SCIENTIFIC ABSTRACT BOKIY, G. B. - BOKIY, G. B.

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• Collection: Scientific Abstracts
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• Document Creation Date: November 2, 2016
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• Sequence Number: 20
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

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y Ram
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T
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9 34-17)
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he qP-acc

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s
ut
nr.
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The
for co-

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.
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ng

to
tht spa6itroup PV. In cobaltitt the inteml
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rrudy Inji. Krist., Aked. Nauk S.S.S.A, 10. M:-98
1964).

cf. C.A. 48, 31FIV; 41), 6018h.-Mieff 1 the Werner aDd

complex
Sal(q wit" I,t!,. pt4+. a Ict Cat' as rents-al
-z -ctures ~F p(NHO'Clicl,
catiuns are discussed; Om

.
H Iran S- [ Ilt(N'v 01C.121 C 1" !,off$-jpt( MAN K,[Pt-
N'tW
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t
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varks betivren 2.30 to 2,35 A., that of coval-

ent Pt-N between 1.08
and 2.03 A. and tlit: Cl-CI d'stance

m-ies from 3.58 to 3.70 A. In

-NIJOCIal, KVINCIAL and KOtOM011 "te took distances

are: K+-Ct' -
3.1-1. K '-01 2.69 A. The tvi-itions of

the stnKtural prolm ties to
those of the t Otical teftactiou.

especially with the mol.,
cr.~:rdlrmfion, aud Ionic refractions.

are nimle- evititnt by the
Ubulat,,S re%ul ~s train prtvinus

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trait, brmiers in itiorg.

and the cokifinution rdra%~~t,tiq, W. Mttl._

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a qui viootim ol The In al ual

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--rokAp% in' the a phut of
-

-
of Pt(ft)arid
T

7
In s (1) far x - for NI
),

NR,Pt-'
-111, 11 4A.
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,
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A '171,
NO:

"M-pt-Nol :fkA~,cmilpf1s, -Mtb -it
Thus I

adda;'d
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-

6f f oljipjs~ NNith cqval. ad-

c
513~11.01 the
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~
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-Cl
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N
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jljxll~r thav for
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ftironger tmwif-inftrrv~t kit, -
iNO, t Ili PHIV) Loviprl,. th~~
tc~.CM, L-ttuo- ~ Slmil ~Ailou-Aldd in 0~111) compd~,-
at

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It is projwo.~~ to U~'j 1 to
d

jr

USWChemical Technology. Chemical Products and Their
AF?lication. J-19
Glass. Ceramics. Building Materials.
Abs Jour: Referat Zh.-Kh., No 8, 1957, 2763-1
Author G.B. Bokiy.
Inst
Title Som Questions Concerning Structure of Glass in
Light of Crystallo-
chemistry.
Orig Pub: YSb Stroyeniye stekla. M.-L.,AN SSSR, 1955,
350-352.
Abstract: The x-ray analysis has proved long ago that
tl:ere am no molecales
in silicates, but even now there are supporteis of the
molecular
structure of silicates and O.K. Botvinkin and K.S.
Yevatrop-yev
belong to them in particular. The absence of molemaes in
sili-
cates, as well as the presence of orderly sections
(crystallites)
in glass are c=sidered in crystallo-ebemistzl- as
jolidly proved.
Thero are no inccqpatible boundaries betweez the theory
of cry-
staLUtes and the theory of Zabariasen, they ixe two
aspects of
Card 1/2 .9-

USSR/Chemical Technology. Chemical Products and Their
Application. J-12
Glass. Ceramics. Building Materials.
Abs Jour: Referat Zh.-Eh., No 8, 1957, 276"
one and the saw question. There are in glass more
orderly
sections (crystallites) and there are also less orderly
sections.
But even in the orderly sections the orderliness should
be less
than in silicate crystals, and the atoms raking the
oxygen brid-
ges connecting these two regions - the orderly and the
disorder-
ly ones cannot be referred either to one or to the
other region,
i.e. there is a continuous transition here and there
are no
phase boundaries among the crystallites. Farthe_-, the
author
objects to making no differeence between organic and
inorganic
glasses, as well as. to schematic pictures of
silicium-oxygen
tetrahedrons developed by G.A. Stepanov. See also FZMim,
1957, 1564, 5159.
Card 2/2 _10-

f3oxzy i~_d.
-.lt)W Chemistry, -.'Inorganic, chemistry'
Filb. 40
BiDkiyj G.-Bil ana'Batsan6v, S..: S.
Utia - I - Orystallo--optical. method~of determining the structure og
complex compounds
Pipriodical i Izv. AN SSSFL Otd. khim.,nauk 2j, 193 1960 Mar-Apr 1955
W~vtract s- -E rimental data-aire'prezented regarding ibe cooidinat4
refractions oil
XPO
tatmralent'- Ft. Tho geometrical configur6tion was iotermin*4 by
cot-:.
paring the experimenta.1ly-measured rofract,'.On indexon with
theorotically
calculated indices for various isomeric foma. The calculation of the
refraction indices vas accomplished by the,Lorentz method. The advan-,
tage's of the crystMo-optical method are 'Listed. The structure of a
newly synthes ized cis-isomer IK2Pt(NO2)4Cl2.was determined by this
new
method. Eight references: 6 USSR and2 Gaman (1933-1954). Tables.
Institution Acad. of So., USSRj,The N. S. Kurnakov lni~. of Gen. and
Inorg. Chem.
Submitted April 27) 1951+

USSR/Geology Sulfide crystals
FD-2175
Card 1/1 Pub. 129-15/20
Author Bokiy, G. B., and Pobedimskaya, Ye A.
Title Crystallochemistry of sulfides. Article 2:
Crystallochemistry of
simple sulfides of the type AX
Periodical Vest. Moak' un., Ser. fizikomat. i yest. nauk, 10, No
2, 121-130,
Mar 1955
Abstract The authors present the results of a survey of the
structural data
on sulfides of bivalent elements. They Jiscuss the structural
typed of galenite (PbS), herzenbergite (S3S)t nickeline (NiAs),
aphalerite (ZnS), vuertzite, millerite (..WiS), cuperite (Pts),
covelline (CuS), TISe, realgar (AsS), an) compounds close to
PbS (NaCl). Nineteen references, includLng two USSR: G. B.
Bokiy Vvedeniye v kristallakhimiyu (Intr.)duction to
crystallochem-
istryi, Moscow University Press, 1954; ",'rystalline structures
of
chemical elements," Vest, Moak. un., No 'j, 1948.
Institution Chair of Crystallography and Crystallochitmistry
Submitted June 5, 1954

DOKI Gr-5
Y1
vp IN Tf4l 1'
91
4 d' Iffurfl- study I --U1
C. and-IM A-
01my 5 ut. M
45-1W,19-5-5).-The x-ray patt~rtls W light-111low 63-1)'t-
(NII0,Cl,I crystA.; characterize their stru~turc as prIs_*
matiewitha - 6.36 _+ 0.05, b - 10.75 =L 0.0;;,c - 11.1-10 1
0.05 A.. 0 - 90,57" space group C,,.-C'2fr ind C'~-Cc'
y - I.P55, 0 - 1.870, and a - 1.855, Electrons tire scat-
tered by the electrostatic potential fields in tie crystal la t-
tice. and the smtttring power of an, atom del; eads on (Z
f.). v~htreZ is the at. no, and f, the scattering factor fox x-
rays, Since f~ falls farther below Z for light ~r alow; than
for heavier ones, it follows that lighter atows are re!atively
ZI: better scattcrers of electrons Thai of x-rays. This method,
was used to yield maps showing both the elect on,d. and the
of p.Rtent!~!~the unit cell. A. 11._Kotloby

USSR / Structural Crystallography. E-3-
Abs JOur : Ref Zhur - Fizika) No 4, 4957, No 9237
Author : j2kiy~, G-Be, Malinovskiy, T.I., Ablov, A.V.
Title : Stru-clu--r-F-o-f I)ihalogenide-Diamines of
G)balt.
Orig Pub : Kristallografiya, 1956, 1, No 1, 49-52
Abstract : The aithors consider the problem of the
structure of pro-
ducts of the combination of two amines with halogenide
of
divalent cobalt. X-ray-diffraction det(wmination is
made
of the crystalline structure Of C0C12"?J(2NIC6H4CH3a
The
trysta,li,optical data are: biaxial, cryste.1s, Zv::~~
900 in-
d1ces of refraction are n a 1#701, n. e, 1*652, and np
=
1.61o. The latti eriNs are: 12-3, 1, 4-59, c 26.1 A;
093045'; ~ x-ra~?53; qmear. 1-483; Fedorov group 12/A.
The photographs were made by the vibration and roentge-
nogoniometer methods with radiation Mo a K~, . The
coor-
clinates of the atoms were determined by constnicting
the
Card 1/2

USSR / Structural Crystallography. E-3
Abs Jour : Ref Zhur - Fizika, No 4, 1957, Vo 9237
Abstract : projections and the Patterson sections.
The interatomic
distances are; Co-Cl 2.24, Co-N 1.92, N-Glqj 1-38,
cl-cl
3.70, Cl-N 3-40, H-N 3-15 A. The v&lenci~ gles are:
Cl-
Co-N 1090, Cl.-Co-Cl 1110, N-Co-N 1110, Co-N-C :1)
1020-
The structure is molecular.zThe cobalt titom s in the
center of an alm st regular tetrahedron, two vertices
of
vhich are occupied by chlorine atoms and twor.by
nitrogen
atoms. The Co-Cl and Co-N bonds are pre~.ominantly
cova-
lent. The tetrahedral structure, in the author's
opinion
should be ascribed also to other product( of the type
C.X2A2
of blue color. r The authors "te that thc. 01
and/3modifica-
tions of the complex compounds Co(24) (blue and
violet) are
not cis- and trar6-isomers. The violet rcdifications
are
probably due to the chain structure with coordination
num-
ber six.
Card 2/2

BOKIT, G.B.;KHODASHOVA, T.S.
I , Wlmrmlill~
X-ray analysis of 1n73-3%0. Eris tallogra f iia 1
no.2:197-204 '56.
(MLRA 9;11)
1. Institut obahchey I neorganicheskoy kbimii imeni
N,S. Knrnjl ova.
(Indium fluoride crystals)

-4ZEL G.B.
.
Concept of daltouidoe and berthell1dom in 'dow of the
atemile thoorY of
crystal structure. Zhur.nearg. khIn. I ne.,S;1150-1161 jo
56.
(NLRA 9:10)
I.Institut 9bahchoy I neorganicheakey khim,.Ii imeni
NegAurnakovs,
Akademil nauk SSSR.
(Chemistry, Physical and theoretical)

go ~ / 9 j 6,.ty,
U Solid State Physics / Geometric Crystallography
Abs Jour : Ref Zhur - Fizika, No. 5, 1957 No. 11581,
Author i Bokiy, G.B.
Inst r__
Title : Law of Arrangement of Atoms in Crystals.
Orig Pub i Kristallografiya. Vyp. 5, H.,
Metallurgi2dat, 1956, 25 36
Abstract i The essence of the law of arrangement of
atoms in a
crystal can be stated at followst the ataas are placed
in the crystal space at points of regular systems of
Fedorov symmetry space groups. The points correspond to
the faces or centers of simple forms of crystals, if
these
centers are coincident with the singular jointscof the
structure, and particularly with the lattice sites.
Each
simple farm can be represented in the forn of a cor-
responding point group, The multiplicity of the re-
gular systems of points (figures) equals the number of
the
Card- 1/2

BOIIY, G.B.
Principles in the classification of chemical compound
including minerals.
Gookhislia noo6;73-83 956* (HLRA 1011)
1. Institut obahcheY I jeorganichookor kh1vii imeni N.S.
Xurnakova.
(Geochemistry)
W*

BOKIY, G.B.
(3"31..,Fedorov and crystallochemistry. Trudr
Inst-ist.ast.i tekh.
10: 19-27 '56. (W.RA 9: 12)
(Fedorov, Ivgraf Stepanovi.-h. 1853-1919)

O-V.,
0

Ur

A

~z~Tj.
A the bt
loaltrite.

U 024

25

if

ki ".tbc-yv Jut

k
wic thalt the 4~

-~:Awtiaw
far uAied:

a

'

Nntbl.:: -1
tiom 60

sac~sllcut
C4

m, ',
,,cat

it al-

vpp~sc4 to i
he UWic ~i~tg
0

tim atrong

he Ac. earths."

J
W Eitel
;

USSR/ Physical Chemistry - Crystals B-5
Abs Jour Referat Zhur - Xhirdya, No 3, 1957, 7269
application of euccessive approxinations in carrying
out
a Fourier analysis. Die structure of chkalovite
appears
to be derived from that of :~-cristobalite. The
filling
of 2/3 of the total ntuiber of Lavsov polyhedra by Na
atoms and the substitution of 1/3 of the Si atoms by
Be
atoms lead to a tripling of the.a and b periods in
chkalo-
vitc compared with the edge lengthr, o-,'
'-cristobalite.
This leads to a sz:all displaccrent of the atomic
coordina-
tcs from their ideal positions.
Card 2,12 - 39 -

15-57-7-9373
Translation from: Referativnyy zhurnalp Geologiya, 1957, Nr
7,
pp 91-92 (USSR)
AUTHOR: Bokiy, G. B.
TITLE: The Crystallochemical Princip*-es in the
Classification
of the Sulfides and Arsenides (Kristallokhimicheskiye
printsipy sistematiki sullfidov i arsenidov)
PERIODICAL: Uch. zap. Mosk. un-ta, 1956, 11r 176, pp 233-240
ABSTRACT: Since the appearance of exper.-.mental crystal
chemistry
in the systematic treatment oJ' minerals, the chemical
composition and the structure of the mineral have
been taken into account. However, the basis for sys-
tematic classification is not the chemical composition
but the crystalline structure of minerals, inasmuch
as different structures exist for similar compositions
(e.g., diamond-graphite, pyrite-marcasite, etc.). The
Card 1/3 crystallochemical classificat.,.on of silicates,
based

15-57-7-9373
The Crystallochemical Principles (Cont.)
primarily on structure, demonstrates the justification of
this
principle. However, one cannot mechanicallF transfer the
principle
of classification of the silicates to the salfides,
inasmuch as the
sulfides are generally solid phases of varying
composition. Such
phases have two fundamentally different types of
structures: 1)
substitution of the atoms of one element for those of
another ac-
cording to the atom-for-atom rule, forming solid solutions
by sub-
stitution; and 2) insertion of atoms of one element into
inter-
spaces between atoms of another element, forming solid
solutions by
introduction (and by subtraction). In the ranges of
mineral com-
position of the sulfides, these two types are incorrectly
repre-
sented by stoichiometric formulas. A classification of
chemical
combinations, including minerals, should be based on the
periodic
law of D. I. Mendeleev. Inasmuch as the valance of
nonmetallic
elements, in going from one subgroup of the Mendeleev
table to
another, varies more sharply than does the valence for
metals,
classes of chemical combinations should be segregated
according to
Card 2/3

The Crystallochemical Principles (Cont.)
15-57-7-9373
type of anion. On this principle, the clas3 of sulfides,
selenides,
and tellurides should be differentiated from the class of
arsenides
and similar combinations. Sulfo-salts fall into a separate
sub-
division in which anions of both types are present. The
authoraeoxr~-
mends.. . that the separation into mineral classes be based
on near-
ness to or identity with structural types. As an
illustration he
furnishes a table of the structural typesAY of sulfides,
selenides,
and tellurides of metals. The author notes that an
intelligent
classification of sulfides can be devel-oped only by study
of the
structural diagrams of the appropriate syst,~ms with
subsequent X-
ray analysis of the solid phases of varying composition.
Card 3/3 A. S. Povarennykh

BOKIY, G, B. and KUKINA, G. A.
Institute of General and Inorganic Cbemistry,
Moocyw-"Crystal Cbenistry of
Complex Divalent Platinum Compounds" (Section 16-2) a paper
submtted at the General
assembly and International Congress of Crystallogniphy,
10-19 Uul 57, Montreal,
Canada.
C-3,800,189

BOKIY, G,P.; ROMOVA, O.,G.
Cr-letallographic criterions for selecting fluorrymrs
used for
growing mrtifici!O. crvstale of o-atical fluorite.
Kristallogrnfilm
2 no.1:158-165 157. (MRA Ir.: 7)
1. Mopkovakiy posudarstyennyy universitet Imen!
Lomonosnmr.
(Fluorite) (Gryetallograpby~

AUTHOR: Bleidelis, Ya.Ya. and_jLkiX,_q.B. 7012-13/24
TITLE: 'The crystal structure of the trans-diamine thiocyanate of
bivalent platinum (Kristallicheskaya struktura trans-
diammindirodanida dvukhvalentnoy platiny)
PERIODICAL: "Kristallograft-va" (Crystallography), 195? V01.29
No.2, pp. 281-283 (U-S-6,R.)
ABSTRACT: Crystals of trans- Pt(NH recrystallised from
3)2(SCN)2
acetone, were monoclinic with refractive indices for white
light, ny = 1.990, n~ = 1.73?, n. = 1.625. The unit cell
dimensions were a = 701, b = 8.27, C = 13.2? KK (all
+ 0.05 KX) and P = 9 approx. The space group was uniquely
given by the extinctions as P2 1/n. d.obs.= 2.90, Z = 4 and
dcale. = 2.88. hOl (103 independent: reflections) and Okl
(76 independent reflections) Patteruc;on and Fourier projections
were made giving the atomic co-ordiiiates (x, Y, z) as:
Pt, (-0.0739 0.184, 0.217); SI, (-0.206, OP50, 0.128);
Card 'A sils (0-193, 0-333s 0-309); NH C-0.130, 0.135, 0-360);
311 .
NH 311' (0.131, 0.230, O-OBI); CII (.'-0-354, 0.154, 0.104);

70-2-13/24
The crystal structure of the trans-dw.ammine thiocyanate of,
bivalent platinum. (Cont.)
NIj (-0.475, 0.256, 0.063); Cjjj (0,.3449 0.2159 0.354);
NII, (0e467, 091151 0.392). The reliability coefficients
were P)CZ = 0.21, 1~ z = 0.30. Distances from the Pt atom were,
SI, 2*26; Sjjq 2.27; NH31P 2.13 aWL NR N11 2.10 KX.
Acknowledgments to M*A. Poray-Koshitii.
Card 2/2 There aie 1 figure, 1 table and I SlE.vic refererce.
ASSOCIATION: Institute of Chemistry,)Lati-lan Ac.Sc.,(Institut
Khimi AN Iiatviyskoy SS
SUMITTBD: January 18, 1957.
AVAILABLE: Library of Congress

AUTHOR: Bokiy, G.B. and Kukina, G.A. TO-3-13/20
TITLE: Cz7stal chemistry of complex divalentplatinum compounds.
(Kristallokhimiya kompleksnykh WyedJnaniy d.vukhvalentnoy
platiny (effekt transvliyaniya v kristallicheskikh
veshchestvakh)
PERIODICAL: "Kxistallo=aft-vall (Crystallo aphy . 195?,
Vol.2, No-3, pp. 400 - 40, (U.Hr.,.R.~
ABSTRkCT Daiing recent years at the Laboratory cf Crystal
Chemistry, Institute of General and Inorganic Chemistry named
after N.S. Kurnakov, Academy of Sciences, USSR, an X-ray
structure investigation was carried out :)n a number of complex
compounds whith belong to the chloramine series of quadrivalent
and divalent platinum. A review of the *.rystal chemistry of
platinum chloramine was made by G.B. BokLy in his works devoted
to the final results of the research.
X-ray structure investigations confiriied the types of
geometrical isomers, which were attributo-d to them owing to
classic stereochemic methods. The formulation of the stereo-
chemistry of inorganic compounds was the result of investi-
gations on complex cobalt and platinum compounds.
OLrd 1/7 It is in complex platinum compounds t1mt I.I. CheimyAev-
found It-rans-directing influence' (1926),

70-3-13/20
Crystal chemistry of complex divalent pl-).tinum compounds.
(Gout.)
In 1951, J~kiy G.B. et al. made the first'attempt to
obtain the quantitative characteristics of trans-influence by
employing the electronographic method in investigating the
structure of potassium trichloroamminoplatinites K 113'tfH30131-
The distance obtained along NH 3 - Pt - (101I(Pt - Cl, = 2-32 kX.)
proved to be somewhat smaller than the distance along ClII_ Pt
- CIII(Pt - C111 = 2.35 Iff.), which we a-:;tributed to the result
of the trans-influence existing in the molecule. Further,
quadrivalent platinum compounds cis-[Pt(IIH 3)2Clj and the face
isomer of K,,rpt(NO 2)3 C131 were investigated. We failed,
however, to obtain the cAantitative characteristics of trans-
influence; but we succeeded in proving I ';hat the nitro group
Card 2jP7 in the quadrivalent platinum compounds possesses a
wealor
trans-influence than chloride and bromino. This was clearly
shown by optical methods.
After establishing this fact we returned to the investi-
gation on divalent platinum compounds of the series of chloro-
amine. We also made a study of compaundii in which eblorine

70-3-13/20
Oard 3/7
D14 - Pbna.
2-h
KLPtNH3
31- H2
+ 0*02 kX*; N = 12; f#or KL'PbNH3 Br3J "'2'), a = 21-75 � 0.04t
b = 8.37 � 0.02, c = 14.42 + 0.02 kX; :1 = 12, space group
Crystal chemistry of complex divalent platininn compounds.
(cont. )
atoms were substituted by bromine and an addendium, poss-
essing the strongest trans-influence, naii.ely the ethylene
group.
An X-ray structure investigation on K(-PtNH Cl.I.H () and
r_._ 3 2
KLINH 3Br,).ji2o was carried out. The rei;ults of goniometric
and optical investigations showed that the compounds are iso-
moiphous and orthorhombic.
The dimensions of the unit cell were determined from oscill-
ation photographs and X-ray g9niometric diagrams. For
Cl
0, a = 20.88 + 0.04, b = 13.10 + 0.02, c = 13-55
The co-ordinates of Pt, Br, K and NH 3 were found by the cal-
culation of projections of inter-atomic functions on plane XY
and XZ, and of electron-density projections on corresponding
planes. (All of the data were obtained from the reciprocal-
lattice photographs with Mo Ke radiation.)
In contra-distinction to the structuie of the anhydrous

70-3-13/20
Crystal chemistry of complex divaleat platinum compounds.
(cont.)
salt, all the K[r.NH C1 H 0 complexes are inclined to Z at
0 3 31 2
approximately 26 . r
The threefold period (for K - 1,1, a = 17,69 b = 8.84,
LYUNH30
c = 4.19 U., N = 4) is caused by the presence of water mole-
cules, which displace potassium atoms from the inversion centre.
This accounts for the increase of the poriod along X by
approximatelY 3 kx- Potassium atoms are. arranged in trigonal
prisms and their co-ordination number is 6. The presence of
water molecules in the outer region also influences the inter-
molecular inter-atomic distances.
At the beginning of 1954, we undeltook an investigation on
-Zeise salts , K(PtC2~4U 31 H20 and KEPtc;~14)Sr,I.H201 to
determine
Pt r 031 and Pt - Br distances in case e';hylene labilizes the
chlorine and bromine, and also to find carbon a oms are
arranged in relation to the group [PtCl PtB
.qand L
The crystals belong to the monoclini,, system, as was found
by Jorgensen in 1900. Goniometric and :)ptical investigations
Card 4/7 have shown that KL13tC04C131 'H20 and K[.PtC2H4Br31
H20 are
isomorphous. The unit cells are determined by oscillation

70-3-13/20
Crystal chemistry of complex divalent platinum compounds.
(Cont.)
photo hs.
For K PtC2H4C'31' H20, a = 10-85 � 0.02, b = 8.53 � 0.02,
4.81 + 0.01 kX.9 0 = 97 0 N = 2, :-'or Kf,-,o H 0
L' A~BrA 2 1 0
a = 11.38 0.02, b =28.?8 + 0.02, c = 5.01 + 0.01 kX.1 0 = 97
N = 2, space groups C - Pr, The atomic c6--ordinates are
2 - 1
obtained from projections of inter-atomLc functions on XY and
XZ and from the projection of electron-density on XZ. At the
end of 1954 there.was published an arti,-.le by Wunderlich and
Meller on the crystal structure of Zeis,-. salts. The atomic
co-ordinates in this article were definLtely at odds with the
authors' article, but in 1955 Wanderlici and Meller published
a paragraph with corrected co-ordinates, the latter being in
agreement with the authors' results.
To determine with greater precision the distance in case of
an addendum with a strong trans-influen-,e - the ethylene group -
the authors investigated an isomorphous compound with bromine
and obtained good results. The analysis of the electron-density
projection on plane IZ made it possible to determine the
Card 5/7 carbon atomic co-ordinates and to find that the plane
of the
ethylene molecule itself is perpendicul3.r to the plane of the

70-3-13/20
Crystal chemistry of complex divalent p*..atinum campounds.
(Cont.)
group ll>bBr 31 , whereas carbon atoms are almost symmetrical to
platinum atoms.
In this way co-ordinates of all the titoms weie obtained and
inter-atomic distances were calculated. Two of the bond lengths
Pt - C1 II and Pt - Br II are normal (2.26 and 2.42 U.); the
third bond length A - C1 I and Pt - Br, I which is in the
trans position to the ethylene m3lecule. is 2.40 and 2.50 kX.
respectively.
As the strong trans-influence of the ethylene molecule is
well known, the increase of bond lengthi.; Pt - Cli and Pt- Br,
seems quitenatural.
Proceeding front crystal chemistry data it is possible to
Card 6/7 determine the position of hydrogen atomi;. There are two
variants
of the arrangement of the flat group C ~'4 in the molecule
Ptc H 0151 In the first variant this plane, when continued
2 4 gol~gbL I
asses t the line Pt - BrI; in the second it is papendic-
~
ular to the line. The difference betwe(:n the inter-atomic
distances obtained for these two variants speaks definitely in

70-3-13/20
Crystal chemistry of complex divalent platinum compounds.
(Cont.)
f avour of the second variant.
There are 2 figgres and 19 references, 16 of which are Slavic.
ASSOCIATION: Institute of General and Inorganic Chemistry imeni
N.S. Kurneikov (Institut obshch,~y i Neorganiche~koy
nimii im. N.S. Kurnakova)
SUBMITTED: March 6, 1957
AVAILABLE: Library of Congress
Oud 7/7

AUTHOR:
Bokiy, G.B. and Parpiyev, B.A. 70-5-23/31
TITLE: X-ray Structural Investigation of Cr,7stals of
u
[Ru(ITH 3)4("O)(OH)10l2 (Rentgenostruk'urnoye issledovaniye
kristallov [Ru(ITH 3)4("0 )(OH) ]C12
PERIODICAL: Kristallografiya, 1957, Vol.2, No.5, pp. 691 - 693
(USSR)
3)4 (NO)(OH) ICl2 7hen measured by
ABSIRACT; Crystals of [Ru(ITH
optical goni8metry had axial ratios a:b:c of 1-535 : 1 : 0.722
and 0 = 101 15' . The refractive indices were 1.830, 1.708
and 1.661. The unit cell dimensions determined using a reti-
graph were a = 11.48 + 0.02, b = 7.44 .+ 0.05 and c = 10-75
+ 0.02 A. The observed density was 2.112 giving Z = 4 and a
calculated density of 2.126. The extinctions were characteristic
foT the space group C2. Intensities were measured from Mo
radiation pictures from a retigraph and Cu radiation pictures
from a Weissenberg camera by visual comparison with a standard
scale. The th_3~ee Patterson projections on to xOz, :~VO and Oyz
,,,.,c,re constructed, CivinC the locations of the heavy atoms and
the xOz and xyO Fourier syntheses were ffade vith reliability
factors of 0.224 and 0.20?, respectively. The atomic osition
u-t_,rd1_/2parameters were found as follows: Ru (C.250, 0, 0.2503;

?0-5 2 /3)~
X -J~ily Striietural Iuvc;stigation of Crystals of 11 zu( MI
'0) eoli
3)4(" C12
Gil (0.006, 0.500, 0.365); Cljj(0.375, 0.1;001 0.146);
( 1-a13), (0.149, 0.210, 0.126); (NH3)II(O' 'L'9' -0.210,
0.126);
(11113)111 (0.349, 0.210, 0.376); (MI 3 )IV (0.349, -0.210,
0.376);
(01H) (0-3?5 0.000, 0.146); N (of RO Uroup) (0.125, 0.000,
0-365); 0 ~of PO)I(O-058, -0-093, 0.397). The Ru atori is
o--tabedrally co-ordinated ri-k-,h the 4 (NH 3 ) Uroups in a
planar
oonfiguration and the NO and OH groups 0in 1he trans
positions.
The Ru - N - 0 bond angle ir, about 150 - ]'he Cl ions have a
co-ordination number of 12, 8 (NH 3 ) groups beinS closer than
t1"e- 4 OH or NO groups.
T"--~re are 1 table and 3 references, 1 of rAich is Slavic.
-ATION: Moscow State UniversitY in. M. V. '.~O~onos6v
(Mookovskiy
0013udarstvenn" Uhiversitet j*, M. V. Lomonosova)
;.,.---,:.ITTED. December 4, 1956.
A,jAII,ABIB,: Library of Congress.
u,-,rd 2/2

-12 Y - 'r, - --
10, C) / V / X, & - ~, /-,),
PAPRIM, N.A.; BOKIT~ GB,
X-ray analyeLs of ammonium
tetrachlorobvd-:-ox.-nitrosoruthenate
crystals. Zhur. neorg. khim. 2 no.8:1972-1974 Ag '57. (MIRA
11:3)
(Arnonium,,compounds--3pectra)

BOUT, G.B.; SHATALOTO TOOT*
Geologi6al excursion to the silver and lead ore
deposits of Mexico.
Ve a t A41 .0 geolot 1"e0g. 12 no.1.47-55 157.
.qsk. un. Ser. biol., PoChT
(Mexico--Silver ores) (Koxico--Imad ores) (MLRk 10:11)

BATSANOV, S.S.; BOKU&__q
Crystallographic and optical determination cf the
structure of
platinum complex compounds. Vest.Mosk.un.Ser.mat.mekh.,
astron.,
fiz., khim. 12 no.2:3-14 '57. (MMA 10:12)
l.Kafedra kristallografii i kristallokhimii geologicheskogo
fakullteta Moskovskogo univeratteta.
(Platinum compounds)

-, --1 , -/ /, L! 11!~,,
BOUT, G.B.; BATSANOV. S.6.
Refractomtric da$ermination of silic&te structure.
Zap. Veen.
min. ob-va 86 no.Y;421 '37. (MIRA 11:1)
(Silicates) (Wractometr,r)

BOKIT, G.B.; PIAJSNINA, I.I.
Infrared absorption spectra of
length interval; determination
infrared spectra. Ysauch. dokl.
no.3:116-122 158.
cyclosilicates In the we've
of silicate structure bF their
vys. shkoly; geol.-geoge nauki
(MIRA 12:1)
1*Moskovskty univervitst. geologicheskIr fakulltat,
kafedra
~;istailqgrafii.
(Silicates--Spectra) (Spectrum, Infrared)
t

BEWT. N.V.; BALTAY17, L.M . InnirTy 01 12 . BRONNIXCVA,
Te.G.; VAYNSHTM,
B.K.; ZEMLNOV, G.S.; IVARONOTA, V.I.;XITAT,,;rJRODSK1T,
A.I.;
PINSM, Z.G.
Fourth International Congress of Crystallographers.
Kriatallografiia
3 no.2:250-260 158. (MIRA llt'6)
(Oryi3tallography-Congrooess)

SOV/20-3-6-20/25
AUTHORS: Plyusnina, I.I. and Boki_y__CT_j,
TITLE: Infra-red Reflection Spectra -'or Ring Silicates in -he
Wavelength Interval 7 - 15 1L ~:Infrakrasnyye spektry"
V
otrazheniya kolltsevykh silikdtov v intervale dlin
voln 15 il)
PERIODICAL: Kristallografiya, 1958, Vol: 31 Nr 6, PP 252 -756
(USSR)
ABSTRACT: Infra-red reflection spectra,were measured in the
range
7 - 15 4 for slices paralled and perpendicular to the
main symmetry axis for singlf:: crystals of the minerals:
eudialite, catapleite, cordittrite, dioptase, vorobevite,
beryl, aquamarine and tourmaline. (Most of these are
reproduced.) Qualitative di'scussion of the features
of the spectra follows. Cat,ELpleite and eudia'lite are
compared. For catapleite, cut perpendicular to the
optic axis, the first main 't:and of the spectrum is a
doublet and for the slice cv'.t parallel to the optic axis
a weakly characterised doublet. For eudialite the
similar band for the slice perpendicular to the optic
axis is a doublet, but for ;he slice parallel to the
optic axis it is a triplet. The second main band in
the region of 13-14 IL in both catapleite and eudialite
for the slices perpendicular to the optic axis is almost
Cardl/2

.SOV/70-3-6-20/25
Infra-red Reflection Spectra for Ring Sili~ates in the Wavelength
Interval 7 - 15 U
twice as intense as for the slices parallel to the optic
axis but its position (wavelength), is the same in both
oases. Similar kinds of observations are made for the
qther minerals but no structural or other conclusions are
drawn. There are 4 figures, I table and I/ references',
3 of which are Soviet and 4 German.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im.M,V.
Lomonosova
(Moscow State University imeni m.V. Lomonosov)
SUBLUTTED: August 29, 1958
Card 2/2

30(7)

AUTHOR:
Boldy,-G. B., Corresponding blember, 3071/ 3,j -
5--' - 11 -31/4 8

AS USSR
TITLE:
Soviet Scientists on the
Exposition (Sovetskiye uchen~,~yu~ o

vystavke)
PERIODICAL:
Vestnik
Akademii nauk SSSR, 1958, Nr 11, up 108-109 (USJR)
AB3TRkCTj
The
author's particular field of interest, the chemistry of

crystals, was given rather little attention in the nationcal

pavilions. He mentions the large-scale model of the crystal

structure of vitamin B 12 which was exhibited in the Briti.91h

pavilion. It was built by the British Acudemician

Dorotti
Khochkin who is well-known and respected in the U33.q

from some
lectures held there. In the Falace 3f Sciences all

chemical
disciplines were grouped together in the Sectior

"The Molecule".
Prcblems of'chain reaction were c-iso shown

here which were
dealt with by the work of Nobel prize winner

N. 11. Semenov,
Academician, arid his school. The article n-o-_~s

on to mention
the unique apptiratus displa~jod in con.,.c_,ction

with the work
on catalysis done by A. it. B,,LJ~Ldin, "~cademiuian,
Card 1/2
S.
Z. Roginskiy, Corresponding 1ember, A'S USjR, Profes.5cr

Soviet Scientists on the Exposition zvr-i, 7J- 7 :1- . -1 -
31/48
N. I. Kobozov and others. In the oection "Th(~ t1le
models of crystals were exhibited the otruct6ires of -..-;,ich
had been determined by N. V. Belov, Ac:idemici~,,4 and ',is
;011031
Furthermore the big horizontal electrcn def--action
-~.LL-Uturz~
of the Institut kristallot;rafii Akad C- 4 ': SSSR
_ - na-;
(Institute of Cry stall ograjAly, AS USj--,N;, t,~pe is
menticn-ed
which was exhibited in this section. The u,.-, ",
saying that the Soviet exhibits would IiLvc mc--Q
impressive ff tne crystul,,~ of the
quurtz produced by Soviet scientistj hiicl LiLic 11--,---.,~
There is 1 figure.
Card 2/2

BOK9-4-. ".11 1 BATSANOV, S.S.
Effect of the degree of Ionization on bond enarg7. Zap.
Voss.
min. ob-va 87 no.2:223-224 158. (MIRA 11:9)
1. Deystvitell Wy chlen Vaesoyuznogo mineralogichankogo
obahchastva
(for Bokly) jChemical bonds) (Ionization)

BOM. G., (Moscow)
(probably GeorgAy Borosovich BOYIY)
"The importaRce of Crystal Chemical Investigaticn for
GoordirAtior. Gherdstr-,-O
paper pxmmtvA
paper submitted for the Sy=
posium on Chirmi3try of Coordination Compounds,
Allahabad, India, 7-a Feb 1959.

BOKIY 1 G. B. ; ATOVff AN, L. 0AN~ PU, VAJI:
KLTKINV~-AILL--"
T07
JWW.IIUvA) ~.T.S.
"New Data on the CryStall Chemistry of Complex
Compounds of
Ruthenium, Ommium and Platin"
a report presented at S~mposium of the
International Union of
Crystallography Lenningrad 21-27 M&Y 19-5-9
SO.- B 3,135, 471 28 July 1959

s o v
mmit mWwvics =7i nIARm
wig,
A Bopwt Vr"ftt" &t VYW"m Of tM U%OMUQNU USION Or "t&U
Lqmlw", 21-17 Mv X"9

-- ----------

5W SOV/78-4-1-15/4F3
AUTHORS: Bokiy, G. B., Sokol, V. 1.
--------------
TITLE: The Determination of the Structure f Complex
Colnpo-'Iridn of
Bivalent Palladium by a Cryotallo-optical Method
(Opredeleniye
stroyeniya kompleksnykh soyedineniy dvukhvalontno6o
pal-ladiya
kristalloopticheskim metodom)
PERIODICAL: Zhurnal neorganicheskoy khimii, 1959, Vol 4, Nr
1, PP 74-78
(USSR)
ABSTRACT: The connection of the crystallo-optical properties
with the
inner structure of the bivalent palladium complexes was in-
vestigated. For the first time the dispersion of the
refraciicn
index of biva lent palladium complex compounds was measured.
From the data on the dispersion of the refraction index and
the density the molecular and coordinative refraction forX.,
was calculated and is shown in table 2. The method of de-
termining the geometrical structure of the trans-compounds
Pd(NH3)2 C12and Pd(NH 3)2 (N02)2 was investigated by the co-
ordinative refraction. The geometrical structure of the com-
Card .112 pound EPd(NH 3) 4] [Pd(N02)2C'j , as yet unknown,
was also de-

SOV/78-4-1-15/48
The Determination of the Structure of Complex Compounds of
Bivalent
Palladium by a Crystallo-optical Method
termined by coordinative refraction. Tho comparison of the
coordinative refractions of bivalent and tetravalent platinum
with palladium is shown in table 6. In complex palladium com-
pounds the amine group is connected less steadily to palladium
than the ~_itrito group. The complex compounds of bivalent
palladium, which contain nitrito groups as addondum, are
5im-,Iar
to the complex compounds of bivalent platinum. The trans-
effect in bivalent platinum complex compounds is as strong as
in bivalent palladium complex compounds. There are 7 tables
and 6 references, 3 of which are Soviet.
SUBMITTED: October 2, 1957
Card 2/2

5(2) 05855
AUTHORS: Parpiyev, N.A., Bokiyj G*B9 SOV/78-4-11-8/50
TITLE: The Structure of the Crystals of
Hydroxo-nitroso-tetrwaine
Ruthenium Chloride
PERIODICIL: Zhurnal noorganieheakoy khimli, 1959, Vol 4, Wr
11,
pp 2452-2459 (USSR)
ABSTRACT: The compound ?u(NO)(OH)(NH3)43Cl2 was supplied by
V.I. Goremykin. The resultant goniometrio values of the
monoorystals are listed in table 1. The compound is
diamagnetic, and its magnetic susceptibility war, determined
by V.I. Belove. at the Institut obahchey i neorganicheskoy
khimii im. B.S. Kurnakova Akademii nauk SSSR (Institute of
General and Inorganic Chemistry imeni N.S. Kurnakov of the
Academy of Sciences, USSR). The piezoelectric effect of the
crystals was measured by V.A. Koptsik at the fizicheskiy
fakulftet MGU (Physical Department of Moscow State
University).
The lattice constants were determined by X-ray analysis.
The crystals belong to the space group C2. For the X-ray
analysis, the authors took radiographs of the zero-contour
Card 1/3 line with the help-of a KPOR camera with molybdenum
radiation

05855
The Structure of the Crystals of Hydroxo- SOV/78-4-11--8/50
nitroso-tetrazine Authenium Chloride
and an RGNS camera with Cu radiation. Table 2 contains
experimental and calculated values. In order to find the
general feature of the structure, projections of the inter-
atomic function were drawn on the surfaces (010) and (100)
as well as the projection of the electron density on these
two surfaces (Figs 1,2,4,5). The structure of the ruthenium
-.ompound under investigation is compared in figure 3 with
that of potassium chloroplatinate. Figure 6 shows the dis-
tribution of the atoms of hydroxo-nitroso-tetrammine
ruthenium
chloride within the elementary cell. The structure is based
on the octahedral complex cation [Ru(NO)(OH)'(NH3) 4]2+ and
the chlorine anion. In the complex ion the Ru atom is placed
in the center of the octahedron wh3mfour corners lying in
one plane are occupied by NH groups, while the two other
corners in trans-position ar~ occupied by the groups NO and
OH. This trans-position of the NO and OH group is character-
istic of all complex compounds of Ru investigated so far,
which has never been pointed out before. The interatomic
Card 2/3 distances in the complex ion are: Ru - N (from NH
3) - 2.23

05855
The Structure of the Orystale.of Hydroxo-. SOV/78-4-11-8/50
nitroso-tetramine Ruthenium Chloride
Ru - N (from NO) - 2.07 1, Ru - 0 (from OR) - 1*98
Accordingly, the linkage of Ru to NO and OH is closer than
that to NH . Zae atoms Ru, N and do not lie in a straight,
but form aa angle: Ru - N - OrjO150 The interatomic
distances of neighboring complexes are in good agreement
with the intermolecular distances calculated from the Van
der Weals atomic radii. There are 6 figures, 3 tables, and
8'referenose, I of which is Soviet.
ASSOCIATION: Moskovskiy gosudaretyennyy universitat im.
M-V- Lomonoeova
(Moscow State University imeni M.V. Lomonosov) Institut
khimii Akadomii nauk Uzbekskoy SSR (Chemical Institute of
the Academy of Sciences of the Uzbek SSR)
SUBMITTED: July 20, 1958
Card 3/3

24(2)
A7JTHORS: Bokjy,_f,__B_., Corresponding Member,
SOV/20-128-1-20/58
-W-SUSSR, Atovmyan, L. 0., Khodagheva, T. S.
TITLE: On Some Special Crystalloebemical Features of the Complex
Compounds of Ruthenium and Osmium
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 128, Nr 1, pp
78-80
(USSR)
ABSTRACT: The afore-mentioned compounds have been only little
investi-
gated from the crystallochemical standpoint. These elements
contain several stable groupings of the metal with light atoms,
i.e. primarily with oxygen and nitrogen. The metal - hydrogen
bond may differ according to the nature and number of the other
atoms linked up to nitrogen: Me - NH 3' Me - NO 2' file NO,Me-N.
A similar series may be obtained for oxygen-containing com-
pounds: Me - OH 2, Me - OH, Me - 0. There is a certain similar-
ity between these series, which the authors believe to be very
important for the chemistry of these compounds. This fact has
hitherto been to much neglected. The solid bond Ru - NO is a
specific property of the complex compounds of ruthenium. The
Card 1/4 authors first point out some facts known from previous
articles.

On Some Special Crystallochemical Features of the
SOV/20-128-1-20/58
Complex Compounds of Ruthenium and Osmium
New data is then given on the structure of the complex com-
pounds of ruthenium and osmium, which contain NO, N, H2 0, and
C1 as components. The compounds K2~RuNOC' 51 and K21RuC15H201
exhibit the dame structure and belong to-the deformed structure
of the type K2PtCl6' The structure of K2LRuN-:)Cl 0 was inves-
tigated more in detail. The bond Ru - N - 0 is linear, and the
distances Ru - N and N - 0 amount to 1.70 ~' and 1.25 % . This
is also confirmed by the following concept: Me = +N - _0 .
Investigation of the Ru NO bond is continued with the com-
pound K2 [RuNO(OH)(1102)4 The osmium compounds K20S 5NCl 5
and KOsNBr 4' 2H20 exhibit the same structure though their
chemical formulas differ. These compounds are interesting
because of the particular features of the sixth component,
i.e. of nitrogen. In the structures of K2 [09NC1,1 and
Card 2/4 K LOsNBr4H20] H20 the distance Os - N --,1.60 is
distinctly

On Some Special Crystallochemical Features of the
SOV/20-128-1-20/58
Complex Compounds of Ruthenium and Oamium
shorter than the Bum of covalent radii (1.35 +0-55 - 1-90)-
The chlorine atom (which is in trans-position to the nitrogen
atom) Is a shortened distance on the coordinate N - Os - C1
(-)2.1 ). All this indicates the possible existence of a
linear group which is similar to 0 - Os - 0. The above series
Me - N and Me - 0 are very similar in Ru- and Os compounds
because the distances Me - N and Me - 0 are shortened in both
cases. The authors then report briefly, on the final members
of the series of nitrogen-containing compounds. The assumption
of linear groups in 0e permits a new interpretation of the
structure of the series of complex compounds. The authors
believe that a compound of the composition K 20so 4' 2H20 con-
tains the osmyl group K 210802 (OH) ] . They began to analyze
4
the structure of this group. Complex compounds similar to
those investigated here are also found in Ru and some other
metals. In many cases investigated in this article the one
coordinate of the octahedral complex differs greatly from the
two other coordinates. This assumption will be checked by seve-
Card 3/4 ral examples. Them are 2 tables and 14 refemces, 5 of
which an Soviet .

On Some Special Crystallochemical. Features of the
SOV/20-128-1-20/58
Complex Compounds of Ruthenium and Osmium
ASSOCIATION: Institut obahchey i neorganicheskoy khimii im.
N~ S. Kurnakova
Akademii nauk SSSR (Institute of General and Inorganic
Chemistry imeni N. S. Kurnakov of the Academy of Sciences,
USSR)
SUBMITTED: June 12, 1959
Card 4/4

3/0 8 1/60/000/021/001/018
A005/AOOl
Translation from: Referativnyy zhurnal, Khimiya, 1960, No. 21,
p. 19, # 83741
AUTHORS: Bokiy, G. B., Khodashova, T. S.
TITLE: Crystallochemistry of Indium
PERIODICAL: Mineralog, sb. Llvovsk. geol. o-vo pri un-te, 1959,
No. 13, PP. 53-64
(English summary)
TEXT: The authors review the crystallochemistry of the
In-compounds, The
peculiarities of the metallic In-structure, its intermetallic
and inorganic com-
pounds are shown, as well as some regularities of Its
geochemical behavior. The
affinity of In is pointed out to form covalence bonds with low
coordination
numbers in intermetallic compounds. For inorganic compounds of
in(3+) with
oxygen and halogens the coordination number 6 (octahedron) is
characteristic, with
the elements of the Vb- and VIb-subgroups the cnordina-,Ion
n-amber 4 (tetrahedron).
The affinity to the formation of tetrahedral covalence bonds
with elements of the
VIb-subgroup increases with the transition from above downwards
within the sub-
group. By analyzing the compound structures of In with formal
valence (2+) il Is
Card 1/2

Crystallochemistry cf Indium
3/081/60/000/022 /00 1
A005/AOOI
Shawn that actually either In-In bonds take place or
simultaneously in k3+) and
In are present. For In+ the coordination numbers 7 and 8 are
charac%eris-ctC. -n
geochemical respect, great similarity is observed between In
and Zn (in s~,ilflide
minerals) as well as between In and Sn (iin compounds
containing oxygen). Tl%at is
obviously dependent on the crystallochemical properties of
In in the compo"Ind
groups mentioned. The specific crystallochemical analogy
between In and Ug -'s
also pointed out.
T. Khodashova
Translator's note: This is the full translation of the
original Russian abstrac*.
Card 2/2

FHME I BOOK EXPIDITATION SOV/4253
Bokiy, Georgiy Borisovich
Kristallokhimiya (Crystallochemistry) 2d ed. [Moscow] Izd-vo
Mosk. Univ.,
1960. 350' P. Errata slip inserted. 8,000 copies printed.
Ed.: Ye. M. Romanova; Ed. of Publishing House: S.F.
Kondrashkova; Tech. Ed.:
M.S. Yermakov.
PURPOSE: This textbook is intended for students of higher
educational insti-
tutions.
COVERAGE: This is the second edition of the text pablished
under the title
Vvedeniye v kristallokhimiyu (Introduction to Crystal
Chemistry) by the
Moscow State University in 1954. The present text consists of
four parts
and contains material on gemetric crystallography, geometric
theory of
crystal structure., basic conceptions of crystal chemistry and
crystal
chemistry of the more important classes of compounds. The
first and second
parts were entirely rewritten,- the third part is the same as
in the first
C ar-&-r/Lc-

Cr7stallocb=istry
SOV/4253
edition., and the fourth part contains partly new
material. The author thank
Ye.M. Rww for helping to prepare the manuscript for
publication. There
are 19 rererences: 12 Soviet, 4 English, and 3 German.
TABIE OF CONTENTS:
Foreword
FIRST PART. IAWS OF GEaKETRICAL CRYSTAI=RAPHY
Ch. I. Concept of a Crystal Crystalline Matter, and
Crystallography 7
1. Crystalline matter (7~- 2. Basic properties of a
crystal (8).
3. Crystal and crystalline matter (9). 4. Crystallography
(10).
5- Abundance of crystalline matter (11). 6.
Crystallization. Single
crystal industry (11),
Ch. II. Law of constant Dihedral Angles it Crystals 13
1. First works devoted to the study of the external form of
a-Ustals (13). 2. Methods of measuring crystals (14). 3.
Methods
of calculating crystals (16). 4. Derivations frm the law of
constant angles (18).

PCRAT-IOSHITS, Mikhail Aleksandrovich; BOUT, G.B.,
red.; KONIRAMKOVA,
S,F., red,; TZRKAKOT, M.Sep tekhn;'rede
[Practical course of X-ray diffraction stuky of
crystal,stractures]
Prakticheskii kurs rentganostrukturn6go analiza.
Moskve*' Izd-vo
Hook,univ, Toi,2, 1960. 6n i), iMIRA 130)
1. Chlen-korrespondent M SM (for Bokiy).
(X-RAT GRYSTALLOGRAPHY)

130MY, G. B.) PORAY-KOSHITS, M. A.
I/
-u~- . Tbe Crystal Chemiatry of Complex Compaurvio ol'
Metals of Group VIII."
Acad. of Sciences, USSR.
lyiper siibmitted for 5th Gen. Assembly, Symposium on
Lattice Defects, Intl. Union of
Crystallography, Cambridge U.K. Aug 1960.

_;. IKIY. ~G- --`
Complex compounds having multiple bonds In the inner
coordination
sphere. Zhur. strflkt. khim. 1 no-10.72-79 My-Je 160.
(HIRA 13:8)
1. Institut neorganicheskoy, khimli Sibirekogo
otdeleuiya AN SSSR-
(Complex compounds)

KWDASROVA, T.S.; BOKIY, G.B.
Structure of potassiym nitrosopentachlororuthenate.
Zhur.
atruk. khim. 1 no.2:151-158 JI-Ag 160. (MIRA 13:9)
1. Institut obehohev i neorganicheskoy khimii im.
H.S. Kurnal-ova
All SSSR.
(Potassium compounds) (Ruthenium compounds)

L.O.; I" BOKIY G -1
. 1'.
Stnxture of K20si,C19; and K[Os,l.'Br4fl2O] 1120.
Zhur. stnkt.
Idiim. 1 no. 4:501-503 N-D 160. (14MI 14:2)
1. Im+ktut obahchey i neorganichasicoy khimii AIT
imeni
;%S. Kuimakova i Institut neorganichaskoy hiAnii
Sibirs',.oro
otdcleidya IT SSSR, lovosibirsk.
(Osmi= compounds)

BOKIY, G.B.; POIRAI-KOSHITS, M.A.
Crystallography of cowplex compounds of metals of
group 8. Kristal-
lografiia 5 no.4:605-619 JI-Ag 16o, (MM 13:9)
1. Institut obshchey i neorganicheakoy khimii im. N.S.
Kurnakova.
(Complex compounds)
N,

BOKIY, G.B.; KUKINA, G.A.
Structure of platinum cis-ethylonsammine dibromide
crystals. Dokl.
AN SSSR 135 no.4:840-842 160. - (MIRA 13:11)
4
1. Institut obahchey i neorganicheakoy khimii AN SSSR.
2. Chlon-korrespondent AN SSSR (for Bokiy).
(Platinum compounds)

.BOKITI G.B.; SHIRNOVA. N.L.
Grystallochemistry of arsenides. otibnides, and
bismuthides.
Vest. mosk. ua. Ser. 4: Geol. 15 no. 5:22-37 s-o l6o.
(XIR,L 13:12)
l..Kafedra kristallografii i kriatallokhtmii
Moskovskogo
universiteta.
(Irsehic c6 ounds) (Stibnide compounda)
MUIsmuth compounds)

SIIAFRANOVSKIY, Ilarion Ilarionovichl BOM, G.B..,
red.;FOPOV,
rod.j FEDOTOVA, A.I., red. i O.A,, tekhn. red.
[Mineral crystalB; curve-faced skeleton, and
grawalar forms)
Kristallq mineralov; krivogrannye, skeletnye i
zernistye for-
my. Moskva, Gos.naucImo-tekhn.izd-vo lit-ry po
geolel okh-
rane nedr, 1961. 331 f6ryst&llography) (MIRA 15:1)

.. -.BOK-Up--!.L.;---VULIFp B.K.; SMIKHOVA, N.B.
Crystal structures of ternary metallic compounds. Zhur.
strukt. khim.
2 no. 1:74,111 Ja F 161. (MIRA 14:2)
1. Institut neorganicheskoy khimii Sibirskogo
otdeleniya AN
SSSRp Novosibirsk, Voyenno-vozdushnaya inahenernaya
akademiya
im. N.Ye. Zhukovsko~o i MoskovskLy gosudarptvennyy
universitet
im. Y,V. Lomonosova.
(Metal crystals) (Alloys)

BOKIY R.; ATOVMYA.4, L.O.
Covalent atomic radii in multiple bonds.
Zhur.strukt.khim. 2
no-3;308-311 My-Je '61. (KRA 15:1)
1. Institut neorganicheskoy khimil Sibirskogo otdeleniya
AN SSSR,
Novosibirsk i Institut obshchey i neorganicheskoy khimii
imeni N.S.
Kurnakova, AN SSSR.
(Chemical bonds)

BOKIYJ, G.B.; RCIAANOVA, YO.M.
Polyhedra in the atnictures of complex
sulfoarsenides,
Mistallografiia 6 no.6,.869-871 N-,D t6l. (IFIU
14:12)
1. Moskovskiy gosudarstvennyy imiversitet imeni.
M.Moomonosova,
(Crystallography)
(Arsenic compounds)

S/07 61/006/008/002/018
B121YB203
AUTHORS: Bokiy, G. B., Tsurinovj G. G., Sokol, V. I.,
Kolodyazh-n-yy, V. Z.
TITLEs Immersion liquids for crystallo-optical studies at low
temperatures (_1000C)
PERIODICALi Zhurnal neorganicheakoy khimii, v. 6, no. 8, 1961,
1754-1758
TEXTs This study concerns the determination of optical constants
of
crystals in wide temperature ranges from +250 to -1000C using the
immer-
sion method by means of a thermostat installed in a VC-10 (GS-10)
goniom-
eter. The method worked out permits a determination of refractive
indices
at temperatures to -150 'OC with an accuracy of 0.50C. The
temperpture con-
stance was controled with an 3TIbOl (EPV-01) or MP~7~-54
(MRShchPr-54)
electron potentiometer. Several immersion liquids wi h refractive
indices
of 1.378 - 1.705 were used for determining the refractive indices
of
crystals at a temperature below -1000C. The refractive index of
crystals
A+f
ain( -2)
is calculated from the formula: N where N is the refractive
sin A
Card 1/2 2

Immersion liquids for...
S/078/61/006/008/002/018
B121/B203
index and A the prismatic angle. The dependence of
refractive indices
the temperature of the respective liquids is expressed by a
line whose
angle of inclination depends on the refractive indices of
the liquids.
There are 2 figures, 1 table, and 12 references: 1
Soviet-bloc and 11
non-Soviet-bloc. The two most recent referenoes to
English-language
publications read as followst Ref. 71 R. Meysowitz, Amer.
miner. ~7,
853 (1952); Ref. 81 R. Meyeowitz, Amer. min. 40.. 398 (1955).
on
ASSOCIATIONt Institut obahchey i neorganicheskoy khimii im.
N. S. Kurnakova
Akademii nauk SSSR (Institute of Gpneral and Inorganic
Chemistry imeni N. S. Kurnakov of the Academy of Sciences
USSR)
SUBMITTED: July 19, 1960
Card 2/2

DOKIYP G.B.
Crystallochemical factors determining the behavior
of water in
frozen clay s6ilo. Vest.Moks. un. Ser. 4: Geol. 16
no.1:15-21
Ja-F 161. (MIRA 14:3)
1. Kafedra kristallbgrafii i kristallokhimii
Mookovskogo
universiteta.
(Frozen ound)
(Clayr

B~KIY G.B.; ZAGALISKAYA, Yu.G.,- POMIMKAYA, YO.A.
1. j
Crystallochemistry of sulfideao Report No.3t Sulfur,,
selenium,,
and tellurium of the A12 typee VestAoskouneSers 4: Geolo 16
no.3%18-33 W-Je 161. (KM 146)
1. Kafedra kristallografil i kristallokbimii Mskovskogo
universitata.
(sulfur) (Selenium) (Tellurium)

G&Ulvlterie Zbyust [Ilauy, Rene-Just);
SHAFILANOW9KIY, I.I., prof.;
ZABOTHINA, O.S.Ltranalator); STRATANOVSKIY,
G.A.ftranalatorl;
SMEVIKOV, A.V., akadeinik, red.; BOM, G.-B., red.;
PETROVSKIY, I.G.p akademik, red. ;-MFD-IiEY'E--V-,
i4.N., akademik, red.;
KAZANSKIYI B.A.9 akademik, red.; YUDIN, P.F.,
akaderik-, red.;
DEIDNE, B.N., red.; SMIRIN, A.M., red.; ZUBOV,
V.P.I. -prof.,red;
LEMEV, D.Y., prof., red.; FIGUROVSKIY, N.A., prof.,,
red.;
KUZNETSOVp I.V.,, kand. filos. nauk, red.;
ORIOBISHIIII, D.V.,kand.
istor. nauk, red.; SUSHKOVA, T.I., red. izd-va;
%IIRNOVA, A.V.,
tekhn. red.
(Structure of crystals; selected works] Struktura
kristallov;
izbrannye trudy. Sostavlenie, statlia i primechaniia
I.I.
Shafranovskogo. Redaktsiia A.V.Shubnikova i
G.B.Bokiia. Mo-
skva, Izd-vo Akad. nauk SSSR, 1962. 175 p.
Translated from,the
French. (MIRk 15:3)
1. Chlen-korrespondent Akademii nauk 5=1 (for Bokiy,
Delone)
Samarin).
(CrystallograpIV)

BDKIYI G.B.; ARKHIPENKO, D.K.
Oxonlum ion in vermiculites Zhur.etrukt.khim. 3
no.6s697-702
162. (MIRA 15:12)
1. Institut, neorganicheskoy khimii Sibirskogo
otdeleniya
AN SSSR i Institut geologil i geofiziki Sibirskogo
otdeleniya
AN SSSR, Novosibirsk.
(Vermiculito-apectra) (Oxonium comp%mda)

BATSANOV, S.S.; BOK I
j G.B.
Possibility of studying the hydrogen bond In
hydroxides
according to the interatomic diatances.
Zhur.strukt.khim. 3
no.6j716-718 162. (MIM 15212)
1. Institut neorganicheakoy kbimii Sibirskogo
otdeleniya
AN SSSR.
(Hydrogen bonding) (Hydroxidos)

ATOV14YAN.. L.O.;.P~ ~.~
Structure of the NH4Na[MoO C 0 ] ~20 complex and
its place
in the classification of ;Zj9Aen*u; compounds.
Dok1. Ali
SSSR 143 no.2:342-344 I-Ir 162. (MIRA 15:3)
1. Institut obshchey i neorganicheskoy khimii im.
N.S..Xurnakova
AN SSSR. 2. Chlen-korrespondent All SSSR (for
Boldy).
(Molybdonvm compounds)

KRAVCHENM, V.B.; BOKIY,. G.B. -,
Crystalline structure of searlesite NaBSi2P5(OH)2-
Dokl AN SSSR
143 no.3:690-692 Mr 162. ~MIRA 15:3)
1. Inst.',.tut neorganicheskoy khimii Sibirskogo
otdeleniya AN SM.
2. Chlen-korrespondent AN SSM (for Bokiy).
(Searlesite)

BOXIY., GeorSi7 B.
"Crystal chemistry of coaplex compounds."
r,eport to be submitted for the Sixth General AeswIly and
Intl. Congress of the
Intl. Union of Crystallograpby (IUCr), Rome., Italy, 9-18
Sep 1963
Moscow State Univ., USSR

SHAFRANOVSKIY, Ilarion Ilarionovich; otv. red.;
SEMENOVA, Ye.A., red.izd-va; ZAMARAYEVA, R.A.,
tekhn. red.
Evgraf Stepanovich Fedorov. Moskva, Izd-vo Akad.
nauk SSSR,
1963. 282 p. (MA 1617)
1. Chlen-korrespondent AN SSSR (for Bokiy).
(Fedorov, Evgraf Stapanovich, 1853-1919)

KRAVCHENKO, V.B.; BOKIY, G.B.
Some physical properties of natural and artificial
diamonds and
their dependence on the atomic structure. Trudy IAFAN
AN SSSR
Ser. Wol. no.9:178-186 163. (MM 16:12)

BOK17r, G.B.; BATMOV, S.S.
Structura3 aspect of traniseffect. MweirtruktokhImt 4
notlt8o-u
,Ta-lr It63. (KM 16t2)
1. Institut neorganicheskoy khimii Sibirskogo
otdeleniya IN SSSR.
(Gmpl6x compounds) (Rafractametry)

I ~ G.B.
ATOWIYAN, .0. L~91~4
Structure of the crystals hlahl'41M*O~C2041, ;~1120-
Zhur.strukt.khLn..
4 lio.4:576-583 Jl-Ag 163. (I-MHA 16:9)
1. Institut kIdmic)iuL;Io-,, Miki AV SSSR, Mm3lva i
Institut naerga-
nicheskoy khirdi Sibirskoao otdelenipa AN 56SR,
':ovosibirsk.
(Molybdcnun ccmpo-unds) (X-ray crystallograph,,r)

BOKIY,, G.B.; SAUMUVA, N.L.
Systematics of structural types. Part le Zhur.strukt.khiA4
4 no.5.-744-756 S-0 163* (KMA 16: 11)
1. Moskovskiy gosudarstvann-yy universitet imeni Lomonosova,

BOKIY, G.B.1 BER3UKFR, 1.13,
Reason for the low trans-activity of the nitro group
in octahedral
complexes of tetravalent platinum. Zhur.strukt.khim. 4
no.6:
934-936 N-D '63. (WRA 17:4)
1. Institut neorganicheskoy khimii Sibirskogo
ot,deloniya AN SSSR
i Institut khimii AN Moldavskoy SSR.

BOX.I.Y, - G.B.
Development O'f,N,S,Kurn&kov's coneepta in modern
aryBtal
("Kurnakov lectures," Dec.6, 1962). Zhur.noorg.khim. 8
1040 Yf 163.
%
(Cryst&Uograpbyl,
chemistry
110.5tlO33-
(MM 16: 5)

BOKIYP_~4~9 SOKOL; V.I.
)b&'od of date rm*tion of the density of crystalline
compounds
stable at low temperature. Zhur.~eorg.khim. 8
no.5t1O41-lO"
* 163. (Crystals-Density) (Liquids-Density) (Y.IIU 16
t 5)

BOKIY, G.B.; KACHALOV, A.I.
Crystalline forms of astrakhanite. Vest.Mosk.un.Ser.
4:Geol. 18
no.2:58-60 Mr-Ap 163. (KRA 16:5)
1. Kafedra kristallografii i kristallokhimii Moskovskogo
I
universiteta.
(Bloedite)
dor

BOK1Y , Georgi7 Borisovich; PORAY-KOSHITS, Xikbail
Aleksandrovich;
tmLvv, red.; DOLIVOa-DOBROVOLISKAYA. Ye.M.
2
red.
[X-ray structural analysis] Rentgenostrukturnyi
analiz. Mo-
skva,, Izd-vo Mosk. univ. Vol.l. Izd.2. 1964. 488
p.
(MIRA 17:12)

ACCESSION NR: AP40192-(O -9/0192/64/005/001/006b/0069
AUTHORS: Venglovski, 3.;-B__0k_iY. G.B.; Pobedimskaya, Ye. A.
Y" , ,
TITLE: Crystal structure of titanium diarsenide TiAs2
SOURCE: Zhurnal Strukturnoy khimli, v. 5, no. 1, 1964, 64-69
TOPIC TAGS: titanium diarsenide, crystal structure, x ray
an&lysis, Paterson function, electronic density, titanium
ABSTRACT: X-ray analysis of TiAs2 was conducted in order to deter-
mine its crystal structure. It crystallizes into a new structure
8.96, o 3.50 A, N S. All
type. The rhombic cell is a 13.27, b
atoms hold the position 4 g of the spatial group D" - Pn- . The
schematic of atom grouping on the plane xy and the spatial drawing
of TiAs2 structure are given in Figure 2 and 3. Determination and
specification of coordinates of atoms was made according to pro-
jections of the~'Patdrson function and electronic density. Final
distribution is given in enclosed figure 1. Orig. art. has: 3
Card 114

ACCESSION NR: AP4019270
figures, 1 table.
ASSOCIATION: Institut fizioheskoy kh1mii (Institute of Physical
Chemistry); PoM skoy Akademii nailk., Warsaw . (Polish Academy of
Sciences); Moslcpvskiy gosudarstvVnny*y unlversitet Imp N.V.
Lomonosova (mqsCoW:'.State Univerpity)
AdQ: 27MAr64
13,Mar6~
SUBMUTED: -
DATE
ENCL: 02
SUB CODE: CH - NO REF isov: 009 OTHER: 002
Cord 2/4