SCIENTIFIC ABSTRACT BAKHSHIYEV, N. G. - BAKHTADZE, I. D.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000103110015-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 6, 2000
• Sequence Number: 15
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

Ullivel-sal 5/o5l/62/012/005/003/021
L032/1';514
of phLhalamitle, tierivatives. The formula is Leotind to
be in
Lzood agre%!iaent with experiment. Pre'sent results
indicate that
the tiieovy given in the above paper is capable of
providing is
-;at',-;factol'y qW-111titiltive (1XVIallatioll of tile
expol-iment 1
a
d(!P('lldejlCe of t;lU Stokes shift ill tile fluorescent
spectra oil tile
nature of tile molvetit for a large group of aromatic
compounds.
There 4re 7 figures and 1 table.
SUBMITTED: March 23, 1961
Card 3/3

S/051/6U/012/005/007/021
9195/E485
AUTHORS, flit lihshiyev, N.G., Klochkov, V.11.*, Neporent,
U.S.,
TITLE: Absorption and fluorescence of' the vapourj4 of
anthracene and its derivatives
PERIODIC,%L: Optika i spektroskopiya, v.12, no-5,
1962, 582-585
TE.XT The absorption and fluorescence spectra, fluorescence
yields and oscillator strengths of anthracene (1) and six of
its
meso-derivatives were measured. The derivatives were:
9-methyl anthracene (IT), 9,10-dimethyl anthracene (III),
9-phenyl anthracene (IV), 9,10-diphenyl anthracene (V),
9-diacetyl-amino-anthraceno (VI) and
9-acetyl-aniino-anthracene.
The results show that the transition from anthracene to its
derivatives is accompanied by a spread in the absorption and
fluorescence spectra. This spread is more proaounced in aryl
derivatives than in Alkyls. the oscillator strengths of
molecules in vapours arc frequently larger than thoso of
molecules
in solutions. The oscillator strengths increase with increasing
temperature. At relatively low temperatures the oscillator
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S/051/62/012/005/007/021
Absorption and fluorescence E195/E485
strength in vapourn in nearly identical with that in solutions
at room temperature. The closeness of the oscillator strengths
of' 9,10-diphenyl anthracene molecules in vapours and solutions
suggests that the temperature has a small effect on the
absorption of this compound. Measurements of fluorescence
yields after excitation by mercury light (313 and 365 MU) are
given in Table 2. These data do not agree with those previously
obtained by B. Stevens (Trans. Farad. Soc., V-51, 1955, 610)4'
G.A.Kundzich and A.A.Shishlovskiy (DAN SSSR, V-97, 1954, 429).
This discrepancy requires further checking. ' There are
1 figure and 2 tables.
SUBMITTED:
April 8, 1961
Card 21t 2 ,

5/051/62/013/001/002/019
E039/E420
AUTHORS: Neporent, B.S., Bakhahiyev. N Go Lavrov, V,A.
Korotkov, S.M.
TITLE: The effect of medium on the properties of the
electronic spectra.of complex molecules during the
gradual transition from vapour to solution.
PERIODICALs Optika i spektroskopiya, V-13, no.1, 1962, 32-42
TEXT: The position and width of absorption and fluoroBc'ont
spectm
in 3-mothylaminophthalimide are examined with change in
concentration of ethor in the range from 0 to-58 x 1020
molecul g/cm3 during the transition from vapour to the liquid
phasol i.e. 220 --4 20'C. It is shown that all the spectral
characteristics investigatedchange monotonically with
concentration of other and that there is no sudden change during
the phase transition in the solvent. The results are fully
tabulated and are also shown graphically. The dielectric
constant changes from 1.0 at 220*C to 4.3 at 20*C whili the
Card 1/2

UMHM-i, E.G.
Universal molecular interactions and their effect on the
position
of electron apeotm of molecules in two-component solutions,
Part 53
Dependence of spectra on the electrio propertiesS dimensions,
and
structure of the molecules under study, Opt.i spektr. 13
no.1:43-
51 J1 162. (MIM 1527)
(Molecular spectra)

s/oci/62/013/002/001/014
E032/E514
AUTHOR: Bakhshiyav, N.Q.
TITLSt inti-a-ri'a-6-18cular interactions And their effect
on the position of the electronic spectra of molecules
in two-component solutions. VI. Dipole moments and the
structure of molecules of some derivatives of
phtlinlantide in the ground and firist excited o1actronle
states
PERIOPICAL.- Optilca -k aliektrookopiya, v.13, no.2, 1962, 192-199
TEM The re4jilts of previous papers (Ref.l: Opt. i sipektr.,
l0a 717, 1961; Ref.21 Xbid, 13, 43, 1962) are extended to the case
whdre the angle between the dipole moments of noreculos in the
8ropnd and excited states is not equal to zero or lc3O*. The
f0 r4ulas for the dina;e moments and the latter angle are then used
to-.4ompute numerical-Values for these quantities and to analyse
the-!structure of ninbodorivatives of phthalantade (3,6-diamino-
phthalamide, 3,6-tatratietliyldiatniiiophtlialartide,
3,6-diaccrtylamino-
phtiialan,lde, 3-dimethylamino-6-amitioplithalaatide,
3-aminophthalamide,
3-acetylantinophthalamide, 3-m 0thylaminophthalamide, 3-dimethyl-
alnilnl thalamide, 4-aminoplithalamide). Comparison of the
Card 22

Universal intermolecular'... S/051/62/013/002/001/014
E032/E514
experimental results obtnined.by the method t;uggested in Rof.2
with theoretical calculations showed that the spectroscopic study
of intermolecular interactions in solutions is a very sonsilivo
quantitative inethod which can be used to determine the nckt'.re of
those interactions and to obtain vuluable infornntion on che
electric and geometric, properties and the structure uf*..7.r-w
molecules
in the ground and excited states. The present and pr,%r.;--is
re5ults
obtained b.%~, the author are said to constitute convizi,-Lzig
evidence
that intardolecular interactions of the universal type are of
great, and in many cases prodontinant, importance in the description
of the effect of the solvent on the spectra. There are 3 figures
and 4 tables.
SUBMITTM MmY 30, 1961-
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S/04e/62/026/010/003/013
BIOI/BI86
AUTHORt
TITLEs Effect of solvents on the intensity and position of bands
in
electron spectra of mdlecules
PERIODICALi Akademiya. nauk SSSR. Izvestiya. Seriya.
fizicheskVa, v. 269
no. 10, 1962, 1237 - 1240
TEXTs Based an Western papers$ a short'survey is given of
results from re-
search on the effect of the medium on the spectrum. Reference is
made to
the author's papers (Izv. AN 353R, Ser. fiz. 22, 1387 0956)1
Optika i
spektroakopiya, 7, 52 (1959)1 ibid. 10, 71't 6961)) wherein two
types of
this effect are distinguishedi specific interaction caused by
formation
of H bonds, complexest etoof and universal interaction caused by
the 6ffect
of the solvent as a dielectric medium. The linear dependence of
%)max in tbo
-fluoreacenoo opectrum of 4-amino-N-methyl pbthalimVd6 on 6 and
n of the
solvent is quoted as an example from the paper by B.-S, Neporent
and the
author (Optika I. spektrookopiyal So 777 (1960)). The effect
which the re-
Card V2 I

3/048/62/026/010/003/013
Effect of solvents ... BIOI/B186
fractive index of benzene an4 heptane exerts on tho,a"boorption
spectrum of
3-dimethylamino-6-amino phthalimide dissolved therein, quoted
from the
author's dissertation (GOI,,L., 1959). There are 3 figures, The
most--
important English-lan g~Le references aret N Bayliss, E. MoRa
Chem., 58, 1002 (1958r, Y. 06shika, J. Phys, ;oo, Jaiant 9,
594;Iij9;4P)hIye
N. Mataga, Y. Raitu, M. Koiitimiq Bull. Chem. Soo. Japanj 299 46
(1956)1 E.
McRae, J. Phyd. Chem., 61, 562 (1957).
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S/020/62/145/605/006/020
B104/B102
AUTHORS: Bakhahiyev, N. G.t Girint 0. P., and Libovt V. S.
TITLE; Relations between observed and true absorption spectra in
a condensed medium
PERIODICAL: Akademiya nauk SSSR. Dokladyt v. 145, no- 5, 1962t
1025-1027
TEXT: -Inventigation of the relation between the molecular
absorption
coefficient E(V) of a substance (or the coefficient K(u) in
Bouguerle
law) and the Einstein absorption coefficient B(u) leads to
') I a (V) C
B (V _ 8 (v) n(v) c Ec,, (v)M
hV E74;-(v)
where n(v) is the refraction coefficient of the medium, E~p the
mean macro-
scopic field of the lightwaves in the dielectriog Eq~ the effective
micro-
field of the lightwaves, j(V) an arbitrary function. From this
equation
it was concluded that the spectral courne of the experimentally
determined
quantity E(v) of a condensed medium does not agree-with the true
spectral
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-a/020/62/145/005/006/020
Relations between observed and... 11104/11102
characteristics of B(V).of the absorbing center. Hence to determine
the
true spectrum of B(V) of the aboorbinp particles in vurious media
the
experimentally determined spectra need correction taking account of
the
effective internal field. It is sho"n that the observed and the true
absorption spectra of particles in a condensed system do no~ agree
as
regards position, Intensity, or shape.
PRESENTED: April 3, 1962, by A. N. Terenin, Academician
SUBMITTED: March 27, 1962
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S/051/63/014/004/005/026
E039/E420
AUT11011s: Ilaklishiyev, N.G., Girin, O.P., Libov, V.S.
TITLEi The relation between the observed avid true absorption
spectra of molecules in a solid medium. 1. Univerani
influence of the effective (internal) field
PERIODICAL: Optika i spoktras)(opiya, v.14, no.4, 1963, 476-483
TEXT: A more precise understanding of the dependence of the
experimental values of absorption coofticient KOO on frequency V
is of major importance in spectroscopy. The true absorption
Apectrum of molecules follows the form calculated front the Einstein
coefriciont of absorption W A, but whon the investigated
mol-cculen are in a solid body the observed spectrunn K(V) avid true
spectrum W,)) can differ in positJon, intensity and shape of
bonds. This difference line negligible dependencc on the universal
effect which is connected with the change in intensity of the light.
waves acting on the molecules in a (4olectric (the effective or
internal field) and dotermines the form of the frequency dependence.
A simple theory is constructed which accomplishes the transition
from experimental to true spectra by the calculation of o co-riplex
tensor parameter of the effective field, which completely determine&
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S/051/63/014/004/005/026
The relation between ... C039/8420
the value and spectral path of the correction. The theory is
based on the relation between quantum and classical parameters
characterized by absorption on the one hand and experimental values
on the other. This enables the relation between values of K(\))
anti B(,)) to be determined for the case of anisotropically
--polarixed unolecules and f6r--isotropically absorbing media
(liquid.
solutions, amorphous solids). A now and more accurate oxprossion
is obtained for determining the integral of the intensity of
absorption bands from experimental data.
SUBMITTED: August 20, 1962
Card 2/2

L 11162~kl MP(J)/W (I )IFW(p )/BTkq --A
ACCESS10N KH: AF3002782 S/0051/63/014/006/0745/0750 0
AUTHOR: BakhWjj=j, N, Gk; GArkj_2. P.; Libov. V* S.
TITIZ: Relation between the observed and true absorptionspeetra of
molecules in
a condensed mediums 3. Taking into account the influence of the
effective
(internal) field according to the Lorentz and Onsager-Doettcher
models.
SOURCE: Optika i spektrookopiya, v. 14, no@. 6v 1963, 745-750
TOPIC TAGS: molecular absorption# true spectra# Onsager-Boetteher
model, Lorentz
model
ABSTRACT: Ths.present work is conoerned with the problem of
determining the rela-
tion between the observed and true absorption spectra of molecules
in a condensed
medlux in the framework of the Lorents and Onsager-Boettcher
models for the mnle-
cule plus medium (solvent) system),, In earlier papers (Optika i
spektro., 14, 28,
1963 and Doklady AN SSSRk 14% 102!;,, 1962) the authors derived a
general equation
for the true absorption spectrum in terns of the observed
spectrum, the correction
for the universal influence of the effective (internal) field, the
components of
the tensor of the effectiv* field lArameter, and the direction
cosines of the
dipole moment of the transitions In the present paperp specific
but generally
applicable calculations are perfonied for the case of
isotropically polarizing
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..............

L 12162-63
ACCESSION NR: AP3002782
absorbing-moleculoso-It is shown that.-dopending on the-properties o
-fthe w 1s-
cule and modium, there may ocaur different phenomena which W distort
the' tylue
spectrum: shift the bands and alter their intensity and shapeo Tho
specific case
of the absorption in the region of the f1mdamental frequency of a
hypothetical
liquid molecule is examined and the 4ffe!:t of corrections of the
efftotive field
according to the Lorentz-and Oneager-BoeLtcher thecries is shown. It
is pridicted
that appreciable changes may be expepted in the electronic spectra of
strongly
absorbing oubstances, such as,41es.1121t is pointed out that failure
to alloit for
the distorting offsets of various faetoi-a may lead to serious errors
in int,erprot-
ing experimental spectra. The authors plan to discuss the properties
of same
t Orig. art. has: 26
particular substances and systems in fuure contributions.
formulas and 2 figures
A&IJOCIATIM None
SUBHr= 20AU662 DATS ACQDt 15Jul63 ENCL: 00
SUB CODEt 00 NO REF SOVI 005 OTHER: OW;
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L 10161:L3.
WW/W
ACMION IM: _030603-13 V)/0040/63/02T/005/0623/1)16
-'% -I ,171T
AIMM PI!Eskiwa I. V.; B*h~Myeyp: 11. 0.
_j
TMX: Qwmtltative Investightion of Vie tememture dependence of the
absorption and fluoresew.,ce spe*tM of qavlex 'molecules (Report;
xievew!_
CoOerence on Luminescence held In Xinalt 10-15 Sept, 19621
SOURM: Izvestlya AN SSSR, - Serlys, fixicheakayup -r* 2T noo 5s i963
-62T
1523
TOPIC TAGS: aboorptIon-of molecuUsp. fluorescence of molecules.,
aminophthallaidesp nolecular Interacti(kh
ABSTRkCT*.----IA-*n earlier- paW-we of-tlie-euthorllp
-B&khshIy)ev._N._G.__(Opt.'
-717#- i96i)-prqpsed a siqile-but general-theory describing Use-
Influence on the electronic spectra of wlecules In liquid
two-componerit
solutions of - universal Intermlecular :~&teractlonz of- the
orientation, - WIuctiort,,
dispersion and dMuixiic types.- - The key equation chars terizes the
f~*queww -
shift in going from vapor to solution :*a a function of the
dielectric constant.,
1ndex of refraction wA other parawters of the emitting and solvent
noleculeso -
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---------- -* ------ ---------------- -------- -------------------

L ioift-63
ACCESSION NH: AP3000313
The present work Is devoted to appliention of the Bakhahlyev theory
to
interpretation of experimental results as regax-da tenperature
dependent
frequency shifts. jetve=gated compounds were 4-amino, 3-amino amd
3 r
3,6-aminophtalimide_01 in be=ene, etkW1 acetate and isoanV1 alchol.
.0
f
The absorption and f orescence spectra were recorded at tenperatures
from
20 to 250-35VC on a modified SF-4 spectrophotometer (absorption) and
a
photoelectrIc spectrometer* The axperimental data are presented in
the form
of curves and tables, While a detailed d1scussion of the
e.Verimental results
will be published elsewhere., It In pointed out that In the case caf
mDno- and
dimlne pk,,UalWde derivatives the effect of temperature an the
absorption
and fluorescence spectra is quantitatively predicted by the
Bakhohlyev theory.,
which indicates that univermd intermolecular intwactions play a
decisive role
in the tenperature behavior of the spectm of the investigated
cocpounds, in
solutions, Orig, art, W: 3 eqmUous 2 fiWes and 2 tables.
ASSOCIATION: none
SUBLITM. 00 DATE ACQ: 12JUD63 ENCL: 00
SM ~~ E NR MW SOV: 017 arm: 006
Cord

11 9~52_63 nM(l )A-W.(v)1H1)_S--AFM-1A`D1&5D- 3-1JP(G)
ACCWSION NR: AP3WO580 S/0051/63/014/OC,5/0634/0638
AMHOR: DakhshiYeY,_N,_,_G,i QIrIng o-, P.; Libov, V. S, 7-
TITLE: Relation between the observed and trre abaorPtion spectra of
molec-jles-~\
in the conden&ed state. 2. Method of determining the correction for
the
universal influence of the effective (internal) field
SaME: Optika I spektroskopiya, v. 14, no- 5, 1963, 634-638
TOPIU TAGS: absorption spectra,, Internal fields
ABSTRACT: In earlier cont--ibutions by the authors (Doklady AN SWR,
145, 1025,
1962; Opt. I spektr., 14, 25, 1963) it was pointed out that the true
absorption
spectrum of molecules is the freTtiency variation of the Einstein
absorption
coefficient B, and then when the molecule is in a condensed state
the observed
spectrum, characterized by the usual coefficient K, differs from the
true
spectrum,. Accordingly in the presmmt paper-there am diaveloped
methods for
determining the nz&iitude and frequency dependence of the conxction
to that
observed spectrum due to the unIversal influence of the effective
(internal)
field of the molecule, It is demonstrated that the requisite
relationships
Cord 1/2

L 9852-63
ACCE=ON NR; AP3wV%O 0
betvenn the optical charwteristics of an isotropic absorbing madium
and the
microscopic characteristics of the absorbing molecule (the
polarizability and
effective field tensore) can be found in several ways, two of vhich
are considered
in some det&il. The first Is base-4 on use of the general expression
for
polari7ation of art absorbing dielectric; thn second consists in
seeking the
relation bet-ween the quantum Ywchanical and classical quantities
characterizing
pressions for
the absorptive capacity of the wlecule in a condensed medium, Ex
determWna the effective field and otber parwwters of molecules in
different
media from- experimental data-are-adduced. orig. art. has: 23
equativas.
ASSWIATION: none
SUNUMD: 2OAug62 DATE ACQ.- 12Jun63 ENCL: 00
SUB COM PH Na JMF SDV: 005 OTHO 002
Card 2/2
.............. ................. ............... ....

8/053/65/079/002/002/004
B102/Bi86
AUTHORSs Oirint 0,, Po I and Bakhqhiy*i,--N. 0.'
TITLEt Tht effect of the solvent on the position and intensity
of
the bands In infrared moleoule spq9tra
PERIODICkLi Uspekhi fizioh*skikh naukp ve 79, no. 2. 19650 2~5.
262
TEM The present artiolo CivIso an Inoomplete-roview of the
litsp~ture Of
recent years and a critical diequesion of 'the most important,
papers.
dealing with the dolvent,offecte,on the IR band spootrao'
Spooial Otton-
tion is paid to possibilities of generalisation and to the
theoretical
difficulties that arias in a proper desori'Ption'of the
interaotion* There
are 14 figures, 2 tables$ and 125 references.*
dard i/i

1, 12814-63 :Imp( )/EMCj/'ECL(r_~/8DS F~ P RY,/WW 63
AP3002214 N1-N)/150/006/L02%/1259
AM"HOR: Bakhohl'yev. X. G.; Girin, 0. P4.; Lib,-.r. V. S.
6bd eel
Tn= ---- Aplarelat and true- Omorption- opectra -of-Uquid MC!~-
4-JA-the
740-810 cm- range
SOME- All SSSR. Doklad3r*, v. 150, no. 6, 1963,, 1P56-1259
TO)'XC TAGS-. absorption spectra, CHC13, CC14, abcorption coefficient
MIMLACV: The authors presented in a previous paper (DAN, A51 1962,
1025
thl? relrttionohip between the observed nolecular absorption
coefficients and '.he
trie (Einstein I a) toeff icients Vnich are detervirtnedd by the
internal -properti es-
of the molecule. The corre-eAl.ot factor is given by the changes of
the ele0jric-,.
.-field of -the liE;ht wave caused by the medimn. In t1he present,
work this
correction in urma Tor_dbt-&[hM- the rmd evzorptlon
c-0effitient"f-t-h-a
opectrtm which correspond3 to the fundenental vibration of C-01. The
abcorntion
SPectm-1 01 MICI anl CC14 In both the liquid and gaseous state were
experimentalIN'
tained and torrected accor&ing to the mentioned foi=ulas.
*Card 1/2

L 128j41-0
AMSSION NR: Ar3OOnl9
The obsen-ed and the corrected spectra absorption coefficients exe
given i:l two
figu.res. The regults confirm the conclusions of the quoted paper
that ti-c
observed absorption spectra differ greatly from the true ones. This
report van
presented by Academician A. V. Terenin, 18 Jan 63. Orig. art. has-,
3 formulas,-'-
2 figure,
ASSOCUTTOR: none
SMH=ED: o4jan6v, r.ATE ACq- 24,TV163 r' NGL: 00
SUB CODE: M, EL NO RE? SOV- 002 om-R: oO4
Cotd 2/p-

BAKHS11EVJI N.G.
-
Now apnotrosoopic method for studying the anisotropy
of electron
transitions in polar molecules. Dokl, AN SS9R 152
no.32577-580
S 163, (MIRA 16t12)
1. Prodstavleno akademikom A.N.Toreninym.

LIBOV)4V*Sq;-PAKHSHIYEVO N.G.
Quantitative study of the absorption and dispersion
of CHI"? and
OC14 in the region of strong infrared absorption
bands.OP . i
spektr. 16 no.2o223-227 F 164. (MIRA 17W

BAKHSHIYEV, N.G.; NEFORENT, B.S.
Further on universal and specific interactions
"universal" solvent scales (in connection with
V.P.Kolobkov's article). Opt. i spektr. 16
164.
in solutions and
V.V.Zelinakii and
no.2051-359 F
(MIRA 17W
9,

M. KI;S!IIyi-;V, 14.G.
Universal molecular interacti~r,.,,, tu-.cir e0i,'oc,~
~jri !Ir! 110aition
of electron spectra of mclocul,:,-, in two-,~,.mq on-znt.
soluztlorij. I~art
7. Opt. i spektr. 10 no.5:8,'I-!i3l~ :,Y 1,01:9)

1.11.10vt V.6.; 11 ~ i, ii -'~j 111 ~j . (, . ; ( j
' ; ~' T ,' , ~, . 1'.
Folation between the obaeri~-(' tirici tr-,if,-
opectra In a condonsed medJim. )'!~-.t 14. OpL. I
spchtr. 16
rio.0:1016-10.>3 Jo IN,. (MjrtA 17S9)

Wr L 1-157 EN, I lip(c)
FAcd-wkl AR6031872 SOURCE CODE: UR/0058/66/000/006/DO92/DO92
AUTHOR.; Allipeavich. I, BakhshjXjX,- 1j, -.G. ; Korovina. V. M.
TITLE: Optical constants of diluted solutions of complex molecules
SOURCE: Ref. zh. Fizika, Abe. 6D752
REF SOURCE: Sb. optich. tooled. molekulyarn. dvizheniya t
mezhmolekulyarn.
vzaimodeystv. v. zhidkostyakh i rastvorakh. Tashkent, Nauka, 1965,
187-205
TOPIC TAGS: optic constant, complex molecule, absorption line
ABSTRACT: The differences of refraction indices of a solution W and
solvent
in a field of ^-s 600-200 m," have been measured for diluted
solutions of
n- nitrosodim ethy) aniline in Ccl
4 4), rhodamine in water 41), crystal violet in
water (111), and malachite green in water (IV). The values of
[(n-n)max-(n--fi)min
x 105 are: 1-3. 8, 11-5. 9, 111-7. 7, and IV-4. 7. The calculations
by equations
of the Davidov theory,'is in good agreement with the experiment.
Experimental and
i calculated absorption lines and dispersion curves of solutions are
presented.
E. Broun. [Translation of abstract]
SUB COM 20/
card 1/1

L 148374A HWT(1) UP(c) AT
-ACC 'NR: AP50,25298 SOURCE 0DDg3__'_ UR10631/65/019/004/0535/0143--
AUTHORx DA shijay. 1. 0.
ORGt None
TITLE: Universal intermolecular interactions and their influence on
the position
Of electron spectra *I molecules in two-component solutions. Part
9t Anisotropy
of redistribution of electron density in polar organic molecules-
during optical
excitation ILI% 414N 75-
SOURCZ: Qptika I spektroakopiya, v. 19, fio. 4, 1965, 333-543
TOPIC TAGSI molecular Interaction, dipole moment, electron
spectrum, electron.
density, phthatimide. malaimi4a, molecular spectrim
ABSTRACT: On the basis of experimental data obtained earlier, the
magnitude and
absolute orientation of vector AAt (which is equal to the vector
difference
A40 - N89, 140 being the dipole moment of the molecule in the
excited state and
A 8 being the dipole moment In the ground state) were determined
relative to the
skeleton of the molecule for a group of phthalimide derivativet.
Vector A4
characterizes the arzisotropy of redistiribution of the electron
density during an
optical transition, and provides an indirect indication of the
direction in which
-Card-1/2 _-UNt-539.1.196.3

L 14637-66
ACC NR: AP5025298
the electron cloud of the molecule is shifted during the excitation
process. The
data obtained on the electronic structure and spectroscopic
properties of phthsli-
aide and maleimide derivatives are in accord with many earlier
investigations of
compounds of this class, performd by.other authors. It in concluded
that
spectroscopic method* based on a quantitative stu,ly of'tbe effect of
Intramolecu-
lar interactions on molecular spectra provide valuable information on
the proptr-
ties of excited states of molecules and their electronic
configuration, and also
on the nature of the corresponding energy transitions. Author to
grateful to
Yi Z. Ch. Grabovskiz for a discussion of sore probleas dealt with in
the article
and for useful comments. Orig. art. has: 6 figures, 4 tables, and 4
formula*.
SUB ODDEt 20 SUSH DAM Muhi4 -ORIG REFt 013
Card 21

L 36431-66 -PW(WWTW/WT* :W-(c)
Ap6oi542o SOURCS CODNI UR/0031/66/020/003/0783/070
AUTHORS BakhahkTvj N. 0.1 Piterskayap I* Ve
OROS
TITM Universal intermolIg nterAstions nd their effect on the
position of
:lectron spectra iff mmolecules n-1wo-'oomponent solutionse Part
121 Dependonce of ab-
orption and fluorescence spectra ofjkthalimIdIlderivatives on
tenerature sad the
state of aggregation of the solvent (+20 to -1960Q -
SOURCES 'Optika i spektroskoplyaq Y. 209 no. 5t 19"t 783-?92
TOPIC TAGS1 absorption spectrum, fluorescence spectrums, electron
spectrump molecular
interaction
ABSTRACT: Using the concept of the important part played by
universal molecular in-
teractions In the phenomenon of spectral shifts in solutions for
my relative values
of T; (time of orientational relaxation of the molecules of the
medium) and T#
(time spent by the molecule studied in the el*otronio state)p the
authors InvestigaW
the absorption and fluorescence spectra of a series of organic
molecules in solutions
between +20 and -1966C. This temperature range was chosen because
any relative valuel
Of 1r; and rf (from 'r,'. 4C ?,-0 to t" >> 10 ) can be obtained in
its The oompounds
studied (4-aminot 3-aminot 3-mnomethylanino-9 3-aoetylaminov
3.6-diaminot 396-t*tra-
methy1dikmino-9 and 3~6-diaootylaminophthalimide) had oontimous
fluorescence and ab-
UDCt

1 3&31-66
ACC NR% AP6015420 0
sorption spectra,, and the solvents used were isobutylq butyl and
propyl, Alcoholp and
glycerin. The results show that the important role of universal
intermolecular inter-
actions in the temperature shifts of electron spectra of
molecules in solvents in con-
firmed In the low-temperaturs r&M as well. It is concluded that
the theory (N, 0,
Bikkhahiyevo Opt. i spektr.t 169 821t 1964) permits a
satisfactory description of the
influena6 of temperature and state of aggregation on the position
of electron spectra
of molecules in a temperature range reaching 430-3WOC. Origs arts
has$ 3 figurest
3 tables# and 2 formulass
,.20/
SUB CODRI ON SMM DMI 0214b65/ WM RVa 034/ OM MWI 007
Card 2/2

ACC - NRs 06018439 SOURCE CODE: UR/0051/66/020/006/0976/0981
AUTHOR-. Bakhahivev, N. G.
ORG: none
TITLE: Multiple intermolecui~ar interactions and their effect on the
electron spectra
position of molecules in binary solutions. X111. The physicochemical
properties of
some molecular complexes
SOURCE. Optika. i spektroskopiya, v, 20, no. 6, 1966, 976-981
TOPIC TAGSt intermolecular complex, electron donor, excited state,
electron spectrum
ABSTRACT% A spectroscopic method of determining some electrical and
geometrical cha-
racteristics and physicochemical parameters of molecules is analyzed.
The method is
based on a quantitative investigation of the effect of intermolecular
interactions on
their electrW$Rectra. The following two complexes were examined: a
complex of 1-~
-ethyl-4-carbomethoxypyridine with iodine (ComrwlexAl), and a complex
of hexamethyl-
benzene with tatrachlorophthalic anhydride (CompleA II). Ccmplex I
was investigated
with a number of solvents of different chemical composition. It
appears that its low
intensity broad band in extremely sensitive to intermolecular
interactions, in the
transition from a pyridine to an aqueous solution, it shifts into a
short wave range
by more than 10,000 cm 1. An evaluation of the dipole moment revealed
that in the
UDCt 539.196.3

L 01341.11-67
_X_ - - -
CC N ka AROiMg
formation of Complex 1, a complete electron transfer from the
aromatic molecule to io-
dine takes place; this transfer is followed by a transformation of
the interacting
particles into an ion pair. Complex II is of the w-donor-acceptor
type, formed by in-
teraction of i-electron clouds of molecules. After experimentation
with 9 different
solvental previously reached conclusions as to the electron
structure of Complex II in
both principal and excited states were confirmed. The spectrosc?
,pic method can be
successfully used for the detemination of a number of microscopic
characteristics of
molecular complexes. Orig. art. hast 4 figures, 2 tables, 3 fomulaa.
SUB CODE:07,20/ SUBM DATE: 02Feb65/
ORIG REF: 010/ OTH REF: 004
2/2

EFENDIYEV, F. A.,, prof.; ABDULIAMp M. M.; BAKIISHIYEVA,
Ye. B. (deceaBed]
Qangee in blood coagulation factors and fibrinolytic
activity in
leucoBes. Probl. gemat. i perel. krovi no.10:19-28 161.
(MIRA 14112)
1. Is Azerbayfthanskogo nauchno-iseledovatellskogo
instituta
gematologii i perelivaniya krovi (dir. - dotsent G. A.
GuBeynov)
I fakulltetakoy khrurgicheekoy kliniki (dirs - prof* Fs
As
Efendiyev) Aserbaydabanskogo gosudaretvennogo
raeditsinBkogo instituta.
(USUCOSIS) (BLOOD-COAGUIATION) (FIBRINOLYSIS)

, L 4, 1 ~ - f 7-rp 1 1 1-/I T -J~ 1 -(C , J D/ j G.
L
ACC NR, AJ~015441 SaJRCE CODES UR/0031/66/020/005/0918/0920
AUTHORS B&khshU3%A&j0,&,?.; Karapetyang V, 19,; Morozovp A. M.
two-
Offit none
4_.characteristice of lsnthgn~ sodium molybdate single crystals
TITM Opt~o
17 1
SOURCES Optika i Mmktroskoptyaq v* 20, no. 5v 19661 918-920
TOPIC TAWS molybdatep lanthanum corpoundt sodium compoundp
refractive indexo
optic property
ABSTRACTS IALrge single crystals of I&N&(MoC4)2 whose C axis was
parallel to the axis
of growth wore grown on a seed by pulling from the melt# and their
absorption Spectra
&M refractive indices were measured. Tho absorption spectrum of an
L&N&(MoC4)2 cry-
stal taken with SF-4 and IKS-14 spectrophotometera is shown in the
figure. It is no-
ted that the absorption spectra are typical of all crystals having
a scheelite Btruo-
ture. Refractive Index measurements showed that the light ray is
"fractionated" on
passing through an Wa(MD002 prismp apparently because the lattice
of this binarY
molybdate is highly disordered ~+ This factor is also thought to
cause the relatively
broad luminesoence lines of Nd in I&Na(MoO#)2 and the broad ESR
lines of this com-
pound reported by other authors* Authors express their deep
appreciation to A, I.
Stozharov and P. P. Foofilov for their steady interest and helpful.
disoussioii~-siq AM
UDC1 535-321 + 535-34115W.0

-L 3441&~~6----
,;~_CC__,NR_, AP6015441
te Yo. M. Sychey and I. A* Shubs for assistanoe in the work.
Orig. art. has$ I fig-
urs and I tables I
a
3UB CODSI 201 SUBK DATZI 160st65/ ORM FdWI 003/ OTH R371 006

j n A, --I- -.-

- (16 riL X )) ;g- ) 1 1 7 'J'_ I e / - ~4' d- -
USSR/Organia Chemistry. Synthetic Organic Chemistry. E-2
Abs Jour iR*f Zhur - Khimiya, No. 8, 19570 26681.
Author :. AbdulAyev, G,K,; Bakhshizado, A.A.
Inst if Az orb&
Title iAnalysis,of Booondary Products of Direct
Hydration of Ethylene,
Orig Pub tElmi eserler, Azerb. univ. Uch. zap. Azorb.
un-tail 1956, No. 10, 25 - i0.
Abstract aIt was established that the secondary pro-
ducts of the direct hydration of CH2=CH2
in presence of phosphate catalysts contained
46,~% of olefins, of wMah there was 7'3%
of dione hydrocarbons, 27-13% of paraflins,
J% of which having been allfatic alcohols
the fraction 2,2-dimsth~lbutanol was 3epara-
te1d), 19.9% of naphthenes and 6.77% of aro-
matics. The fractions 2-mothyl-pentans,
Card 1/2

BAXHSHI,ZAIM, A,A.; SMIDOV, R.I.
Liquid-phase oxidation of wi-xylene and p-xylene. Uch, sap.
AGU
ho.1:61-64 156. (XITd 12: 1)
(41ens)

SAIDOV. N.M.; BAK HI-ZAA, A.A.; MCMUNIT. S.D.
Liquid phase oxidation of xylaue isomers bjr
atmapheric oxygen@
Aserbekhim.shuro no.lt23;2 159. (MM 13:6)
(kiene) (Oxidatl n~

MKHTIUVp S.D. j BAYJiOHI-ZADR, A#A.; Si;IWV,, N.14.
Photochemical oxidation of xylene isomers [in
Azerbaijani with
OVM=Y in Russian). Azerb. khIM.Shur. no,419-14 159.
(KM 14%9)
(lylerle) (Ultraviolet rays)

3/o81/61/000/002/023/023
AOO5/A1Ol
Translation from: Referativnyy zhurnal, Khimiya, 1961, No. 2,
p. 608, # 2RI09
AVMORS i Bunlyat-zad*, A. A., Pialman, 1. 1., Brikffishi-zade,
A. A.
TITLE: The Copolymerization of Olefines. Report I. The
Copolymerization
of Ethylene With Propylene
PERIODICAL: Uch. zap. Azerb. un-t. Fiz.-matem. i khim. ser.,
1959, No. 4,
pp. 77-80 (Azerb. summary)
TEXT: The authors studied the polymerization of
ethylene-propylene mix-
tures containing 13-15% by volume of propylene, on a chromic
catalyst in the
presence of a solvent (benzing "galosha"). The optimum
temperature for the
studied conditions is 100-110 C, the optimum pressure lies
within the range of
30-35 atm. The data in literature are corroborated: the
molecular weight of
the polymer decreases with increasing temperature and
increases with increasing
pressure.
Author's summary
Translatorts note: This is the full translation of the
original Russian abstract.
Card 1/1

BAIHSHI-ZADX, A.A.; SJUDOT, N.M.; SMIIUIOVA, N.A.
Separation of x7lene Isomers by the alkylation method. Aserb. neft.
khos. 38 no, :37-38 S 159. (MIRA 13:2)
7xylsue) (Alkylation)

MKHTIYEV-,- S-.D.-,-I- BA)KaFiSH------7-A-Dg-- -
, A.A.j MKHTIYEV, S.I.
Synthesis of glycerol by the direct hydroxylation of
allyl,
alcohol by hydrogen peroxide. Aserb.khim.shur,
no,5147-58 161,
(KM 1515)
(Glycerol) (Allyl alcohol) (Wrogen pamcide)

833,33

S/02 60/133/005/010/019
Y

B016
B060

AUTHORS:
Dalin. M. A., Academician AS

AzerbSSR, Pialman, 1.
1.,

RA"M-7nde -A.
A.. Buniyat
-Zade, A. A.

l
l
J
TITLE:
-GoDo1-ymerization
of ELhZlene
and
With Propyle

a- utylenelon Chromium Oxide

Catalyst
PERIODICAL:
Doklady Akademii
nauk SSSR,
1960, Vol. 133, No- 5,

pp. 1084-1085

TEXT: The authors wanted to carry out the synthesis uentioned
in the
title and to study more thoroughly the properties of the
substances
mentioned. The first results of their investigations are
supplied in the
precent paper. For their experiments the authors made use of
Vishnevskiy's
mixer (Ref. 3). The solvent used was extraction benzine
purified by
activated chromium catalyst. The catalyst was prepared by the
well-known
method of Ref- 4. The ethylene- and propylene fractions of
pyrogas were
used as monomers. The butylenee were produced by dehydration
of n-butyl
alcohol upon aluminum oxide of the type A-1 (A-1) at 3600C.
The mixture
Card 1/3

83133
Copolymerization of Ethylene With S/020/60/i53/005/010/019
Propylene and a-Butylene on Chromium B016/B06O
Oxide Catalyst
contained 2 - 3% of isobutylene and 97 - 98% of normal
butylenes. The
butylene fraction was dehydrated on fine-porouB silica gel and
calcium
hydride during production. The gan mixtures wore prepared in
carefully
dried metal balloons. After the pressure drop had stopped the
autoclave
was allowed to cool and pressure was reduced. The copolymer
taken from
the autoclave was heated together with the catalyst in a vessel
with
ligroin, and was subsequently filtered off the catalyst on a
paper filter.
The polymer was then washed with ethanol, dried, and analyzed.
Table 1
shows the properties of polyethylene, which constitutes a
copolymer of
ethylene with propylene. It contains (in by weight): propylene
12.6.
ethylene 67.4, and ethylene-a-butylene copolymer (7~v' of
butylene and
93A of ethylene). As can be seen from Table 1. the copolymers of
ethylene with propylene and with a-butylene differ from
polyethylene
with respect to melting temperaturue, solubility in n-heptane,
and
specific elongation In cold drawing. The greater flexibility is
striking
but so is also a lesser strength of the ethylene-propylene
copolymer an
compared with polyethylene. The ethylene-a-butylene copolymer
comes near
Card 2/3

83133
Copolymerization of Ethylene With S/020/60/133/005/010/019
Propylene and a-Butylene on Chromium Bo16/Bo6o
Oxide Catalyst
polyethylene as to strength but surpasses it as to elasticity.
There are
1 table and 5 references: 2 Soviet, I US, I Belgian, and I
Italian.
SUBMITTED: February 5, 1960
IV
Card 3/3

HMTIYEV,, SGD.j BAKHSHI-ZADEj A,A.; WMTIYEV, Me
0---
Synthesis of diatomic alcohole by the hydrOX71&tiOn Of Olefim
with hydrogen peroxide* Amb.khim.shur. no*603-38 160,
(KCRA 108)
(Alcohols) (Olefins) (Hydrogen peroxides

IL wu
-n-(.

S/081,/62/000/004/006/087
B102/B101
LUMORS i Dalin# M. A., Shenderoval H. I., Pialman, I. I., Bakhahi-
jq,~~ Vedeneyeva, L. Ya., Buniyat-zade,
TITLEt Synthesis of polyethylene and of copolymers of ethylene with
propylene and.a-butylene on an chromium~o 'xide catalyst
n'y,y* zh~rnal 4
PERIODICIL& Referativ ^L 1~ Khimiya, "%: 1 1962, 66~g.abstrAqt_v-,
0126 (Azerb. khim. zh.j no. 1, iq6i, 17 - 22)
TLXTi Purification of dhylene (1) was carried out on a pilot-plant
scale
allowing for an increase in efficiency of the oxide-chromium oxide
catalyst (COC) up to 176 - 250 9/9 when I is polymerized in
extraction
benzine purified with sulfuric-acid, or in oyclohoxano (120 -
1~011cj
3 - 5 hrop 45 at, COC oonoentration (1.13 - 0.25~;)- When ethylene
is co-
polymerized with propylene (11) (6-7 - I5A by volume) (110 - 1200C,
40 at)
in benzine in the presence of an CaG2 activator (M~ of the
catalyst's
weight), the offioiency of the COC is reduced to 68 - 135 g/g owing
to the
lower reactiyity of Il and to its incomplete purification. The
copolymer
..Card 1/2

S/08 62/000/004/086/087
Synthesis of polyethylene and... B102YZ101
(CP) differs from the polymer of I by its lofti'#crystallinity. The
con-
tent of crystal lljnq*,~pae dyoreases with :Lricreasing
polymerization
temperature and incr4a'see h '`p'KV a uve 01OPS melPt. -point in OC,
npture atrelig 1~ n, kg/cm an, . volubility in
relative elongation in,~ t 2
n-hoptane are enume~:Ueal I it)s ;6. 130 IM o~','V 6oo j z6o~ + 3ao
10 - 15;
CP of I with 11, 122 - 126 726 10~0, 17b ~20, 6Q -'70;'CP of I with
a-butylene (2-5 - 4.5 vol%i, 125 127, 500 600o 250 - 3001 30 - 40-
[A.betracteris notet. Complete tianslat ionj.,
Card 2/2

DALIN, M.A.; BaIISHI-ZADE, A.A.; PIL'MAN, I.I.; BUNIYAT-ZADE, A.A.
Some propertie3 of the coplymer of ethylene v-ltb propylens,
Azerb.khim.zhur. no.1:2,1-29 '(0. (MIRA 34:9)
(Ethylene) (Propenp)

8/061/62/000/006/045/117
BiOl/BliO
AUTHORSs Buniyat-zadej A. A., Belkinst A. U.9 Bakhah-i-sadej,Aa
IA
Petukhova, L. X.
TITLEs Destructive alkylation of toluene by means of pentane
PERIODICALt Referativnyy zhurnal. Khimiyat no. 6, 1962, 199,
abstract
6Zh114 (Uch, zap. Azerb. un-t. Ser. fiz.-matem. i khim. n-,
no. 1, 1960# 91 - 95)
TEXTs Destructive alkylation of toluene by means of n-pentane
over a
synthetic aluminosilioate catalyst was studied. The effect
of.temperatae,
pressuro, and the volume rate on the reaction was investigated.
The
experiments were made by a method described earlier (RZhKhim,
1957, no- iN
45505)- It has been found that the main products of the
reaction are
aromatic compounds and a fraction boiling out at 125 - 450C,
n20 1-4970, d 20 0.8650. Raman scattering showed that this
fraction con-
D, 4
siste of 27 % n-, 47 % m-, 12 % o-xylene, and 14 % ethyl
benzene. Oxida-'
tion of this'fraotion by means of MO 4 in alkaline medium
yields 87-7 %
Card 1/2

3/081162/ooe/006/045/ii7
Destructive alkylation of ... B101/B110
0 20 20
phthalio aoide. The fractions with b. 145 - 200 C, n 1-5010, d
0-8704o'
20 20 D 4
and with b.> 2000C, n 1-5390, d 0.899, consist of methyl ethyl-l
D 4
methyl isopropyl-, methyl isobutyl benzene, and other aromatic
compounds.
It has been found that at 350 - 4500C the components of the
reaction
0
remain practically unchanged. At 450, 475t and 500 C, the total
yield in'
catalyzate with b.> 1250C suddenly increases reaching 11-5v 12,
and 17-41k,
respectively. A temperature increase up to 5200C has no
noticeable effect
on the course of reaction. If the volume rate is reduced from
0.5 to 013
and 0.1 volumes of raw material per unit volume of the catalyst
and per
ho.ur, the yield in produotsboiling out above 12500 increases
to 21.6 and
27.6 ~, respectively. If pressure is reduced from 40 to 20 atm
the yield
decreases by more than 2/3, and an increase in pressure up to
60 ats
affects the reaction course only slightly. The gases ariging in
the
course of the reaction consist mainly of saturated hydrocarbons
and
hydrogen. (Abstracter's notes Complete tr&nslat ion.3
Card 2/2

DALINO M.A.; SHENDEROVA7 R.I.; PISIMAN, I.I.; BAKHSHI-ME, A.A.1
VEDENEYEVA, LIY&.'; BUNITAT-ZADE.. A&A.
Synthesis of polyethylene and ethylene copolymers with
propylene and oL-butyleae on a chromium oxide catalyst,
Azerb.khiz.zhur. no.ltll-22 161, (Kim 14 2 8)
(Polyethylene) (Ethylene)

MEKHTIYb'V, S.D.; BAKHSHI-ZADE, A.A.1 SEIDOVO N.M.; KAMUROV, YuG*
Separation of m- and p-xylenee by selective alkylation followed
by dealkylation. Neftekhimiis, 1 no-ls5W9 Ja-F 161..
(MIM 15 32)
lo Institut neftekhimicheskikh protaessov AN AzSSR.
I (1yiene) (Alkylatign)

DALIN, M.A.; PISIMAN,, I.I.; BAKWHI-ZkDE A.A.--
BUNIUT-ZkDE, A.A.;
POKOTILOVA, S.D.
Copolperisation of ethylene with At-olefino on a
chromium
oxide catalyst. Azarb.khim.shur. no.20-16 161. (wk
14:8)
(Ethylene) (Clefins) (Pblymerization)

SEIDOVp N.M.; BAKHSHI-ZkDES A.~.; CHERNIKOVA, I.M.1 MELIKOVA, Z.M.
-Transformations Oro( -methyletyrene on aluminosilicates. Aserb.-
-tWdvUtur. no.5sk7-62 '62. (KMA 16: 5)
(Styrene) (Aluminosilicatea)
i! Oll

~ r, .1 -, . , I A '-iAWV, G. I .
*":).. I ~ (! 4`1 .6. , bli.,. " Y, . ~!., A -'. . .
~ ~ KY--, I I I ,,, A IN,-, $ P . A . , A '- I IOA F
;,
rf- EII,4.(,Alc catnly3ti n the
rv-i~!t'on of -,,,pnlyxurlzatlcn of ethylene .i!tti
6(-olefins.
Azorb. khin. zhur. no.lillW125 104, KRA 17s5)

L ~ - 1 , ~': A -RY
rTR/03j(,/64 /Wo/oC*A~041/0045
A t A P"Z) '10"
A q V~m beq rv0 N. IMnkhti-rev. R%k-hahiml~ A. A. I FL&MbIL~, Tu.
a.
-'q - Is
WUWY! AL-"rtkny4xh^nakiy kh1jmJc!Nv"iY Zhurnal, no. 4, 1964, 41-45
!Topic TAGS: Stvine prv"Jene, catalysim
kbstroct? This article presents the "jolts of one of the stages
in a detailed
or itw dimer1ratt" -f alefina 1n an offort to reveal
tf- r't a,..I 1'') stow 6.4ye
No '