SCIENTIFIC ABSTRACT T.A. DOBRYNINA - M. DOBRYSHMAN

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SCIENTIFIC ABSTRACT
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7-4. cw-tama_~Ift ~eo~=~-A It t DOBRYNINA# To Ao Cand Chem Soi -- (dies) "Physiooohemioal study of the triple system LJOH X H202 =H20,and the synthesis of peroxide compounds of lithium." Mos, 195Z 10 pp with graphs,20 om. (last of General and Inorganic Chemistry im N. S. Kurnakov, Acad Soi USSR. Laboratory of Peroxide Compounds), 180 copies (KL, 24-57, 116) -13- 85601 8/062/40/000/006/012/025/Xx o B02O/BO60 AUTHOR: Dobrynina, TITLE; Solubility Isotherm of the Ternary SysteAiOH - H202- H20 at 30-50 and Study of Lithium Peroxide Hydrate PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk, 1960y No* 6, ppo 961-965 TEXT: The existence of lithium peroxide perhydrates L12O2-H202.3H2O, L12O2.H2G2.2H2O and L12O2.2H2O2 was established during the study of solubility of the ternary system mentioned in the title at 100, 00, -100, and -210C, the composition of the solid phases being determined at the same time (Ref. 1). Hydrate forms of lithium peroxide were not found. Lithium peroxide perhydrates are, however, little stable, and readily --Rrate crystalline hydrogen peroxide on heating as well as in vacuum. At --neratures, one had reason to expect either the formation of - or that of its hydrated forms as solid phases in the 856o1 Solubility Isotherm of the Ternary System S/062/60/000/006/012/025/XX UOH - H202 - H20 at 30.50 and Study of B020/BO60 Lithium Peroxide Hydrate system concerned. The investigation was conducted in a water thermostat with a contact thermometer. Sampling and analysis of liquid phase and the "rest" for active oxygen and lithium oxide content were made by the method described in Ref. 1. The composition of the solid phases formed in the system is determined by the "rest" method. Data obtained on solubility in the UOH - H202 - H20 system at 30-50 are given in Table 1 and diagrammatically shown in Fig. 11 the same diagram being shown in rectangular coordinates in Fig. 2. The solubility of LiOH.H20 at 30-50C amounts to 6.83% U20 or 10-95% UOH. At 30#50 in the LiOH - H202 - H20 systemy the existence of the following solid phases was established: LiOH.H2O, Li 202-H2 0, U20 20H202-3H2 0, Li 202-H202- 2H20, and Li 202- 2H20 2* The solid phase LiOH.H 0 exists at 30-50 in the concentration range of hydrogen peroxide in tRe liquid phase from 0 to 1.63%. At low H202 concentrations in the liquid phase at 30-50C the author established the formation of a new solid phase U202-H 20, which was not established under the conditions of Ref. 1, and which exists in the hydrogen peroxide 85601 Solubility Isotherm of the Ternary System S/062/60/000/006/012/025/XX LiOR - E202 - H20 at 30-50 and Study of B020/BO60 Lithium Peroxide Hydrate concentration from 1.63 to 6.17%. At 6.17 - 34.82% there exists the solid phase Li202* H20 2-3H2 0 and at 34.82 - 59-51% E202the solid phase Li202-H 202- 2H20. Li 202* 2H202is formed at a concentration of 51-59 - 61-57% H 2020 The limit of investigated H2 02 concentrations in the system mentioned in the title was 64-57%. At still higher H 2 02concentrations a violent reaction set in under strong heating. Li 2 02-H 20 lithium per6xide'hydrate obtained synthetically was studied with the aid of the thermal differential 4' analysis. The differential curve of Li 0 1 0 heating is shown in Fig. 3; 2 2' 2 it differsifrom the heating curve of anhydrous peroxide by a higher endothermal effect beginning at 1000 and caused by the removal of the' crystal water. When heated up to 1000 lithium peroxide monohydrate separates water and passes over to anhydrous Li202. The endothermic effect beginning at 3250 corresponds to the decomposition of U202. Lithium peroxide hydrate was submitted to X-ray analysis also by G. A. Gollder; Card 3/4 85601 Solubility Isotherm of the Ternary System S/062/60/000/006/012/025AZ LiOH - E202 - E20 at 30-50 and Study of B020/BO60 Lithium Peroxide Hydrate the interplanar distances are given in Table 2. The author thanks S. Z. Makarov for valuable advice. There are 3 figures, 2 tables, and 6 references: 3 Sovietj 1 US, 1 French, and 1 Italian, ASSOCIATION: Institut obshchey i neorganicheakoy khimii im. N. S. .Kurnakova Akademii nauk SSSR (Institute of General and Inorganic Chemistry iment N. S. Kurnakov of the Academy of Sciences USSR) SUBMITTED: February 3, 1959 n - -.2 A 1A 82688 S/062/60/000/008/001/012 B004/BO54 AUTHORS: Makarov, S. Z. and Dobrynina, T. A. TITLE: Synthesis and Study of the Properties of Lithium Peroxide Diperhydrate I PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk, 1960-~.,,No. 8, pp. 1321-1324 TEXT: In a previous investigation of the solubility in the system MOH - H 202 - H20 in the temperature range -21 to +30 0C, the authors obtain- ed the compound Li 202* 2H 202which could not be prepared in a pure state. The present paper reports on the synthesis of this compound. Li 202'R20292H20 was troated witb oonootitratod 11202 at 0 to -21 0C, and the resulting pro- cipitate wap filtered off, Table 1 gives the analytical data of some pre- parations. They still contained mother lye which could not be vashed out with cooled ether, and vere unstable. To obtain pure Li 20 2tH2021 tke pre- parations vere dried at 10 torr and 0 - 2 0 C, or at 18 - 21 0C in an Card 1/2 62688 Synthesis and Study of the Properties of Lithium 5/062/60/000/008/001/012 Peroxide Diperhydrate 'BO04/BO54 exeiccator over phosphoric anhydride. Table 2 indicates the analyses of the substances obtained at 0 _ 20C, and Table 3 thoue of the oubetances ckb- tained at 18 - 210C. Fig. I shows the change in the content of 1120, and H.0 during drying. The preparations dried at IS - 210C %ere unstable. At 0 - 2OC, however, a preparation was obtained after 15 days' drying that had the composition Li 202-2.02 H202-0.18 1120. It was X-rayed at -45 OC by G. A, A. Gollder. The lattice spacings indicated in Table 4 show that this compamd has a peculiar structure differing from that of other lithium peroxides. A thermal analysis showed that Li 202*2H202 heated to 50 - 6ooC violently de- composes within 16 mint and passes over into anhydrous L12 0 2 betv on 650 and 1000C. There are 1 figure, 4 tablesp and 7 references: 3 Sov17 I US; V~ 2 German, and 1 Italian. ASSOCIATION! Inatitut obahchey i neorganioheskoy khimii Akademii nauk SSSR (Institute of General and Inorganic Chemistry of the Academy of ScienoeL_USSR) SUBMITTED: April 16, 1959 Card 2/2 ACCESSION NR: AT4028333 S/0000163/000/000/0085/0093 AUTHOR: Do Makarov, S. Z. (deceased) ,br nt y __q TITLE; Peroxide compounds of lithitim and their-synthesis SOURCE: Soveshchaniye po khimii parekisny*kh soyedineniy. Second, Moscow, 1961. Xhimiya perekiany*kh soyedineniy (chemistry of peroxide compounds); Doklady* soveshchaniy. Moscow, Izd-vo AN SSSR, 1963, 85-93 TOPIC TAGS: peroxide compound, lithium, peroxide synthesis, hydrogen peroxide, lithium peroxide ABSTRACT: The authors plotted a ~olythermal diagram showing the range within which'. a solid phase in saturated solutions of the LiOH--H2O --H20 ternery system exist Investigation of this ternery system showed that lithium peroxide was not formed'sin the temperature range of -21 to +300C during the interaction of LiOH with H202 Li 0 synthesis is possible by two methods. In both methods of lithium peroxide 2 2 synthesis, lithium hydroxide and hydrogen peroxide are the initial products, however, the t4kmperature conditions and the concentration of hydrogen peroxide were different. A schematic of the instrument for producing lithium peroxide is shown. The data obtained from the experiments of lithium peroxide synthesis are presented in ta-bles. ACCESSION NR: AT4028333 In conclusion, the authors claim a physical-chemical investigation of the ternery system LiOH--H2-0 --H 0 has made it-possible to develop two methods for the synthesis of lithium peroxide ihr.ough its derivatives of a hydrate or hydrogen-peroxide type; Li 202*~H20 and Li 202"'202* (2-3~"20 Orig. art. has: 4 tables and 2 figures. ASSOCIATION! Institut obahchey L neorganicheskoy khimii im. N.S. Fjizmakova AN SSSR (Institute of. General and Inorganic AN SSSR) SUBMITTED: 13Dec63 DATE ACQ: 06Apr64 ENCL: 00 SUB CODE: CH~ NO REP SOV: Oll OTHER: 024 Card 2/2 DOBRYHR;A, Tatlyapa Aleksandrovna; VOLINOV, 1.1,, kand. khlm. -'- ' -i:iaiik*, otv.red.; DRAGUNOV, E.S., red. [Lithium peroxide) Perekis' litiia. Moskva, lzd-vo "Nauka," 1964. 49 p. (VIRA 17:7) "W5,11ii I ill 'N, Ap A.; U7YOKMIRAI, R.8. Paroxyh and hydrate.-~ of' rubidi-m and cdzilum carbcnal Fepcrt No. 1. Solubilit,7 isothbrmn of the ternary systenms Rb2t,'03 - H202 - il,)O and C32CO3 - 1120 2 - 1120 at PO'C" !ZV- AN Z) I -,,A 17, - 6) ,3S5",C.1.3er.khl.m. no. 51790--~,94 My "4. 1 1&. , 1. Inntiltut obsllichay I nacrganJ.chask.:~y khtmil im. Kurnakova AN SSSR. T. and hydrate'S ran,, IT S the tornary ter, Zf;,crt No.22 Physicorhemical ~tlldy 0 Rb-)C03 - H2(2 - H-)O. Izv.AN Ser.kliim. nc.1:37-42 166. T W~ 1. Tzint.1tut ct)sj,cloy i noorgunIciiesLoy 10iin-il im. N.S.Kornakova 'dl MLNOYLOV, S.1te.; CHAMIN, V.N.;-DOBRYNINA~, T.I.; VOSKODOYNIKOV, G.V. Isolation of crystalline catalase from horse erythrocytes ajhd the study of some of its phybicochemical properties. Biokhimiia 26 no.3:408-1+.U My--Jo 161. (MIRA '14: 6) 1. Chair of Biochemistry, Obomo-Phoxwoeutic lnstitute~ Leningrad. (CATALASE) (ERYTHROCYTES) CHAMIN, N.N.; Separation-of an amorphous and crystalline catalase from waste products of blood serum production. Trudy Len.khim.-fam.inst. no.l~~11_14 162. (MIRA 15:10) 1. Laboratoriya enzimologii pri kafedre biokhimii (zav. prof. S.YeAnoylov) Leningradskogo khimiko-farmatsevticheskogo instituta. (CATALASE) 7-0-A- , 4:~, ~k \ ~ ) \ .. V, sHmiff, N.i.;DOBRYNINA, T.P.;TIKarXTWA, Ye.A.;YBGORDV, Yu.p" Catalytic dehydrogenatlen of Isopentans. Isr.0 SM,Otd.khimo nauk no.5:952-953 S4 055. (Km 9:1) I.Justitut orgazichookey khtail luent I.D.Zolinakoge Akadenii nauk SM* (BOams) (Behydrogenation) -age a Txt- AE I'M. prt.W.Ilu, !Q,-. walk air tilt 2 hm at ;SZ41' I)v r-,ducin-'n It i,. vT'. 1 c 1) O-B'P\ AUMM: Timofeyeva., Ye. A.; Kleymenava, V. M.; Dobrynina, T. P. 62-1-18/23. TIIU: Application of the Kaufman-Gallpern Bromometric Iodine Number Determination Method to Certain and C6 Hydrocarbons (Primaneniye C5 bromometricheskogo metoda opredel6niya iodnykh chisel po Kaufmanu- Oallpernu k nakotorym uglevodorodam sostava C5 ' Cd. FERIODICALs Izvestip Akadenii Nauk SSSR Otdeleniye Xhirdchaskikh Nauk, 1957., NO. 1, pp. 122-123 WeSeSoRel ABSTRAM The applicability of the Kaufman-Gallpern method to the determination of iodine numbers and the content of unsaturated hydrocarbons in catalysates obtained during the dehydrogenation of n-pentane , iso- pentane and n-hexane, is discussed. The tendency (of the basic saturated hydrocarbons aa well as hydrocarbons forming during catalysis, and artificial mixtures of these very same hydrocarbons) toward the bromine solution is analyzed. It was established that the bromometric Card 1/2 method of determining iodine numbers (the Kaufman-Gal 'porn method), when 62-1-18/21 Application of the Kaufman-Gallpern Bromometric Iodine-Number Determination Yethod to.Certain C5 and C6 Hydrocarbons applied to individual monoolefines C5 and C6 and their mixtures with alkanes., offer highly satisfactory res6lts. The authors determined the coefficient with the aid of which it became possible to utilize the Kaufman-Gallpern bromometric method for the determination of the content of monoolefi4p in their rij~ture with conjugated dioleflnes and alkanes, Detailed results of this investigation are presented in unmunbered table on page 123. Table. There are 5 Slavic references. ASSOCIATIONt Academy of Sciences of the USSR, Institute of Organic Chemistry imeni N. D. Zelinskiy PFXSENTED BYs SUBMITTED: October 10, 1956 AVAILABLEs Libroxy of Congress Owd 2/2 L "Investigation of the Antiknock properties of individudal petroleum hydrocarbons." S. S. Bovikov, B. A. Englin, T. I. Naryshkina, A. P. Subbotin, E. Ya. Lapshina, T. P. Do'brynina, and I. D. Inozeintsev, Khim. i Teklinoi. Topliva i Masel 1957, No. 9, 7-TT.-The following octane nos. were found for the synthetich hydrocarbons, k listed after addn. of 11.0 cc. of "r-9"/kG. b~,fore and after aadn. of 20,4a naphthenes: cyclopen'Umne 104.3 and 104.9; eth,,,Ic,,,cl()- Pentane 104.3 and --; iuoprmi,icyciopentana 104.8 and 102.0; 1,1,3-trime- thylcyclopentane 104.3 and 10t.1. Octane ratings of the folluming nonsynthetics are given as: cyclobexane 93; nethylcyclaboxanae 14 c-ehylcyclohexznC 7-33; isopropyleycol1exane .92. H. L. Olin/ AUTHORS: Shuykin, N. 1.~ Timofeyeva, Ye. A. SOV/62-58-6-12/37 TITLE: The Contact-Catalytic Dehydration of Isopentane in Dependence on Temperature (Kontaktno-kataliticheskaya degidrogenizatsiya izopentana v zavisimosti ot temperatury) PEnIODJCAL; Izvestiya Akademii nauk SSSR, Otdelcniye khimichookikh nauk, 1950, Nr 6, PP. 726 - 729 (USSR) ABSTRACT: In an earlier work (Ref 1) the influence exercised by temperature upon the dehydration of n.isopentane in the presence of an aluminum-chromium catalyst was investigated. It was found that at 500-550 0 the reaction of the dehydration of n.pentane attains the state of equilibrium. In the present work the same investi- gati-o-n,,is carried out with isopentane. It was found that in the interval of 500-5500 the dehydration of isopentane attains a state of equilibrium. At 500-5500 the amount of isopentene obtained from isopentane exceeds that of n.pentene obtained from n.pentane by 7-6 mol %. Less "coke" and gas was formed under existing conditions (by the dehydration of isopentane) than by the Card 1/2 dehydration of n.pentane. There are 2 figures,4 tablesand 5 The Contact-Catalytic Dehydration of Inopentane in SOV/62-58-6-12/37 Ieopentane in Dependence on Temperature references, 4 of which are Soviet. ASSOCIATION: Inatitut organichealtoy khimii im. N.D.Zelinskoco Akadenii nauk SSSR ( Institute of Organic Chemistry imeni N.D.ZelinGkiy,AS USSR) SUBMITTED: December 6, 1956 1. Isopentane-Dehydration 2. Isopentane--Catelysis 3. Isopentane-Temperature factors 4. Aluminum-chromium catalysts -Performance Card 2/2 `or~ ro arb, 11-- (:if 111 f f Tii i c) - C hr c m i it rT, - ' o t a u in a v %ti-'~,voclorodov razlichnogc t v u 5 t 1 rn j-. 1 y '~l r_1 fl C k Ft + 2 U t Q a r f Or rLfft~ ha ii he ~Y,,re s n c i7- o f omd:-' catrily.,-t:~ on :7r~rtaizn condi tior.-, aromatir. hydroct-rbail.-. ~a-p 'Conmed alkar,.~-s, nEving 6 and ~~urbvn atcou in th,., ifl-lin i7~lliai-D. Th~ r-lt or:- th.--,,, nre nr~t --l-dtA Nir a -Hreof v./clizntion I. It iho ]vo.- -,f `,iiL, aro:r:ati7,n*.icn of f:!,.d dirc~,,te('L to of -,ii+,,:rnl c,-i n~ilturn ttc.,l -.-Ith ',h~ r,;~,Vction-n of in ly: I C, a Y- i!1 t i ht~ ~~e err:, i ra t d 1!1 -A"; ;,Z~-Il~e ,f Orgarji(, Nl-ini-:~trv iimc-n4 D. Zelinskj~r 'Af~ T"P Pt~ t-lm ry tl c58 SOV/62-58-7-18/26 1~: Shuykin, N. 1. 1 Timofeyeva, Ye. 'x., Plotnikov, Yo. IN, -'.2Lryayevn, Kle~.menovat Ve 1% T Tht~ iletoti~,ns o.,' N.Alkafies ~"ith a CS) tructure in the Presenco of AlLim, no-Chrclaiu-ri-*Fo t !sqsi~.an-'C at a Iy sts (Prevrashchenlya n.alk-anov sostava Crl- Co v Prisutstvii al.,,tiinokh:t-r,lmokaliyr-%vr,t-.o katalizatlora)-I Ivve...JiYa Akad,riiii naul, 'SOS.R, Dtdelenlya k1li-micheskikh llauk, 1958, Nr 7, pp, 896-898 'MR) ABSTRACT: The production of alkerles and alkadienes by means of the cat,,jl,jti,, dollydration of the alkanes iL of scientific and practleal intorect. In the present brief report the authors desurlite, tle rpaction of nwalkanep (from pentane to nonane) in tho of P-I,--mino-chromium-potasciii)m catalysts of hi(,), nctivity an,.; %3tability in the deh:;dration of ino-I pentane. It was shavai that on thin-' conditions asl3umed catalyst!7 oould be obtaln-id frorm thes,.? alkanes which ecnt,%inc-d B-29 I/"- -)-r unnaturate(i atit4 of &romatio hydroeprhons. FinE-Ily ~'a r 3 1 the authorii point tc. t4t., fao6 that after thr~ dek-tiration of 3AVI"62-5-18-7-1 3./26 ,Th.- Ren r-. ,, !Ons of' '."Lth a f~-' -C. Struct.-ire in the Presvnco of A'. um ino-Chrom, lur-!;o tlaa.~i t -Lim ~;,-.talystq the U c 9 n.alkaneq they obtained catalysts which contained mor,~ ~I-ian 14 c~ of ulkeneso There are 1 figure and 5 reforenoc..-3, 5 of which are Ooviet. AS'O, 0"' 14AT I ON Tlistitut organicheskay khimli im. IN, D. Zelinskogo Akadernii nauk SSSR (Institute of Organic Chemislry Imeni. N. D. Zelinskiy AS U S-R) SUBMITTED: February 17,.1958 ~i ~vnd i n f-7 mb er c ciejces T F T ro"I.-L Im t ion r n-Pent tint- ndi T t i n i re 8enc e of I u, m I a s a t Z~ J i z i - . U y C, c,,,:-; j a v pri.-, r i. tv i i a Iy um rnviok al i revo e~o C. I t a 1 1, z; r or;-i 1 Jotlc.-Av u. R p u 170,11"p. C 1, Ithough mixed clatalysts (Ref 4, as montioned in the titi-~ c----,-, be found aireLdy in earliex, impers the. authors of this rn a 0 4' ouccee,!~~d for the firslu tiMe in th._- deter in ti r o~ the moit favorable quantity rnfio of the, Co!:,ipon-,-2zIts and t1:0 coardit-Icrs of the previous,! of formusae are mentioned tot-other i%'i-th tl-~ formlae for t ion. Tiv., influence of a) b) bulk veIc,,,-ty ob volarmyn sic Oro!-_t t Ild C) tht~ dul"It -;on C-1, thv vorking 1llvQs'iivatcd vdth r(,.uv~~ct to t'lc: Ca`-aci' t y o_,~* d e hyclrat2ort of the mentionod cat,%Iyst. ;',fter ert,:h re-generation Ca cl ~:a-,alyi~t Lwas treated for 1,1~) hourg with 'hydrogen. a) Ta"-,Ie 1 !4 aml Isoventane In --~rezence of Hit- restlits -)I* the tonneraturc ""hich jzpuarnntee yield of penteneounrl, n rc-rt-ai,- ~he re:ni'lts of the e---.,er'mentr il ti bul% i-i 71 Accov,i -Li'q, t,,-, !.!i i "ho pent,~ne i.1nil '::c- ~C.'Ido d1opend on flik, ilhe lower It 1 ii,~gher the influcrice. Thus thc rI*-It:j,jTo of velocity from G io reduce3 the izonentene ri-f-ld from 38 To 'Iffid 11--? yicld of pentenes from I Lo I t 11--, 9 0 d '57 tnis ln-~~Iuence I)ractically ceases. c) The higher thp t~~!"Iner;-'tvre the riore rapidl-y decre&se.~ Lne aclivily of the ~:.,~al'Yst respect to time (Fig I I a viorkine -'~210 of an 18 juinutns- duration tho conlent iri- from 25 -rv reight it-, '115 in Conlic-Cti-On 1"'ith a cf temnev?itllva from 500 to uomrllto~; Fov the iof~- )v:v'IIg- the Clitfily8t. j.~ I'l-l'o t".-t in a Cy 0 1 11 oil r rj Z-1'. r1 d 1 "1 if! i I I I I t E 'I un, I o f b h 0 J he -1,11an %t 5 17 t) i 0 -.v i t h I'le 1 6 c, om pa r u (I t 1 7 end I'Lu 4!1" C, 0!, t1,,-. t the 'OrO "'Uh the 1111der .,07/2o-121-z-25"' 7 ~l Y 4 Deli,' drogenation of n-Pentane ~znd Isopentane in Presence of hlumo-Chromiurn- T,otassium Catalysts the just mentioned ~conditionu. There are I fir ,ure, 2 tables, - -6 7 xelfe-rencen, 4 of which are Soviet. ASSOCIATION: Institut orgailicheskoy khimii. im. N. D. Zelinskogo AkEldemii nauk SSSR (Institute of Organic Chemistry imeni Zelinski.; ;.S USSR) SUBM IT TL,~D .JanuarY 4, 1958 Card 3/3 ~ ( 3) Ar THOR Timofi,,,,p--,ra, Ye. A,., Shuykin, 11. 1., 90-1/62-59-5-1VIO T. P., Kleymenova, V. ",. TITLE: Effect of ftwe VAIMMW' oi the Catalytic Dehydroacnati-or, of nr-Pont sue and Isopentane obllyemnoy skorosti na kr%talitichealcoye degidrirov~.niye n.pontpna i i7opontana) PERIODICAL: I%vestiya Akadeinii nauk SSSR. Otdeleniye khimicheokikh nauk, 1959, i1r -5, 'pp 875-878 (USSR) ABSTRACT; In previous works (Refs 1-3) on the temperature effect on the dehydrogenation reaction of nrpentanG and isopentane the authors" showed that this reaction attains equilibrium at a sWe veloc- It'y-of 0-5/hr in the temperature range between 500 and 5500. .Lii cunnection with it the,effect oL' the tbroughput rate on the reaction mentioned has been invcstigatad in this work. Y~-Pentane was investigated in the ter.Derature range between 500 .-5500, isopentane in the name temperature range and at 5750. The oace velocity: 7tas varind .-~'rom 0.3-1-7/hr. The method of analysis and the invenntigatirn conditions ware e~imilar to those of the works (Refo 2, 3). The rr.,~ults obtained are shown in tables 1-4 iind figruros 1 nnd 2. Tnbles 1 Card 1/3 and 3 show the eff eat of thr~ qMe Ve3.OQj4 on the dehydro- Effect C Space Velocity 6n thp Catalytic SOV/62-59-5-16/40 Dehydrogenation of n.-Pentano and Inopentane genall-ion reaction of nrpentano a~jj isopantano, rvinoctively. Tables 2 nnd .4 show the molar bn1ance ~f th~~, ronction and th,~ seloctivity of tho cntalyst of Min -t,,,.-o t,3ompo-onds mezition*d. The figures show tho moIRr balnnco Oopcniing- on thf, t1hroughm.-A rate, Aluminum chromium potr~03jjjM Cptajyn4.-:, wcro u-.:),l in tji~ reactiono. It aDDeared thnt 'Oic dc,3o--'ince of the mono-olefin yield on the qMe 'Velocity decre-ses with temnoraturo rirv.. If the reaction is carried out at a optce velocity of 0.3-1.1/hr at 550 and 5750 the yield is not 'changc~ at, all. Optimfim reaction conditions -Prevnil at 5500 and a owe' valoc- ity -~f 1.1/fir. Under thc3e conditinn's 45 mole isopentene and 5 mole 75 isoprene were forned from isopentane. 39 Mole~41 pentene are formed from n.-pentane. The iso-nrene -,rield is T)ractically independent of the chance of ~Opaoe velocity; it never surpasoes 5-6 mole of the isopentane let throigh. There are 2 figures, 4 tables, Pnd 3 Soviet references. 5 (3), 5 (4) AUTHORS: Timofeyeva, Ye. A., Shuykin, N..I., SOV/62-59-9-46/40 Dobrynina, T. P.t Kleymenoval V. M. TITLE: Lifetime of a Catalyst Without Regeneration at the Catalytic Dehydrogenat.ion of Isopentane PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk, 1959, Nr 9, pp 1623 - 1626 (USSR) ABSTRACT: The present article is the continuation of the investigations of these authors on the dehydrogenization reaction of pentanes on aluminum chromium potass 'ium catalysts. The reao'.4-an scheme is described. This showed that the yield of amylenes at higher re- action temperature is independent in a w1de -".ge of the volume ate of the initial substance. In the present paper investiga- tion was carried out Gn.the influence on the dehydrogenation re- action of,-the duration of the operation cycle of the catalyst between jogenerations at 500, 527, and 5500. At 500 and 5500, 28 e3, rments were carried out until the regeneration of the catalys-6, and at 5270, 33 experiments. Table 1 contains the in- dices of thd different work cycles. It showed that when the re- action temperature was higher the aotivity of the catalyst de- Card 1/2 creased faster. The maximum yield was obtained at 5000 in ex- Lifetime of a Catalyst Without Regeneration at the SOV/62-59-9-16/40 Catalytic Dehydrogenatior. of Isopentane 0 periment Nr 8. At 527 and 550 the maximum yield was obtained al- ready at experiment Nr 3. The yield was larger at higher tempera- tures, but decreased faster and it was considerably smaller at the end of the experiment series as when carried out at lower temperatures. This effect was explained by the shielding effect of the large quantities of formed isoprene on the catalyst. The yield of isopentanes is larger at lower temperatares, because side-reactionB do not occur at these temperatures. No isoprene forms at 5000. Therefore, it is preferable to repeat the regene- ration of the catalysts when using it at higher temperatures (after I hour) and to carry out the reactions at high volume ve- locities (there is a possibility that more initial hydrocarbons are consumed). At 5270 regeneration has to take place after 3 hoursp and at 5000 after 6-8 hours. There are 1 figure, 2 ta- bles, and 3 Soviet references. ASSOCIATION; Institut organicheskoy khimii im. N. D. Zelinskogo Akademii nauk SSSR (Institute of Organic Chemistry imeni N. D. Zelinskiy of the Academy of Sciences, USSR) SUBMITTED: December 25, 1957 Card 2/2 S/595/60/000/000/012/oi4 E196/E485 AUTHORSi Shuykin, N.I., Timofeyeva. Ye.A., Dobrynina T.P. TITLE; Contact-catalytic dehydrogenation of pentanes SOURCE: Vsesoyuznoye soveshchaniye po khimicheskoy pererabotke neftyanykh uglevodorodov v poluprodukty dlya. sinteza. volokort i plaaticheskikh mass. Baku, 1957, Baku, Izd-vo AN Azerb. SSR, 1960. 261-265 TEXT: In earlier published work, the authors found tbal dehydrogenation of n-pentane using catalyst composed of oxides of Al, Cr and Mg in molar ratio 45:30:25 at 500 to 550'C with space velocity of 1.2 hr-l gave condensate containing 21 to 26% pentenes, i.e. 18 to 19% of the transformed'pentans. A more effective catalyst of the composition A1203, Cr203, K20 (90.7:5.6,3.7 mol %) gave from isopentane at 527*C an 87% yield of catalyzate with art olefin content of 38%, consisting of all isomeric isopentenes, mainly 2-methyl-2-butene and also n-pentans (0), isoprene (2%) and small quantities of pentene-1, pentene-2 and toluene. Under identic*al conditions, n-pentane was dehydrogenated in 88% yield to a product containing 31% of olefins including: pentene-2 (28%), Card l/ 3 s/595/60/000/000/012/014 Contact-catalytic dehydrogenation ... E196/E485 pentene-1 (3%), also isopentane (3%) and pentadieneskl%)~ The yield is increased by 3 to 4% if the catalyst is reactivated with hydrogen. The same catalyst was used to study the effect of temperature, space velocity and the duration of working cy,:les, The catalyst's activity is claimed to be such that reaction equilibrium is reached at 500 to 550*C with a space velocity of 0,,3 to 0.5 hr-1. The affect of space velocity on the yield of pentenes varies with temperature. At 500*C the yield of isopentents is reduced from 39 to 27 mol % when space velocity rises from 0.5 to 1.1 hr-1. The corresponding reduction in the yield of isopentenes is 46 to 42% at 5270C and none at 5501C. At 575:C space velocity can be varied from 0.3 to 1.7 hr-1 without effect on the yield, The catalyst's active-life deer-eases with increase in reaction temperature. In order to obtain maximum quantity of Isopentenes without regard to the usage of raw materials, high reaction temperature (550*0 and high space velocity (1.1 to 1.7 hr-1) are recommended. if, however, the objezt is to get tht highest conversion of isopentane to isopentene, then the lower temperatures may give more economical operation, There ars Card 2 /3 Contact-catalytic dehydrogenation 2 figures, 2 tables and Soviet-bloc. Card'3/3 S/595/60/000/000/012/014 E196/E485 AUTHORS: TITLE: PERIODICAL: 86414 S/062/60/000/008/022/033/XX BO13/BO55 Shuykin, N. I.., Timofeyeva, Ye. A., Plotnikov, Yu. N., Petryayeva, G. S., and Gayvoronskaya, G. K. Catalytic Dehydrogenation of Isohexanes Izveatiya Ak"demii nauk BSSR. Otdeleniye khimicheakikh nauk, 1960, No. 89 pp. 1457-1465 .-TEXT: The present paper is a continuation of the investigation into the dehydrogenation of hydrocarbons of different strucituries over an aluminum- chromium-potassium catalyst. The catalyst is discussed in detail in Ref.l. The 2-methyl pentane, 3-methyl pentane, and 2,3-dimethyl butane used in this investigation were prepared by the Grignard reaction. 2,2-dimethyl butane was obtained by pyrolysis of pinacoline alcohol acetate ~Ref. 2). The experiments were carried out in a continuous system, at 500 C and atmospheric pressure and a flow rate of 0.5 h-1. The catalyst was re- generated after every experiment by oxidation in air at 700 C. The properties of the isohexane catalyzates are listed in Table 1 and the Card 1/3 86414 Catalytic Dehydrogenation of Isohexanes S/062/60/000/006/022/033/XX B013/BO55 composition of the gases formed in Table 2. For comparison, the correspond- ing data for n-hexane are also given. As Is shown, dehydrogenation of 2-methyl pentane, 3--methyl pentane and 2,3-,dimetbyl butane yields 34-40% unsaturated hydrocarbons. Isohexanes form up to 2% and n-hexane up to 43% aromatic hydrocarbons. 2,2-dimethyl butane was found to form 15% un- saturated hydrocarbons. Formation of aromatic hydrocarbons was not ob- served. The gaseous products formed from 2-methyl pentane, 3--methyl pen- tane and 293-dimethyl butane contained 84 - 90% hydrogen, 9 - 12% methane, ethane, and propane, and 1 - 4% of other alkenes and alkanes. The gas ob- tained from 262-dimethyl butane contained 72.6% hydrogen, 21.2% C -C alkanes and 6.2% of other hydrocarbons..These data show that 20-jim9thyl butane is less stable under the given conditions than all other isohexanes. This conclusion was confirmed by the examination of the-liquid catalyzates. Analytical. data on the catalyzatecomposition allow the conclusion that, in hydrogenation under the given conditions, all the isohexanes form alkenes containing essentially 6 narbon atoms. Isomerization was not observed in dehydrogenation of 3--methyl pentane. Slight isomerization occurred during dehydrogenation of 2-methyl pentane and 2,3..,dimethyl butane. 2,2-dimethyl butane formed alkenes during the catalytic reaction. Approximately half of these alkenes were isomerizatLon products: 4-methyl 2-pentene, Ca:rd 2/3 86414* Catalytic Dehydrogenation of Isohexanes S/06 60/000/008/022/033/xx BO 1 3YBO 55- 2-methyl 2-pentene and 2,3--dimethyl 1,3-butadlene. Finally, a thermo- dynamic calculation of the-reaotion isohexanes ---)-isohexenes was carried out (Table 8, Fig. 2). It is evident from the results obtained that the experimental yielde of isohexcnes approach the equilibrium yields. Fig. 1 represents chromatograms of an artifi.,ial hydrocarbon mixture and several fractions of isohexane catalyzates. The authors thank R. N. Shafran for carrying out the analysis of the gases. There are 2 figures, 9 tables, and 9 references: 7 Soviet, 1_US, and 2 British. ASSOCIATION: Institut organicheskoy khimii im. N.,D.,.Zelinskogo Akademii nauk SSSR (Institute of-Organic Chemistry imeni N. D. Zelinskiy of th Academy of- Sciences USSR) SUBMITTED: February 17, 1959 Card 3/3 TIMOMMA, YO.A.; SHUYKIN, N.I.; DOBRININA, T.P. Dehydrogenation of 2j, 2,, 4-trimethylpentane on an alumina-chromium oxide-potassium oxide catalyst. Izv,AN SSSR.Otd.khim.nauk no.5; 863-867 Yq 161. (MIRA 14:5) 1. Institut, organicheakoy khimii im. N.D.Zelinskogo AN SSSR. (Pentane) (Dehydrogenation) TIMOFEYLVA, Ye*A.; SHUYKIN, M.; DOBRYNINA, T.P. Poisoning of chromium-alumina catalyst with cyclopentadiene and furfurole. KinA kat, 2 noA1574,-580 Jl,-Ag 161. (14IBA 14:10) 1. Inatitut organicheskoy khimii AN =R. (Catalysts) SHUYKIN, N.I.; TIMOFErEVA, le.A.; DOBRDM., T.P.; FLOTNIKOV, Yu.N.; PEMYAIEVAp G.S.; GAIVORDXRUMFp-T-.W.- Catalytic dehydrogenation of isobexanes. Izv.AN SSSR Otd.khim. nauk no.80457-1465 Ag 162. (MA 150) le Institut organicbeekoy kbimii ix. N.D.Zelinskogo AN SWR. (Hexule) (Dehydrogenation) SHUMP N. I.; T3240FErEVA, Ye, A.1 FLOTNIKOV, Yu. N.; DOBRYNINA T. P ; PETUAMAP G. S.; SMIMOV, V. S. Preparation of C6 - CIO alkenes br the catalytic dehydrogenation of alkanes. NefUkbimia 2 no.4:457-466 A-6ft. 162. (MIRk 3-5: 10) 1. Institut organicbeskoy kbixii AN SSSR imeni N. D. Zelinakogo. Mraffins) 619fins) (Debydrogetation) I D c, 43 t%,, y NI iv t9 ShTPOL-I.L- TDWZMA, TSA-, nDTHIKOV, T.P., DOBMINA, T.P. PETqUTUA, 0:6. Catalytic debydroCenation of set]WIpestaces and a 2,3-diMtV%butww. Report preeented at the 12th Coafersaos on Mgh molecular weights scapounds, devoted to monmers, Bakas 3w7 April 62* SHUYKIN, N.I.; IIOZDNYAK, N.A.; DOBRYNINA, T.P. Catalytic . alkylati.on of tetralin. Report No.9: Alkylation of tetralin by alkene fractions of paraffin c;acking. Izv. AN SSSR. Ser. kbJp. no.llt201.1-2014 N 163. (MIRA 17:1) 1. Institut organicheskoy khimii imeni N.D. Zelinskogo AN SSSR. SHUYKIN, N.I.; POZDNYAK, N.A.; DOBRYNINAp T.P. Catalytic alkylation of tetraline, Report No.10t Possibility of using the dehydrogenation catalysts of n-nonane for the alkylation of tetraline. Iav. AN SSSR. Ser.khIm. no.3:530-534 Mr 164. (MIRA 17%4) 1. Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR. SHUYKIN N.I.; POZDNYAK, N.A.; D(BRYN1P,_~,-.P_- Action of cation-exchange resin KU-2 on the primai-f alcohols of normal structure. Izv.AN SSSR.Ser.khim. no.9:1705-1707 S 164. (MIRA 17t10) 1. Institut organicheskoy khimii im. N.D.Zelinakogo AN SSSR. S I IRMIN, IN.I.; PUDIdAlf, N.A.; PqBRYNINA, ; . .1. Catuly-Lic alkylation of tetralin. Report 11: AlkyluiLion of tetralin in the presence of titaniiim Letrachloride. Izv. AN SSSR Ser. kbim. no.1:119-123 165. (14TRA 18: 2) 1. Institut organicheskoy khimii im. 7elinskogo AN SSSI. KOZIMINA, Z.P.; r -Potential of baYerite and of the products of its heat treatment. Koll. zhur. 26 no-5:592-594 S-0 164. (MIRA, 17:10) 1W'v.Y j : j Z W Rp 1115MINE IF-0 At is a v n At U It Ad a 0 1 A 9 to It it tj M Is 14 It 1A A 1, z AA m n' A t too 16 Ate-i-I M-0.0-5-- Psocitus ale FRIPPIRMS .016 Allaradon of' iho I ajilii acid co'cm'pWdon of the brain .00 gin laralad" to Wagoof man, It"Swail..j. q It", 1, t rhysiol. V. S. S. R. 9. ZW-24(in Ingish, =3-4) -00 (1111W tudysies were nuule of brolnit from subject. who *00 hm dLT.Af troulm. not trout disraw, for tryptophan, tyto. sm. C histidine and I)-4nc. Tric age. ~00~ 00 I=iav W) Yrs. Tryptophan dmrasm -00 oo gradually with age; cystine increases Irtiot infancy to 9 00 1 hen rmains const. Atzinine reachr- a tuait. at it. -00 y"" and drops slightly afterwards; trystine of the cerebellum see 001 i1wredOW, ronxii1embly between infancy and 1) yt.%. The 00 a cystine and lysine contents of the mebellunt differ sharply 0 from ificise of the Iscruispheres in all age pmps studied. see I I references. C. S. Shapiro 1W, go 0 goo see goo x90 lee too 0, S L A DITALLURGICAL LiTINATURI CLAIMPICATIOU slow NO-114T 141011.2 W1, ON11 cat OlUll slaiii atit o-v Lit _T_r__F F a I 1 11 (W 0 0 v I IN " 5 a 4 3 1 7 Is 1110 U ta AV 10 LS 0 Cr Is UP 0 im V W 111 Of u n ft Is Is I Is 0 0 0 0 0 0 9 9 0 0 00 0 *0 010 o o 0 o 0 0 0 0 0 - 0 0 0 0 0 0 0 0 a 0 0 a 9 0 0 0 0 0 -All DOBRYI.-M-A'V.~., Mr., Chair of Biological & Organic Chomistry. =nt Wedical Instiute,, MOSCOW I-, I It Aminoacid Conte-t of Human Muscel. Proteine," Biokhim., lo, iza. 1, 1945 - 0 00.3 09.3 oov 00's I L A 11LA I a 0 ... ... a I;;; t I;" i WD## .. I toaaw Ott avw off U 9 AV 10 &%1; to 0 to p 0 a a a n a pt a it *0 0 0 0 :10 o o * 0 of 00 000000010 0-0-0 0 0 0 0 0 0 0 0 * 0 0 0 0 0 6, p ol 0 fli-i-99 off gig; 0; 4 It u U u 11 10 0 -af,-b N a . 7 F ob a N., - a L~"-" 0 CC 911 0 Joe *kv A. W.." ; w itsid bcaln low-prittelts diet on tile 11 dMe r000MOM of *Wft rlkt~. Doltrynim and P. Maklinkhaw Mcoad Mawow Wtdr' 11111111W V . kkiaiya it. 604QW)l cf. Lfbinixe. C.A. 42. "VA.- f In The ~ of a pmr-priterin dkA. tb* Wh1wly o W by wUvtr tiew of wbite rats is kwered by ithatit ME The iftcriesse fs the result of a dIsturbance In the 301 e. iunctka of O"tka = swems Which Cautlyst the ruyk l W id o a et py dtambuttivat of anduo It wid the ax %he it- of brain W-tit I h . e case n t end lumarle avials. crcsoe of ers;i1nitlaw 6 " sevoMfign6ril by a d6tuthitner at the risayinle systems which askust pvmvk, futuaric. and mxdnk acklia. The sawlide drhytImlenaw vaul ev. toclaronat arstrats wv unaffnied by a lutt-prottin dkt - 14. Priestley v 6 a age I-Of 0 0 400 aam I -- too 600 woo 40 goo goo "go 1:10 0 Off 1100 'Die 9, Z!, r x l#ft it"In" WOO 00 -ii-i - __ a a -N, 0000000 0 Igo 000000000*0 111 0 0 * 0 0 0 0 0 0 0 0 a 0 DOERYNINA, V. I. -, -_,- . -~ . ~, - I - . - . ~ Iffaot of low protols diet on tissue respiration and ascorbic acid content in thO brain tissue in white rates Uchen. japski vtore moskove mod* Insto Stalins, 1:133-138 1951. (CLML 21:3) 1. Docent* 2* Department of Pharmacology (Read -- Honored Worker in Science Prof. V. I. Skvortsov, Active Member AMS USSR). Pharmacists Trainirle; nndulneemi-nt .)f phni-maciste. Apt. dplo ro. 1, 1952. Monthl List of Rutsinn Accessions. Library of Cone-recs November 1952 MCLASSIFIED 1 Dc STI-M. IIAP V. I. Docent 2. U-33R (600) 4. Pharnacy - Study -.nd Teaching 7. Trair---- research.and teachina, jerscnne! i:.-. th-e ncst im)crtant task cf 1-)harmaceutical institutes. Apt. delo no. 2. 152. 9. Monthly List of Russian Accessions, Library of Congress, Februwy 1953. Unclassified. ne P hermaceuticale 52 ;USSR/Medici "From the Rostrum of the XIV General Assembly of the International Organization of Pharmacists," Docent V. I. Dobrynina J'Aptechnoye Delo" No 3, PP 78, 79 Gives brief account of the meeting of the Organi- zation held in Rome in 1951 with participation of USSR representatives includina Dobrynina. The papers mentioned in the account dealt with sci- entific developments, new drugs, dosage, interna- tional standardization of phnrmaceuticall nomen- clature, training of pharmacists in variouE, 2 2 2.T,'-':, :0- ou~tries,' compilation -of'An~ internet.iongLI pbirm_ 'copoeia, etc. Emphasizes interest in USSR develop- ments e1winced by representatives of other countries. 221T24 DOBMIKIs V. I.$. Docent,--. Pharmacy - 5tudj and Teaching Department for the Advancement and Specialization of Pharmacists. Apt. delo no. 4, 1952. Y,ont---- List of Russian Accessions. Library of Congress. November, 1952. UNGLAS3TFTvn - ---A DOBRYNINk, V.I. In memory of A. N. Adova, 1890-1952. Aptech. delo, Moskva 2 no. lt?8- 79 Jan-Feb 1953. (CUL 24:1) 1* ]Director of Moscow Pharmcoutic Institute of the Ministry of Public ~;alth. 2. The deceased was Dean of Moscov Pharmacoutio Institute. IVANOVA. H.A.; KLYOTIVA, A.D., doteent, xaveduyushchiya kafedroi marksizma- laninismu Moskovskogo farmatsevtichqskogo inatituta; DOBRYNIXA. V.I., dotsent. dirqktor Nogkovskogo farmatsevtichee~ogo ins-IMIN7 I. V. Stalin'B work *Xoonomic problems of socialism in the U.S.S.R.'! is a great contribution to the treasure house of theories of Marxism and Leninism. Apt,491o 2 no.2.-7-13 Mr-Ap 153. (MLRA 6:5) 1. Kafedra vArksizma-leninizza Moskovskogo farmatseyticheskogo inatituta Ministerstva zdravookhrananiya SSSR. (Zqonomics) w BULMOV, T.I., aspirant- DOBRYNINA, V.I.. diiektor, doteent. Pharmacoutical.centers. Apt.de i6 2 n6.2:22-24 Kr-Ap 133. (MMA"6-5) 1, 11afedra orgi~iisqtsit farmatseitichookop del& Koskovskogo farmtsev- tichaskogo Instituta Hinisterstra *dr*vdbkhrMenijva SSSR. (Phar~a6y) DOBRYNINAq V.L$ predeedatell. Department of correspondence courses. Apt.delo 2 no.2:63-64. Mr-Ap 15 (HLRA 6:530 I* Sektalya po kadram Aptechnogo soveta pri Glarnom Aptechnom Upravlenil Ministerstva sdravookhranoniya SSSR. (Pharmaq--Study and teaching) DOBRYNIXA, V.L. predeedatell. Nft"MMMWW All measures should be empl,)yed to provide the neoDle with better pharma~ cautical service. Apt.delo 2 no.36-5 My-je -5-3. (91,RA 6:6) 1. Sektsiyapo kadram Aptechnogo soveta pri, Glavnom aptechnom upravlenii SSSR. (Pharmacy) BULENKOV, T.I., aspirant; DOBRYNINA. V.I., direktor, dotsent. .MWWWWM--- Norms for the evaluation of the quality of medicinee pre-Dared in pharma- cies. Apt.delo 2 no.3:9-10 My-Je 153, NLRA 6;6) 1. Kafedra organizataii farmatsevticheskogo dela Moskovakogo farmatsev- ticheakogo instituta Ministerstva zdravookhraneniya SSSR (for Bulenkov). 2. Moskovskly farmateevticheakly institut Ministeretva zdravookhraneniya SSSR (for Dobrynina), (Drugs-Standardo) KOSTYAKOVA, A.I., doteent; DOBRININAs Vol.. dotoent, direktor. - .,Mo. - 1, , ftsw""~ qualitative determination of quinine in pharmacopoeial preparations, by the fluorescent method. Apt.delo 2 no-3:17-19 MY-Je '53- (MLBA 6:6) 1. Hoakovskiy farmatsevticheskiy institut Ministeretva zdravookhraneniya SSSR. (Caiinine) SHEKYAKIN,.Y.M., K&MV, A.N.; MEDVIDEVA, N.K.; DOBRYNINA, V.L. dotsent, di- . rektor. "W"W""Sha-ZA"Aw Chromatograms of vegetable extracts. Apt.delo 2 no-3:19-22 MY-Ja 153- (MLRk 6:6) 1. Moskovskiy farmatsevticheskly institut Ministerstva zdravookhraneniya SSSR. (11mtract a )(Chromatographic analysis) KHOMOVA, 0.1.; SHERYAKIN, Y.M..* professor. zaveduyushchiy: DOBRYNINA, V.I., dotsent, direktor. N"*W"MNW Determination of admixtures of heavy metals in pharm&zeutical preparations, by the method of chromatographic analysis. Apt.delo 2 no,3:22-25 MY-Je 153. (MURA, 6:6) 1. Kafedra analiticheskoy khimii Moskovskogo farmatsevticheskogo inStitUta Hinisteratva zaravookhraneniya SSSR (for Xhokhlova and Shemyakin). 2. Xo- skovskiy farmatsevticheskiy institut Ministerstva %dravookhraneniya SSSR (for Dobrynina). (Chromatographic analysis) BELOUSOVA, A.G.; DOBRYNINA. V,L, dotsent, direktor. Apparatus for drawing off liquids with a pipette. Apt.delo 2 no.3:54 My- is '53. (mLRA 6:6) 1. MoBkovskiy farmatsevticheskiy inBtitut Ministerstva zdravookhraneniya SSSRI (laborutories-Apparatus and supplies) DOBRYMITA, V.I., doteent, direktor. Pressing tasks of the higher pharmaceutical school. Apt.delogno.4:9-12 JI-Ag 153. (MIRA 6:8) 1. Moskovakiy farmatsavtichaskiy instil-ut Hinisterstva zdravookhraneniya SM. (Pimrmacy ) BULMTKOV, T.I., aspirant; DOBRYNINA, V.I., dotsent, direktor. a Vitall probletas in the theory of organization of pharnacy. Apt.delo,no.4: 13-14 JI-Ag 153. OQU 6:8) ,o dela Moskovskogo farmatsevti- 1. Kafedra orgunizataii farmatnevticheako.- cheakogo inatituta Mini9teratva zdravooklarmeniva SMR. 2. Moskovskiy far- mtsevticheskiy institut Ministerntvu zdriLvookhraneniva SSSR (for Dobryn--na). (Pliurmacy ) SHEMWIN, P.M.; ANMYSV, A.A.; GUWOV. I.L.; XOXROVA. V.I.; DOBRTNINA. V.L. doteent, direktor. Possibility of using precipitation chromatography for the separation of mixtures of organic compounds which play a role in pharmacy. Apt.delo 2 no-5:33-39 S-0 153. (MIRA 6:10) 1. Kafedra analitichaskoy khimii Hookovskogo farmateartichaskogo instituta Ministerstva sdravookhraneniyfL SWR. (Chromatographic analysis) SHYMOVA, M.D., professor; DOBRYNINA. V.I.,, doteaut, direktor. History of the origin and LWrovement of methods of breaking down organic ardbetanoes for the Isolation of metal and arsenic compounds. Apt.delo 2 no.5:55-62 S-0 153- (wT-RA 6:10 1. Nafedra suds'bnoy kbimli Moskovskogo farmataevticheakogo inatituta Xiiiisterstya sdravookhraneniy& SM. (Arsenic organic compounds) DOBRYNINA, V. 1. Correspondence coarsese '~Y)t. delo 3 no,4:38-39 Jl-Ag '54. (Y-LRA 7:8) 1. Direktor Xotkovskogo farmtoytiebookogo institute. (PHARMLCY, education, *Russia, cort9spondenos courses) Further improvemeirt in pharmaceutic education by correspondence. Apt. delo 3 no.6:24-26 N-D 054. (MLRA 8:2) 1. Direktor MoskovBkogo faruataevtichaskogo institute, Ministerstva zilravockhraneniya SSSR. (PHARK&GY, education. in Russia, corespondence courses) Name: DOBRYNINA Valexitina Ivanovna. Dissertation: The Effect of Protein Deficiency in Diet upon Chom Composition and cartain Metabolic Proces.,es of the Brain (Ex- perimental S`iVdy,)., Degree: Doe Med Sci Affiliation: Moscow Pharm Inst Defense Dete, Place: 10 Oct 55, Council of the 2nd Moscow State Mcd Inst imuni Stalin Certification Date: 28 Apr 56 Soiirce: BIWO 4/57 Loqntry Catosory V Abe. Jour, Ref Zhur-Biol', No 19, 19580 No 89828 Author Inatitut. Titlo OrIS Pub, Abstract increase of the dose of caffeine, the intensity cont'd. of tissue respiration increases, which is re- fleeted in the 0 consumption. When prescribing caffeine as a stimulant of the nervous system in a weakened condition of the organigm, it its recommended that glucose be administered simul- taneousI7 as an important energetic substratum for the nervous calls. Bibliography: 19 titles.! ~Card: 2/2 CATFC;Ci--,Y v AFS. JoUrt. P~UAC%1.) Vo, 1 1959, Va, 4398 A Ul T K 0 P, T1112 01-.'~ 1. RIB.: A Y'S, 11, .1 r."!,:bnbly duo to a slow elimination of CH from tho C It 01.1-animn. 'The activil 'Y Of enzime. Systerls, parti- cipating in the splitting of glucose in the ,,ere tIssues is prosorvod during the adm4liiist-ra- tion of CH.-- Prom ~he author!a sumnar- y CARD.- 2/2 DOBRYNINA, V.I. llql~~ ~ Yor further progreas in higher pharmaceutical educatioa. Apt.delo 6 no.l-.28-30 Ja-T 157. (MIRA 10-3) 1. Direktor Moskovskogo farmatsavticbaskogo instituU. (PHiRMGT--WUDT AND TJACHING) DCBRYNINA. V.I., professor First all-Russian conference of pharmaceutical institutes and departments. Apt.delo 6 no.5:94 S-0 '57- (MIRA 10i11) 1. Predesdatell organizatsionnogo komitets Pervogo Vaerosetyekogo soveohchan*a formatneytichaskikh institutov i fakul'tetov. (PHARMACT--CONGREMS) -saridrovna, jrof.; SVESUNIKOVA, Yokaterina Alsk DOBRYNIA.&,V . .. "; ROKOOVA, Z.A., takhn.rod. clo sent; DEBOV, 9'.S., Dbnual for practical studies In biochemistry] Rukovodstvo k praktichoskim zaniatitam po biologicheakoi khimii. Moskva, Goa. izd-vo med.lit-ry, 1958. 342 P. NIRA 12:1) . (BIOM14STRr-ZZABORATORY AANUALS) DOBRYNP!A,_V.I-.--.p"f . lel-,,~-,~.- Current conditions and prospects In training pharmacists In the UsS.50RO Apt.delo 7 no.4131-35 Jl-Ag 158 (MHU 11:8) 1. Direktor Mookovskogo famatsevtichaskogo institute,* (PHMWCT-SMY AND TRACHING) SIDOROVA, S.G. . prof.: DC)BEyNIIIA, V.I.. dots. Stimulating Offect of pbenothiazine on sheep development. Vaterinariia 35 no.5.'118-121 MY 158. (MIRA 12:1) 1. Stavropollskiy, sel'skokho ZyayFitV lannyy institut. (Phenothiatins) (Sheep) DOBRYR U Valenti !t ._;XM2XW6,pro.f.; RUCHMIKO, L.F., red,; p N.L., tekhn. red. [Textbook of biochemistry) Uchebnik po biologicheskoi khimii. Mogkva, Medgiz, 1963. 446 p. (MIRA 16:12) (Biocberaistry) DOBRYNINA, V. P.: bobr~rn ~ V. p.: ",)ata~jn the study of diagnostic puncture of the liVer," Trudy Kazansk. gos. atomatol. in-tap Issuo 29 1949, P- 277-2160, - Bibliogs 26 items Sos U-5240, 17 Dec. 53, (Letopis 1zhurnal Inykh Statey, No. 25, 194-9). DOBRr,;INA2 V. P. Dobrynina, Y. p.s "The treatment of ulders by intramuscular autohemolysis injections," Trudy Kazansk. gos. stomatol. In-tap Issue 2, 1949, p. 289- 296, - Bibliog: 21 items SOt U-521+0, 17 Dec. 53, (Letopis Wiurnal Inykh Statey, No. 25, 1949). DOBRYNIMA, V. P. pobrynina, V. P. "The treatment of pulmonary suppurations under arrv- area conditions during the period of the Fatherland Wart 194.1-1945,11 Trudy Kazansk. gos. stomatol. in-ta, Issue 2, 1949, p. 297-305 SO: U-5240, 17 Dec. 53, (Letopis 1zhurnal Inykh Statey, No. 25, 1949). USSR / Human and Animal MorphologYp Nqrmal and Pathological. S-1 Abs Jour I;tef zhur - Biol., No 18, 1958, No 83620 Author D6brynina,_V._R Inst Chk-Q:ov__Mea1-caL Institute Title Cytomorphological and Cytochemical Variation in the ldver of Patients with Pulmonary Tuberculosis and Hepatolienal Syndrome. Orig Pub Tr. Chkalovskogo med. in-ta, 1956, vyp. 51 133-138 Abstract To determine in vivo the morphological and cytochemical variation in the liver of 25 patients with pulmonary tu- berculosis, use was made of the method of aspiratory tap- ping of the liver. 12 patients were subjected to the Quick test and the Tokata-Ara reaction. In all patients the fuchaina-mercuric chloride test was positive, and in 6 patients there was a drop In the synthesis of hippuric acid. In the case of patients with fibro-cavernous Card 1/2 USSR / Human and nimal Morphology., Normal and Pathologic-tl. S-1 Abs Jour Ref Zhur - Biol.,, No 181 1958., No 8362o pulmonary tuberculosis, albuminous, adipose and lipoid degeneration of the liver were noted. In two of these, there was found hepatic amyloidosis) and in one case, t%my- loidosis of a greatly enlargad spleen. In hematogenno- disseminated pulmonary tuberculosis.. degenerative changes in the liver are especially sharply pronounced in cases of subacute course of the disease. There is no parallelism between the morphological and the functional changes in the liver; sometimes, even in the cnae of gross morpholo- gical lesions in the liver, no functional disorders are observed in the organ. -- V. G. Zaytsevskaya. Card 2/2 AUTHOR: Slavin, V.I., Dobrynin~~t__Y_1&_- SOV-5-56-2-3/43 TITLE: The Stratigraphy of Jurassic Deposits of the L7vov Syncline and the Cis-Carpathian Marginal Depression (Stralvigraf-iya yurskikh otlozheniy Llvovskoy mulldy i Predkarpakskogo krayevogo progiba) PERIODICAL: Byulleten' Maskovskogo obshchestva ispytAteley prirody - Otdel geologicheskiy, 1958, Nr 2, PP 43-54 (USSR) ABSTRACT: The author gives the results of recent research work on the Jurassic dpposits of the L'vov syncline and the Cis-Carpathian depression, carried out in co-operation with the Geological In- stitute of the AS USSR, In this connection, the names of Soviet scientists, who devoted their studies to this subject are mentioned, such as A. Alit, F. Peniash, F., Stanislavskiy, P.A. Gerasimov and Ye.A. Gofman, N.R, badyzhenskly, Ya.M. Sandler, I.M. Yamnichenko, K. Voytsik, D. Keshmen, K, Glazevskiy, and S.I. Pasternak. The entire profile of the Jurassic de- posits can be divided into three formations (see Figure 2). 1) the Sokal-, (Lias) formation consisting of sandy-argillaceous and carboniferous deposits; 2) the Rava-Russkaye (bat-Callovian) formation consisting of dolo-mite, gyp3um, anhydride and clay deposits,and 3) the Bukovina formation (Upper Jurassic period) Card 1/2 consisting of limestone and marl deposits, A more detailed SOV-5-V-2-3/43 The Stratigraphy of Jurassic Deposits of the !,Ivov Syncline and the Cis- Carpathian Marginal Depression classification of the Jur838ic deposits of the L,vov syncline and the Cie-Carpathian marginal depreusion has up to now been impossible, There are 4 charts and 7 references. 4 of which are Soviet and 3 Polish, Card 2/2 DOBRYNINA. V. Ye- Jurassio of the oouthweatern Russian Platform and Carpathian piedmont. Trudy VNIGNI no.29:154-161 vol. 2, 161. (MIRA 34t7) (Ukraine, Western-Geology, Stratigraphic) I Ii, Dlying in 0) ontged Mr. Vj DolffV11111if ii" CTU. 1hrm. 1.r. JTT. S F. 1.) drying'A llit. Immilc(liatt: Intwlayeiscan lit- u."'I'lattA 5-18 tillit., ill w(min-4 air lit r(mmi tt:mp. Th,: 1110111d callulA lit wi-11 lit dirplig the toll raillidi (("it Willi llf~- trouslinish. Chas, IMATIC SHTEYMAN, Ye.A.; MORDOVSKAYA, Ye.A. Complexometric detarminatio: of bismuth and lead in Vhe presence of tin. 7Av. lab. 30 nr.10t1200-1201 164. 411-RA 1814) DOBRYMKIY,, A.; VARSHAVSKIYI A. Use of welding in a carbon dioxide atmosphere in the manuf-AOture of latticed metal elements, Prom. stroi. i insh. sooro 4 no.3: 13-16 My-je 162, (MIRA 15:7) 1. Glavnyy inzhener Nikolayevokogo savoda metallokonstruktsiy (for Dobrynskiy). 2. Glaynyy evarobehik'Nikolayevskogo zavoda meta.Uokonstruktaiy (for Varshavskiy). (Steals Struotural-Welding)' DOBRYSIIEV, F. Business Education School for management personnel in Soviet connerce. Sov. torg. No. 3, 1953. Monthly List of Russian Accessions, Library of Congre5j, June 195), Uncl. DOTRYSHi..V F. B., ero . ,m: Fotogrammet Riya tPhoto urametry) itoscow-lghg. DOBRYSHEV, V. I. Cand Med Sci -- (diBs) "Data for the morphology of t1he humnn suicral plexus." Voronezh, 1957. 25 pp with illustrations (Voronezh State Med Inst. ChRir of Normal Anatomy), 250 copies (KL, 14-58, 117) -104- ~aSHCHENKO, X.P.J, dpktor khimicheskikh jhaijk- FLIS,~,�.Y,., kad.khimich. nauk; BYKYAYEVA,,(41.K., kand.WiWoh.!!z'4k; KRMQV,6.1 Z.M., OM,khlizich, nauk; ZfiLkSq'K,Yu., kand,khirAc nauk;.BtQSHMYN, I.I., i-nzh.; DOBRYSHIN 'KD -inzk.; FISH inzh. Technology of the production of chlorine dioxide. Trudy LTITSBP no.8:81-88 161. (MIRI 160) (Cklorine oxides) DOBIRYSHIII, K.D.; FLIS, I.Ye.; FISH, S.I. Study of the dissolution proc~eases of -chlorine dioxide and chlorine in the formation of bleaching solations. Zhur. prikI. khim. 37 no.llo.2382-2387 14 f6j, (MIRA 18:1) DOBRTSHMkN, M.; MZADZE, R.I. Relation between pressure fields and the wind in a barotropic atmosphere. Trud7 TSIP no.86:55-62 159. (MIRA 12:9) (Atmospheric preasure) (Winds)