SCIENTIFIC ABSTRACT BASHKIROV, A.I. - BASHKIROV, A. N.

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December 31, 1967
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VAJ:I,IYi,V, Yu.E.; RAISUTCV, R.I;; A.I. Experimental study of the stru0ture Of oil and gas flow in a flowing well, Neft. khoz. 39 no,4:41-44 Ap 161, (MIRA 3.4:6) (Oil reservoir engineering) . ", ; . I 'v ~.-. I . , - ~;.h 1.'T i3,K,, -'., '. "Ixru,"ni, Approximate sOlution of the nrohlem of the flow toward a well with a horizontal joint. Irv.AN ~~R.Otd.takh.nauk-Mekh.i mashinostr. no-5:183-185 S-0 '61. (Hydrodynamics) (MIRA 14:9) BASHKIRM,, A.I.; BRISIMU., A.A.; VASILIYEV, U.N.; ILWUTOV, R.A. Propigation of elastic vibrations in oil wells. Trud7 VNII no.35:3-10 161# 6i1 Vella-Vibration) (MIRA 15U) 77] AMBAY0, 1) VASILYEV, Yu.,N,; MK5VTOV, Fathods and results of the experimontal study of the gas-oil mixture flow in a flowing well. Neft. khoz. 39 no.12:38-40 D 161. (14IM 14:12) (Oil reservoir engineering) ARKHANGELISKIY, V.A. (Moskva); AUZBAYEV, D. (Bugullma); BASHXIBQY-A A.I. (Bugullma); VAILIIYEV, Yu.N. (Bugultma); MAMTfiOV, R.A. (Bugullma) Investigating gas-oil mixture flow in gushers* Inzh,zhur. 2 no,1:55- 68 162. (MIRA 15:3) 1, Institut mekhaniki AN SSS i Tatarskiy nauchno-issladovateliskiy inatitut. (Oil reservoir engineering) I V T it r 0 A _I k I =VJ 7f A: 1A A d, a 1i luved~ptlm at the Pechars cosu. N. 161. Raraviltw. m7(-1j. A. Vhollcf- Kkim. Trerdpl., IX .3 3 3. . $4, 00 .-RAmulut a" disin. Irms wilb analyses 14 gas alld jar. A. A 11. -00 00 s .00 see 09 J~~ :da 0 0 goo zes loot, 4i o wee 'a aw a 0 a v of a ft it 0 a a A of a Of a a it it on a 1 134 904004:;G006C 04*09969990906, 466900990069100 of* 00090 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 0 900000 0 0 0 0 0 0 0 0 o 0 0 0 0 0 0 0 I ' T ", 1 U cy It k 1 M t (A n 1) t' I I I I 00 Is10 so o Oki ,0 lie 00 0 it #0 ! ;^00 0 00 so= t 00 J, 00 to. 00 so- 1"P~:z -Y 'Y go , 00- am "I If! mMi" is&A Aq pwWpaa,+l I* 0 ISMIAMOV au -%""PDA -ulqp Put -Qllaq3ql X4 PUT 00 - ,a1" J" p- al!pd-d- aqi !2 P" AN I =71 off so , ss- f to an Imp A mm C Npvm 'AMPM 'I ' % PU AGRjWWSr4!-AAnAVn)j roe ~ j : '4PO&P pahwawq Ps so M4 "040 q 90 " ' - ov 4 0113 a 13 lo ? A I a 1 111-0 V v r it It It If v OF w OF w IT w w v v w 0 a 0 0 0 0 0 0 .6 o 0 9 0 * o 1 0 0 *1* 0 9 * 0 0 o 0 0 a a * 6 0 0 0 0 o 0 0 0 .00 00 0 000 0 go Co 0a 0 0 0 0, # 6 0 6*60604410:600 ", I So a it u 31 so 6 0 C 0 V 4 18 A L 0 0 PQ to S T UP Tj III !.1 ! " .0 ! ! ? ! ~i 0-9 VI'll l!-- :3.6kelits 1*6 4.0 at. 641111116 1 r. W-co mayeausts well 40,111116"171) 14141111111111 11,3511"I'llk" Is Goo, 00 000 It es, 0 v 'V '-pi- -v!jw41qdA1t-pAq us jswaan Aq setilrimis plaw 'clUjiWfl Aq pap. 5"Ims; Sjud!O11 :0. ~: I. C. PUN plailtopit, .141 All W" al to jAn aqj 10 -ut"m '131131-413H US XUIIULI.%M %PtM 3111*11111PRIa" 10 SM11*111 ww- J-s %10)41.mu I).lulqtuaa aql Aq ApiviroM P" MASS go -txltuw ;owtLL * on mopq -q mill PIM Re" P.A=m -v .9 ma aqt P U041-MIS) N) U! P11310) ZIA-rv I p- -Vr I 1-iole I qo~rl 1-irri pus p- 4 PORP -0 1- 1 -1. p m-w WAM~ 5 4 pus A641wirow-N-V A"Awv-.1 'It- Pon Ito win Lou"m 841 0" spem 00 of :Or 00 00 0 ve v I -Su IS a 0 f- 1 4 1 00 Of 06 00 'Irk, " - I I g a i ! I poll I "t 5 .0.0 "llpf 4 1 1 1 ff. A-. Md Un by waddal whi, ftatic the 0 dmim vm atomic IN the Put W*o tot Pbmd a. Md "i 1,11.4- Mid am pntcajoff. .00 pwt ON dw te tw W"v 16"d the bC C7,0AM_ H d C A H - Sli u * u A. vt r"m" tbg d phimm. pommake dw w". a trViudw PbVW6 bt ii X7 4 ;41 ALkk)4GKA L L OM ATk*9 CLAW C, Off" 81 __ 1-1 - - _ _I L I., . - low 41"alif. . 00"11 .1. ~. -i- :E17 u lot a 00 al .1 q me IV *is 16 * 0 0 0 0 * 6 0 0 A. A. Mcwhillack zoo ties ....... i.*-. %. gee v '14 slo 0 6 0 0 4 SIR "fill 0~16 to . Adrud" MA pwauld" of puaft hoiin ftr of the N" w- V AeWukw s Wn U A kkay4mid M - . . - . . vy p p 11M. KlWm. Tw&r MT -VP SO , :OA detive4 ffm The tat by BAS of pwaffift (as the tw) wow wN. The lftb4"*9 frWAM. CrY249. MIS! SlOrtatillf. nw pws&o b akrkss, cdorks mW 0" to light. /It coMaW so 0 tm I%. nd b shedw to tbm parefti of 00 nV6 CU. A. A. Botbtbnk X*q 00 00 goo t i ~,Lw 00 s Woo t s logo "I O-V =0 valall 61111,01 do awv AS) 94 u 8 AT go . I 1 4 . I . 0 0 000 Igo' IiI i i 01;9*::; ;01;: ;00:0119010 op INN the Plot- mW D. B. OrwMln- 84AW- a&* jVNI.-Tbe PWtb&-- JC668. rwp&o Mb we in an i . on mv- temp. catbooWim 6 "Wdwl 0*4 is ob~ Is adda. I* ltsj,-13m% tm 1) cmtg. pbomb 2L"Jo cwbwyel=1%11s'Cb".wW baso SJD- SAO% ii~ bmgoa. %bM is Msb in pbnv&. -boxyUr Instmat with H404 OW NSON I* prodwt 4 d. 0.7774, 1 no. . A. A. .19 a%$ 041 allall am aiv at# r-- u 1 0 00 49 it It It 9 K w a tc K Ito a 1,14 #A v aw 9 iff to v a If -00 at* coo IU99 -0 11 AOL- 14- lfw- I, Al U I' I a- ~& I I- A I Lji-b-u -e-ApPit'.- 1-0 be At. 00 04 00 A 4 hr dke 486WIM66" 40 amble Is Wo 'I M - - - I-- .. U .00 6 ww I-- -- f-1 & 0 dY&Nbkm Kidw- U0409M).-Intradme lato a -00 bb U w 80 m6 4d S N N&GH m1m.. avWimg contact of .00 am. = =(= Plan in the cup 0.1 to 03 1. of .00 mdAL a 0: 11=2. Dws in .600 wbkb am Wb:nA!Vc*mbustiou let the bomb X410 vaim. and careluOy Aake for 10 win. in vwb A 0 lots., pr"Cat ibe cup from do tka*". 00 Tranger the contents of the bomb to a I mftuwim 000 00 Amak, All to dw mark &w tbw=wbly 2k*'* r1we in s"ber 100-w, " the swoe amt. X.6H too as wu 0 *scid In the bmb, 0 ibe k* to the mark mW "hate. woo 0 CW 5 ...1 tW M. M 3 ce.of tbead.. hm tb. bb moo sad t1trate with an OAS N HCL 0 ivilb tbome obtabmd by the coo A. A. DoebiHngic Moo U '00 :1 woo use bp 0 0, a! CLASUFK& spew i-mviAt. 21C.- woo ri flisil 00 04V Ali a So 4 K a 19 a 191 v a to of isa 60 :10 0 0 0 0 0 * 0 0 0 0 0 0 9;q 0 0 0 0 0 0 0 a 0 6 0 0 0 0 1 C D 0 9 IS A.---L - 2 P-- 0--P% 0 "ClIVA41191) 1"111141111 IT3l%*MllVl$Q Vic-Ott so ile* %Il,l o PCs ar I -M Qrv of sex H 'fl,tv 3 jo Wadi- -4 Im atqlpm=w 841 pere *on Irr OR, of pamn fm, au 96 Oll- rpw P-A- 003 *280" j0 luaAM3 aqL -EwRe"a2ultvaquen"I %Tl'0()PX+()ftNpavw0 'Ir 00 so* p frill ^L 'l1: 0, )a am"w a IM PIM W f"p",Sjq 0 jol qlwq pastp arman it- aum a4LL 'a IWO ptm.q- %21*8R PUNY" 040-- P"M aq) rea- maw so- Ir 0 it, z7li~-l - r . I, -01 a - AM- lr~- 1-9 Vic fell- U-TMok -RA 00 00 0, sea 00 8 00,1 0 -3 0: go, IL 1. MY- "It i I- - L. P. Kran*. JWw. rwmUp ropmrv.-z cf. C. A. ". 70511.-nw kc.6mene diaMair Imen At ~m. a# Cbertmh Caab ft 901, reduced witb H. is ibe prevence at Alo oxide produced Went. w-aW thakise. 0-methyinaphthak4w, =hylnapbth&k,wb.yl.ar.quiaoHft. A. A. Elachtlinak & a - S L A09TALLUISCAL UVIROUlt CLASWKATAN ow ..a .. I sold" it 0.. oft .00 -00 .00 '00 '00 00 ,so go 'too 00 see ties ISO too see! I b u A' :il 9 0 9 0 0 0 0 0 0 0 0 0 0 0 0 0*4 A *sees 0 0 0 * 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 A PC W itsels d so Z1111110 d So CbwemM=w OV Mb A" K. a. 9 'MIM *. &!N~.~G. A. too jr too do W-91MOM).-Ilitio amb km the tampt dprWt aft v"bk cm Pa. Tbq YkW an Av. of 9-10% of law- g tw wifth Is mAr evedtod. Deft" clowww. - 00 -31, mod a ebea. amlpb of "Ism = 000 1 l o4o e U L~~..SLI .89TALLWGICAL &ITEROW CLASSOICAVOR two" Wtoolo - 0 1 %!Iosa 0 '-f '1 -1-1-6 * I-, u Oli 00 " to 0 4 a 0 0 :j: : : : : 0 0 0 0 0 0 0 0 0 0 it i, aw -00 .0 0 =so dpo t4goo 200 0 1-4, ; 4;ii 0 0 010 0-41 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00 e 0 0 SO 40it 0 0 8 0 0 0 # 0 0 0 0 do 0 so 0 0 0 0 -- - -W~j Oct -I- - I 4 4 A A 0, 0 it T a~'i 000 *.3 :ow 00, set IV I -_-_ If 9 -A-L-~&- well Is commodke- with cwboWsWott at baraw easla. 4A.AX ij Orechkin No V. 1. VOR"WISIM 6. WD-909M.-Mis cak ks of Darsaw b cau be kmcrw4 by whftbur".11"s Zburls cash (40. 46%1 or AtWwk w4tw PD-U%). 9.9w coals I be und. In sm&Uer quantities (about -181V TO* bed 96wlt a ni obaf"d with bisbly oxktiml coals. the lowat with the low temp. carbuniution coke from Barna coal. 71w ndxt. ahdkdd in all emus be cart.. broken up or'brksuetted. Atootts the chats. *4- =res. RA. NsOU AJC3o asid ZwCh cause lem de- c"ale in the "kime Zhily. A jww ,V. I., lealas life akft sbWty or coal is dwwik*d. The ez Neg. CW' A out tog the =ca of findins a suitaw-metbod 4 A a carbunkAng the a Coal Without cakbq so as permit a better dists. of volatile vAbstancts. A. A. Dotbifingk. -ILA ORTALL41*GKALUflgdfWICLAIWICATION 9-2- .00 .00 ~40 '00 '00 4*0 "09 so* 800 so* coo so* sto not 61 b u a p to a3l; 4 1 If 0 ; 'I 511 A-1-1 1,tilt I A 00 00 c fee 400 .1 00 60 :J: J U__ '13MA _1 . A-" Jv_ "Pitt b= M1110 L, A. V A. 30 761118 - Mornmilt tmf the -tar Inum the /butinA C'MIN'ti the kulmillidorvoalt. firtil Itiom neutral 4voulds- bum and cuboxylic addoo and c%td. with lvtr. cthff. wrfr -distd. (34 nim. of "). The fraction Ib (0-1461 wist tivated with Izz Were fractionated in wromov (12 mm.) sadv1=11.1"bilcid Allpfudiscris I I un. M II0. -tilt r%tv-) In= elk. u4". at to' I'm the awtompikas that the o11 actrum cady at the okadde toncid). The vacen of MuO.- was decalurbed with MnSCN. and after acidifying with 35% 110h. the arlds Immed were ;I ram 4W d. The Ur Oter treatment with ether and N&AIM was 1111141:111 didd.tWona water hath. The friw0corialtbisdi"Ots 4, (b. IMP) had acid an. MIX IIC%H and ClImatill were dolected In the dWoUltite. The scidt of high b. p. am" mt standing and have arld vo. 264-3. 11jerr cftbephvewbc~jvintary tantrunt the Zhurintk I.I. h-ve all un" 41, hot". A A. lNwWwnv I L A 111I&LLW4KAl, L119114,11WAR CLAMPKATION moo.. 11-lebov. as ~Itj Wove -a I 4 S 117-y-T 0 u : Ato so ALI to a a a a It st a n at x i :0 0 0 0 0 : 0, 0 0 0 40:0:0N0009000000009000000049 i ;C7 -00 16 -00 see coo 99* 400 coo moo 13001 00 tie 0 It V. woo UL AM A I III Od 0 11 9 A 2 a to Zf I ift :;* & 0 0 * 0 9 6 0 0 4 0 0 0, !000000*0000099::: so: so "so 00 60 *00 go live 00.1 *so see Ieg, Meo ges, it AtIA&LOOK&L U0409" CLAMICAIM *so 21.- IV 10 al; AM I I a w 0 a v I N a w a a 3 a L l L, I I a I a -7 Proparsda ol pere PbOR fross dw phamols of cad ftr. &,.N',L1,*xbkkvv and 1. U. Vener. BaU, arad. sn. 11. ft. - - S.S., Mist W. $wk. 1%4, 4*-W.-Tlw phrool-crew4 Iraklion 01 1W is IfMtSd With NADII-ACAV8441 Ft J"~d. 09 r s b sid ati the h l k d i th t vapo -p a e e pu I WHID0 vact e con- ana on. passe n o p I th li ld h h 00 e . e -p app. & n ase proma. t qu 'reduml-Fe fteut is Wed directly to the braWAfv%4 p trWtiM 10 SOU. Of SPPM1, 3%. run OWN kO MUSS 6 bested under a idua covideimt at 11* b.p. of the liquM 00 1 (approx.18P)SwIllus. VwPbOllobtalnedm.39-40'. Thi*hmol room with The Ft realprot to forni bentene. a of Wi Whenyl.Pegandfl. The amt. of bmarne obtained wa- goo o ea. 57%, and of bb)btnyl &=. 11% of I he I hiophrool p Z coo The pleetuils ae . pun In the vapAir phaw in R - ~ t b t P YXI W h d 1 F h 060 ecein yre u e wvd wit t t fewnto rr 1 S. g, ' for 3 bri. at WD , hi The lietuid phaw. in a S&I-nd. gis- i 91 xOO fisA with a redu coadvamr. The Purified Product was reciiW in a bubbOul column with 23 Flaift. ?Wing 0 16 5-191 narrow trwtW (18 b 18D 2%) P . . . w , , NolfteSwaslound. T*reactionoliblophenolwiththe a see FereaLrutbepnet)TV: st2W-Witlavlok-ni. Vert- agent (40A It. riduced at i(**) reacted at 2W% with 21.4 hl see ophenal passed 21.4 troducc4 at the rate a & t I to ive 12 2 Aw of W1 r d t d am I . - q- o ac an a. M . (at t p IN*) of gas (92% of which was H). The liquid rewion :3 f to ivv benorne and 0u g yNt n e n a . L OL (LASIVIKA.1W too we 41,411 as COV All s 03 Is 0 1 1 -4 v U 0 a W " ft f# x a a w 11 It 2 rj:1 0 14 9 0 0 Ole 0 0 0 9 0 0 0 0 e 0 0 0 0 0 0 0 0 0 0 e 0 0 111 0 0 0 0 0 0 0 *&W ILI *11 PIKIS"i Ala 040PINIAge NMI 0 7V 'so 'as goo-h 2"S, NEW 93TWO rOR MARATION UY STURNZ FRUK GRUkZ ONSOL. . 00 Bashkirov A $ end laravaely A X (ALU aced sol V.R.S.S. CI &ol ~041 TW-Ts-=0-76367721 J ins% patrol 1945, 31, 217A). Crude bensol "go frois U.S.D.R. ooke ovens contains 0.7-1*6% of styrene, which Is concentrated in the 3W161 (135-1500C.) fracti n of which It *00 forms approximately 20f. Us styrone-aan be separated by Worination 2e0 (at a t sspsraturs.~ 5 Q# for" styrene dichloride which boils approximately 100 . higher than xylol, and from which It say be o so%# @operated by vacows distillatIft. A "% yield of the diddaro 3:gs sell oompouDd &a obtaismKo. the styrene may be regenerated by do- go* chlorination over a cathlyst formed by reduction (at 5OD-550*C.) lee 9 of bogiron ore. Ds Worinstionj oarried out In the upour phase 0#0 (15-2D) at 275-180*C.# Is strongly exothermic and oooUng arrangements age If :1 smat be made. lield of -1& -64a dishar compound is 90%. I f! WhoproduA obtained is of h1gh purity. 0[! was "I bet Almi-IL-ADETAL'LUROKAL WERATWO CLASWV4YOU V 00 V 1110M IMT1111VO Mm 160.0" it 141080 W&t 4MV Get evil" 011 4114A21 0A 0" ail it K a to st 0 0 a 0 0 0 0 0 0 0 0 0 0 01: 0 a 001, NOR 51 179 -3 q All d-11 ;4j. ?8p. i jr! j I , '~j gal - u, -!ft~ 5 v8. I.' H9 a -I~jlj .111 n=22WII Ii z .1 ~tj -6 all V71 OW j AR lid see goo goo coo - :00 no Oro sdftovg -J t.206. a I T 0 00 &S It 0 0 aIt T--7 -T I M-Ist ~;O; in a 00 :000000000000 a 'dok 0 0 0 0 0 0 0 0 0 0 o o 00 00 00-00 0 0 6 * 0 0 a 0 0 4 0 low r04 o' 0- 0000 0 04 00060 - Yu. a. .41 (1) 00 thatualumplion that the telliall. di #;QWatwfta it a Catalyst 00 which a cbrm- reaction in taking place. and e on in rt substance placed In the tube. In l b l f b m ! to t rste o evo ution (cot INS. a sorpdols) of beat d beach- pi" ional to the rate of the reaction event f th d n i f o e e ect ment V o I the .1ifferential therriowtir' V(40."d and lostrikerv. B.I.Om 1010 C.A. ". $M6) suloplift a nershoo.1 of ekta. of the fraction 00 loviloortly d8lds. plovielvel the I 40slity factor I in == 00.31, 0 - I (dRIIII) 1% ottiliclently I of the IMP. .1tallillment ref the latter coullition. Involving practical 0 trinjo. inde-pendence of tb* beat of reaction, of the auto of beat rateocities, and of the brat conductance, wall tested 6613 esiominwalally un the oxidatkin W Cu on a Kitelvisubt go. Ca"Irl M 3143' and at 1111", whereas at 248' oaklation Is " 00 a complete. its tie" at 81) . coled. on the assumption 9 CORM (between OD and 20") wall 2747% *OR . . 26.7974, by mullytiad deta.. cort iw- caft". is permissible. for gorneval procedure Identic measurements involvin a ti l w n i t l t I o co s s s o n p g g n. will to agalmot the time 1; the am led The not of a is to tocisess. the curve and the tee ve of at ordinte times to Z 1 1 and 4) - 9 Is, - it.) where x - am of : reacted J Integration from 8 - 0 to I gives the wee Ix. Ther of the gas in the resectiou none bring mist., the rat of Jr. action (unlorm limited by the pencirestiols of Ot t b a SMI&C 0%W alai) dxld8 - & (a - S)'.W V - AV (a - X). Is the case of a finot-order reaction. tilt plot of oloagalast Is is straiglit Use its * gives the rate e4ed. be the H 1% 1: L & ase Me y6naw I& a Initial amt.). 7U error r ft 1" I I of F U It &1 00 Ati a K a 11 it . 000 *to* 9 111 0 0 00 00 0' 4 due to low at brat Is imusaierial dil- fermeor does met exceetl That for w of cooling Is valid. anel the total brat capacity. brat coad.. and the beat of reaction are practically comet; in veto range. (2) R t made on Co ;"a by 100 MI %7 &.;I ,b 2.6 S. C" las Ult) in --b mi. HjO. pietse. with KOH at 100", washing witb hot IIjO, drying awl ustmUlin & to cylinders 2-4 min loing, steel herviting I A hors at The therrineecoilople was di*Uwl between 6 mi. of the catalyst and a Mi. of S" Cylitedess. sited. toy inim, plaml in Ow sAtur luter of .1 &w. diam The catalyst was reduced to Cu by If. &1 6.6 1 .he. ml 946". thilalkm at M" with a dry gas mist. of 2.61, Ch + 97-h% No, &10 I.Ar.. was complete In 441 ruin.. furth; I Imsoooogr tof sit causid no drile"Ina to the galvancomelcr (in sucivulve tithiallious of the slault ralslyst, Itellowillit relocated te-ducthon-. tier integral* c"froolotioding lei Ss incresard teguloaly tor.j. IV?. 210, W4 oil. cm.). indi- cooling increasing activity of the Cu catalyst. At W". in an air stream at it I./hr. the reaction come to a halt after I I gain., furtherpassage4alf causingtiochalWalo,. From the total area qr. read on The v (1) PIN. as cousparrel with the area corresponding to IW% ozidatimi (at 245 1. tbor degree of oxidation at 80" was 27.37q of the C rese t (1hatoxidiseds1245"). (3) Bythe linearity ~WS~ Plot of vo, against the jx detd. by readings at various staIrs, thr fraction &I FO' Is of the Steel order. with 11 O.W (lime In Than IF 1r I v Ls F" 0 9 a a ) 0 00 :.go i-00 00 1 -00 1-00 !.go .00 coo .06 .700 are* 1;00 U4111410 tu wee BAMM~vp I-. N. Bash'--irov, A. IT., Stepanova, V. D., and Sukhotinskaya.. T. M. A sel-etive mejthod of processing primary tarn", (Report 1), Trudy Monk. in-ta tonkoy ldiir. tekhnologii In. Lomonosova, Issue 2, 1949, P. 43-58, - Bibliog: 6 itens, SO: U-3'42, 11 March 53, (Letopis tZhurnal Inykh Statey, No. 8, 1949). BASMIROV, A 11. ,azin in the presence of Bashkirov, A. N. and Vinhirova, T. D, "Cracking of kor, aluminum chloride". Trudy Mook. In-ta tonkoy Vhim, toklinolof:ii im. Lomonosova, Issue 2, 1949, p. 66-69. SO: U-3042, 11 March 53, (Letopis 'Zhurnal Invkh Statey, 11o. 8, 191,9). IISSRAnginearing - Gas Analyzers Gas Analysis Nov 49 "Gas Analyzer for Two-, Three-, and Four-Component Mixtures," Yu. B. Kryukov, V. V. Kamzolkin, A. N. Bashkirov, Petroleum Inst, Acad Sci USSR, 11 j,p "Iz Ak Nauk SSSR, Otdel-Tekh Vauk" No 11 Proposes new-type gas analyzer for analysis of two-, three-, and four-comronent mixtures of CO I CO H2, and N2 (or CH ~. Provides for automatic analysis at various rates cf Fas ffow. 'Apraratus uses rhei;eters, and calcium chloride and ascarite tubes. Submitted by-Acad S. S. Nametkin. PA l5crT13 Modmdoes of the orutheala of b ' *--b- 'rene trwalion Ut orcWting shimitan"waly with It. Ow twkwir a ! A ewbo monoxide end t1 fm i"V + oll- + + V/Is 2) COI + i Vu. It. Kryulmw, and V n. " 011.0 4 (1 - x - OCO + (sa x + alit" % were 9 w niole fraction CC) reacted arowdin to e uation SOO S.S.S.R. 67. I(rjv-3ItIq4q). The rwtjim ob. S q t) ) d H C Ill i l h i l WVW an F0 Mtslysts. 2 W + III - X " + C". Ino r& 1wr ow e C Ill t . an e Init a PD. e - ts confinsf to the r-clion CO + 2 11, - -C + 11.0 Ill t 1 h. wartioll k. In t1w 1.1 _~. I. b - 24/f 1 4 U) A amaving on Ni mail Co. ts atter1wriftl as the am of the '(1l timitent in i he IwAuluct). nt the 2M It% twfv d w L caw, JWUMArY MCtkIO 11, and the subsequent Kcaudafy reliction 6 - 13d/11 + + 200 + "Ill. The CO + 11,0 - C(h + Its (1,11). This point at view is 'ItHrmweA - At - Vist terme,l the contractioll. depir-2dion Ar cqwTebarAtc-j tYY ASWIYWSW the pavousprodwsobtained, d F haFifunentally. A altAnts laj~l values. up to Oll,--alC4. Oll to 21). 11,0addini in onts of the reacting IrAl mist . on pilt ir catalyst. with mists. COAII a 1:1 in the pnmcwv of adalvAl 11,0 vapar, at 220-60* under aten prve- . . , is fintrul tit have rvartni conipletely scrolding 1.1111. r,j 00 suft, at spam vrlovil y - 100ihr. The b wtill an initiAl inixt. CO It. IlrO - 44.5:44.5. 11. an an ' ' lion 1. is TXpMw4 by CO + will - 1/9 a T Fe-Cu-1n-KWOAWwtguhv c atatym, at 140 . 00 i t ODD + (I - x)CO + (we - 1/, 4119, where 11010 30)6% A cipti. - ralol. - 21 .4%. A CDC CC - 1:1 34 13 00 IrAction Co "wird. of tiloir. 11, 1.-1 nioi, co wilb ,ou all ' " vlhr vatalvat, at X141 , g4vr 4 iwg. %NvvittactWn of -32 Al p. ' '0 , "" . A - 72 4"~; l1w VYWhIol Ilydrovaltetwo, ,i I, lip. I'm is Tral,111-41 *bell 110, is elitninalvil. IC* T S fAtio tit the tales of reactions IU Aiul 1. on the W Cat.ilyst, tit 24(1*, i%:1.4. on the 2nd catalyst. at =111". it is 13.0. The ptimary reaction tio Ni, Co. and Fe is. identi. Cully. TrActiOn 11, And L'th 1% 3 W"414AFY IW11kItWt, 14. TIUM 1111141,014141,116t 1,111MAItOll CtatUPICIVIOU Ewk,wCf,/ saftorg ----- --- ...w V-1f- r-4--r-T-17 v 1 4 b u AT 10 It' Is a to 0 4 a a it It K a a It ;o , -Amim ir-11-T, 71 --- Aft- -1-1-4 rw o iii a I w P 0 61 0-) _67-10, us a I is 4111111 *00 41111,411, =00 9*0 we 0 bee Ilk 0 - -.. ~"- - 4z _`_-- --- , , , . ~ .. . I- - , ' , ~ - ., : ~ .- t~hemical Abst. - 4 Vol. 4S No Feb. 259 1954 Fuels and Garboulzation Products lole tion of indepjrum ~Mdg coauff biizese. A. lair C ..d. h -. p-1,.'7'= - --Crude nzeDe is distd.. and the fraction b. 170-1920 Is removed and treated with 16% N&OH and with 317, HiSO to remove pbencis -and excem allmil. The product L dtied.~d then chlorinated at -3 to -5' while the mixt. Is v4wou311 stbred. The chlorinated mirt. h distd. at 8-10 mm., and the fraction contg. CoElsCit. indent diddoride (U), is removed at I IG- 182'. About 90% of Indent Is converted to 11, which is reduced to indeve in about 90% yield with Pe and steam. 11 6 dechlorinated In the vapor phase at 16-20 mm. and 175-180'. The reduced material is again vacuum distd. tlo Add Indent, C4H,. b-in 181.4-192.5. d,': O.QM x~* 1.5754. mol. wt. 116.8. m. -3.1% picrate w. 97.0-98.0*. Geonte G. Rtrnar~ ' Cfi b Co + + CHl + COs. and CHO + HA, od 00 M C my 0 a rosaft of tw swo-Im readion A ChWWOW* H .,.jkmWdksAlVby&- co + so - C04 my :L;t" onalact tbo pm-td tb. elpts. in obkb a v Appm Miami" reaction lkam tAkbW DbKt -clable eamt Is me WOO Valk ioW HIO ih Pa. wm, r"NW"d coodlostion betWOU WOO 10 fgmted :H.- tU MW ;2 add. at SWO do-O 84 a Poo-O opw rk, 012"s "i al VIETKAW Wo ad r*CVW. wkh tbt . a" W. - &*Wow at llwl-t~Zldrl odw them ton U-b 90, I. so PITW# COIL A.. t CE6 100.0, M 6-tca. in. OW no IIIIS 1,4 41 tbeanva iN+ Hi cli, + CO, and JW 40 CO, UL OW Ft aike. CO, CIMI, tbrou& a ,,,dary fenetwn between CO ?A Intr3ed N. Than mod lu. 'the dii"tioli, IJ "The 4tiestim ~ or Hydrocarbons," A. N. Basbkirov, "Dok Ak Nauk SSSR" Vol ILMCMVIII, K 7'e~ Review subjecton basis of USSR v v process can be mad to proceed in n tion by appropriate choice of con n ad of suitable catalysts (MD04 or ad No 2). Cites exptl data shoving course of oxidation. Describes e e formed in reaction on course of re r cordizg to emptl results, oxidatio io LISSR/Chemistry - Petrole= (Contd) phase proceeds vith successive spli terminal C atoms. Describei oxida C14 alco and aldehydes and of.mixti isolated from oxidized paraffins. Chemiml Abst. compounds In the puth*~W 01 Vol. 48 No. 9 Role of Y", a " u . hvdfowunL from carbon Monoxide and h di~W. MaY 10, 1954 i~d Organic Chemistry Fir"Chem. SO. ~ Mk-!*-BngI. tmnsInflGn)------See A". 47, 3216 USSR/Chemistry - SynIthetic Liquid Pwlsf TUI Catalysts "Concerning the Problem of the Investigation of JAqi Catalysts for the Synthesis of Hydrocarbons. From' ~ Carbon konoxide and Hydrogen," Yu. B. Kryukov, A. 1. Bashkirov "Trudy Inst Nefti" Vol 2., pp 92-109 The present methods for evaluating the, performance c Lron catalysts are inadequate. A new method which. J more precise has been developed. This method, whidl 18 described in detailconsists in determination of the degree of conversion and of all other indices 243TI1 rational utilization of analytical data an the gaze 'i before and after conversion and of other experiment. ally found values. The method can be used for otbei catalysts besides iron. PkS&,I4-JV? A. N. USSR/Chemistry - Synthetic Liquid Fuels Jul/Aug 52 "The Role of Oxygen-Containing Compounds in the Synthesis of Hydrocarbons From Carbon Monoxide aml Wdrogen." Yu. B,, Kagan, Yu. B. Kryukov, Ye. V. Kamzolkina, A. N, Bashkirov, Petrole= Instv Acad Sci USSR IIIz Ak Nauk SSSR, Otdel Khim Nauk" No 4, pp 649-657 Article states that results of the expts described show that a1cs cannot be regarded as intermediate products in the synthesis of hydrocarbons, and that iron catalysts, under the conditions of hydrocarbon synthesis, accelerate the oxidation of ales and aldehydes. Advances hypotheses explaining the formation of oxygen-contg compds (by-products of hydrocarbons). PA 229n6 STORCH. H.; KAGIN, Tu.B.[translatarj; KRTUILOY, Yu.B.Ctranslatorl; LOKM, S.H. [translator]; LUKIWITS. Y.G. [translator]; PAWKI- ROY. A.N., professor, radaktor. 1--amm"M [The Fischer-Tropsch and related syntheses (original title); translated from the InglIsh by W.B.Xapn (and others)] Bill- tas uglevodorodoy is okisi uglaroda I vodoroda. Perevod 9 anglilskogo IU.B.Xriukova, S.M.Loktova I V.G.Luklianitea. Pod red. A.N.Bashkirova, Moskva. Ind-vo inostrannoi lit-ry, 1954. 516 p. (K= 7:8) (I%mthine process) (Catalysis) T_r I n-- t af t t A NS-,-Sk, Vol 4, 1954, 159-i72 1,2-Dihalogenated hydrocarbons were passed through a heated tube con- taining pyrophoric iron. The reaction products were olefins when the poly- merication and iscvetrization were inhibited. Using this method, olefins were prepared from 1,2-dibromo substituted n-parfinB frcm C2 to C8, cyclo- pentane, cyclohexane, styrene, indene, and tetrabranocyclopentane. The yield ranged from 80 to 90%. (RZhKhim, No 3, 1955) SO: Sum-No 845, 7 Mar 56 BMHKIROV,,*,X,.; KHOTlMSILAyA, M.1. Oondition of the dual relation In olefins obtained in synthesis from carbon monoxide and hydroxide. Trudy Inst.nefti 4:173-175 #54. Off-IM 8..1) (Olefins) (Carbon monoxide) (Hydroxides) "A Study of Certain OYidated Catalysts in the Synthesis of Hydrocarbons from Carbon Monoxide and Hydrogen" Iz. A. Nauk SSSRI Otdel Tekhp Nauk., No. 8, pp. 147-53, 1954. The composition and characteristic features of certain new catalysts for the synthesis of hydrocarbons from carbon monoxide and hydrogen are described and didcussed. These new catalysts contain neither iron, cobalt, nickel, nor ruthenium as their basic component, but one of the poorly reductible metal oxides (ThO2, M902, A1203, etc-) and are called, therefore, oxidated catalysts. I 3ummary - 550423 lk VIA P, A - I I - - T I . - I . ~l . ~t , - I; ~ . ., !'-Y 4L~. ( w 4,1 Ll - - ---~l - - .--- -,.. .. A v,-ut-t zA b !. -- I, -lt~ ~', ~ -1 (01-7 : d,wlewing the (,,nta,t litne to half reduces ~ - '. 1"."; ., 'i, :!-- -1 -, , - I !!.. , , 47 ~ 4~~ M MIM -4F -21~Z p" sz;.- A,u th. 7", ,4 .I I iz I I 0 -2 ~ 11, kwwr BASKIROV. A.N., PrOfIssor. 3ymthesis of higher alcohols Of the f&tV series by direct q=Jdatio, Of P&r&ffl**- XhIM,lk&Uk& 1 prem. (Alcohols) (p&r&f:fib) ~ 1 110-3:273-281 156. (MMA 9: 9) ��������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������-1 9 I A '7e vz~ "I ffll iR I-, I m4w..' T USSR/Cherdcal Technology Chemical Froducts and Their 1-13 Application. Treatment of nutural.gases and petroleum. Motor fuels. Lubricants. Abe Jour Refurat Zhur - Khimiya, No 4, 1957, 12955 Author Baahkirov A.N., Loktev S.M., Khatimakaya M.I. Title Co vZsUM5 Synthesis F-roducts rrom 00 and H2 over Mi Kieselgtihr Catmlyste 18-22 Orig Pub Khimiya, i tekhnologiya topliva, 1956, No 5, Abstract Presented are the results of investiption of the compo- tion of gaseous and liquid products of the synthesis from ,coN USSR/Kinetics - Combustion. Explosions. Topochemistry. Catalysis. B-9 Abs Jour Referat Zhur - Xhimiya., No 6., 1957P 18633 opion that the special properties of catalysts reduced in CO are connected with the carbonization of the redu- ced iron and the formation of cementite Fe3C' Card 2/2 273 MR/Physical Chemistry Kinetics. Combustion. B-9 Explosives. Topochemistry. Catalysis. t1s Jour : Referat Viur - Khiraiya, No 2, 1957, 3852 Author : Bashkirov, A.H.V Khotimakava M.I., Kryukov Yu-B. Inst institute of Petroleum, Ac4demW of Sciences USSR Ti tIL: Synthesis of H)droewboha ;.'rm Carbon Monc)xije and Hydrogen over "Sintered" iron Catalysts Orig Pub Tr. In-ta nefti, AN SSM, 1956, 8, 162-167 Abstract Study of the effects of the conditjuns of reductJon upon the nechanical strengl.,,- w.,' activity of precipitated.! ',Ic- tivated Fe-catalyate 'j, thc process of synthosis of 1-.y- drocarbons. After troritment of the catalyst in a current of H2 at 800-8500 ail(~ space velocity of 2000 hour-1 for 2 hours, the reduced air' sintere(I specimens ire of suffi- cient mechanical (-urab-,.IJty; thoy tire inactive at atrios- pheric pm-ssure and are tictive at % pru-s-siLre of 200 atwspheres, temperature of 3000 an-~ space velocities Card 1/2 - 143 . - -17 USSR/ Physical Chemistry Kinetics. Combustion. Explosives. Topochemistry. B-9 C&UlYsii Abe Jour Referat Zhur XhiMlYR., No 4) 1957) 11286 kithor Bashkiio* K.N.- L6kteV S.M.."gabirove. 0*.V. Ntr6ler(ap * Acadeiv of _8616fides USSR Title St6dy 6f Some Aetal Oxides in the SynUiesis from Carbon Monoxide and Hydrogen Orig Pub Tr. In-ta nefti AN33SR, 1956, 8, 168-175 Abstract Study-of catalytic adtiidty 6f'6xidis Of Pb- On Cd, M6,'V__Crl Oil map O~ Til VI'Al,'Xg,,'fJr',' "M (irith"Witimi- . ~~S,)njjjlithe'~*'G&'idon2of syhthisis of * hydroearb6ns' fi6k idituii -CO 1'i lln-diiCWAtion . 0 1 i~itezi-at 30CI-;500,$___aAa'30 &U_piealr~re (_i569&tz 1;'the-itasi-of Th02' 0. and Al~l at space fa6diti6V1M;M_hoiii;-l._ -_WdeVof_PIi, Shl And'* Cal.iuiad_thi-ibo*6-:itited 66,iditioa, i3~e -iediced' t6- thi metal'&nd"their acti*ity ii-Wky-ilij~ht.- C!&t&I*bt-Used 6ii*&kides-of-M6''-W.-8i, Mal -V,I X~- ihoir lii~b-iiftiirit~ ba piodiidii ii6itly - iAsioii- IAi6carb6"-.- - Oitalyiti bixdd'dA'6iid6i of'Ti adid Or vere' fduiid- to be inti~tivi'*-"-Rigieit'i~6ti*ity is exhibited by'SiO2 +,2% K2C03, the yield of liquid reaction products ~/2 vith.. thii - 6&tAlyst beiz4 -of ~ 30-60 -ejj3. '-C;ranWAt4dK2C03,'__and also 6A iati*itia-'chiic6ba Are'inacti*e, -It U h6ted thit,6~1 -Ciatal~stli -(if viii , S~Athesii-Ui66& -6n CO and % unt possess the property of activating the CO molecule. 2/2 B-9 J__ USSR /themical Technology. Chemical Products 1-17 and Their Application Industrial organic synthesis Abs Jour-4 Referat Zhur - Khimiya, No 9.. 1957, 32035 Author : Bashkirov A.N., Novak F.I. Title : Study of Thermal and Chemical Activation of Tale Catalysts for Synthesis from Co and H.. Orig Pub: Khimiya i tekhnol. topliva, 1956, No 10, 32-36 Abstract: The possibility is shown of utilizing in the synthesis from CO and H2of catalysts (C) with a tale base (natural magnesium hydrosilicate). In preparing active catalyst from tale a preliminary thermal activation of the latter, by calcina- tion at about 6oo*' is necessary. It is shown that the formation of liquid products of the C ard 14 USSR /themical Technology.~ Chemical Products 1-17 and Their Application Industrial organic synthesis Abs Jour: Referat Zhur - Khimiya, No 9, 1957., 32035 synthesis over tale C, the latter must be ac- tivated by compounds containing ions of alkali metals; of the 16 compounds that were studied the most active are carbonates and nitrates, and of the reagents those the anions of which con- tain atoms of metals (Cr, Mn. W etc) are less active. Substances containing the tons Br-1, Cl-1 and SOY-2 deactivate completely the C, but the F-ion was found to be a very active promoter. Taking into account the specific features of the crystallochemical structure of tale, the assump- tion is made concerning the role of thermal and C ard 2/0~ USSR /themical Technology. Chemical Products and Their Application Industrial organic synthesis Abs Jour: Referat Zhur - Khimiya, No 9, 1957, 32035 chemical activation in the process of formation of liquid products of the synthesis from Co and Hp- C ard 3A ry y a Card 1/2 Pub I AUthora oe Title C r, Card 1`2 U~. per-. C-) - 12. ui FIF III WMM SO T M, - ~i ~ '-'t m- -_,g '&-SHKIROV, 1~,N- AUTHOR: Bashkoriv, A.N.,, Kamzolkin, V.V.9 Sokoval K-M and Andreyeva, T.V. ~5_4_2T1~ TITIA: Method of determination of primary and secondary higher alcohols of the fatty series in their mixtures. (Metod opre- deleniya pervichnykh i vtorichnykh vyssikh spirtov zhi3Mogo ryada v ikh smesyakh) PERIODICAL: "KhimiTa i Tekhnologiya Topliva. i Masel"Whemistry and Techn-orogy of Fuels and Iubricants)l95?,No.4,pj?-7-ll (U.S.S.R) ABSTRACT: During studies of higher alcohols prod,4ced by a direct oxi- dation of paraffinic hydrocarbons it was found difficult to determine the content of primary and secondary alcohols, as methods described in the literature (2, 3, 4) were found unsat- isfactory when the number of carbon atoms in the molecules exceeds eight. The method is based on some regu)rities in the xidation reaction of higher n-aliphatic alahols with chromic Card111 ocid in glacial acetic acid. The accuracy of the method on av- erage 5% (Table). There is one table and 6 references includ- ing 3 Slavic. ASSOCIATION: Petroleum Institute Ac.Se.U.S.S.R. (Institut Nefti AN SSSR) AVAILLBIE: AUTHORS: Krykov, Yu '*'B. Butyu . gin, Yrt Liberovi, L'T., Stepanovaj It.D. and 1 65-6-4/13 TITLE: The use of radioactive carbon for the investigation of the behaviour of methane under conditions of the synthesis of hydrocarbons from 00 and ~2 on iron catalysts. (Ispol'Zov- aniye radioaktivnogo, uglaroda dlya issledovaniya poveden- iya. metana v usloviyakh-sinteza uglevodorodov iz 00 1 R2 na zheleznykh katalizatorakh)', PERIODICAL: "Khimiy Topliva ~Chemistry and A i Tekhnologiya - i Masel" ( Tectmology or Paels and LubrTcants) 19571 No .6, pp'*'26-33 (USSR).. ABSTRACT: A critical survey of the literature on the problem of the role of-methane in the synthesis of hydrocarbons from CO land H2 is given'. An experimental investigation of the abovelroblem.12p carried out usi33g methane containing radioactiveng C,4ORadioactive methane was obtained VY hydrogenati 2 over an Bi-A1203 catalyst and CJL'kO, was obtained by dec *omposing a mixture of BaC03 + BaC14CO 3 with sulphuric acid. The apparatus used for the sypthesis of bydrocarbonB is described and shown in a diagram. The Card 1/3 catalyst used was developed in the Petroleum Institute of The use of radioactive carbon for the investigation of 'the behaviour of methane under conditions of the synthesis of hydrocarbons from CO and ~,,on iron catalysts'. (Cont'.) the Academy of Science of the TX.S.]C, its Pe 304 + 10 (AL203. + Sio 2) + E20 with an addition of chromium (ref 24). It was obtained by the melting of mag- netic iron oxide with activators and crushing the mass pro- duced to 2-3 um sized. Before application the catalyst was reduced in a stream of hydrogen at 1000 0 for lr*3 hours. ~In order to obtain a high activit and stability it was also treated for 18-20,hours at 390 0 and 20 ati~. pressure with the synthesis g, a- W + % (1:1) passed with a volume velocity of 1500 hr- '. Pome preliminary experiments indi- cated that a good reproducibility of results was obtaineC Typical results are given in tables 2 and 3 and in table 5 results of an experiment with radioactive methane (material balance of the process and the distribution of products ob- tained) are given, The results of fractional and radio- metric analyses are given in table e, It was established that under"experizental ponditions (20-25 atm, 310 09 volume velocity 1150 hr-1, CO-IR2 = 1:1) methane behaves as an i1art substancet it does mot participate in the format- Card 2/3 ion of higher hydrocarbons and does notreAter into the The use-of radioactive carbon for the investigation of-..-the behaviour of methain under conditions of the synthesis of hydrocarbons from CO and ~2 on iron catalysts' reaction of isotope exchange with carbon mono 0 bon dioxide and bydrocarbons There are 5 tablesp 1 figure and 29 references, including 10 Slavic. ASSOCIATION:,Petr oleum Institute of the Academy of Sciences of the US.-S.S. (Institut Nefti AN SSSR)'. AVAILABLE: Card 3/3 BORKIROV, A.N.; KAGAN, YU.B.: Ibrm' S.M.; MOROZOV, N.G. Use of Iron ore catalysts In the symthaels based on carbon monoxide and hydrogen. Trudyinst. nafti. lOt234-246 157. (Catalysts) (Hydrocarbons) (miRk 11:4) LOMMOTo A.N.: XAUN, TU.391 10nWo Me; SKOKKINs T#V~; GOLIDIN9 BeAel Activating characteristics of molten Iron catalysts used In the synthesis based on carbon monoxide and hydrogen, and reduced at high teMperatures. Trudy inste nefti. 1M47-261 157* (KIrt llt4) (O&Ulyvts) (Hydrocarbons) UGAN, U.S.; BASUIR:OV9 A.I.; ZVIZDKIM, L.I.; ORLOU, N.A,,; KLIGIR, G*A, Influence of reduction conditions on the proportion of molten iron catalysts used in alcohol synthesis from carbon monoxide and hydrogen. Trudy inst. nafti. 10:262-268 157. (MIRL 11W (Alcohols) (Carbon monoxide) (Hydrogen) j AUTHORS: Kryukovp Yu. B.# Butyugin, V. I., Liberov, Le G.,, Stepanova, N. D., Bashkirov# A, N. 62-11-23/29 TITLE: Synthesis of the Butyl Alcohol Containing the Radioactive Carbon Isotope 014 (Sintez butilovogo spirta, soderzhashchego radioaktiv- nyy izotop ugleroda 04) PERIODICALt Izvestiya AN SSSR, Otdel.Xhim.Naukp 1957t Ur 11, pp. 1404-1406 (USSR) - ABSTRAM Here a new method for the synthesis of butyl alcohol,which is tag- Sed by radio-carbon c14, is introduoed. This method is character- ized by simplicity and a high output of special product. The me- thod consists of two phasess magnesium-organic synthesis of butyrio aoid w4th elimination of the latter in the form of so- dium-butyrate and the restoration of the salt by lithiumalumin- umhydride. The method can be applied for the synthesis of dif- ferent alcohols containing the radio-oarbon CU. It is shown that a synthesis of the tagged butyl alcohol is also possible without preceding elimination of butyrio aoid by means of immediate re- storation of the magnesium-organio complex 0 OR -OMgBr C3H7 a by lithiumaluminu+ydride. There arc -1 01-vic references. OSOCIATIONj ftt4V1*= Iwft#*e of tM.Al USSR (Institat pettl AkeAenll Card 1/2 BASHKIROV, A.N.60 doktor tekhnicheskikh nauk, professor; KAMZOLIIN, T.T.. kandidat kunicheekikh nauk; LODZIK, S.A. Technological elements of the production of higher fatty alcohol$ by the direct oxidation of paraffinic hy0ocarboris, Mael.-shirlprome 23 no.7:24-26 157. (NLIIA 10:8) 1justitut neftl AN SSSR. (Alcohols) (Hydrocarbons) (Oxidation) ----- ---------- ------ KRYMOV, Yu a Be) BASMMOVI As N. BVrMIN2 V. K., LIBEROV, L. G. and STEPANOVA) He D. (Petroleum Institute I[ AS USSKi "Intermediate Oompounds in the Synthesis of Hydrocarbons and Oxygen-Containing Compounds of Carbon Monoxide and Hydrogen on Iron Catalysts." P. 58- anl :~aa :a 4~ *2 v3m-f. on 1~rs(& ef PvAdtcka,-~tive! ane, radla, 1r,-in im Na!1cmaj 1.,camy r.04 S-Aon~4t, 111r~acow. 1:4-v0 .,J, zz~~Z,, 19,8" o'! -,-'w ~!rv all Qnd S-IiAtOke Y~adlallc-~ :-r~t a"A KaLa Adlila rctr of A, it iNt-Prrjy "ovu!!1! cl,7 C4 ja z pill XAGAN, Yu.B.; B&SHICIROT, A.N.; KRTUMDT, Yu.B.; LOnW, S.M. Formation of the active surface of fused iron catalysts for synthesis from 00 and H2 . Xhim i tekh. topl* i masel 3 no-3: 14-22 Mr 158, (MIRA 110) 1,Inatitut neftl AN SSSR, (Catalysts) (Iron oxides) (Hydrocarbons) BASHKIROVI AeVol XWOUCINO Vero; SOEDVA, X,M#; ANUMVA, T.P. Position of the hydroxyl group In alcohols produced by liquid phase oxidation of n-paraffin hydrocarbons. Xhim. I tekh. topl. I masel. 3 no.6tio-16 is 158. WRA 11:6) l.Institut nefti AN SSSR. (Hydroxyl group) (Alcohols) (Chemical structure) AUTHORS:.- Bas!j~~A._N.,-Xagan, Yu. B., Kli-er, 0. A. 62-58-4-21/32 TITLES Cmposition of Products Obtained by the Synthesis of Aminus of Carbon-, Hydrot;en- and Ammonia Uonoxide (Sostav produktov sinteza aninov iz okisi ugleroda, vodoroda i ammiaka) PERIODICALs Izvestiya Akademii Nauk 5SSR,0tde1en;be Khimicheakikh Nauk, 1950, Hr 4, PP- 504-506 (USSR) ABSTRACTS Already earlier the authors realized the synthesis of the alkyl amines of CO and a=onia in the presence of molten iron catalysts. The synthetizing products ob- tained contained up to 25% aliphatic amines. Further- more a perfection of the used catalysts was carried out. A stable, active and rather selective catalyst was found. In the presence of the catalyst the aut ors synthetized on moat favorable conditionst from 1 m~ 12olo grams of synthesis products (without water). Of these viere 54,o% alkylamine8 (30% of which in liquid and 21,o% in gas state). Tables 1-4 give information Card 1/2 on the results of the elementary analysis of some The Composition of the Synthetization Products of the 62-58-4-21/32 Amines of Carbon-, Hydrogen- and Ammonia Monoxide fractions of the destillation and the physical con- stants of some fractions. There are 4 tables and 12 reforenceB, 3 of which are Soviet. ASSOCIATION: Institut nefti Akademii nauk SSSR (PetXV1 Institute., AS USSR) SUBUITTEDi November lo, 1957 AVAILABLE: Library of Congress 1, Catalysts--Synthesin-Study and teaching Card 2/2 AUTHORS: Xr~-ukov, Yu. B.,_A~Eshkirov, A. H.V 62-58-5-22/27 Butyugin, V. K., Liber--ov-,-I-.--o.--,-tt"anoya, N. D. TITLE: Conversions of Butylene on the Conditions of Synthesis of by Way of Molten Iron Catalysts (Prevrashoheniya CO and H 2 butilena Y usloyiyakh sinteza iz CO i H2 nad playlenymi zhelez- nymi katalizatorami) PERIODICALi Izvestiya Akademii Nauk SSSR Otdelaniye Khimicheakikh Nauk, 1958, Nr 5, pp. 642-644 (USSk) ABSTRACT& The present report is a trial of investigating the ways of conversion of the olefins forming in the process of the synthesis of the hydroolrbons and of the oxygen-containing compounds of CO and H2.Butylene marked by means of the carbon isotope C14 in the state (polozhenii) I served as indicator of the behavior of olefin under the conditions given by the synthesis. The experiment has shown that butylene does not part- icipate in the formation of alcohols, as well as in the form- ation of highest hydrocarbons (by way of Cq~ neither and that it is no intermediate product. Butylene can react with CO and under the investigated conditions by producing & C5-hydro- H Card 1/2 2 carbon. 'At, also submits to dehydration, oxidation and hydro- Conversions of Butylene on the Conditions of Synthesis of CO 62-58-5-22/27 and H2 by Way of Molten Iron Catalysts cracking. There are I figures, 1 table, and 11 references, 9 of which are Soyiet. ASSOCIATIONs Institut nefti Akademii nauk SSSR (Petroleum In3titUtS AS USSR) SUBMITTEDs j&nuary 2, 1958 1. Hydrogen Isotopes--Synthesis 2. Carbon monoxide--Synthesis 3. Ethylenes--Chemical react-.,)ns 4. Butylene-Chemical reactions 5. Carbon isotopes (Radioactive)--Applications Card 2/2 - ----- - ----- -- ATITHORS: - -Tin Ph1.r41MggW_- A--m- lramrolkin, V. V; Soko~ra, K. M. and kidreyeva, T. TITLE: The Position pf Hydroxyl Groups in Al-Ichols Prepared During the Liq4id Phase Oxidatioo of n-Paraffin Hydro- carbons. Mpolozhenli gidroksil'no7 gruppy v spirtakhp poluchayemykh pri thidkofaznom okisionli ---paraftnovykh uglevodorodav). MRIODIOAL: Khimiya i Tek nolofiya Topliv i Masell. 1958p Nr.G. MSSR lo 16 - . pp. ABSTRACTt When iinre stigating the position of the hydroxyl groups d d th th i l t th th l h e me o he au ors use n e a co ol molecu ep of cxldizing alaoh-^#ls with potassium d1ohromate in a medium diluted with sulphuric acid (Ref.4). During the oxidation of primary'aloohols, carboxylia acids, with the same number of C-atems as G;ntained in the initial alcohol, are obtained. During the ex! -dation of asoondary alcohols, the C-C bonds are split at the hydroxyl groups, and carbo371ic aolds with a lower number of C atoms in the molecule are formed. Therefore, it is possiblE; tt determine the position of the h droxyl groups according to ~ the eompoaition of the acids. ome sida reactions take place when the process is carried out stalphuric acid Card 1/3 at in,%reased tamp&ratures- The authors in7eatigated the The Position of Hydroxyl Groups In Alcohols Prepared During the Liquld Phase Oxidation of n-Paraffin Hydrooarbons. oxidation of individual aliphati alocnhol.,3 with varying positions of the hydroxyl,group ?4-tetradecanA, and 7-hexadeianol) with subsequent identlfivatic~n of the acids. The method of F. Kraft (Ref.4) waa sli&htly modi- fl6dv and distillations were oarried cu~ according to the,method described by L. K. Obukhava Ref.5). The Y,ei&.t of the reotifioation eolumn was 40 cm and the diameter le4 em. A mixture of hydroaarbonsr from which the olefins and aromatic hydrocarbons had been separated, was used aa ~.,arriar. The content of esters in the frac- tions was calculated or. the basis of the eater number of the fraotion. On tho basis of the composition of the aoids it was possible to conclude that oxidaticn of the aloohols cacurs mainly at the hydroxyl g-Aoups. Dis- drepanoies In the rule of Papay, oacur at Inoreasing dis- tano es of the hydroxyl greups from the end hydrooarbon a - The neutral oxygen-containing oc~mpound tom. a (ketones), obtained during the oxidation, were subjeoted to second oxidation reaction. The total yield of acids ;: 96%. The ',.ziestigated fractions ef alooholswere concluded to be a mixture of Isomers of secondary p- hoxadeaanols Oard 2/3 in wh1oh the iscme-As are oontained in equal molar The Position ' of liydrbxyl Group6 In Alcohc!'* sPreparad During the Ll-juld Phase Oxidation 111hr-affin Hydroo of n- arbon.00 quantitiez. Ex-perimental details on the ox-fdation of the indl:viduai alcohcls are given-TablaW I and 2 give the composition of oxidation producta of ali%oliols and of their distillates;' the distributic-n of acids is shown in Table 3. During experiments on defining the position of the hydroxyl groups in the al^,ohelsp a frac- tion of aloohols boiling between 125.0 - 126.e, with an hydroxyl number of 229,50 was oxidized The nsutral oxygen-oonta-Al.ning oompounds were subjezted to a second oxidation reaotion. Results are g,-.;Fen I.n Tables 4 and 5. These experiments showed that during the oxidation of n-paraffin hy4roaarxbons in the liquid phase, a-secondar-) alcohols are fc--mad. The hydrcxyl groups of these aloo- hols are situat6d at different- 0 atcms cf the molecule. It was also found that the reautivity of the secondary 0 atoms of mcleoules of k,.igl-.er n-paraffin hydrocarbons to oxygen is practic-ally idlentical. There are 5 Tables and 8 Ref6rencest 4 S,-qiet, 2 German. 'A. English and I Card 3/3 Dutoh. ASSOCIATION-. AS USSR (Institut nefti AN SSSR) SOVI 65-59-7-7/12 AUTHORS: Bashkirov, A. N; Loktev, S. M. and Sabirovaj, G. V. 1-11~~l-,!-,.-Iz,~."~.~..~.-Z.l~~*-~~,A~.. TITLE: Hydrogenationof Aldehydes and Ketones in Mixtures With Other Organic Compounds. (Gidrirovaniye al'degidov i ketonov v smesyakh s drugimi organicheskimi soyedinanl- yami). PERIODICAL: Khimiya'i Tekhnolo~iya Topliv i Masel, 1958, Nr.7. pp. 39 - 45. (USSR . ABSTRACT: The authors investigated the selective hydrogenation of compounds containing a carbonyl group to aliphatic alco- holsiespecially 0 - 020). Starting materials used were liquid products obtained during synthesis from CO and fractions of these productso or individual aldehydes an ketones (Table 1). The hydrogenation was carried out in a continuous process. Copp6r-chrome-barium and niokel- Magne ium OXalatq# as well as fused iron catalysts, were used T70 - 75 amQ). Details of the preparation of the above catalysts are given. Table 2 gives results obtained during the hydrogenation over a copper-chrome-barium oata- lyst at 100 atms,at various temperatures. Experimental conditions during these experiments were those described by He Adkins (Ref.~j and D. M. Rudkovskiy (Ref.9). Table 3t results obtained during the hydrogenation over nickel- Card 1/2 magnesium-oxalate catalysts at atmospheric pressure and S OVI 65 -58- 7- 7~ 112 Hydrogenation of Aldehydes and Ketones in Mixtures With Other Organic Compounds. 500C. Iron catalysts were first investigated by V. N. Ipatlyev (Ref.2. 18 and 19). However, the yield of aloo- hols.was low, and the yield of decomposition products high. Very good results were obtained when-the hydrogenat- ion was carried out over fused iron catalysts at pressures above 100 atma, and at a temperature of 20000. Table 4-. data on the hydrogenation over Fe",04t 1MO0,3- When lithium- aluminium hydride was used in ether solution (Table 5), it was possible to achieve practically complete reduction of the oarbonyl and also of other oxygen-containing compounds to alcohols. Yields of alcohols range between 70%- 80% for copper-chrome-bariLAm and n4.ckel-magnesium-oxalate catalysts and 90% - 98A for fused Iron catalysts. There are 5 Tables, 19 References: 11 Soviet, 3 English and 5 German. ASSOCIATION: Institut nefti AN SSSR Petroleum Institute of the Academy of Sciences of the USM. 1. Aldehydes--Hydrogenation 2. Ketones--Hydrogenation 3. Organic Card 2/2 compounds--Hydrogenation AUTHORS: KaZang Yu. Bj ~Ba SOV62-50-lo-19/25 Kryukov, Yu. B.j Loktevt S# 11., Orlova, N. A. e-ITITLE: On the Mechanism of the Catalytic Efficiency of Fused Iron Catalysts in the Synthesis of CO cnd H 2 (0 me"na- nizme kataliticheskogo deystviya pl--vlcnyA.h zhelozny.',h katalizatorov ninteza iz CO i H 2) PERIODICAL: Izvestiya Akademii nauk SSSR. Otdoloniye khit:iicho31:ikh nauk, 1958, Nr lo, pp 1274 - 1275 (USSR) ABSTRACT: In an earlier paper the authors showed that immediately after the reduction (by hydroZ;en at 10000) fused iron cata- lysts in the hydrocarbon synthesis of CO and H 2 are not active any more. Only under the working conditions of the synthesis when the b-as mixture CO+H 2 is passed thr6uGh the catalyst Gradually becomes active (for 18-2o hours). This phenomenon may be explained by a number of simultaneous reactions competing with each other. Due to the course of these reactions com- peting with each other the metallic iron reGenerates Card 112 often (under the conditions of the synthesis) from its A: ~ THL-, S: Y~_- . '~. , _; - - . / '_ '. -, - .. - .. , I ~ Kryu4k-ov, Yu. B. , Lo"tev, S. Orlcva, 11. A. TITLE: On the Mocheaniam of the Catalytic Efficiency of Fused Iron Catalysts in the Synthesis of CO and H (0 mcl:ha- 1 2 nizme zataliticheskoGo deystviya plavleny1ch zheleznylzh katalizetorov sintena iz CO i H 2) PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khiviche3kikh naul., 19531 Nr 10, pp 1274 - 1275 (USSR) ABSTRACT: In an earlier paper the authors showed that immediately after the reduction (by hydro,~en at 10000) fused iron cata- lysts in the hydrocarbon synthesis of CO and H 2 are not active any more. Only under the working conditions of the s~-nthcsis when the jas mixture CO+H 2 is passed through the catalyst gradually becomes active (for 18-2o hours). This phenomenon may be explained by a number of simultaneous reactions competing with each other. Due to the course of Viese reactions con- 0 -enerates petin with each other the metallic iron re, Card 1/2' often (under the conditions of the synthesis) from its 1. 0,.,, tne ldec..~an Ism, of t.-ic, Cat lytic Eff 'L ci e:.cy of F%Ii--(~,d S~~V/-(-2- L- I o- 1 V2~1~1 Zron Catalysts in the Sy~nthesis of CO and H 2 compounds, and at the surface of the operatinG catalyst the dynamic equilibrium of the surface phases of different chemical structure is obtained. As a consequencc of these processes the activation of the catalyst occurs. Neither the iron itself nor compounds that might be formed from it are the reason for the activation of the catalyst surface. The hypothesis formed for the chain mechanism of the catalytic efficiency of iron catalysts (according to which the synthesis of CO and H 2 is caused by the reactions of carbon and hydrogen monoxide Nvith iron and its compounds on the surface of the operatinE, catalyst) was described in detail by the authors. There are 1 table and 1 reference, . .7hich is Soviet. ASSOCIATION: Institut nefti Akademii nauk SSSR (Petroleum Institute AS USSR) SUBMITTED: April 8t 1958 Card 2/2 KAGAN, Tu.B.; IiASHKIP-OV. A.B.; ZVEZIMINA, L.I.; ORWYA, N.A. Fused Iron catalysts in the synthesis of higher alcohols from carbon monoxide and hydrogen. Trudy Inst.nefti 12:200-212 158. (Alcohols) (Catalysts) WRL 12:3) BK;1EKIROV, A.N.; KAI&GUINA, Te.V.; KnWUN, Tu.B. Particular aspects of the decomposilton reaction of carbon monoxide to 0 and C02 In the presence of fused iron catalysts. Trudy Inst.nefti 12: 213-227 158. (NIRA 12:3) (Carbon compounds) (Catalysts (Chemical reaction, Rate of) KAGAN, Yu.B.; RASHKIROV, A.N.; LOKTEV, S.M.; Wlk)ZOV, N.G.; ORI~')VA, N.A. Effect of the introduction of ferroalloys on the activity and stability of fused Iron catalysts for synthesis based on 00 and 92. Trudy Inst. nefti 12:228-239 158. (MIRL 12:13) (catalysts) (Iron ailoya) (Cbemistry, Organic-Synthesis) BASHK I ROV. A. N. ; IUV AK, F. I. Studying conditions of synthesis from carbon monoxide and hydrogen on.talo cataly:t:~ Trudy Inst.naftl 12:240-245 '58- (MIRA 12:3) (Cat,Lly t (Chemistry, Organic-Syntheais)