SCIENTIFIC ABSTRACT BERLIN, A. A. - BERLIN, A. A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000204930007-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 8, 2000
• Sequence Number: 7
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

AUTHOR% Berlin, A. AA
8564o
S10641601000100610011011
B020/BO54
TITLE: Synthesis and Properties of Polymers With a System of
Cqnjug te Bonds I
PERIODICAL: Khimicheskaya promyshlennost', 1960, No. 6, pp. 6-14
TEXTt The present paper deals with polymers with aromatic
nuclei which
are bound to one another either directly or by such groups or
atoms as to
guarantee a continuity of the conjugate Tir-electron chains
The'accumulation
of benzene nuclei in the macromolecules may lead to the
formation of
linear, linear-annular, angular-annular, ramified, flat
("aromatic
parquet"), or three-dimensional structures. With an increasing
number of
bound aromatic nuclei, the melting point and the
thermostability of
molecules with linear structure increase, while their
solubility falls. An
introduction of methyl groups lowers the melting point, and
improves the
solubility in aromatic hydrocarbons. For the production of
highly heat-
resistant polymers,10those with graphite-like structure are
most interestirg
therefore, the s~Ebdy.of synthesis and properties of linear
polahenylemLl_
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85640
Synthesis and Properties of Polymers With
B/064/60/000/006/001/011
a System of Conjugate Bonds B020054
and polymers with graphite-like structure seems to be mos",
important.
This synthesis can be performed either by conversion of
low-molecular
aromatic compounds, or by intramolecular destructive
cyclization of certain
acyclic high polymers, or by dehydrogenation of polymers
which contain
bound alicyolic groups. A perfluoro polyphenylene obtained
from p-dibromo--
or diiodo tetrafluoro benzene is particularly heat resistant.
Poly-
phenylenes are sparingly soluble in aromatic hydrocarbons,
and show an
anomalous dependence of n/c on o. The high temperature
coefficient of
solubility, the anomalous viscosity, and the dependence of
the intrinsic
viscosity on the displacement velocity, as well as the
unmeltability show
that the polymers consist of relatively short, but strongly
associated,
solid, almost linear macromolecules. An introduction of
methyl groups in
the polyphenylene chain changes the properties of polymers
considerably.
The integral and differential curves for the distribution of
the highest-
molecular fraction of polym;_wthyl phenylene show that the
fraction contains
small amounts of products with molecular weights of up to
300,000. The
author describes the production of linear or poorly ramified
polymeric
aromatic compounds by reaction of Cul+ with benzidine
bisdiazcnium, the
effect of azo groups in polyphenylene polyazo compounds and
their
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8564o
Synthesis and Properties of PolYL-2r6 With
S/064/60/000/06/001/011
a System of Conjugate Bonds B020/BO54
vJ.scosityt the paramagnetic electron resonance of these
compounds and
their eleotrophilic properties, the transition of
polyphenylenes on
heating from the singlet- to the triplet state, the synthesis
of polymers
with heteroatoms in the benzene ring from aromatic diazonium
compounds
and their properties, the synthesis of polyphenylene oxides by
oxidation
of 2,6-disubstituted phenols with oxygen in the presence of
CH2C12 and
pyridine, the synthesis of aromatic polymers with a conjugate
quinone
P,Toup and with amino groups and their properties, Further,he
deals with
polymers with hetero- and metal cycles in the conjugate chain.
Fig, 4
shows the temperature dependence of the specific electrical
conductivity VX'
of thermolyzed polyacrylonitrile'land Fig. 5 the temperature
dependence of
the electrical conductivity of 'a polymeric chelate complex7of
ethylene
percyanide with iron, The author mentions V. Vansyatskiy, [as
well as
V. A. Tallroze of the Institut khimichesko~ fiziki A SR
(Institute
of Chemical Physics of the AS.:USS.1 . There are 5 figures and
48
references: 17 Soviet, 16 US.- 6 German, 4 British, 1 Italian,
1 Swedish,
1 Swisso 1 Australian, and 1 Belgian.
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00 t,1091 2X09,
I
AUTHORSs Berlin, A.A.i-Xhanukayeva, I.A.
8h288
S/138/60/000/006/001/008
A051,/AO29
TITLE; The Pro4uction and Main Properties oArafted Copolymers of
Styrene'land Rubber.
PERIODICALt Kauchuk i Rezina, 1960, No. 6, pp.,,20 - 22.
TEXT: The article presents the results of an investigation on
graft-
ed copolymerization of synthetic rubbers and styrene in aqueous
dispersions
(latexes) and a solution of the polymer in the monomer. The
methods of
conducting grafted copolymerization in heternzenous dispersion
systems of
polymers and monomers in various liquid mediums have been
developed only
slightly. The author has prgliously published an article on the
subject,51
(Ref- 7), Bgtadiene-styrene CKC-30 (SKS-30) and
butadiene-acrylonitrile
latexes of CKO-18 (SKN-18) 9 CKW-26 (SKN-16) g and CKH-40
(SIM-40) rubbers
were taken for the investigation. Table 1 shows the results of
thecompara-
tive characteristics of the rubber and styrene copolymer.(in the
ratio 33:
66), and the mechanical mixture of a similar composition and the
initial
components. Table 2 gives the figures on the main
physico-mechanical pro-
Card 1/3

84288
S/136/60/000/006/001/008
A051/AO29
The Production and Main Properties of Grafted Copolymers of
Styrene and
Rubber
parties of the produets of the interaction between the styrene
and rubber,
The data show that during the reaction an ifiltiated destruction
of the rub
ber and the formation of branched structures takes place. An
investiga-
tionof the thermomechanical properties showed that the formation
of branch-
ed structures somewhat decreases the vitrification temperature
and the
thermostability according to Martens (75 - 780C instead of 80 -
850C), but
increases the temperature range of the highly elastic state and
the tem-
perature of transference to the viscous-fluid state (Ref, 7). The
styrene
copo2ymers grafted with butadiene-styren3 rubber are not inferior
to the
so-called latex polystyrene as to their dielectric properties and
have a
higher resistance. It is noted that a-comparatively large amount
of rubber
is required in the grafted copolymerization in latexes of
synthetic rubbers,
Apparently in this process the chain transference process takes
place with
a lack of intensity for the following two reasonss 1) incomplete
contact
between the rubber particles covered with the emulsifier and the
monomer,
2) the presence of antioxidant admixtures, disrupting the growing
chains.
When conducting grafted copolymerization in the mass. the
conditions are
Xard 2/3

84288
S113816010001006,10011008
A051/AO29
The Production and Main Properties of Grafted Copolymers of
Styrene and
Rubber
more favorable due to a better contact of the ingredients and
because pre-
liminary purification of the rubber from admixtures is
possible. The
authors point out that by developing a method for grafted
copolymerization
of styrene and rubber the amount of elastomer would be reduced
and a more
tensile and durable product could be produced under
atmospheric conditions.
The principle used in Reference I by the author in solving
this problem
is outlined. An investigation of the mechanical properties of
the grafted
copolymers obtained by this method shnwed that even in the
case of a small
amount of rubber added plastics with rather high mechanical
properties
could be produced (Table 3). It becomes apparent that with an
increase in
the rubber latex (under given experimental conditions) the
dispersion and
the stability of-the styrene emulsion increase, which
facilitates the con-
tact between the components and rendets their interaction more
effective.
This, In turn, leads to the formation of the grafted
copolymer. There
are 3 tables, 2 figures and 7 referencess 6 Soviet and I
American.
ASSOCIATION: Institut khimicheskoy fiziki Akademii Nauk SSSR.
Kuskovskiy
Khimzavod (Institute of Chemical Physics, AS USSR. Kusov
Card 3/3 Chemic-al Plan-4.

BERM, A.
S~nthests and properties of polymers witb a conjugated
bond
system. Zhim. prom-no. 6:444-452 8 160. NEU 13:11)
(Polymers)

20250
S/138/60/000/012/001/009
A051/AO27
AUTHORSt Berlin, A.A., Gillman, I.M.
TITLE't The Production and Properties of Block-Copolymers Formed
in the
Mastication of Rubber and Polystyrene Mixtures
PERIODICAL: Kauchuk i rezina, 1960, No.12, pp. 1-3
TEXT: The authors have investigated the main physico-mechanical
prop-
erties of materials produced in the mastication of polystyrene and
various
elastomer mixtures. Mention is made of the favorable conditions of
block-
-copolymer-formation, especially in an inert gas medium, during
mastication
of polymer mixtures. It is stated that the mechanism of this
reaction can-
not be ezplained by poly-recombination of the radicals alone,
since in this
case the chain reaetion has the greatest significance, leading to
the for-
mation of black-copolymers and branched macromolecules (Ref.1). The
authors consider that the peroxide macroradicals formed by
interaction with
02 due to the chain nature of the mechano-chemical
block-copolymerization
process can serve as active components taking part in the
formation of the
block-copolymers:
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20250
S/138/60/000/012/001/009
A051/AO27
The Production and Properties of Block-Copolymers Pormea in
the Mastication
of Rubber and Polystyrene Mixtures
R~ + O~' ROO-
R OT + --CH - CH~- -oR OOH +-C'- CH2_
A n I
X
X X
CH - + R 00'-.*-C -CH
2 n 1 2
OORn
R 00*+*CH CH - R OOCH - CH - etc.
n 1 2 n 1 2
X X
(friction number 1.25,
average molecular
with butadiene CK6
Mastication in an air medium on rollers was performed
t-150-1600C) using mixtures of polystyrene (block.-type
weight Mav ~ 80.000 and emulsion-type-, Mav '200.000)
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20250
S1138160100010121001100ci
A051/AO97
The Production eaid Properties of Block-Copolymers Formed in
the Mastication
of Rubber and Polystyrene Mixtures
(SKB)q butadiene-styrene CKC-30 (SKS-30),
butadiene-acryloLitrile CKH-18,
CXH-40 (SKN-18, SKN-40) rubbers, polyethylene (M ay -
200.000), polyisobu-
tylene (M ay a 200.000), butyl rubberland chloroprene rubber.
It was noted
that materials with the greatest specific toughness and static
bending re-
sistance were formed from the combined mastication of
polystyrene A mix-
tures with 20-25% synthetic rubbers of the SKS-30 and SKN-18
type (Fig.1).
Masticated rubbers produced onan emulsified polystyrene and
SKS-30 rubber
(25%) base are characterized 2on the average by the following
figurest 2
specific toughness, kg.cm/cm .... 53-60t static bending
resistance, kg/cm
930, heat resistance accordgng to Martens, 0C... 86, tangent
of the
angle of dielectric losses at 10 cycles... 0.0019, water
absorption per
hour, g/dm2 ... 0.01. The authors point out that the
development of the
mechano-chemical theory on block-copolymerization in the
rolling of polymer
mixtures helps to explain the observed drop in the stability
of the mate-
~ial when adding a radical acceptor (1 2) and also certain
dyes on the
rollers. It is concluded that the introduction of these dyes
and the
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20250
S/138/60/000/012/001/009
A051/AO27
The Production and Properties of Block-Copolymers Formed in the
Mastication
of Rubber and Polystyrene Mixtures
radical acceptors lower the stability of the material
probably,due to an
inactivation of the macroradical parts formed during the
mechanical de-
struction of the polymer chains. There are 2 tables, 1 graph
and 6 refer-
ences:5 Soviety 1 English.
ASSOCIATION: Kurskiy khimi-cheskiy zavod (Kursk Chemical Plant).
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1P
87642
S/191/60/000/012/001/016
.19- .2 2 2.0 B026/BO66
AUTHORS. Berlin, A. A., Kronman, A. G., Yanovskiy, D. M., Kargin,
V.A.
TITLEs Impact-resistant Polyvinyl Chloride
FERIODICkLt Plaoticheakiye massy, 1960, No. 12, pp. 2 - 3
TEM Heat resistance and impact of PVC are comparatively low which
con-
siderably confines its range of applicability in spite of its other
good
Properties. It is possible to increase the impact strength of PVC by
synthesizing vinyl chloride polymers grafted with various rubbers, by
means of a chain transfer reaction. The mechanical properties of
Viniplasts obtained by this method are, however, no better than
those of
Viniplast made of PVC. The present paper investigates the physical
and
thermomechanical properties of Viniplast obtained from compositions
consisting of PVC coplasticized with a polar synthetic rubber(PSR).
Owing
to interaction of functional groups of PVC with the rubber,
interlaced
structures of grafted copolymers are formed. PVC was mixed vith
stabilizers (litharge, calcium stearate) which were hot-rolled along
with
the adequate amount of PSR. Plates were out from thin foils of the
rolled
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87642
Impaot-resistant Polyvinyl Chloride S/191/60/000/012/001/016
B026/BO66
material, and a stack of them was hot-pressed. In the test of
Viniplast
containing 10% PBR of different types, its physical and
mechanical
properties ranged within T following limits: specific impact
strength
from 57.2 to 84.8 kg.cm/cm (8.6 for initial PVC)j maximum
tensile
strength from 3970to 532 kg-CM2 (550 for PVC); vitrification
point
between 76 and 80 C (75 C for PVC). The addition of 10% PSR to
the
Viniplast, thus, increases the specific impact strength up to
the 6 to
10 fold, whereas the tensile strength is somewhat reduced, and
the
vitrification point is maintained. The dependence of the
specific impact
strength, tensile strength and relative elongation on the
rubber content
in Viniplast was investigated (Pigs-1-3). The optimum ratio of
PVC:PSR
for obtaining Viniplast with high apecific impact strength is
90:10
(Fig.1). The introduction of 2.5% rubber increases the impact
strength
of Viniplast to the tbioefold. At a rubber content of 15 - 50%,
Viniplast
samples were not destroyed in the impact test owing to their
high
elasticity. With increasing rubber content, tensile strength and
relative elongation of the material (Fige.2,3) decrease, and
the surface
of Viniplast becomes uneven and rough, beginning from a rubber
addition
of 25 - 30%. The temperature dependence of the specific impact
strength
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87642
Impact-resistant Polyvinyl Chloride 5/191/60/000/012/001/016
B020/B066
of impaot-reeistabt,Viziplast was studied in a rangd-of from -600 to
+60"C, and it was found that a Viniplast with 5 gnd 10% PSR exceeds a
Vi'niplast from PVC even at a temperature below 0 C. The specific
properties of impaot-resistant Viniplast become particularly
manifest at
room temperatures. The.absolute value of.the.specific impact
strength could
,)nly be determined+at temperatures below zero. Table 1 gives
comparative
data.of this.factor obtained on compositions with 90% PVC and
10%'PSR, and
on,PVC samples. The principal physioal and'thermomechanical
properties-of
impact-rresistant Viniplast, as well as of PVC-Viniplast,
are'presented in
Table 2. There are 4 figures, 2 tables, and 1 Soviet reference.
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83818
S/190/60/002/005/008/015
d.,uv 2 2,0 5 B004/BO67
AUTHORS: Berlin, A. A.,'Jiiogon'kiy, B. I., Parini, V. P.
..;Q - - -
TITLE: Production and Properties of Some Aromatic PolymerA
PERIODICAL: Vysokomolakulyarnyye soyedineniyav 1960, Vol. 2,
No. 59
pp. 689-697
TEXT: In an earlier paper A. A. Berlin and 7. P.-Parini
published the
synthesis of homologous olyphenyliseries by decomposing
bis-diazobenzi-
dine or bis-diazobenzidine-3,3'-dicarboxylic acid by means of
salts of mc--
novalent copper (Ref. 11). The present paper reports on this
reaction and
on the properties of the products obtained. The biB-diazo
compounds"pere
decomposed with an ammoniaoal solution of copper sulfate,
which had been
stabilized with hydroxylamine hydrochloride. No different
results were
obtained with air supply or in argon atmosphere. An addition
of the di-
azo solution to the copper solution, however, yielded
products with
higher molecular weight than those obtained in the inverse
procese. Ana-,
lyses of the products obtained are given in Table 1. Nitrogen
could nci
be completely removed. The chlorine content decreased with
increasing
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838M
Production and Properties of Some Aromatic
S/190/60/002/005/008/015
Polymers B004/BO67
molecular weight (Table 2). So, it is probe y b-)und to t e
end grOU-D. The
following polymer structure is assumed: C- 6H 3- C6H 3- N_
6H3-y6H --C 1;
X k R ;I-V
R = -H or -COOH. The content of azo groups increases with
increasing length
of the chain. The carboxyl group in ortho-position favors the
elimination
of nitrogen. Fig. 2 shows that the loss in weight on heating
(up to 450 cc)
attains rapidly a limit for every temperature. The infrared
spectra taken
with an WKC-11AIKS-11) spectrometer proved the mere
para-substltu*.On
in the aromatic ring as well as a probably quinoidal
structure of the ring
and rod form of the molecules. The latter fact explains the
anomalous VX
viscosity. The spectrum of electron paramagnetic resonance
taken with
D. G. Semenov's radlospectrometer (of. Ref 18 11) indicates
unpaired electrons
- nfirm
whose concentration is of the order of 10 1019 and co s the
radial.
character of the reactions. The shortness of the polymer
chains obtained
is explained by the formation of stable biradicals which, due
to the
delocalization of unpaired electrons, have only a low
reactivity. The
formation of such biradicals was proved by reacting polymer3
with F-di-
ethinylbenzene at high temperatures. Unmeltable and insoluble
products
were formed. The magnetic properties and the electrical
conductivity of
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83818
Production and Properties of Some Aromatic
Polymers
the polymers will be described later. The authors thank I. A.
Blyumenfelld,
Yu. Sh. Moshkovski and A. A. Slinkin for studying the spectra
and
magnetic properties. There are 2 figures, 2 tables, and 19
references:
8 Soviet, 8 US, 2 German, and I Dutch.
S/190/60/002/005/008/015
B004/BO67
ASSOCIATION: Institut khimicheskoy fiziki AN SSSR
(Institute of Chemical Physics of the AS USSR
SUBMITTED: January 18, 1960
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S/190 60/OO2/OG6/O0!/'O',-
B01 5YBB064
AUTHORSt Berlin, A. A., Uzina, R. V., Shmurak, 1. L.
TITLE: On Some Factors Influencing the Adhesion of Rubber on the
Tissue Fiber, Steeped With Latex Albumin Mixtures
~ERIODICALt Vysokomolekulyarnyye soyedin.aniya, 1960, Vol. 2,
Nc~. 6_..
PP. 832-837
TEXTt The adhesive power between rubber and tissue is of special
importance in the production of tissue-reixiforeed rubber
product-, Such as
oar tires, bands, assembly lines etc. To ircrease the adhesive
power, the
ootton- or man-made hber tissue is steeped.with albumin
conta4'nAng latex-
mixtures in the USSR. A method of producing'a water-soluble
mo;ifilc~atlcn
of keratin (keratein) from industrial waste products was developed
Ref. 6) in the laboratoriya vysokomolekulyarnykh soyedineniy
MTIM&P
Raboratory of Highmolecular Compounds Mjj.MNZ~,_The waste
products are
treated with strong reduction-, or oxiaizing agents, with the
--S-S~~
cystine bond of the keratin macromolecules being torn; thus, the
water-
soluble keratein forms. Investigations carried out by the authcrs
(Ref. 7)
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On Some Factors Influencing the Adhesion S/199(60/002/006/m'
-2.
of Rubber on the Tissue Fiber, Steeped With BO15/BO64
Latex Albumin Mixtures
showed already that keratin,., is a complet;9 substitute for
casein that h:15
hitherto been used for the above-mentioned steep solutions,
The present
paper mentions some of the results obtainod on the behavior
of kerptt'n.
and other latex albumin mixtures used for tissue steeping. The
power of rubber on steeped tissue may be assumed to depend on
the
of amino acids with polar side chains in i;he albumin
molecule., In this
respect, keratin does not very much diffe:;- from casein and
albumin
(Table 1, values of adhesive power between CKU-(SKB-), CKC
-,30AM
(SKS-Z,OAM-), and HK (natural-) rubber and tissue
steepe`a-`w`1'T'F7i.::'Z'N1:
keratin and albumin containing mixtures rospectively). Sinoe
album,.-a's
represent polymeric electrolytes, their properties are
influenced by the
pE. Experiments showed that an inerease of the pH of the
steeping m1Xt*-.XrP_'-,
reduces the adhesive power of rubber on steeped tissue. The
incra~*~~ in
the ionization of the albumin molecules taking place in
alkaline
was assumed to bring about a directioning of the molecule
chal-n and
tion of a net structure. These assumptions were confirmed by
det~~rm`n-"rg
the value b/a (Table 2) (b . longer axis oil the extended
mole---,u1_k'G_
a = short axis), as well as by measurements of the flow time
(illl
Card 2/3

On Some Factors Influencing the.Adhesion
S/190/60/002i'006/00'1/012
of Rubber on the Tissue Fiber, Steeped With B015/BO64
Latex Albumin Mixtures
on pressure) on casein- and keratin solutions through a
capillary, The
"longer" the albumin molecule is the longer will the flow time
be The
poor adhesive power of rubber on tissue steeped with solutions
of a highel
pH is due to a deterioratitin of the mobility of the "extended"
a3birmln
molecule. There are 4 figures, 2 tables, and 19, references: 0
Sovit~tl,
4 US, I German, and 1 Austrian.
ASSOCIATIONs Moskovskiy tekhnologicheskiy institut myasnay i
molochncy
promyshlennoBti (Moscow Technological Institute Qf ~he Meat-
and Milk Industry). Nauchno-issledovatel'skiy institut
shinnoy promyshlennosti (Scientific Research Institute of
the Tire Industry)
SUBMITTED; January 23, 1960
Card 3/3

X,
87031
S/190J60/002/007/015/017
A020/BO52
AUTHORS% Barkaloy, 1. M.p Berlin A. As Golidanakiy, V. I.,
Dzantiyevl D. ~A`W
TITLE: Radiation Polymerization of Phenyl Acetylene
PERIODICAM Vysokomolakulyarnyye soyedineniyav 1960p Vol, 2f Noo 7P
PP- 1103-1107
TE XTs Purpos#of this-paper,was thei investigation of kinetics and
the
mechanism of the radiation polymeris~ation of phenyl acetylene which
was
initiated by electrons with an energy of 1-5 Nev.T%cirradiation was
carried
out in special curettes (Pig. I a).'rhe electron beam was introduced
through a plane-parallel glass window 0-5 mm, -thick. For accurate
thermo-
stating within the range of positive'ttemperatures, a different type
of
euve-tte was used (Fig. ltb). The.teml-eratures of the
polymerization were
-iq6'.to +850C- The reaition yield was.not higher than 10 - 12%,
since in
all experiments theinitial stage of~.qolymerization -as
investigated. The
radiation does was determined,by a ohOnLioal dosimeter (0.02 mole/l
of
Card 1/4

Blot
R
is. on Polymerization of- Phe4l
iLd I ti 5/190J60/002/007/015/PI7
Acetylene B020/B652
cuso 0.002 mole/l of Peso and
49 49
by the Institut im. L. Ya. Karpova
Fe3+
0,02 1 which was recommended
1 H2SO4)
(Institute imeni L. Ta. Karpov). The
developing
was photometrically examined by a Ot -4 (SF-4) spectro-
photometer. The IR spectra of polyphenyl acetylene were studied by
Yu. Sh.
Moshkovskiy. The polyphenyl agetylene yield rises proportionally to
the
dose of wide ranges k107 - 10 roentgen) (Fig* 2), Even with the
largest
doses applied, no noticeable destruction of the developed polymer
wa.8
observed. This seems to prove the absence of effective inhibitor
additions
whose presence would be indicated by the S-shape of the curve. In the
presence of atmospheric oxygen, the polymer yield is increased to
the 1*5-
to 2-fold under otherwise eval conditiors. With-a certain dose# the
polymer yield does not depend on :Lt* quaLitity, not even at
temperatures
near the melting point or when the liquid monomer is exposed to
radiation.
The dependence of the polymer.yiela'on the qua~tity'of the dose was
also
investigated (Fig. 2) at 0 and -7800. The extremely low dependence
of the
polymerization rate of.phenyl acetylene on the temperature is also
typical. Experiments were carried out rega:Tding the polymerization
of
phenyl acetylene in nonane and ethyl aoetateo In these two solvents
the
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8703L
Radiation Polymerization of Phsnyl S/190A0/002/QP7/015/017
Acetylene B020/BO52
polymer yield differell widely from that exp,~.oted on the
basIs of the ad-
ditivity law (Fig- 3)- A ver.* effective radiation energy
transfer (the
radiation is absorbed by the solvent molecules) to the phenyl
acetylene
molecules is observed. Substances with structures of the
polyacetylene
type have the same properties as aromatic hydrocarL-onsf namely
that of
taking up.the.energy of ionizing radiation. The laws of phenyl
acetylene
polymerization in.many respects are specific, sometimes e-ven
the opposite
of those of the usual radical polymerization. Stimming up one
may say that
the.polyphenyl.acetylene yield is approximately 8 - 9 molecules
when the
radiation is 100 ev.: In the liquid phase, polymerization'and
initiation
rates are proportional.-The activation energy is.as low as
approximately
700.kcal/mole. A mechanismi was suggested which explains the
unusual
results by-the.specific properties of highly conjugated
products during
the-polymbrization of phenyl acetylene. In these products a
strong de-
localization of unpaired elements takes place, and the
reactivity of
.aimilar~molecules is reduced with an increase in their length.
There are 3 figures-and 6 referenceei 4 Soviet and 2 US.
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Radiation Polymerization of Phenyl S/190/60/02/007/015/07
Acetylene BOZO/BO52
ASSOCIAMONs -Inatitut-khimioheakoy fiziki AN SSSR (Institute of
Chemical Physics of the AS-USSR)
SUBMITTEDs Marah-26p 1960
Card 4/4

86293
s/190/60/002/008/004/017
B004/BO54
A o ck~
AUTHORS: BerlipL A. At Krofiman, A. G., Yanovskiy, D. M.,
Kargin,
-V. A.
TITLE: Modification of Polyvinyl Chloride by Rubbers
PERIODICAL: Vyaokomolakulyarnyye soyedineniya, 1960, Vol. 2,
No. 8,
pp. 1188-1192
TEXT: The authors attempted to make graft copolymars from vinyl
chloride
and rubbers. In contrast to the unsuccessful copolymerization
with the aid
of latex reported on in Ref. 2, they used coarsely disperse
rubber emul-
sions. Photogelatins, Sulfanole, or polyvinyl alcohol were used
as emul-
sifiers. Copolymerization vas conducted by two methods: 1)
swelling or
0
dissolving of the rubber in vinyl chloride at4D-70 C, and
subsequent poly-
merization in an autoclave after adding ammonium persulfate as
initiator;
2) rolling of the rubber with ammonium-persulfate powder at
room tempera-
ture, ans subsequent copolymerization with vinyl chloride in an
autoclave
at 60-70 C. Viniplast was made from the reaction products by
adding
calcium stearate, lead monoxide, Neozone D, and transformer
oil, kneading
at 155-170 0C, and pressing. The resulting products showed
worse physical
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86293%
Modification of Polyvinyl Chloride by Rubbers S/19
60/002/008/004/017
B004YB054
properties than pure polyvinyl chloride* On the other hand, a
joint plasti-
fication of polyvinyl chloride (PVC) of the type n�-4 (PF-4) with
HK (NK)
natural rubber, CKS(SXB) butadiene rubber, CKH (SKI) isoprene
rubber,
C,KH-26 (SKN-26) butadiene-nitrile rubber, and chloroprene rubber
(nairit),
led to the following results:
PVC combined Content of
toughness
tensile strength
relative elonga-
with-. rubber, %
-
k&-cm4cm2
kgjcm2
tion, %
(without rubbe
r) 0
8.6
550
82
natural rubber 10
9-7
354
4-4
butadiene rubber 10
6-7
350
5-8
is6prene rubber 10
3.7
357
9.7
hairit 10
16-5
437
81.5
butadiene-nitrile

rubber - - 10''
34.6
551
100
Rubbers with marked polarity (nairit ' SKN-26) showed double to
fourfold
toughness. Hydrogen bonds are likely to form between the polar
rubber
and PVC. There are 2 figures, 2 tables, and 7 references: 1
Soviet, 4 US,
1 Belgian, and 1 French.
SUBMITTED: March 21, 1960
.Card 2/2

BIMLIN A.A. - S L.Y.; 73DOSIM, B.I.; YAMVSKIY, D.M.
R.- -A I I STUM
Graft copolymerizarion. Pbrt 6: Fractionation of the
products
from1he graft polymerization of -Vinyl choloride with
the
butyl methaerylate-mothaerylic acid copolymer.
Vysokom.
eoed. 2 no.8:1227-1233 Ag 160. (MMA 13:9)
(Ithylene) (Methaorylic acid)

Y 85482
5/190/60/002/009/017/019
S".1810A 4*~06 2103,2103 B004/BO6O
AUTHORS, Berlin, A. A., Dubinskaya, As M.
TITLE: Studies in the Field of the Mechanochemistr of Polymeric
-Substances. X. Initiation of PollMerizatio3with Radicals
Forming bn the Destruction of Macromolecules by Means of
ultrasonics
PERIODICAL., Vysokoniolekulyarnyye,soyedinenivA,, 1~60, Vol. 2,
No. 9,
PPo'1426-101
,TEXT: In contrast to otbw.-papers (Refs. 1, 2, 5), the authors
studied the
.ultrasonic destruction and the formation of copolymers in
anhydrous medium,
solutions Qf#polymethvl methaerylatel(PMMA) in
acrylonitrilMmethyl
methacrylate, and Styr, ene.9 Tne molecular weight of PMMA
(visco6imetrically
determined in benzene ) was 3,1609000. The solution of the
polymer in the
monomer was exposed in argon atmosphere to ultrasonic radiation
of
1500 kc/ see and a calorically measured intensity of 5 - 50
w/om2. The
apparatus had been described earlier (Refs. 69 8). Since the
temperature
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83482
Studies in the Field of tlxe.Mechanochemistry
S/190/60/002/009/017/019
of Polymeric Substances'...X. Initiation;of B000060
Polymerizati~on With Radicals Forming on the
Destruction of Macromolecules by Means of
Ultrasonics
rose to 50 OC, cdoling spells were put in. The degree of
polymerization
was determined on the vtrength of changes in the refr&tive
index of the
solution, on the strength of increace in the polymer weight,
and - in
acrylonitrile - on the strength of the nitrogen content. For
control, L)~
monomers alone were acoustically irradiated, and no
polymerization
occurred after 30 min either. Acoustical irradiation of 1-2%
PMMA Solu-
ti6ne in the monomers always gave rise to polymerization,
the rate of
which decreased in the order aorylonitrile - methyl
methacrylate styrene
(Tablel). The reaction of PMMA with acrylonitrile was
examined more olose-
ly. Table 2 gives the action of various
ultrasonic-intensities, Table 3
supplies the experimental results at 7 w/cm2, 1-5 min
irradiation, and a
3 min pause. A block copolymerization of PMMA with
polyacrylonitrile
(PAN) was establishedo The infrared spectrum of
the-oopolymer with a
ratio PMMA/PAN - 30/70 exhibited both bands of the nitrile
group and of
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83482
Studies in the Field of the Mechanochemistry
S/190/60/002/009/017/019
of Polymeric Substances. X. Initiation of B004/BO60
Polymerization With Radicals Forming on the
Destruction of Macromolecules by Means of
Ultrasonics
the eater group. The viscosity and the Huggins constant were
also de-
termined (Table 4). The thermomechanical curve (Fig. 4) for
PWAA/PAN - 47/53 and for a mixture of the polymer components in
the
same ratio-shows that the copolymer has a branched, partly
arose-
linked structure. As in the Polymerization bZ means of gamma
IrayiO
an after-polymeriziation occu;f-ed here as weii, especial.1y K;
WTT-gnr-11
temperatures. There are I figure, 4 tables, and 12 references:
4 Soviet,
2 US$ 3 British, and 3 German.
ASSOCIATION: Institut khimicheakoy fiziki AN SSSR
(Institute of Chemical Physios of the AS USSR)
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Studies in the Field of the Mechanochemistry
of Polymeric Substanceso X& Initiation of
Polymerization With Radicals Forming on the
Destruction of Macromolecules by Means of
Ultrasonics:
SUBMITTEDt April 22, 1960
8 482
S/190/60 002/009/017/019
B004/BO60
k~
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S11901601002101010091026
B004/BO54
AUTHORS: Liogon'kiy, B. I., Lyubchenko, L. S., Berlin, A. A.,
Blyumenfelld, L. A., and Parini, V. P.
TITLE: Polymers With Conjugate Bonds and Reteroatoms in the Con-
junction Chain. XI. The Spectra of Electron Paramagnetic
Resonance of Linear Aromatic Polymers
PERIODICAL: Vysokomolekulyarnyye soyedineniya, 1960, Vol. 2, No. 10,
pp. 1494-1499
TEXT: In previous papers (Refs. 1, 2), the authors obtained aromatic
polymers by reaction of bia-diazotized benzidine,
benzidine-3,31-dicarb-
oxylic. acid, and 0-toluidihe with monovalent copper-sa ts; the
following
structural formula is given: R
C1 ~_,L~ N2_ C1
(polymer I: R - H; polymer II: R- COOH; polymer III-- R = CH The
electron paramagnetic spectra (epr) were taken (Figs. 1-3) o1 these
poly-
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Polymers With Conjugate Bonds and Heteroatoms in S119
60/002/010/009/026
the Conjunction Chain. X1. The Spectra of Elec- B004YB054
tron Paramagnetic Resonance of Linear Aromatic
Polymers
mers and the copolymer from I and p-diethinyl benzene, and
the concentra-
tion of the nonpaired electrons was found to be 1018 - 1019
in 1 g of
substance (Table) by comparison with the epr spectrum of
diphenyl-picryl
hydracyl as a standard. All epr spectra showed a signal with
g-factor 0
2.00 which remains unchanged on heating to 300-3500C and
cooling to 77 K,
and-is interpreted as a signal of the conjugate bonds. The
broader epr
signal, which is superposed to this signal-in unheated
samples$ could not
be analyzed because of the superposition, and is interpreted
as a signal
of less active, free radicals with localized free valency.
The signal ap-
pearing additionally in the insoluble fraction with g-factor
2.05, which
disappears on dissolution, is ascribed to low-molecular
particles. The
stability of the epr spectrum in the vide temperature range
indicates the
paramagnetic character of at least part of the polymer. There
are 3 figures,
1 table, and 9 references: 8 Soviet and 1 US.
ASSOCIATION: Institut khimicheakoy fiziki AN SSSR (Institute
of Chemical
Physics of the AS USSR)
SUBMITTED: April 25, 1960
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F(I b 7~.,
86327
S/190/60/002/012/014/019
B017/BO78
AUTHORS: Berlin A A , Kronman, A. G., Yanovskiy, D. M.,
Kargin,V.A.
TITLE: New Method of Obtaining Graft Copolymers
PERIODICAL: Vysokomolekulyarnyye soyedineniya, 1960, Vol. 2, No.
12,
pp. 1839 - 1844
TEXT: A new method of obtaining graft copolymers by interaction
between
the polymers is suggested by the authors. This method permits to
modify
halogen-containing polymers with polymers having
nitrogen-containing
heterocycles. A case in point for such a reaction is the
modification of
PVC with methylvinylpyridine rubber under the formation of graft
copoly-
mers which are salts of quaternary polymer bases. Vinyl plastics
obtained
from such polymers have an impact strength ten times as high as
that
prepared solely from polyvinylehloride. Fig.1 illustrates the
temperature
dependence of some thermomachanical properties of some polyvinyl
plastics.
The two-stage formation of trimers is explained. Fig.2
illustrates the
influence of the rubber content on the properties of polyvinyl
plastics.
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8632
New Method of Obtaining Graft Copolymers
S~19Y60/002/012/014/019
B017 B078
Fig-3 shows the vitrification temperature of polyvinyl
plastics as a
function of the admixtures. It is demonstrated that the
thermal stability
of polyvinyl plastics is not impaired by a methylvinylpyridine
rubber
content up to 25%. The method auggested here may be applied to
vulcanize
various halogen-containing polymers with methylvinylpyri-dine
rubber.
There are 3 figures and 13 references: 9 Soviet and 4 US.
SUBMITTED: May 24, 196o
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69009
AUTHORS: Berlin A.A., Xatveyevat N*G% S40
11460402910310011004
TITLE: Polymeric Cholute Compounds
PERIODICAL: Uspokhi khi=:Li, 1960p Vol 290 Nr 3, pp 277-297 (USSR)
ABSTRACT: The autbors describe now ways of preparing polymeric
materials with
properties required for technical development. one of ihose is the
syntheeis of chelate compounds. Cholates are known.to be resistant
to acids and bases and to agents which react with free metals (Ref
1).
Many 0slates are extremely stable at comparatively high tempera-
turea%14000 and higher). Groups which are able to form chelate
rings
Tlwh--t io' be termed chelating groups. Provided they are suitably
arranged in the molecule, electron donor groups contained in
cholating
groups can form cholato rings in the presence of olootrophilic ions
or atoms. The stability of these oholate rings is much increased if
these donor groups are in conjugation to each other. Examples are
given on p 278. The resistance of those oholate rings to chemical
agents and beat is determined by a number of factors: the structure
and chemical nature of the cholating group, the ring tensiong the
number of rings connected with the corresponding ion, the elcatron
structure of the complezing ion. In most cases, ohelates are highly
V