SCIENTIFIC ABSTRACT BABKINA, N. G. - BABKO, A. K.
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Collection:
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CIA-RDP86-00513R000102910010-7
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RIF
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S
Document Page Count:
100
Document Creation Date:
November 2, 2016
Document Release Date:
June 6, 2000
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10
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Publication Date:
December 31, 1967
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SCIENCEAB
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MILYAYET. Arkndiy Pbvlovich; BABKINA, N.G., red.; ZUBRILIKA, Z.P.,
takhn.red. I- -----
[Manual on sericulturel Spravochnik po shelkovodstvu. Moskva,
GoB.izd-vo sellkhos,lit-ry, 1960. 345 p.
WRA 14:3)
(Sericulture)
M."'IENU Ili IN, , A.P., prof... dokt.o-r, -sellkhoz. natd:. --as-L'. dieyatell
nauhi R-F.,-R: BABi"I"A
I o red.
[Effective 1ife of fam wnimalsj ~Ircki ispoil-zovaniia se-il-
skokhoziaist,veiukykh zhivotny.'~:h. Miosknra, I.-A-vo "Folos,"
196/4- IS2 p. 17:7 )
TOI-VE, M.F., prof., doktor sellkhoz. nauk; &4BKINA, N.G., red.
[Feeds of the U.S.S.R.; composition and food value] Korma
SSSR; sostav i pitaiellnost'. Izd.4. Moskva, Izd-vo "Kolos,"
1964. 446 p.- (MIIbI 17:8)
1. Chlen-korrespondent Vsesoyuznoy akademil sellskokhozyaystven-
nykh nauk im. V.I.Lenina (for Toiiune).
ROD I ,-,NC.,V . V,,V. I- ."-;HABi--R!)Hu)V, L A.; at. i3K N.,G, . r.:-d,,
[Mul-tistory beEthives and methods for beekeeping) Mn-gr-
korpusayl u.'Jni A. metody pchelovoz.hdenila. Izd.2.9 pe-
rer. I dop. Moskvav Kolosp. 1965. A57 1).
PADUCHEVA, Aleksandra Ieonidovna; BGYKO, Dmitriy Fedorovich;
BABKINAI, N.G.J* red.
[Hormonal methods for increasing the fertility of farm
animals] GormonalInye metody povysheniia plodovitosti
sellskokhoziaistvennykh zhivotnykh. Moskva, Kolos, 1965.
302 p. (MIRk IS:4)
POLYAKOV, I.I., prof., doktor biol. nauk; BARPNIOVA, K.V., dots,.,kand
sellkhoz. nauk; KAZANTM, F.I.I., dots., kand. Bellkhoz.
nauk; ORLOV, A.V., dots., kand. sellkhoz. nauk;.BABKnIA,
N.G., red.
-1-
[Practical course in animl husbandry] Praktikum po zhivotno-
vodstvu. Moskvaj Kolosj 1965. 222 p. (MIRA 18:7)
MASLOV, V.A., lnzh., GIADYS107A, L.P., !,~7)71.
Us.-Ing resistance welding c:!' 3prayers and autoclav#3s
instead of gas and autoira.-~ic wqld-ing under flu-c. Svar.
proizv. no.904 S 164. (M:RA 17.12)
1, Kuntovoy Wel svarki Ponetakogo soveta narodnogo
khozyaystva.
,,- / - I- I( /,1" 7
/- ) -r- 1/1, A / /~ -;, ~- /,
VASILOYEV, Ilikobij Aleksandrovicb; BABONA, N.T., red.; GORIKOVA, Z.D.,
tekhn.red.
[Raising sheep on state farms] Wtsevodstva v sovkhozakh. Moskva
Goo. izd-vo sellkhoz. lit-ry, 1957. 91 P. (MIRA 11:55
(Sheep breeding)
B A BFMTA , 0 . I.
IlRelief Forriu-na. Activity of Sna-4 on the Eya:r.:.le of Khibin, the Territory
Near Moscou and the Western Caucasus." Cand Gno,g Sci, 1..oscow City Peda,-,oZical
Inst imeni V. P. Potemkin, Moseaw, 1955.' (KL, No 14, Apr 55).
SO: Sum. No. 704, 2 I~ov .55 - Surve:., of Scientific L-d Techmical Dissert,tiOTIS
Defended at USSR HiFter Mucational lnstitutions
BA3KINA, V.iL., felldsherites.
-.1400--Q ~11-1-*"A -
Feldsher IAkov Grigorlevich Brusko. Fel'dA akush. no.1:58-59
Ja 154. (MLRA 7:1)
(Brusko. IAkov Grigorlevich, 1892- )
L 15882-66 EWP(e)IEWT(m) WH
1ACC NR: AP6002807 SOURCE CODE: UR/0237/60/000/011/0027/0031
1AUTHOR: Denikina, L. I.; Selezneva, A. M.; Shchavele 0. S.; Babkina, V. A.
!ORG: none
'TITLE: The depqndence of thermooptical properties of silicate glasses 'on their composition
iSOURCE: Optiko-mekhanicheskaya promyshlennost', no. 11, 1960, 27-31
TOPIC TAGS: silicate glass, temperature dependence, optic glass, glass property
ABSTRACT: The present paper gives the results of Wyexperimental study of the average in-!
crease
in the value of the absolute index of refractioii-in glasses caused by increases ini
------ - ---The four base glasses used consisted of
temperature at 643, 508, and 480 mp waveliniffis.
1) S102-80, K20-4, Na2O,3-16, and As203-0. 1; 2) S'02-80, K 0-8,- Na 0-12 and A8203-0. 1;
2 2
3) S102-75, PbO-19, K20-6, and A8203-0. 2; and 4) S102-75, B203-3, AB203-0- 2, BaO-7,
ZnO-4, K 0-8, and Na20. 1 0
-3. They contained various amounts of S'02, TiO2, B 03, A
2 2 2 31
0, C aO, K 0 admixtures. Experimental d
A8203', Sb203, PbO, BaO, Zn. 20, and Na2 ata orga-
ARKHIPOVA, T.N.; KRYUKOVA, A.S.; BABKIIIA, V.G.
"Glikasin" sizing agent. Tekst.prom. 20 no.4:54-55 Ap 160.
(Melamine) (Sizing (Textile)) (MIRA 13:8)
FENIKSOVA, R.V.; PETROVA, I.S.; VIIT.LSYUNAYI'-'-',, BABKIIJA, V.G.;
NESTEROVA, G.A.
Use of proteolytic enzymes of Actinomyces fradiae 'or removal of
j
wool from raw hides. Prikl. biokhim. i mikrobiol. I no.3:257-262
My-Je 165. (MLRA 18:7)
1. Institut biokhimii AN SSSR Lmeni Bak-ha.
BABKINA V G ; WRABIAN
Y K.M.; OSTROVSKIY, V.S.; RABINOVICII, Ya.M.;
BELOTSERKOVSKIY, M.Ye.
7
Liming of pig skins 'with a reduced quantity of sodiumtsulfide.
Kozh.~'Oobuv.prom. 5 no.2s2l-22 F 163. i (MIRA 16:5)
(Leather)
BABKINA, V.G.; DOWNIMIN, MS..,, ABRAW)VA, N.I.
Change in shades taking place in some vat dyes under the effect
of moisture and temperature, Zhur, prikle khim. 37 no.6:1328--1333
Ja 164. (MIRA .18:3)
1. 1.1auchno-issledovatel'skly institut organicheakikh poluproduktov
i krasiteley.
NUFMXHAMETOV, R.N.; BONDAREVA, L.V.; _~APKINA V.G.; DOKUNIKHIN, H.S.;
ABRAMCYVA~ N. I.
Study of the behavior of some vat dyes in fabrics from their
fluorescence spectra. Zhur. VKHO 8 no.5:588-589 163.
(mm 17:1)
- 1. Nauchno-issledovatellskly institut organicheskikh polupro-
vodnikov i krasiteley.
KURAMSHINA, M.G.; SHIKHOVA, N.M.; GRIGORIYEEV, I.I.; KONOKOVA, Ye.I.;
BABKINA, V.L.
Inpunological indexes and the biological activity of streptococci
in the combined treatment of rheumatic fever. Vrach. delo no.9:20-
24 s 16o. (MIRA 13--9)
1. Sochinskiy nauchno-issledovatel Iskiy institut kurortologii.
(ANTIGENS AND ANTIBODIES) (STREPTOCOCCUS)
(RHEUMATIC FEVER)
B IRA,--S-,L
Influence of factors at the Sochi-Matsesta Health Resort on the amount
of cholesterol-in the blood of patients with atherosclerosis of the
cerebral blood vessels. Vrach.delo no.11:85-88 N 160. (MIRA 13:11)
1. Klinika neyrorevmatizma (zav.
instituta revnatizza.
(C.HoLESTEROL)
(SOCHI--HEALTH RESORTS,0
(ARTERIOSCLEROSIS)
(BRAIN-DISEASES)
- prt%.,. K.F.Nikitin) Sochinskogo
WAURING PLACES, ETC.)
Resistance of ornamental plants to flue gas.-Biul.Glav.bot.
sada no.33:48-w-52 159. (MIRk 12:10)
1. Botanichnskiy sad Dnepropetrovakogo gosudaratvannogo
universiteta.
(Dnepropetrovsk-Plants. Effect of smoke on)
BABKINA, V -M. ''. ~ -
Flowering decorative plants for industrial sites. Naucb. zap.
Dnepr. un. 78:28-38 162.
Selecting he-rbaceous decorative plants for flower g!%rdens
accordinr tn the time of flowering. (71-85) - - -- -
I . (MIRA 16:10)
KURAMSHINA, M.G.; SHIKEOVA., R.'K.; KW'OKOVA, Ye.I.;,,_A~HKIN;Aj V.L.
At ~
Dynamics of immmological indices in rheumatic patients.
Kaz.med. zhur. 4t7-8 Jl-Agl63 (MIRA 17:2)
1. Mikrobiologicheskaya laboratoriya ( zav. - starshiy nauch-
nyy sotrudnik M.G.Kuramshlna), klinika kardlologii (zav. -
dotsent N.M.Slfflchova) ~ klinika aktivnogo revmatizma (zav.-
prof. M.M.Shikhov) Sochinskogo instituta kurortologii.
-B;~HKINA, V,Yil.; CHUB, Yo.(I.; GA-PUNINA, --,.V.; SPIDAIII, I.K.
L~', watory model of a steaminp .,ntt for corrosion tests. Zav. lab.
30 no.1:1280-1.231 164. (MIRA 18:4)
1. Nauchno-issledovatellskiy institut osnovnoy khimii.
BABKINA, Ya.A., inzh.
Introducing semiautomatic welding~Iin a medium of carbon dioxide
in the building of petroleumi chemical enterprises in Barshkiria.
Trudy BashNIIStroi no.1:122-131 162. (MIRA 17:3)
^- _
Map of the natural zones of the ocean; comments on D.V.Bogdanov's
article nMap of the natural zones of the ocean". Okeanologiia
2 no.3062-563 162. (MIRA l5s7)
(Oceanography--Charts, diagrams, etc.) (Bogdanov, D.V.)
BABEGV, ~"l I eks~-y 1'.F ~n-~ v j i-h; KC611ECHN Ili , - Iv:,Trj,,ivi- ::13 - ~ ~ ~ ~, , ". . : .~ 1 7 1
. -- , ! . I ~ *, I V. ,
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TfIlkinum. . Leningrad. Gi6romotenizdat, 1-),.
-1
(t,11RA 1; : " .1
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64 i
I A I~ . I 1 9 v III)SAW11,16 III# "XIIIJ2 13 )d 21 36 J, a ' is ifoubabisulan4l 41 W 41 a at*
AIL r. a I a k__ a -IN.. p ~ a R I -_ I- v -T - 1 90 Ct 4.t b 9 It j s a,
Volumebic debtrintuaboil, Cd SMdr. add Ift jlxit~ N. A. T&%AMARV di a
jjApXG__LjFaixjkji Kkem. Zkar. S~ Pt. S. 71-XS(I9M)).-FinrIY Pulverized gls%!i is
KI; artA concd. JICI, to ahich is added ak. to dr-
treated In a I't di.%h with a mixt. of
0 crease the mt,kv. of KAN; after imrtillog OW ppt. Is filtered thepligh a paraffined funt-L.-
00 knit wAJIrd with UIrl, ale, Thv filitate tqvilirt with tile Mirk IVIvT i,% wt4rd kill ill it
flask with 0 "41% oft4kit (in"olvi-It the ftwnwd F it4l toA ept )AU, 111tratt-41, %hilelk Ing .00
00 watrued oil the water bilth, with 0.5 N NaM I to the coulplete clarification of tile liquid
0 6 iver the ppt., or to change of the color of thv neutral red indicator. Tbrav.accuracy
jr is About +0 3%. The applicatinii (if IfF in-tend of KF k not advi-able. am IlF Is
11
alwavii contamioated with Sitli. CIIAIL. IIII-ANC
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00
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Voteminatiou of Kdkun carbonate In miscilmit,
YoUnate. A. H~ t~L(Ukraiue Chem. J., in),
- s
l1kij. -30*. unt carbomssfw present it,
SCI.I. 197
(
'bicarbonate in exceis of 3-1% can be duermined by
dw ordinary methoda. Where the content iot lower. it
can W detiribliisod tolorimetrivally by compariwn of
the eolow obt&iW on addition of phenolphtholvin with
-00
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9-k -1 -L.&-.M A--AILL A- MWL
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L;-.,/ I)Oftfalft"Its of famic oxide, alumina, Jim#. mwnb
md Ieelftft IN 1111111110. A. M, 4%lIla,
00 9 *33. No. 2. " 20-2;
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1',-s. VArnion. M. NO-sm,th /nit. 1f/4C7-'3fArinvtr--
00 1933. N'-,. 111; J. Sm. Wals 7,,h. 19, :,',$-,A, Ih, lf"al-
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treiated in the cold with a frembly prrpd. NaM ".a. 14
cc.ofO.1 NN*DHwW 16ce.olo.1 N 1) &M the hrown-
S; black color is muipared with stantlard solos. SWIt, in the
-'e anti .
suln. Obutild 1* tentomf by filtration anti At, I%I n
fly plim. with ftx-%hly ptvpd. HSCO.' Cba%. 1118fiv
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min ita!ion in the form of AI(Olf)a by alkalis
ip
'
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by
d
,
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the precipitate,
after solution in acid. *is I ' led t litrixtion or the excess
'u
o 00
acid. To eliminate ,, ll;=,olyvis
d he Al' k. It 1,
boLod fly the mudate in tile presence of hjgCh.
method it
i
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l
30
40
f
;
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se an
im
ta
to
M
n. 71e
odometric
mr1luml 41u$ he U~I. The "Ution. after tecatruent With
R.Cv()., is nrulrahad and afterward hailM
with KI.
K 1(h. aud CaClt; dW removing the iodine. the FrAidual
The tlwthtxl is Inntrexpensivrand r 00
lets ptex-i'v but Call he IIM41 if great Tiantilk-i of hfit0and
Then%Attecan w6trateduaiderimil.
iuX with alumina and u%ing turthyl red until the voinplex
K~IAI-(CrOt)jl ib formed. The turthod 6 rApid but not
"D 11*91111agluxult tin
0o0 *0
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06 "Cates. AJ;-. k'aim. K". Zhu,. 10. 13:3 -47
h
f
00 e
in t
titrati4m o
i,frwttcr of CsCl, &I al.mit 90' j. th-mly r%s,-t ts.~Ilm.l of
'
oe
~
volinnettic drin. o( Sit h in %ilwairs. At ltjw tenip. j 17
"Itti Phenol red %Ati%facit"Y fc~ultfi ste P(Kqibir only at
00
high diln. Titration curves are given at lboth Icnips. fin
rOO
Na.SiF. alone as well u in tbe prewrice of NaF and Cecil,
coo
at varying degrees of hydrolysis. G. Tolpin
3
se 0
no*
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1, 01 t A.11ALLUPGIC.1, 1.111-TUXI CtASSIFKAISC"
too
to: 4
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POCCISMS MAD Okaottlatl
SIMPLIFrED nOT.MITINETRIC TITRATION, A.T. BABKO
00 a well! Zavodskays, Lab. S. 1387-8 ( 1936 I.F. Lyubimov.
*0 & Ibid. 1388. -- App. for rapid titration Is illustrated
and described in detail. cl'as. Blanc
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t
'
lie ob*t was lit
IM-41(im) (Ckmkan suounsfy).-I
16 ks of M-allpatin lake in wq.
luvrolasts lbow
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q 1"I A" 1 012). rficvI"1
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so j! coutit. comm. cd alimdu tb quaritit of lake iDcfvaws lit a
U"
wA&r ratio than &be cm InLreswus rotwn' of
4L"
4
00 A.nd allsawin t1tv 4111n.
1
o1
Ion of
1
Al. At Us 61014
Pr
WO
ll Al
k
l
I
l
i
o
mo
.
W
l
l
lwr"m The Allit. of filhistin twAllillwi
Chat. 11611C
11`9
7
No 0
At. it A
t; i~;' uA'-' 71-- J.t V3701ZI.F
Joe
u " 0 1 A. r- ,
19 U R a a a
. I '- -
so 0 0 el~
06 A
a
0
0
go
000 !
I AMA L I
_jtD. A %D_ !_I I
FiOCI~1791 A%D Pio"11.1% 1.01A
oempagads. M.
.,Wkwaw, Cow Tba of A wharsts is i -o x io-4. am its ~00
6061terAma" d k" "A MbMMWWA- opwinm dow not dMw fnm that of (11) or
at 4*--M mo., but bus on &"tkml hand st soo- -00
.
-A~KAk&bso (smu. fw. lusiv. lv*y, 1"1 3, no. 3
v~m
t
am Trooft or A] &&I Fa am dpkqmIW4 in the
m= W, SIMI. of O.W% (1) an added to the 00
00 0
"'I"Um at ft 1
w
ask a
-dowk
11141 of colour (1~
boM* am a sohdke (DMMWW S-40 g. of A.I,0,+Fe,, ).
f
llo
b
N
=90
,
.
.,
WWI HMA with x -6~ 2 x 1111" Wd ir" 4 1 x 1048 o
pwagi,
y I UL asek of X-N&OAc and -AvO
O
am the
,
44)r
mad. is macis up to 16 ml
The cog
coo
d A
omplete at ))j 5; thk
up ,
.
PtI&M
Sim
6Y UN FMWtit4 K1UUO1%, UNIX a
-fift
L
7
I-
rog
4
above WMA it
&
7III
fi
l er t of I other 46G.-= mp,
t
to detoormiod. the Fe + Al -w-t-ut, I. read fmm I
stly A
ksoeisted (
no OPeett"gum Of
111i III Alma* i&ut W" tW of HAI
1
11 th An emPirie4d cun-0. Fe atom 6 (letermined simfiarly, '0 0
10
e
, 0
MwIlIDD-400mP.; uking a filter tranAmitting tight of x 6oo-4wo m,;
A] b given kv diffmince. R. T, z0 9
A I a. % L A &EIALLWGICAL, LIMAYU111 CLAIWKAIIDN
.11 o-vost
u III AV I
- -1g; I; g; ; A; 1111111111 Kait Igo
0 to is, Ole 0 0 *
sol __ ____ *of
ZOO
logo
t-o 0
A Z Z. too
1juslowl; a- ji.
mr 0
tw 0 0 1 IN 1'1 5 i1 a 3 1
AID A I 111% dAC
0001000o0 ***be* 0000 oo::l
;i
*Sol
0 4r-
0 ap
OV
Ow
411 0=
Sep
Ow
*01
IM I U011411121 Nimbi
A 6 c 0 v S Is A L 0 Fe 0 1 T vv
.0-to MOIR
0
Nis go W!
a cm AV a
tocall
OU311 '1q R" ptm rA
amtojpxq as IN .14d 31 1 *11ovv 'film
PM "N't 1114111 q.141A '011*111
AN 4PA lull-it Ag Ilve #HN "H3) I
psm jjN
~~ U311.1.
ql!A 93 Pull CHN qyA IV P- OA 4()tlll~
P"W`OIq _1W 01 '0011 Rita paq pus i;ONH qj~m aldill,
aq, z 0,-j 'I JMvZ
"Micy !n-tv It .0
M 'J"I 'If*[ 0806 rwIt"I "Joy
,13011Y to"
'd P"M OjW'vX 'V *A~rtrWE -y -K *s" iq
, " P MOP --N IR P" sevow"M SIM10,
at "Ma womosm
9W.-Mvp is$ powevir 0963
J, so
fIL
IF 041
fir
til
So jaI73 .11 Q.,
tr-r--T--1r a ii -61
I T
a a it 9 K (T ?I it at it it a of 9 a jr It It of Oil 9111"till 11 4
to 0 0 0,
O'w WOW
3 6 1 a I to if (I it M 16 It a is 11 X
~A B xjTxM:Hlf UZI if C if U at
a M~FR LE4JL--1--t--t-j -.-L-t k j A a --A LIP 0
kD peortyl.ts ..I,.
00 The Istrestiptin of SJUMIDUM oxalatif Complests and
thifir isdUndes #w the deterw1ution of Aluallnum, A. 00
K. r*' --[Sslrdm~fel- Ral,-l Kfif-
a '14rMJ~121V,4. M28431WIM K hi- - Rt.'"al - Zhu,. 1,
No. 7, 117.-Prm the curve of the irm and 4 1 be corn -
00, hined ams the existence of Al(CA.).- AK,04),-.
00 Ali(COi)*; A (CA)*. and Al,(C,(.).)* ... it presumed.
.A
In the 4em. of Al by watralisatiou, in older iqs &-id the
*0 effect of hydrolysis Al b embined Into an o%alate com. .00
0 To det. Al iodometrically,
0 plex K C. A. 3D, 21321).
neutralite the %oln. conig. Al in the prc~ence of the oWate .60
00 and of 11901, boil the soln. with C&CI, to remove oxalate, -00
00 add KI and a goln. of KTO~, back-titrate the excrts iodate
with %0,--. A) can be drfd. a little let% acrurisfely by coo
widlar to the Al call "n. an cxccx ig a siandardized coo
ofs-,, K1~7, ode., neutraliting to mt-thyl red, and titrating
the excritsexalate with an AIC4 vAn. Thecoloroffriethyl
00 it rrd clistrig" when all the oxaJifte is combined as At- goo
W~ R. l1rim
$00
%1010111) It .3.1 got 47 - --
is -islia;- . 1, 1 i i zm
Od 0 0 a I v go 5 a 0 3
'0 IL4 641,
1*1 11 Klo
000 00 **go 0 0 0 0 0:6 go 0 0 09 0090 0 0
-
i
4
0 *
~110
P 00 0 0
m1 1 1 4
s
1 1 s is it it it m is is ip I a IS 4 Js as it At U I' a it v a a a
I it P v a
. '
o
n it st is a ate
4 1. a x P a I I 1_11 .
- i
t
a cc n ail li 4 d A f A I
Jj.
00.
4
of
NTbfp appiludom of solid ftdwU# &puts (in auslysiel.
,
00 .
A. K, halika. Zatomilikaya ]Ajb, 6. In
-
sirtn. of Cu and So in bromcs and Rabbitt metals toy
thi
ntethod (C. A. 22. 2MV. the bc~t rrsuili
he -400
Air by reduction with rkctrolytic Hi in strongly
= -00
IICI Submit. in the Jones rovdisoctur sold duW1 m lkiletilm-
00 metric tittation o( Sn I I with 0.1 X KNInO4 Ito all in- -00
'nt yellow (CaCI, in 11CI) and that of Cut with WI
t
%
-00
K.C,^ and dipbenylamine. The pre-sence ofq) and
I'll is- harmilcm. The detn. of Fe slid Ti in itttlellitc i% see
00 'Jj- based on the reduction of the :1 elements by viectrolytic
see
t Zil and Cd and that of Fe by III. Ti is not rtilueed hY
o0 ,i Hi in dil. HISO.contg. N&N%O,. The reduction isvilmi-t Gee
00 j its the Jones app. After the reduction with Zn or Cd in GO 0
dil. H.90. Tolls., the stairs of Fe and Ti is titrat"t with
'
00 rhe tilmied
KINN04 or XjCrA and dipliessylantine. too
00 It mills. is trmt"I with 11,0 to 11K) 2(No 'V. %-W. alld 5.7 a.
Nabk), tolowrr thravidily, alld 111C Fe Is triblet-11 veoll
00 z Ili alml titrated AsAbovc. lh, gee
9 taikA Ist-medurri; ate deactitmi. .1kovat rrf~tvmv..
coo
Chas. Mani: goo
gosll
S a .L A MATALLURCKAL LITINATURI CLOSIO'KATION
SIGN. S1114111 1.
i 180080 it ON, Get
- filial4pt 44,11 -aw"Y sit
I
__
U IS 10 a ; 1 0 - - 1 7 1 V 1 0
AT
Ot for IF it IP a a a of K 4 it a it a
S& a M., 0 a 0 1
go 0 00 o It o o Goo** 0 0 di 0 0 0 0 0 0 0 0 0
0 0 q 4 goo* Goo goo* g ***I
****,]A
**Gomm
0*000000*000too 0 00 0:0 Selo go 00 0*0 0 * 09 0 0 6040606
0
CTvq W 11 u is It 15 3e v v 14 c . . .. %T C% 'y
Wt-WAL11
00.
0*
00.
_ojj4 pW, q IO:jrH &timjjd aq _90a 00
00
plflafr4 .(101R -ago ~ Lilpf-0 To 1) *OUKN1',VH)
00
00
SO
*1% P0110,11t) 91 Uolmliv Aillpt" ot& %all ItI-) It III
0 N. ,
'
Ol
l
,
0*
9
ill Pu
OWHTP 'OPA PM"l in,"
or.
O it P- J.
)JI
J, *0
(M 411
ul lnjv 1"I
**
.
0
1
t
111,
4m,
.4*u! PUG D"
K)"
it% All Imitollo) p.11111V uv IJ)()jA,(tjjK)
.,(Rt-tvj .-11,NNIV
'R 00
04v
ON 0. Moptivilim'i luolln"Jo
00
:lu3 (ic-itt joA uxomi v m gin a6vigg.1,milia atil puge
00 IM)OW410 ll.AUI 4111 '*(Xjk
. p -If 9-1 qjpA
, I
0
,
,
I-w-"(fit IN '01 U01 00
11alp 11(d
4jifij ~)j ~ .06VOIJ*t"
fit V
I
V
. 00
-001116 OUIPJA Ad me plow Qj;mjd 10 -amoupme"a W
00
*W ews
00
1
*
1
, i
,
1
0 o So o 4.
0 0
0
Ak__
_ ~
0
0
t
0000 0 0 0 0 * a 0000 00 00 eii
-W ~-r-
71
t tilt
.
w
11,
,
r y
j IL L U .
00
60
00
00
00
A.
;lee
00
N--iliMul"'
11
c
h
00 e
,6
S
by t
Alwass to 're LfORU With
in 3-1 Mg-
f will-
0
Mg. o
. lue i, diomoke4l in
Method. 10-15 Si(),, the rem ned
jjFtoremovO
dyesmdetern'
W
_
A, Ti an
1j,
_I - 'Cal
of Inith
ON, Mg lo jg
d Un
.
,
fl,o n
the 901 tim by known Inothod"
.;d K ..I N-
u
i
n
.it,
&re beted
10 by known T
1
,
.
in tj, Iv,,11
detor"jined
lee
ve
"
0 .
IM
dIG
0 it ICU r1ritt [[a(
0 it it K goo
-
0
e
0
. 0 to 0
A- A. I M
41~
O in
li
bk
o,
s
112 baildes of copper mud blanuth. A. K.
,-
-
I
-
o
!
g n-M
A
CIii
w Kit-. Bull. scs., Ree. Chiffl. No.
f.
. . U
n
melll
a )tnulan, 101-3; in English, I(XI -5) OW.-Chloride anti
0 bronside cornplexcs of Cu and III weir investigated.
'4n%, with vadous conens. of Cu and balide and with a
S
tal vonM. cforn. of Cu wetr lorriml, in otdrr to study
zoo
00, 1 r Vali0to, J4d9VV 44 the C.'roplel loartallon. The dMia
00 a indicate that both Cu and Ili forin a III). of vinpIrs stmi-s
which are capable of dimocn. in stagrii. c. x.. to
in soln
.
--
**
-
* and
WW
BiB
C
C
C
r
u
I
.
for-ni CuCV, Cu
4
4
,
.
Milt.- It. Z. Kantich roe
A I JO I L A101 TALL UNGICAL MI'VAT1,01 CLAMPICATIOu
two.,
i
too
e
u is A. -a As
0 It It I
061
,
too
~ ` i
III I 1 13 a3
4411% "Ulm ""lull" Ona
~
:
1
Ole 0 0 0 0 & 0 0 0 0 0 & 0 0 0 0 0!
0 0 0 0 0 0 0-0 0 0 * * * * * * * * * S * Q-* * *
1
-ji~ 0 0 0 * 6601
0 it
1 1 0 11
a
s
*0
00 J
of Ar
L
U 0 a, -0
q 0 0 0 0
0
0_0"d IT-We WANO-44--1111 0-0 1 9
it is U if I, of 0 IF' it 7, N- is m fivil,11 Uld PAID lot) ""at 41 4141 maple
L
.Z181
_vc 0
#%its ..0 1, P1.111%
Application Of labor-COUIPIrs COUSPOUnds In Colo-
trimetry. Detmallastlos of aluminum by meant of &urin-
hiew"M add. A. K, lloiblo. J. IPNWJ t1em.
(U. S. i. R.) 12. Iw-.(in Vvelich.
11hournitwinictiric conit. of the disrn. t-f amin-ricar-
ioxylic acid as an Indicator for thi- cunwrt,hm In a lwi-iv
Soln. wils fuund to tx 13-1. TIw Mom ol the couil-I.
tit the div WhIll Atin tbr VoK. &PA Ott stwitrintitick Sliet-tit
'd Ow "Mitth, at wcN fill of rarikult, limms, at the d.vr 01H
and 61 -1 were deld. The limitation isif Ow 41shIlY di,-
(triAlins (inmr-emplex) milt (M - R) 6 explained hv~.
M* + Ilk z~! NIX + 111%,alterrhy the mimation 4 MR k
vlow to that (if the Ilme anion (R-) of the dve; lim"vet,
lKvaitw tit 1he adAtil. txwut lbettectinilwk. with Al- anti
Fr* ate f-mird in ariclic wAn%. The di--n. Itf
the inner."aupirtl itails of At unit Fe Ic K__-
INWIM-VINIMI. whem Ninstitt 41,111,11.
Nw.. I Ili file 16tvio of Illib alitalill alld Allimilivallivni.-
lit. $44,141 its-10 tvillIfI41441 44 fedfirfIlIf It# file
dent, tit Al. Allmilit IS Imsch vs, rmimsisill I-vois- -.1
IIle 01.1wats""t. 4 a highly r0writ ald ... I "I lilt, 41Y.- itills
incle.sw In I'll. Ttiv atilintliewl.,wlic wid litisivil. A
wht" vatimitm fit lilt, sirmet Oahtlilv lo-dt%l Ow *,,tk%t
of Imiller milus. and a Strattr m(4at almwptim tivIll.
A. A. limbiliniti,
4#11MUNOKA1. 1,111111111,1110 (LAUNKATION
t I"
a I it One
171 W1 4 a tw a -a -0 1
it 44 '14
q 0 0 0 0 0 0 0 v 0 0 111 0
0
0 0 0 0 Ile 0,0 0 0 0 0 0 4111, 0~9 0 0,411, 0 0 0 0
see
0,
#00
tie a
"0e
tie
wee
be
A
f L,
0
0 A
09
00
00
fe 4f
00
00
oo
0:
0
00
. . . . . . . . . . . I .. .1 . . . . . . . . . . . I . . ; 4_
090690900000090, 0 wwztf 9000900901000009
4 1 6 1 1 s 0 11 U 11 ;4 is is it M to '"ITT-111 11 v ji w Is It V a Is AD 41 d) " 46 6~ce
a L -"-I- Q_ A- I I a I M_JM_" IV E(~A__j '.1 1 _t J, B, t..j _k -I- 'r-l-A-
5- b bjID.~"IFS '.t' ..v F~
0
The a of Inner-tomplex compounds In color-
=.,KFvMbko. Trudy I'sejoyms. KuRIfirmfoll
At 2, =v320V43)-M(nt coliximetfic drtn, i -00
is bated on the fact that the i*n is tran%fartiml into a cam- ~00
plex compd. 11w intensity of the cokar and the dixvwn.
INKISI. of the colored complex (as a weak rkvtnAyte) ure '00
It. oloat , taut ti of the vumpItx couiltil. -00
rhe ..W1, tv"IMI'l "Coust"the fatier It is to franfortil -of
twol M"411 IIKV4 of Ow 11"1 111111 lite ('044NI 41-11114%
funijbil.; thus, The slightly 11I.vot'g. L-411111kin., Roth fit .60
intitf-COMpIC11 COMW!... Aft IW't 10f t444"hilr(tY.
W. R. Ift,111,
=00
Al
pal
CLAIIWK -AM
lawaso "it Q.. cat
U 9 0 10 As - i . -
a i i - i -
09 W K it If
0 0 0 0 0 0 0 0 0 0 0 0 0 0
OT:
roe
roe
Vo 0
coo
!zoo
zoo
t4d, so 0.
s Bt I a I' *_-, F_ -__ it,
W, _L T-a _fw -0 a w .1 K No- _401 a :B -1 1 K9
0 0 0 0 6 0 0 0 a 0 q * a 0 0 a 0
W W W i, ~ , v CS - g ~ ~ - , ~
e , - - . , -
--v 4 * i rP
l
M
d
11 4 11, 0
V
Y
j 15 1, It is Im Q A,
11 A ~ , I
L
i
1A M go
M V it 0 40 41
#
A _
_1- a --A -_
__.
. _
_
_
.,
f. . -040
A j I T%P_ l!IJIM
R
INtect libation cif nkktA "Milth d6o6YWi*giiN NNV-
' -041
7
0. jbcvchruk
tim. A. K;
0~ -got
.111
,,u
11
b
k
1
sample it
In 110~crz live with a small quantity
of limil.
NO hoil to rrmo%T N oxid
I
l
00 -A
.
,t
jvu
cv
tale lcvj, laa,,Jl
.
k
1
es.
n f
le tartrate varlAhMl
r
90 I.Ix" I;e,, jjjt,.lf"_ ~Iih tt;- kin. 4 Ni hy mran, -4
unk,t fir mnlik-14AY u%idavd.
ll I: ci the ruethod. add to the soln. !~l-5 nd. uf thiq R.. helle.
%It (ir tartaric acid and winic N11
011 untill Nil
ud's t.
,
a
Is flitter curnlAurd In "npir& limin As a testrale tx a .
,
(Altallied. Ill tile flut"Ir vartatuics. slid !i-41 C. tj xml,
flunride. 71- dri. N1 in .1ml. di_ul%~ tl.,'~JJJ g. td thr let (IM' %(VC1 "n.. orUtIM617 *till NIJ4011 jimly *till
'
til %'If
i
i
W
z
m
nx un
.
or apprati.
rhe ppt. i,
"kill, or ItgIllil. DuIll. by the fluoride Intlil-I
).Irk[, forlicr r"llt, flnul th- obuin'NI by tit, lartf.tr
llwthcxl
fil the
win-urr 4 cu ill,
o
t
t
1
t N
.
c
n
en
a
~
I ran
1
'
'
d
b
2
i
d
l
h
0 0 rt
.
var
litl[InS C
t
e IlWtll4XI. (1) It
y
-
0.5 c. of thr alkly fit JICI
caidixc with IISO
1xvil
.111,
,
',
.
with coki water to 4`01-711 till
&,fit I A g
of Zu or Al W%
goo .,
.
ings, shake. for W-15 min. (lictict nithout hcati~llj;), lilt'!
waill with dil. IICI (1: IOU),;uld 3-5 in]. of 11NO, in 0.5 -
1.11 till. (i I frO... bod until all Fv i~ oxidized and X ~,itulcs 17 r
are Mumvd, add 3-5 g. of tartaric acid and N1144M until
Q') Diss(Ave tile alloy samp3e ill IICI. add.5 K. 44 Nat-.
nrut aitte with N1140H until Nill "1w al-JR-ar" "cullf,t
-
l'
ct,hwize the I ft,ruied with
ill tile pr,~n-d
h(h
'
-- Igoe
mild a stuall vicr%% iA N
(h
and 5 fig. tif AcONa 4a -iviv.
N11,011, anti litrate a, umial I Cu call Isv drid. ~itnultanv- 13*0
Imlitly Istri-snim: ill lilt- plLwIlcr 14 F- tile Fv vitl,l~ In,
'Altl 1116:14.1111,
1141111
ties
be*
IVALLUMOCAL
A
I
9-z
D.
st
L
7 woo
114ttoall ,
Iflabo 41v owl aft 41, _ ___ !
L
u AT to IS
it ; , r.
, 9
U0 n .6a
i
1 1 0
000004 * 0 0 0 6 9 0 0 0 0 0
to Goo 00
0 q goo 0 0 0 0 a a
a A_ I. A I I 1 4 q A, L_ V
"'r-4 A
V: A
rk
A i
compirl corupwrids in &VAlyticid chfulistry 16.
State I'tuv_ Kirv).
00 1J, PWAIM)i A rtvio, .4 mi, knw~ a coo
action, tv.1111ing it) the hwillathm W (willph % -ful.k. 11-1 Coe
tit analytical chrunstry. The IsI,,r dw twing.
eew t1i'll coo
I'liqlcrtir,' Chang- in the o'Lidatit"l-mloctiml
00 Cll~ttlg%'S Ill the -Ally. lltltitlg eiIIIIj)l(-% cog
in cAllas during the formation of "ImpIrl litl
fctt lict's. 11'. R. fit-ill)
4100
zoo
kill ILA MtIAkktr(.KAL Liftailvot (LAIllpfcAfmif
It
'No.,
Oki vjkjll~t .1,401 'Im ONV is~_
U it AV PO it AA- 1w -0 All:
~; " it tv it a stir Its Itern (tic No 11 f :14
lo 0 0 :1* 0 6 0 0 0 0 0 if 0 0 0 0 111 0 0 0 0 0 0 0 0 0 a o 0 o
00 go* 0 000000 0 0 (111 9 0 0 0 0 a 0 0 0 0 0 0 0 0 006 0 0 ei
40*00 ooooooo;;;Q;;,
4 1 1 1 1 10 11 UUMUM Ills It
It I a a it
4,
06 if A.C.
!=_- k
Pit KQ11 Afto
Al
;a ;it ~;*;v ;a ;U oil id,
p
_I_ W_A_
A ('09
'" _Lq~__ -00
00
w emosm. A. K. stahko.- J. Gere.
6
es n. R-Me ex-
q k
C4,.. (U.. _q.k.) 13, 743 17(1145)~Mt
7
.
l
Wi
t
d
j
J
id
l
(R)
ff
h
06 an
n ac
so
u,
a
e
ows t
uLt
_
. s
cy
1
0*4 \Fel
ferric tons form the vialet cainjilex (C411
00 cot
6z The &,%ocn con%t KI [it 4 X 10-11 and the binding
'is about equal to that of R to 211.
energlp'of R'to PC
Addn. cJ n1mr Fe W the "Y'nPlPx ha* no ef"'. '"'t '11-
0001 j_rm.4vm the mint. of R (vitiay by raWug the 0 0 Lvums
-
00.3 11.
forlostion of the red mriplex FrMT-. 'Kt - 3.5 X 10
Atabout 111O.Ayellowcoluplex'FeR,--- islotmed. KI
ffer., which do not
d h
fi
v
u
n
e, It 14 (11MCM11 to
1.1 2 x l
4 temet -with Fe. but salicylic add-milcylafe bufferg %iprk
00 fairly well. Theoretical calcm-1. of the lfi%-". consts.
i
i
agree rairly well with the rxptl. vahms. A nomm-Tain
4 the rAri0t1~v-'Plv%- Ill a m1l".
it,
h
g .
rso
lor detr. t
V
1
tj
I
w
w,
i LA A
b U S AV ID AS
Is It Is it
1144,
i;4 -m
4, 1 JL rw 0
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4
w vt
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, a
A 4 of
4
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!!Lee
I-so
Tke feernation of complexes of merals -ith %rak Acid*
00 V:
Eq ilibria in Sollutions of ferric xmlic~latr lerric Scetat
v
'
10 -,, OV,
k. IlAhko. J. Che.. 1S.7.
A.
l
:
0 ,
fli"M:-Vefriu~ i'm $I'll . ..... 14'. il
o
%
4
.
acetate ion, Imt ferric ilm foram Oil, comph,% I vit
At 01 3.0 -3.7 addia. of ~Llivvjalt` iOll (It ~ W I Ill' All t At V
der oultit. Frmll- 1.~. mi-, ,( ill,, vi,,I,t
",
I
-
(,A
l
4 1
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.
l,
,v I
1:1-H,, but (millatioll i~ lighttv (OM-1-
"
coo
l ill ill, pte~, it-,
Whell the 1.11 of the lwff,-r i, illelva,tA w,
th
W coo
~
-k
R, the OAr Imik ill Wild ww", I-,.
effect k overvolur toy the bitillcr I'll, Alld I'A V, It, I"Im..
00 The equil. cono. for the rcoaction FvRj- +
2
O
.2 X IW
)
F1e(OAcl,* 4- 2k-- is fAiriy e,,n-l. ill-3-
Atioll.S.0an,15.41. The dissocrt. mn,t. of the F-lwyji,
ovillple% ew"ll. ftstol thi4 Value fAirly ~01 ill, Ill.-
00
vAllit., vvtled. ltv ollw( 111villiul, H. M. 1
WALL L)rGX1L UTINAI tAt
-77-
141CC)
lose
.11.1, Cool a., J,
sire
tt
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boo
wool
U lot Aw oo IS I - ; ; ; - , - .1 -, ~ -
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k,..
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hr
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w (Pht 11:01 ". 'I lit- Ow
t
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levlate .1011114". I
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-VAIrd In 'frovaltrA 141 %tifilm It I-
114.11 stAtOly III lit
(twitiallon 44 lite ti'lliplett Iml I'lle 06.11"
con.t. For Me salicylate Wit% I'mud It; 1.- 1.11 X Ili
tilt- dl-tl. (A it, V1.11'.1 F,- i'mill
w lit
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71- a -1
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1t
a study (if the ioull.ttiw
Ir
s
tvv
an
00 clim.itirfrd its a monottiolic avid, I he vAlue 2 X III - it,,, .00
obtainmi. U. InsUliflity constants of thic. cadmium, .00
and load didilmates. A. K. PAI-ka Anti A 'r. llhi1ipenL,,
p
Zkor. A*W. Kilivi. 21 M 11.1flill-.1. VhC i1m.114111%.
:,
00 ell mr. 1. kiiawd by K
'
WA.,
~ I
1 1
/
: 1
.11.
it it 1AVAIVIII Surtill. Ill.- C;~Ijm. 11
. ,
M
(1111111A)IIAIrs Was AIUIIIW by I "IcIll-I mithut'i by P, Wh
1III. ill thr.'e Jill hmmo I
(C.A. 22. 21M). 71w
go led (a lif W1. r ",tfllavling v.1112r. 1'.1 h
Z7
"
COATIsru"
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0-11
It -
< 111
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. f,w
,
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wctv Air nljz. 0A X 1
Z
an fur Hills, 2.2 X 10-2l. A ClUtIfLIFI-11 i% tlr.t%Vtl Ik -
d
I wt, 11 t1mve dithiwiltri, und t~.- twitntIlvidiur wimwitim,-,
And sulfitles. The sligy. pt(Auct u( the sulfides i, ,f Ov zoo
00 %ttO.- twdcr of magnitude u% (if the INIffl-l1-111filig fbilli-
1
., -
241jus Jilt I III frVetMiurticr. Tfw react I I N1 DYI 4- 111
00
1411, 1 211111 wA4 4,111,61411 I'll. 11411 14 lillitillit I I", 'Alivil
I**
00 11111 kmCCI'l
0 =OY Ow ivw-u- ill fi~ dilhiarmle aull dithis,litAir in fill- CO, soo
*wf Lli~r will be ppm%. tquij aull file "Hirst. .4 It's in III,
-
31-1.
aq. layff will be it[ the order ell magnitude IA 10
-u 4W. Thtv%. for the lituiting ;00
ca., Kor.t where S is thr.-Ay. pr-lurt. Till-
tlithil'"Llf- that frart with )Its "Its't .,Iifv Kwa... ~31-
Sull. F(K Zn A:',.r., tb.-r,,I,wv Zn
will bvIAJv.
Wk~c_autl it% dithironate will rcAct -ith 11,; 1- fiwm
uthille., Th~i,t w.%q vnafirmvit by ripr. M. 11~11
A
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Z
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Q-- Oivs,,inn mid
-4 3b)-dea-
A i 6w , I
nictlic'i., of anill),45 of tile WirdViorof variulls com.
pNx clivoi. cmiriis. in Win. ondur specific wrilitions. IliT
f1c tit, f-I-prqu-i-tiv, 6. Inacil Ito tile Lori Ott lictivil orviiIIII, ON.
vrmn-s fram lvljivli tire aquil. fartue if ci~tnhiad for .1 filvell
coilditioll.
7.
Babkoo A. X-
2113
THE REACMN or NICK" IDN wrrH IDAMEMICILy-
M THE PRESENCr OF OXIMUS0 AGIRM. _AX--
Wbkc6 Tra"lald fea. Zlr~
Az imal-killIM bal b", rzal. ttJ t!., ~C!- %1' .11
dimr:kjl9q=lmr 1. the pl-r- .' t &-"
that toolmy cxlkmrll~ art a gL-d -tterim for
co.paring the a ... tt;,ity d '-rt-j b) this
=a-$ tbxl fit, mr-tt-dy -f re.g-l
jor #Qwlk4 N) FS lerr""d 4hr*g;Qld tu -be rtv.=* of
clidjualt, The emposlikoft a thr carriple2 W-ae sladird by
p1tyalmdrinicil melhols al eulwthm ansiyals. It was IDUM
that vlon the extras .1 o.-Airl is filigN, the C.MW511100 of
the C.~Plem is NI: H,rt. - 1: 1 Weir. the ..- of ~Ldsml
Is 1-ge. the -11. 1. 1: 3. The !-1- od the mIrpl- 12
M~rusttazl. I! In eh~. that courney to TeVy.1'. "eve. 11,#
CO)MY103 Is airombinslice d NO with ustda-
2
*;?? ti? rr flat a 41 Q u u
A-A-2
0* *"Coins As* PROPIRIIII wofff
set
4d k"
**41 13.
8 (1 Own) ).-4Dn the bwo of tbc Is(
tke v"w of dw 2nd
41A
*0
d =
. tw 14
06". vwmu -14. Thewduafmag-
dbwm. OWN. w"
anding
with clall"
se P
nits& b cmkwmd
of ukFw4v facb0b. By use of the
"waWs dnvloped the stud of Fe compirses with
OWN& ead we. "is, the fornatice twmmll Fe
I.Momd, an %be hatA, d wit" m no.
S" VYIVftVAWW 14 it
W 4.1 wjwl"ophs we prew"IC41 Im coottaltatical of stability
** of Stop it at vwkws I'll velp", offir's d C%,Tm
IlIfth--
WON "w"
916w vab" wm nmdmwl f1wil-ttally Ity turalle III
1
No , 11w CAIM1*4 I* own ule w 1,11 4 11,
"l
VIAM WhOl
it I
p
d
r
re*
s
iVI
l Awe blaf*t
.
I pd
lk .
cb!ws to "d at pit K-b.
f See
o we*
Cleo
goo
~
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X 9 1 a a
e 90
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1
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to v 14 is 16 11 a I) At a m a is 71 it )q I )i J, M 14 U is U Is1 16 P & 11 4) 41 M di n 0
10
go - 00
.00
Complex compounds of thir ferric Ion with some phellold
and h~dC Kier Stale Univ. ~. J.
acIds..-JI.,~ ,,,b1
( S _ _
Gen. IT k f61 W1946) fin Rim~ian);
. Zi4
cf. C.A. 40, W.91- In ciDinplex cotnjid~. of Fe Rith
uslieviie wid. PhOll. Me Wicirlme. and pyrocairchol
t-, the rnrrcr of the chem. bonding of ifir er,6rdinatiog aninrs*
%ith Ve cation Is not motre than the hond eni-rKy of cor-
00 rs%lwindina anionq with It Ion. Froin the valuts of sli-p-
%i%e dlww". It I% l"sible to emalAW1 the vouilection be.
00 13 lw"n the distribution of Fe among the variou% i-oniplex
I I
orin nit the stability of the complexes. Slwctrographic
data of thew cnintilexes are reviewed. G. N(. K.
V.*q
roe
go coo
go
COO
coo
so
-.1,
A 1 1, L A *t?&LLUVGKAL LIT(ItAlitAf CLASWICA710M
3z., t 1- 1. ------ we 0
.31,ji F3Wt-
A Un It *[Klan I ; X4 All I1 1) %a a N o I is of 2 jj a 2 0
oT u u Iv -0 IsIg CP rw It C& 4 1 Ul I i 1A
1J. N i
.1p,11 -.4.4P"R.
v W if U It As it U 9~
A so, ~ -,
I ills, lthiL: M AA CL IV, U Is A
uc)mjt4jr k.,11kpirl" A 1, lul-W. J I-ek.
is id I Ism. I,,,g tit-
SVN al '.1-1 twi. .
Ve , ,
1,19 /.,1 %-11AA11 ... I m mill I.A.11 -1111.114(1-1
or 1
'I', d "lit, 1,-K ISIL'N I fmill :4 fit -4 1, Imm
m%.. I"fAld I'll "Is ..11"i Im its, 3 s.,.Wr I loth-;
I'll 1110. M "Imolml. !F("''!
vi,till, i-4v mt I ...... I lit Ili I ~~ Its
vI 11111.1coll I, I
m ~-k, \ I,oo t I%-% is" stlit
1.1.0. the -m-l ...... -,It... t I,." Its , ."'.I III . 11) 1, Ill, ill's
1, -1 c.,11-10"111 "till 11tr Ind- I'll 11ith
,I I'm it
1, "1"011,11.1o Os~ 'Ntlittl ..... . kit N . Ill 1, 1 lit, tit if., -..I. I lit. .1- ties
-.11 1 ITITI, o, I... ..... I hv I,,% I hill ii vmli %4ft.fJ"j,K it 1 .1%. d'i.1
'll """, ' I" 11;"N' \i-1 1-1, Is, 11 It 1 3%, -111.g it. Ille I0,J)
00
f "I'll 1"LIN 1. It-oll fill, vilills'litill
00 a milml, vkllil,. tit Ih, list% .m, It,. II.,l 111.
Athr Will'i !h. v 0 0
at', ti,tV.
10 , 1, -,-It SI,A) '111.1 7 F. ilk' \ I I in, ~ lit
00 11-1,,I m 'It, 1 Kl% -ft As mtf, .( I Is. v;O 0
is so, I It, liov I 1., .1,1,11.
- -I-,
00 1. (14 f F' . . ..... t', f~'t
Is, .1, till . . .....
..it, at . ......
14, 1"", 0
t,.IAI ;I,
...... I loss. 11"', .4 i moo
m
~~O .4 J.,
!100
1 M
it, 1 .4 t I .
I,W. I St 1. 4'.
m loll, st*.N j,"t" J.1" 0- ),,,1 11,40 .., I i 00
g I'll .1 :11,111 lilt "m". l1..41 11 1.% A .1141.,t M.4111141111
41'. 1 111 1 1 -%~- ..I Ill.. I'm. Is '1.., 1,,4,1 it. stsiti Logo
-msi IF Im- I's
is 1~' *,1, 1, -A.I
If,, l""llikil 11 i-OWN 11 At Ots
...... .. I _w loll
b u U AV ii,
so IV P I'll t 4, 21 411 W IsIr ff a it door 1410 It I i Not 40
0 00 0 gel** 0 0 0 0 * 0 0 e go 0 * 0 a 0 0 40 & 0 0 0 0 0 * 0 0 0 0 0 0 0 0 0 lllll
014400000000000000 0000 0-111I.-C t-9 0-40-#10 0 0 0 0 0 0 0 0 0 0 0 0 0 6
: -.- , I I - .
"Ferric-Rhodanide Complexes," Zhur. Obslich. Khim., 16, No. 1-0, 1946. 11, r. Inst. Chemistry,
Acad. Sci. USSR, -1945--
,-,An,,C,, A. K.
----M
"Complex Ferric Sulfocynures in Solution," Dok. AN, 52, No. 1, 1946. Inst. Chem. Acad. Sci.
1945--
e A
0 ,
' V x V
AA so- ze W a
Octlislis A"O '400fatiat WOCS
0
18.114. The I'm
at
I in A
=rIblasia:
VIM Park It.
m
C
d
-
ft
an he.
a
d Ditki
t
A
K
l
00 scria
es.
.
oa
.
A. T. Pilipenko, Journal a/
"V
R
R
00 -t
.
chensfitry (U.SS.R.I. V. 2.
.9
71. p. 33-42. oln Russian.)
as Results of R study of tile com;x)kt-
d
b
ove compoun
tion of tile a
s In CO.
solution. equilibria between the dithl-
tonates and the metal salta at differ.
ent pH and concentration values, and
h
eq "llbria between tile dit
izonlites
is'i'd H.9. RchitionshipA between tile
dithironates. nulphides,and the anitno-
intates of tile respective n1plaill,
A S 0 "--1 at, LU-46-IC A-L -L--tT-I-g A-T U; 9- -C-L -a$W-K- -ATI a-1-9
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- V.S.
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j0 WOMMI "I WHMI *AOIW No -pq ~.t - -sit p
I Umfl
I-UM-qvnA Aq ifa jo ja"=mrj=j mp -1%3
-1-1 -1 -
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.fmm- N
in 1-t3 10 *"" 'pop- "30103 a "is
ti 1*11M tiltft IPIW (td) ps"-Id paMw Apsuapil
-"VZ
y Tmr
*V '(fi4ics ptagatilmoo 0?glint. Ip 'be
fal4k
it
wee
IF
1 47- 1 r w v 9 v a
for! cp to or a It a of Cal A " Ii I
04 0 8600 a h 4 11
14 4
dh a a a Am, A
--V-v V v a U
A 11111.1u, lip.
A ;~.s;ljjw L A r. _rA
ARM)
jjl
00
0 4
owe -1 the hydrogen ion concesitmilivia Do Claimed
00
A. K. ItAblita-ZaniJill-ijim lAb. 11, AUM
(II&.1nhe pit to appristrarKV of mint.
inirnw cislite rtis Iw "W. from the stability cionst. of the
ces"Pt"s 'A 11w 't- a' title comp4ex-im"dog
949 MCM. (1) With -trOUg skills, IGWff Pit 21WAYS 14"ce's
conelr4rs fivasitimri. ca. ""t"" Fe-* and *%*"_- "'
00 lit --I I , Vtle Aj1j%Xt"ktIV VNIHMACT (ily-TVAtitlit 94
00 is , ,
1%4.4. Aft.1
1 .614*- It. .,+* .4 Ve M is. . A.116411V
00 U ; Ill 114.1. Slid I lie L" I odist.
so a ith M. not to litithirt Ill ctiewn.: with
c4her acids.
asi 11ICK), us 11%(h. %be coke of both and
inerr
Aters with decirrising pit. and then minains
roast. lwlwrm pit 2 and O.h. (2) Analoormis calms. for
Willi ani-J. ,I "vok ;tvidt. v%viltIllififtl Iter "it.
it. 1.11 "1 .111411 a .141"1 fl#('IkK% I he metal tilts IS IkMUjjj ill I jw-1111,11 %, till 4n ctu~,
of OM Mal. It". atr~ 411 the Fe Ittemit is tKKjjjd ill
Thelinthinzaridiiyat
Which the colwrli vissoplet; i. fill t.1111r. is the higher thir
ram" set I lie risillplex 4ortivills WA Ari'l. I h~
diewwn. conitt.. and the highev the isiAlislity
r
CAM%t. of the complex. Mus. witis & :14al Ill-
Ia, over Fe * * *, tlw cotor birgisas to faile at 111 > I X
10-4. with a ID-fold excess, only at I It *1 > 3 X It) -a.
IUC the permissible pit limit for the color of the Fe ' * *-
nitroistlicylitte complex is about the same as for the I Pe-
sall - complex. is due to the fact that. while the strencth
of the famw aciell is about 15 tittles gMter 111411 11LIt
44 11.101. file 11alillily tit (ha, I,wtlwf rsimpiris Is I.mi-f ill
41%41, l1a, "Ill,, 1 1110.1,14
is 1h. .1 il-illev
is( the i,omplril 1. Illitelooled ItY Me r t4iiii,irli I Ill, lall ' m.1
a"dussly. even in the lwrwmv of a 104t4d excess of I It-
Sol, the CDIM Of lCulail be" to Tassish at pit - 4.5.
ILA
i against pit 2 for I Fesall *. Since the (omnSt-yellow I
Mpleit of ll**** with chroinistropic acid 6 morr ist.tile
than IIW Willi I'
ille
I- to 1.11 1 (lit l1w 111411 1.11 Odl,. 4 1111111
1 ts, .4 11W "Mill.tra .11.1 1.1.111 0
IN X, a IllnillIsIr loirow-ktion 0 1--ighet-coindmatril
CEF-Ics with a diffffent Mile, and a chAnce of the Mar
of the coardinAting treak acid owing to it% indicator prtqwt.'
ties. N~ Th4wi
too
0
0
G 0
00
too
oo
a !21, ~~l C"'wo'clowes,
soloso "Alt owe a" eel! 0
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_0 r- 1 9 1 13 11 12 13 w Is is 11 Is to
11 1 v is 5 x Vail Nil 1u
9 --L -A- K f _2 K-1 - 1-1-m~ 0 cc -w u4 c - I
C41erimekk dalwalsatims of Averise. A. 9. tkbk,,
(Kiev Staft UnIv.). Zmabloys Lol. 13, NO-7(1947). -
-
-
00 F cas be ddd. by the reaction P
+ Mit s:2 UP + R
1wevided UP is stable wW MR (or ankin K-) has a strong
colmalims. The ferric thincyansle method is characlet-
00 ieed by low statsility of the Iwo duoridt cAsmiAn and wftk
0
10 v"Ation. Conwqw"tty It 1114Y he (4
t
b
:
0
: rut 1% le" tult4
ir
h1javd IN studying compks equillbtis
for cohrimstrk dets. IU No of c*nWkx W Ti wilth 11#(~
'3 astwas the so& Met #Matsu i at fiami pki
M
U me C'Me
ion.
but " for isteems coisrat method has ad-
I
arm tbe falvic flAwyanste proced-ille but is
z=
l
the Th sawl Zr aliewrin methods. One ad-
of do T1 feectim is dot 90s-' and POrl hawr
'm
2
1
a Ti
I
#
b
=
on
ss -
, .
-1
w -, 1
A.
y
th" on b oatilikto, A16411H t4"njdp%r% tif Th and It
h
b
l
W
I&t
e ftguiteawnts as go sta
ity slid CAMaikitl
i
y t
better than cow reactions. However. many ions fulin
low-dissociatint complis. with Zr and Th. B. Z. 1C.
&%*.sLs -tvAuvrrKAL L1111MATIAt CLAISWICA11ON
w V011014 Nit U U Cl tl N "a a I I%
0 00 oie 0 0 0 0 0 IS 0 0 0 0 0 00 0
)4A Jill N"441 duioaEw
r L -I- b- I '4_0 -A. A-L_L~
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roe
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00
boo
C;.i ~'
gas
Tiff sw 5 a a 3 0 v
EA
9 0 0 0 0 0
4, 41 :1 w of 4 4' is r, 01 Q
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41" 1. pit -I i; I I?. A& I It'(71 I; SIN litt-1410 I Ili
lItit
with lovol, 0.1 Af NZI~141, )KIR.-Fed to a klinwil 1,11, inliat
110111011111111 IlIt'"ll,11 filh-IN V1011 file jilfill
1114.1111 It 1011. 111 Ai'll, IV Aloft V 1*111, VI 01 VII 1,01 lot.'
mplit"t 111, 1-11, 01"A- "fill 1 411.1 l-
oll 1.11 3 aml I'll , ql~ viiIII VI aml VII. "It
It %.I .. %ilh Ill 41.4 IV, "..
44- At 1-11 l1w I I., t
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t vrre;t 1,11 7 it to 00W, From Ow
-urvr%. the di-ts. "Hw% AmI .4 C11.1W Alld C11.
I
00 AW, - -. tr-l,,, A ric derivril by taskiog I he undille tit 1 he
f1witif (I'll 4M
00
ICII&III $111111 1,1111lod IN111* "lilt g
A,,,%: fill , p. I A, Ill 4.1 C_I. 411 111P)
lot.,
"two.. 4..,l A: - 41---o -#W -4
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I'% A. I.-C A, "m I., I'll .0, vAIm I
littill K-Wl*~ ejjt-t;;eIIC eIIAjALIVli%[k- l'hC li*t" jWFItlit
-tv,troctuma Ow -419IN11 - -1 cute" ill t1l"111 1.1 I'll-
-ott'l. - tile 41i'trithi.
[,It total I I I, %Ill - I . 11.01 tit 1.11 31.
twis Ito Of, t'llal C16 1. 1.."% cit I " and 01.1W,
Ill. the
log t Ili- I'so It". - I
VIA, A.-Imr, Ildlet 46.11, at
.1, ve. ,I lag I %:o I 'I fit Ivim, ill - I"K J."41 I
Al"VAI Will I'll Al ('If [it-ill 0 ill At 1.1
4tjAm, IW111141 loilli-All.91 ..I tile va"Ilplei, I'mom-
J!hC 149111,
Ala.114 WALL~96KAL LiTtIlAlkil CLAS% IFKAI MR
u IS AV
to 011 IS a IS 9 PC If u It 111
I Sir
0 910
0 0 0
0 0 0 41 0 e 0 0 0 0 0 0 0~0
0 0 0 0 41 0 0 0 0 0 0 * 0 *-
nab MPIIA~Jkv 16,11 'it it 1.. 10 $ogf it 4 43 twtire
I., AA Of CC W (I
N.4i I It I I ..... ..1 $1. tit AmAlmof
Lij. ',d, AI -Ioa . A, II-M IIY
2124); IL. C..I. 41, ~kWiiej ItImn the
w"01 lj~Nf fill 11.1 It Cut %11.1~ %lilt 3 (If 11 if till 411
X11"kil At lilt 1,11,41 1,1144 %.4 21 "p. fill Jill I~ N. 'Alth
tdl.l~ 1. V, . VII, '11". .4 11, 41 .1 01 , sai I 1 -60
t'411 % I-. Of 1111 M ., 1111. 11 1 V. V, V 1. V 11, At r 1. 11-11 1. 1.
.1, imm . IN't 114. "'.. J.. . 11. AI .0-11 0. ".1 -
I Ih, .4... . .4 A. A-1 A , .... oaw 1'. it.. .4
C.0.4 A-0 C,INJI, AILA14. I.It 6% 11w v%tarm,
C10,11, -. Ow C'.111INI.
fly Alkali at a1.411 I'l I 11. C-11pari-I of K. - It, zoo
tile -rrv,I."s-Ioax riped. lFe-ij-',;I I,lPr.W'l
Ili 11 1 ill,- 1111101 If..41rl ~1,1101flr 44 tile Fr-S'll
1~cjlplj-% .0"mot 1.1 -4111.11 Off, .4fl, W,quile, to 0.40
Soo
itt-i Vig~zvl --Ilti I-
141, .4 A.,
I..Il.t .4 Ill SOO
N 11-a
z;O 0
!age
see
pe
'7.
4 1 3. a 1W 0 A A -1 v IM
0 0! 0
0 010 0 0 a 0 0 0 0 0 0
00e9090 00 0 40000 0 Goo 8164-44,66 -44 9 0 0 fill 0 Wo 0 0 0 -07w-
I ) I
A I I JI t I 1 11 X 11 U if 14 If LO 11 Ll "AfhVnAiaAL17A W 11 A4 I a t1 1. P 4 C U
1
D
1
1
A
A
i 11 64 13're
. -
00 . I .-
- -
-
, L_A__# F
9 1 _j _ U.. Y
_A_. T
_
A
fl
f __ 1 0 00 9; W, U I 4t s
f
.
"
~
rx~
,
d
,
th
_
W-la-
VJt
TT
00
-
a
0
cum
iocyamis compeas. A, K.
114 U
J
GeR
Cken
S
8 R
OU-140917
) 17
(U .
rd t-
%
,
KA". of Mull (rading lit
t
ll 1-00
.
.
.
.
.
.
.
.
) al,814.
An"
joentel %RVV~ (up to 375 trip) on culd". a
1
'A (in R1104410--i[l) The rittitwitiou f - log h/ 1 of fulfils. (O.Olb V.11XI AN of NC$ - but thrfr still f- no stnmPtiOn
1
-00
:: C oil).] At Moo,-- wilt 0.1 NSUCA, in varying ploportions hand in the visOlle: this appears Duty at higher NCS- ;
;
1
0
at coast. total voll., in excess KNCS and IICI or 1188(]tii. contents and is fully developed at aboift 0.1 31 - The shift -
0
00 it ElX2SUF"I With A hIUC-gTT'Cn light filter and plotted agaittlit of ultraviolet absorption. without atiAmPtioll in the visible-
-41100
. I . the Mal. r4t io Mo' *jSn' *, &bows a nux. at 1: 1. 1 letter. is tvWatly due to - IMD(,N;cs)lll*.
00 a t. the oxidation state of Mo in the eakwd ~pkx is S. The grneral whenw of the transitions it Mo`* + mNCS- -60
1 (2) In lniltS- Of Mal' With NCS_ At COU%t. total VOI.. If " lmo(NCS).111-14 (Caiark~%) + (S - wWCS_ =2 _111111 6
frun"ured uuAlef thickamits of 0.05 to 0.2t) non.. with a Mo(NCS)s (ml). the transitions occurring at abOUt 0.045
fight filter transmitting in the region of W) top) h.Li a tuas. Atando.w.UNCS-. (4)Froultbetlatleolthecurveol
1 at a trial. rAtic; 1:5; bence the coutpitz is l6fo(%C.S)b. * against log I NCS- 1. at ronst. "intent Of MOM follows 415411111111
:
3
! The mat. if sharp in 0.4 31 soins.. leas shup in 0.2 M
if
d 9L
t l
I Jf
l
l
f
l that in Mo (colorlevi) 4- aNC.S- -, Mof VCS). (culored).
an
s
it
.
; tota
* a
lio
a
ls with incteasing diln., the corit. a - 1j) to I.t; the diwwn. coast. K - I Mal -
00,31 Indlicatins increasing di"orn. of The Complex. (3) The
0.001. hence. ow half Of the
coo
00 a Shape of tile r (-Utve% at NCS- concul. below the 1:5 ratio total Mo exist% in the fam of the coinirril Complex at a
l -at the inax. (iiinws convex to the atis of stra-luaii) Inill. al, NCS- of alillut 004 Af. lownraw of INCS-1
callen
00 ~l rates fornfation at a colurk-41 ronspil. lrlw(Ttl Mo(NO)i
' . coo
00 ul Mot
. It% twilin. apiwars front the Iflot a( r against
ali
' I
% abovt 0.".4 U rewll% in a weaktidull Of the color, evi-
00
j
t w system
to
- Mu(NCS)A: the deviiii"t of the me- dently owing to Imitation 14 the lem.irtitnwly rolored 0
0 tUAI 0 ftOfn thAt cAW- by situille additivity. corresponding
N. Timm
r4:411110
0 a the degree of decolarizatimi. is MAX. at a poi"t Close to
C
.
to The compn. lMo(NCS)l4* or jMo(%CS)2l8l. Tbm
complexes are foruml at km NCS-- the colored Mo- 0
(NCS)s exists only in the presence of suffilicint excess of
-
! NCS
. This is bum oat V)flloits of caffalia" thecown.
",:J CS - 0 PwAft throvillb a insist.
l,
I-C eare--fa Ma
giva rlse to Incre4wrill fannation of a
comi4ex. Further tIVNICOVe is t"vrd from r
zt! curm In tht Uhmiriolirt: the alf"wilm of a 0JKj5 M
A*
lie.
It'
~
J
U V& AV
-0 it';
Pat) Ila 14 911
Of
6
I'd 0 04 1 A) a 31 0
n I to
KX
q
0000 010 0 0000000 411100 * 0 0 0
~16*9
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0-10 0
0
0 411401
0 eie 0 0 0 0 0 0 0 0 4 * 0 0 0 0 0 0 0 0'
0 *10 * 0 0 0 0 0 0 0 0 0 0 * 0 0 0 0 0 0
!*0 gee** 0 0 0
0 14611.- ~4~ 0 ~" i -
0. T 0. 10 UP it f Al It 11 1: a 41 U is At Ott'ro
t IF C a I
F__A A_jL_L_
.1113. FO
P341lieFW1 (1), but the finkagm air not its stwill; as
thw. foulld %vith Co sin't I will be stable allty itt 'Lilt pres-
lisreadllybolAnCliCls..
springly in W4 JIM C-.114Ch. 71- ell Complex, (Ifill.
slinilar complexes- of KI and Co Otowv the -Lalne hJuMor.
Coolpf" formatien In all these_oh,s. b. Oxi-vc(l,
us the trttal coulplexiii nip all eleeply colored. Siiifmali-
cylle Beld also gives tt-mry- coinplexes, a,;- shown by the!
dee colatutions prodila-d. 1111s; 6 true for ultm~;&Ikvlic';
uthl".1so..And the collqAleles cj the WITT Art.Al"i histy .
in wAtcr. , In all thtmi owupiciies (xU.6 diust coulz arniz:
zalicylie aidd) it k nc~er plimitil
QDL
kmothtr, ~ i.e. an aniolit bound In the ewdim
stays ked. Under conditims whern the 1card'
sphere can be filled uith ankal, the tomllition 61
qpplexes can w foulrer Oneur. lVerner JaCCIbson
BABKO, A. K., PILIPaIKO, A. T., REVILEE;'I'D BY KuZNETS-01, V. 1.
Chemistry, Analytic
Calorimetric analysis., Zhur. anal. khim-, 7, No. 1, 1952.
9. Monthly List of Russian Accessions, Library of Congress, 1951. Unclassified.
2
V.-,SR. J0$2. 7. 3-13).
ism n 0 1& I%vly milAil
ClIftf, 4LR tIMI WIN ~b`hv it. 11 Iceant lillusilly bl,
rllggunat~j In I itemakin twmn - td
phaw and di'm4val a t. %.I ullipw litilw(Anco, The u- .,I the
pt&vAA ,I phykv- u%KAL aitalysis AU a allutioll, fow"i-Itto"
.1 fur studyinS wAuWbtL:h4vW* In iwmevA-*
kjmak)u , rtu" 1. -of 4-.Kl". It ll-lumn
Illorby MAI pri. "a mfirillt] 1. I.mr cjmsr&; (1) Ahmonce W
c-X%4c% fiximmkim, chmactclimd by a mAk. Imalutoill). 41 the
" IVAIVI" jKlInt ('the - WW - q1w fut ust in chomical analysis).
I 't"Ing udnplell iUftUatHXI With It lYpt. nGt C0431rdillStlVely
saturalvd, HSI,, chwacterind by a mill. at the rquivakzce
"nt juo rjLcrlq cg cuoulkan 4unfil. J3) cianplex formatim where the
lopt. I% a ovoctituatively s4turait-4 cumj~md. eg. No.AIFG.
chaffowtertuld by a tvdMCtklkl in ~Aabdity with excess, W vommon
cAtknu. atkil 14) weak %olupli,x Immatim tk-t%%vn the um. A Oll,
Pill lOw nuijwity u( teal pilt. confi,tim it, tills type), ( I , im,
ga by X), cliarachrriird tp), a cur%v ob,minoc . max. whem I h,,.rr
is no ezmo C.Asa>C.IIg. Thi'sisfurth"com I.-%I by
the react kon CuoC, + Ma, CsAxs, + 2 Cu 4. which Lakes
14"Ce vimuillittiv an 2 Irm, slaskillif "M Cusco with a ~,In.
1 #4 Mx: %h, Cu * 1. fulthvt "W"I to Itu , I %but
'A,gf' L surfuttk, A,, -11w ~pt,, aligissallY tvd-
-own (Ctcus). Ismoturs white (CAgm - ran M." ex.
ellauju bcto%ren $Witt C6AS, nod a San. of 04'. Joel not
take jilacv. (Is (frAttucitt at molid CiCut Oft O-W Y
"n. " IISCIv. the p L bertmon sthile W,118), awl -IN-
tal Cal, Smilar y. volid VeAs, WOW wills a "It. of
Is. t... If
I
IIS(IN(N). also., 4 I'pt. conts. only list. -Aith all the Ag aulux
Iota solo. Treatontut of %olid Coll& %illa either Cu* or
Ag+pmIumnocisanstintheispit. Hythiedefirtitissnof
4, one shoid(I cxptct, at emit. 11141. Ift"JI'lCiffil -
comt., Im. cxccu Ag' slarmid dextu the s4y. at C*Asj
arvagly, and euvo of Calls in in. less strongly. Thi-
was confirtuc4 by cxpts. A *oIn. of KI AuNI(I d"t"Is.
CoAt, amordins to CoAg, (solhO + I- + 2 IIjO r-, 2 Asti
(isolit!) + Colts + 2 Off-, with the rQuil. const. K - ICr
1141101111.11-1, - 4 Y 111 -1, 11 Ith a I JV WAD. of KI,
~L
6ft"
USSR/ Chemistry - Vanadium Jul 52
"The Study of Colored Complexes of Vanadium With
Hydrogen Peroxide, " A. K. Babko, A - I . Volkova,
Inst of Gen and Inorg Chem, Acad Sci, Ukrainian
SSR
"Zhur Obshch Xhim" Vol 22, No 7, pp 1108-1116
States that a study of tae :optical properties
of solns showed that vanadium forms 2 colored
compds with hydrogen peroxide. Notes that in a
strongly acid medium, where [H--) is N,
an intensely colored ccmpd is formed with a
compn corresponding 0 cl:l. Tn o-n alk
to V:H-t:' 2
229T30
irreedium, a weakly colored peroxide compd is
formed with a compn corresponding to V:
1:2. Says that a comparison of the visible dis-
socn of the vanadium complex, formed in an acid
medium, with its great stability In relation to
acids, indicates that the vanadium dyed complex
with hydrogen peroxide, formed in an acid medium,
does not contain a bond like Me but represents
an addn- compd of the type ZVOX (Hp )~ (5-2x).
2
229T30
-BABKOj, A. K.
ola co p of vanadium said hZkM*c'
K. fkhk a .614"r. UOSMU111 ARM
Z
Chemical Abst. *ZAT M J. Urn, CAM. U.S.-Y,X, ZZ. 1149-MI952).--
Vol. 48 No. 6 Colored solvis. were prepd. by combtnint a loin. of 6 X 10-1
M NHMN and a eoln. of 8 X 10-OAI A. Color Intensi-
Mar. 25P 1954 ties were measured with the Pulfrich colorimeter at 485 inp.
Inorganio ChemistrY Vanadium forms with Hj% (1) In Wngly addle solu., sit
Intensely colored stable compd. In which the ratio V:HtCh -
1: 1. and (2) in basic soins. a lesi Intensely colored corapd.
i
h
h
V
i
O
vr
t
t
e rat
o
: Hr
t - 1: 2. Dissoco. const. of the tirst
Compd. Is IC .1 x 10-0.
it 1, te c PTlelea. A. K. Bubko and A. M,
v a t~~
)LrArl A jum'.
7he '04CI16A!, a
Ag q:f dcrtr-it
(N,j~,&An.~th (;.:- : , ''
~f K-X (0.01-IZ~ WCTc dcu~ sit -104. The Nuil. reactun
13 remed a3 ]Djf -IoSE - mlog-
1 = tbt s3apt of 'brIX-1 O.Dlttd aphst log
Pro
m wam dete. Rod 6e equil. conxt. X caled.
Lol IX-1 wcA obtAned fr c= the pntenthd of Ag-.Aa (Ior
CI -,xj Br bit not f~,r P, ' Sil -' 1,.m the p-rewial o! the
BI electrode, and IBLX(.---l -'I %ras LLSTM ed to be "jual to the
toi..I BI omcn. TIe foflo~ing ecrail. masts 2,nd the vor-
rv-pmding compl"rs are miriv K, - 1Di"j!X-j'!
~BLKQI -1 a" 3-8 X 10- for C1. 2 X 10-:1 for Br. and 3.1 )<
10-11 for 1; K~ - IBP'jjX-1'/1BiX-.j are rLS X 10~ for
Cl Intl 1.5 X 10-4 IuT llr~ K, - [Di"JIX i,
2 for C1. 1. Bencowiti
t/,4 85. DefermIn Milo Quivalent Jmm by ineaus 01
tetrabor , A ,.J, . Clem., U.S.S.R.,
ate. - M:125):- ~c paper of -Schigol et al.
1953, 8 [2), 1
(Brit. Absir. C, 1953, 157) is niTon . nit adverst,ly
r2ots ,etVT, i
criticised. The Lxpe Rdly arrangcd
and the results were Inadequate to give the cone
cluslons stntcd. G. S. SMITII