SCIENTIFIC ABSTRACT BALENKO, N.G. - BALENOVIC, K.

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• Collection: Scientific Abstracts
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• Release Decision: RIF
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• Document Creation Date: November 2, 2016
• Document Release Date: June 6, 2000
• Sequence Number: 3
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

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HAUNKO, V.G,--
Doodsonts and Lecolazet's methods for harnonic analysis of
tidal observations. Trudy Polt.grav.obser. 9:48,94 161.
(MIRA 14W
(Hamonic analysis)
(Tides)

Inflienco v.~ rolt'hods of aralysin of rt,-rt'i tidou
n rancic.,n orro
0-' ro of initial orOdwAcs. Trudy l'olt. Crav.
ol--,cr. 10:3,`-4.3 ('4:E'A 14: 11)
( T i, -~ 9'-, )

:,-C, ir
Contribution of lon.-I~.0ri:)d waves to the results of 'h--,,:%o-Ac
analysio, of tiontbly a-rica of cartli tidle observatici~.-,. 1YVdy
Polt. grav. obser. 10:44-50 161. Ovmm lJoal)
- (Tidca)

s/i6g/62/000/008/020/090
E202/E-92
AUTHORS: Ba lenko, V. G. I and Zakharchenko, S. N.
,rITLL: Certain problems of comparing the methods of liaimonic
.analysis of Earth tides
PERIODICAL: Referativnyy zhurnal, Geofizika', no.8, 1962, 21,
abstract 8 A 143. (Tr. Poltavsk..gravimetr. observ.
AN USSR, 10. 1961,, 20-37).
TEXT; The problem of systematic error in harmonic constants
of the tidal waves is discussed.. This arises from incomplete
elimination of the disturbance waves. The recording of the
observed tides suffered due to the displacement of instrument
zero
and random errors, and it was not therefore possible to use it
for
solving this problem. In ord 'er to do so, a six-monthly
theoretical
curve of gravity force in tidal variations was calculated,
whi'ch
included 79 largest waves of the lunar-solar tide. The analysis
of
the results of processing the theoretical curve according to the
methods of Dudson, Lekolyaze, Matveyev and Pertsev has shown
that
the smailest errors in harmonic constants were obtained with the
method of Lekolyaze. Noticeable errors appearing in the
remaining
Card 1/2

Certain problems of comparing ... S/169/62/000/008/02o/ogo
E202/E192
methods in wave N2 are.due to disregarding small waves with
frequency close to the frequency of the N2 wave- All methods for
the principal waves determined gave relative errors not greater
than 10.o. The problem of systematic disturbances introduced into
the periodical part of the tidal ordinates by combinations
stipulated by B.P. Pertsev in order to eliminate the zero shift are
discussed (see Ref.zh. Geofiz. 1, 1960, 157). It was shown that:
1) longitudinally periodical waves are excluded together with the
shift of zero sufficiently well; 2) as a result of incomplete
attenuation of the tidal waves when the shift of zero is excluded,
into the'amplitudes of the determined waves is introduced a
systematic error which for the waves N2 and 01 e_ 15o, for M2
< 0- 31c, .3nd for S2 and Kl 0. 21,'0'; 3) if the zero shift may be
represented as a third degree polynomial over the 49-hours
interval, then this will fully exclude the combination of ordinates
as stipulated by B.P. Pertsev.
CAbstractor's note: Complete translation
Card 2/2

S/169/62/000/0081019/090
E202/E192
AUTHOR: Bal-enko, V.G.
TITLE The effect of methods of harmonic annlysiL of Earth
tides on.the randoin errors in the derived ordinates
PERIODICAL: Referativnyy zhurnal, Geofizika; no.8, 1962, 21,,
abstract 8 A 142. (Tr. Poltavsk..Sravimetr. observ.
AN USSR, lo, 1961,138-43).
TEXT: It was shown that according to the method given by
Lekolyaze for the evaluation of the influenne of random errors in
derived ordinates on the tidal waves determined by means of
harmonic analysis, the methods of ' Dudson,
Dudson-~Lennonj-Lekolyazej
Matveyev and Pertsev are equally good, as far as the effect of
random errors on the results is concerned. In the process of
traniformation of the derived ordinates, the ordinates of random
errors lead to the formation of fictitious waves of the same period
as the waves which are being determined. The author has carried
out a detailed study of the effect of these. fictitious waves on the
results *of the analysis. Selecting a large series of rpndom,
Card 1/2

s/169/62/000/008/019/090
The effect of methods of harmonic ... E202/E192
numbers satisfying the nortrial Gaussian law of distribution,
the
author subjected the said series to harmonic analysis using
various
methods. The results of this analysis have shown-that fictitious
waves, in view of their random character and their amplitude and
phase, have no effect on the transfer of' the error of harmonic
constants det'brmining the waves. If random, errors of the
ordinates
satisfy normal law, then the errors in the determined waves will
also follow the same law and their magnitude would correspond to
the meanings found according to the method of Lekolyaze.
[Abstractor's note; Complete translation.]
Card 2/2

s/169/62/000/008/021/090
E202/E192
AUTHOR: Balenko, V.G.
TITLE of-longitudinally periodical waves in the
results-of harmonic analysis of the monthly series of
observations of terrestrial tidei
PERIODICAL: Referativnyy zhurnal, Geofizika,'no.8, 1962, 21,
abstract 8 A 144. '(Tr..Poltavsk. gravimetr. observ.
AN USSR, lo, 1961, 44-5o).
TEXT: The effect of incomplete exclusion of the longitudinally
periodical waves of terrestrial tide on the amplitudes
and-phases~
of the principal tidal waves which determine in the harmonic *
analysis of the tidal variations the gravitational forces and the
inclinations of Earth surface is discussed. Dudsbn, Lokolyazes
Nfatveyev and Portsev methods of harmonic analysis are discvssed.
It is shown that the largest error in the longitudinally
periodical
waves is~introduced when the Dudson method i 's used, and the
smallest when either Lekolyaze or Matveyev method is adopted.
The author's conclusions are confirmed by the analysis of two
Card 1/2

Contribution of longitudinally ... S/169/62/000/008/021/090
E202/EI92
-nonthly series of theoretical values of longitudinally periodic
. V
tidal waves. Ilowever, the error brought into the results of the
analysis by incomplete exclusion of longitudinally periodic
waves was found to be negligibly small in all methods.
EAbstractor's note; Complete translation .1
Card 2/2

retl~od of harmonic analysis of earth tld~-v.
Lq

.BAIRRO. V. G.
Dissertation defended for the degree of
CaAdidate-of-PhysicomathematicAI
Sgiences at the Institute of Earth Physics imeni 0. Yu. Shmidt
in 1962:
*Comparison of Harmonic Analysis Methods for Monthly Series of
Terrestial
Tide Observations."
Vest. Akad. Nauk SSSR. - No.-4, Moscow, 1963, pages 119-145

r~ MZBKQ, YAGO
Gomparative evaluation of the quslity of ridding
determinable
waves of the effect of disturbing wav9s in combination
methods of harmonic earth tide analysis. Trudy Polt.
grav. cti~per. 11:61#"73 162, (MIRA 15-.11)
(Tides)

HAIENKO, V.G.
T7
Contribution of the movement of the zero point Jo
R cos S" and R siu i of determinable waves of earth
tides. Trudy Polt. grav. obser. 3-1:74-87 162.
(MIRA 15:11)
(Tides)

BALS110, V.G.; TEVTUSHENKO, Yo.I,
Pevtsevla method for a harmonic analysis of 50-day series of
obser-
vations of tidal gravity variations. Trudy Polt. grav. obser.
12:
27-47 0. (Tides) (MLA 16:9)

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BALENKO -fu-* K.
Ft~obloms ef engineering Fsyehclcgy. S-adostroenie nc.6:84 Je 165.
(MIRA 18:8)

USSR/ Chemistry Cat--lytic corver,-low
Card j 1/i Pub. :L5i - 14133
Authors Khromo-, S. L., Balenkova., E. S., Akishin, P. A,, arKI
Kazanskiy, B. A.
Title Contact conversiorw of propy1cycloheptane in the presence of a
platinized
carbon
Periodical Zbar. ob. kh1m. 24/8, 1360 - 1364, August 1954
Abstract Contact conversions of propyleyclohoptAne were investigated
in the
presence of platinized carbon at 3200. It vas established that such
contact conversion reactlons take plaw with th3 formation of barge
quantities vi I-riothyl-l-propylcyc3ohexane and some aromatic
hydrocarbons
(toluene propylbenzene, butylbenzene, o-, ot- and p-methyl propyl
benzenesi. The approximate ratio of hydrocarbons in the tot-321
catalysate
mass of contac' conversion of propylcycloheptane, is described. Seven
references: 6 USSR and 1 USA (1937 1954). Tables.
Institution State-Unive -YC~SC67,w-
March 6., 1954

WSB Onemistry - Cata3yLic conversiOn
Card 1/1 Pub. 151 15/42
----------------- KhromovP-S.- alerkova, E. B.; and Kazansskiy, B. A.
XU Ora
Tith Contact conversions of butylcyc3oheptane i-n the prv*ence "P
platit-lized
C.
ftrlOdWa Zhur. ob. Wim. 4/9, 1562-1566, Sep 1954
Abetract The behavior of butyloyclopentane in conditions of
dehydrogonating
catalysis was investigated. Contact conversion of butylcyclopentane
over platinized carbon was studied at 3200. It was established that
such contact conversion3 result in the formation of large quantities
of 1--xi.-t~Crl-l-butylc,-clohexane and aromatic hydrocarbon mixtures
con-
si6tina of toluene, butylbenzene, o-, m- and p-methylbutylbenzeLteo,
the f7actional composition of which are shown in tables. Four refer-
ences: 3-USSR and 1-USA (1937-1954).
Institution State University, Moscow
Submii,ted March 6, 3.954

NNW
B-M-N
Mii.s-s-s-R. 06. M-7

USSR/Chemistry
Card Vl
Author* 3 Khromov, S. I-, Balenkova, E. S., and Kazanskiy, B. A.
Academician
Title S Contact converaions of 1-methyl-l-propy1cyclohexane in the
presence
of platinized carbon
--SSSR, 960 Ed.- 2p; 295 297 ___Uay 1951~
Periodical s Dokl A14
-Abstx__-a_C't_ S Synthesized hydrocarbon 1-methyl- I-Propyl eye lohe
7rane was contact-)d
at 3200 with a 101--platinized carb(,ri, as a res-it art arori,atio
carbon and im%utable bdsic hyorocarbon mixture -nas obta'i,ed, Thi3
arojuatic hydmcarbons separated througn chroratog-rarhic
over s1lica Eel were subjected to tz-iorvltgh fractlunation over a
coliinn
witn an effectiveness of LO theoretical plates. It Yms established
that the trend of the contact conversion processes for 1-Metiq1-1-
propy1cyclohexane is the :;ame as W the conversion of 1-1fiethyl-1-
ethyleyclohexane. Four USSR references, 51"ce 1937. Tables, Ur-,pE,s.
institution 2 Tne M. V. Lomonosav State University, N. 1). Lelinskiy
Laboratory
of Organic Chemistry, Moscor.
Submitt-ed 3 February 26j, 1954

t13SR/Chemistry
Card I
AutUrs j ~hrontov, S. 1. , 1~alcn!kova,_ S. AlklshiD, i ~'. A. and
Kazinskiy,
D, it., Acadlci%
Title I Gontict cr~,wersions of I -rethyl -1 nhcxino in the presence
of
platinum coated carbcri
Periodicea t Dold. AN SSM~ 97p Bd. 1, 103 - 106, July 1954
Abtrwt 3 Formula is given showiW, the trond of the chei-,ical
reaction _je_a4Jn&_tO-
the conversion of 1-met
~hylot.'-A)utyj.nyol-ohaxanq over a - platinum- co-atedL -
--Rio_
-such-hydrotar ns a
ained by the seconddry chemical conversions
occurring during the catalysis of butyl benzene. The. approximate
ratio
of aromatic hydrocaftons found In the catz~.Iyaate obtained from
contatt
conversion of 1-methyl-l-but3~..cyclohexane, is described. Five
references:
4 USSR, I USA. Tables, graph.
Institution : The H. V. Lomoliosov State University, The N. D.
Zelinskiy Lab. of Org.
Chem..$ Moscow.
Submitted : April 27, 1954

z

JHRCKOV. S.Z.; KWDRATIYW, D.Ao;,Yl
XAZARS]rff B.As,skademik.
'V,~EIMMW
Contact transformations of 1. It dimethyldloyclohosyl In the presence
of platinized narbou, Dokle AN SSSR 109 no.1:109-112 Jl-A 1 69
fz 9:10)
1. Moskovskiy gosvidarstvennyy univereltst imeni M.Y. Imonosova.
(Dimet,hyldicyclohwql)

t
k~ -
4~
f.

A t.li I

KHROAM, 6,I.;BALEHKOVA,Y9.8.; KAZAIiSKIY, B.A.
Catalytic dehydrogenation conditions for transformations of
1.1-dialkyloyclones with five and six membered rings. Vast. Hook.
un. Ser. mat.. makh., astron. fis., khim. 12 no. 6;225-236 157-
(MIRA 11:10)
1. Kefedra khimii nefti Moskovskogo gosudarstwennogo universitats.
(Cyclic compounds)
(Dehydrogenation)

&Oot= nu

V..ro.jw N........ V-5 -A

VIA"

S/08i/6o/ooo/b22/002/016
AOO5/AOQl
Translation from: Referativnyy zhurnal, Khimiya, 1960, No. 22,
pp. 174-175,
88528
AUTHORS., Kazanskiy, B. A., Khromov, S. I., Radzhnbli-Seidova,
N. A., Palen ~oyy,_
Ye,.S
. AUM
TITLE: The Formation of Aromatic Hydrocarbons at
Contact-Catalytioal Trans-
formation of Heme-Dialkyl Cyclohexanes Over an Aluminum
Silicate
Catalyst
PERIODICAL: Azerb. khim. zh., 1959, No. 5, pp. 3-12
(Azerbaydzhan summary)
TEXT: The transformations were studied of
1-methyl-l-alkyl-cyclohexanes:
1,1-dimethyl-cyclohexane, 1-methyl-l-ethyl-cyclohexane,
1-methyl-l-propyl-cyclo-
hexane, and 1-methyl-l-butyl-oyelQhexane in a stream system
over a synthetic
aluminum-silicate catalyst at 50OUC and 0.23 hr-1 volume
velocity. Hereat the
following reactions proceed: detachment and rupture of the
side chains, methyla-
tion In the nucleus, isomerization of the six-membered cycle
to the five-membered
one, and hydrogen disproportionation. Aromatic hydrocarbons
are the main trans-
formation products (output about 33-45 percentage by weight
with respect to the
Card 1/3

S10811601000102210021016
A005/AO01
The Formation of Aromatic Hydrocarbons at Cont~ot-Catalytica2
Transformation of
Heme-Dialkyl Cyclohexanes Over an Aluminum Silicate Catalyst
transformed 1-methyl-l-e-lkyl-cyclohexane): mixtures of the
isomeric xylols and
trimethylbenzenes, toluene, and a small quantity of benzene; in
the XYlol mixture
the isomers content decreases In the sequence meta > para >
ortho-isomers, whereat
the content of the meta-isomer is approximately twice as high as
that of the para-
isomer for all 1-methyl-l-alkyl-cyclohexanes. The absence among
the transformat.4rn
products of 1-methyl-i-propyl-cyclohexane, 1-methyl-l-butyl
cyclohexane, propyl-
and respectively butyl-benzene points out that the alkyl group
with larger chain
length detaches easier. Moreover, alkanes are formed If in the
main gaseous &lka-,ie,%
predominaaitly CP8 and Colo), six-membered naphthenes
(cyclohexane, methyl-cycilo-
hexane) and five-membered naphthenes (cyclopentane,
inethyl-cyclopentane, 1,2-
dimethyl-eyelopentane]. With Increasing side-chain length of
'L-methyl-l-a!~,yl-
cyclohexane, the degree of transformation increases from 42% for
cyclohexane up to 84% for 1-methyl-l-butyl-cyclohexane, The
transformation of
1-mE,thyl-l-phenyl-cyclohexane over the same catalyst proceeds
easier than that. of
1-methyl 1-aNl-cyclohexane, and 8% of
1-methyl-l-phenyl-cyclohexane undergoes
already ;t 350 G the transformation. without formation of gaseous
producto. Among
Card 2/3

sloBil6oloOO102210021016
AQ05/A001
The Formation of Aromatic Hydrocarbons at Contact-Catalytical
Transformations of
Heme-Dialkyl Cyclohexanes Over an Alumlirum Silicate Catalyst
the transformation products, aromatic hydrocarbors are
predominant (46.5% benzene,
5% toliiene) and naphthenes (about 40%)-. a mixture of the
Isomeric dimothyl-
cyclopentane, ethyl-eyelopentane, and methyl-cyclohexane. Under
the same condi-
tions, the transformation degree of phenyl-cyclohexane amounts
to 57%, and the
transformation products are benzene (48.9%) and
methyl-eyolopentano (48.5%).
Assumptions are expressed on the possible ways of naphthene
formation. 1,1-
dimethyl-e.yelohexane was obtained by the described method
(Zelinskiy, N. D.,
Yelagina, N. V., Dokl. AN SSSR, 1950, Vol. 73, No. 3, P. '105),
modified according
to Xhuan-Minlon, which led to increasing output of
1,1-dimetbyl-cycl6nexane from
58 to 78% with respect to ketone. 1-methyl-l-ethyl-ayalohexano
was obtained with
3E% output by the aotion of' I-ohloro-l-methyl-cyolohexane on
(C2115)~Zn in tetralin.
The synthesis of 1-methyl-l-propyl-cyolohexane and
1-methyl-l-butyl-cyolchexane
was performed by interaction of 1-chloro-1-methyl-cyclohexane
with the correspond-
ing RMgBr (R is alkyl) with 6-12% output.
1-methyl-l-plienyl-cy~:lohexane was ob-
tained with 53% output from 1-met~iyl-oyclohexanol-l and
benzene in the prespnce of
A1Cl3- A. Belotsvetov
Translator's note: This is the Pill translation of the original
Russian abstract,
Card .3/3

5-,?.2 0 0
AUTHORSt
TITLEi
PERIODICALs
69792
S/055J59/000/06/22/027
B000002
Yhr6m6V, 9. 1. Rtl&nkava. Ye. S., Sankav, R. G.
Synthesis and Catalytic Conversions of 1,11 -Diethyl yclohexyll
and 1-lethyl-l-tertiary-butyloyclohexane Under the Conditions of
Dehydrogenation Catalysi I
Vestnik Moskovskogo universiteta. Seriya matematiki, mekhaniki,
astronomii, fiziki, khimii, 1959, No. 6, pp. 180 - 185
TEXTt The authors describe the synthesis of 1,11-diethyl-dicyclohexyl
produced
for the first time: Cyclohexanone and ethyl magnesium bromide yielded
I-ethyl-
cyclohexanol-1. This was dissolved in ether and caused to react with
its organo-
magnesium compound. Copper chips and CuCl were used as catalyst. Pure
prepara-
tion was made chromatographically, 1-methyl-l-tert-butyl-cyolohexane
was for the
first time produced by the reaction of dimethylzino and
I-Cl-l-tert-butylcyclo _
hexane. The latter was obtained by dehydration of cyclohexanol into
cyclohexene
via Al 2 03at 3800, and by condensation with ter-t-btitylchloride in
the presence
of BF 3' Both compounds whose physical constants are given in table
1, were de-
Card 1/2

Synthesis and Catalytic Conversions of
1,11-Diethyldicyclohexyl and 1-gothyl-l-tertiary-
butyloyolohexane Under the Conditions of Dehydro-
genation Catalysis
69792
B/055/59/000/06/22/027
B004/BO02
0
hydrogenated on platinized coal at 320 . The following results
were obtaineds
1,1'-diethy1dioyolohexyl mainly develops ethylbenzenet
1-ethyl-l-phenyloyclo-
hexane, 2-ethyldiphenylt and low amounts of phenanthrene (Scheme
and Tables M).
From 1-methyl-l-tert-butylcyclohexane 70% of toluene and 25% of
tertiary butyl-
benzene were produced (Scheme and Tablesl,2). These reactions
indicated a
weakening of the C-C bond of the two neighboring tetrasubstituted
carbon atoms.
There are 4 tables and 10 references, 5 of which are Soviet.
ASSOCIATIONt Kafedra khimii nefti (Chair of Petroleum Chemistry.)
Vr
SUBMITTED: March 30, 1959
Card 2/2

KHROMOV, S.I.;BALINKOVA, Ye.S.;TRZSRGHOVA, Ye.G.
F W.
,-.qn
Synthesis and contact transformations of cyclopentylcycloheptane in
the presence of platinized carbon. Vest Hook. un. Ser. mat., makh.,
astron., fiz.j kh1m. 14 no.2:143-148 '59 (MIR& 13:3)
1. Kafedra khimii neftl Moskovskogo gosuniversiteta,
(Cycloheptane) (Carbon) (Platinum)

BAIZNKOVA, U.S.; SOSIfIlk, I.Ye.; TUROVA-POLTAK, M.B. ; MOMOV, S.
1.
Studying the affect of aluzAnum chloride on cyclodecans.
brief report. VesteMosk.un*Saremt., mekh.. astron., fit., kbim,
14 n0-3:203-204 159. (MIRA 13:5)
1. KafecIra organicheekogo kataliza Moskovskogo~ gonudar-
stvennogd universiteta.
(Aluminum chloride) (Cyclodecane)

50) SOV/79-29-7-24/83
ATYMORSt Radzhabli-Soidova, N. A*# Khromov, S, I.$ Gitina, R.
M.,
Balenkova, Te. S.# Treshchova, Ye, G., Kazanskiy, B. A.
TITLEs Contact TraKnaformations of lpl-Dimethyl Cyclohexane
and I-Mothyl-
I-ethyl Cyclohexane in the Presence of an Alumiaosilica:te
Catalyst (Kontalctnyye prevrashcheniya 1,1-dinetiltsiklogeksana
i 1-metil-l-etil-taiklogeksana v prisutstvii alyumosilikatnogo
kataliza0ra)
PERIODICAM Zhurnal obshchey khimii, 1959, Vol 29, lir 7, pp
2212-2218 (USSR)
ABSTRACTt The numerous.Ruasian petroleum typos contain amon.-
other
cycloparaffin hydrocarbons 191-dimothyl cyclohexane and
1,1,3-trimethyl cyclohexane (Ref 1). According to reference 2
also the transformations of 111-dimethyl cyclohexane at 5400
over an aluminosilid6te catalyst are described. For the
authors it was of interest to investigate the behavior of the
most simple mixed methyl alkyl cyclohexanpa in the catalytic
cracking pro(;ess over an alumlnosili6ate catalyst. Per this
purpose the behavior of 1,1-dimethyl cyclohexane and 1-mothyl-
1-ethyl cyclohexane over the above catalyst were investigated
0
at 500 , In this connection Gaseous products, a liquid
Card 1/3 condensate, and coke which separated on the catalyst
vere

Contact Transformations of I,I-Dimethyl Cyclohexane SOV/79-29-7-24/83
and I -Me thyl-1 -ethyl Cyclohexane in the Presence of an
Aluminosilicate
'Catalyst
obtained. The gaseous products were first fractionated at low
temperatures and then determined. The liquid conai~nsato was
subjected to an accurate roctification, chromatographic
adsorption on silioa gol as well an to optical and chemical
investigations. The following per cent composition of the
reaction products of 1,1-dimethyl cyclohexane, were found:
hydrocarbon 21.4%, liquid paraffin hydrocarbons 2.6%,naphthene hy-
drocarbons EL4$ aroma-tic hydrocarbons 45 2%, oolne 22.4%. For
1-methyl-I -ethyl
cyclohexane (in wt%): 10:8% gaav:coas hydrocarbons, 23-(Y/.' mixture
of paraffin naphthene hydrocarbo.ns, 40,5% aromatic hydrocarbons,
25-7% coke. Under-the chosen conditions of catalysis the
separation of the alkyl groups which are in the quaternary
cyclic carbon atom# hydrocracking process, methylation,
aromatization as well as the isomerization of the six-membered
cycles into five-membered ones take place. The main products
are aromatic hydrocarbons and in small quantities paraffin and
Card 2/3

Contaot Transformations of 111-Dimethyl Cyclohexane
SOV/79-29-7-24/83
and.1-Mothyl-l-othyl Cyclohoxane in the Presence of an
Aliminosilicate
Catalyst
naphthene-hydrocarbons. The direction of the contact trans-
formations of the mixed dialkyl cyolohexanes are illustrated
by the scheme in the experimental part. There are 6 tables
and 11 references, 6 of which are Soviet.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet (Yoscow
State University)
SUBMITTED: June 3, 1958
Cara 3/3

XHHUMOV-p SO I -.-~,i-BALDNKOVA,
Synthesis and catalytic transformations of
1,11-diethyldicyclo-
hexyl and 1-mothyl-IL-tert-butylcyclohexane under
conditions of
dehydration catalysis.
Vest.Mook.un.Ser.mat.,makh.,astron.,fiz.0
khim. no.6:180-185 '159- (MIRA 13:10)
1. Kafedra Waii nofti Hoskovskogo univeraiteta.
(Cyclohexyl) tOyclohexane)

IMMOV, S.I., BALUKOTA, To. S.. TAZA SKIT, B.A.
Catalytic converstoas of haptamethyleae hydrocarbons under
condi-
tions of dehydrogenati6n eatalysia. Vest. Hooke un. Ser. 2:
khim.
15 no.2t)&.'41~ Mr-Ap 160. (KIRA 13-.6)
lo lafedra khImil neftl Moskovskogo universiteta.
(Sydrobarbons) (Dehydrogenation) (Catalyeis)

S/020/60/1,'5/002/020/036
Bo16/BO52
AUTHORS:
TITLE:
PERIODICAL:
Kazanskiy, B. A., Academician, Khromov, S. I.p
Liberman, A. L., Balenkova, Ye. S., Vasinal T,, V.,
Aleksanyan, V. T., and Ster-1n_,__RTT_. Ye.
Contact'Transformations of Cyclodeoane in the Presence of
Platinizea Charcoal
Doklady Akademii nault SSSR, 1960y Vol. 135, No. 2,
pp. 327 - 330
TEXT: The authors studied the following problem: Hitherto (Refs.1,2)
it
has been stated that cyclodecane on platinized charcoal is directly
transformed into azulene. In connection with the C 5
dehydrocyclization
(Ref-4) which has been discovered in the meantime, the question arose
whether the formation of azulene is a secondary- process, while deca-
hydroazulene is formed in the main reaction (transannular C 5 dehydro-
cyclization) and yields azulene by dehydrogeriation. To prove this
reac-
tion, cyclodecane was catalyzed on platinized charcoal (5 and 20% Pt)
Card 1/4

Contact Transformations of Cyclodecane in the
S/020/60/135/002/020/036
Presence of Platinized Charcoal Bo16/BO52
at 300 and 310 0C and without tear gas. It wai shown that the major
part
of cyclodecane iv transformed. After rectification, the catalyzates
were
chromatographed on silica gel, and their Raman spectra were studied.
The catalyzates proved to be complicated mixtures containing
aromaticy
paraffin, mono-, and bicyclic naphthene hydrocarbons. Naphthalene
and
o-diethyl benzene were found to bo most important. Small amounts of
a-methyl indan, ri-butyl benzene, 4i ndan, and o-methyl benzene
were de-
tected. Approxime,tely equal amounts of n-decane,
cis-.decahydroazulene,
and 1,2-diethylcyclohexane, a small amount of trans-decalin. and a
hydrocarbon of unknown spectrum were detected in the paraffin -
naph-.
thene part. The formation of decalin. and naphthalene is obviously
the
result of traneannular C 6 dehydrooyclization, while
decahydroazulene is
obtained from cyclodecane by C dehydrocyclization. This indicates
that
5
C and C dehydrocyclizations a!:e caused not only by the closure of
5 6
open chains, but may also occur within a cycle while bicyclio
systems
are formed. Thus, n-decane can only have formed in the catalyzate by
cleavage of the ten-membered cycle. Since hydrogenolysis; has been
Card 2/4

Contact Transformations bf Cyclodecano in the S/02 0 16 0/1 ;,'
5/'C, a2/0:)
Presence of Platinized Charcoal BoRBO~Q
achieved only in cycl'es with no more than 5 hydrocarbon atoms,
this ob-
servation is of fundamental importance; Hitherto, the formation of
o-diethyl benzene and 112-diethyl cyclohexane has not been
explained. It
is pointed out that none of the traditional reqctions can be used
to ex-
plain this observation. The followinb, reaction!scheme is
suggested for
cyclodecane on platinized charcoal:
CHI- CHI - CHI - CHI CBS - CHI - CBS - Cl 1.4 - Clio - CH-.1
CA13 C-H&
CHI - CHI - eHt ~- CHI Clio " .1
ry,
CHI --~'CH, - CHI-'- CHI &I-
CIHI CIHI
The remaining hydrocawbons detected in the catalyzate were
probably
lormed by secondary transformations. There are 4 tables and 9
references:
6 Soviet, 2 US, and 1 Swise,
Card 3/4

Contact Transformations of Cyclodecane in the,
S/02q/60/135/002/020/036
Presence of Platinized Charcoalk B916/BO52
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M.V.Lomonosava
(goscow State University imeni M.V.-Lomonosov). Komissiya
po spektroakopii :kkddemii nauk SSSft (Commission of
Spectroscopy of the Academy of Sciences USSR). Institut
oxganicAeskoy khimii im. N.D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni
N. D. Zelinskiy of ihe Academy of Sciences USSR)
SUBMITTED: July 20, 1~60
Card 4/4

B/020J60/135/003/030/039
Bo16/BO54
AUT~ORS: Khromovj so-lot gal ikova, YA, S.,j Lishenok, 0. Ye_,
and Kazanskiy, B. A.9 Academician
TITILE:I Catalytic Transformations of Cyclononanelin the Presence
of Platinized Charcoal
PEVIODICAL: Doklady Akademii nauk SSSR, 100, Vol. 135 No- 3,
pp. 627 - 630
TE4T; The authors report on their experiments to clarify what
transfor-
mat,ions cyclononane undergoes on platinized charcoal at 30000. They
found that about 96~o of cyclononane are transformed. They determined
in
thq reaction produdts (approximately in ~): indan 68, 1-methyl-2-ethyl
beAzene 22,*n-propyl benzene 2, and n-nonane 7. The authors conclude
from.these resultsthat tivo main processes take place: a)
dehydrocycliza-
ti4n*of cyclononane t'o hydrindane, and further dehydrogenation of the
lalter to indan,\b) direct hydrogenolyais of the nine-membered ring to
fo;m n-nonane~. The enclosed diagram illustrates the transformations
me4tion-ed=.e authors explain the formation of n-propyl benzene and
Ca4d 1/2

Cajalytio Transformations of Cyclononane in B/02ol6o/135/003/030/4039
thin Presence of Platinized Charcoal Bo16/BO54
.1-rhethyl-2-ethyl benzene by the following process: During the hydro-
ge4olysis of the five-membered ring in indan, two C-C bonds are
ruptured:
I)fone separated from the benzene ring by another C atom, and 2 one
ad5acent to the benzene ring (the latter bond to a lower extents. Th'e
aulhors explain process a) by the formation of's new bond between C,
and
C5i"-' the nine-membered ring, apparently due to the sterio position
of
carbon atoms in the cyclonoriane molecule. There are I figure, 2
tables,
an4 11 references: 4 Soviet, 2 US, 1 French, 2 Swiss, and 1 GermRn.
ASMIATION: Moskovskiy gpsudarstvennyy universitet im. M.V. Lomonosova
(Moscow State Univeraity imeni M.V. Lomonosov)
SWRAITTED: July 28, 1960
Figure
Ca~d_2/~

TUROVA-POLYAK, M.B.; BALENKOVA Ye*SL*j-SO8NINAt I.Ye.; KOOHN., S.I.;
YOKINA,, T.P.
Isomarization of polymethylens hydrocarbons under the effect of
ablviiymm chloride*' Part 14: loomerization of oyolononane axd
cyclodeoane.. Zhur.ob.khim. 31 no.6al976-1981 A 161.
(MM 14&6)
1. Moskovskiy gosudaratvennyy universitat imeni M.V.Lomonopoira,,
(Cyol6docane) (Cyclononane) (Ioomerization)

I
BkZMOVA, Ye.S,- XMOMDVP S.-I.; SHOKOVA, E.A.; XUCHERYAVAYA,
N.N.;
STERIN, Kh.Ye.; KAZANSKIY, B.A.
Catalytic conversions of cycloheptane. Neftekhimiia 2 no.3:
275-279 My~e 162, (HIRA 15:8)
1. Moskovskiy gosudarstven'nyy universitet imeni Lomonosova i
Komissiya po spektroskopii AN SSSR.
(C.Voloheptane) (CatQ'Yals)

SHOKOVAt E.A.; KHROMOV, S.I.; BAIENKOVA, Ye.S.; BOBROV, A.V.; SM N,
Kh.Ye.; KAZANSKIY, B7.k-.--'
Catalytic conversions of cyclononane and cyclodecane in the
presence of nickel catalyat. Neftekhimlia 2 no.3:280-287
My-Je 162. (MIRA 15t8)
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova i
Komissiya po spektroskopii AN SSSR.
(Cyclononane) (Cyclodecane) (Nickel catalysts)

Bj4ZWaVAr-Ya.S.; ALYBINA, A.Yu.; AVDEYEVA, T.I.; KHROMOV, S.I.;
KAZANSKIY, B.A., akademik
Catalytic conversions of cyclododecane in the presence of
platinized carbon. Dokl. AN SSSR 155 no.1:118-121 Mr 164.
(IURA 17:4)
1. Moskovskiy gosudarstvennyy nniversitet im, H.V.Lomonosova.

BALWKOVA, Ye.S.; ALYBIVA, A. Yu.; HOCINOVA,
11HReVulf, z~
I I . 1 0 ;
XUAIISV7, P. %
Catalytic c-niversations of cyclowidee-ane in the
pi,c-,,,Pnce of a
-I * ~ . I U& 4 .
, 11(ir-tel'.11in- -
( A, WtO
Its Moslovski-,,- imen-, Y.14. Tcmono-
sova, Kafodra ldiimli nefti.

I I
.~a XT-TA, S.;,KFlAFlZ,)VA. N.A... FR2.11K, MJ.; FURq-[OV, S.T.j
KAYANUTY, B.A.P
9 --16
akademik-
Transformations of methylcyclonor."& 'An the presence of a
farroplatinum
cataly---t.. Ookl, AN SSSR 158 riu,100.112-11"I5 0 164. (MIRA
17~10)
I- Mo�k5vakiy goaudaratvanzyy txniv,%rs!Lr4t im- M-V.1-moncti6va.

--- -- - - -
KHROMOV, SII.;-DORZHIN CHULTEMI-BALENK0% YO.S.
Catalytic conversions of 1,1-dimetbyloyclobexane on platin=
catalyste at increased temperature and pressure of hydrogen,
Neftekhimia 4 no.314'13-4,16 Yq-Je 164. (MIRA IW)
1. Kafedra khimii nerti Moskovskogo gosudarstvannogo universiteta.

CntalyLlc. transforuiticim of I 'ci
on I)Iatjnz%,:i catalvats under
c oi ict I L. I)IT1.1011 e
Aona of elovated tv!nport0aire und hytlroimi . , r
Vest. Io,-,k. un. Ser. 2: 20 no.1:51-55 Ja-F 165.
(:J] PI 18: 3)
1. Kaz'edra khi,:,.Ii IiefLl- 111cskovskogo univer.,-itcta.
I

BAIDIKOVA, Ye.S.; KIIAFIZOVA, N.A.; KHROMOV, S.I.;
KAIZI'kN-SKIY, B.A., akademi',--
Conversions of methylcyclooctane in the presence of
platimun
catalysts, Dokl. AN SSSR 161 no.6:1329-1332 Ap 165. (MA
l8s5)
1. Moskovskiy gosudarstvennyy universitet im.
M.V.Lomoncsova.

13AIT'NKOVA
X, Ye.S. YWAFIZOVA-N.A.; KHROK)IJ, S.1.
Conversions of cis-8-methylhyndrindan in the presence of
p3atinized carbon. Neftekhimiia 5 no.6:797-800 N-D 165.
(MIRA 19:2)
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova,
kafedra khimil nefti. Submitted Dec. 31, 1964.

PURKAYASTHAp R.; BAMOVIC# A*
Strecker degradation of vL -amino acids with 13_phenyl-o_O_,4-
dioxopropionanilide. Croat chem acta 32 no.2slO9-110 6o.
(EHAI l014)
1. Chemical Laboratoryq Faculty of Sciences, University of Zagreb,
Zagreb, StrMswWerov, trg 14, Croatia, Yugoslavia.
(Amino acids)
(Pheny1dioxoproplonanilide)

14

nr mi-i
3.lvr,i m w la". concd. Ila a 0-,
Fidded Rnd the tnivt. let stand ovemight At 0' to give 10
C.
m Wx), (detomrn.A I)v adli~ M
On
'M hTs., afid cr)r~-

INN DL-Beft Vachyl ith".
A I r 1 5 014 4 - IS I I A C

Aiiakp

5% HU. afthnizallan, extn. %v;ih FoO.kv md evnp-j.
-0j.
IfilYu 6113.6 T 1.5 g. IX V inin.
77
-41t
-),IQ6 RD4-1 fir,
MUM
9.
_-Awl %vh'

DAMNOVIC, B.; FUZ, D.
Syfithetic studies in the chloramphenicol series. IV.
Synthesis of a
threo-DI,chlora-,aphenicol 11,ase from DL-serine methyl
eti.cr. p. 149.
CROATICA CHEMICA ACTA. (Hrvatsko kemijsko drustvo,
Sveuciliste u Zagrebu
i Hrvatsko prirodoslovno drustvo) Zagreb, Yugoslavia. Vol.
27, no. 3,
1955. (Arhiv za kemiju) In English. -
Monthly list of East European Accessions (EEAI) ILp Vol. 8,
no. 8, Aug. 1959
Unel.

DAIal,Wlcl K. Yu_-Qr,,.-Iav
With M. bladenovic, "Action of thionGl chloride on
acetyl-a-cleLlOlic acid,"
Chem. Abs., 1940.

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so 1111111 &CUMINYWR of rabbit musde.
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see The at list Immilt,J Ity lite
by
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rabbit musifir rawailml J.alt jig. mclill ill
c7be Acti'le"'Ife"t 1"'Awl- 61-it
Ontcnt. 'kich all allimilit (if at-till call 4*11W ma%. arli.
valkxi (4ithc myoniij M-Aut ill usilK,le (1;1P', am-liesty).
ZOO
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arfi%itv. J'lv4" Fift.11%.
too
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MOWN; K*
Yugoslavia 030)
Technology
Contribution to the knowledge of the polyoxo-
compounds. III* Sym-dibenzoyl acetone* pe 41,
Arhiv Za Kemiju, Vol. 18, no. 1-4, 19L6.
East European Accessions List 11 Library of Congreso,
Vol, 1. no, 14, Deco 1952, UNCTASSIFIED,

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1
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0 0 0 Ill 0 0000 0 0 0 0 0 *go** 0 00 0

00
a 000,

0 logo 0 0000 0

a M."40
T LI-A T &V.!% 11
oq Ai
add
KVkkMI6 and D- Sunko (UIIIV. 749mb, )vio- ~00
go el list)
00 In 4(V CC- hIrOll *&% trealvil with 2111k) 00
tv, 0, KOII' III small parli%M14 and Willi cotiling. allownt
00 to stand IN he%. at 25'. 3v%4t. lor 1160 whied. the wititle
-00
Acidified to Congo to at 0'. exId. With litio, the ICIA) -04
00 a exts. dried. theAeoll and tltvO removed i's Krue, the *00
00 'Il crude residue (20-211 9.) dried over 11,Wk in a voteitum
desiccator. dissolved in A) cc~ alK. VIO, and too cc. pett.
00 1 ether (it. 30-W') added. Ott rotQInS to ()* there wool
=00
ttlotained 8-0 g. plait
00 a -s, In. %0-7'. Recmtn. from Pilo.
IWIr. t(h IlxCI1rCOCiI,COJI (H), in. No. which 6 410 0
00 a gave a M=111-red coke with FeC4. 11 (0.30 g.) wai
go a twitted 15 "Llo. at 110'. Cooled. irmted with Rt#O, the
U*1,0 PoIn. washed with NsIICCh Wit., coned., and the to
00 W :
residue subillimed at 2r) min,land 110" to give 0.17 g. !go:
00 a 11310firCOMe, m. M-9'. n ( 9.) In 110 cc. concill. IGSO.
let stand at 0* 10 Inin.. then poured an let. gave 0.0 It. so
ISCO-CII, _COZ1qPh. In, 243 - Wom q. k.), R (3 ;a
In 6rl( ale. IICI after 24 hn. at room temp. rAve 145g, s
Id. The trearted hydrolysis of I by mild alkali to give
zoo
C"I only 1401,420JI t1tayer and Perkin, Ber. 17. 0408901
could M be reprateil since no exact exgl details were
Z
19W.A.-A i", given. arry L. Yale tso 0
boo
0
o
U
too
t
dAW
U it &1 00 111, 1- 'ov -tort It goo R'['Wql Ittia 118(KWA 1:1,
loooo*ilo*ooooooooooo0000041!*Ooooooooooooo00000'
i-T-0,60660100011111000 00000000000 Oleo o 0 000000 000000 000,
n: I

Amino &d&. V. Unction of V-&Buh4dtut*d Slytyl
tMorid" viak diumothut. A now synthesis of some ti.
alastine derivatives. 114denovif, %. Urvii-ant, D. Crrar,
And NI. TkAlkk (t' Z--'b Vutosl&via). J. Org.
CA,., 10. TCU'A. 45, 04179A-Whrtt-4,
N-itkoutnulmitutrd glyc I clik-Li,. (1) and ClioNt swe
( %AK4onts, X.N-disubst1lut"I 1. surb u RCII,COCI (III
~k - P.C*114(CON\ throughout the ahair.). give SCH,
COCHN. (11111. 11. prepd. by frhuxins 7 g. RClI,CWl
K4-.S*. AddiuSirriulu,
Ally 7.5 S. 11 in W cc, ether 1.1 CII.N. from NO a. NIC.N-
(NO)CONII, In SM cc. ether at 0' lives 751,; In. tn. 08-
(dtx%,tnpn ). Heating 2,3 X. III in 30 cc. EtOlf with 0.1
S. AffO in 5 cv. KIM gives.33% RC1I,CfICOjQ, nerdir.,
in. -,;.' 3'. Treating 4.0 g. M tit 25 cc. AcOll %ill, 5 tv
fleating
019 s. III in 30 cc. CUM at 60-70* and adding 25 cc. 11.0
(1-1 M CnIK-41. )I M,4 give fWI% RC)I,COCIIA)11, In
142 licating 3 C. III with 20 cr. AcOll at 1,04111" give.
-119.7% ROWIRCM0.1c, m. NO W. Refusing :1 s. Ill
in I(%) tv. McOxf with 1.5 S. Imm4. CuO 4 hn. rive, Sk%- -
R01,O)C11.0mi, m. 89.5, (Imidathazoar. M. 3XII; :.Z
d1f11lr#,phrm~14yd;aw%r, tit. 20#'l. Ifealing3g.111in'01C.
PhOl 12 -3 hm at fX)* gives 4119,' RCH.WC11,011b. privu%.
tit. I.W". Relluxing 2.29 C. iff ..d 2.29 g. pkic M in
.%[C,CO 0.5 hr. gives 44% RC11,CY)C11VOcs111(,V0,).-
pale yellow nerdics. m. F. R. f1rauns,

K. YUGOS-ILIV
With D. Brovet-KeGlevic, "AnIno acids (IV) spiti-'esis Of tile
holmoloEy of I-
leuc:bie ------- s3mthesis of B-araino-d-nethylcoprdic acid," Cheni.
Abs., 1952.

T! ZrA TTO?ttrt,~, ,I
E'N't EM MTzr3p--1j 0--o-

, , , , , , , ~ r
- , , n . - " - .
I' . , - c I I - .
I , 1 ~

BAIa"n, 1c) K. Yugoslav
With D. Flea., "Amino acids (VI) s)mthesis of
L-B-amino-d-benzy1thiobutyric acid,"
Chem. Abs., 1953-

I - I-
aul V %.,) &.
With D. Fles, et al,
Chem. Abs., 1953-
Yuzoalav
"Synthesis of W-B-aminobutyric accid frc-- L-al.~iue,'w

.---4;euiitry # YUGOSUVIA T
CatOC;OrY: Humn *and Anizl PhysioloL7. Intornal Socrotion,
Pancreas
.*.bs Jour: F=iol-i NL"19) 1958s 89008
Author : Fister, V.; AlloGretti, N.; Zaj!~,~ Munk, R
Iast : Croatim Natural Science Society
Title z The DiabutoLcmic j',ction of Pyroi.wcaa~xics.
Orig Pub: Glasnik biol., sak. Frvateko pircodosl- drustvo,
1953 (1955) 2 Dj 7, 148-149
f,bstract. gyrovecason, (I) in doses of 80 Yvjkg causcs
diabetes in rate. Glycein cliangea arc eirdlar
to thoso followin6 adrAnistration of 'a1cxan.
I is toxic, i*~ dopmeses tho respimtory ccnter,
and the mts perish vithin 4 days. It is evident
that the diabotogenic action is caused by the
Card 1/2
T-70

the$
do
01
dritures I 31AWA iT&S. Still L-
OW, D
.-Addit. of 5.4. te. 48% HBr to 5 S.
co
),N('TlhfeCOCHN, in 27a m. HOAc and
~r. at rourn ternp. Ivith aw cc, H
98.5%
OW01,C1.600. I&Jkj -34.7 :1: 1841001481"w"CO),
------
-6rinveried linji Cdh N :u 15 in n. to 9$ V,
":
84k(l), It by romeopic solid tit M'(decompti.). 1cr -7.04
(P-~~-Yphexymutan-?-mw, 100c,'O, in. 76*, [al 177.6
pyridininni salt, 92%, in. 215'(de-
eorn~.) in).,
)B?. 100%, tn. 0-15' "Je-
1
cmpn,). Mixing 6,014 niole I In 15 cc. 11.0 and 4 cc. FtOll
with 0.014 ninta P-Me,NCjI1,NO In 70ce. EtOll,voollngto
6'. aldint 0.014 mole N NnOft during SOO min- and lUttr-'
-W AWFIO - k M --4* PVe 50% L-0-es#o(CO~NCHAle-
ng Cr. M it. a
CVC71:A'~-O)C411,A1M=er. (11). m. 153* (front dlomne-
RiO). SitniWly p .1 0-r4ff4cO)3m(CH#NCOC11:-
NHOXVANMe~-t, W% m.'154,*end the *40-n1dh3d-
N-Pkk94ry;l-Wyrosij:s6w) Ow4k, 02,,, Tn, IM'. Shak&A'
1,6t U. 3z C. 11 , 15 ee. 6N 11~90.' and Is cc. r-40
unt the H visis d6solved, thoroughly extg. the sq, layer,
with Elio, rmhfnjt the ext.. with 5N lf*SOA and
:11A 8 1 .!IS Dn ALA-mi; P-070 (.7XI.-
tJ'Wkdippgidodkyj)tjyo=l a green-yellow -41, let IV - 1.34 :h
4* (c 1.12, dry I'Ago, converted by refluxin hrs, In
&-0411ANIfs2to 70%
~OAc
with an equbnohv amt, of
sublimed at 150*7
.0 mm., M. 119* (from Moll), fall; 9.38 A: Or.1'
0.85, abs. EtOH). Similarly preM. In 93% yield.
imi"AArlyual 111). m. 06.51, was ' "verted to 78%
0. Soln. ofO.(X)4 moeu'DM and 0.01 inole
CgHt(SHN in 14 cc. 3% anhyd. HCI in dioxane and concit.,
to dryness after 4 days roorittemp. aveloo%bis(elhyll-
emmercOW), m. 21
k1hyll&xal (76% front the nitrane), ba..160'.
jalij 8.75 * 0.5 (c 1.50, 6,11s); quinoxalipst deriv. (50%).
m. 126% 1.1V -42.4 +- 0.9* (c 0.1. ahs. UtOll); bis-
.2~m* prier fill (82% p). tit. 140'. or, with I mol. Celle,
in. 72 (1 r41.$, I.JV -40 A: OV (c 0.40, -AWICO).
jOin W. Green

Al

X
Some derivatives of o
t!Eally act4c

.
p
Ask It *.Irll"%i~. N, lip"JillC
,

QV' 1,
ON
k

,
A R,-c:uinund-Zct,cI!c rdu liwi of alxiiit 15 .-phth-d-

1,C)l Olloride
~-. -I( Ilo-30, %%itil 51,~ I'd-ILISO,

-SIPWZ, of I IA. 1K I %%us
CV01%vil, wit'lling the

r,xf Ntilll 1'1~0. of 111L. hi:O from the
filtratc. nod

;".1A-1,- ill. Alfdo. if imil mult- NIIjCl to I 1111sle
I and

~1
l IC jl;t 1, ;t1 th, mkill, mot. nim litolt. diln" Itfit
r

"t
.1., "ills JI;0 wid it Iktil%~ NIII, And Et.-O imu.

di 11~ 11iLt ;1. 1
'lilole 1, 1.1 11106 (Cll..-

I'd J.' diox,:w 3~k, dry IICI at 20' for
4

'Y" , :11 4.1 Odg. 1120, cold it-cmieg. gave

ih- i,O, !, ,, m- i, pz
4, o- crystd. from McOll.

N N'-p,; !,al,
!-I it!5% yihl) tit I I"

,
I" I", - 'I I W I (,- 2 16 C. 11.1 , '110111at loll tit

it 01 111111,
(111 1 Ill. gJVV 11.11ti.11 1:11THIllution: semieds,bowne,

tit. 226';
tit. 203-41% di-lit

acclut tit. 53% lal'S -2.7 :1: 0.3* (c 3.7 UtOll);

ethyl
invicaptild, m. 06" (rucetusite, 25% yield obtained

iz
from irl McOll) Itl6w. of the mother liquor tit lWiO'l
0.03 min g3kire 70"1 a.fiv, oil, (olo 48.7 :h 0.4" U 2-16

akichwt?
(6717.1 tit.

Its

"D 4: 0.5'; dism. at I~ "10frm:11.1i2w,
-14
P.'
i153., b#T7AW7"j.'j P,1 - 4.7 +. I . 4 5
ig ~17yk.! Pt
IDI'll -M.140 :1: 1 1). 0-Meshyl-N-phihalpyl
Mehyde (1M%) m. 88* (mJ14 -150 A: I' (c 0
senticarbaso;Poe, sit. ih-9 , di-Et acelaf (81(i.
14-m 100% fal it - 108' _+ 0.4* (c 2.30 Ht,0)
(distit. did not
cbtmgc the ~)); ethylene mercaptal (89%). in.
IVI*, 1.1'a
-105+0. (C0,11CII.C1J. Refluxing the Uc':t1II mth I
"lole MHOW In E1011 for 11 mill. tenloved tile
Jv.N-
phtImloyl gtoup Fa the insol. h,drazide (11)) And
COUCH.
$4 mcgla of the filtrate Fave tlc following
couilkis. Tho
"'I'mptab werr similarly treated for 4 brs., A'
IICI 3dika
to OIL mixi.. and the mixt. kept at 0' to givv
inure 11; Ow
filtrutc treatc-41 uith execis NII,011 alid cmd.
mith Mso-
-Alanima aldrhWe di-Et oretat (3dP') b Da-10 (hath
ICI); f-thyli-11'. wet,
0111 I~S -* 0.3& (c I..I">
captal(070 ).1),t 1-16-551, i"Pl, mi, :L 0.2' (c
1.9,14C11,C)'),
MIA -21.0 + 0.2' (c 2.40 ribylene jormip!.d.
N-14 fail' -10 2 ~+ I'(cO.021CA1.). 0-3h.1hyl-i -
lyroske ahhl;~e-di-Et 'a-'elat (SO.5%) after
1mrificati I -,
an AIO, colutun, h..n RKV, fail,* -79.'_~ :-. 0.1'
Ic 0.73
MIMS)- J01111 W. Or"l,

-,:'Wcr,c fitid
Vill
I-A-jAi"it bPj) in
r~v;llilm throng)]
Ai lmlv 210- ---,J
v'r ~31

-tD MUMS knd tM ll~t dhw,~4

-raticm cd optic
A.

. . . - -
I- I I
- 1 1* - ; I . ! . . .. . . 1 :1 1 - I ., I I ! .
. 7 1 1 . .

um vith a Poo,

tericki by Nlycr On,., atograrby of A on Miatman No,
Euu;csceuct could oc dei,ctr-j. lp gii aat-nwi to ~rd
-Int, it, mmr."eni, Ivy I Cro!",

I/Th, III I~ol~
LIP!
i A Jj.
LL,

YUGOSLAVIA/Organic Chemistry - Naturally Occuring Substances E-3
and Their Synthetic Analogs
Abs Jow : Referat Zhur Khimiya,.No 2. 1957) 4),63
Authot : Balenovic K Dregant). N., Gasport, B., Jambresic, I.,
omas.c, 0
Title : Some rerivatilieo of L-Cysteine Aldehyde. An Improved
Preparation of S-Benz.VI.N-Phthaloyl-L-Cysteine. Amino
Acids. XXXI.
Orig Pub : Arhiv kemiju, 1955, 27. No 4, 207-210
Abstract : A method has been worked out for the preparation of opti-
cally active S,.benryl-N-phthaloyl-L-cystein (I), which
has been converted into S-benzyl-N-phthaloyl-L-cystineal4
dehyde (II); a number of derivatives of 11 have beCL
prepared. Mixture of finely comminuted S-benzyl-L-eys-
tein (0 -033 mole, I--- C/- '7 D -1- 280) and phthalic, anhydride
-4
(0-035 imle) heated (bath temperature 130-135-) while
stirring, for 30 minutes, dissolved in C6H6 and from
Card 1/3 - 119

YUGOSLAVIA/Organic Chemistry - Naturally Occuring
Substances E-3
and Their Synthetic Inalogs
Abs Jour Referat Zhw - Khimiya, No 2, 1957, 4563
filtrate I tis precipitated with petroleum ether,
total
yield 90%-, Mp 108o, C_,