SCIENTIFIC ABSTRACT DOMBROVSKAYA, YU.F. - DOMBROVSKIY, A.V.

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SCIENTIFIC ABSTRACT
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AGA BA BOVA-SKOBELEVA f V.V., kand. med. nauk; DOBWKHOTOVA, A.I., prof. [doceaijed); ZHUKOVSKIY, M.A., kand, mod. nauk; LEBEDEV, D.D., zaal. deyatell nauki prof.; MARTINSON, MS., kand, med. nauk; MOLCHANOV9 V.I., prof.( NOSOV, S.D., prof.; SOBOLEVAp V.D.# cloktor mod. nauk; SOIDVIYEV, V.D., prof.; SUKHAREVA, M.Ys.j prof.; SHAPIRO, S.L., kand. med. nauk; SHERMAN, R.Z., doktor otv. tied. nauk; SHIRVINDT, B.G., prof.; WWMVqL&X&, Yu.F red.; POTAPOVAp I.N., red.; BELICHIKOVA, Yu.S., tekhn. red. [miltivolume manual on pediatrics) Mnogotomnoe rukovodstvo po pediatrii. Moskva, Medgiz. Vol.5.[Infectious diseases in children; aerial and droplet Infections) Infektsionnye bolezni v detakam vozraste; vozdushno-kapelInye infektsii. Red. toma S.D.Nosov. 1963. 547 p. (MIRA 16:6) 1. Chlen-korrespondent Akademii meditsinakikh nauk SSSR (for Skobeleva, Soloviyov). 2. Doystvitellnyy chlen Akademii medi- tsinskilch nauk SSSR (for Dombrovskaya). (PEDIATRICS) (COMMUNICABLE DISEASES) BERKOVICH, L.M., doktor med. nauk [deceased); VOLOTOVy A.N.# dote.; VALENTINOVICHp A.A.., dots.; DOMBROVSKAYA, Yu.F., prof.; KOSSYURA, M.B., knnd.7me&..-n-a-uk"';-kUER, Tif-X.-,':kand. med. nauk,- MASLOV, M.S.,, prof. (deceased]; POD"YAPOLISMA, V.N., prof.; SEMMOVA, N.Ye., zasl, vrach RSFSR; UOYOTOL, Ye.N.,, prof.; ZHUKOVSKIY, M.A., red.; KOROIZV, A.V., tekbn. red. [Hultivolume manual on pediatrics) Mnogotomnoe rukovodstvo po pediatrii. Moskva, Medgiz. Vol.4. [Diseases of the digestive tract. Diseases of the liver and skin, Vitamins and vitamin deficiency diseases] Zabolevaniia pishchevari- teillnogo trakta. Bolezni pochek i kozhi. Vitamiry i bolez- ni vitwinnoi. nedostatochnosti. Red. tome. E.N.Khokhol. 1963. 721 p. (KIRA 17:2) 1. DeystvitelInyy chlen ANN SSSR (for Dombrovskaya, Maslov). 2. Chlen-korrespondent AMN SSSR (for Pod"yapollskaya, Khokhol). DOMBROVSKAYA, Yu.F., profe Characteristics of the pathogenesis of penumonia..in newborli. infants. Pecliatriia'41 [i.e. 42] no.W-12 F 183. (MMA 16W 1, Deystvitell*y ohlen, A14N SSSR. (INFANTS (HWBMN)-DIMOES) ' (INFANTS (PREMkVJRE-DISE (PNEUNDNIA) otv. red.; GROEBAKII S 1-1 prof.(Moskva), profp profaj reds; ISAYEVA, L.A.0 dots,(Moskvaj, ;e;.'., 140SOV, S.D., prof., red.; PONOMAILEVA, P.A., Prof., red.; SKORNYAKOVA, L.K., red.; SOKOLUVA, K.F., prof., red.; SOKOLOVA-PONO'lWZVA, O*D,p prof., red.; TUR, A.F., prof., red.; EHOKHOL, Ye.N., prof., red.; ISAYEVA, L.A., red. [Transetctioms of the Eighth All-Union Congress of Pediatricians) Trudy V111 Vsesolumnogo s1lezda detskikh vrachel.. Nofilwa, Meditsina, 1964. 530 p. (MIRA 17:8) 1. VseEo-,-uznyy sllyezd detskikh vrachey. 8th, Kiev, 1962. 2. Zavtodurualiehaya.,keLfedroy*detakikh bolezney AHN SSSF.* Dayetyl.tellnyy chlen ANY-SM (for-DwtrbY9k&ya).- 3. Za- mestiteilldirektora Instituta pediatrii AW1 SM (for Nosov). 4. Zamestitell nachal'Aika upravleniya spetsiali- zirovar.may meditsinskoy pomoshchi Ministerstva zdravo- okhranEniya SZSR (for SkorrWakova). 5. Glavnyy pediatr Ministeratva zdravookhraneniya RSFSR (for Sokolova). 6. Deystititelinyy chlen D21 SSSR (for Sokolova-Ponomareva). ?. Predsedatell Vserossiyskogo obshchestva detakikh vracheyp Deystvitellny-y chlen &JI SSSR (for Tur). 8. Zaveduyushchiy kafedroy dets'-,cikh bolezney Kiyevskogo meditsinskogo instituta, Chlen-korrespondent AMN SSSR (for Khokhol). ABEZGAUZj A.M., prof.; BUBNOVA, M.M., prof.; GUREVICH, Ye.S., prof.; ZHUKOVSKI-f M.A.# st. nauchn. sotral KARYSIIEVA, X.A., kand, med. naul: * tdoceased); MAZURIN, A.V., dots.; NOSOV, S.D., prof,; VISEVICH, N.I., prof.1 RAYTS,,.M.M., prof.; SOKOIDVA-PONWAREVA, O.D.; SrUDENIKIN, V,,Ya., dots,,* TOKAREVICH, K.N., prof.; SHIRVINDT, B.G., prof.; DOHBIZVSKAY-k'- YU.F., otv. red.; OSTROVERKHOV, G.Ie., prof., glav. ree. [Multivolume mamml on pediatrics] Mnogotomoe rukovodstvo po pediatrii. Moskva, Meditsina. Vol.6- LInfectious diseases in children) InfektsionzWe bolezni v detakom vozrLtate. 1964. 660 p. f (MM 170) 1. Deystvitellnyy chlen MIN SSSR (for Dombrovskaya, Sokolova-Ponomareva) DOIBROVSKAYA, Yu.F., prof., red,j DMITRIYETA, N.M.# red. [infectious ana allergic diseases in children] Infektsionno- allergicheskie zabolevaniia u detei. Moskva. Meditsina, 1965.- 349 p. (MIRA 18:2) 1. Deystvitel1ryy chlen ON SSSR (for Dombrovskaya). DQI,.UWV,SKAvA- vii-E.,,-prof. otv. red.j ZVYAGINTSTVA. S.G., vrof. red.; SOKOLOVA, T.S., prof.,, red.,GAMBUROO R.L....-profaqred, Luurreur. roblems of the pr7siology and patbology of childbood3 SovremenmVe problemy fiziologii i patologii detskogo vozrasta. Moskva, Meditsina 1965. 317 p. tKUIA 18 -.6) 1. Deystvitelinyy chlen AM SSSR (for Dombrovskaya). !MESV-SUU&l,U-F- Infoctive-allergio faetor in the pathogenesis of respiratory diseases in childrime Cook. pediat. 20 no*3t320-323 Mr 165 1, 11, Meditsinski3p Institutp Moskva* 111283-66 -Mff -UJjM(J1j[jM(b):a-- % ACC N" AP6000770 SOVRCE CODE: UR/OPJ13/65/000/009/0045/0049-., IAIUTHOR: RS "bovs@.,.,Ls lu,.,.r*; ?otg,,pov,, 1, 1,; Kite-yev,, A* V,; D .emido G. Ye,,, j L ORG: Moscow Division of Lenin Medical Institute jLm. I. M. Seebenov of 'Physicians' Graduate 8 -tud-i@es (Tsentrallnyy institut uaoversh-e-nif4o-v'-anAya vracbey); All" Vnio"n' Scientifi,3 Res carob _Jpati@qte. Instrus!. ments and Equip-i 'nienit- (Vs-* isio-y-u a sledov stel I ski y institut @ff0,d1td1hskikb'1n- strumentov I oborudaventya) )I TITLE: Hand oporeted eleotronarosol,generstor and its clinical application ISOURCE: Meditsinskaya promysblennost' SSSRI no. 9,, 1965, 45-.'.9 TOPIC TAGS%. medical equipment,, aerosol dispenser, electric [,onerators clinical meoicine,, charged particle .ABSTRACT** Hlectroserosol theropy with aerosol particles of apprcximate- ly identical. electric charge can be easil-y applied with this generator ror individual inhalation., called Mectrosol. - 1 eae developed by MIIMIO. It: works with compressed air at 0,3 stmospberes or more and Card L A1983-66 ACC NR% AP6000770 bail asimple PUlverizer for dispcrsing.tbe medination, which is electri- ea3ly charged in the same operation, The inhelator ann bo ssfel7 turned in any direction and the porticlets ran be positively or negatively charged. The ourrent is 127-220volts AG. It can ala6 be used for sim- ple inbalstlon@end is easily disavaimbled for cleaning and sterilization Clinical application (mostly with negatively charged aerosol) Involves daily or every otbor day inbelationa of 5-15 rainuten for adults and 3-7 minutes for children U to 30 treatments may be given and tho course may be repeated afte; A weeks, rbis treatment has been found to.have a fcvorable effect on respiratory organs, blood chemistry and oirouls- tioro AntibiotIc inhalation obvialles the need for repeated injectionse The generator may also be used for disinfection and in industry for thin film deposits, This apparatus has been testeds accepted and reconmended for aommercial. production, Orig, art, bast 1 figure6 SUB CODE: .061 07# lid SUB14 DAM 26Apr65/ ORIG REP: 006/ OTH REP: 002 CWj DOMBROVSKAYA, Zinaija Lndreyevna [Orpnization and planning of textile goods] Organizat.jila grovli tokuti2lMmA tovurmA. lit-ry, 1962. 146 p. the whole3alo trade in , planlrovanig optovoi tor- 1-,Qgkvn, Gos. Izd-vo torg. (MIRA -117.6) 1 VERZXMOVSKI, 7. (Wierzahowski, J. ]; DOMBRMKI I T.; GANOVYAK, Z. (11anowiak, 2. Study of the nutritional value of nutria meat. Vop. pit 19 no.2: 87-88 Mr-Ap 160. WRA 1417) 1. Iz kafedr uki o pishchevykh produktaldi (zav. - prof. 1. Verzhkhovski Meditsinako7 akademi:L i otdola gigiyeny @itaniya oblastnoy sanitarno-9pidemiologichoskoy stantbii, Gdansk, Pol'sha, (m T) (CMU) KOGAN, A.. kandidat takhnichookikh nmk; DOLOPIZA, 0., kandidat skamol- chosikift sauk; DOCEMMIT, A., kandidat okonowichookikh nouk. Dete-rululng the ampoolty of water pi as. Zhil.-km.khes.5 no.6.: 23-2/4 '55. (Water pipeal (miaA 9; 1) DOMBROYBUY, A., kand.eifonom,. nauk; GOLITSW, L,# bind,ekonomonauk MWOOm"Mm'"M Oftatistics-of mrban econocgrg by NA.Kokovin. Reviewed b7 A.Dombrovskii, LGolltsman, Viil.-kom. khoz. 10 no.10:34 160. (MIRA 13: 10) (OLties and towns -Statit t1cm ) (Kokovint N.A,) DOMBPDVSKTV, A. Expand the rlghta and increase the effectiveness of the IlTransflol," agency. Mor. flot 23 no. 12:14-16 D 163. (MIRA 17:5) 1. Nachallnik Potiy:,kogo agentstva "Trunsflot". W)MOVSKIT, A. A. DORBROVSKIY, A. A. MAnatomotopographical Basin for Operative Treatment of CisenUrosis of Large-Horned Cattle." Cand Vet Sol, Alma-Ata Zoo-veterinary Inst, 16 Jan 34. (Kazakhata Pravda, 6 -Tan 54) SO: SUM 168. 22 July 1934 DWSHEVSKIYp A.A.t kand. tekhn. nauk Sugar resiotant flooring. Pishch. prcm. no.1:143-150 165. (MIRA 18:.U) DOMBROVSKIY, A. A. BA7AM.IOV, V. M. Arkh. i DOMBROVSKIY, A. A.lKand. Ekonom. Hauk., SMOLENSKAYA, R. M. Arkh., FELZER, YU. S. Inzh, I Nauchno-issledoN-atellskiy institut arkhitektury i prcmyshlennykh sooruzheniy akademii arkbitektury BSSR Razmer,hcheniye ir mnol,,oetazhnykh zhilykhdomakh moskvy obshchF-stvennykh uchrezhdenty i obsluzhivayushchikh pomeshcheniy Page 7h SO: C213.ectip i of Armtatlnrm of Sclenji-fic Rosearg,,h Wnrk on Conat=ctlonm COMAU ad in 195Q. Moscow, 19!51 FAMICRG, A.I., kand.okon.nauk; kand.okon.nauk; TWOT, N.S., kand.ekon.nauk; SKVCRTSOVA. N.T., Imnd.ekon.nauk; IRROUIOTA, T.A.,, kand.okon.nauk. PrInImli uchastiye: BCLOTIRAq O.A.p kand.okon.nauk; GULIBINOTICH, N.J.. PROTSWO, D.I., red.; IIALAZKOV. X.P., takhn.red. [3conomics, organization, and plannix4; of municipal services] Akonomika, organizataila i planirovanle gorodskogo khosiaistys. 'Pod obahchei red. A.Z.Fainberga. Koalcva, Imd-vo K-va kommm. Ichos.RSM , 1959. 451 Pe (XIRA 13:2) (Municipal services) MUSHUM, X.A., prof. -Edeoeadedl; UOUBROMIT, A 6-v-doteent; TRITITAXOT, A.?.. doteent; SOLOMNIXOT. V.A.. dotsent; BOGOTATMSKjY,I;T*I.o dotment; OMMOT, A.D., doktor takhn. nauk; ITAXOY, T.M., prof.1 KUZIMSCf, N.V., kand.takhn.nauk; S61TIKOys, ]F*Aot prof., doktor takhn.nauk, retsenzent; GA It Te.Ya., dotsent, doktor takhn.nauk, reteenzent; PAUSKIT, T.M., doteent, kand.takhn.nauk, retsenzent; LUGININ, N.G., kand.tekhn. nauk, red.; UUTROT, P.A., tekhn.red. Diesel locomotives) Teplovosy. Koskvs, Vaes.izdatellsko-poligr. ob"edinenie N-va putei soobahcheniia, 1960. 340 P. (Hru 14.- 1) 1. Laningradakiy ordena Lanins inatitut inzhenerOV 2hele nodbroshno- go transports im. skademiks T.N.0brastoove (for Mitikov: Gakkel*, Panskiy). (Dismal locomotives) DOMMOVSKIY9 As I* (Co-author) See: VE&SLER, _ L _ L. Dombroveld.ys Ae I* and Vokalers I* Le - "ProplVlactic medical examinations of the population of Rostov Oblastp" Tru4 Rost, rentgeno-radiole i onkol. in-tap Issue 2. 19481 P, 7-11 so: U-3565, 15 March 531 (latopis 'Zhurnal IxWkh Statey., 11o, 14.. 1949), DOI,MROVSKEY,, A, I, (Co-author) Sew MEILSWABAWIll lu, D. DwjbrovakLv.,, A. Iovand Greysbman,, Yu. D. - "'Treatment of cancer af tho pnotate gland.11 Tru(br Rost. rentgeno-radiol. i onkol. in-tap Is= 2# 19489 Pe 55-62 SO: U-3566,, 15 March 53, (Ioatopis 'Zhurnal ImVkh State7'0 No. 14,, 1949). DOIWOVPKIr,, A. I. Dombrovskiy., A, 1, - ffX-ray castration in treatment of cancer of tho MsMar7 &land,,# (Qualilying dissertation),, Tructr Rost. rentgeno-radiol, I, onkol, In-tag Issue 2g 1948o P. 03-64 so.. u-3566, 15 march!532 (Letopis lzb-nal 'rWkh Statey., libe l4g 1949)e DOMBROVSKIT. A.I., professor Training of roentgenologists. Yest.mutA rad. no.1:93-94 Ja-IP 155. (Kft 8:5) 1. Is Roskovskogo seditsinskogo instituts, (dir.prof. G.S.Ivakhnenko). (RONNTGINMMT, oduoation. - in ftsmia) DOMBIIDVSXIT, A.I., professor. Fandly dynostoole(dynostonts cleldn-cranialls). Vest.rent. I red. no.3:86-89 My-Je 155. (KLRA 8:10) 1. Iz Icafedry rentganologit (zav.prof. A.I.DombrovokV) Rostov- skogo seditainskogo institutes (CLBIDOCRUM Df ODSTOSI S, came reports & x-roy) SOW&JQP_1@EY A.. fessor Mw The so-called ostsoid ostsom. Test.rant. L red, 32 no.1:85-91 J11-Y 157- (KIRA 10:6) 1. 1z icsfedry rentganologit Rontovsk6go seditainakogo institute (ilir. - prof .G.S.Ivakhasaka).. (OSTIONA. OSTBQIM. differ. diag,) Abstract 3 casen -)f osteoid oateoma with localization in feinur and t1bl a are cited A len,-.thy bwItnbenign course of the disease and favorable tnfluen,e of roentgenotherany was noted. 2 observ2tions are also cited in one clinically 2n-] histologically sarcoma of femur W25 not recontsed, In the oth.!y osteoid osteoma of femur was t-aken for sarcoma. It is sunposed t 2L OStA04A-08te:712 should 'e con9,,:4r--! '25 Ost-@Omyeitis. A.1-Ashkenzi (Ref. "hur. Biol., ..'o ')'-, 1@,5:', 9;@310) DOMBROVSKIT, A.ILg.Lr.O@, (Rost ov-na-Donu) ...... :-, 91adicactive phosphorus in medical practicew by Grof j II.D. Daboyi. Pleviewed by A.I. Dombrovskil. Trach.delo no.5:553-555 VT 159. (MMA 12:12) (PHOSPHORUS--ISMOPXS) (MWVTI, I.D.) GRABMO, I.1o, prof. (Boot oy-na-Dona, ul, K. Gortkogo, d.102, kv.4); DOMBROVSKrY, A.Z., prof.1 ]aMrNOT, A.B., dotsent No'lle'm of radioactive Iodine therapy In stanocardia; preliminary report. Vest.rentJ red. 34 no.2:31-34 W-AP 159. (MM 13:4) 1. Iz Rostovskogo-na-Dom meditsiuskDgo instituta (direktor - prof. Te.M. Gabarev). (ANGINA PICTORIS, ther, radiolodine (Pas)) (IMM, radioactive, ther. of augins, pectoris (Ras)) DOMROVSKD.'p A.I* j prof.; MEXHONOSHINp. A*A. Bovinophilic granuloma of the atomach. Vi'st. rent. i rado 35 noe 5s8l-83 3-0 160. (MIRA l3s12) 1, Iz Rostovokoy oblaotnoy bolinitay (glavrq7 vrach M.F. Mokrousov) i kafedry rentganologii i radiologii (zav. - prof. A.I. Dombrovskry) Rootovokogo meditoinakogo inotituta (dire prof. P.P. Novalenko). (STOM&CH-TUMORS) DOKBROVSKITO of. (Rostov-na-Donu) 1@ ij.A-Pr wHadioaotive substances in pbarmacotherapy and dlagnosiam Aj, Lesho'hinskil, Reviewd by AiI,;Dombrovekii.. Vrneh, dplo fio.12i 3J@l D l6o. (MIU .14-- 1) , (RPIOINTOPA16-THERAPEUTIC USE) (IMHCHINSKIlp A.F.) D(kIBROVSKIY,,-Alaksandr-Iosifovich; LUCHEVSKIYO A.S., dots., retsen- ze.nt.; BESSTRASHNIKOVA, M.L., red.1 MARINYUK,, M.I., tekhn. red. (Roentgenology] Rentgenologiia. Rostav-na-Donu, Rostovskoe knizbnoe izd-vo., 1961. 221 P. (KRA 15W (RADIOLOGY, MEDICAL) GRAW110, I.K.;,DCRRROVSKIYj A.I.; KUDIROV, A.S. Remdts of treating stenocardia with radioacti-re iodine. Mod. rad. to.5:25-ZI 162. (MIRA 1538) 1. Iz knfedry fakulltetskoy terapii (zav. - prof. I.K. Grabonko) i kafedry rentgenologil i radiologii Uav. - AJ. Dombrovskiy) Rostovskotro gosudarstvennogo meditsimkogo instituta. (AINGIINA FEGTORIS) (IODINE--ISOTOPF.11) DOMEROVSKIY, A.I.; NEXHOROSHIN, A.A. Intragas.trio forelp bDdien simulating tumors. Vest. rent. i rad. 37 no.5t68-69 S-0 162. (KIRA 17:12) 1. Iz kafedry rentgano-radiologii Rostovskogo mcditsinakogo instituta i rentgenovskogo otdeleniya Rostovskoy oblastnoy bollnitay (glavnyy vrach M.F. Mokrousov). DOMHRCVSXATA, TuT., prof.; VALITXR, Te.M., kaud.wed.nauk; CENCEWLIN, A.B., kand.med.nauk; DOKEROVSKIT, A.N.p kand.wed.nauk; 1tOGW* A#A*# kande madenauk Age factor in the reactivity of the organism to hypoxemic st$ites; parallel alblical and experimental findings. Vest,.MN SSSR 14 no,-3: 18-29 159* (NM 12t3) (A)IOXIAD effects, W fiotor In animal & human reactions (Rus)) (AGING. effects, on animal & human reactions to anoxia (Rus)) 11,5W y Al EXCERM MEDICA See 15 Vol 12/11D Chest Dis. 0-. t 5 9 2069. CHANGES IN THE LUNGS DUVAO DYSENTERY IN EARLY CHILDMOD (Russian text) Dombrovsk N. - PEDIATRIYA 1959, 1 (61-66) Multifocal (broncho-) @pncurnurda wan Munu tn-t&out of 37 infants under 2yr. of age Aying of dysentery. Histological examination revealed in addition various degrees of interstitial pneumonla in 20 of the caues - elther as separate foci or diffuse - most pronounced in the first 6 months of life. In premature infants and in infants who In suffered from repeated attacks of respiratory affections. Lunji changes "'riedl 'c" rding to the chronicity of the process- after 3 weeks there were areas of sero-haemorrhagic changes. extensive haemo-offusions and marked interstitial pneumonle changes. Investigation of the argyrophilic fibres by the silv,!r impreg- tnation method revealed considerable changes in them in the lungs in thcee cases where the case history showed severe toxaemla and respiratory insufficiency, Those changes undoubtedly were the result of derangement of general metabolic processes. The lung changes are not specific for dysentery and reflect the con- dition of the general constitutional reactivity. (L, 7. 15) DOM13ROVSK&YA,Yu.I.; ULITIM, A.; ORMHULIN,A.S.; W!TROIP@KII@,A.N.. PJGOV,A.A. Role of the age factor in hypoxemic states. (Olinico-exper!awntal studies). Act& mod. hun. 15 no.1399-115 160. 1. 11inbm detskikh bolezney i 7Sentralloan Nauchno-istiledovatellskeyk laboratorip imeni, S. 1. Chechulim 1 Koelcovsko&o Ordetux lenina. Neditsinskogo Institute, imeni I.M.Sechenova. (ANCXU) (AGING) DOMBROVSKAYA, Yuliya Fominiabna. Prinimali uchasti-ye: CHECHULIIW , A.S.j, kand. mod. nauk; ROMBROVSKIY, A.11.,_nauchnyy notr.j ROGOV, A.A., nauabrqy sotx.1 DMITRIYEVA, N.M.., red.; MIRONOVAI A.M., tekhns red. (Clinical aspects and pathogenesis of bypoxemia in the growing body; clinical experimental observations] Klinika i pategenez gipoksomii rastushchego organi=a; kliniko-eksperimentallmye nabliudeniia. Pri uchastii A.S.Chechulina, A.N.Dombrovsko i A.A.Rogova. Moukva, Medgiz; 1961. 254 pe (MIRA 15:4F I* DeystvitellrWy chlen Akademii meditsinskikh nauk SSSR (for Dombrovskaya). (ANOXEMIA) DOIMROVSKlYt A. V. USSR/Ghemista7 - Sulfonation Acidophobic Compounds Aug 49 "Sulfonation and the Sulfonic Acids of Acidophobic Compounds: VIL Sulfonation of Unsaturated Hydrocarbons," A. P. Terentlyev., A. V. I)cmbrovWdy, Lab of Org Chem, Moscow State U, 4J PP "Zhur Obahch Khim" Vol XIX, No go PP 1-467-71. Pyridinesulfotrioxide does not enter into reaction (up to 1500 C) with paraffins, cyclo-paraffins, homologues of bensene, and olefine with double bonds not adjacent to the and carbon atom. However, alpha-olefins (hexens-1. heptene-1) react at 1500 C. Prepared berium salts of sulfonic acids of cyclohexenel metbylene-cycloloxmne, camphene, styrene, and indene. Submitted 7 May 48. PA 149T28 I zi WOMbadstry - fttaUenei Alpba- Apr 49, Thenyl chemistry - Sulfumtion "Sulfurization of Alpba-Phanylbutadiener," A. P. Terent,yer, A. T. Dombrarskly, Cbem Faculty., moscov State U ineni X. T. Lcmanosar, 3 P-D "Dok Ak Nauk SSSR" Tol LXV, Iro h, pp 513-515. going pyrid I -sUlfotri=ide, sulf OM&W PhOU71- butadlens with a Tie3A of 54 of the theoretical vith beating up to 1000 for U,hours. Barium =d godium salts of phenylbut4sdiens, gulf o acid ob- tained were white arystalUc w4botar egg, 81416bt-17 41/49M WSR/Ch0Mi8trY - But&&Iene, Aipba- Apr 49 Phenyl (Coutd) soluble in eold water, vb-iob discolor potassium permangLnats-amd brcmin water, amd. add f atoms of bydrogen in the presence of a nickel oatalyzer. Submitted by AoeA A. 1. Nesmayanor, 31 Jan 49. 43.A9T6 04'2021@W aaftlatua War" 41449 Diu* itpdlsoom Ana wis"W" A. P. Tnoottimg A. T. volibwIfteft U'lowd *0 Vol Lmmmw. VP Mmk A ft* OMF *1 12MI, pp 859-862. &two =36- syc2opmtod4stoo huted to ft a coiar ququueo or jvrldln*-wjlfttrloxUW and tbm proossod with m=Ws 4nd bu7too Ma kritu nalt Ism a i v m ted ulth alcoW2, Subcdtted I Jbn 49* PA 66/1,9223 rv 11- "Sul k'o-.,; Lion of :I-drocarbonq." 'I ci,@@:r-i!n of Canr'- Sci- jub 6 U'un 4), 1109ro-d jr(!cr of t'-min 5tlati ;.JI. Lmini ii'. v. Lomonosov. Sunmar7 82, 18 Dic 52, Ijinri,@rtations Vrestntnd for in 'Iwi-inn,3 and ,14iginn In Ooscow 5 7119. -Cyii- 11-0., it va, J a I ro 1 nTi c I I '.I n ip, ti-J-3e PAw. campht"? with to (@-fc S', Irm C.O.) in V rd (01,0,4 In a pea)t-d r), 13@. 5 %altr 1"I @h,tj 1-I'd -0 41 K I'm ffrom Iffi- M@-Cjl, i"Aldal@, y V- - 71, f-I -j- .1- C. kf k A" NWIO&k acids Of addophottle COMPM411. If. SWe"Usis of slyrtaty itad -*Ld fMirwint Mile P. Terrul'ev ath) A. II, lotn!L1,ript ,;;: jJ.r-(,@11. ChCIn.i 20, VtjAjAj_KV --b-Mi MAJ). cf. C.A. 44, ..Sullititalkat of yreat with firridibe-s(h by Inierm"fistr furipti. of I'hCJI:CIJCjf:Cffj &lit- by the terminal jxmitkin. Ifrat. '. yrevir. I T t lipidine,14),, awlit nit. (CICIf,1, 14 hn. at ItAl' in a wwW Sidov. ft,11,mc-I by tresintent with UMVIml by C(h). alid cull. ob lp't Ill() IgA%t 13 it. (/'At 71., - CMW&)I11d. IKKI11Y 001. Its kl-14 II*U; Ilk' K wild XI udh met toblAinAbIr by nwulhem w4th ewl-males. the AC ton qqvorii I- I@ t- un.table oil Iiev"48W' A. Ita Ityl. 44as"M -,n Iwhin. .4 AgNI). to bMns M ilw- %*. -# x Nat$ Widly turns I'lawk. The f-ef Gsd ffmon low Rd @Lsa fit t Alto" slow y over . to M bo I In d PiI 12)", Skoellint 4 A. Na saft with If Alowed by acidifiration. lirlds tin- Xg. It mic acid- oliwalkM of the so 1411 with lint K%1"0. yields 9 . Warming thr 'N& At with 2 pirls PCIo cove P401:01SM]. "I. MM, (11"m C41I.I. wlik-h. hfairel I hr. with said. W. Ntf,. gave III, dwod*, m. 1112". while beating fit Wit with 2-ansm-PYWAInt in The ly'voincr cot "Tidi"e ".a. Iy S.v' 'he e"fft, ... line in. 11445'. A.Mit. 4 fir water I., tin sq, M.111. 44 t hr NA @stl (fruill H1011). fleeting .5 it 1,1101 CI(CII CIII. IM:.* it. pymine4k)" 6 Int. (CM1112, alut 11:1 g. M-CsIONOPill is% maNtitter) 4 fir%. at 11111' sitniluty Save 49.61-.: (PACH:- Ofell: ell-VIA1184; Nd 544 thy treatment of the ps ult with MkOh). is ra-ily v4. in 11.0. -mirtatinn with KNNO@ yields HtOll; cat"Flete hy&qr"atinn of the No salt ir@ HP over Raster -N gave The %nit). analog. wbik aMn. of 1 2 atoms It. Ulawled by KI-InOoxidaiiint. rradily-gav* ' Phl-11,C117041, as M) as Went 111011. 0. U. K. DOMBROVSKJyj A. V. USSEVChmifftr7 - &aflowtion ISDUOMUon and Sulfonic Acids of Aoidopbobio Compounds. XIII4 Sulfonation of Cyclopentedi Enos 0 A. PI Torent' yovp A. V. DombrovWdy., lab Org Cbem imani Acad 11. D. 2911noklyp Howow State U "Zhur ObaWk Ihis" Vol 1119 So 29 278-2801 /IW PYridine-staf6trioxide is suitable agent for eWonation of cyclopentadiene. Obtained for Ist time cyclopentadiena-(193t--mlfonic-(5) acid in form of its barium salt. PA 176T3.5 USSR/Miamistry Sulf4ination Suiro nation and Sulfonic Acids of Acidophobic CCqMnds. XV. Sulfonation of Dienc Hydrocarbons XLth a Conjugate. System of Double Bonds.1 " A. P.* Terentlyev, A. V. Dombrovakiy, Lab of Org Chem, Moscow State U "Mur Obshch Xhim" Vol XXI, No 4, PP 7o4--714 Hearted divinyl, isoprene, diisopropenyl vith ex- cess of pyridine-sulfur-trioxide, to form diene nonosulfonic acids vith sulfonic groups at end of conjugate syst (not described in the lit). Obtained for lot time butadiene-1,3-sulfonic acid-1; 182221 USSR/Chemistry - Sulfonation (Contd) Apr 51. 2-4metbylbutadiene-1,3-sulfonic acid-1; ana 2,3- &bwtby1butadIene-l,3-sulfonic acid-l as Ba salts. Zzamd reaction m;ech and structure of compda. DOMBROVSKIYj A. V. USSR/Mmmdotry' Sulfawtice 91 NOT 51 "Sulfwation of Uhsatmted Carb*Wl Compoundsy" A. V. DM*rov6kiy,'Cbernovtsy State U "Dok A Nauk SSSR" Vol , No 3, pp 431-413 Dioxane sulfw, trioxide is used as a sulfonating agent for introducing the sulfo,group into the virql group of an unsatd carbonyl compd. The sulfc, group goes, f(w the,most part, to the end carbon of' the conjugated system C a C C a 0. 23AT15 swioudoa ad umilarawd compounds. L M Is & good tuffmating agent*torreactimswMacrokinarMeCH:CMCHO. Ith mom uwfW than pyrMW6,1;0,, the Litter y;eW4 only taffy and polymeric products at elevated. temps. and not react- Ing at lower temp. To 80 ml. ke-cold (CHP)i was =18 it. SOs and the soln. treated at 0* with 10.5 all. dlozw-.e dried ova KOII. the ppt. of I which appra" Instantly. Issomewlixt sol. In (Clig(Vi. ToI0.5g,scrolein 'in 2C mi. dioxane was added at 01 s. freshly made soln. of I In (CHaVA)v; the reaction occurred Instantly with evolution Chemical Abet. VOL 40 NO- 4 Feb. 25# 1954 Organic Chemistry of heat, and the tea-colorcd soln.. ';et stand W-W min. at room temp., deposited a small amouit of apparently diawne jahl qf acroltinsulfonk acid (1). This treated with'aq. suspension of 40 if. D&COj In 200 mi. H#O until the reaction was neutral and the filtrate from U10,coned., yielded 40 S. C*1hO4Bae.#MO- boiling with C4He and dr)ing in taina gave the anhyd.Qt, which. with ahat soln.of XgSO,. yltliled the K jall (11). The soln. of H givei the Ag mirror test stir) reduces Vehling soln.; It also feduces KWO. and reacts with Br-HgO ve readily. Hydrogenation of the It Ill 11.0 over Raney at ram temp. gave a sotirl. "hith re- acted with XMnO# and Dr water. bit failed to give a AX or Febling test. Oxidation of 11 with K?.tnO. in sq. KOH gave (COJI)j. Thus I acid conlans the SOIH group on terminal C atom: Hot-SCH, ClIcilu. Similarl 15.75 g. Alfc1l; VICHO with 37.9 1. 1 rave 36z S. CIYJAISBO.": the K s411 was obtained by metathesis. The prilduct showed qua]. tests similar to those Of the =rok-M WU]og and all r t reduction failed to react with Febling or Tolk-us rrigo-ni z oxidation with x3filo, vre (MMI. Ileum the Millollic a(idi%AkC(SOt1[):C11C11O. suln. In3t ikeorup. aud loies 11.,;0, Lmi tvm,a. %vitli vvalKI, I,, the cum, ilic ftee wid. sit. ilv- rit@ '," off is 1111.0.1ble el-4-13 ill 30118. A* ka t DOMBROVMaY, A.V..(Cherneytey). 0.- Substitution reaction In-unsaturated compounds* Usp.khim. 22 4097:777- 820 JI '53. (HLRA 6:7) (Substitution (Chemistry)) (Compounds, Unsaturated) -j.,!, l@@ @., -. ;j- ......- q Abstract now method* or:briomimUng unsaturated compounds with 111oxane-dibromitle.:- Is described. Thei@reaction to carried out, an a rule, vithout the sol- vent by slowly Chilling the reaction mixture with water, The separatica and purification or final substances is very simple: the reaotion.mix- -ture, is -treated: w1bh- water and then extractod-with othar. _-After cation of the other -layer the bromine derivatives are !soparated by d1stillation. Seven referenceii; _'@5 USSR dating 1906, 1895, 2 German dating 1902.' Institution v The Chernovitsy Stato University, Ukr-SSR Submitted October 9j.: @1953, DDHEROVSKIT, A.V.; STADNICHIM, M.D. Interaction of the complex &&It off-nitrophourldiazonium and ferric chloride with alcohols. Zhur.ob.khim.25 no.9:1737-1739 S 155. (KML 9:2) l.Chernevitaki.r g4,sudarstvennyy universitst. (Diasentum compounds) (Alcohols) mcetylenics It rjkt*a t idA.. 11. Sullm% U-1- d=11,001s. TNNinlsm A sullona flon r 1410inut 11 @ obi III Ir 0 (It. ur, bm 4p. -&V. t1littIRP pill @fii Irphy I i -I-- -5(Mre $03 45W -The dlo@am- 114 cam x, %rM 0, r @(Iot,dt,lfrpm 4(;, e ,,. M,44 nil. di,,xanc 81111 160MI. (C 30-40* Witt), CV5 11 ter HQ4., - lat"ttlis lrxil Urrin -uvutrAiadr,n-,, vk 14 @ztiiscd ClIft(4.3 Oat m *Ih qq@ WCO, drid , L ve SA - Sa, T te fwjiltr ivith, KaSoi 1!6ve @ IMIJArty i,2 WinTilt @ud I(, S. dimmam- (. WI ,( i 4 i " Ah u 11 C 0 A @ ., & tr t le to cl 's. t, 1, " I t tati4 l h d , 'From.10 rpi 1 w r . map e n prcp 1@ t rount'and 9@ g.-SQ2, the. micthm betur run at 'kootn'temp pVV,RJ%cr 45 m1no Of @epctltiaj fiAlosted by ' lhj@ ,X jail s by-imOssinge i4th 1. IF04. Tht: Ba -Wl OxIdi itt sat): with dff X hit) tOB tile Ila " 'Addii ive h 4r di f . 14 ;q MI ( Yj ; o M v usatte @ 1, g I MAG' 0-3! 'm WIAC14 In O) ! M%,e it t Of I , a 1 j- , Its. @it 1, ex. . $ Pp 'Ve t of 1"+Tzril @, of 4 m t l A c%litipliz, sifi ul X a I II - j ityVieft I t PrCK'VVI U@I`VU&11 0 Cyclic filittirmtd iatt such Ri 0,&CIf:Cns(W5, wbich with 1110 opent it3j li i l l ing lelding 1f0,SCIT:itH0$tNXT, wilich aft n @ I neumi on zat io Ip rrn a qydic DA ftk nvi4virig botil ttle ack Ic Olowed by denvage to GS(Ii alul HQ'SCII, - CIrL Iter rvurnuixins to the I 111=1 pmfilet" of 11- CCl:J, :krtyl 11 atmm@ being prcu4it lit all (Ith very active PettrbonAhereis the Ili[ rmli.lity ardfrect @um US Rife. @G, M. Kow6paq DOKBROVBKIY, A*T*; INUMIYU, A.P. I-` '' Halogenatiot. and arylatio-a of itnoaturated compounds with aromstia diazo compaunde. Part 1: Tbo reaction of bromc and chloro diazophanol with 1,3-butadiene and some conversions of 4-chloro I-phenyl bittene-2. Mar, ob. khim. 26 no.10:2776-2782 0 156, (KIM 11:3 ) 1. Hookolroki.y Gosudaretvannyy universitet. (Diazo comporands) (Unsaturated compounda) zi -@,MMA Igo IWO .......... d'o-TO tot AQA W104 2:t kut Otc, with T040 thati WfA and 42 If.,, f uA Ctg@ W, in, 110@ rf, cm ffic CIV. at, tr -1 Ri:46 1 10. The Mdltt. kit W -p4tNlr4f F.Mis, by td -1, Outialituav. C.4; so, 1.7 (10.3 'fiftBr and' OJ WN We 1h AA as" dild "114 To Ll male b-atadiene Its 4-03 Me P3. @@o 0; diiwa N la 4 klft 1 ims; tbe M 20 1[,, w% ,Y g AlU d . the V l ON i was strougly zd @ kft 6 92-3*. LAW#: Law; mqi I 1 r. a 8 21 1 bi 9+ 14 Im I . ' @ ' 42 LoP rpj b, lf 4 1 , ..6($1 .3790;' 40 1 MF4SGM9f 57 1 @2 b 6 . 2 lh_. 82*? _ 84s. 1.3410. 1.0175; 4, -40%,)h, WA, UMCO, rA 4.1; M6 Jo 7" bow E 0 Vi mull "Ccew a lumit it teffut In lQ-I& =6. y Mat th 1111 trMOICHI CHO -,PA. 90chi &"0 26 ji, t.5m A. 02ma -41ytj 02%, 1 bj 85-7 b, $6. 1 owl I-AM, ;wZ 06-r.' -qi I. vbo 11014m, W) a kilt wriv"prem. IFY iteatial 04 In AddW 01he di nut. WiM d9hydCOW(Vilgilon WU AlprA*yqd mwgiskk, k &Ujidt frmt the uWve ditm a em tho i i -:&mtd; tfiktute; their tag; beill UVAIT' 134 9 V24 W.40,71. I I6ok 14 in I Wd T1fd WW diW19 POP& f.M 0 *em- (Net W, mo) I 'i,44imM*f,S4*U' owl, Ali to to. MIA% J; 0* 'VA o.qwi (from v id A cett, C.A. 4o, 9 t KID 0. mi bw a '44 AUTHORS1 Dambrovskiy V.9 and Terentlylev, A. P. 79-2-30/58 -1-T, 'A. TITLE: Halogenoerylati4m of Unsaturated Ccmpounds with Aromsitic Diazo-compounds. Part 3. Reacti(m of 4-Chloro-l-Phonylbutene-2 with Potasslum Hydroxide and a New Method of Synthesizing alpha-Phenylbutadiers. (Galoidoeriliro- vaniye nepredelInykh soyedineniy aromaticheakimi diazoaoyedineniyami. III. zz'v- Vsaimodaystviyq 4-kblor-l-fanilbutena-2 a yedkim keli i novyy Metod sinteza alfa-fenilbutodivena) PERIODICALs Zhurnal Obahchey Xhiniio 1957j vol 27, No 2, pp. 415-.U8 (U.S.S.R.) ABSTRACTt The effect of patVassium hydroxide solutions in methyl, ethyl, n-propyl and n-butyl alcohols waa'investigated. It was found that the reaction of 4, chloro-l-phenylbutene4 with potassium hydroxide solutions in alkyl alcohols results in simultaneous formation of alpha-phonylbutae-tone and homologous I-phenyl-4-alkm-butenes-2. A now method was developed for the synthesis of alphs-phenylbutediens by tho separation of the hydrogen chloride from the /+-chloro-l-pbenylbutens-2 with the aid of a potassium hydroxide powder in dioxane or by distillation In vacuum over potassium hydroxide. Alkali alcohol solutions were found unsuitable as reagents for the separation of Card 1/2 the hydrogen chloride. Efforto to employ other known methods of separating 79-2-30/58 Hal-ogencarylatim) of Unsaturated Compounds with Armatic Din2o-Cempolmda the hydrogen cKaride,, a. g., reaction with quinoline, methyl-or dimethyl- amino,-pyridlne emd triethylamine have not produced pcisitive results. Complete tarring of the reactim mixture took place ir. every case. 1 table. There axe 8 references of which 4 are Slavic ASSOCIATIONt Moscow State University PRESOME BY.- SUBMITTEDt February 20, 1956, AVATLABLEr Library of Congreas Card 2/2 V", AUTHORSt Dr#n1hrmrnkiy, A V.; Teren4wv, A. P1 Yurkevich, A. H. 79-2-31/58 TITLr,t Halogimarylation 6f Unsaturated Compounds with Arcstatic Diazo- Compounds. Part 4. Synthesis of beta-Arylalkyl Carboxylic Acids. (Geloidariliroiraniye nepredellnykh soyedineniy aromitichaskimi - diezosoyedinen!'.yami. IV. Sintez beta-arilalkilkartmovylch kislot). PERIODICAL: Zhurnal Obahchiiy Xhimii, 1957, vol 27, No 2, pp. 41@@421 (U.S.S.R.) ABSTRAM This report deocribes the results obtained from the conversion of hnlogenophenylation and halopnonaphthylation products into corresponding beta-substituted propionic and isobutyric acids, analogues of which found application in the role of plant stimulants. Bxper@ments shoved that mothylacrylate'and methylmeth6crylate react with diazonium salts in an aqu6ous--acetoniq solution in the presence of copper diabloride forming inethyl esters'of alpha-chloro-beta-arylpropionic and alpha-'bhloro-beta- arylisobutyric *aid (methvl-alpha-chloro-beta-arylpropionate and methyl- alpha-chloro-bgtaL-arylisobutyrate). Reduction of alpha-chlbro-beta- Card 1/2 phenylpropionitrile and mothyl-alpha-chloro-beta-r)hi)nylisobutyrate with 79-2-31/58 Halogenoarylotion of Unsaturated Compounds with Aromatic Diazo-CompotmdB. Zn in ice cold acetic sold produced good yields of bgta-phenylpropionic, beta-phenylisolratyric, 2-(alrh&-naphthyl)- and 2-(beta-nopbthyl)-propionic acids. I table. There are 8 references, of which 2 are Slavic ASSOCIATIONt Moscow State Unfversity PRESENTE BYt SUBMTTTED: February 27, 1956 AVAILABLEt Library of Congnise Card 2/2 te M .'T&mo 'lay' 'Id :U - 1 AM 3,674 P.Dr N.Std, ,efxf- by a in goo ltla*d 51xvn)" 12-44' 3340,clA, TjY_1r, r 4 50c, t4 -4 b"94,51 JC 7%j bi LZIS-40, 1. ro Uei but Vi NA,OAC ai- C6 fiw@tnd c4t faaaifavw@fj -PrCPI- 41[fWV In ou-M Meditala, low 1,74-V,1.030. 1.2188',! 0,02, LZM, 11eta W" 0111, xmuo4: to acup so 74p Ilk. 86 'Iud d4mK& m 137' OMid, k0win dimno, ke H 11sr tft ahm 1.5070, 0.1 711; v f4*(Yj. 00 79 'MAO; 2.4b . I - 6' ; " 63 Ate,aP V Ewa; # to. 1341; Mi ali Kum. WIT R M E w .6,4-7@06 A /2 AUTHORS: Kupi>64aya, N. B., Dombrovskiyj A. V. Terentlyevt A. P. 701-11-26/56 TITLE: Haloidarylation of Unsaturated Compounds With Aromatic Diazoeompounds, (Galoiderilirovaniye nepredellnykh soyedineniy aro,matioheakimi diazosoyedineniyami). V1. AbsorpLion Speotra of Arylbutenes, Arylbutudienes and Arylbutenines in the Ultrayiolet and Visible Part M. Spektry poi.ploshcheniya v ulttrafioletovoy i Tidimo@ oblastyakh arilbutenov, arilbutadiyenov i arilbuteninov PMODICAL: Zhurnal Obshchey Khimii, 1957, Vol. 279 Nr 11, pp. 3041-3047 ('USSR) ABSTRACT: The chlorarylation-method vo::-ked out for butadiene-1,3, its homologues and analogues peniits to obtain the chloraryl- butenes simply and with yiulds of 50-7o 04. This synthesis is realized by the interaction of the dienes and the diazotized aromatic amines in an aqueous acetone solution in the presence of a catalyst (CuCl). Among the many conversions of the chlorarylbutenes the splitting :)ff of hydrogen chlorido which leads to the formation of a-aryl- butadianes is mout interesting. Thi3 splitting off was Card 1/3 worked out with the aid of caustic potash in dioxane. Haloidarylation of Unsaturated Compounds Olith Aromatic Diazooompounds. V1. Absorption Spectra of Arylbutenes, Arylbutadienes and Arylbutenines in the Ultruviolet and Visible Part 79-11-28/56 Various arylbutenines (X C C11 = eli-c I CH) weru also P4 obtained in the name manner. Thanks to the obtained material of structurally vimilar compounds it waa attempted to determine the dependence of the absorption spectra of these products on their structure, the results being in agreement with those of other authors. Thus the absorption spectra of the arylbuteneep arylbutadienes and arylbutenines ware taken. It became evident that the substituents in the nucleus which are no strong chromophores exert no influence upon the character of the spectrum, but that this depends on the po3ition of the n-electrons in the molecule. The introduction of a strong chromophore chanees the character of the spectrum. There are 6 figures, .5 tablee, and 6 references, 2 of which are Slavic. Card 2/3 Haloidarylation of Unsaturated Compounds With Axomatic 79-11-28/56 Diazocompounds. VI. Absorption Spectra of Arylbutenes, Arylbutadienes and Arylbutenines in the Ultraviolet and Visible Part ASSOCIATION: Moscow State %xiversity (blookovskiy gosudaretvennyy universitet) SUBMITTED: September 27, 1951, AVAILABLE: Library of Congress 1. Arylbutenes - Spectra 2. Arylbutadienes - Spectra 3. Arylbutanine3 - Spectra Card 3/3 Al:,PEORS: Donb V. 79-11-25/56 ,Terear,yev, A. P. TI TLE Haloidnrylation of Ummaturated Compounds ;ith Aromatic Diazocon-pound,; '01- _tloi&-.rilirovwr-Aj@@, uc_,)ri)3-C-l,nykh Boyedinenij aromaticheskimi diazotoje4@:1,1ri.,; --ILI - VII. Reactions '.1ith Acrolain :ind C.-rtO.'L;' '1 d e (VII. Hea'@tsii a ukroleinam i krotonovyi@, P:L RI C DI CAL Zhurnal Ob3hche@@ Xhimii, 1-957, Vol. 27, Nr 11, pp. 7 .1047-TC50 (USSR) _113STRA.CT: Th@@ OZIly CXW-.10l(J Of [@ V(i_-1IOtiOn "OtTiu(JU aldehydes and itromatic dia@,,oFmlt;3 ij found ix. th-: b, Maervrein and aollaborator@;. Iii. .ti@,n of tk;-_ convorsions I:C ;,'ta iuin@@tur)ttcd :--Ah aropla"ic., th,3 atit!Iorr, iavosti. t,?(4. tli_ liitlierto not doscribed refteti--n !@tit,-@en chloro- 13ror.-odiazonEi (C,11 iT X) !-.nd @@ull a,@ In an @@ 5 2 .111IL'Ous or,..jtnn,@ soiiiti@-n in th_- cf (-n%1,d(.-r chloride th--3:30 jOir ', ;ill :.r,4 one lins.1vid @-&tom thc _-nnaxii.L w, th..; doublu !),)nd > 0 - C < Vhr, yie I I Card 1,12 1, lda Ju the a'".! !X,_! on ?.-he Haloidarylation of Unsaturated Com,)ound3 'Jith Kromatic 79-11-29/56 Diazooompounds. VII. Ruttction,.4 With Acroloin and Crotonaldt-@hydo t@;.j@joratur@..- iiaod in th,, n-n'l on tho mediiiin. The b3st @ieldu :-iru @@Iejh@rdus tire subjected to the !@ation of t,.@-utral solvtinn; of diazosalta, u,ith an a@'.dition of cE,.Ioiuia h5droxid@ to the rQactian mixture. Thur, the haloidohunylar)-lation of ac;o1ein @zd arotonaldehyde was Iescribe;d. ZynLhealzed woru the unrlier @itiknowrj c.-chloro- ,tnd u-c,hlorc-p-,hanyl- butjric acid aldohyae, propionaldehyda and a-chloro-P-phun5-lbutyric i@.cid aldehyde. There aro 8 refurenae3, 3 of -ihich are 31avic. i.. ASSOCIkTJOH: Moscow State University (:-oukcvskiy fcaudarstyonny-, universitet) SUBIZITI12D: October 25, 1956 AVAILABLE: LibrarW of ConCrens 1. Acrolains - Chemical reactions 2. Crotonaldehvdes - Card 2/2 Chemical reactions 3- Copper chloride catalyst - Applications AUTHOR: Dombrovskiy, A. V. 79-11-30/56 TITLE: Haloidarylation of Unnaturated C,=pounds With Aromatic Diazocompounds (Gaicidariliroyan:;ye nepredell.nykh Loyedineniy aromaticheskimi diazosoyedineniyEmi). VIII. Chlorarylation of Pharyl-, Vinyl- and Isopropenyl- acetylene (VIII. Khlorarilirovaniye fenil -, vinil - i isopropenilatsetilena). PERIODICAL: Zhurnal Obshchey Khiniii, 1957t Vol. 2'11. lir 11, pp. 3050-3054 (USSR) ABSTRACT: The reaction of the aryldiazochlorides with ;@heriylacetylene in an aqueous acetone solution in the presence of copper chloride was hitherto not treuted. It ij of interest, as it may directly 'Lead to stilbones. The r,---action wi@x also performed with vinylacetylene, althxx-h it was reported in a 0 U patent that chloraryl df,@rivatives -,an be obtizined from vinylacetylene and sone diazosult@,i. In th,@ irejent @aper the authcr reports on th@@ reoults of the in-;est!i;ation of tile interaction between izopropenyl- acetylene and the chlorldieo of aa well as on aome conversion.j. of tht; obtained -:1i1c-r,-,..ry!.dPrivatives. Card 1/2 It was found that 1--hc-nylacr--tyl@-ne v, th @,. n,@-utral 3olution of Haloidarylation of Unsaturatod Covpounds 4.1th Aroa4tic 75-11-30/56 Diazoeompounds. VIII. Chlorarylation of Phanyl-, Vinyl- an] It3vpru,1ony1jLct@ty-lene. diazooliloroi,hen-,1 -e,ith an excess of 50,L'I, formu a so-called -ZO loa-chlorostjilbene". @ /. o'L r@nua3nin(; buhind unchanged. Vinyl- jnd iaoproponyl-acetylene r-_,act with aromatic diazusalta under th@_ samc- co;'Witions aa -phenyl- acetylene, where ',,hlorc-4-aril'butint.-@ fu@riri. The atructure of these haloidarylacetyl(ines was by the qualitative and quantitative dotermination of ace',@Ienu. The fc:tmula of the chlorarylbutinea: Ar - CH C1 - C 2 Cil 2 j. R There are 2 tables, and 6 references, @. of which art? Slavic. ASSOCIATION: Chernovtsy State University (Chernovitokii c-osudarstvennyy universitet). SUBMITTED: May 17, 1956 1. Ary1diazoohlorides - Chemical reactions 2. Phenylseetyiene - Chemical reacticna Card 2/2 3- Copper chloride calalyst - Applications AUTHORS: Dombrovski . A. V., Yurkevich, A. M., 79-12-1--3/43 Terent'Yev, A. P. TITLE: Halide Arylation of Unsaturated Conpounds With Aromatic Diazo-compourias (Galoiua_2ilirovaMyr_- nepredellnykh soyedineniy aroma ti che skimi diazosoy,@-eineni.4ami)- IX. Synthesis of the a - Halide - P - krylpropionic and of the P - Arylisobutyric Acid(I&Sintez - a - Ealoid arilpropionov .ykh i P - arilizomaslyunykh kislot). P_'A110DICZP.L: Zhurnal Obalichey Xhimii, 1957, Vol, 27, lir 12, pp. 'j34,6-3!49 (USSR) ABSTRACT: In the course of experiments for the purpose of conducting a direct synthesis of the phenylanaline and of its derivatives with an utilisation of the halide arylation reaction of the acrylnitrile, the authors developed a synthesising method of the a- halide - P - arylpropionic acids by means of a hydrolysis of the a - halide - P - arylpropionic nitriles, usinE a mixture of formic acid and hydrochloric acid. The synthesis known up to now of a - halide - P - aryl- propionic acids with the help of nitrous acid and hydro- chloric acid is not applicable to the production of amino- Card 1/3 acids. The method proposed herc for the hydrolysis of the Halide Arylation of hot Saturated Compounds With Aromatic 79-12-33/43 Diazo - compounds. IX. Synthesis of the a - Halide Arylpropionio and of the P arylisobutyric Acid a halide - P arylpropionic nitriles with the help of the aforesaid mixture of acids leads quickly to the formation of the corresponding a - halide acids with an almost quantitative rate of production. The heat:LnC of the nitrile chloride waa conducted with the three to five fold amount of 85 @ formic acid and of concentrated h:idrochloric acid. By this means, the following acids were obiained: a - chloro - 0 - phenyl a chloro - P -I- - nethoxy phenyl -, a - chloro - P 5-C chloro phenyl, a - chloro, P - (2,ij di-chloro phenyl a - chloro - P - (..TL - bromo phenyl) a - chloro - P - (p nitrophenyl) - and a - bromo P - phenylpropionic acid (see formulae). Subject to identical conditions a chloro - P - phenyl - arLd a - chloro - P - (Tt-- nitrophenyl) isobutyric acid were synthesized from the corresponding methylester. Card 213 Halyde Arylation of Unsaturated Compound3 Hith Arou-.itic 12 - Diazo - compounds. IX. Synthesis of the a - Halide Arylpropionic - and of the P - Arylisobutyric Acid There are 9 references, 4 of which are Slavic, IISSOCIATION: Moscow State University (Mo3koyskiy go3udarstv,@al@,;-I, universitat). SUBLIMED: November 26, 1956 AVAILABLE: Librarj of Congrea3 1: :Halide-'P-arylpropionle acids - Synthests 2 Arylisobutyric acids - Synthesis 3- Cyclic compounds - Halide arylation Card DOMRROVSM., A. V.: Doe Chem Sci (dies) -- "rhe reaction of halocrylization and arylization of unsaturated aramtic compounds with diazocompounds, and its use in organic synthesis". Moscow, 1958. 29 PP (Aced Sci USSR, Inst of organic Chem im No Do Zelinskiy)p 160 copies (KL, 'No 2, 1959, 118", DOMMOVSKIY A.V.; GANUSHCUK, N.I. Synthesis of 4-N-piparidyl-l-phanyl-2-butens and its hamologues. Ukr. khim. shur. 24 no.1176-78 158. (MIRA 11M l.Chernovitakiy gosudarstvennyy univervitet, kafedra corgemicheskoy k:himli. (Butem) //V 1-5 k & v 3 BONM, A.S.; DOMBROTSKIT-,.A.T. Mici;-c`r@y"@s,ta,lloscopic reactions of the* nitrate ion with the aid of 4-n-piperidyl-l-phanyl-2-butens. Ukr. khim. zhur. 24 no.1:99-102 158. (MIRA ll.,4) 1,Ghernovitskly gosudaretvonnyy univermitat. (Nitrates) (Butane) (Crystallization) DOWROVSKIY, A.V.; GANUSMHAX, N-1- '11@ lorination and arylation. Ukr* khtm. zhur. 24 no. 2:217-221 1513. (MMA 11:6) 1. Chernovitakiy gosudaretvannyy univarsitat, kafedre organicbeskor khimit. (Isoprerm) (Chlorination) rk 0 V 1-9-1-47/65 AUTHORSt Yuri-cvich, A. It. , Donbrovnkiy, A. V. , Terentlyev, A. P. TITLM The Haloidarylation of Unsaturated Con-.)ounda With Aromatic Diazo Compounds (caloidoarilirovaniyu neprodellnyl-h soye- dineniy aromaticheo%limi diazosoyodinoniyami) X. The Synthesis of DL-Phenylalanine and Its Honolo-ues (X. Sintez DL-fenil- alanina i yego Gonolo--ov) PERIODICAL: Zhurnal Obshchey Y'hinii, 1953, Vol.20, ITr 1 pp. 227-230 (USSR) ABSTRACT: In connection with tho haloidarylation reaction of the arylic acid derivatives the authors had earlior %orked out a prepa- rative mothod for the a, Inthcsia of oL-haloid-F-arylpropionic and P-aryl-ioobutyric acids by oaponification of the nitriles and eaters of this acid with the aid of a mixture of formic ani hydrochloric acid. This oade it poo.9ible to find a Gene- ra-l method for the s',%?1tbooir, of DL-P-paenylalanine and its hozzioloZ;uee fron acryInitrile and methyl!ietacrylate (see the process of reaction). On direct action of am-rionia and amineG upon ot-baloid- propionnitriles an a rule no aminonitriles C-,jrd 1/3 Eire fovwd, with 1- exception of o(,..c*,Iilo.-c-p-phenylpropion- 7 -471/063 The 11aloidarylation of Unsaturated Compounds I/Ith Ars-aasi.c Di;--zo Compou-'Ids X. '1'he Synthesis of DL-Phenylalanine and Its florolo'Nes nitrile which yielded 11, P.-dipben.-laianine by the influen:@e of aniline and by subsequent saponifit.-ation rf aminonitrile with Cal.13'IiC potash. On heati.n.- jf c