SCIENTIFIC ABSTRACT BRILKINA, T. G. - BRILLIANT, O.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000306920010-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 9, 2000
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

F'RILKIM) T. 6,
Dissertation: "Investipration. of Organic Doron
Gomple,.-.ec of U~Te M (BRIO. " Cane
Chem Sci, Gorlkiy State U, Gorlkiy, 1954. Referativnyy
Zhurna.1--Ijli--iy'a,, ]-'oscowjp
No 8, Apr 54.
SO: SUM 284, 26 Nov 1954

O
T

P
"i

,
'

':
and Ph 11 flo-14-(38111 yield
tn
WE V '(C4R 0) 1*
I,
(state univ, b0ki) Air - Obikkel
r. 6. DrjjLina
and
Khi#1-nn4I"(1Q14V cf. CA. 48, 31:9Y.-Aadiii of 30
.
,
1he ai.-solo. contained MR. Refluxingig-kRcall,~-
'

tul. 0.3N Afell in 1340'undtr A, to 2.4 g. Ph.13in 9110
Pha In
MOMO-FrOlf 2 bra. gave A basIc solij. which licide
d
nod PhOlf
N11j
(Cii1l,)M~ with 75
HeIft 3 g
L%vc after rvapn. a cryst. residue of _LijBPAMe). which
decomposes on.expmdrt to air; soln. in H:O yields some
.
.
~
ditJ 25 ftd. 140 5 Irs. At teflux Jpvej
Pbjtand gives a basic soln.;
fresh 2q. 901nS. gave no rPtS.'
't. CjoHs and 1.1 f. 1%bMis. along
iflill sorne MIA.
gimilat re-ictloit a klWh4e
if
life-p) kave pa Mcph
with Kor NIH, salts.botcas piolongLd standing
ppts. furtned;:..
'
s
,
f
and sonte PhOll. gitnitar tenet To
Pit gm C

thus NAIDA41. was obtained. sTmetritatirm a the
sta
comple2 accounts ter formaVY)a of is sub nce SIMI-
j
In 4bh. aloublMoll, groups as Cj.IH4, aiong with plienyl-

'
larly, 5.54 0. (I-CtMi)X2C&Ho in EtO and 1.15N EtLi in
'
boricadd, To3.0g.kllPhin~tlryMeOHginl.1.252IDrs
1.
In WOH was added; Win. with H:O give 1.6 g. PbDr
t., which after
vacuum drying yiMed
f thi
A
l
tr
ted
t
bl
Li
i
C
ff
Vj
3F
)
.
g. Phi I if phenylboric acid. Similar reaction of LiDPh,- -
-uns
-
n. o
ea
a
e
an a
r
q. so
s
,
w
j
&
f
with KCJ or NH.Cl gave nftt-- several hrs. a ppt. of the CM-
Citf4ii"
;Ath Brs In aq. soln. gave P-BrCoM Me (S00")'

d
K

responding K or NH4 salt;_ only N11.11)(C.F10.1 was 2n&
and
iphenylborle acid, Ilturntnatlan of 3.5 C. RE
gave snme r
H
Ph
and PhOH
In ClIC4 IOR hr*
To 4;
lyzed. - Mating 5 g. YJJPh with 80 mi. EtOCJ1sCHs0H
.
.
o,
i
#
g. KBPho in dry MejCO 7.3 S dry PeCl was added. The,
and 20 tal. 11%0
&-7 hrs.. followed by stem distn. of C no
n
mixt
5 hr
heated 0
gave on ~9
64% Us (based on losy:
.
gave AcIf aud PhOH, along with crude diphenylboric ai
Similar reaction of NUMPhs gave a low of I-T1h group
:
.
.
.
.
oup .8
of I Ph gr ), I g
~dPfi yibo~c eid; the solu.
=d
~ K
1
G
f
en
di7.
M) In 2 hrs,-,. the aq. residue tained PhOR and
R
-
c 3
tells
or
J
fe
o_1WM9_;1

'D
phenylboric atid. Aealans NU

6dea tyke 0 h-, .100' tave
it

67 3 .2 o o &Z. T.~
1,97 0 ? 04D Cg) SOV/81-59-5-15249
Translation from: Referativnyy zhurnal, Khimiya, 1959, Nr 5,
p 167 (USSR)
AUTHORS: Razuvayev, G.A, Brilkina T.G.
TIMt An Investigation of A-IRleactions of the M[BR 41
complexes
PERIODICAL. Uch, zaD. Gor'kovsk. un-ta 1958, pp 169 - 173
ABSTRACTs It is shown that when Li[B(C H_5)4]2LiBr (I)
interacts with Hg in
%'-L -type
C
HC1 C6H'- HgCl is formed, w0h proves that the M[B(C6%t)41
compl' coW~ounds are capable of reaoting with Bg with t e
ex
formation of only one free radical from the elementorganic
anion.
NH4[B(C6H5) ClOH71 (I!) and K[B(%~)3 ClOH 71 (111), when
reaoting
with Hg in -dinaphtby mercury, which, in addition
&C13 form Ck V
to the absence of phenyl derivatives of mercury, points to the
primary break of the naphthyl. radicals from the complex
anions
studied. The thermal decomposition of II at 120 - 1300C causes
the formation of naphthalene and tripherxyl boron ammoniate,
i.e.,
the mechanism of the thermal decomposition of the anion also
Card 1/2 takes place with the separation of one naphthyl
radical from the

SOV/81-59-5-15249
An Investigation of Free-Radical Reactions of the M[BR 41
Complexes
complex. II and III are obtained by their precipitation from
the aqueous
11
solu'ion of Li[B(C6H 10H which is synthesized similarly to I
(G. Wittig
5) 3C: g
and others. Liebigs Ann. em., 1949, Vol 563, p 110), with the
addition of
NH4Cl or KC1. respectively.
V.A.
Card 2/2

88569
S/020/61/136/001/017/037
B0161BO55
AUTHORS, Aleksandrov, Yu. A., Brilkina,_11_.G., and Shushunov,
V. A.
TITLE: Bistriethyl-lead Oxide
PERIODICAL: Doklady Akademii nauk SSSR, 1961, Vol. 136, No. 1,
pp. 89-92
TEXT. Bistriethyl-lead oxide,((C H ) Pb) 0, was synthesized
with a view to
2 5 3 2
establishing its properties and studying it in detail. In an
earlier work
the authors had found that bistriethyl-lead oxide has a marked
accelerating
effect on the oxidation of hexaethyl dilead by oxygen. They
assume this
effect to be due to free radicals formed by decomposition of
bistriethyl-
lead oxide. Basing on their own results, they state that this
compound has
never actually been obtained by other researchers (Refs. 2-4),
since
bistriethyl-lead oxide hydrolizes in alcoholic and aqueous
solutions. The
authors therefore applied a different method: They dispersed
metallic
sodium in n-nonane, removing the n-nonane thereafter by
decanting and
distilling off, and then poured on dry benzene. To this mixture
they added
a triethyl lead monohydroxide portion so calculated that sodium
was well
Card 1/3

88569
Bistriethyl-lead Oxide S/02o/61/136/001/017/037
Bo16/BO55
in excess. In the course of 2-3 h triethyl lead monohydroxide was
trans-
formed into bistriethyl-lead oxide which is readily soluble in
benzene.
After filtering off the solid residue, and distilling off the
benzene,
bistriethyl-lead oxide was obtained as mobiley faintly
yellowish-green
'liquid with a sharp specific smell. At room temperature,
bistriathyl-lead
oxide hydrolizes to triethyl lead monohydroxide (to an extent of
98-99%).
Alcohols and tertiary alkyl- and aryl hydroperoxides act
similarly to
water, transforming the bistriethyl-lead oxide to oxy- or peroxy
compounds
of triethyl lead, besides triethyl lead monohydroxide. At
temperatures of
only -100C, several of these reactions occur at an appreciable
rate. The
authors studied the effect of methyl-, ethyl- and benzyl alcohol,
dimethyl-
phenyl carbinol, tert-butyl-and a-isopropyl phenyl hydroperoxide
on
bistriethyl-lead oxide. The following compounds were obtained:
ethoxy
triethyl lead, terto-butoxy triethyl lead, a-isopropyl-phenyl
peroxy
triethyl lead, methoxy triethyl lead and a-isopropyl-phenoxy
triethyl lead.
The organic oxy- and peroxy compounds of lead are unstable and
decompose
gradually at room temperature in sealed ampoules, accompanied by
a color-
change to redbrown. Bistriethyl-lead oxide reacts vigorously with
acetone
at room temperature, under formation of triethyl lead
monohydroxide. In
Card 2/3

Bistriethyl-lead Oxide
88569
S/020/61/136/001/017/037
B016/BO55
the presehoe of a great excess of acetone, mesityl oxide and a
resin which
was not further investigated were formed. On heating,
bistriethyl-lead
oxide-decomposes comparatively rapidly with liberation of an
equimolecular
mixture of ethane and ethylenep and 1% butane. The residue is
tetraethyl
lead (Ref. 7). There are 2 figures, 1 table, and 7 references: 2
Soviet,
2 German, 2 US, and 1 British.
ASSOCIATION: Nauohno-issledovatellskiy institut khimii pri
Gortkovskom
gosudarstvennom universitete im. N. I. Lobachevskogo
(Scientific Research Institute of Chemistry of the GoilkiY
State University imeni N. I. Lobachevskiy)
PRESENTED: July 4, 1960, by M. I. Kabachnik, Academician
SU13MITTED: July 4, 1960
Card 3/3

S/030161/000/004/013/015
B105/B206
AUTHORS: Razuvayev, Q. A., Corresponding Member AS USSR,
Latyayeva,
V. N., Candidate of Chemical Sciences, Brilkina, T. G.f
Candidate of Chemical Sciences
TITLEt Homolytic reactions in the liqixid phase
PERIODICAL: Vestnik Akademii nauk SSSR, no- 4, 1961, 124-127
TEXT: The first simpozium po gomoliticheskim reaktsiam v
zhidkoy faze
(Symposium on Homolytic Reactions in the Liquid Phase) held in
Gorlkiy and
Dzerzhinsk from December 7-10, 1960, is described. The
Symposium which was-i
attended by about 500 chemists, was convened by the Nauchnyy
sovet po teo-
rii khimicheskogo stroyenJya, kinetike i rigaktsionnoy
sposobnosti Otdele-
niya khimicheskikh nauk Akademii nauk SSSR (Scientific Council
for the Theo-
ry of Chemical Structure, Kinetics and Reactivity of the
Department of
Chemical Sciences AS USSR), the Gor1kovskiy
nauohno-issledovatel'skiy insti-
tut khimii (Gorlkiy Scientific Research Institute of
Chemistry) and the ob-
lastnoye otdeleniye Vaesoyuznogo khimiohesl:ogo obshohestva
im. D. I. Mende-
leyevs. (Rayon Department of the All-Union (.11hemical Society
imeni D. 1. Men-
Card 1/5

S/030161/00()/004/013/015
Homolytic reactions ... B105/B206
deleyev). The following reports are mentioned: By the method of
electron-
ic paramagnetic resonancep V. V. Voyevodskiy clarified the
structure of ben-
zene chromate cations as well as the aromatic ionic radicals, and
establish+_
ed the formation of hydrogen atoms during the irradiation of the
system Fe
+H2S04+H20 at 770K by means of ultraviolet light; M. B. Neyman,
A.L. Bucha-
chenko reported on the formation of stable radicals which can serve
as basis
for the determination of active, short-lived radicals; A.IL
Terenin, B.L.Kur-
batov, R.F. Vasil I yev, A. A. Vichutinskiy, a N. Karpukhin, L. M.
Postnikov, and
V.Ya.Shlyapintokh reported on the method of chemiluminescence; K.S.
BagdasarL
yan, R.L Milyutinskaya, E.A. Trosman, and V.A. Borovkova
investigated the
reactions of the phenyl- and nitrophenyl radicals with aromatic
compounds by
the kinetic method; V. F. Tsepalov foundan expression for the rate
of con-
sumption of an arbitrary component as function of the concentration
of reEe-
ing substances; I M. Emanuel' discovered the dependence of the
oxidizing of
liquefied hydrocarbon on the concentration of the solvent; F. M.
Emanuel',
E. K. Mayzus, and I. P. Skibida reported on the production of
alcohols and
ketones according to the chain- and molecular method of the
oxidation of
n-decane; B. V. Yerofeyev reported on complementing the previous
theory of
primary initiating by a secondary initiating$; K. I. Ivanov and Ye.
D.
Card 2/5

S/030 61/000/004/013/015
Homolytic reactions ... B105%206
Vilyanskaya showed that aniline added to an oil already in a
state of oxida-
tion is converted into a product behaving similar to a peroxide
radical which
accelerates the reaction; B. A. Redoshkin and.V. A. Shu.9hunov
showed the
dual effect of metal salts of variable valenoyj A I..
'Alichachenko, M. 'P.
Neyman, and K. Ya. Kaganskaya determined the average xifetime
oi peroxid.
radicals of trimethyl heptane (3.5 see); I. V. Berezin, K.
Vatsek, Go Chu,
and N. F. Kazanskaya classified a number of free radicals
according to their
kineti'd'indices; Ye. N. Gurlyanova, 1. G. Chernomorskaya, and
M. S. Felld-
shtdyn discovered the direct dependence between exchangeability
of the
compounds S-S, S-N, S-C and their vulcanizing activity; G. A.
Razuvayev,
0. G.Petukhov, Ye. V. Mitrofanova, and V. N. LatvavPva showed
that the use
of isotope methods permits the discovery of new reactions
during the oxida-
tion of organometallic compounds, which cannot be determined by
other meth-
ods; V A~ Shusblinnv, Yu. A. Aleksandrov, and T. G. Bri.lkina
submitted a
scheme of the oxidation process of the organometallic compounds
investigated,
N. S. Vyazankin, G. A. Razuvayevy Yu. I. Dergunov, and 0. A.
Shchepetkova
reported on the homolytic cleavage of elementary compounds;
Yu..A. 011dekop
and N. M. Mayer reported on the mechanism of the homolytic
synthesis of
organometallic compounds; N. P. Khyrak and V. A. Pallm reported
on the homo-
Card 3/5

S/03o/61/000/004/013/015
Homolytic reactions ... B105/B206
lytic character of the formation of organomagnesium compounds,
A. V.
Savitskiy and Ya. K. Syrkin reported on the spectrophotometric
investigatioris
which were utilized for determining the thermodynamic indices of
the oxida-
tion reactions of ferrocene and rutheniumcene by means of
iodine; G. I.
Nikishin and V. D. Voroblyev reported on the linkage of the
alcohols C 5- C10
to a-olefins of the composition 0 6-C ; G. 1. Nikishin, Yu. N.
Ogibin,
and A. D. Petrov reported on, esters 19f dicarboxylic acias
which are linked
to y-olefins unde-r formation of esters of a-alkyl
carboxylic.acids; G. A.
Razuvayev and L. S. Boguslavskaya reported on the production of
glycol
esters; M. G. Gonikberg and V. M. Zhulin report'ed 'on the
production of an
unstable polymer at a pressure of 5000 kg/cm2,_which is
depolymerized at
customary pressure; A. P. Meshcheryakov and.l. Ye. Dolgiy
reported on the
production of substituted cyclopropane derivatives by addition
of methylene
radical and its derivatives on alkenel A. N. Nesmeyanov, R. Kh.
Freydlina,
V. N. Kost. M. Ys:. Khorlina, T. T. Sidorova, R. G. Petrova, and
A. B.
Terentlyev arranged the investigated radicals according to their
relative-
stability; M. F. Shostakovskiy, Ye. N. Prilezhayeva, and L. V.
Tsymbal re-
ported on heterolytic reactions of the additions which are
strictly subordi-
nated to the rule of transaddition; G. M. Strongin reported on
the conforma-
Card 4/5

8/030/61/000/004/013/015
Homolytic reactions ... 3105/B206
tion of products of the homolytic addition of chlorine on
benzene. The
delegates of the Symposium expressed the wish to discuss
regularly chemical
problems connected with the homolytic reaction in the liquid
phase.
Oard 5/5

S/081/0/000/1019/032/085
smoo BI *.O/B138
AUTHORS: Aleksandrov, Yu, A.,_Jrilkina, T. G., Shushunov, V. A.
TITLE: Oxidation of organometallic compounds, 3.. Synthesis and
some properties of triethyl lead oxide
PERIODICAL: Referativnyy zhurnal. Khimiyaj no~ 19, 1961, 145,
abszract
19Zh44 (Tr. po kbimii i khim. tekhnol. (Gorlkiy), no. 3,
1960, 381-387)
TEXT: The oxide of triethyl lead (I) was obtained by reaction of
disperse
metallic Na with triethyl lead monohydroxide (II) in benzene.
Idecomposes
at rj 200C, reacts vigorously with acetone and acetaldehyde, and
reacts
instantaneously with water to form 'JI quantitatively. When
reacting with
methyl, ethyl, benzyl, and a,a-dimethyl-benzyl alcobolsi as well
as with
hydroperoxides of tert-butyl and a-cumyl, I gives the
corresponding oxy
and peroxy derivatives of triethyl lead, which are unstable at
-1200C.
The rate of thermal decomposition of ! at 70-900C without solvent
was
studied. The products obtained consist of an equimolar mixture of
C H and (with an impurity of 1-1.5 % of butane), 0.97 mole of
2 6 C2H4
Card 1/2

30206
8/081/61/000/0)~)/032/085
Oxidation of organometallic ... B110/BI;8
triethyl lead per mole of used I, and a solid substance
containing 87.1
of Pb, which is insoluble in organic solvents. The authors
assume that
the accelerating effect of I on the oxidation of hexaethyl
dilead by 0 2
in n-nonane solution is caused by the ability of I to
decompose with
the formation of ethyl radicals, whereby a degenerate ohain
reaction is
effected. For Report 2 see RZC, 1961, BZh231., LAbstracter's
note:
ComDlete translation.]
Card 2/2

S/081/61/000/024/011/086
Y7 00 B138/B102
AUTHORS: Aleksandrov, Yu. A., Brilkina, T. G., Shushunov, V. A.
TITLE: oxygen oxidation of distannio ethide, diplumbic ethide
and
tetraethyl lead
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 24, 1961, 75,
abstract
24B541 (Tr.lr khimii i khim. tekhnol., IGorlkiy no. 1,
1961t 3 - I
TEXT: The oxidation of distannic ethide (I), diplumbic ethide
(II) and
tetraethyl lead (III) by oxygen was studied in solutions of n-C
9H20 and
06H3C13 at 50 - 90 0C. Additions of triethyl-tin peroxide cause
considerable acceleration of oxidation cfIalthough the initial
increase
is not sustained, the reaction rate returning to normal in the
course of
time. The products of oxidation of I are tin diethyl oxide, tin
triethyl
oxide, CH3CHO and H20. Activation energy of the process is 19;5
kcal/mol~
In oxidation of II lead oxide, 111, 02 H5OH, CH 3CHO) and H20
are formed.
Card 1/2

S/081/61/000/024/011/086
Oxygen oxidation of distannic... B138/BIO2
The dependence of oxidation rate of II on temperature and initial
concentration is of a critical nature. Considerable variations
in the rate
of the process are observed with very slight (6o to 62-5 0C for
instance)
variations in these Darameters. Additions of lead triethyloxide
accelerate
oxidation of II, and additions of H20 retard it. C 2HV C2-H4,
C4H10 , CH3CM
1120, the 1-hydro-2-oxide of triethyl lead, the 2-hydro-2-oxide
of diethyl
lead, and the mono- and dioxide of lead are formed in oxidation
of III.
Addition of solid,oxidation products considerably accelerates
oxidation of
III. [Abstracter's note: Complete translation.
Card 2/2

ALEKSAMROV, YU.A.; 4UMU. T,G-. SHUSMiNOV. V.A.
TriethYllead oxide. Dokl,AN SSSR 136 noal:89-92 ja 161.
(MM 14: 5)
1. Nauchno-isoledovateltakiy institut khiTnii pri
Gorlkovskom goau-
darstvennom universitat itu N.I.Iobachavokogo.
Predstavleno aoAemikom
M.'I.Kabachnikom* M
(L46ad compounds)

32431
S/020/61/141/006/017/021
B103/B147
kS_j?00
AUTHORS: Shushunov, V. A., and Brilki
TITLE: Regrouping of some organotin and organolead peroxide
compounds
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 141, no. 6,
1961, 1391-1394
TEXT: The regrouping of Sn and Pb peroxide compounds was
studied. Since
the monohydroxides of trialkyl and triaryl tin are strong
bases, they
react readily with peracids to form the relevant
organometallic compounds:
ROO RIO
i I
Rl-Sn-OH + RCOOOH Rl-Sn-OOCOR + H 20 (4). Such a compound can
be
I
'Rill R"! ROO
regrouped similarly to: RI-6-OOCOR --> RIOXOCOR (1). The
product
I I
RIO I Rill
formed is hydrolyzed with separation of the relevant
organometallic oxide
and other oxygen-containing compounds. A homogeneous reaction
mixture
of equimolar quantities of triphenyltin monohydroxide with a)
peracetic,
Card 1/5

32La
S/020/61/141/006/017/021
Regrouping of some organotin and ... B103/B147
or b) perpropionic acids at OOC was kept in the dark at room
temperature.
Within 40 - 50 hr, the peroxide compounds in the solutions
were completely
consumed and gradually well-defined needle crystals were
precipitated
without gas liberation. In cases a) and b) they were insoluble
in cold
and poorly solubl8 in hot benzene. In case a) it was a
non-meltable
product up to 230 C, in case b) the product could be softened
at 1700C
and formed a non-melting compound on further heating. Acid
hyirolysis
resulted in the formation of free acetic and propionic acids,
respectively.
On the basis of their quantities and the amount of (C 6H 5)2
Sn(Off)CI
(melting point 18500) formed on heating of the precipitations
with HC1,
the formation of (C6H 5)2 Sn(OH)OCOCH3or (C 6H5)2 SnO-(C6 H5)2
Sn(OCOCH 02 L/f/
is assumed in the regrouping. The yield was 72% in case a) and
45% in
case b). A considerable quantity of finely crystalline
substance9 0
insoluble in water but soluble in methanol, (melting point 128
- 130 0)
was obtained by alkaline hydrolysis of the alcohol-dissolved
compound;
under the effect of HC1, this substance is converted to (C
5F6)2 Sn(OH)Cl.
In both cases, 90% of phenol (related to the hydroxide) was
isolated
after seuaration of the solid products and the unreacted
initial hydroxide.
Card 2/5

3 h_3 1
8/020/61/141/006/017/021
Regrouping of some organotin and ... B103/B147
This is explained by
C'H'O - OCOR + H30 - AW, Sn (OH) OCOR + C,HjOH (5)
~H,
CBHS
COH60 - Sn - OCOR + CHzOH (wia)j'Sn (OCHa) OCOR + CHaOH (6)
~H&
,The same reaction was performed with (A triphenyl lead monohydroxide
Lind a) in a) methanolt d) dioxan sulfuric ether; furthermore
with (B) triethyl lead monohydroxide ivith a) and b). In a) the
filtrat*e
resulting from precipitation and filtering of the scanty diphenyl
lead
oxiae precipitate was treated with aqueous alkali. A white
precipitate
formed from which phenol was isolated (yield W/o, here and later
related
to initial A or B). By boiling methanol, the water-insoluble
precipitate
was'separated into A and diphenyl lead oxide (C). Total yield in 0
from
the r6abtion mixture: 35% of the theoretical value. A reacted slowly
with a) in d) owing to its poor solubility. Nevertheless, 40% of
phenol
C.ard 3/5

3201
S/020/61/141/006/017/021
Regrouping of some organotin and... B103/B147
was isolated after long standing in the dark at room temperature
and
subsequent heating for 3 hr at 500C or for I hr at 700C.- A was
not
completely consumed. The reaction of a) in e) was impeded by the
poor
solubility. Also in this case, a compound was dissolved after 2
hr of
shaking, which yielded phenol 0%) after hydrolysis. A slight
quantity
.of gas escaped in the initial stage of the reactions in d) and
e). The
result-s were less clear-in gase B with a) and with perbenzoic
acid. On
standing for 36 hr, at 10 C the peroxide compound was slowly
regrouped.
Snow white large crystals of triethyl lead acetate were
precipitated
(melting point 156 C, yield 75%). B reacted with a) in aqueous
solution
rather rapidly at room temperature with slight gas liberation.
After
24 hr standing in the dark, no peroxide oxygen was found, but
acetaldehyde
(Pwirg to oxidation of ethanol) as well as tetraothyl lead (owing
to
disproportionation of triethyl lead acetate or diethyl lead
diacetate).
The reaction of B with perbenzoic acid in e) was similar to that
with a).
After standing for I hr at,-20 to -10 0C and subsequently for 12
hr at
room temperature, no per8xide oxygen was found. Triethyl lead
benzoate
(melting point 125 - 127 C, yield 35~) was isolated from the
solution.
Moreover, a readily water-soluble organolead compound formed
which was
Card 4/5

32 431
Regrouping of some organotin and...
S/020/61/141/006/017/021
B103/B147
not further investigated. A water-insoluble precipitate,
diethyl lead
dibenzoate (melting point 1620C), precipitated from its
aqueous solution
after long standing in air. There are 14 references: 3
Soviet and 11
non-Soviet, The three most recent references to
English-language
publications read as follows: P. D. Bartlett, D. M. Simons,
J. Am~ Chem.
Soc., ~2, 1753 (1960); E. Buncel, A. G. Davies, J. Chem.
Soc., 1958,
1550; R. K. Ingham et al. Chem. Rev., 60, 460 (1960).
ASSOCIATION: Nauchno-iseledovatellskiy institut kbimii pri
Gor1kovskom
gosudarstvennom. universitete im. N. I. Lobachevskogo
(Scientific Research Institute of Chemistry of the Gorlkiy
State University imeni N. 1. Lobachevskiy)
PRESENTED; July 13, 1961, by M. I. Kabachnik, Academician
SUBMITTED: July 12, 1961
Card 5/5

BRILKINAP'T*Go; SAPOINOVA., M.K.; S UIUNOV., V.A.
~,'V
Triphenyl lead omide. 7b ob.kbinie 32 no.8:2684-2~86
Ag 162.
kgm 15:9)
(I-6ad compouzide)

ACCESSION NR: AT4028346
S/0000/63/000/000/0291/0297
AUTHOR: Aleksandrov, Yu. A.; BjLjkLR&,2._G.,;- Shushunov, V. A.
TITLE: Soma tin and lead orgaiie peroxide compounds
SOURCE: Soveshchaniye po khimii perekisny*kh soyedineniy. Second,
Moscow, 1961.
Xhimiya perekisny*kh soyedineniy (chemistry of peroxide compounds);
Doklady*
~soveshchsniy. Moscow, Izd-vo AN SSSR, 1963, 291-297
TOPIC TAGS: tin, lead, peroxide, tin organic compound, lead organic
compound,
,peroxide compound, metal-organic compound,, metal-organic peroxide
~ABSTRACT: Results of the investigation of some properties and
reactions of triethyl
tin peroxide, tert-butal triethyl lead peroxide, a-cumyl triethyl
lead peroxide,
di-tri-ethyl lead-n-di-isopropobenzene diparoxide, as-wall as
triphenyl-tin-peracetate
and triphenyl-tin-perpropenate, triphenyl-lead-paracetate,
triethyl-lead peracetate.
and triethyl-lead perbenzoite are related in this article. The
peroxide compounds
were easily hydrolyzed by water with the formation of tridthyl-tin
mendhydroxide~
(or triethyl lead monohydroxide) and hydrogen peroxide (or the
corresponding hydro-
:peroxide) at room temperature. The results of the analysig.are
presented in a table.
~The above mentioned compounds were produced, precipitated, and
characterized for the
Card 1/2

'ACCESSION NR: AT4028346-'
first time. The thermal decay of triethyl tin peroxide
andits,reaction with hexa-
ethyldi-tin in a n-ionane soluti6n was investigated. Definite results
were obtained
Yhich indicate the decay of triphenyl. tin-peracetate and triphenyl
tin parproponate,
oas well as triphenyl lead perAcetate by means of regrouping. Orig.
art. has: 3
formulas, 6 figures and 1 table.
'ASSOCTATION: Gor'kovskiy gosudarstvanny*y universitat im.%.I.
Lobachevskogo
.(Gorky State University)
:SUBMITTED: 13Dec63 DATE ACQ: 06Apr64 ENCL: 00
'SUB CODE: CH _J
-No REP SOV: 011 OZER: Oll:
Card 2/2

TI
L 318-67 EW,(J) /-EW"rW /EW~(t) I-E -IJP(c) %M/WW/JD
Xt AJM6021382 ~bnograph UR/
Brilkina, Tamara Grigorlyevna; Shushupov, Vasiliy Alekseyevich
ith hydroge And peroxi s V (Reaktsii metallo-
Reactions of qrRanometallic compounds de
ogranicheskikh soyedineniy s kislorodom 1 perok syami) Moscow,
Izd-vo "Hauka,"
a966. 265_,p.. biblio. (At head of title: Akademiya nauk SSSR.
Otdeleniye obBhchey
i tekhnicheskoy khimii) Errata slip inserted. 3300 copies
printed./
TOPIC TAGS: organometallic compound, group I metal, group II
metal, group III metal
group IV metal,'.organoboron compound, organosilicon compound,
reaction with oxygen,
reaction with peroxide
PURPOSE AND COVERAGE: This book is a review of studies on the
reactions of oxygen
and peroxides with organometallic compounds containing metals
of groups 1, 11, 111
aidIV. Reactions of organoboronjand organosilicon1compounds are
included. Chapter
5 reviews the reactions of oxygen and peroxides with
organometallic compounds con-
tainingdifferent metals Me'-Me" and Me'-C-Me" bonds, designated
as compounds of
-class 1 and class 2, respectively. Chapter 6 reviews the
reaction mechanism of
oxygen and peroxides with various organometallic compounds.
There are 210 Soviet
End60qWestern references. The references are given at the end
of each chapter.
TABLE OF CONTENTS [abridged):
Introduction -- 3
UDC; 547.1'

ACC NRs Am6021382
0
Chapter I. Reactions of oxygen and peroxides with
organometallic compounds con-
taining metals of Group I -- 10
Chapter II. Reactions of oxygen and peroxides with
organometallic compounds con-
taining metals of Group II -- 50
Chapter III. Reactions of oxygen and peroxides with
organometallic compounds con-
taining metals of Group III -- 97
Chapter IV. Reaction of oxygen and peroxides of
organometallic compounds con-
taining metals of Group IV -- 143
Chapter V. Reactions of oxygen and peroxides with
organometallic compounds con-
taining atoms of different metals -- 232
Chapter VI. Reaction mechanism of oxygen and peroxides with
organometallic com-
pounds -- 243
SUB CODE: 07~ SUBM DATE: 15Jan66/ ORIG REF: 219/ aTH REF: 6oo
kh

- - - - - - - - - - - - - - -
L 10803-67 EWT(m)/EWP.(J)---R~V-W-
ACC NRt A137003493
SOURCE CODE; UR/0074/66/035/008/1430/1447
i AUTHOR: Brilkina, T. G.; Shushnov, V. A*
ORG: State University, Gortkiy
TITLE: New developments
compounds
SOURCE: 11pakhi khimii,
In research on the oxidation%f or
v. 35, no. 8, 1966, 1430-1447
TOPIC TAGS: organometallic compound, peroxide
ABSTRACT: The synthesis, properties, and reactions of
organorrictallic compounds
are currently subjects of intense interest, in view of their great
theoretical
and practical importance. Much of this interest has been centered
upon the
reaction of such compounds with oxygen, and since it has bean
demonstrated that
such a reaction is accompanied by the formation of organometallic
peroxides, !
attention has also been centered upon the reactions of various
peroxides 'with
o
r ranometalli- c cor
t, pounds. The authors survey tlha general pr:biciples and mochan i
Pas and specific examples of the oxidation of arganonot allic
compounds by
oxygen, as well as the Keactions-.of organometallic cop,2ounds with
organic and
Lnorearnic. Peroxides - LJPRS t 38t979 Orig.
SUB CODE: 07 / SUBM DAVt none / ORIG REF: 076 / OTH RZFt 092
UDC: 547.24:547.438
.ard 1/1'/ ----

BRILL.A.
The adartation of the natural uas cementation process in
our metallurgical
plants. MALURGIA SI CONSTRUCTIA DE MASINI (Metallurgy and
Machine Construction.)
2:26:Feb 55

BRILL. A.; BUMONSOU, V.
'
Notes on action of streptomycin. Gruxlioa 20:6 Suppl.
2:117-119
1952. (OLML 24:2)
1. Brill, A., Acting Director of the Institute of
Tuberculosis,
Bacarest; Bombacescou, I., Director of the bwtitute of
Tuberculosis
Branch in I"i.

BRILL, A..; BUMBACESCU, N.
Observations on thiosemicarbazonee. Gruslica 20:6 Suppl.
2:119-120
1952. (GLKL 24:2)
1. Brill. A.. Acting Director of the Institute of
Tuberculosis,
Bucoxest; Bombacescou, N., Director of the Institute of
Tuberculosis
Branch in Usi.

BRILIg A.; CIMM, I.
Apbulatory consolidation treatment of tuberculous
patients having
renumed work; prevention of relapses. lb-nnian M. Rev. 1
no-3:43-45
Jul,Y-Sept 57,
(TUMCUIMIS, FUIMNART, ther,
ambulatory ther. of patients returned to work, prev,
of relapees) -

RUMANIA / Pharmacology, Toxicology. Chemotherapeutic V
Agents, Antituberculous Agents.
Abs Jour: Ref Zhur-Biol., No 18, 1958, 85256.
Author :-Brill, Aj, Baicoianu, S., Bungetianu, G,,
Butnaru,
-D7.7-Buzemuu-, M., Herscovici, A~
Inst : Not given,
Title : The Treatment of Pulmonary Tuberculosis with
Cyclo-
serine.
Orig Pub: Ftiziologia, 1958, Vol 7, No 1, 25-30.
Abstract: 25 patients with bilateral chronic
ulcero-caseo-
cavernous tuberculosis of the lungs, with complete
or partial resistance to tuberculostatic prepara-
tions' were treated for 3 months with cycloserine.
As the result of the treatment, there was clinical
improvement (weight, fever, cough, sputum) in all
patients. Slight changes in the X-ray picture
Card 1/2

RU14ANIA / Pharmacology, Toxicology. Chemotherapeutic
v
Agents, Antituberculous Agents.
Abs Jour: Ref Zhur-Biol., No 18, 1958, 85256.
Abstract: were noted in six patients, arid
disappearance of
bacilli in the sputum In 10. In 3 patients there
were changes also in the EEG. The authors recom-
mend treatment with cycloserine only in cases which
are hospitalized, and in which there is resistance
to other chemotherapeutic preparations. From the
authors' summary.
Card 2/2
58

BRILL, A.P conf.; CORNEA, P., dr.; IONESCU, I., dr.
Secondary effects of the treatrnent of tuberculosis
with tuborculo-
static subutanceso Mod. inter., Bucur 13 no.6:885-993
Je 161.
1. Din institutul do ftziologio.
(ANTITUBERCULAR AGENTS toxicology)

BRILM, D.Ye., prof.; ORLOV, Yu.M., inah,
Ifivestigating valves for marine automatic control systems.
Su~ostroania 29 no.70D-31 J1 163. (MMA 16:9)
(Marine.anginearing) (Hydraulic control)

BRILL$ Juliusz, prof. dr. ,
C--
Actual problems in animal pasteurellosee. Zoos probl
post nauk
roln no.33:3-10 161.
1. Xatedra Mikrobiologii, Wydzial WeUrynar7jnyp Szkols
Olowna
Gospodarstwa Wiejskiegoj Warszawa, Kisrowni)c; Prof,
dr. J. Drill

Bl= J-p SZYNMNIGZ Z,
Podloze vybiorese do hodowli mUslwwcow rovM rAn
(HWsipsle-
tbr-4-x rhusiopathine). CSOlective media for
&7siplsloUwlz
rhusiopatbias cutuif Modp, dowl, milcrob, 20-4 ig5o--
P. 4o7-
170
I* Of the Institate* of ML=-obl4o'~!'- 'And "IW of the
Ybdi*4
. . lar -
Facult6v of Wanaw Universi* id&bf the'Regional batitute
of 74terinary Flygiew in i,
OLML VOL 208 No, 10 Oct 1951

A1_3 I-
J'e
BRILL, J.; SZYNKI]WICZ, Z.
Selective substratum for the culture of Xrystpolothrix rhusio-
pathise. Med,wet. 6 no-9:516-517 Sepp"Q. (CLML 20z3)
l.'Of the Institute of Microbiology and Serology of the Veterinary
Faculty of Warsaw University and of the Regional Institute of Hy-
giene of the National Veterinary-Institute Br4ach in Lodz (RwA-
Prof.,Tulluez Brill,M.D.). I

BRILL,J.;GOL1BIOWSK1.jS.
Salmonella dublin vectors In cattle in the �ierads
districts
Mod. doew, mikrob.,.Wares, 4 no,.3:316-317 1952.
(GLML 23:3)
1. Summary of work progress presented at llth
Gongress of Polish
Microbiologists hold in Krakow May 1951. 2. Lodz.'

BRILL, J.;GALIS, A.
Studies on bacteriophaggs for Salmonella dublin in
foogg in O&ttlee
Ned. doew. mikrob., Warez..4 no- 3:317-334 1952,
(GLML 23:3)
1. Sumary of work progress presented at Ilth Gongres$
of Polish
Microbiologists held in Krakow May 1951. 2..Wareaws .

BRILL, J.;KIKUIASMM9 X.
Studies 0u antigea structure of Nrysipelothrix
rbusiopathias.
Red. doew. mikrob., Yarsts. 4 uo..3*-323-!-324
1952.,(CLKL 23:3)
1. Smsmary of work progress pr*s*nt*A at llth
Congress of Polish
Kiorobiologists held in Krakow May 1951. 2. Warsaw.

BRILL, J. j;ZnMI3WICZ, Z.
fu~~
Selective liquid culture media for ItryalpelothrIx
rhuslopathiae.
Xed. doew. m1krob*11 Wares. 4 no. 3t324-325 1952.
(OLKL 23:3)
1 Snumary of work progress presented at llth Congress
of Polish
;*Icrobiologiats hold in Krakow May 1951. 2. Warsaw.

Oyll IICGHOWSKA, S.
Classifloation of strains of Irysiplelothrix rhusiapathiae
according
to their hemaggl!itinatlon properties. Red. doew. mikrob. 5
no-3:291-292
1953. (CIML 25:5)
1. Warsaw.

I. ~~41 ~-TIWMIXV OWSKI, S.
Localization of Salmonella dablin in cowcarriers. Med.
dosw. mikrob.
5 no.3:295-297 1953. (OLML 25:5)
1. Lods.

BRILL, J..-WOYOMIECHOWSKA, S.
Culture of infectious abortion in horses virus on
hwaan amnion
transplants on chick embryo chorioallantole. Mod. dow.
m1krob.
5 no.3:346-347 1953. (CIML 251-5)
1. Warsawo

POIAND/Discaser, of Farm Animals - Diseases Caused
By Viruses R-2
and Rickettsiae.
Abs Jour : Ref Zhur - Biol., No 10, 1958, 45417
Author : Brill, J., Golebiawski, St.
Inst
Title The Evaluation of Serological Reactions in the
Flocks of
Poultry vith a Low -Percentage of Infection with
Salmonell
Pullorum.
Orig Pub Roczn. muk rolniazych, 1956, E67, Wo 3,
339-356.
Abstract No abstract.
Card 1/1
- 17 -

POIAND / Diseases of Farm Animals.' Disea-6es Caused by Viruses R
and Rickettsiaoi
Abe Jour Ref Zhur ~- Biologiya., No 2, 1959, No. 7441
Author Aleksandrovicz, Perkavska, E.
IM t Not given
Title The Yqelogram of Horses Sick with Infectious Anemia
Orig Pub Roczn. nauk rolniczych, 1956, E 67, No 4, 465-470
Abstract The blood picture was examined in some groups of
horses; healthy, naturally diseased and artificially
infected with infe 'ctious anemia (IA), suspected of
suffering from IA and suffering from various abcesses.
The corrolation of zyelocytes to reticular cells amount-
ed in healthy horses to 1*5 - 4. in horses nick with
IA arA in horses with abcossas to 1e The similarity of
changes in the bone maxrw which are observed in IA
and in aboosses of an unknown etiology does not permit
Card 1/2

USSR / Diseases of Farm Animals. Diseases Cauaod by Viruses
and Rickettsiao.
Abs Jour Ref Zhur - Biologiya, No 2., 1959, No- 744o
until death of the animals occurs. In chronic IA
processes, H quantity my become increased to 10 - 14
ana. more in 80 fields of vision depending upon the
resistance of the organism and the remoteness of the
completed relapses In other diseases H is only found
In cases of nuttalliosis, pneumonia and in surgical
processes; hemosiderocytes were absent in healthy
horses. -- L. S. Gobernan
Card 2/2
13

POLAND / Microbiology. Microbes Pathogenic to Man and F
Animals& General Problems..
Abe Jour Ref. Zhur _-Biols'j~Nof-21j 19581 No. 95117
Author Brill,' Jq'f4 Mikulaszek, E.; Truszozynaki, M.
Inst
Title immunochekoal. *Investigations into the Anti-
Senic-.Stru6ture.of.the Erysipeloid Bacterium.
Oris Pub Bull. Ac* ad.:-polon- 'ecl. y 7~1957p Cl., 2j
-5; 405-411
Abstract Autolysates,were prepared f rot the bacteria-
of
Exvysip~eloibkx. xhusiopathiae. type A by means of
repeated lYe -_ezing an,1_U_a_w_1_ng; a poly sap
oharide-
priot-ei-n.. and'p'-ol~sitcobAi~id6-fra--Ction were
obtained
fr6m'aut6l~sat6s aft 8'r-boiling the extrr_,.,L i.~i.a
1%. 14d6t1o_,aq1d,,and'by1 precipitation with alcohol
in.an,Acid.mediumi-:Nuol'eo-protein fractions vere
ob t-airied.'f ro.m'.badt eria -pre cipit at 6 6,
which re-
Card 1/3

POLAND / Microbiology. Microbes Pathogenic to Man and. F
Animals. General Problems.
Abs Jour Ref. Zhur - Biol., No. 21, 1958, No 95117
polyssacharide haptenes enter into the
tion of E, rhusiopathiae: one (FPF) represents
a specXt-Ic type of serological reaotiona of ml..
crobe connected with the protein and also en-
Uering partly into the nucleo-protein fractions
composition and the second (APF) which is freed
from the cellular membranes under the influence
of alkali.
Card 3/3

311114 J.; GOLIBIOVWSKI, S,./ /
0 1
lot Isolation 0 e auiR from swine in Poland, Acta ricrob. polon.
6 no.2-.115-132'195?.
1495 ? ~-
1. Z Wojewodakiago Zak"Ladu Itigieny Weterynaryjnej w 1,3dzi i
Katedry
Mikrobiologii Wydzalu Woteryraryjnego SGGW w Warazawic Idplynelo 20
lutego
1957 r.
(BRUCELL&
suis. 1st isolation from swine in Poland. (Pol))
(SWD13
1st lsola*ion of Brucella suis from suin in Poland (Pol))

mm--j j.-
J. Brill: I'SchweinesaImonellosen," Monatshefte fuer
Voterinae-nnedizin,
(Leipzig), 12/15, 1 '~ucllst 1957, PP. 400-412.
This -,as a paper delivered at the :,lain ~-Icatiiir of the
Scientific Socioty
for Veterinary 11-iodicine in the DDR (13-14 October
19,4,-',) in Leipzig. Tile
author's address is given as Poland, I,-.'arsza%-ia, u1.
Grochowska 2-72.

POLAND/Microbiology - Microbes Pathogenic for Man
and Animals. F
Drucellae
Abs Jour : Ref V%ur Diol., No 22, 1958, 99450
Author : Brill, Zaplebiowski, St.
Inst
Title : Complex Investi(Ation of a Brucellosis
Nidue
Orig Pub : Roczn. nauk rolniczych, 1957, E 68, No
1, 93-120
Abstract No abstract.
Card 1/1
- 92

7PT Tj.
-i I J.
"Diei~nosis o' the tlib-rculo-;-is. o'
p. (11 br)rn 4
iare. ZerniedelF!tvi. Vol. no.
.'rah,.
Mont.h3v InOex of Ir, Vol. 7, ~J, 11-111

I- BRILLP J.; POLITINSKA, E.; NOWICKIp A.; ADACH~ D.
(Warszawa)
The phages of Er7sipelothrix rhusiopathiae of swine.
Rocz nauk roln
wet 70 no.2/43259-261 160. (En, 10:9)
(swine) (Emipe:Las)

BRIIIP J.; POLITYSNKA, E.(Warazawa)
Lyeogeneeie in Brysipolothrix rhusiopathiae auum. Rocz
in-lik roln
I wet 70 no.1/4:261-262 f60. (Em 10:9)
(Swine) (Brysipolas) Mysine)

BRILLj, J.- prof. dr.; MIKULASZEK.. Z... prof... dr.
::4-~ Y
Results of the contest announced in 1958 by the
Microbiological
Cc=ittee at the II Department of the Polish Acadezy of
Sciences
and the Polish Microbiologists Society. Kosmos biol 10
no.6o.651-652
161.
1. Frzewodniczacy Polskiego Towarzystva Mikrobiologow
(for Brill)
2. Przewodniczacy Kmitetu Mikrobiologicznego Polokiej
Akademii Nauk
(for Mikulaszek)
(Microorganisms)

BRILL, -Tu:Liuigz; WOYCIEGHOWSKA, Staxiolawa;
MALICKI, Konrad
I I .
Cultivation of the infectious equine abortion virus
(Dimock) in
humv, amnion transplanted on ehisk embryo
shorioallantois. Mod.
dosw.inikrob. 13 no.105-41 161.
1. Z Oerodka Badania Ronienia. Zalmssego Klaezy I.
W., Warszawa
i z Katedry Mikrobiologii Wyds. Wet. SGGW, Warszawa
Kierownik:
prof. dr Jultuez Brill.
(VIRUSES culture)

BRILL, Juliusz, prof. dr
Introduction to the Symposium.. Ze5z probl post nau),
no.
460-10 164.
Slecord International Meeting on HemorrhRgio
Septicasmis. organized
by "k0 in Kuala Lumpur, Malaya, January 29-FebruarY 3,
1962.
Ibid.09-93
1. Department o4crobiology, Faculty of Vet'erinary
Madicine,
Central College 6' Agriculture, ldarsw4.

BRTLLIP OOD, -
~-- - ~
Gross sections of reactions of H93 with light nulle" IAd.
fiz. I no.It
55-60 ja 165. (MRA 180)

21 (8)
AUTHORS; Brill$, 0. D.p Sumin, Le Ve SOV/89-7-4-13/28
TITLE: The Excitation Curves of the Reactions B 11 (d, 2n)C
BeN" 20C 11 # B10(dp n)C11, and C12 (d, n)N 13
PERIODICAL: Atomnaya energiyap 1959, Vol 7, Nr 4, pp 377-379 (USSR)
ABSTRACTs The excitation curves were measuxed by employing the
pile methol
at the initial energies of 19.0 '1 0.2 Mey of deuterons and
38-5 t 0-4 MOV of CL-partiales. The foil piles were irradiated
by means of a beam emitted from a cyclotron. Piles of such
foils were irradiated with deuterons, which were produced from
a mixture of boron and polyBtyrenej the polystyrene serving as
a binding agent. Foils with a thickness of 5-10 MgIOM2 and a
boron concentration of 20-3qo were used. The energy of the
bombarding particles in the individual foils was determined
from the range-energy curves. The reduced activity of the foils
was measured by means of a Geiger counter under standardi2ed
conditions. After irradiation of the boron-polystyrene foils
with deutetonss the two half-lives 20-5 and 10 min were found
for the duration of the decay of the zraclei C11 and N13.
Card 1/3 These nuclei are produced in the follovving reactions on
boron

Me Excitation Carves of the Reactions B (dj 2n)0 SOV89-7-4-13/28
Be 9(04 2n)C 11 B10 (a, n)C 11 and C12 (d, n)N13
and carbon (which are contained in the foils):
11 11
(a) B (d, 2n)C Q - -5.0 Mev
(b) B10 (d, n)C 11 q - +6.-5 118V
(0) G12 (d, t)C 11 q - -12.5 Mev
(d) Q12 (d, n)N13 Q - -0 1.28 Nev.
The H13--nuclei are produced in the foils only in the reactiona
C12 (dt n)N13 I and therefore the excitation curve of this reaction
13 11
was determined by separation of the activities of N and C
with respect to the half-lives by-employing the method of least
squares. The relAi4e.- course of'the excitation curve of the
12 13
reaction C (d, n)N agrees with the results obtained by
D. Wilkinson (Ref 2). The second diagram shows the carve for the
activity yield. of C11 in a pile of boron-polystyrene foils.
At low deuteron energies the gurve has maximum, which
Card 2/3 corresponds to the reaction BIO(d, n)C. 1T , and shows an
increase

The Excitation
Curves of the Reactions B 11 (do 2n)C
SOV/89-7-4-13/28
2n)C 11
Bd(vL
-n)N13
n)C 11
B10 (d
and 012 (a
1
,
o
,
,

12 _11
at energies above the threshold of the reaction C (a, t)c

The 2
next diagrams show the excitation curves of th4

reactions B io
(do n)C 1ip-and B11 (do 2n)C'1after separation. At

low deuteron
energiesthe coarse of.the excitation curves

may differ
considerably from the'true curve because of the

great thickness
of the foils,ana because of the blurreaness

of th:6 deuteron beam
with resp"t to the energies. In the case

of an irradiation of
beryllium foils with cc-particles a ireak

activity with a
half-life of the ord er of 100 min is found

besides C 11
activity. The former may be'attributed only to

P18 (.r1 /2 . 110
MO. The authors thank H. A. Vlasav, S. P.

Kalinin, and A., A.
Ogloblin for their interest in the present

investigation. There
are 4 figures and 2 referencesi 1 of

which is Soviet.
SUBMITTED:
March 269 1959
Card'3/3

0 1
MESSBALM, RUDil F L. Dr6sebauer, Rudolf LIJ; BRILL$,
O.D. (translator];
SHO F.L.,red.
Reeonpnce nuclear adsorption ofy -quanta by solids
without
tO 0 UBP- fiz- nauk 72 no.4:658-671 D'60. (MIRA
13:11)
c 14
(Gamma rays)

PAUND, R-V-[Pound, R.V.]; BRILL'. O.D.[tranalator];
SHAPIRO, F.L.,red.
Weight of photons. Usp. fiz. nauk 72 no.4:673-683
D,6o.
(MIRL 13:11)
(Pbotons)

85564
S10201611136100110091037
.2 4~4 6 0 0 r11'3?, // 6 0) //S-Y) B019/BO56
AUTHORS: Brill'. 0. D., Vlasov, N. A., Kalinin, S. P., and
io-ko-1-ov-, -L.S.
TITLE: The (n,2n)-Reaction Cross Section for C 12 , N14, 016
and P19
in the Energy Interval of Prom 10 - 37 Mev
PERIODICAL: Doklady Akademii nauk ssn, 1961, vol. 136, Vo. 1,
PP- 55-57
TEXT: In the tests described here, the reactions D(d,n)He3 and
T(d,n)He4
were used for the neutron production; they were induced by
means of 20 Mev
deuterons. The experiments were made on the cyclotron of the
Institut
atomnov Pnprgji AN SSSR (Institute of Atomic Energy, AS USSR).
The neutron
energy was changed into platinum foils by slowing-down. Solid
T+Zr-
targets and gaseous deuterium targets were used. In bombarding
the
deuterium and tritium targets with fast deuterons, also
neutrons with a
continuous spectrum were formed besides the monochromatic
neutron group,
due to (d,pn) and (d,2n) reactions. The intensity of the
continuous
spectrum exceeds that of the monochromatic spectrum somewhat,
but there
exists an upper energy limit, which is about En C= E d - 4
Mev. For the
Card 1/4

12 88564
The (n,2n)-Reaction Cross Section for C
S/020/61/136/001/009/037
F14 ) 016 and F19 in the Energy Interval of BO19/BO56
Prom 10 - 37 Mev
recording of the relative (n,2n) reaction yield with various
neutron
energies, special carbon, NH 4N03 and CF2 specimens were
produced. They
were irradiated with neutrons at an angle of 00 under standard
conditionsl
the P-particles were measured by means of a Geiger counter.
The decay
curves of the specimens were determined. The background caused
by the
target backing in the case of o15 amounted to 30%, with N13 to
s0%, and in
the case of F16 to 88%. The absolute cross section of the
(n,2n) reaction
was determined for carbon at En = 34 Mev, and for fluorine at
E n = 25 Mev
and 14 Mev. The absolute cross section for nitrogen and oxygen
was measured
by comparing the annihilation t - activity of NH4NO3 and water
with the
t -activity of a carbon specimen by means of a scintillation
counter. The
results are graphically represented in Pigs. 1-4. B.V. Rybakov
and
L. S. Sokolov are mentioned. There are 4 figures and 14
references: 4
Soviet, 1 Prench, 1 Canadian, and 1 US.
PRESENTED: July 8, 1960, by A. P. Aleksandrov, Academician
Card 2/4

12
The (n,2n)-Reaotion Cross Section for 0 S/020/61/136/001/009/037
N14,1 016 and P.19 in the Energy Interval of B019/3056
From 10 - 3T MOV
SUBMITTED: April 4, 1960
12
Legend to Fig. 1: Cross section of the reaction C (n,2n)C11. Data
according to Brolley at al.'. (Ref. 6).
-Legend to Pig. 2: Gross section of the reaction N 13. a) Data
14(n,2n)N
according to Paul at al. (Ref..1). 6) Data according to Dudley at al.
(Ref. 2). 6 ).Data according to Ashby at al. (Ref 3).
i6 15
Legend to Fig- 3: Cross section of the reaction 0 9~n
2n 0
Legend to Fig. 4: Cross section of the reaction P1 n:2n~F'8- a) Data
according to Paul at al. (Ref- 1). cr) Data accordin to Rayburn at al.
(Ref-
9) Data according to Ashby at al. ef . 3
(R
Card 3/4,..

-777-7-
Fq F~5, A S/020/61/136/001/009/037

BRIIII, O.D.; PANXRATOV, V.M.; RUDAKCFV, T.P.;
RYWOV, B.V.
Cross sectione of the reactions T(d, n)H94 and
D(d, n)He3
in the 3 - 19 Mov, deuteron energy range. Atom.
energ. 16
no.2:141-143 F 164. (KIRA 17:3)

BERL 0- D- CH=EV-1 V. !.-)~ OG IN) A. A.
ffL--t~
"Investigation of some reactions corresponding to
triangular graphs."
report submitted -for Intl Conf on Low & Medium Energies
Nuclear Physics,
Paris., 2-8 Jul 64.
Kurchatov Inst, Moscow.

BRILLI, T.H., doteent
Climate of Siberia and the microclimate of unheated
buildings
of summer pioneer camps. Gig. i san. 24 no-8:37-42
Ag '59.
(MIRA 12:11)
1. Iz kafedry arkhitektur7 Tomekogo
inzhenerno-stroitellnogo
instituta.
(CLIMATE)

BRILL', T.M., inzh.
Use of prefabrication techniques and the economics of
building
children's health institutions. Sbor. nauch. trud.
TISI 8:126-134
161. (MIRA 15:1)
1. Kafedra arkhitekturnogo proyektirovanlya
obshchestvennykh
zdaniy Moskovskogo arkbitekturnogo instituta.
(Health resorts, watering places, etc.) (Construction
industry)

BRILLA, J.
-
An introdu-ction to the relazati6n method.
P. 193o (Slovenska akademic vied. Ustav strvebnictva a
architekturyl PRAGE, 1954
(Fublishect 1956) Bratislava. Czechoslovakia)
Monthly Index of East European Accessions (FEAI) LC. Vol. 7,
no. 2,
February 1958

TV006160100C)IOC410081018
A125/A126
AUTHOR- Brillir; J-.
TITLEt Mixed boundwT problems.-of anixotropia plates
PERIODICAL: Studii pi Ceroeta"ri do Meoaniol Aplioatt, no. 4,
ig6o, gog - 923
TEXT: Special attention was paid.during.the last few years to the
mixed
boundary problems of thiri plates, but!-only fow,papers deal with
the solution of
mixed boundary problems of anisotropio plates, e.-If.,
the-,artioles by G.,M. L.
Gladwell (Ref. '1: Some",Mixed Boundary-value
Froblems'-of,Asolotropio Thin Plate
Theory,, Quart. J. Meoh. Appl. Math.,XII,,l, 1959)j,H.:Zorski
(Ref. 2: Some Cases
of Bending of Anisotropio Plates. Arch. Mech. Stoa., XI, 1, 1959)
and the author
Ref. 3: J. Brilla, Einige gemisohte Randbedingungen anisotroper
Platten.-ZAMM
sub. tiparl). The-presentlarticle examines the general solution
of a semi~in-
~
finite anisotropia Olate,-- the contour of which is alternately
free or rigidly
fixed, and has n free sections. The material has an elastic
symmetry only in
relation to the median plane of the plate. The solution of the
problem leads
to two singular integral equations, which can be reduced to a
Hilbert - Riemann
Card 1/3

R/008/60/000/004/008/018
Mixed boundary problems of antisotropio plates A125/A126
problem. Considered is an anisotropio elastic plate consisting
of a material
which has an elastic symmetry parallel to the median plane of
the plate. The
stress: specific distortion relations contain 13 elastic
constants. The solu-
tion in the center of the plate, referred to a system of
rectangular oarthesian
axes having the origin in the median plane, has to satisfy the
equation of ani-
sotropic plates. The general solution of the equation of
anisotropic plates is
known. Studying an anisotropic semi-infinite plate y'70, for
which the first
derivatives of the w sag along the contour are given, the author
deduces the
expressions of the t (zl) and I (z2) holomorphous functions in
the zl and z2
planes. He then considers a semi-infinite anisotropio plate y> 0
with mixed
boundary conditions, having its contour alternately free or
rigidly fixed. Con-
sidered is finally a semi-infinite plate, stressed along its
free contour by a
constant bending moment m and a constant force q. If only one
condition on the
contour is changed the singularity has no more Grailatory
character. The given
solution is valid for the whole semi-infinite plate y70. The 02
constant
influences not only the sag of the semi-infinite plate, but also
the distribu-
tion of moments. There are 2 figures and 6 references: 3
Soviet-bloo and 3
non-Soviet-bloo. The two references to the English language
publications read
Card 2/3

R/008/60/000/004/008/018
Mixed boundary problems of antisotropic plates A125/A126
as follows:G. M. L. Gladwell, Some Mixed Boundary-value
Problems of Aeolotro-
pic Thin Plate Theory. quart. J. Mech. Appl. Math., XII,
1, 19-59; H. Zorski,
Some Cases of Bending. of Anisotropio Plates. Arch.
Mech. Stos., XI, 1 (1959).
ASSOCIATION: Ustav Stavebnictva a Architektury SAV
(Institute of Civil Engi-
neering and Architecture) in Bratislava.
SUBMITTED: January 10, 1960
Card 3/3

S10441621000100110391061
C111/C222
AUTHOR: Brilla, Jozef
TITLE: The solution of problems for orthotropic plates with
the
method of affine transformations
PERIODICAL: Referativnyy zhurnal. Matematika, no. 1, 1962,
59,
abstract 1 B 285-("Stavebn. d(asop.11, 1960,8, no. 1,45-59)
TEXT: The solution of the equilibrium equations for
orthotropic plates
with an orthotropy of the 2nd type (i.e., for such
anisotropic plates
for which the bending resistance satisfies the condition
2
Dxy = D xDy ; to this type of orthotropy belong cross-wise
reinforced
concrete plates) is reduced to the solution of the equations
for isotropic.
I yr
plates with the help of an affine transformation x = x1 , Y
= B
Examples are given for the application of this method to
problems with
different boundary conditions.
[Abstracter's note : Complete translation.]
Card 1/1

R/008/61/000/005/001/005
D289/D305
AUTHOR: --Brilla, J.
TITLE: Contact problems of the elastic anisotropic half-
plane
PERIODICAL: Studii a~ri de mecanica aplic a
9~i cercet at', no. 5,
1961t 9-987
TEXT: The article was presented at the International Congress of
Applied Mechanics held in Stress, from August 31 to September 7,
1960. It deals with contact problems of n rigid punches adhered to
an elastic anisotropic half-plane. In the present article, the
author first establishes the basic stress equations which, after
having introduced the stress function Fj may be expressed by:
~2F a' 32F ~2p
C~C~ W y ~x2 xy ~x ~y (2.2)
Card 1/ 11

Contact problems of the
He then examines an elastic anisotropic
along the y = 0 side by the p(x) and
conditions of Dirichlet, and deduces
aJJ,U 4 _2a 16r' 3 + (2a 12 + a66 )F2
R/008/61/000/005/001/005
D289/D305
half-plane y>0, stressed
t(x) loads which satisfy the
the characteristic equation:
- "26/' ' '22 = 0 (3-7)
This equation agrees with the characteristic equation of the
gene-
ral solution of the anisotropic plate's differential equation,
mentioned by S. G. Lekhnitskiy (Ref. 7: Anizotro nyye plastinki
(Anisotropic Plates), Gostelchizdat, Moscow, 19M. According to
Lekhnitskiy, the roots of this equation are not real but
complex-
conjugated two by two. The roots might be separated from each
oth-
er, or might be repeated. The author only uses the repeated
roots
of the characteristic equation. Aussuming that the infinite
stres-
ses are equal to zero, only those terms of the general integral
F
can be used, for which Re[i AlaYI