SCIENTIFIC ABSTRACT BABURKIN, N. - BABUSHKIN, A. I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000102920003-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 6, 2000
• Sequence Number: 3
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

BABITRUN, 1-1.
Lifesaving equipraenL of brw-t-1. I'll-A ~4 nz).121--35-36
D 1 b4. (MMA 1818)
1. Mci:skoy inspektor upravlicv,1-3a

13ABTJROV, A. , student; GLAMOVA, N. , studentka; GUTNOV, A. , student;
ZVEDIN, A., student; LEZRAVA, I., student: SADOVSKIT, S.,
student-, SUKHOOVA, Te., studentka; KHARIMNOTA, Z., studentka
From the diploma project to the map of Siberia. Tekh.mol. 28
no.7:6-7 160. (MIRA 13:8)
i~ "' - '. '...
1. Koskovskiy arkhitekturnyy insfi
(Cities and towns--Planning)

BABIMOV, I. -- -
1:,, ,-
Trainee courses are a big and important work. Each. transp. 19
no.10:57 0 160. (MIRA 13: n)
1. Starshiy inzhener otdela kadrov Severo-Zapadnogo rechnogD parokhodstva.
(Inland navigation--Study and teaching)

81J~MHIX, S#S.i GREBENYUK., A.A.; BABUROV, V.I.; POB&ZHIWV, N.F.; ROMOV, V.t.;
. MRAMENROV, V.G.
Development and introduction of the AK'A-1-TPI double core drill.
Razved4okh. nedr 29 no I ~'a 1.63i (MIRA 16:2)
-1:57-59 0
1. Tomskiy politekhnicheskiy institute
(Core drilling-Equipment and supplies)

GORBUNOV, V.F.; BABUROV, V.I.; OPARIN, Yu.A.; REDUTINSKIY, L.S.
Raising the efficienc7 of fettling operations. Lit. proizv. no.9:
13-15 S '64. (MIRA 18:10)

GORBUNOV, V.P., kand. tekhn. nauk)- BABUROV, V.I.
Evaluating the vibration of chopping and riveting, hammers.
Mashinostroitell no.242-43 F 165. (MIRA 180)

G kai)ci. n~I-.::;
I Iz h
n testinl,. of the e.('F(,.ct ot, thle cla:~-Zic properties of
the viaterial being drilind rn the inte-niII'l 1`1%,, ;eS fl-ICi pjr~j-
1
me,L,.:).rs Of a manual pneL,,.-,iat-'c hammer. 1"V. v
Ts. itcheb. -,av.; gor,
-hur. S'. i
I- TOMISI:iY pol-itekhmicherki,l, 14.11sti,.11t. kafedro-
gorriyhh -,iashin i ruiniclinof7o tran-sporta.

t 24549-66
ACC Nh: Ap6oo6315 M SOURCE CODE.- UR/0413/66/000/002/OC)34/0035
AUTHOR.: Baburov V* Yea 111411
ORC none
TITLr,: A device for the internal cooling of tubes. Class 18., No. 177916
SUMCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki', no. 2. 1966, 3h-
35
TOPIC TAGS: cooling, internal flow, pipe, cryogenic device
ABSTRACT: Thia Author Certificate presents a device for the internal cooling of
tubes. The device includes a circular nozzle which is located on the ring of the
support (see Fig. 1)9 It-provides uniform cooling of the inner surface of tubes
Fig. 1. 1 - support (spindle),
2 - flange; 3 - conical plug;
4 - moving disk.
C ard 1/2 UDCt 621-784.8-462-i

SVETLICBNYY, V.I.., red.; BABUROV, V.V., red.; DESYATKOV, G.V., red.;
KRA ILINIKOV, F.A.,'red.; K7=YAVTSNV, A.O., red.; SVMICHM,
B.Te., red.; MIRNOV. N.S.. red.: SMARMY, V.A., red.;
MZM, A.5j. red.izd-va; GILMNSON. P.G...tekhn.re-4.
[Regulations and norms for city planning and construction (69
41-38)] Pravila i norz7 planirovki i sastroiki gorodov. SK 41-58.
Isdanis ofitsiallnoo. Koskya, Gos.izd-vo lit-ry po strolt..
arkhit. i stroit.materialam, 1939. 178 P. (MIRA 12:7)
1. Russia (1'923- U.S.S.R.) Gosudarstvenn" komitet po delas
stroitel'stva.
(City planning)

BABUROV 11 V.
Our new obJgations. Av-t. dor. 2/+ no. 1:1-j ja 161.
1 (MIM 14:2)
1e Rukovoditell brigady komministichaskogo truda DSR-1
Moskovskogo avlaniya stroitelletva.
T (Road construction)

TOSTRIKOVA, A.M.; SaHAROVA, V.V.~ Prinimali uchastiye: FIWEO, F.Te.;
YWIMOVA. N.M.; BABUILSKATA, Z.T.; POZDNTAKOVA, K.I.; SHCHEGLOTA,
K.D.; KUWOYA",*-Y-.T,.;~-IFOD"TACHIKH, P.G.. red.; STRONGIN, T.L..
red.; PTATAKOVA, N1, tekhn.red.
(Public health in the U.S.S.R.; compendium of statistical Zdravo-
okhranenie v SSSR; statisticheskii abornik. Moskva. Gosatatizdat
TsSU &SQ, 1960. 271 p. (MIRA 13:8)
1. Russia (1923- U.S.S.R.) TSentrallnoye statisticheskoye upravle-
niye.2. Otdel statistiki naseleniya i zdravookhranoniya Tsentrallnogo
statisticheskogo upravleniya SSSR (for all except Strongin, Pyatakova).
). Chlen Kollegii TSentrallno-wo statiaticheskogo upravleniya SM (for
Pod"yachikh).
(PUBLIC HKALTH-STATISTICS)

R.
I J- L, 2.6'. (-~*~;j;il
i'larining and s'atistics in reg'ments and ba'tallons. .~).
1!ol., 8, no. 6, J~lne 1954, Beograd, Yugosbivia)
SIO: flon-Uhly list of European Accessiviis, LC, V-jl. ~, no. 1
Jan, 1"55,

PAPURSKT, R.
Combat firing by rifle units.
P. 18 (N'ojni Caasnik. Vol. 10, no. 8, Aug. 1956. Beor~rad, Yugoslavial
Monthly Index of E;~st European Accessions (EFAI) LC. Vol. 7, no. 2,
February 1958

RABU,';, M.
Directions on roal construction. P. 306.
(RINTSTA TRANISPOitTURILOt. RUMANIA. Vol. 3, no. 8, Aug. 1956.)
SO: Monthly List of East European Accessions (EaL) LC, Vol. 6, no. 7, July 1957. Uncl.

NRt AP6021:179
SOURCE CODE: RU/0026/
AUTHOR: -Diosi, P.; Nevinglovschi,_Olimpia Babusceab-12avosin, Livia
ORG: none
TITLE: Comparative study concerning the cytopathic effect induced by cytomegalic and
herpetic viruses An human embryo cell cultur s
SOURCE: Studii si cercetari de inframicrobiologie, ve 16, no- 5, 19651 409-413
TOPIC TAGS: virus, man, morphology, cytology, diagnostic medicine
ABSTRACT: The authors report that the morphologic chages caused by human
cytomegalic virus and by herpetic viruses in human embryo cell cultures in liquid
media show distinctive characteristics which permit differentiation of their
cytopathic effect. The changes also permit an early tentative diagnosie. Origo
art& has: 4 figures and 1 table. [JFHS)
SUB CODE: 06 / SUBM DATE: none / ORIG REF: 002 / OTH REF: 018
MC_

BABUSEK, F.; TICHY, V.
Humidity control in the insulation of transfor7ner wirings. P. 530.
(Elektrotechnicky Obzor, Vol. 45, no. 10, October 1956. Praha, Czechoslovakia)
SO: Monthly List of East European Accessions. (EEAL) LC. Vol. 6, No. 6,
June 1957. Uncl.

BARS, 11.
BABUS, Y. Pennanent control of quality of road work in the course of the
technological process. p. h60.
Vol- 3, no. 12, Dec. 1256
REVISTA THANSPORTURILOP.
TECHNOLOGY
RUYANIA
So: East European Accession, Vol. 6, No. 5, May 1,057

: --l. -I,- I -;-.- I-- .
"Dynamics of iievelopment of Grain Aicro~lora -~.-hlcch have
IHI.-miated in an ~acpcrinental Grain Field"' 3i'g. i
t
San., Vo. 5, 1949, Dept, Nlutritive 'Hy-iene, ..utrition
Inst., Acad. Med. Sci. USISR, e4F&~ .

BABUSENKO, A.M.
Studying the serological properties of Proteum and its relation
to the etiology of food taxinfectious. Vop.pit. 14 no.6:26-29
N-D 155. (MLRA 9:1)
1. Is mikrobiologichookoy laberatorii (zav.--prof. Y.N.Azbelev)
otdela pishchevoy gigiyany Institute, Pitaniya VIN SSSR. Moskva.
(FOOD POIShI11G, bacteriology.
Protaus. serol.aspects in determ.)
(PROTWS INFZtIONS,
food poin.,serol. aspects in determ.)

BABUSENKO, A.M.; VESELOV, A.Ya.
Antimicrobic characteristics of the essential oils of some plants.
Trudy Inst. mikrobiol. i virus. AN Kazakh, SSI 5:26-31 161.
(AURA 15-4)
(Essences and essential oils) (Materia medica, Vegetable)

, ~, 1) - --, , % / , 11
13 ~, 6 k_~ -) r- ty,NL ~, f -I - , I ,
USSR/Pharmacology. Pharmacognosy. Toxicology - Medicinal Plants. T-5
Abs Jour : Referat Zhur -,Biolog:Lya, No 16, 1957, 71738
Author : Babusenko, A.M., Yurchenko, M.A., Popenko, A.K.
Inst
Title Phytocidal Activity of Some Wild Garlics.
Orig Pub Uch. zap. kazakhsk. un-ta, 1956, 21, 24-30
Abstract The phytocidal activity of 6 species of Allium, (A.
longicuspis Rgl., A. obligLm L., A. caesium Shrenk., A.
decepiens Fish.; A. sativtzm L. and A. porrum L.) was
studied. The activity was established by Prof. B.F.
Tokin's method by "steaming" for one hour of a freshly
planted culture of microorganisms in a Petri dish. It
was shown that the volatile fractions and the juice of
all tested species of allia posess bacteriocidal pro-
perties towards gram-positive and gram-negative microor-
ganisms. The most powerful phytocides appear to be A.
longicuspis and A. obligum. The maximal activity of the
Card V2 - 6o -

.USSR/Eharmacology. Pharmacognosy. Toxicology - Medicinal PLants. T-5
Abs Jour : Referat Zhur - Biologiya, No 16, 1957, 71738
allia is shown up to the moment of the plant's
quiescence. During the quiescent period up to
the growth period the garlic's activity changes
little, but from the moment of growth its acti-
vity increases greatly.
Card 2/2 - 61 -

DUBYAI)BKIY, V.M.; BABUSENKO, I.D.; TARKHOV, V.M.
New technological plan for minin thin coal seems using a cable
unit. Trudy NPI 101:185-201 160. (MIU 15 :5)
(Coal h-Aling machinery)

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BABUSHKINq AeAe; UVAROV, A,V.; IGNATIMA, L*A,
Infrared spoetroscopic.analvoia of the adsorption and surface
reactions of ethyl and wthyl alcohols on aluminum oxide. Pis.
sbor. n0-3:161-167 157. (MIRA 110)
1. Moskmakly ordena Ienina i ordena, Tmdovogo Krasnogo Znamni
gosularntyennyy unive"itat in. N.T.1ozonosoTa, i Institut fizi-
cheskoy khtall AN 3609
(31thmol-Speetra) (Methanol-SPectra) (Alumimm oxide)

WUSMN, AA,; GUSNA, N*Go; Y3MIYANOVA, V.H.
....... .......
Infrared spectm of molecular compounds composed of boron tri-
fluoride and various anines, Iris. abor. no*-3:212-213 157o
(MIRA 11:8)
1, Nookovskly ordena Isuina i ordane, Trudovogo Krasnogo Zuawsni
govadarstyenun universitet im, N.V. Lomonosove, i Institut
fiticheekoy Wall AN SSSM~
(Azine-S~eetra)
(Boron fluoride--Spectra)

BABUSMaN, A.A.; GVOZMff, B.Aq; GLAZUNOT. F.Ya.
~ -
Spectrophotometrie equipment for continaous absorption analysis and Aw
recording gas concentrations, Piz, sbor. Z,0-3:36(~-363 157.
(mm n18)
1. Institut fizichealcoy khimli AN SSM
(Spectrophotometer)

4
PRirwioT'Ko, 0 F
24 (T) PHASE I BOOK EXPLOITATION
SOV/1365
LIvoy. Univeraytet
Plateilsay X Viseacrutnogo o3vashchanlya po spektr03kopil. t. Is
Holakulyarnaya bpektroak~piya (Papers of the 10th All-Union
spectropoopy)
Conference on Spectr~ssaop;f. Vol. 1: F41ecular
IL-vor) lxd-To Llvoy3kogo wd-ta, 195~1, 499 V. 4 000 ooplaw
printed. Sarleat !tat Pitychnyy zblrayk. Typ.
Additional Sponsoring Agaiwo,7i Akadezdye nauk SSSR. Komistslyst po
spektroakopil. F4*t ijazar, S.L.1 Tech. Ed.- S&ranyuk, T%V%j
Bditorlal Boards L&nielterg, OtSs, Aeadarlsslan (Reap. Ed., Decest"d)s
Neporent, B.S., Doctor of Physical and Mathematical Saleacen.
Fabelinskiy, I.L., Doctor of Physical and Mathematical Sciences,
Y&tarlkasAp V.A., Doctor of Phjsioal and Mathematlosa Soleness,
Xcraitak:Iy, V.O., Candtdata of Technical S.Ienc.s, Ragakly, S.M.,
Candidate of Phzaloal And Mathematical Sciew: KlImovakiy, L.K.,
Candidate or Phyalitsal and Matham&tical Scinc :: Killyanchult, V.S..
Candidate of Phploal and MatverAtical Sciences, and Glaubarmn,
A. U., Candidate of Physical and HAthenatical Sciences.
C&M 1/30
A. Ovozdev, &a P. Va. 411twov.
B
tr -it for the Continuous
Spaotrophoto;O
_le RqulpDe.
Absorption Analysis aM4 Registration of Oat
Cortaontration, 360
Arkhanaellskaya, V.A., B.I. Vayn!>era. and T.X. Rarw"s
Simple method or vote-tv-,jar4 t-%* Passing or Some
OMattl )PAtorials in Schumann's Spectrum Region 363
OludInkint, N.P. Sp4atrophotonatric DhtemizAtion of
Vator Purity 364
Onahkin, O#Vs Condensed Dinchama Through a Capillary
S
t
C
i
I
nuous
oat
poo
rwo
n
as : ro"rful 3zr4rca of
ape tral Studies
365
Takavlow, S. Ys. A Wedge-sthaped Black Body " a
Source of Radiation for Spectrophotmisstrio
Nessour"Writs 368
COY4 23/30

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Sov/51-4-4-6/24
AUTHORS- Babushkin, A.A., Kovalev, I.F. and Yemel'yanova, V.M.
TITIE: fnW the Vibrational Spectra of Molecular
Compounds of Boron Trifluoride with Substances Containing
Nitrogen and Oxygen. I. F 3 B.NH3and F 3B.ND 3
(Issledovaniye kolebatellnykh spektrov molekulyarnykh
soyedineniy trekhftoristogo bora s azot- i kislorod-
soderzhashchimi veshchestvami. I. F 3 B.NH3 i F3B.ND 3)
PERIODICAL: Optika i Spektroskopiya, 1958 , Nr 4,
pp 468V-40713IV(USSR).
ABSTRACT: Boron trifluoride was obtained by decomposition of
C6H 5N2*BFY Purity of boron trifluoride was checked spectrally
and only SiF4 in an amount smaller than 0.5% was found.
Molecular compounds of boron trifluoride with ammonia and
deuteronmmonia were obtained by condensation of ammonia (or
deuteroammonia) on freezing by means of liquid nitrogen in
an ether complex of boron trifluoride,(C2H 5)2O.BF 31 in a
metal test tube. A white crystalline substance was obtained
which was re-crystallised in water (or heavy water) or in
acetone. In re-crystallisation of F B.ND from acetone, a
Uard /4 3 3

Sov/51-4-4-6/24
Investigation of the Vibrational Spectra of Molecular Compounds of
Boron Trifluoride with Substances Containing Nitrogen and OxyEen.
I. F3 B 'NH3 and F3B.ND 3
replacement of &uterium. by hydroGen occurred and a mixt~urle
of compounds with different degrees of replacement of hydroGen,.
by deuterium was obtained.. This i;,~ixture was denoted by the
formula F B.NH.D where i and k may have the values 0,
3 a. k I
1, 2, 3 and i + k 3 The spectra were recorded using a
spectrometer IKS-11 in the region from 2-5 to 15 P . To avoid
absorption by atmospheric water vapour and carbon dioxide,
nitrogen was passed through the spectrometer. Samples were
prepared by placing a layer of paste of the substance studied
between two plates of -rock-salt or by placing a dry layer of the
substance between the same plates. Raman scattering spectrum
of an aqueous solution of the molecular compound F 3BAH 3 was
recorded by means of a spectrograph ISP-51 with a photoelectric
attachment UF-320. The infra-red absorption spectra of
Y3B..NH3and F3B.BD3 are shown in Figure 1. Calculations of
the force field and vibrational spectra were based on moleoular
models with C symmetry for F B.NH and F B.ND (Figure 2)
Card2/4 3v 3 3 3 3

sov/51-4-4-6/24
Investigation of the Vibrational Spectra of Molecular Compounds of
Boron Trifluoride with Substances Containing Aitrogen and Oxygen.
I. F3 B.DH3 and F3B-.ND3
and Cs symmetry for F 3B..NH2D and F3B..NHD 2' To calculate
the force constants, the authors used their own experimental
results on the Raman and infra-red spectra of F 3B.NH3 and
F3B..ND 3 (see table on p 471). The observed frequencies for
the mixture denoted by F 3B.NHiDk were used to check the
calculations. The force field for F 3B.NH3was calculated
by the method of Vollkenshteyn, Yellyashevich, Stepanov
(Ref 18) and Mayants (Ref 13) using "spectoscopic masses"
for hydrogen and deuterium. From 49 force constant!6 which
det-rmine the potential function 18 were taken to be equal
to zero. The calculated force constants are given at te
top of p 4?3. They were calculated using the BESM computer
of the Ac..Sc. USSR. The table on p 4?1 shows that there is
good agreement between the observed frequencies and those
obtained by calculation using the force constants. The
Uard3/4 authors also calculated the coefficients of induction which

Sov/51-4-4-6/24
Investigation of the Vibrational Spectra of Molecular Compounds of
Boron Trifluoride with Substances Containing vitrogen and Oxygen.
1. F3B..NH3and F3B-14D3
are given in the middle of p 473. The authors thank
A.I. Shatenshteyn for supply of deuterated ammonia and
R.I. Podlovchenko for help in carrying out the calculations
on the computer. There are 2 figures, 1 table and 19
references, 6 of which are Soviet, 8 in English, 2 German,
1 French, 1 translation of Western work into Russian and
one other.
ASSOCIATIOR; Institut fizicheskoy khimi AN SSSR (Institute of
Physical Chemistry, Ac.Sc. USSR), Saratovskiy
pedagogicheskiy institut (Saratov Pedagogical
Institute) and Moskovski gosudarstvennyy universitet
(Moscow State University
SUBMITTED: June 14, 1957
-'---f'ard 4/4 1. Boron florides-Spectra
. v I

60*V/51 -5-'~-5/21
AUTHORS: Babushkin, A.A., Gribov, L.A., Guseva, N.G. and Yemallyanova, V.M.
TITLE; Invostiption "'of the Vibrational Spectra of the Voloctilar ouipounds- of
Boron Trifluoride -with Nitrogen and Oxygen-Containing Subsi--n2as.
(Issladovaniye kolobatellnykh spektrov molelmlyarnykh soyedinaniy
trekhftoristogo bora s azot- i kislorodsodarzhashchimi vashchostvar-ii) -
II. On the Structure of the Yolecular Gompounds of Boron Trifluoride
with Methanol, Ethanol and ifater (11. 0 stroyenii molelmlyarnykh
soyodinaniy trakhftoristogo bora a metanolom, otanolom i vodoy).
PK.RIODI CAL tOptika i Spoictraskopiya, 1958, Vol 5, Ur 3, pp 266-263 kUSSR)
AR3TRACT: Part I is given in Ref 1. Boron trifluoride forms two types of
molecular compounds with viater and the two alcohols. In one typo
there is one molecule of water or alcohol for each molecule
of BF3 (1:1) -while in the other typo there are two molecules of vatar
or alcohol for each BF3 molecule (1:2). The authors obtained the
infrared absorption spectra of molecular compounds of both types:
BF3.1120, BF3-2H20, BF3.CH,3a!, LFOCH,30H, BF,3-C2H,9CRi, BF3-2C2H5011-
The measurements were made in two, spectral regions; the roGion of
oard 1/13 fundamental valence vibrations of OH and CH (2000-34800 v.1-1) and the

sov/51-5-3-5/21
Investigation of the Vibrational Spactra of the Yolecular Compo,.Znda of Boron
.trifiluoride vith Elitrogen and Oxygen -Containing Substan-ces H. On the Stractare
of the Molecalar CoLapounds of Boron Trifluoride with Lethancl, Ethanol and Water.
region of absorption of their first hamonics (55,000-7,300 cm-'). -the
measurements in the harmonic region were necessary in order to avoid
con.-%sion due to possible decomposition of certain ~1:1) molemalar
compcUrids. The measurements were made using an IES-11 spectrometer.
In t-he region 3500-3800 cm-1 a two-boam lKS-2 spectrometerwas also
used. For measurements on corrosive liquids a special call was made
of toflon (Fig 1). This was used to measure the absorption in the
fundamental frequency region. In measurements of absorption in the
har-,onic region a glass cell was used. BF3 was obtained by the method
described in Ref 1. Synthesis of molecular compounds was carried oat
in vacuum. A known amount of the additive was placed into the reaction
vessel and frozen. The vessel ivas punipel out and then filled with
an appropriate amount of BF.3- Fig 2 shows the absorption spectra of
tho molecular compounds BF.3.2CHPH, BF3-'G,~,H~DH, BF3.2H,:O (curvei, 1,
2 and 3 respectively) in the region 24-M-3800 am-1. Fig 3 shows the
ab&orption spectra of all the six molecular compa--nds studied, in the
oard 2/3 racion 5700-7500 cm-1. No absorption bands ivare found which could be

-5-3-5/21
OV3.51
Investigation of the Vibrational Spectra of the 11olecular Compoiands of Borcn
Trifluoride vith Nitrogen and Oxygen -Gon-t,-Aining Substances .11. On the Stractur3
of the Molecular Compounds of Borcn, Trifluoride with 1.1athancl, Ethanol and Wator.
ascribed to valence '7ibrations of OH of the oxoniuri ion. The exparimental
results lead to tho conclusion that the (1-01.) molacalar cC4-,ipcrards are
pcl~inarically aesociated by means of +he hydrogen bond, and the k1.2)
comnlexes are dim,3rs with the following wvrurtare
R R
I I
PPI 11,H-9
H A
6-H-4-BF3
There are 3 figires and 12 reforencea, 3 of viiich are Soviet.
ASSOGLITIONT ;Ins ti tut fizichesicoy kh!ariii AN S~;SR; I~Toskavekiy gosularstvernyy
universitet, fizichesli:iy falwlltut, loifedra optiki kInstitute of
Physical Chemistry, Academy of Sol-ences- of the U.S.S.R.; Mos~-ow State
University, Department of Physics, Chair of Optics)
SIGBIMMD: October 26, 1957
Card 4/3 1. Doron fluoride compounds-Spectra 2. Tnfrared spectroscopy-
Applications

--A S ; GVOZIMV, B.A.; GLAZUROV, P.Ya.
Photoelectric apparatus added to the spectrograph for the purpose
of absorption analysis. Trudv kom. anal. khim. 8:258-265 158.
(MIAA 11:8)
1.Institut fizicheskoy khimii AkademU nauk SSSR.
(Absorptiometer) (Spectrograph)

AUTHO'S: Babushki
iaj,A4_ Kovalev, I. F., SOV/48-22-9-33/40
--*eMyrr~ya-n-ovaq V. M.
TITLE: Spectroscopic Investigations of the Striicture of Some
Complex Compounds (Spektroskopicheskiye issledovaniya
stroyeniya nekotorykh kompleksnykh soyedineniy)1.11olecular
Compounds F 3 B.NH3)and F 3B.N:)3(1.Molekulyarnyye soyedineniya
F B.NH i F B.ND
3 3 3 3
PERIODICAL-, Izvestiya Akademii nauk SSSR. Seriya fizicheskaya, 1958,
Vol 22, Nr 9, PP 1131 - 1131 (USSR)
ABSTRACT: Thka is a oondenBation of the paper whioh was published
under the above subtitle Nr 1 in tho "Izvef3tiya Akademii
nauk SSSRII by A.A.Babushkin. The spectra of infrared
absorption and of combination dispersion of the compounds
in question were recorded in the laboratory of the Institut
fizicheskoy khimii Akademii nauk BBSR (Institute of
Physical Chemistry AS USSR). The field of force and the
vibration spectra were computed by I.F.Kovalev. The com-
putatiorewere based upon the model C 3D for F3B.NH 3 and
Card 1/2 upon the model C S for P 3B.NH2D and F 3B.NHD 2- The spectrum

Spectroscopic Investigations of the Structure of SOV/Z18-22-9-33/40
Some Complex Compounds. 1. Molecular Compounds F3B.NH3 and F3B.'ND3
of the two last mentioned substances served as control.
The results of the computation of the vibrLLtiOn spectra
of F B.NH and of its deutero derivatives, their inter-
pretation3and that of the computation of the potential
function were considered to be satisfactory. The value
of the force constant of the bond B-N, which equals
4,4-jo5 dyn cm 1 indicates a sufficient strength. The
activity in the spectrum of combination dispersion
corresponding to the vibrations of the B-N bond indicates
a covalent nature of this bond.
ASSOCIATION.- Institut fizicheskoy khimii Akademii nauk SSSR (Institute
of Physical Chemistry,AS USSR)
Card 2/2

A*,JTIIORS: A- A., Gribov, L. A., Guseva, SOV/48-22-9-34/40
-- 'PO
i. G.,' eTe-l-lyanova, V. M.
THTLE: Spectroscopic Investigations of the Structure of Some
Complex Compounds (Spektroskopicheskiye issledovaniya
stroyeniya nekotorykh kompleksnykh soyedineniy) 2. On the
Structure of the Molecular Compounds of Boron Fluoride
With Methanol, Ethanol and Water (2. 0 stroyenii molekulyar-
nykh soyedineniy trekhftoristogo bora s metanolom, etanolom
i vodoy)
P13RIODICAL: Izvestiya kkademii nauk SSSR. Seriya fizicheskaya, 1958,
Vol 22, Nr 9, PP 1131 - 1133 (USSR)
A13STRACT: This is a condensation of the paper which was published
under the above subtitle Nr 2 in the "Izvestiya Akademii
nauk SSSR" by A.A.Babushkin. Boron f'luoride forms two
types of molecular compounds with water and alcohols: in
the first type one molecule of water or of alcohol falls
to one molecule of F B, (1:1), in the second type two
molecules of water o; of alcohol fall to one molecule of
Card 1/4 F3B (1:2). At present several authors share the opinion

Spectroscopic Investigations of the Structure of SOV/48-22-9-34/40
Some Qomplex Compounds. 2. On the Structure of the Molecular Compounds
of Boron Fluoride With Methanol, Ethanol and Water
with Paushkin ~Ref 3) according to which the molecular
compounds (1:2 can be considered t 0rep esent oxonium-
type compound s: IH20)+ EF3B. OH] -, [R. OH 21F3B. ORJ
q
Hence the structure of the molecular compounds in question
cannot be regarded to be established beyond doubt.
Attempts to find an absorption which is characteristic
of the oxonium. ion were unsuccessful. The absorption
spectra in the range of the first harmonic of the OH
valence oscillations (Fig 1) show a great difference
between the spectra of F 3B.10RH and of F 3B.20RH. As no
evidence was found in the spectrum confirming the presence
of the oxonium ion it can be assumed that the oxonium form
is either not realized at all or that its concentration
is too low. This paper presents a comparison of the wave numbers
of the fundamental oscillation and of the first harmonic
of the OH valence oscillations of methanol, of ethanol, and
Card 2/4 of water without association (diluted solutions and vapors)

Spectroscopic Investigations of the Structure of SOV/48-22-9-34/40
Some Complex Compounds. 2. On the Structure of the Molecular Compounds
of Boron Fluoride With I-Jethanol, Ethanol and Water
with the frequencies which correspond to the maxima
of the absorption bands (1:2). The experience gained
by this comparison leads to the conclusion that these
compunds are associated among themselves by means of a
hydrogen bond. The wide absorption bands of the compound
(1:1) are also caused by their association by means of
a hydrogen binding. The difference in the band widths and
in the wave numbers corresponding to their maxima can be
traced back to the diff-erent process of formation of the
hydrogen binding in both (1:1) and (1:2) compounds. The
- existence of a narrow band in the compound (V..2) is considered
to be related to the association of two complexes in which
four hydrogen bindings form a closed cycle structure for-
mula (II). The absence of absorption bands which are
characteristic for the terminal hydroxyl group (hydrogen
binding) in the frequency range of the fundamental frequency and
first harmonic of the OH valence oscillations also corro-
Card 3/4 borates the existence of the structure (II). There are

Spectroscopic Investigations of the Structure of SOV/48-22-9-34/40
Some Complex Compounds.. 2., On the Structure of the Molecular Compounds
of Boron Fluoride With Methanol, Ethanol and Water
1 figure and 3 references, 1 of which is Soviet.
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR(Institute
of Physical Chemistry,AS USSR)
Card 4/4

AUTHORS: Babushkin _Yukhnevich, G. V., SOV/48-22-9-35/40
LL~~
)3erezklna, Yu. V., Spitsyn, V. I.
TITLE: Spectroscopic Investigations of the Structure of Some
Complex Compounds (Spektroskopicheskiye issledovaniya
stroyeniya nekotorykh koriploksnykh soyedineniy)3- In-
fluence of Water Dn the Structure of Para- and Meta-
Sodium-Tungstenate- (3. Vliyaniye vody na stroyeniye
para- i metavollframatov natriya)
PERIODICAL: Izvestiya Akademii nauk SSSR. Seriya fizicheskaya, 1958,
Vol 22, Nr 9, PP 1134 - 1135 (USSR)
ABSTRACT: This is a condensation of the paper published under
the above subtitle Nr 3 in the "Izvestiya A.kademii nauk
SSSR" by A.A.Babushkin . It covers the investigation
of the infrared absorption spectra of paratungstenates
bNa 2 0.12W03) with a composition of 28 H 20, 19 H 20, 9 H20,
4 H2 0, 2 H 20 and of water-free tungstenate. Two ranges,
that of the valence- and deformation oscillations of the
Card 1/2 tungstenate ion (700 - 1700 cm-1) and that range

Spectroscopic Investigations of the Structure of Some SOV/48-22-9-35/40
Complex Compounds. 3. Influence of Water :)n the Structure of Para- and
Lieta-Sodium-Tungstenates
(3000 - 3800 cm- which is especially favorable for a
study of the aqueous state were investigated. Besides,
the absorption spectra of meta-sodium-tungstenate (Na 2 W4013)
with a composition of 10 H 20, 7 H2012H20and of a water free
meta-sodium-tungs't,enate were studied. A comparison of
the results of the investigation of various hydrates
of para- and of -net-a-tungst enates permits a joint treatment.
An immediate connection between the coordination of the
water in the complex and the anion structure of the iso-
poly compounds was established to exist. A modification
of the water coordination at a dehydration leads to an
alteration of the structure of the anion. The maintenance
of a stable coordination of the viater does not lead to
an alterartion of the structure of the complex. There are
2 figures.
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR (Institute
Card 2/2 of Physical Chemistry IAS USSR)

5W ,
AUTHORS; Ba.buahkin, A. A., Gribov, L. A., SOV/20-123-3-22/54
-GV�4mNff T-A
TITLE: The Nature of the Bond Between the Central Atom and Some
Unsaturated Molecules in Complex Platinum Compounds (0
k,haraktere svyazi mezhdu tsGntrallnym atomom i nekotorymi
nenasyshchennymi.molekulami v kompleksnykh soyedineniyakh
platiny)
PERIODICAL: Doklady Akademii nauk SSSR9 1958, Vol 123, Nr 3,
PP 461-463 (USSR)'
ABSTRACT: The problem of the bond between metal.S and the molecule
mentioned in the title was investigated in numerous papers.
A respective survey is given in reference 1. According to
A. D. Gellman (Ref 2) the platinum atom represents at the
same time an electron donor and acceptor. In consequence of th:js
a covalent double bond results between the central atom and
the olefin. Chatt and Duncanson (Ref 4) suggest a scheme for
this bond which can be regarded as)T-electron interaction.
The authors do not agree to the interpretation of the spectra
observed. Chatt and Duncanson (and Ref 5, According to them)
Card 1/4 conclude from their interpretation that the double bond of the

The Nature of the Bond Between the Central Atom SOV/20-123-3-22/54
and Some Unsaturated Molecules in Complex Platinum Compounds
olefin is maintained also in the complex formation. The
authors state, however, that the reasons for this fact are
not sufficient. The purpose of their paper was therefore to
perform a critical analysis of the infrared spectra of
complex platinum compounds with ethylene, propylene and
carbon monoxide: 1) contrary to reference 4, the frequencies
in the range above 3000 cm"lare a necessary but by no means
sufficient proof of-the maintenance of the double bond
C . C in the olefin part of the complex. Due to the similarity
of the electron configuration in the CH 2-grouP of the ethylene,
ethylene oxide and cyclopropane molecules the authors suppose
that the olefin is forming with platinum a compound according
to the type of a triangular cyclic structure. 2) According to
the above-mentioned statements it is more correct to attribute
the frequencies of the ethylene and propylene complexes with
platinum in the range 1490-1516 Io the deformation oscillation
CH2(Ref 7a), but not to the frequency of valence oscillations
Car-i-2/4. of the double bond C.~ C. 3) The frequency of the non-plane

The Nature of the Bond Between the Central Atom SOV/20-123-3-22/54
and Some Unsaturated Molecules in Complex Platinum Compounds
deformation oscillations of the CH -group is a typical
feature of olefins (Ref 8). The absence of this frequency
in the complex compound under consideration and the presence
of 4 additional intense frequencies between 1300 and 700 cm-
(as compared with the spectra of the initial addenda) proves
a considerable transformation of -the ethylene molecule that
must be related -with the transformation of the double bond
C - C into a single one. 4) The above-mentioned considerations
are in accordance with the data on the structure of the complex
compound mentioned (Ref 9). According to these data, the
ethylene molecule is v6~rti~al to the PtCl -plane and, shows
3
with respect to the latter, nearly a symmetric position. The
distance between the carbon atoms & = 1-50 1 is a value
characteristic of a single bond between these atoms- 5) The
analysis of the infrared spectrum of-the complex compound
proves that the double bond C ~ C in ethylene is transformed
into a single one on the entrance of the platinum atom into
CE;rd 3/4 the inner sphe.re. Therein the strength of the bond between

Thi Nature of the Bond Between the Central Atom SOV/20-123-3-22/54
und Some Unsaturated Molecules in Complex Platinum Compounds
platinum and the carbon atoms is according to the order
of magnitude of the strength identical with an ordinary
covalent bond. 6),The statements made in points 1-3 are
valid both for K PtC 2H4Cl 33 E20 and K [PtC3H6 Cl 33 -H20-
For this reason the authors claim that the structure and
nature of the formation of the propylene bond with the
central atom are similar to those of ethylene with platinum.
There are 10 referenoest 5 of which are,Soviet.
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR (Institute
of Physical'Chemistry of the Academ~ of Sciences USSR)
PRESENTED: July 7, 1958, by V. I. Spitsyn, Academician
SUBMITTED: June 26, 1956
Card 414

IVLULRII~N )il. j",
"Investigation of the infrared absorption spectra of some aquapoly- and
heteropoly- compounds," report to be submitted for Int'l Conf on Coordina-
tion Chemistry, IUFAC, London, England, 6-11 Apr 59.
Institute of Physical Chemistry, Moscow, USSE.

SOV/78--4-4-'9/444r
AUTHORS: k1n A...A, Yukhnevi.,-h, G.. V., Berezk_4na, Yu. F.,
Spitsyn, Vikt. I.
TITLE: Investigation of the Effect. of Water or) the Structure -f
Sodium Paxa- tungstate and Sodium keta-tangstate Using

Method cf infra-red Albso
.pt-4-on Spectra (Issledovaniye vllyaniya
vca,y r~a --trz.,aniye pa_-~a- i metavollframa-*Zov natriya =-_-tod,)ni
irlfrakraSrY1~11 SpEktriz~v pogloshchenlya)
PERIODIVAL: Zhuxn~_._ nec-rgan4
ionesk,~y kh.4mii, 1959, '101 4, Nr 4, p1, 323
(USSR,
ABSTRACT: The aulkhors investigated the effect of water upc-, the atra~.--~uze
C~f r~ara and 'met-a tungstat6 and the type of -conding of
t'he watE~r in,.the anions of t'hese compounds. The inf--a-red ab-.
sorption-spaatra of sodium para and-meta tungstate wezZ jlc:tt~d
for different wat-er contents using 'he IKS-1,
wit-h sodium chlrride and !it'_-ium fluoride Prisms. The
,ibsorption spectra fcr sodium para-tuing state with 28H,0, 19H 20;
9H 0. 4H 0, 2H 0 and 0.2H 0 per molecule of Na W 0 &q 7 "l, 1.
2 2 2 2 10 ',2 41 -
as the ar,,Vdroue para-tungstate were investigated. TIZe I e , t
P--d 1 A gation was carried out over the spectral rariges 700-1-7100 :,x"

SOV/78-4-4-19/44
Investigation of the Effect of Water on the Structure of Sodium Para-tungstaze
and Sodium Meta-tungstate Using the Method of Infra-red Absorption Spectra
and 3000-3800 CM71 . For sodium para-tungstate hydra~.es in the
transition from 19H 20 to 9H20 a marked change in the structure
of th? coordination water and in the structure of the anions
occurred.*The structures of the hydrates of the sodium meta-
tungstate remained unchanged. Using spectroscopic methods and
isotope exchange of hydrogen against deuterium it was found
that in the sodium para-tungstate with 28H2 0 three forms of the
coordination water exist. One of these forms is present as the
hydroxyl group ' which is bound directly to the tungsten atom.
Likewise in the hydrates of the sodium meta-tungstate there is
a form of the coordination water as the hydroxyl group bound
directly to the-tungsten atom. Infra-red absorption spectra
of sodium meta-tungstate were plotted for 10-7 and 2H2 0 and
the anhydrous sodium meta-tungstate in the ranges of 3000-
3800 cm- I and 1300-600 cm- 1. These are shown in figures 4 and
These spectra show that there is no difference between the ab.-
Card 2/3 sorption spectra of these hydrates of sodium meta-tungstate.

SOY/78-4-4-19/44
investigation of the Effect of Water on-the Structure of Sodium Para-tungsta".".
and Sodium Meta-tungstate Using the Method of Infra-r6d Absorption Spectra
No specific absorption was foiInd fox, the,,anhydrous sodium
meta-tungstate in the range 3000-3800 cm-1. The differences in
the-optical densities of thevarious-hydrate's are shown in a
table. A further table gives the wave numbers (cm-') of the
absorption maxiias. of the hydrates of sodium meta-tungstate.
There are 5 figuresp 2 tables, and 8 references, 4 of which
are Soviet.
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR (Institute Of
Physical Chemistry of the Academy of Sciences, USSR)
SUB11ITTED: ia;ruary 13, 1958
Card 3/3

5(2) SOV/78-4-7-12/44
AUTHORS: Babushkin, A. A., Gribov, L. A., Gellman, A. D.
TITLE: On the Character of the Bond Between Central Atom and Olefine
in Complex Compounds of Platinum (0 kharaktere svyazi mezhdu
tsentrallnym, atomom. i olef:Lnom v kompleksnykh soyedineniyakh
platiny)
PERIODICAL: Zhurnal.-neorganicheakoy khimii, 1959Y vol 49 Nr 7P
pp 1542-1547 (USSR)
ABSTRACT: The present paper analyzes the infrared a pectra of compounds of
platinum with ethylene and propylene. Table 1 gives the *aquen-
cies for K H Ptel H 0 and XfC H OH 0. It is con-
102 4 31- 2 - 3 6PtCl3] 2
cluded from the spectra that in both compounds the carbon double
bond-is ruptured and a triple ring is formed in ethylene
H2 C
1/"PtC13* This is confirmed by a
comparison with the spectra
.
H2 C
of ethylene oxide and ethylenimine. The interpretation of
frequency within the range of 1500 cm-1 as a valence shrinkage
of the C=C-bond, as given by J. Chatt and L. A. Duncanson
Card 1/2 (Ref 9), is therefore considered to be improbable. Figure 1

BOV/78-4-7-12/44
On the Character of the Bond Between Central Atom and Olefine in Complex
Compounds of Platinum
shows the infrared absorption spectrum of propylene and of the
propylene-platinum. compound.'There are 1 figure, 1 table, and
24 references, 12 of which are Soviet.
ASSOCIATION: InBtitut fizicheskoy khimii Akademii nauk SSSR (Institute of
Physical Chemistry of the Academy of Sciences, USSR)
SUBMITTED: March 25, 1958
Card 2/2

TUXMVICH, G.V.; BABUSMIN, A.A.; KOLLI, I.D.
Influence of water on the etructure of potassium silico-
tungstate. Zhur.noorg.khii. 5 no-5:1176-1177 W 160.
(MIR& 13:7)
1. Institut fisicheskoy khimii Akademii nauk SSSR. lafedra
neorganicheskoy khimii khimicheskDgo fakullteta Moskovskogo
gosudarstvannogo universiteta.
(Potassium silicotungstate)

BABUSHKIN, Alsksandr ~~ ~ dots.; BAZHULIN, Pavel Alekseyevich,
Fedor Andreyevich, prof.; LEVSHIN, Leonid
Vadimovich, prof.; FROKOFIYEV, Vladimir Konstantinovich, prof.;
STRIGANOV, Arkadiy Romanovich, doktor fiziko-matem, nauk;
GOLIDENBERGt G.S., red.; GODRGIYEVA, G.I., tekhn. red.
(Spectrum analysis method8]Metody spektrallnogo analiza. (By]
A.A.Babushkin i dr. Pod red. V.L.Levshina. Moskva, Izd-vo Mosk.
univ., 1962. 508 p. (MIRA 16:2)
(Spectrum analysis)

BABUSHKIN,,.-A.A.-y--GOLIKOVA, V.S.; KRYLOVA, L.M.; KII-ELIFELID, Ta.M.;
~-'~~"`~--"~ZUBOV, P.I.
Use of infrared spectrometry in studying the kinetics of the
formation of polymer coatings. Izv. AN SSSR. Ser. fiz. 27
ho.7:978-980 163. (MIRA 16:8)
1. Institut fizicheskoy khimii AN SSSR.
(Solid film) (Spectrum, Infrared)

- -
.~Az~ %EDNIKOV, A. K.; STROTKU1, ~*~. 1.
Measurements of the Energy Loss _,f Alpha Particles in Tnin Layers of Gold
on Semi-Conductor Spectrometers."
report submitted for All-Union Conf on Nuclear Spectroscopy, Thilisi, 14-22
Feb 64.

ACCESSION NR: AP4041037 S/0120/64/000/003/014210145
AUTHOR: Babushkin, A. A.. Gorin, A. I.
TITLE: Auxiliaries to the IKS-14 spectrophotometer for investigating the spectra'
of very thin films
SOURCE: Pribory* i tekhnika eksperimenta, no. 3, 1964, 142-145
TOPIC TAGS: spectrophotometer, IKS-14 spectrophotometer, infrared spectrum.
photometric wedge
ABSTRACT: Auxiliary devices to the,2-beam IKS-14 spectrophotoincter
1: necessary for recording the inf rare&,spectra of monornolecular films are briefly
described. A multipass i:ell comprises two pairs of flat mirrors, each pair
reflecting the beam 11 times; thus, the light passes the test film 22 times. The
;1; standard 4-tooth "comV (photometric wedges) was replaced with a single wedge
I
.1 'which increased the sensitivity to low optical densities fourfold. An experiment
2

ACCESSIONNR: AP4041037
corroborated the fact that the linear relation between the wedge travel and the
transmission remained intact. A potentiometer bridge of 0.03% resolution was
provided for extending the recorder scale. Records of NF6 and Ca stearate
spectra illustrate the gain in sensitivity. Orig. art* has: 4 figures.
ASSOCIATION: Institut fisicheskoy khimii AN SSSR (Inst-itute of Physical
Chemistry, AN SSSR)
SUBAUTTED: 08Jul63 ENMI 00
SU'B CODE: OF NO REF SOV: 000 OTHER: 003
z

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.1 o6166-7-65 /Sb/AW-AS( )_2~
Evr(M)APF(c )'Anq1EwP(j VT Fca-h/p,_VFS4 an UP
/RM
ACUMM. NR: AA0426DD -9/0D76/64/038/007/1043/1845
AUMOR: babusbk1up As Av
TITM A wv method for investigation of surfaCe~rDpertiCS Of GDU&.
SOMWE: Zhurnal JUzicheskoy kbird-1: V& 38o no- To 1964o 1843-1645
TOPIC TAGSI Infnired speotr~*hotmetry,, monolayerap adsorptionj eherdeal structure
ABM71AM: In tbjU3 vork ~:Lt was ~ necessary to Improve a serial type spectrophotometer
IKS-14 in order tA) record infrared (IR) spectra of monolayers. It was necessary
to use special cells with multiple passage of li&t flux through the Investigated
thin film of subwtance. The get-up consisted of two plane mirmrs located parallel
to each other and at IM C vith respect to the axis of the Ught path. An addi-
tional AYAt9A of Jdl'1162t Vag tMea to foci the sou=e image into the plane of the
correcting prism of t3m photometer. An x-al SDus optical system was placed in the
channel of the coaparAzon, beam. Me investigated substance iras placed on the
mir=r surfaces &f tv-o plane mirrors. The light beam was reflected eleven times
from the surfaces of these nirriors and., consequentlyo it passed through the invest-
igated substance M t1nes., This enabled dearaasing of the tUa3mess of the
C01.1 2/3 - ~ - , , .. --- - -

:L 6667!-65
'AMMUCH NE: AP40426DO
sqeclmen., necessary for recording of the spectrum., by two oiders of magnitude,
down to a monolayer. The mirrors on which monoleyers were placed were produced by
A;hermal deposition of metal In a relatively low vacuum (10-4 m). Consequently,,
tbe netal had oxide filme. The oxide film on aluminum reaches a thickness of 45 A
iind It does not Umrease, while on copper the oxide film Increases with time, but
it is still of the saw order of magnitude. It consists primarily of ciTrous oxide.
The absorntion bV these oxide films occurs in the long wavelength region of the
:cTectrum-1 ~')'7 ~Icrons)- In this work Investigation made of the IR spectra of
mionolayers of different substances (met lmethacg7late, Mthy1mthacrylate in
W24, haxamethylerieimine-3,5-dinitroben te) on _ :L r surfaces of metals.
Zoa the
Ibis method permits sUidy of the zone structure of semiconductorr, and changes
-rithin such zones during introduction of impurities or during adsorption of differ-
ent substances. Xt is concluded that the use of this metbod W be extended if on
retal surfaces onjj places a very thin film of another substance and studies its
interaction vith the taLtrd substance. Orig. art. has: 2 figures.
ASSOCIMIDN; inw4itut nzichesiDoy khimu Akaaenii nauk sm (institute of Pbysical
Chemdatry Acad=V of Sciences =R)
C
Ord

V
SiMaTTKD.0 Oa7ulb"3 EVCL* OD

BAEUSHIKIN, A.A. (Mosl-va); KRYLOVA, (Mloskva); GORIN, -.i.
Interpretation of the infrared absorption specLra of formaldehyde
in aqueous solution. Zhur. fiz. khi-m. 3S no.10-.2361-2366 0 164.
(MIRA 18:2)
1. Institut fizicheskuy khirnii ANT SSSR.

BABUSHKIN-5 A.A., KRY1,0111A, 11-14~ (Moskva)
Interpretation of the infraigd spectra of water-soluble phenol-
formaldehyde resin. Zhur. fiz. khim. 38 no.10:2367-2371 0 164.
(MIRA 18:2)
1. Imstitut fizichaskoy khIm-A AN SSSR.

JL- 2505" Ovipno w8mlEo o I- lip P
ACCE3SION NR: AP4047985 S/0076/64/039/010/2462/2465
AUTHOR: B.abushk.in,__&. A.; B1Agopra~Yq",._A,_ A._;
qavrilLina, S. A.
TITLE: Investigati,Dn of the process of curing the diglycidyl ether of diphenylol-
propare by w!~ans Df boron trifluoxide ethe.ra e
SOVR(',I~. Zhurnal fizicheskoy khirnii,- v. UP ho. 0, 1964, 2462-2465
TOPIC TAGS: diphenylolpropane derivative, curing, polymerization, boron tri-
fluoride etherate, reaction mechanism
ABSTFACT: The reaction mechanism of the curing of the diglycidyl ether of di-
phenylolpropane with 33F3,C1(C2H,)2 was studied spectrophotometrically. The
curing of the material, i.e. , the film-forming reaction, was followed by measur-
ing the optical density of the IR absorption '.Dands characteristic of the ether oxir-
ane riug, and of the ether and the hydroxyl bonds. Studies were made running
the re;ictions for 1. hour at 30C using 116 ca-~alyst. The reaction was characterized
by a ducrease in the number of epoxy groups and an increase in the ether and hy-
Card 1/ 2

SUBMIT TED: 04Sep63 ENCL* 00
SUB CODE: GC, OC NO REP SOV-. 004 OTHER: 002

7
VM00) Pc-4/Pr_4
ACC~ESSION NR: AP5002571 89676/64/038/012/2706/2799
AIMIOR: DabuEjh)dn, A.A.; Krylova, L.M.
TITLE: A sWdy of -ii~e-t~6~sit!6ii--oTwater-.~soluble-p4enol-forznaldcheereBin Iffir. on a
_7
soM base
SOVRCE: Zhurnal lizicheskoy khImfl, v. 38, no. 12, 1964, 2796-2799
TOP'IC TAGS: resin film, water soluble resin, film formation, infrared spectroscopy,
opt] cal density, phenol formaldehyde resin
ABSTRACT: A-stage water-soluhle phenol--formaldehyde resins, synthesized by Me
G1311-4 method, were deposited on polished sodium chloride plates or on mirror-brigbt
aluminum surfanes in an infrared spectroscopic analysis of the physical and chemical
pr(w,esses occurring during the formation of resin film. The authors present semi-
qualitative comparisons of the optical densities of the individual absorption bands.
Spoctral characteristics were also recorded for the various stages in the formation of a
film, ir, order to study processes accompanying the solidificatJon rjf a film. Dispersed
particle coagulation was noted at approxim2tely 100C. Coalescence resulting in the
fo3-mation of a i3olid film took place at about, 160C. Phenol alcoholn bond rapidly at 100C
Card 1/2
MMMOMWIMM film

L 43-179-65
ACCESSION NR: AP5002571
ani bridges of the -CH2-0-CH2-or - CH2-0-CH2-OCH2 - type form between the phenol
licks. Heating to 160C results in conversion of the latter type of bridges into the
fo:-mer, as well as incipient decomposition of -CH2-0-CH2- bridges related to the
fo-mation of clidnonomethides. Similar chemical conversions, the rates of which
were governed by temperature, were established for other temperature environments.
"The authors express their gratitude to 0. A. Koresheva for her assistance and to
S. 1~1, Mf~,qljqhpryp*rva, wbo familiarized &m with the techniques of synthesizing resins
of this type". Orig. art. has: I figure and I formula.
MSOCIATION: histitut fizicbeskoy khimti, Akademiya nauk SSSR (Physical chemistry.
institute, Academy of sciences, SSSR)
SUBMITTED: 08Ju163 ENCL: 00 SUB CODE- GC, MT
110 REF SOV: 004 OTHER: 000

MEMIKOV., A.K.; BAHUSHKIN, A.A.
Silicon surface-barrier alpha-detectors. Prib. i tekb, -~'