SCIENTIFIC ABSTRACT D.M. CHIZHIKOV - D.M. CHIZHIKOV

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000308920002-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 12, 2000
• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

C'Z//Z_
Subject
Card 1/1
Authors
Title
Periodical
Abstract
USSR/Chemistry
Pub. 152 - 8/22
A ID P - 917
Chizhikov,, D. M. and Smirnov, M. P.
Removal of zinc from lead-zinc alloys by the vacuum method
Zhui,. prikl. khim., 27, no. 5, 514-526, 1954
The optimum temperature for this process is 6000C. At that
tem erature the highest amount of zinc can be extracted
96p
_98%), and the condensate contains the lowest amount of
lead (0-03-0.07% of the initial amount). Seven It-lables,
14 diagrams, _ Perences (2 Russian: 1935-1951).
Institution State Institute of Nonferrous Metals
Submitted Ja 17, 1953

FD-2627
Card 1/1 : Pub. 41-13/21
Author : Kreyngaus, B. P. and Chlzhikov, D, M., Moscow
Title : On the mechanism of the reaction of oxidizing cobalt,
in so-
lution, with ozone.
Periodical : Izv. AN SSSR, Otd. TWEh. Nauk 4, 141-142, Apr 1955
Abstract : Describes tests whereby cobalt, in solution, is
oxidized with
ozone. Concludes that the reaction is ionic with a simultaneous
hydrolytic separation of cobalt. Photograph of test apparatus.
Three USSR references.
Institution
Submitted February 25, 1955

USSR/Emgineering - Metallurgy
Card 1/1 Pub. 41-n/17
FD-2930
Author : ChizhikoyL D.,.M., Gulyanitskaya, Z. F. and
Bogovarova, N. N.,
Moscow
Title : Electrical and thermal conductirity of certain
copper nickel
sulfide alloys
Periodical : Izv. AN SSSR, Otd. Tekh. Nuak) 6, 109-113)
June 1955
Abstract : A study of the compositions of alloys of copper,
nickel and iron
sulfides. Presents relationships betveen amount of iron and
the
specific electroconductivity and thermal conductivity of the
copper-nickel mattes. Tables, graphs, formulae. One
reference,
USSR.
Institution
Submitted February 25, 1955

GVUWIANI. GsG.;MDNT5MTA.T.Yo.;CBIWIK(W. D.M.
-- OWA" -9=*-AA%e4O
Kinetics of the carbon monoxide reftation of
copper oxide.
Inv. AN SUM. Otdo.tekboasuk se.8:140-144 AS 135.
(NLU 9s1)
(Ce"or oxidt) (Carbon mosoxid#) (Reduction.
Chemical)

USSR/Engineering - Metallography
Card .1/1 Pub. 41 - 13/15
FD-3029
Author Kreyngauz, B. P. and Chizhikov, D. M., Moscow
wMMMMWMbftWMKftW*Ab-
Title On the effect of oxygen and the role of sodium sulfite
tn the process
of the cementation of cobalt from solution by metailic zinc.
Periodical Izv. AN SSSR, Otd. Tekh. Nauk 9, 167-169, Sep 55
Abstract Presents the results of a study on the effect of
dissolved oxygen and.
the role of sodium sulfite on the cementation of cobalt from a
solu-
tion of its sulfate by metallic zinc. Describes experiments
conducted.
Live drawing depicts set-up. ConcludeE; that dissolved oxygen
has a
negative effect on the rate and degree of cementation of
cobalt.
Graphs. Five references, 4 tJSSR.
Institution:
Submitted : May 3, 1955

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GUROVICH, N.A.; CHIZHICOTO D,K,; DXKISOTko G.K&
Hydrolysis of solutious of indium sulfate. Ttudy Inst.
met. U0.21
78-86 156. (MM& 10:11)
Ondium sulfate) (Hydrolysis)

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USSR/Physical Chemistry - Surface Phenomena. Adsorption.
Chr.-.satograpby. IDn
Exchange., B-13
Abst Journal: Referat Zhur - Rkdziya, No 19, 1956, 612G7
Autbort Chizhikov., D. M.., Alltshulerj, 0. V.
Institution: None
Title: On Adsorption of Selenium on Activated Caf$;ns
Original
Periodical: Zh. fiz. khimii, 1956, 30, No 1,, 220-222
Abstract: Study by means of ~r-radioactive Se75 of Be
adsorption under dynamic
conditions on activated carbon AG and KO from mixture of Se
and S
vapffp in argon, obtained by evaporation of Se-S melts
containing
O.d6-5% Se. In all Instances the Se/S ratio at the adsorbent
is
2-5-3 times greater than in the melt and 5-6 times greater
than in
the vapors. With Increase of temperature adsorption of Se
decreases
sharply. On desorption S is removed moze completely. 15-24 Se
are not removed even on heating to 1,0000 and by action of
different
solvents: Na2S, pyridine, H2SO4, HN03 and alkalip this
portion of
Card 1/2

USSR/Physical Chemistry - Surface ndmena. Adsorption.
Chr-matograpby- Ion
Exchange"B-13
.9
Abet Journalt Referat, Zhur - XhImiyap No 19.. 1956, 61207
Abstract: Se is irreversibly chemosorbed or forms a solid
solution of Se in
carbon. The main portion of Se is adsorbed physically.
Card 2/2

C V"'i z ~1 -1 k, ') JI D. ri .
AUTHOR: Pakhomova, G.N. and-Ohizhikov, D M. 285
TITLE: Influence of the anode material on the electrode deposition
of cadmium. (Vliyanie materiala anoda na elektroosazhdenie
kadmiya.)
PERIODICAL: IlTsvetwe Meta3 *711 (Non-ferrous Metals),
177, No. 1, pp. 46 - 49, (U.S.S.R.)
ABSTRLCT: The investigation described had the object of finding
conditions for the electrolytic production of cadmium with the
total content of impurities not exceeding O.Olya. For this
degree of purity the material of the anode is important, and
lead-containing anodes weie found to be unsatisfactory.
Suitable anode matqAals were found to be 14;17.) silicon cast
iron. With such electrodes the optimal conditions for the
electrolysis with pure electrolytes are current density at the
cathode of 60 amps. per sq. m, temperature 35 0 and lower
cadmium-concentration limit 20-30 grams per litre. Under these
conditions, the anode consumption rate is 0.009 gram per
ampere/hour. Impurities in the electrolyte should not exceed
the following values: 1 mg/litre Cu 20g/litre Zn, 3 g/litre
Fe, 1 g/litre Ni, 0.5 g/litre Co, O.~ g/litre TI and 12 g/litre
Ma. Oxidation of impurities' does not occur on silicon-iron
anodes, and for this reason the presence in the electrolytes
of manganese, Jxon, chlorine and thallium ions does not
decrease the yield of cadmium.
There are 3 refeiences, of which 2 are Russian.

/fo 14'
j)
137-1957-12-23524
Translation from: Referativnyy zhurnal, Metallurgiya, 1957,
Nr 12, p 98 (USSR)
AUTHORS: Kovylina, V. N., Chizhikov, D. M.
TITLE: An Investigation of the Anodic Polarization of Alloys
of the Sulfides
of Copper, Lead, Zinc, and Iron (Issledovaniye anodnoy
polyarizatsh splavov sullfidov medi, svintsa, tsinka i
zheleza)
PERIODICAL: Tr. In-ta metallurgii AN SSSR, 1957, Nr 1, pp
70-77
ABSTRACT: A study of the anodic polarization of tf.--
sulfides of Pb and
Zn, as well as of certain alloys of the sulfides of Cu, Pb,
Zn,
and Fe. The potential was measured by the compensation method
by means of a PPTV potentiometer. A saturated calomel
electrode
served as one of the half-elements, whereas the other one was
com-
posed of the alloy being studied, immersed in an appropriate
solution. The sulfides of Cu, Pb and Fe were obtained by
heating
the mixtures of the pure metals and S. The powdered sulfides
were then melted in a Silit furnace and held at their melting
tem-
peratures for a period of two hours. The alloys of the
sulfides
were prepared by fusing mono-metallic sulfides. Anodes of
Card 1/2 2Ox25x5 mm were cast with the sulfides of the alloys
and Pb-.

137-1957-12-23524
An Irtvestigatfoti-.of.*the:-AnodibI.PolarizatLon of
Alloys (cont.
sulfide. The temperature of fusion was IZOOO The cooling
was
accomplished in air. The changes in the potential were
deter-
mined with the following Da values: 50, 100 150 200, Z50,
300,
350, 400, 450, 500, 550, 600, 650, 700 a/m~. The potential
was
measured 1 min after the given D had been established. It
was
established that an increase in the temperature displaces
the
potential of the sulfide alloys in the direction of the
electro-
negative values and moves the potential jump into the area
of the
higher D's. The anodic dissolution of thetmma~r alloys of
the
sulfides of Cu, Pb, and Zn should be performed at a tern
erature
of 500 and with a value of D not exceeding 250-300 a/m The
electrolysis of the quaternary illoys of Cu, Pb, Zn, and
Fe should
be performed at a temperature of 500 and a D which does not
exceed 500 a/Mz.
G. S.
1. Copper sulfides olloys-Anodic polprizption 2. Lead
sulfides
alioys-Anodic polrrizetion 3. Zinc sulfides alloys-Itnodic
polerizption 4. Iron sulfides P.1loys-Anodic polerizetion
Card Z/z

k, A', T".
137-19571-12-234721
Translation from: Referativnyy zhurnal, Metallurgiya, 1957,
Nr 12, p 9Z (USSR)
AUTHORS: Pliginskaya, L. V., Chizhikov, D. M.
TITLE: InvezAigation of the'Ca'thodic -PolariZiltion of
Nickel in Sulfate
Solution* (Ijsledovaniye katodnoy polyarizatc-ii nikelya
sullf,itnykh tastvorakh)
PERIODICAL: Tr. In-ta metallurgii AN SSSR, 1957, Nr 1, pp
78-84
ABSTRACT; A presentation of the recults of art
investigation of the cathodic
polarization during the precipitation of Ni from sulfate
solutions
as a function of the temperature, the pH of the Eolution,
the con-
centra.tion of the metal, and the preFtence of Cl iowi in
the electro-
lyte. The initiaJ sulution war, prepared with highly
purified
eJectrolytic Ni (99.99 percent Ni). The cathodic
polarization
was measured at: D = 20 - 400 a/m2, while thick Ni
precipitate
was observed; the pH of the solution varied from 1 to 6. The
greatest variation of the potentials was observed at a pH of
2.5 - 4.5 (140 mv 0-atof 170 mv), whereas at a pH of 4.5 -
6.3 the
change in polarization was rather small and constituted
approxi
Card I/Z mately 30 mv. The addition of 30 g/lit of Cl ion
lowered the

;~7 1957 i~-~3472
Inv e b t i ga-1--io-1 Of tl-Lr~ Cat liodf-c, Po .1 a
ris-aC'--'n of I\T.*-~.C 'cont . I
. k . I
polarization by 20 mv. Tile influence oi the NaCl on tile
extent.
of the polarizati*n is more pronounced in the preFence of
boric
acid. If no boric acid iF present and the 30, 40, and 60
g/lit
Nickel solutions are in the form of NiSO 4' the polarization
of
Ni diminishes with increasing concentration of N;. in the
--olution.
Raising the concentraticn of Ni from 30 to 60 g/lit- at
D=?00 a/m?
reduces the po3arization by 30 mv. Adding 5 g/1:4-, boric
acid to a
solution containing 50 g/lit of Ni, at a temperature of 600
and a
pH of 5.7. increases the polarization by 25 mv, an additicn
of
20 g/lit boric acid, at D= 200 a/m" , increases the cathodic
polarization by 75 mv.
G. S.
1. Nickel-Cathodic polc~rizrltion 2. Sulfate
solutions-Applieptions
Gard Z/?.

V
137- iQ57- 12-23487
Translation from: Referat.ivnyy zhurnal, Metallurgiya. 1957 ,
Nr 12, io 93 (USSR)
AUTHORS- Rvabov. V. A., Zviadadze. G. N., Allt:~huler. 0. V..
Chizhikov, D. M.
-----------
TITLE: The Reaction of Titanium With Its Tetrach"loride
(V2,aimodeyatviye
titana ,-. ye8o tetrakh1oridom.)
PERIODICAL: Tr. In-ta metallurgii AN SSSR. 1957, Nr 11, pp
85-92
ABSTRAC'r: A study of the condition-.% nece5.,;ary for the
formation of the
lowe.-t chlcride5 produced by the reaction of Ti w; th TiC34
* Twice-
distilled T;-C~'4 was employed in the experimentL. The
po%vdered
Ti, a metal obtained by means:- of magnesium-thermal process
foilowed by vacuum distillation, contained 99,7 percent T;.
The
partial pressure of the TiCl '4 was computed from it, lose.
in the veF:sel and from the volume of Ar passed in the
cr;ur-,e of
the experiment. The purification of Ar wa-- acccmphiihed by
passing it through a layer of Ti-sponge hedted to a
temperature
of 7006- 8000. Prior to the introduction of the TiC14
vapor.;. Ar
was blown through the cold reaction tube, The furnace was then
turned on and the TiCl w1s introduced Into the tube after the
Card 1/2 necess-ary experimental temperature wa5 reached.
After "he

j 37-1957 -1 C`2,3487
The Reaction of Titanium With -Ttr, Tetrachloride
comp)etion of the reaction, the reaction products were
extracted
from the tube in an Ar stream and -were then
investigated. It
was established that the reaction of Ti with TiCl4 iz
affected by
the temperature and by the partial pressure of TIC14 ' At
tern-
peratures between 300 and 5000 the reaction produces
TiC12 I
along with TiCl, .
whereas higher temperatures produce TiC13 in the range
The most likely reaction between Ti and TiCI4
inve,-.tigated (300 - 9000 ) is described by the formula:
Ti+ TiCI 4 =T-LCI2
G. S.
1. Titoniwn reaction 2. Tetrachloride-tipplications
Card 2/2

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