SCIENTIFIC ABSTRACT N.M. CHERNYSHEV - YE. A. CHERNYSHEV

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000308630002-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 12, 2000
• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

BUTKEVICHp G.V., doktor tekhn. nauk, prof. (Moskva); CHKRNYSHEV,
N.M., kand.
tekhn. nauk (Moskva)
Present-day problems In designing and testing
high-voltaize.swit-behes.
Elektrichestvo no.7-22-30 J1 165. (MIRA 18:7)

C"m
- SV-
Fatending the sides of gondola care for best transport.
Zhel. dor. transp. 38 no.11:72 N '56. (MLRA 9:12)
1. Zamestitell nachallnika, gruzovoy aluzhby dorogi.
Odessa.
(Railroads--Cars)

CHMSMI N. T.
1273. vaestoronneye razvitiye obahchestvesmogo khoz srra i
rost oposhchestvennogo
bogatsua kolkhozov. Pyatigorsk. 1954. Igo. 20sm. Most.) N D.
gos..Un-t.
im. V. M. Yolotava. kafedra pour* ekonomU). 106 dkz. B.
ts.-:54-5415.Q/-
SO: Knizbna;ya Letopis, Vol. 1, 1953

BDRISOV, Yevgeniy Filippovich; RWVER, lzraill
Moiseyevich, prof.;
LARINA, Raisa Yofimovna; MADYANOV, Aleksandr
Stepanovich;
SAMOYLENKO, Ivan Ivanovich; CHERNYSHEV,.,Nikolay
Tikhonovich
[Reader in economics; precommunist means of
production] Khre-
stomatiia po politicheskoi ekonomii;
dokommunisticheskie spo-
soby proizvodstva. Pod red. I.M.Brovera. Moskva,
Gos. izd-vo
"Vysshaia shkola," 1963. 378 p. (MIRA 16%7)
1. Prepodavatai kafedry politichaskoy ekonomii
Volgogradskogo
pedagogichaskogo instituta (for Brover, Larina,
Madyanov.,
Samoylenko, Chernyshev). 2. Vsesoyuznyy zaochnyy
finansovo-
ekonomicheskiy institut (for Borisov).
(Economics)

CHEWSHR.O.A.
A~r- . ~ ~--. . ---
Cold deep drawing of nonferrous metals on hydraulic
presses. Stan.
I instr. 26 no.8:31 Ag"55. (KERA 8:12)
(Deep drawing (Metal work))

CMNYSHEV, 0. B.
2780;8. CHERNYSHEV, 0. B. - Opyt vyraahchivanlya
R. Kury v pruddvykh usloviyakh. Trudy laboratorii
S. 262-75.. --Bibli#ors 8 Nazv.
osetrovoy molodi v nizov'-yakh
osnov ryboud dstva, T. 11, 1949,
SOt Letopis' Zhurnallnykh Ststey, Vol. 37, 1949

AH4hh1iGUROJJ6K1Y, Aleksandr GrIgorlyevich, kandidat
teklmicheskikh nauk-,
CHb;R14y~HNV__Qlflz Ll I 1,inzheaer; B.&LIMIKlY, Ieonid
=11 'A
Mikbeylovich, in-z5eller,i ft-SIZVA, V.,-., iuzhu-er,
veduohchly
re"ktor; ZAYTLViV, G.Z., inzhener, redaktor; ?OaU!A'.RZV, V.A.,
tekhnicheski7 rudBktor
[Instruments for disclosing static incieterminateneas of
girders]
Priborl dlia raskrytiia staticheskol nnoprede111---,-.uti
balok. Moil!ws,
Akafl.nsuk 66~,R. 1956. 13 p. (Pribory i atendy. Team 2,
no-P-56-525)
(Testirg iaciiiaes) (Girders) 10:13)

0-L
SOV/124-58-7-8103
Translation from: Referativnyy zhurnal, Mekhanika, 1958, Nr
7, p 113 (USSR)
AUTHORS: Arkhapgorodski~,.A. G. , Chernyshiv., 0. L:.
TITLE: Mechanical Calculation of Statically Indeterminate
Beams
(Mekhanicheskiy raschet staticheski neopredelimykh balok)
PERIODICAL: Tr. Nikolayevskogo korablestroit. in-ta, 1956,
Nr 8, pp
3-24
ABSTRACT: A description is given of an instrument for the
mechanical
calculation of continuous beams resting on independent
elastic
supports. To determine the support moments and the amount
of sag which the supports undergo, the span loading is re-
placed by a.,concentrated force the magnitude and
distribution
of which ar'e"so selected that the angles of rotation of
the sup-
port sectioi~6;1-are the same as those produced by the
actual
span loadin `f.'Additional concentrated forces are applied
to the
elastic supp rts, such that the pressure of each span on the
elastic supports is the same as it would be in the presence
of.
the actual load. With the load thus transformed, the bending
moments and amount of sag remain unchanged. The instrumerit
Card 1/2 in question is a uniform continuous beam subjected
to

SOV/IZ4-58-7-8103
Mechanical Calculation of Statically Indeterminate Beams
concentrated force loads along its spans and at its points
of support. When
a stepped variable- section bearn is calculated, the spans
are made to vary
accordingly. All necessary formulae are given for
determining: a) the
concentrated forces needed to replace a given load, b) the
requisite analog
span lengths, and c) the requisite stiffness of the
analog's elastic supports.
The bending n7forri-ent in the support sections of the
analog is expressed by
the curvature (measured with a curvature meter); the
displacement of the
supports is determined with an indicator. Formulae are
included for trans-
lation of the analog data into data applicable to
full-scale conditions. A de-
scription of the instrument is given, and a photograph of
it is shown. There
are examples of calculations.
A.A. Kurdyumov
1. Beams--Mechanical properties 2. Beams--Mathematical
analysis
Card Z/2 -

SOV/124-58-5-592Z
Translation from: Referativnyy zhurnal, Mekhanika, 1958, Nr 5,
p 140 (USSR)
AUTHORS: Arkhango rods kiy, A.G., Belen'kiy, L.M., Chernyshev
TITLE: A Device for Design Calculation of Beams on Flexible
Sup-
ports on a Continuous Flexible Foundation (Pribor dlya
rascheta balok, lezhashchikh na uprugikh oporakh i splosh-
nom uprugom osnovanii)
PERIODICAL: V sb.: Issledovaniya po teorii sooruzheniy. Nr 7.
Moscow,
Gosstroyizdat, 1957, pp 575-586
ABSTRACT: Description of a device serving for the mechanical
calcula-
tion of statically indeterminate beams lying on free flexible
supports. The basic idea of the calculation with the aid of
this
device consists in the following: The original beam is replaced
by a similar model; the loads and the coefficient of the
rigidity
of the supports ki are simulated; the sagging of the supports
fi
is measured, and their reaction is calculated on the basis of
measurements thereon by the formula Ri = kifi. Then the re-
sults obtained from the model beam are extrapolated for the
original beam. A continuous flexible foundation can be simu-
Card 1/Z lated by the simple device of increasing the number
of flexible

SOV/124-58-5-5922
A Device for Design Calculation of Beams (cont.)
supports. Examples of calculation are -,iven and the
possibility of extended
field application of the described device is commented
upon,
P.I. Klubin
1. Beams--Design 2 Beams--Testing. equipment
3. Mathematics
Card Z/2

ChT,11MY'SHE 11, 0. N. and DUGAYEV, V. A.
"Therinobaric Field of the Troposphere Over Mloving
Anticyclones", Tr.
Inst. Matem. i Mekhan AN Uzbek SSR, No 12, 1953, PP
71-75-
Qualitative analysis of peculiarities in the
evolution and notion of
near ground anticyclones is processed -krith respect
tot lie inean troposphere
pressure and temperature. A total of 36 cases of
anticyclone motion in
European USSR is anal.,zed and conclusions nade for
the forecasting, of
motion anL-'A development of anticyclcnes. (RZhFiz,
No 1, 1955)
SO: Sum. No. 143, 5 Apr. 55 '

KOCHERZHEVSKIY, G.N.; GOLDOVANSKIY, P.N.; ZHURBFNKO,
E.M.; CHERNfSHEV, O.V.
Logarithmic antennas for shortwave operation.
':Iektrosviazl 17 no.12:
5$-67 D 163. (MIRA 17:2)

fit
CCESSION NR: AP4041000 64/000/006/0012/0018
A S/0166/
AUTHOR: Kocherzhevslci~, G. N.';. G'oldovanakiy, P. N.; Zhurbenko,
E. M.;
Cherny*shev, 0. V.
TITLE: Input impedance of short,-*ave.log -periodic antenna
SOURCE: Elel~trosvyazl, fio.:.6, .19 6 4'12-18
it antenna, antenna input
~'TOPIC TAGS: antenna, short wave antenna, log period
impedance, radio communica~tion
ABSTRACT: The results of an experimen.tal ir~vestig.ation of the
input ilinpeaance
0~ some spatial and planar log-periodic antennas are.reported..
Input -~re sistance
vd. frequency curves are presented on the basis, of measurermnts in
the
1.200 - 1, 000 -mc band. a spati4 anfe"A with a trapezoidal radiator
and oC - 140,
z 0. 86, and ZOO was tested.'. Similar curves are reported for two
other
antennab having triangular radiat;re ind at m 300, rC z 0. 9 j and
y/ 200 and 400
/Z
twid

iACCESSION NR: AP4041000
The results of experiments intended'to raise the antenna input
impedail~e b
y
raising the characteristic impedance*of th6 distribution feedisr
are also presented.*
',A formula and graphs are'loffered for calculating the input
iz:hpedance ~f log-
'Periodic antennas. Orig.'art. hak: A3 figure&, 4 forn-ulas.-iand I
table.
ASSOCIATION: MEIS (Mbs cow* Eleletrotec'hnic~l Institute of
CornzramcatiOns)
'SUBXUTTED: 2lSep63 ENCL: 00
1-:SUB CODE: XG NO REF-SOV: 002 BOTHER: 003
:Car7e 2/2,

CHERNISREV, F.
Work of voluntary inspectors. Avt. tranap. 43 no.h5 Ja 165.
(MIRA 180)

'~ CHF P,
v'- RNYSW~
The first thounand. NTO no,5:59 My 160. (MM 14:5)
I* Predoedatell Buryatskogo oblastnogo pravleniya
nauchnc,-
tekbnicheakogo 6bahchestva stroitellnoy industrii, g.
Ulan-Ude.
(BurYat-Mongo:Lia-Techaical sooietieo)

CHERNYSHEV, P., Geroy Sotsialisticheskogo Truda
On the duty and honor of the Soviet engineer. Sots. trud 8
no.9:
3-11 S 163. (MIRA 16i10)
1. Glavnyy inzh. Laningradskogo metallichaskogo zavoda im.
XXII s"yeida Konmunistichaskoy partii Sovetskogo Soyuza.

S.I., red.; RADMAUT, A.N., tekhn,red,
Diew building rmtoriale and components mde of local raw
materials] Hovye stroitelinp materialy 1 12deliia iz
mastnogo
syrlia. Ulan-Ude. Buristakoe knizhnoe izd-vo, 1960. 58
P.
(MMA 14:3)
(Building materials) (Building blocks)

CEIERHYSH&V , F.F.
Soluble starch. Tekstil.Prom. 10, No.l. 38-9 '50. (MLRA 2:12)
(CA 47 no.15:7802 '53)

C'RE-RNr,SH&V,
IVANOVA, M.N.; VLASOV, P.V., CIW-UUU.,JMy&j VTATKIN, A.L.
reteamnat;
XMIYANOVA. F.S., redaktor; OUSEVA, Te.M., redaktor; RUMASOVA,
0.1.,
tekhnicheakiy redaktor
(Work- organization for assistant foremen servicing automatic
cotton
looms (AT-100, ATS-5 and N)] Organizatsiia truda
pomoshahchnikov
mastera, obalushivantuahchikh avtomatichaskis tkatskie stanki v
khlopchatobnmazhnoi promyshlonnosti (AT-100, ATS-3 i R) Pod
red.
F.S.Kupriianova. Moskva, Goo. nauchno-takhn. izd-vo
Ministerstva,
prorqshle tovarov shirokogo potrableniia SSSR, 1954. 166 p.
(Looms) (IMU 8:4)

CHERNYSILEV, P. G.
Handbook for estimating the cost of railroad construction
2. perer. izd.Mosk-va 3
Gos. transp. zhel-dor. i2.d-vo, 19h8. 245 p. (49-54252)
TF193-G5 1948

CHKRNYSHEV, P.G.; VASI:LIYBV, IT.P., inzhener,
redaktor; YUDZON, D.M.,
A'Aw." -j '. , W- -
-j' -.1, mw
Akiy redOctor.
[Handbook on estimating in railroad construction]
Rukovodstvo po
11 ostavlenliu smet na zholesnodoroshnoe
stroitel'stvo. 3-9 perer.
izd. Moskva, Goo. transport. zheleanodorozh. izd-vo,
1952. 231 P.
[Microfilm) (MLRA 7:11)
(Railroads--loonomice of construction)

CHERNYSHEV, Petr Georgiyevich-,' FILIMONOV, Semen
Yevgenlyevich; HUSANOV,
iipy~evc e
8v c eceased]; BABKIN, Aleksandr Rodionovich;
KRISHTALI, L.I., red.; BOBROVA, Ye.N., takhn.red.
(Estimates. bookkeeping, and technical records in
construction
and track management) Smety, uchat i tekhnicheakaia
otchethost'
v stroitel'stve i putevom khozisistve. Pod obahchei
red. P.G.
Chernysheva. Moskva, Gos.transp.zhel-dor.izd-vo,
1959. 235 p.
(MIRA 12:9)
(Railroads--Accounts, bookkeeping, ate.)

USSR~l General and Special Zoology. Insects P
t
Abs Jour: Ref Zhur-Biol., No 1, 1958, 2355
Author Chernyshev P.
Inst
Title The Control of Granary Pests In the Stavropol Area
Orig Pub: Zashchita rast. ot vredit. i bolezney, 1956, No 4,
30-32
Abstract: In the dry steppes of Stavropol, the rice weevil
[Calandra oryzael and the Rhopalocera cockchafer
(Tenebrionidael greatly harm the humid grain in the
granaries. The cleaning of the grain on clear winter
days, at a temperature of below 00, destroys these
and other pests. In mounds of grain, the top layer
of 10-15 centimeters infested by the Plodidia inter-
puntella Hb, should be removed and cleaned through
sorting, while the waste should be disinfected.
Card 1/2
27

L

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s!,. ~,.r

T,

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e v

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e

th

-itas Df vib warrang, of the gral'o -a-0: r~.Cn Oe.2v-.

horn(A baf?tla krecorded har-a for tile

ly in
i voicorded pr%3vioual

,,..;ra-L Und
C A. TM 09 Y ~7
-ld
D c bev T,
w:.-u v rec
d all
b.-'L k beet
m~r,; -n
t"47,
E5" "3-11
j J
C'X

SOLODOVNIKOV, V.G., glav. red.; MIR&X-LASHVILI, V.N., zam.
glavo red,j
GOLANSK.IY, M.M., red.; DIKANSKIY, M.G., red.; W11USHER,
K.Cfj
red. - LININ 2 Z.V. . red. I FITT11, L.A. , red,;
CHEINYSHEV, P M
red.; SHAPIRO, A.I., red.; SBEVCHENKOp G.14., red.,-
GUSEVA,, A.P., tekhn. red.
tinternational econordc organizations; handbook] Mezbdunarod-
nye ekonomicheakie organi2atsii; spravochniks 2., dopo. izda
Noskva, Izd-vo Akad. nauk SSSR) 1962. 1108 p. (KIRA 15:2)
1. Akaderdya nauk SSSR. Institut mirovoy akonomiki i
mezhduna-
rodnykh otnosheniy.
(International agencieB-Handbooks, manuals, etc.)

CHMWSHEV, P.R., inzh.
Transition of repair shops to gas fuel. Zhel. dor. transp.
41
no.10:68 0 159. (NIRA 13:2)
l.Nachallnik tokhnologichookogo otdola
proyaktno-konstruktorskogo
b7uro GIavnogo upravlonlya po remontu podvishnogo sostava
I proizvodstvu
zapasnykh chastey.
(Railroads-Repair shops)

BEZTSMM, Viktor Ivanovicb,, inzh.; PETROV, Vasiliy
Afanaslyevich, kand.
tekhn. nauk; SAKHAROV, Mikhail Borisovicb, inzh.;
TUIRWTSEV, Va-
siliy Ivanovich, kand. tekhn. nauk. Priniml uchastiyp
CBMWYSHEV,
PAt2-inzh.; KHUDOKORMOV, V.I., inzh., retsen2ent; EVIN,
G.D., inzi.,
'i~e-t5enzent; DERGACH~ Ye.So) inzhoj retsenzent;
GROKHOLISKIY, N.F.,
kand. tekhn. nauk, retsenzent; VIKOIAYEVj K.I., kand.
tekhn. nauk#
retsenzent; SMARAGDOV, G.I., kand. tekhn. nauk,
retsenzent; ZOLOTNI-
KOV, IX,, kand. tekhn. nauk) retsenzent; VISHNYAKOV,
B.I., aspirant,
retsenzent; ARSHINOV, IsM,, inzh., red.; MEDVEDEVA,
M.A., tekhn. red.
[Car repairing at factories] Remont vagonov na zavodakh.
By V.I.Bez-
tsennyi i dr. Moskva) Vses.izdatellsko-poligr.
ob"edinenie M-va pu-
tai soobsbehaniia, 1961. 363 p. (MIRA 14:12)
1. Kafedra "Vagox3y i vagormqye khozya-ystvo"
Leningradskogo instituta
inzhenerov zheleznodorozhnogo transporta (for
Grokhol'skiy, Nikolayev,
Smaragdov, Zolotnikov)
(Railroads-Cara--Maintenance and repair)

~HR~U,3HML, P.N. ~ inzh.; CHURSIN, Yu.G. . inzh.
Mechanization of external washing and cleaning of
tank cars.
Mekh.i avtom. proizve 15 no,6:34,37 Je 162. (MIRA
:L4:6)
(Tank cars--Cleaning)

CHERNYSHEV, Pavel Nikolayevich; SOROKA, Araentiy
Kirillovich; NALIVAYKO,
Petr Nikolayeifib-,--WWL', Ya.P., inzh., retsenzent;
BRAYIDVSKIY,
N.G., inzh., red.; HEDVEDEVA, M.A., tekhn. red.
(Repair of cars on a conveyor; the experience of Kanash,
Darnitsa,
Borisoglebak, and Nizhnedneprovsk car repair shops]Remont
vagonov
na. konveyere; opyt Kanashakogo,, Darnitskogo,
Borisoglebskogo i
Nizhnedneprovokogo vagonoremontnykh zavodov, Moskva,
Tranezhel-
dorizdat, 1962. 155 P. (MIRA 161l)
(Railroads-Repair shops)
(Assembly-line methods)

GHERNYSHEV, P.P.
.1 ---------
Remote results of surgery of peripheral nerves
necessitated by gunshot
wounds. Vop.neurokhir. 17 no.2:46-53 Mr-Ap '53. MRA 6:5
(Nerves-Surgery)

lq)- y-
MUZHINSKIr I A., Isureat StaUnskoy prenii; CHKWSHNV, P.S.,
inzhener,
rqjA2=t; JMACHXMV, S.Ys., inzaenar, redalnor; FETEMIF, X-Nes
takEffe-HiekLy redaktor*
[Methods of machining complex surfaces on machine toolej
Metody ob-
rabotki slozhnykh poverkhnostai na MOte,110r62bushchikh
atankaM.
Moskva, Goe.nauchno-tekhn.W-vo maehinostroit.lit-ry, 1955.
315 P.
(Microfilm] (MLRL 8:5)
(Metal cutting) (Surfaces (Technology))

CIMWSHEV, PoSe, inzhej2er*
- i
.6.
Weldments in steam, gas, and hydraulic turbine
manufacture at the
Lenizffad Metallurgical Plant. Inergomashinestroanie
its.4:19-23
Ap 156. (leniWad--Thrbines--~Wolding) (MLU 9:7)

AUKCHZYZV, A.A.; MW IN, S-P.; BXLYAVSKIT, V.A.; KOI0TIWV,
A.N.;
M010KANOV, B.T.; HMASO7. A.M.; LAVRENENKO. K.D.;
POLKIRTSIff, K.K.;
RDZHIESTVINMEIT. A.P.; SATJMVSKIY. A.Te.; SIRYT, P.O.;
SPIRIDONDV.
SMTMNKO
K.i.; CEMW -SHUbIN, L.Ae
Savva Mikhailovich Zherbin-1 obituar7. Elak.ata. 30 no.2:96
7
'59- (MIRA 12:3)
(Zherbin, Sav7a Mikhailovich, 1903-1958)

XHIZHNYAK, P.D., glavnyy red.; GLAZOV, G.A.,
zam.glavnogo red.; B-16TUMBARG,
V.A., red.; VASILIKOV, B.A., red.; GWSHKOV, A.T., red.;
ZHCLOBOV,
V.V., red.; KAMV, P.V., red.; KWITU, H.K., red.;
KISELEV, M.I.,
red.; KOWTGOV, I.N., red.; NOISEYEV, A.A.i red.;
NOVIKOV, A.P.,
red.; SIMIN, S.A.. red.; CHRRNUM,_Pq~t_~_red.;
SHAGURIN, K.A.,
red.; SM , I.Ye., red.; DRICIRTOYEVA. I.K., red.;
SHMOVA. A.V.,
tekhn.red.
(Experience of mechanical engineers; technical
information
publication] Opyt mashinostroitelei;
informatsionno-tekhnichaskii
aborni.k. Leningrad, Sovet
nar.khoz.Loningr.ekon.administrativnogo
raiona. TSentr.biuro tekhn.info taii. ig6o. 88 P.
(MIU 1):11)
(Mechanical engineering)

CHERNYSHEVI P.S., Geroy Sotsialisticheskogo Truda
Soviet engineer is Ahigh title. NTO ~ no.l2s2-5 D 162.
1.1 (MM 16:1)
1. Predsedatell soveta pervichnoy organizatsii Nauchno-
takhnicheakikh obshchostv, glavnyy inzh. Leningradskogo
Meta]Mcheskogo zavoda imeni XXII s" yezda
Kommunisticheskoy
partii Sovetskogo Scyuza. i(EngIineers)

,GffMMIEV Geroy Sotsialistichaskogo Truda
ttj-
.Visible features of communism. NTO 5 no.6:5-6 Je 163.
(14MA 16:9)
1. Predsedatell sovets, Nauchno-tekhnicheskogo
obshchestva i glavnyy
inzh, Iserlingradakogo metallicheskogo zavoda imeni
XXII slyazda Kom-
munisticheskoy partii Sovetskogo Soyuza.

4 2
L

Accmiow NR: tP5o14Cjl4
F

AUTHOR: Ghern~yeihev, P.S. (Engineer); Pclishch~
`Engineers

TITIA: Selectior
of a promising type of high-p-
- 5ti-&L-gas turbine

SOUKE: Teploenergetika, no.
12, 1964, 32-36

TOPIC TAGS: electric pover engineering, steam Lu
r_~ine. g&s
turbine engine, elec-

tric pow-:!r production

10STRACTt Several compounded
steam-gas tur"',nor

~-r,:,nrqd.

jUatala Plant kLMFj prom-1*99 'to flMd
extenvIve app

liontion in Siberia. These tjr-

bines in irrRo pow r qtntiono
will p-rodura mm!-3

ch,~ni)or ^nxal. ~rvr- z

thev Arn .19Rii ecoramical thnn
oomoarkble west

ftwi ~.IS mmonoiek. .!%q i,

c V~` in k-,7,h 4r, ;~dli-

I tray-

tiono

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ACMSION NR: AP5014914

The UIP ip p"sartly building
h1ghly officiont

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ivith this ty-pe of t%L-bin~, Inmdiate atton't "ov Li'. W, mad t 0 a
d-- 0 1
the gas tLrbine exhauet gao,#v are dmpod Intc U? -naco 1~
-,q r t,,ar t, I m;3 0 og:ib i ftr, ti Ong
LeninVadakiy 6t-allicbeekiy mv("l me'-'agrkl p
SUM=- M: Oe) IV=: 00 SUB COM ES
NO ESY 30v: ooo OT 000
v -r;i'
~L'cam

I OFW MOD SOURC2 5/000/005/0039/0046
.6005405 bODE.'* UR/0323/6 __?
q.
AUTHOR: Marchenk-o L _N (Engineer); Kotoy, M. P. (Professor); r2
..Sorokina 1 .0 sh~eza ~.L_Ye..
candidate of technical sciences); Cjj~
ACandidatte of chemical sciences)
ORG: Kiev Technological Institute of Light Industry (Kiyevskiy
tekhnologicheekly institut legkoy promyshlennostl).
TITIE: Investigation of the physical and mechanical properties of
cements with polyamide, polyeater,.and R!j~~ bases
SOURCE: IVUZ. Tekhnologlya legkoy promyshlennosti, no. 5, 1965.,
39-46
TOPIC TAGS: cement, polyamide resin, phenolformaldehyde resin,
polyester, elasticity, adhesive, adhesion
ABSTRACT: New therm.0plastic, rapid-setting, and elastic adhesive
resins have been obtained with polyamilde, polyester, and phenol-
formaldehyde resin bases. These cement compositions (19ILQL)_~ban be
used for obtaining an adhesive-re'inforeing seam for mechanized ad-
hesive joining of parts of footwear and clothing. The effect was
studied of the phenolformaldehyde resins on the properties of KTILOL
cement. The effects of various polyester resins on the strength and
Card 1/2

L 24727,66
elasticity of adhesive joints was analyzed. Compositions based on
.,polyether resins having a 1:1 molar ratio of anhydride and alcohol
with the acid number before the-moment of gelatinization have greater
adhesive-joint strength and 1e s adhesive-seam thickness. 0 1 a t.
has: 5 figures and 4 tables# FBased on author's conclusionsf flu]
SUB. CODE:. Il/ SUBM -DATE 18Jan65/ ORIG REP: OlO/ OTH REF: 00:
Card 2/2
LS

'/EWP -07V;2AWP(h')/ETC
SOURCE CCE)E: M/OP96/66/000/003/0002/0007
C F( i -:'POI- ar); Chermrs
iabehl*. r~Li(Enginq hey, 44~
--(Engineer)
wias~ Hinie~M-_br He Powirp: and: T4ranoport Machine Building-IM
ime.,XXII Con
avy,
tte, OF4U(Ninisterstvo tya2helogo., energeticheskogo i transportnogo
mashin OP
ostrume
.-I-ITIEv~' Present status and futitrb'Itrendo. in tbi~ development
of power Me turbine
Zo
pp q9,*ir&tika#.
_00
--,turbine 6o in io power
npressor., turbine cool g., thermoelectr
Z"biL
t b1ade
-turbintr un ts W th
e4fiort, U,bein- de- to develop gas
ma
d 26: -.C~CUB`: to .-improve -thermal power plint-,econoniy.,. The
cimbine steam-g
TIWTI), together with several boiler
Cebtral;.Boiler and. Turbine. Institute
-`:aii ~:ti ifie- plants,- are engaged, in, Idevel-o-p Ing steam-gas
units wit
d . u,r,b h high
-40
-.Pressure steam generators. Two of these units)with capacities of
ahd 14 Mw have already been-built and are being tested. Preliminary
work is under way to build a similar 200,000 kw steam-gas unit.
Construction h" been completed and operational tests are presently
'being 66hducted on several conventional gas turbine units: these
include
'Ll~yLl~Am.-I~e- Leningrad _Metal.Plant (W); a 50 Mv uniti: by
Cc ux: 621.439.(o48)

V`
ACC__NRS -AP60.13395
the Khvwk6v Turbine Plant (KhTP); a 12 Mw unit the Nevsk Plant (NP
and-alsoa 4 and a.1.5 Mw unit built by the-.Kalugs Turbine Plant and
the
Leningrad pja~t "Economizer". Despite the development of these gas
turbine units, it is noted that the Soviet gas turbine building
Industry
'bas-notyet accumulated sufficient experience to produce highly
efficient-,
lan&operationally reliable power gas turbines demanded by the power.
lengineering industry. Soviet industry is furthest advanced in gas
turbine technology in the field of compressor drives for gas
pipelines.-.,,
'The-,Soviets are presently mass producing 4-10,000 kw
turbocampressors
.:for pumping natural gas. Considerableoperational experience has been
accumulated with 4--5,000 kw units especially at the Nevsk machine
building plant. The operational reliability of gas turbine drives is
presently 98%. The intensive research and development work how being
'conducted is expected to yield new improved,prototypeB of high-power
gas,
'turbines and their subsequent mass production.
e.Leninjrad- Metal Plant, the largest' Soviet supplier of steam
nes is ~'_ doIng most of the'eurr- r'ese ch - work. At. the . end of
ig6o
ent: ar
alit-` 6
j 00-0, -kw iAurbine protot pe, The principal
ia iuie~- -f -t h o1 or
is turbine is---the~'e fective co, ing,;Iof,-the rot
-totdrs ma e~of perlite ch
a es poss
rome--:
7~
I - ' h d
i* :700"C
e~ 6 tee&-__ ate inlet. XP o.,
d num- .,-During t e es gn
t 'is t'u ine,~ Ia. gire
and.-trAnufacture. of' the basic 'model"of h rb at deal of
~experimantal research work was carried out jointly by fhe TsKT1, the'
Kiev-_P_olvtech the VT1, and others. Among the most

~-777~7 nF7= -.:n
4f
AF
C,N;Fii
Rt
-The development and.aerodynamic'
compressor- flair-tbrouszh sectionn. f1sil Ir
testID&
pressors ~-at maXimum, rpjz~, ..and teasuring,the dynamic stresses in
the -
t" CC! Asor,bla~d6s; -.2) ~ aerodynatmi.; and I vibrational testing of
the turbine
stages t, 3) testing-and refinement ofthe~cdmbustion chamber and its
com-
PoPenisi'-and.4.)'the testing of the-turbine cooling system.-At the t
ime the''
;fiiit Lur--~ine protot las compieie~'tx~re- were m fadlities
forrunning "hot"
ype,
Uttests, andi.,therefore a. large Oorti6n'.oi the experimental testing
was.
conducted under-actual operating conditions. As a result of'these
-exp i I etations, new. ty.pes of : flame tubes and burners were
II-._ ta op
_d
Makii*,lt Possible at a'*700 C,eas temuerature to ensure.that
th tibii in-- the, temperaiure fi6ld:-before'the turbine id less "tKan"
'36 that' the.waximal-Lflame.tube t erat exceed 600*C.
,emp ure does not
Ihe major diffic-ulty*encounteted'dutinglf6sting was the temperature
monitoring oUthe rotor and blade roots'.. This problem was solved by
designing a special multipoint switch which was mounted in the axial
boring of the turbrine rotor. The test results are being used.to make
necessary design modifications in the.construction-of a series of
similar turbine units for the Yakutsk power station.
"Me len1mgrad Metal 71-ant bias -recently ;completed the,design and
experimental testing and has started on the construction of a 100,000
kw~
gas turbine unit. The high compression ratio and interstage. cooling
wM make it possible to achievo an efficiency of 27--28%.
3A
.1 Card

L 23133-66 EWA(h)/FCC/EWT(1) GW
ACC VR: AP6006670 SOURCE CODE-. UR/0203/66/006/001/0143/0146
AUTHORS,. Chavdarov,- So Sol qhkrnyeheva, S., Po; Shatkhin, _.Kh, Z.,
ORO: Rostov-on-Don State Univerai (Rostovakiy-na-a-Donu
gosudarstvannyy
universitet)
I.TITLEt Stability of reflections from the sporadic E la and olair
activity
jSOURGE: Geomagnetizm i aeronomiya,, v* 6. no., 1. 1966, 143-146
TOPIC TAGS: solar activity., E layer,, sunspot, solar cyclep
electromagnetic wave
reflection
ABSTRACT: The authors point out the contradictions in the literature
concerning
the dependence of E-layer reflections on phases of the solar cycle.
They consider
the following parameters characterizing stability of reflection from
E. (parameters
that they previously introduced into the literature): duration of
continuovis
reflections, (pEd Tv;~ probability of the appearance of E. during
certain
hours of the day-with a given duration of uninterrupted reflections
(hereafter
I
called P)j, 6) the stability coefficient, characterizing the rate of
decrease in
Card
1/2 UDCj 55O*388z2t523-745

L 23133-66
',-Ar.C HR: AP6OD6670
probability P with increase in A number of observational data are
examined,
particularly ionospheric data from Rostov-on-Don for 1960-64 in
conjunction with
1958-59 data. Graphs of probability for these periods have been
otteds From
Pi
an examination of the results it'appears that P and 9 are the best
parameters for
I detailed definition of the B. layer. The normal probability of the
E. layer has
no detectable connection with the cycle of solar activity. The
probability of
the layer with a given duration as 'T increases shows a notable
reciprocal
correlation with the sunspot number. A reciprocal dependence on
phase of the
solar cycle is clearly manifested in changes in duration of
reflections and in
the stabi2ity coefficient. The reciprocal dependence of P and 9 on
the sunspot
number may be explained to some extent.by the fact that in a year of
maximal solar
activity the proceasee at work in the ionosphere are more sharply
manifested, and
these lead to an increase in amount'of reflection of short duration.
Orig. art,
bass 3 figurese
SUB CODE t OIA 03 SUBM WE s 24fty65/ ORIG REF: 007/
COM 2/2

CHERNYSHEV, R., inzh.
------
A d.c. millivoltmter. Radio no.5:57-60 W 165. (14IRA
18:5)

CHEEPMYS~IEIII_,-S~. I
First results of the work of the Ltkraip-~an
Agricultural
Transportation ~Center. Avt.transp. .142 nn.3:7-8 Mr
164.
(MIRA 17:4)
1. Zamstitell ministra avtotransporta i shosseyrqkh
dorog
UkrSSR.

CHERWMHEV, S.
Consolidation of automot4ve transportation units
and the
centralization of servicing and repairing. Avt.
transp.
43 no.4:34-35 AP 165. (MIRA 18:5)
1. Zamestitell ministra avtomobillnogo transporta,
i shosseynykh
dorog UkrSSR.

CHERNYSHEV, S. (Moscow)
"SYnthese und Eigenschaften Silicium enthaI!,ender Styrole."
paper submitted for the Symposium on Organic and Non-Siliceous
Silicon Chemistry,
Dresden, 12-14 May 19%.
1
Y
i

Xechanize loading and unloading operations more
rapidly. Avt.transp.-
38 no-11:10-12 N 160. (XIU 13311)
I* Zamestitell ministra, avtomobillnogo transporta
I ahoasayzykh
dorog TJSM.
(Loading and unloading--Technological innovations)

,.~PBERNBREV-9.,.S. -
Care of man, Ayt, transp. 43 no.12:6-7 D 165. (MIRA
18:12)
1. Zamestitelt ministra avtomobillnogo transporta i
shossaynykh
dorog UkrSSR.

CHERNYSHEV, S. F.
CHERNYSHEV, S. F.: "Basic problems of assembling
multistory
skeleton-panel dwelling houses". KharIkov, 1955. Min
Higher
Education Ukrainian SSR. KharIkov Construction
Engineerin.g Ist.
OLssertations for the Degree of Candidate of Tecl2nical
Sciences)
50. Knizhnaya 2etopi5 1, No. ~2, 24 DecemDer, 1555.
Moscow.

CHERNYSHEV, Sergey Fedorovjqh;_KOXWPIIT, K.P.,
red.; BABILICHANOVA,
G.A., tekbn. red.
(Aligment in the assembly of structural elements]
Vyverka
pri montazhe stroitellrykh konstruktsii. Kiev,
Gosstroi-
izdat USSR, 1962. 97 p. (MIRA 15:7)
(Precast concrete construction)

SHVIDENKO, Valentin losifovich, prof.; MAT0101IN,
Vladimir Pavlovich,
dots.j kand. takhn. nauk; WIITOV, Aleksey
Mikhayloviz:;h~
dots., kand. tekhn.nauk; FOKOV, Rostislav
Ivanovich, kand.
takhn. nauk-, CHEMSM.,,- rpy,
_W je4oravich,, dots.kand.tekhn.
nauk; YAKDiENXO, L.I., red.
(ABsembly of multistory induatria" 'n,",iings]
Montazh mnogo-
etazhnykh promyshlanxVkh zdanil. Kharikov, Izd-vo
Khar*-kov-
skogo univ., 1964. 142 p. (MIRA 18:3)

L 31326-66 EWT(I)/Esyr(m)/EWP(J)/T/ETC(M)-6 IJP(C) Wyi/JV;/Fi?,i
ACCESSION NR: AP5025984 UR/0294/65/003/0051070010707 r~q
547. 211+547.~ 212:532. 13+533. 21 0;?2
AUTHOR: Kessellniqn, P. M.; CttLnyshev, S. K.
r-r
TITLE: Therxnd~hysical characteristics of some hydrocarbons at high
tempera-
tures -~ I Il 1 -0 1 1 -~i_
SOURCE: Teplofizika vysokikh temperatur, v. 3, no. 5, 1965, 700-707
TOPIC TAGS: hydrocarbon, ethylene, ethane, methane, gas properties,
equation
of state
" J~'~ tUA 04
ABSTRACT: the 'bj~e he woi-k was the simultaneous determination of
the
transport properties and 'Ehe second and.thirdvirial coefficients
of methanel ethanel
and ethylenilover a wide temperature interval including the high
tempe:~aWre re--
gior~.~he t~h4ioretical treatment is based on the following
averaged potential func-
tion for intermolecular interaction:
,u 4e(T)
11(1(Tr) I r
VM 10)
in which the potential parameters 'O(T) and 9 (T) are not constants
but are some
:crd 1/ 2
I I

L 31326-66
ACCESSION NR: AP5025984
functions of the temperature. Based on data from the literature,
calculated
values of the viscosity and the second and third virial
coefficients for methane,
ethane, and ethylene are tabulated for temperatures from 300 to
3000 K. Values ct
-the viscosity, calculated by this method, are found to agree with
experimental
data within 1-21o. However, at high temperatures where experimental
data on
compressibility are not available, the use of the potential
parameters for a spher-L
ical potential found from the second virial coefficient leads to
unsatisfactory re-
sults; the deviation in this case between theoretical and
experimental values
reaches 10-1516. This is attributed to'insufficiently realistic
values of the spherl-,
cal potential for describing the interaction of nonspherical
molecules.. A comparl
son of calculated and experimental values of thermal conductivity
shows a devia-
-tion within'the, experimental error (from 1-376, and only reaching
5-616 at low
temperatures). Orig. art. has; 7 formulas, 4 figures~' and 4 tables
ASSOCIATION: Odeaskiy tekhnologicheskiy institut im. M.' V.
Lomonosova
(Odessa Institute of Technology)
SUBMITTED: 24Jul64 EIN U.U: U_U_ SUB CODE. 017, 2-0
NR REF SOV: 007 OTHER: 015
Cc*rd 2/2 (7,

FOWIN, K.'~..,-GHFRNY~,3HEV, s.m.
Characteristics of the formation of the Oil Pools of
the
Praskoveya-Achikulak Area of uplifts. Trudy 14lhKHiGP
no-43:
75-81 163. (KRA 17:4)

~.4&.;ZHDANOV,
VAGIN, S.B.; GORDINSKIY, G.Ye.; GRIBOVA, Ye.A.;
DUBROVSKAYA 'y A
M.A.,, Prof. ; ZYUZINA, N.G.; KARTSEV, A.A.;
ENYAZEV,V.S.,dotp.;
LEONOVA, R.A.;POKROVSKAYA, L.V.; .51DARIKOV,
Yu.A.;YUDIN,G.T.,dots.;
SOKOLISKAYAJ, Z.V.; TOMKINA, A.V.;
USPENSKAYA,R.TV.jprof.;FOMK1N,
K.V. kand.geol-min.naukL GBEWSHEV YAVORCHUK, IN.;
BAKIROV, A.A., prof., red.; DDIENTIYEVA, T.A., ved. red.
[Geological conditions and basic characteristics of oil
and
gas accumulations in the limits of the Epi-Hercynian
Platform in the south of the U.S.S.R.] Geologicheskie
uslo-
viia i osnovnye zakonomernosti razmeshcheniia skoplenii
nefti i gaza v predelakh epigertsinskoi platformy iuga
SSSR.
Pod obshchei red. A.A.Bakirova. Moskva, Nedra. Vol.2.
1964.
306 p. (MIRA 17:12)
1. Moscow. Institut neftekhimicheskoy i gazovoy
promyshlen-
nosti.

CHERNYSHEV, S.M.; YUDINP G.T.; PLOTNIKOV, M.S.; KONONO"
, I.B.
Recent data on the distribution of red-colored and
magmatic
rocks in the Kuma region of eastern Ciscaucasia. Izv.
vys.
ucheb. zav.; neft' i gaz 8 no-3:8,12 165.
(MIRA 18:5)
1. Moskovskiy institut neftekhimichesviy i gazovoy
promyshlennosti
im. akademika Gubkj-4a i trest
"Stavrcp.)llneftegazrazvedka".

w
CHERNYSIEV'j S~.T~.,.aajirart
Mcogenetic deformation- of trap rocks -in the
Angara Vialley.
Izv. vys. ucheb. zav.; geoll. i razv. 8 no.
12:78-85 D 165
(MIPA 19:1)
1. ITsesoyuziiyy ordena Le-nina
proyektno-izyskatellsk-ly i
nauchno-iss'ledovatellskiy institut imeni Z. Ya.
Zhuka.

91i itip i i i *- i -0 i i-4-0- 44-0--or-&-e-offimum 2~WA
~:W~W JIWVMMS W W W
"I a a )i b )a 17 26 pju o u u ii a u 46 a
slid$& y9 11011U11U441"A"A
r a I F 1~9 I L 4 A-A
00 A I .,, - - .
00 ------
00
60
0 B. V. Chanyabev.
:0 v P'OkmWya
IOU. 11. 2M.-Me(boch; for vxtiuguW&g petmkum
fires wt revierwWo and It f2 concluded that air or chem, j,09
(mm Is mWk adled for minsubhins fim~ Of light Oili -00
inclading Savoline and Coils. Itach tank AoOd 1w ptu.
vWcol with a kxV*l pipe i-yourn for aimislul thr ci.
tinsuishing Medium llans.141dudler
-00
go
Slow
00
-00
=00
-goo
J 0
tte 0
LA Of I AALUR W&L MfOATWt kt AIIWK41 k9ft t
--gia#j 'OjtvDal .1,1)) AW NT is I
If
b u v Aw io m ?r It
0- 00 00 0 0 0 0 * 0 0 * 0 g 00
0 0
0 0 0.0

r.qMMHrLV, s.v.
22623. CHFMYSI.!FV) S.V. opyt borlby s bolezntyu auyeski
porosyat. Veterinariya, 1949,
No. 7, S. 12-13
SO: LETOPISI No. 20, 1949

0- Y ye-
1. RUDNEV, L. V.; CHMMHEV, S. YE.; ABROSIMOVO P. V., Arch.;
KHRYAh-OVv A.F.,Archo
2. USSR 600
4. Moscow University
7. 26-story building of Moscow State University3, Gor. khoz.
Mosk, 23) No. 7,, 1949.
9. Monthl List of Russian Accessions, Library of Congress, APrI1
-1-953, Uncl.

14(10)
~130V/19 _59-6-219 7/709
AUTHOR:
Skripko, V.L., mid
Chernyshov, V.P.
TITLE:
lin Installation for Thermal Ground
Reinforcement
PERIODICAL:
Byulleten' izobreteniy, 1959, Nr 6,
p 60 (USSI')
ABSTIUCT:
Class 84c 9 1. Nr 118766 (598799 of 4
May 1956). 1)

kn installation as in title, employing hot
gases, ob-

tained in the combustion process of liquid,
gaseous,

or pulverized fuels, which are introduced into -the

borehole already drilled in the ground. The installa-

tion is
provided with a compressor mounted on a verti-

cal shaft
togethe:& Ydth a gas turbine feedin- the

air necessary for
-the fuci combustion into the bore-

hole, and with spray
burners for the feedinG and

spraying of the fuel. To
-Litilize the kinetic onorcy

of the hot gases for drivin~~
the compressor, the

installation is made in the form of a
hollow cylin-

der being lowered into the borehole and
containing
Card 112
the spray burners and the compressor with
the turbine.

-0-0V/101-59-6-297/309
An Installation for Thermal Ground Reinforcement
The turbine is installed in tile lower part of the
body and the spray burners - in the coribustion,
chamber formed by the space between the compressor
and the turbine. 2) Additional spray burners are in-
stalled in tile lovier part of the body to obtain a
further increase of gas temperature. 3) Ring-i~ha ed
spray burners are used to simplify the design. L,13
A:n electric motor is used to start the turbine and
the compressor.
Card 2/2

5~ (3)
AUTHORS: Cherayshev, Ye. A., Dolgaya, M. Ye. SOVtj'9-29-6-15/72
TITLE: The-Reactivity of a-A- and Y-Chloroalkyl-Bilane-chlorides
in
Friedel-Crafts' Roaction (Reaktsionnaya sposobnost' a-,#- i
Y-khloralkil,silankhloridov v reaktaii Fridelya.-Kraft-sa)
PERIODICAL: Zhurnal obahchey khimii, 1959, Vol 29, Nr 6, pp 1850
- '853
(USSR)
ABSTRACT: In the Friedel-Craftareaction with different a-)P- and
)('-ehloro-
-alkyl-ailano-chlorides the authors showed the qualitaCtively
different reactivity of these ohlorides (Ref 1). It was found
that the chlorides with P- and y-positions of the chlorine
atom have a considerably larger reactivity witb 7espoGt to the
silicon atomp than the a-chlorideB; the substitution of an al-
kyl radical for-the chlorine atom on the silicon atom in the
ohloro-alkyl-trichloro-silanes always increases the reactivity
of the ohloride (i.e. CH 3SiC12CH2 Cl is more aotiye than
Cl3SiCH2Cl). In the present paper the quantitative oomparison
of-.the reactivity of the chlorides under reyiew in the Friedel-
-Craftareaction is described. The reaction rate of each chloride
Card 1/2 was determined by means of the evolution rate of the
hydrogen

The Reactivity of a-fi- and Chloroalkyl-silase,z~
SOV/79-29-6-15/72
-ohlorides in Priedel-craf-A-F.Reabtion
chloride according to Lebedev (Ref 2). This experiment is dealt
with in detail in the present paper. The negative induc-tion
ef-
fect (-I) of the groups Cl3S11 and R012Si is shovn to exert a
considerable influence upon the reactivity of the bQnd C-Cl, in
which connection the conjugation etfect of the S-C ano C-Cl
bonds is added to the action of the induction effect in the
case of the 0-chlorides, The magnitude of the --onjugation ef-
fect of the Si-C-bond with the C-Cl bond in the A-chlorides
depends on the nature of the radicals or atoms linked with the
silicon and decreases considerably on substitution of the chlo-
rine atoms for the alkyl radicals. The results of the experi-
ments are given in the tables. There are 2 tables and 2 Soviet
references.
*(Institute of
ASOOCIATION: Institut organicheskoy khimii Akademii nauk SSSR
Organic Chemistry of the Academy of Sciences, USSR)
SUBMITTED: May 279 1958
Card'2/2

50) SOV/2o-126-4-2B/62
AUTHORS: Korshak, V. V., Corresponding Member AS USSR;
Polyakova, A.M.;
Sakharova, A. A.; Petrov, A. D., Corresponding Member AS
USSR;
Chernyuh0.V,,.._jq,. A.
TITLE:
Polymerization of Vinylaromatic Organosilicon
Compounds

(Polimerizatsiya vinilaromaticheakikh
kremniyorganicheskikh

soyedineniy). The Derivatives of
(x-Methylstyrene (Proiz-

vodnyye a-metilatirola)
PERIODICAL:
Dolclady Akademii nauk SSSR, 1959, V0.1 126, Nr 4, PP
791-793

(USSR)
ABSTRACT:
The authors already examined the
polymerizability of the

compounds mentioned in the title,
containing silicium com-

bined to the carbon of the benzene
ring. In doing so, they

produced glass like polymers and
defined their properties.

The compounds mentioned in the
title are described in the

present article in this regard,
but they contain silicium

which is combined with the benzene
ring through methyl groups.
Card 1/3

SOV/20-126-4-28/62
Polymerization of Vinylaromatic Organosilicon Compounds.
The Derivatives
of a-Methyletyrene
Polymerization was carried out under an excess pressure of
6000, in the presence of initiators of the radical type:
azo-isobutyric-acid-dinitryl (ADN) and the tertiary butyl
peroxide (TBP). A comparison of the polymerization results
with ADN and TBP being present, showed that the polymer
develops more guickly in the presence'of ADN (concentration
0-3 m01-% at 80 ) than it does when TBP is used at 130*- In
the first case the molecular weight of the polymers is
higher
(Table 1). The values of the viscosity characteristic of
the
a-methylstyrene-polymer and silicium-substituted a-methyl-
styrenes decrease in the transition from the polymer
C6H 5C=C112to the polymer (C 2H5)3 SiC6H47-CH2 and to the
other
I
CH3 CH3
polymers (C H ) Si C11 C 11 C-CH and (C H ) SiCH CIT C H CH
2 5 3 5 2 6 41 2 2 5 3c 2 2 6 47- 2
CH3 CH 3
The thermomechanical properties of the polymers change in
the
Card 2/3 same sequence (Fig 2).

SOV120-126-4-26162
Polymerization of Vinylaromatic Organosilicon Compounds.
The Derivatives
of a-Methylstyrene
There are 2 figures, I table, and 2 Soviet references.
ASSOCIATION: institut elementoorganicheskikh soyedineniy
Akademii nauk
SSSR
(Institute for Elemental Organic Compounds of the Academy
of Sciences, USSR). Institut organicheskoy khimii im. IT. D.
Zelinskogo Akademii nauk SSSR (Institute for Organic
Chemistry
imeni 11. D. Zelinskiy of the Academy of Sciences, USSR)
SUBMITTED: April 5, 1959
Card 3/3

rz (2 ~ 7 S C.
AUTHORS: M
U Li Kuang-l-'ang
-Ye-mber AS USSR .*- ~ . ~ , A. D. r Sn 3 nd,_
TITLE:
A Rew lfethot of Synthesizing Jkromatuio, OrganDsilicon
:11onorfiers
PE.:~IODICAL:
Dohlady Akadei,,iii naid: SSSR, Vol.
127, T~r 4, Pr 808-811

(USSR) .
ABSTRACT:
The well-known and
E;enezally eriploy;%d methods of the above

synthesis are
enumerated. in th~? int-roductory (Refs 1-0). TIle

data
contained in two patents (2efs 6, 7) as well as Tefex_enasa

prrvcd that the reaction HS*,.Cl . CIO 6 11 __> Cl,S_1C 6H,
-f HIC 1
3 5

in principle Is possillble in th-_- gasecus ph-a-se.
Accordingly the

authors fourd that - at a temperature i:ise of
the reaction Tange

0
-.0 550-700 - chlorine a-fyls -teadily condense with hydride

,L preSSU~_C
silanes in the gaseous phase a (see

reaction scheme, whore R =
aromatic vadinal, 111 ~ CH 3 C -3- C2 H5

and n = 0.1). The
condcnsate obtained t-as rjubjected to

fractional
distillation. Two methods were employed practically

yielding
the same result8: the fra-,tion 00-1321 con3isted of a
Card
1/3
riiixture of benzone and chlorobenzene
990 of
the frixtion 134
1

-
,
.

I
A New Method of Synthesizing Aromatic Organosilicon
30'T/20-127-4-22/60
Monomers
ohlorobenzene and phenyl trichloro silane, while the fraction
199-2020 correspondedto phenyl trichloro silane. For the
purpose
of producing phenyl trichloro silane the authors investigated
the
effect exercised by the temperature of the reaction range(Fig
1)F
the duration of contact, and the ratio of the initial reagents
upon the degree of conversion of IISiCl,, and on the yields of
condensation products. The main reaction is accompanied by a
side reaction according to another scheme which is indicated by
the occurrence of large quantities of SJ-Cl4 and benzene.
However,
the quantities of SiCl 4 are always greater than those of
benzene,
which shows that a third scheme is.'
+nvolved. The gaseous reaction
the molar
products ronsisted almost entirely of H'.1 and H21
quantities of H2 corresponding to the molar excess of SiCl 4
Vd- t h
respect to benzene. This permits the assumption that SiCl 4 is
a
product of the reaction 4HSiCl, 10 3S-PLC'-' 4+Si+H 2 0Eence
the
interactions between HSiCl 3 and C6H5CI are accompanied by
pyrolysis of HSiCl At 700(), about 10~ of the initial
..ard 2/3 3 * ia

A New Method of Synthesizing Aromatic OrEanosilicon
SC)V/20-127-4-22/60
moromers
~ricblorosilano are subject to pyi-olytic splitting. The
pyrolysis
U
of chlorobenzen- is very slight. The i-afluencte exerted by the
d-aration of contact on the .omplete conversion of
trichloroL;ilane
and on "he yieltsof SIC14 and n
1611rS~C!-A. is revealed by fig-ure 2.
t, that jh,--~ oi3 t-im'LLM rLITIO Of chlorobenzene 'to
P gurc, 3 ilidicates
trichloro si lane is 2 A n Inc-rease of the latf~,r up to 3 1 1
does ii~-,t altc-:r the yleltl of pheryl tr4chlorosilaile, but
ircraases
t-be quantity of.the rt-,;ultant SICIL 40 in prine.1ple, the
inter-
a,.-t'Lon between ghlarobenzene ~-,nd methy! dichlorssilane
prl-veed-='
ac.~~,vrd-ine to the saine scheme, inc.luding the abov,- The
resu-ts are shown. by figuTe 4, BIigh-tcnPo-I.-V.I-Ure
sopdew-,atlun ha,~-~
several advanta.-es ca -,,ordono~iJ-Ion c,.f hYdr-'Ole
U-rol-,atic C-OI!)P--)-LIIIds in the 1-iquiJ I' nay niso be
V~Pplilf---'I t-,
other chlorides. ".'here: are 4 f`eva-:-~s ct-cld 110
refle-renc-E:-ss 5 Of
vil-if.ch are Soviet.
ASSOCIATIONg Institut organicheskoy khiriiii im. N. D.
Zelinskogo Akademii nauk
S35R (Institute of Organic. Chemistry imen::: N.D. Zelinskiy
of 'hc-
A-2%ademy of Sciences, USSR)
SUBMITTED- Kay 22, 1-1159
Card 3/3

LI GUAN-LIM [Li Xuang-liang]; PETROV, A.D., nauchnyy
rukovod#e1l; CHKR
SHE;V.# Ye,A#,, kand, kbim, naukp nauchrory
rukovoditell-I
[Investigation of the bigh-temperature reaction of
silicon bydrides
with orgamic ehlaridm3 Issledovanie vysokotemperaturiiggo
vzaimo-
deistviia kremnii-gidridov s organicheskimi khloridami;
Avtoreferat
disser'tatsii na soiskanie uchenoi stepeni kandidata
kbimichaskikh
nauk. Moskva, In-t organicheskoi khimii im. N.D.Zelinsko
0, 1960.
13 P. f1MIRA 14: 10)
l.ChlerW-korrespondenty AN SSSR (for Petrovp Cherr#Bbev).
(Silicon bydride) (Chlorides)

fur z
vt H low,
If, -1
0: 0 P P
'kit k t, Uk
r
vit;
19; r J
- ;.;
Ixf 4
Ha
v it. P. v g ail 48~
2 q I
all I--;k
a v C', In
5 P. A Av I ; A
U'k
V V-P!
9- AUH
JIM
Rpi
-I _8

5 1700
7 -b( -) (--) "'
.
Sov/b2-1610- 4/ /.)7
AUTHOR:
Chernyshev, Ye.
A.
TITLE:
Radical Type Addition to '~/-Alkenylsilanes
PERIODICALt
Izvestiya Academli nauk SSsR -Otdeleniye khimicheskilch
-

iJ33.R)'
nauk, 1960, Nr 2, PP 80-83 (
ABSTRACT:
The reactions of
triethylviny-isilane, triethylallylsilane

and
diethylmethyl-'/-butenylsiiane with butyric aldehyde,

benza-ldehyde, carbon tetrachloride, and chloroform

were carried
out in the Dresence of benzoyl peroxide with
-

thy-1methyl-
heating. The reaction oi aldehydes with die
CZ)

-
./-butenyisilane yielded 3-metil~6-3-ethyl,-3-silanundecan-

8-one,
bp 227-1280 (3.5 mm)
1.4470; 3-methyl-3-
, n

.
D

ethyl-3-sila- 8-phenyloctaii-8-one, bp 16~-264' (3-5 mm),

n20
1.5168. The reaction of CCI and CHC1 with diethyl-
D 4 3

methyl-'/-buteny1silane yielded -1,Ll-trichloro-h methyl-

6-ethyl-6 silicooctane, bp 127-11290 (3 mm); n D

1.4647;
1,1,1,3-te'urachloro-6-rpethyl-6-ethyl-
Card IA~

Rzkical-Type Addition to CL-,
Y-Alkenylsilanes fj .1
78o68
sov,/62-60-1-14./37
-6-silicooctane. bp i-r-8-1300 (3,5 mm', n20 1~4860.
J D
The radical type addition reaction proceed readily
L
in the case of viny-l- and '/-butenylsilanes and slowly
in the case of allylsilanes. This indicates the presence
of conjugation of Si - C wi--b the doub--le 'bond in
position In respect to silicon atom. The possibipity of
the conjugation of Si - 'I-, bond is determined by the
nature of other groups or atoms attached to silicon,,
which determine the electronic structure of the SA - C
bond, There are 23 references, 1- Soviet, 5 U.S, and
I Japanese. The 5 U.S. references are, Burk1hard,
C~ A., Krieble, R. H., J. Am. Chem. Soc., 69, 2687
(1947); Seyferth D., Rochow, E. G., J. Org. Chem.,
20, 250 (1953); Goodman L., Silverstein, R. M.,
Gould, C. W~, J. Org. Chem,, 22, 597 (1957 Gordon,
A. P., Patent 2715113; Sommer L., Bailey D.., Goldberg,
et a!., J. Am. Chem. Soc., 76, 1613 (1954)~
ASSOCIATION: N. D. Zelinskiy Institute of Organic Chemistry of
the
Card 2/1 /9C "OE",Y
)I-

S/062/60/000/008/008/012
5.110

B004/BO54
AUTHORSi
Chernyshev
, Ye.
A., Dolgaya,
M. Ye., and Petrov, A. D.

'

TITLE:
~N:i~trati~qn
of
~Arqmq~tic Silicon
Hydrocarbons With Different

Position o
f the
Aromatic Ring
With Respect to the Silicon

Atom

PERIODICAL:
Izvestiya
Akademii nauk SSSR.
Otdeleniye khimicheskikh nauk,

1960, No.
89 PP. 1424-1428

TEXT: In the introduction, the authors discuss the papers
hitherto publish-
ed on the nitration of phenyl silanes (Refs. 1-10), and
mention a paper by
B. N. Dolgov and 0. K. Panina (Ref. 2). The authors attempted
the nitration
of the silicon hydrocarbons mixed with benzene (CH 3)3 Si(Cil
2)nC6115(n
- 1, 2, 3, 4) by means of "rival" reactions, and the
determination of the
relative activity of the o-, m-, and p-positions. The
nitration was carried
out by means of fuming nitric aoid in acetic anhydride at OOC.
A formation
of nitro-toluene, ethyl-nitro benzene, propyl-nitro benzene,
or butyl-nitro
benzene was not observed. Thus, the Si-C bond is not
sepsra~ed* Table 1
gives the yields in ortho- and para-nitro derivatives
(meta-derivatives
did not form). The high yield in ortho-derivatives in the
--ase of tri-
Card 1/2

Nitration of Aromatic Silicon Hydrocarbons With
S/062/60/000/008/006/012
Different Position of the Aromatic Ring With B004/BO54
Respect to the Silicon Atom
inethyl-benzyl silane is explained by the fact that the silicon
hydrocarbon
molecule forms a complex with the nitronium ion, in which Si is
bound tc
the oxygen of the nitronium ion, which facilitates the attack on
the orthc-
position. According to C. K. Ingold (Ref. 11), the relative
activity cf The
aromatic rings was determined in the series of compounds (CH )
Si(CH
while the activit of benzene was taken &a unity, Table 2 sh9w; that
the compound (CH 3~3 SiCH206H5(n - 1), in *w1lif'oh the benzene
ring is in
position to-the silicon atom, has an extremely high activity,
which cannot
be explained either-by sterio factors or by the inductive effect
of the
substituent. A conjunction of the Si-C bond with the aromatic ring
is as-
sumed to be similar to-the-conjunotive effect of the Si-C bond
with -.C-
or C-01. Stroctural formulas show the relative activities of the
ortho-9
meta-, abd para-positionsof the silicon hydrocarlt;ons
investigated and of
-some other benzene compounds (on the basis of R'efs.3, 16). There
are 2
tables and 1'6 reference ,a: 5 Soviet, 5 US, 5 British, and 1
Czechosl--vakian.
ASSOCIATION:
SUBMITTED:
Card 2/2
Iskstitut organicheskoy khimii im. N. D, Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N.-D.
Zelinskiy of the Academy of Sciences, USSR)
March 13, 1959

KORSHAK, V.V.; POLYAKOVA, A.M.; SALHAROVA, A.A.; MIRONOV,
V.F.; CHEUIYSJf3V,
Ye.A.
Polycondeneation of haloallql (haloaryl)halosilanes under
the influence
of metallic sodium. Vysokom. soei. 2 no.9:1370-1374 S 160.
(MDU 13:9)
1. Institut alementoorganicheakikh soyedinaniy AN SSSR i
Institut
organicheakoy khimii im. N.D. Zelinskogo AN SSSR.
(Silane) (Sodium) (Polymerization)

B023/B0064
AUTHORS: Qer A. and Tolstikova, N. G.
TITLE: Bromination of Some Aromatic Organosilicon Compounds
and the
Reactivity of the Bromides Obtained
PERIODICAL- Izvestiya Akademii nauk SSSR. Otdeleniye
khimicheskikh
nauk, 1960, No. 9, pp, 1505-1600
TEXT: This is a continuation of previous investigations and a
study of
the effect of the character of the silyl group (at a gradual
exchange of
the chlorine atoms in silicon for alkyl radicals) upon the
rate and direc-
,fton of the brQmination reaction. A series of compounds C 05
CH 2 Si(R)nCl 3-n
was brominated at n - 1 -.' 3. It was found that in the
bromination of
benzyl-ethyl dichloro silane just as in the case of benzyl
trichloro silane
the paraisomer alone is formed. When benzyl-diethyl chloro
silane is
brominated, chiefly the paraisomer forms and, to a very little
extent, the
metaisomer. Finally, in the case of benzyl.-trimethyl silane
para- and
metaisomers form to about the same extent. In the series
Card 1/4

4b
Bromination of Some Aromatic Organosilicon
S/062/60/000/009/007/021
Compounds and the Reactivity of the Bromides B023/BO64
Obtained
C6H5CH2Si(C2H5)n Cl 3-n only paraisomers form at n = 0 L 3,
regardless of the
number of chlorine atoms or alkyl radicals bound to silicon. In
continuation
of the studies of the reaciivity, equimolar mixtures of benzyl
trichloro
silane, benzyl-trimethyl silane, benzyl trichloro silane,
0-phenyl-ethyl
trimethyl silane were brominated~ Benzyl-trimethyl silane was
found to be
28 times as active as benzyl trichloro silane, while
P-phenyl-ethyl tri-
methyl silane is only 2.34 times as active. This incieased
reacti.vity of
benzyl-trimethyl silane is explained by the conjugation of the Si
- C
bond with the aromatic cycle. Furthermore, the fcllowing pairs of
com-
pounds were brominated: phenyl trichloro silane and benzene,
benzyl tri-
chloro silane and benzene, as well as P-phenyl-ethyl trichloro
Silane ani
benzene. In the first case, only benzene was brominated, phenyl
trichloro
silane remained unchanged. Benzyl trichloro silane was 4.7 times,
and
P -phenyl-ethyl trichloro silane was'5.B times more rapidly
brominated 'than
benzene. That means, that the reactivity of the series C1 Si(CH )
3 2 n
increases gradually with increasing n. Thus, in all cases only the
Card 2/4

Bromination of Some Aromatic Organosilicon
Compounds and the Reactivity of the Brom,-des
Obtained
7
induction effect of the trichloro silyl group
tion effect of the Si - 0 bond with aromatic
in benzyl trichloro silane. The reactivity of
5/062/60/000/'009/007/021
B023/BO64
appears, while the conjuglt
~ycle is completely suppressed
the aromatic organosilicon
S
halides R 3Si(CH 2)n\-===/ Br at n = 0 -'. 2 was studied as
compared to the
action of nucleophilic reagents. Methods of V. N. Ufimtsev
and M. M.
Malafeyeva (Ref. 6) were applied. Two series of compounds
were investi-
gated: (CH Si(CH Br and (C H ) ) '(/~ 'Br at n - 0 1 21,
WCH
.3 3 2)n 2 5 3 2 n \ ---- -- I
Table 2 shows the results. It was found that in the case of
the aromatic
bromides, c,(-bromides (n T)O) have a higher reactivity than
r-bromides
(n = 2).'P-bromides (n = were least active, Thus, the
existence of the
conjugation effect of the Si - C bond with the aromatic cycle
is confirmed
in these compounds. If there were only the induction effect
of the
trialkyl-silyl'group, the reactivity would have to decrease
gradually~
The authors thank Yu. P. Yegorov and I, Lifanova, who carried
ol-.t
the spectral analysis, There are 2 tables and 7 references: 6
Soviet and
Card 3/4

Bromination of Some Aromatic Organosilicon s/o62/60/000/009/007/021
Compounds and the Reactivity of the Bromides B023/BO64
Obtained
1 British.
ASSOCIATION: Institut organicheskoy khimii im. N.D, Zelinskogo
Akademli
nauk SSSR (Institute of Organic Chemistry imeni N. D.
Zelinskiy of the Academy of 3(:4ences USSR)
SUBMITTED: March 13, 1959
Card 4/4

U-1121
5AIN
S/0 6 ?/-_Q/'00"`/O09/0G8/0 2 1
B02 3/Bo64
AUTHORS: and Petrov, A. D.
,~e)L, Ye. A., Klyuk'~na, E. N.,
TITLEt Acylation of Silicon Hydrocarbons and Synthesis of the
Silicon-containing Alpha Methyl Styrenes
PERIODICAL: Izvestiya Akademii nauk SSSR, Otdeleniye
khimicheskikb
nauk, 1960, No. 9, pp. 1.601-1606
TEXT: This paper continues previous investigations (Ref,. 1).
The authors
aimed at improving the method of acylating the aromatic
silicon hydro-
carbons previously developed by I. A. Kulish (Ref. 3).. At the
same time
they explained the problem of the reactivity of benzyl- and
P-phenyl-ethyl
trialkyl silanes in the acylation reaction, A method of
competing reactions
was applied to determine the relative reactivity of
trimethyl-benzyl
silane and P-phenyl-ethyl trimethyl silane. A mixture of one
mole benzene
with one mole P-phenyl-ethyl trimethyl silane or with one mole
trimethyl-
benzyl silane was acylated by one mole of the acid chloride of
capronic
acid with one mole aluminum chloride. Trimethyl-benzyl silane
was found to
be 24 times as active as benzene, while P-phenyi-ethyl
trimethyl silane
Card 1/3

Ej,71.).1
Acylation of Silicon Hydrocarbonfi and Synthenia
S1062160/000100910081021
of the Silicon-containing Alpha Methyl Styrenes B023/BO64
was only 16 times as active in the same reaction.. It, is
obvious that-he
increased reactivity of benzyl silane is due to the
conjugation of the
Si - C bond with the aromatic cycle. Organosilicon ketones
were obtained
in yields up to 7qc when studying the competing reactions,
while the
maximum yields of the previous studies were 35%. The
authors' assumption
that the yield in organosilicon ketones would have to be
highm~r if the
reaction were carried out in benzene solutions, proved to
be correct. At
a molar ratio silicon-hydrocarbon ; benzene equal to I : 2
to 1 : 4 in
the solution, the yield increased considerably, Table 1
shows the com-
parative data on the yield when the old and the new method
was used. All
ketones were obtained with reaction in the benzene
solution. Table 2 shows
the formula, the yields, and properties of the ketones
obtained.. Corres-
ponding alcohols were obtained from the parasubstituted
acetophenones with
the help of the Grignard reaction using CH 5MgCl; the
alcohols were de-
hydrated to styrenes. Partial dehydration of the forming
alcohols took
place already in the course of the-reaction. Only in two
of four cases
alcohols were obtained in the pure state. Table 3 shows
tho formulas and
properties. Alcohols and the fractions obtained in the
cours,~ of distil-
lation, which corresponded to the mixtures (Nf styrenes
with al,_-~,ho'_'s-,
Card 2/3

87121
- /1 -0 ~
Acylation of Silicon Hydrocarbons and Synthesis S/062 27
of the Silicon-containing Alpha Methyl Strrene~-- B02--l'BO64
were dehydrated. Alcohols, with three silicon valences saturated
with
methyl radicals, were subject to dehydration already when boiled
with
KESO 4' Alcohols, in which three silicon valences were saturated
with ethyl
radicals, were only partially subject to dehydration with KHSO V
There are
3 tables and 8 references: 7 Soviet and 'I British,
ASSOCIATIONs Inatitut orgunichoskoy Ichimil im. N. D.
"llol.in:,kogo Akftdem~i
nauk SSSR (Institute of Organic Chemiotry imeni
N. D. Zelinskiy of the Academy of Sciences USSR)
SUBMITTE,D: March 13, 1959
Card 3/3

87167
S10621601000101210061020
urs, -gn,~ B013/BO55
AUTHORS: Che,3zny~sbax, Ye - A..., Mironov, V. F. , and Petrov,
A. D.
TITLE: New Method for the Preparation of Organosilicon Monomers
by High-temperature Condensation of Alkenyl Chlorides,
Aryls and Olefins With Hydrosilanes (Expression used to
denote silanes in which the silicon contains at least one
unsubstituted hydrogen)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye
khimicheBkikh nauk,
1960, No. 12, pp. 2147-2156
TEXT: The present publication treats the investigation of
high-temperature
condensation as a method of preparing organosilicon monomers. A
method for
the syntheais of vinyl silane chlorides (the expression
11silane chloride"
is used by the author to denote that all available hydrogen
atoms bound to
silicon are replaced by chlorine) was developed at the
laboratoriya khimii
uglevodorodov Instituta organicheskoy khimii AN SSSR
(Laboratory of
Hydrocarbon Chemistry of the Institute of Organic Chemistry AS
USSR). Its
practical realization, however, meets with difficulties. For
this reason
Card 1/4

87167
New Method for the Preparation of Organosilicon S/06
60/000/012/006/020
Monomers by High-temperature Condensation of B013YB055
Alkenyl Chlorides, Aryls and Olefins With
Hydrosilanes
the authors at the same time investigated another method, the
uncatalyzed
high- temperature condensation, basing their study on
publications by
C. L. Agry (Refs. 4, 6). In this investigation, which was
started in 1956,
the authors tested the general validity of the reaction
described by Agry
and extended it to complicated hydrosilanes (Refs. 8, 010-17).
The optimal
conditions for this reaction were found to be 580-590 C and a
contact time
of 20-25 see. The simplicity of the required apparatus,
accessibility of
materials, safety and high yields render this reaction one of
the most con.-
venient of the existing methods for synthesizing vinyl silane
chlorides. The
authors studied the high-temperature condensation with vinyl
chloride of
all the hydrosilanes of the series HSiR nOl 3-n (n = 0, 1, 2,
and 3). Yields
of up to 80~L were obtained with trichloro silane (n = 0).
Trialkyl silanes
(n=3) gave no condensation reaction (Fig. 1). This compound
gave a different
reaction which the authors termed a reduction to distinguish
it from the
condensation: R3SiH + ClCH=CH2 ---> R3Sicl + CH 2= CH 2* The
authors also dis-
covered a new type of interztction between h.),drosilanes and
olefins (ethylene
Card 214

87167
New Method for the Preparation of Organosilinon
S/062/60/000/012/006/020
Monomers by High-temperature Condensation of B013/'BO55
Alkenyl Chlorides, Aryls and Olefins Witb
Hydrosilanes
and propylene)(Fig. 2) which represents a novel reaction in
the organic
chemistry of silicon: CH =CH + 11sicl -60000, cjj,=cjjsjcj3 +
11 2' Baoing on
2 2 3
the inventigation carried out the high-temperature
condensation of hydro-
chloro ailanes (Ilsicl,, RSiCl2H) with mono- and polychloro
alkenyls may be
claimed to constitute a new, generally npplicable and
convenient method of
synthesizing unsaturated organosilicon monomers (Table 1).
Pundamentally,
the reaction is an entirely new way of forming Si - C bonds,
and may be
described as homolytic silylation. Apart from the three
existing methods for
the synthesis of aromatic organosilicon monomers, the authors
suggest a
fourth method, the reaction of hydrosilanes with aryl
chlorides at high tem-,x
peratures (550-7000C) and atmospheric pressure, i.e., in the
gae phase
(condensation): RCl + HSiR'"l -4 RR'SiCl 4- HC1; R = aryl, RI
= CH or
11' 3-n 3-n 3
C2H5; n = 0, 1. Some of the results viere published earlier
on (Refs. 13,
29-33). They are given in a generalized form in this work.
Reactions of this
type have been patented (Refs. 34, 35), the necessity of a
catalyst being
indicated in both publications. The authors, however, were
able to show
Card 3/4

87167
New Method for the Preparation of Organosilicon
S/062/60/000/012/006/020
Monomers by HiCh-temperatture Condensation of 11013/11055
Alkenyl Chlorides, Aryls and Olefins With
Hydrosi lanes
that thp condensation of aryl chlorides and hydrosilanes to
aryl chloro
0
siltinco proceeds quite satisfactorily at 550 -7000C in the
absence of a
catalyst. The reaction vas carried out in an empty heated
quartz tube by
pass-in.i- through the aryl chloride/hydrosilane mixture at
rates permitting
contact times of 10 to 100 sec. This enab-les the reaction to
be performed
in a continuous process. The material of the tube is of
principal importance.
Yields of various aryl chloro silanes obtained in this manner
are giver, in
Table 2. The method can be applied for the preparation of
arbitrary aryl chlo--
ro silanes with 2 or 3 chlorine atoms bonded to silicon.
Monomer yields are
about equal to and in some cases even higher than the yields
obtained in the
catalytic reaction of aromatic compounds with
hydrosilanes.There are 3
figures, 2 tables, and 37 references: 28 Soviet, 7 US, 2
British, and
1 Czechoslovakian.
ASSOCIATION: Institut organicheskoy khimii im. N. D.
Zelinsko~:u Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D~
Zelinskiy of the Academy of Sciences USSR)
SUBMITTED: June 27, 1959, supplemented September 24, 1960
Card 4/4

CHFIWSHEvt Ye. A.
condensation of silanes with aryl chlorides; a
method of preparing arylehlorosilanes. Coll Cz Chem
25 no.8:
2161-2166 Ag '60. (MI 10: 9)
1. Institut organiabaskoy Ichimli Akademiya nauk
SSSR, Moskva-,
(Silanes) (Aryl groups) (Chlorosilane) (Chlorides)

ATITHORS
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ABSTRACIP:

die catal
oxi

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-ields div4ny'ber,,ze~;e and -r-i ~z - .r~

aration of 511arles,

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added wlth, st 1 r,1

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Synthesis of Allphatic-Aromati--:

Their DeInydrogenation,
i z
un 8'
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j

(7,61" C'.i s I

'0
T

-T
ci 1 Ql.c~ ~
h

D

4'-) w a p re p a f

c1,
reac-en, to vii i i c

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was heat,e'ci for 4
hlal.~rl'

priat'on of (1)

a mixture on a --iA
'a
s e v 0, --'a 1
1, L a - ~- 1-0

S

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Syntj-~e~3t~; of' Allp-hatic-Aromiatic SIlanu,-,
. , _P Y)
S C)IJ I
Their Dehydrogenation -Ui , -
di-[[~3'-(methyldici-iloi,c)sil,,,1 lethyil -benzene I T ) failed
to prOdUce a liquid product of catalysts, Dehydrogenation
of trinthylsilyleth, lben.-ene ove.- the s~,!?e catalyst at
0
550-560 yielded 87% of a product, n .49-5. C h r oi,,-, a -
tog-aphic analysis of T~ h eobtaine.~! gas Ind,11.catej that it,
contains 39.2% methane at'~] 5`5-7% DL;3 t 1 11. at- 1 on
11
01 catalyzate oduced three fractions: first, tp 28-
0 4 1 0
b8 (25 mrp) , n D 1 - "855; second,, b9_100 ( 2 mm
1.5003; third, bp 102-io6o (?5 mm,, I DIs'll-
D
lation of 1-he catalvsls )vcduct av,.d analysis of the ob-
ttilned gas indlcate-rhat'alorg wltuh dehydrogenation a
decomposition of (III) to by-products takes place. The
-:_,xpevi!nent5 with compouna (,T TI ave being conti ued. De-
h- -1 L,ogen al, s 0
JU Lon of trichlovoctlh, _,ilan , 1); 97-1.b, r120
D
1.14'~)70, ove'r oxld~ 1
C! - C~
ferric nll-rale, at
of this compound takes place wlt.h the fo-mation of side