SCIENTIFIC ABSTRACT DAVANKOV, A. - DAVANKOV. A.B.
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CIA-RDP86-00513R000509810001-7
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S
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100
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July 28, 2000
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December 31, 1967
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SCIENTIFIC ABSTRACT
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'Re emo I t .~ ?
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1. DAVANIN, A. I.
2. uss,,~ (600)
"Calculation of Characteristic ifigh Water Levels." Zapiski po gidro-
grafii, No. 1, 1948 (43-48).
9. Meteorologiya i Gidrologiya, No. 3, 1949.
4W Report U-2551, 30 Oct 52
DAVANKDV,, A.
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A OCTALLUNGICA L LITERATURE CLAMPKATION
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frWU She pullyincr. 11W clo"llikonk under wbirit.puly-
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Ibe characirrivi" of live protitwi (vWxrihy, =ItcWuq
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V
AA I t a im 0 N w 1 0 IN 9 3 4
Am
; ~
; V
J t
rim I
11 I.
I
0 so* 0 a 0 * 00600.00 0 0 ft 0 0 & 0 0
l
a seel 0 0 00 goes 0 1 .0006 **so*** 0%
'Pas
Oq_;
.4 Dayan
00 SW D. Va. Pmpb. X". iltv".
tustaw 14; ;Q;m I,
oil
41 ~
-1-
'b. b.
i--
Doi
Slow
s0'%
use:
L A StIAL LV"KA% MfNkl$AlCLAMWVATOM
61"s 4" VOUSAV Wei
SMADAID .11 4mv ass musin 824121 da ww Us
u a Ts' a' 'a I W. s A 4 - 2. A-'U
4 0 f ,14w, e
o* 4) 00.0 so's 6 goes 04 0 0 0. * 0 0 4 it Al
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o
DAVAMOV A.B. kandidat takhnicheakikh nauk; PRUPIS,D.Ya., mladshiy
. 0
, nauchn" Botrudnik
Lye-resistant abrasive materials. Xhim.prom.no.2-53-54 F,47.
(Abrasiv )~) (KRA 8:12)
A. 1) fty, A.
. i ~OA vm'u'kur.
~P,41",-,Kkfm by
cmullim Pot;"-Ii" W Stylent
or copoly"Wristim al goptkyj mothmay to and vinyl
actlate with (NIIJAA as a Catalyst. 7U p
Womadeq-dw
is the I,
dyes (0YOW . W moolkyle"u) too the dia-
vicift. log pracm rmh boo cbem inter-
=-betorlubmactbdelbimic dyes= Mk piy~- Two-
"aaclusion was bmd *a tM haverims obkmdo-: (1)
The um of PUM&Ae mtslyst produces
,-haracter (1-4 am Sim or pDaymmor
is pptd. an clamtka OFTIOR camW COOMPICK b" a high
the Z;;. .1 U4M MA Chem. mactlim. (4)
polpmer dimmalm in are. "twoutste som cVWW
win& c"m in the am at SMI its in ukkk the beak dye
by iWI is prmtkaUY IDW- H. K. LAvinpton
DOININ, M.N., skademik. otvetetvennyy redaktor; GAPO, Ye.N.; GAM, T.B.;
ZOEUMINA, Ye.S.; WHINSKIY, V.V.; BIWIKAYA, I,M.; SLIUVAIVA. G.M.;
ROGINSKIY, S.Z.; UNOVSKIT, N.I.; F=. N.A.; K=W, A.V.; NZYYABI, I.Te,;
SLINYAKOVA, I.B.; MUTSIT. F.I.; U)SIO. I.P.; T.ROSrIANSKAYA, Ye.B.;
TIOLINA, A.S.; DAVANKOVI, A.B.; SAWAM, K.M.; BRUMBFM, Ye.M.; IMKOVA,
Z.V.; VZZWVA, Ww.VIT!95W'SKIY. S.A.; MIMYLOVA. Ye.ii,-. KAZANSKIY, B.A.;
RYABCHIKOV. D.I.-, SHWAKIN. 7.M.; EMOVICH, V.L.;BUNDILI. A.A.; SAVINOV.
B.G.; VZW. V.P.; 3PSHTSYS, Y&.A.
[Research in the field of chromatography transactions of the All-Union
Conference on Chromatography. November 21-24. 19501 Issleaovaniia v oblasti
khromatografft; trudy Vseooixtznogo soveshcbaniia po khromatograf-"L, 21-24
noiabria 1950 9. Moskva. Izd-vo Akademii nauk SSSR. 1952. 225-p.
NLRA 6:5)
1. Akademiyu nauk SSSR. Otdolenie khimichaskikh nauk.
(Chromatographic analysis)
DAVANK01r, A.B.; SOKOLOVA. Ye.A.
C"ting properties of awalsion polymethyl methacrylate. Zhur. Prilclad... lhi.m..
26, 217-20 153. '(Ww .6:3) -
(CA 47 no.21:1179~8 15)).
WA-1
R=nkov, A. AA1W_ "Ob Isbiratellapi.adsorbtaii krasitelei iskusstvernyni
e adjRrbtion of- y s .yn
affio ami") Selectiv thetic resins, Zhar. Prikl.
Khirtiis. Vol 26, No 12 pp 1,299-90,l .Dec. 1-953
Study of dying bydkophobje,resins by,aqueous 86114tions of organic dyes. It
was found that the polymers of,- Ivinyl chloride, in presence of peracidic
substances exhibit pronouncpl sid 'soO~ttveproperties with respect,to basic
dyes's Acid and dinct'dyes do 't"
no extract tolyvirWl chloride from its aqueous
solutions. It is possible to separate It4susing polyvinyl chloride. Chemi-
cal similarity between basic dyes and polyvinyl chlokde indicate the presence
of furctional groups.
DAV 01T, A B.
--Ne-W-M-OW073 of dep anol nofindust wastwwaterz.-~
"7- P2
A. B koy and eva 1. 'Met-deleev
mmW . G(OtANA 9 -.Vftffff~ , 1939,
Tn-ii-ex-EFE-nge r-eilns are'sathfactory fo
r
the re
re oval 61 ghenols from'samples of Industrial waste
liquor.b,.j the la . scale. The most satisfactory renins of
IoWjnanuf;,Pxe MP\FKh, N-0, TN, PH-9, and EDR-10.
Poiregenemflon of the mini, the soIns. of NaOH or N11,011
areused. The: conc-n. -4 phenols in the regencmdon liquor
Is btlow 12%, G. hl, Kosolipnff
DAVAINOV, A. D.
"Concerning the Extraction of Nenol Fron. Aqueous So-3cutions by Yeans of Arl:,-ordte
Res ins .H an article included in the book It-The Theory and Practice of the Application
of Ion-Exchange Agents 11 edited by K. V. Chmukov and publi.shed by flip AS USSR 1955,
164 pp. P
PAVANKOV,
- ~-~
Selective adsorption of dyes by synthetic resins. Soob.o nauch.rab.
chl.VXHO no-1:32-38 155. (MIRA 10-10)
(Dyes) (Adsorption) (Resins, gynthatic)
K A - CS,
USSR/ Anrlytical Chemistry Analysis of Inorganic Substances G-2
Abs Jour Referat Zhur Khirdya) No 4)~1957o 12045
Author Davankov A.B., Laufer V.M.
Title DeteriAnation of Precious Metals by Means of Ionites
Orig-Pub Zavod. laboratoriya, 1956, 22) No 7) 188-789
Abstract Snall amounts. of Au.and Ag (fractions of mg per 1 'iter)
are separated1rom cyanide solutions with an anionite.
So 5. oixtaining KAg(CN) or HAWC14, is
lution of PH 3, a
passed throud), an cadoorption colmm fiiied with anion-
exchange resin NO in thb chloride forn. In tho case of
solutions containing 0.5-20 rg/liter Au., fed into an ad-
sorption colwm
7-8 rzi in diameter, with a resin layer
250-300,i= In depth)_rato of filtration must not exceed 15
ml/n, inut.e. - With. solutions, containing large excess of mi-
neral.salts Ororganic admixtures the rate of filtration
Must be decreased. The amount of solution that is filtered
through.the adsorbent is detemined by the initial
Card '3L/2
t fir'n of -etq tic
ei. I from
-
L
11,9
-
,77
,
;
t
V
.
S
1
.
IMM
.
'
I
V
AM v. M-L-'aler.
!howa rAt
highly pnrtyas specumem uf -luade UU43a "t1tallp
;-eArs vvc-re e5e~~tjve in exin. of Au Ir,,in waste liquo-ri,
AJW combustion of the ruin, from M%~ to 100% -flu was
rccDvtytJ. The baQe liquors wete made sliglitly urid with
IICI und -,-t: th, puwd. rt.4iis 1 5 lirs.,afte;
which the r,~iL'uiu wa, !~cpd, wa-stied, mid ipiAvd.
G. M. Ko-~Iaj~"ff
-2"
DAVANKOV. A.B.; LAUM. Y.M.
Ion exchange and the distribtuion of gold ions in repinous absorbents.
?Svet.met.29 no.11:1-6 N 156.. (MLHA 10:1)
(Ion exemage) (Gold)
. .
.
..
.
.
..
.
, ds"-Wo
ate V XIAilf# (2h. PW. Rhim 1959
A
imssins, in byar 4
(1): CW
a) and sulphato (IM formr, vrith grain si2ee 0-5-*-8 mra..
Were used $or too recowry of gold irom. yum sq. selutions Lq
Y-AujCNj and tom indus trW wast6 (chlay from plating bsth3).
-
1
,nth filt-ation rate
gold In YzIntlom vras 24 mg,/L. p1l 7 -,
Amovnt 0
'
!~S,Dw, recovery of gold
10 ml-jmiz and -E =i layer d th 190 mm
- R
th
d
~
9
~
!W
ep
en resiz
eld-d
1
vrAs achi-yed 1~y U; I and
%.
3
8S797-22o-'-J'
md 74-215,~
ns
77
cab "
A. t,
ka
'
7-7-
77- -77 7
.
'if
'
:~
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7
7
DAVANKOV, A. B.
CHMUTOV. I-V-;otvststY*nAYY roda*or; SHRMYMN.;Y.M., profesRar, otyst-
styanVy rodaktor,- WAX rodaktor; RACHINSKIY Y.Y.,
redaktor; SAIADA Ir.,X.M. rodattor; bmiov, P.L.,Iprofeseor, re-
daktor; TROSffANSKATA. Ye.V., professor, redaktor; 73GOROV, N.G.,
redaktor izdatelletya; ASTAYIYIVA, G.A., tokhnicheskiy rodaktore*
[Studies in ton-exchange chromatography; work of the conference
an the application of Ion-exchange chromatogr&pby in medical and
food industrY3 Isslodovanila v oblanti lonoobvencoi khromotografill
trudy soveshchaniia po primen-aniiu tonoo*bmennoi khromatografil T
meditsinkoi i pishchevol promyshlennoiti.' Moskva, 1957- 193 1P.
WaA 10:6)
10 Akadeadys, nauk SSSR.Komissiva po khromXtografii-2*Chloz-k*r-
respondent Akadeall zauk SSSR (for Chmutov)
(Ion exchange) (Chromatographic analysis)
SOV/137-58-8-16648
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 8, p 58 (USSR)
AUTHORS: Davankov, A.B., Laufer, V.M.
TITLE: Recevery of Precious Metals by Ion Exchange and Secondary
Processes Occurring in Ion Exchangers (Izvlecheniye dragots-
ennykh metallov s pomoslich'yu ionnogo obmena i vtoriclinykh
protsessov, osushchestvlyayemykh na ionitakh)
PERIODICAL: V sb.: Materialy Soveshchaniya po primeneniyu ionnogo
obmena v tsvetn. metallurgii. Moscow, 1957, pp 73-79
ABSTRACT: A device for saving Au from industrial caustic solutions by
adsorption on anionite resins of low swelling capacity, porous
structure, and fundamental properties favorable both to ion
exchange and to adsorption, has been developed and tested suc-
cessfully under industrial conditions. Dissociation of such
anionites in aqueous solutions with formation of cations of low
mobility facilitates coagulation o-f-Au and ensures speed and
completeness in precipitation thereof on the adsorbent. The
resin is separated from the soluti4by means of a Nutsche
filter. Joint ion exchange and reduction by hydroquinone was
Card 1/2 applied to Ag and Au solutions. This significantly increased
SOV/137-58-8-16648
Recovery of Precious Metals by Ion Exchange (coijj~ *)
7A
the absorptive capacity of "H-0" anionite and made it possible to extract up,
to 112.856 Ag and 114.6% Au relative to the weight of dry resin (and this did
not even exhaust its absorptive capacity). It proved possible to extract up to
721o of the Au in sea water when 50 g resin was used per 500 liter of solution,
but the resin was contaminated by Fe salts. The "H-0" resin is suited to re-
covery of Au frorn highly- contar-ninatcd, exhausted caustic electrolytes, but
regeneration of the resin by the usual means is not possible. "H-011 resin
permitted the extraction of 80-901o Au from a solution of Au resinate in turp-
entine containing 3.5 g Au per liter.
Ye. Z.
1. Gold--Recovery 2. Silver--Recovery 3. Ion exchange resins--Perforniance
Card 2/2
g
P
-4 A
ioti Ail from a
d ar
t
',"
ge an
q.
F At V. us itivt-sti.
roup
..
g
12% On SwOrmg ld
13!~
in vot b
d
1
.
.
'
y
Fri I' Mnd AgNo) Was
Mle a(
irk
it
P
M rhe end of the =W -iey6e, baviiiR ui~, rba'
b ~-
~
1- -
AgNJ-..Zh "T"z pv.7iods Irm 3 hr~
if, ys -I ll~' !v5il: Was -Asll~ ~ilh
-
lbu ChlVridClX-MkljO4lLSj-J.C
it lo
]l 3 5 .
ing 7p
Mitred Ifirbugh the V~Jatmj,
jkn aad G.~5~4 g~ ar -of ris:n -5 U.);
Az were,
AUTHORS: Davankov, A., B., Zambr07skaya, Ye. V.9 SOV/156-58-2-42/48
BorzeUova-,-T.--Y&.
TITLE: On Granular Polycondensation and on Polymerization in the
Production of Ionites (0 granullnoy polikondensataii i
polimerizateii v proizvodetve ionitov)
PERIODICAL: Nauchnyye doklady vysshey shkoly.Khimiya i khimioheskaya,
tekhnologiya, 1958, Hr 2~ pp- 369-372 (USSR)
ABSTRACT: The shape and the physical properties of the particles of the
synthetic resinslused as ionites are of great importance for
practical application. Most of the ion exchanging resins have
with
hitherto been produced as grains of irregular shape ('
sharp edges). They are obtained by crushing the solidified
polymer. The 10 - 15% of dustlike waste forming in this
connection oannot (with one minor exceptiong Ref 1) be
properly used in industry. The costs for their ap lication
as fertilizers in agriculture are too high (Ref 23. The
Polycondensation mentioned in the title is based on the
Card 1/3 solidification of the polymers in liquid state. Thus, crushing
On Granular Polycondensation and on Polymerization BOV/156-58-2-42/48
in the Production of lonites
is not necessary and the waste decreases to 0,3 - 00~-
According to temperaturey intensity of mixing and the
properties of the surface-active substances in the solution,
ionites can be obtained as spheres of different size. This
shape of ionites has a number of advantages as compared to
that of the irregular grains, The problem of the methods of
production of such spherical ionites has not been sufficiently
elucidated in publications (Ref'3). The authors made it their
object to produce several already known and several new
anionites of spherical shape. Final solidification was
obtained by an additional heating of the polymer in liquid
state in different media: oilep benzene, glycerinc, saturated
NaCl- and CaCl - solutions and others. The test results were
2
Obtained by using transformer oil as solidifying medium. On
contacting the oil the polymer drops are covered by an oil
film which prevents the coagulation of individual drops and
thus the formation of greater aggregations. At a temperature
Card 2/3 of 6o - 65 0 and with intensive meelianical stirring
On'Granular Polycondeneation and on Polymerization SOV/156-58-2-42/,18,
in the Production of Ionites
(propeller mixer 200 rev/min) solidification of the drops was
completed after I - 1,5 hours;in conclusion further conditions
for an optimum quality of the spherical ionites are given.
There are I figure and 4 referenceaD 3 of which areSoviet.
ASSOCIATION: Kafedra tekhnologii plastmass Moskovskogo khimiko-
tekhnologicheskogo instituta im. D. I. Mendeleyeva, (Chair
for Technology of Plastics of the Moscow Institute of Chemical
Technology imeni D. I. Mendeleyev)
SUBMITTED: October % 1957
Card 3/3
DAVARKOV.,.A.B.; LAUFM, V.M.; RAZGILIIMYZV, N.Ye.
Extraction of gold from discharge electrolytic solutions by
ion exchange. Zhur.prikl. khim. 31 no.3:494-497 Mr 158.
(MIRA 11:4)
(Gold) (Extraction kCii;6-mistry)) (Ion exchange)
SOV/136-58-5-15/22
AUTHORS: -D&yaglec-ov, A. B.,_-Lauf er , V. M. , Tarusin, V. P. ,
neginsk-ij, O.Ye, and Ruzhnikov, M.S.
TITLE: A Pilot-plant Scale Experiment on the Extraction of
Gold from Ion-exchange Resins After Adsorption
1Foluprox.ysh16hnyy op~,t vydeleniya zolota iz !C'-_;cobirenny1&.
,sir-ol posle adsorbtsii) 91
PERIODICAL: Ts-t,-etnyye Metally, 1958,Avr 5, pp 81 - 82 (USSR)
ABSTRACT: The authors discuss some examples of gold recovery froo-
ion-exchange resins being effected after ashing the resin,
They describe work at an enterprise controlled by the
J_ -ry oS the USSR)
Minizterstvo fina:nsov SSSR (Finance ",Jnist
in wbhh gold was extracted frwr- spent el%~,ctrolytes '~.-Lth
the aid of type N.-O resin in two 1 665-4= high tubes
(73 mm dia.) in series. 9?.6 litres of spent cyanide
electrolyte was passed at 10 litres/hour and an ash
containing ?3% gold was finally obtained., The Cold was
extracted from the ash by high-frequenoy melting under
borax in a graphite crucibla in separate portions. The
experimental data are tabulated, showing 99.8_10jo' recovery of
Card 1/2
SOV/136-58--5-15/22
A Pilot-plant Scale Experiment on the Extraction of Gold from Io---
exchange Resins After Adsorption
the gold present in the original solution. The authors
found that with careful ashin in ceramic vessels and
fusion under borax, complete extraction of the gold from
the ashed residue was obtained.
There are 1 table and 4 Soviet references
1. Ion exchange resins--Adsorptive properties 2. Gold--Processing
Card 2/2 3. Gold--Production 4. High freWiency heating--Applications
DAVANKOV9 A. B.
[Grigorii Semenovich Petrov) Grigorii Semenovicb Petrov.
Moskva, Izd-vo Moak. khimiko-tekhnologichaskogo in-ta,
'1959. 3-1 P. (MIRA 16:11)
(Petrov, Grigorii Semenovich, 1886-1957)
nrv
5(2), 18(6) 0" '1156-5j`-1-52/54
AUTHOPS: Da-vafflzov, A. B., Laufer, V. M.
-----------
TITLE. On Kew Methods of the 10"oncentratic,n of Gold on Ion Ex-
chan,,~ers by the Ai& of Ion Excl.mn-c and of red,;x rrocesses
(0 novykh Imetodakh kontsentrirovaniya zolcta na ion-ita-kh
s romoshchyu. ionnoco obmcna i olcislitclino-voss'uaiiovitellnylch
protr'0200v)
PZRIODICAL: lohlady vysshey sh'z-)ly. Lhimiya i khimic~hesk-nya
tehhmlil -:-iYa, 105", 17r 1, pp 21(;2 - 2o5 (US---'-L1)
ABSTRACT: The ads~r-, tiGn of the gold saits -!AuC! 11 and 1.aAu (C'7) 2 on
synt"otic resin anion excham,ers 1111-011 and "TN", and t'lle
elution of those salts by thiourea or J-j,rdrC,chlc,:Lic acid
in acetone and athyl alcohol are invcsti-7ated. The results
are listed in tablcs. The com-olex AuCl- salts could be
4
reduced by hydrequinono. Thio reduction re-liborzat~os the
ionoacnic groups of 1j-' e excl,an~;er and re-establishes its
excLa.-.,-e cno~acity. *.-iith the Au(C1T)- -ions the reduction
2
c(.1uld no[; bo. effected. Th,,;r3 cn-ltj cuuld, h-~-wcver, be ro-:ii.--vod
Card 1/2 from the resin by wonk basic soluti-ons or by Y,--ncral acids.
- V llr6-~~ 9-1-52,154
()-i Nev Illethods of the concentration or Gold on Ion j k' / ',
and
rs by the Aid of Ion T cf Redux P-occs~;~s
D,cl,ai --c
0C.1"(1 not, bc offectud
--C'1(1 Uluti~ "i
In (JUP-11titative
(Te.bic). The tutal gold ccntant Could be jrc.,,--,rvcd only by
u
the burnin.- uf tl,'c rcsin. There are 2 t,"bics -nd 71SoViel
references.
jr,frij plastmass
A S S -C C I AT D- I iKafedra tchhno
'-3.c;'eskcsjo instituba im. D.
Tcc'~ J:jolo3y of -Ilasticsso-' tile tif Ch'Otical
h
TcchnoloLy ineni D. I. Mendelayc"r)
!-'ay 27, 1'1~58
C ard 2112
5(3)915(8)
kUTHORS: ,,,,.Davan.kov, A. B., Babehinitserp T. M.9 SOV/156-59,0-5-7/48
t zenk6*i"-----
TITLE: Innergranular Chemical Transformatiom in the Copolymeres
of Styrene-With Divinylbenzene (0 vnutrigranulInykh khimi-
cheskikh prevrashcheniyakh v sopolimerakh stirola s divinil-
benzolom)
PIRIODICAL: Nauohnyye doklady vyashey shkoly. Khimiya i khimicheoXaya
tekhnologiya, 1959, Nr 2p pp 363-367 (USSR)
ABSTRACT: The authors investigated two forms of the chemical reaction
in the polymeres mentioned in the title, which were used in
granulated form (diameter 0.25-2.0 mm): 1) Nitriding wfth
following reduction of the nitrogen group, and 2) Chloro-
methylating with following substitution of the chlorine atoms
through aminogroups. Copolymeres with a content of 2P 39 49
and 10 % divinylbenzene were nitrided. After nitriding, the
nitrogen contelit avergged 12-14 % (Table 1). A high content
of divinylbenzene aggravated the nitriding and resulted in
a lower nitrogen content. The nitrided granulate was of yellow
color and its mechanical hardness decreased. The reduction
Card 1/3 was carried out - after am unsatisfactory trLal with zink -
Innergranular Chemical Transformationsin the SOV/156-59-2-37/48
Copolymeres of Styrene With Divinylbenzene
with tin (II) chloride in hydrochloric acid. With increasing
interlacing of the copolymeres, the force of the reaction
decreases (Table 2). The static anion-interohangeabil'ty of
the best resin test-pieces amounted to 6 25 mg-equiv/g for
0-5-normal hydrochloric acid and 7.75 mg:equiv/g for 0-5-nonmi
sulphuric acid. During the second series of tests, copoly-
meres with a divinylbenzene content of 2, 4, 6, 8, and 10 %
were treated with chloromethylether (Table 3) and their
chlorine content was determined. The copolymeres with a
Cl-content of 18-19 % were substituted with trimethylamine.
The rest-content of chlorine amounted to 7-10 %, the nitrogen
content to 2-2-5 %- When treated with pyridine instead of
trimethylamine, the copolymeres contained 9 % chlorine and
also 2-2.5 % N. The static anion-interchangeability was
2-3 mg-equiv/g for 0.1-normal hydrochloric acid. There are
3 tables and 4 references, 2 of which are Soviet.
Card 2/3
Innergranular Chemical TransformatiorBin
Copolymeres of Styrene With Divinylbenzene
PRESENTED 13Y* Kafedra tekhnologii plastmass
gicheskogo inbtituta im. D. 1.
Technology of Plastics Moscow
imeni D. I. Mendeleyev)
SUBMITTED: December 11, 1958
the SOV/156-59-2-37/48
Moskovskogo khimiko-tekhnolo-
Mendeleyeva (Chair for the
Institute of Chem.,cal Technology
Card 3/3
_S10- 81/'60/000/019/00'1/0 12
AOO6/AOO1
Translation from: Referativnyy zhurnal, Xhimiya, 1960, No. 19, P. 522, # 7936.9
AUTHORS-, - Davankov, A.B., Zambrovskaya, Ye. V.
TITLE: The Use of Acid Esters of Dithiocarbonio Acid as a New Type of
Ion-Exchanging MaterLal_~
PERIODICAL: Tr. Mosk. khim.-tekhnol. in-ta im. D. 1. Mendeleyeva, 1959, No. 29,
PP. 72-b2
TEXT: The possibility was established of converting watier-soluble salt's of
various acid esters of dithiocarbonic aoid (ethyl and butylxarithogenate of
potassium, cellulose xanthogenates, 'polyglycerins, poly-viryl alcohol and its
copolymers with malein anhydride) into a non-soluble form by means of adsorptlon
on. the "H-D" resin. The authors studied the exchange capacity of ionites ot.-
Ways were found of
tained under dynamical conditions from AgN03 solu4_'(,_"s-
3oncentrating on the aforementioned adsorbents gz~at amoun-ts cf silver with the
use of reducing agents (19 - 31 mg-equ/s). A zynthe,-is was di~veloped of a con-
densation. MMC (MMS) resin containing sulfohydril groups (5.76% S) . Investigat-iMS
Card 1/2
S31/0 81/60/000/019/007/012
A006/AOOI
The-Use of Acid Ez-'-",ers of Dithiocarbonic Acid as a New Type of Ion-Exchanging
Material
were made of the sorption capacity of the resin (granulated and non-grarulaved)
with respect to Ag cations at 20 and 60 0C. and of the possibility of-extracting
silver vat of the column.
Ye. Zambrovskava
Translatorts note: This is the full translation of the original. Russian abstract.
Card 2/2
S/081)ra 1/000/00 i/b 14/0 17
AOO~/A105
Translation from, Referativnyy zhurnal, Kftimiya, 1961, No. 1, P. 515, # IP39
AUTHORS- Davankov, A.B., Davankova, D.A.
TITLEt On the Problem of Chemical Transformations of Polyvinyl Alcohol
PERIODICAL: "Tr. Mosk. khim.-tekhnol.,in-ta Im. D,1. Mendeleyeva!', 1959, No.
29, pp. 93 - 98
TEXT: The authors investigated some chemical transformations of polyvin-yl
alcohol. Hereat benzyl ethers of polyvinyl alcohol were obtained with a high con-
tent of benzyl groups (66.4%), and their properties were studied. Chlororhethylat-
ed derivatives of the benzyl ethers of polyvinyl alcohols were obtained. It is
establishqd that the disintegration of the polymers in consequence of nitrating
of the benzyl ethers of polyvinyl alcohol and subsequent reduction of the nitro
gr,,-)ups into amino groups is observed, which leads to compounds that are soluble
in alkali hydroxides; highmolecular quaternary ammonium bases with exchange capa-
Cara 1/2
S/08 1/6 1/'000/002/0141-117
AQ05/A105
On the Problem of Chemical Transformatio~is of Polyvinyl Alcohol
city for 1 n-solution of HCl 1.5 mg-equ./9 were obtained by chloromethylizing of \j
ordinary benzyl ethers of polyvinyl alcohol with their subsequent treatment with
trimethyl amine hydrochloride.
E. T.
"Iranslat-orls note: This is the full translation of the original Russlan abstract.
Card *2/2
ZURAKOVA, L.B.; PA!~~OV~ A.B.
Chemical conversions In granular 2-mtbyl-3-yinylpyridine-divinyl-
benzene copolymers and other cross-linking agents. Trudy NMI
no.29:99-107 059. (KIRA 13M)
(ftlymers) (Pyridine) (Benzene)
DAVANK07, A.B.; ZAMBROVSKkyA, YO.V.
Extracting silver by ionitem modified by the adsorption of xanthic
acid. Izv. vys. ucheb. zav.; tevet. met. 2 no-3:82-C8 '59.
(MDLA 12:9)
l.Moskovskiy 1-.himiko-takhnologicheakiy institut, Kafedra tekhnologii
plastmass. (Silver) (Ion exchange)
DATASKOV, A.B.; LILUM, T.H.; RAKITIN. S.V.; LVIAN, L.G.; CHXRMBkY,
Recovery of noble metals by anion-exchar4ge resins from waste
and. industrial solutions of electrolytic copper plants. Izv*
vys.ucheb.zav.: toyet.set. 2 no.6:134-141 '59.
OaRA 13:4)
1. Moskovskiy khiaiko-tekhnologich9str,4-, LLstltut. Kafodra
tekhnologli plaStimes.
(Copp'er industry-By-pproducts) (Ion exchange)
(Precious metals-Metallura)
5(2) SOV/eO--32,-4-5./47.
AUTHORS: Davankov. A.B... aufer, V.M.
--------------
TITLE% -
Or. the Problem of Elution of Precious Metals From Anionites
After Adsorption (K voprosu ob-elyu-irovanii; blagcrodnykh,
metallov iz anionitov posle adsorbtsi,i)
PERIODICAL: Zhurnal prikladnoy khimii, 1959, Vol 32, Nr 4, PP 727-734
(USSR)
ABSTRACT: The el-ation and relative resistance tc reducing agents of
complex ions(AuCIZ, A,(CN)~) adsorbed on anionites is inves 'ti-
gated here. The A,;,""
-4 ions adsorbed.on. a "E-011 anionite are
easily red,.,cied to metal by hydrcquinone. They a ccumulate on
the resin after several. sorption cycles in the quantity of
'
more than 5 mg-equ. per gram of adsorbent., The Au(CN)2
ions
are displaced by the solutions of sodium sulfide, hydrosirl-fide
and kydrosulfite whithout reduction. This indicates the high
resistance of cyanide anions to reduction and depc!~ition
action of these agents. It is known that thiourea enters into-
the reaotion of complexformation with metals, the sulfides of
which are insoluble in water. The thiourea complexes are ..
Card 1/2 easily decomposed in weakly alkaline solutions with the forma-
SOV/80--32-4--5/47
On the Problem. of Eluti~-n of Prec:io,~.s Me"als From Anionites After Adsorption
tion of sulfides. In is possible to extrac1t; 'l-he precious
mietals Lompletely from resin adsorbents by this met-hod. 'The
beL~t res-ilts are obtsined with a 2.0--sclution of 'l-hio-area -and
a 13%-solut Lon of hydrochlor:~o acido Kurnakcv is -tuentioned in
the text.
There are tablee, I graph, ar.d 2 Sov-lat refererj~r_-3.
ko
SUBMITTED: September 1.9. 10:~-
Card 2/2
-15-3610 75675
SOV/80-32-10-24/51
AUTHORS; Davankovj A B Oratynskaya, A. N., Laufer, V. M.,
Irp-5-skly, A G.
TITLE: Deionization of Acid Albumin Hydrolysates by Anion-
Exchange Resins
PERIODICAL: Zhurnal prikladnoy khimii, 1959, Vol 32, Nr 10, pp
2269-2275 (USSR)
ABSTRACT: Various domestic ion-exchange resins were tested for
the separation of amino acids from the mineral acids
residue in casein hydrolyzates. Slightly basic MMG-1
and AN-2F, medium basic N-0 and EDE-10P, and strongly
basic AV-16 anion-exchange resins were investigated.
EDE-10P and AN-2F resins gave the best results; the
adsorption of Cl- and S04__ was complete, and that of
amine nitrogen insignificant. The degree of deioniza-
tion can be quickly determined by the pH value of the
filtrate. When pH < 5.5., the deionization is practi-
Card 1/2 cally 100%; at pH = 5.5 to 3.5, the Cl- content is
Deionization of Acid Albumin Hydroly3ates by
U
Anion-Exchange Resins
7 f:j '75
0
SOV/80-32-lo-24/51
below 0.2%; pH4 3 shows a low degree of demineralization
of the hydro.lyzate. The laboratory tests were repeated
with practically identical results in a p.*'L.-'Lot installa-
tion with stainless steel filterIng column of icn-
exchange resin eapacity- are 5 ta-ble--i I flgure;
and 5 Soviet references.
SUBMITTED: July 21, 1958
Card 2/2
DAVANKQV,_Alaks&-f'r oriso-vich-, FEWHENKO, V., red,; VOLYNTSEVA, V.,
jakhn.red.
[Magic grains] Volshebuys serna. Moskva, Izd-vo TaK VM3(
ONolodaia gwardil:.," 1960j, 60 p. (MIU 13:8)
(Ion axe-hangs)
5"%r5SO$
A 12J 0
AUTHORSg
TITLE-.
CAD Z101 'ZIDS
83701
Sllgo"601002100610061012
B015XBo64
Davankov, A. B., Zubakova, L. B.
Synthesis and Investigation of Highmolecular Tertiary
AminesAand Quaternary Ammonium Compounds on tha Basis of-
the Copolymerslof 2-Methyl-5-vinyl Pyridine With Various
"Interlacing" Agents
PERIODICALa Vysokomolekulyarnyye soyedineniya, 1960, Vol~ 2, No. 06,
PP- 884-890
THM An industrial method of producing 2-methyl-5-vinyl_p1rid~ne
(Ref. -1) was developed in the Yaroslavskiy nauchno-issledo-Vatel's I
institut monomerov (Yaroslavl' Scientific Resea-roh Institute of Monom-krs)v
serving as a basis for producing important types of synthetic rubb~lr
(Refs.. 2,3). The preseiit Investigation-deals with the me,%hanlsm and ',-.he
conditions of a copolymerization of 2-methyl-5-vinyl pyridine with
divinyl benzene (2-6%) and triethylene glycol dimethaorylia ester (2-20%)~-
The high-molecular tertiary amines t)btained were t7ans!ovmed into
insoiu'bla -.quaternary ammcnium bases by alkyla~,Ion. and the pxoduo+3
V~
Card 1/3
83?01
S/19
Synthesis and Investigation of Highmolecular . 0 (:,~~/,,N2/006/006/012
Tertiary Amines and Quaternary Ammonium Compounds B015YB064
on 4--he Basis o1 the Copolymers of 2-Methyl-5--vinyl
Pyridine With Various "Interlacing" Agents
obtained sZbJected to different physiao-chemical tests (anion exchange,
ohemical stability, water absorption, swelling in organic solvents ets:1),
On heatingi or irradiating 2--methyl-5 .__V4 nyl pyridin-a with 0~44 of ben?.Oyl
peroxide only with a quartz lamp of the n-PK -2 (PRK-,2) typed the reattior
products obtained were only soluble in organic solvents,, Copolymeriza-
tion at 70-800C (end at 1000C) and a duration cf 4-5 h of 100 parts by
weight of 2-methyl--5-v~.nyl pyridine and 4 parts by weight of di7inyl
benzene besides 0-4 parts by weight of ~enzoyl peroxide in suspension
resulted in a solid copolymer, insoluble in organic solvents, with weekly
alkaline character, and anion exchanger properties (Table 1). k1kylaUon
was carried out in the same cylindrical glass reaetion vessel as co-
polymerization, with benzyl chloride; para-toluene sulphomethylate, ethyl
iodide and mathyl iodide being used. Products of benzylation and methyla-
tion with para-toluene sulfo acid methyl eatter had the highest capaoilty
of exchange. The degree of alkylation rises with the reaction tine, An
action of strong acid solutions (5 N and 9 N HNO 3P H2so 4) and lyss
(1 N and 9 N HaOR) upon the anion exchangers in the form of tertieTy
Card 2/3
83701
Syynthesis and Investigation of Highmolecular 5/190/60/002/006/006/012
Tertiary Amines arid quaternary Ammonium Compounds B015/3064
on the Basis of the Copolymers of 2-Methyl-5-vinyl
Pyridine With Various "Interlacing" Agents
amines was found to cause no reduction or their static and dynamic
exchange capacity with respect to 0.1 N HC1 k-Ta,)Ie 2). The exchangers
have a high absorptive power for phenol from ag.ieous solutions and a good
exchange capacity for silver cyanide complexes~ There are 1 figure, 2
tables, and 9 references, 7 Soviet and 2 US.
ASSOCIATION& Moskovskiy khimiko-tekhnologicheskiy institut im,
D. I. Mendeleyeva (Moscow institute of Chemical Technology
imeni D. I. MendeleyevT
SUBMITTED& February 19, 1960
Card 3/3
S/190/ 60/002/009/020/023/XX
B004/BO56
AUTHORS: Davankov, A. B., Zambrovskaya~ Ye. V.
TITLE: Synthesis and Application of Polymers With Thiol-- and
Thione Groups
PERIODICAL: Vysokomolekulyarnyye soyedineniya, 1960, Vol. 2, No. 9,
pp. 1330-1334
TEXT: The authors aimed at producing a cation exchanger containing SH-
and =S groups and which, besides being used for analytical purposes, may
also serve for the separation of metals, whose sulfides are difficultly
soluble in water. For th.& synthesis of such an exchanger--resin, the authors
used two methods. 1) The'ICArr(SDT) resin was obtained by the treatment of
a chloromethylated copo-rYi-erof styreneland 2-4% divinyl benzene with
thiourea. The SDT resin contained 11.3 -: 15.48% sulfur, and was hydrolyzed
by means of 5% NaOH. The yield was 70--65%, referred to the initial chloro-
methylated copolymer. The sorption properties of this resin are only little
influenced by the pH. The dynamic exchange capacity, measured by means
of 0.1 N AgN`0,, amounted to 2.7 - 2.8 mg-eqtdy'19. The regeneration was carried
Card 1/3
Synthesis and Application of Polymers With S/190/60/002/009/020/023/XX
Thiol- and Thione Groups 13000056
out by reducing the silver with NaHSO 3 or Na2so 3" When NaHSO3 ?ias used,
no decrease of the absorption capacity occurred. In eight cycles of sorp-
tion and regeneration, 238.7% Ag, calculated per weight of the resin, and/
or 22.1% mg-eqiAv/g referred to metal were adsorbed on the cation exchanger.
2) The'CHrjSNK) resin was obtained from a polymer containing amino styrene
and 2%=iATinyl benzene by means of diazotizing with an excess of HNO 2 at
50C and treating the diazo compound with potassium ethylxanthogenate, The
sulfur content of the resin was 5,16 - 6.10%. The dynamic exchange capaci-
ty determined by means of AgNO 3 was 2.13 mg-equiv/g. Also in the case of
this resin, NaHSO proved tobemore suited for regeneration. because the
capacity did not aecrease to such an extent as when using the Na 2so The
authors further investigate;ffH(TN) resin synthesized by A. B.,DavaKov
and V. M. Laufer in the kaf-eTr-aplastmass (Chair of Plastics) of their
institute. TN is a polycondensation product of thiourealmelamine and
formaldehyde. The exchange capacity, which was T-eT-ermined _~ccordilg; to the
above method, vas 2.70 - 4.44 mg-equi~/g, There are 3 tables and 6 references:
1 Soviet, 2 US, and 3 British,
Card 2/3
F
Synthesis and Application of PolymvrB With S119016010021009102010231XX
Thiol- and Thione Groups B004/BO56
ASSOCIATION: Khimiko-tekhnologicheukiy institut im. D. I. Mendeleyeva
(Institute of Chemical Tech.ology imeni D,, I. Idendeleyev)
SUBMITTED: March 29, 1960
Card 3/3
DAVANKOV, A.B.; 1AUPER, V.M.; IOSILIVICH, A.I.
New methods of sorption and desorption of silver by ionites in an
electric field. Izv. vys. ucheb. zav.; tsvet. met. 3 no.4.61-88
,60. (MIAA 13:9)
1. Moskovskiy khimiko-tekhnologicheskiy institut. Kafefra tekhnologii
plastmass.
(Silver) (Ion exchEtnge) (Zlectric fielde)
24738
S/080/60/033/007/024/024/XX
15'.-Noo D270/D304
AUTHOR: Davai-dcov, A.B. and Morovintseva,-11I.A.
TITLE: Intragrannular chemical.transformatlons in copolymers'
of viny-1 toluene irith divinyl benzene
PE1110DICAL: Zhurnal priltl.~dnoy Ithimii, v. 33, no. 7, 1960, 1676-
1679
TEXT: The relationship between the structure of polymers and their,
transformation, especially for the little-studied compounds of.vi'
ny-;
lene N-rith benzene and tolueneY has much practical and theoretical
significance, so the authors investigated the c6polymerization of
vinyl,toluene with divinyl benzene and the conversion of this'com-
pound into a high-polymer amine. Copolymerization is effected-in
-water in a glass cylinder fitted with a mechanical. paddle-mixerand
reflux condenser. After heating at 75 - 85c)-for 5 - 6 hours on a
water bath small c% anule 1i
Mr g; (di am. 0.25 - 1 mm)-wl- ch assume a reddish
color on washing a-nd drying, are separated'from the solutions... The
relationship is shou-n,"L"irst -noted by Ye. B. Trostyanskaya et al
Card 1/3
24738
S/080/60/033/007/624/024/,~Y.
Ihtragranular chemical... D270/D304
(Re-'. 4: Khim. nauka i prom., 21 5, 593, 1957).of the numbet of lat-~
eral bonds in the molecular lattice of the copolymers to the swell-
ing,of the granules in dioxane. Nitration is accomplished by cobl-
ing a mixture o" the granules with HI'103 and H9S04
and then heating.
it -on a water bath for *2'* .! 6 hours at 73' - 80U. Depending on the
exact teraperature- and length of nitration, intermediate.-products
with'a content of- 3.55 9.2976 N2 are obtained, possibly thro.ugh
the following reaction:
-CII-CHt- -cli-C112-
IN
.24. Not
H3~
CO
N02
The nitro groups are-subsequently changed into 'amine groups by'thei3~~
reduction with SnC12 in HCI at 1000. The granules thus synthesized'
have a dark-bro~-m. or black color, the yield being 73 - 9.5% The
.most complete nitra 'tion and reduction results *from an original
ture containing the least divinyl benzene 2_475~ of the weight of
Card 2/3
24736
S/080/60/033/007/024/024/XX
Intragranular chemical... D270/D304
vinyl toluene. Unde these conditions the exchange capacity of the
amino-resin is 5.5 and 5.9 mg equivs/g for 0.1N HC1 and 0 *5 H2SO4
respectively. The most stable granules, however, are prepared
from copolymers containing the maximum amount of divinyl benzene -
8-10%-. In conclusion the authors stress the importance of the re-
lationship between the nitration and reduction reactions and the
number of lateral bonds in the molecular lattice of the studied
copolymers during during their-conversion into amines. There are
I figure, 2 tables and 4 references: 3 Soviet-bloc and 1 non-Soviet-
bloc. The reference to the English-language publication reads as
follows: H. Zentman, J. Chem. Soc., 982 (1950).
SUBMITTED: December 7, 1959
Card 3/3
39U9
S/081/62/000/012/063/063
B150101
16"S t Do
AUTHORS: Davankov, A. B., Zambrovskaya, Ye. V.
TITLE: Synthesis and application of high molecular compound-s-
containing thiols and thionic groups
PERIODICAL: Referativny;f zhurnal. Khimiya, no. 12, 1962,- 669, abstract.'
12R89 (Bb."Isaled. v obi. prom. primeneniya sorbentov.11
M., AN SSSR, 1961, 27-~O)
TEM. Sty-rene'copolymers with 2-4-/6,.divinyl benzene,.which contain
sulfhydry- groups and are weakly acid cation exchange resins, are
produced by the action of a solution of thiourea kin-whte~'or dioxane)
on a ohloromethylated granular copolymer' (0.8:1)-with a 70-85~ yield ands
a sulfur content of 11-3-15-3~. The exchange capacity from a 0.1 11
solution of AgNO after 8 sorption cycles is 22.1 milliequivalents/g;
3 !4'
the Ag+ is reduced with a 10 NaRSO solution.. Ion exchange resin,-
3
containing functional SH groups, is obtained also by diazotizing a-co-
polyimer of a7dnostyrene (11A N and divinyl benzene avollen in
2)
Card 1/2
DAVANICOV, A.B.; ZJLNBROVSKAYA, Ye.V.; GERASHCHENKO, Z.V.
Synthesis and study of sulfhydryl derivativen of
polystyrene and its copolyners. Part 2. Vysokom.soed.
3 no.10:1468-1473 0 161. (MIRA 24:9)
1. Moskovskiy khimiko-tekhnologicheskiy institut imeni D.I.
Medeleyeva.
(Styrene polymers) (Mercapto compounds)
DAVANKOV, A.B.; VITOL, O.A.; FAYNGOR, BA.
Chemical transformatioris of gramilar copoly*rs of vinyltoluene
with diviny-lbenzene and other "cross-linhing" agents. Part 1:
Chloromethylation of vinyltoluene and divinylbenzene copolymers.
Vysokom.soad. 3 no.10:1566-1571'0 161. (MIRA 14:9)
1. Moskovskiy khimiko-tekhnologicheskiy institut imeni
D.I. Mendeleyeva.
(Benzene) (Toluene)
DAVANKOV, A.B.; LAUFER, V.M.
Electrochemical. method of aorption knd desorption of-silver
on ionites. Izv.-vys. ucheb. zav.; tsvet. met. 4 no.4:121-123
161. (MIRA 14:8)
1. Moskovskiy khimiko-tekhnologicheskiy institut, kafedra
tekhriologii.plastwils.
(Sorption) (Silver ions)
(_. AVANKOV,__A_&-~-aBAKOVA,, L.B.; SPAMOVAp N.A.
F(xtraction of nitrophenols from sqtLeom solutions by anion exchange
resJns. Zhur. prikl. khim. 3tjnq.2s403-4(Y7 F 1619 (NIRA 3.412)
(Phenols) on exbhange) *
DAVANKOV, A.B.; ZUBAKOVA, L.B.j ANTONOVA, A.B.
Preparation and chemical converaion of macro-molecular tertiary
azineo into quaternary pyridine bases. Zhur. prikl. khim. 34
no*5:1310-1116 My 161, (KERA 16%8)
(Amines) (Pyridine)
DAVAM UO. A.B. ;APTOVA. T.A. GITERM Z'SH.
!-r6ductioni-Triocesoes.ai 4on on
,,04dition ad oll*er 66h6ontrat
iloirm-"Change ''ri., -0c.8:1852-
Ag 161 14:8)
(saver),
w-ftduetion -eacti*),
(idn exchange r~sius)
DAVANKOV, A.B. (Moskva); LAUFER, V.M. (Moskva); GoRDIYEVSKIY, A.V. (Moskvai
Storerooms of the Atlantic Ocean. Priroda .50 no.12:101-103 D
,61. (MIRA 14:12)
(Atlantic Ocean--Uranium) (Ion exchange)
DAVANKOV,-Aleksandr Borisovich,- FAYNBOYM, I.B., red.; RAKITIN, I.T.,
tekhn. r,,id,,*-'--,---'-',-,
[Ion exchangerslionity. Floskvra, Izd-vo "Znanie,," 1962. 40 P.
i'. (Novoe v zhizni.,.nauke,,ekhnik6. IV Seriia: Tekhnika, no.2A.)
(HIRAL 15: 12)
(Ion exchange resins)
~j
S/149/62/000/002/007/008
Aoo6/Aloi
AUTHORS: Da ankov,-A. B,,, Laufer, V. M., Azhazha, E. G., Gordiyevskiy, A. V.,
2
.Kiryushov, V. AN.
TITLE,: Experiences in extracting uranium and other elements from Atlantic
Ocean water
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy, Tsvetnaya Metallurgiva, no.
2, 1962, 118-3.23
TEXT: Experiments of extracting various elements from Atlantic Ocean
water were carried out in 1959,.during the sixth Atlantic expedition of the
Marine Hydrophysical Institute of AS SSSR. Water from various parts of the
Atlantic was filtered through an absorption column mounted on board the expedi-
tion vessel. This vinylplastic column, 1,600 mm high with 63 mm internal diam-
eter, was filled with 3.5 kg granulated H-0 anion-exchange resin in C1 form of
64% moisture. An amount of 59,189 liters of water was filtered through the
column at an average rate of 40 1/hour. The qualitative and quantitative deter-
mination of various elements in the resin was carried out by radiometric
x-radiation, luminescent and polarographical analyses. The amount of uranium
Card 1/2
S/149/62/000/002/007/008
Experiences in extracting uranium Aoo6/Aioi
extracted on conversion to the tdal amount of air-dry H-O resin was 303 mg
according to data of radiometriciLl analysis; 413 mg according to luminescent
analysis, and 417 mg-'accordirijg;to polarograph~cal analysis. The pranium content
in the Atlantic water calculz.~ ed from these data was: 5,12 . 10-13 g/1; (radio-
metric analysis); 6,99 - 10- g/1 (luminescent analysis) and 7.04 10-6 g/1
(polarograghical analysis) or og conversion to normal sea water 4.7 10-6g/kg;
6.41 - io- g/kg and 6.47 ' 10- g/kg, respectively. Semi-quantitative spectro-
scopical analysis of ash residue after burning the 0-H resin was used to estab-
lish the presence of small amounts of silver, strontium, bismuth, zinc, copper,.
manganese, iron, aluminum, silicon, calcium, magnesium, and sodium. The silver
content in the absorbent was determined by cupellation of the ash residue after
barning 200 g 0-H resin. An amount of 2.5 mg pure silver was then separated out
which is 5.75 , 10-7 g per one liter of water. There are 4 tables and 13
references: 6 Soviet-bloc and 7 non-Soviet-bloc
ASSOCIATIONS: Moskovskiy khimiko-tekhnologicheskiy institut (Moscow Chemical and
Technological Institute); Kafedra tekhnologii plastmass (Depart-
ment of the Technology of Plastics)
SUBMITTED: February 25, 1,061
Car d 2/2
S/190/62/004/007/008/009
B119/B180
AUTHORS: Vitol, 0. A.
TITLE: Chemical rearran-ements of granular copolymers of vinyl
0
toluene with divinyl benzene and other "crosslinking" agents.
II. Chloromethylation of copolymers of vinyl toluene with
ethylene p la'
.,lycol and diethylene glycol di,-,Iethacry tes
1062,
ZIERIODICAL: 'Tysokomolekulyarnyye soyedineniya, v. 4, no. 7,
1093-1097
TEXT: The authors studied the chloromethylation of vinyl toluene - ethylene
glycol dimethacrylate and vinyl.toluene - diethylene glycol dimethacrylate
in granular fo�m (grain size 0.5-1.0 mm) by means of monochloro methyl
ether in the presence of SnCl4 and ZnC12 as catalysts. The content of
ethylene glycol dimethacrylate and diethylene glycol dimethacrylate in the
polymer was 2, 6, or 10~4. Reaction time and catalyst concentration wie~re
varied in the experiments between 0.05 and 0.75 moles SnCI 4' or 0.1 and
0-75 moles ZnCl2 per base molecule of the copolymer. The following
Card 1/2)
S/190/62/004/007/008/009
Chemical rearrangements of granular B119/B180
optimum ::eaction conditions were found: reaction time 2-4 hr, dependirig
on the co-,itent of crosslinking agent; 6-1051 crosslinking agent in the
CoPol.ymer; 0.3 moles ZnCl2 per base molecule of copolymer in the '
reaction --aixture.' Copolymers containing 28.8~6 chlorine were obtained,
corresponlimg to 158 chljoromethyl groups per 100 ben7ene nuclei. Reaction
times-over 4 hr reduce an existing; chlorine content (formation of methylene
bridges ivith separation of H01). Catalyst contents over 0.3 moles per
base molecule of 7poly-mer cause a higher C1 content in the final product,
but reduce its mechanical strength. There are 4 figures. The most
important Engliah-language reference is: K. Pepper, H. Paisley, 11. Young,
J. Chem. Soc.,-1953, 4097-
ASSOCIATION: Moskovs 'kiy I-,himiko-tekhnologicheskiy institut im. D. 1.
Islendeleyeva (11,0800%V Institute of Chemical Toohnology imeni
D. 1. Mendeleyev)
SUBBITTED: May 3, 1961
Card 2/2
DAVANK UFER, V.M.; AZHAZHA, E.G.; GORDIYEVSKIY, AN.; KIRYUSHOV,,
V.N.
Recovery of uranium and other elements from the water of the
Atlantic Ocean. Izv. vys. ucheb. zav.; tsvet. met. 5 no.2:118-
123 162. (MIRA 15:3)
1. Moskovskiy khir-iiko-tekhnologicheskiy institut, kafedra
tekhnolo ii plastmass.
Rtlantic Ocean--Uranium) (Marine resources)
BAKHRAXH, Ye.E.;--PA
,YANKQV-,-A,,B.; MARTEIRS, L.A.; LAUFER, V.M.; SOKOLOVA, N.M.;
OBUKHOVA, Z.A.; FILIPPOVA, N.Ye.
Cultivation of the plague microbe on media of acid casein hydrolysate
demineralized using an ion-exchange resin. Zhur.mikrobiol.., epid. i
immun. 33 no.3:51-55 Mr 162. (MIRA 15:2)
1. Iz Gosudarstvennogo nauc~no-issledovatollskogo instituta
mikrobiologii i epidemiologii Yugo-Vostoka SSSR "Mikrob".
(PASTEURIWA PESTIS) (CASEIN) (ION Examm RE-biNs)
S/080/62/035/004 /006/022
D267/D301
AUTHORS: Davankov, A. B. , Lauf er, V. M. , Bortel E. --nd Tep-
lyakov, M. M. --
TITLE: Sorption and subsequent desorption of yttlerbium and
europium on granular ionites in an electric field
PERIODICAL: Zhuriial prikladnoy Ichimii, v. 355, no. 4, 1962, 769-773
T--.;'XT: Thi successful application of redox processes for the con-
centration and desorption of noble metals oil granular ionites in an
electric field prompted the authors to use these processes in -the
case of some lanthanides endowed with variable valency. Having cho-
sen Yb and Bu as the elements to be tested, the authors intended
first-to check the possibility of desorption in the electric field
of tervalent cations adsorbed on ionites, and then to try to re-
dUce them to divalent ions and utilize the low solubility of sul-
phates for the purpose of concentration. Conditions have been stu-
died of extracting and concentrating Bu and Yb from dilute solu-
tions by means of'the cationite KJ-61,(KU-2), and a method has been
Card 1/2
S/080/0'2/035/004/006//022
Sorption and subsequent D267/D301
developed -L:or achieving complete (> 955) desorption of Eu ions
from the adsorbent and for obtaining concentrated solutions o-;L, EU
by amalgamation. Yb did not, form amalgams with Hg. The method of
desorption in the electrical field with the use of a Hg catChlode
can be used to separate Eu from Yb and other rare-eartuh elements.
Electrochemical desorption of Eu and Yb in the presence of E,,SO
C- 4
solutions as electrolyte did not ensure a complete extr;-j-k;tion of
uhese elements. There are 3 figures, 2 tables and 28 references:
18 Soviet-bloc and 10 non-Soviet-bloc. The 4 mopt recent references
to the English-language publications read as follows: K. S. Spieg-
ler, Techn. Rev., 100, 1953, 303; A. H. Creer, A. B. E~Indle-r and
V. P. Tevmine, Industr. Engng. Chem., 1958, 166; R. S. S-Lamborg,
J. Seidl and J. Rahm, Folymer Sci., 31, no. 122-123, 1955, 15-e-4;
R. KU~,jj.jj, Toll exchange resins, Now York, 19~,8.
SUBMITTED: April 13, 19061
Card 2/2
I VA.B~! Z'UBkKOVA.,
,-PA &!JhQ L.B., ZVEGIMTSEVA, G.B.
Complex formation with phenols arAl absorptive capacity of
high molecullax woigbt d6riyatives of pyridine. Zhur.prikl.
Iddm. 35 uo.r-It1I33-W5 My '62. (IMRA 15: 5)
(F~,ridine) (Phenoa s)
O."')n ox-~hange reeins)
DAVANKOV LB_,-APMVA, T.A.
Desorption-of silver and the regenezation of electron exchange
resins by the electrochemical method. Zhur.prikl.khim. 35
no.1022171-2175 0 162# (MIRA 15:12)
(Ion exchange resins) (Silver) (Electrochemistry)
0/190 3/005/002/013/024
X6
a I
D10 102
AUTHORGV. Divalikov A'- 24. j:_,81Ato p. .19U.19 9 P.'M&
TITLE: Hijbitol soul sr'dorivaif*fos 'Of. U-Nothvi styrene# 'I Bois*
AM 00polymerol of-'a-liethyl styrene
5'
MIZODiDAit. VysokoA6 ekdlyarnyye, it I
'23
TEXT-j,',:.0J.r1cb Ahe *ion copolymerization ot
arow yrenwvi U*411"yl'-Aen`ssioc'~ D
agent Were
.68 a rose linking
in 'Ah f bj 1' no ion aopolmrbo-.-
onck: 0 OAS a rolide Bug 0 ~.
'i so n 6 at
io f '~Olyvinyl aloohol
1on4as. Q!* u
-95
0. initlator, The yield wan'84 .
- -1600 0 Using: 11itt as
`
- - "ifi 44449; "S il . is C
0760 hkk )qi I ", the- - ni ix U14"and i -after 7 bris
Afi
or,: klobu Ar: gk"u1A7::'*sr"9 obtairiedi the,diemeter of Ai&-:*.'
th
o#pacity in b4h - it
#,on Oilt The". illit~g~ ej
6
ohl 1,tv
Oro A ARAG,
d_1*6A66hio~iO' hy,
;h' r-de acid. with inoreigirg.
9 ore
o-
f croselink
oOnt . t
a on no,
is from 152% with 4A DVYJ 0
4
r
o
ll.
wMazeucM Sam
/19OJ63/005/002/Oi3/024
-,'H 'ghmoledu st-t.
B1
/B102
cqpoeniratio~. of Ahip -initiator 'and 'additiong -of
:hid'sn'~-atceleratina offoot....Copoly"
on'" 0 d." tbok.~`place also witho
f ut
lie hye dride
4~
'hi: "iiO9604r,,ratio oi-,-c~-Oethy~, styrone and .'Mal-eio
-h. t *as obtained
Xati n r
0.
&f ter3hra-.&V 60 Cj-~-*ith, oVrs,tio,-of...j:4~,. 0o2 bentoylperoiidej,the-
'at 75 d~'had thie 0.109-
Mepo ~'!Ji~iyl~ioile "1 0' 1' 'rimi th
iby-yMer: i1. "4;:~ Inst si!-oopo ~nme
prop 0 -i
II - -.,. . quolly,wi
ftpus' copb ynera'are foi~xlids' There axe 1. fiore iaid
t
ASS001saf Ov, t "Oloji6hei iy ivistitit 1M. is-I-'
lhlnikb~- ek, k
14, Ch4stical Tichuolqq
Do LA".-
%M- V2 i-19
SUP(ITTED 1 6 64_