SCIENTIFIC ABSTRACT GRIB, V.P. - GRIBANOV, I.P.

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• Collection: Scientific Abstracts
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• Original Classification: S
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• Document Creation Date: January 3, 2017
• Document Release Date: July 27, 2000
• Sequence Number: 9
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Concerning Imides of Phosphorus Acids.
Infrared Absorption Spectra of Imido-
phosphates and Imidophosphonates
77069
sov/62-59-12-13/43
T7ialb,A N-methylimidophosphates are colorless liquids,
easily hydrolyzed by water with formatJon of met.*-~yli-
mides of dialkylphosphoric acids. They react -uh
CS2 as follows:
(ROW, = IM H:, + CS. -t (Ifu)j S + C I I
E. M. Popov, I. F. Lutchenko, V. N. Smorchkov, I. Ya.
L
Kachkurova I. V. Obreimov took part in thJs work.
There are 4 figures; 2 tables; 12 references, 1 German,
2 U.S., 2 U.K., 7 Soviet. The 4 U.S. and U.K. refer-
ences are: L. W. Daasch, J. Amer. Cheri. Soc. 76, 3403,
1954); L. W. Daasch, D. C. Smith, Analyt. Chem. 23,
453 ~195fl; D. E. Corbridge, J. Appl. Chem. 6, 10,
456 1956 ; D. E. Corbridge, E. J. Lowe, J. Chem.
Card 11/12 Soc. 1954, 4555-

Concerning Imidea of Phosphorus Acids. 77069
Infrared Absorption Spectra of Imido- sov/62-59-12-13/43
phosphates and Imidophosphonates
ASSOCIATION: Institute of Element-Organic Compounds, Academy of
Sciences, USSR (Institut elementoorganicheskikh
soedineniy Akademii nauk SSSR)
SUBMITTED: April 18, 1958
Card 12/12

KABACHNIK, M.I.; GILYAROV, V.A.
I
Imides of phoophorus acids. Report No,5: Reactions of trialkyl-
phosphites with hydrazoic acid. Izv.AN SSSR.Otd.khi-.nauk noe5:
816-818 W 161. (MIRA 34:5)
1. Institut sl~mntoorganicheskikh ooyedineniy AN SSSR.
(Phosphorous acid) (Hydrazoic acid)

KABACIMIK, M.I.; GILYAROV, V.A.
Wdes of phosphorus acids. Report No.6: Trialkyl-N-adylimido-
phosphates. Izv.AN SSSR.Otdokhim.nauk no-5:819-823 Yq 161.
(KIR& 14:5)
1. Institut elementoorganicheakikh noyedineniy AN SSSR.
(Phosphoric acid)

KABACHNIK, M.I.; GILYAROV, V.A.; FOPOV) Ye.M.
Imides of phosphorus acid. Report 7: Amideimidolic tautomerism of
amides of pentavalent phosphorus acids. Izv.AN SSSR,Otd.khimonauk
noa6:1022-1030 is 161. (MIRA 14:6)
1. Ixwtitut elementoorganicheskikh soyedineniy AN SSSR.
(Phosphosus acids) (Amides)

KAUCHNIKv M.I.; GILDROV V.A.- POPOV, Ye.M.
Tautomerism of phosphamidines. Zhur.ob.khim. 32 no.5:159&-1604
Yv 162. (MM 15:5)
1, Institut elementoorganicheakikh soyedineniy AN SSSR.
(Phosphorus acids) (Amidines) (Tautomerism)

GILYAROV. V.A.
"Tautomerism of certain inddea of phosphorus acida."
KhimiYa I Primeuaniye -ean for, rgran-ic K- -0A 4f~v
apolication of organonhosptx)Mit Colinoutvlt~'s A. -,fF_
~'ubl~ by Kazar hffll~ Acad, ).nt. TISFrt, Y-,Zwow
Collection of coifr,,Irnto- oavena orv---jnnt,*-d ,zit t!w
Ghemistry, of ,rjmw)urm4.

GILYArOV. V.A.
I
oaction of salts of dialkylphosphoras acids with diazometbane."
R
rMM-ini,pa 7 r-,
A~
iv)~' by Ac.)(,-,

KABAGIRIIK, CHZHMJ GHZHEN-DE[Ghand Ghtng-tieh.'j;MATRWOV, Ye.l.
Problem of tautomeriBm of 14-acylamidophosphates and N-acy2amidophoophinates.
Izv.AN SSSR.Otd.khim.nauk no.9:1589~1599 S c62. (MIRA 15:10)
1, Institut elementoorganichookikh soyedineray AN SSSRs
(Phosphorami,d~c acid) (PhoBphinamidi6 acid) (Tautomer-ism)

P--4-'/Pr-4 F,P L
ACCSSIHON MR i AP5012451 J;III.-I .4i UR/0062/65/000/004/0665/0(~
54-1
AUMIM"ISt
TITTLE.-
SOMIGE!
Kabachnik, M. I.,, Gilyarov, V. A.; Chang, Cheng-te
TrJgJJZ-J=M-nq~limidoLhosphaII; I as conjugate systems
All SSSR. Izvestlyn. Seriya kh5micheakaya, no. 4, 1965, 665-669
TOPIC T-40 : conjugate system, phosphate, alkylation
ABSTRACT: Trialkyl-n-acylimidophoalihates aa conjugate systems were investigated,
and it is shown that these compounds: enter into substitution reactions according
1,2; 1,4; and 1,6 types. The 1,2 reaction was obtained by heating triethyl-
:,-',~-,'~f',-,,ioro-a(--etylimidophosphate with triethy.1amine. ir this ~~7-ocess the nitro-
c~ tertiary base underwent e-lky. Iation Irl triethyI T%hosphilla. The 1,4
reac.ion was observed when triailql-.n-.acylimi(iophosphate was acted on by HC1.
-t~e Lni-daphosphate goes to amidophosphite and allc7l halide is uplit off. 7he
~,b reaction was encountered in the reaction of trialkyl-n-acylimidophoolhate
with allql halide. On heating IxWJql-a-acylimidophoaphate with meth7l. iodide
or ethyl bromide at 100-130C for 4-6 hours, ortho--allcyl-n-(diethyl phosphoryl)
i-minoacetate ifl formed. When this same prccedure was attempt3d W-ith
Card 1/2

-5-444&65-.---1.-
ACCESSION NR: A-P50=51
triethy-l-n-d-Achloroacetylimidophospbat"O (and methyl iodide), no reaction was ob-
ser7ed. The lower reactivity of the acetylimidophosphite uay bo due to lower
r
I
ucleoPhilicity of the carborql ox7gen at the 9,cpense of the '-nductive effect of
the ketually trio thy! -n-tr if luoro-;l c e t-T1, 1m,- -:+C's -71h8 te reacts
unsubstitut'~l .r4.e,---,rl-n-acet,;-Ii--idophosphat4a
triet~iyiamlne-4 whereas
loea nr;'. react VIWTFI-erhylamim under the samo conditions. D, lis therefore
maintained that the tetrahedral phosphorus; atom may ant-ar the conjugate chain
6 5 4 3 2 1
-11 0 Orig. art. has: I table and 10 formWlae.
A
ALSSOCIATION: Institut elemGmtoorganicheakikh awredinemiy, Akademii nauk SSSR
(Institute of Hatero-Organic Comtounds, AcadenV of Sciences SSSR)
SUBKIWED: 15Ap--63 SNOL: GO SUB CODEt DGY GG
NO REF SOV: 006 DTHER: 001
Card 2/2

,L U31-66--,
ACCESSION NR: APS022927 UR/0062/65/000/OOFI/1331/1336
543.422 + 66~r7lg.l
qdf ;& 7 / 3
AUTHOR: Matrosov, Ye. I.; GLIjrarov, V. A.; K#bachnik, M. I.
TITLX: About amidoimido-tautotieriam of H-phosphorylamidophosphatesiand phosphines
SOURCE: AN SSSR. Izvestiya. Sorlya khimicheakaya, no. 8, 1965, 1331-1336
TOPIC TAGS: amide, Imide. tautomerism, N-phosphorylamidophosphate, phosphine,
IR spectroscopy
'ABSTRACT: The amido-imido tawlmmerism of amides of acids of pentavalent phosphom c
A 0 A OH
P P
\NHR
was investigated by IR spectroncopy. The IR absorption spectra of H-phosphoryl-
imidophosphates and phosphines are shown in fig. I of the Enclosure.. The IR ab:-
sorption spectra of N.-Phosphorlrlamidophosphates and phosphines; are shown in fig. 2
of the Enclosure. For the coMiounda in question, vibrational frequencies corrs-
Card 1/4

-L-3-131-66--
ACCESSION NR-. AP5022927
sponding to P N group occur.in.the 1296-1338 cm-1 region and those corresponding
to P = 0 group occur in the 1210-1253 cm I region. The IR spectra indicate an
amide type structure of the H-phosphorylamidophosphates and phosphines. The phos-
phoryl group may form a strong hydrogen bond to the HH-groups and, thus, cause a
strong shift of the bond corresponding to N-H vibration toward wave numbers short-
er than 3100 cm-1. As a result, the absiorption band characteristic for M-H Vibra-
tion in N-phosphorylamidophosphattts and phoaphines, 0
0
P
N-H ...
>P~
occurs at 2700 ca Orig., art. Wist 2 figures, 2 table's
ASSOCIATION: Institut elementoorganicheskikh soyedineMy Akademii nauk SSS&
(10-tuute of Elawntal 2ESante Catpounds, Academy of SciencssjSSSR) 1~4r_ri
SUBMITTEW UJan65 ENCL: 92 SUB COIDE: GC, OC
NO REF SOV: 005 OWER: 002
Card 2/4

CCESSI(W MRs Ap

tie
4ft lift
it

cc CL

cx

"L all.

Card 3/4

AbsOrptlon
,

-d(OVO)
AA

L 25325-66 ..EWP(J)/EW"r(m) RM
ACC NRs H6019323 SOUHCE CODE: UR/0079/65/035/008/1476/i48:L
17
AUTHORi Kabachnik, He L; GALwrcry. Vo AK%du-a-ytsev,2A-Y&--
ORG: Institute of 0r6&no01ownta1-9qmpourdq-.,_ AN SSQ.-(Institut elomontoorganichoold.16
soyedinen
S
TITIE: Study of conjugationIn 9'ystema wWi a tetrahedralX~2 A~�rus atom*,
Phosphudde.syster4- 17
SOURM obahoh6y khirdi, 1r, 35, no, 8, 1963. 1476.IWI
TOPIC TAGS: tautomrism$ orgonio 14iosphorus compound, mthylation
ABSTRACT: The reactions of 0 0-diethyl-14, NI-diphenylphosphamidine
and of 0,0-diethyl-N-phonyl-N;-m-tolylphosphamidine with C$2 were
'investigated. The products were 0,0-diethyl-N-phenylamidothio-
phosphate and aTY1 isothiocyanates. Formation in the second case
of a mixture of phenyl isothlocyanate and m-tolyl Isothio0yanate
confirmed the existence of phosphamidine tautomerism. In the
methylation of Na derivatives of diarylphosphamidines with Melt
a mixture of t~o methylation produets formed when two different
e:ryl groups were contained in the diarylphosphamidine. The ratio
'between the two methylation produots depended on the nature of the;
~substituents In the aryl_Sroups._ The tautomerism of diarylphos-
Carci 119 UDC2 546,16-5h%&172,1-

KABACIDTIK, M.I., akademik; GILYAIROV, V.A.; YIJSUPOV, TAI.M.
Stable salts of alko-cyaninophosphoniurns with a delocalized onium
charge. Dokl. AN SSSR .164 no-4:812-815 0 165.
(MIRA 18.10)
1. Inatitut a lemon toorganiche uki kh voyedinonly AN St-,~R.
"I

L 31272-66 EVrr(m)/EWP(i)/T RM
ACC Mr7--Ap-65j-2~96 SOURCE CODE: UR/OC,79/66/C36/002/0274/0282
AUTHOR: Gilvarov. V. A.; Tovetkov, Ye. E.:_Kabachnik. M. 1.
.................
ORG: Institute of Heteroorganic Qomj&undp. AK_apR (Institut elementoorganicheakikh
soyedineniy AN SSSR) ac 11 VIII. N-a
TITLE: Imides of phosphorus idij cylimidophosphates and -phosphinates
and N-acylamiTo-pho-sph-ates and -pho~phinates
NUKE: Zhurnal obshchey Idlimi4v, 36, no. 2, 1966,. 274-282
TOPIC TAGS: organic phosphorus compound, chemical synthesis, dissociation constant,
organic amide, molecular structure, IR spectrum, azide, imide
ABSTRACT: A series of now azidophosphates and'azidophosj%inates wa produced
by the-reaction of chlorophosphatign and chlorophosphinates with triethyl
ammonium azido. N_Acylimidophos~hates and -phosphinates were 8-yhthesize0by
reaction of acyl azides with esteim of phosphorous and phosphinous acids,
and then dealIqlated with hydrogen chloride to the corresponding N-acylamido-;
phosphates and -phosphinates. The concentration dissociation constants of &.11
number of X-acylamidophosphateg wore determined, wid it was concluded an the
basis of the Bronated rule that those substances possess an amide. not an
imidol structure, Infrared. speotpR,of the products were also studied. arA.
will b~ published separately. 'OrIg.'art. has! 1 figure and 4 tables. [JPH51
SUB CODE: 07 / SUBM DATE: 1ONov64 / ORIG REF: 014 / OTH REF: 008
Card 1 /1 (J J UDC%

L 31273..66 _ EWTfM)/FY_W/j_RM
SOURCE CODE: UR/0079/66/036/002/0282/0289
AUTHOR: G11yar , V. A.; Kabachnik. M.
ORG: ij~stitube of He'cerqoi:g~!~njq LomDounds. AN 5,UR (Institut ejementoorgpq~icheskikh
soyedineniy AN'
TITLE: N AII and some of their properties
I "' _.~ 1.--*-'_ rulli _11-1A8
SOURCF; Zhurnal obnhchey khimii, v. 36, no. 2, 1966, 282-289
TOPIC TAGS: organic pho:3phorus compound, chenLical synthesis, organic amide, reaction
niech,ui.15m' '!ubstiUuen'-,
ABSTRACT: A scrins of diothylphosy,hor7l-N,Nt-diarylamidi~es and
e,iol~'iy'li'l-ic,r,pliiriyl-ll,?It-d.iarylamidines were synthesized. 7bo diethylphos.
plior.,rl-"",',4"-(Uarylamidino:j wore synthesized from diethyl chlorophosphite and
&ryl_~'k.nr.3 through intormodiato 0,0-diethyl-N-amidophosphite3 (some of which
for tho first time). In the Mthesis of diethylphosphinyl.
N,', I _6 ryltuaidinoa, tbo intemodiato 11-phMylanddodiethylphosphinite was
produc,:k~ W.- trivisw-dnation frort H-diethylazddodiethylphosphinate und aniline.
The pronotmcod nucloopflilic character of the phosphamidines was noted. A
methoa 3L" Syn the si Z L0 -alkyl -N, N I --diary1di amidophosphat e 8 with various
substituents in LIrie widdo groups wan found. Orig. art. has: 5 tables. [J M11
SUB CODL: 07 / SUPM DATE: 21,Feb65 / ORIG REF: OW / OTH REF: 005
Card 1/1- UDC: 546.183:547-398.5

1-3402Qt6.6- - EWT(M)/-EWF(41----PR-.
ACC NNt 25530 -S0-UJt-C'E--*-C-0D-Et UR)OFO-79W,76j6-/O-OlTOO-~7-/0-661
AMOR: Kabachnik, 11. 1.; Gilyarov, Ve A Kudryavtoev, Re Ve
ORG: Institute of flotoroorfranic C*M2unds. AN SSSR (Institut e1ementoorganichoskikh
soyedinaniy AA 31'35,Z)
TITII',,: Reactivity of sodium dorivativos of phosphanAdinesi 11othylation of ambident
anions of 11, ill-diarylphosphamidinos by mthyl iodide
SOURCS: Zhurnal obahchey Iddmii, v- 36, no. 1, 1966, 57-61
TOPIC TAGS: PiotlVlation, anion, olectron donor, sodium compound
The polar influences of substituents on the course *of methylation
of sodium salts ot N,Nl-diarylphosphamidines by methyl iodide were studied.,
Fifteon socUum derivativas of 0,0-diethyl-N,NI-diphonylphosphamidines,
substituted in the phenyl rings, were used. The course of mothylation (at
,one of the two nitrogan atoms) was found to depend upon the nature of tlia
substituents in the phenyl rings. The ratio of the yields of mothylatioa
products obeys a Hammett equation or the typo log (Q
a/Qb) = 0.757(d,3 - o'k)
0.022. Mothylation was found to be directed primarily toward the more
nucleophilic nitrogen atom, i.e., tD that situated closer to the more
electron donor (or less electron acceptor) substituent. Orig. art. has:' 2 figures
and 1 table' DMS: -3M991
0
SUBC%!,~ ~,07 / SUB11DATE: 22Feb65 / ORIGRW-. 0q&/ fya[Myla 010
Card. 547.
I CY -7

C-14 Y/4k?o[), 1,01,
GILYAEOVA, M. A. "StratigraphY and tectonics of the karelian formation in
central Karelia, I' Uchen. zapiski (Lenin-r. gos. ped. in-t im. Gertsena), Vol.
u
LXXII, 1948, p. 125-67 --- Bibliog: 19 items
SO: U-3566, 15 March, 53, ( Letopis 'Zhurnal Inypk Stately, No. 14, 1949)

GILTAROVA, M.A.
Stratigraphy of the Pre-Cambrian of the losozero region (Tunguda) of
the Karelo-Finnish S.S.R. Vest.IpansusielO no.1:139-150 Ja 155.
(Kosozero region--Geology, Stratigraphic) (MM 8:4)

GILYAROVA.,.M.A.
Stratigraphic position of the Stwe&arl volcanic complex. Uch.sap.
Len.un. no.209:80-100 '56. (nU 9:8)
(Farelts-4k)ology, Stratigraphic)

GILTAROVA, N.A.
Qmarts porphyries and keratephyres of central Karelia. Uch.
zap-LGU no-215:58-83 '57. (MIR& 32:5)
(Rarelia-Forphyry) (Karelia--Keratophyres)

GILTAROVA, M.A.
Pillow lavan in the Suleart area In southern Karelia and the
genesis of pillow levas. Ucb.zap.LGU no.268:3-69 '58.
(MIR& 12:6)
(Karelia-Lava)

M,LYARO-VA. $.A-,-
Oa sme controversial p-oblemo of the Pre-~brian geology of
Karelia. Vest.LGU no*24i34-37 162. (KrM 16 12)
(Karella-Geologys, Stratigraphic)

GILYAROVA, M.A.
Karelian basal formations (Lower Proterozoio) in the Parandovo-
Nadvoitay region in the Karelian A.S.S.R. Vest. LGU 18 no.18:
15-27 163. (MIRA 16:11)

GILYAROVA, M. Aa
Weathering surface and congol-merates in the Lauima.. "'illey of
Pechenga District. Vest ILU 19 no. 6.-22-30 164. (MIRA 17-5)
,*;-~ , %. ~fl & . -w a ~. v;~, -14-

GILYAROVA, V.14.
-------
Ultraviolet radiation in animal husbandry. Vest. AN cSSR 31 nc).11:
V
115-116 N 61. (MIRA 14;11)
(Ultraviolet rays--Physiological effect)
(Stock and stockbreeding)

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(;bunt y rO-R!.'A 11-,2
Category Chemical Technology. Chemical Processing of
Solid Fossil Fuels
Abs. Jour Ref Zhur-Khimiy-i,No 14, 19591No 90982
Author % Tkhe 1)en; Pechuro, XS.
Institute
Title Reacteability of Coke Derived from the Korean
Brown Coal of' tile Aodi Relzion and from Anthra-
cite of the Sanchau Repion ~KNDH)
Orig Pub. Kh-.,akhak ka khvakhak ko nop, 1957, N'o 3, 157-16,
Abstract No abstract.
Card:

AUTHORS: Em Tkhe Don, Pechuro, N. S.0 SOV.156-58-1-38/46
Gilyarovskaya, L. A.
TITLE: Use of Movable Checkers for Thermio Coal Processing (Primeneniye
podvizhnykh nasadok dlya termiche8koy pererabotki ugley)
PERIODICAL: Nauahnyye doklady vy9ahey shkoly, Khimiya i khimicheskaya
takhnologiya# 1958, Nr 1, pp. 157 - 16o (USSR)
ABSTRACT: In some production processes a moving laminated solid phase
is successfully used as & catalystp heat carrier, or adsorbent.
As investigations of the authors have shown, this principle
may be extended to thermal processing of pulverized solid
fuels, too. In order to prove the technological possibilities
of this method, the authors decomposed two samples of solid
fuels showing different properties and heating behavior: a)
a boghead from Olenek, an easily meltable fuel, and b) brown
coal from Ao-Di(Korea) of low mechanical and thermal strength.
Table 1 gives the features of the two coal sorts, table 2
the semicoking products, while table 3 contains some data
on the composition of first gases from this partial carbonization.
Card 1/3 Table 4 features the coal tars from both coal sorts. These

Use of Movable Checkers for Thermic Coal Processing sov,156 -58-1-36/46
coals were thermally processed on a movable, circulating
checker under particular consideration of the variability of
gas yield and gas composition with temperature. The pilot plant
is shown in figure 1. As a checker cast iron balls of 4,8 mm
diam. were used. The grain size of the coal processed was
0,5 to 1,0 mm. In table 5 the products obtained are given,
while figures 2 and 3 show the content of combustible gas com-
ponents, and the gas heating value, depending on the temperature.
Besides thermal decomposition of coal from Ao-Di some thermo-
chemical prooesses have also taken place, whereas processes of
thermal decomposition prevailed in processing the boghead
from Olenek. The following conclusions were drawn: 1) Accorling
to the principle described easily meltable fossil fuels can be
processed. 2) Industrial gases can be generated from pulverized
fuals under consideration of reagents containing oxygen, with .
this process. 3) The solid residue can be burned, the generated
heat being used for preheating the circulating checker. There
Card 2/3 are 3 figures, 5 tables, and 3 references, I of which is Soviet.

Use of Movable Checkers for Thermic Coal Processing SOV/156 =~a-i-,,e/46
ASSOCIATION: Kafedra neftekhimicheskogo sinteza i iskusstvennogo zhidkogo
topliva Moskovskogo instituta tonkoy khimicheskoy tekhnologii
im.M.V.Lomonosova (Cbair of Petrochemical Synthesis and
Synthetic Liquid Fuels of the Institute of Fine-Chemical
Engineering imeni M.Y.Lomonosov,Moscow)
SUB,MITTED: September 20, 1957
Card 3/3

- GILYAROVSKAYA, L.A.
Alkylation of phenols by olefinB in the presence of fluoroborine
dihydrate. Izv. vys. ucheb. zav.; neft' i gaz 2 no.8:63-69 159-
(MIRA 12:32)
l.Institut tonkoy khlmicheakoy tekhnologii im. M.V. Lomonoeova.
(Alkylation) (Phenols)

F S/020/63/148/006/014/023
B117/BI86
AUTHORS: Bashkirov, A. N., Corresponding Member AS USSR,
Shaykhutdinov, Ye. M. j,jLly~~a _L.A.
PITLEj Oxidation of monomethylsubstituted paraffins in liquid phase
in the presence of boric acid
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 148, no. 6, 1963, 1309 - 1311
TEXT: The effect of the tertiary carbon atom on the conversion of mono-
substituted -paraffins during oxidation and on the composition of the
alcohols formed is studied. For this purpose, 2-methyldodecane and
8-methylpentadecane-were synthetized according to Grignard's method. These
h drocarbons were oxidized in Un apparatus described previously
y
(A. N. Bashkirov, Khim. nauka i prom., 1p 273 (1956)) under normal pressure
at 165 - 1700C for 3 - 4 hrs, using a mixture of nitrogen and oxygen with
3.0 - 3-5% 02 (consumption 800 1/kg-hr). The main conversion products were
compounds containing hydroxyl with a yield of A45 mole%. The alcohols
formed were identified as a mixture of tertiary (Pj25 - 30 mole%) and
secondary alcohols having the same carbon skeleton and the same number of
C-atoms in the molecule as the original hydrocarbon. The secondarl
Card 1/2

S/02o/63/14a/oO6/O14/023
Oxidation of monomethylsubstituted... B117/B186
alcohols proved to be'a-mixture of a variety of isomers. Hence it was.
assumed that, under the oxidation conditions described, the tertiary
C-atoms are more reactive with respect to oxygen than the se6ondary C-atome
of the highest monosubstituted paraffin molecules. There are 3 tables.
ASSOCIATIONt Institut neftekhimicheskogo sinteza Akademii nauk SSSR
(Institute of Petrochemical Synthesis of the Academy of
Sciences USSR); Moskovokiy institut tonkoy khimicheakoy
tekhrologii im. M. Ar. Lomonosova (Moscow Institute of Fine
Chemical Technology imeni M. V. Lomonosov)
SUBMITTEDz July 26, 1962
L_Card 2/2_

C-7/4 ryW R 0 VSA',jYvV
', X& -,?
'Therapeutic gymnastics and massage in rickets and 17potrup)7.0
I.IL.Ginzburg. R.G.*Soro-3hek. Revieved IV I.P.Giliarovskaia.
Pediatriis, no.6:91-92 N-D 154. (MIMA 8:4)
(PHYsIcAL Tmayr) (RIMTS) (GIIMURG, I.IA.)

GILYAROVSKAYA. Ye.P.; TMOHIROVA, A.Y.; BILEYKINA, A.M.; RODIONOVA. O.Se
Uaing ozooerite in the compound treatment of dysentery in children.
Pediatriia no.8:81-82 Ag 157. (MIRA 10:12)
1. Iz detskoy bolinitsy Iment F.A.Dzerthin8kogo v Moskve.
(OZOGUITB) (:DYUNTERY)

GILTAROVSYATA, Te.F.; GOLOINIU0.
Treating highmoritis in
duction of penicillin.
1. Iz detskogo otdoleniya
G.S.; BUI)AGOSSKATA. G.A.
children by the electrophoretic
Pediatrits 37 no-7:88 JI '59.
(MIRA
polikliniki No.2 Moskovnkogo gorod-
intro-
12:10)
skogo otdela zdra6voWdiraneniya.
(MICIIIIII) (WAGTROPHORNSIS) (SIITUSITIS)

BASHKIROV, A.N.; G''ILYAROIISKIY, L.A.; ALENTIYEVA, Ye.S.; KOZLENKOVA, R.V.;
KUROCHKTNA, AX.'---'----'-'- -
Effect of aromatic hydrocarbons on the oxidation of paraffins in the
liquid phase in the presence of boric acid. Neftehhlmiia 1, no.5:777-
779 S-0 164. (141RA 18:1)
1. MoekovskLy Institut tonkoy khimLcheskoy tekhnologii imeni M.V.
Lomonosova i Institut neftekhImIcheskogo sinteza Imeni A.V.Topchiyeva
AIN SSSR.

GII;IARO'IBKIY, Vasilly Alcks. LECEAaED
Yledicino see ILC

GILTATtuyal-,~-, VL,-JMTI-, tu-a~o-- ~-,- C'T-. 52774[5
.ols
Moskva I Moskovicbi (Moscow and the Muscovites) I-loskv,,A, Koskowkiy liobcchi~y, 1955.
478 P. Illus.

GILYM.IOVSKIY, V.A., zasl. deyatell nauki, red.; FEDOTOV, D.D., red.;
kiu~AREV, F.M., kand. med. nauk, red.; RIKHTER, G.E., kand.
med. nauk., red.; FELODMAN, E.A., kand. med. nauk., red.
(Transactions of the Scientific and Practical Conference of
Neuropathologists and Psychiatrists of the Baltic Republics]
Trudy Nauchno-prakticheskoi konferentsii nevropatologov i
psikhiatrov Pribaltiiskikh respublik. Riga, M-vo zdravookh-
raneniia. Latviiskoi SSR, 1956. 466 p. (MIRA 17:5)
1. Nauchno-praktichoskaya konferentsiya nevropatologov i psi-
khiatrov Pribaltiyskikh respublik, 1954. 2. Deyetvitellrqy
chlen AMN SSSR (for Gilyarovskiy). 3. Direktor Instituta
psikhiatrii Ministerstvazdravookhraneniya SSSR (for Fedotov).

TT
MAKAROT.',O.N., kandidat tokhnicheakikh nsuk; ZHITOT, B.N., inzhoner;
SHASICKOVA, T.D., 1whetior; SHTITN, I.Ta., Inzhener;
GILYAZErDINDY, L.P .01 Inzhoner.
Preliminary beat treatment of coals for coking. Koko i khIm.
no.4:12-17 '57. (MM 10:5)
1. Mookovskiy kbimiko-tekhnologichaskiy inatitut imeni
D.I. Mendoleyeva.
0 (Coal-Carbonl2stion)

SOV/136-58-8-2/11
ADTHORS: Zuyev, V. P; Gi.'Lyazq,tdinmr,.L_ P. and Yevreinova, M. 0.
TITLE: The Chemical 0o6position of Crude Petroleum Products Used
In the Manufacture of Carbon Black (0 khimicheskom
sostave neftyanogo syroya dlya pr6tzvodstva"'.x&
yz h i
PERIODICAL: Kauchuk I Rezina, 1958* Nr 8. pp 12 - 14 (USSR)
ABSTRACT:- The kerosIne-gati-oil fraction (obtained during pyrolysis
and coking of petroleum) is used as raw material for t4e
preparation of Set carbon black In the USSR. In the"USA
and England arontatised gas-oil fractions, obtained during
the thermal-andoatalytic processing of petroleum,are used
for the manufacture of the activated carbons HAF,ISAF and
SAF. No detailed investigations have been published on
the effect of the chemical composition of the raw material
on the-yield and properties of the carbon black. The nat-
U're-of the gas _oil fraction of crude petroleum and its
products is defined by the GrozNII method by which the
percentage of arovatiop naphthenio, paraffinic and olefin-
io hydrocarbons Is determined. The authors used the n-d-M
method (Ref.3) for definining the composition of the pyro-
lysis and of the coke distillate. They determined by x ri
'
ments the molecular w ght M9 the refractive index w~
nd
g
Card 1/3 ? The hydrocarbon content was do-
the speolfic weight d

SOV/138;5~--Wll
The Chemical Composition of Crude Petroleum Products V ed in the Manu-
facture of Carbon Black
.fined by chromatographic analyzis'aocording to the TsIATIM
method (Ref.6) and the degree of unsaturation of the sam-
ples was determined lodometrically. The physioo-ohemioal
characteristics of the samples of raw material are listed
in Tables 1 and S,, and results of the chromatographic
analysis in Table 3. The total content of pure paraffins
and olefins 1h the pyrolysis fraction does not exceed
5%; therefore, this fraction consists of aromatic and
naphthenic-arota-tio'hydrocarbons, two condensed rings
and partially unsaturated side chains. The content of
paraffinio-naphthofilo hydrocarbon in the coke distillate
fraction varies between 40 53 . Approximately 50%
of this quantity represents pure paraffinic and olefinic
hydrocarbons and it comprises 27% dicyclio aromatic hydro-
Card 2/3 carbons. The degree of aromatitation Increases in both

SOV/138-58-8-2/11
The Chemical Composition o-f Crude -Petroleum Products Used In the
Manufa,cturc of Carbon Black
fractions when the temper.--tture is raised (Table .55).
The rlenro~c- of aroizat-jx&tlon and cyclisation can be
increased in the colle d-stillate fraction by boostin,~
the contEp~'.- a-7 hiLb boilipt-fractions. There are 5
j
Tables and 7 Ra.feronces- t' Soviet and 4 EnLlish.
AO'SOCIATION: Nauchno-issledovr:0;,3l's1ciy institut 3hinnoy promy-
shlennosti Institute of the T-;,,r- Industry)
Card 3/3

jov/68-561-11-16/25
AUThORS: Gilyazetdine-v-1rw-P-,-y Evreinova 1,11.D. and ilrok1lorova L.I.
TITLE: -'- Ail InvestiLation. of High Boiling Fractions- of Coal Tar
using the Method of Uhromatographic Analysis (13sladovaniye
vyookokipyasLcftikti fral,,t,,,iy lmnennouCollnoy straoly metodom
khromatograficheskogo analiza)
PERIODICAL: Koks i Khimiya, 1958, Nr 11, pq 51-54 (USSOR)
ABSTRACT: An attempt to apply the chromatographic method for
the group chemical !ompmLtion of crude unpurified fractio.7~s cl
coal tar is described. The mothod adopted was as fo.21._,ows:
18g samples were passed throuilh two columns in sp-riCs
filled with silicagel; for desorptlion the following
solvents (200ml each) wore used in succession: xl-!~exane,
n-hexane + benzole; benzole, ethyl ether, alcohol-bonze-ae,
ethyl alcohol and ace-tone. Primary identification cf
de.sorbed hydrocarb6ns and organic compounds was based on
the colour of the,,.-~ solutions and chror.,iatogra--)hic curves
(Fig 1). This jtils later confirmod by coef-ficients of
refra U
,~tion, raelting temperatures, molecular weigh's
Card 1/3 (cryoscopy in benzene) and iodine nu.,.1bers of products freed
from solvents. Physico-chanical characteristlic3 of the

SOV/68-58-11-16/25
An Investigation of High Boiling Fractions of Coal Tar using the
0
Method of Chromatographic Analysis
identified grouis of coml)ounds for the investigated coal
tar fractions are given in Table 1, physico-chemical
characteristics of the coal tar fractions investigated in
Table 2, and the results of their chromatographic analysis
in Table 3. The following chemical groups were separated:
1) paraffinic, naphthenicoand olefinic hydrocarbons,
2) monocyclic aromatic hydrocarbons, 3) naplithonic-
aromatic hydrocarbons and Dhenylalkenes, L~~ dicyclic
j
aromatic hydrocarbons, 5) phenanthrene group,
6) anthracene group, 7) tricyclic hetero compounds,
8) pyridene bases and 9) phenols and other acid comDounds.
On the basis of the chromatographic analysis the number
of aromatic rings and the content of carbon in aromatic
structures for mean molecule of the sam')les investigated
were calculated, whereupon the raolecule weight was taken
Card 2/3 as the same for all groupS and equal to the molecular

.3-ov/68-58-11-i6/25
An Investigation of High Boiling Fractions of Coal Tar using the
Method of Chromatographic Analysis
weight of the starting sample. In this way some new
characteristics wero obtained for the individual coal
tar fractions, namely the dogree of cyclisation and
aromatisation.
There are 3 table,, 1 figuro and 9 references (7 Soviet,
2 English).
ASSOCIATION: NII Shinnoy Promyshlennosti (Scientific Research
Institute of the Tire Industry)
Card 3/3

S/138/60/00q/008/007/015
AUTHORS: Gilyazetdinov, L.P.; Zuyev, V.P.; Llvshl';2: F.B.; Saulina, V.V.
TITLE: The Production of LDw-Module F~jrnacp Carbcn Blacks From Liquid Shale
Raw Material
PERIODICAL: Kauchuk I Rezina, 1960, No. 8, PP. 32 - 35
TEXT: The effect of the chemical composition of the raw material on the
properties of the carbon black was studied on shale oil, shale softener and it3
mixtures with green oil. The experimental procedure for the production of furnace;
carbon black with an output capacity of 20kg/h was described in Refs. 1,2. The
content of oxygen and oxygen-containing compounds in the liquid shale raw ma-,erlal
is 10.9 and 77.8%, respectively, which is a significant difference from green oil..
It was established that with an equal specific surface the carbon bla,'k prcduced
from shale raw material has significantly lower oil numbers than carbon bla~~ks
from green oil. Rubber* containing carbon blacks derived from a shale softener
and Its mixtures with green oil are close to robbers with gaseous channel carbon
black in their physico-mechanical properties. The carbon blacks -from shale raw
material produce rubbers with low inodulao and high relatIve elongations. Tests
were carried out on semi-active and active carbon blacks and it. was noted that fhe
Card 1/ 2

S/138/60/000/0(,'8/007/015
A051/AO29
The Production of Lower-Module Furnace Carbon Blacks From Liquid Shale Raw Material
vulcanizates of the standard mixtures based on (.KG(SKB ')'. CVC-_10AN (SKS-30AM)
containing 8hale carbon black had low modulac at high -Yalliez~ of 'he tena,11",Y IlTit,
and the specific elongation. With an increase of the shale softener tn the 1,11--'a1
raw material, the tensile strength ohanges within the limits of 220 - 2.5'1
whereas in moVae with 300% t-he elongation and npeoifi..~ elongations are equa.1
130 - 56 kg/cm and 47o - 667%, respectiyely. The 1c-4 stxu.-It~rallzation of t,ht
carbon blacks produced from shale raw materiall and the low modulais :f the vulz~anl-
zates using these carbon blacks is explained by the speolfir effecl.r. of the f:,Yyz,~n,
organically bound with a raw material molecile on the frrmat,ion prcl~-e_z~; -)f tl,.e
carbon black particles in a turbulent flame. The authors poln,~ oul. -chat merh-
anism has not been completely investigated. They strezs the -fact that the shftle
oil and the shale softener can be applied as raw material to -the prodilo',lon of
speoial low-module carbon blackz or ati a component par*. of raw waterial, wlil~t,
gives the carbon black a low struoturalization with a wide varlety of properries,
There are 4 tables and 7 Soviet references.
ASSOCIATION: Nauchno-issledovatellskiy institu-, zhinnoy promyshle-nnosi-J.
Research T-nstitute of' the Tire Industry)
Card 2/2

s/o68/6o/ooo/oio/ooi/ooi
9071/E435
AUTHORS: Gluzman, L.D:j. fAi,.LZazetdinov, L.P. and
iolchanov, B
TITLEt On the Utilization of High Boiling Coal Tar Fractions
for the Production of Carbon-Black
PERIODICALs Koks i khimiya, 196o, NO-10, PP-51-54
TEXT: The problem of production of an active carbon black from
raw materials derived from the coking by-products and the
development of technological and GOST standards for coal tar
raw materials for the production of carbon black were investigated.
Typical samples of coal-tar oils (creosote absorption oil; a
mixture of absorption and anthracene oili anthracenelfraction I;
anthracene fraction II; pitch distillate) from the Kadiyevsk and
Zaporozhsk Coking Works were taken for the investigation.
Physico-chemical characteristics of these oils and, for comparison,
of some petroleum oils are given in Table 1. Group-structural
analysis of the petroleum and coal tar oils was calculated by the
methods given in earlier works (Ref-3 and 4). The product of the
total number of benzene rings in the molecule and the content of
carbon in the aromatic structures, named "aromatization factor"
Card 1/4

s/o68/6o/ooo/olo/ool/ool
E071/E435
On the Utilization of High Boiling Coal Tar Fractions for the
Production of Carbon-Black
(A=KoCa) was conditionally taken as the main physico-chemical
characteristic of the raw mat-)rials. This index at Ca,