SCIENTIFIC ABSTRACT BLIZNYUK, N. K. - BLIZNYUKOV, V. I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000205520017-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 22, 2000
• Sequence Number: 17
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

Reactions of Acid Phosphites, Thiophosphites,
S10791611031100110161025
Phosphonites, and Dialkylphosphine Oxides Wit4 BOO1/BO66
Disulfides
3 Soviet, 1 US, and 1 Polish.
SUBMITTED: February 2, 1960
Card 3/3

$8413
S/07Y61/0 31/001/017/02 5
BOO IB066
AUTHORS: Petrovt K -A Bliznyukp X. X., Studnev, Yu. F., and
Kolomiyets'
TITLE: Monoalkoxy-methyl Thiophosphonates and Monoalkoxy-methyl
Phosphonites
PERIODICALt Zhurnal obshchey khimii, 1961, Vol- 31, No- 1, PP- 179--
184
TEXT: In order~to simplify the synthesis of the above compounds
described
in Refs. 1 - 411 the authors studied the addition reaction of sulfur
to
the monoesters of methyl phosphinic acid;
OR - P OR + S )CH P OR
11 4
3 0 H 3 S OR
The rate of this reaction depends, above all, on the nature of the
solvent
to be applied. This reaction, for instance, proceeds rapidly and
smoothly
in dioxane, but does not take place at all in ether. Like dialkyl
phos-
phites (Ref, 6), also alkyl phosphonites add sulfur in ethereal
solution
Card 1/3

81483
Monoalkoxy-methyl Thiophosphonates and !079/61/031/001/017/025
Monoalkoxy-methyl Phosphonites BOOI/BO66
only in the presence of bases (triethylamine). The reaction rate
of sulfur,
which is higher with monoalkyl phosphonites than with dialkyl
phosphites,
corresponds to the change of the electron density on the
phosphorus atom.
The structures of the resultant monoalkyl thiophosphinic acids
were con-
firmed by their conversion to salts and esters. The novel
monoesters of
methyl phosphinic acid were obtained by reaction of
methyl-dichlorophos-
phine,with alcohols in the presence of tertiary amines in a molar
ratio
of 1 : 2 1 1 (90-% yield)t 11.1 OR
CH 3PC12+ 2ROH + RI 3N )OR3P + RI3N - HU + RCl
211 \ H
0
Not only the tertiary amine serves as a H01 acceptor, but also the
resultant neutral phosphonite (Refs. 8 - 10) according to the
reaction
z OR
RIP )RI - P , + RC1 (Refs. 8 - 10). The monoalkoxy-methyl
(OR)2 + He' 1) H
0
phosphonites well soluble in organic solvents are 'stable
compounds which
do not change for years in pure condition. The yields of
monoalkyl-phos-
Card 2/3

88411
Monoalkoxy-methyl Thiophosphonates and B/079/61/031/001./017/025
Monoalkoxy-methyl Phosphonites B001/B066
phonites were between 75 and 90 There are 1 table and 16
references:
9 Soviet, 6 US, and I Polish.
SUBMITTED: Pebruary 2, 1960
Card 3/3

PETROV A.; BLIZNYUK. N.K.:-SAV-OSTENOK. V.A.
Reactions of su.1fenamideo with,compounds of trivalent
phosphoAs.
Zhur. ob. khim. 31 no./+:3,361-1366 Ap 161. .14:4)
(Sulfanamides)
(Phosphoruo organic compounds)

PETROV, Kok.,, ELIZWKp N-K.p MkNSUHDVo I.YU.
*Reaction of acids pbosphites, thiopbesphites, phosphonitesm and
dialkylphonosphine oxides with dimLlfides."
Kbimiya. I PriverAniyo pogfororr
cvd ~jj~y ",C)'Wrriatry art.-I
'anicheskikv,
joy ill-
aPt)licatiOr Of OrgOnOPboaphome cormumis) A. YF,
0ublo by Kasar Affilo Acndt
Collection of comlet.- on-eve Dresented at the IV7-9- Kazar..
Chleml3try of ';rganonhosphorua Govmund4.

PETROVS X.A., BLIZNYUK9 W.K., SAVMTENOKP- V.A.
"Reactions of sulfenamidis with compounds of trivalent
phosphorus."
Kbimiya i Primerseniye Fosfororganichaskilrl-,
Soyedinniy (UhardexT am-t
apDlication of organophosTihorvs connow0b) A. TL~ Ld!2
i'ublo by Kazar Affil. Acadc, ~oi. "-V 3*t
Collection of com)I.stft voers oresented at the 191,"
Kazan '-on'vrrnc~? -~*j
Chemistry of :;i*ganooIit)9nhomj4 Goru)ojindq.

AA~9-65 'swT(8)/zP?(C)/ZWvP(J) Rm
ACCESSION MR: AP5021969 Up, /0 e 6F_~ 5C~ (1 1.4 1 of~ I F~
AUTHOR: Dlizn uk, N. K. olomi-rets A. F.; Khokhlov, F. S.
TITLE: A meth-~d for producing alkv1(arv1%T*hiopho-sphnnv -r.: 12.
No.
EOURCE: Byulleten' izobreteniy i tovarnykh
I znakov, no.
TOPIC TAGS- phosphonic acid, aLkylphosphine, chlorinated alinhatic
clmpouri3,
chloride, phosph,--~rus, organic sulfur compound
ABSTRACT: This Author's Certificate introdmce5 a muthod f ~~r-
J)roduc ing dil ar~
thiophosphonyl dichl-orides based on alkyl(arvil)phosphonvi
dichlcri-les. The process
is s i-mr-l 4 fiee. a-.v! -he producT y iel d is j1)1_---..3~"?,!
~",- 1 - .- - I .. .. I .
phony! dichlorides in white phosphorus and suifur at
ASSOCIATION! none,
SUBMITTED: .28Har-63 ENCL: 00 SUB Com: CC, GC
-F - SOV.- 060 OTHER- 000
.0 RE
--nano=
T.
a N

41P-" '-7
7777
L.-~~ 0 66,-, -SWOT /K JIV,
JAN.0-
ACC WU='GODE: UR/W86
Gllk: A?5M56T?
AT RS
Kvqshw~: Z. N.; SoIntseva L Libmm, B Ya.;
JTHD Bliamilt, N
k A- I SeVitOV'L L-zB.
B
-~ Z

-kL- -405646 EW ~,IJP (C)
26-
AGO .NRf AP5025679, SWRCE~PPDEs UR/0286/65rq�/qM6/00

BLIZNYUK, N.K.; LEVSKAYA, G.S.,- MATYUKHINk, Ye.N.
-- -I.--
New synthesis of secondary haloarsines. Zhur. ob. khim.
'115
no.7:1247-1250 Jl 165. (MIRA 18:8)
1. Vsesoyuznyy nauchno-isoledovatellskly instlLut
fito~atologii.

ACC M AP6033452
SOURCE COM UR/0413/66/000/018/0038/0038
INVENTM Dlixnyuko, N~!K,; Khokhlov# P, So
ORG: none
TITLEi Preparation of alkyl dichlorodithiophosphateso Class 12,,
No. 18590.2 [announced by All-Union Scientific Research
Institute.of
Phytopath6logy (Voesayuznyy nauchno-iseledovatel'skiy institut
fito-
patologii)l
SOURCEt Izobret prom obraz tov zn, no. 18, 1966, 38
TOPIC TAGS: alkyl dichlorodithiophosphate, phosphorus
thiotrichloride#
alkyl mercaptodichliorophos')hate, alkyl thiodichlorophosphate
U(140t_
e)j,-A C-*%A C_ A-L"4-~
ABS~kRACT'.* To'broaden the raw material base for the preparation
of alky
dichlorodithiophosphates from phosphorus thiotrichloride, in the
pro-
posed method the latter is heated with alkyl mercapto- or alkyl
thio-
dichlorophosphates at 150-200% under elevated pressures* (W.A. 501
SUB CODEt 07/' SUBM DATEs 30Jun65
Card

ACC NR, AP60334SS SOURCE CODE: UR/0413166/000/018/0039100~_97
~Ap N ~Ks Kvashap Z. N.; Nifantlyev, E, Yes;
INVENTOR: lai;z~.n %11~j
Varshavsk iy .0 ~S..
ORG: none
TIT~E: Preparation of O-alkyl eaters of dialkylphosphinic acids.
Clais 12, No. 185905 [announced by All-Union Scienti 'fic Research
Inspitute of Phytopathology (Vaesoyuznyy nauchno-issledova&al'skiy
insiitut fitopatologii).],
SOURCE: Izobret prom obraz tov zn, no.*18, 1966, 39
TOPIC TAGSt alkyl dialkylphosphinate, phanylarsenic acid
p6t-
ABSTRACT: To obtain biologically active compounds, dialkylphosphinic
acids are treated "with alcohols in the presence of phenylarsenic
acid
as catalyst. The reactior~ is carried out with excees.alcoh,)l and
azoo-
tropic removal of water at 180-2206C. [W.A. 50]
SUB CODE: 07/ DATH.s 15Nov:65 a
Card 1/1
UDC; -547.26'lltl.07

ACC NRt AP6033460 SOURCE CODHt- UR/0413/66/000/018/0040/i
INVENTOR: Bliinyuk,.No K.; Khokhlov, P. S.
0R9: tione
TI LE: Preparation of alkyl dichlorodithiophosphates, Cla-~s 12,
No 185912 [announced by All-Union Scientific Research Inst-tute of
Ph topathology (Vaesoyuznyy nauchno-isoledovatellskiy insti,.ut
fito-
patologii)]
-SOURCE: I'zobret prom obraz tov zn, no. 18, 1966, 40
TOPIC TAGS: alkyl dichlorodithiopho hate, phos horus
thiotrichloride,
.alkyl dichlorophosphate .1 PA"j a"+~-l X I" A&,.2_' 69: AV.-
ABSTRACT: To broaden the raw material base for the preparation of
alky
dichlorodithiophosphates from phosphorus thiotrichloride and
phosphoric
acid eaters by heating the reaction mixture up to 150-200'C, alkyl '
dichlorophosphates are used instead of the eaters of phosphorus
acids.
The process is carried'out at elevated pressures, [W,A, 501
SUB CODEt 07/ SUBM DATE: 05Jul65

ACC
SOURCE CODE: UR/0079/66/036/002/0363/0363
t3~
AUTHOR: Nifantlyev, E. Ye.; Gavrilova,, A. I.; Bliznyukj, N. K
ORG: none
TITLE; New method of synthesizing ethyleneimides of-ph6sphorus acids
,SOURCE: Zhurnal obshchey khinii, V- 36, no. 2, 1966~j 363
TAGS: chemical synthesis, imide, organic phosphorus compoundq
chemical
reaction, esterification, organic imine compowW
ABSTRACT: Throe now methods were developed for synth esizing
phosphoothylenai-:
midos. Dialkyl phosephites wore found to0react with carbon
tetrachloridet
othyloneimino, and triethylamine at 0-20 to form othyloneinides of
dialkylphosphorous acids. Both acid phosphonites,
totraalkyldismides of
phosphorous acid, and all7l hypophosphites take part in the
reaction; in
the latter case diethyleneimides of alkylphosphoric- acids are
fomed.
,Zthylonoimido esters of phosphorous acid are produced by
alcoho3,vsis of
mixed othyloneimidodialkylamides when amino hydrochlorides*are used
as
catalysts. Ethyloneimines of trivalent phosphorous acids can-be
produced
.by reaction of the correspondimg dimethylamides with othyloneimine
under
:considerably milder conditions than under transamination
reactions. These.
reactions are model syntheses and-ar-&-now being used to produce
other-wise
difficulty accessible ethyleneimides of phosphorus acids. (JPRS1
SUB CODE*. 07 SUBM DATE: i3may65
Card
UDC: 547.261328 +

L 31810-66 EWT(1)1i*(WvtNP(J-) ~6~im
ACC NR3
SOURCE CODS4
AUTHOR. Blik" Kolondyots, A. F.; Kvasha, Z# No; Lovakaya, Gt S#a
Antipina, V. Ve
OIG: JM-Union Scientific Research Institute of Phytopathology
(VsesoYuZnYy
nauchno-issle-dovatellskiy institut fitopatologli-)
TITIE't. DiaDyl phosphites and me oal1(y1phosV11Lites
SOURM~; Zhurnal obshchey Ichimii, V- 36, no* 3, 1966, 475-48o
TOPIC TAGS: orranic phosphorus compound, chemical reaction
kinetics, toxicity,
plant injury, chemical synthesia, ester, azootropic PA.-t-uro
AiSTLUCT: It was fowid that diallkyl phoaphitas and
monoall(ylphosphinites are
produced in high 5-iolds (almost quantitative) indopendent of the
temperature
atwhich tho reagents are mixed, and degree of removal of hydrogen
chloride
!from the reaction zone, by boiling the reaction mass, containing
the reaction:
products of alcohols with phosphorus trichloride or
dichlorophosphines, an
asterirication catalyst (such as sulfuric acid or p-toluenesulfanic
acid
band a solvent,with azeotropic distillation of -ter. A preliminary
estimatei
was made of the herbiciddoacti:vity of some of 'the tan compounds
synthesized.)
.In the tests the aboveground portion of the plants (the kidney
bean as a
typical dicot and the oat as a typical monocot) was sprayed with
emulsions of;

L 31810-66
ACC NR- AP66"
.the compounds in a 0.05% solution of the -w*Otting agent-OP-7
in water. 'The'
compounds of this group exhibited high selectivity with respeot
to dicots,
their toxicity depending substantially on the aryl radical (the
-tendency
,coincides with that in aryloVacetic acids), with
4-chlorophenoxyethyl qsters
being the most active. Phosphinites were more
toxio.than_p)~q~phij-kqs. Orig. rti
hast. 3 tables. fJPRsj7
SUB CODE: 07, 06 SUBM DAM 24Aug65 ORIG REF:. 007 OTH REF: 003
Card 212
0 ~I

L 31811-66 EWT(M)/EWP(j) RM'
ACC NRI AP6021679 SOTrACE CODE~ IR.70079/667036/oo3/0480/0483
AUTHORt BUZWWJ~A~- ~*Kolom*yets, A., K
----So Go Iasha. Z, 11.j LeXRhML Go Sj
Zhenchuzliln,
ORG: All-Union-Sciontific Research Institut) of Phytopathology
(Vsesoyuznyy nauchno.
isaled l1skV institut fl-i'ulvetalogii)_
TITLE: Reaction of pherolates with ethylene eblorohydrin and
dialky1chloro
phospliattos in aqueous solutions
SOURCE: Zhurnal obshchey lftimii~, 70 ~6 , no .3, 1966, 1180-483
TOPIC TAGS: phenol, chlorohydrin, phosphate, aqueous solution,
chemical synthesist-
reaction rate, chemical kinetics
ABSTitkCT: The synthesis of aryloxyethanols and dialkylaryl
pihosphatesly
the reaction of phanols with ethylene chlorohydrin and
dialkylehlorophosphates,!
respectively, in the presence of aqueous alkalies was studied. A
change in
-the order of mixing of the reagents was found to substantially
increase t1le
:yields of the products. This was achieved by simultaneous synchronous
addition of the alkyl (or acyl) halide and solution of alkali to tho
phenol at,
a temperature sufficient for a relatively rapid reaction. The rate of
addition of the reagents in each concrete case was regulated so that
the
-reacting substances would not accumulate in the.reaction mixture
during the...,
Card 112 UDCj 547.562:542-951-3/4:546.1

L 31311-66
ACC NR. AP6021679
process; the p1l was maintained constant at a level close to
neutral. The
optimum temperature for the production. of aryloxyethanols was the
boiling__
polnt'~f'tho mixture, whilo that for dialkylaryl phosphates was
found to be 0-250.
This change in the order of addition of the reagents is equivalent
to conducting
the reactionlin a large excess of the phenol, Orige art* hast 2
tables. fJ-PRS-7
j
SUB CODE t 07 SUM DATE;. 24Aug65 ORIG M F 003 OTH REM 006

ACC NR. AP6029020
MNTOR: Bliznyuk I
E
i":.Varshavskiy~ S. L.; L:
SOURCE CODE: UR/0413/66/000/014/0023/0023 I
ts, A. F.; Strelltsov, R. V.; Kvasha, Z. X.;
x a-.
'VQhG:-- none
14
!-.TITLE: Preparation of O-al~xl-S(S-acyloxy)ethy thi
183745. [announced by All-Union Scientific Rese
(Vsesoyuznyy nauchno_'iss1-ed_o_v=ate 'skiy inst1tut fito
SOURCE: Izobret prom obraz tov zn, no. 14, 1966, 23
Pbosphinat?s.v/ Class 12, No.
Institute of PhytopatholoRy
TOPIC TAGS: mercap to ethyl ester,
carboxylic acid, phosphinic acid dichloride 0'e19j9A.1.1C_ Aq0Z
A-104 (A3 041MAO&AA0
PW0,51';Y0A.11C 401~0,'
ABSTRACT: -In'the proposed method, O-alkyl S(O-acyloxy)afhyl
thiophosphonates
.,..of the general formula:1-
(whe'i~~ R and il'.are alkyl, substituted alkyl, substituted aryl,
or
aryl; R" is lower alkyl) are obtained by the reaction of 0-mercapto-
ethyl carboxylates -with a phosphonle ester chloride or with a
mixture
of phosphoni6 acid dichloride and an alcohol in organic solvents in
the presence of HC1 acc~eptors, ee g., tertiary amines. Orig. art.
has: i
I. formula;- [WA-50;- CBE No.
SUB CODE: 07/ SUBM DATE: 28Jul65/
UDC: 547.2613.18.07
Card

ACC NR- AP6029024 SOURCE CODE: UR/0413/66/000/014/0024/00241
INVENTOR: Blizn uk, N. K.; Kvasha, Z. N.; KhDkhlovP. S.; Libman, B.
Ya.; Beym,
A. I.; vershinin r. V. A=
7--
ORG; none
TITLE: Preparation of S.S-dialkyl dithiochlorophosphates-~ Class 12,
No. 183752
SOURCE: Izobret prom obraz tov,zn, no. 14, 19661 24
TOPIC TAGS: insecticide preparation, dibutyl dithiochlorophosphate,
butyl
mercaptani, mercaptan, chlorinated organic compound, phosphate,
pyridine
ABSTRACT;
-To increase the yield in the preparation of S,S-dialkyl
dithiochloro-
phosphates, e.g., S,S-~-dibutyl dithiochlorophosphate, by the
treatment
,of alkyl mercaptans (e.&., butyl mercaptan) and pyridine with
phosp6ryl
-chloride, the reaction is conducted in the presence of ammonium
salts
;of substituted polythiophospho4c acids, e.g., ammonium phenyl
dithio-
lphosphonate.
SUB CODE: 07/ SUBM DATE*. 24May65 [WA-50; CBE No. Ill
Card 1/1 UDC: 547.419.1.07

ACC NRa AP6030566 SOURCE CODE: UR/0413/66/000/016/0034/0035 i
_Khokhlov, P. S.; Dotsev, G. V.; Libman, B. Ya.;
INVENTOR: ZIUA
Beym, A. I.; Troitskiy, V. N.
ORG: none
TITLE: Preparation of acid chlorides of dithiophosphoric acid. Class
12, No..1848631
.SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no.
16, 1966, 34-35
TOPIC TAGS: dithiophosphoric acid chloride preparation, alkyl
chlorodithiophosphate*tl;
aryl chlorodithiophosphate, alcohol
ABSTRACT:
rn the proposed method, acid chlorides of dithiophosphoric acid
RO>PCI -
RIS n
S
(where;R and RI are an alkyl and an aryl) are obtained by treating
alkyl(aryl) chlorodithioph osphates with alcohols or phenols. The
reacti6n is carried out in organic solvents in.the.presence of an
acceptor of HC1, e.g., tertiary amines. Orig. art. has: I formula.
[WA-50; CBE No. 11)
SUB CODE: 07/ SUBM DATE; 25May65/
LTDC:
Cord 1/1

ACC NR1 AP6030568 SOURCE CODE: UR/0413/66/000/016/0035/0035
INVENTOR: Kolondyets, A. F.; Strel'tsov, R. V.; Varshavskiy, S. L.;*
Libman, B. Ya.; Protasova, L. D.
ORGf none
TITLE: Preparatiori of 0,0-dialkyl S-(B-acyloxy)ethyl
thiophosphates. Class 12,
No. 184865. [announced by the All-Union Scientific Pasearch
Institute of
Phytopathology (Vsesoyuznyy nauchno-issledovatel'skiy institut
fitopatologii)]
SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no.
16, 1966, 35
TOPIC TAGS: pesticide, dialkylacyloxy ethyl thiophospha4e.,)
PW0_'PHA7e_
iABSTRAM
j~.To obtain O,O-dia lkyl S-(O-acyloxy)ethyl thiophosphates-of-'the
general
formula:
1'(where Ris a lowe alkyl R' is an alkyl, substituted -akyl', ary'l,
!.or substituted.aryl), dialk;1 chlorophosphates are treated with 0-
:;mercaptoethYl carboxylates in the presence of HC1 acceptors, e.g.,
!:tertiary amines. '-f-IM-50; CBE No.- III
ISUB COI)k: - _07/ * SUBW_Dkff:- 2 8*jul65
I Card 1/1 UDC: 547,419.1.07

ACC M AP6035682 "M,';6---SbiT~d_CODE: UR/ 413/66/000/019?003 0030
'0
111VEN"IOR: Bliznyuk, :N.. K.; Kvasha.,, Z, Varshavokiy, S. L.;
Libman,
B. Ya.
ORG; none
TITLE:-Preparation of esters of trithiophosphonic acids. Class 12.,
No,1
'18'6464 [Announced by"All-tynion Sdientific Research Institute of
Pny+ap9A6kjj,
,(Vsesoyuznyy nauchno-issledovatellskly institut fitopatologii))
SOURCE: Izobreteniya, promyshlennyye obraztsy, tova'rnyye znaki,
no. 19,
1966, 30
TOPIC TAGS: vWidAgkaphosphonic acid~ester, mercaptan, tertiary
amine) a"
To increase the yield.in the preparation of esters of
kBSThACT: trithiophosphouic acids by the reaction of alkyl (aryl)
thio-
phosphinic acid dichlorides with mercaptans, the reaction
is conducted in the presence of amine salts of polythio-
phosphoric or polythlophosphonic Acids as catalyst. -The
catalysts are formed during the reaction when tertiary
amines and phosphorus sulfidea are added to the initiaL
reaction mixture,
I (WA-50; CBE No. 141
SM CODE; 07/ SUBM DATE--,l5Sep65 (PS]
/i, cardlA-- UDC:547,26,118.07

ACC NRIAP6035683 (A I w~ '=A' 3- -.'-ijA/C4f M66-1666-16,i 9
6~1-10-dyi-
CE CODE
INVENTOR:' Blizn u1c, N. K.;_Kolomiyets, A. F,; Ivershina, L. P.
-'ORG: none
TITLE: Preg2vrvion of phosphonic ester chlorides. Class 12,
No.i86466
SOURCE: Izobreteniya, promyshlennyye obrazts~, tovarnyye znaki-,
no. 19,
1966t 31
TOPIC TAGS: phosphonic acid,ester chloride, atimB phosphinate,
phosphorus -Amachloride C-avv,~A" %,T6A-,C.0
ABSTRACT; To broaden the raw material base for the preparation of
phosphonic ester chlorides from monoalkyl phosphinates
and a chlorinating agent, a mixture of phosphorus trichlo-
ride and chlorine is used as the chlorination agent*
[PSI
(WA-50; CBE No. 141
SUB CODEt 07/ SUBM DATE: 04Sep64.
cardiA UDOA 547.261118.07

SOURCE CODE,--.- UR- 6-4f -~-16
-AtC - NRA P6035087 (A, A 6760bloY�'d
INVENTOR: Kvasha, Z. N.; Ko Xomiyets, A-. F.;
Varshavskiyj 8, L.; Libman, B. Ya.
l
ORG: none
TITLE: Preparation of O-alkyl O-aryloxyethyl methylphosphonates,
Class
12, No. 186473 (Announced by All-Union Scibntific Research Inst
'itute
of Phytopathology (Vsesoyuznyy nauchno-isaledovateliskiy institut
Citopatologii)]
SOURCE: Izobreteniya, promyshlennyye.obraztsy, tovarnyye znaki,
no. 19.,
1966, 32
TOPIC TAGS: aabauDphosphorus compound, phosphonate,
ABSTROT: In the proposed method, 0-alkyl 0-aryloxyethyl
methylphos-
phonates are obtained by the reaction of 0-alkyl methyl-
chlorophosphonates vith aryloiyethanole in the presence of
HC1 acceptors,.G.g.,'tertiary amines.
(WA-50; CBE No. 1)i)
SUB CODE: 07/ SUBM DATE-.,.26ju165
I Card 1/1 UDC:5
*Cps)
1118.07

I'ACC NR,AP6035829- -SOURCE CODE:
IINVENTOR: K.; Xvanha* Z. N.
ORO: none
TITLE: Preparation of alkyl~(aryl) dithiophosphonic acid anhydridesf
Class 12, No. 187016
SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znak-l-,
no. 20,
1966, 36
TOP-10 TAGS: 099aasphosphorus compound, dl**&;~* hoSDhonic-
aoidvanhydride
To simplify the process for preparing anhydrides of alkyl-
ABSTRACT: (aryl)dithiopho phonic acid.s bq,the',reaction of
alkyl(aryl)-
'thiophosphonic :efd dichlorides with H2S on heating to
125-130*C, the reaction is carried out in the presence of
;.gtalytic amounts of pyridine, quinolines or their deriva-
tives*' The reaction is conducted in an or-gauic solvent,
coges.chlorobenzeus,
'[WA-50;-CBE NO-.141
SUB CODE: 07/ SUBM DATE: 2lDec64
Card 1A UDC:547,241-312.07

ACC NR, AP6035832
CoYr-.-. V976V3/66/ 076~~C/66jf/V0311
jalmov,0 0. V.; Libman, B, Ya
INUNTOrx: "DI;LZny Troi
V*. N.; Miolchlov, P. S.; Dotsev, 0. V.; Kalutskiy, L. A.; Beym, A. I
Verhsinin, P, V,; Mandel'baum, Ya. A.; Varshavskiy, S. L.; Mellniko~,
N. N.
OM none
TITLE: Preparation of derivatives of tri- and tetraphosphoric acids6
Class 12, No. 1.87019
SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye snaki, no.
20
1966, 37
TOPIC TAGS: m* alkyl trithiophosphate,
alicyl tetrathiophosphate
A(IA
ABSTRACT: 1. the proposed method for the preparation of derivatives
of tri- and tatrathlophompboric acids of the general formu-
las
L-C#!d 1
(RS),,PXRI)
07

Ap6o3f.:832
(where R is a lover alkylo RI Is a substituted alkyl or
aryl, and X in O.or S), physiologically active compounds
with low toxicity to manuals are obtained by treating di-
alkyl-trithiochldrophosphatos vithalcohols, morcaptans,
or thiophanole In organIc-solvents In the presence of HM
acceptorag preferably.tertlary amines. [PSI

ACC NR: AP7013151 SOURCE CODE: UR/0413/66/000.*021;0040/0040
NVEWOR: BlIznyu Khokhlov, P. S.; Libman, D. Ya.; 'Vershinin, P. V.;
Beym3, A-.T.--,-Va-rshavskiy, S. L.
ORG. none
TITLE: Nothod. for preparing alkyl(aryl)dithiodichlorophosphates,
Class 12,
no. 187785
SOURCE: Izobretanlya, promyshlennyye obraztsy, tovarnyye znaki',-
no. 21, 1966, 40
TOPIC TAGS: heterocyclic base compound,.mercaptan, organic phosphate
SUB COUE:' 07*
ABSTRACT: A method Is claimed for the preparation of
alkyl(aryl)dithio-
dichlorophosphates, which differs in that forthe purpose of'extendinw
the
utilization of, resources andincreasing tho yield of useful products,
phosphorous thiotrichlorido is subjectedto-reaction with mercaptans;
In the
presence of catalytic quantities of heterocyclic bases, for example
pyri-
dine. 1.3-1PHS: '40,4
Card

ACC W AP7013152 SOURCE CODE: UR/0413/66,1000:021 0040:0041
MEITOR: ilAznyuk, N. K.; Ehokhl6vt.P. S.; Dotsev, G. V.
DRG*. none
TITLE: Method for preparing alkylthiondichlorciphosphatest Class 12,
No. 187786
SOURCE: Izobrotenlya, promyshlennyye'obraZtsy, tovarnyye znaki, no.
21,
1966, 40-41
TOPIC TAGS: acrylonitrile', phosphate, Alcohol, organic phosphorus
compound.
SUB CODE: 07.
ABSTRACT: A method Is clained for.the preparation of
alkylthiondichloro-
phosphates by reaction of phosphorus thlochloride with alcohols,
differing
In that for the purpose of obtaining higher
alkylthionidichlorophosphates,
the process is conducted In the presence Of 4 hydrogen chlorlde
acceptor,
for example acrylonltrile. LJPRS: 40AL27
Cwd 1 UDCi 547.27,118.07

IVANOVA,, Z.V., kand. sellskokhoz. nauk; BLIZNMLN.&~ kand. kbim. nauk;
KOWN:EYETS.9 A.F.; FULYAKOVA, R.V'.-
Now means for controUing pests in empty granaries. Zashch.
rast. ot vred. i bol. 7 no.9:39 S 162. (MIM 16t8)
(Granaries-Disinfection)

_ BLIZNMMKL INI.N._* 19WBOTICH, Tu. A.
Radar observations,of Draconids In Met.
Astron.toir.
no.206:8-9 D 159. (XIBA 13:6)
1. lafedrs astronouli Kiyevokogo gosuniversiteta.
(Netepre-October)

S/1 69/62/X0V606/088/093
73 D228/D304
A-U T.H 01.1 Bliznyuk, N. No
TITLE; Radar observations of auroras in Tiksi Bay in 1959
PERIODICAL: Referativnyy zhurnal, Geofizika, no. 6, 1962, 26, ab-
strazt 6G147 (8b. rabot Do Mezdunar. geofiz. godu,
KiyevBk,'un-t, no. 1, 1961, 76-81)
TEXT: Radar ob~sex;:4ations were made in Tiksi Bay on 4-meter-band
'stations. The pulsd duration was 8 ?sec, the repetition rate was
50 c/s, the pulse power was 110 kw, the receiver sensitivity was
10-13 W, and the range indicator screen scan was 1050 km. The ob
servations were conducted at a noise track height of 4 mm. The rad-
ar worked on two identical Uda-Yagi-type antennas, each being a
metallic pointer on which nine vibrators were placed. The antenna
pointers were arranged one above the other in a vertical plarle:
the upper at a height of 11 m, the lower at a height of 7 M. Both
-antuenna systems were designed in the form of one rigidly coupled
Card 1/2

391P4
S/16 62/00 6/088/q93
Radar observations of ... D228YD304 0/000
device, fastened on the reductor's axis, by means of which
their
circular rotation was,realized. It follows from the diurnal
varia-
tion of the appearance of all forms of auroral reflections in
1959
that there is a maximum for the appearance of reflections
around
midnight local time.' The diurnal variations of the appearance
of
diffuse and discrete auriral reflections in 1959 are given. It
is
established that reflections are observed only from auroras of
a
radiant structure. ~-Abstracterls note: Complete translation._7
.--01
Card 2/2

3,1910
8/194/62/000/007/111/160
D271/D308
AUTHOR: Bliznyukq N.N,
TITLE.- ~adar~obs~ervat`ions of aurora borealis in Tiksi'Bay
during-1959
PBRIODICA1% Referativnyy zhurnpLl. Avtomatika i radioelektronikap
no. 7, 1962p abstract 7zh3OO (Bb.-rabot po Mezhdunarv
geofi,%. godus Kiyevsk. un7tr 19619 no. 1, 76 - 81)
Tj;XT: Main paramet-6ra of the radar station in Tikei Bay and me-
thoda of radar obsef,vation of aurora borealie'.performed there in
1959 are described.,--Characteristici of radio reflections'are shown''
flections are gkien-only by aurora orea-.,k
It is established th4t re b
lie of radial structure and that signals reflected during the-Polew,
day in no way differ from those.in other seasons* LAbstracter's
notes Complete translation.]
Card 1/1

BLIZNrUK) N. N.
- -----------
Hadar observations of auroras in Tiksi Bay in 1959. Sbor. rab.
po mezhdunar. Geofiz. godu no.1:7641 161. (MIRA 15:10)
(Tiksi-JIadar meteorology) (Aurorae)

SEDMOV, Yu;S*') gornyy insh.1 DAVIDOVICHj I.I., gornyy insh.;
BLIZNYUKI
P-F-p gornyy inzh,
Record set by.Dobropolle miners. Ugoll Ukr. 5 no.4:35 Ap 16:L.
(MM 14:4)
(Donets Basin-Coal mines ana mining-Labor produotivity)

BLIZNYUK, P. Ya.
Bee,Culture
11
An argument for "cold, wintering of bees. Pchelovodstvo 29,
No. 1, 1952.
Monthly List of Russian Accessions, Librar7 of Congress,
May 1952, UnCLASSIFIED.
M

BLIZ14YUK, S; L.
Bliznyuk, S. L.
"The Connection between Theory and Practice ;Ui the
Training of Pupil.9.11
Kiev State U imeni T. 0. Shevchenko. Kiev3 1954,
(Dissertation for
the Degree of Candidate in Pedagogical Science)
So: Knizhnaya letopisl., 110. 27j 2 July 1955

BLIZNYUK. 4-,L kandidat pedarogichookikh nauk.
1" --
TechnicAl education and the relation of theor7 to
pmetice.
Politelth.obuch. no.7:10-13 JI 157. MIRA 10: 7)
(Technical itducation)

BLIZNYUK, V.A., inzho--elektromekhanik
New weights-measuring transducers* Goro zhur. no-9:52-54 S*
162. (MIRA 15:9)
1. Gosudarstvemlyy institut po proyektirovaniyu oborudovaniya
P,0 dobyahe i-obogashcheniyu rudp Krivoy Rog.
(Strains-and stresses-Measurement)
(Mining enginsering-Eleotronio equipment)

- - I - 7 ~ " , , -, . r I
I( ~ . , .1 ' , j 1. '; . i ~T c i-,,,.,r,4 , -
t tc I 1; 1,* G. , k wA . f ok.'k-m . n -.!.I k
w... c
Bibliog.raj--hy. Prof. tokh. obr. 21 no.1101 III
t t "'
( 1" ~ ii;~-,*, ILs -.2 )
1. DKIlwAskly PE'-Jag(,g',,heBhAy ir-stlitut
(,ca, B!l2nrLd-).

BLIZNrUKp V. A., insh.
Automatic counting.of loaded cars in mins:transportation.
Not. i gornorud. prom. no.1:51-53 A.-F 163,
(MIU 16:4)
1. Gosudarstvennyy ine'titut po proyektirovaniyu oborudovaniya
po dobvehe i obogashchaniyu rudl Krivoy Rog.
(Mina railroado-Cars)
(Automatic control)

CHITAYEVAp S.A., insjh.;L,!L- ~ZNM-)--VfA--s insh.
Portable vulcanizer. Gor. zhur no.401 Ap 163s (MI% 16:4~
.
ls Gosudarstvannyy institut po proyektirovaniyu
oborudovaniya, po
dobyoho I, fbog"haheniyu rud, Krivoy Rog.
(V4canization-Equipment &nd oupplies)

VYDREVICHI B.I.; KARANDASHOV, Yu.I. j GAVRILIN t
L.F.; AL1ZkqRWpy,-4
-M-A-4.KOLITSOV, M.M.,- YAVNIITICH, Ya.A.j
FROLOVA,
O-A* L.A.; MOSYAKOV., Yu.F.
[Metal products for industrial use; a handbook]
Metallo-
izdeliia promyshlennogo naznacheniia;
spravochnik. Pod
red. E.A.IAvnilovicha. Moskva, Metallurgiia,
1966. 727 p.
(MIRA 19:1)

ARSIRIY, Yu.A.; BLANK, M.I. BLIZVW, V.F.; GLUSHKO, V.V.;
KLITOCIENKO, 1.41'.1 LITVIRUV, V.R.; PRIJ x.A.M.; PANIKIV,
A.M.;
FISTRAK, R.M.; CHERFAK) S.Ye.; CHIRVINSKAYA, M.V.;
YARCIIENKO, L.M.
Plan for the areal study of the Dnieper-Donets Lowland.
Trudy
VNIIGAZ no.14:3~-17,162* (MIRA 15: 5)
(Dnieper-Donets Lowland-Petroleum geology)
(Dnieper-Donets jmUnd-Gasp Natural-Geology)

BLIMUL V.&, otvatetvannyy sa vypusk; TOWN, DA.,
tekhnicheakty
re
o r
(Collection of designs of spare parts for wide gauge
railroad ears:
undercarriages and impact couplers) Allbom chertezhei
zapasnykh
Cletalei vagonov zheleznykh dorog shirokoi kolei;
khodovye chasti
i udarno-steepnye priborys Xoskva, Goa. transp.
zhsl-dor. izd-vo
1956. 386 Pi (MLRA 9.-i0)
1. Russia (1923- UI.S.EI.R.) Gjavnoya upravlaniye
vagonnogo
khosMetva.
(Ra-ilroade--Cara)

BLIZI otvatstvanyy s& vypusk; 201MOVA, U.N., takhnicheskiy
redakto_~'.
US 1P
(Collection of designs for spare parts of broadgauge
railroad cars;
brakes] Allbom cherteshei sapasnykh detalei vagonov
shelesnvkh dorog
shirokoi kolei; tormozuoe oborudovanis. Moskva,
Gos.tranep.zhel-dor.
izd-vo, 1957. 234 p. (KIRA 10:11)
1. Russis, (1923- U.S.S.R.) Glavuoye upravleniye vagonnogo
khosysystva.
(Railroads--Brakes)

BLIZNn-K, V.P., OtTetstyOUM57 Sa vypusk; BOBROVA,
Yo.N., tekhn. red.
of designs of spars parts for broad gauge railroad cars;
body parts and interior equipment for freight caral
Allbom
cherteshei "apasnykh detalol vagonov zheleznykh dorog
shirokoi
kolei; d6tall, kizovovi i vnutrennego, oboradoyaniia
g'ruz'ovykh
vagonov. Moskva, Goo; trausp, shol.-dor, izd-.Yo, 1958
263 p'
(xIU 11to
1. Hassia. (1923- XJAX) Glamys, upravletdye vagonnogo
khozya;~stya,
(Ballroado-Preight care)

KOMAROV, S.G.; SAXOKHVALOT, S.F.; BIZAVNBTSNV, N-V-;
BOMBARDIROys-P-P-11
AMILDIA, A.A.; BLIUM, V.P.; L&MIN, V.I.; PEROT, A.B.;
VASILITU,
I.P.; 3RODOVICH,'-W-.Sr.-,-XM , A. M. ; AT 3m. V.D.;
Ymmor,
V.A., iuzh.,red.; ARSHINOV. I.M.;insh.,red.; VERINA,
G.P.,tekhn. red.
[Handbook on. the repair of freight -ral Spravoebaik Do
remoutu
gruzovykb vagonov. Moskva. Goa. tranwi-0 shel-dor.
izd-vo. 1958. 503 p.
(K-In
(Railroads--Freight cars--Maintenance and repair)

BLIZNYUK, V.7,, otv. za vy sk; BOBROVI, U.N., takhn.red..
[Automatic couplers; designs of automatic coupling equipment
for
wide-gauge railroad opre and models for testing purposes]
Avto-
steepka; charteshi avtostespnogo oborudoTaniia vagonov
shelesnykh
dorog shirokoi kolei i shablonov dlia ago proverki. Moskva,
Goo.
transpe shol-dor, Izd-vo, 1958. 284 p. (MIRA 12:2)
1. Russia (1923- U.S.S.R.) Glavueye upravlenlye vago4nogo
khozyaystva.
(Car couplings)

BLIZOI v VeFop otva sa vypaskj BOBROVA, Te*N6,, takhn.red.:
(Album of track designs for all-metal passenger ears] Allbom,
oherteshei, telesfiek toollnometallicheakikh paseashirakikh
vagonov, Mookvao Gos*transpoz6l-rdor.Izd-vo, 1960. 124 p.
(MIRA 13:5)
1. Russia (1923- U.S.S.R.) Glavnoye upravleniye vagonnogo kho-
2yaYstva,
(Railroads-Passenger cars)

BLIZIP .; GAVRISH., V,Ks; GRITSAY# Ye.T.; KELIBAS, B.I.;
KLITOCHENKO, I.F.;
4_LZ,,
MARTYNOV,, A.A.; FALIYp A.M.; FOPOVp V*S.; SHAYKINp I.M.;
YARCHENKO., L.M.
Stratigraphic boundaries and oil and gas potentials of the
Upper Cretaceous sediments in the Dnieper-Donets Lowland.
Geol. nefti i, gaza 8 no.4t2B-35 Ap 164. (MRA 17:6)
1. Glavnoye upravleniye geologii i okhrany nedr pri Sovete
Ministrov UkrSSR, Kiyevskaya ekspeditsiya tresta
Ukregeofizrauvedka,
Kiyevskaya ekspeditsiya Ukrainakogo
nauchno-issledovatel'skogo
geologorazvedochnogo institute i Chernigovskaya ekspeditsiya
Ukrainskogo nauchno-issledovatellskogo geologorazvedochnogo
institute,

BLIZNYUKt V. M.
BLIZNYUK, V. M.: "The surgical treatment of adenoma of the pros-
tate gland in patients with and without si#estrol treatment".
Sverdlovsk, 1955. Sverdlovsk State Medical Inst. (Dissertation
for the Degree of Candidate of MEDICAL Sciences)
.SO: Knizhnava Letonlal No. 51, 10 December 1955

3uZam.-J.H. kandidat meditsinakikh nauk
Two-stage transvesiaal adenomactomy in adenomatous hypertrophy of the
prostate. Urologiia 21 n6-3:18-21 JI-3 %. (WBA,9:12)
1. Iz urologicheskogo otdalanlya (zav. V.H Bliznyuk) Sverdlovskoy
oblaati klinicheakoy bollniisy No.1 (Glavn.V vrach U.S. Levchenko)
(rROBTATI HnWnOPHr, surge
two-stage transvesical adenomectoaq)

BLIZNYUK, V.R.i kand.med.nmuk; ASTAVY]OV, D.A.
Immediate and late results of vesicomigmoid anastomosiss
Urologiin
23 no.2:8-12 Mr-Ap 158. (MIRA 11:4)
1. Is urologicheekogo otdoloniya (zav. T.N.Tratlyakova;
konsul'tant
Imndidat neditainakikh nauk V,N.Blisnyuk) Sverdlovskey
oblastnoy
klinichookoy bolluitey (glavnyy vrach M.S.Levchanko)
(BIADIDERp surge
vesico-sigmoid anastomosis, immediate and remote
results (Rus))
(COLON. surg.
same)

BLIZNM, V.H. (Sverdlovsk. 6# uIj Tobollskayn. d. 31.
k7.2)
morlg"eor;y i adenoma of the prostate gland. with and
without pr io
6v us
synestrol therapy.' Nov,'khir.arkh*- n0,'2:81 Mr-Ap
158 (min 11.-6)
1, Urologicheskoye otdeleniya (zar. - V.M. Bliznyuk)
Sverdlovskoy
oblastno.v bollmitsy No.l.
(PROSTATE GLOU6-SURGERY)
(3CSTROms)

BLIZNYUK, V.M.
-----------
Intra- and extraorganic lymphatio system of the bladder and routes
of lymph flow from its various segments. Urologiia 26 no.1:41-46
,61. (KIRA 140)
(BLADDER) (LYMPHATICS)

BLIZNYUK, V.M.,, dotsent
Resection of the bladder in epithelial tumors. Urologiia 28
no-3:4-1-45 163 (MIRA 17:2)
le 1z fakulftetskoy.khirurgichoskoy kliniki (zav. - prof.
V.F.Kolosovskaya) Sverdlovskogo meditsinskogo instituta.

W.-W v so
0 a 11 it to ti ti it J. a AS it 11 M 0 M a At 0 -&--iv- iv a-
A C A a A Ut-A-T-L~AA A IZ a-04j-- A C )-j- I -.v -o
00 4 1 St xottl-s up up! as lot, ..t,
6.0 "COID111% 1.919.
good of MIGation,
00 A! A; d the Llk-opfw=uk. M. Mth-h1foaggae"naikov and G. U.
of rekkXikd VO~d*$kWg* )7014 1939.
_M%,"Itet of superdwSe on the comparative
go C v1dustiort of lot knock of motor fuels was studied with a
so a Wauktsha enthoe using (ormuy Aviation g"Oh"t, Baku
poolint, OrA Casolim. arod DubroW inecontg.ribyl
fluid w c. p. beuxem. The antiltnocrIffect of The c1hyl
00 A Ouid was apparently not affected by supercluirting.' The
Frintrat stability t knocking was shown by unloatd.
00 1 cvmlpds.. the naph=t and aromatic conigods. were atwout -00
of &:! equal but both we.. next to the unsatd. complis.. wW)c P
see
00 the pareffins knocked the worst. The odane number
dttd, I the C. F. R. tarthod gives im Indication of the
00 value the fud for work under su har oul hen
thalt Is a mail difialcom lu to 10CM. 9 =X of
60 pu&Sw wA umatil. comiz. Wban the clifference is no*
00 larp, fob with dw satas mt Is properties under
v4pstcharging will bave diffwant ectiAme sambers by Um
00 Z C, P. R. method. Such discrepancies may reach lip to are 0
four Octane Units. 11, Z. K211fich
.4A
fie 0
1 9-2- tj
4- SITALLUNOW-AL LITINAIM CLASUPICATIC)" 0
0
I %Jaw Ito 0
40104Q, wit o4v out 411131 a" a.. M
U 0 AV 10 11 -Aj 0
to to 1, to a of it a W" S, U st no A I is, ad 0 to IF I If IN 9
All .4 3 1 1 44 - , .
d�ril
4 1 0 0 1 9 0 * 0 O's 0000 0
:0 0 0 0 o'# 0 0 0 0 090, ,
OT 4
40 180,0010 0 0 0 0 000 0 4W0 0 0 0 0 610 o go 0 0 0 0 0 0.40 Wo

SOBOM, S.K.-, insh.; EM N, V.A., kand.tekhn.nauk; OUS, G.N.,
doktor tokhn.nauk: MIN, X.G., doktor takhn.neuk, V rabote
-pr4v&4 U uchastiye; BWZNMOV, S.A..; ROZEKOY. I.M-;
RLLUM I V. S.
Desulfuration of pig iron outside the blast furnace by lime
with the additionof aluminum powder. Sbor.Inst.stali
n0-39:5-15 l6d. (MMA 13:7)
1. Kafedre, metallurgli stali Moskovskogo ordena Trudovogo
Krasnogo Znameni institute, stali Im. I.T.Stalina.
(Cast iron-rXetailurd) (Deoulfuration)

3 7 2 318
s/148/62/000/003/003/011
d. /1,06 E071/E435
AUTHORS: Vishkarev, A.F., Kryakovskiy, Yu.V.,
Bliznyukov, S.A., Yavoyskiy, V.I.
TITLE; 'inftuence of rare earth elements on the surface
tension of liquid iron
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy.
Chernaya metallurgiya, no-3, 1962, 60-67
TEXT: The surface activity of rare earth'elements in iron is of
importance from the point of view of their modifying effect which
is caused by preferential adsorption of surface active
components on faces of growing crystals, inhibiting their growth.
In multi-component systems, changes in the surface tension could
be due not only to the'adsorption of a given component but also
due to various physico-chemical processes taking place in the,
melt (e.g. deoxidationidesulphurization, changes in the activity
of other components),'for this reason the influence of rare
earth elements on the surface tension of specially purified
liquid iron was measured (not more than: 0.020% C, 0.015% Mn,
0.005% sit 0.0028% P9 0.002% S and 0-003% 02)- The metho(F
Card 1/3

E0
60
s/i48/62/000/003/0()3/011:
Influence of rare earth ...
E071/E435
consisted,of measuring the maximum pressure of gas bubbles in
vacuo or in a controlled atmosphere,. Well purified argon was
used for blowing bubbles and as a protective atmosphere. The
apparatus and experimentalprocedure are described in some detail.
It was found that cerium and lanthanum are surface active. In all'
cases, first additions of cerium (up to 0.45%) lower the surface
2
tension of iron by 100 to 120 erg/cm , whilst further addition of
cerium increases the surface tension of iron due to its reaction
~,with oxygen,,.~and sulphur. Lanthanum acts similarly but a.
decrease in the surface tension was noted only after the first
addition (0.1%).~ This is explaine&'by a higher deoxidlizing and
desulphurizing ability of lanthanum in comparison with cerium, 1
The influence of the admixtures present in iron on changes-in the
surface tension on the addition of rare earth elements (Ce, La.,
Nd-, n
Pr) was-demonstrated-by using ordi ary armco iron and
carrying out experiments without a.protective atmosphere. In thi
case additions of rare earth elements-caused an increase in th
surface tension of iron; only irk a few cases was a small decr
observed after the first addition. This indicates that the,
Card*2/3

BLIZNYUKOV,j5#A.; VISHKA]MVp A.F.; VAVOTSKIYj Vole
VIIA%3~.V-I>----
Equipment for detomining the surface tension of liquid
metals*
Izv. vys. ucheb,., mw.! ket, 7 no&7:227-Q32, 164
1
(~rm 17:8)
1. Moskovskiy institut stali, i splavova

,X XMAIJUvp~Ko aid
ViAP yM':by dip
OOS idd.
00 tbobWl 1""deddsb ^a see
It mom
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ce 41
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was
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it
S. 5 L A IKTALLWWAL LMNATWI CLASWCATM
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u ii it it it it-it vi
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owl 9
toltaliltal MASSOWIN
dillt
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lot
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still,
d v 1 4
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0" &-~KSUUAW "OSITARS NMI
The
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Idw N!
0~ =- -~ N., =ag
194

.
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6 Chems. (U
A. 5"'AU "so of sn"O"Mim
w
obset"I In the
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t
ture
A
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ruc
s
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e
many s
u
MMUSM

16 0 41

vwm of wip -em and pyrzat

mone. The Ph-

codynamlepiVer
lesof thearcumpd

t. have a definite frIa.

flou to the

Ism teed
hirdtaitianudkmenwtum. The

decream o

f toxielty and auttpyretic
action of the phenyl-

hydisAut I

n 6 cauved hy

000

the sUte of
"sonsom In the pymxdom ring. Physiol.

066

actim of antipyreas Is tonvased by substitution of hie

in the
2-position, whkh causes ad too" of basicity of

0043

the N and
this In tum. facilitates tbt d-mlopment of the

004

henyUydradve
structure. Tbt'wtion of tip IN
arreawd by subultution of N&Iq In the 4.
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-
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m
transition to the Pyrarnklone structure).

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a lit color in I and the formation in Moll and

of comprIs. of
biradical type (revealed by the ah-

a see

99,3
tion rai were obqervrd. The tran-ition of 1
an Man er the Influrnecof NaOlit
into ult-like min
xt,

~04
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afa biradicat tym withan increav n(the intruirity 44 tire

40 0

3
pritutry volorsition was also i4-scr%vd. Grmt nubilivy 4

coo
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ing separately hydmw&azo structures of pheny1hydraxior

9
and the emjupted %"irm MCCIUChir. and al~

AL-
(Weparately) the
pyrsit4our and benzene ring structurr~

with the establishment
between them of a mi"le state of

40 a
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oir
f M
i
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806

upon the duration of act
on a
aout. o
w
m , tatc

oorrevondins to the pyrarolp Hot and then to bettrew.

with the formation of colored nit-like compris. of the bi-
di
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d
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1

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ow
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ence of all the ahme structures and the tv"bility of their

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nee

A.
A. Porigorny

A I a I L A SITALLUKKAL LITERAU41 CLASWKAI - R_z*1r=__=.=__

00
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I A
As If NW. N. A. Valyuh 0. Sn Auld'
A. R. LutsW. Trudy Whar'kar. -W.JAM~Iov loss. -
jo.S. M.Kirpm No.4,4"(1944).-InwaWil tubes, NA, *00
few" with ftme with The stitratiou bess. .0#
Istif mainly an (be Me. to a fewer extent an the ring.
-11AMC (92 C.) with 21) 9. NA (maw ratio 123) at WO. 1 .6
atm., 24 - In.. about "% allsololotnts. lJ-J2% j oltrotoluents
am not any further Ill lot
00:4 t (CO#H)#, 10-16polluds of altrailoo at the Me Smull, Well
with NA;
WIl. 14 - 'be" Is no ~ioa over the iuttrttlWiste stage W "ro'.
**a 4-6% Tstd. wit NalL -24% uhreseted tolu,". u1se, Ac.0 06
go& 0 at 00% the same results were: obtained in I hr. In Oome
toluene was formed. wall 1`01-d by AcOli, on triaitro~
cam (after 160 hr*. at 3U*, after 1.6 hm. at 7W) ca * 0 S. Thm
omarred. Catalysts usuatr favoring nitration of rts a**
(imline, Fe, Cu. and Jig norstes) failed to Indu m-e the
b-rewumwithNNA. EX00WACAnbellreve"twIllywfluff
60*6 the reaction tube with UtAink" sttd %havillp, " by
dils. with PhN(h or CC14; an amt. of dilutut double that
0 * .3
1.~ of the PhMe doLs not inhillit cithar nitration at tl* Me
.00160
or addation. IxTreashis the mot. of NA from
1.7 mok-s (per look PhMc) also resulted in
slower reaction. Notration of the. i is prolnoted by
widn. of Ar.0, with 0.27 took AW,fp: Z lphmo, 2 S, 0 0
at "0. 1 hr.. 2.4.6-tsittitrotoluene wall obtairdl]
from an Nutmal. ruixt- of rhme + NXN with 0.6 oluie
CC340 the yiem Of thL nit"Aalutne (Cadim being autt; *40
as against 17% with only O.UG took AcjO; further In.
amw of the amt. of Ac*O is unavailing and may C3uW
7, . I
-Pbd-. as does increase of the temp. to a unja& ilm
ansts. of reactanis we changed or higher dilo. with CCI,
is used: 140-1t; NM - I - 1 .2 tuols.. with 0.9 took CCI..
0.4 took ArP, at 70*. 3.5 Jim, gave 11% 2,4.6-ttinitru,
tobatm, 30% total nitrotoluene fraction. The town.
Vo*
S&NOW "is O-V Ag ji
WOOD *A
-U aAT oo- it 1 0 1 W 14 5 a a 3, 1 V
to t#0 Ot 91 It a- it U It d1a;
0 0 6 0 00 0 00 a 0 * 0 0 * 0 0 o * 0 Go* 6! /'/
0 00 0 010 0 0 0 0 0 00 0 0-0%9 0 0 0 0 0 00 0 0*0 *1

IILIZNTITKOV, V. T.
"Absorption spectrs and electronic structure of quinoline
derivatives which serve
as starting wterial for antimalarials. I. Tautomerism of
isomeric 2- and
4-aminopyridines." (p. 1204)
SO: Journal of General Chemistryt (Zhurnal Obahchei Khimii),
21,952, Vol...?2 No. 7.

.-:~ . . . -, :-. ~z
.- ... . -:-i~
~. 1, , " - ., 1~2 , ,I , , , -
.1.1 i , - -- - -'! -
,, , ~ ,, - ; , , ~, . R -_ . ~:
,-- -.. . . - I t2i. P ~ ,
- - - - - - ~. Nf., - , ..- il
.:. ---, ~ - - e -1 1.

V* 1.
YSSR/Chemist ~~,iuwvdutbqals.. 21 Aug 53,
'Mutual Influence of Substituents in the
Antimalarial
Comp ound 'Quinoline 45,-"L~V- 1. Bliznyukov
DAN SSSR, Vol 91, No 6y pp 1337-1340
~,The ring nitrogen in "quinoline 45," 1. e...
6-methoxy-
4--
(4,-diethylamino-11-methylbutyl-amino),-quin6lin
e)
is an electron acceptor with regard to-the group
j in neutral solns,(meta.orientation),,and an
electron
c tho, pars, orientatio
.,Ionoi (or n),vith regard to the
O.CH3 group. When positively charged, the ring
nitro-
gen. becomes.an electron acceptor exclusively
with
6.
1-i6spect to,both the, .4 -NH -_md OCH3,groups,
.2 _the
MIS - vas detd~-.,~ by~ abior'ption
spectroscopy.
Pieseated ~.bj,,Acad V. M.. Rodionov 22 Jun 53.

N CA/ vt:
,physice ezdstry Molecule, Chemical Bond. B-4
Abs Jour: Referat - Mmrual MximdYa, Ito 3, 1958, 6923.
Author V.I. B3-iznyuk6v, V.M. Pa=ikov.
'Inst,
Title Absorption Spectra and Structure.of Substituted Quinolines
Serving as Initial Products of Antimalarial Medicaments.
III. Tautomerism of 2- and 4-oxypyridines. 010
Orig Fab: Zh. obahch. khimii, 1955., 25j, No 9, 1781-1794.
Abstract: The ultraviolet absor
ption spectra of 2-axygyridien (1), 4-
aqNridine (II), 1-mtby1-2-Fyr1dcme and 2-ethmqpyrigne in
neutral solventaj sulfuric acid and soclium ethanolate were
studied. It follove from the, similarity of the ultraviolet spec-
tra of I and 3:1 with the spectra of their N-metbyl derivatives
1. . -'-- 4- T -"A rT 4a 1r%rm+.aA a+. +ligm -M-my M+"^m=-n_ T+

USSR/Physical Chemistry - Molecule, Chemical Bond.
Abs Jour; Referat- Zhurnal MdMiYa, No 3., 1958j, 6923-
46",
B-4
0-ox7acetophenone and 2- and 4-aminopyr-idines that the ring
nitrogen in the molecules of I and II is an electron attracting
atom, and oxygen is an electron giving atom. In accordance
with the abovej. following structm-e formulae of I and II are
proposed. DependJmg on the reaction (medium) conditions, the
molecular electron system can be aeformed withproducing a re-
action center either on oxygenjor an nitrogen, the result of
Card 2/3 -13-

q UWPhysical Chemistry - Molemae: Chemical Bond. B-4,
Abs Tour: Werat. Zhurmal IQAmiya., No 3, 1958,, 6923-
which will be a dual reaction capability of I and II. No
tautomerism was disclosed in I and 11 by-the speatra. It is
&own that I and II produce salts by the oxygen bond with
acids, as well as with all-alis (in the ease of an acid, the
proton is added to oxygen, but not to nitrogenj. and in the
case of an alkall.* a proton is detached from the ring nitro-
gen) - See part II in MgWm~, 1955, 31016 -
Card 3/3 -14-

Name: BLIZI;YUY,.OV. VasMy Ivanovich
Dissertation: Relation botweenelsetronic struo-
ture and anti-moleaular activity of
derivatives of quinoline and benzol.
Degree i Doo Pham Sci
Affiliation: Khartkov Pharm Inst
Defense Datdj Plaoe: 7 May 56) Council of Moscow Pharm
Inst
Certification Date: 15 Jun 57
Source: BKVO 16157

AUTHORS: 13liznyukov V I and Sokol, L. S. 79-12-17/43
TITLE: Absorption Spectra and Structure of Quinoline Substituents
Serving as Basic Material for the Production of Remedies
Against Malaria.
(Spektry poglos.hoheniya i stroyeniye zameshchennykh khinolina.,
sluzhashchikh iskhodnymi produktami dlya protivomalyariynykh
aredstv)
IV., Absorption Spectra and Structure of Neoplasmoohin
(Spektry pogloshcheniya i stroyeniye neoplazmokhina).
PERIODICALz Zhurnal Obshohey Xhimii 19571 Vol. 27P Nr 12, pp.
3254-3260
(USSR)
ABSTRACT; The absorptionspectra 6f 8- (5-diethylamino-2-pentyl)amino-
quinoline (of neoplasmochin) proved as complicated. For their
e
"anation the absorption spectra of 8 - aminoquinoline were
xp~
investigated. The effect of the solvents on the absorption
spectra of 8,; (5-diethylamino-2pentyl) aminoquinoline (of
neoplasmoehi and the 8:- aminoquinoline were investigated.
The spectrum of neoplasmoohin in tetraohloromethane oolution.
has a resemblance to thespeotra of 8-aminoquinoline.and-their
othobenzenederivates which have one oubstituent attraoting
Card 1/2 electrons and one repulsing them in the ring, on which
occasion

Absorption Spectra and Structure of Quinoline Substituents
79-12-17/43
Serving as Basic Material for the Production of Remedies Against
Malaria.
a strip occurs on,the described spectrum which occurs also-
in that-of pyridin. Under the influence of hexane and the
dipole solveAs-th6 pyridine-strip of the neoplasmochin dis-
appears and a strip occurs on its orthobenzene spectrum
like it is the case.with the orthobenzenederivatives with
substituents repulsing two electrons.
There are 3 figureep 4 tables, and 14 references, 10 of which
are Slavic.
ASSOCIATIONs Mmwtkov Phirmic6utlca3 -Mistltttte.~:~
(Kharlkovskiy.tA-rmatsb'vticheakiy institut).
SUBMITTED: October 1, 1956
AVAILABLE: Library of Congress
1. Quinolines - Spectra 2. (4uinolines Structural
analysis 3- Malaria - Therapy
q
Card 2/2

AUTHORS: Blizn .-Solonskayal 11. T. 79-28-5-24/69
TITLE: Absorption Spectra and Structure of Substituted Quinolines
Serving as Initial Products for Antimalaria Preparations
(Spektry pogloshcheniya i stroyeniye zameshchennykh khinolinag
sluzhashchikh iskhoanymi produktami dlya protivomalyariynykh
sredstv)V. Structure and Tautomerism of the 2- and 4- Amino-
quinolines (V. Stroyeniye i tautomeriya 2- 1 - 4- aminokhino-
linov)
PERIODICAL: Zhurnal Obahchey Khimii, 1956, Voly, 28t Nr 5t
PPo 1241 - 1247 (USSR)
ABSTRACT: The methods of spectroscopy are of doubtless importance
for
the solution of the problem of the structure and tautomerism
of 2 - and 4 - aminoquinoline, although the conclusions from
the various works are not always clear. Thus Steak and Ewing
(Shtek i Iwing)q as well as Hearn, Morton and Simpson (Gern,
Morton i Simpson) (Reference 1,2)q based on the investigations
of the ultraviolet spectra of the 2 - and 4 - aminoquinalines,
believe these compounds to be tautomeric, while the spectral
results by Angual and Werner (Endzhel i Verner) (Reference 3)
Card 1/3 maintain the contrary. In the present work the
spectrographic

79-28-5-24/69
Absorption Spectra and Structure of Substituted Quinolines Serving
as Initial
Products for Antimalaria Preparations. V.Structure and Tautomerism
of the
2- and 4- Aminoquinolines
investigation of the 2- and 4- aminoquinolines was in-
vestigated more it detail, namely in solutions of hexanep
ethanolp trichlormethane in water, as well as chloric-sulfuric-
-hydrochloric acid solutions and the alkaline solutions of
sodium alcoholateb The influence of the solvents, acidous and
alkalineq on the absorption spectra of the 2 - and 4- amino-,
quinolines, of 4- acetylaminoquinoline and of 1 - methyl- 4-
-iminoquinoline was investigated. It was found that in solvents?
without.any noticeable influence on the ring nitrogen (hexane,
dioxan6), the "benzene-pyridine spectrum" is decisive for the
2- and.4 - aminoquinolines., and the "benzene-quinonimine
spectrum" for the I- methyl - 4 - iminoquinoline. The "benzene-
-pyridine spectrum" of the 2- and 4- aminoquinolines does not
change essentially under the influence of ionizing solvents
and hydrochloric acid of different concentration, however, onj.,
this occasion 11o - or p-aminopyridine absorption speretra" occ,
~.ii
This poinii3 to a binding of a positively bound ring nitrogen Ui~l
Card 2/3 with the ring and with the 2- or 4 - amino group.

-79-28-5-24/69
Absorption Spectra and Structure of Substituted Quinolines
Serving as Initial
Products for Antimalaria Preparations. V. Structure and
Tautomerism of the
2- and 4- Aminoquinolines
According to the absorption spectra in the ultraviolet part
a tautomerism for the 2- and 4- aminoquinolines is denied.
There are 6 figures and 33 references, 9 of which are Soviet.
ASSOCIATION: Kharlkovskiy farmatsevtichookiy institut
(Kharlkov Pharmaceutical Institute)
SUBMITTED; November go 1957
Card 3/3

A
AUTHORSI Bliznyukov, V. I.., Sukhomlinorq,A. K. 79-28-5-25/69
TITLEi AbsorptMoMpfie"IME'And Structure of Acridine
(Spektry pogloshcheniya i stroyeniye akridina)
PERIODICALt Zhurnal Obahchey Khimii, 1958s Vol,,, 28, Nr 5,
ppD 1247-1249~(USSR)
ABSTROT: The authors repeated the spectrographic pictures of
earlier scientists (references I - 4), howeverg in other
solvents: in ethanolp dioxane, tetrachloromethane,
dichloroothane, in the ethanol solution of hydrogen
chloride of different concentration, in concentrated 987;
sulfuric acid and in 6076 jmdilmdc ciaid. Thanks to the
influence of the condensed benzene ring,the absorption
spectrum of acridine is strongly displaced in direction
to the longer waves, compared to the quinoline spectrum.
Besides, an increase of the intensity of the long-wave
bands by 3-5 fold takes place in the spectrum of
acridine. Due to this fact the 11pyridine band" of
acridine is partly covered by the I'longwave benzene band"
Card 1/3 and appears only unclearly in the spectrum of the dioxane-

Absorption Spectra and Structure of Acridine 79-28-5-25/69
- and-hexane solution of aoridine (figure 1). The
11pyridine banP of acridine appears clearly in the
spectrum of,hydrogen-ohloride-aoidous 9-aminoacridine
(figure 1, curve 7). In the formation of acridine salts
a deeply colored displacement of the'longwa,.e band limit
of acridine occurs, which is not the case with short-wave
ones. The spectrographical investigations characterize
the weakening of the aromatic character of the pyridine
ring of acridine in the formation of salt and coincide
with those of the oxidation. kreferences 79 8). Acriaine
thus yields a complicated ultraviolet spectrum in
organic solventsD in which spectrum the present bands
characterize the pyridine (quinoline)- and benzol ring.
The mutual influence of these rings shows up in the
increase of intensity as well as.in the displaoement
of the corresponding absorption bands ir& the direation
to thelonger waves. The absorption spectrum of the
acridinium. ion in acidous solutions is understood to be
a complex spectrum and consists of benzene bands of
"anthraoenell and the benzene bands of the I,ortho-type;-
Card 2/3 which mutually cover each other. There are 2
figures and

Absorption Spectra and Structure of Acridine
79-28-5-25/69
8 references, 2 of which are Soviet.
ASSUCIATION- Khar1kovski-y farmateevticheskiy institut
kKhar:kov Pharmaceutical Institute)
SUBMITTED: November 29p 1956
Card 3/3

AUTHORS:
TITLE;
PERIODICAL:
Bliznyukovq V. 1.2 Sukhomlinovp As K6 SOV/79-28-6-39/63
TU-eAbsorption Spectra and the Structure of the Bisulfite
Compound.of Acridine (Spektry pogloshcheniya i stroyeniye
bioullfitnogo soyeaineniyaakridina)
Zhurnal obshchey kbimiiq 1958, Vol. 289 Nr 6, pp. 16io-1613
(USSR)
A13STRACT: Data in papers concerning the structure of the
bisulfite com-
pounds of acridine are full of contradictions. Graebe (Ref 1)
(Grebe) was the first to describe two products of the con-
version of aoridine with sulfurous acid and with sodium bi-
sulfite. The one of themg C H WSO HKa, consisted of color-
less crystals which easily Vs2ol4d in water, the other,
was red and a compound difficult to dissolve: C I H NSO H-__
*'N' N. Later on Wirth and Lemstedt (Wirtp LemsAtelat) 3(Ref 2)
at iguted,the structure of the sodium salt of acridane-9-
-sulfo acid (formula I) to the colorless product. Drozdov
and Cherntsov (Ref 3) took the colorless product of acridine
to be a sulfurous acid salt of sodium and acridinium (,I)
Card 1/3 (see scheme). GrigorovskiY (Ref 4) regards both formulae
of

SOV/ 79-28-6-39/63
The Absorption Spectra and the Structure of the Bisulfite Compound of
Acridine
the structure as not sufficiently proved. In order to find
which of the ~wo structural formulae of the colorless bi-
sulfite compound of aoridins, (I) or(II), is the correct
one, the absorption spectra of this product can be compared
to those of adridine derivatives having a pyridine ring of
quinold structure, e.g. to those of dihydroacridine, lo-methyl-
-9-imino-acridine. By this method and by the additional com-
parison with the acridinium ion it could be possible to de-
cide in favor of one or the other formula. Concluding the
authors found that in the absorption spectra of the bi-.
sulfite compound of aoridine in sodium sulfite solutionp as
well as in ethanol and aqueous solutionsp a quinone absorp-
tion band occurs immediately after the production of the
solutione After 6--days storing of the aqueous solutions this
quinone band disappears and a return to the speetrum of
the aoridine ion takes place. It was explained that the
structure of the colorless bisulfite compound of acridine of
the empiric formula9C H 10 0 NSNa-2H 09 represents a sodium
salt of acridane-g-sullo aoldp whicK on the action of water
converts to the sulfurous acid salt (at the nitrogen ring)
Card 2/3 (1). There are 2 figures and 8 references, 2 of which are

30V/ 79-28-6-39/63
The Absorption Speotra and the Structure of the Bisulfite
Compound of
Acridine
Soviets
ASSOCIATION: Kharlkov'3kiy-.fnr- tsevticheakiy inetitut
(Kharikov Pharm.aceutioal Institute)
SUBMITTED: February 20, 1957
1. Acridines--Spectrograpble anal~jsis 2. Metalorganic
compounds
--Spectra
Card 3/3

AUTHORS:
TITLE:
PERIODICAL:
ABSTRACT:
Card 1/3
Bliznyukovp V. I., Sukhomlinov, A. K., SOV/79 -28-6-4o/63
The Absorption Spectra and the Structure of 2-Methoxy-g-Amino-
acridine (Spektry pogloshcheniya i stroyeniye-2-metoksi-g-amino-
akridina)
Zhurnal obahchey khimiip 1958* Vol- 28, Nr 6p
pp. 1613 - 1616 (uzqn)
The spectrographic investigation of the 2-methoxy-g-aminoacridine
was of interest as the acridine with a methoxygroup in the po-
sition 2 displays a considerable activity against malaria (Ref 1).
The absorption spectra of 2-mothoxy-g-aminoacridine were inve-,
stigated by the authors in ethanol, dio,,xane, ether, sodium al-
.coholate, an ethanol solution of hydrogen chloride of various
concentrations as well as in concentrated sulfuric acid. The ana-
lysis of the absorption spectra of 2-methoxy-g-aminoacridine in
neutral solvents (Fig 1, curves 192,5,6; comparison with curve
3 and 4) showed that in the case of a common presence of 2-methoxy-
and 9-amino groups in the aoridine ring the "benzene-pyridinell
spectrum of acridine is maintained with two absorption bands being
located on it. The absorption spectra of 2-methoxy-g-aminoacridine

The Absorption Spectra and the Structure of 2-Methoxy-Sof9-28-6-4o/63
-9-iminoacridine
in various solutions are shown (Fig 1), and in concentrated.sul-
furic acid (Fit,2). Concluding the authors investigated the in-
fluence of the solvents as well as of acid solutions on the ab-
sorption spectra of the mentioned acridine, and showed that the
ring nitrogen is capable of attracting the electrons under the
influence of subAtuting groups as well as to emit them. The
composed spectrum of 2-mothoxy-g-aminoacridine was recognized
as "benzene-pyridinell spectrum of acridine on which three ab-
sorption bands are located corresponding to the separation conver-
sion of the substituting groups with ring nitrogen through the
n-electron system of the acridine',ring. The authors found that
in concentrated sulfuric acid a double acid salt forms at the
ring nitrogen and at the amino group of 2-methoxy-g-aminoacridine.
There are 2 figures and 5 references, 5 of which are Soviet.
ASSOCIATION: Khartkovskiy farmatsevticheskiy inatitut (Kharlkov
Pharmaceuti-
cal Institute)
SUBMITTED: February 2op 1957
Card 2/3

'The Absorption Spectra and the Structure of
2-Methozy-SCV179-28-,6-40163
-9-Aminoacridine
1. Acridines-Spectrographic analysis

AUNORSt _AjL!nyukov,_V. I,.,j Sokol, L. S. 30V/79-29-2-46/71
TITLEs Absorption Spectra and Structure of the Substitution Products
of
qainoline-which Serve as Initial Products for Anti-Malaria Remedies
(Spektry pogloahcheniYa i stroyeniye zameshchennykh khinolina,
slazhashchikh iskhodnymi produktami dlya protivomalyariynykh
areastv).
VI. On the Interaction Between the Substituents in the Ions of
8-Aminoquinoline. 6-Methoxy-8-Aminoquinoli-ne and Some of Their
Derivatives (VI. 0 vsaimodeyatvii zameatit-eley v ionakh
8-aminokhino-
lina, 6-metokei-8-aminokhinolina i ikh nekotorykh proizvodnykh)
PERIODICAL& Zhurnal obshchey khimiiq 1959P Vol 299 Nr 2~ PP 575-581
(USSR)
ABSTRACT. As a result of earlier investigations (Refs 1,2) the
authors observed
the similarity between the quinoline ion, with regard to the eles-
tron struoture, and o-aminnstyrene or a-amir-oacetophenone. This was
found on the basis of the comparative absorption spectra in the
ultraviolet range.,It could be expected that the ions of 8-amino-
quinolinev 6-mothoxy-8-aminoquinolins and their derivatives would
in the same way as the -corresponding benzene dex4vatives. On
the basis of absorption-spectnim analysis the following results were
found (6 figures): the combined spectrum of the charged ion of
Card 1/3 8-aminoquinolime so that of a benzene der-I'Vative with an
elect-ron-

4
SOV/79-2,9-2-46/7,
Absorption Spectra and Structure of the SuboUtution Products of
Qiinoline Which
serve as Initial products for Anti-Malaria Remedies ~ VI. On the
interaction
Between the Substituents in the Ions of 8-Aminoquinoline,
6-Metboxy-B-Amino-
quinoline and Some of Their Derivatives
attracting and two electron-repelling aubst-ituents in the
positions
192 thi's connection it was found that 'tha
0 was explained. In V
ring nitrogen takes part in electron transitions as a substituted
amino group by enterIng reactio4 once with the
electron-attral-ting
vinyl group and then with the el"tron-repelling 8-NHR group
through
their-electron system of the be 'iizene ring. The combined
speot-rVM of
the charged ion of 6-me thoxy-8-.1'aminoquinol ins av that of a
benzene
derivative with an,electron-attracting and three
eleatron-repelling
substituento in the positions 41,2v3;5 was also explained. In
thig
-.connection it was found that the ring nitrogen is capabli; of"
taking
part in electron transitions once as a substfo-tuted amino gr-Mp
and
then as a positively charged nitrogen. In the first case the zon-
jugation of the amino group takes place with the
eleotron-attrai~ting
vinyl groups,.while, in the second case thp conjugation of
nitrogen
takes place with the 8-NHR group thr,~ugh thaqr-eleotroa
system'of the
benzene ring. The salt formation of the 8-,NHR group of 8-amino-
Card 213 quinoline causes the return to the spo~~-trum of the
quinoline ion and

Absorption Spectra and Structure of the Substitution Products of
Qlinoline Which
Serve as Initial Products for Anti-Malaria Remedies. VI. On the
Interaction Be-
tween the Substituents in the Ions of 8-Aminoquinoline,
6-methoxy-8-Aminoquino-
line and Some of Their Derivatives
that of 6-methoxy-8-eminoquinoline to the spectrum of the 6-methoxy-
quinoline iono-There are 6 figures and 15 references, 12 of which
are Soviet.
ASSOCIATION: Khartkovskiy farmatsevtiche akiy institut
(Kharlkov Pharmaceutical Institute)
SUBMITTED: November 2, 1957
Card 3/3

50)
AUTHORS:
TITLE:
FERIODICAM
ABSTRACT.
Card 1/3
SOV/79-29-4-59/77
Sukhomlinov, A. K., Bliznyukov, V. I.
Absorption Spectra and the Structure of Acyl Derivatives of
9-Aminoacridine (Spektry pogloshcheniya i stroyeniye atsiltnykh
proizvodnykh 9-aminoakridina)
Zhurnal obshchey khimiif 1959, Vol 29, Nr 4, pp 1316-1320 (USSR),
The investigation into some properties of the acyl derivatives
of 9-aminoacridine kiggested that their form was that.of imines
(I) (Refs 1,2). Acoording to other data (Refs 3,4), the mono-
and diaoyl ,derivatives.of 9-aminoacridine are considered
derivatives of the 9-amin o group (II). The determination,of the
dipole'moment did not solve the problem, since the sum totals'of
theivectors are~almost identical in the case of the imine- and
amino forma of the diacetyl derivatives of 9-aminoacridine
(Ref 5)- In order to approach'the.solution of the problem con-
cerning the structure.of the aoyl derivatives of 9-aminoacridine,
the ultraviolet absorption speotra of 9-monoacetyl-, 9-.aoetyl-
butyryl-, diacetyl-, and 9-propionylacetylaminoacricline were in-
vestigated. 9-diacetylaminoaoridine was obtained by heating
9-aminoacridine with an'excess of acetic anhydride (Ref 1), them

SOV/79-29-4-59/77
Absorption Spectra and the Structure of Acyl Derivatives of
9-Aminoacridine
rest corresponded, with respect to their melting points, to the
,data to be fou nd.in relevant publications (Refs 1,6). The ultra-
violet absorption spectra were investigated in hexanel dioxan,
ethanol, chloroform, and dichloroethane, in ethanol solutions of
H01, and in 60% chloric acid. A comparison of the absorption
curves of 9 aminoacridine, it,s acyl derivatives, and acridine in
dioxan as well as in other solvents (Fig 1, Curves 1-3; Fig 2,
Curves 1-4) shows that the replacement of the hydrogen of the
~amino group by the acid residue causes the long-wave band to
shift toward the shorter waves. In the salt formation,.eg. in
the case of the ethanol solutions of HC1, the absorption spec-
trum of 9-monbacetylaminoacridine shifts toward the long waves
(Fig 3, Curves 1,4, Comparison with 5), and resembles the spec-
trum of the acrisinium ion. The absence of the "quinone-iminb
absorption band" in the spectra of the mono- and diacetyl deriva-
tives of 9-aminoacridine in neutral solutions, and, on the other
hand, the presence of the 11pyridine absorption band" in acid
solutions show that the mono- and diacetyl derivatives should be
considered derivatives of the amino form. There are 4 figures
Card 2/3 and 9 references, 7 of which are Soviet.