SCIENTIFIC ABSTRACT BOLSHOV, V.M. - BOLSHUTKIN, D.N.
Document Type:
Collection:
Document Number (FOIA) /ESDN (CREST):
CIA-RDP86-00513R000206130012-6
Release Decision:
RIF
Original Classification:
S
Document Page Count:
100
Document Creation Date:
November 2, 2016
Document Release Date:
June 9, 2000
Sequence Number:
12
Case Number:
Publication Date:
December 31, 1967
Content Type:
SCIENCEAB
File:
Attachment | Size |
---|---|
![]() | 4.38 MB |
Body:
ALEKSEYEV, S.M.; BQL1aHOV, V.M.; VITKOV, M.G.; GUKIN; V.I.; IVANOV,
V.M.; MALININ, R.M.; PILTAKYANp A.M.; PLENKIN, Yu.N.;
SODDLEVSKIY, A.G.; BURLYAND, V.A., red.; BORUNOV, N.I.,
tekhn. red.
(Handbook for beginning radio amateurs] Spravochnik nachi-
naiushchego radioliubitelia. Pod obshcbei red. R.M.Malinina.
Izd.2., stereotipnoe. Moskva, Gosenergoizdat, 1963. 623 P.
(Massovaia radiobiblioteka, no.400) (MIRA 16:5)
(Radio--Handbooke, manuals, etc.)
(Radio operators--Handbooks, manuals.. etc.)
; ., N
BOLISHOV, V., inzh.
Low-frequency amplifiers. Radio n0-4:31-34 AP 163.
(Amplifiers, Elect-ron-tube) (MIRA 160),
-BOLISHOV, V., inzh.
Detection and detectlW circluits. Radio nio-3:32-36 Mr 163.
(MIRA 16:2)
(Radio detectors)
FIU.TOV, Igor' Semenovi,.,b,g BOLISHOV, V.M.p red.
[Two.-chaiaiel low-,frequency amplifier riykl acou3tical --ystemj
Wukhkanallnyi usilitell nizkoi chastat-i J zvukovai.a kolon-
ka. Moskva, Energila, .1965. .14 p. (Vlas5ovaia radiobiblio-
teka, m.564) WRA 180)
L 34809-66
t ACC NR: AP6021803
SOURCE CODE:
INVENTOR: Bol'shov, V. M.; PQ elltsov, A. N.; Smirnov
uR/o4l3/66/000/012/0072/0072
V. 1. '7
ORQ: none
TITIZ: Device for the contactless investigation of the pooling of blood in organs
and vessels. Class 30, No. 182847
SOURCE: Izobreteniya, promyshlennyye obraztey, tovarnyye znaki, no. 12, 1966, 72
TOPIC TAGS: blood sensor, human physiology, animal physiology, blood circulation,
hemodynamics, hemodynamic sensor, P4.Fr11Y,5rn0GR,,,7pNe
ABSTRACT: An Author Certificate has been issued for a device used to study the
pooling of blood in organs and tissues. It consists of a housing, high-frequency
Fig. 1. Block diagram of device
Card
1 - High-frequency generator; 2 - power source;
3 - sensor; 4 - Q-measuring circuit.
UDC:
.471.621.38:612.14
L 34852-66
ACC NR: AP6015149 0 1
shape. The synchronized generator is represented by a blocking generator, whiled
a diode -transformer comparator performs the functions of pulse generation and
pulse comparison. The process of synchronization is explained, and formulas
describing zones of synchronization are developed. Two experimental circuits
designed along the above lines were tested with these results: (1) An electron-
tube circuit ensured a maximum division ratio of SO-70, with a supply-voltage
Variation of t 20% and a synchronizing -pulse frequency of 75 kc; (2) A
transistorized'circuit exhibited a maximum division ratio of 40, with the same
� 20% voltage variation and a temperature variation of * 20 + 7SC. Orig. art. has::
19 figures, 26 formulas, and I table.-
SUB CODE: 09 / SUBM DATE: OSApr64 / ORIG REF: 002
Card 2/;-
.1 ; e; t, , " -
- "' "' "'~L" "'
BOLISHOV, V.P., Cand Tech Sci-(diss) ~-. - i of exDcris~- -; data
on the viscosit,, and heat conductivity of vrater vapor. 11 Ka~;an' , 1958. 10 PP
with Craphs (14in of higher Education IjSSR. Yazan' Chemico-Technolog-ical
Illst ill S.M. Kirov)) 1-50 CoPies (K1,,30-58, 126)
FELASK I BOOK EXPLOITATIOX sov/1826
Akademila nauk SSSR. Energetichookly Institut
T0PIOPor*dach4 I toplovoye madellrovanlye (Heat Transfer and "J,
modeling or Heat Processes) Moscow, lzd-vo AN SSSR, 1939.
419 P. Errata @lip Inoorted. 3,50o copies printed.
9d
s
M.
A.
M1kh I Academiclant Ed. of Publishing
2os&
;u
;
D
,
so vano To
A
02. Ed. I G. X. Shovchonko.
0 PWO5Zt The book to 1jitelmded for scientists concoriZed with heat
transr*r, heat eats@ n, and hydraulics of liquid =etals, etc.-
COVEUGZs This collection Is dedicated to he momory of Academician
N. V. Kirpichey who in the twenties initiated a systematic
Inv*ettgation or heat transfer processes and the efficiency of'
heat apparatus. Later he led the development of roxparch work In
this fiold. Two special collections devoted to works or Kirpiche;.,
sahoal
have been published. one in 19)8, Mat*rialy a 0108 hchanlya
s
p0 W4 lirovanlya (Materials of the Conrerenc; on Plodoling) and In
1951# Toorlys podoblya I modelirovanlye (Theory of Similitude
and Modoling). The present collection prepared in 1936 represents
further devolop"nt of' the work of this school. This theory is
fundamental for the analysis of many heat problems In the field of
electrical and radio engineering. Of great-Importance are the
first eyetowistio investigations of heat transfer and jhe
hydraulics of liquid metals which as a now kind of heat carrier
My be Used Lim the various branches of modern engineering. As.a
result of special investigations or some cases of convective
beat t
n
f
d
ra
s
er# 4
ependence of the process on the kind of liquid.
t-0 P41r8tUrG. Pressure, direction of the heat flow. and othor
raotors, was discovered and established. On the basis Of' a wide
"riallsation of experimental data, now dependable recommeftidat tons
or heat asialys&* of
n
ineorin
ui
went war
e
dev
l
d
e
e
ope
g
g
q
. Or no
p
:
less Intorest Is the ork on heat transmission In boiling liquids
and Me condensation of vapors. All Investigations aro%basod on
the theory of slailitudo. the nature or whi h. according to K. V.
C
*
g N
irpichev, to that of
experimentation.' Work on the theory of
l
& regu
ar regime applied to a system of bodies with an internal
source of heat In of Interest for the future.
Card 2/20
Vemnov. A. 0. On One Supplementary Condition of Simlinrity or
-WFr4rUTRr--Proce ones 298
,One, supplement.&" condition of similarity of moloculur
processes was established consisting or Lhe requirement
of identity of density fields 0 f the probnWitty dlatribu~ion_
Similarity oquations describing the kinetics or mOlOcu1sr
processes or transfer were established. Zxperizental datA on
viscosity and heat conductivity or gases are eeneralized.
There are 13 roferencest 10 Sov Iat and 3 -Triellsh.
Card 16/20
Heat rraftsf*r (Font.)
rOV/1826
rf_m . & C., and V. ?. Poltshov. ren~r&ljr,~.jon or '_xpairtmentcl
-Date, an thi Viscosity or -Itq..o1 )1)
Th " Sone'ralization deperldr an the 'AnOwltdge Of' c"Irct,:1~nts
or heat Onductivi'YA -nd of the dynamlc viscosity Y- -'A 2
aver&" values of those coerricients tire doternInq'I by rr;,Pho
y . y (t) LMdf..f- (t) drawn a-cording to exPOrSmant.a.' ~atu fOr
various pressures. The method deacribed was veriric~i or. the
.orpera
example or a wide range Of a turez and precoures of'
The generallted relations n y be, unad to Increase kro-ledfe of'
hen tconductivity am VISCONIty coarrICIL, f., I tear. ~1'hout
further experiments. ' D- -- T.-mrot and G. 3. *Jnri-nCt 11k afe
mentioned in relation to eX12 riontal d-t2 an', L~e eluatl- or Y.
There are 5 references' L' Soviet end I English.
107-57-3-23/64
AUTHOR: Bol'shov, Yu.
TITLE: Pbwer-Siip~T,~_,df'an Antensifier. Experience exchange.
(Pitaniye antennogo usilitelya.. Obmen opytom)
PERIODICAL., Radio, 1957, Nr 3, p 19 (USSR)
ABSTRACT: Utilization of the antenna co-axial line is recommended for bringing
the 6. 3 volt 50 cps heater supply to an antenna amplifier. A simple circuit
diagram shows additional capacitors and choke coils necessary for the separa-
tion of frequencies. A "UPT-21' attachment as an antensifier was tested with a
"T-2" TV set; no interference attributable to the power. supply was observed on
the screen.
There is one figure in the article.
Card 1 1
PADALKA, Ye.. takhnik-loytonant; BOLISHOV, Yu., mladshiy sarzhant
,
Radio-controlled imitator of a target. Voen. vast. 38 no. 6:70-
72 Je 158. (MIRA 11:7)
(Military art and science)
(Night fighting(Militar7 science))
BOLISHOV, Vladimir Mikhaylovich: BOLISHOV, Yuriy Mikhaylovich;
PETROV, V.A., red.; VORONIN. K.P., tekhn.red.
[Simple designs for the beginning radio amateur] Prostye
konstruktaii nachinaiushchago radioliubitelia. Moskva, Gos.
energ.izd-vo, 1959. 71 p. (Kassovaia radiobiblioteka, no.346).
(MIRA 13:6)
(Radio--Receivers and reception)
8(2), 9(4)
AUTHOR: Bol'shov, Yu.
05391
SOV/107-59-8-11/49
TITLE: Measuring Probes With Semiconductors
PERIODICAL: Radio, 1959, Nr 8, pp 14 - 15 (USSR)
ABSTRACT: The author described the application of DG-Ts diodes
in ineasuring probes for tube voltmeters. He shows
three circuits for connecting a DG-Ts27 diode. In
FiGure 2, a diagram of such a measuring probe is showrn.
There are 3 circuit diagrams and 1 diagram.
Card 1/1
PHASE I BOOK EXPLOITATION SOV/46oo
Bel'shav.,, Yuriy Mikhaylairich
aLMrmichnyy p;~y~emnik anzistorakh (Economical Transistor Radio) Moscow.
Gosenargoizdat, 1960. 31 p. (Series: Massovaya radiobiblioteka, vyp. 371)
110,-COO copies printed.
Mtorial Board: A.!. Berg, F.I. Burdeynyy, V.A. Burlyand, V.I. Vaneyev, Ye.N.
Gen~.shta-j' !.S. -Dzhigit., A.M. Kanayeva, E.T. Krenkel'Y A.A. Kulikovskiy, A.D.
Smirnov. F.1. Tarasov, and V.I. Shamshur; Ed.: L.Ye. Levitin; Tech. Ed.;
K.P. Voronin.
FURPOSE: This bc~oklet is intended for the radio amateur.
CCITEPAGE: The booklet describes the construction of a homemade, economical
trttasistorized straight receiver, which is reccemended for the radio amateurs
residing in areas without electrification. The receiver can be assembled from
ccumon standard. components,, and its circuit diagram is comparatively simple.
N3 personalities are mentioned. There are no -references.
Card 112
Ecoar-mical Trcin6-1,stor Raclio
TAPTI CP CC-\TENI?S-
General ,-taxactard.sticA
Basic DI-)iFlam
,x.ter,ts
~xmp.
Ccustructim and Wiring
Adjuziurn~znt.
Various T-,Ype;-; of Receivers
Testing the Transistors
AVA7.1ABLE: Library of Congress (TK6564.T7B6)
Card 212
I
scr.;/46--Do
3
3
7
13
18
27
30
JP/rsm/gap
12-16-6o
PCHMINp V.A.; IZKATIDVA., V.N.; BOLISHOVAR SJO
Effect of benzene solubilization on the catalyt4c jprqpwM9-W
pepsin. Dokl.-AN SSM 3.42 no.4:950-953 F 162. (KMA l5t2)
1. Moskovskiy gosudaretvennyy universitat im. M.V.Lomonosovas
Predbtavleno.aWemikom PA.Rebinderom.
jBP:.Psen.))
SolubLlity
A A
0
zW h1wrallgallen of Ow FArWtum of StW by 14ftnq "I
K M. tkl,-
(in Rug-i&n
)
"ma
ille
1 O
l
,
,
ft
ts 6
ff
va
A I
ftlx~ra~
1
F
t
'
Octury
. Zat-.&kaia bubO"tOHW(t (
A
1079-1086
t 1947
3
S
.
, P.
ep
t06), V. 1
,
010 The work described was undertaken because of
the beat
the need for closer standardization In
00
W W tregtnjent of tool steel. Results showed that the
00
0 above method, which Is applicable mainly to the
proposed by N. C. Akulov In 1934,
surfaes layer
so W ,
09 4F is satisfactory.
:11 in
CLASUFOCAII"
A)DOO, ON, Jal
=00
gee
goo&
awe
too
as's
NPO
ago
U n AV M3 4%;; ; ; ; ; ; I I
ir
0.41,0
K. ".
Akulov, 111. ;., -"'Lokliina, 0. 1., Bol'sho -a. K. M., ani Chernovl-i, Investigation
of the const;nt of !ha anist.-z)py of ~ner, 'u-,"'D. P 855'
L, --y in triple illoys of the system Nl-~
I
The c3nstant of 5nistropy for the tilple system Ni-Cu-~%o ch~-~nges '-s the amount
of cop-er and molybienum are, increised.
3c--entific Inst. of 1hysics, Yoscow St3te University
J uly 7 9 19 "1 S
SO: J:)urnnl of Technical P'.-.ysics (USSP) 19, N.D. 1-1, (10,40,)
Us law of sWozimstim to estsuradesit in cubw stash.
X.S.Akulov,stsilK.M.11ol'shava. Pettleit.VoikoeVvir.
S. No. U. Set. Nam& No. 6, 79-al
()WjD).-Tbe legion its which tempered C steels approach
m1n. Mrrespotion to the interval of fields W)U-I.W orroveds
and cats tic described by the formula: a ~ (.41119) + (BIRA)
+sp- In thi. law the lot term bass very high wt. fur steels.
in the temIx-red state the Ist term exceeds the 2nd by
orvc-raltimes. This means that In the law for (be approach
to min. for martersoite. the term Allit is 0( major tmpor-
tatter. On the other hand. for homogeneous alloys, even in
the cold-workt'd state. the Ictirn B/111is of major Importance
in the law for the approach to saw. Another difference
between the approach to satn .of C steeh and homogenrou%
all I- that for fetupered marten%ite of high-C steels. the
~T B has a nell, silto The appearance of a neg. sign for
;
B and a very large value of the coefficient A for mancnOc
it explained by the action of strains within It. J. R. L.
iL i"15T59
Lam/metals Mairtenmito 1 Apr 50
"Lav of Approximation to Saturation for Marten-
site," N. S. Akulov, Act Mem, Acad Sci Belo-
russian SIM, K. M. Bollshova, Inst Phys, MoB-
cow State U imeni Lcoonosov
"Dok Ak Nauk SSW vol =, No 4, pp 633-636
Considers coeff A, B, C in gen forzula for s 5-
c*ptibility K = I/If = kp + A/jff2 + B/H3 + cM
Graphs of K ve R (up to 1,400 oersteds) for
various percentages of carbon. Also A, B, C
vs T (UP to 30000 for various carbon contents
'Oup to 1.12% c). submitted.6.Feb 50.
175T59
S-vsuov~, K.m.
"Investigating the Effect of Feterogencity end Interml Stressen on ?",pp-netim In
n, Moscow Order Lenin State U
Str,~ g Fields of Alloys With an Iron Base." Sub 21 Nov 51, 11
imeni ?4.V. Lomonosov , for degree Cand. Ph;YaicomfttheftkticaI -Sci.
Dissertations T)resented. for science and engineering degrees in Moscow during 1951.
SC:Sum. No. 480, 9 ~L-y 55
UWR/Physi~s - Magnetization Oct 52
"Investigation of Magnetization of Heterogeneous
Alloys Fe-W and Fe-Cu in Strong Fields," K. M.
Bollshova, Magnetic Lab, Sci-Res Inst of Phys
C) '*Vest Moskov U Ser Fiz-Mat i Yest Nauk" No 7.,
0
H
pp 63-69
0i State that subject investigation is of independeni
B,- interest since it permits one to trace the in-
fluence of small additions of a nonmagnetic
co=ponent on the behavior of the anisotropy
constants of subject alloys. Verifies the
usual law of susceptibility k=A/1424-ri/IT-31 k
in the case of t Ition 'to iaturation. A&= that
an extra tem CrAmis sometimmir needed, Submitted
23 Feb 52-
243T100
'DOL'-3,iOVA, X. 1.~.
7
ne t i s m
Effect of heterogeneity and inner tensions on the nagnetisin of alloys
4
with an iron base in strong fields, Izv. All SSSR. Ser. fiz. 16, 110. 5, 1952
14onthly List of Russian Accessions, Library of Congress, June -1953, Uncl.
U.WR/Physics - Magnetization Sep 5~
"Magmetization of Heterogeneous Materials in
Strong Fields," K.M. Bol'shova, Moscow State U
"Zhur Ek-sper i Teoret Fiz",.Vol 23, No 3,
pp 349-356
Investigates experimentally the behavior of mag-
netization of ferromagnetic materials in strong
magneti:: fielda. Shows that in agre ment vith
theoretIcAl assumptions the term A/P entering
the exp77-ession for susceptibility in the law gov.
erning apyroacb 1.0 satn appears in Fe-Mo alloys
during passage beyond limits of soly, that is,
vhen nonmagnetic inclusions occur in the structure of
the sample. States that the lst coeff A is larger
the larger the inclusions in the material. Thanks Prof
Akulov, wbo proposed this theme.
227T90
Otv*er
10159* :tVsvtkM evre of nam4leily Ortal am from
.
Is Sfrom$ IN. S. Akulov ar;l K. M. flol'iLlKn-a-
, Doklady Akadrmil Nauk SSSA. Tww Wr.. V. 81 AIR, ZT7'M.7-
I P. 817-819.
Arrow inm &M an Fe alloy containinil 41 Mo orre m"1 in
r,,perlawatal detrFmInation of the aim-a. Dals are chaned-
I
B0L*.-'3!-',GJA) K.i.i.) -LOEjIiAJV T.A., j3LWi, K.P
"The Study of Ma.:.nctization of Fer-ites in t.he .1e.-ion of the.
Curie Point" U~oscow)
Conferenct! on Fhys.-L~-s of iilL rnetic Phcna.,ena,
I
I-lay 1~~51-`, Sverdlovsk, USSR
. 1 1 N~ao--- -f-
- ldz~- ~
BOLSHOVAS K6 M.9 BELOV, K. P., and MUJ=, T. A., (Moscow)
"The Study of Magnetization of Ferrites in the Region of the Curie
Point," 8 PsPer submitted at the International UInference on Physics of
Magnetic Phenomena, Sverdlovsk, 28-31 IbY 56. -
48-6-2/25
AUTHORS: Belov, K.P., Bol'shova, K.M., Yelkina, T.A.
TITLE: Investigation of Ferrites in the Vicinity of the
Curie-Puint (Issledovaniye namagnichiVaniya ferritov v oblasti
tochki Kyuri)
PERIODICAL: Izvestiya AN SSSR, Seriya Fizicheskaya, 1957, Vol. 21, Nr 8,
pp. 1047 - 1054 (USSR)
ABSTRACT: The paper under consideration deals with the magnetization pro-
cesses of some ferrites in order to determine the temperature
change on spontaneous magnetization near to the Curie point. It
is maintained here, that such data are missing in literature,
although they are of great importance, because the mech&nism of
ferromagnetic phenomena in ferrites are different from ferromag-
netic metals. The sections of the paper are headed:
1.) Samples and methods: 7 samples of Mn-Zn ferrites with a
-
varying MnO content T
20 -. 40 ~) and 2 ferrites of Co-Zn alloy
were selected. The measuring of the magnetization curves was
executed according to the ballistic method. The samples were
mar.,-netized in a solenoid with a field strength of 2500 Oe. A
Card 1/3 ballistic differential winding, consisting of two sections of
48-8-2125
Investigations of Ferritles in the Vicinity of the Curie-?oint.
4500 spires each on an ebonite body, was mounted on the electric
furnace containing the sample. Forcalibration a one-layer wind-
in- of thin wire was prepared, which was wound on a body of the
identical form and size as the sample. By introducing- this wind-
ing ins tead of the sample calibration was effected. 2.) The
curves of actual magnetization of ferrites near the Curie point:
Here it is established, that in this case the well-known thermo
dynamical equation 2 H
Ot- + P a- _67 is applicabb, Er denoting
the specific magnetization and thermodynamical coeffi
cients. The conclusion is drawn, that the sequence of the values
of the para-processes of ferrites under investigation corresponds
to the sequence of ferromagnetic metals. The theoretic relation
between the intensity of the paraprocess and the value of the
Curie point is stated here as follows: The lower the Curie point,
the weaker is the interaction and the higher the effect of the
excitation of the external field, implying a higher intensity of
the paraproceS3es. 3.) The reaction of Un-Zn ferrites ih weak
fields near to the Curie point: Here the magnetic anomalies are
deocribed, of which allegedly no data are to be found in litera-
Card 2/3 ture. These data consist of the fact, that the final magnetiza-
48-8-2/25
Investigations of Ferrites in the Vicinity of the Curie-Point
tionpf the above-mentioned Mn-Zn ferrites, starting from low
temperatures, first dearoaaes at the approach of the Curie point,
startsto grow just before reaching the Curie point, and finally
falls off after reaching a certain maximum. The coercive force
behaves similarly, which, in some cases, shows a very accentuated
rise from the minimum to the maximum. These anomalies can be re-
produced also, if the samples are isolated from the influence
of air. No anomalies of this kind were found in Co-Zn ferriteB.
There are 9 figures, 1 table and 7 references, 5 of which are
Slavic.
ASSOCIATIONi Dept. of physics of the Moscow State University imeni M.V. Lo-
monosov
(Fizicheskiy fakultet Moskovskogo Cos. universiteta im. M.V.
Lomonosova)
AVAILABLE: Library of Congress
Card 3/3
24(3)
Author. D-yako., I.P., Candidate of Pky.i~.I- ncT/55-56-2-54/35
Matheinatic.1 3.1 .....
TITLX, Sumay of ftyare Ik" by f -..CO.
UsIvar.Ity&LthwAU-tfti= C-Crestoothe Pbywks if -&-tic
Material. (Obs.r
M T$e9oYUXnoa ooVoahChanli po fIX k try
PtILODICA.La Testnik Wookovskogo Vnlvbr3I-.,-a-r~ya -1ar-111,
"tronotdL, flilki, khlal, 195~13, Sr :.;p .1.17-2150 (:=A)
A337RAC-. Fro= Doc-tir 6 - 1t,1957 there took place it.* fourth ~rion
Congress an phvoica of cagnetic mtrrtalm in L-mirgrad. (The
first two zestinv took P:ace !546 anj f95, t- :ver!l2v,k.
the third avettiW 1956 in Itc.cow). The car.Cress ...
ty . Academy of Scl*.c.8 of the V:SR. D.y.rtz.ct of Phy,J-1-
Rathe"tical Sciences, Scientifi. Co-cil on ?,Andawntal
Problem of Magnetism. :r.2!1-.uto for Samicorduclors of it*
&c*d..y of Scl.a.... =32 and C.-itt.. Car Tt-
were sore than 300 p.rtitt;%tar., 51 lecture- -,r- ei-,
4.ong tt-As tbe following lecture. of the repres--a-1,ws cf
the Moscow State Cnl,.r.ity
rcfas.r
R.T. T.1-clst. T..?. K.rItvy", L.ct.r.r C,. the
actyof . - ti,;I-r,a: of t-v
,:
2. frof-sor 2.7. -,*1 ... In. 7..Y. Xarh.rl~ , A-Istant
OnM,-,IL4
712.c41ty of Ferri "I",
,
r r -11ter.11 ~.I- nUhk.,. A,;Imn-
;
12frect or natt. vI..I.&"y = Lho Frvqu~acy CbArw~-tvrlstjc.
of rerr,t..,.
"
L4aturer -riations of S--cturv -d Lott.
T
Dt9tyar
.
t is;
f;
;
.
r amen* i Proper. f It 3F.,.
N.A. q_mkovskiy. Lecturer, S.Ya. Prol.kaya. :unior -cieMtifLc
Io* I
III -
"'
1*
Ile Pro;.rtl.. z1
k
:.
L r.r "Kagn.-o.tricilon Przp rtl* i
;
C. . D
rr.f..#.r T..Z: t-d-skiy, I.bolo,. A.sr.t.nt
-
-
Zloctrtc Proper-fe
a
af li-:-Feriftes".
ApireAt arnatic ?rarertts. &r.1 :%ricture of Ifang-se
a
*r a , I a"*
1
9. $.A. :SPI,k.,. zint., 1-1-tific
PAL- 3.s. Pra;.rtl-. of
10. $.A. Ztol'kS;,
ti. -d Y,.:. F~=-,-. :,,i--r of
r ".. pr-.C;w--y
12.
K.P. an.
Tizz, --, :.r.. L.7.
*
Y-
15. Pr.f
A'.'~Y. X-r tt Lb.; --ri c!
r .%t
T
If
%
AUTHORS: Belov, K. P.,_Dolfshov,~~~, SOV/48-22-10-23/23
~F_
Yelkina, T. A., Zay sevat M. A.
TITLE: On Magnetic Properties of Ferrites Exhibiting a Compensation
Point (0 magnitnykh svoystvakh ferritov s tochkoy
kompensataii)
PERIODICAL; Izvestiya Akademii nauk SSSR. Seriya fizicheskaya, 1956,
Vol 22, Nr 10, pp 1262 - 12Q12 (USSr')
ABSTRACT: In the present paper the authors performed exact measure-
ments of the magnetic properties of mixed lithium chromite
ferrites (which were annealed and hardened) in the case of
different annealing after hardening. For the investigation
a system of ferromagnetic lithium spineis that contained
chromium of the common formula
Li 20-0 - 2a) Fe 203 ' 2 a Cr203 (for a = 1,25; 1,5; 1,6; 1,7)
was synthetized. The following magnetic characteristics
were investigated: 1) Temperature dependence of the spontan-
eous magnetization of a (T); 2) magnetic moments of the atoms
(the measurements were garried out by A. V. Ped1ko);
Card 1/4 3) temperature dependence of the residual magnetization of
On Magnefie Properties of Ferrites Exhibiting SOV/48-22-10-23/23
a Compensation Point
the limiting cycle in the temperature range of from -30 0 to
about 10to .200above the compensation point (by the astatic
maCnetometer); 4) temperature dependence of the paramagnetic
sensitivity (according to the ponderomotive method). The
measuring results showed that the ferromagnetic spinels
Li FeCr in a certain range of solution exhibit an anomalous
shape of the curve as (T) with a compensation point. This
has been predicted by Neel. In contrast to the theory it
was found that the compensation never was perfect. The
phenomenon of an imperfect compensation may be explained by
the heterogeneity of the samples. An other considerably
greater difference is that the value of the absolute satura-
tion computed (according to Neel) from the distribution of
the cations does not agree at all with data found experimentally
(Table 2, column 3 and 5). The modification of Neel's
theory suggested by Yafet and Kittel (Ref 6) is capable of
explaining this discrepancy qualitatively. The explanation
is as follows: As the measured value of the magnetic value
in these ferrites is lower than the value computed according
Card 2/4 to Neelts theory and M B' "A' in this case the negative exchange
On Magnetic Properties of Ferrites Exhibiting SOII/4-8-22-10-23/23
a Compensation Point
interaction within the sublattice B compared with the inter-
action between the sublattices A and B must not be neglected.
The measurements showed that the value of the absolute
saturation in the system LiFeCr-ferrites becomes higher
in the case of hardening. In technical publications there
are data on the influence of hardening upon 6 0 of various
simple and composed ferrites (Refs 10 and 11) and theories
(Refs 12 - 14) explaining the results of the papers (Refs
10 and 11). According to this C 0 depends on the distribu-
tion of the cations on A and B . This distribution, however
depends on the temperature. In the present case the problem
became more complicated as apart from the cation distribu-
tion also the variation of the angles between the magnetic
moments in sublattices was possible. The possible influence
of these two factors excludes a comparison of the experimental
values found of saturation in hardening with respective
theories. The question of the influence of these factors
probably might be answered by means of radiographic and
especially neutronographic investigations. The authors
Card 3/4 express their gratitude to K. G. Khomyakov and T. I. Bulgakova
On Magnetic Properties of Ferrites ExhibitJng SOV/48-22-10-23/23
a Compensation Point
for valuable suggestions. There are 10 figures, 3 tables,
and 14 references, 4 of which are Soviet.
ASSOCIATION: Fizicheskiy fakul'tet Moskovskogo gos.universiteta imeni
M. V. Lomonosova (N-1,,t, Uf Physics at the Moscow State
University imeni M. V. Lomonosov)
Card 4/4 uscomm-Dc-6o,966
,,Z 1/. -.7,27 6r 0 69004
AUTHORS: -Bollshovap K. M., Yelkina, T. A. S/055/59/000/04/008/026
BO14/BOO5
A~
TITLE: The Anomaly of the Coercive Force of Ferrites in the Compensation
Point
PERIODICAL: Vestnik Moskovskogo universiteta. Seriya matematiki, makhaniki,
astronomii, fizikit khimii, 1959, Nr 4, PP 85 - 90 (USSR)
ABSTRACT: Ferromagnetic spinels of the composition L12O(5 - 2a)Fe 20 3* 2aCr 203
with 1.!G~d:!52 have the characteristic property that their sponta-
neous magnetization changes to zero not only at Curie temperature
but also at lower temperatures. This temperature is called
compensation point in which an equilibrium of magnetic moments
of the sublattice may be observed. Experiments carried out by
the authors (Ref 3 ) showed that an anomalous change of the coercive
force of these ferrites is found in the temperature range of the
compensation point and of Curie temperature. The authors give two
reasons for the fact that u alight
be aoderts.ined at compensation point: i) 81i&ht fluctuations in
the chemical composition. 2) Heterogeneous cation, distribution in
Card 1/3 the spinel lattice. A discussion of the possible causes of the turn
1-r
6 0
The inomaly of the Coercive Force of Ferrites in S/055 59 000/04/008/026
the Compensation Point B014/BO05
about of spontaneous magnetization leads to the conclusion that the
coercive force increases with increasing approach of the temperature
to compensation point, reaching a maximum at this point. To check
this assumption, the authors carried out experiments to determine
the temperature dependence of coarcive force, of spontaneous
magnetization, and of remanent magnetization. In all compositions
and heat treatments it was shown that the coercive force passes a
distinct maximum in the range of ,'.he compensation point which seems
to confirm the original assumption of an anomalous temperature
course of the coercive force in the range of the compensation point.
An analysis of the data obtained (which are to clarify the causes
of the anomalous behavior of coercive force) shows that with the
approach of temperature to the COMDensation point the magnetization
curve flattens more and more, which suggests an increasing influence
of the rotary mechanism on the maFnetization of ferrites. Table 2
shows that in hardened ferrites the difference between Curie and
compensation temperature becomes smaller, which suggests that
hardened ferrites have a lower anisotropic constant than annealed
ferrites. There are 5 figures, 2 tables and 6 references, 4 of which
Card 2/3 are Soviet. \X
69004
The Anomaly of the Coercive Force of Ferrites in S/055/59/000/04/008/026
the Compensation Point BO14/BOO5
ASSOCIATION: Kafedra obshchey fiziki (Chair of General Physics) tr
SUBMITTED: October 27, 1958
Card 3/3
AUTHORS: Bol'shova, K.M. an .d Yelkina, T.A. SOV/126-8-3-24/33
TITLE: Increase in Coercive Force of Mixed Cast Ferrites and
Chromites in the Compensation Temperature Range
PERlODlCAL: Fizika metallov i metallovedeniye, 1959, Vol 8, Nr 3,
pp 461-463 (USSR)
ABSTRACT; Ferro-magnetic spinels, the composition of which is
described by the formula Li20 x (5-2a)Fe2O3 x 2aCr2O3,
in the range of a =.1 to a = 2, are characterized by the
fact that their spontaneous inognatization is reduced to
zero not only at the Curie temperature but also at a
lower temperature at the so-called compensation point
(Ref 1 and 2). The authors have carried out a thorough
experimental investigation of the temperature course of
spontaneous magnetization of the above materials in the
compensation and Cunietemperature range (Ref 3). An
analysis of these results has led to the conclusion that
an increase in Mc of these ferrites must occur in the
compensation range Tk1 which is associated with a sharp
decrease in magnetization as the testing temperature
approached Tk' The figure on p 462 shows the temperature
Card 1/2 dependence of the magnetic 1-:roperties of the ferr
SOV/126-8-3-24/33
Increase in Coercive Force of Mixed Cast Ferrites and Chromites in
the Compensation Temperature Rang2
L12O x 2-5FO203 x 2.5Cr203 in the compensation
temperature range: 1 - temperature dependence of -the coercive
force; 2 - temperature dependence of the spontaneous
magnetization a,.(t); 3 - temperature dependence of
residual magneiiam created at any given temperature
arl(t); 4 - temperature dependence of residual magnetism
created at room temperature Or(t). Earlier obtained
magnetization curves for ferrites of the system LiFeCr
become more sloping as the compensation temperature is
approached, which points to the gain in prominence of
the role of the mechanism of rotation in ferrite
magnetization processes. There are I figure and
4 references, 2 of which are Soviet and 2 Western.
ASSOCIATION:Moskovskiy gosudarstvennyy universitet imeni
M.V.Lomonosova (Moscow State University imeni
M.V.Lomonosov)
SUBMITTED: October 10, 1958
Card 2/2
30078
(o37,1101 1161) S/048/61/025/011/024/0"I
B117/B102
AUTHORS: Bol'shova. K, M., ~.nd Yel-kina, To A-
TITLE: Viscosity and hysteresis properties of ferrites due to
electron diffusion
PERIODICAL: Akademiya nauk SSSR, Izvestiya, Seriya fizicheskaya, v. 25~
I no~ 11~ 19619 1407-1410
TEXT: The following ferrites were examined: no. 1) Mn Fe, no. 2)
.1,4 :A04
Mn Co Fe 0 - no. 3) Mn Fe 0 ; no. 4) lin Co Fe 0
1-35 0-05 1~6 4' 1.8 1.2 4 1-75 O~05 1,2 4'
Magnetic viscosity which appears between 1 and 250 oe was measured in
static magnetic fields between +20 and -200 0C, In some cases magnetic
viscosity exerted a strong effect upon magnetic reversal- Though field
direction was changed, the ferrite remained magnetized for se-eral hours
in the former direction. This effect, up to now unknown, was found to be
particularly strong in a certain low-temperature range as well as in weak
and medium magnetic fields. Specimen no. 4 displayed the greatest delay
of magnetic reversal, Por no- 1 and no- 3 viscosity was lower and
Card 1/3
30076
S/048/61/025/011/024/031
Viscosity and hysteresis ... B117/B102
appeared also in weaker fields. In such fields.. a-c hysteresis loops
(50 cps) were recorded by an oscilloscope. No loop forms in weak fields
in which magnetic reversal takes a long timed With increasing field
strength a perminvar loop appeared first, followed by a normal and
finally by a rectangular loop. The loop shape was chan in this way if
the specimen is demagnetized at room temperature, Whengris reversed at
measured temperatures the oblique line changes in a jump-like manner to a
distinct rectangular loop (Ir/Is- 0.98), with increasing field strengths
An abrupt rise of induction, forming a step in the loop, is observed if the
field strength is increased in the temperature range beTween -"00 C and
-150OCi where viscosity is partioularly high, The saturation magnet-o-
striction in a 2500 0e field was measured by means of pickupe glued onto
them. The effect of viscosity upon magnetostriction was noticeable only
in specimens no. 2 and no, 4~ Magnetoatriction depended largely oil the
method of demagnetization. As for specimens no, I and no~ 3 (without
cobalt), viscosity was lower, and the degree of magnetostriction did not
depend on the method of demagnetization. For the ferrites examined~ it
was found that a connection must exist between the hysteresis and
magnetostriction properties and magnetic viscosity. One and the same
Card 2/3
S'/04B/61/025/011/024/031
Viscosity and hysteresis- B117/B102
mechanism is probably responsl'ole for all these properties, Uniaxial
anisotropy, which was discovered in these ferrites is probably due to
electron diffusion: Ion diffusion is little Drobable at such low tempera-
tures, The finite diffusion rate deDends on temperature and on the
magnetic field strength. This explains the limitation of the temperature
and field ranges in which the described phenomena are observed- The part
played by cobalt has not been clarified, The unclear statement contained
in the literature regarding the relationship between the perminvar effect
and relaxation according to Richter was substantiated by establishing a
direct relationship between the viscosity properties of the examined
ferrites in static fields and their hysteresis Droperties in the same
field range, There are 4 figures and 5 references: 1 Soviet-bloc and
2 non-goviet-bloc.
Card 3/3
24704
S/056/6!/0A0/005/C0A/O19
E102/B201
AUTHORS: Bol-I shov.-a,-X~-M._, Yelkina, T. A.
TITLEt Viscosity and hysteresis propetties of manganese-iron ferrites
with cobalt admixtures at low tempera:ures
PERIODICALt 'Z,Iwrnt%I oktiporimitallnoy i
no. 5, 1961, 1299 - 1301
TEXT: A study has been made of the magnetic viscosity, magnetostri,,tion,
and hysteresis properties of polycrystalline ferrite specimens of the
com-oosition Mn Cc Fe 0 at low temperatures. Measurements of
1.75 0-05 1.2 4
the magnetization of this ferrite at low temDeratures ir. static fields
of 4 - 250 oe indicated its enormous magnetic viscosityx magnetization
rises, after the constant field is applied, for 17 hours, and, after the
field polarit is reversed, it is conserved in the old direction for
another hour ~in one case, for 174 min). No information has been found
in the literature regarding this effect. Viscosity proved to be highest
at temperatures from -100 to -150 0C and fields not over 250 oe. On the
Card 1/3
K~
RMINS aM'
20014
S/056/6!/'040/005/004/019
Viscosity and hysteresis properties ... B102/B201
same ferrite, the saturation magnetostriction was measured at 2500 oel
as a consequence of the high viscosity, magnetostriciion was found to
depend strongly on the method of demagnetization of the specime-. The
hysteresis loops were also recoi.Aed by an oscilloscope in alternating
fields of 50 cps. Rectangular perminvar loops were obtained in this
range. A comparison of the change of the loop shape in growing alter-
nating fielils with the magnetic viscosity in static fields shows that
the character of the shape modification is closely related to the mag-
netic viscosity in static fields. If the time of magnetic reversal is
very long, the hysteresis loop will have the form oil a line; if it is
short (which is the case with certain fields and temperatures; e. g.,
at -1250C and 43 oe), that is less than one minute. a perminvar loop is
then obtained. This can be explained by considering that the ferrite
concerned causes in each domain an uniaxial anisotropy under the effect
of the magnetic field (with an ax4- -f slight magnetization in direction
of the vector of magnetization of the domain concerned). The appearance
of uniaxial anisotroD is due to electrop diffusion. 1.1ost like;- an
y + Y9
electron exchange takes place between Mn and Un ions of a higher valency.
Card 2/3
4704
3/0a6/6!/G40//G05/C,G4/0l9
Viscosity and hysteresis properties... B102/B20,.
Professor K. P. Belov is thanked for his interest.
There are 3 figures and 1 non-Soviet-bloo reference.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet (Moscow State
University)
SUBMITTED: December 29, 1960
Card 3/3
B-OLISHOVA, K.M.; YELKINA, T-I.
. . . . .............,..I..
Determining -the field induced ~cnstsnt of uniaxial mag7neti-,
&n.isotropy in llx,-Fe ferrites. Fiz. met. i metailovv~-i d ~ 17
no,.6-.819-826 Je 164. i.MIRA
.,. MiskevsM gosudarsiv-cnnyy universitlet imeni
1 -Y
BOLISHOVA, K.M.; YELKINA, T.A.
Viscuous behavior of magnetization in Mn - Fe ferrites at low temperatures.
Vest.-Mosk. un. Ser. 3: Fiz.,-astron. 18.no.6:59-64- N-D 163.
(MIRA 17:2)
1, Kafedra obshchey fiziki dlya biologov Moskovskogo universiteta.
ACCESSION NIR: AP4023413 S/0046/64/028/003/0596/0600
AUr1IOR- Bollshova, X.M.
TITLE: Low temperature anneal in Mn-Fe forrites ffeport, Symposium on Ferromagae-
tism and Ferroelectricity hold in Leningrad 30 May to 5 June 196V
SOURCE: AN SSSR. Izvostiya..Seriya fizicheskaya, v.28, no.3, 1964, 596-600
TOPIC TAGS: ferrite, magnetic lag, ferrite magnetic lag, manganese iron ferrite,
manganese iron cobalt ferrite, induced'uniaxial anisotropy, ferrite ion diffusion,
ierrite electron diffusion
ABSTRACT: Magnetic lag was investigated at temperatures from -900C to -1600C in
ferrites having the compositions MnI.BrOl.204 and Unl.75CO0.05Fel.204- Both single
crystals and polycrystalline material wore investigated. Curves of magnetization
versus time were obtained at various temperatures and for various values of the
magnetizing field. Relaxation times from 0.5 min to a day were observed. Activation
.energies were calculated from the temperature dependence of the relaxation times'
corresponding to 75% and 95% saturation. The activation ener&7 for the material coa-
taining cobalt was 0.32 eV, and for the material without cobalt, 0.23 eV. MagZati-
Card 1/3
ACCESSION XR: AP4023413
zation curves corresponding to various stages of magnetic annealing (from 0.5 min
to 270 min) were obtained. From the magnetization curve obtained at the bogirminCs
of the anneal, Anti the oquilibrium magnotithtioij cujvo (Infillito Anneal) t the limit-
ing value of the induced uniaxial anisotropy constant Ku was calculated. Ku was
strongly temperature dependent, having a maximum at about -1350C. The maximum value
.of Ku was about 9000 erg/cm43 for the material containing cobalt, and only 66 erg
~cm-3 for the material without cobalt. The fall of Ku at temperatures above -1350C
:is easily understood in terms of L.Neel's theory of directed local order (J.Appl.
iVhys.30,SuP*pl.No.4,3S,l959). The decrease at lower temperatures is ascribed to in-,.
:crease of the cubic anisotropy constant. The constant W in the expression C
:cos2;U for the interaction energy of the cation with the spontaneous magnetization
(CC is the angle between tile trigonal axis and the spontaneous magnetizatiun) was
to?
calculated from KU = C GIC, where c is the concentration of cobalt. It was found
to be 10-15 erg/atom. In view of the work of S.Iida (J.Phys.Soc.Japan 17,Xo.1,123,
1962) and A.Braginski and T.Merceron (J.Phys.Soo.Japan No.10,-1611, 1962), the be-
havior of thematerial containing cobalt is ascribed mainly to ionic diffusion of
C02+. The behavior of the material not containing cobalt is ascribed to electron
diffusion by electron exchange among the Mn ions of different valence on the 16 d
sites. Orig.art.has: 3 formulas and 3 figures.
2/3
Card
ACCESSION XR: AP4023413
ASSOCIATION: pizicleslciy jakulltet Mosicovskogo gosudarstvennogo universitota (Phy-
sics Departmont, Moscow State University)
.SUBUITTED: 00 DATE ACQ: 1OApr64 EXCL: 00
SUB ccmt PH NR MW SOVI 001 071MRt 006
3/3
Ccird
r -7717-
ACCESSION NR: AP402oO49 5/0032/a/030/003/0350/0351
AUTHORS: Villyams, 0- S.; M.; Oleynik, 0. V.
TITLE: The effect of sample form on the mechanical properties of steel YJ1181410T
pipes
SOURCE: Zavodskaya laboratoriya, v. 30, no. 3, 1964, 35o-351
TOPIC TAGS: steel pipe, steel Klil8iaorr, mechanical property., elastic propertyj,
cold rolled pipo, high temperature treatwent, olonryation, rupture
ABSTRACT: Tensile tests of cold rollod nj-,)os shmied tivit their mechanical
properties depend on the sample form. This rolation was studied in samples 260 mm
lona and in snaments 8 nii wide cut from the pipc,; produced of steel KII.IGN10T
0.09 C; 18.10 Crj 10.22 Ni; 1.17 iin,- 0.50 3i; 0.011 S;and 0.035
The samples were treated thermally (700-.110CC) before being tested in a 30-T
i-aachine at the rate of 4 mu/min before the metal flow started, and of 20 mm/mi-n
thereafter. The results revealed that the mechanical properties of the segments
were better than those of the pipe samples, except for the local elon.gation
(measured in the necked area) which was 3-6% larger in the pipe samples than in
the segments. Ilia plastic properties (elongation) of segments increased regularly
Card 1/2
AGGESSION NR: A?40200~9
with the increase of temperature and reached a maximum, at 1050-1100C. In pipe
samples it remained practically unchanged in the interval 950-110W, whereas the
r1rain size sholied a considerable increase. This may be taken as evidence of the
distorting effect of the sample forin on the mechanical properties of pipe metals.
The same effect was observed7by measuring the variation in the wall thickness
along the pipe segments and on metal strips 8 mal wide cut from the pipes. In the
pipe segments the deformation was uniform along the whole length, while in the
strips it was concentrated in a zone exterding approximately over 1/3 of the
sample length. Orig. art. hast 1 table and 2 figures.
ASSWIATION: Nikopollskiy yuzhnotrubny*y zavod (Nikopoll Southern Pipe Plant) -
SUBRUTEDi 00 DATE ACQ: 27kiar64 BNOL: 00
SUB CODEs HA NO REF SOV3 000 OTHM 1 000
Card 2/2
ACC NRs AP6026676 SOURCE CODE: UR/0181/66/008/008/2313/2319
AUTHOR: Bol'shova, K. M.; -Andreyeva, T. B.
ORG: Moscow State University im. M. V. Lomonosov (Moskovs y gosudarstvennyy universitet)
TITLE: Low-itemperature magnetic viscosity in single crystals of Mn-Fe-Co-ferrites with a
deficiency of iron
I
Fizika tverdogo tela, v. 8, no. 8, 1966, 2313-2319
TOPIC TAGS: single crystal structure, crystal orientation, ferrite, manganese compound,
iron compound, cobalt, magnetic viscosity , (10ep5r,9's- AUIS67WOPP
'RACT: In connection with the hypothesis that the uniaxial anisotropy observed at low
matures in Mn-Fe-ferrites with and without cobalt Is caused by directed ordering of the ion.
3+
and Mn occurring as a consequence of electron diffusion, the authors investigated low-
WM
th
-rature scosity In pingle crystals of Mn-Fe-ferrites with a deficiency of iron and wil
ikirsa-conits of cobalt In static magnetic fields. Magnetic viscosity and induced anisotropy
studied on two single crystals of the composition Mnl.75COO.O~Tej.204 (No. 1) and
7Co0.jFej.204(No. 2) 60 and 50 mm long, and 7.3 and 6.6 mm in diam r, respective
mall relaxation times at low temperatures (2 min at -80C) observed in the single crystalb
WC NRt AP6026675
C;~
r the ferrites and also of the low values of #fv--Dn energy (Ql = 0.16 eV and Q2 = 0.32
V) indicated that the noted magnetic viscosity cannot be ascribed -either to the mechanism of
aparation (formation of a secondary phase oriented by the field) or to a disturbance In the bal-
nee of ions Cog:~ owing to diffusion of ions. Apparently the notedphenomenon should be ascribed
the mechanism of electron diffusion. It is quite probable that in Mn-Fe-Co-ferrites with
deficiency of Inn there Is a ce#ain quantity of trivalent tons Co3+ which if true, can be re-
Latributed In the magnetic field by electron transfer between C02+ and Co5+ so as ~ mhdmize
Le total free. ei~ggy and produce uniaxial anisotropy as a consequence of directed ordering. It
i emphasized In conclusion that & difference' between the viscosity observed and the viscosity
DreWore Investigated In ferrites Is that it was not frozen by cooling to nitrogen temperatures.
he viscosity appeared ooly within a limited temperature range and in weak and moderate fields.
i strang fields the viwosity did not appear even at temperatures where it is maidmel. The
More thank K. P. Below for bb Interest In the work. Orig. art. has: 6 figures and I formula
DD CODZ: SO/ SUBM DATM 29NovU/ ORIG RZFt 002/ OTH REFri 011
OT
A=NR--AP60l29o4 SOURCE CODE: uH/0075/66/021/bo4/o4:u/o4l4
AUTHOR: _Alimarin., 1. P.; Bollphovat-M-I.-
ORG: Moscow State University im. M. V._L2MQnQ�_QX (Moskovskiy gosu-
darBtVe-nnyy univerBi.tet)
TITLE: Separation of traces of-gallium from zinc by partition
chromatography
SOURCE: Zhurnal analiticheskoy khimii, v. 21, no. 4, 1966, 411-414
TOPIC TAGS: gallium, zinc, partition chromatography, trace analysis
ABSTRACT: The behavior of gallium and zinc under dynamic conditions
on a chromatographic column with fluoroplastic 4 and tributyl phos-
phate has been studied. A method has been developed for separating
small amounts of gallium from zinc. Gallium has been quantitatively
separated from zinc at ratios of 1:1-to I:lo4 by partition chromatog-
raphy on a column. Orig. art. hast 2 figures and 1 table. [Based on
author's abstract) [AM)
SUB CODE: 07/ SUBM DATE: 02Apr65/ ORIG REF: 008/ OTH REF: oo6/
12-
Card
ACC NR: 11,P7 02,~,S~ ('4) SOMICE CODE: UR/0189/66/000/006/0059/0063
.0
AUTHOR: Bol'shoT T. A.; Alimarin, 1. P.; Lltvinchovaj A. S.
ORG: Anal3rLical Q'Inemistry DODartmentq(Kafedra, analitichoskoy khirnii
of small amounts of In from Ga by partition chramatograplay on a
'-TLP.1 Separatiop
columr.with teflon;
SOURCES Moscow. Universitet. Vestnik. Seriya II. Khimiya, no. 6, 1966, 59-63 i
TOPIC TAGS: indium, gallium, chromatography,44&-,-
ABSTRACT: A rapid method for separating trace amounts of gallium and indium by column
partition chromatography on teflon has been developed. It is based on the difference
in the stability of chloride and bromide comlexes of these elements. The conditions
of separation were determined by studying 'he behavior of gallii-,m and indium in the
systems hydrobromic acid solutions - tributyl phosnhate (T-B11) and lithium b.-omide so-
lutions - TBP, th6 extractant used being TBP. In ihe system 0.8 1-1 HBr - TBP, indium
was found to be q#ntitatively retained on teflon when the solution(in which In:Ge =
I.1) was passed at 0-5 ml/min. SODaration of indiwa from gallium -oresent in the ratio*
of 1:800 was also ~ satisfactory. - T6 systems 1 M LiBr - TBP and 3 il HC1 - TBP wers
also found to be,suitable for the quantitative separation of In and Ga. Orig. art.
has-' 3 figures and I table.
SUB CODE: 07/ -SUEMI DATE: 13Jan66/ ORIG REF: 003/ OTH Rut 003
Cnrd UDC: 541.183:546-0~_~~
~ L;1JCUU_UU __ r,-.71 k U7,rr I If r,-,-_-kTT1)fr15U kK)--z I -~Lu-EL5T/a,..;
ACC NR. AP6028336 SO CE CCf]~E'-Iyk-/O-~-9-5/66/00~C/064/0568/0573'*!
le4
AUTHOR: Bol'sh2j,_A.,A..-..
N ib~
ORG: none
/5
TITLE, Some laws in formation of ionospheric ~homogeneitics, and their connection
with particle "Pour-out" from outer space
SOURCE% Kosmicheskiye iseledovaniya, v. 4v no- 49 19661 560-573
TOPIC TAGS: ionosphere, radio wave propagation, space telemetry, artificial satellite
rarefied plasma
ABSTRACT: On the basis of systematic data reduction certain observati were made
concerning radio-signal fluctuations from Soviet artificial satellites7 These
fluctuations have a "twinkling" nature and have been recorded on all Soviet satellites
put in orbit during 1958--1962. It is postulated that these fluctuations can be
explained satisfactorily by relating them to diffraction of radio waves on ionospheric
inhomogeneities. The frequency of these fluctuations is shown to depend on the
latitude position of the satellite as well as the time of the day. A definite connec-
tion'was also established between the "twinkling" and the scattering phenomenon from
F-layer reflections. A careful study of cosmic particle bursts indicates some connec-
tion between the prevalence of radio-signal fluctuations and cosmic particle flux (in
bursts). It is postulated that these sudden fluxes give rise to ionospheric
UDC:
1.910.
ACC NR: AP6028336
(::5 i I
iinhomogeneities which in turn are responsible for radio wave fluctuations in the
I
.Ialtitude range 1000-1500 km. Orig. art. hast 7 figures and 1 formula. [041
SUB CUDE; 20/ SUBM DATE, 1500t65/ ORIG RU: 003/ OTH R-EF: 006
Card.- - 2/2 fv
~1_1 -
ACC
7~~
AP6009848
- -
SOURCE CODE: UR/0413/66/000/004/0038/0038
"T
AUTHOR: Bolty!qnskiY,_.A. &t PshenichnikS?v. Yu. V.
ORG: none
TITLE: A multicommand active control device. Class 21, No. 178883 [announced by
y 1~ay Aviation Institute (Kuybyshevskiy aviatsionnyy institut)]
'SOURCE: Izobreteniya, promysblennyye obraztsy,*tovarnyye znaki, no. 4, 1966, 38
TOPIC TAGS: automatic control, grinding machine
ABSTRACT: This Author's Certificate introduces: 1. A multicormand active control.de-i
vice for regulating the feed on a grinder. The device contains a gauge assembly, a
comparator connected to a reference voltage unit, and an activating relay system. Mea
surement time is reduced and electric command adjustment is provided by making the
comparator in the form of a generator which sends out a control pulse when the gauge
signal and the reference voltage are equal. 2. A modification of this device in
which a filter is connected between the generator-comparator and the activating relay
system to reduce interference.
SUB CODE: 09/ SUBM DATE: 23jan65/ ORIG REF: 000/ OTH REF: 000
UDC: 62-523.8:621.924.1 72--
MORDOVTSEV, A.I.; DOLI-ADVA, L.P.
Effect of individual vitamins and their comple-xes on the con-
ditloned refle:~ activity in pigeons. Vop. pit. 23 no. 5-41--45
S-0 164. (MIRA 18? 5)
1. Laboratoriya fizicheskikh metodov izucheniya fiziologicheskikh
funktsiy (zav. - prof. M.A.Sobakin) Instituta pitanlya AMN SSSR,
Moskma.
28544 8/133/61/00W907/015/017-
Ao54/A12q
AUMOVI!, Villyams,. 0.. 8 Boll shova- ine-ers
TIMEI-' Effect of heat treatment on the intercryst's.1lite c-orrosion tendenoy
of tubes made of 1X18HqT (1Kh18KqT) steel
PERIODICAL: Stall, no. 7A 1961, 647 - 648
T=I Tubes made of M18NqT steel display a tendency to 11rileibrystallite
T
corrosion. In order to establish the qauses of this phenomenon and -k-.o eliminate
it by cou&.ermeasures- tests were carried out in the Nikopol-Iskiy yuZIMO'.Tabn~ry
'(Nikopol:" Southern Tube Plant) with cold-hardened and colli-roll&d 04,
zavod
various dimensions made of-M18KqT steel'with a ratio of the I.'!- and G oontemt-
varying between 4.0 and 6.9. 80-mm tube sockets were heated by sters Of 500C
(e. times of 250C) from 8500 to 1,3000C. The .holding time was 30 minj followed
by 'cooiling o1 i air.~ The-heat-treated tube sockets were tested for intercrystallite
corrosion -according to FOCT (G63T) 6032-58 oil. saLmPles without homogenization lafter
stimulating annealing at 6500C for two.houre. At.the same time.the grain size and
the amount of bonded titanium were also controlled. It was fvand that the tenden-
cy to intercrystallite corrosion in the stedl tested increased after hardening
Card 1/2
28544 3/133/61/()00/007/015/017
Effect of heat treatment. on the intercrystallite... A054/A129
from 1,1750C and higher temperatures. The overheated metal displayed a laa-ge-
grain structure and low amount of bonded titanium. By modifying the titanium and
carbon content ratio from 4.0 to 6.9 the overheating temperature of the tube caus-
ing the tendency to intercrystallite corrosion was not affected to asty great ex-
tent. This trend could be neutralized by repeated hardening from 1,05011C, during
which the amount of bonded titanium increased 1 1/2 - 2 1/2 times. The grain size
is not conclusive to determine the intercrystallite corrosion teMdeTiCy of the me+AL
The amount of titanium rvis also to be considered: with a content of bonded t-itani-
um above 0.2% the metal as a rule displays sufficient resistance against inter-
crystallite corrosion. There are 2 tables.
ASSOCIATION: Nikopollskiy yuzhnotrubnyy zavod (Nikopolt Southenn Tabe Plant)
Card 2/2
ACCESSION MRS ARhO3626h 5/0337/64/000/003/105VIC10
SOURCES Referativr4vy shurnale XetallwgiYav Abe- 33338
AUTHORS Villymoss Oo go; Bollahovap He Mel Neshivayas, So Ke
TMZ# Conoerning the carburisation of Kh2b11CM stainless sta"a
SOUROEs Sbe Pmixwvo t4mbe vrp, n. No# Heta2lurgisdatp 1963p 103-3.06
TOPIC TAGSs Stainless steel carburization,. interax7stalline corrosion# steel
lubricationp steel lubricant
TRMSIATICKs An investigation was mide into the effect or the cam., osition of the
lubricant remaining on the surface of pipes after cold deformation and of the terb.
perature and duration of soaking during heat treatment on the process of carburim
zation and tendency toward intercrystalline corrosion (TIC) of pipes made of
i JKblBNIOT steel* The lubricant used consisted of graphite with machine oilp gra.
phite with water glass,, and talc with castor oil, Prior to the heat treatmentt the i
specimentep 80 m Ion& were coated with the lubricant and plaaeo in =wLU cyllndsz~
2/2
C.-
ACCESSION HM AR4036264
smeared with a mixture of clay md asbestoss After being heated at 1100o for 30
min and cooled i air., the standard specimens were tested for TIC, with prelimina.17~
"inducine tempering at 6500. All the specimens subjected to heat treatment in con-
tact with C-containing lubricants acquired a TIC. The greatest TIC was caused by
the mixture of graphite.and machine oil# and the smallest by the mixture of talc
and castor oils The damage done by intercrystalline corrosion is greater the great-.
er the depth of the carburized layers A study of the depth of the carburized I.Wr!
under condit Do!
Uons of saturation with C in the solid carburizer between 700 and 110
showed that the depth varies from 0*016 m at 7000 to 0961 m at 11W0 (soaking
times 30 zin)e The TIC was observed after soaking for 90 min at 75CP* A second
heat treatment of the carburized specimens for Un purpose of all-inati" the TIC
is not aftinables, an it, cn4 causes the depth J the carburized layer to Increase.
M. Shapiro,
DAIS ACQs I?Apr64 M Ms ML ViCL 1 00
VILIYAMS, O.S.; BOLISHOVA, N.M.; OLEYNIK, O.V.
Effect of the type of the sample on the mechanical properties
indices of pipes made from 1810T steel. Zav.lab. 30 no.3:
350-351 164. (MIRA 17:4)
1. Nikopollskiy yuzhnotrubnyy zavod.
I"'EWA (d) /TZEEI~N ENRCkV
AP600C
A 1610 MJWIJDI'HW SOURCE CODE: UR/0129/65/060/012/6040/0043
AUTHOR: Vil'yamss 0. S.; Bol'shova, N. M.; Koval#, M. Ya.
ORG: Nikopoll Southern Tube Plant (Nikopol'skiy yuzhnotrubnyy zavod)
TITLE: Effect of temperature and rate of heating on the grain izeof Khl6Nl2T ateel
4q, 5- 5-) 11 - I
SOURCE: Metallovedeniye i termicheskaya obrabotka metallov, no. 12, 1965, 40-43
TOPIC TAGS: grain size, steel, metal tube, titanium, heat treat furnace/
Xhl8Nl2T steel
ABSTRACT: Annular ?Oecluene of-XhISN12T steel (0.08% C, 1.41% Mn, 0.66% si, 0.017% P,
0.007% S, 17.85% Cl(, 11.3n wi, 0.50% Ti), cut from cold-rolled boiler superheater
Itubes, were heatedNAt 800-1200% an increasing the temperature by 50-100'C at a time,
for 30 min, and air-cooled, vith'the object of dertermining the conditions under
which grain homogeneity can be maximized. Experiments with the use of different fur-
naces (muffle, induction, box, continuous roller) showed that the most auitable fur
nace for this purpose is the continuous roller furnace, (furnace length 10 m, travei-
ing rate of tubes 0.4 =/min, temperature 1200-1230*C). The higher the heating rate,
the higher is the temperatqg ,,e:d d to obtain a roughly identical grain size. In
addition, ths effect of Ti a i: size was investigated on specimens of work-
hardened tub" from two melt and compared,with specimens of Ti-free MOM steel;
t
I
L 12067-66
ACC NRs AP6000610
it was found that in Ti-containing steel the grain size decreases with decrea
an"d increases with Increasing temperature at a faster rate than
temperature
-In addition, given the same heating temperatures, the microstructur.
free steel.
Khl8Nl2T steel containing 0.44% Ti becomes sore coarse-grained then the microstrue-
ture of the same steel containing 0.65% Ti. This is attributable to the retarding
effect of titanium carbides on grain growth. An the titanium carbides become di3solvei
at elevated temperatures, an Intensive grain growth sets in so that then, at tempera-
tures above 11500C, the grain size in T ining steel (KhlBN12T) becomes much
larger than in Ti-free steel (thISNIO) =igtsart has: 2 tables, 3 figures.
SUR CODE; 11, 13, 20/ SM DAT19: none/ ORIG REFto 003/ OTH RIF: 000
2/2~
-c0-- croerementS7-C-T -ha-y -(c-.UUt-,
v lamiamese. and Cows)- T. A. BcA's1lu%,a. UchrSyr
apiski Vifrb3k. vet. Inti. 137
Xhim. Biol. Khim. IgSS N.' 11,127-Th, eul`t't'c'n't'of1"Co'
M". a~d Cu in clovmr Ila), is gm* ter than in cercal-gruss hay.
Hoy mude froul, young grasses and quirkly dried coutahm.
W-c Mul but tile Wntent Of Co and CU is greater in hay
made Imin mure trature'gnm-teg. B. S. Levine
AUTHORS: Starobinets, G. Boll shova, T. 1A. 75-13-2-15/27
IITLE. Determination of Rorm -al Hydrocarbons in laraffins by Means of
the Adsorption Analysis (Opre~eleniye u-levodorodov normallnogo
stroyeniya -T parafinalch metodom a(loorbtsionnogo analiza)
PERIODICAL: 2hurnal Analiticheskoy Khimii. 1~58, Vol. 13, Ilr 2,
jp-r- 235-241 (U5311)
I
ABSTIUCT: 1) The authors investiCated the adsorpt-ion of low 'boiling
fractions of benzene solutions of normal hydrocarbons on urea.
These normal hydrocarbons were isolated from commercial
paraffins. The obtained experimental data are reproduced by
the Langmuir isothermal adsorption curve. The adsorption
coefficients and the limiting value3 of the adsorption
increase with increasing mean molecular weight of the fractions.
2) The isothermal adsorption curves on urea were investigated
for a number of commercial paraffins, but also for paraffins,
which were obtained from solutions of isoparaffins in benzene,
toluene, and carbon tetrachloride by purification, On that
occasion the concentration of the paraffine was kept constant,
while urea was added in increasing quantities (up to 12 U on
Card 1/3 1 g of paraffin). The isothermall curves of the purified
-Determination of Normal llydrocirbons ill Pta-affino bY of 751-13-2-15/27
the Adsorption Analysis
paraffins end in clearly expressed hurizzontal lines. which
correspond to the complete adsorntion of the dissolved parafffin.
The isothermal curves of the commercial paraffins, on the
contrary run out on the same conditions into lines. which are
inclined towards the abscisse and which indicate the fact
that the adsorption process in this case represents 'the sum
of 2 processes: The adsorpTion of the normal hydrocarbons
and the adsorption of the iso-h,'drocarbons. It was sho,.-.n tha,
the ordinate, which was obtained by extrapolation of the
inclined final line on an urea content of zero, renresents a
measure for the percentage of normall. hydrocarbons In the
pa-raffin which is to be exanined. The result of the analysis,
obtained this way, is independent of the nature of the solvent,
This fact proves the reliability of the method.,
3) The methods, described in publications, for the determir-
ation of normal hydrocarbons by means of urea in S;eneral
give too low results, These methods correc-pond in their
essence to the investigation of only one point of the isu--
thermal curve, while a unique conclusion on the percentage
of normal hydrocarbons in commercial samples is possible
Card 2/3 only because of the examination of the whole isothermal
Determination of 11ormal Hydrocarbon-- in Paraffins by IMeans of 75-13-2-15/27
the Adsorption Analysis
adsorption curve, which is concluded froin tlc results of this
paper.
4) This method, Tiorked out by the authors, is sirapie in an
experimental respect and can be performed with small substance
quantities. It i; based upon the-analysis of the solutions,
which are in equilibrium, and therefore it is free from
errors, which are caused by transfer, washing out, and
decomposition of the complex coi-iipound oil urea with the
hydrocarbons.
There are 5 figures, 1 table, and 22 references, 11 of which
are Soviet.
ASSOCIATIONt Belorusskiy gosudarstvennyy universitet im. V. I. Lenina,
Minsk (Minsk,Belorussian State University imeni V. I. Lenin)
SUBYLITTED: May 31 , 1957
1. Methanes--Analysis 2. Hydrocarbons--Adsorption 3. Hydrocarbons
--Determination
Card 3/3
BOLISHOVA, T.A.; STAROBBETS, G.L.
Partition chromatography of hydrocarbons from solid petroleum
paraffins an carbami4q. Khim. i tekh. topl. i masel 6 no.3:17--21
MY 161. (MIRA 14:5)
1. Belorusakiy gosudaretvennyy universitet im. V.I. Lenina.
(Hydrocarbons-Analpia) (Urea)
tit
PC
7
BOL'SHOVA, V.G.
7'Prosts in Gorkly Province. Sbor.rab.po sinop. no.2:134-158
158.. - (AIRA 12:6)
1. Gor'kovskoyo byuro pogody.
(Gorkly Province--Frost)
AUTHOR: Bol'shoy, V.A., Engineer SOV/110-59-6-15/24
TITLE: Some Possibilities of Using Speed-Indicating Relay
Type RKS (0 nekotorykh vozmozhnostyakh primeneniya rele
kontrolya skorosti tipa RKS)
PERIODICAL:Vestnik elektropromyshlennosti, 1959, Nr 6, p 65 (USSR)
ABSTRACT: Induction relay type RKS is used for speed indication
and control in the range 900 to 3000 rpm. The rotor of
the relay is coupled to the shaft of the motor to be
controlled; the stator of the relay is free to rotate a
littler so as to operate contacts as shown in the figure.
Rotation of the magnetised rotor sets up a torque in the
stator which is proportional to the rotor speed. As the
stator turns an arm presses on contact springs opening
a normally-closed contact and closing a normally-open
one. A feature of the relay is that the contacts are
not continually opening and closing because the normally-
closed contact opens an appreciable time before the
normally-opened contact closes. Thus there is a range of
speed in which the moving contact is either in the
neutral zone or is firmly over one way or the other. The
Card 1/2 relay is adjusted by altering the tension of the springs.
SOV/110-59-6-15/24
Some Possibilities of Using Speed-Indicating Relay Type RKS
Tests showed that the relay operates over the speed
range of 100 to 475 rpm. At a speed somewhere between
450 and 500 rpm, the normally-opened contact of the
relay is firmly closed. Thus at speeds above 500 rpm
the relay can only indicate that the motor is running
but cannot measure its speed. Test results are
tabulated for relays regulated for three speeds of
160v 225 and 450 rpm. It will be seen that the operation
of the relay is unreliable within a speed range of
50 to 80 rpm. To avoid the transmission of multiple
signals.at low speeds it is advisable to use in the
signalling circuit a relay with a delay time of between
1.5 and 2 sec. There is 1 figure and 1 table.
Card 2/2
1. BOISHTEnN, 1. 1.
2. USSR (6W)
3. Wood Pulp Industry
4. Modern high-quality sulfite pulp mill.
Bu. prom. 17 No. 11 - 19 52.
9. Monthly List of Russian Acessions Ubrary of Congress, February 1953. UnclauEified.
BOLSHTYANSKIYt M.P.
Experimental investigation of stresses in an earth foundation.
Izv. Sib, otd, AN SSSR no. 1-1:29-33 160. (MM 14:1)
1. Transportno-energaticheakiy institut Sibirskogo otdeleniya
AN SSSR,
(Foundations) (Strains and stresses)
BOLSHTYANSKIYq M.P*
Temporary stresses in oompacted ground. Izv.Sib.otd-AN SSSR no.5:
41-45 161. (MMA 14:05)
I.. Transportno-energetichaskiy institut Sibirskogo otdeleniya
AN SSSR, govosibirsk. (Soil meebanics)
BOLSHTYANSKIY, M.P&
Experimental study of stresses in * heterogeneous loose medium.
Oan., fund. i mekh. grun. 4 no.6sU-13 162. (MIRA 16:1)
(Soil mechanics)
BOISHTYANSKIY, M.P.
Stresses and shifts in a thawing soil foundation supporting a
plate6 Izv. SO AN SSSR no.2 Ser. tekh. nauk no.1:27-32 163.
(MIRA 16:8)
1. Transportno-energeticheskiy institut Sibirskogo otdeleniya
AN SSSR Novosibirsk.
tSoil mechanics) (Thawing)
BOLSHTYANSKIY, I.I.p.; 1.114TSER, A.V.; SOKOLOV, Yu.V.
Experimental study of stresses J.n a two-layer granite foundation,
Izv. SO AN SSSR no.10 'er. tekh~ nauk no.3:1136-139 ~b3.
(MIRA 17: 11)
1. Transportno-energaticheskiy institi)t Sibirs1cogo otdo"Leniya JAN
SSSR, Novosibirsk.
BOLISHUKHIN, A.N., inzh.
laying cold aspbalt concrete pavements at low tei;peratures.
Trudy MADI no.23:144-152 '58. (MIRA '12:1)
(Pavements. Concrete-Cold weather conditions)
.1 ~ BOLISHUKHIN, I.D., inzh.
YAKUSHEV V.I., inzh.
Using ancborp for shiD r-hecking during laimching.
Sudostroonie 26 re.T209)t54-117 * 160. (1-111RA 24~-U)
I*'-' Mnchova ) S-
.(Ships--~-Lavaching)
41
f kand. teklin. nauk: V.PI; *~AhcFjo-N T,S.
SOKOLOV Ya.A., . A)LISIR)KIIIINY I
....
Concerning salt spots and faced ceramic products. Stroi.
mat. 9 no.7:31-33 J1 163. (MIRA 16:11)
BOLISHTJKHIN, V.P (Leningrad)
"Alnorganic chemistry in questions and answeran by Erich Tillo.
Reviewed by V.P. Bollshukhin. Khim. v shkole 17 no.1:90-91
'Ja-F 162. (MIRA 15:1)
(Chemistry,, Inorganic-Study akd teaching)
(Tillo, Erich)
SOKOLOV, Ya.A., kand. tekhn. nauk; YAKOPSON, T.S., inzh.;.B0L'SHUKRjTI,
V.P., imh.
Using barite wastes for the binding of Nsible saltq in clays.
Stek.1ker. 2-2 no-10:35-37 0 165* (MIRA 18:12)
1. Leningradskiy inzhenernc-AroitelInyy institut (for Sokolov,
Yakopson). 2. Novosibirskly inzhenerno-stroltellnyy institut
(for Bollahukhin).
Ytic pfepamtlm of k4 am A xWr4ut of scetir,
-at.
---2 isr. f)bjkl-;T-KV ge of.41011-
Cr -caloyst Id Iluum Dis
-33UOH over -Md 1~
Lwhtp2d Stee UnIv., 1049) M W.W up to 2V;-~
MeCOPr al=g with 6~' D M--2CO and 2017c Y-,CO. Pa5siMc
nbc-mcs cd the formantlon d prud=t-s Rn bfiefly d; uss~d-
Formati-ap,of MeCOPr pro~ablyw,,tus by L,,rdcii~'xltFlr, -if
CH with Prello OT hlt~:Co, The Inults L'T V-.Irlk~as
=pa- knd iTactant prapartioms (1: 1 to 3: arr tpbul;~t~'.
Distr: 4E4j
'P.01 ISH-Mll) j
Ye. V., 1SEZH1'-"'7SK1Y S. ~Ia.y
"Formation of 1~ydrazine in Liquid Ammonia Due to Fvst Electrons, in the
collection, Effect of Ionizing Radliation on Inorganic and Crg~anic aYmLtx�xX
System, Moscow, Izd-vo MIT SSSR- 1958,416 pD.
Coll. of articles feDresents contributions of Soviet scientsts in the fteld'
of Radiochamistry, completed in years 1951-56 at Inst. 11hys, Chem, AS LGM, Inst.
of Physics and Chem. im. L. Ya. Karpov, Moscow State Univ, and ir other institutions.
Abst: the formtion of hydrazine due to fast electrons leads to a
stationary hydrazine concentration conditioned by the balancinE,, of theit rates
of direct and inverse reactions. The reaction efficiency is 1 - 1.2 molecules of
hydrezine per 100 ev. 2 tables, I fig, , 6 ref, (3 Sov, 3 English)
MYASNIKOV, I,A,;_BOLISHUN, Ye,V.; GUUIAN, E.Ye.
Mechanism of radical adsorption on semiconductors and the
desorption of radicals from hot walls. Kin. i kat. 4 no.6:
867-877 N-D '63. (MIRA 17:1)
1. Fiziko-khImicheskiy institut imeni L.Ya. Karpova.
ACCESSION NIt: AP4008168 S/0195/63/004/006/0867/0877
AUTHOR: Myasnikov, 1. A.; Bo'llshun, Ye. V.; Gutman, E. Ye.
TITLE: Mechanism of radical adsorption on semiconductors and desorption
of radicals from a hot wall.
SOURCE: Kinetika i kataliz, v. 4, no. 6, 1963, 867-877
TOPIC TAGS: zinc oxide, zinc oxide film, zinc oxide electric conductivity,
electric conductivity kinetics, alkyl radical, radical adsorption, radical
chemisorption, radical desorption, hot wall emission, ketones photolysis,
ketones pyrolysis, free radical, free radical reaction mechanism, free radical
reaction kinetics
ABSTRACT: The electric conductivity of ZnO films under stationary conditions
and the kinetics of electric conductivity for chemisorption and desorption of
i alltyl radicals were Investigated. The relationship of the disappearan.ce of free
Card 1/3
ACCESSION NR: AP4008168
radicals in a g - ven volume, the adsorption of radicals on the surface and the
conductivity (sigma) of the film, based on the light intensity I and the pressure
of the gas forming the radicals (concentration of molecules M) is shown: At
low intensity and high film temperature (low radical concentration on the sur-
face), the relationship isfir-st order in the volume and on the surface (1)
a - I - [ M ] where a is ' "'o . At higher concentrations or intensities, rela-
tionsNps (2) a -X-f TM-1-or (3) a-.,
VI IM] obtaih, 1. e ~it is firk order
in the volume an&2nd order on the surface, or vice versa (2), or it is second
order in both locations (3). The kinetics of the conductivities of *the. film during
adsorption and desorption of radicals, as derived from experimental data
obtained by photolysis and pyrolysis of ketones, compare with these principles.
A new variant of the method for deterinining relative concentration of radicals
is proposed. This is based on measuring the starting rate of change of the
electric conductivity (at the instant of radical appearance. or at a change in
their concentration). This determination can be conducted automatically in
1-10 seconds. A new phenomenon was observed - the desorption of radicals,
card 213
ACCESSION NR: AP4008168
on heating, from walls of a glass or quartz vessel in which the radicals were
first found. "The authors thank Sr. laboratory worker A. P. Sy*soyeva who
participated in the experimental part of the work. " Orig. art. has: 8 figures
and 20 -equations.
ASSOCIATION: Fiziko-khimicheskoy institut. im. L. Ya. Karpova
('Physical- Chemical Institute)
SUBAUTTED: 29May62 DATE ACQ: 09Jan64 ENCL: 00
SUB CODE: PH, CH NO REF SOV: 006 OTHER: 005
ca,d 3/ 3
MYASNIFOV, I.A.; &OLISIRRI, Ye,V. Prinimala uchastiye KOZIT-47AIU!'' ~ ~11
. \ I ., -. .
Methods used in investigationB of the heterogeneaus recombinati ~
of free radicals and of their interaction with the edsorbed ~ ybr.
Kin. i kat. 6 no. 6t99701002 N-D, 165 (MIRA i9:1)
1. Fiziko-khimicheskiy institut imeni Kr-rpova. Pulmltl-e-d Mny 215,
1964.
86841
.3 a o 13 >0 3 o Id V3 / 11113)
1,5-,3 /
S/020/60/135/005/031/043
B004/BO75
AUTHORS: Myasnikov-, I-. A. andJjQ;_'J1h11,n ft"L%M44
TITIE: - Adsorption of Alkyl Radicals on Oxide-Semiconductors
PERIODICAL: Doklady Akademii nauk SSSR, 1960, Vol. 135, No..5,.
pp. 1164-1167
TEXT; In a previous paper (Ref. 1), the.first-mentioned author has-shown
that the adsorption of atoms and radicals on the surface of oxide-semi-
conductor films, e.g., n-type ZnO, causes a change of the conductivity of
the semiconductor. The present paper quantitatively investigated the re-
lationship between the radical concentration and the ZnO conductivity. By
means of a nPK-2 (PRK-2) lamp, acetone vapor was photolyzed in a quartz
cell having a mobile quartz frame, onto which the ZnO film (thickness about
5 p) 'was applied. The partial pressure of acetone vapor amounted to 0.1 -
100 mm F1g, the pressure of the inert gas (He, Ne, Ye) to I - 200 mm. Hg-
Temperature was 200 - 300 0C. The distance between ZnO and the aperture,
through which the photolytically generated CH 3. rad icals entered, could be
varied between 1-15 am by means of the mobile fraM6. The difference
Card 1/3
86841
Adsorption of Alkyl Radicals on Oxide S/020/60/135/005/031/043
Semiconductors B004/BO75
Aa = a0 - a was measured (ao = initial conductivity). a = conBt/-p J3) was
obtained for a as a function of radical concentration n, a = const/ VI"(5)
as a function of the intensity I of the light absorbed. In Fig. 2 the vali-
dity of equation (5) is experimentally confirmed. When the partial pressure
of acetone was constant, ZnO conductivity linearly increased with increas-
ing pressure of neon. On the strength of these results the authors draw
the conclusions that recombination processes and the reactivity of radicals
and other free particles of various gases can be investigated by means of
this method. Different alcohol radicals have different effects on the
conductivity of the semioonduator, so that they can be identified in very
low concentrations by means of the method described. The authors thank
Professor S. Ya. Pshezhetskiy for discussions. There are 4 figures and
7 references: 2 Soviet, 4 US, and 1 German.
ASSOCIATION: Fiziko-khimicheskiy institut im. L. Ya. Karpova
(Physioo-chemioal Institute imeni L. Ya. Karpov)
PRESENTED: June 22, 1960, by S. S. Medvedev, Academician
SUBMITTED: June 17, 1960
Card 2/3
6-
ts_
4
42 44,1.46 10
0
Card 3/3
86841
S/020 60/135/005/031/043
B 04%075
Legend to- Fig. 2: ZnO conduc-
tivity as a function -of lirht
intehsity in the presence of
photolyzed acetone; t =300 0C;
cetone ~ 5 mm-Hg a) I -f(Aa),
Pa
with increasing 1, 2: with
decreasing.I; b) in a logarith-_
mio representation for two
filfts of different thicknesses.
lb J~ (4 --tv-1-840
BOLISHUNOV, Ya.V.
Negative induction in tbo proceas of learning verbal material.
Vop.paikbol. 5 no-5:79-86 S-0 '59. Ma 13:3)
1. Kustanayskiy goeudarstvennyy pedagogicheskiy institut.
(Learning, P3ychology of)
GAVRAIM, V.V.; YUS, M.Ya.; BOLISHUTKIN, D,N.
X-ray analy0is of cavitation arooion in matals. Yiz.met.
metalloved. 1 no.3:494-499 155. (MLRA 9:6)
I.Kharikovskiy politekhnichaskiy institut imeni V.I.Lenina.
(Cavitation) (Metallographr)