SCIENTIFIC ABSTRACT A.N. FRUMKIN - A.N. FRUMKIN

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000513820007-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 13, 2000
• Sequence Number: 7
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

ROZENMID, I.L.; PAVLUTSKiYA, T.I.; FRMIN, A.N.. akademik.
New principle in the investijWtion of atmospheric corrosion of metals.
Dokl.AN SSSR 91 no.2:315-317 JI '53. (KLRk 6;6)
1. Akademiya nauk SSSR (far-b-akkin). (Corrosion and anticorrosives)

[IN, A.N., akademik; KIY3SSZRC,V, K.G.
Poisoning of aluminosilicate catalysts by pyridine bases. Dokl.AN SSSR 91
no.3:553-556 JTI 153. (MLEIA 6:7 )
1. Institut neftj Akademii nauk SSSR (for Miyesserov). 2. Akademiya naak
SSSR (for Frumkin). (Catalysts) (Aluminum silicates)

AEIMV, YO-L; SPIRO, N-S.; nUNKIN.-A.N., akademik.
Relation between conaentrations of isoactive aqueous two-component solu-
tions. Dokl.AN SSSR 91 no-3:573-576 Jl 153. (KLRL 6:7)
1. Akademiy& n=, SSSR (for Frumkin). (Solutions (Chemistry))

IFRUKKDI, A.N., akademik; FORSBWK, G.V.; KASHOVITS. V.P.
Conditions for the nodeling of the electric field of electrolysers. Dokl.
AN MR 91 no.3:593-593 J1 153. (KLBA 6--7)
1. Vaesoyusnyy alyuminiyeva-viagniyevyy institut (for Forsblom and Yashovets).
2. Akademiya nauk WM (for Pr~in).
(Mactrolysis--XLectromechanical analogies)

RYSS, I.G.; 31LIX3NBARD. A.G.; FRUKICIN, A.N., akademik.
, , , "MIA-wWw
ThermochomistrY of flut>-boric complexes. DokI.AN SM 91 no.4:865-868
"53. INLRA, 6:8)
.9
1. Akademiya nank SM (for Frunkin). 2. Mhepropetrovskiy metallurgi-
chaskiy institut in. I.V.Stalina, (for Ftyge and Ilkenbard). 3. DAepro-
pat,rovskiy eel I skokhozyaystvenW Institut (for Rye@ and Blkenbard).
. f4owpoands, Complex)' (Boroin) (Fluorine)

BELyAyEV, I.N.; BERGW, A.G,; NOMIKOS, L.Io; )7RUMKIN, A.H., akademik.
Electric conductivity of diagonal cross sections of ternary reciprocal sys-
tem In melts. Dokl.AN SSSR 91 no-5:1103-1105 Ag '53. (MLRA 6:8)
1. Akademiya nauk SSSR (for Frumkin). 2. Rostovokiy-na-Donu gosudarstvennyy
universitet (for Belyayev, Bergman, Nomikos).
(Phase rule and ecptilibrium) (Electric conductivity)

BWKH, G.A.; FHMIN. A.N., akademik.
Investigation of the mechanism of action of accelerators for rubber vulcani-
zation. Vulcanization of rubber with sulfur isotopes. Dokl.AN SSSR 91 no.
531107-1110 Ag '53. OUxA 6:8)
1. Akademiya nauk SSSR (for Frumkiu). 2. lievskiy tekhnologicheskiy institut
legkoy promyshlennosti. (Vulcanization) (Sulfur--Isotopes)

ISAGULYANTS, G.V.; ANDRMV, Te.A.; KOSOIAPOVA, N.A.; FRUKKIN, alrudemik.
Obtaining caproic sold tagged with radiocarbon. G14, in carboxyl. Dokl.AN
3SSR 91 no-5:1123-1124 Ag '53. (MWA 6:8)
1. Akademiya nauk SSSR (for Frumkin).
(Cuproic acid) (Carbon-Isotopes)

IGFA, Z.A.; ROZEMMESKAYA, G.B.; FRUNKIN, A.N., akademik.
Measuring the adsorption of iodine ions on iron. Dokl.AN SSSR 91 no.5;1159-
1162 Ag '51. (HLR& 6:8)
1. Akademiya nank SSSR (for Ynudcin).
(Adsorption) (Iodine) (Iron)

ZADUHKIN, S.N.; YAWN, A.N., akademik.
Surface tension and heat of evaporation of metals. Dokl.AN SSSR 92 no.l:
115-118 S 153. (MLR& 6:8)
1. Akademiya nauk SSSR (for Frumkin). 2. labardinokly gosudarstvenW
pedagogichookiy institut (for Zadumkin). Netals)

GOLI,EZR, G.A.; ZHDANOT. G.5.; UMNSKIT. H.M.; nUHKIN, A.N., akademik.
Radiographic determination of the structure of picryl chloride. Dokl.Aff SSU
92 no.2:311-314 3 133. Off-RA 6:9)
1. Akademiya nauk 3SSR (for Iramkin). 2. Yisiko-khimicheakiy institut im.
L.Ya.Karpova (for Gollder. Zhdanov and Umanekiy).
(Radiography) Meryl chloride)

BOPMKOV, G.K.; SLINIKO, M.G.; FILIFPOVA, A.G.; YRUMIrIN, A.U.. almdemik.
Catalytic activness of nickel, palladium. platinum, in respect to the reaction
of oxidating hydrogen. Dokl.AN SSSR 92 no.2:353 5 '53- OWU 6:9)
1. Akademiya nauk SSSR (for Yrumkin).
(Oxidation) (Hydrogen) (Catalysts)
I
I
i... J.:

FIALKOV, Ya.A.; BURIYANOV. Ya.B.-, FRUKKIN, A.H.. L&ademik.
Complex compounds of PC1 5 with aluminum and iron chlorides. Dokl.AM =R 92
no-3:585-588 S '53. (MLRA 6:9)
1. Akademiya nauk SSSR (for 7rumIcin). 2. Inatitut obhschey i neorganiche-
akoy 1-thimii alcadamii nauk Ul-rainskoy SSR .
(Compounds, Complex) (Chlorides)

ZATDICS, A.L.; STOTANOVA-SINITSKATA, I.G.; FRUMKIN, A.N., akademik.
Ordered structure of films of hydrated cellulose. Dokl.AN WSR 92 no.3:
601-602b S 053. OMRA 6:9)
1. Akademiya nauk SWR (for Frumkin). 2. TSentrallnyy nanchno-iseledova-
tellakiy institut kozhevenno-obuynoy promyshlennosti (for Zaydes and
Stoyanova-Sinitakaya). (Cellulose)

~N
Reductfon "In a t6d at the horptas mercm-CA00f.
kaikiWlit S~ 1. Ziubtiav. DoUtdy Akad. Nauk
current jutrip and a hys-
t_-OP in tll(~ "laX09TUPhIC CedUCtlOn r4 the nitrate [on
(1) were ob-crvicA in the prc~tuce of 1,a* ~ ' but not in that
of ',%(Clf.),* and Ca* *. The jump, digappearc.Ld up" Wt-
ring, Rnd the rcdui,,lj,m imenflil thiftcd wPh chanp In p1l.
Thtse elleets are talen to Ifulkale that the P*Liroeraphic
tccluction of I tit lhe pm-n(t of La Is tatalyzed by OV,-.
Nine Off- are formed when I Wreduccd to N'th, z9 sidistan-
tiated by the conen. ratio 1:11~ at cfinditlons where the
114on wave stafo to sipp-_-tr behind the reduction wave of
the 1. The exact merbanbrn of the 011-i#m catidysis Ii
not elm, but It 14 rrapvs-d that (here rmy exist in equil.
NOv- + 011- ;zt IINN04-- whicb normally Iks far at the,
leit but Is moved rnm(.Wfl..t to the right umler the t!Wro-,
itatic Influe= of La + +. Andrew Dravnicks

ZHD"OV, G.S.; ZHURAVL3V, N.N.; XEVIN, L.S.; FRUMKIN? A.H., ukadezaik.
Radiographic determination of the fornation of solid solutions in baron
(K61U 6:9)
ewruide. Dokl.Ali SSSR 92 no.4:767-768 0 '53.
1. Akademiya nauk SSSR (for 7mmkin). 2. Moukovskiy mekhanicheskiy institut
Ministerstva kulltury SSSR (for Zhdanov, Zhuravlev and %evin)
(Baron carbide) (ELdiography)

RYABCHIKOV, D.I.; I-AZAR V, A.I.; YRLT14K41. A.11., akadeinik.
Chromatographic separation of molybdenum und rhenium. Dokl.All SSSR 92 no.4:
777-779 0 '53. (MLRA 6:9)
1. Akademiya nauk SSSR (for FTumkin). 2. Institut geokhImii i analiticheskoy
khimil im. V.I.Vernadekogo Akademii nauk SSSR (for R7abchikov and Lazarev).
(Chromatogranhic analysis) (Molybdemim) (Rhenium)

xThe reduction QL_h9dU1xXLUULU an a inticury drrp Wc-

S R trade. S ky
;Plam Doklady A LJ.
a "!Ago
0&7#
Aaiiii S
92
72
A
C
..
i-tru,
.
.
,
. 42,
6351f., Vildrailika, Kkimiya 2, 12.541952).-71c poLmo.
graphic curves obtailuj for the rceuctiou of hydroxy'ainine.
I I Clan a I fir ilrop electrode are discinised. Thc reduction
wus earrical out In tile pmence of iolls of Various Valences
r-,%"*. and IA"**). The curvcs are ctWfFtC-
terizedby2waves. The first, which has a half -wave paten-
to thm of 11 *' alnlcl~t dt-Ap1mars if an equiv. amt.
tial Clow
ofalkalihaddediothesoln. ItIjcWncIudt-dthatthiiwAve
is due to reduction of 11 " whidi Is formed by the hydrolysis
of N11.0 The second wave is simiLar to thut for
it I-; shifted toirard more 1". Values as the valencc on the
cations is iticreascd. On acidification this nave is shifted
addn. of ikkall shift,; It
toward tnore neg. values and tile
toward more fins. valuts. Roth %vave:i are diffusion-type
-A aves. The data lcurl to the conclusion thm the reduction
occurs according to the equation: NHIOII + 160 + '-c-
Nils + 201L- which. In tlit presence of La", Is auto-
c2talyzed. by tbe Oil which are formed In the reaction. T
Itortar Leac
7

UKSHE, Ye.A.; LEVIII, A.I.; IKIN. A.N., ukademik.
Effect of the adsorption of cations on electrodeposition of copper from
pyrophoophate electrolytes. Dokl.AN SSSR 92 no.4:799-801 0 153.
(MLRA 6:9)
1. Akademiya nauk SSSR (for Yrumkin). 2. Urallskiy politekhnicheakiy
institut Im. S.M.Kirova, Sverdlovsk (for Mahe and Levin).
(Copper--Blectrometallurgy) (Pyrophospluites)

Journal of the Iron and Steel Inst.
June 1954
YrOFerties and Tests
ilk
Active Kiitii
and the
(ion of Hydrosen into I=
_qB.
(Vokladli Akademli N4Uk "MR..
t
(In Russian)., A study of the transfer of 't Milan over.
potential through an Iron disiphragin with th';XIMUlwaous
measurement or the amount of hi,drogen diffused through it
during cathodlo 1plarization In so utions of puro IN IM and
In the presence of an Inhibitor (tatrabutylammordurn sulphate
with potassium bromide) Is described. On additJons of arsonto
to the, polarization 'colt in conoontrations of 10-9- 10-4 Af.
with and without the Inhibitor, the change of potential under
the Influence of the diffusing hydrogen was riot obser~ad.-
This result is In'dPposition to the views expressed In the
literature that the Incroasod diffusion of hydeaga . observed
In the presence of arsania, is duo to the slower removal of
hydrogr from the ilinphravn surfaco.-Y. o.

KUZMMOV. V.A.; KOCHMIN, V.P.; TISHCHENXO. N.V.; POZDNYSHIVA. Te.G.; FRUMKIN,
A.N., akadenik.
MONO
Investigation of surfaces tension of the alloy: tin - cadmium on the bound"Y
vith the fused euteotic: Li - KC1 in a vacuum. Dokl.AN SSSR 92 no.6:1197-
1199 0 '53. (MIJRA 6:10)
1. Amdemiya nauk SSSR (for Yrumkin). 2. Urallskiy gosudaretvannyy universi-
tat im. A.M.Gorlkogo. gorod Sverdlovsk (for Kusustsov, Kochergin, Tishchanko
and Posdnysheva). (Cadmium-tin alloys) (Surface tension)

ZHDANOV, G.S.; POSPIWV, V.A.; FRUMKIN, A.B., akademik.
Unequal length of metal oxygen bonds in certain metal oxides and the "molecular*
structure ZnO. Dokl.AN SSSR 93 no.1:97-99 N '53. MRA 6:io)
1. Akademiya nank SSSR (for Yrumkin). 2. Fisiko-khimicheakiv institut im.
L.Ya.Karpova (for Zhdanov and Pospelov). (Metallic oxides)
77777

WOVOKHATSKIT, I.P.; KALININ, S.)C.; FRU)MIN. A.N., akademik.
Fluorine content of certain natural waters of Kazakhstan according to spectral
analysis data. Dokl.AN SSSR 93 no.2:289-291 N '53- OaaL 6:10
1. Akademiya nauk Xaz.SSR, Alma-Ata.
(Kazakhstan--Vater-Analysit)
2. Akudemiya nauk SSSR (for Fruakin).
(Analysis-Water-Kazakhatan)
(Fluorine)

KACHMIN, L.G.; FRUMKIN, A.N., akademik.
Probability of the formation of ice nuclei in supercooled water. Dokl.AN SSSR
93 no.2:307-310 N 133, (MMU 6:10)
1. Leningradskiy gidrometeorologicheskiy institut (for Xachurin). 2. Akademiya
nauk SSSR (for Frumkin). (Ice)

DIYAKOV, A.A.; FRUMKIV, A.H., akademik.
Certain problems In the electroreduction of persulfate. Dokl.AN SSSR 93 no.
4:685-687 D 153. (MMA 6:11)
1. Akademiya nank $SSE (for lFrum4cin).
(Reduction. Xectrolytic) (Persulfaten)

SAMSONOV, G.T.; FRUMKIN, A.N., akademik.
Physical properties of certain Intrusion phases, Dokl.AN SSSR 93 no.4:689-
692 D '51. (XLRA 6:11)
1. Akademiya. nauk SSSR (for Frumkin). 2. Mookovskiy institut tovetnykh
metallov I solota im. N.I.Xalinina (for Samsonov).
(Xstals) (Solutions, Solid)

19 - Y,
Us~n/ Chemistry - Physical chemistry
card'A Pub. 147 - 14/26
Authors 3 MAyzlish, R. S. ; Tverdovskiy, 1. P.; and Frumkin, A. N.
Title I Adsorption phenomena on Hg and alcohol-water solutions of electrolytes
Periodical I Zhur. fiz. klAm. 28/li 87-101) Jan 1954
Abstract i Two series of electro-capillary curves representing ethyl alcohol - water
NaCl(sat and ethyl alcohol - vater NHO(sat) syatems were measured and
it becW evident that the boundary tension of the aqueous salt solution
decreases in the zone of electro-capillary maximum*as result of introduction
of alcohol into the solution., Addition of water to the alcohol salt
solution leads to reduction of boundary tension on both ends of the electro-
capillary curve. It was established that the negative adsorption of
alcohol corresponds to the po3itive adsorption of water. The calculated
adsorption isotherms on the boundary with air showed that both salts in-
creased the alcohol adsorption and displace the adsorption maximum toward
less concentrated alcohol solutions. Ton references : 5-USSTR;'4-USA
and 1-Enelish (1913-1953). Tables; 1.yaphs.
Institution Institute of Applied Chemistry, Leningrad
Submitted March 14, 1953

USSR/0119131r.7
Card 1/1
Authors t Kalish, T. V., and Frumkin -.0 A. N.
Title t -ion on
a
Effect of anion adsorption on the reduction of an 52O
.
.
drop cathode
Periodical % Zhur. Fiz. Khim. 28p Ed. 3, 473-489, March 1954
Abstract It is shown that the reaction of electro-reduction of an S208-lon
on a mercury electrode is retarded by the adsorbing anions. The
rate of this reaction, at a positive surface charge in relation
to the nature of the indifferent electrolyte, decreases rrad-
ually. The.potential at which the current intensity correspond-
ing to this reaction reaches 0.6 In proportion -tothe maximum
diffusion current is displaced toward the nes~atlve side. At a
negative surface charge one can observe a certain weakly ex-
Tressed dependence of the rate of electro-reduction upon the
nature of the anions which in this case are oriented in.reverse
sequence. The effect of adsorption anions leads to the con-
vergence of the potential with the point of the zero-charge.
Thirty references; 1 US3R, since 1919. -tables, graphs.
Institution I Acad. of 3c. USSA Institute of Physical Chemistry, Moscow
Submitted June 11, 1953

FRVFMNj P~-N-
USSR)Che&A. N.
stry
Card 1/1
Authors i Kalish, T. V., am Frutkin, A. N.
Title i Position of the zero-charge point and its effect on the electro-reduction
of a S208 anion on a drop electrode
Periodical i Zhurs Fiz. Khim., 28, Bd. 5p 801 - 805, May 1954
Abstract Exneriments showed that" the beginning gf the descent of the Dolarization
curve, during electro-reductian of S208 on a drop electrode consisting of
40% thallium amalgam, is disvlaced by 0.5 v toward more negative potentials,
.which corresponds with the nosition oj.~the zero charge point of thallium
amalgam. The retardation of the 3208 reduction reaction over a mercury
electrode'in solutions containing n-octyl alcohol is determined by the
:absorption of alcohol molecules, the action of which is affected by the
negative charges of the surface. Seven USSR references. Graphs.
Institution : Acad. of So. USSR, Institute of-Physical Chemistry, Moscow.
SubmItted : July 8, 1953

FRM,raN. A. N.
USSR/Physics
Card 1/1
Authors Frumkino A. ff., Academician, and Zhdanov, So 1,
Titb Origination of sudden changes In current intensity and
hysteresis loop on l,olarization curves during electro-re-
duction reaction
Periodical DPkl. All SSSR, 96, Ed. 4, 793 - 796, June 1954
Abstract During the reduction Of 1103 and 3VO2 Ions on a mercury drop
electrode in the presence of LA , an Intermittent Increaae
in,the current intensity may be observed when a certain po-
tential Is reached. The anomalous form of the polarization
curves Is due to the autocatalytic effect of 01r, 'formed dur-
In(- the reduction of ions. An approximate theory of ~h03e
phen mena Is Given. The hysteresis loop is best expresaed
at F~ = 3 - 4 and d1sappear3 ELt a mitch hif.-her acidification
and olicall7ation. Three references. Craphs.
Institution
Submitted April 7, iq,54
177

USSR/ Chemistry Physical chemistry
Card 1/1 1 Pub. 22 - 29/48
Autbors t Frurikin, A. N., Academician, and Zlidanov, 1.
Title t Reduction of a nitrate-ion in an acid %!editur. in the presence of La
PerlOdIC&I I Do~. AN S3SH 97/5, 867-870, Augu3t 11, 1954
Abstract The phenomena observed during the reduction of a nitrate-ion, is e.j
in conditions when the reaction of the nolution in the near-electrode
layer cannot transform into the alkali zone because of the continuing
reaction process, are discuss~.-d. The reduction of a "~03 ion in an
acid mediwzi Is followc~d by Die reaction of 11-separation. The final
product of V03 reduction (a=ionia), at p1l values, attainable in the
presence of L~3+,surplut;, i3 included iLn the solution, basically in
the form of a NH'" - ion. Three references: 2-LISSR and I-Polish
4
(1951-1954 . Graphs..
Institution :
Submitted : June 16, 1954
77777777

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-7
----------
VESTNIX AFID--Iaj IZI~jj-r
rOtwnal of the Acaderl of Sojeric,3S
LI
Chemical "otonoen Soction, mootiq,- hold on *Dectr4b-Dr 13, 19bb.
'Eirief Sw=Aries are given Of W follM?ifk~ ,to f-upors reaA )t th~!t
j'I 0 t I rxg -Novi", of work on adsorption phanon,-.anp. at "Ir.-Ij boundl=y
bot-oon votala and solutic'M 49121XI=-
"Work on diroot investi(;ation cf ti-,o topcu-rs;-,!,y j--Id t,,
dr-Vid-bhomioal adSOrPtiOn Of WividuW -Icrl trans-
fcrira,~ions in mat-ale"0
By S. Z. RoLlRaY.L and
T14v-
7

weloptnedrv-eTe-C-1 rochetm4l)
verlmn trenai to me ae
r4inetlem. A V proxy KNxm Ameliks.
"3~ sli, Akad. Nouk S.S.S.R.
1955.401- 19-Reccut work on the kinetics of electrochel".
ft-tetion,% is rtvimcd to show its cl(v~c Connection With the

k
nt
N4 m At NoV
4
we( W t 11 U_
IrbythestAffol I
t"Iftlet"ce to diffu%ion proble 11, *0 U~ in ating
71 Clectrodes, elementary reaction mechanistus C ulvin
electron achange, rlLrografhic half-ave n
nction0 o d wx of the
or, y of d lam
Of .1 111P19'a-lus. C. If. F.
c(At7Vu ckuu,4Z;~
:z
.7.;..

All 'Z~ /t/
3120*
~~ign rhemEpu and
tswuuyc 1!!VlCnllQ I emmiro ilflhe"Ik. I& klmtlks
(flussian, A N Frunilk-In. Ustx-khl k1sithil, Y. 24, no, 8, 19Y
P. 933,950.
Relatiou of q1tenadika eigr~nt sapaug;j=. baldness. and
extef n2, friction of Illetal to tile potenliToTa-int(allic electrode
in sulhic acid. Craphs, tables.

rimmkIm. Z- rr. via. Agg". 4v. fom-
I,-
tmrrTTAemyjG.A. 44.13fulf)-as4umvi th it ne long acris"
lating at the baer C.4 a 11C dr-ep are whilc in 'C'
-3 ANY M4 V. dg. am kept gm-At bY the trulk ell.. cund~ of (lie
7:Y.
frw

Vol.
:7,1 ..!i I vj. Pio~, A; 1:
To fj.j At 1.1'.Cl,
--FF.T
I ~--.
i 14'
W~lq in ki,~
'r, 4 O.I.Xf I-c", 'I
llyllrnkylvvin~ i,j;i4 On
~n th~~t IN11,01C ,f
h
d, ,~:r(kd on fL, I'll 'd
1,11.W-o. I I ,,
ing ourma i - "t), V.
f hd Ar
C~Clv~.tl fr~m I, it ~i 110 azl,! N4
ts~ Olf o-,,
M i.

TICHKIN, M.I. A. U.
IrIYAMIYN~. --- 1. 1. - -1 1 1
Activation enere7 of the hydrogen-ion discharge. Zhur.fiz.khim.
29 no.8:1513-1526 Ag 155. (KI-RA 9:3)
(Hydrogen) (Electrolysis)

F ~ UM K
,rUS,,,.Rl Chenistry - Physical cliuastry
Card 1/2 Pub. 147 - 11/21
Authors i Florianovich, G. 11., and Frwkin, A. N.
Title i Iaectro-reduction of anions over a mercury electrode
Periodical I Zhur. fiz. khim. 29/10, 1827-160) Oct 1.955
Abstract I The reduction of numerous anions was investigated on a mercury drop and
amalgamated rotating cathodes. It was found that anions begin reducing at
sufficiently negative values of the potential when the electrode surface
is charged negatively (relatively difficult reducible anions) and that the I
anion reduction begins at such potentials at which the electrode surface is !
positively charged (easily reducible anions). The effect of foreign cations:
Institution Moscow State University im. M. V. Lomonosov
Submitted February 15, 1955

Card 2/2 Pub. 147 - 11/21
Pe~lodical Zhur. fiz. khim. 29/10., 1827-1846, Oct 1955
Abstract on the anion reducing process was invcstigated and it was established
that the cations affect the magnitudes of minimum currents and increase
same. The effectiveness of the cations depends upon their charge and
concentration. Thirty-four references: 7 Czech., 6 USA, 18 USSR, I Fr.
and 2 Eng. (1932-1954). Table; ~Taphs; drawing. v

m V, N ~ ~), kl,.
kU
F
y

WBRI Chemistry - Phyaical chemiotry
Card 1/2 Pub. 22 - 31/52
Afathors I Frtunkin, A. N. Academician. and Aykazyan, E. A.
Title I The kinetics of ionization of molecular hydrot!en on a Pt electrode arid
the role of anions
Periodical 6 Dok. AN SSSR 100/2, 315-318, Jan 11, 1955
Abatraot I Investigation was conducted to dote'rmine the relation between the
current density of,molocular hydrogen ioni7ation on a disc-type smooth
Pt. electrode and the potential anti nature of the anion at various qins.
The hydrogen dissolved was kept in equilibrium with the hydrogen at
atn4cspheric pressure.
Institution t The M. V. Lomonosov 3tate Univers.ity, Moscow
Submitted October 8, 1954

Periodical Dok. AN =;n 100/2, 315-'318, Jan 11, 1955
Card 2/2 Pub. 22 - 31/52
Abstract It was found that the processes of ionization of adsorbed H and dis-
charge of H ions are practically in reverse order and that the rate
of the.procous on the whole is detemined by the hydrogen adsorp-
tion and desorption Ltages. The effect of the anions was found to be
the strongont when the olectrodo potcntiala wore most positive. Ton
referencesi 9 USSR and 1 Geman UM-1952). Graphs.

A/
USM/Ch^mistry - Electrocbemistz7
Card 1/1 Pub. 22 - 34/54
Authors i F A. ff., Academician; Kaganovioh, R. L; Gerovich, M. A.1 and
V a evi Y-0-Tts
Title s The mechanism of anodic formation of persulfates
Periodical I Dok. AN SSSR 102/5, 981-983, Jun llo 1955
Abstract I Sulfate eleolrolysis experiments were carried out in water enriched with
the heavy 01 inotopep in alkali and weak acid electrolyte at possibly lov
temperatures to establish the condition most favorable for the anodic
formation of persu2fates. The.results indicate that the first product
formed on. the anode is an ox7gen-containing water-oxidation compound OH
which in turn oxidizes the S04- ion within the volume of the solution.
Seven referencest 3 'USSRp 3 'USA and I German (1922-1954). Table,
Institution t Acad. of So., USSR, Inst. of Phys. Chem. and the M.Lomonosov State
University, Moscow
Submitted April 11, 1955

401
~torkftl re, i- an ~l L
rm--f m rrogtcz!;. The Litter lvd--,drs sf ,*rs t;f
,Itilf,mizr~cm thnsuufarec-I liciu,As which are Cali i~A
3 tli,! -,Irvm~xc rf tbe ruface 14ytr of puc-.
di! !-A* "'n"I
!:ub-'utut'A f%tty
INA tap-
Lf C!Cf.'.Qlytt:l. li. Fu~

USSR/General Problems - Methodology. Scientific Institutions A-1
and Conferences. Instruction. Questions Concerning
Bibliography and Scientific Documentation.
Abs Jour A.N. Frumkin.
Inst
Title ~of~a Scientist and Revolutionist.
Orig Pub Xhim. nauka i prom-st', 1956, 1, No 5, 573-574
Abst-,act To the 10th anniversary of the death of A.N. Bakh
(1857 - 1946)-
Card 1/1 - 4 -

TZMKIN, R.I.: nux~;#.,-~~.Xc
On the paper by O-M-Polterak *The activation energy of hydrogen
ion discharge and th" problem of absolute potential in electro-
chemical kinmtlcs*. Zhur.fis.khim-30 no.5:1162-1168 My 156.
(MLRA 9:9)
(Hydrogen) (Potential, Theory of) (Polterak, O.M.)
.. -7-- ~- 6,1.

YRUMN, A.N.; 1OFA, Z.A.; GIROVICH, M.A.
Potential difference at the water - air interface [with Inglish
summery in Insert], Zhur-fis.khtm. 30 no 7:1455-1468 J1 156.
(MLRA 9:11)
1. Moskovskly gosudarstvennyy univereltet imeni N.V.Lomonooova.
(Blectrochemistr7) (Potential. Theory of)

Catcgcry: USSR Physical Mer.1stry - Flectrochemistry. B-12
Ats Juir: Referat Zhur-aimiya, No 9, 1957, 30132
Author : Terkin M. I., Fruxhin A.-N.
Inst : not given -
Titl,-- : Co=ents cn the rependence of Hydrcger. Overvcltage on Nature of
the Cathode in Connection vith the Paper by Ryuchi and Delae
(Ryut3hi and re-lakhey in the Original).
Crig Pub: M. fiz. khinii, 1956, 30, No 8, 1885-1888
Abstract: A diza-ussim article (RZhKhir., 1956) 125-e7); see also RMKftim, 1956,
54c66.
Card 1/1 -10-

d phtnc nneltz

FRUMXIff, A. N.,
"A Contribution to the Ovcrvoltage 'Ibeary uf Hydruiren " Z(.-LtschrLft Fuel-
,- y
Physikallsche Chumle." (Periodlcul of 11hysLeal Chemistry), October 1957.

,,, /~ /,/) A., //. /I
YAKOBI, B.S.; YRUMXIN, A.N., okademik, red.; 5MLRUOYA, A.Y., tekbn.red.
wh-Am"mmm.11-
(Work on electochomistry; a collection of articles and papers]
Raboty po alektorkhimit; obornik statei i materialov. Pod red.
A.U.Frumkina. Moskva. Izd-vo A~md.nauk SSSR, 1957. 301 P.
(.Electrochemistry) (XnU 11:2)

FRU!M1111L A. N.
Adcorption of organi-- subatenceu at the metal electrolyte
solution interface ard its influence on electrochemical processes.
Academy of Science, U563R, Physical Chemical Laboratory of Surface
Phenomena, Moscow, U.S.S.R.
A paper to be presented at the 2nd International Congress of Jurface
Activity London, April 1957

FRLWMf, As
Moscow
"Fassiverung von Flatin In Bezug suf Oxydationavorgenge In der
Losung" a paper submitted to the International Symposium on Passivity of Metals,
2-7 Sep 5T, Darmstadt, Germany.
C-3,800,126

e cid rn~Lhdi ~n Ifft,
d ctwpimek. A. N.
Rei v 1'~1~0~.!!4~.'Vl A
TPUA-Y Kc,-.!c It, AdizUni 195,.

----- -----
JI
Di~tir. 4'

~..Goaeral quesuons 6s ef 15" etnefulad guo dnu WIS
thedy of fank Aldrog"J.7 A - N- F,=kia, A kad.
-
-
7Va-
Uk TW, RL?Q-38.-A
view ffluitrating the rclation Ww"n the E=trodem Watt-
ks azd the kinefts for imic reaWons that teLke piace in
S
Rovtar

'I., .- lo .1-1 /w~ '-~
/ I" '--, - /'/
YRTWIN, A.H.
The scientific work of A.M. Bakh. and its role in the develop-
ment of physical chemistry in the USSR. Izv.AN SSSR. Izv.AN SSSR.
Otd.khim.nauk. no. :776-7el ii '57. (MIRA 10110)
~Bakh, Aleksei Hikolaevich, 1857-1946)
(Chemistry, Physical and theoretical)

Im-mixt ,
Disausolon, Probl. )dn. I kat. 9:P76-2?? 157. (MIRA 110)
(Anioias)

AUTHOR: Frumkin, A. N., Academician 30-10-13/26
---------------
TITLE: Tasks of the Institute of Electrochemistry
(Zadachi instituta elektrokhimii).
PERIODICAL: Vestnik AR SSSR, 1957, October, Nr 10, pp. 99-101 (USSR)
ABSTRACT: The electrochemistrv has to solve a series of great tasks
within the sixth Pive-year Plan. The AS USSR decided
therefore to organize within its scope proper institutes of
electrochemistry.
The problems set to these institutes can be characterized
as follows:
1) Enlarging of the theoretical electrochemistry in order
to clarify especially the question of electrochemical k1metics
and thermodynamics.
2) Obtaining of new chemical sources of current which
satisfy severest service conditions without relaxing.
3) Obtaining of new seean--dary electrochemical sources of
current from atomic energy.
4) Determination of the phenomena occuring between
semiconductors and electrolytic solutions.
5) Clarification of the processes at the primary and
Card 1/2 secundary electron emission correlated with the presence

Tasks of the Institute of Electrochemistry 30-10-13126
of contact potentials at the limits between metals
and semi-oonduotors.
6) The possibilities of electrolyd s on a lar6e technical
scale should be studied in connection with the
construction of new Uxg6 elictrie- pawer'plants.
AVAILABLE: Library of Congress
Card 2/2

FRUMKIN, A.H.; NIEDLAYEVA-PEDOROVICH. N.V.
-OWN
Electric reduction of anions and adsorption of cations. Vast. Moak.
un, SerP matemekh, astron. fis. khim. 12 no*4:169-184 157.,
(MIRA 11:5)
l.Kafedra alektrokhimii.Rookovskogo gosudarstvannogo universitata.
(Blectrochemistry) (Anions) (Cations)

AUTHOR: Frumkin, A.N. 62-12-2120
TITLE: 'On Some Genertil Problems of the Electrochemioal Kinetics and the
Theorj of Ion Reactions (0 nekotorykh obshchikh voproa&kh elektro-
khimicheskoy klinetiki i teorii ioruiykh reeLktsiy)
Report Delivered at the Meeting of the Chemical Depa-Ltment of the
AN USSR on October 31, 1957 (Doklad na sessii otdelerdya
khimicheskikh nauk- Akademii nauk SSSR, 31 oktyabrya 1957 g)-
PERIODICAL: Izvestiya AN 3SSR Otdeleniye :,1iimicheskikh Nauk., 1957, Nr 12,
pp. 1429-1438 (USSR)
ABSTRACT: The reviewer distinguishes between three stages in the develqument
of modern -chemistry; in his report, however, he deals Yrith the last
stage, i.e. the development of electrochemical kinetics. The b&31,:
condition rms to penetrate more deeply into the metal-eleotrolyte
boundary structure. The results achieved are described as very vicde3t.
It in further said that a number of new physical methods of investi-
gation are appliea. The author then deals rrith the adsorption of
gases on the slarface of solid metals. The determination of the de-
pendence of the velocity of the heterogeneous chemical process on the
pressure of the gases taking part in the reaction requires knorilledge
Card 113 of the isotherwal l1nes of adsorption of the surfaces of the catalyst.

On Some General Problems of the Electrochemical Kinetics 6,, 12-2,120
and the Theory of Ion Reactions. Report Delivered at the
Meeting of the Chemioal Department of the AN USSR on
October 31, 1957
For this purpose in most oases the isothermal lines of adscrpt-lon
according -to Lengqur (Langmuir) were used. Measurements, which
we
aere carried out la.-t by Shlygin, Ershler and the author bet en
1929 and 1938, led to the unexpected conclusion that the quantity
of hydrogen adsorbed on platinun is linearly modified in fir3t
approximation (see forriulae p. -1431). The author then deals with the
electric capillary phenomena and anomalous properties of thin layers
of liquids. After describing the hitherto distinguished 2 kinds of
tram ition ( f rom, the adsorbed layer to the new phase) , the author
mentiona the results obtained recently by Dyryagin and his collaln-.o-
rators: he wan able, by means of optical measurements, to show that
by approximation to the point of saturation the strength of the -Ad--
sorbed layers of polar liquids (as e.g. of water and of nl-cohol) on
the smooth surface of glass actually attains some dozen molecules
(up to 100 N). The author aealt in aetail Yrith the result of the in-
vestigation of the ratio between the electrode processes and the
ion reaction,- in solvents (see f1g. 1). Independent of the conception
Card 2,13 formed of the participation of the adsorbed anions in the elementary

On Some Geneml Problems of the Electroohemio&I Kinetics 62-12-2/20
and the Theor7 of Ion Reactions. Report Delivered at the
Meeting of the Chemical Department of the AN USSR on
October 31, 1957
process, there is no doubt that they form little bridges (mostiki)o
which connect the electrode vrith the cation ~233 . There are
3 figures and 42 references, 33 of which are Slavio.
ASSOCIATICK: Institute for Physical Chemistry of the AN USSR (Institut
fizicheskoy khimii Akademii nauk SSSR).
SUBMITTEDt October 1, 1957
AVAILABLE: Library of Congress
Cara 313 1. Chemical engineering-Conference 2. Gas-Adsorption-Metals
3. Electrochemical kinetics

~/The of A=W.
V. Nibh~jnra (IF
-
7)
vich ar:J VvI.-IT.
&,de:7m of Ow thcoty Lf FIC'Haro
50, G2g) by Klvak, a-vt L-,itinen ~i, A 10,
ans-ii-rml, The 0 cc an~c!i-4 t~ ~111:rl s,rG-'j.-!Y
InflueurtiA by the ekrtrujl~~, Charao ..14 tl,Q ~A 1!4-'
ulvl,tv~,
of th- tharge oit fl-C. "i'l c:.:.
la."m Net.", I atill. vi-It'g. Ci
rcptt !c, C i

hr! zifl,v)rpt~,n (if th- mi-I ;-Iri titi.
:vzhis in
Chute ~~miilivv. i1i -III
of th-
with wl!CZUc
-
~
l
ded b
di
h
i
;
a-9
f
e cr'nd
rvvo~
l
n t
tioui of
k
y
rcoctiDg partiela,., L631i(f,tir. jr

FRUMKIN, A.K., akademik
......... w.-..
Tasks of the Institute of gleptrochemistry. Vest. All SSSR [271
no.10:99-101 0 157. (MIRA 10:10)
(Electrochemistry-Research)

AUTHORs Frumkin, A. N., Member of the 30-11-18/23

TITLE: Meetings with Polish and German Chemist8 (Vatrechi s pollakimi
i nemetskimi khimikami)
PERIODICAL: Vestnik AN SSSR, 1957, Vol. 27, Nr 11, pp. 122-128 (USSR)
ABSTRACT: After Polish electrochemists had paid a visit to the Institute
for Physical Chemistry AN USSR the author stayed in Warsaw an a
guest of the Polish Academy of Scicnce. The research worka~n the
field of electrochemistry are concentrated in the Institute for
Physical Chemistry under the direction of the eminent scientist
V. Sventoslavskiy. The Smyalovskiy-Laboratory (physical chemi-
stry of electrode-processes) is on a very high scienitific level;
the investigations of the dependence of the penetration of hy-
drogen on the composition of various admixtures in steel, such as
oxygen, sulphur, phosphor, are carried out on a broad basis. The
collaborator B. Baranovskiy succeeded in discovering some new
effects of motion of the liquid upon the passage of current. Pure
calculation works on various problems of quantum-chemistry are
done in the Laboratory S.Mintsa by theoretical physicists (the
students of the well-known physicist L.Infelld). The Laboratory
Card 1/'3 for Physico-Chemical Methods of Analysis (under the direction of

Meetings with Polish and German Chemists.
30-11-18123
V.Kemull) which is connected with the chair for anorganic analy-
tical chemistry of the Warsaw University, is distinguished by a
special many-sidediiess and topicality of~themes. A method for do-
termining minute traces of admixtures in metals was worked out in
this laboratory. Much work is also deveted to the investigations
of the mechanism of electrode-processes. Thus, for example, a
marked breaking of the electrode-processes by absorbed foils of
the hydroxidation was determined. In the Laboratory B.Kamenskogo
the investig-ition of tht: potentials on the free surface of various
solutions is successfully performed. The aim of these works is a
comparison of these potentials with the ph~-uiolugical activity of
organic compounds. Many workii are distinguishcd by special origi-
nality. -Then the author reports on his iL:.,preasions during the
visit of the scientific research institutes in the DDH (GDR).
He participated in the Berlin Colloquy on the kinetics of electro-
de-processes. K.Shvabe (Dresden), chair-,Ian of the organization-
committee, talked on the theory of the overvoltage of hydrogen.
M.Brayter (Munich) reported on the investigation of the anode-
formation and the cathode-restoration of the surface-oxidations
on electrodes of noble metals in acid solutions. Of special inte-
rest for the author was the detailed exciian-e of opinions in a
Card 2/3 0

Meetings with Polish and German Chemists.
30-11-18/23
small circle on the most important still unsolved problems of
electrochemical kinetics. In the technical college in Dresden
the author hold a lecture or, "The restoration of anions in an
electrical manner and the adsorption of cations" and in the Aca-
demia Leopoldina in Halle he talked on "The adsorption of orgqnic
substances on the boundary metal-solution and its influence upon
the electrochemical processes."
AVAILABLE: Library of Congress
Card 3/3

USSR/Physical de~ls~ly 'ectrochemistry
I
D-12
Abs Jour Referat Zhur - Khimiya, 110 1, 1958, 56o
Author A.N. Frumkin, A.S. Titiyevskaya.
Inst
Title Electrocapillary Phenomena In So)-utions of Thallituii Salts.
Orig Pub Zh. fiz. khimii, 1957, 31, No 2, 485-492
Abstract Electrocapillary curves (EC) for the solutions I ii. H2SO4
t x n. TlpSO4 (x =0-01; 0-05; 0.1 n.) and 1 n. U;03 -f -
f-0-01 n HNO3 + x n. T)1103 (x :n~ 0-01; 0.1 and 0.2 n.)
were plotted In the reCion of the polarization of the Hg
electrode from -i-0.1 to -o.45 v (satur. c. e.). A drop
of the boundary tension was revealed at the ma-xima of the
curves, as well as a shift of these maxima in the positive
direction, which reached 0.29 v in the case of Lhe solu-
tion 0.2 n. RN03. A little surface activity of Tl-t ions
was revealed also at positive charCes of the H,- surface.
The conclusion was made that Tl- behaves as a ty-piral
Card 1/2

-USSR/Physical Chemistry Electrochemistry. B-12
Abs Jour Ref Zhur Khimiya, No 1, 1958, 56o
surface tension lowerinF, cation. A detailed thermodynamic
analysis was carried out; it showed that this conclusion
did not disagree with the conclusion concernin- the adsorp-
tion of atomic T1 on the boundary between the T! amalgams
and solutions not containing Tl ions (Frumkin A.N., Goro-
detskaya A.V., Z. phys. Chem., 1928, 1-36, 451). It was as-
sumed that not only simple, but also conTlex T1`7ions can
participitate in the adsorption process.
Card 2/2

~-7
\/1-vestigation of
Iddition Of VOMAC hj-jf09Cr tO f-n3-r=cr' 4~! 11,
MI ty
The
elp,, I C'I~A and
I ~-, ?I, C A5 1RKw i'l-
duc~d ~It c~t h,;ae eurfare --i, ii
%!i I-,t , . ' j;I
CICC"FL-de Surface ~'v
r-q cc funism at Ijw 0 vaiur"t."i 11, 11 :'. ';I,';~' I
if the =ftwc C'Iyetswc with ads"A.:'~ I
cteCtMt)-dli CGOijiti0i'l, e., j-4 Jnf"'t-wed 'i'11 F~
V'L[U-4. At high 7 walLes 't If tyuuwt - I-t 1',- 6,
atu-mg L~Io- some deft-tize .Jul, 'A it ~ ,- : 7 ~ ":;" -
mcchanigra Lb-- dliminatkn C-d st H PIU3. f,14.v, lqw-~qs'
and F&I =uill 9 v~alues tim incrc-.,~e jitust t,, mvcr%e~y
6:m21 to the exchange cufre.;t (if thz
The cLadw:uru wert c,-vvpsrvj vWi ey~~li

IOFA. Z.A.; FRMTKIN, A.N.; iAZNI(;EDCNKO, E.A.
Effe)ot of the nature of cations on the rate of hydrogen
separation from alkaline solutions (with summary in English].
Zhur.fiz,khim. 31 no,9;2042-2051 S 157. (MMA 11:1)
l.Moskovskiy gosudarstvennVr universitet Im. M.V. Lomonosova.
(Cations) *(Hydroged) (Solution (Chemistry))

/6

AUTHORS Frumkin, A.N., Academician 20-4-33/6o
Rikolayeya-Pedorovioh, N.Y.
TITLE The Super-equivalent Adsorption of Cations on a
Negatively Charged Mercury Surface.
(Syerkhekyiyalentnaya adsorbtsiya kationov na otritsatellno
zaryazhennoy poverkhnosti rtuti.)
PERIODICAL Doklady Akademii Nauk SSSR, 1957, Vol- 115, Nr 4,
pp. 751-754 (USSR)
ABSTRACT In a demonstration of electrooapillarity It is usually
assumed that among the anorganio ions only the anions
possess a specific adsorbabilityl that the concentration
of the anorganio cations in an electric double layer is
only determined by the quantity of their charges. But there
exist published data which point to the inaccuracy of such
a conclusion. A direct conclusion on the different ad-
sorbability of the cations of alkaline metals in solutions
of 0,1 N - chlorides becomes olear from Grahame's paper
who determined the precise values of the differential
capacity of the latter. His conclusions are in bad agreement
with experimental data. In order to avoid oontradiotions
in the interpretation of test results, it is simpler to
CARD 1/5 assume a certain, although not large, cation adsorption

20-4-33/60
The Super-Equivalent Adsorption of Cations on a NeLatiyely Charged
Mercury Surface.
with a larger radius. The study of the temperature coeffi-
oient of the reaction of electric anion reduction leads to
the same oonoluaion. Measurements of the differential
capacity in 0,01 N- chloride solutions of alkaline metals
were performed, in order to check the guess of the specific
cation adsorption. A pendent mercury drop served as test
electrode. The obtained results are given in tab. I A.
The curves oonoern the differential capacity in 0,01 N-
solutions of lithiumv potassium and cesium chlorides.
A difference in the capacity for cations with Yarius radii
is here not only observed in the case of considerable
negative potentials, but also close to the zero-charge
point where a minimum occurs on the curves. A difference
in the-oapacity values of lithium and oesium chloride
solutions furnishes an additional indication concerning the
speoifio adsorption of the cesium cation.
CARD 2/5

20-h-35/69
The Super-Equivalent Adsorption of Cations on a Negatively Charged
Mercury Surface.
This conclusion nVI however, not be considered an un-
equivosal, sinde the data are in such solutions
complicated by the Cl- adsorption. The most convincing
data aoneerning the super-equivalent cation adsorption
may b*.obtainod by measurements of the differential
capacity on negatively-ohargod electrode surfaess in
the presence of such an anion, as *.g. J-, whose ad-
sorption in the surface layer markedly influences the
value of the differential capacity. Such measurements
are performed by the authors in 0,1 X solutions of
NaC1, HaJ, CsCl, Caj, as well as in 1,1 N solutions
of
KCI, 1 N KJ + 0,1 N KCI, 1 N KC 1 + 0,1 X LaCl
and
I N KJ + OpI X LaCl3
The data are given in fig. 1 B and 2 A. From them follows
CARD 3/5 that in the case of sufficiently negative polarizations

20-4 - 3,:;/6o
The Super-Equivalont Adsorption of Cations on a Negatively Charged
Veroury Surface.
the iodine anion stop* to exert an influons&, and the
values of the differential capacity for the correspond-
ing chlorides and iodide* are in agreement. In the case
of still stronger negative potentials the capacity values
are only determined by the cations present in the solution.
But the potentials at whom the difference between the
capacity values of the corresponding chlorides and
iodides disappear* are not ouqal and depend on the
nature of the cation. As may be seen from fig. 1 D and
2 A, in the case of oroggativ* potentials the sapasity
in the pr*s*ne4 of 0:4 or La*** in connection with the
penetration of anions into the electric double layer
suddenly iner*&sex as aospared to W or X*. The fast
that the superequivalent adsorption of sations may lead
to the penetration into the surface layer also in the
case of negative potentials, b*oozea especially obvious
in the adsorption of organic cations. Fig. 2 B gives data
concerning the dependence of th* differential capacity
in I N solutions ofEl, KBr aud KJ in the presence of
CARD 4/5 1o-3 N(c4R9)4 2 s04
CARD 5/5

AUTHOR: Frumkin, A. N., Academician 20-1-27/42
TITLE: On the Difference of the Potentials and the Accumulation
of the Components of the Solution in the Diffusion Layer
During Steady Electrolysis (0 raznosti potentsialov i
nakoplenii sostavnykh chastey rastvora v diffuzionnom sloye
pri statsionarnom elektrolize)
PERIODICAL: Doklady AN SSSR, 1957, Vol. 117, Nr 1, pp. 102-105 (USSR)
ABSTRACT: The present report attracts attention to some peculiarities
of the distribution of concentration and the potential in a
diffusion layer during steady electrolysis. The author first
investigates the case of the steady electrolysis of a binary
electrolyte with any concentration which consists of a
discharging cation with the valence n 1 and a not
discharging anion with the valence n2. For the difference
of the potentials between a point on the surface of the
electrode and a point in the center of the solution it
holds that
(RT F)ln (a II/a 12).
/n2 2
However, the value of all/as cannot be determined from this
2 1
Card 1/3 formula, because not but only ~ + Aj can be determined

On the Difference of the Potentials and the Accumulation 20-1-27/42
of the Components of the Solution in the Diffusion Layer
During Steady Electrolysis
by measuring. Here denotes the modification of the
potential difference y between electrode and solution as a
-1
result of the change of c,ncentration in the layer near the
electrode. Next, the expression for ~ + Ay which
corresponds to the above formula, is written down. The
measurable quantity I + Ay is expressed not by the average
but by the individual activities of the individual ions. It
would be of great interest to apply the equation for I +&Y
the concentrated solutions, as e.t;. acids. The author
first investigates the case of a diluted acid which t-ontains
a cation 1, discharging on the cathode with the valence n 1
and the concentration cl (in equivalerts per cm3) as well as
a not discharging anion 2 and a not dischargin& cation 3 with
the valences n and n and the concentrations c- and c
Because of the2condition of electric neutrality 2it 3'
holds that a + c '2* Next, relations between the
concentrationl of h: not dischargine, ions on the ourface
Card 2/3 of the electrode coo, cif and in the int,~rior of the
2 3

On the Difference of the Potentials and the Accumulation 20-1-27//,2.
of the Components of the Solution in the Diffusion Layer
During Steady Electrolysis
solution outside the double layer durinE steady
electrolysis are given. At cj/c; - 104, n 3 - .1, and n2
the degree of enrichment of the not dissolving cation is 10.
The practical applicability of such an enrichment process
is, however, limited. However, the analytical applications
of such an enrichment are real. In conclusion the author
illustrates the relations between the total and the "ohmic"
decrease of the potential in a diffusion layer on the basis
of an electrolyte with three ions.
There are 3 referencesq 2 of which are Slavic.
SUBMITTED: July 30, 1957
AVAILABLE: Library of Congress
Card 3/3

L
AUTHOR: Frumkin, A.N., Academician 25-1-8148
TITLE: Fuel Element (Toplivnyy element)
PERIODICAL: Nauka i Zhiznl, 1958, # 1, P 17 (USSR)
ABSTRACT: The author, one of the leading Soviet electrochemists,
recommends that re3earch on the fuel element be intensified,
e.g. the composition of highly efficient high temperature
gas elements be studied and experiments with high temper-
ature elements which make use of solid electrolytes with
good conducting qualities be carried out. The discovery
of such an electrolyte, where the transmission of current
is carried out completely by oxygen anions, would represent
a remarkable achievement in this field of science.
AVAILABLEt Library of Congress
Card 1/1

FRMIKIN, A.N., almdamik; LUKOVTSET, P.D., doktor khim. nauk
--w1whent state of knowledge of the mechanism of electrode processea.
h'him. nauka i prom. 3 no.4:410-417 '58. (MIRA 11:10)
(Chemical reaction, Rate of) (Eloctrochamistry)

AUTHOR: "lo'ne given-.
62-513-4-30/132
TITLE: Anniversary Session of the DePal*tment
for C,-cnical Sciences of tiic 1,; u.:,Li,-L on October 3o and 31,
1957, an(I Gpneral 1!eetinz; of the De,,,artment for Chemical
Sciences on )ecember 11~ and2o, 1,057 (Yubileynaya sessiya
otdeleniy-- a,k SSSR t 30-31
ol-tyabrya 1957 G,i obshcheye oobraniye otdeleniya khiniches-
kikh nauk 19-2o dekabrya 1957 -,)
PERIODICAL: Izvestiya Akadenii 11auk SSSR,Otdeleniye Khimichcskikh Nauk,
1958, lir 4, pp. 521 - 524 (USSR)
ABSTRACT: On the occasion of the 4oth anniversar,, r of the October
Revolution a reunion meeting of the Department for Chemical
Sciences of the AS USSR took place. In his opening speech
11. 11. Semenov pointed out the outstanding succes of the USSR
in the field of sciences especially in that of chemistry.
Scientific lectures of the nensions viere held by the follow-
ing scientists, as was mentioned already earlier: Knunyants,
Member, Academy of Sciences, and A. V. Fol:in on the "llitra,
Card 1/4 tion of Fluorofines",A. L. Mlidzhoyan, I'le-iber, AS Armenian SSP,

~'2-53-4-3o/132
Anniversary Session of the Department for Chemical
2ciences of the A3 UZ~!;R on Octol-or 3o an(; 51,111".-71 and Cc--Qral '~.'eotin~:
of the Department for Cho;.,,ical Sciorces on Dccc..i'~~or 19and 2o, 11~157.
on the "Investi,r,-ations in t'!c 2ield of t,,e Syntiesis of
Physiolo(;ically Active Compotinds", R. I.M. Freydlina,Doctor
of Chenical Sciences, reported on the "Investi~;:,tion of
the Telomerization Reaction and Ue Reaction of the Synthejis
on the Basis of Tel orwroll (Rof orenco 2). B. A. Dolroplook,
Doctor of Chemical Sciences, spo!:c on the "Generation of
Free Radicals in Solutions and Tl~ eir Reactions in !Iodel Sy-
stems," A. 14. Frumkin, Member of the Academy of Sciences,
report ad_o_-fi--"B'_o-m.-eF__a`Fr, oral Problens of Electrochemical Kine-
tics and the Theory of Ion Reactions" Rc~erence 4 9 A. V.
Kiselev, Doctor of Cliemical Sciences spoke on
Reference 5
"Some Problems of Adsorption Theory", 7.1. Emanuel' (Reference
6),Doctor of Chemical Sciences,reported or. "Now Problems
in the Field of Ciain Reactions", V. L. Tal1ro:-.e,Ca-didatc
of Mlemical Sciences, spoke on ria-c-s-spectroscopic investiga-
Card 2/4 tions of ion-and radic~.-l reactions, A. P. Rebinder,laember,

62-56-4-3o/32
Anniversary Session of the Department for Chemical
Sciences of the AS USSR on October 3o a:-,1 31, 1'1'57, ;"-Otin,-
of the Depart-,ent for Mcinical Scionces on -Ilece-lbor 11and 2o,l~,57
Academy of Sciences, drew conclusions -,-:ith re".-a:-d to the
developriont of physico-chen'lical
I. V. Tunan-lrev, Corre.,; pond i n:- jl-'.enter of the AS USSR, L;avc
now data on the chei.,.iolry of co-~te r: re D. I.
2yabehikov and ot'ierns spoke on the 1111roble-ir, of tile Chc%iis-
try of Rare Earth Elc-7icnts"; the final lecture -war, th:A
of V. A. Sol:olov, Doctor of Che7.ical Sciencer,on the "Ca-
lorinetric ,'camtre,~icnts -.t Hi,-h Te:.,.j)eratiir s".
General Rc,cizlar Mlcetin~; of the Dcpzrt:.ci,,t for C'.c;:iirtry of
the AS USSR (Dece.--,ber 19 - 2o,1957):A. I. Brodskiy,Correspon-
dinC; Meriiber, AS USSR,cpol:e on the "Investil-at-Jon of So,-,e
Reactions of Peroxides and Peracids of Hydro,-,cri by IMeans of
the Isotopic '-Tcthod11,M. I.i. Shemyal-in, Corrcn,~ondin.- L'ember,
AS USSR, npo'~e on the "Use of 1115 for the Explanation of the
T:ec:ianisra of So7,e Or.--anic Reactions", 0. A. Reutov, Doctor
Card 3/4 of Chc.,.,icn1 Sciencea,reported on VX "Inventi,.:.tion of the

62-50-4-3olN
Anniversary Session of the Deparb=t for Chemical
Sciencc.j of the AS US.;R on October 3`0 ard 31 , P`57,,-ld "e;'-val 1.ieetinu
of the Depart-iont for C~.Crlical Sciericc.3 On Dccc-11,cr 19 and 2o, 1957
Electrophil and llomolyticaal Rea,:tions of t!-.e Substitution
in the Carbon Atom by Means of the Method Of I.-OtOT)e Ex-
chanLoll,I. P. Alimarin,CorrespondiiiL, Member,AS USSY., rcPor-
ted on new methods of determination of the division of
rafe elements usinu or.-anic derivative sulfuric-,selenic-
and telluric acids, V. G. Levich, Doctor of Chemical Sciences,
reported on the "Diffusion Yinetics of Heteror-enous Chenical
Reactions in mobile Liqui(Is".There are 0 references,all of
which are Soviet.
AVAILABLE: Library of Con~;ress
1. Chenical indwtry-USM
Card 4/4

76-1-241P
AU'2HORS: Frumkin, A. N. Polyanovskaya, 11. S.
------------ -
TITLE: Eleotrocapillary Phenomena in Salt Solutions of Thallium and Cad-
Mium II. (Elektrokapillyarnyye yavleniya v rastvorakh soley talliya
i kadmiya. II.)
PLRIODICAL: Zhurnal Fizichoskoy 1(himii, 1950, Vol. 32, 1fr 1, pp-157-163 (USSR)
ABSTRACT: Anomalous electrocapillary curves in thallium salt solutions. In
the earlier works of the authors (reference 1) experimental results
of the electrocapillary mercuric curves of solutions with thallium
salts were given. The measurements werecontinued up to the poten-
tial ? -0,45 with a normal calomel electrode. Bj this, the cur-
rent passage through the solution in the capillary of the capilla-
ry-electrometer could be determined. On occasion of a control inea-
surement carried out according to the i-.iethod described in reference
1 with lightly acidulated 0,2 11 TINO + 09VIT YNO 9 it was rhown
that these measuments can be continhd up to mo e no-ative poten-
tials (If - normal). By this, a --dpillary curve of a strange form -
with two maxima - vian obtained. It is shown that in this case ac-
tually two clectrocapillap, curves belonCing to different systems
are measured in exporiment. The curve situated at the left is, as
Card 1/4 this is shown in the firut part of this work, the electrocapillary

76-1-24/32
Electrocapillary Phenomena in jalt Solutions of Thallium and Cadoium.N.
mercury curve of the thallium salt solution. Further:aore, it is
shown that the right part of the two-humped curve ohows the electro-
capillary curve of the Tl-arialgam with constant composition in a
rV 0,9ff KNO3solution. It is shown that at YK, -0,562 with an
accuracy of up to 10 ;"" the composition of the azial~,,am formina in
the capillary of the+electrometer remains constant, whilst the con-
centration of the T1 ions decreases at least by the tenfold, i.e.
up to 0,02 If. At 0,642 the boundary value of es (concen-
Y - Tl
tration of thallium in amalgam at the boundary with the solution)
is obtained with an accuracy of up to 1 /'o, whilst the c3 + value
Ti
(concentration at the boundary with mercury) decreases up to 0,002N.
The descending branch of the electrocapillary curve of the Tl-amal-
gam io near to that of the N KIM,, except it is displace somewhat
to the negative side. In the refdrence 2 of one of the authors it
is shown that the boundary-stress must increase by - 0,5 dyn/cm
in a sulution of equal composition at potentia13 being -more nega-
tive than -1,1 on oc,,-oion of the conversion from mercury
to 0,45 of amalgam. This fact correoponds to an avera-e displace-
ment of the descending branch by 3,5 mV in the direction towards
the more negative potentials. This displacement is oubjected to
two further effects. The conditions for the arising of these effects
Card 2/4 will become clear, if the potential decrease and the quantity of

2
Electrocapillary Phenomena in L;alt Solutions of II.
the concentration variations produced on occ,.~Aon of the current
passage throuGh the capillary are det~rraincd. If ,-,I! the3c effects
are oii:_ined up it can be seen that the deocendin[; branch of the elec-
trocapillary curve 0,211 '21,110 + 0 311 121C in co-.inarison to the
same branch of 11 KFO oolutih Lius't dispiace itsclf by -2,7+2,7+
+ 3,5 = 9 ,-1v to tho Lgative side. The di3placenont oljzcrved on
occanion of the experimQnt amounted to about 10 :,X.
The ~.lectrocapillary phenomena in caLLAkim oalt ;olution. Ao it was
shov-m b~? 1'.. 11. Frunkin and F. Servis (refert.nce 3) the point of
the zero-charge of the cudmium w-ialgan in FC1-, -,::Ir- and KJ-Solu-
tions displace itsdf , as in the case of tballiuja salts into the
direction of the more nel-'rative potentials. T.A3 -.,t--s also confirmed
by the neaouremtns of the clectrocapillary curves of the a:-1a1.L,,am
by A. V. Gorodetskaya. It is shown th2t the tot--I curve obtain-od
on occasion of the measurement of tho dept~nderce of It,.c boundary-
stress of mercury upon the polarization in the 21,0:7 .-~3r + 0,5N
CdBr -jolution distinctly consists of tWO CICCtrOCLpJlIar,,- curves.
The left one is to be considered as the ,enerLl (-1cckrac,-.`pillary
curve of :acrcury in the solution mi~rtionod, w-ilst V-10 ri ,---ht curve
has to be tn-.en for a electrocapillary curve of cad:.~,iu::i nllul~,a3 in
Card 3/4 the Y.73r-solution. Analorouo re2ults aerL obt:iin~zd the 0,611 KBr+

7 2,'j/~ 2
Electrocapillary Phenonena in Salt Solutions of `2halliun and
+ 0,21[ CdBr2-solution, whilst in the caue of the +
4. 0,211 CdSO -jolution n salient point in the tot:!l _Ou4e
C01114not be4found. It is a3:jned that in thi3 Oy3tC L tl'.(! -urface
activity, as well of the Cd -ion in the solution, of the Cd
dissolved in i,icrcury, is much too small. Thei-e are and
6 reforenceo, ;.11 of which are ~Aavic.
AS20CIATION: AS USSR. Institute -of Physical Cheniotry. "oocow
(Akaderaiya nauk SSSR. Institut fizicheakoy %hinii.
SUB1,11ITTED- November 5, 10,56
AVAILIBLO: Library of ConEreso
Card 4/4

/41/v -
AUTHORS: Frumkin A N Aeadwdelan 2o-3-32/59
_ie~_Wo ~ra
TITLE: The Ionisation Kinetics of Yolecular Chlorine
(Kinetika ionizataii molokulyarnogo kh1ora)
PERIODICAL: Doklady AN 338R, 1958, Vol. 118, Nr 3, PP- 530-533 (USSR)
ABSTRACT: The authors investigated the kinetics of the electric
reduction of chlorine on a rotating diak-shaped platinum 2
electrode. The surface area of the electrode was 0,78 mm
The chlorine was produced by electrolysis of 15- per cent
HC1 and washed by letting it pans through the solution in
test. The electrode to be investigated vas activated before
the experiment, The performance of the experiment is de-
scribed shortly. At not very high excess voltages the
amperage of the ionisation current for chlorine depends on
the fact, wether the voltage changes from the more anodic
potentials to the more cathodic ones or vice-versa. A
limiting value of the amperage of the ionisation current
must exist, which is determined by the dinsociation velocity
of the chlorine molecules. Besidee,no linear dependence
Card 1/3 between the excess voltace and the loCarithm of the cathode

The Ionisation Kinetics of Molecular Chlorine
2o-3-32/159
current is obtained. The amperaGe of the cathode current_in
case of given exceen voltage cannot depend on the con-.-j. 40-
centration of the chlorine ions [cl-J. For the potential
of the electrode and for the excess voltaGe formulae are
j;1ven. In case of vnlidity of a certain asnumption*'given
here in detail a linear dependence must be valid between the
locarithm of the corrent denEity and the potential (or the
overvoltage). Thin aonclusion in also proved by the ex-
periment. The independence of the current denaity on [Cl-j
in cane of given potential of the electrode proven the
irreversibility of the state of nelf-sustained ionisation.
The results of the experiments M well into the score of
the theory, if the followini; Is assumed: The proceso of the
ionisation of Cl. pasnec the folloring two states:
Cl')+ e C1 + Cl-; Cl + e "Cl- apart from
2d?orbgjffu3, sor~pd `f-
thb state o he on of H 2* he first one of these
both reactions is irreversible in case of sufficiently high
excess voltai3e. There are 4 fieures and 4 references, all
of which are Slavic.
ASSOCIATION: Chair for Electroch-mictry of the State University imoni
M. V. Lomonosov, Moscow (Kafedra elektrokhimii hloakovsko.go
Card 2/3 -o3udarstvenno.-o universiteta imeni 'A. V. Lomonosova)

The Ionisatioii Kinetics of Molecular Chlorine 20-3-32/59
SUBMITTED: September 25, 1957
AVAILABLE: Library of Congress
Card 3/3

2o-119-2-36/6o
AUTHOR: Frumkin, A. N., Member, Academy of Sciences, USSR
TITLE: On the Stoichiometric Number of the Reaction of Electro-
chemical Hydrogen Desorption (0 stekhiometrichookom chisle
reaktaii elektrokhimicheskoy desorbtsii vodoroda)
PERIODICAL: Doklady Akademii Nauk sssn, 1958, Vol. U9, Nr 2
PP,4.'318 - 321 (USSR)
ABSTRACT: First several previous papers dealingwith the same subject
are mentioned, discussing the applicability of a criterion
proposed by J. Horiuti and Yukasima (Reference 6) concerning
the explanation of the mechanism and of the nature of the
slow stage of the transition of hydrogen ions into molecular
hydrogen
(2A+ + 2e_g====* R2)'
At present usually the stoichiometric number V which is
Card 1/4 equal to 2/,k is used as criterion. HereV denotes a number

2o-119-2-36/6o
On the Stoichiometric Number of the Reaction of Electrochemical Hydrogen
Desorption
characterizing the process. This number V expresses how
many times the slowest stage must be repeated in oder to
pass the whole process once. When the surface of the electrode
is homogenous and when the displacement of H adsorbed on
the surface of the electrode is not connected with a noticeable
activation energy the amounts of direct and inverse reaction
velocities v 1and v 2 of the stage discharge-ionization
H + Hadsorbed
and of the direct and inverse reaction velocities v 3 and v4
of the stage of electrochemical desorption-adsorption
Hadsorbed + H+ + e-f==; H2
Card 2/4 can be represented by the here given equvtions, The further

2o-119-2-36/6o
On the Stoichiometric Number of the Reaction of Electrocladeal Hydrogen
Desorption
course of the calculation is followed step by step and the
results are mentioned in detail:
V - I + 1/21 - I + i 01 /21 011*
Here-i 0I denotes the exchange current in the sta,,Ie discharge-
-ionization and i 01I denotes the exchange current in the
stage desorption-adsorption. Only with i 0I