SCIENTIFIC ABSTRACT Z.A. DALIMOV - M.A. DALIN

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000509530005-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 12, 2001
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

DALIMOV, Ziyad Aminovich
(Hydroaeroioatherapy for hypertensign] Gidroaaroionoterapiia
gipertonichaskoi bolezni. Tashkent, Medgiz, UzSSR, 1959.
151 P. (MIRA 13:9)
(HIPERTBNSICH) (AIR. IONIZED)

1, ~ DALIMOV, Z.A. f kand.med.nauic; ADKIMKOVA, O.D. , klinichoskiy ordinator
Treatment of hypertension with
gos. nauch.-isoaj /,Inst. kur.
(HYPERTENSION)
Tashkent mineral water. Trudy Uz.
fizioterno.15;183-192 159.
(MIRA li.,: 9)
(MDJL~A-L WATE,-S)

OBROSOV, A.N., otv. red.; MUMINOV, U.K., zam. otv. rod.; BULAMV,
P.K., red., VASIL'YEV, L.L., red.; DALIMOV Z A , red.;
KATSENOVICHY R.A., red.; KETKO, M. ., rod.; Y-INKH, A.A.,
red.; CHERNYAVSKIY, Ye.A., prof., red.; SHRAMKOVA, G.A., red.;
TSAY, A.A., tekhn. red.
(Aerolonization and hydroaeroionization in medicine] Aeroioni-
zatsiipL i'didroaaroionizatslia v meditsine; materialy. Red.
kollegiia: A.N.Obrosov i dr. Tashkent, Medgiz, 1962. 305 p.
(MIRA 16:6)
1. Vaesoyuznaya konferent5iya po aero- i.gidroaeroionizatsii,
Tashkent, 1960. 2. TSentrallnyy institut kurortologii i fizioterapii,
Moskva (for Obrosov). 3. Kafedra fiziologii cheloveka i zhivotnykh
Leningradskogo gosudarstvennogo universiteta (for Vasillyev). 4. Uz-
bekskiy gosudarstvennyy nauchno-issledovatellskiy institut kurortolo-
gii I fizioterapii im.N.A.Semashko (for Katsonovich). 5. Gospitsal-
naya terapevtichaskaya klinika Leningradskogo gosudarstvannogo me--
ditsinskogo instituta im. I.P.Pavlova (for Bulatov).
(AIR, IONIZED-THERAPEUTIC USE)

,l'l..-i::, .".. -
it Laijoratru-,, ):,. -- . ',*,"P - ". ~ ~ f I ~ -, , -- - ~ c-, I,- f- -
;.:, , - -li--L, -
b -I - -
19"c' '-9
Dr. 1'ec"-i. c i .
if- - A
L:-'7 (j -U 7nst. for i-lech. alid ',",ectr.)

DALIN, A. D. and P. V. PAVLOV.
Rotatsionnye gruntoobrabatyvaiushchic i ze-aerclnye mac-iny. Xaskvz,
Mashgizp 1950. 257 p. illus.
Bibliography: p. 255456.
Dredging and mxcavatinG rotary -ac-ines.
DLC: TA.735.D3
SO: Manufacturing and Mechanical 7-ngi.,-.- ering in the Soviet UnIon, Library
of Congress, 1953.

DALIN, A.l.SERDECHNYY, A.
Agricultural YAchinery
New machines for the improvement of meadows and pastures. Kolkh. proizv. 12, No. 2, 1952.
2
9. nnLL1x List of Russian Accessions, Library of Congress, June -19W. Unclassified.

ns, t
el

DALIN, A.D., doktor tekhn.nauk
'-~ 11, " -
Combine for soil cultivation and saving. Makh. i olsk. sots.
sellkhos. 16 no.4:22-26 '58. (MIEIA lltlO)
1. Tessoyusmy nauchno-issledovatel'skiy, institut kormov imeni
V.R. Vill7amsa.
(Agricultural machinery)

_BALIW,_Aj),, 4oktor sallskokhoz7a7stvannykh nauk; OSIRAEDV, I.G., kand.
oel'qkokhozya7stvennjrkh nauk-, KAI?AYTA=rY, H.S.
Now tillage practices for raising corn and root crops outside
the Chernozem belt. Dok1. eked. sellkhoz. 21 no.9:7-13 '58.
(MIRA 11;10)
I.Vsesoyuznyy nauchno-issledovatel'skiy, Inatitut kormov imeni
V.R. Villyamea. Predstavlena, otdelenivem zemledeliya Vsesoyuz-
noy akademii sel'skokhozyaystvennykh nauk imeni V.I. Lenina.
(Corn (Maize)) (Root-crops) (Tillage)

doktor tr)l-hn.nauk: C;0U)MINKOV, A.D., V&nd.uol'akoVhor:.nuuk;
0811kViKOV, I.G., kun(l.unllnl.-okhoz.nauk; KARMAE'SKIY, 11.5,
Now motbodi) of miltivating i3oll for cern and root crops in the
non-Cherno;:em zona. Dnkl.Akad.snl'khoz. 24 nn.8:45-48
159. (MIRA 111:11)
1. Vsef3o.-uzny7 nauchro-issledovatel'skiy institut kormov imeni
V.H.Villyamsa. Predsitavlona akademikom A.N.Karpnr~-.o.
(Tilliti-ti) (C'n r n 0-~i 1 z o ) )Olont vropfl

DALIN, A. D.
"New Methcd:-, of Grasslsnd Trq)rrjv(~m(,nt.-
A 1, 1. -Un i on Sc e nt J f J, c Re s ca re h I n s t. of Fod (3 c r 1 m.. V. 1). V I I '-,fn m,-, , 1, -,! n T:rj , ;'t---)s c r~! I Ob I c~ s t '.
report to be presented at the 6th Intl Grassland Congress, neading, En;Tllnnd, 11-21 Iru-; 160

DALIN, A. M.
UM/ftgInSwjM 00t 1947
Condensation produots
rmpuw yAohlnwy
"Autewtic Pumping Out of Condensate," A. M. Dalin,
TepIctlektroProyekti, 3 PP
"Promyshlermaya.ftargetiks" No 10
PA
Won iliustrated artlola do ibing a system of P=pIng
o oudeneate *. out of - a ondenser mts by means a a f lost -
Ing relay with a Fisher - float chmaber. This to also
a gua-Antrodwtion to an autcWtic method of p=pftg
aoudenzate out br momm of eleatrolyte relayes'
23T63

Rp As He
DALIk, A. M. -4he acaumlation and recovery of condensed water. mookya, Oos. energ. isd-TO,
1949. 239 P. (50-21358)
TH7575-D3

uee of metaIg !a ~h- ~-.
V, ia.t nc.4:1-6 Ap 16C. (:~ 1~~ "- : - )
(H6ating pipea)

DALIN, A.M., inzh.
Approximation method for determining diameters, lengths, metal
exponditures, and cal,ital c--jedditurac o-.-' -:,!:udcipal
It U 14:9)
networks. 31ek. st.L. 31 no,8s33-3qAg 160, (;.E
(11.3ating from cstntral stations)

~ , : I .* . "! . , '. f ~,, - .
". f , ,:;- ~a 11 ~:! 1. ~ 0. - ~ i, ~-- ; - 7 -. - -, -. i ~ ! . - - '. , -~ - . .- I. J3 1 rl
, - , I T I
U.-Ar-t 1411 1 1, 2 C~i i rl. . V .. . t .. ;- 1 . ;. .- . ~':
I (,-',. - - - )
.i - n , 7. 11

~N
J Al
IfLI~*C
.
..5 1 1. cat" at
.
f -P
#a
"
asticklift A-*
c o!
I
~

ROPU411013 Of AICOW f1`0111 01111084 obtained from cracked gas. If. A. DAlus'an't
V
M
Outuirys
AwrNWAIWaskfif N
laaw
l
Kh
19
fl
11
N
.
.
.
i
e
ituo
osye
,
o. ;1. 14; 75 In a
,
y
wfill -1111411u(8
%-Alf l4ant for larr
FlOll cil
l,
)g
'ird f
"m th
I

00 f .
.
e
'l
f
. om-titlelf,il
i
l
fly (left
1414k and Itestwhow%kays (C
A
27
2M)
h
k
l .00

j ,
.
.
e CI,W
ll
,
, %
gd~ 164- jlA%.A%
thtough Cact.
a cbarcuaill stvauttler
a scrtsh1wr chAr
rd with
,j&
t
O

a ,
,
y
j
uir it "a
s
q
Otj-hrd with HS(N. through a hydfolywr for the firpe. of &1c. frLan the alkylvullurse acid.
'
I
lle fraptirs of &k. ps" through a cuodenwr into the receiver. rectifier. vitnidsiser and
tit storage
'r
The sic
obtained is A% Th
i
ld
d f
5
4
i
5
.
.
-
e
Var
e y
e
tom
.1
-2
~ 1wriatiit of
fi .00

of r i
qpftopottkin tit vatioui pan% of the equipment and un4ati%lavoty rrgent-rafewn pro-
tv lute u%vtJ in nvoriffilloning the charcoal. ea if. fare dt-4cril"I in t1cf,ail As well
'0 .So
00 a a%
w app. autl vark)uv rrcmnm-J.fL-- A. A. l1whifinik
06 j 41

Go
Go x
00 s 0

0 .00
'So*

9 0
t
Ar. t .
0 1 r ARCIALLUR-GICAL 1.11111AILAII CL-AISWKATOOM
- O-V ;0
411044 -1
-T-
-
- a ANa
a T I a 10 1

U IS 10 ##o IIt ,
I "
It ; S
a
a 0 it St At it
4 1 14

0 0 0 0 0 6 0 0 0 0014
.0 0 0 0 f 0 0 a 0 0 0 0
0 a 0 0 0 0 0 a 0 6 0 0 0 0 6 4 0 0 *0 0 0 0 6 0 9

-
-n-M

0
0

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0 0 4 * G 1* 0 0 0 6 0
O
rOse
I K 11 It 11 14 Is 1. It Is It a D )d A 16 11 A A L It L; 13 M 9 Is L' X 19 41 Al it
A A f. Al f -6 1 'L L it -M F 9 R 1-1 v As CC Cc (t -1
A

16, method of prepusticitt of ethyl alcohol from pt. -90
tro'lennog"Se"' "l--"L)Mb"4nJ%'-S-GUIU3fYA. 1'rilmr. -90
/it AU-Uxiinu Jfeettoll Alf-Votion S.,i.
,
J"fireirwas 11'
rk
11
h
-* 0
e
eis,
a
m, 19m, Gojtj. T
,kh.
(,,rxo-Gn4, Nell. Isdat. 1934. No. 3. A2.5,46. & (,_ .4. -.0
28. 744MVII.- Tke ea"t" betwerx dithwexe and jkV.-Se
'
a0. -The highest cianvii. 4 C.It.
wu a
tower with it roosting centrid Lhalt "utpled with Imiddles
and perforated disks. The &Wt tutiatedat f~RIrevuhations
14Y uain., the C,11, contEnt of the ps amounted to L15%.
-
the t
tu
I)
NP
d
1

-
e
p. was
,
an
the llrS(X used had a sp. or. "I =00

00 J1, 4-1 DW. These condilions a,sured a thorough "1111"t

f
id
d

a
0 o
ac
an
Ia.%; lower and hixlkr %peciN of the ruuw .
proluced lower yields. T14 hydr4pis of ethyi jadfaric 0
attid.-Furtty-oriven ff. of the ethyl sulfuric acid iiijitt.

0
and 53 1. HaO were placed into 2 different futuscls con.
d 0
invir
to orse cotiortion tube wh~ic a piurtud iniiit. of rise

4111 0 :4 liquids, look place. Thi, usixt. Imsed then into a %vrtival

; zi t flinder cLu
led with glass tk-" and hca(ed by an irlec.

1
!K r-isustice. The sepd. ll&vO4 was continuously siphuntd
off at the bottom of thistrylindvir
while the a1c
%a
d

2
00 f .
,
pocs an
stearn moved upwardly alwirbin; addid. of the latt,,f
",
ti
b
f 400
t
ons. to
e
1
inally condenscd in a Uchipt condcu%ci, 1*0
064 yields 12A X. C,11,011. A. A. li,xhtlinxk
49

A S 0 S L A ajTAtLLrGKAL LITERAT641t CIISSWK-M-
- -- - - - - - -
t

It .%,-
Iti
R *9 K U

0 0 a 9 W W
9006000*600000 4 0 0 If - - "; .0 0 6 a 0 0 0 0 0 0
I a 1 4 1 1 9 0 11 ii is m It is I? to is aL:l a 4 Is JS Ago ff Is A an 11 U UIs a As V it Is it 41 48 61 411,119
A I c A IL-1 -A..AL-" -L a _4 it a a A I v I I I I~ it AA a cc A I I a -a-
.0 ,c' , .0t.1 it .,Orr to
10".101.11
Refininill artionatic cointiounds lobtsoln9d train petnileum
Coono vii, M. A I valin wid V kov& A ...
00 if-fm fujil. Sit 0. M m
00 lu lbir venning Clot. slid MiNle and cjl'%t~' *Ifli
11'so. in a flofixotitill rvIlndrf rquil.1-1 with
940 attached to it shaft filtsiculot of (looll I"WA) r. it. co.' the
-hrti and to rcconovel (4
00 'Wid shocild bt ititputoml Ito haft ago
0. -ludir Is eawalial af(rr rik-It irrartric-ot. I'llit 11101libil
It, vra file arid convorripikat it. wa.. .16ti4m i,srv no*
00 j, rr%ulls were obtimined in a sili,w phaw i-tiorat wlikh
wato roccird by Imusing lbir cru'le C.11, thfulljoh two
t- in vol~-im, and tmatjjijc it with it 75 141" too
a wid in the firitt. &nil a V517, arid tit the x"mil to-O
Ih sl'~ acid
total awhi cahd. m a P,
A A It-ii-I'll it
a I a t k A 81TALLUtifil(Al. LifORAVU41 CLASPO'NATION It I-
It Is oo;-"; --JW
I $stis 0 1 so to I a
U 19 AV
its 11,11,100411 fill flit Of a is it K to PA
I I * 9 q 0 4 : : : : v 0 0 0 9 9 0 0 0 q 0
4 0 0

0 0 0 *1-
000000000000000*0044
" a
03 1 1 )4s# is V snail JIM us amJ11X*o 0"40 alto
'i , al
AL-C IF it I- - " $- 11- 1..
00 A $.%Q-k*Afs* 0
"ACOA .......
0
00
00 C
Pf"W" of I" do" ftom OtItykee I pumlw
00 (na pst, We Mon. VU. V.S.OutuiryttandIA.A.
0 ~Woouskfj Nfftyawf Kkvystvfv ins,
P" I
d. C. A - 30, 56M.-In a Systematic in.
:0 of the Stwi* F It WGA to"d that WWx%
;Zt variety of catAylat trW aWy Fe &M Ag citta-
FS give a coo. yield of Rto" from CO. "A R00A. -*4
Etoll yiew per I Box. H'80' r Iwo
I?b37j5
/;-U) (IN
l.) wall 4 g. wujmt catalysts, =
catalyst. and (6.8) " 23 with As cat The
Mectioa temp. with IWO Caw I, -7V This
M
:0 ptfwts udmr as Pe =Ft contest of the H990. =0 o
The CO 0
9 0 go 0
U00
'00
Ol
w
100
'00
ASN.SLA atIALLUOtGKAL 1.111IR&UNI CLA%%JPKAIICM 9 2
~O 00 81 '40
.00 ti
-.I -T-1 IF 1 -1, -1 -V .1, 4, 1 4 u ON- -a- 1- Xog
OT u 0 A, '0 A, I ; to 11 tv it Is It K a W W
g I 111, 0 oro 0 0 0 0 0 0 0 0 0 * 0 0 0 a AL 0 0 41
a 0 0 0 0 0!0 0 0 * 0 *0 00 go 4
ooooeo:ooooooeeoooeoeooogooeeoeoeoooo*ooooooo:~
0

1 v
. v IF A I I AA U a W U Ill

Tko compogiUmt of synthetic ethyl alcohol and the
10 Infliswo q(Torlous factaft during its sysitbesic V S,

.A. Valin aind
Gutyr". jlkj,j
'
lle pit$-
ghaftsk" 1936, Xo~ A. 72 eC. -I
00
co"Of"u4sints.Diprupylt-lic ill 10,11.1,A,jilsolho,
liulk of great 4mtq, ot pwYllarts Awl I-PrUlf 4114 lo a
i"l%ideirshk 6weri"A its tile y1cld of FtOll ill llic iff-al-
uilrist witb IJSO.. Cork-d. opsl%j M.,A), Ila, hillim
1-4ruserillne propertics thmi w,,Akrr liciij. Hill, ps--
pro= Tb~ by'll-Aybi.. of lb~ '0q1-
0 WNW 'led Uut at devetvi 1",.P.. -W
the 'I P".,Lbct must be (wpi'lly reti-vej frotu
.3 the rqwl. S.-to 1, fown Ifir lit(lif by
wilin't Ila rwrilly-l'i'l, fdrientr
A. A. 11-1-timilk
00 2!
A S 8 1 1, A stIALLUPWAL 0111101,011 CLAS$1F)CATIC.
j T- --I-
I VIM
It it ~'a A
0
=of
coo
= 00
xq*
. 00
see
coo
#A I t 4 ew --w- is 13 -3 lp
q 0 * * 0

0 0 4 0 0 0

i:
I
A b IF x x
, I - L
0 M
1
M
,
_

y1 akohol from petroleum gases
Systhitalsofiso o
A
t
t
IQJ6.
"16,A11
rit,
I In ill,l
"
f

AIIII-Al an WrI111- Of vil 111-4 ~I-

IWO N:"; 4, "1,. and ti'v
V14-111 1.3%
d i, id i. 2.4 2.9 kg. per &g ale. I br lw,~ -1-
14 1, f.6 coffinirtrial 34MIC In-. - i.'kS W*~. 111. rqmp.
ItOrnt U,,Cd dIkl Mi I)IIX-TU AM AIV,,'111441 AIIII i1ir
AfV tOIN112jor FIIIMn FVfC7CVk-.
coo

of
C
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of

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1tv ,
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0 9 0 0 0 0 0 a 0 0 0 0 0 0 0 0 eiso
1
1
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I It I I I 1 9 IT it it to W is it
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l
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o mis is U Is Is a is V is P a so 0 a ma q
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-
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1 4 1 0
..1, so- -.9101

so The reaction of ethylene with sulfuric acid. M. A
0*
U awl V. S. Gulms. Nfltsoo,~
W1 -
,
A . 10,17, Not. ;. 14 N. Ahloot~ Korpt-W. A., I' N., 00
or o4 it. fit, likim, I's I., tu"rolo- list ."'No .
-00
...I star is., W -4j&Qd,. 'd Ill, 4 11. "dog."t. Is,,
"Ptil. were pot Ile sued. In ota App. III Whis Is & Show flow of -00
as of Coll. passed over revolving loomittirm worl I-A will, file 4, Id 40
the shape of thew loaddlors tind Ihrsr mjrfi~v indlirt1-1
the junt. of acid &nil of Cill. u-1 sit) It* the it A, still, -00
a 20-2.5% concri. ,I Coll. with a 1-1 IL' alM. Wt-
-00
sure the write mAtits were obtained sit 7 hts. *~ wris,
obtained by other inve,tig,ums its an autwL&vr lutivultil
p
8
: l
0a with a inizer with 98% of Coil. At 15 atin. prv-utr in -11, o
=
9 n tuore hes. Fxpt-i. with a It' (W~ c-lstI- ,( Coil, will,
05.4 or tim.7% It'SO, ,how"I that the pull, of th. 11,11 (IMI
i
0j loll the drill. W a. Ill u_J Ill, vt,A-,l alm-1 hm-I,
0 wuh ItIr ilk-li-4- of Ow Colt, -.). so list.. it.. sodd .I it..
00
Ale. insoirdied hut,Aily. Illo, I.-,t 'It,
with lot)% Coll, whussc .ucn. w&% ki,tot mu,t. thfmisth,mt zoo

r the elipt. Follits. on the ahvirlition of a ~Npo~~ convit. to(

I
- Colt. by varying compts. of IftNA), at I atin. anti At to)-12

je attil. pressures permit deducing M' f(ollowing rrLalwu~hip
91-4) (y - 1.19) ~ C, whtrc x i4 the etmu-n. of th
x

t J,' I i I %. Y the still. of fit-111 U-A In ki(. Jill, Ill Ak., CA
i; (
c"Is.4t. equal to W.0 it I alill. 4114 W.10 at it; IL., Jill)
I'to itioure & isinalh-ir 4--xff. #)I Acid ctxpj~llmlllioli fill to,
:
,
lig., ka. .4 Ak-. instead W 1 bc throirtival 1.1 its. I.,. s. I Not
d %hould not lost less than %V t-t,uoil. at I still , stO wit I---,
than tM17. At 12 Alm. The iliat *tth
A 111.1frWielostly hipth pteil%tut A OCIII bolus , -11,1 1%
sed- Thi% would lierruit the utsis A thi,
A I S L A -ITALLLFGKAL LITtI110161111" ' I v.%

. Alt 0
so products of Et.SOj for the slam lityin of Coll, in a -u.
tinuouts production c rte. %V- R. limn are 0
It

To tv it 69 a a of U I't Ur it at
X -0,01 W --
mI__ 1 ra
n IT an S 0 tW D

IN 0 0 0 se

9496606006906
0 0 0 0 0 0 4 * 0 4 # 0 .0
U Is Is 16 V Is a It n a US
A I -,C -A,
00 4
PDOCIIIIII ARO POCIP141106

0:
09

6004000*0 T""'
0 0 0 0 IS 0 0 0 0 4 0 0 0 0 0
a III V a 0 a o a a a vito
I
production of organic compounds from the waste prod-
A
M
,
.
ucts of Vtolysis and cracking of petroleum.
19311
Ih~! !1
6
;
it
,
. s.
,
1
U.1in. t to, them. 1R.J. x.
A'jIjwu-k-.kxi of th~ ptduclun, of HIM. I*t,(?. M,A.
solYrIll, ato otlitt Inothatti fromi Ibe
mod. and nn%ild. IlyllItKA11"911 A* IW
t'T 4, 1 i.~.
lTALLUMGK_AL_LIT#SATL4R1 CLASSWICATION
via., lll~vjkl.
.10 'V. ;1481"11.1
-T --T; -; I __I, V : ?I
Is Al .1 74 -,. V I U
0 IT 11, IP 1, it all I Is It a tt If OIL " I I& *A L
: 's
000
Soo 0 aIS 0 : 0 : N 6 to 0 0 0
0 0 0 0 0000 000 0 0 14 o to
I,
al
Go
loss
'J.".
a 1W a - -8 -1 w __N' i -;a -i- -3 1 1 '04
a 0 0 0 * 0 00009 0
o o*ooooooooooe:,

A JL,
of the reaction of' tion of Demo
0 a' "00
Presence of Wam, am an 0. N..
v and e i VA.
Iso to Isma i son 0 "S Usti. Akad. Nauk
~mCN~4k.1Q10'Gl7_-2'9 _R tk,,
33.9 .9 Kkim. Nauk 101 , 017-29.-Reactkn of'
)RI. ;KA IlPh fit the ptese-oce of IICI. and with C411# in the
olefins. leads to fortnation of complexes, the
presence of
decomPs. Of which with 1130 YKIS alkylatcd PMducts.
Under similar coutlitions, reaction of Cjla with AlC)j in the,
4 presence Of HC1 dots not form a complex, and under high
-temp. conditions them am formed substances which on'
hydrolysis yield tars. Thus, complex formation occurs bjr-
exchange of proton for a radical of al I type. The propov:
tion of ruo..- dl- aral vlylkylatedkjivs. In the complex 1
depends an the compo. of the reaction mixt.. Indicating an.
q
equil. between the components used and the complex formed.
:,ne "I. part of the awnplex 6 a inixt. of alkylated beames
Wid. not tnenly the trkilkyhtted matn'litf. Alkylation of
Wo w1th propykno proceeds )a 2 star". r .1 olefin
to the compliz and exchange of the hydrocarbon frag~mcnt of
the complet with the reuctants. None of the existing thL--
-ylatian reaction In its complexity.
pries cover the alk
Kosolapolff-

N.1
~ m -I . . '.1i
MAMEDALIYF,V,Yu.G.; DALIN,M.A.; WfKDOV.T.I.
Catalytic dehydrogenation of isopentane frnetion. DokI. Al' ' Azerb.
SSR 11 no-1:13-19 '55. (MLRA 8:10)
1. Institut khimii Akademii nauk Azerbaydzhanskoy SSR.
(Dehydrogenation) (Butane)

USSR/Chemical Technology - Chemical Products and Their
Applicatlon. Industrial Organic Synthesis
Abs Jour Ref Zhur - Khimiya, No 1, 1958, 2144
Author Dalin, M.A., Markevich, S.M., Borisov, A.M., Mamedova,
'7-. - ~'~
Inst Academy of Sciences USSR
Title Technological Development of the Synthesis of Ethyl Alcohol
by Direct Hydration of Ethylene.
Orig Pub Sb.: Khim. pererabotka neft. uglevodorodov. M., AN SSSR,
1956, 568-577
Abstract Description of the technological system and of results of
the experiments on direct hydration of CA,, to C.,H_40H (I),
in an experimental industrial unit with a reactor of 0.5 m
in diameter and 8 m high, using H3PO,? as a catalyst.
Duxing the experiments the following optimal conditions of
Card 1/2

ULLIN, M.A., dotter takhxichoskikh nauk.
State of the mamifature of unsaturated gAveaus hydrocarboas and the
synthesis of ethyl alcohol by direct hydration of ethylene. XhIm.
nauka i prom. 1 10.3:259-272 156. (KIRA. 9:9)
(Hthyleae) (Alcohol) (Petroleum products)

DALIN K L,._SHIDXLWBIIKOVA, A.Z.
Catalytic dehydrogenation of hydrocarbons for the pr " ration of
butadiene and isoprene. Trudy Inst.khim.AN Axerb.35a 15:84-98 '56.
()aSA 9:11)
(Butadiene) (Isoprene)

USSR /themical Tecl~nol~j&~.
and Their Application
Treatment of natural gaz3ez; and
Motor fuels. Lubricants.
Abs Jour: Referat Zhur - Kh1miya, No
Author Mamedaliyev Yu. G., Dalin M. A., Nl~jinedov T. 1.
Inst Institute of Chemistry, Academy of Sciences
Azerbaydzhan SSSR
Title Catalytic Dehydrog,;nation (--,f Isopertane Fract1l.-J-i
Orig Pub: Tr. in-ta khimii AN AzSSR, 195b, 15, 13*--,-1!3
Abstract: See RZhKhim, 1956, 59259
Card 1/1

f)"-jj'tj . i i )(I,-0 ~~ I ~' ~ I
) DALIN, Harjc.Aleksan4.rqvl.,ch; MARKOSOY. Petr Ivenovich; SHBIUMOVA, Roza
"""Isaakovm; PROKOVIYEVA, Tatlyana Vlqdimirovna; SHIMSTIHA, Ye.T.
redo; SHPAK# Ye.Ge, tekhnered.
(Alkylation nf benzene by olefins] Alkilirovanie benzola olefinami.
Moskva, Gos.nauchno-tekhnAzd-vo khim.lit-ry, 1957. 117 P.
(Olefins) (Alkylation) (Benzene) (MIRA 11:2)

T) i-~ ~ %- ",).V\ , VA.
MAMMALIYET, Yu..G.; DALIN, M.A.; SHIKHKAMOBEKOVA, Z.A.
"- " -
Dohydrogenation of isopentenes to leoprene under reduced pressure.
Dokl. AN Azerb. SSR 13 no.g:-961-965 157. (VLRA 10t9)
1. Inatitut khimii.
. (Pentane) (Isoprene) (Dehydrogetiation)

~~,/ ;,~.
MAMBDALIYHV, Yu.G.; DALIN, M.A.; SHIKHKAMBEKOVA, A.Z.
.
Analyzing the pentane-pentane fraction of catalytic cracking. Dokl.
AN Azerb. SSR 13 no.11:1159-ii64 '57. (MIRA 10.*12)
1. Institut khimli AN AzerSSR.
(Petroleum--Analysis)

S07/64-5a--6-3/15
AUTHORS: Dalin, T.I. A. ,Burmistrova, R. S. , Taniyants, 'K. D.
TITLE: 9he 1)mol$i1s 4720DIstil3ate Oil (Piroliz g-azovogo benzina)
Study of Pyrolysis Under Semi-hI&Strial Conditions (Izucl~eniye
piroliza v polu:;avods%ikh unloviyakh)
PERIODICAL: Khimicheakaya promyshlennost', V,158, Nr pp 333-335 (USSR)
ABSTRACT: An analysis of the pyrolysis of liquefied gas (Tuymazinsk)
for the production of a raw material for unsaturated com-
pounds was carried out on a oemi-technical scale. The 1,asoline
consists mainly of a pentane-hexane fraction. A schematic
drawing and description of the testinG plant are -iven. The
analysis of the gas obtained by pyrolysis was carried out
in the apparatus 'U~SIAM! -51 and W.1, . 1"he regults obtained
are given in a table and indicate, amonj-, other things, that
a temperature increase does not only reSUlt in a higher
yield of gau, bitt also in an increased concentration of
ethylene. 08timum conditions stated are as follows: te.7pera-
ture of 220 , a contacttime of one zeconl, and an addition
Card 1/2 of .9team to the exteat-lof 20 per ceL bv Under these

f,)
The Pyrolysis of Ligbt DistilUte Oil
Stu-~Iy of Pyrolysis 1'rider 3emi-jnftgtrjSa Conditionc
conditions the yield of gas obtained by pyrolysLs i:- F,2 per
cent by weight (of the raw material), tl~e ethylene crintent
beinc 31,8 Per cent by volume, the content of propylene
and ethane 7 and 4 per cent by volume, re9pectively. The
yield of' liqitid carbon io 16 per cent by wei;-ht- 45,1-) yer
cent of which boil at 78-112(). If the -.-s obtfiined hno a
composition that is similar to that of the raseo, obtained by
the pyrolysis of the ethane and propane-:,ropyl fract-ions,
it can be conducted to the separating unit alon,,- wit-. the
other Cases, and it is not necessary to cliankre the pro,iuc-
tion units for the individual olefins. There are 4 fil-,ures
and 3 tables.
Card 2/2

DALIN, M.A.; SHENDMVA, R.I., VE189NEYEVA, L.Ya.; PISIMAN, I.I.
Polymerization of ethylone on a chromium catalyst. Dokl, A-1 Azerb.
SSR 14 no.12:991-996 N58- (MIRA 12:1)
l.Predstavleno akademikom AN Azerb. SSR M.P. Wagiyevym.
(Ethylene) (Polymerization)

) PHASE I BOOK EXPLOITATION SOV/4054
Akademiya nauk SSSR. Institut nauchnoy informatsii
Khimicheskaya promyshlennost' SSSR (The Chemical Industry of the USSR)
Moscow *' Goskbimizdat, 1959. 457 P. Errata slip inserted. 4,100 copies
printed.
Sponsoring Agency: USSR. Gosudarstvennyy nauchno-tekhnicheskiy komitet.
Ed.: R. S. Romm; Tbch. Ed.: P. V. Pogudkin; Editorial Board: A. P. Vinogradov,
S. I. Vollfkovich, N. M. Zhavoronkov, M. I. Ivanov, V. S. Kiselev, 1. A.
Lunacharska,va (Scientific Secretary), S. S. Yedvedev, B. D. Mellnik, A. 11.
Planovskiy, A. Ya. Forabeako (Chief Ed.), and A. V. Topchiyev.
PURPOSE: This book is intended for the personnel of the chemical industry. It
will be of interest to the general reader interested in the development and
structure of the Soviet chemical industry.
Card 1/6

The Chemical Industry of the USSR SOV/4054
COVERAGE: This book contains 18 articles on various aspects of the Soviet
chemical industry. Among the developments in the production of raw materials
for the manufacture of chemical products discussed are: 1) the use of raw
materials synthesized from natural gas and petroleum to replace food products
in the production of synthetic rubber, alcohol, detergents, etc.; 2) the
production of acetylene from natural and petroleum gases for the synthesis
of vinyl chloride, acrilonitrile, chloroprene, trichloroprene, 1, 4-butadiene,
and other organic substances, based on methods developed by M. G. Kucherov,
A.Ye. Favorskiy and others; 3) the production of acetylene from saturated
hydrocarbons by cracking methane (and its homologs) at 14500 in an electric
are between two special electrodes in a gas reactor, by pyrolysis (thermal
oxidation) of methane in an improved furnace designed by B. S. Grinenko, by
high-temperature pyrolysis of propane and butane in tubular furnaces, or by
other methods of producing acetylene for the production of synthetic rubber,
ethyl alcohol, and other organic substances; 4) the synthesis of halogen deriv-
atives of aliphatic hydrocarbons for the production of solvents, refrig-
erants, pharmaceutical products, ete.jand 5) the production of rubber ac-
celerators from nitrogen-containing aliphatic hydrocafoons. The history of
plastics production in the Soviet Union is reviewed, and n s, locations,
and products of plants as well as the names of outstanding personalities in
the field are given. The technical level and prospects of further develop-
ment of different branches of the plastics industries are also discussed
card 2/6

The Chemical Industry of the USSR SOV/4054
along with methods of manufacturing plastic articles. A special ap-
paratus designed by Ye. M. Mogilevskiy and designated "Wo' which permits
preparation of viscose solution in one operation is discussed. It is being
used to replace the complex, conventional equipment with great savings in
space. General trends in the technology of synthetic fiber production are
also discussed. A historical review of synthetic rubber production and
the achievements of outstanding Soviet scientists in this field are given as
well as names, locations and products of synthetic rubber plants. Rubber
production and the manufacture of rubber goods are similarly reviewed.
Statistical data and outstanding personalities in the development of the
aniline dyes, paints and lacquers, mineral fertilizers, insecticides and
fungicides,, sulfaric acid, soda, mineral salts., radioactive and stable
isotopes, and chemical reagents industries are given. Catalytic processes
and automation and automatic devices used in the chemical industry are
also discussed. Thirty-eight photographs included in the book show outside
and interior views of some Soviet chemical industry plants, as well as
their manufacturing, material-handling and laboratory equipment. 1himerous
personalities and facilities are identified in the body of the text.
References accompany indi-.-Ldual articles.
Card 3/6

The Chemical Industry of the USSR sav/4054
TABLE OF CONTENTS:
Introduction 3
Korsunskiy, O.V., ItAj,_~Dali ~ A.N. Planovskiy, and R. 1. Chernyy. The Basic
Orgs.nic Synthesis Industry 11
Garbar, M. I. The Plastics and S)mthetic Resins Industry 75
Birger, G.Ye., and A.A. Konkin. The C~temical Fibers Industry 111
Zakharchenko, P.I. The Synthetic RubV.-r Industry 137
Suslyakov, A.V. The Resin Industry 168
Kbrolev, A.I. The Aniline Dye Iadustr, 197
Belovitskiy, A.A. The Production of IA.,,-quers and Paints 219
Mellnikov, N.N. Chemical Means of Proiecting Plants and Eliminating
Weeds 234
Card 4/6

The Chemical Industry of the USSR
Vol-fkovich, S.I., A.M. Dubovitskiy (deceased), and N.A. Sintalin. The Production
of Mineral Fertilizers and Fixed Nitrogen 256
n1yanov, N. S. The Chemical Mining Industry
Malin, K.M. Sulfuric Acid Production
Boguslavskiy, N.M. The Soda Industry
Yakimenko, L.M. The Chlorine Industry
Bogachev, G.N. The Production of Mineral Salts
Globus, R.L., V.G. Brudz1, and G.V. Chuchkin. Chemical Reagents and
High-Parity Substances
Frolov, YU.S., Ve V. Bochkarev, I.F. Tapitsyn, and R.L. Globus. The Prepa-
ration of Phdioactive and Stable Isotopes: A New Branch of Chemical Tech-
nology

The Chemical Industry of the USSR SOV/4054
Boreskov,, G.K., and V.S. Chesalova. Catalytic Processes in the Chemical
Industry 4og
Yelshin, N.N., and N.Ya. Festa. Automation of the Chemical Industries 438
AVAILABLE: Library of Congress
Card 6/6
JA/dwm/fal
9-16-bo

56) - SOV/64-59-5-4/28
AUTHORS: Dalin, M. edova, V. M., Kasparov, A.S.
TITLE,': Catalytic Vapor-Phase Hydration of Propylene Into Isopropanol
PERIODICAL: Khimicheskaya promysh-lennost?, 10,59, Nr 5, PP 385-367 (USSR)
ABSTRACT: The optimum conditions for vapor-phaje hydration of propylene
W into isopropanol (II) Yith the aid of phosphoric acid
catalysts were investigated on a pilot plant together with the
IKhF AS USSR (Ref 4) and wabsequently on an experimental plant
(capacity; 1 t of (II)/24b). The kinetics of this reaction was
alread,' , investigated by N.M. Chirkov an(' V.I. Tsvetkova (Ref 3).
The scheme of th,,~ pilot plant used here is given in figure 1
from which it Ma-IL '~

'TJ a +
.10 f")(
_ th, he fraction of propylene (with
a minimum of 0%4 vc!me(Q)is mixed --,iith the vapor condensate in the
ratio (0.7-1): 1 and rearhes the reactor at 170-1800. After
condensation of II) the mixtj_re again passes through the plant.
The condenoatte c-ntaing 15-18% by acight (II). Coarse-pored
silica gel (poro ity 65,~) saturated with 50'..' orthophosphoric
acid (III)(first 'juality according to G06T 1,0114-39) was used as
Card 1/2 a catalyst (C). "'-1e bulk weight of the (C) amounted to 0.112ke/l,

Catalytic Vapor-Phase Hydration of Propylene Into SOV164-59-5-4128
Isopropanol
the (III)-content to 41-5% by -weight. The equilibrium constant of
the reaction was computed accoTding to Vvedenakiy's equation
(Ref 6). The follow;ng optimum conditions were found:
Temperature 170-180 , pressure 9-11 atm, volume velocity ot M
500-650 hours -1 , molar ratio (water: M - (0-7-1) % 1,
concentration of (I) in gas 80-90%. Under optimum conditions
the conversion of M to (II) amounts to 5-6,0 for one passage
with an efficiency of 96~-. There are 2 figures and 6 references,
5 of which are Soviet.
Card 2/2

T""-'ll 'I'M
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11TY 'M
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'I 't T 11 It -n'T"g) -.1 VaI
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.1 J..r .1,12 ...1I.02 -4 J. ~v q_ VARA qz , =TNISMT
(jgGr.) W, d '656&
I.R.-Ty lirqls ~J-tmufs ql 30 -11t4.1 ;a ....
WS

DALIN, M,A.; DIAMAT-UlAip A,,,.; PISIMNI, I,I.; A.A.
Copolyinurization of (ithyl;:nt,, with I)ropyl.cn(-,. A;,,jrb. 11,him.zhair,
no.,4:21-26 1119. ll~:(?)
(Profeno)

YAMEDALIM, Yu.G.; UALIN, M.A.; SH1KFDWTDIW.OVA, A.Z.; WOMV, T.I.
Dehydrogenation of isopentane and isoplentence to form isopreme.
Trudy Inst.khim.Ali Azerb.SSR 17:123-130 '59. (MIRA 13:4)
1. Institut khimil All AserSSR.
(Butane) (Butene) (Isoprone)

s/595/60/000/000/007/01'i
E196/E435
AUTHORS- Ma me da I iyev, Yu,G, , Dal in. M,A Shik I
TITLE-., Some results of research on defiydrogl-na . i,jD rL I
isopentenes to isoprene
SOURCE,- Vsesoyuznoye soveshchaniye po khimtchesko-, p-~rs--raho-1-
neftyanykh uglevodorodov v poluprodukty -jiya -62nt~z,
volokon i plasticheskikh mass. Baku, lg*;7,,
Baku, Izd-vo AN Azerb,SSR. 1960,. 21q 225
TEXT-. In their search for an economical. raw material fzr th,~
production of monomers of isoprene rubbe-, considered t.he be:5t
synthetic rubber now in production, the author_~, -arrie~d out
investigations of C5 fractions contained in thi--rinal and
catalytically--cracked gasolines, This wa:3 done fox- the puy-pose
of determining the quantitative relationship bexw~,en h-i~ -ariou-s
pentenes and isopentane of these fractions,. Th~_ and
quantity of these isomers was determined chemically and by
spectrum analysis; the results are given in Table 2 Th-,
dehydrogenation of isopentenes to isoprejj~- was -_arri-~d Out in th,f
presence of industrial catalyst K 12 and K 16. normalis, L-d fo-
Card 1/,

S/593/6o/ooo/Goo/oo7/oi4
Some results of research E196/E435
conversion of butenes to butadiene, As t de hydr ug~na , i- or, i
favoured by the reduction in partial prtmsjur.~~ of t ?I) n T.!
the expe r illlerL t 3 we r e ca rr ied ou t C- L t lie r t n pa rt. ta 1 -i, ~ uuln tnm H'~
or w.Lth 4 to 10% of steam as dL]uent , at t,empprr.'Ou--~ r a ii 1; 1 rl
from 5130 to 63CC with velo--ities of 1 0 tc 2,0 k b Th
catalyst was rea,:.t i va ted by pa ssing a 1r ditir ing 3 to
tempera tures not exceeding that of the -experirr.~-rt
-ere obtained wi th ca 4a ly.st K. 16 a t 540 'C -i it. k
isoprene in 25 to 26% yield per pa_,ms or to 811% ~,n "I-
decomposed isopentene.-i. An important
dehydrogenation ratio- of the three i cm r I 1 0 1 11 H O.Irl j
*. he C 5 f ra c t i on f r ,,,!I pf~ r - ol etim r o 1% n Q T 1-~;
mean-i that a mixtilire of isc:p6~tn,_ -ne_~
i n d i v I. dkia 1 r onipo n ~ n i ~z b o f (, r I- de 11 yd, og -- no t.~n I - r~,
B,S Koro tkevi ii h . A . Z Do- cigo-hin k I Y and A i5o 11 . 1
in the article, rh e'z T t~ .21 f I git.) I
7 Soviet-bloc and I r, o n - S o,.' i e t - h 1 o,. Th e I, on Hi
langiia ar pi.tbl i :,a t i on ri:ad,~ a s f o1 i ,u -
Brown R, and o t I-,Qr Tndti- 1. r E 1-1 ;E I t:v
Ca rd 2/,~

Some results of research
s/5qs/6o^ocj/(j(j~j/(jO7/(Ji '#
Et96/E435
In C5 f-ra' f 'or' It 1 t A ": 1
Hydrocarbon from t hernia 1 r on a 1 1
cra..-kiniz 'a W1W r I ng
I S 0 F) Oil ta 11 e 20 il
n-pentane 18
pentene-1 12
entene-2 fract
p
3 - me t hy I bit tene -1 8
2-inethylbutene-I 5
2--methylbutene-.2 12
Card 3/3

S/595/60/000/000/008/014
E134/E435
AUTHORS: Mamedaliyev, Yu. G. , P~n ~jt-,-Namedov, T, I.
TITLE: Some results of work on the catalytic dehydrogenation
of isopentane fractions
SOURCE: Vsesoyuznoye soveshchaniye po khimicheskoy
pererabotke neftyanykh uglevodorodov v poluprodukty
dlya sinteza volokon i plasticheskikh mass. Baku, 1957,
Baku, Izd-vo AN Azerb. SSR, 196o, 227-232
TEXT: The paper deals with the catalytic dehydrogenation of
isopentane to isoprene, the object of the work being an economic
process for the manufacture of isoprene from the pentane
petroleum fraction, leading ultimately to the production of isoprelle
rubber. A fraction containing 94 to 96% isopentane was passed
over the aluminium chromium catalysts K3, K5 and K9, which are used
for the dehydrogenation of propane and butane. The work was
carried out in a single passage of the isopentane over the catalyst
in the continuous equipment described by the authors elsewhere
(Ref-7: DAN Azerb SSSR. 1955, 11, no.1, 13; Ref.8: DAN Azerb,SSSR
1956, 12, no.1, 3; Ref.9: Tr. In-ta khimii AN Azerb.SSR, 1956, 15,
106). The effect of temperature and flow rate on yield and
Card 1/ 3

S/595/6o/ooo/ooo/oo8/ol4
Some results of work on E134/E435
product composition was studied with catalyst K3 in the range of
490 to 5300C and space velocity of 0.7 to 1~5 per hour. The
product contained 3-methyl-l-butene, 2--methyl-l-butene and
2-methyl-2-butene in the ratios of 1-3t-4.6-il-o, Some dienes were
formed, The work with K5 was concentrated on 520"C and a space
velocity of 1 per hour and gave ratios of 1~0%3,6,10.,O foy the
'~C and a
above methyl butenes, A temperature range of 520 to 570
space velocity of 0.5 to 3 per hour were employed for K9,
effects of temperature and flow rate on yield and composition was
investigated. The liquid product was about 90% of the is3ptnit?ne
feed, The yield of unsaturated hydrocarbon increased from zD
4050' with rising temperature, 2-methyl-2-butene wa-3 found
the main isopentene formed (up to 70%). This may be due to
isomerization. of other isopentenes by the alumina catalyst '.arrii:!
in the high temperature zone. The effect of dilitent3 -in 'he
presence of K5 was also investigated nitrogen ~-arbon dioxidr-
hydrogen and a hydrogen/methane mixture being employed. Onay
results with hydrogen are givan and higher dilution rz~tios WPTIA
found to increase the amount of unsaturated Ur to
Card 2/3

S/595/60/000/000/008/014
Some results of work on E134/E435
of unsaturated hydrocarbons were obtained but no isopentene
analysis was carried out. Best results were obtained with
isopentane-hydrogen ratios of 1,.3 -4- in these circumstances
about 8% of diene on weight of isope~tane feed were obtained,
The authors consider the catalysts suitable for the
dehydrogenation of isopentane, N.I.Shuykin is mentioned in thf-
article for his contributions in this field, There are 4 figuret:,
and 31 references: 15 Soviet-bloc and 16 non-Soviet-bloc, The
four most recent references to English language publications read
as follows: Ref.17: Britton E.C., Dietzler A.I., Nodding C,.R,,
Industr, Engng. chem., 1951, 43, no.12, 2871. Ref.18-. Blue et i1
Industr, Engng. chem., 1952, 44, no.11, 2710; Ref,20~ Eichens.
Selwood. Journ, Am. chem. Soc., 1947,, 69, 1950, 2698, 1948 70,
2271; Ref.26- Kearby K. Industr. Engng, chern., 1950, 42, no.2.
296~
Card 3/3

SRAENOV, N.N., red.; MAMEDALIYEV, Yu.G., red.; DALINP M.A., red.; IIAGIYEV,
d'; SHUYKIN, H.I.,
M.F., red.; ALIXEVt V.S., red.; KRAIITSEL','B.A., re
red.
[Proceedings of the All-Union Conference on the Chemical Processing
of Petroleum Hydrocarbons into Intermediate Products for the Synthesis
of Fibers and Plastics] Trudy Vsesoiuznogo soveshchaniia po khimiche-
skoi pererabotke neftiarqkh uglevodorodov v poluprodukty dlia sinteza
volokon i plasticheskikh mass. 1957. Bakuq Izd-vo Akad. nauk Azer-
baidzhanskoi SSR, 1960. 313 p. (MA 34:7)
1. Vsesayuznoye soveshchaniye po khimicheskoy pererabotke neftyaWkh
uglevodorodov v poluprodukty dlya sinteza volokon i plasticheskikh
mass. 1957.
(Textile fiberst Synthetic) (Plastics)

DAIIN, M.A.; BAFIISHI-ZADE, A.A.; PILIMAN, I.I.; ELNIYAT-ZABE, A.A.
Some properties of the copilymer of ethylene vith propylene.
Azerb.khim.zhur. no.1:211-29 '(0. 14:9)
(Ethylene) (Propene)

IALIN, M.A. ; SEOUDEROVA, R.I.
Purification of 6thyl alcohol obtainod
of ethylene. Xhim.prom. 110-4:275-277
by direct hydration
-Te 16o.
(KIRA 13:8)
(Ethyl alcohol) (Stbyleno)

291L36
7 5 6 6
AUTI!ORS: Palin.-Al.. A,., Sp:ivak, R Ye , Burmi-itrov, Ye F
TITLE: Production of para-tertiary butyl phenol on the basis of
I
the commercial C 4 fraction of but.nno dehydrovenation
products
PERTODICAL; Referutivnyy zhurnal, Khimiya. no i',', i~,61, abs'r~.ct
17JI45 (Azerb. khl:!,. zh , n:) 6. in6O, 21 25)
TMT: The possibility of achieving a com:-lete extraotior. of isobutylene
(I) (at a content of from the C 4 fraction of the dehydrogenation
process by means of phenol (II) is shown. Qualitative p-tert-butyl phenol
is thus obtained, and part of hi;,hly conci~,ntrated I is separated, The
optimum conditions for the alkylation of II with the C, fraction wt-,re found
0 -1
to be a temperature of 100 C, 10,K by weight of 1001/~ 11,.)SO4an a catalyst, a
velocity of the fraction vapor of 0,25 !n/ /nec in the 'Lr,,e colu:~,,n cros.4
section, and saturittion of the alkylate I molo of I 1)~!r irt-olo of 11 A
Card 112

291436
S /0~, 1116 D/O 1 '/1 GzVl, 66
Production of para-tertiary.- EIOI/'B*102
Partial dealkylation takes place if temperature is increa--,d to 231; and
98 - 99 5% of I is separated. Divinyl, which is -resjnt in the fra(:tl-~.n
in an amount of 3 - 4%, is not affected if r he proc-ss tq,;,P- pac un -,
I .. - , e
optimum conditions- [Abstracter's note: Complete tr;ins.-ation
C,ird 212

DALIN, M-A .; KULITEV, A.M.; NURITEVA, Z.D.
The Azerbaijan chemical Ind?wtry during the last 40 vears. Axerb.
neft. khoz- 39t26-27 Ap 160. (MIRA 13111)
(Azerbaijan-Petroleum chemicals)

BURMISTROVA, R.S.
Fyrolysis of Karadap gas condensate. Azerb. neft. khoz. 39
no-I(405):41-42 Mr 16o. (MIRA 14.9)
(Karadar region-Gas, Natural)

DALIN, M.A., akademik; VEIMMUWA, L.Ta.; SHEND3ROVA, R-I-
Polymerization of etbylene on a chromium oxide catalyst.
Dokl.AN SSSR 133 no.1:182-185 Jl 160. (MIRA 13:7)
1. Akademiya nauk AzerbSSR (for Dalln).
(Etbylene) (Polymerization)

83133
AUTHORS:
TITLE
PERIODICAL;
S/020/60/133/'005/010/019
B016/BO60
Dalin, Academician AS AzerbSSR, Pis'man, I. I.,
Bakhshi-Zade, A. A., Buniyat-Zade, A. A~
Copolymerization' of EthXlenel With ~iej
_E ~Butyl~enejon Chromium Oxide Catalyst
and
Doklady Akademii nauk SSSR, 1960, Vol. 133, 110. 5,
pp. 1084-1085
TEXT: The authors wanted to carry out the synthesis mentioned in the
title and to study more thoroughly the properties of the substances
mentioned. The first results of their investigations are supplied in the
present paper. For their experiments the authors made use of Vishnevskiy's
mixer (Ref. 3). The solvent used was extraction benzine purified by
activated chromium catalyst. The catalyst was prepared by the well-known
method of Ref. 4. The ethylene- and propylene fractions of pyrogas were
used as monomers. The butylenes were produced by dehydration of n-butyl
alcohol upon aluminum oxide of the type A-1 (A-1) at 3600C. The mixture
Card 1/3

83133
Copolymerization of Ethylene With S/020/60/133/005/'010/019
Propylene and a-Butylene on Chromium B016/Bo6o
Oxide Catalyst
contained 2 - 3~ of isobutylene and 97 - 98~ of 1101-mal butylene,- The
butylene fraction was dehydrated on fine-porous silica ~-el ,nd calciu::1
hydride during production. The gas mixtures were prepared in carefully
dried metal balloons. After the pressure drop had stopped the autoclave
was allowed to cool and pressure was reduced. The copolymer taken from
the autoclave was heated together with the catalyst in a vessel with
ligroin, and was subsequently filtered off the catalyst on a paper filter
The polymer was then washed with ethanol, dried. and analyzed. Table I
shows the properties of polyethylene, whic."i constitutes a copotymer of
ethylene with propylene. It contains (in d by wei',,ht), propylene 12.6,
ethylene 87.4, and ethylene-a-butylene copolymer oC butylene and
93% of ethylene). As can be seen from Table 1. th~-- coiolymers of
ethylene with propylene and with a-butylene differ from polyethylene
with respect to melting temperatures, solubility in n-heptane, and
specific elongation in cold drawing. The greater flexibility is striking
but so is also a lesser strength of the ethylene-propylene copolyzer as
compared with polyethylene. Tile ethylene-u-butylene copolymer comes near
Card 213

83133
Copolymerization of Ethylene With
Propylene and a-Butylene on Chroi.,iium BO 1 (,)/BC)60
Oxide Catalyst
polyethylene as to strength but surpasses it as to ela-sticify. T'nort,
I table and 5 references: 2 Soviet, 1 US, 1 Belgian, and I Italian,
SUBMITTED. February 5, 1960
Card 3/5

DALIN, Mark Alakeandrovichi VASINA, T.V.9 red.j ZAZULISKAYA, V.F., tekhn.
red.
(Petrochemical syntheses] Neftekhirdebeskie sintezy. Moskyag Goo.
nauchno-tekhn. izd-vo khIp. Ut-ryp 1961. 97 p. (MIRA 14:8)
(Petroleim chemicals)

S/081/62/000/004/086/087
B102/B101
AUTHORS: Dalin, M. A., Shenderova, R. I., Pis1mant I, I., Bakhshi-
zade, A. i__., Vedeneyeva, L. Ya., Buniyat-zade, A. A.
TITLE: Synthesis of polyethylene and of copolymers of ethylene with
propylene and.a-butylene on an chromium oxide catalyst
PERIODICAL: Referativnyy zhurnal. Khimiya, ua- 4, 19,62, 66-9,-abstr,act
4R128 (Azerb. khim. zh., no. 1, 1961, 17 - 22)
Ti~.XT: Purification of Ethylene (I) was carried out on a pilot-plant scale
allowing for an increa3e in efficiency of the oxide-chromium oxide
catalyst (COC) up to 176 - 250 9/9 when I is polymerized in extraction
benzine purified with sulfuric-acid, or in cyclohexane (120 - 1300C,
3 - 5 hrs, 45 at, COC concentration 0.13 - 0.25A. When ethylene is co-
1,
polymerized with propylene (11) (6-7 - 15~ by volume) (110 - 1200C, 40 at)
in benzine in the presence of an CaC 2 activator (201;, of the catalyst's
weight), the efficiency of the COC is reduced to 68 - 135 g1g owing to the
lower reactivity of II and to its incomplete purification. The copolymer
Card 1/2

S/08 62/000/004/086/087
Synthesis of polyethylene and... B102Y3101
(CP) differs from the polymer of I by its lower-crystallinity. The con-
tent of crystalliji"phase decreases with increasing polymerization
temperature and increases wfth ~99su`Ve. ~~PfA6e, me~ting.-point in OC,
relative elongation in ~, r 'upture8trepgth.,in,k'9/cm2, and'solubility in
n 1 11-2'6 30P 6oo, 26o.-r 300, 10 - 15;
-heptane are enumer'hie'di I ~~. 11 t
CP of I with 11, 122 126, 720 1020, 170 - 220, 60 70,"CP of I with
a-butylene (2.5 - 4.5 vol%), 125 127, 500 - 800, 250 300, 30 - 40.
[Abstracter's notes. Complete trianslation],
Card 2/2

DAIINP M.A.; PISIW, I.I.; HAKHSIII-ZOE., A.A.; BUNIYAT-ZADE, A.A.;
--FMMILOVA, S.D.
Copolymerization of ethylene with At-olefins on a chromium
oxide catalyst. Azerb.khim.zhur. no.2:9-16 161. (MM 14:8)
(Ethylene) (Clefins) (Polymerization)

S/064/61/000/003/002/009
B101/B203
AUTHORSt Dalin,_M,.,-A., Spivak, R. Ye., Burmistrov, Ye. F.,
f2i"I'mitinova, L. M.
TITLE: Joint production of isoamylenes and para.-tert-amyl phenol
PERIODICAL: Khimicheskaya promyshlennost', no. 3, 1961, 21-24
TEXT: Isoamylenes are Used as raw material for the production of iso.-
prene. They are profusely available in the cracking products of petroleum.
Their fractional separation is, however, made difficult by the adjacent
boiling points of the individual hydrocarbons with 5 C atoms. Therefore,
the authors studied the selective production of isoamylenes by alkylation
of phenol and subsequent decomposition of the phenol amyl ethers into
phenol and olefins. They used as initial substancess 1) pentane amylene
fraction with 15-20% isoamylenes, 30-35% n-amylene; 2) phenol with the
melting point at 410C. 95-6% sulfuric acid was used as a catalyst. The
first experiments were made with an electrically heated glass column.
Phenol was filled into the column, and the required H2SO 4 amount was added
under stirring. After heating, the vapor of the pentane amylene fraction
Card 1/8

S/064/61/000/003/002/009
Joint production of iaoamylenes ... B101/B203
entered the column from below through a Schott filter. The reaction
products were condensed. The dealkylation was performed in a rectifying
column with filling from short glass tubes. Liberation of isoamylenes
started at 1600C, and was finished at 2050C- However, p-tert.-amyl phencl
also formed as a by-product. Resin was left behind as a distillation
residue. The initial fraction and the resulting isoamylenes were analyzed
in a nitrogen flow by absorption in 64~ H2so4 (isoamylenes) and 84YO H2S04
(n-amylene) in a brH(VTI) gas analyzer. The authors studied the effect
of the temperature at which the phenol was alkylated on the yield in iso-.
amylenes (Fig. 3). At temperatures above 800C, the amount of amyl phenol
increased. 1% of sulfuric acid referred to phenol was found to be the
optimum admixture. Larger admixtures increased the amount of resin
residue. Fig. 6 shows the yield of isoamylenes as a function of the molar
ratio isoamylenes i phenol. If 1:1 is exceeded, the formation of amyl
phenol increases (Fig- 7). The optimum established was a pressure of
2 atm at which the reaction products were better condensed than at at-
mospheric pressure. Still higher pressure may lead to condensation of
the initial fraction in the alkylation -vessel. As the laboratory apparatus
Card 2/8

joint production of isoamylenes ...
s/o6 61/000/003/002/009
B101~13203
only permitted a low vapor velocity, tests were made with the pilot ap-
paratus shown in Fig. 8 which permitted a vapor velocit.y of up to
m. sec with stronf.;ly reduced resinificPtion. Tvble 1 *hows the results.
As amyl phenol was fori-,ied besides phenol ethers which decomposed again on
heating, the authors studied at what ratio phenol ; ai,.~,,l phenol (desiGnat-
ed initial molar saturation) the optimum yield in iSoa:zvlenes was ob-
6ained. Pig. 9 shows tile result. Experiments made under the supervision
of 1.1. 1. Arkhipov at the Ivanovskiy khimiko-tekhnologicheskiy institut
(Ivanovo Chemotechnical Institute) showed that the resulting --ryl phenol
cculd be used for the production of phenol formaldehyde resins. Papers by
V. N. Ipatlyev, I. P. Tsukervanik, and Z. N. Nazarova, V. 117. Isagulyants,
and P. P. Bagryantseva are mentioned. There are 9 figures, 2 tables, and
8 references: 3 Soviet-bloc and 5 non-Soviet-bloc.
Card 3/8

Joint production of isoamylenes
Legend to Fig. 3: a) temperature;
b)yield of isoamylenes in % of
the absorbed vapor;
Legend to Fig. 6: a) molar ratio
isoamylenes : phenol; b) yield of
isoamylenes in % of the absorbed
vapor;
S/06 61/000/003/002/009
B101 YB203
NS, 45
x 35
25
V 90S0 f0a
*C
Fig. 3
Z 6,5
t,.x N
55
45 fig.
7
35
T7
Card.4/8 Fig. 6

Joint production of isoamyleneo ...
Legend to Fig. 7: a) molar ratio
isoamylenes : phenol; b) phenol
and amyl phenol, by weight
slo6zl6l/c',400310021009
B101/B203
moj7.vpNoe ronnyoweNue
7
Card 5/8

Joint production of isoamylenes ...
Legend to Fig. 8: 1" cylinder,
2) bath, 3) heater, 4) throttle
valve, 5) alkylating column,
6) water cooler, 7) cooler for
propylene, a) steam, b) initial
fraction not reacted, c) liquid
propylene
S/064/61/000/003/002/009
B101/B203
Card 618

Joint production of isoamylenes
S/064/61/000/003/002/009
B101/B203
Legend to Table 11 1) amount of reacted fraction, g, 2) stear- velocity
in the free cross section of the column, 3) content of isoamylenes
(% by volume) in the fractions, a) initial, b) residual fraction, 4) yield
of isoamylenes in % of the adsorbed vapor, 5) amount of isoamylenes
dealkylated in the temperature range:, c) up to, 6) concentration (~o') of
isoamylenes dealkylated in the temperature ranCe-
CKO il
POCT
napos D 3COAePYAaH

tj We "30aw". Ko"qC"TPIItV
bO Ielton, Aeal
BI X0 1130. 1,.' 1,117110F, 0 HIlTePU
a 1. ;L , ) 11
P lit P KIIIIINX D HIMPMOC
1% lW 04) H3W-H'
xlul~~Saxltii%
Ae lemnepaTYP

-
11pollywello
ePPOKitHil, Z I
Cr46OA10
ceitellitit --
;
1
or 110 TeW"C?3TY;O
-f-
K040iIHIS "CxoAhon 'tt, 10,11 " __- . - - --,
OTICOARIlleft. r . AO 1601
, 160-2M*
IGO-21w
.(:to 160
3110 0,05 10,0 .5.2 t5.2 W.2 1-,,8 50.8 92,1
62" 0 0.10 18,0 8,2 5 1 , 1 58,4 .11 1) 54.2 93.1
3920 0,23 18,0 G,-I 62.3 .10,5 59.5 64.2 9.1,6
5520 0,29 18,0 6,3 62,8 3.3,0 62.0 61.3 90.0
.1670 0,55 9,5 0,9 8s. 1 2,11.0 72 . 0 68 3
' 91.0
62N 0,87 18,7 2,4 85, 2 13.0 5
87, 1) 74 95.7
1070 90
0 1 12, 5 1,1 9.r, Y3, -2 9,9,1
Card 7/8 .

Joint production of isoamylenes,
Legend to Fig. 9t a) initial molar
saturation, b) yield of isoamylenes
in ~b of the absorbed vapor
c;
Card 8/8
S/064/61/000/003/002/009
B101/B203
Fig. 9

DALIN, M.A,; SPIVAK, R.Ye., BURMISTROV, Ye.F.; VYAZIMITINOVA, L.M.
Combined production of iso-amylenes and para-tert-amylphenol.
Khim.prom. no-3:169-172 Mr 161. (MIRA 14:3)
(Butene) (Phenol)

PISIMAN, I.I.; DALIN M A - MMEDOVA, E.S., KASIYANOV, V.V.
Producticn of 6~-butylene by the dehydraticn of n.butyl alcohol
on A-1 aluminum oxide. Report No.l. Azerb.khim.zhur. nc.6:67-72
,61. (MIRA 15:5)
(Butene) (Butyl alcohol)

PHASE I BOOK EXPLOITATION SOV/6195
Nauchnaya konferent3iya institutov khimil Akademiy nauk Azerbayd-
ahanskoy, Armyanskoy I Gruzinskoy SSR. Yerevan, 1957.
Material'y nauchnoy konferentsil instittitov kh1m1i Akademly nauk
Azerbaydzhanskoy, Armyanskoy I Gruzinskoy SSR (Faterials of the
Scientific Conference of the Chemical Institutes of the Academies
of Se'ences of the Azerbaydzhan, Armenianand Georgian SSR) Yerevan,
Izd-vo AN Armyanskoy SSR, 1962. 396 p. 1100 copies printed.
Sponsoring Agency: Akademiya nauk Armyanskoy SSR. Inatitut organi-
cheukoy khimll.
Reap. Ed.: L. Ye. Ter-Minasyan; Ed. of Publishing House: A. 0.
Slkuni; Tech. Ed.: 0. S. Sarki3yan.
PURPOSE: This book is Intended for chemists and chemical engineers,
and may be useful to graduate students engaged in chemical re-
search.
COVERAGE: The book contains the results of research in physical,
inorganic, organic, and analytical chemistry, and in chemical
engineering, presented at the Scientific Conference held in
Yerevan, 20 through 23 November 1957. Three reports of parti-
cular interest are reviewed below. No personalities are mentioned.
References accompany individual articles.

Materials of the 3clentlfic Conference (Cont.) SOV/6195
silicate mineral) as a catalyst carrier have been deter-
mined. The study was of interest because this petroleum
fraction is used as diesel and jet fuel and Is degraded
for those purposes by the presence of n-alkanan. Optimum
conversion conditions were obtained with hydrogenation
under 30 atm. H in a flow reactor at 450*C with a hydro-
gen/hydrocarbon molar ratio of 3: 1 and a hydrocarbon space
velocity of 0.5 hr-1. Catalysis with 0.5% of Pt or ?d on
Al.O. or "gumbrin" caused an extensive conversion of normal
undecane and dodecane and improved the motor properties of
hydrogenation-cracking products by increasing their heating
efficienoy by 80 kcal/kg and reducing their pour points by
16 to 48.5*C.
MamedalAyey, )Cu. G, M. A. jalin,_ and T. L MAMg-Ov, Cats-
-1ytic Dehyarogenatfdff7o~6 Ioopenl~a_ne Praction' 324
Vartanyq!i,_S,__A-.-, V. N, iama n Sh. 0. Ba
_.~;4 Z=vyA__, and _dapyan.
-Sin-tiiiale and IdiFe-sEgation of Amin oace t~1_e_nfc__Ai~d_cL-AYko-
xyvinylacetylenio Alcohols 336
C a rd

DALIN, M.A.
Development of methods of production of olefin hydrocarbons.
Report presented at the 12th Conference on high molecular-weight compound
devoted to monomers~ Baku, 3-7 ~prii 62

PECHM, P.S., MEAKWIEVA, A.P., GRISHI-A, G.A-, BURMISTROVA, E.F.
DALINV, M.A.
Dissociation of fluid petroleum products in an electric discharge.
Report presented at the 12th Conference on high molecular weight
compoundsp devoted to monomeres Bakus 3-7 April 62

~'~/064/62/000/002/001/008
B105/B101
AUT"rois Dalin, Ouseynova, Z. D., Savel'yov, Yu. V., Taniyant.9,
T-. D., Buri,-iistrova, R. S., Belen'kaya, Ye. L.
'I'ITLF: Production of high-purity ethylene
101) 1 C It L :Khimicheskaya pronyshlennost', no. 2, 1902, 1 - 5
Ir Snecial purification mothods of pyrotras for the production of
hie,ii-purity ethylene are described. The study was conducted in an
exPerimental plant with a productivity of 800 110/h as follows: (1)
Pnrific~ltion of the gas from sulfur compounds and carbon dioxide by means
0
of ,1.6,/-" IraOI-1. The pyrogras is previously cooled to 15 - 18 C to eliminate
polymerizable hydrocarbons, and purification is performed at a waterinG
density of 7 m 3/m2.11, a linear Oyrogas velocity of 0.04 m/s, and a
t
-ninerature 0f-50 0C .
c 1 (2) Dehydration of the Cas in two stages: from an
initial pyrogas moisture of 225 mf,/~IM3 to 20 ME,/,,;m3, as well as from, 20
to 10 MCIVNIO. Silica gel of the following, specificatio was tested-
volume zeight 0.85 9/cm3; specific pore volume 0.320 cm?/F,; specific
2/F i
,; average Dore radius 11.8 joi. Dehydration of air an
surface 537 m d
Card 1/3

'roduction Of hi""~I-pllrity ... 10 1
ethylene waf; performe] under laborator.,!- conditions by :..eano of molecular
the Grozz'
sieve Of tile type )roduced at NII, tile Gorlkovskaya opytnaya
baza VNITNII (Gor'kiy 77xperimental Bace VNIIN~))' and, the Institut
fi-icheokoy kiiiniiii AN (Inntitute of Physical Chemistry AS Ukr;SI?).
The volume -,,,eight of the molecular sieve variec bet,;.een 0.45 and 0.7
ulcr.3- (3) T'he purification of the ethylene-ethane fraction from
ncetylene may be realized by selective Ilydror-,enation in the presence of
cataly.sts, or (for more than 0-5','j C H ) by absorption ,,;ith organic
2 2
solw~nts. An induotrial nickel-chromo catal'vst zas tested in an
ex.o e r ime n t a I In I a ii t .Yhe ethylene-ethane fraction -.,-ith a content of 0.025
to 0.1) '..,, acetylene was h~,Iroj-enated by the metharie-'hyJrogen fraction of
t '-, e oyror,,as at 150 - 190 C, 25 - 25 atm, 4003 - 6000 li~i volume velocity,
and a hydro-en concentration of 25 - 30'/" in the methane-hydrogen fraction.
(4) :.ethane removal of the ethyleno-ethane fraction by fractional
di,-~tillatiori tit -23 to - 520 C. Tile methane and carbon inonoxide content in
ethylene after methane removal %-,as determined by the xT-2h (KhT-2?.,)
chromatograph. Activated carbon of the type AP-3 (AR-3) ,-,as used as
'( references: 1 Soviet and
'doorbent. There are 4 figures, 2 tables, and
C) non-Soviet. The four most recQnt references to English-language
'lard 21'.

6/1Ub4/1Wl/1jUU/002/001/000
Production of* high-purity. . . B105/BlOl
publica t ions read as follons: H. Stanton, Petr. Refiner no. 5, 1)59,
177; R. '-;'. Reitmcier, 1-1. Fleming, Chem. Enfr. Pro,-ress 5~,, no. 12,
1958, 48. U. S. Catalysts and Chem Inc., Louisville, Kentucky, 1958.
Card 3/3

PISIMAN, I.I.; DALIN !--, M.A.; KASIYANOV, V.V.; MAMEDOVA, E.S.
Preparation ofc< -btitylene bi dehydration of n-butyl alcohol
on aluminum oxide A-1. Azerb. khim. zhur. no.3:49-58 162.
(MIRA 16:12)

DALIN, 1,4A.; MiEhl,')93JEVA~ T,I,,
_L , , P IT
The 12-th Conforonce on Maerm.,.oleculp-r Compoulals, jj, r ro-
(:.lIp. jr,7)
no.5:384-385 My 162. - A -11. ') r ,
(Macromolecular compound-----Ccn~~rg..-,scs)

St2O4/621002/003/002/002
1032/1232
AUTIIORS: __Dalin._M_&. and Chcrnysheva, T. 1.
TITLE: 12th Conference on high molccular-weight compounds, devoted to monomers
PERIODICAL: Nefickhimiya,v.2,no.3,1962,415-419
TEXT: The conference was organized by the Otdclcniye Khimicheskikh nauk AN SSSR (Department of
Chemical Sciences AS USSR), Akademiya nauk Azerbaydzhanskoy SSR (Academy of Sciences, Azerbaidjan
SSR), Gosudarstvcnny komitet Sovida Ministrov SSSR po khimii (State Committee for Chemistry of the
Council or Ministers of (he USSR) and Soviet narodnogo khosyaystva Azcrbaydzhanskoy SSR (National
Economic Council of Azctbaidjan SSR). The Conference took place in Baku on April 3-7,1962, and was
devoted to the problem of starting materials for polymerization and polycondensation. 650 representatives of
103 organizations took part, and 142 papers were heard. D. F. Kutepoy, vice-president or(he State Committee
for Chemistry of the Council of Ministers of USSR, presented -a report on "The state and the prospects of
development of monomer production." R. G. Ismailov discussed the problems of development of the petro-
chemical and refining industry. V. A. Kargin spoke about "The expansion of the realm of monomers in
connection with progress in polymcrization."The report of M.A. Dalin was devoted to the development or
methods of production of olefin hydrocarbons. M. F. Nagiyev reported on "Contemporary problems of the
technology of petrochemical synthesis." The section of olefin compounds heard reports on productien of
Card 115

12th Conference on high... S/204/62/002/003/002/002
1032/1232
of methylpentancs and or 2,3-dimethylbutane. Methods of synthesis or vinyl-cyclo-hcxane were discussed by
Ya. M. Paushkin and by A. V. Topchiycv, S. D. Mckhtiyev. The section of metal-organic chemistry heard a
revitw report on "Phosphor organic monomers" presented by M. 1. Kabachnik, Ye. L. Gefter, P. A. Mo5hkin
and T. Ya. Medved'. M. 1. Kabachnik, P. A. Moshkin, S. L. Varshavsky, L. P. Kofman, Ye L. Gcftcr, G. V.
Tkachcnko, A. A. Danilevich reported on an industrial method of synthcsis of di-fi,fl-clilor-clhyl of vinyl-
phosphinic acid rrom ethylene oxide and phosphorus trichloride. A series or reports on the synthesis or
various phosphorus-containing monomers was presentcd by the Kazan school of chemists (A. N. Pudovik,
Ye. V. Kuznctsov. B. F. Malichenko, 0. P. Grishina, etc.). On the synthesis or phosphorus-containing dicar-
bonic acids reported V. V. Korshak, T. M, Frunze and V. V. Kurashev. Yc. F. Bucherenko (lOKh AN SSSR)
reported on (he possibility or synthesis of phosphorus-sil icon hydrides starting rrom unsaturated phosphorus
containing compounds and silicon hydrides. Reports on silicon-organic compound with alurnating siloxane
and carbon elements were presented by A. M. Polyakova, M. b. Suchkova and V. M. Vdovin (INEOS AN
SSSR) and by N. S. Nametkin and N. A. Printula. (INKhS AN SSSR). Telamerization of silicon-organic
cycles -was discussed by K. A. Andriyanov and V. V. SCVCTny (INEOS AN SSSR). A simple method for the
synthesis of aryl-fluor-sil icon-hyd rides was proposed by Yc. A. Chernysheva and M. Ye. Dolgaya (IOKH
AN SSSR). V. F. Mironov and H. N. G. Dzhurinskii reported on a new preparative method for the synthesis
Card 315

12th Conference on high... S/204/62/002/003/002/00,1
1032/1232
of gcrmat 'iium-containing monomers. The SyFlthCSiS of mcfacrylates and acrylatcs containing aluntinum,
boron, germanium was discussed by G. S. Kolesnikova, S. L. Davydova and N. V. Klimentova (I NEOS AN
SSSR) The only report on tile use of hydrogen-containing silicon organic monomers, tile manufacture of which
is nonexistent, was made by A. Morozov (Goskilimkornitet). The section of starting materials for polycondcn-
sation heard reports on monomer production for tile synthesis of polyamides and pol,cthers, polycarbonates
and D cpoxidc resins. Production of maleic anhydride by oxidation of butylenes was discussed by B. L.
Maldavskii. Reports from (hc Institute of Organic Chemistry, A. S. Latvian SSR discussed tile possibility of
production of maleic anhydride and'malcic dialdehyde from furfurol. Experimental data about production of
phthalic anhydride by oxidation of G-xylol were given in reports by A. F. Kamncva and L. A. Muzychenko,
and by Kh. Ye. Khcheyan. A. F. Pavlichev., S. M. Arbitman. B. K. Kruptsov. Several communications dealt
with methods for production of tcrcphthalic acid. Production of hydroquinonc and resoncinol by oxidation of
p- or m-diisopropylbenzcnes with air oxygen was discussed by V. V. Fcdorov, M. S. Belen'kaya, et. al P.A.
Moshkin, N. 1. Kutsenko, L. K. Filippcnko proposed a method for production of dicarboxylic acids with ten
carbon atoms in the chain, using vinyl as starting material. Reports from INEOS and INKhS AN SSSR dealt
with a new manomcr for the production of the syntheric fiber dode-Kalaktan (L. 1. Zakharkin, V. V. Korneva,
G. M. Kunitstsraya, A. N. Bashkirova, V. V. Kamzolkin, K. M. Sokova). Data on the synthesis orperchloro-
Card 4/5

l2th Conrerence on high... ~/204/62/002/003/002/002
1032/1232
alkcnc6, perechloro-alkendienes and perchlarocyclodienes were given by Yu. G. Mamedaliyev and M. M.
Guseinov (INKhP AN AzSSR). Ye. G. Denisov, V. V. Kharitonova (IKhF AN SSSR) discussed the mecha-
nism of oxidation of cyclohexanol to cyclohexanone. The section of vinyl compounds heard the survey report
by M. F. Shostakovskii on "The state and prospects of development of the manoiner chemistry on the base
or vinyl compounds". The conference heard reports on the synthesis of new monomers from acetylene and
dCTiVatCS of acrylic acids, vinyl ethers of the aromatic series, vinyl ethers of penta-crythrite (IOKh and Irkutsk
IOKh AN SSSR), vinyl-carboxylic acids OVS AN SSSR), vinyl suabstituted cyclic hydrocarbons (INKhP AN
SSSR), vinyl substituted cyclic hydrocarbons (INKhPAN AzSSR), etc. Direct synthesis of acrylonitride on
the basis of propylene was reported (Baku Experimental Factory, Inst. im. Karpov and Inst. of Chem. Science
or KazSSR). Reports dealing with production of vinyl chloride from dichloro-ethane and acetylene, synthesis
of allyl-vinyl ethers, vinyl substituted cyclohexane hydrocarbons (INKhP AzSSR). methods or purification
of vinyl chloride, synthesis of unsaturated oxides, unsaturated nitro-compounds, etc., were also heard. The
concluding plenary session heard a report by N. N. Sernenov.
Card 515

or
6/24 02/018/010/003/004
D2 04 YD3' 07
AUTHORJ: Dalin, H. A. and iobkina, V. V.
TITLE: Some laws governing the oxidative ammonolysis of
propylene
PERIJDICILL: Akademiya nauk Azerbaydzhanakoy 63R. Doklady, v. 18,
no. 10, 1962, 27-29
TEXT: The heat of reaction
C if -t- NH + 3 C) ----> C H
3 6 3 2 2 3 3
-1 ,
has been calculated as -123.332 kcal.,mole Lrom literature datua,
and the standard change of entropy as 17-957 cal-mole- 1deg- 1. The
0
free energies varied from -116.262 kcal-mole at 298 K to --i01.232
at 12980K, tale corresponding values of log K (where K is the
P P
Card 1/2

6/249/62/'0Ic3/010/0J3/004
Some laws govurning ... i)204/;)j07
eqUilibrium conotant) uc)in,,r bu.0 and 17-0. As wi--tss
rinientally, the reaction may jrocced practically to completion,
0
even at 1JOO C. The dei;ree of conversion of propylene,(X, is given
as 1-e %,.,Iicre 'L
-k'r, - is ti:.-le and k is a ve'ocity constant, which
obeys Arrhenius' equation. This expression .,:as confirmed ex,.,cri-
mentally between 430 and 4700C. T'herc are 2 fiLil,ures and 3 tables.
3UBMITTED: October 10, 1962
Oard 2/2

.DAIJN; M.A., akademik; LOBKINA, V.V.; ABAYEV, G.N.; SEREBRYAKOV, B.R.;
- -- ---,--PLAKSUNOVAp S.L.
Production of acrylonitrila based on propylene and ammonia.
Dokl.AN SSSR 145 no.511058-1060 162. (KRA 15:8)
1. AN Azerbaydzhanskoy SSR (for Dalin).
(Acrylonitrile) (Propene) (Ammonia)

DALIN, M.A..; SEREBRYAKOV, B.R.; LOBKINA, V.V.; GAMIDOVA, E.B.
Mechanism underlying the roaction-9 takin:; place in the proce" Ott
oxidizing ainraonolysis of propylane. Azarb.khim.zhur. no-4-.99-102
163. (FIIHA 17:2)

F I Sl

GUREVICH, V.R.; DALIN, M.A.; VEDENEYEVA, L.Ya.
Polymerization of ethylene on a chromia catalyst. Azerb.khim.
zhur. no.6:37-43 163. (MIRA 17-3)

SEREBRYAKOV, .1j.V.; DALIN~ H.A.; KONOVALICHUKOV, A.G.
Some regularities in the reaction of cyanoothylation of hydrocyanic
acid. Dokl. AN Azerb. SSR 19 no.11:31-34 163. (MIRA 17:3)
1. BNIIolefin.