SCIENTIFIC ABSTRACT BASS, M.M. - BASS, Y. B.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000203920001-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 6, 2000
• Sequence Number: 1
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

uss, H.K4,-- 41f tnent (Kiyov, ftsarlyevskaya, ulo d,9,ky.16)
Use o~rubba- %ponge as an alloplastic material. Vost.khir. 75
no.3sll3-116 AP 155. (HDRA 8:7)
1. TZ k%fedry khirurgii detskogo vosmata (I*o. vavwdots, AX
Shurinok) Kiyevskogo ordena Trudovogo Krasnogo Znameni meditsin.-
skogo instituta im. akado A.A.Bogomolltsa.
(SURGARY. PLASTIC.
resin sporre in apploplasty)
(IMSINS1
sponge in auoplasty)

BASS, X.M., doteent.
6o.wnital diaphragmatic hernia. Yest.khir.76
no*8:21-25 S '55,
(K6RA 8:11)
1. Is kliniki kbirargit detskogo vosrasta (l.o.sav.
kaf.dots.
A.R.Shurinok) Ityevok.ord.Trudovogo Krasnogo Znameni
medits.inst.
akad. A.A.Bogomolltva. Kiyev, Nazarlyovskaya u1. 9
kv.16.
(HERSIA, DIAPHRAGMATIC
congen.clin.aspects, compl. & -anA ement)

BASS, M.M., dotsent
Correction of extensive defects of the diaphragm In diaphra-
gmatic hernia (experimental homoplasty) Vest.khir.76 no.10;
71-78 N '55- (MIRA 9:1)
1. Is Itafedry kbirurgit detakogo vosrasta (i.o.say.--dots*
A.R.Shurlnek) 11yevskogo ordena Trudovogo Krasnogo znamen,
maditsinstogD Instituta In, A.A.Dogooolltea
(HKMA, DIAPHRAGNATIC. surg.
exper.honotransplantation)
(TROSPLANTATION
diaphragm, honografts in exper.ourg. for diaphragmatic
herniaj

USS. M.N.. doteent
M=_ ow
Scientific consulotion vork at a medical Institute.
Sov.sdrav.
15 no*4;13-18 Jl-Ag 1569 (KLRA 9;9)
It Is Xiyavskogo Orden& Trudovogo Xrasnogo Znansni
maditsinskogo
instituta imeni A.A.Dogonolitma. 2. PredsoUtell
nauchno-konstull-
tatsionnogo byuro.
(SCHOOLS, MICAL,
consultation serv. in Russia (Rum))

RUB, N.M., doteent
Surgsz7 for congenital occipital hernia. Vop.neirokhir.
20 no-3--
44-43 *-it '3 6. (XIM 9: 8)
I, Is klialki Aetskcr khtrurgit Ki4Vvskogo
useLitsinskogo Instituta
(MCBMWOMI)

BASS. M.X.. doteent
ongenital absence of the diaphragm in a newborn infants
Pedlatrila
39 no-5-.72-75 B-o 156. (NW 10a)
1. Is kliniki khirargii detskogo vosrasts, (i.o.say.
kafedroy -
doteent A.R.Shurinok) liyevskogo ordena Trudovogo
Krasnogo 2nameni
meditsinskogo instituta (dir. - prof* T99798hamrsy)
(DIAPERAGN, abnormalitleep
agenesis, case report (Mus))

USSR / General.ProOlems of Pathology. Transplantation U
of Tisgues and Tisiue.Therapy.
--.Abs',Tour-. Ref Zhur-Biolt, No 11, 1958, 51564.
Author ; Bassi.-.'Ho ~M.-
Inst : NVtV"*_
Title : ElTerimental, lAvestigation of Foiniation of Vas-.
oular i Conneotiona 1ji, In';pla,'ntation of a"Ru.bber4~1
Sponge) UeeA t
Orig Pub: Eksper " khirurgiya' 1957 No 5, 50-54.
1 ?
Abstract: Investigations were carried out on implantation
of pieoes of rubber sponge (S) of different var-
ieties in the suboutaneous tissue, skelletal
musoles and diaphragm of 80 rabbits and 9 dogs.
It was establisbed maoro- and microscopically
that within 87 days arteries developed in the
capsule surroundAng the sponge. Penetrating
Ca rd ~1-/ 2

'T-r!-w -TIT--
BASS, H.M.,-Idpts.
Diaphragmatic hernia caused
10~iatrtta 35 no.12:53-38 D
by injury in a four-year-old girl.
057. (MIJU 11:2)
1. Is k8f9dry khtrurgil detakogo vosrasta ( t.o.sev, - doteent
A.I.Shurinok) Kiyevskago orderm Trudovogo Krasnogo Zrameti
meditsin-
skogo institute iment A.A.3agomolltes, (dir. - doteent
X.P.Aleksayeako)
(DIAPHRAG*-HUNIA)

BAW M M ; DOC MAd SOi (diss) -- T~Japhragmal herniae and the
correction of
extensive defects of the diaphragm". Kiev,, 1958. A2 pp (Kiev
Order of 1,0or
Red Banner Yad Inst im Acad A. A. Bogomolets), 250 copies (KL, No
5, 1959, 151'.)

BASS, H.M., doteent
"Form and Content of Scientific Abstracts" by M.K.Dalle
-~,~giAteLEmrAL.L*NJ&ii.-.VriLehodelo'no.2:215 It, l5g.. (miRA
12:6),
1. Predwedatell nauchno-konsulitatelonnogo byuro Kiyevskogo
meditalnekogo lustitutag
(SMICAL VMTING) (DALI, M.W.)

RASS9 -H.H. JXlyev)
Repair of defects of the diaphraip with rubber spo
Zkoper.
khir. 4 no.4:47 Jl-Ag 159. Ime IOR& 12: 11)
(DIAPHRLOM surg)
(RITBM)
or/
I f~
I
v
/.t

B&SS, M.N., dotsent
Use of a rubber sponge for alloplasty. Xaz.ned.zhur. 40
no.3:48-50 Vq-J9 159. (MIRA 12:11)
1. Is kliniki khirurgii detakogo vozrasta (say. - doktor med.
nauk A.R.Shurtuok) 11yevskogo ordena Trudovogo Krasnogo Zmmenl
anditainakogo instituta.
(Smimy. PIASTIC;)

BASS# M.M.9 kand.med.mauk
Noblem *f divertionlum of the beart, Pediatriia 38
noogaglop-
87 Ag 160. (MA 13 t3.2)
1. Is Irlimiki kbirargii detakogo vozraota (save
kafedroy -
doktor moditsinskikh nauk A.R. Shurizak) Kiyovskogo
ordena
Trudarogo Kramogo Z=eni neditsinskogo ikhtituta imemi
akad. A.A. Bogamolttea (dir. - dotsomt IsPo Alokoo"nko)
(RCM-ANOMaTIES AND MWaTIES)

F
BASS, Mikhail, Mandelevich for Doe Mod Sci on the basis of
dissertation defended 8 Jart99
-- -7-
in Council of Kiev Order of labor Red Banner Mad Inst im
Aoadamieian BoSomolets,
entitled "Diaphragmatic hernias abd replacanont of extensive
defects of the
diaphragm." (BXViSSO USSR, 1-61, 20)
_70-

B-Ms M. M,,, doktor mad. nauk
Joseph Idster-, on the 50th,amlversar7 of his death. 'lest. khIr.
no,2,.127-129 (MIRA 1582)
(IMTERp TCBVH$ 1827-1922)

BASSj M-Mt.2-4&tor mad. nauk; ISAYEVA, E.G.
Lethality in acute appendicitis in children
according to
clinical materials for sixteen years (1946-1961).
Pediatriia
42 no.3:67-M Nr'63 (MM 17--2)
1. Iz kliniki khirurgii detskogo, vozrasta ( zav. -
prof.
A.R. Shurinok) Trudovogo Krasnogo,ffhameni
meditsinskogo In-
Btituta imeni akademika A.A. Bogomolftea na. baze
Bollnitsy
imeni M.I.Xalinina (glavnyy vrach V.A. Udintseva) i
Spe-
taializirovannoy detakoy klinicheakoy bollnitsy
Qlavnyy
vrach T.P. Novikova),.Kiyer.

BASSf a 0 0 tor mods nauk; GLUZW, D,F.0 student; .
Foreign bodies in the gastrointestinal tract in
children.
Naze mod, zhure 055-57 Jl-Agt63 (MIM 3.7 s2)
I* Kafedra khirurgii detakogo vosrasta ( zav. -
prof. A.Re
Shurinck) Kiyovskogo, moditainakogo.inatituta.

BASSj dol.-tor ned.naWc
~S_ -
Pupil of tho Creat I'lirogov. HaukA i rJiyttia n no.9:60 S 161.
(IJIRA 34:10)
(Karavaevp Vladimir Afanaslevichp 1811-1892)

3"S, X.T.
Diagaostia errors and surgical procedure in
Seboanlein-Renoch
yux,yam. Pedlatrila no,4:71-74 JI-M 154, (MM 7110)
1. Is khirurgichookogo otdalenlya, (sav. otdolenlyea
Ir.B.Zoakials)
Rovianskey bolinitay (glavayy vrach II.GSushkov)
(PMMI I(STHROMBOPINIC9
diag. errors & surg. in)

BAWO M.V. (Romyp &makoy oblastip ul. Karla Marksas d.28p kv-5)
Use of an acoersoory liver lobes Klim,khirs no*9971 3 $62o
(MIM 1615)
1, Mdrurgiabookoys otdeleniye (save - K.D. Ioakimis) Romenskoy
bol"nitsy., &mmkoy oblastle
(LIVER.-"OMaTIES AND DEFORMUS)

SOV/68-59-7-9/33
AUTHORS: Kanevskiy, V.Pa. Kopychev, P.A., Basp,.M&1jL..,
Golldberg,
A.So and Lokshin., . M.A.
TITLE: An Increase in the Efficiency of Operation of Pistonless
Jigging Machines
F&RIQDICAL: Koks i khimiya, 1959, Nr 71 pp 21 - 2? (USSR)
ABSTRACT; The re-design of the pistonless jigging machine
operating
at the Makeyevkp- '.7orks is described. Main points are:
1) dif,-erential ucriving gear which permitted regulating
the velocity of the medium within wide limits; 2) the
automatic regulator of the removal of rocks and of the
intermediate product was replaced by a pneumohydraulic
one which secured the constancy of a high quality of the
products; 3) the discharoa of heavy fractions is done
with the aid of a pocket in front of the outlet which
decreased the contamination of heavy products with lighter
Card 1/2 fractions; 4) the number of pulsations was decreased
from

SOV/68-59-7-9/33
An Increase in the Efficiency of Operation of Pistonless
Jigging
Machines
96 to 32 per minute; 5) a scheme for automating the
control of the discharge of air in relation to the load
was developed. The above modification decreased-coal
losses with rock by a factor of 5 - 7 which varies at
present between 0.2 - 0.5co. The yield of the fraction
of specifie,gravity 1.5 - 1.8 in rocks decreased and
varies within 0-5 - 3-0513'. Coal . loss in the inter-
mediate product decreased by a factor of 3 and varies
within 3. 7%.
There are 5 figares and 4 tables.
AS,~OGIATIONS: Dnepropetrovskiy gornyy :Lnstitut
(Dnepropetrovsk
1-a-ning Institute), Make evskiy koksokhimicheskiy zavod
(Makeyevka Coking Works~
Card 2/2

BASS, M.Ya.: BINKMCH, V.A.
Using pistonless Jigs for ore dressing. Gar. zhur.
no.5:62-65 Wy
,63. (MIRA 16:5)
1. Mokhanobraherset (for Bass). 2. Pridneprovskiy sovet
narodnogo
kbozyayatva (for Binkevich). (Jigs and fixturts)

BASSp M.Ya,,, inzh.; BINKEVICH, V.A., inzh.
f
Using plungerleas jikwin ore dressing. Sbor. nauch. trad.
KGRI no.17:195-201 163. (MIRA 17:1)

BASS, N.A., inzh.; ZABEZTIANSKIY, I.I., inzh.;
KARARZINA, N.A., inth.;
---MDMI-iWKO, A.P., inzh.
Automatic voltage regulation in the substations of an
electric
power syst6m. Elek. sta. 32 no.12:18-25 D 161. (MIRA
15:1)
(Electric power distribution)

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it u to it ?A bvian& silo
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decanted lkuW to drr
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pun lack "m obtained. It contained
l
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him &W cholesterol vo
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All
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itted)ormleckbin deM%
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sor
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4-tLA &tlAiAW.K&L LORSOURt C &UWOCATOR
too
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1")~4~T , ~- /"-I
DIMIDOTA, T,Mo: BASS,-R.Ho
Tk-4-68-1 device to do oratimo the foreign wtter content In
cotton. Telmt. prom. 17 no.7o.63-64 il 157. (KLIA 100)
(Gottom-Grading)

BANg go, slasarl
00' Devices used in transporting damaged automobiles into
garages. Art.
tranep, 36 no,2-30 7 158,
0(Automobiles-Mintewmee and repair) .(MIU 1332)

KUZINI.NSKIYP A., doktor khimicheakikh nauk., prof - BASS Sinsh.
hhAmj- 00 jus of polymrs. Tekh.mol. 29 qo.6:15 161.
(mm 1437)
(plutics)

BASS, :1.
About brake fluids. Ivt, transp. 43 no.M24 0 165.
(MIRA 18tIO)
1. Br1gadir slesarey avtokolonny No.2239 g. Klyeva.

1;19-sal SX-

Combined at4a'ef froo aiml, hottod sultur and'N-phenyl-
!-uqV law - an the oxf6dom of vulcanW119
LAftdjLLg2jML
Eq- 1Y 9411 191MAR z1ar. Fralad
V . tive processes In -
ra" .1ca.1tatess In t Interval 8D-1 ' wat followed Id
connection with'the eff*et of It" and bound S. Free S is'
oal a weak *but actually a hamdal Inhibitor, since,
&Wg 3b 6 very immil lengthening of the Induction period,
It lesdf~t*Tlotenxe addni. stmiuril lomation of the val.
canW1 Bond (Pol l4de) 8 In On absence of 2-CtoHy-
ta a =Ite inhibiting effort on oxidation.
NHPh M4!tls
Free 3 "ecdvt action of I and Is. therefore, -
hanatul at high-temp, oxidation conditions; in addn; it cm11A
for unnecessary &W undesirable consumption of the smine
and ves, too short an Induction period. In the presence of
free 9 autocatslytic oxidation of the vulantute develop&,
even with an amMe comn. up to 40% of Its original value;
the ambe whkb rentaing at the Initiation of dete"Ale 0
absorpkiorkbas Ioms than 0,5 the Inhibiting powex In em. parl-'
son 1WRA t" Pam imloo. Bound 8 parmpates In the oil.
44tive Protest alml witis the 4ydrocarbon part of the vul-
ca"Isate", 0
~N,
. . .........

XMIKINSKIY, A.$.; BUS. Sol.
Ninth conferende on general problems relative to the
chemical
and physical properties of high noleemlar weigbt
compounds.
rauchA res. 16 no.40,744 Ap 157. (KUU 10: 7)
(Naakftoleeila'r compounds)

AUTHORS: Igonin, L. A.,,Bass, S. 1. SOV /2o-121-4-22/q,4
TITLE: Infrared Absorption Spectra of Oxybenzyl Amines (Infra-
krasnyye spektry pogloshcheniya oksibenzilaminov)
PERIODICAL! Doklady Akademii nauk SSSR, 1958, Vol- 121, Nr 4,
pp. 652 - 655 (USSR)
ABSTRACT: In the process of solidification of phenol
formaldehyde
resins by hexamethylene tetramine oxybenzyl amines are
formed as intermediate products (Ref 1). They are multi-
nuclear compounds the phenol nuclei of which are connected
by dimethylamine nuclei and(- OR 2---NH - CH27)and tri-
methylamine bridges ((N(CH 2 - Y' It isWieved that in
the course of solidification these bridges under the
thermal influence become methylene and azomethine bridges.
It was interesting to prove these assumptions by means
of infrared spectroscopy. There are no papers dealing with
the same subject. Results of the spectra mentioned in the
title of some oxybenzyl amines are mentioned which were
Card 1/4 obtained by interaction of phenol and its mononuclear

Infrared Absorption Spectra of Oxybenzyl Amines
SOil2o-121-4-22154
derivatives with hexamethylene tetramine (Fig 1). Based
upon data in publications some intensive bands could be
identified in the spectra of the following model substances:
2,21-dioxy-3,5,31,51-tetramethyl dibenzyl amine (I) and of
trioxybenzyl amine which corresponds to it (II). Figure 2
shows spectra of absorption of multinuclear benzyl amines
which
are relatively low-molecular (Ref 4)- Apart from the above
mentioned absorption bands (Fig 1) intensive bands exist
within the range of 12,2V which corresponded to the three
times substituted berz.-ne ring, e.g. to the terminal groups
of these compounds. further bands prove that the p-sub-
atitutes of phenol react with hexamethylene tetramine
accompanied by the formation of mainly dibenzyl amines. The
o-substitutes form, however, mainly tribenzyl amines (in
accordance with Ref 1). Figure 3 shows absorption spectra
of oxybenzyl amines with a high molecular weight which
are formed by interaction of phenol with hexamethylene
tetramine in a diphenyl solution. On thewhole they are
nothing else but the spectra of figure 2 and are, however,
considerably ramified. Owing to the above mentioned results
Card 2/4 the possibility arises to use the characteristic
bands in

Infrared Absorption Spectra of Oxybenzyl Amines
SOV/2o-121-4-22/54
the range of 11,84R and 11,92V for the structural investigation
of the solidification processes of the phenol formaldehyde
resins in all cases where solidification undergoes the
stage of formation of oxybenzyl amines. There are 3 figures
and 4 references, 4 of which are Soviet.
ASSOCIATION: Nauchno-iseledovatellskiy institut plastmass
(Scientific
Research Institute of Pl"tics)
PRESENTED: April, 3, 1958, by V.A.Kargin, Member, Academy of
Sciences,
'USSR
SUBMITTED: February 11, 1958
Card 3/4

SOV/138-59-4-14/Zof-
AUTHORS:- Kuzlminskiy, A.Se and Bass
4 & - .2 - ,-
TITLE: The VIIIth Mendeleyev Congress (VIII Mendeloyevskiy
Anyoud)
PERIODICAL: 'Kauchuk i Razina, 1959, Nr 41 pp 47-48 (USSR)
ABSTRACT: This Congress on Pare and Applied Chemistry was hold
from 16th to 23rd Marcht 1959 in Moscow, and was attended
by 1 500 representatives of Soviet Research Institutes#
chemical factories and many foreiga associationse
Academician A.H. Nesmayanov opened the meeting and
enphasised the importance of the Mendeleyev Congresses*
V.S. Fedorov,, representative of the Gosudarstvannyy
Komitet Soveta Ministrov SSSR _po khimii (State Committee
of the,CWnall of Ministers of the UbibR for Chemistry) drew
attention to Soviet aehieNeiwaun~% in chemistry. The
following papers were reaa during the Congress: V,Ao
Kargin, on the "Basic Problems in the Chemistry of
Polymers"; A.N. Nesmeyanov on "The Periodic I"--
Card 1/2 of D.I* Mandeleyev and Organic Chemistry"; NoNe
6emenov

SOV/138-5-4-14/26
The VIIIth Mendeleyev Congress
on "Basic Problems of Chemical Kinetics"-, A.P. Aleks-
androv on "Chemical Aspects of Utilizing Atomic Energy";
Ya. K. Syrldn, Corresponding Member of the Academy of
Sciences of *he USSR9 on "The Basic Problems*of the
TheorY-of Chemical Bonds" etc. Special attention was
drawn to the chemistry of high-molecular compounds and
to methods for preparing starting materials-for the
synthesis of polymers based on petroleum crudes, further
modification of the properties of polymers (block- and
graft polymers, radiation vulcanisation etc.), V.As,
Kargin discussed,thres rain aspects of polymer chemistry:
prepaxation of polymers which can be used within wide
temperatwi ranges-, preparation of now and easily
accessible polymer materials and processing of polymers.
Further details of the lectures are to be published at
a later date*
Card 2/2

IMIMMSKIT, A.S;;(-BASS, 3.1.
Summing up the results of the Intermational Symposium on Macro-
molecular Chemistry In 1960. lauch.1 rez. 19 no.10:1-6 0 160.
(HM 13:10)
(Racr4uolecalar compounds-Gongresses)

S~ 3 j> J%Z
68847
AUTHORS%
Igonin. L. A.y Gintsborg, E. GeV
3/076/60/034/02/006/044

Krasulins, N. ., Bass, S. I., BO10/BO15

Kargin, V, Ao

TITLEs
Investigation Of 0!;Lbonsylazines Obtained Prom
Phenol and Its

Mononuclear Derivatives
PERIODICAL:
Zhurnal fisiohookoy
khimiij 19609 Vol 34* Nr 2t pp 287-294 (USSR)
ABSTRACTs
On the basis
of publication data it may be &soused that o:Mbensyl-

amines form &a
Intermediates in the hardening of LovolaoWphenol

formaldehyde resins
with boxamethylonststramins. In ozybousyl-

amines, the phenol nuclei
are connected by disethylamins- or tri-

mothylamine bridges* At high
temperatures, these bridges are trans-

formed into mothylons- or
asomethine bridges. In the present case,

a series of
oxybonsylamineaq obtained from phenol and its mono-

nuclear
derivatives, were investigated thermomeabanioally as well

&i by
spectral analyois. The absorption spectra were taken
by the

.
IKS-ii spootrograph, and are given for 2,21-dioxy-3p5#30,51-tetra-

motbyldibousylamine and the corresponding tribenzylemin* (rig 1).

The absoTption bands observed ct ii-84
A in dibensylsaine and at

,
il.92/t in tribenzy1smine are traced back to the disethylenamins-
Card I
/3
szd trimethylandaine bridges between the phenol nuclei. This

68847
Investigation of Oxybonsylamines Obtained From
S/076/60/034/02/006/044
Phenol and Its Mononuclear Derivatives B01O/BO15
assumption is confirmed by the absorption spectra (Pig 2) of the
multinuclear oxybonsylanines. The latter wore prepared by a
method
described earlier (Table 1p preparation conditions). All spectra
of
the oxybonsylamines obtained from phenol and its para-substituted
derivatives show the 11-84/4, band whereas with oxybonsylamine
ob-
twined from o-ohlorophonol this band lies at il.92,jl,. Thus, it
can
be soon that it is the reaction between hexamethylenetetramine
and
0 the sononualear phenols in a diphenyl solution that leads to
the
formation of the polymeric oxybonsylamines (Table 2. suggested
structural formulas of polymers). The polyoxybonzylamines
obtained
from phenol and its par&-substituted derivatives are amorphous
linear polymers reticulated by individual cross bindings. The
poly-
mers have very strong chains whose T, value lies above their
thermal
stability. The o-substituted derivatIves form strongly ramified
and
reticulated polymers. The polyoxybonsylamines obtained from
phenol
reticulate under the effect of beat, and pass over into a non-
meltable and insoluble state whereas polybonsylamines obtained
from
o- and p-substituted derivatives of phenol are thermally
instable,
and decompose at a temperature above 16000 forming low-molecular
Card 2/3 products. There are 6 figures, 2 tables, and 6
references, 1 of

68847
Investigation of Oxybentylamines, Obtained From
3/076/60/034/02/006/044
Pbsnol'and Its Mononuolear Derivatives B010/D015
which is Soviet.
ASSOOIATIONt lauchno-inaledovateltakiy institut plastichookikh
ease
(Scientific Research Institute of Plastics)
SUBMITTED: April 3, 1958
Card 3/3

IOCNIN, L.A.; GINTSBERG, B.G.; KRAWLINA, N.A.; !!~Ssj S-,~;
KARGIN, V.A.
(Moskva)
Hydroxybenzylamines obtained from )ben,,>l and its
mononuclear
derivatives. Zhur. fiz. khim. 34 no.2:287-294 F 160. (MIRA
14:7)
1. Nauchno-issledovatel'skiy institut plasticheskikh mass.
(Benzylaxine)

34136
S/138/62/000/002/009/009
0 A051/A126
AUTHORS: Kuz'minskly, A.S., Bass, S.I.
TIM: Conference on aging and stabilization of polymers
PERIODICALt Kauchuk I rezina, no. 2, 1962, 50 - 52
TEXTt The conference, convened by the AS USSR, the USSR Council
of Minis-
ters, State Committee on Chemistry and the Ministry of Higher
and Intermediate
Special Education of the RSFSR, took place at the Institute of
Chemical Physics
of the AS USSR, from November 14 - 17, 1961. Over 200 delegates
participated
and 62 papers were presented. Academician V.A. Kargin spoke on
the subject of
aging and stabilization of rubber, various plastics, fibers, dye
and lacquer
coatings, and he stressed the use of fillers and polymer
substances as stabilizem
V.B. Miller, Yu.A. Shlyapnikova (BbF AS USSR) discussed certain
law sequences of
oxidation destruction of polypropylene in the presence of
antioxidant-aromailc
amines and phenols. The conclusion that inhibitors initiate tJv
oxidizing pro-
cess of the polymer is confirmed. M.V. Neyman and A.L.
Buchachenko (MF) spoke
on the results of an investigation of stable radical products,
formed in thermal
and catalytic decomposition of hydroperoxides In the presence of
various anti-
Card 0

34136
S11381621000100210091009
Conference on aging ...... A051/A126
oxidants. 0.1. Likhtensbteyn (IKhP) presented the results cf a
theoretical in-
vestigaticn of the effects of inhibitors on the oxidation of
hydrocartcns.
Several papers dealt with the study of 'the synergezic effect
of inhibitor mixtures.
A.F. Lukovnikov, F.I. Levin and M.S. Khloplyankina ( D-W)
investigated -rhe syn-
ergism of mixtures of certain secondary amines with various
sulfur-containing
compounds in the process of oxidation of isotactic
polypropylene at 2000C. An
Investigation of tina behaviour of stable radicals of
diphenylamine, pheny'L-f- nqh-
thylamine, etc., In the presence of a number of
sulfur-con'taining compounds, with
the decomposition of the hvdroperoxides using the EPR spectra
was conducted by
M.S. Xhloplyankina, A.L. Buchachanko, (IXhP). A.B. Gagarina,
Z.K. Mayzus and
N.M. Emanueliy, confirwed experinentally the existance of
critical concentra-.ions
of inhibitors In l1quid-phabe oxidation of hydrocartons,
predicted by N.N. Seme.-
nov for slow chain reactions with degenerated branches. A,S.
Kuz~minskly &rd
Yu.A. Goldovskiy (NIIRP) reported-on certain laws of oxidation
of polydimethylsfL-
oxane rubber at 250 - 3000C. A discussion was given on the
Investigation of
aging of wthylvinylpyridine rubber and raw rubber, based on
the latter, by L.G.
Angert, A.I, Zenchenko and A.S. Kuz'minskly, (NIIRF). The
report, of Z.A. Tara-so-
va, I.I. Eytingon, L.G. Senatorskiy, T.V. Fedorova, 0.1.
Andrcnova and B.A. Ds-
g4dkin (NIIShP), dealt with the results of an investigation on
th6 action of
Card 2/5

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Conference on aging .....
S/138/62/000/002/009/009
A051/A126
certain thloamines, thiophenols and synergetic mixtures,
based on the latter,
during the process of vulcanization and in fatigue of NR,
isoprene and butadie-
nestyrene rubber vulcanizates. 7he paper'of O.L. Slominskly,
V.A. Kargin and
Ye.V. Reztsova (INEOS AS USSR, NIIShP) concermed the problems
connected with the
transformation of macroradicals formed in high-elastic
polymers under the action
of mchanical tensions during processing service of these
polymers. T.O. Deg-
tyeva, I.K. Sedova and A.S. Kuz'minskiy,(NIIRP) presented the
msults of an in-
vestigation of thermal decay (250 - 3800C) of the copolymer
of trifluorochloro-
ethylene with vinyl4dine fluoride. Yu.S..Zuyev and A.Z.
Borshchevskaya (NIIRP)
reported on the results of an Investigation of corrosive
crackin 'of deformed
rubbers, based on carboxyl-containing butadiene-styrene
rubber, NKC-30-1
(SKS-30-1)], in solutions of HC1, CH.3COOH and ozone, and
also of rubbers based
on NR and natrite in ozone.- A conclusion was drawn that
thedestruction mechanism
of rubbers in aggressive medil, in the deformed and
non-deformed state, is not
the same'. The use of the condensation of aniline chloride
with acetaldehyde as
stabilizers of'raw and synthetic rubber products was
discussed by L.P. Zalukayev,
T.I. Zheltukhina,*L.Ya. Sinitsyna (VNIISK). Certain papers
dealt with the re-
sults'of a study on destruction and stabilization of
polyolefines. Ye.N.- Met-'
veyev, et al. (NIIPP) investigated the oxidation of
polypropylene at 120 - Itooc
Card-3/5

6
S/&/'6 2/000/00 2/009/009
Conference on aging....- A051/A12G
and showed The connection between the rate-of oxygen
absorption and property
changes cf polymers, both in the presence and absence of
--various stabilizers. 711e
paperof V-.D.'Molseyev and V.I. Buskin (IKhF) dealt with the
theory on computing
the rate of depolymerization, isomerization and transfer of
the chain in thermal
destruction of vinyl polymers using experimental data. V.S.
Pudov and B.A. Gro-
mov (IKhJ?) showed-that the primary process in
thermo-oxidation destruction of
polypropylene is the for?= on'of peroxides, the decomposition
of which causes
the formation of a complex mixture of the products of
oxidation. N.V. Mikhaylov,
et al., (VNIIV) made a study of certain stabilization features
of polypropylene
and fiber based on the latter, and analyzed the reasons for
discrepancy in the
induction periods of oxidation for the polymer and Its fiber.
P.1. Levin, P,A.
)(Irpichnikov, (IKhF) presented the results of their
investigation of polypropy2ere
stabilization with mixtures of phosrUtes and sulfur-containing
compounds, not
causing the appearance of a coloured polymer during the entire
induction period.
Certain possibilities of using the spectral methods for
studying the aging pro-
cesses of-polymers were stressed by V.M. Chulanovskiy,
(NIIShP). N.S. Yenikolo-
pova, L.A. Dudina and L.V. Karmilova presented the results of
an investigation
on the thermal and thermo-oxidation destruction of
polyformaldehyde. A.A. Ber-
lin, et al., repated on the effect on the stability of
polyvinyl chloride polymers,
Card 4/5

Conference on aging .....
34136
3/138/62/000/002/009/009
A051/A126
with a system of conjugated links, produced in the
polymerization of acetylene
hydrocarbons, or in the splitting off of atoms or groups from
the macro-molecules,
S.R. Rafikov (INEOS, AS USSR), N.V. Mikhaylov (VNIIV) spoke on
the thermal and
thermo-oxidation destruction of polyamides. Several papers dealt
with destruction
and stabilization of condensed resins, photochemical destruction
of intracellulose
coatings, property changes of lacquer-dye coatings in aging,
destruction and sta-
bilization of cellulose ethers, radio-chemical transformation of
pc7gethers, thermal
destruction and stabilization of polydimethylsiloxane. A special
meting of the
conference was devoted to the synthesis of new stabilizers~
amines, screened
phenols, phosphoro-organic compounds, light-stabilizers of the
benzo-phenone row,
derivatives of n-phenyleneamine, quinoline and phenol, as
Inhibitors of ozone
aging of rubbers, etc. The importance of an all-sided study of
the behaviour of
real polymer materials under various conditions of storage,
processing and service
was emphasized. Resolutions were adopted to intensify the
theoretical work on
aging of real polymer systems, for unification of various
methods for evaluating
the. aging process, and to increase publications on the problems
of aging and
stabilization of polymers.
Card 5/5

BERL No A.A.; ~fs - I.
Influence of *local aotivatloO affect on the Inhibiting
activity of aromatic bydrgoarbono. Xxv.A.N
SSSR.Otd.khim.naulc
no.8:1494 Ag 162. (MMA 15:8)
I. Inatitut tonkoy Irblynicheakoy takhnologii im.
M.Lomonosova i
Inotitut lebimichasko7 fisiki AN SSSR.
(Hydrocarbons) (Lihibition (Chemistry))

BASS, S.I.; Prinimala uchastiye: TIMOFL?YEVA# G.V.
------
Use of tert-butyl hydroperoxide for the quantitative
determination
of tri-n-butyl- and triphenyl phosphites.
Zhur.anal.khim. 17
no.1:113-116 Ja-F '62. (MIRA 15-2)
1. M.V.Lomonosov Moscow Inetitute of Fine Chemical
Technology.
(Phosphorus organic compounds)

KUZIMINSKIYO A.S.; BASS, S.I.
ft,
Conference on agUg and stabilization of polymers.
Yauch.i rez.
21 no.2:50-52 F 162, (KMA 15:2)
(Pol7mers.-Congresses)

lp 423.86
S/07 6762103 6101110161021
3101/BISO
AUTHORS: Bass, S. I., and Medvedev, 8, 3,
-----------------------------
TITLE: The mechanism of the inhibiting action of phosphites in
the
oxidation of paraffinous hydrocarbons
PERIODICAL: Zhurnal fizicheskoy-khimii, v. 36,- no. 11,
1962,.2537-2539
TEXT: Triphenyl phosphIte (I) and tri-n-b*uiyl phosphite (II)
were studied,
with the oxidation of hexadecane at 140-1600C and atmospheric
pressure.
The peroxides content of the reaction mixture was determined
iodometrically,
and the consumption of I via-the quantitative reaction of I
with tert-
butyl hydroperoxide. A linear increase in the induction period
and a
decrease in the peroxide content were found with increasing
concentration
of I, as well as direct proportionality between the amount of
oxygeli
absorbed and the initial concentration of I. When 4% 1 was
added, no
further 7peroxides were formed. The rate constants of the 0
consumption of
I (k-10 moles/liter-sec) were 66 5 at 1600C, 39.2 at 150 C, and
23-3 at
1400C,-the activation energy was il kcal/mole. II proved much
less
active than I. Addition of 1.2A phenol had no effect on the
induction
Card 1/3

S/07 62/036/011/016/021
The mechanism of the inhibiting... B101YBISO
period, but lowered the oxidation rate and oxygen consumption.
From the
k k1 - k 2
reactions RH + 0 + HO - R + 0 ---* RO I R RH ROOH +
2 2.1 2 2 02 +
k k I k
Fi62 + P :13--p R6 + P-0; R6 + P"::44 k + PwO; ROOH '+ P:4 ROH
+ P-0, where
P is the phosphite, P-0 the corresponding phosphate, and
assuming that
k24 k 39 the induction period was found to be -r - P 0/2w.,
where P 0 is the
initial phosphite concentration, and w 0 is the initiation
rate. Hence,
this assumption leads to a linear function correspondine to
the function
T - f(P0 ) which had been found experimentally. The more
intensive action
of 1, as compared with II, is attributed to the effect of the
electron
acceptor phenyl groups. The inhibiting effect observed after
the induction
period is 'based or. a competing reaction of the phenol formed
by hydrolysis
of 1, and explains the result of the direct addition of
phenol.- Thereiare
3 fi.-ures.
ASSOCIATION: Moskovskiy institut tonkoy khimioheskoy
tekhnologii im.
14. V. Lomonosova (Moscow Institute of Fine Chemical
Technology imeni U. V. Lco-onosov)
Card 2/3

S107616210361011,10161021
The mechaniam of the Inhibiting... B101/blao
SUBMITTED: April 4, 1962
Card 3/3

INRLIN, A.A.; BASS, S.I.
"Matrix effects" during the activation of compounds
having a
conjugation system'in the reaction inhibiting the
oxidation
processes. Izv. AN SSSR. Ser.khim. no.9sl652-1654 S
163.
(MIRA 160)
1. Institut kbimicheskoy fisiki AN SSSR i Institut
tonkoy
khimichaskoy takhnologii im. M.V.Lomononova.
(Pollmers) (Oddation) (Inhibition (Chemistry))

T
5
6/63/037/00
/07 3[016/0210
B101/B215
AUTH01"IS: ~Bassj S. I,, Ziliberbrandt, A. M., Berlin, A. A.
TITLE: Study of the mechanism for the inhibiting action of compounds'
containing a system of conjugate bonds on thermal oxidation of
low-moleoular and.pollmer hydrocarbons. 1. Inhibiting
acenes:on the.oxidation of paraffin hydrocarbons
PERIODICAL:: Zhurnal fiiiah6skoy khimiip v. 37, no.. 1963i 682-685
n i
TEXT. This a. a.report on 4A h biti g itation of anthracenso
napfithacen,
and pe ntacene on the oxidation.".6f -cetane.and ceresin at 160 and
200 0a'.
The following data are given for tbe.adoorption rate of oxygen in thi'
presence of. 8--mmoles/kg of:,acene- in.% of*the adsorption rate
without.
0
90 at--160 09:55, at 2600' a PCI
inhibitorr naph pentacene 65 t' 160
at 2000 0. 'At 16o0 0 the~length of. the induction :period in
affe'eted-in.the
sequence anthracene