SCIENTIFIC ABSTRACT BATUYEV, M. I. - BATUYEV, M. I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000203930011-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 6, 2000
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

10 of dw &mark am"dation of (any saids Is,
41 ROMO "Alltrift- Xf. I. 11-tuev (A4,47.
U.S.S.R.). Invil. Mail, VitO N.Y. M-7-ves, rv
f 1 16( C.A. 42, 3*11c. WAk-Whru
". 61 191)
f.,, acid I. - in CCL, the karnifin fivunww,
2042, and ZW coo. - I coo lot almerved. I first 'd
r
ukh liviomp to the C-11 cmp. the two others to the
-G-Hirrompolaills I fins.
wW to If#O them lines are diffused to a land because of
the bremikup, of the diumn, which 6 however wit complete
siam C-11 Imp lion IN) and 1710 rin. - I still persim
In MOW Vapor at M* there next to the dinivic
9 fmqueseT The 0-1f frTew
A , w 0!1 risoomseric IICOOII s.1
the ring
Im Cos. At 14, fr:q
aun
disiapp"r; I he 2w $rise d,( C -I AIM line 0-(
nwwbm"erk- 0- -11 are the vinly itne. present. Its I not
IIOAc i he intensely piUdart! 2044 em. *I line belmi; f'.
lbs, symovetsk, the line M111 cm. I to the istitisymnsteirk
wril,tatim of she C-11 grosip. The lissri, ~VW nd .11VX
cin.-I art attributed Inths:0-11 gtimpof theditsmieving
I*ftuw they are not P t
dimen aft lirsilten upl =ad utheiyn altid'10exIA&T in( %hihveveV1*hc#
cochm. in Mi. the dinters being priment in such xuliss.
Tbm results cunfinn pmvkpuQy futind differences; in Poly.
oterintium between IIOAc and IICOOIIis one group and i
the other fatty !&c~ as another group. S. IAltswer

in, at= I. "wins 0(
p4jayAW. S-Jak S.S.S.R. ".
fe". (Ruv%iAn J*ovw PA. 1 1"S. 11,
Mio: cf. C.A. 38, 01911, 41, IRMA; 42. 32111C In a he
%lw"ra got blithly nmmt. oq. "n.. ot ktill Aml NA(lif
(#0 wl,-%) MAW ""s, a AM The JRwj-w.1%f (Ifire --( th,,
wille 11,0 hand a :1 ly Swinnilwit, 41111-aigh Mmurwit'.1
pwo~Ae*W line j&I micill. -1 This h1w gracluAly lach,
will% offt-rAomming v~n. (&mu toll.5 ofi~pprmr*-
In its plav a kini hand minwArvat A rh,-
findinp bw"te that the qualiffySt. sinleplic i.1 Ivrrwnt its
Irv". a400. and Is 41corayrd Wit h lncrr "Its dohl. and fit*.
wti. Tbv0lliAm(omAi11IwNKI%r
vv" In cov-1. out 4111Ai.
cryst. lattic"; lbrMtwe, 11 in vq1 a in-c ilwo. The high-
frequemy OW
water krpl In trwis vr*wls. The Jifftfrnt cheow nalurr
of the Olt amps of wicts arA 0( lux$ is apluttllt frol" the
fart that the Mifical rvitl"u-t Ail the 11 lkwul allwan at a
higber frequvwy in how* (4IMI-1191(lmit, 11 IhAll jil At-jils

BATUYEVs M. D
noevelopment of Aranilar Dimeric Association of Fatty Acids
in Spectra of Combination
Dispersion of Light by the Wdroxyl Group," Dokq, AN, 59, No.
6., 1948. (Inst. of
Org. Chem., Hbr. Acad. Sci. ) c1948

BATMV, M6 1.
USSR/Chemistry - Aromatization 1 Mar 1948
Chemistry - Catalystsp Chromium
"Aromatization of Diallyl on Chromium Catalysts." A. F. Plate,
M. I. Batuyev, Inat.
Org. Chem, Aced Sci USSR, 4 PP
nDok Akad Nauk RSSR, Nova Ser" Vol LIX, No 7
Experiments made on the isomerization of diallyl. into
dipropenyl. over catalyzer of
Cr203/AI203 at 300 and 4000.* Show that in these conditions
benzene is formed,
the content of which is 6% in catalyzate obtained at 3000 and
11% at 4000. show
that application of refractometric methods of analysis to
determine the dipro-
penyl. in catalyzates obtained in isomerization of diallyl on
oxide catalyzers
that can cause aromatization may lead to errors as result of
benzene content
in the catalyzers. Submitted by Academician B. A. Kazanskiy, 6
Dee 1947.
PA47TIl

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it .
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.
1
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Off
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app
Milli. lot the C --It rvg"&. agAill-I a Wckarvulftl
the rc&a where. in clicitatim by the I ~ triple' r~3W' 0-11
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the duublorl ZMand XCIM is
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frequency ul fill
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1
h
,
moomoortic 0 - It frequency 3578 cm. -1. Further proof

o

00
a faint" 3rd
folnerm the sharp doublel 21#42
, 2W, wit
"
The lamor litors ore found In HCO
H
I
im 2M cm
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M8 11cluble, I%,

00-3
.
.
s
vapow at about go', whereas at 140'. when decompe.
in 41i). (5%)
6Wns.ol AcOll in CCJ, slad in liquill )11

2*0

0-

into momomen in complaW, the 4a"t dhapptars and
healed to JAW.
while the Off lusid W the polymer I& ab-

ovist
On woln
In dimune &old in li
0
the rin
ditum are

roe

a
owly The C -.1f line 2W4 Socraists; at the sum thnev the
;i
lww 0-It frequency a" of the welootlow a
.
.
#
.
g
IMPIEVII Up And new loydrultru-banded cb&ht compiroors

71w
dbapprarstam 4A th,- 2D42. 2M doublet =*
i
arv formni lorlwmn AcOll Awl ditoxanr tuals * The Off
t
; b
d
w
Ih i
di
i
b
d
d

1~- twooves that it belongoo to The 0-11 ul the cloctic diraw.
t,,
mr
..
.
vx
c
oocrd
an
s rvp
y . di
I 'A .1
The 04 bM the moomou"
the ring dism
and

if
i
,
and that, in the liqukl pltaw. C-11 Wiles no part in hydru-
madins. On ooln. in JIM. in ciontrast too CC14. door
imn

.
,
F the Polymer UPP04n. re the form of a sharp line. a
-in
t

00

1
law is W rclwvw into lines, only becomrs tuol,t difluor
i
diffuso, Awtolct. ad .
r.
d tww. the car
ton"oundins
wave noc
In IIC(hII
AcOll
and %Ic
CIICIIICOJI
aft

'
a
aml I* *Wlcvl to kalgro, wall". Likewise. In v4n J
.
.
.
.
.
.
"Wonamer, 3563. 315jlf~ awl aV.2; dinwr 2042,

00

21M, 30A
and:1131, 31Kb; pulymer

00

U111. And wow. V Thm

AS

too*

So-ILA MULLURGICAL 1.1111101011
CLASWK&TIN
a-1-

.34.1 OL..,!

s
fee

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1W D U, 0 M1 K
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BATUEV. M 1.
_3
on a
late and X A7
at,
Dokkdy au S.
HI:CHCH3-,
0 X9 over ft,
Crw%-AhOacAtaI't 16*: mol.." I -in a 9-5-mm. tube
73
catal
with- 20 mi. yst ,At,a and 10.6 M1.1wr
5
'dowmte,gave7. 9~catsf te1jr 9.2 g. rbon)
n'D' 1.4285; at 0
400 Ar ow
an '17113. te 13.0 g.
9" 10-2 9- Product. NV 1.4278;. t Is tch , ta
he t ba
fl"; brnwm,'the 2nd 11% (by opt 1 1 6). Ined
ka ana y%
of bialtyl 0,.Crcoin. Ah(h at mo-s* it vel It
w 1 10
bm 813-
2 d
4534. .1m, ff

- - -VMW~--D
BATUYEV, F. 1.
UZAINSHY, B. A., LIBMAN, A. L. and BATUYEV, 1-1, 1. CA;
42-6448/h
(Academy of Sciences) e4svol
Doklady Akad. nauY SSSR 6IJ67-70 (194.8)
Cyclization of paraffin i5;jrocarbons with a quaternary carbon
ator., and
rechanism of the arovetization of paraffins on platinized
carbon.
-- D

BkTUYF.V, -M. 1.
USM/Chemistry - Qyclopentans~ Derivatives Sep 48
Chemistry - Biqy4o-(l,,2,.t28)-H9pt4m9
wStructure of BIqyol*-(l,2,,2)-H*ptarA,,II Aced B. A.
Kazenaldy, A. V. Koperina" 14. 1.
Batumv 4 PP
*Dok Ak Nauk SSW* Vol LnI. No 3
Discussion of experimental data on cooversion of
bicyclo-(1,2.2)-beptans, largely,
obtained in authors' laborstoryg points out that it should be
considered a cyclopentans,
derivative-and not a cyclobexane vith a metbylene bridge
connecting carbons I and 4o
Submitted 6 Aug 48.
PA 36/49T23

Patu-vev. H. 1.
(Last-.0ra. Chem. USSR,
Compt. rend. acad. sol.
Vibration frequency of
Raman spectra.
!Lcademy of Sciences)
TMSS M, 913-6 (1948)
the hydro3yl group of fatty
acids in the gas phase in

BATUYEVI M. L
11 Calpliri'Method of Detailed Inesti tion of the Irdividual
Compsition of Gasollnesw-~~
W
(Implakenyy VAtod DetaUsirovomago Iseledovanip Individuallao'go
Sostava Benzinov),,
0. S. Landsbergp B. A. lazansklyj, P. A. Ba0g,14n, M. I. Batxwev, A.
L. Liberman,,
A. S. Platej, and Go. A. Tarasoval edited by V. S.
Fedorovv-Zds-Vo-ptekhizdqt,
Moscow/Leningrad, 1949, 68 Most 3 rubles.
Subject method is based an apectral analysis.
SOz UspoW Wall Vol 18v #6v 1949; Vol 19p #Ip, 1950 (W-20083)

I-.; p-.11 - ~ ,,- " i' "'i",-
, , II, "
I
38W. BATUYEV, M. I., BORISOV, A. YE., AND IESMEYANOV, AN.
SEYEEKTRY KOMBINATSIONNOGO RASSYEY1.14IYA SVYATA
)MLORVINIL'INTMI PRO12VOMMIRTUTI
I SURIXY. IZVYESTIYA AKO NAUK SSSR, OTD-N.IrE. MIK. NAUK, 1949,
No. 6, S. 567-69. - BIBLIOGR: S. 569

Z77-*-
1-1371t~ mt .6 'r. Fit.
(11MV); d. C.A. 42. W44.-Thr
mWalmian thcary at lrkcauuauaimt~w 64
1=1- the It boW. latermal. vibrstbm Wter the
lfcquency P of S-atramol. Vibratkm$. The v of
the foriner
arO.01 at thatal O-li vilicatiams. Tbelattef
May awified to a verks of dismce frequeacks or
to
1bgraigs bwWs wW The munlifird P can tw Uwascr
1114"
ti,arigiW. FrQ is abomrved in time Oil opmm of
j#vo%&FY
&ad kw&ry aVpiwtk mkm eft ' The akkr lbftffir*
of I'
11 tmd CC~uM IM ectaunt jar A sbilt of r.

ed amm. 49 yeboaW b&Mw ft W.
from" b sys6ma 0-H ... 0. ucv
IP 6!
ra- W. :31
lWb-9(190)1 d. pm-liol obstf-Ul"alul-104
ry,61
fur the lrcqwmein r mW the band ~sict X iml
thr (III
No, Oll in amme"m 1160. MrA in oil-
flulic.41. 11 qh~
.mww of R a8alud v b extrapabW to knm P. I
he lollmv -
ins E valum we obtairAml - bydvAftd 011 -
127. VtO 1,11
I.%. creUe diwm of 11COalf 73. IlCOIf [VI. 0
cr~ -ul. A
LOChOsAlkal-lienk. With Stem'* equalims W.I.
I . 11*111) Ow polmW bwvkr to pgaian tramal-
v fit"" 14
IV awAkf filimifial wd. is esiod. 1, it It..
rp.,~ 67 LIAI,
WAhfWhYdM4lldOll-wA6 4C(C(h.)%, I'llAun
Mid A qc 80.

I , -
BATUYEV, M. I.
"Destructive Hydrogenation of Isobutylene Polymers,," DdIc.
AN, 640 No. 3, 1949.
"Spectra of Combination Light Scattering of Chlorovinyl
Derivatives of Mercur7 and
Antimony~, Ir.. Ak. Nauk SSSR, Otdal. Xhin. Nauk, 60 1949

Tb* mapselfte onA strughtre of dMubviyIes" &*4 trj~
If- f-baly! WcoW *ad" Jbq infig-
A, P.
OW A. 1). Petrov (Axed. Sci. USS.R.. Nim"W). lar.l.
AW. Ank SJ.S.M., OW. Khow. Vawk 1030. 00-3~
Rtfluxial 14 1. iso-DoOlf with 1.3 1. Me' 110)o 6-8 be%.
so=.. w"lax, MA drying the two. layer, Save M- One;
416. lesisoNd*wo. with amat 301*, &W-avieum. The
PLAN"" I*Mfwi~ "In%wed 44 i~%ltutrknr *'~ "-hulf"r I.".
01"1 30141. byde..-aflums 414% Tjlr .1111WI lr~lowl VWL1.1
ic mai"al evnevs-"utina s.- iii"woho.
-I%Itfw (1). which sm further dion. it d% q%f inw X.";
lairly port 111). 1. Io$ oil,
0-70". av I J"' &Sul 63". 1. 1., Illo - its .1 ~;. I:-
Irv 1.4012' . confirmation wa~ hat by Ranun sitertca cot the
COSUpdo. and of their hydrogenation Iwaducts let. flasbulin,
d at., C.A. JO, 14rt). The catire octrue fraction tm thi.
twis was given the constirs.- -,Soq U. 1.5"; 1. and 10%
2.1.~4-trimmbri analog. The triiWaitykne obtsined was
Menticul with that obtahmi ftmn iontni-t lent at W. it b.
I Tm V. sf:. 0.71M, OV I'M,. awl M Is"I"Wenali-KI core
the salsi, lbvdVswwlou. b- I--$ P, I , 1.- 10 76M',. *I!
LCM. Wralifirtl I-v the Ramen %%
In acvwd with U InIn**t's otouosati.Ro
.ludie. (e.A.M.&WI). tftislst~%n by shchiamate mi%t.
It %-f the llutkrcw wid JJ. Ross. IgAr. S. 1147
(IM); II. M. 0-7* (italIr an sew flehl ).
Vicislinji the Me turr mi%,... b. :117 '21W. d; DAMI, av
1.44M. the it" wit gave a djawk avol, wt. in C.U.. The
cnidatiort products we identical with t1kne fnmn Irdvibuty.
Ir"r made from isobuirk-ne at W. 1". 311. xCWA"rA4

CA
M ~ =mum AD - g-
ibe be p w om aw
No.&== bow mo"
AOIL
Mato" moomm I tails
=W r -
1. sw OWN is
tht Was wo MR *AWP. bot SSW
bod. IUM. ro A am r ow do I
"m sm MA OA4L*_ '!!ms
Iml-
venom! so tka On 0044 *100 A-
A AM ft W A. 3.
:.O=w
60 so no
0. b..k E
I . IM 00=
N" IN cm
A ow $I I ' lbombstaismost"tibeo6fpospin
1*6
1"Pow. m aWpbO&Wft. - - i I F
10 k am
Ow tbl= at a
wkIh modolsibs.01 N. T.
SPJL
IL one.
9h fw the bydroind Oll- IN04M 0014
2 tm r GA"m rMI2,
Mg We Web VIONAMR.
at am a&-$. ift L=w
*8017wom-1 ww a mmovsk " low
1111MI " mdom _. =*a-".
W @I scm "d r.-V-zm I
do go cA do w
a I=.- 12-,
hat
low $90a .
an Loom - ' br ft=nr_'

Ch
PU d CA 44.2AM
r, 1= 6004. mWb "4in. thp
~T--Pdf. 1'- 11
11141dulatim tbtwy in by -
maclujaw"rh 'be 'I IXPWI in ROIL - . OR, olf
Irs the (111 Im"I of 1111 CAI.Inw
r1l'i"it 11w to a #11ww" lillf wIM"flom in the
"im tN*A4j
'colon, I
Irld-I by a quol"fin's."W'rij l1w"

CIO
bw=bd Of &W" ofoddli -W alsobels
a" d I RAWS qm*o4ag~,L 9mv. A. P.
Meditkoolowt mail A. 0. ivem tAcad. M..
- tI-89=4
VA.&R.). Aw. fibml- Two-As. so.
7U hopm, c4 the Off vibmtion in akb. decreaw%
with bwroming mW cbu*cW. to U
in W the otx= ft ele:
?.C.&U,j;H III "MIS ,b ar-n-V
I Olm
or 10 M. lb4vlwc4,1c,-A*
im. air., is laidwalsk"Ur task. is -puticular.
CI. It cwhim1wo romilly OH Wr Cl. to U. the acid
M
cbwwkr is am* emupdmm. in particulm the am of
140. timelplo"K144led, d the dift-Atr ofestaAcatka.
7u stromom " I& III, wbicb Imm a', W -l in readily,
is mot otwified by HCI, mad is " &hpimmd an bestial
in the tNF9 d WdirA. 7% ft'%Ultb COR&W dial iU-
OR ow of %be OH sraup kmm its vitsmuott
hwp-T. X. 71m

BATUYEV$ M. I.
"H,*jd"carbons of the Cyclopent eries with a Double Bond in the
Side-Chain.
II. Vinylcyclopentane.," by A., P-gate., P. N. Shafran., and M.
I. Batuyev (J. Gen
Chem. USSR.9 1950., 2oq 472-279 - M Translation 505-531)
Del7drating the acetate of 1- or 2-cyclopentylethaml by pyrolysis
furnishes
vinylcyclopentane., the structure of which in estabUshed by its
chemical behaviour
and by the frequencies of the combined light-scattering spectrum
which are listed,
Mg cyclopent7l chloride (I) a-A MeMo furnish
1-cyclopentyletIm-ril., C7Hlh0 (33%).9
b-pe 73-76P/32 - go mm., dz 0-92280, -n4v 1-45 which yields its
acetatd,, C 602
.p. 76-79 /24 M-s q79-18507 '41 mDv 3,4561,, when M~&'
(84%)., b _4R mej, d 0-9408.,
with #c2O and gradually treated with H2P04 (d 1%-Ac 0 (prepared
-overnight) at
:P38 . Ethylene cide -and I turnish 2_qyclopentyleXn~l, 07H 0
(27%)s b.p.
94-960/24 Ymb.,, d2T 0.9190., ju 1-4576, similarly transformeed
ithe acetate.,
C 0 b~p. 98-16P/34-35 mm.s 193-1W/742 0-9541., 1-4399.
2 bb
mMyRis of the acetates by passage in a slow stream Of N2 over
glass wool contained
W
in a Mo glass tube heated-to OOP gives 16nyloyclopentane., Cflh
(37) (;~'80%)p
b.p. 98-2 - 98-50/75o m., A2 0-7667., % 1-4191, Oxidation of 37
wi!~ cold
4hgives H*00 and cyc pentanecaitoxylic acid, b.p. 215-220P.9 d g
1-0597,
_JOKMno
1
1-5 1- 5; neut products are not obtained, H. Wren

BIJUUX, Y, I
mm~Act 6 ination* Scatieri Apr 50.
n9
Chemistry - Organic Compounds
"Study of the Degree of Oxidation of Certain
Alcohols and Phenols by the Method of Combine-
tion Scattering of Light,ln M. I. Batuyev~jl
A. P. Meshcheryakov, A. D. Matveyeva, Inst of
Org Chem, Aced Sci USSR, 5 PP
"Zhur Eksper i Teoret Fiz" Vol XX, No 4
q
Shove by subject,metbod that *increase in d6gree
,;'of oxidation of OR group in a series of alcohols
(pentamethyl
ethanol phenol, trichlorodimettdrl
~jethsnol) is in complete agreement vith chemical
data.,, Submitted 8,.Jan 50.

togv (Acad. US.SJt.,
d. C.A.44.2UW.-My
tojOrm aW Val'bm. C.A. 44.934. 1.

Z~R TV EV.
BMISOV. A. Y6.
Pawn Ef fact
Raman spectrum of chlorovinyl derivatives of mercury and
antimony, Uch. tap* Hoek. un.,
No. 132, 1930.
Monthly List of Russian Acceasione Library of Congr-es October
1952, Unclassified

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tm,w p4olmiss,
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all It, Ili lwkivr 4% .6 fall"I. #IN- .1.01"
lot
44 Ibir All-, if i. frAliv -rri th.1 1144.
I.wm wait"ll of two Oil Pimp 44 thir Ake.
iilf~ldw It-. In
Tow
041ne. clime .1 tell 1w curaded to alkyl
lidikko and oxv-
replant. it n4emnm to cetkirtlone of data cm
nw~mrm
&"d Oil COMMIXI'l- RlIffiltd- Tow,
vismirwifirwk lbw &W On twim"T alm tin at W2 m
~ - 9.
few onvollaty alve. 3w &I%# Im IrcIlAry a". at
31113 ir"Wil G. M, K0401AIMAY

USSEVChwaistry - Isomarization sep/Oct 51
*Wchanism of Inomerization of Hydrocarbons of the Olefin, Series.,R
A. D. Petrov.,
M. A. Cheltsova, M. 1. Batuyev, Inst of Org Chem,, Aced Soi USSR
01% Ak Vauk SSSR, Otdel Khts Naukw No 3, PP 571-575
Expts on isomerization, of hexene-3.. 4-mtbylpentene-1 (1),
2-methylpentene-2 (11),
and bydroixonerization of 2-othvlhexene prov d that isomerization of
normal and
branched hexenes and octanes, with formation of 1 or 2 side chains.,
results from 2
parallel, independent reactlons. Found that II con t be.inowerized
to form 2 side
chains,, uhile I gives good yield of 203-dinothylbutene-1.
PA 195T16

BATUYEVI M. 1.
USSR/Cht.mistiry -m Wtbot4a FoSIA
vaia3guo k*%i~wauaa ur coibm x(maids With %*time Ti. wammunatim
of Cazbm Monesift With a-ButowtO T&*.,T4i Syduss, N& 1, Lrahov,
M. to ftttw",p X* Do
Z&U=kiya Imat Or& Chess, " Bel ussit
slow, Ak 24mk SSSN ')t&l XUA Smko No 6j, vp M-4727
-4na. imAlostim aC roootim 41manged tir tbm In X9464, allthCft
BUXUAKI
brb eamtIon of GO ulth nQntww at 190 and I ats In the pnowme of
4.6%
"PVMft&VMU t
(C41-r3V
qtdA condeamto boUs In the ranp MQT60,
It oatmists at pwaffin brdromarbous and 28% aawfto On
hydrogewtion TIM
of tim It 0.1520, M cc*4m tt*n is 24 va-% CS

USW(:hsmjstry Petrojew% IsomulLs&Um
190werisatLono of 020firac 1" 00"tM* O"r AIVAdamdUcatmes As 4
Petrov# A* Vc
Dataywit A00016M IMStp ACAd Sci, (mn
"In Ak Nak =j Otftl ft&tM *W )b 6# pp 70-752
Iwegtlm~ catalyda is 1 , a risatim on alud=giUcate c ataapt of
a Maber of
olerinic hydrocarbonm ande conKtione exclaftlK cmcKr4*
PrOPO&GN awhAULM Of
immerisation irmavirg wplitLaR off of olefin ftyxiLcataXyst ar
fVra
v a U"
101"adl to t cy=propaw va ring
c SHWOrNre waft !Mm bond.
ng ~ ov In-the uwatd Woducts, the
double bond is umially next to the aide alkyl grOW-
PA 297M

,y4,Lrogen Bond and the Physical Idealism of
Its
Predissociation Theory," M. I. Batuyev
"Zhur Piz Xhim" Vol XXV, No 7, 884-895
Criticizes the predissoclation theory of
the,hydr6_
gen bond,-referring to It as harmful and as a
typ-
iftl example ofthe formalistic tendency in
physics.,
Daides that spectroscopic and other exptl data
prov predissocn. and discusses this point at
length.
Rn4wgos in p6lemIc with N.'V. Vollkenshteyn,
M. A.-
Z117ashevich, And B. I . Stepanov, azathors of
mono-
p'sph "Oscillations of Moleeuleo'n qM (State

. a*
W.
ML =
ll~
and.t
-?..
0

ITWS, Ta.,T.; PUZITENIT, I.V.; BATUUV, X.J.
Catalytic hydrocoudensation of carbon monoxide with olefins.
VIII. Hydro-
coliain-sation of 4i oxiIdo.with is6tr~iyfsns. IsveIat-.
84886RO
rhim'*" auk-1526,978-81.
W.47'no"-2141122 10)
1. last. 0r&. C%te~k.,.U4. U.S.S.R., Moscow.

Usin/chamistry Resonanci-e-blasome'ric:
't.ov" ~2
Theory
"Heitler's and London's Theory of the
Chemical Boad
as a Basis for the Resonance-Mesomeric
Theory and.
the Defectiveness of this Basis,, 11 X. I.
Batuyev,
Moscow
"Mur Fiz Khim" Vol 26., No 3.1, pp,
1694-171o
The author does not agree vith the view of
others, to
vlt, that the resonance-mesomeric theory
does not
evolve from the quantum mecbAnism. He sees
this
the as an atten" to qualitatively transfer
Halt-
lir. I 7sand, Loridan I a chew boad -
theoryj.L rewding, tbe
N' to th4r,MOrell 60iPIAM =Olivett
SLIACO')"~'
t6'the a4thor.. this -Chem bond-theary
IsItbe varY,_'
,fowidation of the
resowMce-me8CMeriC.thaOrY), and..'
,:is defectives then, ipso facto, the
resonance-
Shasomeric theory is also defective.
Batuyev con-
daims the theory of, Heitler, Londons
Paulihg and
others for destroying the conceptiou ui
the "in-
dividual" mol established by the
principles of
Lomonosov.and Butlerov. In,'affirming the
indi-
vidual chem structure'of the mol,
the;author tin&
the dhem theory of Heitler- &:Ad
Lobdoii'invalid;
ccwseqaently~ the resonance-mesomeric
theory is
Insupportable.

I
SHOSTAKOVSKIr, - 14. F. - A&=, X. I* - TjUpAEV, p. v. - HATV9=4L,
A. D.
Oxonium
Oxonium theory and its optical substantiation on simple vinyl
ethers.
DOkl. AN MR 89 no. 1, 1953
9. Monthly List of Russian Accessions, Library of Congress, may
-1953. Unclassified.

ti atild of The hyt:rogta ~~=d in 6u,110 gjjorW-jj:t,1
=W

-
ycolii and p(AygisTols

p- AIA
N'r ~
ad
sP
chwdoal Absto
-
.
flfl-014 Pf fr.N,0Vt'qj e.11'" j'j C4%~%,I,

Vol - 48
KII)CII-ollb. (ACII-CIIJ11f,~. ;-,,I
,

tht)%t Q, bl~F-A,r iii
of ibc
APT. 100 1954
lypipal 1111ratIlIg djit

o
sao
~; ~! o 1) Ic u1 01. %-, t, q! u o1, 11 1 , ~
n
tc,-~C-n. 14 tilt
fibcr~ in thv 6,;nvri~-

cip:vl. wvl C.4nnot

form 11 bmv& k1sa lower
b.tx, and Imsvt

Vmn am showitby their isoemm viiyljfyei~1%!thvt%. 'tilt

latter show isotnerization into the acetaix In r-olns. In CCI.~

tbiv
&4~x not. omir lit C41L.

rF_ tv
Ca
a Unts by tho ctrnbime.4 trohml. It. Twi gs-4GEnts
A. F. Batt% A~ !..I-
_Batum, T. v. BvTvmYi%, iv,tl 0. A; Tixyalz', -. 1).
vt-
7S.
-S.S~R_~ QW1, Xbfm. Na"k,19K
from" Kimnlmlak ma 'wete txamd, by' the Combined
optieal-distol vritthod, 1u fractlans b~ tander, 1W ovtx 70
NY," were IdentiFed, Ouf accounting for 40
bydrom
of the, tow cmupli, -It Is shown tbat despite tbe claw
urigin of tl~e. -gwtAmeivs geajvWhkally. mlsidrnjA difm
fermom J11 compn. slit foutid, * 11Z. Suralth _141 11 -T-77777~~,
I, iVIA
m6m.- 6 A- 134iAnIld
-A.- Tarumvc Aid. f
OT*i
j,41-Two' spoeximemm of ~ S;trakhan gasoline3 were -
vt".,by the comb)"d method, V, bLvh a -47 h~
'Cumpa,' Disto. cljivei and Astij.. data !am cited.
G.M. Kowuporr

KAZA SKIY, B,A,; LANDSMG, G.S.; PLATI, A.F.; LIBROM,
A.L.; KIMAYLO-
VA. To.A.; BAZRULIN, ?.A.; BATUnff, X.I.; UKHOLIN,
S.A.; BULOOTA, T.F.;
TARASOVA, G.A.
Composite method for the determination of Individual
hydrocar-
bons in gasolines. Part 3. The Surakhany gasolines.
Izv.AN SSSR.
Otd.khim.nauk no.2:278-291 Mr-Ap 134. (MM 7:6)
1. Institut organichaskoy khimli In. N.D.Zelinskogo,
Fisichaskly
Insti-tut, In. P.N.Lebodeva Akademil. nauk SSSR.
(Hydrocarbons) (Burakhany-Patroleum)
(Petroleum--Surakhany)

W77.
L
Oumhw O"m to on NM at Op" BWy Gi the bydrv'.
R Vw bmd in &*mA iii&Wuyl others ut gly4cb and Vr.
~Oyc4u. M. F.'Shwakovskil Nt I. Buturv, P V Tu
~g - Ift.
L.and A 6. zcfi~da
jc4m. kkim' N414 d' CA. 49, &MV--
FAMWI SWUa Of C1J%:C11OC11tCH2()H, Clit:CHUCHr
cHiCHMi, ell&THO-
CHxC1lsW11iC1lvO11,
Abil cramd. 'ne
-t repf~=&d. The eykik t4cctati do not show the
nroLr 10W cim. I or tho3c nbove WiO wbkh
=
:art prmut in tht vinyl uhtm of 'lm Oycols. The= fre-
ncies am U&*Xd., re-op., %rith the (11poble Wad atO WILIft
jAcilllatkm uf the CH sit a &O)it tvnd. 11m 1;ittc-r
(mclucm-kn Am ~pmakj -it SWO-312~) c-ii, -, Aik, 4t 490-
A00 CIA, -1 the gly -0 de-YiY5 show :& ivLle bAnd cd the HID
ur Pholl, ThLL. ~ HO a-rcot t1we
zr.mfaun iTavnn~l. I'l bosW he wldt4;h and diffwl-vucsA of
the band spcak, fr iti latuaicl. cz~.r"tn!r. This j-2 also
zonfuYnt-d by tiyo,-opk dcto. Q1 uIal. k, whkh O(iwa
propr_~i%e k.111(hil. With kw'rv_'~&o corwo. of the Vinyl
g!,,',x1l ebers _,i *ell -_5 by t1it highez v6cmities Aowu by
the vinyl Ely" ctimri 4% compur6on with the. cyclic isectuis
of the !Fdme mol. wt. Tste mahs expidin the r-14tive
ummaettvity of vh-iyl glow;coleffi4trs (utmu vtnyl ckrivs, nith
fr** 1i0) i.-1 ;Walk invdks,~ ihoe the 0 At= ts shv*dy in-
TQ!Vc[l ~A 0 1i bc~lad. G. M. Ko~~apA_

Aph"k-unab
h wrs felt tut
With stnictwu
&cash iren lpn
),-In view of the kiiowu re-
of pbenob an besting ef wo.
loinstim w hexam of
= .1 'fisatic amt.A,)
I mlAt t"WEdwo fautf-um6m
imet d 110: M*c"(0171,144
xy IASM; AhCH(OC.L'r,)O,
1. 132, *V IAM. The inter
7&-"'. dn*,750, mV I -M I
aotstin "W Lusy Una WM;i
cars _by ~b* pbenol comporm
" M.-MI"09 U" ho wro
4in the presewt of sk
1 W.O. do D-Om.
po. N 111-120. do
C113: CHOCM4, b.
swtra of the above
too Sum of the Ue%.
0-mmi MCICM Rji -----------------
of the" VomVmtnt%4

-7
l1xv
ul ~ -%-,t9Q?4LC
" - "Onz-96.W10~9to owl;
Povawsau 103
W,39 " oqI.Iq
0)1 wo )o D vq mridgip oqv
6?P'O'
A 01
DI mil.
am
4v,4*
Ma, sa'Am
:Ojn;mm
u3u()O alp Of
in
uw
4,9 ..Ulos ul
"duVo pp
)o ~=I pill .I aAnd zip
11M JQA8
0)11 qaW - I
W4tddt plft "Otp
3 411A, -
P of - IwM2
MOS0423 Aq
tac
IT

,.Zf IMF
oi
76f
~r- -kit
'gag
MR,
C2
ix ce qt
717

SHOSTAKOVSKIY.M.F.; BATUTSY.M.I.;
CHXXUUYZVA.I.A.; KkTVZMA,A.D.
Optical study of certain othanolamine, vinyl
others. Izv.U
SSSR. Otd.khim.uauk no-3-'544-55o my-je 55.
(KLRA 9:9)
1. Institut organichookoy kbiall Imeni
N.D.Zollaskogo Akadenii
nauk SSGR.
(Vlrql others) (Ithanol)

MA.
L A.'
Ilw;, 0- "4 A-,
oldd~
Aftd
sw 18U. U5. *4
"Vil Amd w S%0)
a MIN
V
, . ef..C 4 0-9,0).6
ftj.mRV 49, all
j:UQM 0( a
4b), qW2b
mini: W. I
Q,tam0l, lrb,,- '. I
A 0 0
U; t)m chim dmmn"bUm at 1104(1 It Ib
Pauli b amiwd to it "ertam of
141 1
44MIM figles .ataido- - bwms. rho empeb. 173 jai 1b)# 1 (10 !-1 1
as well ,Iw -IIdw MUG of dif. 4
~O boi:4. Cn' es the 2ow
I
Are ZVOrted: jCg The ocl: 0
'a (a) 0:CHOCURM ma" 1 4 fil-I IINI), 2114(a),
2) MORE o4va"
I _W2) b
7 57 ,
o mix ES4 .224M2 41
4 50~: 0: 819(4). 0
3 -1112 4) a( 0 4 : 81
1
'm O'l Bil-
J_' R
*% l I . ,
2 Iw( L, 1 011, 0 35 1"' 8710
112871
2 lag) - J, I 1] 0
17 w I boa 11
6).1817, 'a 493( 0) 1
3b; 1
I
_410) 1811yo
"4 24- 2%0), 3024 - , Oav(ll 2M
hZj
h171( .(4 MPZ- 1) 3MI(j) W-1 .-NO). 287 i
2 Fi0owt
) I U), 1
8. loo 0 Q 0
3),j 2.1 71~ Q,
4 " 1) ~.Wl'
4).
10.
17(
4(ji 11 2b).
0A)IU bi,
I
10
Ob I 1b. 3b
0 2
G
A

Vsruthesia
7P7
- ---------

USSR / Physical Chemistry. Molecules. Chemical Bond B-4
Abs Jour i Ref Zhur - Xhimiya, No, 8, 1957, 25790
Author 2 A.P. Meshoheryakov, M.I. ~~t_viv, A.D. Matvayeva.
Inst : Academy of Sciences of USSR -
Title i Synthesis of Tertiary Butyl-Hydroperoxide and Ditertiary
Butyl Peroxide and Their Opt'-cal Study in Lig~t of Ques-
tion of Hydrogen Peroxide wt.raoture,
Orig Pub 3 Izv. AN SSSR, Otd, khim. n,, 1955, No 4, 742-749
Abstract - Tertiary butyl hydroperoxide (I) and ditertiary butyl
'Jjy-
droperoxide (II) were prepared by alkylation of 1 mol of
27% H20 with 2 mols of monotertiary butyl sulfuric acid
(III) ai 0 to 100 in the duration of 4 to 5 hours; the
yield was 80%. 11 is separated from I by the treatment
with a 10 to 20% N&OH solution at 0 to loc. In is prepa-
red b~ the absorption of isobutylene by the 63% H.SO.,&t 0
to 20 . Spectra of combined scattering of I and II are
Car& 1/2 - 33

-13AT Ii
;41

/Optical a .t.udy of an-d-
),Ahe regLiarity of Worizatim of these compounds. Lt. 1.
V11--twev, A. D. Pt:trvv, 'V.~A. Pcmomarcnko, and A, D,
Matv"va. , lzrt:o ALd Vauk S.S~S.R.' Oide). xhim.
JV.uk 1956, lj~ii5l-Tht'I!A~Dwing Itumn Spectm
re detd.: Rt4S: IT(K3), 284(2
4), 974,6), IW7(4), 1234(6), 1276(0), 1297~O
1370~1), l4le"61, 1165(g), 2734(2). 2K, 1 (3).
RtIsicif
I&SM, 2100)), 2142(j), L;?1(2). 301 4). 31-4) 325(l).
461(4), 4TIN(6), 007(3), 7;V3). 74 3): 977(5),
1213!1'~4~' 1"'N~D)' 1467(7),
2, , '~1741(21). 2327 29 4(d), -'11)41(2),
1
2~14-6~, 1), 2070~.0'-: I I I(I), 12GO 1. 167, (1),
.1 1, -12-'(W, 457-
2
1 231,11, 2 25 1 1 3 11(5),
!a27,'i),
14(fiftb), 1;63
2CL34(4). 2,967(3),
l",(5), 212~XO), 264~0), ~W4),
5WI), V~0(3), 77crS(4), 7MY 5), 813~5~),
27-17(l), '~929(1)~ 2SS91% 2914(2), 2113go),
IT73k:'). XrSiCb. 321Y,43, lfiii(2), 17P40), IWO),
12JJ7), "104i.;j, 717(1) 07W2',,
1015(4)'12 -M, 1~.
27- 1, ). ~ '
_4k(1). _N~O~J7), _1931(2), :NJ46k(i), 2UN-'3),
'Fj,C, 371(3), -10.5KIO). .157(l), W(W,
CS'2(7), iOXO). 9112(7), 101.1(0), 1057(2). It RI 8),
31 1'~
I MCI). 11510). 11 "pit 1)~ RSN). 4)
A~ j
2 VAO

9;? 12, 1
mIPJ D' RIT 1; UlWomix tric vibradwi. The Intoosity N the
symmr",~ vibraqr~n of Mc! 6 rdatlVdy more intVAC Lliall
that of C.; I., utatcr pritoulzatim, ~f the CH t-rid
in tile Clip givui;. Protonuation fia-w:s the upproacti or
ptrictrati"n of It into ihe ti-umn oTbitai of the, bund.
Ainmir th, thti fire marle:
are ci*,.m:-,wtd td
of h),,(--r Oc-c-troucg!'zi-I~ S1 m coull.."Fl--l!
-6,; whivh kazis 10 ~% fit Aciwn, IoNvald C
~-,:u the Si atagi, biit the cfl'c~t is, rt,styii-ted Larrely to flie
grcAi" Pnd havi li!fl, vff~,i cni tri-mmd M, groups.
.1 Cl thc
-within Me und C-Hg gronpa. Tn view of the prolvable tice
tronic distribution, the "nullq i)i zhIcirination of silanes mr.
-'i m 4k.,ck .11 ffiv
e%pLine'd ~ Chhmlmt;r- .,f i S
c1l, grollpr GARI)4 tc: Ff";:1,"f I k 11"'N d M 1wattans;
inti-cAuctiol, f C1 In pl~,C, A F ,t gr~ui)'.
results vventually in exclusivt- iti-A cm tl!~. Me goups.
u,mig. w the Omlron-~,ttrVMI,~, ef!(~ t oi Ow Cl atwizi or. Si.

USSR Physical Chemistry. Molecule. Chemical Bond. B-4
Abs Jour i Ref Zhur - Xhimiya, No 8, 1957, 25736
Author : M.I. Batuyev
Title : To The question of Experimental Proof of B4ker-Nathan
Effect.
Orig Pub : Zh. obahoh. khimii, 1956, 26, No 7, 1888-1896
Abstract : Basing on bibliographic data of other authors about
ch&rao-
teristic frequencies of molecule vibrations (Trambarulo R.,
Gordy W., J. Cho*. Phys., 1950, 18, 1613), an attempt was made
to check the correspondence of the concept of Baker-Nathan ef-
feot (hyperconjugation) to actuality. The conclusion is &r-
rived.at that the electron mechanism proposed by the hyper-
conjugation hypothesis has been experimentally disproved and
that the electron;-nuoleus interaotions in the molecule are in
fact more complicated.
C&rE 1/1 - 7

-BATO-AV. M -T,

Ei,

t IOR CBPBdty *1
le4
da

ancl t,
r",

U3SR/Physical 'y - Molecule, Chemical Bond. B-4
Abs Jour : Referat Zhur - Khimiya, No 1, 1958, 14o
Author : M.I. Batuyev, V.A. Ponomarenko, A.D. Matveyeva, A.D.
Sna gova.
Inst : Academy of Sciences of USSR
Title : Cis-Trans-Isomerism of 1,2-Di-(Trichlorsilyl) Ethylene.
Orig Pub : Izv. AN SSSR,-Otd. khim. n., 1956, Noll, 1420-14-21
Abstract ; Cis- and trans-isomers of 1.2-di--(trichlorailyl)
ethy-
lene (I) were detected by the spectrum of multiple scat-
tering. The range width (43 cm7l) between the determi-
ned frequencies of double links C C of the cis- and
trans-isomers-of I, unusual as compared with cis- and
trans-isomers of other compounds, was noted.
Card 1/1

-vf-

20-2-26/62
AUTHOR BATUYEVp M.It.,
TITLE --Un- Conjugation in Butadiene
(K voprosu o sopryazhenii v butadiene, Russian)
PERIODICAL Doklady Akademii Nauk SSSR, 1957, Vol 115, Nr 2. pp 291
- 294 (U.S.S.R.)
ABSTRACT It is known that the addition of haloids and.hydro-haloid
acids to the
simplest of w-conjugated systems, i.ee butadiene-1,3, takes place in
form of a primary act as wall in the positions 1,2 as in 1,4.
Accord-
ing to'test conditions one of these directions will be dominant.
Accord-
ing to the Ingold theory (and others) these double reactivity of
divi-
nyl is explained as follows: nTwo conjugation factors become
effective
in these react ions, namely the static (mesomeric) effect and a
dynamic
(electromeric) effecto The first one manifests itself in the
molecule
and outside the reaction, the latter in the moment of reaction*"
Effect of the static conjugation. It is caused by the prevalance of
the
structures 1 am 11*8mong all I Z V and other structures in the
divinyl
molecule.which are discussed in the mentioned theory in connection
with
the quantum mechanic description of the molecule by the method of
loca-
lized pairs. In anothers fundamentally identical denomination., -
it is
caused by the prevalance of electron displacements Ha (I +). II) in
all
possible II& - Va and other shifts, The same is explained by
schemata
of structure and once more described in other technical terms
according
Card 113 to the same theory. In the divinyl molecule-the atoms 1,4
in a certain

2o-2-26/62
On Conjugation in Butadiene
different with regard to their chemical structure. They
rearrange
tautomerically and enter the reaction in its final stage,
namely
during the addition of the negative ion to divinyl.
(1 illustration, 19 Slavic references).
ASSOCIATION
PRESENTED B.Y
SUBMITTED
AVAILABLE
Card 3/3
Institute for Viaml Foals
(Institut goryuchikh iskopayemykh Akademii nauk SSSR)
NAZAROV, I.N., iAember of the Academy , April 25, 1957
3o.3-1957
Library of Congress
"7T
115 141 4C (;ILs )- Molecule,,Chemical- Bond.
Abs Jour: Referat. Zhurnal Xhimiya,. No 3, 1958, 6979-
B-4
Autbor : Z.1wW4YeV, VoA- Fonom_-enko, A911. Matveyeva, AeDs
Snegovas
Inst : Ac&dwW_`~f-Yeiences of USSR.
Title :optical investigation of Intermolecular Inferaction Si
... el.
Orig Pub: Izv-. AN SM. Otd. lebim. n., 1957, 17o 4, 515-53-6-
Abstract: Bl~" of lines referred to the valence vibrations
C-Cl(722
-1) was observed in the Faman spectrum
cm and si-cl (448 cm
of the silico-organic t3 -halide C'3s'CH2CH201. This blurring
disappears in cyclohexane solution. Also., it is not observed
in compounds of the Cl Si-CH2CH2~M2C1, Cl Si-CH2-02-S'C'31
2er types. Thi _~ is expliined
C1-ASi-CH2qH,?CH3 and to s ;9;o
by"the existence of molecular associations caused by an inter-
action analogous to the hydrogen bond. An easy etbY.*Lene and
8=4 formation is observed just in the case of the (3 -halide.
Card 1/2 -22-

USSWEbysical Chemistry - Molecule, Chemical Bond. B-4
Abs Joar: Referat. Zhurnal Mdmiya) No 3, 1958, 6979.
It Is expressed that also the formation of an intermolecular
bond of the Si ... Cl type in C1 Si-C&)CH202a. may be possible.
3
The latter is proved by a modetatee brurRng of the bands O(C-C)
(712 cm-I) and Y' (Si-Cl) (457 cm-1) -
OT'rV 7tsE~K
Card 2/2 -23-

--- -- -------
Waddid o -hAW
7 Tb;,d- Wv-
bth
;~W$.to unzymmetricAlly vlbstitut&4~'& 16.1
Tk . Z& r. Oxs)L-jvj K).-Z%;. 21;-
-44B.06 'K'c"Ruman sW-truia o1
tilt c: C bond hw-, a R-axti" hand 'at 1&131, cin.
.he t.1c gr~,_.p are
the C-H Vibration- in *
ix sym- ;in~ wanym. vibr~h-,a-i, c~;p The-.se -2:r, ~11
hjj;~,rr aan tl~c C:C vibTation, in Coll, 1621, ant' ~11
elpt. sbows tb3t the C;U lxmil in proilene is Milan-
filed rat!-tr thAn letigthpned. The rc--ult is expliunc(I by
"clectronir.ation" of thit; druble bond and by unrqual ck~c-
tron pupulAtion of the CH bonds in the hie, c11, and CHI
groupi. N piopete the Cli bonst in the 2-pix-ition ham a '411
frequerc) off 30G1.1 cm.-I and iv the CH& gmup have
Allareabovotheparrif- I
finic types. The formation of (CHg',jC1. by wVO.n. of HC1
to CH-:CHC112CI at low -.mp. is explaiutd 6y cis-traas
lsonterism of the latter, with the trans ioinct predc -nittathis
at fj~Mtl temp. or fitboVe, Ylejol
ng. w norm
m1c P-roduct.under tImse cohdidazis.- 71it CH bond frem
citte-acles in CIII-ClIcIllicl are: cis form, C11 In Cl-Ig r -)up
2877, 2957, CH in CH glroup 29SO; tram form, W21. ri:*1,13.
Zile 2877, resp. - - % 0. M, 1olapoff
DiOtr; 434J/4E2c(j)

-24;%-- -ham-
fOllh4 t6 U
FIE-

r ----'!T ~z7-,-
MR
7, i --'I 3~m1
-Awl

~l A r .
-V
BATUTEV, M.I.
On conjugation in butadiene. Dokl. AN SSSR 115 no.2:291-294 Jl
157. (MIRA 10:12)
1.Institut gorruchikh iskopayezykh AN SSSR. Predstavleno
akademikom
I.N. Nazarovym.
(Butadiene)

20-3-18/52
AUTHORSt _R~ev ~M- I., Akhrem, A. A., Matveyevat A* D.P
and Nazarovj-'*_- N., Academician lbeemod)
TITLEs Optical Investigation of Conformations of Cis- and
Trans-2-
-Methyl-l-ethyloyclohexanole (Opticheskoye issledovaniye kon-
formatsiy tais- i trans-2-metil-l-etiltsiklogeksanolov)
PERIODICALi Doklady AN SSSR9 1957, Vol- 117, Nr 3, PP. 423-426
(USSR)
ADSTUCTs 1.) According to recent investigations cyclohexane
mainly ex-
ists in a "ohair"-like (kresloobraznaya) form, which possesses
a minimum of energy, The C--H bindings of this form may be
placed at two groupsi a) those which are parallel to the OZ-
axis ("a" a axial bindings) and b) those which form an angle
of + 19,50 together with the OXY-surface (Ile" - equatorial
birrd%ngs). Because of the not great repelling powers between
the hydrogen atoms the "chair"-like form is preferred with
respect to the energy. Forp in the "tub"-like (Ilvannoobraznay
form the distances of each equatorial hydrogen atom (PV 1183
are maller than the sum of two Van-der-Waalls radii.
Xhao:el (refle 1) has formulated a rulet in the ceries of the
poly-substituted oyclohexanes the isomere with 'he gre%test num-
ber of equatorial substitutens is most steady.
Card 1/4 2.) In the thirties Chiurdoglu (ref. 8) has identified
the

Optical Investigation of Conformations of Cis- and Trans-2-
20-3-18/52
7-Methyl-l-ethyloyclohexanols.
ois- and trane-isomeres and others of the ois- and trans-
dimethyloyolohexanole, without distinguishing here the con-
formations, Two of the authors of the present work (ref. 9)
have synthesized the substances (I) and (II) mentioned in the
title and transformed them on tb the known pair of cis- and
trans-1.2-dimethyloyalohexanole (III) and (IV). But their
"conformation" cannot be defined exactly chemically. Here, the
problem is investigated by means of the method of the com-
bination-light-scattering, and for both substances mentioned
in the title spectra were found out.
3-) Guiding principles experimentally proved it.) - g.) served
the authors for the investigation of the obtained optical data.
4.) Cis- and trans-2-methyl-l-ethyloyclohexanols (I) and (II)
form an intermolecular hydrogen compound in the liquid phase.
This is expressed in the spectra by the fading of the frequency-
band of the hydroxyl group. In solutions of these substances
the faded bands disappear, because the interuolecular hydrogen
bindings within the solutions are opened. The 0 -- OR-binding
is equatorial in the 'aimere 1, which has a frequency of the
hydroxyl group 3604 cm- j and axial in the isomere II with a
Card 2/4 frequency of that group 3619 cm-1.

Optical Investigation of Conformations of Cis- and Trans-2-
20-.3adB/52
-Mothyl-l-othyloyclohexanole.
5-) The pulsating frequency in the spectra of the epimeres I
and II in, as well in the liquid state as in solutions not
single, but triplicated. The most intense frequency of the
isomere I is 682 cm-1
, of the isomere !1 693 ow- . The first
belongs to the cis-, the latter to the trans-isomere. These
frequ*ncies remain preserved in the spectra of the solutions.
Each of them occurs in the spectrum of the other substance with
a weakened intensity., Because, as is said, the 0--0H binding
at the isomers I (. cis-isomere) is equatorialf whilst at the
isomere Il (a trans-) it in axial, isomere I is an epimere ep,
and isomers Il - an epimere ee (apart from admixtures of other
conformations).
.6.) This io'confirmed, too, by data on the frequencies of the
C--O bindings, as in the spectrum of the isomers I the frequency
system within the range concerned isl compared to the speotrum
of the isomers II, removed to the side of short wave-lengthe
7-) By the isomeres I and 11 the components of the molecules
(ethyl- and methyl. radicalst hydroxyl) possess a freedom of
und the single bindings. Thing apparently, in the
source of their conversion transformations and of the appear-
Card 3/4 ance of small quantities of unsteady, tub-like
conformations,

AUTHOAS: Batuyev, M. I., lAeshchcryakov, A. P., .;atveyeva,
A.D., 62-1-13/29
TITLE: Optical Investigation of the Structure of the Lower
Polymers of
0
Isobutylene (Opticheskoye issledovaniye stroyeniya nizahikh po-
limerov izobutilena)
PaIODICAL: Izvestiya Ali 55511 Otdeleniye Khimicheskikh 11suk,
1958,
fir 1, PP- 75 - 84 (USSA)
ABSTRACT: The inclination of isobutylene for polymerization
foun6 for the
first fime by Butlerov was investigated already by himself and
described in a deries of papers. This was also done by Wagner,
Prilezhayev, BlItekov and others. The results of the*.-hemical
and optical investigation of the structure of the polymers of
isobutylene hitherto published turned oat to be contradicting.
In the present paper the coincidence (as to the chemical and op-
tical aspects) in the question about the isomers prevailing in
the corresponding fractions is pointed out. Beginning with the
fraction of thIe trimer they are inactive as regards further po-
lymerization. -~he active forms take part in the formation of
high-
est polymers and do not accuoulate in the lowest stages of poly-
merization. Furthermore it was explained that the assumption con-
cerning a conditioned double phenomenL)n (of a double) in the
Card 1/2 field of the frequency of double bindina in lowest
polymers (by

Optical 1:,vesti-atioii of the Structure of the Lower Polywers of
Isobut- 62-1-13~9
ylene
inversion isomerism) does not correspond to the facts(formulae
(1) to (XVI)j . There are 1 table, and 16 refercices, 11 of
which ,Ire 6-1fivic.
ASSUCIATIoN; Instituto of Mineral Riels, AS USSR (Institut
goryuchilch
iakopaye;..Iykh Akademii rouk
SUBMITTED: July 27, 1956
AVAILA13Lz;; Library of Congress
1. Isobutylene-Polymerization
Card 2/2

Al- J1.
AUTHORSi Baturev, M. I., Bardyshev, I. I., Matveyeva, A.D.
62-2-17/28
--------------
TITLEI The Spectra of the Combination Dispersion of the Light of
Some Hydrocarbons (Spektry kombinatsionnogo rasseyaniya
sveta nekotorykh uglevodorodov).
Periodical: Izvestiya AN SSSR Otdelardye Khimicheskikh Nauk, 1958,
Nr 2,
pp. 232-233 (USSR).
ABSTIRAM The investigated terpenic hydrocarbons belong to the
compounds
of the meta-seriee silvestrene-iaosilvestrene-silveterpinolene,
For their physical constants see table 1. The spectra of the
combination dispersion of these compounds were taken on a
three-prism spectrograph ( NO-51). The nature of the two
double bonds in the investigated compounds may be very well
determined in the given optical data. In silvestrene the double
bonds are far distant from each other; it may therefore be
assumed that no interaction takes place between them and that
they are independent. In isosilvestrene the double bonds are
by one C---C member closer to each other than in silvestrene.
In the latter the ethylene-subBtituent is in a -position, in
isosilvestrene, however, in an -position (in relation to the
Card 1/2 double bond of the rinf,7). In silveterpinolene the
double bonds

The Spectra of the Combination Dispersion of the LiCht 62-2-17/28
of Some 1~ydrocarbons.
are still closer to each other and an intensive interaction
takes place. The fact that one of the two double bonds is
cutside the ring and the other one inside the rinp, causes the
complicated nature of interaction of the double bonds, as in
silveterpinolene, butadiene-1,3 and similar systems. There
are I table and 1 reference.
ASSOCIATION: Institute for Fossil Fuels AN USSR (Institut
goryuchikh isko-
payemykh Akademii nauk SSSR) and Belorussian Wood-Technical
Institute imeni S.M. Kirov (Belorusskiy lesotekhnicheskiy in-
stitut imeni S.M. Kirova).
SUBMITTED: September 18, 1957
AVAILABLE: Library of Congress
1. Terpene"pectra 2. Vydrocarbons-Spectra 3. Terpenic
hydrocarbons-Spectra 4. Terpenic lWdrocarbons-Exchange
reactions
Card 2/2

AUTHORS: ALL ~uev.
M. I., Ponomarenko.,
Snegova, A. D.
SOV/62-58-8-13/22
V. A.j, Matveyeva, A. D.,
TITLE: The OptJct.1 Investigation of the 0 - H Bond of Some Alkyl
Silane and Disilane Chlorides and Their Chlorine Derivatives
as Related to the Properties of Their Chlorination (Optichoskoye
issledovaniye evyazi C - H nekotorykh alkilsilan- i disilan-
kh1oridov i ikh khlorpro'Lzvodnykh v avya21 s osobannostyami ikh
khlorirovaniya)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye
khimicheskikh nauic,
1958, Nr 8, pp. 996-'1003 (USW
ABSTRACT: The chlorination of methyl silane and chloromethyl
silaus
chlorides with simultaneous irradiation was first carried out
by Xrieble and Elliot (Krible and Elliot) and later on it was
investigated in detail by Speier (Speyer, Refs 2-4). Then some
phenomena of specifically anomalous character were found. In
the present paper the authors report on the result of their
investigation of the C - H bond as well as of some alkyl
silane and disilane chlorides. It turned out that along with the
Card 1_2 increase in number of the chlorine atcma in silicon and
in the

SOV/62-58-8-13/22
The Optical Investigation of the C - H Bond of Some Alkyl Silane and
D-4-
silane Chlorides and Their Chlorine Derivatives as Reloted to the
Pxoperties
of Their Chlorinativu
alkyl chains of the alkyl silane chlorides a regular increase
of the effective electron density of the corresponding 0 - H
bonds takes place. The anomalies in the chlorination of methyl
silane chloride and chloromethylailane chloride found by ctber
authors could not be proved by the authors. Perhaps the direction
taken by the mentioned chlorination could be called an anomalous
phanomencn. It is assumed that this direc t4 on is oausei lay
spatial hindrances which complicate the whcle process.
There are 7 tables and 8 references, 4 of which are Soviet.
ASSOCIATION: Institut goryuchikh iskopayemykh i Institut organichaskoy
khimii im. X. D. Zelinskogo Akademii nauk SSSR (Institute of
Mineral Fuels and Institute of Organic Chemistry -'moni
N. D. Zelinskiy,,AS USSR)
SUBMITTED: JawAELry 23, 1957
Card 2/2

50)
AUTHORS; B
__Ra ~u 9-1-,-Akhrem, A.A., SOV/62-58-11-20/26
Matveyeva, A.D., Nazarov, I.N.
TITLE: Optical Investigation of Cis- and Trans-2-Methyl-i-Acetyl
Cyclohexanol Conformations
(Opticheakoye issledovaniye konformatsiy tsis- i trans-2-meti.L-
-1-atsetiltsiklogekeanolov)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye
khimichaskikh nauk,1958,
Nr 11, PP 1389 - 1392 (USSR)
ABSTRACT:, In this brief report the authors described the
investigation of
the conformation of epimerio 2-methyl-1-acetyl cyclohexanols M
and (II) obtained by means of hydration of the corresponding
2-methyl-l-othinyl cyolohexanols (III) and (IV) (Ref 2)%
Card 1/3

Optical Investigation of Cis- and Trans-2-Methyl-
sov/62-58-11-20/26
-1-Aoetyl Cyolohexanol Conformations
CH3
C~CH
OH
CH3 0 ais- 0
melting point 56-57
HCamCH CH3
KOH
0=5H
OH
Cf
Card 2/3 (IV) trans-
CH,
.of
COCH3
H 20,HgSO 4 R
0
H2 so4 (1) cis-
melting Point 37-380
HP,HgS0,
R s0
2 4
CH3
COCH
3
OH
(II) trans-

Optical Investigation of Cis- and Trans-2-Methyl-
SOV162--58-11-20126
-1-Acetyl Cyolohexanol Conformations
1.,Ysical properties of 2-methyl-l-acetyl oyclohexanole (1) and
(I~j are given in the table. It-was ascertained that 2-methyl-
-1-acetyl cyolohexanol In the cis-configuration exists
predominant-
ly in the conformation "ae", whereas in the trans-configuratiDn
it
exists in form of an'leell-oonformation. There are 2 figures, I
t%ble,
and 5 references, 3 of which are Soviet.
ASSOCIATION: Institut goryuchikh iskopayemykh Akademii nauk SSSR
(Institv.te of Mineral Fuels of the Academy of Sciences USSR)
Institut organicheskoy khimii im.N.D.Zolinskogo Akademii naak
SSSR
(Institute of 0 anio Chemistry imeni V.D.Zelinakiy oZ the Academy
of Sciences USSR
SUBMITTED: April 8, 1958
Card 3/3

5W

AUTHORSr-
Batuyqv, 1A.I., Matveyeva, A.D. SOV/62-58-11-21/26
fITLE:
Spectrum o e ination Scattering of Light by Hexachloro

Butadiene (Spektr kombinatsionnogo rasseyaniya eveta
geksakhlor-

butadj*ow)
PFJUODICAL:
Izvestiya Akademii nauk SSSR.
Otdeleniye khimicheakikh nauk,1958,

Nr 11, pp 1393 - 1395
(USSR)
ABSTBACT:
In this brief report the authors described the
influence exerted

by the conjugation of double bovda in
hexachloro butadiene upon

different aspects of the structure
of this molecule. When in-

vestigating hydrocarbon molecules
with multiple bonds, usually

the CC bonds in ethane, ethylene
and acetylene 3re assumea as

standards. The convential unit
for the length of the CC bonds is

1,2 or 3 respectively (Ref
3). The length of the CC bonds of

higher order is shortened
and the frequencies of their osciILations

as well as theenergy
are increased Nable 1). Since the multiple

bonds are
characteristic the mentionod mutual changes of their

parameters are a regular phenomenon. On account of these re-

larities conclusions can be drawn on other unknown parameters
C
rd 11
rRaf 7). Although the mentioned phenomena relate to
the-systems
a
3

Spectrum of the Combination Scattering of Light by
SOV/62-58-11-21/26
Hexaohloro Butediene
C12=*l)-(Cl)C=CCl,, Cl-C-=C-CMC-Cl, of which the C=C
and C----C bonds are charaoteriatic, with respect to these
natural-
ly hexachloro ethane (013C --eel3), tetrachloro ethylene (Cy=cm
2)
and diohloro acetyl ono (CICULCCl) should be assumed as
standards.
At present not all data on the parameters of the CC bonds in
these
compounds are available. Available dRta on the GO bonds of hexa-
ohloro ethane and tetrachloro ethylene are given (Table 2). It
has been ascertained that the conjuistion of two double bonds in
hexachl-oro butsdiens leads to a shortening in the length of the
0-0 and 0=0 bonds, i.9. to a certain contraction of the whole
molecule. There are I figure, 2 tables, and 7 references, 3 of
which are Soviet.
ASSOCIATIONs Inatitut goryuohikh iskopayemykh Akademii nauk SSSR
(Institute of Mineral FUels of the Academy of Sciences,USSR)
Card 2/3

AUTHOR: Batuyev, M. I. SOV/79-28-1o-0/6o
TITLE: In the Order of Discussion (V poryadke diskussii) On the
Linkage Arrangement in Butadiene and Its Twofold Reactivity
(0 sopryazhanii v butadiyene i yego dvoystvennoy reaktaionnoy
sposobnosti)
PERIODICALz Zhurnal obshchey khimii, 1958, Vol 28, Nr 10, pp
2903-2907
(TJSSR)
ABSTRACT: A prevalent chemical theory explains the twofold
reactivity
of theTT-conjugated systems by the mesomeric structure of the
molecules themselves, outside the reaction, as well as by the
intermediary carbonium ions formed in the course of the
reaction. According to this theory, the m(,lecule of
butadiene-1,3, as a consequence of the mesomeric effect (the
effect of the static linkage), can no longer be represented
by the classical structure formula (I), but can only be
r,~presented by the formulae of the types (II), (III), (IV)
~;H2~CH-CH~CH2 P CH2-CH-CH-CH2 " CH2'C-CH'=CH2
M (11)
C-CC'2-C-;0' C=aC%:=C-----0
Card 1/3 " ( il il (IV)

In the Order of Discussion. SOV/79-28-10-6o/6o
On the Linkage Arrangement in Butadiene and it-,: Niofold
Reactivity
The adherents of this theory tried to substantiate it by
direct physical experiments; however, after a detailed
study of the experimental material available, the authors
are of the opinion that this view can no longer correspond
to facts. After extensive experimental investigations
described in the paper under consideration, and from the
theoretical considerations based on these investigations,
they arrive at the conclusion that the systems investigated
by them (butadiene-iO, diacetylene, hexachloro butadiene)
do not contain any of the mesomerie structures with balanced
compounds as proposed in the above-mentioned theory, and thatt
in particular, their bonds are not extended. The firstreaction
stage, the polarization of the agent and the attachement of
its cation to the end of the molecule, is explained by the
increased electron density of the methylene groups of
butadione-1,3. The twofold reactivity of butadiene-1,3 is
realized at the second reaction stage and is ultimately
conditioned by the separate spatial presence of the
structurally different Ions (VIII) and (IX) which merge
Card 2/3 tantomerically.There are 31 references, 21 of which
are Soviet.

In the Order of Discussion. SOVP, 9-28-10-60/60
On the Linkage Arrangement in Butadione and T.4,'G IVofold
Reactivity
ASSOCIATION: Institut goryuchikh iskopayemykh Akademii nauk SSSR
(Institute of Kinersl* Fuels of the Academy of
SoiencestUSSR)
SUBMITTED: January 22, 1957
Card 3/3

AUTHOR: Batuyev, M. I. SOV/79-28-11-55/55
TITLE: (V poryadke diskussii)
On the Problem of Conjugation in Benzene (K voprosu 0
sopryazhenii v benzole)
PERIODICAL: Zhurnaj-obshchey khimii, 19%, Vol 28, Nr 11, PP
3147-3154
(USSR),
ABSTRA.CT: 90 years have passed since the introduction of
4e.benzene
formula CH-CH-CH
I A
CH-CH-CH
by A. M. Butlerov. A great number of benzene formulae have
been suggested since then. The formula given by Butlerov
based on the ideasof Kekule' on the structure of the aromatic
nucleus is, however, time and again meniioned to be the one
closest to reality (Refs 8-10). Ingold (Ingolld - Ref 11)
showed in his representation of the resonance-melsomeric
theory
of the chemical binding that if only chemical facts are taken
into account the formula by Kekul4 ( i.e. Butierov-Kekule',
M. Baluyev) is doubtlessly the beat. On the basis of this
Card 1/3 theory developed by Ingold and other scientists
from this

A Topic of Dismosice SOV/79-28-11-55/55
On the Problem of Conjugation in Benzene
formula deductively and automatically (Refs 11-13) the basic
physical properties of benzene are predicted which contradict
the formula by Butlerav-Kekuldq and can directly explain the
symmetry of benzene only by a plane regular hexagon (-D 6h).
The authors of this prediction resort to physical experimental
experiments, however, in the thirties, the physical experiment
was not sufficiently developed with respect to the individual
bonds in the molecule specifically to be determined, so that
wrong conclusions were drawn. The author shows that on the
basis of the most important physical and chemical results
mentioned in a large number and obtained in recent times the
mentioned ideas of the benzene structure by Butlerov and
Kekul4 can no longer be advocated. Thus, the experimental
resulta obtained hitherto do not at all prove the symmetry
of the benzene molecule D6k. On the contrary they tend to
favor the Butlerov-Kekule' formula, i.e. a nucleus with three
conjugated somewhat lengthened double bonds and three shorten-
ed single bonds in the nucleus, with the benzene molecule
Card 2/3 being characterized only approximately by the
symmetry D 3h.

A To]dc of Discussion- SOV/79-28-11-55/55
-On the Problem of Conjugation in Benzene
There are 2 tables and 40 references, 15 of which are
Soviet.
ASSOCIATION: Institut goryuchikh iskopa,remykh Akademii
nauk SSSR
(Institute of Mineral Fuels of the AcadeW of Sciences
USSR)
SUBMITTED: June 2p 1957
Card 3/3 USCOMpWa6003

SOV/20-120-4-25/67
AUTHORS: Akhrem, A. A., Matveyevn# A. D.,
V91 Nazarovt lo Not Member, Academy of
scienoeav USSR (Deceased)
TITLEs Optical Investigatioii of the Conformations of Some Gem-Sub-
stituted Cyclohexanes (Opticheskoye issledovaniye konfor-
matsiy nekotorykh gem-zameshchennykh tsiklogeksanov)
PERIODICAL: Doklady Akademii nauk SSSR9 1958, Vol- 12o, Nr 4, Ppe
779-782
(USSR)
ABSTRACT: The physical properties and the reactivity of the
functional
group depend on its position and conformation. The position
can be axial or equatorial. TAiE can sometimes be determined
chemioally but frequently only by means of physical methods
(Refs 1, 2). The authors deal with the optical determination
of the conformation of epimeric 2-methyl-i-ethinyl cyclo-
.hexanoles (I), (II)q furthermorep with that of 1,2-dimethyl
cyclohexanoles (III), (IV) which they had already earlier
synthetized (Ref 3)1 the method is described in short and a
swey of publications is given (Refs 3, 4). Formerly the
Card 114 acetylene alcohols (I) and (II) were traced back by the

SOV/20-120-4-25/67
Optical Investigation of the Conformations of Some Gem-Substituted
Cyclo-
hexanes
authors to the well known pair of cis- and trans-carbinoles
(III) and (IV) without touching the asymmetric center (Ref 3).
The physical properties of' the produced compounds M - (IV)
are shown in table 1. Tte spectra of the combination light
dispersion in the liquid phase were taken on the apectro-
gram ISP -51 of a mercury lamp having a chamber of the ex.
citinb bxue line of 4558 R. The numerical results of these
measurements are given together with data on the Intensity
of the lines, Purthermore, spectra were taken of 10 % solu-
tions of the first 2 substances in carbon tetrachloride.
The presence of the 2 isomers I and II and of their solu-
tions in CC1 in the spectra in the range of 3 - 4 (instead
of only one)4oharacteristic frequencies of other weak lines
(Table 2) tends to show, that other conformations are present
in small numbers (possibly even in bath-tub shape) in the
mixture where conformations prevail. The prevailing conforma-
tion in the cis-isomer (I) is 11aell (according to Ref 1) where-
as in the transtisomer it is "eel' (see scheme). In the ae-con-
formation the influence of the cycle on the hydroxyl group
in the equatorial posi.~.ion is more intensive than in "ee"v
Card 2/4 where it is in axial position. In the ae-conformation the

SOV/20-120-4-25/67
Optical Inveatigation of the Conformations of Some
Gem-Sul-stituted. Cyolo-
hexanes
hydroxyl group is more protonized than the axial group in
"so". On the other hand the bindings CF~-- , 0----C in -C!~~H.
in the equatorial position which they take in the "eel' con-
formation are more amply supplied with electrons. That meane
they have higher oscillation frequenciesp binding energies
and a shorter interatomic distance than they would have in
an axial position in an "as" conformation (Refs 1, 6). The
interaction between reactivity and conformation in the series
of cyclohexane derivatives was already at an earlier time
observed by the authors. (Ref 7). Cie-a-ketole (V) which
was obtained from an equatorial aoidous hydroxyl can be
aoylated under milder conditions than trans-a-ketole (VI)
which was produced from (II) with the hydroxyl being in an
axial position. There are 2 tables and 7 referenceag 4 of
which are Soviet.
Card 3/4

BOV/20-120-4-25/67
Optical Investigation of the Conformations of Some Gem-Substituted
Cyclo-
hexanes
ASSOCTATION: Institut organicheskoy khimii Akademii nauk SSSR
(Institute of Organic Chemistry AS USSR).
Inatitut goryuchikh Iskoravemvkb Akademii nauk SSSR
(Institute of Mineral Fuels AS rqsR)
SUBMITTED: February 139 1958
1. Cyclohexanes--Optical analysis 2. Cyclohexanes--Physical
properties 3. Substitution reactlion,~i 4. Hydroxyl radica2s
--Chemical effects
Card 4/4

A;S-THORS:
~-Batuyev, M. I., Akhrem, A. A., SOV/62-59-3-31/37
'

iimei ~Wfr,-r. V., Matveyeva, A. D.
TITLE:
Optical
Investigation of the ConformEtimsofthe Cis- and

Trans-=ethyl
Esters of 3-Methyl Cyclohexanol Carboxylic Acids

(Opticheskoye
issledovaniye konformatsiy tsis- i'trans-metil-

ovykh efirov
3-metilteiklogeksanolkarbonovykh kislot)
PERIODICAL:
Izvestiya
Akademii n'auk SSSR. Otdeleniye khimicheskikh-nauki

1959, Nr
3, pp, 556-558 (USSR)
ABSTRACT:
This is a brief communication
on the investigation of the cis-

and trans-methyl asters of
3-methyl cyclohexanol. carboxylic.

acids which were
synthesized according to the scheme described

in reference 1.
The physical properties of the products ob-

tained are given
in the table. It is known that the Auers-Skit

i-
formula for the oid- and trans-configurationsofl,3-disubst

'
tuted oyclohexanes may be applied in the reversible form.

The
same holds also for the esters investigaed: the ois-

compound
has a lower density and a smaller r;fraction index

than the
trans-compound. The Raman spectra of the eaters were

recorded
in the liquid phase by means of the ISP-51 spectro-
Card 1/2
graph with a medium camera of the exciting line 4358 of the

Or.*,ical Investigation of the Conformations of the
SOV162-59-3-31137
Cis- and Trans-methyl Eaters of 3-Methyl Cyclohexanol
Carboxylic Acids
quartz lamp. The eis- and trans-methyl esters of 3-methyl
cyclohexanol carboxylic acids investigated are mixtures of
reversible isomers 1e3e-'W-1a3a and 1e3a=,"1a3e- In the
second
conformation 1e3a mainly the first 1e3e is present. Moreovert
in each of these mixtures admixtures of one conformation are
contained in the other. There are 1 table and 3 references#
1 of which is Soviet.
ASSOCIATION: Institut goryuchikb iskopayemykh Akademii nauk
SSSR (Institute
of Mineral Fuel of the Academy of Sciencesp USSR). Institut
organicheakoy khimii im. N. D. Zelinskogo Akademii nauk SSSR
(Institute of Organic Chemistry imeni N. D. Zelinskiy of the
Academy of Sciences, USSR)
July 30, 1958

5M SOY/62-59-8-26/42
AUTHORSs B&tuYOv, M- Ift MOshcheryakovt A. P,t Matveyeva, A. D,
TITLE:
Raman Spectra of Divinyl Acetylene
PERIODICALs
Izvestiya
Akademii nauk SSSR. Otdele~iye khimicheskikh nauk,

1959, Nr so,
pp 1485-1487 (USSR)
ABSTRACTs
The spectra were photographed by me
ns of the spectrograph of the

type ISP-51 with the Hg line (4358
1). The individual lines

obtained for the compound CH 2 -
CH-C=C-CH-CH 2 are given. Within

the range of the triple bond two
basic fre.quenoies (intensive

doublet) were obtained at 2165 and
2206 cm7l
and four

,

frequencies in the range of the double bonds (intensive
doublet)t

at 1586t 1601 om-1, and two weaker lines at 1629 cm-l'
The

appearance of the doublet is due to the possibility oi the

existence of rotatoryisomers. The splitting-up of the

frequencies
of the double bonds is interpreted as the splitting

of the
frequency of the bond oscillations of two identical dorble

bonds
in each of the two possible isomers. The great number of

lines
(44 as against 30 in the case of one form only) is
Card 1/3
considered to point to the probable existence of both isomers#

Raman Spectra of Divinyl Acetylene sov/62-59-8-26/42
The multiple bonds mustt according to the energy minimum of the
bond system, lie in one plane. On this condition the two isomers
(the ois (I) and trans forms (II)) are possible. The authors
continue by attributing the several lines obtained to the two
isomers by means of comparing them with the infrared speotrum.
The lines are also interpreted as resulting from the mutual
Influence of double bond - triple bond and double bond - double
bond. A table lists the frequencies of the oscillations of the
individual bond types. It follows that'the triple bond in (I)
with a high eleotron density corresponds to a pair of double
bonds with a reduced electron donsityg while the triple bond in
(II) with a reduced eleotr,n density corresponds to a pair of
double bonds with a high electron density. The electron shells
of.
the C atoms of the triple bond in W are more asymmetrical than
in (II) so that there is a greater influence of this bond ui3orL
the double bonds in (I) than there is in (II). In the liquid
Card 2/3

Raman Spectra of Divinyl Acetylene SOV/62-59-8-26/42
phase both isomeric forms are encountered; how-ever, thex* is a
marked preponderance of the trans form. There are I table and
9 references, 4 of whioh are Soviet.
ASSOCIATION: Institut goryuchikh iskopayemykh Institut
organicheskoy
khimii iiu. N. D, Zelinskogo Akademii nauk SSSR Institute of
Mineral Fuels; Institute of Organic Chemistry imeni
N.D. Zelinskiy of the Academy of Sciences, USSR)
SUBMITTED: January 21, 1959
Card 3/3

5W
SOV/62-59-5-25/40
AUTHORS:
Batuy2v -M. la Akhrem, A, A.p Matveyeva,,
A. D.
TITLEs
Optical Investigation of Equatorial and Axial Carbonyl
Groups of

Some Substituted Oyolohexanes
PER ODICAL:
Izvestiya Akademii
nauk SSSR. Otdeleniye khimicheskikh nauk,

1959, Nr 9, pp 1665-1668
(USSR)
ABSTRACT:
The Raman spectra of the following compounds in the
liquid phase,,

taken by means of the ISP-51 spectrograph and the E-612
Hilger

spectrograph.are investigated: - _Ac,otoxy-cyclohexano (I)9
acetyl-,-.,-

oya bx.
aoet v-~1-acetyloycloheirahs II)i

6iy.~1-s&.tyicj6lohex"6
(N)O',amd.trans-~2

M (V).' The phys al data of the

compoundsare given
in the'table. The frequencies obtained are

i en in' ALN) The
configuration of the compounds (IV) and

was do termined from the
results of special analysis. Taking

the largest substituent as basisp
the conformation of (IV) was

found to be trans-ee and trans-aa, that
of (V) cis-ae and cis-ea,-
Card 1A

Optical investigation of Equatorial and Axial Carbonyl
SOV162-59-9-25140
Gr&ups of Some Substituted Cyclohexanes
The amounts of these isomers were found to be fairly equal in
both cases, as was aleo the case for-the two possible
conformations of compound (III), of which equal amounts are
formed. There are'4,tables and 2 Soviet references.
Institut goryuchikb iskopayerAykh Akademii nauk SSSR (Institute
for Combustible Mineral Resources of the Academy of Sciences,
USSR). Institut organiobeskoy khimii im. N. D. Zelinskogo Akad6mi*.
nauk SSSR (Institute of Organic Chemistry imeni N.D. Zelinskiy
of the Academy of Sciences, USSR)
January 21, 1959

50), SOV/62-59-9-26/40
AUT110RSs Batuyevt M.I-,, Akhrems A. A.p Kamernitskiy, A. V.,
Iffatveyeva, A. D.
TITLE-. Optical Investigation of the Conformations of Cis and
Trans-113-dimethyloyclohexanols
PERIODICALs Izvestiya Akademii naukMSR. Otdeleniye kbimioheskikh nauko
19599 Nr 9, pp 1668 1670 (USSR)
ABSTRACT: A reaction scheme for the synthesis of the substances
investigated,
M 0" and (n) 0" is given from a previous paper.
CH CH
3 3
The Auer-Skit transformation rule is valid for compounds (I) and
(II)(Table.). The Raman spectra of the compounds were taken in the
liquid phase and in carbon_,tetrachl-L,_---_4de solution. From-the
data:
obtained, the following.conclusions were drawn: The alcohols form
intermolecular hydrogen bonds in solution (bands split UP imto''.
Card 1/3 lines in the3160-3530 om" range). These hydrogen bonds do not

Optical Investigation of the Conformations of SOV.,/62-59-9-26,/40
Cis and Trans-1,3-dime*.hyloyclohexanols
stem from the hydroxyl group. In the liquid phase complexe:sare
formed by hydrogen bonding of the OH_grotip (continuous:bands in the.:
3600 and 3614 oi-I region)o The hydroxyl groups generally have a
similar position (equatorial) in the associated complex, Thus# in-
(I) their position is ois--la3a and in (II trans-la3e. Their
position was determined at cis-is3e in (18 and trans-la3e and
trans-103a in (II) (equatorial and 6quatorial-axial), relative-
to the OR -group outside the hydrogen bond as the largest
substituaRt. If one disieg'ards the nomenclature of these
configurations and conformations by reason of their formation,
and regards solely their real structure,, deduced from their
physical properties, as~well as taking into account the
transformation rule by-Barton and Hassel (the configuration is
determined by the position of the largest substituent),oxv.; would
have toredefine the cis-ls3a conformation of (I), the form
predominant in 69sociated molecules, of (I)9 and also the
Card 2/3

Optical Investigation of the Conformations of SOV162-59-9-26140
Cie and Trans-193-dimethyloyclohexanolo
trans-la3e conformation of (II). The nomenclature of these
conformations would then be trant-le3a and cis-le3a
respectively. There are 1 table and .7 Soviet references.
ASSOCIATIORt Institut goryuchikh iskopayemykh Akademii nauk SSSR
(institute for Combustible Mineral Resources of the Academy of
Sciences, 'USSR). Institut organicheskoy khimii im. N. D. Zelinskogo
Akademii nauk SSSR (Institute of Organic Chemistry imeni
X. D. ZelinBkiy,of the Acadeny of Sciences, USSR)
SUBMITTED: January 21, 1959

5.3700 77085
SOV/162-59-12-29/43
AUTHORS: Batuj2ya~~, Ponomarenko, V, A., Matveyeva,
11r." .. Vzenkova, 0. Ya.
TITLE: Optical Investigation of Alkylgermanium Chlorides in
Connection With Some Peculiarities of Their Chemical
Behavior
PERIODICAL: Izvestiya kkademii nauk SSSR. Otdeleniye
kh:Lnicheskikh
nauk, 1959s Nr 12, pp 2226-2233 (USSR)
ABSTRACT: Several studies of similar content were published b
the
authors previously (Zh. obahch. khimil, 1956, Vol 29,
p 2336; this journal, 1956, p 1070; ibid., 1957, P 515;
ibid., 1958, p 996). The authors showed that many
chemical characteristics distinguishing organosilicon
compounds from carbon compounds are also present, and
even more pronounced, in organogermanium compounds (this
journal, 1956, p 1146; ibid., 1957, Nr 8, p 994; ibtd.,
Nr 2, P 199; Dokl. AN SSSR, 1954, Vol 94,.p 485; this
journal,1957, Nr 3, P 310). Methyltrichlorogermane
Card 1/6 and methyltrichlorosilane, unlike
ethyltrichlorogermane

Optical Invest~3ation of Alkylgermanium 77085
Chlorides in Connection With Some
Peculiarities of Their Chemical Behavior
and ethyltrichlorosilene, could not be chlorinated
with sulfuryl chloride. Ethyltrichloro-compounds
of both germanium and silicone were easily chlorinated
but the R- directing'effect of the GeCl 3-group was
considerably stronger than that of the SiCl 3-group-
Chlorination of CH 3GeCl 3' (CH 3)2GeC'2, and similar
compounds to di- and trichlorides proceeded more rapidly
than the chlorination cfthe corresponding silicon com-
pounds. The yield of germanium monochlorides was
lower than that of the corresponding silicon compounds.
Dehydrochlorination of Cl 3GeCH2CH 2Cl with quinoline
yielded Cl 3GeCH=CH 2 as main product, and also GeC14,
whereas practically no SlC14 was obtained on dehydro~..-..
chlorination of Cl 3SiCH2 CH2Cl. This can be explained
by an easier )O-elimination in )q- chloroethyltrichloro-
Card 2/6 germane than in )a-chloroethyltrichlorosilane. These

Optical Investigation of Alky2germanium 77085
Chlorides in Connection With Some sov/6-2-59-12-29/43
Peculiarities of Their Chemical Behavior
peculiarities of the chemical behavior of Ge are due
in the first place to its physicochemical properties;
some of these were optically investigated by the
authors (this journal, 1956, p 1243). The present
study deals with investigation,of the vibrational fre-
quencies of C-H bonds in methylene and methyl groups
of tetraethylgermanej and ethyl-, methyl-, chloroethyl-
and chloromethylgermanium as compared with vibrational
frequencies of the corresponding silicon compounds and
normal paraffins. Spectrograph ISP-51 was used in the
study, and Raman of 11 germanium compounds were
investigated. A po ~.J,'Jo explanation for the behavior
of Ge and Si-compoundL. %~- advanced. In chlorination
of CH3CH2GeC1 3-P the electrophilic Cl-atoms of S02CI2 should
be apparently Airected toward electronegative C-H bonds
at atoms adjacent to the germanium atom. However, Ge
has a larger electron dhell than Si; also., the.negative
pole of the CH3CH2GeCl 3 molecule is concentrated in the
Card 3/6~ region of Cl-atoms. These factors do not allow the

Optical Investigation of Alkylgermanium 77085
Chlorides in Connection With Some SOV/62-59-12-29/43
Peculiarities of Their Chemical Behavior
other, more negative, end of S02C12 molecule to
approach the region of the!methylene C-H bonds; the
mclecule moves away from the methylene bond region
toward the methyl group, and the chlorination proceeds
in the a-position to a much greater extent than in
the chlbrination of CH CH SiCl The ratio of Ct to
)a isomers in the chlo~in3tioP~f CH 3CH2Ge C13 with
sulfuryl chloride in presence of benzoyl peroxide
was 1:9, whereas in chlorination of CH3CH2SiCl3 this
ratio was only 1:2.5. It is also evident that the
deflection of the SO V12 molecule from the methyl
2^
group adjacent directly to Ge-atom In CH 3 GeCl3due to
the above factors hinders the chlorination of this
compound, The Raman spectrum of a -chloroethvltrichloro-
ermane showed a considerably higFier number of lines
15 lines inore) than the number expected theoretically,
1
and-a twofold increase of t1ie vibrational frequency
Card 4/6 of methylene C-H bonds. This indicated the possible

optical Investigation'of Alkylgermanium 77085
Chlorides in Connection With Some SOV/62-59-12-29/43
Peculiarities of Their Chemical Behavior
existence of the above compound in two isomeric forms:
Cl-AGe-CH2 C13Ge-CH2
61-CH2 CH2-Cl
(cis) (trans)
Intramolecular interaction Ge .... CI in the cis-
isomer can promote R-elimination:
C13Ge-CH2
CH2~ CH2 + QeC14
CI-CH2
The formation of GeC14 on dehydrOchlorination of
chloroethyltrichlorogermane with quinoline can
thus be explained. There are 8 tables; and
Card 5/6

Optical Investigation of Alkylgermanium 77085
Chlorides in Connection With Some sov/62-59-12-29/43
Peculiarities of Their Chemical Behavior
14 references, I U.S., 2 U.K., 11 Soviet.
The U.S. and U.K. references are: C. L. Agre,
W. Hilling, J. Amer. Chem. SOC., 74, 3895 (1952);
N. V. Sidgwick, The Chemical Elements and
Their Compounds, Vol 1, Oxford, 1950; W.
Cresswell, J. Leicester, A. Vogel, Chem. and
Industry, 1953 19; same authors;, J. Chem.
Soc -, 1952, 514.
ASSOCIATION: Institute of Mined Fuels, Academy of Sciences,
USSR (Institut goryuchikh iskopayemykh Akademii
nauk SSSR)
SUBMITTED: February 1.5, 1958
card 6/6