SCIENTIFIC ABSTRACT FOLWARCZNY, CZESLAW - FOMENKO, A. S.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000413420011-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

FOLWARCZNY, Czeslavp mgr inz.; SOBOMOWSKII Witold, mgr inz.; SUCHORABI
Antoni, inz.
Reliability and safety testing of thermal Inrtallations in
power stations. Pt.l. Hhergetyka Pol 18 no-31Supplement:
Energopomiar 10 no.2:14-16 MrIC4
1. Pion Cieplnyp Zaklad Badan i Pomiarowp Warszawa,

F0P'j~F-',CZNY' C..
FGLWP.7~-CZNY, G. Few a nechine-tractcr station car, consiCercbly increase.- the yie--.Js per
hectare. p. 244.
V01. 6. No. 13, July 19%.
j,'-CHALISACE ZEILILLSTVI.
1
ACRICULTURE,
PrOm, Czechoslovakia
So: East European Accession, Vol. 6, No. 3, ""Xrch 2957

Inz,; SOBOTKOIISKI, Witold, mgr inz.;
SUCHORAB., Antoni, inz.
Methods of performing acceptance tests of thermal eqj~4vment in
power plants. Pt. 2. Energet~ka Pol 18 no. 'Ji.e'511suppr.Mul
nauk techn enorgopomiar 10 no. 3tYl-23 My 164.~
I

F0i:-.;,RCZi,iY. G.
M,
I -,ik-.Ln-- work Lth contracts easier. p. 4;0 (~-HCIU~NISAICS 'Zi-wYLDELSTVI,
Vr4jl. ~,, No. p ho'l;vIlkla)
13, Dee 1956, raha, Czac o
SO: Yonthly List of East Zuropean Accessions (EEAL) LC, Vol. 6. No. 12, Dec 1957. Uncl.
All

CATEGORY
ABS. JOM.
CRIG, PUB&
ABSIRACT
f
I Chemical Tochnolop:y. Chemical Producte and Tneir
Apj)!ic'4tjons--Ghem-Lca,j. f-nvrineorinr,.
r RMimaj. No* 5 19609 Me,
t Ochedunzko, S. md Folwarcznj, J.
Por iriver.
~,-c Flom of (arer, i.p Fipes
i Zesz Naul, Uolitdat~rj l6laakiej, No 3-12 (19.5q)
I ftinT t)ie Urft la.-i of tqerfnodyn~micf3 anfi thf'. c0n-
tinuitly equatim, the authors have devived art eq,,ia-
tion which corrospands to the Failro [Fannot?)
curve. Or. the bas-ILE, of the equation derived, thp
work required for the overcomin.- of friction and
Ue increase in kinetic energy are discussed in
P-il and T-S coordinates.
7. Sokol's!U-j

BARTELIS, A.V.; LEBEDEVA, M.A.; GRASHCHFIIKCVA, Z.F.;
Use of staphylococcal anatoxin in the treatment of mastitia,
Akush. i gin. 40 no.D17-21 Ja-F 164. (MIRA 17:8)
1. Ilauchno-isoledovatellskiy inatitut akusherBLva i ginekolo-
gil. (dir. - Prof. 03. Makeyeva) Ministerstva zdravookhraneniya
SSSR, Moskva.

/62/009/002/001/001
P/032
ray D265/D308
AUTHORt Folvarczny, JAM~r Gliwice
TITLE: Thermodynamic similarity in the case of laminar
flow through a straight circular tube
PER'.rObICALt Archiwum budowy zaszyn, v. 9, no. 2, 1962, 191-238
TEXT*: The laminar flow of heat is analyzed under conditions
of hydrodynamic and:thermodynamio stability i.e. for constant values of
Nusselt number. Taking axial hoat conduction into conaidbration, the
differential equatiop in dimensionless form is derived from tirst prin-
ciples
d2c 1 d S 2) 2] 2)
- + - _)2
d 6 2 6- d 6- (11PLO) wk 1X(1- 6 Pe (23)
for which the solution shows the relationship Nu f (K, Pe) where K -
appears as a now disensignless quantity defined by
Card 1/2

P/032j62/009/002/001/001
Thermodynamic stability in the oasis ... D265/D308
R
X Pe I * (21)
where R - tube radius, L oonstant'length of subtangent to curve of
the temperature difference as a function of tube length, Pe Peclet
number. Neglecting the axial heat conduction$ the values Nu 3.65 for
K - 7.313 and Nu.- 4-36 for K - Op are shown on Nu - X system graph.
Considering the external heat flow through an annular duct ar6und the
inner tube the heat exchange conditions are analyzed which depend on the
coefficient of heat conductivity, the wall thickness, thermal capacity
of the outer flow and the cross-section of the outer duct. Particular
cases of heat flow for which X a 0 and Nu - 4.36 and K + 0 and PeA* oD
are discussed in detail, and heat exchange conditions are determined for
several values of Nu - number of the inner tube. There are 11 figures
and 5 tables.
ASSOCIATIOM Katedra. teorii'massyn oieplnyoh politechniki hlqskiej
(Department of the Theory of Heat Engines, Silesian
Polytechnic
SUBMITTEDt December'- 1961
Card 2/2... ......

FOLWARGZNY, J., dr. ing. (Poland)
Control of complex combustior processes. Ipari energia 5 no.3:
55 M 164.

F., ".;, .1, 21 r 11 y , 1 1 o V,.,. L, (G 1 i -a J,
Contrcl -)f' cowplax cogik,ittit-Gr; owd im~z 11
no. I - ~0-72 1 L" .

-F")T'," lji-~V`o- - -,,"d- I ~c'---O ---
ft, -,- !.., , . -1 ~; '. " ". f, I Lj .
"iNew Type of Terpene Transformations. VTTT. Synthesis of Terperylacetoncetic
,and Tex-penylm-iloric Fzters and Their Cleavage Products.11 Zhur. Ob. Khi-M*.P 22) No.6., 1952

TISHCMCNKO, D.; FOL ADOV, V.
New type of terpene transformations. 1. Synthesis of homotorpends. Zhur.
Obahchey Khim. 22, 1591-3 152. (MMA 3:9)
(CA 47 no.18,9306 133)

TISHCEISNW. D.; PaSIANTSEVA, M.; FOLYAWV, V.
MWWW"_-%W
Now type of terpene transformations. XII.
terpene series. Xhur. Obahchey Xhim. 22,
47
153)
$)rnthesis of nitriles of the homo-
1829-32 152. (MLRA 5:11)
(CA
no.18:9307

"Special Tongs for Sealing Diamonds in a Mandrel by means of a Voltaic Arc".
Stanki I Inmtrument, 14, No. 11-12, 1943-
:BR-.52059019
" t
s

MOYCHO, W.; GUBANSKI, M.LFO LEMANSKA, M.; WAJSBARD, E.
The occurrence of tobacco mosaic virus in tomatoes in Lodz and its
neighborhood. Postepy nauk roln 7 no.lt79-82 Ja/F 160. (EM 9;10)
(Poland--TuAatoes)
(Mosaic disease)
(Viruses)
T MR - I =1
RT

-,A., podpolkovnik militaii
I ~ ~
Our common cause. Za rul. 17 no.1:8-9 JS 159. (MIRA 1213)
1. Predeedatell eksamenatsionnoy komiseli Gosudaretvennoy avtomobillnoy
inspektoil UVD Orenburgskogo oblispolkoria.
'(Orenburg Provtnce-Automobile drivars)

FOMCHMO, GeK.9 general-mayor maditainskoY cluzhby; KOVALET, Te.I.,
---TbIW6-vnik meditainskoy eluzhby; ASEMY, A.A.
Illectrocardioseopic and electroophygmoseople study of the functional
state of the cardiovascular system. Voon.-med.zhur. no.10-031-35
0 159. (MIRA 13:3)
(MG-MCARDIOGRAPHY)

?EASE I BOOK UPWITATION 307)~304
Sovesbahanlye po toorli ILtaynykh protoossol. 5th. 1959
Tochnost' otlivok; trudy soveshch%alya (Accuracy of autiriCs, Trans~
%tionscor.the Fifth C4nfarLncc on the Theory of Founding Proeecs~
Mae ow KlabSix, 1960. 206 P- 3,500 copies printed.
Sponsoring Agancyt A)cademiya nauk S&U. InstItut =schlzored:~c.
Xominalya PO tokhnolosil miabizoatza'T alys.
Zd. (Title pago)s B. B. Oulmay, Doctor of Technical Sclsnoaz.
trofessorj Ed. or PubllshinZ Hou3sz 0. N. Soboleva. Toeb. Ed..
A. Y. Uvarava; Managing Ed. for Literature on Hot-Procoase-d
Natalat S. U. GoloTin, Engineer.
PURP=i This book Is Intended for scientific and tachn1cal person-
uel at sclentitio research inatitutons factories, and sabools of
higher education.
COMMEt The book contains 29 reports read at a conference an the
LCCII=cr of castings. The conference was arrzALziod by the
Committee an Processing in Machine L-aIldj= and apowarel by the
Institut waahInorsdeal" All S= (institute or the Science of
Machines or the AcadoW or 3clencas TJSZR). The reports. pr'a -
sented by leading speal -13 at*, science workaro. and productlc*
peraonnel,diacuas the vrosent state or the probleu of tho see*,&-
racy of "stings and methods of solving the problexx lnvolvod.
There are 58 references, mostly - I ---~ I
Kamarov, L. [Xhg; imoerf. i)ixtortion of 3and Molds
(Maginearl. and Yd Talumn-chin EEnglMerl.
of Castlngs Caused by patterns and 71&zks 125
-PubroTs Z. A. X. (Enzineer). F-Ifect of Ther=al Distortion
or ha Moldij,- Mi,,turgs a,, the Ao"rae7 of Castings 131
The volt oj iavectigatirZ the distortions and thermal stress
In the molding mutures was carried out under the suparvlp-
Ion of P. T. Berg.
4~PQ n,,". (EaSlneer), and B. B. Oul"yev. P-roductlan
0 racjs __ ~
Ion ;4stings In Shall Molds Pr*asad Frm a Waterglaos
,Ltztun
.MuVi 1. P. lZagUeero's. and V- V- "henkov Main"r).
on ox ~rzq rracl I Ateal CasEines'UY Using Chexl-
lardan1na KIxtuzvo----- .... ... 153
~.~btoo;:.N. M'. (Doctor of Technical Sciences. Profosaorl,",
aa-v tEngineeri. Dinanslona.1 Accuracy of Investuamt
CA# &Jaza 160
Gorynnow, 1. 1. (C;anadate of T*Oxdcal Sciences). Dimen-
'vrama-wturrey and Burfaae Roughness or Castings Obtained
by Various Methods 160
0. A. Untor. A. To. Malloy, A. 1. Belyayev, and Zoo-
near V. B. Shul 'man participated In asking castings.
Jb-q&In*arj, and B. B. Oulyayev. Yormation
r the coy. - Par Castiv4s In vie Casting
!~~, C..". 193
RoleanlehVe, A,;,O. (Ingineer). Accuracy of Castings 06-
at& Zolft
at&r 203
Card 6/1

XCVSTAPI=p I.N.p insh.; BMWVSKIY, Yu.?.# kand. takhn. naukj.ZgKCfq~~Oj
-A-~Ip Undo tekhn. nauki GULYATEV, B.B.p doktor takhn. nauk
Compacting molding mixtures by vibration squeezing. Lit* proisvo
no.94-6 0 165. (MLU 18110)

Ile
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TTW4PV3jV VATZWOAZZ Z-7"rC;orM31d
6 5 -OP TIAOS U A 9 UON W)P.Lay

Dispensary SLorage fable MP. Voyenzio-f-iadi ts ins kiy Lhurnal, ~,'o 1, P. 76, 1955.

VOROBIYEV.9 V., inzh.; MUNIN, A., inzh.; SPIROV, V., b1zh.;
Fq~qll~~HWVj, I.) inzh.
Building made of light alloys. Na stroi. Roo. no-10:37-38
o 161. MMI 14: 11)
(Moscow-Aluminump SLructural)

FCNCHMOj Oleg[Fmchanka, Aish] (Brest)
People praise her work. Rab. i sial. 39 no.2'.15-16 F 163.
(MIRA 162-4)
(J'uvenile delinquenoy)

GALIPKRIN, Ye.I.; GORDONOV, A,yu,; YOMCHEVZOV, VeMo
Designing trigger circuits for point contact crystal triodes vith
consideration of interchangeability. Foluprov. prib. i ikh prim,
no*2:340-352 157. Oun 11:6)
(Transistors) (Ilectonic circuits)

MOLCHANOV, A.A. (Novosibirsk); SlGJRSKIY, V.P. (Novosibirsk);
FOMELI -JI*X.-..(Xovoeibirs,.)
Study of the dpaxios of multistable elements based on a
simplified wool. Isy. kV SSSR. Tokh. kib. no.53156-162
84 165. (MMA 18111)

--N-R, AR7004316
A
CC
AUTHOR:-Fomell, B. M.
On'
SOURCE CODE: UR/ V66f6661 fltiiT6/ifi7~1
TITLE: Investigation of aubharm(;nic oscillations in computer elements with one
degree of freedom
SOURCE: Ref. zh. Avtomat. telemekh. i vychisl. tekhn., Abs. 11B12O
REF SOURCE: Sb. Vychisl. sistemy. Vyp. 21.Novosibirsk, 1966, 33-45
TOPIC TAGS: computer design, computer component, computer theory,
Al"-` "~ 0 4-ag Jt" / 04'c!~4z-' / I P'T - T ,.91 C--,IA4-
0,
ABSTRACT: Elements that use parametric subharmonic 9 illations have found wide
usage at the present time; the phase of the subharmonic oscillation serves as a
dynamic state Indicamt in these elements. As nonlinear systems have no principal
difference between an external periodic disturbance and-a parametric effect (because
every periodic process, in such a system,is accompanied by a parametric modulation
of its nonlinear.olements), it is suggested that the oscillations of any shape
whose frequency is submultiple of the external applied frequency be considered as
subharmonic oscillations. A class of dynamic computer elements is considered which
is describable by second-order equations containing, In addition to a strongly
nonlinear function, a periodic function of this form: ~+6+a(x)-t(l)
where b - positive coefficient, &(x) - nonlinear function, f(t) - periodic
function. Qualitative methods are used in an examination of such an equation which

ACC NRi AR7004318
permits finding all possible moti6na in the system. The results were verified on.an
IPT
-5 analog computer equipped with a set of nonlinear units. The resulti were
readout from an oscilloscope screen calibrated in (x, y)-coordinates of the state
plane and having time markings. The above qualitative method of studying subharmonic
oscillations has the advantage over other methods in that it is noncritical to the
form of the nonlinear function contained in the initial differential equation and
in that it permits obtaining the entire set of possible motions simultaneously.
In addition to presentation of the general method, a case of single-domain model
of a ferromagnetio film is considered in detail; the model is constructed after the
Landku-Livshits-Gilbert equation which describes the magnetio moment in a ferro- i
magnetic: n6+On;+Ijj sin 2x+A(t) sin is-es) o. where x - a W'etio-soment angle in the
external field, no 00 - film parawters, f(t) - external field varying on the
same law as the funotion f(t) in the initial equation. Eight figures. Bibliography
of
.3 titles. G. Y. [Translation of abstract]
SUB CODEt 09
Card 2/ 2

BAMIN, G.S.; FOMEN, V.T.
Bending of surfaces of positive curvature under certain
boundary conditions. DokI. AN SSSR 140 no-5:987-989 0
161* (MIRA 15:2)
1. Rostovskiy-na-Donu gosudarstvennyy universitet. Predstavleno
a~ademikom P.S.Aleksandrovym. -I T
(Surfaces of eawo6mt curvature)
(Boundary vaiue problems)

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FOHENM, A.A.
,--- ~Radi~ofrequency magnetic end electric spectra of permeability of the
body and substance of Nnh-ferrites. Zhur. tekh. fiz. 28
no.31506-510 Mr 158. (MIRA 11:4)
(7arrates) (Magnesium-zinc alloyn--Electric properties)

"Use of -Dreparations n-I 3:id FB-2."
00: Vetarimriyn 2C(2): 1951Y P. 46.

S/263/62/000/020/002/Oo6
E194/E135
AUTHORS: Agarkovs A*P*9 Fomenko, A.I., and Kureyko, S.M.
TITLE: The preparation -and calibration of heat resistant
pick-ups
PERIODICAL: Referativnyy zhurnal, otdellnyy vypusk, lzmeriteltnaya.
tekhnika, no.20, 1962, 11, abstract 32-30-91-
(Tr. Novocherk. politekhn. in.-ta, 127, 1961(1462).
57-61).
TEXT. Heat-resistant pick-ups based on potassium glass are at
present widely used to measure static stre *ases that are set up in
components which operate in a high temperature zone. Cements for
heat resistant pick-ups based on potassiuid liquid glass are of good
technological properties, their sole disadvantage being their poor
electrical insulating properties at high temperature. This
disadvantage is overcome by introducing lead oxide PbO which reduces
the ionic conductivity of the cement because of the influence of
heavy io.ns. The procedures for making and calibrating the heat-
resistant pick-ups are described. 3 figures.
Card 1/1 ~Abstractorfs notes Complete translation
Va. i'~

1. YOMENKO, A,N,-, INOUMSEV, Ye K.
2. USSR (600)
4. Lignite - KW1 County
7. Geological report on the results of the.prospecting carried out by the Izmail and Kagal .'
lignite partios in 1940-1941. (Abstract) Izv.Glaw.upr.gool,fon. no.2 1947
9. Monthly J_ist gL jUILM Accgosions, Library of Congress. March 1953. Unclassified.

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Ashinazi, M. 3., Kutsa-ya, B. F., anti Fnrenk-), A. "A si-roli"ie'
d ~, te nn in i ng 'U! t e c ) r tr n s t ~a c t,-,) r(0 r p!: oj! a ph i c pi a t e sU'~- rkl- J!- . z 1:u rna I
Val. XIV, ls~ue 2, '191-9, 47-52
SO: U-1392, 19 August, r3, (Letoris 'Zhurnal Inykh Statey, No. 21, -i949).

mKbuim W Illill C meet. A. 8~
,oil 11~1 16.11=0111.16F
711istalithev luott.
IgA
y Sri. Ukr. 8 R.). Ant. obsAwhire
Khano. (J. Gotio. Clottu.) 20, Ifti,49W0950); cf. C.A
43. Giuli.-Tbe existing data on Invelidgations of the teac:
timin are ctitically reviewed and it is pointed out that at this
War ISO tuaoulu&ive evidence exists for a AIW devisiton at to
,on intra- cw intermol. nitchianism, o( the ptintuy S%cp. The
twilto-trairanSitment of Clio -.01CH.0111% in Ilit pirence tA.
plictsiol-3.3-D, by realizing in a IN totin. 6 Itrit. gave 0.
allylphettol, Isolated either by citu. with 201,'~ N&011.
Acidill'aticitI. extu.. Wul fractionation. Or by P1,111. A allyi-
r,liciRd with IVIsCls so
.1wifillall; olubuslioll Sit tile prI141111-1 phourd Ills, idisoller
M so-ollylphraid-41,5-0j. A alitidAt or.ult wit. .-I,Wticil on
Seffilling Phell:01clit(JI'll ill tile litrwitir (if allyl
phunyl-3,3-Do ether 4 his. in a cot Atli). ThU4. the orlho
ttWtAngement in these rawo; tahc~ pl.tiv imimily Isy a.,
ilIUSS11101- 10131C. Tile PAWMPI-J~;-Pj IAA.~ IIIVIXI. 4WIFIlittig
"I IlrodAd, et a/. (C.A. 44, WLW; sit alkyl rlkt,. Ivrisil.
Ifunt &UYI Iscountle as trivial (cf. lfoulwn, Me Airth'istex
der is . Ommosir, vol. 11J, C.A. 24. )ZIMP. Is.
(1.1,zx
bit, Cl. %L K.

ROZABOY, Ivan Grigorlyevich, starshiy nauchrqy sotrudnik; ZAVITAY3V. Petr
Aleksayevi--h, starshiy nauchnyy sotrudnik; SKATKIN, M.N., radaktor;
YOUNNO. A.B., redDktor; DZUTIYEV, S.G., tekbnich9skly redaktor
[Handicraft lessons for the fourth grade] Uroki ruchnogo truda v
chetvartom klasse. Pod red, Skatkina. Izd. 2-os, lop. i perer.
Moskvvq Gon.uchebuc-podagog. Izd-vo X-" prosy. PSYSU, 1956. 231 p.
(MIRA 10!11)
1. Institut toorii I. istorit, podagogiki (for Rozenov), 2. Institut
matodov obuchenlya Akademii pedagogiahesirtich nauk RSM (for
Zavita.vev). 3. Chlon-korrespondent Akademii pedegogichaskikh nauk
RSYSR (for (Sketkin)
(Handicraf t)

Tra ffn~ WM
w UC4~p run vril;l 111M,
TO a,

A4 e
AUTHOR: Reported by A~. Fomenko. 73-2-21/22
TITLE: Second Ukrainian Conference on Physical Chemistry
(SYMPOSiUMY. Vtoroye Ukrainskoye Respublikanskoye
Soveshchaniye po Fizicheskoy Khimii).
PERIODICAL: "Ukrainskiy Kbimicheskiy Zhurnal" (Ukrainian Journal
of C emiStry), Vol.23, No.-21 March-April, 1957,
pp.2,72-275 (USSR)'.
ABSTRACT: Held December 14-18, 1956 in Kiev by the Institute of
Physical Chemistry im. L.V.Pisarzhevskii (Institut Fizi-
cheskoi Khimii im.L.V.Pisarzhevskogo, AN USSR). Short
summaries are given of the following papers:
TheoFZ and Practice of Catalytic and Adsorption Phenomena.
Ro'iterv VA 1.9 Korneichuk, G.P Rzayev, Pr.B. and Stukanovsk .aya,
N.A. (Xiev):
Results on investigations on the kinetics of oxidation of
sulphurous anhydride to sulphuric anhydride by industrial
vanadium catalysts by the diaphragm method'.
Card 1/20 Values for the velocity constants and heat of activation
were computed. They were not affected by the influence of
macrofactors.

73-2-21/22
Second Ukrainian Conference on Physical Chemistry
(Symposium). (Cont'.)
Theoxy and Practice-of Catalytic and Adsorption Phenomena.
Wont.).
Arnoll dov, E.M., Lyubiteleva,A.7s, and Vol, fson,V Ya. (Rubzhnoye).
Investigations on a composite charge- of a v~~&ium. oxide
catalyst for the oxidation of naphthalene. This was pre-
sented by IF1 AN USSB:.
Roiter,V'.Ar. StukanovskayajY.A*#j Yuza,V~A'., Korneich&pT.k. and
Ushakovaj.E (Kiev)'.
These authors observed that many processes are catalysed by
impure vanadium oxide. Oxygen interchange is revealed only
above 500 C, in spite of the fact that catalytic oxidation
occurs between 300 - 400 C'. 'This is contradictory to the
oxidation-reduction mechanism of the catalysis.
Rusov, M.T'. and Strelftsovo O.A'. (KievY.
Data obtained by.investigatimg the macrokinetics of the
synthesis.of ammonia in a long catalyst bed at high
pressures.
Davtyan., O.K', 'and Ovchinnikova, E'*N'. (Odessa).
Oxidation of sulphurous anhydride on the surface of a
Card 2/20

73-2-21/22
Second Ukrainian Conference on Pbysical Chemistry
(symposium)'. (Cont',j
Theoxy,and Practice of Catalytic and Adsorption_Phenamena.
tuont.)
series of solid catalysts and on activated coal proceeding
at normal temperatures.
Stepkop I'.I*. and Goncharenkop G.F. (Kiev).
They observed a decreased discharge of electrons from
germanium during adsorption of CO and CO and formic acid
vapours. As in the case of CuO, the cathytic oxidation *
of CO on germanium causes a decrease of electron emission*
Glikmany T',S-. and Podlinyaeva? NA'. (Kiev).
The authors proved that sensitised photo-reduction (by
zinc oxide) of methylene blue and thionine can be accom-
plished at the expense of oxidation of OH-ions from zinc
Card 3/20 bydroxide. Thus the oxidation of water can be achieved
with dyes by th'e effect of small light quanta in the
presence of ZnO.

73-2-21/22
Second Ukrainian Conference on Physical Chemistry
(Symposium);, (Cont.)
Theory and Practice of Catalytic and Adsorption Phenomena.
Kornierko, T~,P~. and Polyakov, M.V.. (Kiev).
Oxidation reactions of methane and methanol to formalde-
hyde.
The oxidation reactionsof methane were proved to start on
wall s of the reaction vessel.
Shalya, V.V. and Polyakovq li.f (Kiev).
The authors discussed reshts obtained during the investi-
fation of the kinetics of oxidation of butane-propane
ractions and of methanol by differential calorimetric
measurement. A heterogeneous-homogeneous radical-chain
mechanism of the process was established.
Tovbinq Ji.V. and Savinova,Ye*.f. (Kiev)'.
They investigated the kinetics of the non-stationary
evaporation of water from the surface of a vibrating
string which is in contact with the gas. The mechanism of
the process consists in the formation of transient self-
adsorptive layer and of the desorption of substances from
Caid 4/20 this layer. In a further discussion they investigated the
mechanism of self-adsorption on the-liquid-gas boundary'.

73-2-21/22
Second 'Ukrainian Conference on Pbysical Chemistry
(Symposium)'. (Cont.)
Theoa and Practice of Catalytic and Adsorption Phenomena.
lconl.)
Rastrenenkop A'.I'. and Neymark, I.Ye. (Kiev).
The production of t1taniu silicagel7 titanium-gels and
alumino-silica gel with different -pore structure was in-
vestigated as well as the influence of the macro-structure
of these sorbents on their catalytic properties.
I.E.Neimark's theory on the formation of the structure of
hydrophilic sorbents can be applied.
Sheynfay4t Y.Yu'. and NeYmarkt I.Ye. (Kiev).
ResUlts of investigations on the adsorption of various
substances on fluorinated silicagels.
Adsorption is linked with the formation of molecular com-
plexes and proceeds on the basis of the acceptor-donor
mechanism.
Tarkovskaya, I A .., Chervyatsova, L.L. and Strazhesko, D*r.(Kiev),
presented a paper on the mechanism of adsorption oi electro-
Card 5/20 lytes with the aid of radioactive isotopes. In aqueous as
well as in aqueous-organic media the selective absorption
of salt cations represents a typical ion-exchange process.

73-2-21/22
Second `Ukrainian Conference on Physical Chemistry
(Symposium)', (Cont"
Theory and Practice of Catalytic and Adsorption Phenomena.
kcont. )
Davydov, A'.I', (KharkovY.
..The mechanism of the poly-anion exchange.
Shostenkot Yli. Y. (Kharkov)'.
Results of investigations of the dynamics of adsorption
and desorption of organic substances.
Strazhesko, D',N. (Kiev)'.
Results of investigations in the field of electrochemical
adsorption of ions on carbon from aqueous and non-aqueous
solutions.
The mechanism of the influence of non,-electrolytes on the
adsorption of electrolytes by active carbon was formulated.
This amplif'ies the theory of electrochemical adsorption as
stated by A.ILFrumkin'.
94nory of Solutions of El"trolytes and Non-Electrolytes.
Esell song B.N~. (Kharkov)'. 3 4
Card 6/20 The author discussed the vapour-liquid diagrams of He in He
near to the transition point HeI--),HeII.

73-2-21/22
Second Ukrainian Conference on Pbysical Chemistry
(Symposium)'. (Cont'.)
Theoa of Solutions of Blectrolytes and Non-Blectrolytesf.
'TUont.)
Lifshitst V.1t. (Kharkov)'.
The lecturer elucidated-the quantum theory of liquid 801u-
tions and the theory of phase transitions of type II.bDK7
application to the transformation of He I in He II. T e
theory is proved by investigations on ti;e separation of
the solutions into 2 phases, HO and He*. The quantum
theory of solutions explains the discrepancy of the solu-
tions He3 in liquid He4 from ideal compositions.
Izmaylovj, 9.A' (Kharkov)'
The influence of soivents on the strength of electrolytes.
The dissociation of any electrolytes is considered to pro-
ceed in a number of successive stages: the interaction of
the electrolyte with the solvent with the formation of
addition products, its dissociation into ions as a result
of further solvation and-assooiation of ions into pairs of
ions. The influence of the solvents on the properties of
electrolytes is determined quantitatively by an equation
Card 7/20

73-2-21/22
Second Ukrainian Conference on Physical Chemistry
(Symposium),. (Cont'.)
Theor-Y of Solutions of Electrolytes-and Non-Electrolytes.
kVont.)
put forward by the author.
Mikulint GA*d (Donsoda).
Criti'cal review of the contemporary theories on electro-
1vtes.
~6_ authorts thermodynamic theory on hydration compares
the theory of electrolytes with Mendeleev's hydration
theory. on the basis of experimental data it was stated
that the molar energy of the interaction of particles of
concentrated electrolytes is in a linear proportion to
~F_. The chemical composition and the constants of instab-
ility of liquid hydrates has to be defined by the quantita-
tive theory of solutions as well as the physical theory
elucidating the linear dependence of the energy on Vc-.
Golik# A.Z'. (Kiev)'.
Investigations on the v1soosity, density, heats of evapor-
Card 8/20 ation and other properties of molecular-mixed solutions the
components of which have similar structures.

73-2-21/22
Second 'Ukrainian Conference on Physical Chemistry
(Symposium)'. (Cont.
TheorZ of Solutions of Electrolytes and._Non-Electrolytes.
70ont
Roshchinaya, G P. Miev)'!
The author investigated the molecular light diffusion in
solutions. Results are in good agreement with those ob-
tained by A'.Z',Golik during the investigations of the physi-
cal properties of liquid solutions.
Urazovskiyo B -S-. andlurisko, A' *I*. (Kharkov).
They discussed the anomalies of the thermal relation of
the refractive index for menthol and benzophenone in. points
corresponding to the melting points of their stable modi-
fications. In the case of cis-decahydronaphthalene the
melting point is considerably higher. These anomalies can
be explained by the change of the coordination number in
the structure of the neighbouring order during the transi-
tion from the liquid to tile supercooled state. The anomaly
in the thermal dependence of the refractive index for cis-
decahydronaphthalene can be explained by the reverse isomery
which 'characterises the cyclic compounds of the saturated
series.
OLrd 9/20

73-2-21/22
Second Ukrainian Conference on Pbysical Chemistry
(Symposium)', (Cont'.)
Theory of Solutions of Electrolytes and Non-Blectrolyles
JUont.)
lzmaylov, 1~.A-. and Franke, A~X. (Kharkov).
Investigations on the reactions between butyl alcohol and
carboxylic acids in benzeney and calculation of the yield
of complex products of the reaction.
The compounds have the composition AB2 (where.A = acid and
B = alcoholY. The constants of non-stability and.reaction
energies were calculated from data of their yield. Acids
with acetonep acetonitrile and nitrobenzene give compounds
corresponding to the formula AB.
Izmaylovq Y.A',', Aleksand-rov, V~.V.j and Ivanova) . E~.'F'. (Kharkov).
Influence of the chemical and physical nature of the
solvent and of the concentration of the electroly-te on the
state of energy of ions in solutions.
Markov, B-F". and Shun' na- , LIA'. (KievY
It was shown that t1le electric conauctivity of binary
dissolved salt mixtures, the components of which do not
form compounds, does not appear to be an additive property.
Card 10/20

73-2-21/22
Second Ukrainian Conference on Physical Chemistry
(SymposiumY. (Cont'. )
TheojZ of Solutions of Electrolytes and Non-Electrolytes.
-Mont. )
This digression is more marked during the transition from
continuous solid solutions to congruently melting compounds
Gorenbeyng Ye.N. (Kiev)'.
The inf'luence of cations and anions on the molecular com-
position of electrolytes in solvents with low dielectric
constants.
Hapshtynskaya, Ye.A', and Skarre, O'.R. Ohiepropetrovsk).
Dielectric constant of pure liquids at various temperatures.
The authors f9und that the dielectric con *stant is a function
of their energy of orientated interaction. Assumi% that
this applies also to mixtures the authors calculated the
energy of orientated interaction for 10 solutions at var-
ious temperatures.
Vasenko,Ye.l~. and Blankq 9.G. (Livov).
Investigation on the mutnal solubility in ternary systems:
formamid'e-acetone in benzene, toluene and carbon tetra.-
chloride.
card 11/20
-Ma
TZ

73-2-21/22
Second Ukrainian Conference on Physical Chemistry
(Symposium). (Cont.)
Theo~y of Solutions of Electrolytes and Non-Electrolytes.
7ont. )
Ravikovich, S".D. (Kiev).
Relations between the molecular structure and density of
organic liquids.
Photochemistry.
Dainp B.Ya'. and Asbkina4 M ,.3. (Kiev)'.
Results of investigations on the photochemistry of hemin-
resembling derivatives of chlorophyll.
With the aid of these pigments it was possible to show one
of the stages of photosynthesis outside the plant cell: ,
the photodecomposition of water by small quanta of light.
By observing the spectra of hemin-resembling analogues of
chlorophyll it was possible to clarify the long-wave dis-
placement of the spectral region of the photodecomposition
of water by basing it on the principle of Frank-Kondon.
Mechanism of Chemical Processes and the Structure of the
M0.1 ecuJ e
Tsimbalp R:.N'.VBurmistrov,S'.I'. and Loshkarev,ld.A'. (Dnepropetrovsk)
Card 12/20

73-2-21/"
Second Ukrainian Conference on Physical Chemistry
(symposium). (Cont.)
Mechanism of Chemical Processes and the StrLicture of the
707ecule. Mont.)
Reaction kinetics of nitrosation of azo-dyes with a second-
ary amino-group.
It was found that the reaction velocity changes with the
concentration Cl- and Bt~. Isobaric potentials and ther-
mal effects of the nitrosation reaction were calculate&
from the equilibrium constants and from the functions of
temperature.
Brodskiyp A*.I'. and Strizhak, LIL (Kiev).
Nitrogen-exchange of amino-groups between liquid ammonia
and organic nitrogen-containing compounds at 100 - 200 C.
Nitrogen does not enter into the interchaige. In com-
pounds containing amino-groups attached &L-2-'ectly to the
dromatic nucleust the interchange occurs only in the
presence of strongly negative substituents. "'onsiderable
interchange is revealed in the groups
Oard 13/20 where X = 0, 8, N-(amides of acids, urea and

73-2-21/22
Second'Ukrainian Conference on Physical Chemistry
(Symposium).. (Cont'.)
Mechanism of Chemical Processes and the Structure of the
Molecule. kUont.)
its analogues)'. The velocity of interchange depends on
the negative substituents and on the interlinking. The
lecturers explained this Py the mechanism of bimolecular
nucleophilic substitutioii.
Gellert B-.A*. (Kiev)-,
Investigations on the mechanism of some reactions with
heavy nitrogen',
During the reaction between an azo-dye and diazoni-cun
hydrate diazo-compounds migrate together with their
N-atoms'. During the condensation of nitroso-naphthosultam
with o-phenylenediamine the nitroso-group is split off in
the foxm of ammonid.
Morozov, V'OP~. (Dnepropetrovsk)'.
Calculation of basic frequencies of oscillation of isotope
molecules'.
1). Method of intervals, allowing the determination of
limits of possible displacement of basic frequencies
card 14/20 of oscillation of molecules during complete isotope

Second'Ukrainian Conference on Physical
(Symposium). (Cont'0)
Mechanism of Chemical Processes and the
Molecule, (Cont.)
- substitution.
2). Method of-partial frequencies. Approximate relations
were obtained which permit the definition of fre-
quencies of basic oscillations of the molecules iY1,
and 7.Yl when the frequpncies of oscillation of the'
molecule are known,
"Y2
Medvedevv K.P~. (Kharkov).
Theory on the participation of single-electron bonds in
the structure of molecules and in the electron bonding.
Lutskiy, AYe. (Kharkov)'.
Functional equations on the relation between the micro-
properties of substances and their dependence on the
mioropropertles of -particles.
Carl 15/20
73-2-21/22
Chemistry
Structure of the

73-2-21/2-2)
Second Ukrainian Conference on Physical Chemistr7
(Symposium). (Cont".)
Electrolysis and Electrode Processes'.
Delimarskiyj YV~.' X'. (Kiev)'.
Polarographic investigations on dissolved salts.
The kinetics of electrode processes were investigated. It
was found that the limit currents due to the concentrat-
ional polarisation are defined by the diffusion which is
the slowest phase of the electrode process. The polaro-
graphic waves on solid electrodes conforms to the equat-
ion by Geirovskii - IlIkovich which defines the polaro-
graphic waves for dissolved salts'. .
Stender,V'.'r'.t KalinovskiyYe.A-. and Nikiforov,Ya*.F'O(Dnepropet-
rovsk-)"
i;chanism'of electrolysis of zinc chloride on graphite
electrodes.
Afanashlev, .1!.S-. and Miroshnichenkot 0,Ya. (Dnepropetrovsk).
Investigations on the electroreduction of oxygen and the
separation of bydrogen on magnetite monocrystals.
Gritsan, V.9. and Shun, D-.S-. (Kharkov).
coxd 16120 Influence of fatty alcohols on the spontaneous periodic

73-2-21/22
Second Ukrainian Conference on Physical Chemistry
(SymposiumY, (Contt, )
Electrolysis and Electrode Processes~. (Cont' .
changes of cathodic polarisation and the current strength
in the chain.
This is due to the periodic passivation and activation of
the cathode surface during the electrolysis.
Galushkot V',P'. (Dnepropetrovsk)'.
Theoretical analysis of periodic osci 1lations in electro-
chemical systems and the author's experiments proving the
phenomena.
Galushkol V.P'. and Dorosh, T'.P.
Mechanism of the electro-reduction of some sparingly
soluble silver compounds.
Portnovt Id.k. (Rubezhnoye).
New thymolquibydr.one electrodes for measuring the pH and
its possible uses.
Pamfilov AW. and Tsinman, A.I. (Chernovtoy)
Analysis of the relation of tae erxek;cive activisation
energy of electrode processes and the polarisation
potential.
Card 17/20

73-2-21/22
Second Ukrainian Conference on Physical Chemistry
(Symposium)'. (Cont'. )
Electrolysis and Electrode Processes. (Contt)
In some cases of chemical polarisation the ;low stage of
the process can be defined.
,Ksenzhek, 0'.S'. (Dnepropetrovsk).
Calculation of the activation energy on simple electrodes
from activation energy values on a smooth electrode and
from the electroconductivity of the solutions. .
Experiments were carried out on the.activation energy of
separation of chlorine on graphites.
Afanas 1yev '.8'. and Shevchenko, Y.Y. (D
.,. A nepropetrovsk).
Experimental data proving the theory of the mechanism of
electro-reduction of oxygen on oxidised steel by inter-
mediate formation of hydrogen peroxide.
Brodsk~yt A I t Fomenkof A'.8'.p Abramovay T'.1f. and Gankinal I'.L.
(Kiev)
R;sults of the investigation on the corrosion mechanism
f some metals.
Mrd 18/20 TOhe electrochemical corrosion mechanism and magnesium was
confirmed by using the heavy isotope of oxygen'.
A-5- 34 r__Xt4__;6M,41 *-k,_~

73-2-21/22
Becond'Ukrainian Conference on Physical Chemistry
(symposium)-a(Cont'. )
Electrolysis and Electrode Rrocesses~, Oont'e)
Roykh, I.L. (Odessa)'.
Investigations on the formation of hydrogen peroxide by
metals during atmospheric corrosion with photographic
methods.
Phase Equilibria".
Garberv YV7. N'. (Dnepropetrovsk)'.
Calculation of the mean buoyancies of vapours of complex
mixtures from phase equilibrium curves.
Yermlaym, 1h.V. (Kharkov)'.
Tile viscosity of solutions of tri-component systems
(MgO-Al 20 3-SiO.P CaO-Al.0 3-Sio 2, N9O_CaO_Al,_03 and
WgO-CaO-SiO )'- Their surface tension on the liquid-gas
boundaryq tReowetting with solid solutions and electro-
motive forces arising between the solid phases and equi-
librium solutions.
Card -19/20

73-2-21/99
Second Ukrainian Conference on Physical Chemistry
(symposiumY. (Cont'.)
Electrolysis and Electrode Processes. (Cont'.)
Gluzman, M',Kh~. and Rubtsova, Vr.P'. (Khaikov)'.
Quick definition of the melting point of eutectic binary,
ternary and 4-component organic systems by contact melt-
ing.
Yasnitskiy, B-G'. and Satanovskaya, TsX. (Kharkov).
The definition of the molecular weight, density and
refractive index of chloroacetic aldehyde and its aqueous
solutions in wide ranges of concentration.
Pamfilov, A-.V. and Prodanvle.A. (Charnovtoy).
Physico-chemical investigations on 'cri-polyphosphates.
It-was recommended to the Institute of Physical Chemistry
im. L'.f.Pisarzhevskli AN USSR to hold the next Conference
in 195K. The Department of Physical Chemistry of the
Khar1kov Institute was advised to hold a meeting on the
Theory of Solutions in 1957'.
AVAILABLE: Library of Congress
Card 20/20

SOV-21-58-0-15/29
AUTHORS: Abramova, T.M., Gankina, I.L. and Fomenkof A
TITLE: Investigation of Cathode Reduction of Oxygen to Hydro~-en
Peroxide on a Coal-Nickel Electrode (Issledovaniye katodno-
po vosstanovleniya kisloroda do perekisi vodoroda na ugolino-
nikelevom elektrode)
PERIODICAL: Dopovidi Akademii nauk Ukrains1koi RSR, 1958, Nr 9,
PP 974 - 976 (USSR)
ABSTRACT; The process of cathode reduction of oxy?en is used in tech-
nical production of hydrogen peroxide. However, the mechan-
ism of the reaction which takes place in this nrocess has
not been y6plained thus far. The authors employed the heavy
isotope 0 in order to clarify the origin of oxygen in hy-
drogen peroxide, which forms on a coal-nickel catliode in the
oxygen reduction. As a result of this investigation it was
shown that only molecular oxygen blown through the electrode
plays a part in the cathode formation of hydro.Ten Deroxide,
but not the oxygen of water. These findings are in agree-
Card 1/2 ment with the concept of A,N. Frumkin that hydrof-en neroxide

SOV-21-59-9-15/28
Investigation of Cathode Reduction of Oxygen to Hydrogen Peroxide on a
Coal-Nickel Electrode
formation is due to "newly"-adsorbed oxygen. There are
2 diagrams, 1 table and 10 references, 7 of which are Sov-
iet, 2 English and I American.
ASSOCIATION: Institut fizicheskoy khimii imeni L.V. Pisarzhevskogo
AN UkrSSR (Institute of Physical Chemistry im. L.V. Pisar
zhevskiy if the AS UkrSSR)
PRESENTED: By Member of the AS UkrSSR, A.I. Brodskiy
SUBMITTED: April 21, 1958
NOTE: Russian title and Russian names of individuals and insti-
tutions apnearirg in this article have been used in the
tranall te ra ti or
1. oxygen--Reduction 2. Hydrogen peroxide--Production
3. Electrolysis
Card 2/2

PHASE I BOOK EXPLOITATION SOVPi2l6
Saveahchanlya pa elektrokhImll. 4th, Moscow, 2956.
7. It
Trudy... ; jabomik] (Transactions of the Fourth Conference an Elect
rochemlW; Collection or Articles) Moscow. .1zd-vo AN SSZE.'
2959. V. Errata slip Inserted. 2.500 copies Printed.
3ys kb!
Sponsoring Ageneys Akadatmiya nauk SSSR. Otdalea. -Alchesklkh
nauk.
Editorial Boardi 4R.N. FrumikIn (Reap. Ed.) Academician. - O,A. - YiSta.
Professors S,X. Zhdanov (Reap. Secretary), B.X, tabanov, Pr*'~
fessor, S.I. 7-hdanov (Reap. Secretary); B.N. Kabanov. Prcfaasor~
Ya. X. Kolotyrkin, Doctor or chemical Scloncenj V.V. Losev, F.D.
LukOrtfiev. PrOfeascrS Z.A. SOlQv1y4vAj V.V. Szender. Frofessa~-.
and O.M. Plarianovich; Ed. of Publishing Housot N.G. Yagoro
Tech. Ed. t T.A. Pruvakova.
This book to Intended for chemical and electrical angi-
N,U:. Be., physicists, metallurgists and researchers Interested in
"~ Ous ASDOCtB Of jlaCtrOChtMjAtry.
OVERAGES The book contains 127 or the 138 reports presented At
the Fourth Conference
sent Of Chemical Sclon an Electrochemistry t:7 tha DOPAM-
Academy of Sciences, u ces and the Institute or Physical Chem,
3511. The C012&ctlon V*rt&lzl to diff.rn"t-Y.
branches Of electrochemical kinetics, double 2&y*r theories and
Salvanic processes In met:l elactrodepositon and Industrial *I
rolYals. Abridged discus ions Are given at the and of each djol"!_
*Ion. This MAJOrItY Of reports not Included hers have been
Published In Periodical literature. NO 'OrsOnAlItIO3 Are mentioned.
References are given At the and of moot of the articles.
Kraq_tl_-shCh1kov, A.I. (QOsuaarjtvcnnyy InAtItut AxOtnOY
Nitrogen Industry).,
pniajishlinnostl - State institute or the
rocheisical Reactions or Oxygen 2i
Elect
Oerbovich R A (Deceased) and..R.I. Xsg&ncvlch (M~scc`- State
-
Un v ' he -SO
r.liy5. Study or t Rachani-is Of -6 Anode Processes
-'bylC::binlng Electrochemical and Tagged-ktom Methods 277
Shlygin. A.1_ and G.A. BOgd&.q2t9tkIY_,(XO8cOw State University).
~jW-cj~-&-n3im of the -LTe-itro'thesitcal Oxidation of Some Compounds
on Platinum 2a2
X.a. alk~hchis&r&yta,yan. And A-P-Toelov
(Noskovskly khjmjk-o~tekhnologIche0k1y In3titut Lizeni
D.I. X~ndeleyeve-Moscow institute of Chemical Technology
Is@ Dj. Kend&leyev). r4chanlam of the ZIQctrVlYt1c
,n% 2ar7
Ox datlon or Acetone In Alkaline Solutions
j[homutov, N. yo, (Moscow Institute or Chemical Technology Iment
Rachanlem of Some irreversible Elect-
Card 12/34
292
roly,tic-OxidatiOn Reactions I
T.M r..01,-,-1nd 1,L.-Gankina (Inatitut
'C's *0 _Institute or physical Chemistry
Lnrk'4 S y kRiMll AM U R or iron. Magnesium,
echanIsm Or the Corrosion 29
AS UkrSSR),u.M eavy Oxygen Isotopes 9
Zinc and A inu. With the Ajq of H
Discussion 1A,K_QL-targ, A.?. TOmIlOv, P.D. Lukovt9tv. 302
A. T*dor&4z* and contributing authors)
PART IV. ELECTRODE PROCESSES IN PUSIOXS 309
yesin O.A (Ural 'fik1j pOjjt&khnjcheskiy Institut ;.Ural ?017-
---T;6jjiQ Inatitutd). Electrode Processes In Fu-ed Oxides 311
P Sternhaim.JL Franalml, And 0, N"t&Mlll
Plonts phenaWs'na In Fussc 323
~ Italy). Invest1kWflon Or Ov6rvOltft5s
$&Its
Card 23/ 34

5 (4), 18 (7) 05824
AUTHORS: `.'Fomenl~p A. S., Abramova, T. X., SOV/76-33-10-22/45
TITLE: An Investigation of Metal Corrosion With the Help of the Heavy
Oxygen Isotope. II. Moist Atmospheric Corrosion of Cadmium
PERIODICAL: Zhurnal fizicheskoy khimii, 1959, Vol 33, Nr 10, pp 2249 - 2252
(USSR)
ABSTRACT: In previous articles (Refs 1,2) the corrosion of iron and magne-
sium was investigated by means of the heavy oxygen isotope, and
it was shown that there was an electrochemical mechanism with
oxygen depolarization. In this article the authors investigated
the moist atmospheric corrosion of cadmium by the same method
and made experiments on the oxygen exchange of the corrosion
18
products of cadmium (Cd( OHY with H20 .The latter indicated
that no exchange took place within 60.hours (Table 1). Since in-
vestigations with the help of cadmium filings of the sort KD-O
failed, experiments were made by means of cadmium plating ap-
plied to a quartz tube (inner side). M4 NaCl solution served as
corrosion liquid which was poured into the tube in a deflnite
Card 1/3 quantity together with oxygen at atmospherto preasures The

05824
An Investigation of Metal Corrosion With the Help of SOT/76-33-10-22/45
the Heavy Oxygen Isotope. 11. Moist Atmospheric Corrosion of Cadmium
content of 018 in the resultant water and aseous oxygen was
determined by mass spectrometric analysis fRef 3). Experiments
were made with the aid of natural water in heavy oxygen atmos-
phere as well as with H 2018 in a common oxygen atmosphere. Re-
sults of measurement (Table 2) concerning the distribution of
018 among water, gaseoua oxygen and corrosion products indicate
that cadmium corrodes according to two parallel mechanismap ioeo
an electrochemical mechanism with oxygen depolar'ization (as has
already been observed by Peitknechto Wyler (Ref 5), y&- I- .
Kolotyrkin and L. A. Medvedeva-(Re'f 6)) and a chemical mechanism.
Investigations of copper corrosion have shown that the exchange
0:r CU oxygen with water is equilibrated after 48 hours. 1c-
(OH.)2
cordinglyp the afore-mentioned method cannot be applied here. In
conclusion, the authors thank Academician A. I. Brodakiy for his
help. There are 2 tables and 7-references, 6 of which are Soviet.
Card 2/3

05824
An Inveatigation of Metal Corrosion With the-Help of SOV/76-33-10-22/45
the j1eavy Oxygen Isotope* II. Moist Atmospheric Corrosion of Cadmium
ASSOCIATION: Akademiya nauk USSR,Institut fizioheakoy khimii im. L. V.
PinarzhevskogojKiyev (Academy of Sciences of the UkrSSR,
Institute of Physical Chemistry imeni L. V. Pisarzhevskiy,
Kiyev)
SUBMITTED; March 21,1958
Card 3/3

-/ A -A3 o o 67265
,5~ .2 6 OO(A)
1447-544 SOV/20-129-4-29/68
AUTHORS: Abramova, T. M., Ganki-na,, I. L., Fomenko., A. S.
TITLE: The Mechantem-of-Hydrogen-Peroxi-de-Porma+.ioir-in-the Corrosion
of Metals
PERIODICALt Doklady,Akadenli nsukABSR, 1959, Vol 129, Nr 4, pp 820-823
(USSR)
ABSTRACTs The authors,set themaelvea-the task of finding-an-anower to-the
following question: Is the,hydrogen:peroxide which--is formed
&a. azv-intermedia-te. in the.. corrosion.-nf - metals -caused -by- waAer
and: air.. forned-from. oxygen- of:-ths, air,- frow thart-of -water-, or
f rom.. the: oxygen. of- both? As,. according- tD.,..ref erence- 10, H202is
formed as an intermediate in the cathodic reduction of 0, and 0
is depolarized also in the corrosion of metals in air, the
formation of H 202 from the 0 in air was probable.' In that case
its isotopic composition would have to correapond to that of
gasepus 0. This was checked by the authors by means of 0 18
which was either added to the 0 blown through the solution cor-
is
Card 1/4 roding the metal, or was admixed to the solution as H 202 .The

67265 1.66
BOV/20-129-4-29
The Mechanism of Hydrogen Peroxide Pormation in the Corrosion of Metals
approach of the isotopic composition of the H2 02 formed to that
of gaseous 0 was actually observed by the authors In the oor-
rosion of Zn, Jig, Sn, Al, and Cd in aqueous solution of B202
and during the blowing through of 0. The experiments were made
in the dark at room temperature and took 1 - 24 hours. The
H202 content of the solution was then determined by means of
permanganate (in the case of Zn and Cd the insoluble peroxides
were dissolved by acidification) and the isotopic composition
of U202 s determined by means of a mass spectrometer. Table I
shows thla in the experiments with H 018 + 016 the 018 content
2 2 2
decreases in the H202 analyzed after the experiment is endedt
whereas it increases ir the experiments made with H 0 16 + 0 18
2 2 2
The H202 is thus produced from air-oxygen. A rough calculation
of the isotopic composition of H2 02 to be expected, carried out,
as an example, on Zn, showed a. difference of 13% if compared
Card 2/4

67265
SOV/20-129-4-29/60
The Mechani6m of lVdrogen Per.)xide Formation in the Corrosion of Metals
with the experimental result. Also the differences found in
experiments-with,other-metale are of the same order of magni-
t~de-. The following causes are assumed-to*be responBibles
1 Part-of the 11 ~02 formed is immediately again catalytically
decomposed by the metal. 2) The 0 liberated in this decomposi-
tion partly again enters into reaction accom-panied by the
formation of H2 02' Attempts at stabilizing the H202 formed by
additions of oxyquinoline, sodium pyrophosphate, sodium sili-
cate etc. were unsuccessful. The authors refer to published
data, according to which there is no exchange between the
oxygen of H 0 and of air under the prevailing experimental
2 2
conditions (Refs 14,15), which they were able to confirm b;y
control tests. Thus, as no side-reactions occur, the results
obtained by the authors prove that the H 202 is produced in the
corrosion of metals from the oxygen in the air. It is finally
mentioned that the authors thank A. I. Brodekiy, Academic~sn
of the AS UkrSSR, for supervising the investigations, and
Card 3/4 Engineer 1. U. Frotas for the mass-upectrometrical analysea

67265
SOV/20-129-4-29/68
The Mechanism of Hydrogen Peroxide Formation in the Corrosion of Metals
carried out. There are 1 table and 16 references, 3 of which
are Soviet.
ASSOCIATION: Institut fizicheskoy khimii im. L. V. Piaarzhevokogo Akademii
nauk U55H (Inatitute of Physioal Chemistry imeni L. V.
Pisarzhevskiy of the Academy of Sciences, UkrSSR)
PIIESE14TED: July 13, 1959, by A. N. Frumkin, Academician L11
SUBMITUD: July 13, 1959
Card 4/4

C)
MSE I BOOK EXPLOITATION scv/541o
Ta:;h!centakaya konferentsiya po mirnomu iapollzovanlyu atomnoy
cnergii, Tanhkent, 1959.
Trudy (r.-Iraiuactions of the Tazhkent Conference on the Peaceful
U-~ca of Atomic Energy) v. 2. Taalkcnt, lzd-~vo MIT UzS.'R, 1960.
449 p. Errata slip inserted, 1,500,copieu printed.
Sponsoring Agencyt Akadeaiya nauk Uzbekskoy SSR..
Reapons-Ibla Ed.: S. V. StarodiAbtzev, Academician, Academy of
Sciencei Uzbek SSR. Lditorinl Board: A. A. Abdull3yov, Can-
didate of Phy3ic5 and M'athP-ItI05j D. N. Abdur-2nulov, Doctor
of aledical Sciencea; U. A. Arifov, Kcademician, Academy of
9~,Icnce3 Uzbek SSR; A. A. Borodulina, Candidate of Biological
Siiencea; V. It. Iva3hev; G. S. lkramova; A. Ye. ILIv'; Yu,. "t.
Dobanov, Candidate of Physics and I'lathenatics; A. .1. Nilkolayov,
Candidate of Medical Sciences; D. Ili2hanov, Candidate of Chcziical
S:Iencea; A. S. Sadykov, Correnponding Memnber, Acadczy of Scicncae3
USSR, Academician, Academy of Sciences Uzbek SSR; iu. 11. Talanin,
4-
x

.,Tranvactions of the Ta3likent (Cont.) SOV151110
Candidate of Phypics and 11athematics; Ya. Kh. Turakulov, D octor
of BloloL~ical SrAences. Ed. ; R. 1. Kha-midov; Tech. rd. : A. G.
Babald,anova.
Fn1 CCIE 'ho p011-:ation In int(~nded for aoi,~ntiftc workera and
employA in entox-prl.,,~,n vjh-re ra-dionctIve !--oto!~cij
an"I nuclear radiation are wed fcr ro..iearch In
Icacal, and technological fields.
CCNURAGE: Thiz collection of 133 article5 rcpresentq thc. second
w.)1~--.c of the ~Iranaastiona of the Taz-hkcnt Conferc-nce on the
Dia-eful Uses of Atcnic Energy. ':be Individual artl~lez r~.,cal
with a w1de range of proble-ma in the field of niclea- radiation,
iw~ludtng: prothictlon and chemical analy:,1~3 cf ral'towtive
lantcpo3; invPatigation of the kinctlets of chernical r,~-ac-.tionrj
by meana' of isotc-pen; application of ~ipectral nnalysj-~. for the
manufacturing of radioactive prcparationn; radloastive Ti-athods
for determining the content of elements in the rcck.3, and an
anaiyals or methods for obtaining pure oubatancea. Cer-.ain
Card 2/20

%Transactions of the Ta:3hkcnt (cont.) SOV/5410
inatrvm~nta uacd, such as automatla reZulatora, flo,..zatnra,
level ~iuges, and high-sennitivity gat.-_a-relays, are do:;cribed.
No perz;*malitlos aro mentioned. Huforences folloa individual
articloA.
TABLE OF CONTMITS:
RADIOACTIVE IZOTOPM WD )MCLEAR RADIATION
lilt MIGIN M'' W110 AUD GEOLOOY
Lobanov, Yp. M. (Institut yadcrnoy Miki UzSSR - Inatitute of
Euclear Physics AS UzSSR]. Application of Radioactive Isotopes
and Nuclear Radiation in Uzbokintan
Takcar, and V. A. Yanuahlcovokiy (Inatitut fizilti All Latv
SSR - Institute of Physics AS Latvian SSR]. Problems of the
TypifIcation of Automatic-Control Apparatus Based on the Use of
Radioactlvq Isotopes
Card 3/20
7
9

A. 1., 1. F. Qrarerov, I. P. Franchuk, L. V. Sulima,
I. K~kht-cnko, V. A. Lunanok, A. S. Fomcnko, and A. M. Alek-
X-7. at
.1*;k,.1n [1n;:Utut fizieInczhoy 1,h1MT Tj M=31 - In. Itut of
xhv~it:al !~Mr_tstry AS 1153R). Inveatiagion of the Mechanizza of
07-1:1111.71ng Fviactlcn,:~ by the Isotopic Iliethod 327
f,avrul,htna., A. K. (In5titut geolthinii i analiticheolcoy IC-,imli

- p AN oTIR - Institute of Gaochertlatzy and
V-~rnalikog U -
A-Inlyti..,al' i~rcml V. 1. Vorvaiakly AS U33111. Methods
nf Fad-looke-iii-itry and the rieldo of Its Application 334
E. A., K. V. Cbmutov. and P. P. flazarov. (Inati-
,ut,~ if Physical Chvmlitry AS Study of the Ada-irption
of Alkaline and Rare-Earth Elemants on Black Earth by the
Olrv~,rr At,,m Tlethrd 341
A. 1. [Tad7,h1.1cmkiy gonudar3tvennyy univerlitet im.
1. ~'-nlna--Tad7hik State Univeraity imeni V. I. Lenin]. Co-
_

r,m~,Ipit
atica of Small quantities of Various Cations and Anions
~
,with Nstal Hydroxldo3 349
Ammelogova, N. 1. ERadiyevyy institut im. V. 0. Mlopina
Card 16/2o
VgW ~4,

S/CZ-1/62"000/001/004/067
B156/B101
AUTHORSs Brodakiy, A, I, Gragerov, I. P.# Franchuk, I. F.# Sulima, L,V.0
Xlkh on o Lunonok, V. A., Fomanko, A. S.,
Aloksankin, U
TITLEs L:echanicm of oxidation reactions invoutigated by the isotopic
mothod
PERIODICILt Ra.-erativnyy zhurnal. Khimiya, no. Iv 1962, 60, abstract
1114~9 (Tr. Tashkentak. konforentaii po mirn. iopollzovaniyu
;.;,omn. onergii, v. 2. Tashkent, AN UzSSRI 1960, 527-334)
T=XT: A review of work done by the authors on studying the mechanism of
certain oxidation reactions using icotopest the oxidation of organic
compounds with chromyl chloride, the mechanism of anthranil roGrouping, the
process of oxidation of aniline, o-aniaidine and p-nitroaniline with Caro
acid. The mechanism whereby hydrogen peroxide and certain persulfate-type
inorganic peroxide compounds are Xormed and converted is oxaminedi so also
are the kinetics of isotopic exchange in substituted banzoic acids,
Card 1/2

S/08 V621000100110041067
Uechaniam of oxidation reactions B156/BIOI
benzaldehydes, alcohols, naphthalenes and nitro compounds with H 0
18 references. LAbatracterla notes Complete tranulation.] 2
Card 2/2

33490
S/195/61/002/005/015/027
A 0 El1l/E485
AUTHORS: Pomenko Gankina, I.L., Avramova, T.M,
TITLEz Study of the mechanism of the decomposition of
hydrogen peroxide on activated charcoal by the
isotope method-
PERIODICAL9 Kinetika i kataliz, v.2, no.5, 1961, 732-736
TEXT: The decomposition of hydk-ogen peroxide on activat6d
charcoal was studied by many authors but their assumptions on
the mechanism of this process are in contradiction, In the
present work the mechanism was studied using 018 introduced into
the charcoal oxides (with H202 of the natural isotope composition)
or into the H202 (with ordinary oxygen charcoal), The isotope
compositions of the charcoal oxides-and of gas ous oxygen were
determined to evaluate the mechanism, The 019-contain I'll, charcoal
was prepared by grinding the commercial charcoal type (BAU),
de-ashing with acid, washing, drying and activating in
C02 at 800*C for 6 hours and 1000% for 3 hours,, after this, the
material was treated'with hydrogen at 1000"C (which was then
pumped off at 600 to 650*C), cooled in oxygen-free nitrogen.
treated at room temperature with 018-enriched gaseous oxygen'And
Card 1/4

33490
S/195/61/002/005/015/027
Study of the mechanism ... Elil/E485
stored in heavy-oxygen water vapour. The procedure for preparing
and storing ordinary oxygen-charcoal was identical but ordinary
oxygen.and water vapour were used. Special experiments were
carried out iii which charcoal containing ordinary oxygen was
treated.with heavy-oxygen water vapour whose f nal isotope content
was then determined, or charcoal containing 01~ was treated with
ordinary water, filtered off and its isotope composition
determined by mass spectrometry on the C02 obtained by de-gassing
at 300 to 5500C. For H202, mass spectrometric isotope analysis
was carried out on the oxygen evolved when the peroxide was
decomposed with potassium permanganate: and for water, on C02 VIr
after exchange with the water, Results showed that there is no
exchange of the oxygen of the basic oxides with waier. For -the
main H202 decomposition experiments in a quartz tube ~onta,ining
1 to 4 g of degassed charcoal was put in a furnace. One end of'
the tube was connected to a trap for freezing out the desorbed
gases and to a vacuum installation; the other to a trap !;ontaining
the required quantity of peroxide, freed from dissolved oxygen.
The tube was periodiLally rotated~ After the required',;imeg the
Card 2/ 4

33490
Study of the mechanism
S/195/61/002/005/015/027
Eill/E485
water and undecomposed peroxide was distilled and the --harcoal
degassed as before,, The C02 fraction, collected at 300 to 550'C~
was analysed for 018. In some experiments the isotope composition
of the oxides was determined from the water obtained during their
treatment with hydrogen. Mass spectrometry revealed carbon
dioxide as well as oxygen in the gaseous decomposition products.
In agreement with the views of G.Brinkmann (Ref.6f~ Ang, Chem.,
v.61, 1949, 378) the results suggest that a double decomposition
type of reaction occurs between the basic OH groups in the charcoal
surface and H02 ions of the peroxide
C+] OH- + HOOH -* C] HOO- + H20
followed by C+JHOO- + H00H-4-C+j0H- + H,O + 02Q
The origin Of C02 in the decomposition of H202 on charcoal is not
clear since the simultaneous presence of H20 and C02
, in view of
the exchange between them, alters the primary CO composition.
The observed change in the isotope composition oi oxides on
charcoal cannot be attributed to further oxidation of the coal to
give oxygen compounds, differing from OH groups, whose high-
Card 3/4

33490
S/195/61/002/005/015/027
Study of the mechanism El1l/E485
temperature decomposition could give a further quantity Of C02
with the peroxide Isotope composition. No free radicals on the
charcoal surface were found by the electron paramagnetic resonance
method and this is contrary to the chain mechanism propotfed by
various authors (e.g. Ref.8s V.A.Garten, E.Epinger, D.E.Weiss...
Austr. J. Appl. Sci., v-7, 1956, i4q)~ Academician (AS UkzSSR)
A.I.Brodskiy helped in the work. There are 2 tables and
12 referencess 2 Soviet-bloc and 10 non-Soviet-bloc, The foj-r
most recent references to English language publicationa read as
follows! RefAx A.King, J. Chem. Soc., 1936, 1688~
Ref.5: E.C.Larsen, J.H.Walton, Jo Phys. Chem., v.44, 1940, 70,~
Ref.10s B.R.Puri, L.A.Scharma, D.D.Singh, Ind. Eng. Chem,., ';r.50,
1958, 1075; J. Ind. Chem. Soc., V-35, 1958, 765!
Ref.1.2s M.Cohn, H,C.Urey, J. Amer. Chem. Soc., v.60, 195811, 679,.
ASSOCIATION: Institut fizicheskoy khimii im, L.V.Pisarzhevakogo
AN UkrSSR Kiyev (Institute of Physical. Chemistry
im, L,V.Pisarzhe-vskiy AS UkrSSR, Kiyior)
Card 4/4

FOMENKO AO-So- ABRAMOVA, T.M.; GANKrNA, I.L.
Decomposition of hydrogen permcida in the presence of,$
potassium iodate, bromate, and chlorate. Ukr. kbim. zhur#
U no.1:14-17 f62. (tr MA 16: 8)
1. Institut fizichaskoy- khimii im. L.V. Pisarzhevskogo
AN UkrSSR,

vrtm u xIda a
a
f
-t x
Card 1/2 - --- ---

Nt~ AT5C,)2565
71r,"'r ~)TO( PSS bV
LeQ, ii dild in Lll~ r
2
-t 7
a e TT,
v a I ~-ia j~,
lzlcIwakoly -4-11 Lm. T 7 ~z T
gritute of Physical Cbmistry, -Alt UkrSSR); FAyevsk-ly filial Vffesolnmnegor-nauchno-
,T~ogo fnqt1tuta iskusatvenrogo volokna Me- Brnrvrb, Al I -tnio,n
~ile.-arrh Institute of Synthetir F~-,~r~
-7:7 D 22J-jn6-L
~fT, Np
Pg, Soy 002 OTHER: 003
C~

ACCESSION NR:
AUTHOR: Fomenko
Ye. G.
;-TITIE: Oxidati,
in the radiolysi elf6 4
SOURCE: Ukrains
TOPIC TAGS: po W-1
radical formati
h,
ydroperoxide fo
:ABSTRACT: The f M Fw~m
60, their functi
.ing action of an
ance spectra of
60) and the effe -sill-
Changes in those
Ii radiolysis In
Car,l
_J
----MEMMMM

,ACCESSION KR: AP4033700
3~ C02. The amount of terminal amino groups almost doubled on irradiation; with a 1
e
22 mrad done this correspond d to the rupture of 0 or the C-H bonds in the polymer$
'The viscosity of the polyme ri also changes on irradiation--with 8 mrad irradiation
;~the viscosity decreased during the first 30 hours, then increased, appaxeatl,'Y due
J,to the formation of cross-linked structures. The accumulation of hydroperoxide in
Ipolyeaprolactam on gamma-irradiation in oxygen, the effect of'radiation dose, the.
!;changes in terminal amirio and c&rbo.Vl groups and the viscosity of the polymer weret
I
;exami-ned. H :CO ratio in these products was 2:1; terminal NH2 and C001i groups
2
increased at doses below 15 mrad, ana decreased above that. These data agree with
!.changes in the IR spectra of the irradiated polycaprolactam. It is concluded that
'the R02 kadical formed by radiation oxidation is converted to the hydroperoxide
.and carbonyl-containing compounds by a par&Uel route* Addition of 0.5-3% antioxi-
'dant di- p-naphthyl-p-phenylenediamine to the polymer'does not affect the form of
lithe EPR spectra or concentration of free radicals formed by gamma-irracliation;
I
j,but this additive significantly lovers the amount of hydroperoxide and carbonyl-
:containing compounds formed by radiation oxidation. "N. S. Oleynik and M. T. Koz-
41 vork.'P'... "The authors thank AN USSR academiciani
J.bura took part in the experiment
1. Brodsko,for help la tba vork md participation, in its evaluation,, and also
r
2/3

ACCESSION IIR: AP4033TOO
~.coworkera in the electron paramagnetic resonance laboratory for obtaining EPR
;~spectra and bely in ey&2uating the spectral data." Orig. art. has: 6 figures and
1 table.
ASSOGIATIM. Institut fizichealwy Ithl-Ii im. L. V. Pisarzhevskogo AN USSR,
(In6titute of Pbysical Chemistry) *.Kiyevskiy filial Vsesoyuznogo NXI iskusat."rennov
I Voloknap (Kiev Branch of the All UAou NXI of Synthetic Fibers)
sum=: - I%&y63 ENCL: 00
SM CCDZj OCv, NP. .."No IW Owl.. 010
3/3
w--iR M

-ACCESSION NR: AF040955 a/0020/64/l56/O05/li47/1U9
'or
C r spWding llmemb*r AN SSSR)v
Abr;A
N
Fomffl*oj_A,4~Z..;
AUMORs Brodakiy A.
T- M.; Furman, Ye. G
Darlyeve., E# P.; kukhtenkd,-,f._i.; Galinap- As A.
TITIEt EFR spectra of radicals formhd.during gamma irradiation of polyamides
SOURM AN =Re Doklady*o' v." 156, no. 5,, 1964,, 31474149
TOPIC TAGSt electron paramagnetic resonance, ;FR spectra,
EPR radical spectral, polyamide, polyamide gamma
irradiation,,-hwamethylene adipamide, poly-dmaga-undecane amidep
deuterium, caproamide
ABSTRACT: The authors ponducted this 'analysis because the literary data
pertaining to the structure of radicals formed under the effects of irradiation
are contradictory. The Eni spectra Iof poiy-6-caproamide were recorded. The
irradiation and EFR spectra recording,:.was.,taken at room tempera.ture..The EFR
spectrum of the gamma-irradiated poly%.4&caproamido is an incompletely resolved
quintet Lz 2 s 2 s 2 3 1 with an average width of 74 oersteds between the
'extreme -xi- a i The cleavage between the extrewe pairs of lines 14 and 4-5 is 21
oerstedse. This is 1*55~tix*-less than,the cleovage between ~he lbas.2-4, This
spectrum corresponds to a'-GH -G0-NH-,0&0H - radical in which the unipaired
2'. - ' .* ~ - . . 1 1. 1 L
2':
"rd 1b

~ACCESSION NR: AKG40955'
.:electron interacts witWon4luAydrogon and two Aq#valent p'-hydrogbns. The
.i-CO-GD -(GH ) -CD _NH_ "mole with deuterium in'the two Cfl~ gtb neighboring the
UPS
2 2 3 2
--*carbo.nyl and NH groups yielqo a fully resolved I : 2 s 1-triplbt with a splitting
of a 28 oersteds, an width ofp~56 oersteds b6tweeii the.e3ctreme
.4,'wit~ a general
maxiin 0. This spectrum corrdsponds, to -a _0240-NH-CD-02. rddical. The spectra.
of irradiated polyamides" 00fitaining. 8 and - 10 CH groups in th6 mon6mer twit show
incompletely split 1 : 3 s 1 quadruplQta wi h identical 211 oersted cleavages.
The spectrum for an irrad:rated completeli-crysialline hexamethylerfe adipamide
:CobH-(CH2 is a satisfactorily resolved 1 :-2 s 2 : 2.,s 1
~quintet with a genera Widt of 84 persteds between the extreme maxim8 and with
a,:1: 21 oersteds and a./spa 2.0. 4 corresponds to a radical in which the hydrogen
isp its orf from the Ch group in the# -position to the NH, just as in the poly-,e-
caproamide radical. Tge irradiated*t-caprolacUm monomer produces a poorly
resolved spectrum. When deuterium is introduced into the methylene groups of the
nondeuterated and deuteratdd caprolactam in the NH group a sharp changv~in the
spectrum shape can be observed, The spectrum of - the 00-CD H CD ND,*i
2(G &.2j~ ampl6 is
not as well resolved probably on account of the participation o group
hydrogen -in the cleavage, This spectrum can evidently also bol examined as a
quadruplet with intensity ratio of I I I j I t I Orig, art4 has 1 3 figures.
Card. 2/3..

IM, M
5

'NO"M

GFLLERI B.A.; NEYMARK, I~Ye,; RUBANIK, M.Ya.; GRAGEROV, I.P.; POLYAKOVj
M.V.; IMSOV, M.T.; DAINp B,Ya.; REKASHEVA, AJ., SMUESKJOy
D.N.; LUNENOKP V.A.; ROYTFRI.V.A.; SULIMA, L.V.j ~0-*-
1 ".1,
.. ;*/ Aleksandr Illich Brodskii, 1695- ; on his seventieth birthday.
Zhur. flz, khim# 39 no.6-1540-1541 Je 165.
(MIRA 18:11)

J-
L 24491-66 Epr (n) -2/EWT (Gi/9W(J)/T/9VA (h)/EWA (1) GOIRMIWWIJW-
ACC NRt AP6 980 SOURCE COD91
UR/0190/46/008/002/0261/0266!
AUTHORSt Fomenkoj At 841 Abruova, To Mo Der"yeval E, P.; Galinap A. A#; Furman,,
Ye. 0
ORG: Institute of LMMsical Chemistr7_ im. L. V. Piearzhev2~~ (Institut. fizicheskoy
khimii)
TITLE: Mechanism of action of di-A -naph!!Wl-p:phenylenediamine1 dur4m radiation
oxidation of polyeaproaaide
SOURCE: Vysokomolekalyarvjye soyedineniyal v. 8y no. 2j 1966, 261-266
TOPIC TAGS: polyamide, free radi~alp oxidation kinetics
ABSTRACT: The effect of di-,A -naphthyl-p-pherqlenediamine (I) upon the kinetics of
accumulation of free radicals formed during the process of radiation-induced
decomposition of-polycaproamide (H) was invootigatedp and the yield of gaseous and
oxygen-contaiAiing products of radiation-induced oxidation of the polymer was
determined. The changes of the content of terminal NH2 groups, viscosity, and.IH
spectra occurring in II stabilized with I during the riAiation-induced oxidati6n
were also studied. The methodep involving MR, chromatographic, chemicalf and IR
pe;q 1/2 U.Dct 678-01254+678-6751

L 24491-66
ACC XR: AP6006980
spectroscopic studies, were previously described by A. S. Pomenko, T. M. Abramove
E. P. Dar"yeva, A. A. Galina, and Ye. G. Furman (Ukr. khimich. zh.t 30t 376P 1964501
It was established that I has no effect upon breaking of the C-Hj C-Ns and -C-
bonds during radiolyois of Up but does affect C-N and C-00 bonds during radiation
oxidation of IL The amount of peroxy carbonyl and carboxyl compounds formed
during radiation oxidation of II stabilized with I is considerably lowered as
compared with the untreated IL A possible mechanism for the inhibiting action of
I is offered. Orig. art. hast i table,-6 figures, and 4 equations.
SUB CODEt 07, 11/ SUBM DATEs OX=65/ OUG REFt 007
2 2
';M
'xd MV,
01,

A) SOURCE CODE: UR/0190/66/008/004/0770/0770
AUTHOR:, Fomenko, A. S.. Krasnov, Ye. P.; Abramova, T. M.; Darlyeva, E. P.;
Furman, Ye. G.;_G&1Tn_a, A. A.-
ORG: none
TITLE: Radiation resistance of isomeric aromatic polyamides
SOURCE: Vysokomolekulyarnyye soyedineniya, v. 8, no. 4, 1966, 770
TOPIC TAGS: radiation stability, aromatic polyamide, aliphatic polyamide, gamma
irradiation, radiation resistance
ABSTRACT: The integral dose required for the accumulation of 1.1014 radicals in
y-irradiation of aromatic polyamides is shown to be one order higher than for ali-
phatic polyamides. The radiation yields of hydrogen during polymer irradiation
are two orders lower than for aliphatic polyamides. There were no changes in IR-
spectra and thermomechanical properties of samples y-irradiated in vacuo and in the.1
presence of oxygen. This proves the high radiation stability of aromatic polyamides
(Based on author's abstract.) (AM]
SUB CODE:,,W, ll/ SUBM DATE: 22Nov65/ ORIG REF: 002

)`T-- ---Ijp 1, C I -RM
/EWF GG/
(A)
NRx AP6019061
SOURCE CODE: UR/0073/66/032/006/0549/0554
AUTHOR: Brodskly, A. L: Fomanko, A. S.; Darlyeva, E. P.; Abramovap T. M.; CAU
A. A.; Furmang Ye. Go
ORG: Institute of Physical Chemistry Im. L. V. PisarzheysUl, AN UkrSM(InStItUt
fizicheskoy khImII AN UkrSSR) ~4
TITIZ: Gas evolution during the radiative-oxidative degradation of poly-6-capro
SOURCE: Ukrainskly khtmichoskiy zhurnal, Y. 32, no. 6, 1966, 549-554
TOPIC TAGS: polyamide, oxidative degradation, hydrogen, carbon monoxideq gamma radi-
ation, radiation affect 11
ABSTRACT: Chromatographic analysis was used to find the radiation Y~A~elds of hverogen
and carbon monoxide, the main gaseous products of the radlolys_i!~and radiative oxi-
dation of poly-c-caproamide. GH2 Is about I mole/100 eV fol both processess and does
not change as the do&* rate increases from 0.4 to 5.0 x 1010 eV/g min* G Is equal
to 0.3 mole/100 eV for radiolysis and to 0.6 mole/100 eV for radiative oxfdoation, and
rises to 0.9 mole/100 eV as the dose rate Increases from 0.4 to 5.0 x 1018 aV/g min.
It was found that the combined action of gamma radiation and increased temperature
approximately doubles the values of GH2 and GCO In both the radiolysis and radiative
oxidation of poly-i-caproamildo In the case of a low done rate of gamma radiation, and
that the effect of this combined action an G H2 and GCO diminish" with increasing
Card
W_

L -40099--66
ACC NR. Ap6019661
dose rate. It Is shown that the stabilization of poly- I -c&proamide by the addition
of the antioxidant dl-iS-n4iphthyl-p-phanylonedlemine does not change Gil during
v&diolysis and radiative oxidationp but markedly reduces the amount of L~bon am-
oxide formed during radiative oxidation. Orig. art. has& 6 figuroa and 3 tables.
SUB CODFC: 07/ SUMN IDATM. 31Jan64/ ORIG WS 006
Card 2/2
1775
0, R
o-gA M"m U No= i H