SCIENTIFIC ABSTRACT BORISOVA, L. V. - BORISOVA, N. B.
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S
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The Chromatographic Separation of Rhan-Jum and Tungsten
SOV/75-13-11-22/29
from tungsten. There are 1 fi-ure, I table, and 6 references,
5 of which are So-!,riet...
ASSOCIATION: Institut geokhimi-i i 3naliticheslzoj: khimii im. V. 1.
Vernadsko,-o AH SSSR, (Instil,_,Ip of GeocheTListry and
0
Ana lyt ica I Chmjiti-j~Moxeov AS USSR lama Ve 1. V0rX&d8kiY
SUBMITTED; October 28, 1957
1. Rhenium--Separation 2, Tungsten--Separation 3. Radioisotopes
--Applications 4. Chromatographic analysis--Applications
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RYABOHIKOV, D.I.; VAYNSHTM, Me.; BORISOVA, L.V.; VOLYMS, M.P.; EMLXV,
V.V.; KUTSIM, Yu.I. ':-~
Spectrochemical method of determining bismuth, cadmium, antimonv, tin
and lead in metallic tungsten, niobium and tantalum. Trudy Kom. &nAl.
khim. 12:82-93 160. (MIRA 13:8)
(Tdngsten-Analysis) (Niobium--Analysis)
(Tantalum-Analysis)
J3DRI~_OAI___LLLL-_, HOBk7a)
Fall excursion in the fifth grade. Geog. v shkole 23 no.4:41-46
Jl-Ag !60. WU 13:10)
(Ismaylovo (Moscow Province)--School excursions)
BORISOVA, L.V., RYABCHIKOV, D.I.
"New Spectrophotometric methods for the determination of rhenium."
Report to be submitted for the Intl. Feigl Anniversary Symposium on Analytic
Chemistry
Edgaston, Birmingham, Great Britain 9-13 Apr 1962
S/075/62/017/007/006/006-
B119/B186
AUTHORS: Ryabehikov, D. I., Borisova, L. V., and Gerlit, Yu. B.
TITLE: Chromatographic separation.of rhenium from molybdenum and
tungsten by means of mixed eluents on ~A3 -10 (EDE-10) anionite
PERIODICAL: Zhurnal analiticheskoy-khimii, v. 17,'no. 7, 19629 890 - 892
TEXT: Separation experiments were made with ihe following eluants:
2 M H3PO4 (1); 0.2 M H 3PO4 + 0.3 M Na 2HPO4 (11); 0.2 M R3PO4 + 0.6 M Na2SO 4
(III).. The ionic strength of the solutions was kept constant. The completo
separation and the degree of purity of the Re separated were-prored by
means of R186, Mo99, and w185, whereby good quantitative results were ob-
tained. 40 - 45 ml of 1, 30 - 35 ml of II, and 24 - 25 ml of III were used
to elute equal amounts of Re. Beat results in Re eluation were from III.
There are 4 figures and 3 tables.
ASSOCIATIONt Inatitut geakhimii i analiticheskoy khimii im. V. I. Vernads-
kogo AN SSSR, Moskva (Institute of Geochemistry and Analytical
Chemistry imeni V. I. Vernadskiy IS USSR, Mos9ow).
RYABCHIKOV_, D.I.; BOR150VA, L.V.
RhenilUm- th~iourea complex compounds. Dokl.AH SSSR 145 no.2.*355-
357 J1 162. (19YA 15;7)
I.. Inatitut geokhimii i analiticheskoy khimii imni V.I.Vernadskogo
AN SSSR. Predstavlano akademikom A.P.Vinogradovym.
(Rhenium compounds) " (Urea)
RYIBCHIKOV, D.I.; BORISOVA, L*V*; GERLIT, Yu.B.
Chromatographic separation of rhenium from molybdenum and
tungsten by means of mixed eluents on the EDE-10 anion exchanger.
Zhur.anal.khizi. 17 no.7s890-892 0 162. (KM 15:12)
1. V.I,Vernadakiy Institute of Geoohemistry and Analytical
Chemistry, AcadaW of Sciences, U.S.S.R., Moscow.
(Rhenium-Analysia) (Chromatographic analysis)
A
AFMI._ BM/JD/JG
787
;'fic SSIM NR: ~AP3004227
AUOTF isova,-Le ve
.0 F?yAbqMlmv$ D. I*; MPr
J~
J
pbenylearb
.Determination of lloys,by meanstof di azide
TMI rhenium in d
dakaya lnboratorfy 20, no '785-797
SCUROM" Zavo ~V.
i
t
it
';V IC TIAGS rhonium, alloy , diphonylearbadde-
OF
-ABSTRACT: -method for the determination of rhenium is
An extractive photometric
~P~"O~ plea (with interference only from Cu,, V, SQ, and The method does not recuLre
Bi ent I'm 02 ~ r.0-no
separation of rhenium from Cd fig, zn dival Al Va7
;pre3ird~ary
nt Cr _Zrj and INTb. The method is base
-1 ~nt, trivale TIO$ d on.the
re86 16 of rhenium with dipbeny2ciwbazide In P-normal ID-drochloric acid, the optical
''adnsity, of the resulting substance being es.t mateain a spectrophotometorat 540
sed for a tun
imf.IATd~ gsten alloy
,crons with an accuracy of 51#, The procedure u
ilivk~6s di, gesting 5-100 mg of tbe'.s or 10-15- minutes
gentle heatdng f
larple under
4-th 5:40~ rl of armonia solution.. _by-drop addition of 30%. bydrogan
(under a dro
p= until completely clear), The'subsequent procedure involves drying, treat-
h hydrochloric acid and dissolving in VaOH. For alloys cont~_Ining cr, Co'
Fe Vi, and 'A the- process requires Sestion with ECI and additions of either
i 6r0 ~`./2 .... ..
RYABCHIKOV,,, D.I.; BORISOVA, L.V.
Interaction of perrhenates with diphenylcarbazide and di-
phenylearbazone. Zhur.anal.khim. 18 no.'*7a851-855 J3. 163.
(MIRA 16:U)
1. V.I. Vernadskiy Institute of Geocheiaistry and Analytical
Chemistry Academy of Sciences, U.S.S.R., Moscow.
SAVITSKIY, Ye.M.p doktor khim. nauk., otv. red.; RYABCHIKOV, D.I.J,
doktor khim. naukp red.; BIBIROVA, V.I., doktor tekhn.
nauk, red.; TYLKBA, 14I.A., kand. tekhn. nauk, red.;
POVAROVA, K.B., kand. tekhn. nauk, red.; ~QftISQVA,-,Lj-,.
inzh., red.; MAKARENKO, M.G., red.
(Rhenium; transactions] Renii; trudy. Moskva, Nauka,
1964. 257 P. (MI'U 18: 1)
1. Vsesoyuznoye sovesbchaniye po probleme reniya. 2d, 1962.
RYABCHIKOV, D.I.p otv. red.; ALIKARIN, 1.P... red.; PALEY, P.N.,
red.; BORISOVA L.V.p red.; ZOLOTOV, Yu.A., red.;
SENYAVIN- KARYAKIN, A.V., red.; VOLYNETS.
M.P., re
(Modern methods of analysis; methods of studying the
chemical composition and structure of substances. On
the seventieth birthday of Academician A.P.Vinogrado-I
Sovre nIza; metody issledoyaniia,1rhimi-
cheskogo sostava i stroeniia veshchestv. K semidesiati-
latiiu akademika A.P.Vinogradova. - Mqekw&;0- NaWai - 1-965.
333 P. - (MIDkl8:7)
1. Akademiya nauk SSSR. Institut geokhimii i analitiche-
skoy khimii. 2. Chlen-korrespondent AN SSM,`(for
Ryabchikov).
K:j -1 1- ,-r -, I ,
y/~I- ul?,'S OVA, N. E.; VKHhROVA, N.S.; C- --- T, -,. . ,
r iV.. ~. N ~ B . ; 1 11 -B -~-, - .
- I
Ilse of ceilular cultiires ~Ior the determination of' ar,~L-itcxin
contant in antidiphtharia sera. Zhur. mikrobiol-, ep--d. I immim.
no.11:1,~,,2-123 N 265. (MIRA .18:121)
1. Anri-i 1;. 1965.
1
I
1~-
i Curd' 1/2
D-DRISOU, 7.:.
"Institute of Physics at the Buitga-rian Acador,~,- of Sciclices" G-97) PRIRODA
'. - ~To 1
(Bulgamolm A%adoidla 1',-Wdto) Sofiya Vol 3 It JMI/Fob ~~! r
SO: East -Puro-cean Accessions List 7.r01 2 IT " AuE; !954
- 'o I
BO.qISSIIIMVj, Yb.Pq _ MRISOVA,, "Ye.,
NumBrical forecast of me= mnthly anommlies of air tc:4)C.*xL"*-c
by the statistical muthod. Trudy AAIIII 262:185-192 165,
(1up-h 19: 1)
s, 0
SURNAM, Given MGM"-
Countrys Bulgaria
Academic Degreess [not given]
WWAtions Senior Nurses at the Scientific Research Institute of Pediatrics
(Nauchno-Izsledovatelski In6titut po Pediatriya)
Sou=ej Sofia, Sreden Maditsinski Rabotnike No 7, 19b1, PP 38-40
Datat "The Nurse's Role in the Performance of Blood Transfusions to Young
Children"
Authors;--
(iDRISOVA,
~- -M ~-
-HUX-MA, R,
."164)
BDRISOVAV M. A.
BDRISOVA, M. A. - "The dependence of nicotinic-aold metabolism on the clinical
course of typhoid and on the state of protein metabolism in sintoMzin
therapy". Moscow, 1955. First Moscow Order of Lenin Medical Inst.
(Dissertation for the degree of Candidate of Yedioal Sciences).
SO: Knishnava Ls&gpisl No. 46, 12 November 1955. Moscow
COUNTRY I USSR
CATBGORY :Pharaac;loQr, Toxicology. Chemotherapeutic Preparation*.
Antibiotics -
ABS. JOUR. : RZhBiol. , No. 12 1958j. N% 568o9
!AUTHOR -Borifiova, M.A.
IFIST. -. Stalin 1"iti-tute of Postgraduite Nedicine
TITLE :The Treatment of Typhoid-Paratyphoid Diseases with
Antibiotics
CARIG. FUB. i5b. Tr. Stalinsk. In-t Usoversh. Vrachey, 1957, Vol.27,
135-140
AB-SMIACT :No abstract.
Card:
BORISOVA, M.A., kand.med.nauk
'Studying nicotinic acid metabolism in typhoid fever treated with
synthomycin. Terap.arkh. 29 no.2:70-76 157. (MIRA 11:1)
1. 1z kafedry infektsionnykh bolezney (zav. - doktor meditsinskikh
nauk K.V.Bunin) I Moskovskogo ordena Lenina meditainskogo instituta
imeni I.M.Sechenova.
(CHLORANPHNNICOL, therapeutic use,
typhoid fever, eff. on nicotinic acid metab. (Rus))
(NICOTINIC ACID,,metabolism,
in typhoid fever, eff. of chloramphenicol ther. (RUB))
(TYPHOID "VBR, therapy,
chloramphenicol, eff. on nicotinic acid meteb. (Rua))
BCRISOVA, M.A..
Pblyglucin as an antishock substance in major surgery. Akt.vopoperele
krovi no.7:345-347 159. (MMA 13:1)
1. Gospitallusys. kbirurgicheskaya klinika Ivanovskogo Gosudaretvennago
maditsinskogo instituta (zav. klinikoy - prof. P.M. Maksimov.
(DIOMUN) (SHOCK)
~BORISOVAt M.A*
Studies on nicotinic acid matabolism in patients.with typhoid fever
treated ~rith antibiotics (synthceiycin and levomycetin)associated
with a diet rich,'in proteins. Vop. pit. 19 no.3:42- 160o
1. lz kafedry infektaionnykh bolesney (zav. - Prof. K.V.Bunini
I Moskovskogn ordena.Lenina, me'ditsinskogo instituta imeni, I.M.
Sechenova.
(TYPHOID FEVER) (ANTIBIOTICS)
(NICOTINIC ACID) (PROTEINS)
CHEMVINA, I.A.; BORISOVA, M.A.
Effect of soclium azide on the virescence process of oat
seedlings. Nauch. dokl. vys. shkoly; biol. nauki no.1:149-153
162. (MIRA 15:3)
1. Rekomendovana kafedroy fiziologii rasteniy Moskovskogo
gosudarstvennogo vniversiteta im. M.V. Lomonosova.
(PLANT8, EFFECT OF SODIU14 AZIDE ON)
(OATS)
BORISOVA, M.A.
Condition of the heart in tick-borne encephalitis patients
and convalescents based on electrocardiographic data. Ter.
arkh. 35 no.4:89-921 ApI63 (MIRA 17:1)
1. Iz kafedry infektsionnykh bolezney ( zav. M.M. L7skovtsev,
konsul'tant prof. A.A. Savellyev) Novokuznetskogo gosudarst-
vennogo institute. dlya usovershenstvovaniya vrachey.
BORISOVA, M.A.) kand. nied. nauk
Clini-nl and biochemical comparisons -in the study on the copper
content and ceruloplasinin activity of the blood serum in typhoid
fever, acute dysentery and Botkin's disease. Sov. med. 2-1 -no.6:
45-51 Je 16.j+.
1. Kafedra infektsionnykh bolezney (za-;. - prof. V.,,%
Krymskogo meditsinskogo instituta, Simferopol'.
BO RISOVA, M.A.p kand.med.nauk
Clinical significance of the d3namics of the indices of
metabolism of trace elements, enzymes, and vitamins in
epidemic hepatitis. Sov.med. 28 no.12.-42-47 D 165.
(MIRA 18:12)
1. Kafedra infektsionnykh bolezney (zav. - prof. V.M.
Domrachev) Krymskogo meditsinskogo instituta, Simfe-opoll.
Nauchnyy konsulltant - zav. kafedroy infektsionny)-~h bolezney
I Moskovskogo ordena Ienina meditsinskogo institu;a imeni
I.M.Sechenova prof. K.V.Bunin.
TIMAKOV, V.D.; SKAVROSKAYA, A.G.,-,. BORISGVA, M.B.; ZAMCHUK,L.A.
Antig6nic properties of deoxyribonucleic acid in Salmonella
typhimurium Flo.70. Zhur. mikrobiol.,, epid. i immun. 40 no.1:
5-13t63. (MIRA 16:10)
1. Iz instituta epidemiologii i mikrobiologii imeni Gamalei
iilffl SSSR.
BORISOVA, M.B., inzhener.
Meeting at the All-Union Scientific Research Institute of Petroleum In-
dustry on the results of scientific research work in the field of carboniz-
ed construction materials. Biul.stroi.tekh. 10 no.10:29 My 153.
(MMA 6;8)
1. VNIlstrovneft'. (Garbonization) (Building materials)
7>
6
AUTHOR: Nikol'skiy, A.F. 37-11-6/18
TITLE: Regarding N. P. Ben1kova's and M. G. Horisoval-9,article
"Index K Basea on Data from the a_vTro5v-sY_Na_gnetic Observ-
F
atory for the Years .1916-.1939" (Po povodu stati
N.P. Ben1kovoy i M. G. Borisovoy "Indeks K po dannym
Pavlovskoy magnitnoy observatorii z8 1916-1939 gg.'#)
PERIODICAL: Trudy Nauchno-issledovatel'skogo Instituta zemnogo
magnetizma, 1957, Nr 11(21), pp. 111-118 (USSR)
ABSTRACT: This is a review on the frequency distribution of mag-
netic activity and the daily, yearly and 11-year cycles.
The following authors are mentioned: Kalitina, G.N.,
Mishin, V.M., and Kozik, S. M. There are 2 figures and
4 references, all USSR.
AVAILABLE: Library of Congress
Card 1/1
TST5KLRlAj%.N, I.S.; MILONOV, N.P.; ROC,02HTN, G.V., ?M- ~~'; I
Prospects for tfie use of mipports vu~de of ne. in the
Kdzel Basin. Nauch. trudy PermNIU-1 rio.6-10-3-114 l6z-
(MITIP 18:2)
VANCHIKOV, A.11.9doktor tekhn.nauk; GOIMM9 L.I..9inzh.; BORISOVA. H.I.,inzb-.
---------
Increw3ing packages on P-76 Bpinning machinee. Tekst.pron.
19 no.2:14-19 F '59. (MM 12:5)
(Spinning machinery)
TRAKOVSKAYA, L.I.; IVRfOVA, M.I.; BORISOVA, M.I.
Investigatirg wear-resistant travellers for spinning mebines
witb bigb linear velocities. Tekst.prom. 19 n0-10:39-42
0 '59. (MIRA 13:1)
(Spinning muchiner7)
BORISOVAP M.I., nauchnyy sotrudnik; VLADIIMMV, B.M., natchnyy sotrudnik;
ALITMAN, A.B.; VALAKINA, V.M.;WMIDV, V.L.
Self-lubricating ceramic metal rollers made with graphitic iron.
Tekst.prom.22 no.3:80-82 Mr 62. (MIRA 15:3)
1. TSentralInyy nauchno-issledovatellskiy institut khlopebatobu-
mazhnoy promyshlennosti (TsNIKhBI) (for Borisova, Vladimirov).
2. Vsesoyuznyy nauchno-issledovatel'skiy institut elektromekhaniki
(VNIIEM)-(for AlItman, Valakina, Memelov).
(Spinning machinery)
~r , ~. ", ~ -,
:09
-*~- I
/
M
atmosphere
I I Ali is 9WItUISMOUL11410
A 9 L &_lt- a n W a 34 It b
A
00
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to 1
3 Effect of the fempWitturit of ddriff an the structure of
Warlow types of safels Itels. 0. R. Ilm"kay. Nt. S
V. A. this'lio. A. V. Killeley, 0. A. Likhachevil,
=in. MotOkhows. nokhidv Akad. Nawk S.S.S R
OZ. 040~152(11148); Cf. C.A. 43, 71132d- Three voinpir., 1,
prill.f. liv plOn. frea" NQQA0. with tam,thing, and
At"a 'Irvillit lit I'tlau tellip.. It. watillml ppl. loaktril 24 lit,
in 0.02.V N11,011, still 111, pteIA, from fly pl-li,
with CuSot, drying. rrl"ted treatmeilt %tith hot IItS0,.
Rolf WAS111111, Were Itti-MIlKlIll"I in Mki.11-flCil.1 atilt J-V11
Ill.) .4 NIV4111 aft" li,,"ting 12 h-. I,- I - WN
1011111. 1 1% a vilm"ll, finr'-J-Wir gel, I.We I.Ji.). v 1.1"ki
W A.. 11 inaink inlist (tr4lOvilt 9 - 35-4o A
Ill of usixell 1,mv site, r froin 15 Ion) A. The Rdowpilim,
isotherm of , livAtrit in is typical tit fine-porr all
0
4 vithrills, Irvitlinj nil to ronst. nibiorplion ftom p-'p,
(relative pt"litife 0.11 on At const: !p. - 0,2, the v-4
Of liLlol(i NIC01( AlIllOftleti Is About IMP', of tile Intal pt"i,
r via.; It int-mit" solnewhat with I tip tit :00-3NI", flit-ii
fAllS with futther rising; I up to WXI'. Tile trurve fix pi /-. -
1. idtifted to higher milsorpt ions, has the tattir qhape. Thr
i~.tlivrm foir 11 U - 14)0*) ri" steeply at high p 11.4
shotes ittark"I hirtitefesio. At jtl~ - it 2. mili- tlj -14)
Of the total I.Or Vt%]. 1, fill"I. % ,1111 filling 1,
Oumfies little op Io altont 40i1 -4141% then 1411,t. Tile t~.
Ilit-ml of Ill 11~4 mili'11%. lkt With pip.: At 16 P. - 0.2, ill
(All Of pit"Kily 'Alth ill ing I is much %linvirr than iii
The
the case of Il. Wace area 1, hv the B.F.T
niviliml, plottei as a function of t. remains appmx. comt.
tip Ili about 4(W for If. then falls raphilk., in ahout '.l
I.* t - 1100,; in (lie "%r of III, I 61mri.r,
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Effect of MU=_bj*-qjdde on the catalytic activity of
aluminum la MF-M--r-eraffo-n to, the decomposition of rlbyl
UICA0 - G T-Lpaelskov, V. ArDzis'ko, and M. ~S.-Bori-.
K
Ya, Kagwy vs.-Chem. Inst., AloscoivYTT FtU.'
Fir. Khjyn. 27. 1172-6(IIJ53); cf. G.A. 4Z, 21h.-The
progressive poisoning of AhOa catalysts,by N1a0H vras in-
vestigated. Samples of AIA prepli. in 4 different ways
u-cre made to absorb various amts. of NaOH fr,, so n
then dried and kept I fir. at 450*. The catalytic olcti'!i~;
ul each sample was detd. from the amt. of ClH4 produced
when Et0H was passed over it at 420*. The total adsorp-
tion surface was detd. by means of a sorption balance with
MeOH as the adsorbate. Sp. gr., -. 01. of micropores ill
oc./g.. total. surface in sq. w./g, and sq. in./cc., and total
and specific catalytic activities of each of the initial sample5
are tabulated. The rate coust. for the forumflon of C.11,
19 shown graphically &3 a function of the'amc of adsorbM
NaOR in millitnoics/g. for earl type of sample. The rcla-
tive rate consts. are platted as functions of the no. of inilli-
moles of adsorbM NaOH per .1 cm. of adsorbing surface.
The pore size and total surface .7,Al..Oj are unchanged by the
NaOH treatment. The cataly-tic activity decreases as the
amt. of adsorbed Na0H increases, most rapidly for ih,
snuallest anits. of NaOH. This probably carrc4lxj,,d.,; to
adsorption of NaOll mols. on active groups of the stirfa~e.
It is concluded that the activeregions courprise 5-10110 of the.
total surface of the Alt0a saniples. The 1101. Of aCLiVe
centers per unit surface depends on the parity of the suniple
and not on. the manner of its prepn. J. W. L., Jr.
BORISOVA, M. S.
C/
Cholitical Abstracts -
.
IT-ay 25
1054 v on tfir, cxti-.iii of nutfur- and
in
tiffect nt ignifinn tcnqv.~i it
'
d
, Iyn the wnfrr cvllh~ll" ni it),, tixhk~ Pf fl1Iv7qjjvj%jn an
'
Goncl,al ulj rhysical ri 'I-
v -k~ ia NI.S."Tv
- . . . - ..'! I
f
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s
;r,,r
Fi:. Kh;,,!. it mi
ti'm f'f fht~. lllceh:vtli~m of L-AMv~-;' in 'y~j'ju-; Vic.
lvafft "wount "f AM " 11!1,1 Niff) 1,:Iy; doft. *Fit,- wvp. of a
:'Impic Vf AiZO; i'l va'--mirl v;" m; -vfl 1-m 11K) 0, 11"XV Oitr-
iiig ;- MI-hr. '11i(- vlolvvl 11-0 Nv.j' viricht-d I'V
tilvall, of a bjl,-rre. Tilt- A1:0, cimtai%d !7. 4.5,
I A, :111d 0% It-() at ('01. and 12fy'l " re-p- Tht~ 511r.
N..." 12-7. ;:-J -9. m. ver r. at SOo,
HY19, twl 1"00", t :I ~illdbr tf,11mclit Nf;~Wfjl-
eptirCIN t""vvvj ImA t" 7'fi'~O I'VI-~:Z70,; flx r1l'. ")f rt"IA -Isi"11
-1:~ Iluix. at '1~111-~ 'I lir JT~() ("'!Itc"t :l;ld tilt SlIO.--cc of
at aild Ivey( 2.9' 0.3'3' :171:1 O'Ojr~
resp., and 347, Sri, and I I sq. in. per g., resp. In oxkks
7
Ahe water appears to be held in solid soln. above 40iF .
r
.11. data are tabulated and graphed.
WM/ Chemistry Physical chenistry
-Card- 1/1
Autbors Boreskov., G. K& Dzislko., V. A., and Borisova, 14, so
-Title t Porous structure of catalysts and its.effect on thdr reaction
selectivity
''Periodical t zhur. fiz. khim. 283 E d. 63 1055 lo66, June 1954
Abstract 2 Two cases of series reactions of the first order were investigated to
determine the effect of porous structure of catalysts on their reaction
selectivity. The rate of diffusion transfer, toTard the internal
surface of the catalyst grains and its effect on reaction selectivity.,
was also considered, The selectivity dependence upon the rate of
diffusion was determined by criteria expressing the relation between
Ahe rate of chemical conversion and diffusion transfer for the basic
substance and intermediate product. Four USSR references. Graphs.
Institution The L. Ya. Karpov Physico-Chemical Institute, Moscow
Submitted August 18., 1953
Z_. M/0
AUTHORS:
TITLE:
PERIODICAL:
S11951601001 /001 /005/007
B01 5/B060
Dzislko, V. A., Borisova, 11. S.
Effect of the Acidity of Catalysts on Their Catalytic
Activity I. Polymerization of Isobutylen
Xinetika i kataliz, 1960, Vol. 1, No. 1, pp 144-152
TEXT: The authors studied the relationship between the acidity and the
catalytic activity of the following oxide catalysts: ZrO 2* Sio 21
Al2 03* SiO2, B203' Al20 31 Tago-Sio2, and H 3PO 4 on SiO 2' The acidity and
the number of acid parts were determined by using the indicator method
and eight different indicators with pK from + 6.8 to -8.2 (Table 1).
The catalyst samples investigated were hydrated under standard con-
ditions. Pure and mixed oxide catalysts were tested (Table 2), and it was
found that the maximum acidity was not dependent on the concentration of
the acid component in the mixed catalyst. The acidity function H varied
from +4 to -8.2. The effect of acidity on the catalytic activity 0 was
investigated in the range from Ho=_3 to -8 on the polymerization of VK
Card 1/3
82655
Effect of the Acidity of Catalysts on Their S/195/60/001/001/005/007
Catalytic Activity I. Polymerization of B015/Bo6o
Isobutylene
isobutylene in a circulation apparatus (Fig. 3) at a circulation Tate of
about 800 1/h, at 1500C, and a partial isobutylene pressure of about
300 torr. The experimental results obtained (Table 3) show that with a
variation of acidity by five orders of magnitude, the dimerization rate
varies by the fivefold only. The degree of dimerization (with rest-ect to
isobutylene) amounts to 1.6 on silicon zirconium- and alumosilicate
catalysts at 1500C. This low dependence of the reaction rate on acidity
shows that the isobutylene adsorbed on the catalyst surface is almost
completely "protonized" (Table 4). A comparison with data from publica-
tions concerning the dimerization of iso~utylene on phosphoric acid films
leads to the assumption that the "protonization" of the adsorbed iso-
butylene takes place more readily than that of the dissolved one.
G. K. Boreskov is finally thanked for his discussions. B. A. Kazanskiy,
M. I. Rozengard, and N. M. Chirkov are mentioned in the text. There are
4 figures, 4 tables, and 13 references: 7 Soviet, 3 US, 2 British, and
1 French.
Card 2/3
Effect of the Acidity of Catalysts on Their S/19k~*001/001/005/007
Catalytic Activity I. Polymerization of BO15/BO6O
Isobutylene
ASSOCIATION: Fiziko-khimich&skiy institut im. L. Ya. Karpova
(Physicochemical Institute imeni L. Ya. Karpov)
SUBMITTED: December 30, 1959
Card 3/3
38707
S/598/62/000/007/039/040
/C~? op D217/D307-
AUTH'ORS: Belan, N. I., Idellchik, B. M., Boriso-Va, M. S. and
Chi'Xurova, A. A.
TITLE: Investigating titanium alloy ATI-' (AT6) for its suita-
bility as material for working Aeels of supercharges
operating in aggressive media
SOURCE: Akademiya nauk SSSR. Institut metallurgii. Titan i yego
C,
splavy. no. 7, Hoscow, 1962. Metallokhimiya i novyye
splavy, 288-293
TEXT: Forgings of the alloy AT06, containing 5.8 wt-c,,", Al and 1.1-%
C; r + Pe + Si + B, were studied. The mechanical properties of the
as-received material were tested on probes from the surface and
from the central portion of the forging. In order to choose the
optimum heat treatment of manufactured components and to elucidate V~
the influence of annealing on the*change in mechanical propei-ties
of the alloy, two heat treatment procedures were tried out. One
--of them, recommended by the Institute of Metallurgy AS USSR, con-
Card 1/ 3
S/598/or2/000/007/039/040
Investigating titanium alloy ... D217/D307
sists in heating to 850 OC, soaking at tlat temperature for 1 hour
L)
and cooling in air. The other consisted in heating to 84000, soak-
ing at that temperature for 1 hour and furnace-cooling to 6000C,
follov.red by cooling in air. The alloy was also tested for its cor-
rosion resistance. It was found 1hat the alloy in the forged con-
dition Dossesses a high proof stress, both at the surface and in
the center of the forgings, high toughness and a satisfactory pla-
sticity. Heat treatment of the alloy at 8400C with subsequent air
cooling increases the impact resistance somewhat, without affecting J/'
the original strength ana plasticity. Purnace-cooling from 8400C /I
to 6000C leads to a slight reductioh in Dercentage elongation. The
alloy did not exhibit any tendency to stress corrosion cracking
during testing with application of a tensile stress of 70 kg/mm2
for 750 hours at room temperature in water saturated with H 2S. Al-
so, the general corrosion resistance of the alloy in water satura-
ted with H 2S was found to be high. On bringing the alloy in con-
tact with the steel (1Kh18N9T) with an area ratio of 1 :11
the corrosion resistance of the steel in H2 S-saturated water de-
Card 2/3
S/598/0'2/QOG/007/039/040
Investigating titanium alloy ... D217/D307-
creased somewhat, but still remained at a high lev-el. Under condi-
tions o'L' short-term testing (700 hours) in hydrogei~ at 1000C and a
pressure of 60 atm, no tendency to hydrogen embritilement was ob-
served. There are 4 figures and 3 tables.
Card 3/3
D.Z.ISIKO, V.A.; BORISOVA, M.S.;,KOTSARENKO, N.S.; KUZNETSOVA, E.V.
Effect of the acidity.of oxide catalysts on their catalytic
activity. Part 2: Dehydration of isopropyl alcohol. Kin.i
kat. 3 no.5:728-733 S-0 162. (MIRA 16:1)
1. Institut kataliza Sibirskogo otdeleniya AN SSSR.
(Isopropyl alcohol) ..(Dehydration (Chemistry))
(Catalysis)
BORISOVA,J".; DZISIKO, V.A.; PHEREDNIK, Ye.M.
,!!L . -
Effect of the acidity of oxide catalysts on their catalytic
activity. Part 3: Dimerization of propylene. Kin.i kat. 3
no.5:734-741 S-0 162. (MMA 16:1)
1. Institut kataliza Sibirskogo otdelaniya AN SSSR i Fiziko-
khimicheskiy institut imeni, Karpova.
(Propene) (Polymerization) (Catalysis)
BORISOVA, M.S.; DZISIKO, V.A.; FWAIIYEVA, L.A.; TIMCFEYEVA, L.N.
Acidity of hydroxYl groups Of Oxide catalyst surfaces
studied by means of lnfmred spectroscopy. Kin. i kat. 4 no.3:
461-466 My-Je 163. (MIRA 3.697)
1. Moskovskiy gosudarstvennyy universitet in-eni Lomonosoval
fizicheskiy fakulitat i Fiziko-khimichookiy inutitut imeni
Karpova.
(CatalyAts) (Hydroxyl roup)
(Spectrum, Infraredl
ACCESSION NR: AT4007066. S/2598/63/000/010/0322/0331
AUTHOR: Belan, N. L;-1Bqrisova,. M. S.; Idellehik, B. M.; Chikurova, A. A.
TITLE: Titanium alloys AT-3, AT-4, AT-6 and VT-3-1 as materials for compressor
discs operating in various aggressive media
SOURCE: AN SSSR. Institut metallurgil. Titan i yego splavy*, no. 10, 1963.
Issledovaniya Utanovy*kh splavov, 322-331
TOPIC TAGS: titanium alloy, titanium alloy property, elevated temperature property,
subzero-tenVerature property, AT-3 titanium alloy, AT-4 titanium alloy, AT-6 titanium
alloy, VT-3-1 titanium alloy, titanium alloy corrosion, titanium alloy stress corrosion,'
titanium aluminum chromium alloy, silicon containing alloy, iron containing alloy, boron
containing allcy, titanium alloy corrosiun resistance
ABSTRACT. The possibility of using titanium-base alloys for compressor runner discs
operating in air and aggressive media has been investigated. As shown in Table 1 of the
Enclosure test specimens of alloys AT-3, AT-4, AT-6, and BT-3-1 have been used, and
their mechanical properties, thermal stability, compatibility with aggressive
i_ C.M-1/4
ACCESSION NR: AT4007056
media, and galvanic action with steels have been investigated under various conditions.
It has been found that: (1) Optirrium annealing has practically no influence on the original
mechanical properties of alloys AT-3, AT-4, and AT-G. (2) Short-time tensile strength
of alloys AT-3, AT-4, AT-G, and BT-3-1 decreases with the Increase of temperature up
to 400 C and ductility increases. (3) Impact resistance decreases considerably at low
temperatures, particularly at -80 C for AT-4, at -40 C for AT-6, and below -80 C for
BT-3-1; however, even at the lowest test temperature of -180 C, the lowest impact resis-
tance is 2-3h9LM.. -3, AT-4, AT-6, and DT-3-1 for 3700 hours at
V,nZ (4) Heating of alloys AT
200 C has no m influence on mechanical properties. Heating of alloys AT-4, AT-6, and.
BT-3-1 for 9500 hours at 400 C considerably reduces plasticity and impact strength, but
increases hardness and tensile strength. (5) At room temperature alloys AT-3, AT-4
and BT-3-1 have high corrosion resistance to a saturated aqueous solution of hydrogen
sulfide, to 5% hydrochloric acid solution, and to an 'industrial" atmosphere containing
0. 1% 502 and 0. 5% C02 at 100% relative humidity. Coupling of the alloys with steels of
the type 1X 18H9T and X 17H2 in saturated aqueous solution of hydrogen suffide and with
steels 40X and IX 18H9T in an 'industrial" atmosphere barely reduces the corrosion re-
sistance of the steels. , (6) At room teraperature the corrosion resistance of alloys AT,3,
Card -?/!
i-ACCESSION NR: AT4007056
AT-4, and BT-3-1 to 10% hydrochloric acid solution is satisfactory. (7) At room tempera-
ture alloys AT-3, AT-4, and BT-3-1 have not shown a tendency to corrosion cracking under
simultaneous action of tensile stress (80% of yield) and an aggressive medium: (a) during
500 hours in saturated aqueous solution of hydrogen sulfide; (b) during 1200 hours in 5%
hydrochloric acid solution. (8) At room temperature alloys AT-4 and BT-3-1 have not
!-shown a tendence to corrosion cracking during 1200 hours in 30% nitric acid solution under
simultaneous action of tensile stress (60% of yield). (9) At room temperature alloys AT-3,!
AT-42 and BT-3-1 have indicated a tendency to corrosion cracking in 10% hydrochloric acid -
s,olution under simultaneous action of tensile stress (80% of yiell).. (10) Alloys AT-3, AT-4,
and BT-3 -I have shown a tendency to absorb atomic hydrogen at conditions of electrolysis, at
45C; simultaneous action of tensile stress (60% of yield) during.~he process of hydrogen
absorption leads to th6 brittle fracture of specimens after a relatively short time (20-50
hours). Orig art.-has.:. __10. tables.
ASSOCIATION: Institut Metallurgii AN SSSR (Metallurgical Institute, AN S
....-SSR)
SUBMITTED: 00 DATE ACQ:. 27DecG3 ENCL: 01
SUB CODE: M4 NO REF SOV; 000 OTHER. 000
'Card
ACCESSION NR: AT4007056
ENCLOSURE: 01
Table 1 - Chemical composition, dimensions and number of tested forging billets of titanium
alloys AT-3, AT-41 AT-6, and BT-3-1.
Al Composition, % Dimensions,
InIn Number of
.
loy
Al
Cr
Mo I
Si
Fe
B
Cr, 6, Fe
dia.
height tested billets
AT-3 2.8 0.30 - 0.23 0.51 0. 01 1.0 430 110 1
AT-4 4.69 0.80 - 0.34 0.26 0.01 1.4 430 95 2
AT-6 5.52 0.71 - 0.64 0.29 0.01 1.6 430 95 1
BT-3-1 P. 41 .1.9 , 2.341 0. 06 0. 16 480 120 2
Note- The rest Is titanium
Card 4/4
ACCESSION NR: AP4044388 S/0195/64/005/004/0681/o688
AUTHOR: OzIs1ko, V. A.'; Makarov, A.D.; Borisov&, M.S.; AkImova, N.V.
TITLE: Effect of chemical composition.and mode of preparation on the physicochemi.
cal and catalytic properties of oxide catalysts of complex composition. I Zircon-
lum silicate catalysts
SOURCE: Klnetlka I kataliz, V. 5, no. 4, 1964, 681-688
TOPIC TAGS: silica, zirconium oxide, zircon, catalyst, catalyst preparation, cata-
lyst acidity, silicagel, oxide catalyst
ABSTRACT: The effect of the mode of preparation and thermal treatment on the ca-
talytic activity of zirconium silicate (Zr02-SIO2) catalysts prepared by different'!
methods.(Impregnation and coprecipitation) was Investigated. Tabulated experl-
mental data obtained for samples based on sodium silicate, all annealed 4 hrs. at
500C, show that an Increase In the PH of the medium from 5 to 8 during aging de
cre:ses the surface from 300 to 180 m2/g, while the amount of chemisorbed sodium
ion strongly Increases. The Ion-exchange washing of freshly precipitated gel per-
mits the sodium Ion content to be decreased to 0.006%. The effect of the zirconium
dioxide.- content on the physicochemical properties of catalysts based on silicon
was also Investigated. After the addition.of 0.1% ZrO2 to sillcagel, a
.Card 1 1/3
-7-
ACCESSION NR: AP044388
noticeable acidity appears. All catalysts containing more than 0.33% Zr02 Ionize
anthraquinone. At 1% Zr02 and below. the concentration of the acid centers In-
creases proportionally to an Increase In Zr02 content. For samples containing
1-25% Zr02 the Increase In the concentration of acid centers proceeds slowly*
With a further Increase In the ZrO2 content, the concentration of acid centers
passes through a flat maximum, then decreasts, the maximum concentration of acid
centers on the surface being 1.3 4 equlv./m4 at 14-57 mol.% ZrO2. The reasons
for the slight change In the number of acid centers on the surface when the ZrO2
content Is Increased above 25% are given'. The catalytic activity of the samples
'I in the decomposition of Isopropyl and ethyl alcohols was also studied in relation.,
to the chemical composition of the samples. in the range of 10-25% ZrO
2, the
specific activity is approximately constant. When the catalytic activity and the
concentration of acid centers were plotted against Zr02 content In the catalyst
the activity varied In direct proportion to the concentration of acid centers on
the surface. The act'ivity Is also affected by Impurities frorn the air or alcohol,
especially strongly In the case of samples with a low ZrO content. The effect
2
of thermal treatment on the catalytic propertleis of these catalysts was also in-
vestigated; the data are tabulated. It Is concluded that the activity of ZrO.
S102 catalysts Is determined by the number of acid centers on the surface and ;hat
the catalytic ctIvIty of the acid centers does not depend on the ratio of Zr02
,-to.slo the 4de of preparation or the thermal treatment. "The authors express
Card 2~31
ACCESSI ON NR: AP4044388
their gratitude to Yu. G. Sy*cheva. M. V. Kostyukova and L. Dronova for taking part
j-In the experimental work." OrIg. art. has: 3 figures, 4 tables and 3 formulas.
ASSOCIATION: Institut katalize SO AN SSSR (institute of Catalysis, SO AN SSSR);
Flzlko-khimlcheskiy Institut Im. L. Ya. Karpova (institute of Physical Chemistry)
SUBMITTED: IOOct63 ENCL: 00
sue CODE: ICO cc NO REF SOV: oo6 OTHER: 001
-5"a-rd, 3/3
ACCESSION NR: AP4044389 S/019S/64/005/004/0689/0695
AUTHOR: OzIs'ko, V. A.; Borlsova, M. S.; Aklmova, N. V.
TITLE: Effect of chemical composition and mode of preparation on the physicochemi-
cal and catalytic properties of oxide catalysts of complex composition. 11.
Aluminosilicate catalysts
SOURCE: Klnetlka I kataliz, V. 5,'no. 4, 1964, 689-695
TOPIC TAGS: alumina, silica, alumlnosilicate, catalyst, sillcic ethylate, ammonia,
anthraquinone, catalytic activity, acidity, catalyst preparation, oxide catalyst,
ampholite, catalyst acidity, cumol cracking
ABSTRACT: The effect of the mode of preparation on the acidity and catalytic pro-
perties of aluminosilicate catalysts prepared by different methods (impregnation
and coprecipitation) was Investigated; the data are tabulated. The measurements
ii showed that aluminosilicate catalysts are strong acids: almost all the samples
Ionized anthraquinone, except those which had a very small number~ff acid centers.-
Trcatment with moist nitrogen at 150C did not affect acidity. The ratio of the
number of acid centers in hydrated and anhydrous samples, characterizing the degree
of reaction of the aluminum oxide, depended on both their A1203 content and the
i jno4e of preparation. Treatment of Impregnated silicagel with ammonia Increased the
Card-., 1/3
r,
ACCESSION NR: AP4044389
degree of combination of aluminum oxide. in a sample containing 5% A1203, all the
aluminum oxide was combined with silicon dioxide and the degree of reaction remain-
ed higher than for samples not treated with ammonia. One result of the different
degrees of reaction of aluminum oxide with silica Is the different number of acid
centers on the surface of the catalyst. Samples obtained by coprecipitation have
the highest number of acid centers. on Increasing the content from 0.1 to
A120?
1%, the number of acid centers increases proportional to he A1203 content. A
ly
further Increase In the A1203 content decreases the growth of acid centers. in the
range of 20-75% A1203, equivalent to a change In S102:AI2Oj ratio from 6.6 to 0.5,
the concentration of acid centers remains constant, about I 11equiv./ml-. At an
A1203 content higher than 75% the concentration decreases. When the catalytic
activity of synthetic samples was tested In the cracking of cumol, It was found
that the catalytic activity of the acid centers In catalysts containing 1-9004
is approximately constant and does not depend on the mode of preparation or
A1203
the ratio of catalyst components. It is concluded that the velocity constant re-
fated to a single acid center Is a characteristic value for the catalytically
active component and can be used for the rational evaluation of substances having
catalytic activity In processes of an acidic nature. "The authors thank M. V.
Kostyukova for determining the acidity of the samples." Orig. art. has: I figure,
3 tables and 3 formulas.
2/3
ACCESSION NR:. APW44369
ASSOCIATION: Institut kataliza 60 AN SSSR (institute of Catalysis, SO AN SSSR);
Flzlko-khlmlcheskly Institut Im. L. Ya Karpova (Institute of Physical Chemistry)
SUBMITTEO: 07Jan64 NCL: 00
SUB COOE: IC, GG NO REF SOV: 012 OTHER: oo6
Card. 3/3
DZISIKO, V.A.; BOTZISOVA, M.S.; AMOVA, N.V.; MAKAROV, A.D.
Effect of the chemical Amposition and preparation technicraes
on the physicochemical ard catalytic nroperties of complex
oxide catalysts. Part 1: Silica-zirconlum catalysts. Kin. i
kat. 5 no.4:6SI-W Jl-Ag 164. (MMA 17:11)
1. Institut kataliza Sibirskogo otdeleniya AN SSSR i Fiziko-
khimicheskiy institut imeni Karpova.
L 1329o-66 EWT(M)/E'dP-(J)/T/-4TQ(m) MIIDSIWW
ACC MR: AP6000323 SOURCE CODE: UR/0286/65/000/021/0011/0011
JNVENTOR _,.V. A.;-Borisova, H. S.; P.; Tarasova, D. V.
D74&lko Krasilenko, N
:ORG: none
;TITLE: A method for producing silica gel., Class 12, No. 175925 [announced by the
Institute of Catalysis,SO,AN,SSSR (Institut kataliza All SO SSSR)]
!SOURCE.- Byulleten' izobmteniyJ tovarnykh znakov, no. 21, 1965, 11
TOPIC TAGS: silica gel, mitakimia 01irmlern PRp0,Port9
ABSTRACT: This Author's Certificate introduces a method for producing silica gel by
:precipitating hydroge aqueous solutions of sodium silicate and an ammonium
lAfrom
;salt of a strong acid viith intense mixing followed by filtering and washing of the
result ant. hydrogel. A -granulated silica gel with high strength is produced by
Itreating the hydrogel in a masticator or on rollers.
SUB CODE: 07/ SUBM DATE:. 2lJun64/ ORIG REF: 000/ OTH REF: 000
jW
'Cqrd 1/1.--
------ UDC: 66.097.3~ 661.183.7
UT;
DZISIKC, V.A.; RNIZISM~, M.S.; KAIk'KCH]YIH,V, I-G.; HAFARW, ~,.D.-, ',"IYSAF, ~K
KHRIFDI, L.A.
Effect of chemical composition and the method of proparaticn
m the physicochemical and catalytic-properties of oxidT
catalysts of complex composition. 1%rt 31. Silica-magnesia
catalysts. Kin. i kat. 6 no. 6:1033-11040 N-D 165
NIRA 19:1.1,
1. Institut kataliza Sibirskogo otdoleniya AN SSSR. Submitted
August 13, 19614.
L,, Cand Med 6ci -- (diss) "State of the nervous
BORI�,
:UINA -5 .
systeml\glutathione and choline-esteraze bwdi~x content of the
blood of petroleum workers of Bashkiriya.11 Ufa,1958, 17 pp.
(Bashkir State Med Inst im-W 15th Anniversary of VLKSM)
200 copies (KL, 32-58, 111)
_ 61 -
&R
8(2) PHASE I BOOK EXPLOITATION SOV13393
SOV/1 1 -1-1-113
Moscow. Aviatsionnyy inr:titut imeni Sergo Ordzhonikidze
0 dinamicheskikh svoystvakh sle0ashchikh privodov; sbornik*statey (.On the
Dynamic Properties of Servodrives; Collection' of Articles) Moscow, Oborongiz,
1959. -78 P. (Series: Its: Trudy, vyp. 113) 6,100 copies printed.
Sponsoring Agency: USSR. Ministerstvo vysshego obrazovaniya
.Ed. (Title page): S.V. Kostina, Candidate of Technical Sciences, Docent;
Ed. (Inside book): S.I. Bumshteyn, Engineer; Ed. of Publishing House:
S.I . Vinograd5kaya; Tech.: V.I. Oreshkina; Managing Ed.: A.S.
Zaymovskaya, Engineer.
PURPOSE: This book is intended for engineers working in the field.of electric
and hydraulic servomechanisms,, and for students taking courses at electronic
and aeronautical institutions of higher learning.
COVERAGE: This book contains. four articles on problems of stability and dynamic
accuracy of electric and hydraulic servamechanisms. A studf is~ made of the effect
Card 1/2
D th e
r
the 11 47e
.pt. Ch
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TOLMACHEV, Aleksandr Innokentlyevich, prof.; BDRISOVA N A kand.
biol. nauk
(General directions for plotting maps of the areas of medicibal
plants and the distribution of their concentrations. Methodical
directions for estimating the resources and plotting maps of
the distribution of medicinal plants)Obshchie ukazaniia o po-
riadke provedeniia raboty po sostavleniiu kart arealov lekarst-
vennykh rastenii i razmeshcheniia ikh zaroslei. Metodicheskie
ukazaniia po uchetu zapasov i sostavleni# kart rasprostraneniia
lekarstvennykh rastenii. [By]N.A.Borisova. Leningrad, Leningr.
kbiziko-farmatsevticheskii in-t, 1