SCIENTIFIC ABSTRACT BALANDIN, A. A. - BALANDIN, A. A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000103210011-2
• Release Decision: RIF
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• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: July 27, 2000
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

33491.
The use of radiocarbon (CA) s/195/61/002/005/0i6/027
E030/EI83
An unexpectedly interesting systemlis the decomposition of
isopropyl alcohol on a vanadium trioxide catalyst. The catalyst
was obtained by passing hydrogen over the trioxide at 4170,
The general scheme possible iss
- H2 - 1120
C3H60 C3H7OH C3H6
H2\ / / 112
C3H#3 10
By using radioactive propylene (up to 29 000 imp./min on BaCO3),
and by separating propane, propylene, and the catalysate,
and determining their activities, it was shown that propylene
is not converted to isopropyl alcohol at 5150, and that propane
in formed, not from propylene, but from the isopropyl alcohol.
There are I table and 10-referencess 8 Soviet-bloc and 2 non.-
Soviet-bloc. The English language references read a& followat
Ref.8s V.J. Komarevsky, J.Amer.Chem Soc., Y.69, 238, 1947.
Card 4/5
33491
The use of radiocarbon (C14) B/195/61/002/005/016/027
E03O/El85
Rof.9t V.J. Komarevsky, Advances in Catalysis, v.9, N.Y.,
1957. P-707.
ASSOCIATIONt Institut organicheakoy khimii im. N.D. Zolinskogo
AN SSSR
(Institute of Organic Chemistry imeni
N.D. Zelinskiy, AS USSR)
Card 5/5
33492
S/195/61/002/005/017/02?
E030/E185
AUTHORSi Derbantsev, Yu.j., Balandin, A.A., and Isagulyants,G,V.
TITLEt Investigation of the role of cyclohexene in the
heterogeneous catalytic dehydrogenation of
cyclohexane, using radiocarbon
PERIODICALt Kinetika i kataliz, v.2, no.5, 1961, 741-747
TEXTs The dehydrogenation of cyclohexane on chromia and
rhenium catalysts has been studied, using C14. Chromia, was chosen
as an oxide catalyst, favourable for doublet dehydrogenation, and
rhenium as a metallic catalyst suitable for a sextet dehydrogena-
tion, where the conversion rate of cyclohexone by this process is
negligible. The chromium oxide in 2-Mm pellets was obtained from
ammonium bichromate. Before every experiment tne rhenium catalys.,
prepared by the method previously described (Ref.8a A.A. Balandin,
Ye.l. Karpsynkaya, A.A. Tolstopyatova, Zh. fiz. khimii, v.33,
2471, 1959) was kept for one hour in hydrogen at 480 OC.
A continuous flow reactor was used, with varying initial
concentrations of cyolohexane (obtained by hydrogenation of benzol),
Card 1/3
33492
Investigation of the role of S/195/61/002/00.51/017/0277
E03O/E185
benzol, and marked cyclohe one (activitY 470 pulses/minute
mg BaCO3) obtained from CIZ marked phenol. The catalysates were
analysed chromatographically on.a 7m long spiral column of
diatomateous earth, of which the first half was impregnated with
dinonylphthalata, and the second half with, dio,-Aylsobacnte, the
outlet from the column was led either to a thermal conductivity
detector or for quantitative analysts to a bubbler wMi obaryta
water. in order to obtain barium carbonate. The radtoa:tivitY of
targets made from this carbonate was measured with an end window
counter, ftnd samples taken after 15 min. Ott the chromia
catalyst, benzole was formed by a parallel-consecuti've procesq%-,
conversion of cyclghexane into benzole is 1.5 times raster then
the conversion of cyclohexen#i a considerable part beAng formed
from adsorbed and desorbed cyclohexone and it i.% obviously a
doublet mechanism of dehydrogenation. On the rhenium -.a-.alyst,
there is no consecutive process at alland cyclohexane -is
converted directly into benzole by a sextet me of truwame,

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10 - t L A IOVALLM"&L LIUSAV%M CLAMMAIIIIN
WO*
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IA Nij-11N, A. A,
Catalytic dehydrogenation of *./-butane. A. A. Balandin, N. D.
Zelinski, M. N. Maruchkinx and L. N. Pavlov (Compt. rend. Acad.
Scl. U.S.S.R.11941, 32; 135-130-The Yields of butenes, C,.H 14
11 and saturated hpArocarbons obtained fromowot~11.jwith a
and times of con".
r, ed Cr catalyst st 525-625' act 0-8--3-5 eec-
are recorded. 7be yieia of butenes is 105% (based on ~A decom-
posed) at 550-5750 after contact fir 2 sec. The catalyst' is de-
activated by cooling In V$0 and reactivated by heating in air.
v4sj- etj- cku%., Ao SJJq
6 4 !1 %1 4 St 44 V1, -9 0 it 11 W w &1 0 a
a 101~4 tilt 6.4
%*Aft "NNW to "W" *I ft
nwol" aw". A. W4",
(1, SPO C&M. IOU, to* 1,~,V1VA%aalkt%SXl1k
641011101"1 "641fiva rart wd t. th~ aAaftsis
44 tvk""14, 11"1 -00
It thr 4itittor"sat lilt Wbe" & " %kv WINW11111t.11
matrix. the aktbrak se"I 01611 the Iftlkwity "w"* of th. %%-Ivm it
VMS,
it
00 J
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it
IV it a Of 9 a IN a IN X it a "a
0 0 0 0 0 0 0 0 4 0 0 4 0 0
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I I . I . . . . ~ - , , . . 9 v -
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-4--* $6 A i t V 7 f A t, i QC OU
so 4r
qP
get'
Comfy* dak not al but*"* at i*4dc*4 pres.
N. 1). Z060kd. 1). K. 110611&ROWIA
A. j:k
owe A
ftchessm. Aou. ", ul (14.10
1042, $10 64)(English adinineq); rf. C-4. 3T.
il-vtO.-With a Cr catelyit at 180 mm. lwvsmrv. on rsw
.4 ithip. The mas. dehydrog"allms In effoctoil in abmiri
00 ~vwart thm. The tmp. cog. of dKoi Pa. 6 bialw
00 lbsu that at dobydropution. be" at bkbw lemm,
At~~. opthomm nwAi-
i =im( 8.0 onsm. pnom. 89D0 0.73 W. contact) V.0
00 4 nod. % balsdiew iw~u obtakwd. bomml am Me butylent age
hisaw. Rates of dtky&opmdn W the a folml tit
toaty1m wtv appm. Ow um. C &-position an The
tlw kKTftwo whis rim at temp.
U- too
L
U
14
0000 0 0 0 0 0 010 0 0 0 0 0 0 0
-0 0 0 0 9 0 * * 0 0 0 000 0 (A 0- 0 0 -0 0 0 46 0- 0,41 * 0 0 0 41 0 0 0 see 0 0
of
Ak. -i )f
In8titil4a of ortn-Oo k;llf-Inistry. Jenaru..e-it of 1~- J. `uLtniiKv
-emher 3f t1le Aci~dpu
BAW
"Kinetics of catalytic monoinolocular reactions In a flow Bystem taking Into consideration
the displacement vith foreign substances." (pt 159)
SO: Journ2l of General Ch9mist (Zhurnal Obshchei Khimii) 1942, Vol 12, No 3-4.
1vt)1. O,,&W"t 0".8 AN SISq
A. A.
"On reaction-kinatical method of deteraination of anisochrony." (p. 167)
SO: Jgurnal 0t agagral Gbamixia (Zhurnal Obahchai KhWi) 1942, Vol 12, No 3-4.
Iris+, al WAA~. ChUln-j 4 ti dJSq
-T -T-1
"Topochemical factors in the formation of the hydrides of nickel." Dalfiadin, A. A.9 and
Erofeew, B. V. (p. 170)
SOs Journal of General Chemistry (Zhurnal Obahchei Khimii) 1942, Vol 12, No 3-4.
Ivisf. Ovi. Ch'tM., AO SS51?
'T
'Tul
*The kinetics of the interaction of sodium acetate and sodium hydroxyde, in the molten
state." Palandjn.-A.-A., Jurba, L. I., and Waskevitachl D. N. (p. 179)
SO: Journal of General Chemist (Zhurnal Obshchei Khimli) 1942, Vol 12, No
Iv%Sf- 014w*t c6u~tmj, fig
- i~j J 4
~i .-A-, -..-Ftl
"The selective effect of nickel catalyst and the enerCy of chemicftl linkaCes.' (p. 342)
SO: Journal or-General Chemist (Zhurnal Obshchoi KhImil) 1942, Vol 12, No 7-8,.
Wt. OtI. Ckup., ~N is -11
Catalytic dehydrogenation of butylene to butadlene at reduced
presoure. A. A. Salandino N. D. Zelirkkio 0; K. Bogdanovap and
A. P. Schtscheglova (J.Appl.Chem.ftse.,1942,150128-138) ------
jr-Butent (1) passed through an unspecified catalyst givesebuta-
diene; the yield is UP to 85% oil the (1) consumed and up to
291, on the (I) ""sed through; the best temp. is 580-6000. VIle
yield of (CII.CH!,.Is almost independent of the rate of gas flow ajkd
K 8 orre onds to the equilibri-m concn. A few %, of
nearly as hig c a
(1) are isomerised toA;-butenet and a fev % are fomed.
J. J. B.
A.- A.
Dehydrogenation and decomposition of cyclohexane at high tem-
peratures over metallic catalysts. A. A. Bmlandin and. N. Z. Kozelkov
(J.Appl.Chem.iftion.1194q,,15,139-150).--cycloilexane (1) was passed
over heated metal spirale. There was no decomp. with Fe below
553o or with er-plated Fe below 5,000; a little decorp. occurred
with n1chrome at 3000, and at higher ter.T. much Cl~ctc. was forne(l
in addition to C~11'-,,Platlnlsed nichrone dehyarogenates M at
'zc,O_4C)OO; the rare is lowered by dilution with CO,,at 300-31500 and
raisca by dilution with N
,,,at 4C;oO. Soot gracIttally builds up on
the catalyst, and the energy of activation drops from 101~g.-cal. to
5 kg.-ca.!.pcr ml.; the activity of the. catrayst has a max. at
some medium soot content. An explanation Is given for the promoter
erfect of soot. Palladised nichrone is leav active than platinised
nichrove, and the energy of activation (without sooL) 1B 7 k6--cal.
As
"Sliding" isomerism ("Oliethonerism"), A. Balandin (Acta Physicochem.,
UIW-i 1942s 16p 195-205)- -Where it is possible by change of group,3 in
different ways to arrive at the same compound from the same starting ma-
terials, the products are cilled "sliding" isomerides or oliathomeridea.
'thus, in the formation of HeOAc from AcOll and MeOH, the substances may
combine. as followst He OH + MeCO CH and Me OH + MeGO 0 H. Conditions
for the existence of this type of reaction are outlined, Reactions in
which it may take place include esterification,. formation of others from
alobhols, formation of mixed acid anhydrides, mixed ketones) aldehydea
from formic and anot~sr carboxylic acid, (see.) amines from two primary
aminesp and the reaction between two different peroxides, etc. The in-
vestigation of the reactions provides an important method for comparing
the strengths of linkings and the mobility of groups and atoms. Isotopes,
artificial radioactivity, and optical activity can also be introduced
int study of the phenomenon. AsJ.M.
1696
t
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00'
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ViLmoly A., 1637- 1, S4M
ftff~' is Uw CON" . Pkt "Mb&SWM G"un J.
Mow,
Differential equation Vor the kinetIC3 of contact wd-ol"ulAr
r-actions itIVOSLilated by the I'low wthad. A. "-In (;xta
Pt%,IMCOO~IIM. 11639JOJ-49 L942, 1-1, T-morutical. The rv-~ults
are aj~js'.%!A to Lim dWi.~AroovivitiI.,ii of al~,o:wlj ..tit IL, ooll'-wL,
iso-,vrisation. J. Ii.
O*Jku4t C~tw-j AN ~SSk
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Neu laditame dam -toc. CH,blovoditim , wipwitneats
VIS ttat dim to w" do* so olefiame am prodoced. The
abstract).
C-11
Witb the t&Wysg the Coll AM mom M;ftm" of a
Makillf Ma' I bY kmt 01%z to give K CH, md APAI
H neambiw to " %H c(% livis 00 am - I
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. Z =C&W=
CH~ M
to CHI, Ot and PeC Aftlifir v" "WAS
famovat 6acnames wm
sham with C H Tblm
to the C.H.A reactions. J. it. lm.
Otvac. Chun., 6" SSSI?
t f t
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ril"46816 406ormbisailbe
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thf cuum of a catalyuc fwtko 2DAY be obt&twd by a ttw~~
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L a I r F. a I k L #A of 43 w tt

4 -4tS
A
).-
a"%twGOf&~&j
0"4 vbmby
"-16
40-
00 V. IL
00 f
go
.06
000 Cos
00 J
0 900
of see
go 0

goo
91 rx$ 0
too
it 4 0 109774 a too
6 1 w
""..0 *-Ill via" 0 It a A C'Sa
9 a I
I'Aygit*94ANiM. U. S.S.. Us muft
Mm 11061L amid ol the lAttk* tit
catalysts, Is Ulikk tb* "to and M.
eo catalpt VV tnaMM U of WOMY imirart"CV. is dlKVmM
otth pentrielar referitwo to W defirdireigretalwa of hydrmwetums,
00
Mo&b indicallell the orlentsticeli CA O-C It I i. A-botomw Ilb.
09 oil' atv,
truors, aud tho nvictime an wludlo& u4*4 the Swir metkNI With .0 g
Ill. thf t1thint"O 16" at a Cr "Olialy" Softele, to U% 4
A 4
w to M% of ilimis dwimspreva at 4w. amd a lipatkal
d, TtXl,- 100 1. pw bit. At to ftmp~ ibe ywM tm Ow lVi C4 f u*O 100
1. 71-14) ,r,*A M A--.--.
tie -Iiw -
iacrvaws. draws vadono
so .1 Ito CONSMIko of see
th* I
I It 31
0 -Vur
fit OWN# Ito V
him% Jbit ty decirtwes goo
IN" of w Is.
Ilw Ow so buM "d .mrgo
lop
76 wimet lopeet"t fwtb"
00 IS( 0+40N. + tascodomimicepaiwattie ta I
I hi activity vRii"Vik"k is a pet"m saaaer. The ==
wasticia d& bw &M bew imaisaiml at low mearm, ia
sk" ame 409' 1 is greimillar. Tlw ellim me stum, with !goo
:12 CO, amd N was abo KvillmiL Two mmetbods tw the prodectim of goo
moft A pa V". Tbwe ft.alialill an optimum 1,
PlMo~ w4 C H rompftlively, to Ago
MKI likikat" 4: 4;tI=Rf w4wirwo 11:60
OR tow flece I Mi > figs
MMe > C It The twv" of .1 mln , '.9 aft aim am r
lob D awast
to Slid" Aw"d is the A. M,
goo
It it 4 ISO A I lla w Al 6 0
doe
00 00 0 0 0 0 0 0 0 0 so a 6 0 o *1
saiti 4 4 4 L, I r If p
w I T hit a if
to
so
at L
JL 1K. &
Love liful It. it
00 ft AcM Mj"wmalmito 1'. IN. 13" 11111
I IOU) (in Itits") I , f. C. .4 - ST. *V.I,.t the r %ptl
IF bY 1C. A. Is, 217.)
Ir of NI furvant boo the ft"Im. 'Vill, folk" JIM"
NO#.. Milt *&'I perpl. by bileld'I" Of sag,
SOW Wum Or di"Wvwd In 11110, "Vol. colle. lith"Im ew
%YkWinefialm. lIw&~&WrwdbyIhm- Islivmpn
Jet o 16.1061"1111. NOV. III #wow&* an jutww"N'lielf. fw%kimt CV0
00 UkI IkIftmaIk)r "J*Pto the h III'm .4 Coll, Im"d too
If
of
00 "1111411
AA-1
All
IF
i%o
A$ SSSq
'I I I I "I' A - I v rk, A j -W 6 4 a I a be 0 A, 0 1 "iii
m 91 49 43 441' 6 It all nail Ito I I ft
1 a 0 0 All 6 0 0 0 0 & 0 : 0 0 0 0 0 0
00000 0000 so* 0 0 '46 0 0 9 -1 0 09 0 0 * 0 0
A4
0.09= 04 m4blildillill W WMIUM W IM bWAN 0 akkd.
assbudift awr It, V=4m%. h %
solool M S St 1. Al ON 1, N -~ %,
1043, It *0 310) U'vichwifel-We %iew that the Iwmdks&~-m .,I
Imm %Al. Mgl'hllt &%.I It, 16,11"r Io tht W111A,14-11 A III
-11h vowd as 66 oriteffra4late "W"INVIKI. to tfk.-Ifq~t
SK 14 ISM4CW to N1 Ivy M41*hlk 14 stooorwtol 11 11orlwmat"m
t'I NI hidiklet 11), Intefs(INM of r"twell No &A It lq~Nretlv in
stalt". Thew stag" am mialmootalitK. th; 1,
411111 %4ftl SI Wool 101th the 110MICS A&I %11l. %Ill, 4ml Noll
#,C. thi.14ten. *%kh 10VOrost the I~Iwtfiolbw 0 It.
I*-Cf&CV 411ki IIWMSI.-n 1*1 11TAMS.. the I
12 r"m afe"Irt I-Of IM11101% Ill the 1 11 wo'hu. -
.'n the .411" hAfMI. the I~Mfo-fliffijj .11-I ..h the At-3mlown -1 11.
in the hithidosis vriv small
%A%robis ",or wasmouni I IrOov in I,t,0 as- k-- MaRe IhA. it.-
to ('J1.. I`hM9. anti ii)loooe.
oselfhabre jUgillotirl is >%Am . smarating that dio"' t I
Mg lit on W hyArWo surface "ects the ctolkii&
161*11Y coagoilate The kVI& t' R it.
DpAhft d NAM 600dum awsw bobovom d
A IU IS Oftbd Irm obl"Aaft b6" 110411601 op"
_W'ad N. Kutolkov (Aaa PAynewAva. U.R.S.S.. 1943.
I& .-The catalytic dehydroroal6m sad drcmp~ of
civiobesano owt Ill - &ad N-aichrome michrome. Vr Fr. and re
at NV dW' has tw** ouvestlestad. kichromme ur-11f. and Fr
Wr 104CUM INI-11khtoOf is A P" COW)-OU h-G%htuQA* is 4,
gmAcatalyotalhigWlerap. TbidepusitioutifCdo"cwtilimlook
be deb)AtfteoAlkpa activity of tho catalyst; on be "lattaty.
:
be activitr is incte4wd, DePositim q,f V 1-9 the IAt it( drmintes
4-1 OVKEMQ tok 6splasali-ma. C. R. It.
tAottow s6h V-)
Wt. 9f orjt%Am~c Chem., AN SSSq-
A a c 0 rp 6 a a
0
.tj I

t j

.184okm o0
"I-
1"PF04P
got k
W 1

so. "'I at

o- W"Jp-
""Sp
1 1 Ap *10 Cb " is n cj
S-A
so pne"ad Oup6m" a" so Owww" a4" if
ol fty-wd #qL -WpAq M in "if 10
IW64W P-Al No RNA -M PRM VMMM
""FPO* Me"" - VRIPM
WU VtVPWVA
low Will won" p SM #AM %m" &4%
A"I
44
0
00
so
00
00
!.so
Sol

t --e ro" -v --so

go
i DRILMON CF A014 Ih 1 F't A"A I if!
got HYL)RO'ARPONS ftlandin A A ond Marli.rhkin X N
(,.,omit* rend: 301111al.3, 40#
21.161 r,.C.U.R.A. Pull.1 roraffin vina (msr. 500
0*6 0 , uv. mol , *t. bb4) It n I.- &mood sto voi-olir ,vr r .90
o;romium oxide catalyst at 4500 bbOO C. rho .419
pro1icts had lower mola~-.I&r selghts (295-450) 8*0

and c~-ntlned 304-60A unsaturateds., 40me Joco-hptsltl n "go
occurred# with rorwtJor, or c, rbon, rotlone and
A little aromat
Is ation alno occurreJ.

00

lose
It- of
IN
a Wp
I& I I A-
0 owe so I W861,490
In a
0 41 0 0 *1; 0 0 10 41 0 0 * 9 0 0 0 0 0 0 4, 0 e 10 41 0 0 0 S 0 0 Sol
~-P M616
00409 , 00009009 0 00 so -- -- 0-0-004 9 0 0 '~ 0 & 0_# a 0 0-61A
XltAti.-3 of consocutift rautions onsisting ov biaal-a -ular wi. wilmol zular
:"I L., S. Li.),nson (Go-yt. re cad. ici. 1. mbas 66j,
stalods A. A. 'gala 19. A
II)IJ, 39, equations for com3ccutivu of ttk. 2.,f4j#C ..rt-
SOIVUJ, alm tim msoults ca piz%- I wivi o"ri3wnt in thc ca-i-. or t1to femi,,tioll of
^I froa equimoL. mixtures of N&OAc anA N&Oil* Thet mactiott In made. up 6f two con-
L~utive ones. The firstj the formtion or an intermediate coapound, is Lizols,
:al has a V~Aocity cooff.