * a 0000 00 00 eii -W ~-r- 71 t tilt . w 11, , r y j IL L U . 00 60 00 00 00 A. ;lee 00 N--iliMul"' 11 c h 00 e ,6 S by t Alwass to 're LfORU With in 3-1 Mg- f will- 0 Mg. o . lue i, diomoke4l in Method. 10-15 Si(),, the rem ned jjFtoremovO dyesmdetern' W _ A, Ti an 1j, _I - 'Cal of Inith ON, Mg lo jg d Un . , fl,o n the 901 tim by known Inothod" .;d K ..I N- u i n .it, &re beted 10 by known T 1 , . in tj, Iv,,11 detor"jined lee ve " 0 . IM dIG 0 it ICU r1ritt [[a( 0 it it K goo - 0 e 0 . 0 to 0 A- A. I M 41~ O in li bk o, s 112 baildes of copper mud blanuth. A. K. ,- - I - o ! g n-M A CIii w Kit-. Bull. scs., Ree. Chiffl. No. f. . . U n melll a )tnulan, 101-3; in English, I(XI -5) OW.-Chloride anti 0 bronside cornplexcs of Cu and III weir investigated. '4n%, with vadous conens. of Cu and balide and with a S tal vonM. cforn. of Cu wetr lorriml, in otdrr to study zoo 00, 1 r Vali0to, J4d9VV 44 the C.'roplel loartallon. The dMia 00 a indicate that both Cu and Ili forin a III). of vinpIrs stmi-s which are capable of dimocn. in stagrii. c. x.. to in soln . -- ** - * and WW BiB C C C r u I . for-ni CuCV, Cu 4 4 , . Milt.- It. Z. Kantich roe A I JO I L A101 TALL UNGICAL MI'VAT1,01 CLAMPICATIOu two., i too e u is A. -a As 0 It It I 061 , too ~ ` i III I 1 13 a3 4411% "Ulm ""lull" Ona ~ : 1 Ole 0 0 0 0 & 0 0 0 0 0 & 0 0 0 0 0! 0 0 0 0 0 0 0-0 0 0 * * * * * * * * * S * Q-* * * 1 -ji~ 0 0 0 * 6601 0 it 1 1 0 11 a s *0 00 J of Ar L U 0 a, -0 q 0 0 0 0 0 0_0"d IT-We WANO-44--1111 0-0 1 9 it is U if I, of 0 IF' it 7, N- is m fivil,11 Uld PAID lot) ""at 41 4141 maple L .Z181 _vc 0 #%its ..0 1, P1.111% Application Of labor-COUIPIrs COUSPOUnds In Colo- trimetry. Detmallastlos of aluminum by meant of &urin- hiew"M add. A. K, lloiblo. J. IPNWJ t1em. (U. S. i. R.) 12. Iw-.(in Vvelich. 11hournitwinictiric conit. of the disrn. t-f amin-ricar- ioxylic acid as an Indicator for thi- cunwrt,hm In a lwi-iv Soln. wils fuund to tx 13-1. TIw Mom ol the couil-I. tit the div WhIll Atin tbr VoK. &PA Ott stwitrintitick Sliet-tit 'd Ow "Mitth, at wcN fill of rarikult, limms, at the d.vr 01H and 61 -1 were deld. The limitation isif Ow 41shIlY di,- (triAlins (inmr-emplex) milt (M - R) 6 explained hv~. M* + Ilk z~! NIX + 111%,alterrhy the mimation 4 MR k vlow to that (if the Ilme anion (R-) of the dve; lim"vet, lKvaitw tit 1he adAtil. txwut lbettectinilwk. with Al- anti Fr* ate f-mird in ariclic wAn%. The di--n. Itf the inner."aupirtl itails of At unit Fe Ic K__- INWIM-VINIMI. whem Ninstitt 41,111,11. Nw.. I Ili file 16tvio of Illib alitalill alld Allimilivallivni.- lit. $44,141 its-10 tvillIfI41441 44 fedfirfIlIf It# file dent, tit Al. Allmilit IS Imsch vs, rmimsisill I-vois- -.1 IIle 01.1wats""t. 4 a highly r0writ ald ... I "I lilt, 41Y.- itills incle.sw In I'll. Ttiv atilintliewl.,wlic wid litisivil. A wht" vatimitm fit lilt, sirmet Oahtlilv lo-dt%l Ow *,,tk%t of Imiller milus. and a Strattr m(4at almwptim tivIll. A. A. limbiliniti, 4#11MUNOKA1. 1,111111111,1110 (LAUNKATION t I" a I it One 171 W1 4 a tw a -a -0 1 it 44 '14 q 0 0 0 0 0 0 0 v 0 0 111 0 0 0 0 0 0 Ile 0,0 0 0 0 0 0 4111, 0~9 0 0,411, 0 0 0 0 see 0, #00 tie a "0e tie wee be A f L, 0 0 A 09 00 00 fe 4f 00 00 oo 0: 0 00 . . . . . . . . . . . I .. .1 . . . . . . . . . . . I . . ; 4_ 090690900000090, 0 wwztf 9000900901000009 4 1 6 1 1 s 0 11 U 11 ;4 is is it M to '"ITT-111 11 v ji w Is It V a Is AD 41 d) " 46 6~ce a L -"-I- Q_ A- I I a I M_JM_" IV E(~A__j '.1 1 _t J, B, t..j _k -I- 'r-l-A- 5- b bjID.~"IFS '.t' ..v F~ 0 The a of Inner-tomplex compounds In color- =.,KFvMbko. Trudy I'sejoyms. KuRIfirmfoll At 2, =v320V43)-M(nt coliximetfic drtn, i -00 is bated on the fact that the i*n is tran%fartiml into a cam- ~00 plex compd. 11w intensity of the cokar and the dixvwn. INKISI. of the colored complex (as a weak rkvtnAyte) ure '00 It. oloat , taut ti of the vumpItx couiltil. -00 rhe ..W1, tv"IMI'l "Coust"the fatier It is to franfortil -of twol M"411 IIKV4 of Ow 11"1 111111 lite ('044NI 41-11114% funijbil.; thus, The slightly 11I.vot'g. L-411111kin., Roth fit .60 intitf-COMpIC11 COMW!... Aft IW't 10f t444"hilr(tY. W. R. Ift,111, =00 Al pal CLAIIWK -AM lawaso "it Q.. cat U 9 0 10 As - i . - a i i - i - 09 W K it If 0 0 0 0 0 0 0 0 0 0 0 0 0 0 OT: roe roe Vo 0 coo !zoo zoo t4d, so 0. s Bt I a I' *_-, F_ -__ it, W, _L T-a _fw -0 a w .1 K No- _401 a :B -1 1 K9 0 0 0 0 6 0 0 0 a 0 q * a 0 0 a 0 W W W i, ~ , v CS - g ~ ~ - , ~ e , - - . , - --v 4 * i rP l M d 11 4 11, 0 V Y j 15 1, It is Im Q A, 11 A ~ , I L i 1A M go M V it 0 40 41 # A _ _1- a --A -_ __. . _ _ _ ., f. . -040 A j I T%P_ l!IJIM R INtect libation cif nkktA "Milth d6o6YWi*giiN NNV- ' -041 7 0. jbcvchruk tim. A. K; 0~ -got .111 ,,u 11 b k 1 sample it In 110~crz live with a small quantity of limil. NO hoil to rrmo%T N oxid I l 00 -A . ,t jvu cv tale lcvj, laa,,Jl . k 1 es. n f le tartrate varlAhMl r 90 I.Ix" I;e,, jjjt,.lf"_ ~Iih tt;- kin. 4 Ni hy mran, -4 unk,t fir mnlik-14AY u%idavd. ll I: ci the ruethod. add to the soln. !~l-5 nd. uf thiq R.. helle. %It (ir tartaric acid and winic N11 011 untill Nil ud's t. , a Is flitter curnlAurd In "npir& limin As a testrale tx a . , (Altallied. Ill tile flut"Ir vartatuics. slid !i-41 C. tj xml, flunride. 71- dri. N1 in .1ml. di_ul%~ tl.,'~JJJ g. td thr let (IM' %(VC1 "n.. orUtIM617 *till NIJ4011 jimly *till ' til %'If i i W z m nx un . or apprati. rhe ppt. i, "kill, or ItgIllil. DuIll. by the fluoride Intlil-I ).Irk[, forlicr r"llt, flnul th- obuin'NI by tit, lartf.tr llwthcxl fil the win-urr 4 cu ill, o t t 1 t N . c n en a ~ I ran 1 ' ' d b 2 i d l h 0 0 rt . var litl[InS C t e IlWtll4XI. (1) It y - 0.5 c. of thr alkly fit JICI caidixc with IISO 1xvil .111, , ', . with coki water to 4`01-711 till &,fit I A g of Zu or Al W% goo ., . ings, shake. for W-15 min. (lictict nithout hcati~llj;), lilt'! waill with dil. IICI (1: IOU),;uld 3-5 in]. of 11NO, in 0.5 - 1.11 till. (i I frO... bod until all Fv i~ oxidized and X ~,itulcs 17 r are Mumvd, add 3-5 g. of tartaric acid and N1144M until Q') Diss(Ave tile alloy samp3e ill IICI. add.5 K. 44 Nat-. nrut aitte with N1140H until Nill "1w al-JR-ar" "cullf,t - l' ct,hwize the I ft,ruied with ill tile pr,~n-d h(h ' -- Igoe mild a stuall vicr%% iA N (h and 5 fig. tif AcONa 4a -iviv. N11,011, anti litrate a, umial I Cu call Isv drid. ~itnultanv- 13*0 Imlitly Istri-snim: ill lilt- plLwIlcr 14 F- tile Fv vitl,l~ In, 'Altl 1116:14.1111, 1141111 ties be* IVALLUMOCAL A I 9-z D. st L 7 woo 114ttoall , Iflabo 41v owl aft 41, _ ___ ! L u AT to IS it ; , r. , 9 U0 n .6a i 1 1 0 000004 * 0 0 0 6 9 0 0 0 0 0 to Goo 00 0 q goo 0 0 0 0 a a a A_ I. A I I 1 4 q A, L_ V "'r-4 A V: A rk A i compirl corupwrids in &VAlyticid chfulistry 16. State I'tuv_ Kirv). 00 1J, PWAIM)i A rtvio, .4 mi, knw~ a coo action, tv.1111ing it) the hwillathm W (willph % -ful.k. 11-1 Coe tit analytical chrunstry. The IsI,,r dw twing. eew t1i'll coo I'liqlcrtir,' Chang- in the o'Lidatit"l-mloctiml 00 Cll~ttlg%'S Ill the -Ally. lltltitlg eiIIIIj)l(-% cog in cAllas during the formation of "ImpIrl litl fctt lict's. 11'. R. fit-ill) 4100 zoo kill ILA MtIAkktr(.KAL Liftailvot (LAIllpfcAfmif It 'No., Oki vjkjll~t .1,401 'Im ONV is~_ U it AV PO it AA- 1w -0 All: ~; " it tv it a stir Its Itern (tic No 11 f :14 lo 0 0 :1* 0 6 0 0 0 0 0 if 0 0 0 0 111 0 0 0 0 0 0 0 0 0 a o 0 o 00 go* 0 000000 0 0 (111 9 0 0 0 0 a 0 0 0 0 0 0 0 0 006 0 0 ei 40*00 ooooooo;;;Q;;, 4 1 1 1 1 10 11 UUMUM Ills It It I a a it 4, 06 if A.C. !=_- k Pit KQ11 Afto Al ;a ;it ~;*;v ;a ;U oil id, p _I_ W_A_ A ('09 '" _Lq~__ -00 00 w emosm. A. K. stahko.- J. Gere. 6 es n. R-Me ex- q k C4,.. (U.. _q.k.) 13, 743 17(1145)~Mt 7 . l Wi t d j J id l (R) ff h 06 an n ac so u, a e ows t uLt _ . s cy 1 0*4 \Fel ferric tons form the vialet cainjilex (C411 00 cot 6z The &,%ocn con%t KI [it 4 X 10-11 and the binding 'is about equal to that of R to 211. energlp'of R'to PC Addn. cJ n1mr Fe W the "Y'nPlPx ha* no ef"'. '"'t '11- 0001 j_rm.4vm the mint. of R (vitiay by raWug the 0 0 Lvums - 00.3 11. forlostion of the red mriplex FrMT-. 'Kt - 3.5 X 10 Atabout 111O.Ayellowcoluplex'FeR,--- islotmed. KI ffer., which do not d h fi v u n e, It 14 (11MCM11 to 1.1 2 x l 4 temet -with Fe. but salicylic add-milcylafe bufferg %iprk 00 fairly well. Theoretical calcm-1. of the lfi%-". consts. i i agree rairly well with the rxptl. vahms. A nomm-Tain 4 the rAri0t1~v-'Plv%- Ill a m1l". it, h g . rso lor detr. t V 1 tj I w w, i LA A b U S AV ID AS Is It Is it 1144, i;4 -m 4, 1 JL rw 0 W, 0 .00 .00 .00 .00 .00 800 =00 GO* 000 goo goo goo 00 60 000 0 see 00 ;o0 it vu )IS low 43PAP41 4 w vt 1 al"Malao . , a A 4 of 4 _,-,itssas P. !!Lee I-so Tke feernation of complexes of merals -ith %rak Acid* 00 V: Eq ilibria in Sollutions of ferric xmlic~latr lerric Scetat v ' 10 -,, OV, k. IlAhko. J. Che.. 1S.7. A. l : 0 , fli"M:-Vefriu~ i'm $I'll . ..... 14'. il o % 4 . acetate ion, Imt ferric ilm foram Oil, comph,% I vit At 01 3.0 -3.7 addia. of ~Llivvjalt` iOll (It ~ W I Ill' All t At V der oultit. Frmll- 1.~. mi-, ,( ill,, vi,,I,t ", I - (,A l 4 1 , . l, ,v I 1:1-H,, but (millatioll i~ lighttv (OM-1- " coo l ill ill, pte~, it-, Whell the 1.11 of the lwff,-r i, illelva,tA w, th W coo ~ -k R, the OAr Imik ill Wild ww", I-,. effect k overvolur toy the bitillcr I'll, Alld I'A V, It, I"Im.. 00 The equil. cono. for the rcoaction FvRj- + 2 O .2 X IW ) F1e(OAcl,* 4- 2k-- is fAiriy e,,n-l. ill-3- Atioll.S.0an,15.41. The dissocrt. mn,t. of the F-lwyji, ovillple% ew"ll. ftstol thi4 Value fAirly ~01 ill, Ill.- 00 vAllit., vvtled. ltv ollw( 111villiul, H. M. 1 WALL L)rGX1L UTINAI tAt -77- 141CC) lose .11.1, Cool a., J, sire tt moo boo wool U lot Aw oo IS I - ; ; ; - , - .1 -, ~ - 1, , ; - a jmAm' %I rwit-11 'IT Ill 3 0 0 0 0 0 of* 0 0 0 *go *Do a **go** 00-w-v 4 o 0 of* 0 0 o ! f 0 go o 0 0 9 .g ! 1 L it L 1 6 N h r A it tt L k It 1 4 , 0 n. ~ f ; o Iron 1011 with pbeno), A~ K. )141 k,.. tl~ R IS. '471 -UMM-1 hr Grm. I m SS Millutlat 19. 111, I'm rt,,, "ith plim.-I 4 w (Pht 11:01 ". 'I lit- Ow t v "Wed I lim t he Ills%. "I"Im t,% I itict inn Nw It, I"t t Ill. -141 - ' . i f O l O pj~x 1. j ll Rlltr 0. w F,. ..A lal o levlate .1011114". I ll, di-wit, .40,w (I" Ow compic"k 1. .. x lit .; 1116% it. -VAIrd In 'frovaltrA 141 %tifilm It I- 114.11 stAtOly III lit (twitiallon 44 lite ti'lliplett Iml I'lle 06.11" con.t. For Me salicylate Wit% I'mud It; 1.- 1.11 X Ili tilt- dl-tl. (A it, V1.11'.1 F,- i'mill w lit go i s L a 411AII01t,1141 LMII-1mv (t.iiWIC.I.O. 71- a -1 cr a it OR 04 111 11 w a It it n it K 0 : to * 0 0 * 0 * 0 0 a 0 0 * 9 0 0 00 1o 0 0 * 0 0 Is a 09 so 09 o-'s w 41 Q 41 61 a s 0 -,* 0 to 0 ties zoo too it* tto 0 u0 rA -m - i -i--* na 0 14 * 0 0 0 0 4 0 0 0 * 0 0 0 * 0 0 0 0 0 0 4 6 0 0 0 0 0 0 9 SO 0 0 0 0 0 0 0 0 ofel 4) 0 0 0 O's, -a*--* 0- t Is 4 t, ~$ -.,,I N .14 IV 1* 1~ p " " . D, . 11 . . . 11 I q 1 1- v_t_Y, t, 1 It M At IV It., 09 ' " , ny, _ Acid pnoperdes of dithizone. & K. 11,1141-aiO A. I'. 1 d" _0 Ill 00 4 IM ~ I liko. ZJimr. .4n4l. Kk,.. A , ipt 1 h I ; 96 ' il.-Ile C(All't , II 1t a study (if the ioull.ttiw Ir s tvv an 00 clim.itirfrd its a monottiolic avid, I he vAlue 2 X III - it,,, .00 obtainmi. U. InsUliflity constants of thic. cadmium, .00 and load didilmates. A. K. PAI-ka Anti A 'r. llhi1ipenL,, p Zkor. A*W. Kilivi. 21 M 11.1flill-.1. VhC i1m.114111%. :, 00 ell mr. 1. kiiawd by K ' WA., ~ I 1 1 / : 1 .11. it it 1AVAIVIII Surtill. Ill.- C;~Ijm. 11 . , M (1111111A)IIAIrs Was AIUIIIW by I "IcIll-I mithut'i by P, Wh 1III. ill thr.'e Jill hmmo I (C.A. 22. 21M). 71w go led (a lif W1. r ",tfllavling v.1112r. 1'.1 h Z7 " COATIsru" , 0-11 It - < 111 11) C oo , . f,w , . ,, - wctv Air nljz. 0A X 1 Z an fur Hills, 2.2 X 10-2l. A ClUtIfLIFI-11 i% tlr.t%Vtl Ik - d I wt, 11 t1mve dithiwiltri, und t~.- twitntIlvidiur wimwitim,-, And sulfitles. The sligy. pt(Auct u( the sulfides i, ,f Ov zoo 00 %ttO.- twdcr of magnitude u% (if the INIffl-l1-111filig fbilli- 1 ., - 241jus Jilt I III frVetMiurticr. Tfw react I I N1 DYI 4- 111 00 1411, 1 211111 wA4 4,111,61411 I'll. 11411 14 lillitillit I I", 'Alivil I** 00 11111 kmCCI'l 0 =OY Ow ivw-u- ill fi~ dilhiarmle aull dithis,litAir in fill- CO, soo *wf Lli~r will be ppm%. tquij aull file "Hirst. .4 It's in III, - 31-1. aq. layff will be it[ the order ell magnitude IA 10 -u 4W. Thtv%. for the lituiting ;00 ca., Kor.t where S is thr.-Ay. pr-lurt. Till- tlithil'"Llf- that frart with )Its "Its't .,Iifv Kwa... ~31- Sull. F(K Zn A:',.r., tb.-r,,I,wv Zn will bvIAJv. Wk~c_autl it% dithironate will rcAct -ith 11,; 1- fiwm uthille., Th~i,t w.%q vnafirmvit by ripr. M. 11~11 A ' , - - I * ~ - :w " 0 It 11 . . r .-f 'A A 1 8 'A f, 4 1 W 64 A.I-0 m a W A #I a It (1 3 it CI 443 n 1. 3 Z 000000* ooooo . oooooooooe~ooooooooooo*ow* o i oooo~ . 000000100009 . 0 00*00000006,0000000000000 :: Ot flog 0" OOM IS 46 0 P%1 a I T IV u C" as "1" 190 "14 1100 Iroe I a. %sets% . ..TtmlkLt "01MIM131,13 110114,011iiii lv3l11_jfll1vLI`av-is- %'W~ 4 tow 1") 0.,z.N1 I )~I .4 + i+. Illiclu-1 J., lq)ItI q1 I-Pnl, AlIVA413tiqlallu I '20P Jill) AfqllX)Afj Ilkl4l 'A -.4 11110 "W"r-N WJ81 jo eup-W jo t4gotorytin" Wj-"sap3 0 of 0 b lto*og filtall Un [lot liallows# a 0 A 0 1 0 a 0 0 1111 0 4 0 0 0 I,-dk-0-&AL0AP_" IS 0 & : * 00 0 Of 1 1 1Ill V 11 1, : :110 Ftjos jod eauilifirijpf CnIIII'Wi, C.0111- Z P.W 11 in Nolu ~11 A. K 11 -1 Z,. wjki bul. Kbim.. Q-- Oivs,,inn mid -4 3b)-dea- A i 6w , I nictlic'i., of anill),45 of tile WirdViorof variulls com. pNx clivoi. cmiriis. in Win. ondur specific wrilitions. IliT f1c tit, f-I-prqu-i-tiv, 6. Inacil Ito tile Lori Ott lictivil orviiIIII, ON. vrmn-s fram lvljivli tire aquil. fartue if ci~tnhiad for .1 filvell coilditioll. 7. Babkoo A. X- 2113 THE REACMN or NICK" IDN wrrH IDAMEMICILy- M THE PRESENCr OF OXIMUS0 AGIRM. _AX-- Wbkc6 Tra"lald fea. Zlr~ Az imal-killIM bal b", rzal. ttJ t!., ~C!- %1' .11 dimr:kjl9q=lmr 1. the pl-r- .' t &-" that toolmy cxlkmrll~ art a gL-d -tterim for co.paring the a ... tt;,ity d '-rt-j b) this =a-$ tbxl fit, mr-tt-dy -f re.g-l jor #Qwlk4 N) FS lerr""d 4hr*g;Qld tu -be rtv.=* of clidjualt, The emposlikoft a thr carriple2 W-ae sladird by p1tyalmdrinicil melhols al eulwthm ansiyals. It was IDUM that vlon the extras .1 o.-Airl is filigN, the C.MW511100 of the C.~Plem is NI: H,rt. - 1: 1 Weir. the ..- of ~Ldsml Is 1-ge. the -11. 1. 1: 3. The !-1- od the mIrpl- 12 M~rusttazl. I! In eh~. that courney to TeVy.1'. "eve. 11,# CO)MY103 Is airombinslice d NO with ustda- 2 *;?? ti? rr flat a 41 Q u u A-A-2 0* *"Coins As* PROPIRIIII wofff set 4d k" **41 13. 8 (1 Own) ).-4Dn the bwo of tbc Is( tke v"w of dw 2nd 41A *0 d = . tw 14 06". vwmu -14. Thewduafmag- dbwm. OWN. w" anding with clall" se P nits& b cmkwmd of ukFw4v facb0b. By use of the "waWs dnvloped the stud of Fe compirses with OWN& ead we. "is, the fornatice twmmll Fe I.Momd, an %be hatA, d wit" m no. S" VYIVftVAWW 14 it W 4.1 wjwl"ophs we prew"IC41 Im coottaltatical of stability ** of Stop it at vwkws I'll velp", offir's d C%,Tm IlIfth-- WON "w" 916w vab" wm nmdmwl f1wil-ttally Ity turalle III 1 No , 11w CAIM1*4 I* own ule w 1,11 4 11, "l VIAM WhOl it I p d r re* s iVI l Awe blaf*t . I pd lk . cb!ws to "d at pit K-b. f See o we* Cleo goo ~ 0 ~ ' Is X 9 1 a a e 90 0 00 00 e 1 0 4 00000000000000 0 : : : 'w . 9004 0*004 0 9 00000006 0 a a : : .s S NN NO ;:;goo 0o * o00 0 1"1 -09 A 0 0 0 *go** 0! to v 14 is 16 11 a I) At a m a is 71 it )q I )i J, M 14 U is U Is1 16 P & 11 4) 41 M di n 0 10 go - 00 .00 Complex compounds of thir ferric Ion with some phellold and h~dC Kier Stale Univ. ~. J. acIds..-JI.,~ ,,,b1 ( S _ _ Gen. IT k f61 W1946) fin Rim~ian); . Zi4 cf. C.A. 40, W.91- In ciDinplex cotnjid~. of Fe Rith uslieviie wid. PhOll. Me Wicirlme. and pyrocairchol t-, the rnrrcr of the chem. bonding of ifir er,6rdinatiog aninrs* %ith Ve cation Is not motre than the hond eni-rKy of cor- 00 rs%lwindina anionq with It Ion. Froin the valuts of sli-p- %i%e dlww". It I% l"sible to emalAW1 the vouilection be. 00 13 lw"n the distribution of Fe among the variou% i-oniplex I I orin nit the stability of the complexes. Slwctrographic data of thew cnintilexes are reviewed. G. N(. K. V.*q roe go coo go COO coo so -.1, A 1 1, L A *t?&LLUVGKAL LIT(ItAlitAf CLASWICA710M 3z., t 1- 1. ------ we 0 .31,ji F3Wt- A Un It *[Klan I ; X4 All I1 1) %a a N o I is of 2 jj a 2 0 oT u u Iv -0 IsIg CP rw It C& 4 1 Ul I i 1A 1J. N i .1p,11 -.4.4P"R. v W if U It As it U 9~ A so, ~ -, I ills, lthiL: M AA CL IV, U Is A uc)mjt4jr k.,11kpirl" A 1, lul-W. J I-ek. is id I Ism. I,,,g tit- SVN al '.1-1 twi. . Ve , , 1,19 /.,1 %-11AA11 ... I m mill I.A.11 -1111.114(1-1 or 1 'I', d "lit, 1,-K ISIL'N I fmill :4 fit -4 1, Imm m%.. I"fAld I'll "Is ..11"i Im its, 3 s.,.Wr I loth-; I'll 1110. M "Imolml. !F("''! vi,till, i-4v mt I ...... I lit Ili I ~~ Its vI 11111.1coll I, I m ~-k, \ I,oo t I%-% is" stlit 1.1.0. the -m-l ...... -,It... t I,." Its , ."'.I III . 11) 1, Ill, ill's 1, -1 c.,11-10"111 "till 11tr Ind- I'll 11ith ,I I'm it 1, "1"011,11.1o Os~ 'Ntlittl ..... . kit N . Ill 1, 1 lit, tit if., -..I. I lit. .1- ties -.11 1 ITITI, o, I... ..... I hv I,,% I hill ii vmli %4ft.fJ"j,K it 1 .1%. d'i.1 'll """, ' I" 11;"N' \i-1 1-1, Is, 11 It 1 3%, -111.g it. Ille I0,J) 00 f "I'll 1"LIN 1. It-oll fill, vilills'litill 00 a milml, vkllil,. tit Ih, list% .m, It,. II.,l 111. Athr Will'i !h. v 0 0 at', ti,tV. 10 , 1, -,-It SI,A) '111.1 7 F. ilk' \ I I in, ~ lit 00 11-1,,I m 'It, 1 Kl% -ft As mtf, .( I Is. v;O 0 is so, I It, liov I 1., .1,1,11. - -I-, 00 1. (14 f F' . . ..... t', f~'t Is, .1, till . . ..... ..it, at . ...... 14, 1"", 0 t,.IAI ;I, ...... I loss. 11"', .4 i moo m ~~O .4 J., !100 1 M it, 1 .4 t I . I,W. I St 1. 4'. m loll, st*.N j,"t" J.1" 0- ),,,1 11,40 .., I i 00 g I'll .1 :11,111 lilt "m". l1..41 11 1.% A .1141.,t M.4111141111 41'. 1 111 1 1 -%~- ..I Ill.. I'm. Is '1.., 1,,4,1 it. stsiti Logo -msi IF Im- I's is 1~' *,1, 1, -A.I If,, l""llikil 11 i-OWN 11 At Ots ...... .. I _w loll b u U AV ii, so IV P I'll t 4, 21 411 W IsIr ff a it door 1410 It I i Not 40 0 00 0 gel** 0 0 0 0 * 0 0 e go 0 * 0 a 0 0 40 & 0 0 0 0 0 * 0 0 0 0 0 0 0 0 0 lllll 014400000000000000 0000 0-111I.-C t-9 0-40-#10 0 0 0 0 0 0 0 0 0 0 0 0 0 6 : -.- , I I - . "Ferric-Rhodanide Complexes," Zhur. Obslich. Khim., 16, No. 1-0, 1946. 11, r. Inst. Chemistry, Acad. Sci. USSR, -1945-- ,-,An,,C,, A. K. ----M "Complex Ferric Sulfocynures in Solution," Dok. AN, 52, No. 1, 1946. Inst. Chem. Acad. Sci. 1945-- e A 0 , ' V x V AA so- ze W a Octlislis A"O '400fatiat WOCS 0 18.114. The I'm at I in A =rIblasia: VIM Park It. m C d - ft an he. a d Ditki t A K l 00 scria es. . oa . A. T. Pilipenko, Journal a/ "V R R 00 -t . chensfitry (U.SS.R.I. V. 2. .9 71. p. 33-42. oln Russian.) as Results of R study of tile com;x)kt- d b ove compoun tion of tile a s In CO. solution. equilibria between the dithl- tonates and the metal salta at differ. ent pH and concentration values, and h eq "llbria between tile dit izonlites is'i'd H.9. RchitionshipA between tile dithironates. nulphides,and the anitno- intates of tile respective n1plaill, A S 0 "--1 at, LU-46-IC A-L -L--tT-I-g A-T U; 9- -C-L -a$W-K- -ATI a-1-9 anoxg -A 1 11111011) Hit 0" Obt goo coo q*e Ce* $*a Sao Soo goo We* U %I AV - 1110 M1 ~ 4 ; j ; I ; Ill h1 L 1 111 CW 0 1 9 so 5 a a 3 0 1 OT 91 a VA 4 'a 0 'a 0 a a a 4 0 0 to 0 411 0 * a a 0 0 a a 0 0 41 9 41 0 0 0 411 0 1111,40 0 0 0 0 0 0 i996006*00060414,006690 000000000 060*000000 1.6 : a. . .1 U a ST cm , Ale 0 Y. 3*LfIIO to* Ate At" C40tal I- - V.S. 004 'Don 4 0 quoit 11 -aj UNI 'NJ 101"11 All Pa"00 .31V in$" 00 1110111d 10 - +1111+ INV9- . VZ+11341M !tzdg+ 11419 +4111 + 11111vic 'st1q, +2v pul +4311 q)1.%% "3L-"- COO R--Iq- .212lita it p-I -pd- w" ivql PIMIA)q% tWISAs 0 of, SMI )o Arap V I jo) j ptm 121( lyd jo,pdcm3 AnIpa, j0 WOMMI "I WHMI *AOIW No -pq ~.t - -sit p I Umfl I-UM-qvnA Aq ifa jo ja"=mrj=j mp -1%3 -1-1 -1 - ffwvl "U jo = .fmm- N in 1-t3 10 *"" 'pop- "30103 a "is ti 1*11M tiltft IPIW (td) ps"-Id paMw Apsuapil -"VZ y Tmr *V '(fi4ics ptagatilmoo 0?glint. Ip 'be fal4k it wee IF 1 47- 1 r w v 9 v a for! cp to or a It a of Cal A " Ii I 04 0 8600 a h 4 11 14 4 dh a a a Am, A --V-v V v a U A 11111.1u, lip. A ;~.s;ljjw L A r. _rA ARM) jjl 00 0 4 owe -1 the hydrogen ion concesitmilivia Do Claimed 00 A. K. ItAblita-ZaniJill-ijim lAb. 11, AUM (II&.1nhe pit to appristrarKV of mint. inirnw cislite rtis Iw "W. from the stability cionst. of the ces"Pt"s 'A 11w 't- a' title comp4ex-im"dog 949 MCM. (1) With -trOUg skills, IGWff Pit 21WAYS 14"ce's conelr4rs fivasitimri. ca. ""t"" Fe-* and *%*"_- "' 00 lit --I I , Vtle Aj1j%Xt"ktIV VNIHMACT (ily-TVAtitlit 94 00 is , , 1%4.4. Aft.1 1 .614*- It. .,+* .4 Ve M is. . A.116411V 00 U ; Ill 114.1. Slid I lie L" I odist. so a ith M. not to litithirt Ill ctiewn.: with c4her acids. asi 11ICK), us 11%(h. %be coke of both and inerr Aters with decirrising pit. and then minains roast. lwlwrm pit 2 and O.h. (2) Analoormis calms. for Willi ani-J. ,I "vok ;tvidt. v%viltIllififtl Iter "it. it. 1.11 "1 .111411 a .141"1 fl#('IkK% I he metal tilts IS IkMUjjj ill I jw-1111,11 %, till 4n ctu~, of OM Mal. It". atr~ 411 the Fe Ittemit is tKKjjjd ill Thelinthinzaridiiyat Which the colwrli vissoplet; i. fill t.1111r. is the higher thir ram" set I lie risillplex 4ortivills WA Ari'l. I h~ diewwn. conitt.. and the highev the isiAlislity r CAM%t. of the complex. Mus. witis & :14al Ill- Ia, over Fe * * *, tlw cotor birgisas to faile at 111 > I X 10-4. with a ID-fold excess, only at I It *1 > 3 X It) -a. IUC the permissible pit limit for the color of the Fe ' * *- nitroistlicylitte complex is about the same as for the I Pe- sall - complex. is due to the fact that. while the strencth of the famw aciell is about 15 tittles gMter 111411 11LIt 44 11.101. file 11alillily tit (ha, I,wtlwf rsimpiris Is I.mi-f ill 41%41, l1a, "Ill,, 1 1110.1,14 is 1h. .1 il-illev is( the i,omplril 1. Illitelooled ItY Me r t4iiii,irli I Ill, lall ' m.1 a"dussly. even in the lwrwmv of a 104t4d excess of I It- Sol, the CDIM Of lCulail be" to Tassish at pit - 4.5. ILA i against pit 2 for I Fesall *. Since the (omnSt-yellow I Mpleit of ll**** with chroinistropic acid 6 morr ist.tile than IIW Willi I' ille I- to 1.11 1 (lit l1w 111411 1.11 Odl,. 4 1111111 1 ts, .4 11W "Mill.tra .11.1 1.1.111 0 IN X, a IllnillIsIr loirow-ktion 0 1--ighet-coindmatril CEF-Ics with a diffffent Mile, and a chAnce of the Mar of the coardinAting treak acid owing to it% indicator prtqwt.' ties. N~ Th4wi too 0 0 G 0 00 too oo a !21, ~~l C"'wo'clowes, soloso "Alt owe a" eel! 0 -eel it IAt, ad 04, its :: : A 1 -5 rd 0 a 9 1 If IN 0 a a : IsI 60 000611111 000000000900 000111119000 40 - - - - - 00 00 0 0 0 Aj" Sao 00000 0006 O:w w W w w w W-W-w .0000 pseesie 00900 _C 4 S 6 1 1 v _0 r- 1 9 1 13 11 12 13 w Is is 11 Is to 11 1 v is 5 x Vail Nil 1u 9 --L -A- K f _2 K-1 - 1-1-m~ 0 cc -w u4 c - I C41erimekk dalwalsatims of Averise. A. 9. tkbk,, (Kiev Staft UnIv.). Zmabloys Lol. 13, NO-7(1947). - - - 00 F cas be ddd. by the reaction P + Mit s:2 UP + R 1wevided UP is stable wW MR (or ankin K-) has a strong colmalims. The ferric thincyansle method is characlet- 00 ieed by low statsility of the Iwo duoridt cAsmiAn and wftk 0 10 v"Ation. Conwqw"tty It 1114Y he (4 t b : 0 : rut 1% le" tult4 ir h1javd IN studying compks equillbtis for cohrimstrk dets. IU No of c*nWkx W Ti wilth 11#(~ '3 astwas the so& Met #Matsu i at fiami pki M U me C'Me ion. but " for isteems coisrat method has ad- I arm tbe falvic flAwyanste proced-ille but is z= l the Th sawl Zr aliewrin methods. One ad- of do T1 feectim is dot 90s-' and POrl hawr 'm 2 1 a Ti I # b = on ss - , . -1 w -, 1 A. y th" on b oatilikto, A16411H t4"njdp%r% tif Th and It h b l W I&t e ftguiteawnts as go sta ity slid CAMaikitl i y t better than cow reactions. However. many ions fulin low-dissociatint complis. with Zr and Th. B. Z. 1C. &%*.sLs -tvAuvrrKAL L1111MATIAt CLAISWICA11ON w V011014 Nit U U Cl tl N "a a I I% 0 00 oie 0 0 0 0 0 IS 0 0 0 0 0 00 0 )4A Jill N"441 duioaEw r L -I- b- I '4_0 -A. A-L_L~ zoo roe zo o 00 boo C;.i ~' gas Tiff sw 5 a a 3 0 v EA 9 0 0 0 0 0 4, 41 :1 w of 4 4' is r, 01 Q A IS a 4 IL I, it 41" 1. pit -I i; I I?. A& I It'(71 I; SIN litt-1410 I Ili lItit with lovol, 0.1 Af NZI~141, )KIR.-Fed to a klinwil 1,11, inliat 110111011111111 IlIt'"ll,11 filh-IN V1011 file jilfill 1114.1111 It 1011. 111 Ai'll, IV Aloft V 1*111, VI 01 VII 1,01 lot.' mplit"t 111, 1-11, 01"A- "fill 1 411.1 l- oll 1.11 3 aml I'll , ql~ viiIII VI aml VII. "It It %.I .. %ilh Ill 41.4 IV, ".. 44- At 1-11 l1w I I., t I,- fflev,lf, 11'.1 IN--- t vrre;t 1,11 7 it to 00W, From Ow -urvr%. the di-ts. "Hw% AmI .4 C11.1W Alld C11. I 00 AW, - -. tr-l,,, A ric derivril by taskiog I he undille tit 1 he f1witif (I'll 4M 00 ICII&III $111111 1,1111lod IN111* "lilt g A,,,%: fill , p. I A, Ill 4.1 C_I. 411 111P) lot., "two.. 4..,l A: - 41---o -#W -4 jilt. . lot A, I'% A. I.-C A, "m I., I'll .0, vAIm I littill K-Wl*~ ejjt-t;;eIIC eIIAjALIVli%[k- l'hC li*t" jWFItlit -tv,troctuma Ow -419IN11 - -1 cute" ill t1l"111 1.1 I'll- -ott'l. - tile 41i'trithi. [,It total I I I, %Ill - I . 11.01 tit 1.11 31. twis Ito Of, t'llal C16 1. 1.."% cit I " and 01.1W, Ill. the log t Ili- I'so It". - I VIA, A.-Imr, Ildlet 46.11, at .1, ve. ,I lag I %:o I 'I fit Ivim, ill - I"K J."41 I Al"VAI Will I'll Al ('If [it-ill 0 ill At 1.1 4tjAm, IW111141 loilli-All.91 ..I tile va"Ilplei, I'mom- J!hC 149111, Ala.114 WALL~96KAL LiTtIlAlkil CLAS% IFKAI MR u IS AV to 011 IS a IS 9 PC If u It 111 I Sir 0 910 0 0 0 0 0 0 41 0 e 0 0 0 0 0 0 0~0 0 0 0 0 41 0 0 0 0 0 0 * 0 *- nab MPIIA~Jkv 16,11 'it it 1.. 10 $ogf it 4 43 twtire I., AA Of CC W (I N.4i I It I I ..... ..1 $1. tit AmAlmof Lij. ',d, AI -Ioa . A, II-M IIY 2124); IL. C..I. 41, ~kWiiej ItImn the w"01 lj~Nf fill 11.1 It Cut %11.1~ %lilt 3 (If 11 if till 411 X11"kil At lilt 1,11,41 1,1144 %.4 21 "p. fill Jill I~ N. 'Alth tdl.l~ 1. V, . VII, '11". .4 11, 41 .1 01 , sai I 1 -60 t'411 % I-. Of 1111 M ., 1111. 11 1 V. V, V 1. V 11, At r 1. 11-11 1. 1. .1, imm . IN't 114. "'.. J.. . 11. AI .0-11 0. ".1 - I Ih, .4... . .4 A. A-1 A , .... oaw 1'. it.. .4 C.0.4 A-0 C,INJI, AILA14. I.It 6% 11w v%tarm, C10,11, -. Ow C'.111INI. fly Alkali at a1.411 I'l I 11. C-11pari-I of K. - It, zoo tile -rrv,I."s-Ioax riped. lFe-ij-',;I I,lPr.W'l Ili 11 1 ill,- 1111101 If..41rl ~1,1101flr 44 tile Fr-S'll 1~cjlplj-% .0"mot 1.1 -4111.11 Off, .4fl, W,quile, to 0.40 Soo itt-i Vig~zvl --Ilti I- 141, .4 A., I..Il.t .4 Ill SOO N 11-a z;O 0 !age see pe '7. 4 1 3. a 1W 0 A A -1 v IM 0 0! 0 0 010 0 0 a 0 0 0 0 0 0 00e9090 00 0 40000 0 Goo 8164-44,66 -44 9 0 0 fill 0 Wo 0 0 0 -07w- I ) I A I I JI t I 1 11 X 11 U if 14 If LO 11 Ll "AfhVnAiaAL17A W 11 A4 I a t1 1. P 4 C U 1 D 1 1 A A i 11 64 13're . - 00 . I .- - - - , L_A__# F 9 1 _j _ U.. Y _A_. T _ A fl f __ 1 0 00 9; W, U I 4t s f . " ~ rx~ , d , th _ W-la- VJt TT 00 - a 0 cum iocyamis compeas. A, K. 114 U J GeR Cken S 8 R OU-140917 ) 17 (U . rd t- % , KA". of Mull (rading lit t ll 1-00 . . . . . . . . ) al,814. An" joentel %RVV~ (up to 375 trip) on culd". a 1 'A (in R1104410--i[l) The rittitwitiou f - log h/ 1 of fulfils. (O.Olb V.11XI AN of NC$ - but thrfr still f- no stnmPtiOn 1 -00 :: C oil).] At Moo,-- wilt 0.1 NSUCA, in varying ploportions hand in the visOlle: this appears Duty at higher NCS- ; ; 1 0 at coast. total voll., in excess KNCS and IICI or 1188(]tii. contents and is fully developed at aboift 0.1 31 - The shift - 0 00 it ElX2SUF"I With A hIUC-gTT'Cn light filter and plotted agaittlit of ultraviolet absorption. without atiAmPtioll in the visible- -41100 . I . the Mal. r4t io Mo' *jSn' *, &bows a nux. at 1: 1. 1 letter. is tvWatly due to - IMD(,N;cs)lll*. 00 a t. the oxidation state of Mo in the eakwd ~pkx is S. The grneral whenw of the transitions it Mo`* + mNCS- -60 1 (2) In lniltS- Of Mal' With NCS_ At COU%t. total VOI.. If " lmo(NCS).111-14 (Caiark~%) + (S - wWCS_ =2 _111111 6 frun"ured uuAlef thickamits of 0.05 to 0.2t) non.. with a Mo(NCS)s (ml). the transitions occurring at abOUt 0.045 fight filter transmitting in the region of W) top) h.Li a tuas. Atando.w.UNCS-. (4)Froultbetlatleolthecurveol 1 at a trial. rAtic; 1:5; bence the coutpitz is l6fo(%C.S)b. * against log I NCS- 1. at ronst. "intent Of MOM follows 415411111111 : 3 ! The mat. if sharp in 0.4 31 soins.. leas shup in 0.2 M if d 9L t l I Jf l l f l that in Mo (colorlevi) 4- aNC.S- -, Mof VCS). (culored). an s it . ; tota * a lio a ls with incteasing diln., the corit. a - 1j) to I.t; the diwwn. coast. K - I Mal - 00,31 Indlicatins increasing di"orn. of The Complex. (3) The 0.001. hence. ow half Of the coo 00 a Shape of tile r (-Utve% at NCS- concul. below the 1:5 ratio total Mo exist% in the fam of the coinirril Complex at a l -at the inax. (iiinws convex to the atis of stra-luaii) Inill. al, NCS- of alillut 004 Af. lownraw of INCS-1 callen 00 ~l rates fornfation at a colurk-41 ronspil. lrlw(Ttl Mo(NO)i ' . coo 00 ul Mot . It% twilin. apiwars front the Iflot a( r against ali ' I % abovt 0.".4 U rewll% in a weaktidull Of the color, evi- 00 j t w system to - Mu(NCS)A: the deviiii"t of the me- dently owing to Imitation 14 the lem.irtitnwly rolored 0 0 tUAI 0 ftOfn thAt cAW- by situille additivity. corresponding N. Timm r4:411110 0 a the degree of decolarizatimi. is MAX. at a poi"t Close to C . to The compn. lMo(NCS)l4* or jMo(%CS)2l8l. Tbm complexes are foruml at km NCS-- the colored Mo- 0 (NCS)s exists only in the presence of suffilicint excess of - ! NCS . This is bum oat V)flloits of caffalia" thecown. ",:J CS - 0 PwAft throvillb a insist. l, I-C eare--fa Ma giva rlse to Incre4wrill fannation of a comi4ex. Further tIVNICOVe is t"vrd from r zt! curm In tht Uhmiriolirt: the alf"wilm of a 0JKj5 M A* lie. It' ~ J U V& AV -0 it'; Pat) Ila 14 911 Of 6 I'd 0 04 1 A) a 31 0 n I to KX q 0000 010 0 0000000 411100 * 0 0 0 ~16*9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0-10 0 0 0 411401 0 eie 0 0 0 0 0 0 0 0 4 * 0 0 0 0 0 0 0 0' 0 *10 * 0 0 0 0 0 0 0 0 0 0 * 0 0 0 0 0 0 !*0 gee** 0 0 0 0 14611.- ~4~ 0 ~" i - 0. T 0. 10 UP it f Al It 11 1: a 41 U is At Ott'ro t IF C a I F__A A_jL_L_ .1113. FO P341lieFW1 (1), but the finkagm air not its stwill; as thw. foulld %vith Co sin't I will be stable allty itt 'Lilt pres- lisreadllybolAnCliCls.. springly in W4 JIM C-.114Ch. 71- ell Complex, (Ifill. slinilar complexes- of KI and Co Otowv the -Lalne hJuMor. Coolpf" formatien In all these_oh,s. b. Oxi-vc(l, us the trttal coulplexiii nip all eleeply colored. Siiifmali- cylle Beld also gives tt-mry- coinplexes, a,;- shown by the! dee colatutions prodila-d. 1111s; 6 true for ultm~;&Ikvlic'; uthl".1so..And the collqAleles cj the WITT Art.Al"i histy . in wAtcr. , In all thtmi owupiciies (xU.6 diust coulz arniz: zalicylie aidd) it k nc~er plimitil QDL kmothtr, ~ i.e. an aniolit bound In the ewdim stays ked. Under conditims whern the 1card' sphere can be filled uith ankal, the tomllition 61 qpplexes can w foulrer Oneur. lVerner JaCCIbson BABKO, A. K., PILIPaIKO, A. T., REVILEE;'I'D BY KuZNETS-01, V. 1. Chemistry, Analytic Calorimetric analysis., Zhur. anal. khim-, 7, No. 1, 1952. 9. Monthly List of Russian Accessions, Library of Congress, 1951. Unclassified. 2 V.-,SR. J0$2. 7. 3-13). ism n 0 1& I%vly milAil ClIftf, 4LR tIMI WIN ~b`hv it. 11 Iceant lillusilly bl, rllggunat~j In I itemakin twmn - td phaw and di'm4val a t. %.I ullipw litilw(Anco, The u- .,I the pt&vAA ,I phykv- u%KAL aitalysis AU a allutioll, fow"i-Itto" .1 fur studyinS wAuWbtL:h4vW* In iwmevA-* kjmak)u , rtu" 1. -of 4-.Kl". It ll-lumn Illorby MAI pri. "a mfirillt] 1. I.mr cjmsr&; (1) Ahmonce W c-X%4c% fiximmkim, chmactclimd by a mAk. Imalutoill). 41 the " IVAIVI" jKlInt ('the - WW - q1w fut ust in chomical analysis). I 't"Ing udnplell iUftUatHXI With It lYpt. nGt C0431rdillStlVely saturalvd, HSI,, chwacterind by a mill. at the rquivakzce "nt juo rjLcrlq cg cuoulkan 4unfil. J3) cianplex formatim where the lopt. I% a ovoctituatively s4turait-4 cumj~md. eg. No.AIFG. chaffowtertuld by a tvdMCtklkl in ~Aabdity with excess, W vommon cAtknu. atkil 14) weak %olupli,x Immatim tk-t%%vn the um. A Oll, Pill lOw nuijwity u( teal pilt. confi,tim it, tills type), ( I , im, ga by X), cliarachrriird tp), a cur%v ob,minoc . max. whem I h,,.rr is no ezmo C.Asa>C.IIg. Thi'sisfurth"com I.-%I by the react kon CuoC, + Ma, CsAxs, + 2 Cu 4. which Lakes 14"Ce vimuillittiv an 2 Irm, slaskillif "M Cusco with a ~,In. 1 #4 Mx: %h, Cu * 1. fulthvt "W"I to Itu , I %but 'A,gf' L surfuttk, A,, -11w ~pt,, aligissallY tvd- -own (Ctcus). Ismoturs white (CAgm - ran M." ex. ellauju bcto%ren $Witt C6AS, nod a San. of 04'. Joel not take jilacv. (Is (frAttucitt at molid CiCut Oft O-W Y "n. " IISCIv. the p L bertmon sthile W,118), awl -IN- tal Cal, Smilar y. volid VeAs, WOW wills a "It. of Is. t... If I IIS(IN(N). also., 4 I'pt. conts. only list. -Aith all the Ag aulux Iota solo. Treatontut of %olid Coll& %illa either Cu* or Ag+pmIumnocisanstintheispit. Hythiedefirtitissnof 4, one shoid(I cxptct, at emit. 11141. Ift"JI'lCiffil - comt., Im. cxccu Ag' slarmid dextu the s4y. at C*Asj arvagly, and euvo of Calls in in. less strongly. Thi- was confirtuc4 by cxpts. A *oIn. of KI AuNI(I d"t"Is. CoAt, amordins to CoAg, (solhO + I- + 2 IIjO r-, 2 Asti (isolit!) + Colts + 2 Off-, with the rQuil. const. K - ICr 1141101111.11-1, - 4 Y 111 -1, 11 Ith a I JV WAD. of KI, ~L 6ft" USSR/ Chemistry - Vanadium Jul 52 "The Study of Colored Complexes of Vanadium With Hydrogen Peroxide, " A. K. Babko, A - I . Volkova, Inst of Gen and Inorg Chem, Acad Sci, Ukrainian SSR "Zhur Obshch Xhim" Vol 22, No 7, pp 1108-1116 States that a study of tae :optical properties of solns showed that vanadium forms 2 colored compds with hydrogen peroxide. Notes that in a strongly acid medium, where [H--) is N, an intensely colored ccmpd is formed with a compn corresponding 0 cl:l. Tn o-n alk to V:H-t:' 2 229T30 irreedium, a weakly colored peroxide compd is formed with a compn corresponding to V: 1:2. Says that a comparison of the visible dis- socn of the vanadium complex, formed in an acid medium, with its great stability In relation to acids, indicates that the vanadium dyed complex with hydrogen peroxide, formed in an acid medium, does not contain a bond like Me but represents an addn- compd of the type ZVOX (Hp )~ (5-2x). 2 229T30 -BABKOj, A. K. ola co p of vanadium said hZkM*c' K. fkhk a .614"r. UOSMU111 ARM Z Chemical Abst. *ZAT M J. Urn, CAM. U.S.-Y,X, ZZ. 1149-MI952).-- Vol. 48 No. 6 Colored solvis. were prepd. by combtnint a loin. of 6 X 10-1 M NHMN and a eoln. of 8 X 10-OAI A. Color Intensi- Mar. 25P 1954 ties were measured with the Pulfrich colorimeter at 485 inp. Inorganio ChemistrY Vanadium forms with Hj% (1) In Wngly addle solu., sit Intensely colored stable compd. In which the ratio V:HtCh - 1: 1. and (2) in basic soins. a lesi Intensely colored corapd. i h h V i O vr t t e rat o : Hr t - 1: 2. Dissoco. const. of the tirst Compd. Is IC .1 x 10-0. it 1, te c PTlelea. A. K. Bubko and A. M, v a t~~ )LrArl A jum'. 7he '04CI16A!, a Ag q:f dcrtr-it (N,j~,&An.~th (;.:- : , '' ~f K-X (0.01-IZ~ WCTc dcu~ sit -104. The Nuil. reactun 13 remed a3 ]Djf -IoSE - mlog- 1 = tbt s3apt of 'brIX-1 O.Dlttd aphst log Pro m wam dete. Rod 6e equil. conxt. X caled. Lol IX-1 wcA obtAned fr c= the pntenthd of Ag-.Aa (Ior CI -,xj Br bit not f~,r P, ' Sil -' 1,.m the p-rewial o! the BI electrode, and IBLX(.---l -'I %ras LLSTM ed to be "jual to the toi..I BI omcn. TIe foflo~ing ecrail. masts 2,nd the vor- rv-pmding compl"rs are miriv K, - 1Di"j!X-j'! ~BLKQI -1 a" 3-8 X 10- for C1. 2 X 10-:1 for Br. and 3.1 )< 10-11 for 1; K~ - IBP'jjX-1'/1BiX-.j are rLS X 10~ for Cl Intl 1.5 X 10-4 IuT llr~ K, - [Di"JIX i, 2 for C1. 1. Bencowiti t/,4 85. DefermIn Milo Quivalent Jmm by ineaus 01 tetrabor , A ,.J, . Clem., U.S.S.R., ate. - M:125):- ~c paper of -Schigol et al. 1953, 8 [2), 1 (Brit. Absir. C, 1953, 157) is niTon . nit adverst,ly r2ots ,etVT, i criticised. The Lxpe Rdly arrangcd and the results were Inadequate to give the cone cluslons stntcd. G. S. SMITII