SCIENTIFIC ABSTRACT BERGMAN, A.O. - BERGMAN, A.G.

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CIA-RDP86-00513R000204910019-5
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December 31, 1967
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- . -d I - - - - - -,- titisium and t~~ditm T, thlarid--i Rp of ~hict L, thr T. I - - . -, I I . TP - - .4 ~ ~z -,R -a--,- ,-, J .- - ~ ~ _1-1. rn rl~ - ~ - - , v -I - T,- . ~- -- ~,- - T - --- -- ~ -- ----~-;-- -- - ---- ---- -- - - --- . ---- -- - -- - --- and suUate S. L~m~kh and A a n Ck."l- 45-Min"', ~'ft ~ C.4. 40 A USSR I/ _-u in.vawlb ~-r"ctin-Fsys~~m -aU Lmiscib ty a~ tbzi*; sullatca nbam. 13z jugman. J. -rn. j see 4s 1! r. USSR/Chem'stry Lithium Salts; Jun 53 Cobalt Salts "Mutual Systera Composed of the Sulfates and Chlo- rides of Lithium and Cobalt," D.S. Lesnykh, A.G. tergman, Rostov-~on-Don State U im V.M. Molotov Zhur Cbshch Xhim, Vol 23, No 6, pp 894-901 Investigated the thermochemieal relationships in the mutual ternary system composed of the-Valts Li C12 f CoSO4_+ CoC12 4 Li2SO4. Found that this 2 system consists of 2 ternary systems: CoCI2-LqO4- 273T24 Li2C12 vith atriple eutectic point at 452 0 and 'Cocl Li SO CoSO vith a triple eutectic 2 - 2 4 4 point at 5070. 27=4 BREW, A.G.; SHOLON30VICH, X.Ie. Reciprocal.system of the adiagonal-zonal eutetic type, composed of mets'- phosphates and sulfate* of lithium and potassium. Zhur.ob.khim. 23 no-7. 1075-1085 JI '53, (KLRk 6:7) 1. Rostovskiy Goeudaretvem*7 univesitet imeni Molotova. (Watems (Chemistry)) (Phosphates) (Stilfatea) BZRGW, A.G.; KISLOVA* A.I.; POMAYNO, V.I. Complex formation and metathesis iu ternary systems of tha- sulfates, tungstates and metaborates of lithium and potassium. Doklady Akad. Nauk S.S.S.R. 88. 815-18 '53. (MLRA 6:2) (CA 47 no.22:12090 153) bLve and A. C.. Btr9m". DA!~Jy Aked. X~.I 89, -md, 33 inner Pwiouv =V given for the rrcnnIw-A K, ColIC1. SO,. AnhydrolLainite is not lomtd. K;-50- C.SO" R4504-CbSO.. CoUI,2KICI, -,i CpClj.KC] exhi. Tnei-e z3 A tcm=ry licterosalf (pmte X. ~-hqse mmpn. was uot ftacl-ly dell. and a o,,pple3 i; iumr, th W6 !*lid smte in the hinarv s"im of K,50, IpbA-.e V). StImig cmaplel laf-wIlml is be mtem. The full dlagmm lndicatt~ e~,w-c- o! a eutecilca end 5 truntlomuidmi polats Cm rvaro,, w~f icit3 the cation complexes art In."re stahk tllwrl 1-11C *M,t~-- 1prit typm, in distipetion t~- 'he ~-pondmr 7TI -,~ Mi unauctivity W the d1gonit) crrss-2s,,clion al fer-Ld te. nadir reciproxnJ L. 1. Ak-' 3 ". ~i-uk AgA.---nn5L). Cir-AgiSC), iii i lit firliid p4liamr itt tht- sy-simi, 1~;, and the mv.-4ble tccti,,n 11- Tt-Ut MMY I 111-d bY 2 *IT V`V if PJIMT (C - 47, 2YYMN)~ J,oitharaal cun~- -..i the rovi!, IvT L~c Stable sntion r'r.'p !rL-11 thc more M'.1flort-g- Ag-ab to the Ims cardneting Tl,,A),. sirvillar to tl~e isottitim.4 01 the -,p rrxnd. fur t1ir to tire tonnatica of 11,50, ;wl cand. Which ce-yrtzpUnds la the 1,xmulion (if 11-eU, i., )v than the min. zond. of In the It--d of the -v-!:tms thi cquilibriom ii w-pia,cc! it, thr si,)blr Pail vI 331o of in tire Ir2b simil.t.r IQ idt-it birwy vptrms. lit the 111L~C c" inr.~d -Ulf, in ivbleb cichu;iKc -c clicm of rfmnpl~j fomi-;t t,!-t A ol: Uw/Grlhemls PhysicAll-che stry- cara 1/1 Pub. 147 1?/21 Autbars Bergman, A. G.; Xislova, A. I.; and Posypayko, V. I. About complex-formation in 6 mutual tetra-system consisting of Li, -7Y,;Jcl,, so 'WO4 P&Iodicsl i Zhur. fiz. khim. $,.1489-1496, Aug 1954 -Abstract s- order the stability- of compleX U-1104 and LiSO4. z 'Ki'04 X2SO!, comp=ds in the composition of a mutual tetra U, KIIG1, S042 WOt gystem, the authors irrvest-igated the "interior" of the composition pr sm of this system by means of three book-leaf type and five tri- angular cross sections. It was established that the liquidus surface of the system conBi5t3 Of six basic crystallization fieldstwo of which occupy areas of 10.04 and 21.e1. and the remaining four - the fields of nure components. The internal structure of the investigated c-znposiion- prism of the tetra system, is described. Fivo references: 4-USSR and 1-German (1907-1953). Tables; diagrams. Institution The Agricultural Institute, Krasnodar Submitted February 2, 1954 YNVSZMA, N.N.; AMMO, A.Ge Formation of hoterolonlo compounds in the reciprocal system of po- taselum and zinc chlorides and sulfat-se. Izv.Sekt. f iz. -khIm. anal. 24:162-191 '54; (MLRA 8:4) 1, Institut, obahchey i worganichaskoy khimii im. N.S.Kurnakova Akademli mi SSSB,; (Potassium salts) (Zinc salts) IMRGMN, A,G,; KHITWV, V9A* *ft-- -- I -- Irroveroible-reciprocal system Of POtSABium and sodium chromates and hydroxides* Itv&Sekt.fizvktdm.&rAl. 24:z04-zli '54. (MM NO 1; Voronazhokly gosudarstvenW pedegogicheskiy institut, (Potassium) (Sodium) -7 t. t 1~ a! ...... 1,r,4 Gulf - 4!.4- IN npv i,~27 Formatlon of "mPleres of the anionk tn* between phosphates and OXYM Wta DEER. US '4 "L .S R tm mO,-- (m Aal-, Lm%AV==,-~P A--C--Bxzgmaz Ahwvich~ ml!~Iil ~B-. W, ~"V gm tra C-4. 49, H. L IuMur~ di:14TAM !,.T th~ &rid 1~,' i.--- IRE XX -, . . - , I . . 1. ~ - ;.: . . . 1- 1- . -1 -1-11 .. -.. I - I I I '~ a - -. Eg= =- r~--_ = CQ-= 1 k u IIE - - ',-V " ~Flz. - . lj.~. ; M " - - ,. - i 0 = F ~ ---= !~, , ;- F AXOPOTP YODKO; Interrelations of lithium. sodium, and potassium sulfates in melts. Zhur.-ob.khlm. 24 no.9-.1512-1523 2 54. (MLRA 7.*12) 1. Rost ovskiy-na-Donu GosudarstvenW universitet i Kubanskiy sel'sko- khozyeystyenMy institut. (Silfates) (Systems (Chemistry)) USPI /Chemistz7 CRrd 1/1 2 Pub 151 -8/42 Autbors I Akopcv., E. K., and Bergman, As G* Title A ReversiblyRdiagonal, sodium-and Ntassiiwi chloride and sulfat-I 3yetem Ztiur. ob. khim, 24/9, 1324-1~32, Sep 1954 2 The chemical and stmetural properties of the Na., K1101, SO system, which is a reversibly-adiagona'l mutual system with conditional themal interchange reaction --ffect and triangulation emanating from the com.- positional pole of the 2Na-SO4 # K2SO compouznd, are described. The existence of one tenary e etic point and two transition points was Ute established at 514P. The triangulation square of the reciprocal sys- t,,-m is divided into three triangle phases. The structural diag."=t, made up of thrae basic crystallization fields, is described. references: 6-USSR and 1-German (1905-1954). Tables; diagr3ms. Institution State-Universitly.-Rostov/Don SubmLitted August 31, 1953 Tetra-systeems 7)S5R/Chemistry Card Vl Pabo.151 - 5/37 Authors, I Berg=,, A~ G. Xisl*a, ~A. I.; and Posypayko, V. I* Tiltie i Double decomqposition in the absence of the solvent, Part 2#- Tetra-system consisting of-lithium and potassi= chlorides, milfatee -_%nd turkczstates Periodical Zhur, ob. khim. 24/10, 1722-1730, Oct 1954 Abstract Five Internal triangular sections in a composition-prism wera investigated by inlw-tba-ftman __+ hins! crystal- _r is di~; --fo -of4 dral iwli rw jwism~ 0A sition afA locations -of -tatra-euttotic points of the system, -The resulto 0 P obtained are described in detail. The dentritic form of crystallization of a tetra Li K system -has determinod. Three US&R references RC" S041 "*'o (1936-19541. .-ables; j~ra -'drawings. Thstitution The Agricultural'Institlite., Kuban Subuitted t February 17,1954 2'M --~g uv ;t C-i am) I-IAA~ O~ 14"'1 old 41 21A tbal of ).!0 all't EX-30". L tt~-E-aill The recip:CCA) system of chlotld*s And I leuLUWiw~ end nad. a C, I'm-ri ~i ut~ ~Ovs Qr sq- me r~ripn-; ystcm r'-av"l 11" F Ilk BT~ vm , .1 4;(W. -ith TbLrt :,re cr%.W. heh;,. 0 Casi), I -T"' r4 '. !)IC t-)Ml ama, aml ',' rulc-etit, .1 470' laul iliat It is att l;l'!"C!l~t3 (lie clx'~irxmti.~ll on. th- tui~!% of thvrTll;L! 1.5S (cf. llrrx-,n. V~~Jon of c9ustic alkalies with nitratu and 4 -1 1 A! Mod. NarO S.S.S.R. 25, 203-1,00"Al - 4mi -M! lorm3 txn of C =pds. 211,P.011 Y tR d MY onth NaNO,, NaOJ3.N&N% KOH.U.'(~, 14aOH.Nal%K%, and KN0,.KOH by rtactlon of vritb nitratti and ni- trites. These compds. melt cmagruesitly at 272. 2971-5r 238-5. M5. and 177', ri-P Thrv tnight be considered a5 FxJd Wt2 Na.X%ND., NallINO, Na,HN'Oj, and J X.HNIO.. KOH and NaNWor NaOH and KNO.) do not mact with eaCh other but form a se~ir3 of sol:d solos. Vc.- pors of KOH and NaN(V'or KOH and NnNOO ener mt, an "Chan" re3Cti~, 321 --A- ~d KOH, na. 401 :k 1', wtrr obtai ed by action of 1120 vD the I EurWa MByqj~, 41 F 4 Tile di~~ r'! --!I 4 -t .iraz Tcr c! at crys 'I b and mtritea S. X11 7 dnp~llll 'if tilt M-utual iystcm K, N~t,~'\O, NO~ is etudird. ThE7 fith! corrnpmding to co^xpe, NaNr)~.NZNC), extendq 1, Th-'Ligram. Thc field for cnmpd. NaNr~-KNO~ ta tilt Vstem 0! Taitrato Llunc, 0, ~zb IJIN wid th~ tetxlp- ,f r,-r n0c! ;~,,bubly 9 a npresied ~ppmx. by KNO,.K.N0,. An ~,f tri~mgulatian ~t the syste= is gi,-rn. Furilla MAi-lc A:, "nr ---------- :n a mrnua: L~~ L K 'pd 21-t, f ic -t-T lit V Complex formation in a quetemM trOprmal sy-stern G! fchloridea, sulfates ~ a I stat T~ ~tbiltld ~UgJQJWU6 I Va. and ~ 1, . ~-~) ~nlll A-,$ A 4 ~ ,, 'S 14S" ~0' !~,- cf, CA 49, 735,Aa.-T-he fuiwn rx:rve_-_ h'r the -;:em K-1!C71-, SO.-, WO,-- il-uo that -, Li,WO,.K,'tVO, and U.SO,X~90,, are Iarmc,). ,~jcas are ajw)y~Fdin 410w]. I Rtwi-, L~Oi MIN, L7- Fad MMMk. 'WIN, 101W USSR/Physical Chemistry. Thermodynamics, Thermochemistry, B-8 Equilibria, Physical-Chemical Analysis, Phase Transitions. Abff Jour: Ref Zhur-Khimiya, No 5, 1957, 14695 Author : D. S. Lesnykh, A. 0. Bergman Inst : Rostov on The Don7Un_1v-e-r-5-1T-y Title : On The Problem Concerning Stratification in Fused Chlor- ides and Sulfates of Monovalent and Bivalent Metals Orig Pub: Uch. zap. Rost. n/D un-ta, 1954, t. 20. Trudy khim. fak., vyp. 6, 19-31 Abstract: The liquidus graphs of the irreversible reciprocal sysilam Li, Pb // Cl, S04 and of the diagonal sections of the systems Li, Cd // Cl, S04; Li.. Ag // Cl, S04, Li, Ca, Cl // cl, SW~ and Li, Sr // Cl, S04 were studied by the visual-polythermal method. Basing on the obtained data, as well as on data found In the bibliography, the oon- elusion was arrived at that the Stratification In the melted state takes place mainly in systems containing cations with an 8-electron or 2-electron exterior layer, Card 1/2 IN - IRON ~,-. h~- -_-. , - l- - ~- :1,1~ ME -, I - , ; ~ I z I 7Tj snrfa;~t of th~ s3itim atitist, .16 bcId,, TiCI, USO., TW50s. and USOrTISO,, xil -ontains a ronra-iznti winta; rult~tIC'E" M.P. 32-131, LL-!A-%, uith LiO, MCI, and LiSI), at tquil. pha", cute,-; tic E'. ra v. ='~ 06% TLCI,, 35,', 3l%ThSf%,. with: fiCI, FIL6Z L4SO.-T4SO. as rquiL tmnsitioul :p~lrlt P, m.p. 338*, 68c' 71,C) U St.%, 30% 11"SO"I '416'. 21 ) untli TWI, LiSO., 1.1 TIO). Cquil. plvvW3, T110 aliaguna) 5,-ojwi ~.s the ~Ialllt 5-.Ctloa "I thei sy,Ntmn. -Tht &uble salt noymilly mvjfiBg-,0%4;~t cu!nblil-.t~-dts,wilb,kvomprtl-l-l-1-tll,e-zyt;tmrn, TI)c strall, Ilmjti~a)em is loc2ted obnj the 5okle dtjv,n;i,. and C - -ccupirl -51.7% of the area between 4 and dl~gojlal and covem 2 trysin-field-, LI-S( an. 73jS0,. ne tens ii asym. 111C Fitige ill CrVN atea. low,-Ting bcmnnes volysiti V. N~ wi Tavaralbly rea Mal )I gtom of End ad S. OoNd', A. FP. 0-1 HIP, procal without miplr- foramtion. According to ;ahude WAIho ib-trml tflect (0.47 ",Jx~ equ systm xbvuld be reversible, but tz~ij. dau.--Jr to t)le trwy. 71M 13 also a dixrepivicy between the o1rec- of rxchAnge,reqctF-*--Mft-aud themal -1he KAW to the -11 --C -sy~ bersum-d 3LUDar- .41cl. so, c rwM, chartes,- sbuctr-re of electron layers. I/Termary mutt"d cyfittrl DI cmd potzsSIP . A~ G. L~nllna I Lind A. 1. Kmi,'1.1-4 of 2-, X, and 4-mml,mcni ulixii. of tht in V'a' -y:-,tg propottions are rep-m'-~Itd "y diagtdw of P-m-inn. and a 3quart cmimir--d pr~jrctiow .01 All d!Rgr=; djapD'nmal L-n otbet w-fiovs of the dL-gr.-.vn are a!93 given. vrith table- of ettilon dats. The twn s,,- Jiofil ittftsm0bg varylng proportiani of LW04.X,U'O. to Ll so) k-saj ind L, WO, tu Li,50,.KvFO, are stnble: a zae- Zetflon% art Rtamu:is in th, sviten. tend touwd Ae form7tion a' M,SO.X~so- wid Li~'Vo- Kj'%'O,. Mbe svste~ ba, 4 ro.,~-Iant >I whose temp,, mole % Vill'Op % K-,SO4, C,'o KIWO., and L!sSOj are, rrsp.: 480'. Z. Y.), -, W; 434', --D, The firtt thrte nrc rtamti,n. rd Otc '~-m 0 tmn,it %,t pnint- Ma'c~lm .1,7~ Ardz racIPWRI Systam of loattui imA -lit" d A~ 7,%Ich~irch-nko R"d k i"~)l in the liquid 't;'Ze' is st-.:~' diagmrn has r, fields of c-.,Yitn m~ln" strwght tines, ~n 60~r s,Ie -1 01, (5&4*) alon. g th- diag~ral li~nes radiating Imm ht ~-rr All thest haes z,jcio~: 64.,;~ -i W, -nj, AgNr-I,,Ag7 and ~~AgNrj,-Ag; -h Th~ S.-M66td ap;".~mn~ 'Cdt' ff~T!'-' actix~n (2F--'?.9 k-al ~ z~vj t. m,re !-,rr---,m,i,I rt7i, i, vinul!y Stildled cv4tcms .,t:: Cl "Ir t" whMe svgt,-. !v-" A - A N,-V N~;';O~. kg: -12', 43. 1-5, 43~5, 85.111~ L"5. 14-0 \1 k-rb,- phencemmon of s"ondary periDdir3ty in tbt_a,;Itng earth KTOUP of clemenE. A. G. Berman and N A 'Stale U'vi, , 3z gl=p " zfi~iac,'i int. 1~- III -Dn~ joid :(2) Mg and Sr, on the o2 -Kud zhi~r %ali ut;an , Wiib SA Mg and Sr form only two rj Mficates. .1110 SID, an~ TAM S~Oi ONI m,etal). qn lil.-h fmin th~-e tM, plu, 2 m-, !! tti,rul-! thm the ioni7tatinn potmitish of 'be vlrmtmt~. ms derg r-t L~ppjV to gjlwat~, b~ra-, ~f tht lirnpl,j ioullw gail Nicl: Kr-l ~lllk MK -1 mec', VC! M F(-- 1, 2 K C!, 2~'T C 1: K C" ~-C, 2'~~ Z,-1- 7i N~ ZT if Ak:::mv, noid v'i- ' 'nij n. I'm mA. "I ~1~ I I ic -1i i;; f, il I a t Ba, N0,;, 74 0 !IiC!, 1; in,j: i !i l(v iv 't _3 'O.J) ..,J Thv 3f,hd phiz- :r ff~.~ "0 0. ala! li'Ll- Th'2 "1! 3 lkiN0.1. 1-1), _vI !I,[) ~'1!2.~;. < -I'm lia~d C~C!.. >99 i'LJ and N Cl: