SCIENTIFIC ABSTRACT BASHKIROV, A.I. - BASHKIROV, A. N.
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CIA-RDP86-00513R000203820011-4
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RIF
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S
Document Page Count:
100
Document Creation Date:
November 2, 2016
Document Release Date:
June 6, 2000
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Publication Date:
December 31, 1967
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VAJ:I,IYi,V, Yu.E.; RAISUTCV, R.I;; A.I.
Experimental study of the stru0ture Of oil and gas
flow in a
flowing well, Neft. khoz. 39 no,4:41-44 Ap 161,
(MIRA 3.4:6)
(Oil reservoir engineering)
. ", ; . I 'v ~.-.
I . , - ~;.h 1.'T
i3,K,, -'., '. "Ixru,"ni,
Approximate sOlution of the nrohlem of the flow toward
a well with
a horizontal joint. Irv.AN ~~R.Otd.takh.nauk-Mekh.i
mashinostr.
no-5:183-185 S-0 '61. (Hydrodynamics) (MIRA 14:9)
BASHKIRM,, A.I.; BRISIMU., A.A.; VASILIYEV, U.N.;
ILWUTOV, R.A.
Propigation of elastic vibrations in oil wells.
Trud7 VNII
no.35:3-10 161# 6i1 Vella-Vibration) (MIRA 15U)
77]
AMBAY0, 1) VASILYEV, Yu.,N,; MK5VTOV,
Fathods and results of the experimontal study of the gas-oil
mixture flow in a flowing well. Neft. khoz. 39 no.12:38-40
D 161. (14IM 14:12)
(Oil reservoir engineering)
ARKHANGELISKIY, V.A. (Moskva); AUZBAYEV, D. (Bugullma); BASHXIBQY-A
A.I.
(Bugullma); VAILIIYEV, Yu.N. (Bugultma); MAMTfiOV, R.A. (Bugullma)
Investigating gas-oil mixture flow in gushers* Inzh,zhur. 2 no,1:55-
68 162. (MIRA 15:3)
1, Institut mekhaniki AN SSS i Tatarskiy nauchno-issladovateliskiy
inatitut.
(Oil reservoir engineering)
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*00
forms approximately 20f. Us styrone-aan be separated by
Worination 2e0
(at a t
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approximately 100 . higher than xylol, and from which It say
be o
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diddaro 3:gs
sell oompouDd &a obtaismKo. the styrene may be regenerated by
do- go*
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5OD-550*C.) lee
9 of bogiron ore. Ds Worinstionj oarried out In the upour
phase 0#0
(15-2D) at 275-180*C.# Is strongly exothermic and oooUng
arrangements age
If
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I f! WhoproduA obtained is of h1gh purity.
0[! was
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it
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Catalyst 00 which a cbrm- reaction in taking place. and
e
on in rt substance placed In the tube. In
l
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l
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1010
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00
loviloortly d8lds. plovielvel the I 40slity factor I in
==
00.31,
0 - I (dRIIII) 1% ottiliclently
I of the IMP.
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0
trinjo. inde-pendence of tb* beat of reaction, of the auto of
beat rateocities, and of the brat conductance, wall tested
6613
esiominwalally un the oxidatkin W Cu on a Kitelvisubt
go.
Ca"Irl
M 3143' and at 1111", whereas at 248' oaklation Is
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CORM
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wall 2747%
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.
26.7974, by mullytiad deta.. cort
iw-
caft". is permissible.
for
gorneval procedure
Identic measurements involvin
a ti
l
w
n
i
t
l
t
I
o
co
s
s
s
o
n p
g
g
n.
will
to agalmot the time 1; the am led The not of a
is to
tocisess. the curve and the tee ve of at
ordinte times to
Z
1
1
and 4) - 9 Is, - it.) where x - am of
:
reacted
J
Integration from 8 - 0 to I gives the wee Ix. Ther
of the gas in the resectiou none bring mist., the rat
of Jr.
action (unlorm limited by the pencirestiols of Ot t b
a
SMI&C 0%W alai) dxld8 - & (a - S)'.W V - AV (a - X).
Is the case
of a finot-order reaction. tilt plot of oloagalast
Is is straiglit Use
its *
gives the rate e4ed. be the
H
1%
1:
L
&
ase Me y6naw I& a Initial amt.). 7U error
r
ft
1" I I of
F
U It
&1 00 Ati a K a 11 it
.
000 *to* 9 111 0 0 00 00 0' 4
due to low at brat Is imusaierial dil-
fermeor does met exceetl That for w of
cooling Is valid. anel the total brat capacity. brat coad..
and the beat of reaction are practically comet; in veto
range. (2) R t made on Co ;"a by
100 MI %7
&.;I ,b 2.6 S. C" las Ult) in --b
mi. HjO. pietse. with KOH at 100", washing witb hot IIjO,
drying awl ustmUlin
& to cylinders 2-4 min loing, steel
herviting I A hors at The therrineecoilople was di*Uwl
between 6 mi. of the catalyst and a Mi. of S" Cylitedess.
sited. toy inim, plaml in Ow sAtur luter of .1 &w. diam
The catalyst was reduced to Cu by If. &1 6.6 1 .he. ml
946". thilalkm at M" with a dry gas mist. of 2.61, Ch
+ 97-h% No, &10 I.Ar.. was complete In 441 ruin.. furth; I
Imsoooogr tof sit causid no drile"Ina to the galvancomelcr
(in sucivulve tithiallious of the slault ralslyst, Itellowillit
relocated te-ducthon-. tier integral* c"froolotioding lei Ss
incresard teguloaly tor.j. IV?. 210, W4 oil. cm.). indi-
cooling increasing activity of the Cu catalyst. At W". in
an air stream at it I./hr. the reaction come to a halt after I I
gain., furtherpassage4alf causingtiochalWalo,. From
the total area qr. read on The v (1) PIN. as cousparrel with
the area corresponding to IW% ozidatimi (at 245 1. tbor
degree of oxidation at 80" was 27.37q of the C rese t
(1hatoxidiseds1245"). (3) Bythe linearity ~WS~ Plot
of vo, against the jx detd. by readings at various staIrs, thr
fraction &I FO' Is of the Steel order. with 11 O.W (lime In
Than
IF
1r I v Ls F" 0 9 a a )
0 00
:.go
i-00
00
1 -00
1-00
!.go
.00
coo
.06
.700
are*
1;00
U4111410
tu
wee
BAMM~vp I-. N.
Bash'--irov, A. IT., Stepanova, V. D., and Sukhotinskaya.. T. M. A
sel-etive
mejthod of processing primary tarn", (Report 1), Trudy Monk. in-ta
tonkoy ldiir.
tekhnologii In. Lomonosova, Issue 2, 1949, P. 43-58, - Bibliog: 6
itens,
SO: U-3'42, 11 March 53, (Letopis tZhurnal Inykh Statey, No. 8, 1949).
BASMIROV, A 11.
,azin in the presence of
Bashkirov, A. N. and Vinhirova, T. D, "Cracking of kor,
aluminum chloride". Trudy Mook. In-ta tonkoy Vhim, toklinolof:ii im.
Lomonosova,
Issue 2, 1949, p. 66-69.
SO: U-3042, 11 March 53, (Letopis 'Zhurnal Invkh Statey, 11o. 8,
191,9).
IISSRAnginearing - Gas Analyzers Gas Analysis Nov 49
"Gas Analyzer for Two-, Three-, and Four-Component Mixtures," Yu. B.
Kryukov, V. V.
Kamzolkin, A. N. Bashkirov, Petroleum Inst, Acad Sci USSR, 11 j,p
"Iz Ak Nauk SSSR, Otdel-Tekh Vauk" No 11
Proposes new-type gas analyzer for analysis of two-, three-, and
four-comronent mixtures
of CO I CO H2, and N2 (or CH ~. Provides for automatic analysis at
various rates cf
Fas ffow. 'Apraratus uses rhei;eters, and calcium chloride and
ascarite tubes. Submitted
by-Acad S. S. Nametkin.
PA l5crT13
Modmdoes of the orutheala of b
'
*--b- 'rene
trwalion Ut orcWting shimitan"waly with It. Ow
twkwir
a
!
A
ewbo monoxide end t1
fm
i"V + oll- + + V/Is
2) COI +
i
Vu. It. Kryulmw, and V n.
"
011.0 4 (1 - x - OCO + (sa x + alit"
% were 9 w niole fraction CC) reacted arowdin
to e
uation
SOO S.S.S.R. 67. I(rjv-3ItIq4q). The rwtjim ob.
S
q
t)
)
d
H
C
Ill
i
l
h
i
l
WVW an F0 Mtslysts. 2 W + III - X
"
+ C".
Ino
r&
1wr ow
e
C
Ill t
. an
e Init
a
PD.
e
-
ts confinsf to the r-clion CO + 2 11, - -C + 11.0 Ill
t
1
h. wartioll k. In t1w 1.1 _~. I. b - 24/f 1 4
U)
A
amaving on Ni mail Co. ts atter1wriftl as the am of the
'(1l
timitent in i he IwAuluct). nt the 2M
It% twfv d w L caw,
JWUMArY MCtkIO 11, and the subsequent Kcaudafy reliction
6 -
13d/11 + + 200 + "Ill. The
CO + 11,0 - C(h + Its (1,11). This point at view is
'ItHrmweA -
At - Vist terme,l the contractioll. depir-2dion
Ar
cqwTebarAtc-j
tYY ASWIYWSW the pavousprodwsobtained,
d
F
haFifunentally. A altAnts laj~l values. up to Oll,--alC4.
Oll to 21).
11,0addini in onts
of the reacting IrAl mist
.
on pilt
ir catalyst. with mists. COAII a 1:1 in the
pnmcwv of adalvAl 11,0 vapar, at 220-60* under aten prve-
.
.
,
is fintrul tit have rvartni conipletely scrolding 1.1111. r,j
00
suft, at spam vrlovil y - 100ihr. The b
wtill an initiAl
inixt. CO It. IlrO - 44.5:44.5. 11. an an
'
'
lion 1. is TXpMw4 by CO + will - 1/9 a
T
Fe-Cu-1n-KWOAWwtguhv c
atatym, at 140
.
00
i
t ODD + (I - x)CO + (we - 1/, 4119, where 11010
30)6% A cipti.
- ralol. - 21 .4%. A CDC
CC - 1:1 34 13
00
IrAction Co "wird. of tiloir. 11, 1.-1 nioi, co wilb
,ou all
'
"
vlhr vatalvat, at X141
, g4vr 4 iwg. %NvvittactWn of -32 Al
p.
' '0 , "" . A - 72 4"~; l1w VYWhIol Ilydrovaltetwo,
,i I, lip. I'm is Tral,111-41 *bell 110, is elitninalvil.
IC*
T
S
fAtio tit the tales of reactions IU Aiul 1. on the W
Cat.ilyst, tit 24(1*, i%:1.4. on the 2nd catalyst. at =111". it
is
13.0. The ptimary reaction tio Ni, Co. and Fe is. identi.
Cully. TrActiOn 11, And L'th 1% 3 W"414AFY IW11kItWt,
14. TIUM
1111141,014141,116t 1,111MAItOll CtatUPICIVIOU
Ewk,wCf,/ saftorg ----- --- ...w
V-1f- r-4--r-T-17 v 1 4
b u AT 10 It' Is a to 0 4 a a it It K a a It
;o ,
-Amim
ir-11-T, 71 --- Aft- -1-1-4 rw o iii a I w P 0 61 0-) _67-10,
us a I is
4111111
*00
41111,411,
=00
9*0
we 0
bee
Ilk 0
- -.. ~"- - 4z _`_-- --- , , , . ~ .. . I- - , '
, ~ - ., : ~ .-
t~hemical Abst.
- 4
Vol. 4S No
Feb. 259 1954
Fuels and Garboulzation Products
lole tion of indepjrum ~Mdg coauff biizese. A.
lair C
..d. h -. p-1,.'7'= -
--Crude nzeDe is
distd.. and the fraction b. 170-1920 Is removed and treated
with 16% N&OH and with 317, HiSO to remove pbencis
-and excem allmil. The product L dtied.~d then chlorinated
at -3 to -5' while the mixt. Is v4wou311 stbred. The
chlorinated mirt. h distd. at 8-10 mm., and the fraction
contg. CoElsCit. indent diddoride (U), is removed at I IG-
182'. About 90% of Indent Is converted to 11, which is
reduced to indeve in about 90% yield with Pe and steam.
11 6 dechlorinated In the vapor phase at 16-20 mm. and
175-180'. The reduced material is again vacuum distd.
tlo Add Indent, C4H,. b-in 181.4-192.5. d,': O.QM x~*
1.5754. mol. wt. 116.8. m. -3.1% picrate w. 97.0-98.0*.
Geonte G. Rtrnar~ '
Cfi
b Co +
+ CHl + COs. and
CHO + HA, od 00
M C my 0 a rosaft of tw swo-Im readion
A
ChWWOW* H .,.jkmWdksAlVby&-
co + so - C04 my :L;t" onalact tbo pm-td tb.
elpts. in obkb a v Appm
Miami" reaction lkam tAkbW DbKt -clable
eamt Is me WOO Valk ioW HIO ih Pa.
wm, r"NW"d coodlostion betWOU WOO 10 fgmted
:H.-
tU MW
;2 add. at SWO do-O 84 a Poo-O opw
rk, 012"s
"i al
VIETKAW Wo ad r*CVW. wkh tbt
. a"
W.
- &*Wow at llwl-t~Zldrl odw them ton
U-b 90,
I. so PITW#
COIL A.. t
CE6 100.0, M 6-tca. in. OW no IIIIS
1,4 41 tbeanva iN+ Hi cli, + CO, and
JW 40 CO, UL OW Ft aike. CO,
CIMI, tbrou& a ,,,dary fenetwn between CO
?A Intr3ed N. Than
mod lu.
'the dii"tioli, IJ
"The 4tiestim ~ or
Hydrocarbons," A. N.
Basbkirov,
"Dok Ak Nauk SSSR" Vol
ILMCMVIII,
K
7'e~
Review subjecton basis of
USSR v
v
process can be mad to
proceed in
n
tion by appropriate choice
of con
n
ad
of suitable catalysts
(MD04 or ad
No 2). Cites exptl data
shoving
course of oxidation.
Describes e
e
formed in reaction on
course of re
r
cordizg to emptl results,
oxidatio
io
LISSR/Chemistry - Petrole=
(Contd)
phase proceeds vith
successive spli
terminal C atoms.
Describei oxida
C14 alco and aldehydes and
of.mixti
isolated from oxidized
paraffins.
Chemiml Abst.
compounds In the puth*~W 01
Vol. 48 No. 9 Role of Y",
a " u .
hvdfowunL from carbon Monoxide and h di~W.
MaY 10, 1954 i~d
Organic Chemistry Fir"Chem. SO.
~ Mk-!*-BngI. tmnsInflGn)------See A". 47, 3216
USSR/Chemistry - SynIthetic Liquid Pwlsf
TUI
Catalysts
"Concerning the Problem of the
Investigation of JAqi
Catalysts for the Synthesis of
Hydrocarbons. From' ~
Carbon konoxide and Hydrogen," Yu. B.
Kryukov, A. 1.
Bashkirov
"Trudy Inst Nefti" Vol 2., pp 92-109
The present methods for evaluating the,
performance c
Lron catalysts are inadequate. A new
method which. J
more precise has been developed. This
method, whidl
18 described in detailconsists in
determination of
the degree of conversion and of all
other indices
243TI1
rational utilization of analytical data
an the gaze 'i
before and after conversion and of other
experiment.
ally found values. The method can be
used for otbei
catalysts besides iron.
PkS&,I4-JV? A. N.
USSR/Chemistry - Synthetic Liquid Fuels Jul/Aug 52
"The Role of Oxygen-Containing Compounds in the Synthesis of
Hydrocarbons From
Carbon Monoxide aml Wdrogen." Yu. B,, Kagan, Yu. B. Kryukov,
Ye. V. Kamzolkina,
A. N, Bashkirov, Petrole= Instv Acad Sci USSR IIIz Ak Nauk
SSSR, Otdel Khim
Nauk" No 4, pp 649-657
Article states that results of the expts described show that
a1cs cannot be regarded
as intermediate products in the synthesis of hydrocarbons,
and that iron catalysts,
under the conditions of hydrocarbon synthesis, accelerate
the oxidation of ales and
aldehydes. Advances hypotheses explaining the formation of
oxygen-contg compds
(by-products of hydrocarbons).
PA 229n6
STORCH. H.; KAGIN, Tu.B.[translatarj; KRTUILOY,
Yu.B.Ctranslatorl;
LOKM, S.H. [translator]; LUKIWITS. Y.G. [translator];
PAWKI-
ROY. A.N., professor, radaktor. 1--amm"M
[The Fischer-Tropsch and related syntheses (original
title);
translated from the InglIsh by W.B.Xapn (and others)]
Bill-
tas uglevodorodoy is okisi uglaroda I vodoroda. Perevod 9
anglilskogo IU.B.Xriukova, S.M.Loktova I V.G.Luklianitea.
Pod red. A.N.Bashkirova, Moskva. Ind-vo inostrannoi
lit-ry,
1954. 516 p. (K= 7:8)
(I%mthine process) (Catalysis)
T_r I n-- t af t t A NS-,-Sk, Vol 4, 1954, 159-i72
1,2-Dihalogenated hydrocarbons were passed through a
heated tube con-
taining pyrophoric iron. The reaction products were
olefins when the poly-
merication and iscvetrization were inhibited. Using
this method, olefins
were prepared from 1,2-dibromo substituted n-parfinB
frcm C2 to C8, cyclo-
pentane, cyclohexane, styrene, indene, and
tetrabranocyclopentane. The
yield ranged from 80 to 90%. (RZhKhim, No 3, 1955)
SO: Sum-No 845, 7 Mar 56
BMHKIROV,,*,X,.; KHOTlMSILAyA, M.1.
Oondition of the dual relation In olefins obtained in
synthesis
from carbon monoxide and hydroxide. Trudy Inst.nefti
4:173-175 #54.
Off-IM 8..1)
(Olefins) (Carbon monoxide) (Hydroxides)
"A Study of Certain OYidated Catalysts in the Synthesis of
Hydrocarbons from Carbon
Monoxide and Hydrogen" Iz. A. Nauk SSSRI Otdel Tekhp Nauk.,
No. 8, pp. 147-53, 1954.
The composition and characteristic features of certain new
catalysts for the synthesis
of hydrocarbons from carbon monoxide and hydrogen are
described and didcussed. These
new catalysts contain neither iron, cobalt, nickel, nor
ruthenium as their basic
component, but one of the poorly reductible metal oxides
(ThO2, M902, A1203, etc-)
and are called, therefore, oxidated catalysts.
I
3ummary - 550423
lk VIA P,
A - I
I - - T I . - I . ~l . ~t , - I;
~ . ., !'-Y 4L~. ( w 4,1 Ll - - ---~l - -
.---
-,.. .. A v,-ut-t zA b !. -- I,
-lt~ ~', ~ -1
(01-7 : d,wlewing the (,,nta,t
litne to half reduces
~ - '. 1"."; ., 'i, :!-- -1 -, ,
- I !!.. , , 47
~ 4~~
M
MIM
-4F
-21~Z p"
sz;.-
A,u th.
7",
,4 .I
I
iz
I I
0
-2 ~ 11,
kwwr
BASKIROV. A.N., PrOfIssor.
3ymthesis of higher alcohols Of the f&tV series by direct
q=Jdatio,
Of P&r&ffl**- XhIM,lk&Uk& 1 prem.
(Alcohols) (p&r&f:fib) ~ 1 110-3:273-281 156. (MMA 9: 9)
��������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������-1
9
I
A '7e vz~
"I ffll
iR I-,
I m4w..'
T
USSR/Cherdcal Technology Chemical Froducts and Their 1-13
Application. Treatment of nutural.gases and petroleum.
Motor fuels. Lubricants.
Abe Jour Refurat Zhur - Khimiya, No 4, 1957, 12955
Author Baahkirov A.N., Loktev S.M., Khatimakaya M.I.
Title Co vZsUM5 Synthesis F-roducts rrom 00 and H2 over
Mi
Kieselgtihr Catmlyste
18-22
Orig Pub Khimiya, i tekhnologiya topliva, 1956, No 5,
Abstract Presented are the results of investiption of the compo-
tion of gaseous and liquid products of the synthesis from
,coN
USSR/Kinetics - Combustion. Explosions. Topochemistry. Catalysis. B-9
Abs Jour Referat Zhur - Xhimiya., No 6., 1957P 18633
opion that the special properties of catalysts reduced
in CO are connected with the carbonization of the redu-
ced iron and the formation of cementite Fe3C'
Card 2/2 273
MR/Physical Chemistry Kinetics. Combustion. B-9
Explosives. Topochemistry. Catalysis.
t1s Jour : Referat Viur - Khiraiya, No 2, 1957, 3852
Author : Bashkirov, A.H.V Khotimakava M.I., Kryukov Yu-B.
Inst institute of Petroleum, Ac4demW of Sciences USSR
Ti tIL: Synthesis of H)droewboha ;.'rm Carbon Monc)xije and
Hydrogen over "Sintered" iron Catalysts
Orig Pub Tr. In-ta nefti, AN SSM, 1956, 8, 162-167
Abstract Study of the effects of the conditjuns of reductJon
upon
the nechanical strengl.,,- w.,' activity of precipitated.!
',Ic-
tivated Fe-catalyate 'j, thc process of synthosis of 1-.y-
drocarbons. After troritment of the catalyst in a current
of H2 at 800-8500 ail(~ space velocity of 2000 hour-1 for
2 hours, the reduced air' sintere(I specimens ire of suffi-
cient mechanical (-urab-,.IJty; thoy tire inactive at atrios-
pheric pm-ssure and are tictive at % pru-s-siLre of
200 atwspheres, temperature of 3000 an-~ space velocities
Card 1/2 - 143 .
- -17
USSR/ Physical Chemistry Kinetics. Combustion. Explosives.
Topochemistry. B-9
C&UlYsii
Abe Jour Referat Zhur XhiMlYR., No 4) 1957) 11286
kithor Bashkiio* K.N.- L6kteV S.M.."gabirove. 0*.V.
Ntr6ler(ap * Acadeiv of _8616fides USSR
Title St6dy 6f Some Aetal Oxides in the SynUiesis
from Carbon Monoxide and Hydrogen
Orig Pub Tr. In-ta nefti AN33SR, 1956, 8, 168-175
Abstract Study-of catalytic adtiidty 6f'6xidis Of Pb- On Cd,
M6,'V__Crl Oil map
O~
Til VI'Al,'Xg,,'fJr',' "M (irith"Witimi- .
~~S,)njjjlithe'~*'G&'idon2of
syhthisis of * hydroearb6ns' fi6k idituii -CO 1'i lln-diiCWAtion
. 0 1
i~itezi-at 30CI-;500,$___aAa'30 &U_piealr~re (_i569&tz
1;'the-itasi-of Th02'
0.
and Al~l at space fa6diti6V1M;M_hoiii;-l._ -_WdeVof_PIi, Shl And'*
Cal.iuiad_thi-ibo*6-:itited 66,iditioa, i3~e -iediced' t6- thi
metal'&nd"their
acti*ity ii-Wky-ilij~ht.- C!&t&I*bt-Used 6ii*&kides-of-M6''-W.-8i,
Mal -V,I
X~- ihoir lii~b-iiftiirit~ ba piodiidii ii6itly - iAsioii-
IAi6carb6"-.- - Oitalyiti
bixdd'dA'6iid6i of'Ti adid Or vere' fduiid- to be
inti~tivi'*-"-Rigieit'i~6ti*ity
is exhibited by'SiO2 +,2% K2C03, the yield of liquid reaction products
~/2
vith.. thii - 6&tAlyst beiz4 -of ~ 30-60 -ejj3.
'-C;ranWAt4dK2C03,'__and also
6A iati*itia-'chiic6ba Are'inacti*e, -It U h6ted
thit,6~1 -Ciatal~stli -(if viii , S~Athesii-Ui66& -6n CO and % unt
possess
the property of activating the CO molecule.
2/2
B-9
J__
USSR /themical Technology. Chemical Products 1-17
and Their Application
Industrial organic synthesis
Abs Jour-4 Referat Zhur - Khimiya, No 9.. 1957, 32035
Author : Bashkirov A.N., Novak F.I.
Title : Study of Thermal and Chemical Activation of Tale
Catalysts for Synthesis from Co and H..
Orig Pub: Khimiya i tekhnol. topliva, 1956, No 10, 32-36
Abstract: The possibility is shown of utilizing in the
synthesis from CO and H2of catalysts (C) with a
tale base (natural magnesium hydrosilicate). In
preparing active catalyst from tale a preliminary
thermal activation of the latter, by calcina-
tion at about 6oo*' is necessary. It is shown
that the formation of liquid products of the
C ard 14
USSR /themical Technology.~ Chemical Products 1-17
and Their Application
Industrial organic synthesis
Abs Jour: Referat Zhur - Khimiya, No 9, 1957., 32035
synthesis over tale C, the latter must be ac-
tivated by compounds containing ions of alkali
metals; of the 16 compounds that were studied
the most active are carbonates and nitrates, and
of the reagents those the anions of which con-
tain atoms of metals (Cr, Mn. W etc) are less
active. Substances containing the tons Br-1,
Cl-1 and SOY-2 deactivate completely the C, but
the F-ion was found to be a very active promoter.
Taking into account the specific features of the
crystallochemical structure of tale, the assump-
tion is made concerning the role of thermal and
C ard 2/0~
USSR /themical Technology. Chemical Products
and Their Application
Industrial organic synthesis
Abs Jour: Referat Zhur - Khimiya, No 9, 1957, 32035
chemical activation in the process of formation
of liquid products of the synthesis from Co and
Hp-
C ard 3A
ry y a
Card 1/2 Pub I
AUthora oe
Title
C r,
Card 1`2 U~.
per-. C-) -
12.
ui
FIF III
WMM
SO
T M,
-
~i
~ '-'t
m-
-_,g
'&-SHKIROV, 1~,N-
AUTHOR: Bashkoriv, A.N.,, Kamzolkin, V.V.9 Sokoval K-M and
Andreyeva, T.V. ~5_4_2T1~
TITIA: Method of determination of primary and secondary higher
alcohols of the fatty series in their mixtures. (Metod opre-
deleniya pervichnykh i vtorichnykh vyssikh spirtov zhi3Mogo
ryada v ikh smesyakh)
PERIODICAL: "KhimiTa i Tekhnologiya Topliva. i Masel"Whemistry and
Techn-orogy of Fuels and Iubricants)l95?,No.4,pj?-7-ll (U.S.S.R)
ABSTRACT: During studies of higher alcohols prod,4ced by a direct
oxi-
dation of paraffinic hydrocarbons it was found difficult to
determine the content of primary and secondary alcohols, as
methods described in the literature (2, 3, 4) were found unsat-
isfactory when the number of carbon atoms in the molecules
exceeds eight. The method is based on some regu)rities in the
xidation reaction of higher n-aliphatic alahols with chromic
Card111 ocid in glacial acetic acid. The accuracy of the method on
av-
erage 5% (Table). There is one table and 6 references includ-
ing 3 Slavic.
ASSOCIATION: Petroleum Institute Ac.Se.U.S.S.R. (Institut Nefti
AN SSSR)
AVAILLBIE:
AUTHORS: Krykov, Yu '*'B. Butyu
. gin, Yrt Liberovi, L'T., Stepanovaj
It.D. and 1 65-6-4/13
TITLE: The use of radioactive carbon for the investigation of the
behaviour of methane under conditions of the synthesis of
hydrocarbons from 00 and ~2 on iron catalysts. (Ispol'Zov-
aniye radioaktivnogo, uglaroda dlya issledovaniya poveden-
iya. metana v usloviyakh-sinteza uglevodorodov iz 00 1 R2
na zheleznykh katalizatorakh)',
PERIODICAL: "Khimiy Topliva ~Chemistry and
A i Tekhnologiya - i Masel" (
Tectmology or Paels and LubrTcants) 19571 No .6, pp'*'26-33
(USSR)..
ABSTRACT: A critical survey of the literature on the problem of the
role of-methane in the synthesis of hydrocarbons from CO
land H2 is given'. An experimental investigation of the
abovelroblem.12p carried out usi33g methane containing
radioactiveng C,4ORadioactive methane was obtained VY
hydrogenati 2 over an Bi-A1203 catalyst and CJL'kO,
was obtained by dec *omposing a mixture of BaC03 + BaC14CO 3
with sulphuric acid. The apparatus used for the sypthesis
of bydrocarbonB is described and shown in a diagram. The
Card 1/3 catalyst used was developed in the Petroleum Institute of
The use of radioactive carbon for the investigation of 'the
behaviour of methane under conditions of the synthesis of
hydrocarbons from CO and ~,,on iron catalysts'. (Cont'.)
the Academy of Science of the TX.S.]C, its
Pe 304 + 10 (AL203. + Sio 2) + E20 with an addition of
chromium (ref 24). It was obtained by the melting of mag-
netic iron oxide with activators and crushing the mass pro-
duced to 2-3 um sized. Before application the catalyst was
reduced in a stream of hydrogen at 1000 0 for lr*3 hours.
~In order to obtain a high activit and stability it was
also treated for 18-20,hours at 390 0 and 20 ati~. pressure
with the synthesis g, a- W + % (1:1) passed with a volume
velocity of 1500 hr- '. Pome preliminary experiments indi-
cated that a good reproducibility of results was obtaineC
Typical results are given in tables 2 and 3 and in table 5
results of an experiment with radioactive methane (material
balance of the process and the distribution of products ob-
tained) are given, The results of fractional and radio-
metric analyses are given in table e, It was established
that under"experizental ponditions (20-25 atm, 310 09
volume velocity 1150 hr-1, CO-IR2 = 1:1) methane behaves as
an i1art substancet it does mot participate in the format-
Card 2/3 ion of higher hydrocarbons and does notreAter into the
The use-of radioactive carbon for the investigation of-..-the
behaviour of methain under conditions of the synthesis of
hydrocarbons from CO and ~2 on iron catalysts'
reaction of isotope exchange with carbon mono 0 bon
dioxide and bydrocarbons
There are 5 tablesp 1 figure and 29 references, including
10 Slavic.
ASSOCIATION:,Petr oleum Institute of the Academy of Sciences of the
US.-S.S. (Institut Nefti AN SSSR)'.
AVAILABLE:
Card 3/3
BORKIROV, A.N.; KAGAN, YU.B.: Ibrm' S.M.; MOROZOV, N.G.
Use of Iron ore catalysts In the symthaels based on carbon
monoxide and hydrogen. Trudyinst. nafti. lOt234-246 157.
(Catalysts) (Hydrocarbons) (miRk 11:4)
LOMMOTo A.N.: XAUN, TU.391 10nWo Me; SKOKKINs T#V~;
GOLIDIN9 BeAel
Activating characteristics of molten Iron catalysts
used In the
synthesis based on carbon monoxide and hydrogen, and
reduced at
high teMperatures. Trudy inste nefti. 1M47-261 157*
(KIrt llt4)
(O&Ulyvts) (Hydrocarbons)
UGAN, U.S.; BASUIR:OV9 A.I.; ZVIZDKIM, L.I.; ORLOU, N.A,,; KLIGIR,
G*A,
Influence of reduction conditions on the proportion of molten
iron catalysts used in alcohol synthesis from carbon monoxide
and hydrogen. Trudy inst. nafti. 10:262-268 157. (MIRL 11W
(Alcohols) (Carbon monoxide) (Hydrogen)
j
AUTHORS: Kryukovp Yu. B.# Butyugin, V. I., Liberov, Le G.,,
Stepanova, N. D., Bashkirov# A, N.
62-11-23/29
TITLE:
Synthesis of the Butyl Alcohol Containing the Radioactive
Carbon
Isotope 014 (Sintez butilovogo spirta, soderzhashchego
radioaktiv-
nyy izotop ugleroda 04)
PERIODICALt
Izvestiya AN SSSR,
Otdel.Xhim.Naukp 1957t Ur 11, pp. 1404-1406
(USSR) -
ABSTRAM
Here a new
method for the synthesis of butyl alcohol,which is tag-
Sed by
radio-carbon c14, is introduoed. This method is character-
ized by
simplicity and a high output of special product. The me-
thod consists
of two phasess magnesium-organic synthesis of
butyrio aoid w4th
elimination of the latter in the form of so-
dium-butyrate and the
restoration of the salt by lithiumalumin-
umhydride. The method can be
applied for the synthesis of dif-
ferent alcohols containing the
radio-oarbon CU. It is shown that
a synthesis of the tagged butyl
alcohol is also possible without
preceding elimination of butyrio aoid
by means of immediate re-
storation of the magnesium-organio complex 0
OR
-OMgBr
C3H7 a
by lithiumaluminu+ydride. There arc -1 01-vic references.
OSOCIATIONj
ftt4V1*= Iwft#*e of tM.Al USSR (Institat pettl AkeAenll
Card 1/2
BASHKIROV, A.N.60 doktor tekhnicheskikh nauk,
professor; KAMZOLIIN, T.T..
kandidat kunicheekikh nauk; LODZIK, S.A.
Technological elements of the production of higher
fatty alcohol$
by the direct oxidation of paraffinic hy0ocarboris,
Mael.-shirlprome
23 no.7:24-26 157. (NLIIA 10:8)
1justitut neftl AN SSSR.
(Alcohols) (Hydrocarbons) (Oxidation)
----- ---------- ------
KRYMOV, Yu a Be) BASMMOVI As N. BVrMIN2 V. K., LIBEROV, L. G. and
STEPANOVA) He D.
(Petroleum Institute I[ AS USSKi
"Intermediate Oompounds in the Synthesis of Hydrocarbons and
Oxygen-Containing
Compounds of Carbon Monoxide and Hydrogen on Iron Catalysts." P. 58-
anl :~aa
:a 4~ *2 v3m-f. on 1~rs(& ef PvAdtcka,-~tive! ane,
radla, 1r,-in im Na!1cmaj 1.,camy r.04 S-Aon~4t, 111r~acow. 1:4-v0
.,J, zz~~Z,, 19,8"
o'! -,-'w ~!rv all
Qnd S-IiAtOke Y~adlallc-~
:-r~t a"A KaLa
Adlila rctr of A, it iNt-Prrjy "ovu!!1! cl,7
C4
ja z
pill
XAGAN, Yu.B.; B&SHICIROT, A.N.; KRTUMDT, Yu.B.; LOnW, S.M.
Formation of the active surface of fused iron catalysts for
synthesis from 00 and H2 . Xhim i tekh. topl* i masel 3
no-3:
14-22 Mr 158, (MIRA 110)
1,Inatitut neftl AN SSSR,
(Catalysts) (Iron oxides) (Hydrocarbons)
BASHKIROVI AeVol XWOUCINO Vero; SOEDVA, X,M#; ANUMVA, T.P.
Position of the hydroxyl group In alcohols produced by liquid
phase oxidation of n-paraffin hydrocarbons. Xhim. I tekh. topl.
I masel. 3 no.6tio-16 is 158. WRA 11:6)
l.Institut nefti AN SSSR.
(Hydroxyl group) (Alcohols) (Chemical structure)
AUTHORS:.- Bas!j~~A._N.,-Xagan, Yu. B., Kli-er, 0. A. 62-58-4-21/32
TITLES Cmposition of Products Obtained by the Synthesis of
Aminus of Carbon-, Hydrot;en- and Ammonia Uonoxide
(Sostav produktov sinteza aninov iz okisi ugleroda,
vodoroda i ammiaka)
PERIODICALs Izvestiya Akademii Nauk 5SSR,0tde1en;be Khimicheakikh
Nauk, 1950, Hr 4, PP- 504-506 (USSR)
ABSTRACTS Already earlier the authors realized the synthesis of
the alkyl amines of CO and a=onia in the presence of
molten iron catalysts. The synthetizing products ob-
tained contained up to 25% aliphatic amines. Further-
more a perfection of the used catalysts was carried
out. A stable, active and rather selective catalyst
was found. In the presence of the catalyst the aut ors
synthetized on moat favorable conditionst from 1 m~
12olo grams of synthesis products (without water).
Of these viere 54,o% alkylamine8 (30% of which in liquid
and 21,o% in gas state). Tables 1-4 give information
Card 1/2 on the results of the elementary analysis of some
The Composition of the Synthetization Products of the
62-58-4-21/32
Amines of Carbon-, Hydrogen- and Ammonia Monoxide
fractions of the destillation and the physical con-
stants of some fractions.
There are 4 tables and 12 reforenceB, 3 of which are
Soviet.
ASSOCIATION: Institut nefti Akademii nauk SSSR (PetXV1
Institute., AS USSR)
SUBUITTEDi November lo, 1957
AVAILABLE: Library of Congress
1, Catalysts--Synthesin-Study and teaching
Card 2/2
AUTHORS:
Xr~-ukov, Yu. B.,_A~Eshkirov, A. H.V 62-58-5-22/27
Butyugin, V. K., Liber--ov-,-I-.--o.--,-tt"anoya, N. D.
TITLE:
Conversions of Butylene on the Conditions of Synthesis of
by Way
of Molten Iron Catalysts (Prevrashoheniya
CO and H
2
butilena Y usloyiyakh sinteza iz CO i H2 nad playlenymi zhelez-
nymi katalizatorami)
PERIODICALi
Izvestiya Akademii Nauk SSSR
Otdelaniye Khimicheakikh Nauk,
1958, Nr 5, pp. 642-644 (USSk)
ABSTRACT&
The present report is a trial of investigating the ways
of conversion of the olefins forming in the process of the
synthesis of the hydroolrbons and of the oxygen-containing
compounds of CO and H2.Butylene marked by means of the carbon
isotope C14 in the state (polozhenii) I served as indicator
of
the behavior of olefin under the conditions given by the
synthesis. The experiment has shown that butylene does not part-
icipate in the formation of alcohols, as well as in the form-
ation of highest hydrocarbons (by way of Cq~ neither and that
it
is no intermediate product. Butylene can react with CO and
under
the investigated conditions by producing & C5-hydro-
H
Card 1/2
2
carbon. 'At, also submits to dehydration, oxidation and hydro-
Conversions of Butylene on the Conditions of Synthesis of CO
62-58-5-22/27
and H2 by Way of Molten Iron Catalysts
cracking. There are I figures, 1 table, and 11 references,
9 of which are Soyiet.
ASSOCIATIONs Institut nefti Akademii nauk SSSR (Petroleum In3titUtS
AS USSR)
SUBMITTEDs j&nuary 2, 1958
1. Hydrogen Isotopes--Synthesis 2. Carbon monoxide--Synthesis
3. Ethylenes--Chemical react-.,)ns 4. Butylene-Chemical reactions
5. Carbon isotopes (Radioactive)--Applications
Card 2/2
- ----- - ----- --
ATITHORS: -
-Tin Ph1.r41MggW_- A--m- lramrolkin, V.
V; Soko~ra, K. M. and
kidreyeva, T.
TITLE:
The Position pf Hydroxyl
Groups in Al-Ichols Prepared
During the Liq4id Phase Oxidatioo of
n-Paraffin Hydro-
carbons. Mpolozhenli gidroksil'no7 gruppy v spirtakhp
poluchayemykh pri thidkofaznom okisionli ---paraftnovykh
uglevodorodav).
MRIODIOAL:
Khimiya i Tek nolofiya Topliv i Masell. 1958p
Nr.G.
MSSR
lo
16
-
.
pp.
ABSTRACTt
When iinre stigating the position of the hydroxyl groups
d
d th
th
i
l
t
th
th
l
h
e me
o
he au
ors use
n
e a
co
ol molecu
ep
of cxldizing alaoh-^#ls with potassium d1ohromate in a
medium diluted
with sulphuric acid (Ref.4). During the
oxidation of primary'aloohols,
carboxylia acids, with
the same number of C-atems as G;ntained in the
initial
alcohol, are obtained. During the ex! -dation of asoondary
alcohols, the C-C bonds are split at the hydroxyl groups,
and
carbo371ic aolds with a lower number of C atoms in the
molecule are
formed. Therefore, it is possiblE; tt
determine the position of the h
droxyl groups according to
~
the eompoaition of the acids.
ome sida reactions take
place when the process is carried out
stalphuric acid
Card 1/3
at in,%reased tamp&ratures- The authors
in7eatigated the
The Position of Hydroxyl Groups In Alcohols Prepared During the
Liquld
Phase Oxidation of n-Paraffin Hydrooarbons.
oxidation of individual aliphati alocnhol.,3 with varying
positions of the hydroxyl,group ?4-tetradecanA, and
7-hexadeianol) with subsequent identlfivatic~n of the
acids. The method of F. Kraft (Ref.4) waa sli&htly modi-
fl6dv and distillations were oarried cu~ according to
the,method described by L. K. Obukhava Ref.5). The
Y,ei&.t of the reotifioation eolumn was 40 cm and the
diameter le4 em. A mixture of hydroaarbonsr from which
the olefins and aromatic hydrocarbons had been separated,
was used aa ~.,arriar. The content of esters in the frac-
tions was calculated or. the basis of the eater number
of the fraotion. On tho basis of the composition of the
aoids it was possible to conclude that oxidaticn of the
aloohols cacurs mainly at the hydroxyl g-Aoups. Dis-
drepanoies In the rule of Papay, oacur at Inoreasing dis-
tano es of the hydroxyl greups from the end hydrooarbon
a
- The neutral oxygen-containing oc~mpound
tom. a (ketones),
obtained during the oxidation, were subjeoted to second
oxidation reaction. The total yield of acids ;: 96%.
The ',.ziestigated fractions ef alooholswere concluded
to be a mixture of Isomers of secondary p- hoxadeaanols
Oard 2/3 in wh1oh the iscme-As are oontained in equal molar
The Position
'
of liydrbxyl Group6 In Alcohc!'* sPreparad During the Ll-juld
Phase
Oxidation 111hr-affin Hydroo
of n- arbon.00
quantitiez. Ex-perimental details on the ox-fdation of
the
indl:viduai alcohcls are given-TablaW I and 2 give
the composition of
oxidation producta of ali%oliols and
of their distillates;' the
distributic-n of acids is
shown in Table 3. During experiments on
defining the
position of the hydroxyl groups in the al^,ohelsp a frac-
tion of aloohols boiling between 125.0 - 126.e, with an
hydroxyl number
of 229,50 was oxidized The nsutral
oxygen-oonta-Al.ning oompounds were
subjezted to a second
oxidation reaotion. Results are g,-.;Fen I.n
Tables 4 and 5.
These experiments showed that during the oxidation of
n-paraffin hy4roaarxbons in the liquid phase, a-secondar-)
alcohols are
fc--mad. The hydrcxyl groups of these aloo-
hols are situat6d at
different- 0 atcms cf the molecule.
It was also found that the
reautivity of the secondary
0 atoms of mcleoules of k,.igl-.er
n-paraffin hydrocarbons
to oxygen is practic-ally idlentical. There are
5 Tables
and 8 Ref6rencest 4 S,-qiet, 2 German. 'A. English and I
Card
3/3
Dutoh.
ASSOCIATION-.
AS USSR (Institut nefti AN SSSR)
SOVI 65-59-7-7/12
AUTHORS: Bashkirov, A. N; Loktev, S. M. and Sabirovaj, G. V.
1-11~~l-,!-,.-Iz,~."~.~..~.-Z.l~~*-~~,A~..
TITLE: Hydrogenationof Aldehydes and Ketones in Mixtures
With Other Organic Compounds. (Gidrirovaniye al'degidov
i ketonov v smesyakh s drugimi organicheskimi soyedinanl-
yami).
PERIODICAL: Khimiya'i Tekhnolo~iya Topliv i Masel, 1958, Nr.7.
pp. 39 - 45. (USSR .
ABSTRACT: The authors investigated the selective hydrogenation of
compounds containing a carbonyl group to aliphatic alco-
holsiespecially 0 - 020). Starting materials used were
liquid products obtained during synthesis from CO and
fractions of these productso or individual aldehydes an
ketones (Table 1). The hydrogenation was carried out in
a continuous process. Copp6r-chrome-barium and niokel-
Magne ium OXalatq# as well as fused iron catalysts, were
used T70 - 75 amQ). Details of the preparation of the
above catalysts are given. Table 2 gives results obtained
during the hydrogenation over a copper-chrome-barium oata-
lyst at 100 atms,at various temperatures. Experimental
conditions during these experiments were those described by
He Adkins (Ref.~j and D. M. Rudkovskiy (Ref.9). Table 3t
results obtained during the hydrogenation over nickel-
Card 1/2 magnesium-oxalate catalysts at atmospheric pressure and
S OVI 65 -58- 7- 7~ 112
Hydrogenation of Aldehydes and Ketones in Mixtures With Other Organic
Compounds.
500C. Iron catalysts were first investigated by V. N.
Ipatlyev (Ref.2. 18 and 19). However, the yield of aloo-
hols.was low, and the yield of decomposition products
high. Very good results were obtained when-the hydrogenat-
ion was carried out over fused iron catalysts at pressures
above 100 atma, and at a temperature of 20000. Table 4-.
data on the hydrogenation over Fe",04t 1MO0,3- When lithium-
aluminium hydride was used in ether solution (Table 5), it
was possible to achieve practically complete reduction of
the oarbonyl and also of other oxygen-containing compounds
to alcohols. Yields of alcohols range between 70%- 80%
for copper-chrome-bariLAm and n4.ckel-magnesium-oxalate
catalysts and 90% - 98A for fused Iron catalysts. There
are 5 Tables, 19 References: 11 Soviet, 3 English and 5
German.
ASSOCIATION: Institut nefti AN SSSR Petroleum Institute of the Academy
of Sciences of the USM.
1. Aldehydes--Hydrogenation 2. Ketones--Hydrogenation 3. Organic
Card 2/2 compounds--Hydrogenation
AUTHORS: KaZang Yu. Bj ~Ba SOV62-50-lo-19/25
Kryukov, Yu. B.j Loktevt S# 11., Orlova, N. A.
e-ITITLE: On the Mechanism of the Catalytic Efficiency of Fused
Iron Catalysts in the Synthesis of CO cnd H 2 (0 me"na-
nizme kataliticheskogo deystviya pl--vlcnyA.h zhelozny.',h
katalizatorov ninteza iz CO i H 2)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdoloniye
khit:iicho31:ikh nauk,
1958, Nr lo, pp 1274 - 1275 (USSR)
ABSTRACT: In an earlier paper the authors showed that immediately
after
the reduction (by hydroZ;en at 10000) fused iron cata-
lysts in the hydrocarbon synthesis of CO and H 2
are not active any more. Only under the working
conditions of the synthesis when the b-as mixture CO+H 2
is passed thr6uGh the catalyst Gradually becomes active
(for 18-2o hours). This phenomenon may be explained
by a number of simultaneous reactions competing with
each other. Due to the course of these reactions com-
peting with each other the metallic iron reGenerates
Card 112 often (under the conditions of the synthesis) from its
A: ~ THL-, S: Y~_- . '~. , _; - - . / '_ '. -, - .. - .. , I ~
Kryu4k-ov, Yu. B. , Lo"tev, S. Orlcva, 11. A.
TITLE: On the Mocheaniam of the Catalytic Efficiency of Fused
Iron Catalysts in the Synthesis of CO and H (0 mcl:ha-
1 2
nizme zataliticheskoGo deystviya plavleny1ch zheleznylzh
katalizetorov sintena iz CO i H 2)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khiviche3kikh
naul.,
19531 Nr 10, pp 1274 - 1275 (USSR)
ABSTRACT: In an earlier paper the authors showed that immediately
after
the reduction (by hydro,~en at 10000) fused iron cata-
lysts in the hydrocarbon synthesis of CO and H 2
are not active any more. Only under the working
conditions of the s~-nthcsis when the jas mixture CO+H 2
is passed through the catalyst gradually becomes active
(for 18-2o hours). This phenomenon may be explained
by a number of simultaneous reactions competing with
each other. Due to the course of Viese reactions con-
0 -enerates
petin with each other the metallic iron re,
Card 1/2' often (under the conditions of the synthesis) from its
1.
0,.,, tne ldec..~an Ism, of t.-ic, Cat lytic Eff 'L ci e:.cy
of F%Ii--(~,d S~~V/-(-2- L- I o- 1 V2~1~1
Zron Catalysts in the Sy~nthesis of CO and H 2
compounds, and at the surface of the operatinG
catalyst the dynamic equilibrium of the surface phases
of different chemical structure is obtained. As a
consequencc of these processes the activation
of the catalyst occurs. Neither the iron itself nor
compounds that might be formed from it are the
reason for the activation of the catalyst surface.
The hypothesis formed for the chain mechanism of the
catalytic efficiency of iron catalysts (according
to which the synthesis of CO and H 2 is caused by the
reactions of carbon and hydrogen monoxide Nvith iron
and its compounds on the surface of the operatinE,
catalyst) was described in detail by the authors.
There are 1 table and 1 reference, . .7hich is Soviet.
ASSOCIATION: Institut nefti Akademii nauk SSSR (Petroleum
Institute
AS USSR)
SUBMITTED: April 8t 1958
Card 2/2
KAGAN, Tu.B.; IiASHKIP-OV. A.B.; ZVEZIMINA, L.I.;
ORWYA, N.A.
Fused Iron catalysts in the synthesis of higher
alcohols from carbon
monoxide and hydrogen. Trudy Inst.nefti 12:200-212
158.
(Alcohols) (Catalysts) WRL 12:3)
BK;1EKIROV, A.N.; KAI&GUINA, Te.V.; KnWUN, Tu.B.
Particular aspects of the decomposilton reaction of
carbon monoxide to
0 and C02 In the presence of fused iron catalysts.
Trudy Inst.nefti 12:
213-227 158. (NIRA 12:3)
(Carbon compounds) (Catalysts (Chemical reaction, Rate
of)
KAGAN, Yu.B.; RASHKIROV, A.N.; LOKTEV, S.M.; Wlk)ZOV,
N.G.; ORI~')VA, N.A.
Effect of the introduction of ferroalloys on the
activity and stability
of fused Iron catalysts for synthesis based on 00 and
92. Trudy Inst.
nefti 12:228-239 158. (MIRL 12:13)
(catalysts) (Iron ailoya) (Cbemistry, Organic-Synthesis)
BASHK I ROV. A. N. ; IUV AK, F. I.
Studying conditions of synthesis from carbon
monoxide and hydrogen
on.talo cataly:t:~ Trudy Inst.naftl 12:240-245 '58-
(MIRA 12:3)
(Cat,Lly t (Chemistry, Organic-Syntheais)