SCIENTIFIC ABSTRACT V.T. CHUYKO - T.A. CHUYKOVA
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SCIENTIFIC ABSTRACT
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USSR/Metals AnalYsis, Zinc Nov.50
"Accelerate Method for Determination of the S-1 I
Quantities of Copper in Zinc," V. T. ChuykO,,A. Ya.
Shebelkanovtoeva, Donets Industrial Inst
"Z&-Yrod Lab" Noll, -vP 1309-1312
Method is based on partial pptn of zinc with alkali
hydroxide with successive detn of coned copper with
diethyld.ithiocarbamte of sodium in alk medium. '
Under these conditions, coloration of copper carbo-
nate is more stable than A the weakly-alk, neutral
11"74
UM/Pt,et~alg, ~-Ans,13rsis, Zinc (ContA) Nor 50
or* acid media and may be more easily measured col*ri-
metrically- than in soln of carbon tetrachloride.'
Lowest copper concn, which may be detd by this method"
in o.ooo4%.
0
1,
18M.741
Rapid aetermumbas at antall qunddes a copw to amt.
u,%;u,,1gA, Va. Shcbelkanoviseva (boarts Ind.
W. M. little as
O.tXPGI7oCu in Zn can bedeid. by tbe.'%Ia carbamale method
after suitable vonen. in elk. soln. The conca. is best done
by %thin. of 2 N A011 atsd centrifuging the ppt. which is
tht-ta tal,en tip In 601,"a citric acid aim) analy" rolorimetri-
CAY. G. M. KometAl-Off
~S~R/Chemlstr .-,Analysis, Nickcl-,l Sep/6ct 51.
y
Method's for Determination ofi
Traces of Vickel. III. Determination of 1,iickel
in a Mixture of Cations of the Third ltnalyti-
cal Group," V. T. Chuyko, Donets Ind Innt"I
Stalino
"Zhur Analit Khim" Vol V1, No 5, pp 297-299
To detn traces of metal in complex mixt 1'rom
vhich inhibiting substances muet be sepd,
concn process can be worked out based cn re-
peated repptn of subject metal with different
collectors, or on combination of this method
:UWR/Chemistry Analysis, NicRel S_avbct 51
(Contd)
4ith partial pptn of collector if partial jpptn
with given collector -microc: omponent patr leads
t.6:1 quant concn. Proposes procedure f or'c,oncn
~."of , Ni. from mixt of Al, Cr, Fe, Mn, Co, Zn
18~T12
OR M 0. Y.T.: LOTARRVA, V.I.
Concentration procedure
rhim. Zhur. 16, 612-15
(cA-47"iioJl.-llo7i *153)
l.,DoU Ind. Inst.
T-
YSSR/Physical Ch-Istry - Thexmodynamics. Thermochemistry. Equilibrium. Physico-
chemical Analysis. Phase Transitions, B-8
Abst Journal: Referat Zhur 103imiya, No 1, 1957p 357
Author: Chuyko, V. T.
Institution: Cherkaolk State Pedagogical Institute
Title: On the Applicability of Xhlopin's Iaw to the Distribution in Systems
with Close Comppnent Ratios
Original
riodical: Nauk. zap. Cherkas1k. derzh ped. in-tu, 1954, No 6, 55-58 (published
P
in Ukrainian)
Abstract: It is ohm that the Kolthoff equation (H. C. Jutzy and L 14. Kolt-
hoff, J. Amer. Chem. Soc.., 1937, ~Z 916), vhich gives the distribu-
tion of 2 4ctrolytes betveen the solution and the residue at equal
concentrat~:Mns of the components, is identical with an equation which
had been deduce& earlier (Ratner, Tr. Goo. radievogo in-ta, 1937,
Vol 3) and which gives a theoretical formulation of Khlopin's law.
In the opinion of the author, it may be considered as established that
Card 1/2
,USSR/Physical Chemistry - Thermodynamics, Therpochemistry. Equilibrium. FhYsico-
chemical AnalypU. Plane Transitions, B-8'.
Abet Journal: Referat Zhur - IQ)Imiya.. No 1y 19", 357
Abstractt Xhlopinle law iEI applicable over a wide range of component ratios.
Ratner's equation gives a more exact description of the distribution
of the 2 electrolytes than Kolthoff's equation,
Card 2/2
Distribution of small quantities of hUmpth betweeft thO
solution of copper nitrate and the precrptritro-ottained with
-11, 1 "
basic salts.-V. 1'. ChtlTk-o and4. D. Gol'tsomn (N. S.
~hul4hchiv Ti-on-TR"r =nst.) Orr-a-1117TE-7 -Mur. 20,
K"tiT154,Kin Russtaill).-Ftic distribution of Ili was
stadied by varying the conen. of 111 (0.02-5 ing. lit 10 nil.).
time of contact (6-30 tuln.). concit. of Cu (0.1-0.0125 g.1
mi.), Anti On. (0.05 mg. Ili in 16-100 nit. of qo1u.). The
reversibility of the process wits also studicil. Partial pptn.
df Cu wai done with NaC(h or NaOll. At 5 nig. of III In
10 mt. of soln. All of it %vent Into the ppt. At 0.02-0.25
mg./10 ml. the distribution of 131 t)ctwrctt soln. and ppt.
was pructleally const. Time of conuct (slinking) had no
significant effect beyond 5 min. The promw; was reversible.
This was established by slinking FL Co lipt. contg. Bi with
a CUNO, soln. free of Bi. Win. of the original soln. (10
mi. contg. 0.05 trig. Bi) from 15 to 100 mt. caused more D1
toconeentrateiritheptit. Reducingtheamt.ofiCuInsoln.
had a'stmilar effect. It Is concluded that adsoTlort of III
by basic Cu salt is cs-wittially an exchange reac: on.
Iloseh,
ORMO. V-T.: CHUM). K.G. [Chujrko, K.H.]
~
Using the asudidcromethod, in studying qualitative analysis at the
Teachers' Institute. Nauk. zap. ChDPI 8:11-14 156. (MIRA 11:2)
(Hicrochemistry)
(Cherlmsey-Teachers, Training of)
MAKRIKO, A.U.; CHUYKO, V.T.
Coprecipitation of copper tracee with the 8-hydroxyquinolinates of
some metals. Nauk. sap. ChDPI 8:109-112 156. (MIRA 11:2)
(Copper) (Quinolinic acid) (Chemistry, Analytic--Quantitative)
J,
F
Chill 0 an
Yk
46i p)
'fu It tile vpt,
so
tbO
b the thl
~11. wconft eaq~: w~
I' edikied NO
ir
progrc-451110 v I
alfitmilt of
"I - I ~ -d:'
f M-PbU I rot, of xri:.tcetatc
D (i,,j 2 J
9911, of tho'Cu-when SO jig is initially Inc-swrit, an
;Ient,'
%~Iwn 5 to 10 jsg~ is initially lire.
dy "4 to,
d the jcAll: ~lt liffle
c(liniplete c1l, Ire
Ca!;~s.-r,1j6fi the S-Ilydtoiy&juiaqbnl~ oiniploxci
-ara*extra ded with cflcj~'_ fijllp~'cd h'Y treatillent of
tho extmct witi, U NO, ~md C."dracHall of ('11 froul
the acid extract ivith dithirulle Covi-l mil bu
;act,- stilt, A I d will il"I by
"em -A - . I - - - -- ;, .- .
of -ti
acticin
'0 c is hilothod upp it-d to sal s of Ni uA 6)
I
su errmll--c-11 is incompt"10
is _y extrveted
Und Santa of thr. Ni nr Co apiwio-H in th,.- cllcl~
thu ivors.
X ~'O,
AUTHOR: Chuyko, V. T. 78-3-29/35
TITLE: Methods of Concentrating Traces of Metals by Entrainment
in it Precipitate. I. Concentration by Co-Precipitation.
(Sposoby kontsentrirovaniya sledov metallov uvlecheniyan
v osadok. 1. Kontmentrirovaniye soosazhdeniyem)
PERIODICAL: Zhurnal Neorganicheskoy Khimii, 1957, Vol.II, Nr.3,
pp. 685-695. (USSR)
ABSTRACT: Conditions have been found which secure over 90% co-
precipitation of traces of metals forming slightly
soluble hydroxides with the hydroxides of other metals
during concentration by precipitation of the collector-
substance by excess reagent and by partial precipitation
of the macro-component as hydroxide. For the first
method of concentration this requires a pH value for the
solution greater than that for the precipitation of the
hydroxide of the metal being co-precipitated; the
attainment of the solubility produet of its hydroxide
is not then of prime y importance. Nor is the
Card 1/2 relatively complete eo-precipitation affected by the
78-3-29/35
Methods of Concentrating Traces of Metals by Entrainment in a
Precipitate. I.
ptesence of other electrolytes, differences in
properties of the hydroxides of the metal being
concentrated and of the collector, temperature, the
duration of ageing the precipitate after co-preoipitation
or the order in which the reagents are added. For
concentration by the second method a definite, empirical
ratio between the macro-and micro-component concentrations
must be attained; otherwise the micro-component
distributes itself between the solution and the precipitate
in the normal way. There are 10 tables and 16 referenees,
of which 13 are Slavic.
ASSOC IATION.- 'Chetka say Pedagogical Institute. (Gherkasskiy
Padagogicheskiy Institut.)
SUBMITTED: June 25, 1956.
AVAILLBLE: Library of Congress.
Card 2/2
( u Xkc / I,` ,
CMNKO. V.T.
-r
Distribution of an electrolyte admixture between the salt solution
and crystals of the other electrolyte. Zhur.neorg,khim. 2 no.9:2264-2269
3 '57. (Min 10: 12)
l.Charkasekiy pedsgogichoskiy institut.
(Ilectrolytes)
SOV/137-58-11-23815
Translation from: Referativnyy zhurnal. Metallurgiya, 1958, Nr 11, p 277 (USSR)
AUTHOR: ChuykQ ['Ghuyko, V. T.
TITLE: of Copre`cipi"t'~a_ti,2o"4n_, With Metallic Hydroxides of Metallic
Irnpurities Which Form Dissolution-resishint Hydroxides (K %-opl'ostl
soosazlideniya s gidrookisyami metallov prinieseyn-etallov, obra.,uyu
shchikh trudnorastvorimyye gidrookisi)
PERIODICAL: Nauk. zap. Cherkas'k derzh. ped. in-t, 1957, Vol 11, pp 335- 34 3;
in Ukrainian
ABSTRACT: An examination was made of the phenomenon of coprecipitation (C)
of Cu (N.i) with basic salts (hydroxides) of Fe and Al from dilute solu-
tions and also of adsorption (A) of Cu (Ag) on Mn02. C was performed
from bicarbonate solutions while Cu was precipitated from acetate
solutions under -conditions in which 30 - 700/o of the metal would be
included in the precipitate. The author notes that extraneous electro-
lytes have little effect on Cu, whereas an increase of the buffer mix-
ture brings about a decrease of C. It is assumed that Cu (Ni) is ab-
sorbed by the precipitate during G in,the form of hydrolysis products
Card 1/2 and, therefore,' factors that regulate.!'the hydrolysis should also regulate
ds SOV/137-58 -11- 23815
On the Problem of Coprecipitation With Metallic Hydroxides of Metallic (cont.)
the C process.* It is shown that the A of Cu and Ni salts on Fe(OH)3 has a hydro-
lytic character and that the C of Cu (Ni) increases with the decrease of the stabil-
ity of the compound binding them in the *solution. If Fe(OH)3 contains an adsorbed
or a coprecipitated electrolyte, the absorption of another e1qctrolyte from the solu-
tion can occur by means of ion exchange. Upon a decrease'in the sirent),th of the
solution the A of Cu by the MNO? precipitate increases, whereas the A of Ag remains
unchanged. It is concluded that the distribution of Cu(Ni) admixtures between the
solution and the precipitate of Fe(OH)3[ AI(OH)3] during G and A follows different,
laws which is an indication of*the complexity of the mechanics of the absorption of
electrolytes by metallic hydroxides. The process of absorption of metals by Fe
and Al hydroxides (basic salts) in the form of hydrolysis products predominates,
Therefore, the effectiveness of C of metals which form dissolution- resistant hy-
droxides can be affected by regulating the extent of the hydrolysis of the compounds
of these metals during the C with metaflic hydroxides. Metallic ions are adsorbed
on the MnO2 hydrate by means of exchange with water ions.
V. P,
Card 2/2-
S~JV/ 156-513 -2 - 28/4 8
AUTHORS: Chuyko, V. T., Mamenko, A. U., Todorov, 1. A.
TlTLF,: ~~~~Bismutb-Traces From Metallic-Salt Solutions
by Means of PartJal Precipitation of Ibe Macro-Component a7,
Phosphate (Kantsentr-4rovaniye sledov vismuta iz rastvorov soley
metallov putem chastichnogo osazlideniya makrokomponenta -; vide
Posfata)
PERIODICAL: Nauchnyye doklady vysshey shkoly. Kh-imiya i khimichesk-aya
tekhno~ogi,Ya, 1958, Nr 2, pp. 317-319 (IJSSR)
-ABSTRACT: The determination of bismuth-trace3 in metals where they often
are an undesirable imDurity, is usually carried out according
to the concentration by means of carrying down the salts ov.
these metals into the depooit of the solation. Fcrric hydroxide,
manganese diaxide, metallic sulfiden and oUers are used as
bismuth-collectors (Ref 1). The use of thes;! collectors in-
volves either the separation of biomu~lh from the Or r.
reg(!Iation of the plll-valun of the i-,aititJon. it is i~rir- - ' -
concentrnte bi~~noiti) - as indic-4f;" i- 11- - -: SWIT
qmaltles of the, Mt do not vr~ the photawtrie
Card 11 :Lan of:Ummitbe
"Parait --.8. it
Concentration of Bismuth-TraceB From Metallic-Salf.
Part.lal PrecipItation of the Macro-Component as Plicsphazt,
of the methods described ir - -. references 4, ti,nd 6that f--
quantitative co-precipitation of bismuth can be ottained wi.th
a partial precipitation of copper: a) by JAIncreasir.g the shar~-
of the macro -component in the deposit; b) by mearis of fracti6n-
ation; 0) by increasing the relation betwec-n the IP -values of
both the macro- and micro-componetit; a ~.uitable precipitator
must be selected for this purpose. The authors sf-lected the
last method c) and used sodium phosphate for this purpose. Mor;~-
over, they partially precipitated the macro-component from the
concentrate in order to reduce its quantity in the deposit.
Bismuth was photometrically recorded as a complex compound with
thiourea. The tests have shown that the cc -precipitat ion of
bismuth is in the same way effective rii.-an precipItating the
9 macro-component as phosphate or by introduzing it readily pr~~-
pared. The extraction of bismuth from f;olutiori-O by 14Pans
prepared metallic phosphate deposits can be uned for purifying.
the salts of the same metals of The above
'r,ismuth-concentration was used by ~he aathor!3 for isolating
caDner. ma&nesium, and ~niAt'uros of con-per and Zinc from sa-11A,
J-1 solutions. Bismuth apparently can be in :,he
("o I I Ce I I I, ratio r (ii, B i From Met a I I ic-Sait Sjolut ioo:.'
par4 -J a I Pr;~ c i D J. to n o Ma c r o - C c, ji p o n C-. n t a s P h o s p I i a t
wuN from salb ooliltions of other mr-talo which f orm P, z3 p! i
('.f low solubility. There are I table and 7
v.-hich Eire '.ioviet.
'MSSOC'EATION. Kafedra obshchey i sn-:tliticheshoy kljimii Cherkaaskogo P-~(UA-
gogichen':ogo institut-it im. 300-leVyh vu.,.soye-dinerillya
3 (Chair of General. and Chemist:,,y
Cher4a.-i--sy lpLitltito of PedaEogios ameni on the 0~:cssivj, of
Tercen,.~-nary of the Reunion of the Ukrpvine With Russia)
I~oBMITTED: N~~-,rembllr 8, 1957
Card 5/5
AUTHORS: ~~~~odorov, I. A. SOV/j56-5a-3-22/53
TITLE: The Concentration by Co-Precipitation of the Ir,-.purities of
Arsenic and Phosphorus in Depositions (,Kontsentrirovn.niye
primesey myshlyalrl-_ i fonfora uvlecheniyer, v ooadok)
PERIODICAL: Nauchnyye doklady v,,,,r,:-,Iiey nhkoly, Khii-.iiy,- i 1-himiche-kaya
tekhnologiya, 195a, 11r 3, pp. 4/05 - 497 (USSIZ)
ABSTRACT: The possibility of the concentration of arsenic and phosphorus
in depositions from solutions of zinc and ~ma-nessiura salts was
shown experimentally. It was found that th-~, carryin--down of
microcomponents in the deposition amounts to almost 90~% By
means of this method it 12 1)osniblo to concentratearsenic and
phosphorus from highly diluted solutions (dilution 1:109). The
carryin-flown of the microcornponconts arsenic and phosphorus
remains the same when instead of a partial precipitation of the
zinc and ma.-nesium salts of the sample investigated newly pre-
cipitated zinc or mngncsium o~:idc is added. The mechmism of
the carrying-down of thane arsenate and phonphate microcomponentn
is one of adsorption. Th(,re are 2 tables and 1 reference,
Card 1/2 "?hich is Soviet.
The Concentrntion by Co-Precipitation of the 3011/156-5a-3-22/53
Impurities of ArOcnic and Phosphorus in Depositions
ASSOCIATION: ICBteam ':himii Cherk-asshogo gosudarstvennogo
instit-Lita im-300-leti,-a vo--soyedineniya Ukrainy s Rossiyey
(Chair of Chernio-try at Cherkassy State Universilty i=ani 300
Years Unification of the Ukraine With Russia)
SUBMITTED: November 4, 1957
Card 2/2
LOTAREVA, V.I.; C11UYKO, V.T.
Concentration of iron traces from solutions of nickel, cobalt,
and zinc salts by a partial. precipitation of macrocomponents.
Trudy LTI no.48:119-123 '58. (MIRA 15:4)
(Iron--Analysis) (salts)
CHUYIM, V.T.
Conference of chemistry teachers at the pedagogic institutes of
the Ukrainian S.S.A. Ukr. khim. shur. 24 no.1:133 158.
(MIRK 11: 4)
(Ukraine-Chemistry-Study and teaching)
QHUYKO. V.T.; TODOROV, I.A.
Concentrating vanadium traceo by coprecipitation with metal hydroxides.
Izvevysouchebozave; khirA.i khimetekbe 3 no.6;98E~-990 160.
(MM 14:4)
1. Ternopollakiy meditoinskiy institut i Cherkasskiy pedagogicheskiy
Institut.
(Vanadium-An&lysis)
CHUYKOY V.T.
Classification of the types of adsorption of electrolytes by
heteropolar sorbents in very dilute solutions, Izv,vys,uc~.eb.zav.;
khim.i Id'".tekh. 3 a~*6;1017-1021 160. (RM 14:4)
I* Ternopol'skiy meditsinskiy institut., kafedra obshchey khJm4i.
(Adsorption) (Electrolytes)
q#~MD ~V.TCHUBKOV N.M.; SHPIKUIAV V,M!
Determl tion of copper in biological material and i* concentra-
tion by coprecipitation. Lab. delol. no.2:33-36 F 161.
(MIU 1421)
1. Kafedra neorganicheskoy khimii ( ~-doteent V.T.Chuyko)
zav*
i kafecka fakulltetskoy ihiru~gii (zav. - Prof. A.G.Martynyuk)
Ternopoltekogo meditainskogo institute. (dir. - doteent P.Ye.Ogiy).
(COPPER-4ULTSIS)
DIYACHENKO, N.P.
CHUYKO, V.T.-.
Methods of concentrating traces of zinc by coprecipitation. Zhur.-
neorg.khim. 7 no.4:903-909 Ap 162. (MIRA 15:4)
1. Ternopollskiy meditsinskiy institut, kafedra obshchey khimii.
(Zinc) (Precipitation (Chemistry))
CHUYKO, V.T!j WYAGHENKOY N.P.
Coprecipitation of traces of indium with basic copper salts from
a copper nitrate solution and with zinc sulfide from a zinc sulfate
solution. Zhur.neorg.khim. 7 no-4:910-914 AP 162. (MIRA 15:4)
1. Ternopollskiy meditsinskiy institut.
(Indium) (Salts) (Precipitation (Chemistry))
CHUMP V. T.
Principal laws governing the distribution of electrolyte ions
between liquid and solid solvents. Isv. vys. ucheb. zav.;
khim. i khim. te". 5 no.5:698-702 162.
(MM 16:1) -
1. Ternopol'skiy meditainakiy institut, kafedry obehebey i
biologicheskoy khimii.
(Crystallization) (Ion exchange)
(Electrolyte solutions)
L 11409-63. S/032/63/029/005/002/022
E',1jP(q)/EWT(m)/BDS ASD JD
AUTFICH: Dlyacbenkol N.F -and Chu
yko V.T.
TITLE: Determination of ultrasmall iincVbapurities in cadmium salts and
salts of metals not precipitated by hydrogen sulfide
PERIODICAL: Zavodskaya laboratoriya, v. 29, no. 5o 1963, PP 522-523
n..XT: When.cadmilm hydroxide is partially precipitated from a solution of,
cadmium sulfate the zinc present in the solution as an Impurity is distributed
between the solution and precipitate-. The Zn can be quantitatively extracted
with CC14 if the Cd is in the form of the nitrate or sulfate and a considerable
excess of iodide is added to form complexes with the Cd ions. Thiourea masks the
influence of other heavy metals mucb more effectively than thlosulfate., ordinar-
ily used. Previous investigations showed that traces of zinc are quantitatively
co-precipitated with CdS from solutions containing metals not precipitated by H2S
at pH 2. This was used as the basis of a method of determining ultrasmall
(0-5 - 2 micrograms/gram) impurities:of Zn in such salts (Cd. Al,, Cr, Fe, Ma and
Vi sulfates wereused). The article has 1 table.
ASS,~CIATION:Ternopollskiy gosudarstvennyy meditsinakiy institut (Ternopol* State
Medical Institute)
Uar~d
The Second All-Uniew Conference. on the Preparation and Analysis of
High-Purity Elements, held on 24-28 December 1963 at Gorky State Unf-
versity im. N. 1. Lobachevskiy, was sponsored by the Institute of Chemi-
,stry of the Gorky State University, the Physicochemical and Technological
Pepartment for Inorganic Materials of the Academy of Sciences USSR, and
the Gorky Section of the All-Union Chemical Society im. D. 1. Mendeleyev.
,The opening address was made by Academician N. M. Zhavoronkov. Some
_pers were presented, among them the following:
_pa
V. A. I %k~uk, -and 1. V~ Ne rebetsilka-. Coprecip-
T yko,
itation or'tYdces TM.- Cd) with iron hydroxide.
Z. G. Fratkina and V. S. Shebunin. Spectrochemical analysis of
metal impurities concentrated as volatile fluorides.
(Zhup, RNAL Khini 19 At'), 01 i, Y_ -77 - 7
CHUYKO, V.T..
Principal resulta-and the objectives of further studies in the use
of inorganic cc')recipitants for concentrating metal traces. Trudy
Kom. anal. khim. 15t236-243 165, (MIRA 180)
CIUM050 V.T.v SHPI-OLA, V.M.
Determination of copper impurities in i-ron and nickel salts. Ukr.
khim. zhur. 31 no.6t638-639 165. MRA 18s?)
1. Ternopol'skiy gosudarstvennyy meditainakiy institut.
CHUYKO, Ye.; KURAYEVA, N.
--C~
Mimination of diphtheria in Sevastopol. Pediatriia no.6:55--
59 161. (MIM 14--9)
(SEVASTOPOr,-DIPHTFIERIA)
y 1~_~ , TI-FENY E.V.
_A~; BLORB, G.A.; OVCHAnNKO, F.D.; GUT)OVICH, N,V,.. lb UK)
Activation of kaolin with the cation-actolve substance "alkamon
OS-2.11 Kazh.-obuv. prom. 6 no.9:13-16 S 164.
(MI-M Y, t 12)
71
1 7
a
7
:
_
ACCESSIOR-M XBOD2664
~41i:h'._'organosilanes,,- to repare:04;,spicimian; _eg~ vinyitrichl6rosilarip-~:~eActed-b4
y
p
-
ane
hydrol~sis.and f6rinatioil-of silox type bo
nd6.,. Ififrared-analysis shaded the
'
presence.of both double ~bonds and-: Si-M_ -Si bond
s in -this silica, andIdemonstra-
'
-
A_ -~up to n-early- .5DDC. Allylaxysil .ir-a was
e stability of i" don
d
ted_~ifi s A -.carbon:bOn a
shown to be f ormOd by- f c)rmation of~ Si-4- --bonds which. were stable to ZOOC, the:
oxy-- and~-
'on:heating~.to~-3DO and 50DC. Propy:L
-,amount of. hydroxyl. groups iner
e4sing.
,
-
.
-ethyl-mc~dif ied stlica wqs -also. prepared Used aa,-f illers- in b
utadiene-styrene
r -s d the'butadiene acq
6ni tri let' tooplymers SKN-2615and SIM-40,
crossIlTdting., and:-markedly' improved the mechanical
olef in,;-mF~dif ied iilica
i d pa ticula~rly~.the"ten6ile:-6tienkth:-46 compared with non-mcidified
propert tas an x
'
-carbon black' -or a y m
silica ~ ("white A I
odified silica, Aminopropylsilica war
y reaction i o ltriethoxp~silane and-used as a filler for'.
:obtained -b qlth rmaminopt
py
SKS 30-1 carbo latedp~ou~adiene-styren-e.r'ubberi, b interaction with rubber-
6arboxyls - the terminal amino them: b r'Save an increase in c
groups of rub e ross-
-decr se in-relative elo ation
linking -And mechOical -strength, with::a'~'sIiSht:. ea ng
Carboxylated prepared from -white-:carbon black U-333 via vinyla--
ted si.llica, by-. rpa;ction V Lth..v~pyltrichlorosi lane: and cop6lymerization with metha-
_
crylic acid With SMIV,-15AV(but
aAene copolymer with 157. 2-methyl-5-vinyl-
pyridine), ~he motjif7ied R=er improved.uhsile strength and mechanical para-
meters :as - compariui - Oith ,:ton-modified'.zillca 'Ilia infrared analysis was carried~~.
.
V ot 0 Sidot v~ anI the -carbox_ylateVsilica~vyas studied in detail by
CorcNi A& N '0.
L 10757-63 E PR/FIFP (J) 10k(c)IRIT (m) /RTS-AFtM/
RM INW
SSION NRo AP)M:291- S/IDlYV63/ODD/OD6/003VO034
M
AL ea d); -rappanyuk, &V.; I
Mmau.: 1. H. J(Dec so
THORs Ckuyko j A. A LL ftmd I' U, I
Chuyko, Ye. A.
Ool
chemical' filler- 11 aIiwface mid oniginIC, ra
TITLEa -Effect of fte natiLre: of- on j
the properties of rublaors
SDMMEs. ~Xauchuk i ro-~inavno, G#~~ 1963 X
,70PIC TAGSt rubbers 30," SKK-40j~ ~Wj, finerej: eiHOA, Belakei modffiod ailioal,
Acaa vukazisation, vulconizate -proportioaj t a tr hi.
j vinyl-;a~bstituted mil. m mil a 6ngt
modulusv'swoningi icMaing raftation, butadlene-styrene rubbers nitrUe rubber,
vckUum butadiene . rubb)ri ailica ourface, kydrwtyls,
.000,
The effoot~of the ONINA091: t filler
ABffRACT i rT of the surface anthe physico-
I .. hap at
mechanical proper udied. Wtadieno-st_yreneNS
-Vies'of rubbers lir
nitrile (SM &PW4 o9dium butaft SO)' rubbers loaded with unmcWied Silica
one
51
wA with silica whose -surface hydroxyls had been a~batituted by allyl(my or vinyl
radicals were itsed, , Use ~of modified silica in standard rubber nixes (containing
100 parts rubbeir and !i0 to 60 parts filler) was shown to improve the jksiqq-_
mechanical Portion of the vuleanizates. For examplej, the tensile strength of
-Card.
F 'I.:
10757-63-
-"A'WE=ON N
Rs AP3W.*:291
SKN-rO. rubber *~ontgdlxing 60%,filler- 106r8wed trce U6_0'k
jVos wJtb unmodified' 1
allica to 163,6-10 jid6m* . with vinyl-substituted - silica WnYl silica) I the
respective values of the modulus at 600%'elongation and, swelling at equilibrita
An benzens'were 55.2 and 134,kg/cm2 and 30 aid 15%. This improvezint was
attributed to, greater. co mpatibility of the fine r. g:A the rubber and to a reaction I
between the olefin radicals of-tbe filler surface and.the rubber 'With the
l
formation of C-C and, O-S-C IiAages. -The effect, was: studied of ionizing radiation
._~from a'CdO souree..at a dose rate of7ri./See on nonloaded SKS-30 rubber and cm
d (ratio"
~SKS-30.loade -1/1) with unmodified and with.modifted silica (Belaks) con-
taining 45% vinyl.. m9thyl., or at4lradicals. Irradiation did not arfeat the
tensile strength and -the modulus at 100% elongation of unloaded rubberbut con-
siderably improved thi)se properties in;loaded rubbers,. particularly with vinyl
silica. : The m4udmum offect of. irradiation is attained after 48 hr. lhese~ re- -
ul
s ts were attributedU the participation of the -finer in the formation of the
three-dimenBiOnal,metworke In-particular, theallyl or vinyl groups of -the filler
and the tubber macromoleculen form radicals which link the two through the
tion of covalent bondo, It isconaluded-that the structure and the physico-
i mechanical properties of vulcanizates can be controlled by mcdifying the naturb of,
the Organic,radicals (in the silica surface
Abennoer of such radicala, the compo-
sition-of the vulcanisiates, and-the method of vulcani2ation.-.,Orig. m!t. haS3
Ccird
I i
.2W;A6
,-,.,;-ALL tjt(r: 6022447 SOURCE CODE: UR/0069/66/0'28/002/02"18/0282
AUVHP: Tertvkh, V. Cbm", Ye.. A. __ Chuik-o, E. A.; Chuyko, A. A. -- Chuiko, J211
'N
A. A.; Neymark, 1. Ye.
1:26
'ORG: Ingti&tj *of Physical P1k9mistry, AN TJkrSSR, Kiev (Institut fizicheskoy fai AN
Uk-x SSR)
TITLE: Amino-organo, silicasts chemically active sorbents and fillers of polymer materials
SOURCE: KoUoidnyy zhurnal, v. 28, no. 2, 1966, 278-282
TOPIC TAGS: organosilicon compound, polymer physical chemistry, chemical absorption
ABSTRACT: Clarification of mechanisms by which acid substances react with an adsorbent
surface was sought through an analysis of infrared absorption spectra for the adsorption of
hydrogen chloride on amino organosilica and of methacrylic acid on an amino organoaerosil.
A supplementary analysis concerned adsorption of methacrylic acid7on the named aerosil from
an aqueous solution. Another aspect of the study involved reinforcement of the carboxyl-con-
taining polymer SKS 30-1 by dispersion type arnino organosilicic fillers. Results indicate that
Aemisorption occurs, with an accompanying formation of chemical compounds on the adsor-
bent surface. Amino and vinylaTnino derivatives of silica white A, used as fillers, reinforced
the carbo.-WI -containing polymer through interaction of functional groups and the accompanying
Card 1/2 UDC: 541.183.23
4- _41266-66
ACC NR: AP6022447
crosslinking of polymer and filler. With great satisfaction, the authors express their gratitude.
to Candidate of Physical-Mathematical Sciences A. N. Sidorov and Academician A. N. Terenin
for their advice and assistance in performing the work. Orig. art. has: 1 table and 3 figures.
SUB CODE: 07/ SUBM DATE: 22JulG4/ ORIG REF: 002/ OTH REF: 001
'/ C
Card 2/2 __/_
L 7 EWT in &VP /T UP(A) W-V/RM
-00733-L6
-ACC NRt AP6024846 i SOURCE CODRI UR/0073/66/032/004/0371/0377
AUTHDRI Chu~rko. A. 0; G, Ye.j Tqjgh, V. A.; Chuykog Ye, A,; Artemovp V. A4
NeYmarki r.-Ye.; Th nr& V,
ORGI Institute of 11bysical Chemistryl AN UkrSSR (Institut Micheskoy khsmii AN
TJkrsstc)-
TITIES Carbmtylorganosilical - chemically active fillers for polymers. Fsport No. 1.
Synthesis and adsorption perties of carboxylorgaWailioas, and their use in the re-
Imforeement of virqlpyridine rubber
SOURGE1 Ukrainskiy khimi6heskiy zhurnals V. 329 no, 4,11966, 371-377
TOPIC TAGS: silica, graft copolymers, synthetic rubberp finer
ABSTRACTt Carboxyl derivatives of S02 were synthesized by copolymerization of me
crylic acid$rith vinyl siUcas having various quantities of grafted vinyl groups on
their surfi4e. IR spectroscopic and ion exchange methods confirmed the grafting of
methaorylAo acid to the surface of vinyl silioa. A study of the surface characterie-
ties showed that methanol., diethylandnes,,and pyridine am chendsorbed on the acid func-
tional groups of the carboxylorganosilicas, forvdng the corresponding surface mompound%
Filling of a virylpyridine polymer SS~K~W-11 with carboxylorganosilicas causel a re-
inforcement of the polymer systemp probably because of a chemical intoraotion 1"tween
the carboxyl. groups of the filler and the basic pyridine groups of the rubber imacromdl-
Card 1/2 MXt 1 541.182.23
CHUYKO, A..V., kand.teklin.nauk; CHISTOVA, Ye-M., kand.tekhn.nauk; ROMODANOV,
A.N., inzh.; CHUYKO, Ye.S., inzh.
Floor deformations in enterprises of the canning industry. Prom.
stroi. 42 no.2:19-21 165. (MIRA 18:4)
TAYTS, N.Yu., do):tor tekhn. nauk; KLEYNER, M.K., inzh.; ZAVALISIIIN,
Ye.K., inzh.; KALUGIN, Ya0P. inzh.; FALILEYEV, I.L., inzh.;
KAGANY R.I., inzh. [deceasedi; Prinizall uchastiyei POPOV,
V.N. jnzh.;_9TUWvJ,-A.A., inzh.; MINUKHINA, L.N., inzh.;
KHATSAREVICH, V.R., inzh.; TOLMACHEVA, I.A., inzh.; BAZHENOVA,
VA., inzh.
Technological and thermodynamic characteristics of strip
heating for the continuous furnace welding of pipes.
Stal'24 no.8:746-750 Ag 164. (MIn 17:9)
1. Ukrainskiy nauchno-issledovatellskiy trubnyy institut,
Urallskiy nauchno-iseledovatel'skiy trubnyy institut i
Chelyabinskiy truboprokatnyy zavod.
/1'r
V~
-'7
1115;~
AUTHORS: Ptushinskiy, Yu.G. and Chuykov, B.A. 109-12-4/15
TITLE: Mass-spectrometric Determination of the Composition ol '* the
Residual Gases in Electron Devices with Porous Metal-film.
Cathodes (L-cathodes) (Mass-spektrometricheskoye opredeleniye
sostava ostatochnvkh gazov v elektronnykh priborakh s
poristym. metallo-plenochnym katodom)
PERIODICAL: Radiotekhnika i Elektronika, 1957, Vol. II, lio.12,
,USSR
pp. 1497-1501 (
ABSTRACT: The method of measurement was similar to that employed
by G. Fikus (Ref.4). The investigationias carried
Mthi*erQ
e -
analyser tubes fitted with porous metal-film catho sprovided
with barium oxide fillers (BaO + 1091o Ta). After the sealing off,
the pressure in the tube was reduced to 10-( mmHg. A spectrogram
was then taken for a cold cathode (spectrogram of the background)
and the cathode was next heated to a temperature of 1 000 C
and a new spectrogram was recorded. The results are shown in
Fig 1 which illustrates a spectro ram of the background (shaded
are;s3 and an initial spectrogram Non-shaded areas); the
figure relates the value of the spectrometer current to the
atomic mass. From the figure, it is seen t at the tube with
an L-cathode operating at a pressure of 10-~ mmHg contains the
Cardl/2 following residual gases: hydrogen (m = 2) , helium (m. = 4),
109-12-4/15
mass-spectrometric Determination of the Composition of the Residual
Gases in Electron Devices with Porous Metal-film Cathodes (I-cathodes)
nitrogen (m = 14 and 28), carbon monoxide (m = 28), oxygen
(m = 16) and a small quantity of chlorine (ni = 35 and 37).
Further experimental results are .' shown' in Fig. 2, which
represents the spectrometer current as a function of time.for
various residual gases; the curves of Fig.2 for periods up
to 200 hours were taken at zero cathode currents,,uhile after
200 hours, the cathode was operated at 20 mA. The aim of this
work was not the determination of the quantities of various
residual gases, but rather the detection of all the possible
gases and their mixtures. The author expresses his gratitude
to the Corresponding Member of the Ac.Sc. Ukrainian SSR N.D.
Morguli& for his valuable advice. There are 2 figures and
9 references, 5 of which are Slavic.
ASSOCIATION: Physics Institute of the Ac:.Sc. Ukrainian SSR , Kiyev.
(Institut fiziki An USS4 g. Kiyev)
SUBMITTED: May 8, 1957-
AVAILABIZ: Library of Congress
Card 2/2
A7
AUTHORS: Ptusbinskiy, Yu.G. and. B*A* 109-12-9/15
,~huykov, B.A.
TITLE: Diffusion of the Strontium Vapours through the Plug of
a Porous Metal-film Cathode (D-cathode) (Diffuziya parov
strontsiya skvoz' Subku poristogo metallo-plenochnogo
katoda)
PERIODICAL: Radiotekhnika i Elektronika, 195?, Vol. 11, 140 12
pp. 1530 - 1535 (HSk)
ABSTRACT: The problem has been investigated by a number of authors
(Refs. 1-6) but it was felt that an additional investigation
was justified. The experiments were carried out on a tungsten
plug, having a porosity of 0.2 (see Fig. 2a)i the velocity of
the strontium vapour diffusion was compared with the corres-
onding free flow of the strontium vapour from a "black body"
see Fig. 26). In both cases, the disptnser contained the same
~
mixture (Ba, Sr)CO which was marked by the radiolative isotope
89 3 e
Sr and a quantity of tantalum powder w.hLelr!~w"/in a tantalum
ampule having a siare-like cover. The experiments were carried
out in a special tube (see Fig. 3) which contained a fixed
cathode and a system of seven movable collectors. The presence
of the collectors permitted the measurement of the velocity
of the diffusion as a function of temperature. The measuremgnts
Cardl/2 were carried out over a temperature range of 1 350 to 1 550 K.
109-12-9/15
Diffusion of the Strontium Va ours through the Plug of a Porous
Metal-film Cathode (I,-cathode5
The results are illustrated in Fig. 4. This shows the pressure
of the strontium va-Dours as a function of temperature to a
semi-logarithmic scale. The Curves 2 and 3 refer-.,to the
pressure above the surface of the cathode, while the Curve 1
relates to thq~,pressure in the chamber of the cathode. From
the above, it is concluded that diffusion of the strontium
vapours through a fine plug,having a porosity of 0.2,is mainly
due to the migration mechanism (over the investigated range
of temperatures). The jump in the vapour pressure between the
surface and the chamber ranges from 280 to 1 800 for the
investigated temperatures. It was also found by interpolation
that for the normal operating temperature of 1 000 'C, this
jump would be equal to 100.
The author expresses his gratitude to Corresponding Member of
the Ac.Sc. Ukrainian SSR N.D. Morgulis for his interest and
valuable advice. There are 4 figures and 10 references, 6 of
which are Slavic.
ASSOCIATION: Physics Institute. Aff. Ukrainian SSR Kiy6v
(Institut,fiziki AN USSR,. g. KiyevJ
SUBMITTED: 14ay 5, 1957
AVAIL.ABIE: Library of Congress
Card2/2
rf. JU-0
S-./600 66166
1LUTHORS: Mcri,`Ulis, IT. D., Ptushinskiy, lu. ,-.OV/20-128-5-18/67
Chuykov B. A
TITLEs Some Specific Features of the Partial Adsorption of Residual
Gas Components at Very High Vacuwa
PERIODICALt Doklady Akademii nauk SSSR, 1959, Vol 128, Nr 51 PP 930-932 (USSIR)
ABSTRACT: In the present paper the authors investigate the properties of
a "natural" mixture of residual gases generally present in
electronic devices at high vacuum. For this investigation the
authors use a mass spectrometric device intended for investi-
gations in the field of high-vacuum processes. The inside of
the mass spectrometric analyzer tube employed was fitted with
a long tungsten band. This tube consisted wholly of glass and
was soldered. The pressure of the rosidual gases was
p - 1.10-8 torr. The tungsten band served as the basis on
whose surface the components of the residual gases investigated
were adsorbed. A schematic representation of the mass spectrum
of these gases is given in a figure. The present problem was
investigated by the well-known "flash" method. The relative
Card 1/4 degree of adsorption A I/Im of each component of this mixture
Llik-
66166
Some Specific Features of the Partial Adsorption Q V/20-128-5-18/67
of Residual Gas Components at Very High Vacuum
may be determined from data given in the above-mentioned
figure. This degree of adsorption is proportional to the mean
- Lim BNM n -
condensation probability k m : =m ~ PAM - Ckm , where 11m
denotes the total amount of gas adsorbed within the given time.
The following interesting conclusion is arrived at:
k (He) = 0' i (H (N ). In order to obtain more exact
M m 2 m 2
data on the specific features of adsorption of each gas
component in the mixture, the partial adsorption rates were
determined by measuring the eependence of the quantity M M
on the time t of previous adsorption exposure. This
dependence is represented in a diagram for the 2 main oomponants
H and N For comparison, the dependence AI is shmvn for
t99 totai'llf-lash" of all gases in the ion source. The total
pressure of the gases amounted to p' - 1.10-8 torr. The
desorption of the components H2 and N2 from tungsten after
Card 2/4 extremely long exposure of the latter in the residual gas atmosphere
66166
Some Specific Features of the Partial Adsorption of SOV/20-128-5-18/67
Residual Gas Components at Very High Vacuum
can be investigated more closely by means of the temperature
variation with respect to time. In doing so, the authors
observed the polyphase nature of the adsorbed states of E2
and N2 on tungster4 which complicateo this phenomenon even
more. The third diagram gives the characteristics of
partial dependence on adsorption of the "pumping out" of the
gas components 112 and N2 from the mixture of residual gases,
after the tungsten band had been freed from these components
by "flashing" at high temperatures and then cooled. The
curves shown in figure 2 are qualitative representations of
the integrals of the curves given in figure 3. Investigations
of this problem are being continued. There are 3 fi,-xres and
2 referencesp 1 of which is Boviet.
of Physics
ASSOCIATION: Institut fiziki Akademii nauk UBBR (Institute/o-f the Academy
of SciencesUkr SSR)
PRL'6:,S*TBD: March 27, 1959, by I. V. Obreimor, Academician L-K
Card 3A
66166
Some Specific Peatures of the Partial Adsorption of SOV/20-128-5-18/67
Residual Gas Components at Very High Vacuum
6UBMTTED: Maroh 16, 1959 IK
Card 4A
.1Y,,.:
0/109/62/007/004/01-s,1/016
Ch ~//Ip D290/D302
AUTITLOIRS Ptushins)Uy# Yu-G-j and Chuvk v As
TITLE: Interaction of molecular beams of barium oxide with
incandescent tungsten surfaces
PEIRIODICILI: Radiotekhnika i elektroniKa, v. 7, no. 4, 1962,
687 - b92
TEXT: The Drocesses of thermal dissociation, chemical reac-.ion and:
thermal' ionization were studied in order to elucidate the casic
c1lianism of adsorption and the properties of tungsten cathodes coa-
led with barium oxide. A mass-spectrometer was used. The decree 0-f
dissociation varied with temperature; appreciable dissociation tool-C
place above about 1700OK; dissociation :,,as practically-, omplet-e abo-
ve abQut 22000K (the beam purrents were between 2 x 10,8 and 2 x
x 101~~ molecules of BaO/=2~/sec.). There was no appreciable chemi-
cal reaction if the tungsten surface was only partly covered w--
monomolecular layer of BaO; a vigorous reaction took piace -_'-f 'v',-.Ie
surface has been previously covered with a t-hick layer of 3a0; ba-
rium tungstate is formed. Barium ions were emitted from the tun6s-
Card 1/2
S/109/62/007/0041/01 1/0'ItS
Interaction of molecular beams of D29o/D302
ten surface at temperatures above about 17000K; no _11a0 ions '-,ere
observed. The maximum in the curve of barium ion current a.-lains .
temperature is probably caused by the oxygen that is produced as
the BaO dissociates. Desorption of BaO from the tun:yslen
k.ook Dlace in two stages, starting at about 111000K and 1".0001,; the
two stages were nore distinct the greater the fraction of the sur-
face that v-,,as initially covered with BaO. There -re 5
9 references: 5 Soviet-bloc and 4 non-Soviet-bloc. T'-ae 4 -zst
cent references to the English-language publications -read as fcl-
lows: DT... Inghrari, V1. Ghupka, R. 'Porter, J. Chem. 21hys., 1951,5, 2'~-;"
11, 2159; R. Bayard, D. Aipert, Rev. Scient. Instrun., lc--50, 21, 06,
571; R. HuGes, P. Coppola, H. Evans, J. Appl. Phys., IL)52, L-*3' 6,
b35; P. Russel, A.Eisenstein, J. A'Ppl. Phys. 1954, 25, 8, 95:74-
ASSOCIATION: Institut fiziki All USSR (Physics !nsti`L-.u-,,e -IS
SUBIKITTED: May 15, 1961
Card 2/2
PTUSHINSKIY, Yu.G.;-CHUYKOV, B.A.
Interaction of a molecular beam of BaO with the surface of
heated W. Radiotekh. i elektron. 7 no.4:687-692 Ap '62.
(MIRA 15:3)
1. Institut fisiki AN USSR.
(Tungsten) (Barium oxide)
PTUSHINSKIY, Yu.G. [Ptushyns1kyi, N.H.]; CHUYKOV., B.A. [Chuikov, B.O.]
Peculiarities of the partial adsorption of residual gas
components at very high vacuum. Part 2. Ukr.fiz.zhur.
7 no.1:79-81 Ja 162. (MIRA 15:11)
1. Institut fiziki AN 'UkrSSRJ, Kiyev.
(Gasea-Absorpiion and absorption)
(Vacuum technology)
PTUSHINSKIY, YL,.G.; CIIUYKOV, B.A.
Adsorption of hydrogen cn the surface of tungsten covered by oxygen.
Kin. i kat. 5 no.3:5,13-519 i4j,-,Je 164.
~M:RJP 1,7:13)
1. Institut, fiziki AN 'Jkr-,'Sli.
2.4.'~3f& D299/D302
AUTHO.RS: Ptushynslkyy, Yu.11., and hJ_1-kn,,r-
TITILE; Some -oeculiarities of partial adsorption of residual-
-,as components in an ultrahigh vacuum. Ii
P3RIODICAL: Ukrayinslkyy fizychnyy zhurnal, v. 7, no. 1, 19062,
'19 - 81
M7~'
:-XT: Niew results are given concerning the kinetics of adsorption
of res-f-dual gases and 'V',,,e tenperature stability of residual ,;acos
adsorbed on tuni-Istuen films. The present article is a coln"u-inu--tion
of i,oroulis, Yu.G. Ptushinskiy and B.A. Chuykov (;,ef. 2: D!.S
SSSR, 128, 930, 1958)- In R'cf. 2 (Op.cit.) the ~,-lov; meti-Iod was conL-
bined (for the first time) vith riass-s-oectrometer investii~latio'ns;
such a combined method yields more comprehensive results and is al-
so used in the present investigation. The experimental app:T-attlus
consisted of a mas,_--sDe c trome ter with glass lw2ip-an-alyzer suitable
--or ultrahieh-vacuum investigations. The pressure of the resiLdual
-10-8 m, 0 "Results: TI-e adsor-o-uion charac-ceri-
gases was kept ai 2 "1 hg LI
Card 1/3
S/18 0 2/007/001/012/014
Somie.T)ecuiiarities of partial ... D299Y_Io'02
stics of residual ras comDonents are expressed by the ratio ! /I
(denoting the increase in -ion current during the r-low, and -the ion,
current of the given component, respectively). A firure `L-1he
deDendence of ~~,IL,/im on adsorption' time for 111 21 CH4 and CO + N21
at room temperature; the corresponding curves for lie zmd Ar coinei-
ded with the abscissa. Froi,,i the figure it is evident tiiat 'U.,-.e resi-
dual L--ases can be divided into three groups frorl the point of view
of adsorbability: hydroEen, nitrogen and carbon T.ionc-X.ide are mostu
aciively adsorbed; methane which is not readily adsoroed, and -Ghe
inert c,-ases vilhich are prac-uic:~.Ily not adsorbed at all. 'Hence, in
order io determine the influence of residual 6asels on the surfaces
under consideration, it is necessary -co tuake into account t.,,-e -rate
of adsorpzio-n of the various gas componenTs and not onlly their pres-
sure. I Further, the effec-G of the "Gen-oerature of zHe tunt_,sten filin
on the aOsor-otion of the residual-gas componerits, was lnvestiLr.:-ate-~,
Ui'or a te~-woe~-ature ranL-.e of 3uO io 15000K). it was --found that 0~111,
is completely vaporized from ihe tun3sten surface at T 0000K, 1,2
at T > 8000K, and CO + N 2 - at T ~_, 15000K. Thus, in order to clean
Card 2/3 X
S/1 8 5/6;~/007/00 1 /012/0
6ome pecuiiar-ities of partial . . . -D299/D302
cotiplezely the lu-n-sten surface from, residual gases -ander A-11ra-
nir.h-vacuum condi cions, it has to be heated to tenipcrat-ares above
1~)OuOk. if the temnerature of the surface is 'K.eot at, 7000", it is
possible to get rid of C11 4 and F121 and then to st-udy the adso2.--otinn
of CO and X 2~ There are 2 figures and 3 references: 2 Soviet-bloc
and I non- oviet-bloc. The reference to the Daglish-lan--ua-e pub-
lication reads as --Pollows: D. Hagstrum, Rev. Scl. Instr., 2.1~, -1135
195-53; J. -docker, C. Hartmann, J. Phys. Chem., 57, 153, 11953.
ASSOCLITION: Ins-uytut fizyky AN URSR (Institute of Physics of t-h-e
AS UkrRSR), Kyyiv
SUBI-11TT3D. July 22, 1961
Card 3/3
,.CHUYKOY, Fedor Minayeyipk; ITANOV, G. I red.; POPOVA, T. , tekhn.re-1,;
__TfV_~T.Vihfn_g for the individual] Too dlia oheloveks. Koskva
Gos.izd-vo polit.lit-ry, 1959. 78 . (MIJIA 14:41
(Russia--Economic conditionS3
NAYDYSH, A.M., prof.; BRATISHKO, A.S., inzh.; ZEMLYANSKIY, L.V., inzh.;
LEBEDEV, N.N., inzh.; CHUYKOV G.L., inzh.
- 2 - ~'-
Determining the optimum load on a panel for mines with it
high methane liberation. izv. vys.uchev.zav.:gor.zhur. 7
no. 4s26-32 164. (MIRA 1717)
1. Donetskiy politakhnicheskiy institut, Rekomendovana
kafedroy razrabotki mestorozhdeniy poleznykh iskopaysmy'Ah.