SCIENTIFIC ABSTRACT FR:HALA, S. TO:HAKEN, D.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000617800024-6
• Release Decision: RIF
• Original Classification: U
• Document Page Count: 99
• Document Creation Date: November 2, 2016
• Sequence Number: 24
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTR

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PROVED FOR RELEA~F__n~i~~i~ ~ -
G~aECtIOSS~(`VAKIA~^:ganic Chel;listry. Synthl~tic oriranic Cher:lstry. G-~?
C,bs Jour: Ref Zhur-Khir:~., No 21~, 1q5$, 1315E6.
11$.2vC. (fron methanol) whie:h (4.4 g; by shaking
with sodium (6 days in ether in a welded pipe) forr,:s
diadamant~�1 (IV), yield 1.9 grnn~s, r,~.p. ~~`'C.
(from benzene -methanol) . Upon heating 6.1 l~ris
of ITT with 7 ~;xams rf sodiun. in 2U0 ml of benzene
(4 hours at 20C~ ~ C . in autoclave) , phenyladarlantan
was 1"oz�r7ed (V), Yield l.7 grans, rn.p. $2 C. (from
benzene and raethanal), ~rhich upon hyrir~gc:natinn over
Ft (fron PtOa) in glacial e,ce~tic acid fo~-rned cyclo-
hc~xyl adanentan (VI } , yield 0 ,) arai;ls (f~�~m ~ .I+R
grams of V), m.p. 104.5` C. (f'~�orl rlFthano;li . Upon
shaking 4.15 grans of ITI and 20 grams ~ f C ; H,-~r
with sodium in ether (10 day.) , one c~bta:ined 0.8
grar:is of IV and 0 . ?_ grams of e thyl:'lcLzruln~~ari , b . p .
Card 2% 3
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Fa u1t a~' t~~~t~ma]. ~~r~.ence.~, ~-
versity _~? _
OTtG: Department of Ana7.ytical Chemistry, ~ Y
J~- E. Pur a Brno (Katedra ana].,yticke ctiemie, I'x'i~'odaveTeeoretical~andUlfiysical.{~
J . E. purkyne ; Department of Ttadiochem:~stry, Faculty � f x
Brno (Katedra te~oreticke a ~y5ikal.xri chernie,
Cllemistry~ Universi.t~y o.~ J � ~ � ~'k3'i1e
' tJ. Furkyne ~
r,adiochemicke oddele-ni, Prirodavedecka .fs~kul:t~a, tlna.vcrs~.ta J.
T~TI,t: Polarographilc determination n~ stab~.].ity cnngt~n}tts of campl.exAs n,~~`
SQ(~,CF: Chema.cke l;i.sty, no. ~, 1.96, 3f~5w3~~9
'T'OPIC TAGS: polaro~raphic s~nalya~.s, .stability constan#~, complex mal.eGU'l.e, mercury
compound, chemical kinetics., electrocheuu.st;ry
~-BSTRACT; Graduvenska akadenii~: ved (for Po~pisil) , /~~ Ltaninov~t zavody,
Plzen (f'or Ha1xa., Mar~elli, B~;lik ~ Vild, Ucningc~r, Drahy, Masek, Urbanek,
Juza, Kral and Dol.ezal) � 5 .. Prvni brnen;~ j.a s tro j irna, Zavody Klementa
Gottwalda (,for 13udi~1 and Islas) ., 6 ~, 5tzi tnz v;,~ztcwnny
tts~AV tepolrie te'~i?z1icky (for Jerie, Kacer and, Skarecky) , 'I. Clen
korespondent Ceskaslavenska alcadelnie ved (for Jerio and Juza) .
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2/009/61/000/007/003/004
E 112/E 135

e praduct~.on of synthetic rubber.
There are ~. figure (diagram of Gille~ipie appar,~tus) , 2 tables
(results of analyses) and 9 references : 6 ,Cze+~h, 2 English and
1 French. The English language references re:~d as follows; ,
Ftef. 2: D.T.C. Gillespie, Ind. Eng. Chem. A.E. , 123, 5?5 (1946) .
T-~ef.8: L.H. Horsley, Azeotropic data. ~ti'ashingiton, 1954, No.?837.
ASSOCIATION: Ustav fyzikalni chemie Ceskoslove~zske akademie veci,
Pra h s -.~
( Institute of Physic~hl Chemistr}~, Czechoslovak AS,
Fra gnu e )
l~ontribution to the purification and analysis of isoprene. II. '
for the study of the economics of industrial isoprene recovery for
th
SU:BAIITTED: November l4, 1960
Card 5/6
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z/oo9/161/000/007/003/004
E112/E.135
to t:he purification and analysis of isoprene IT.~
Contrlbut~.on x
a13 x~ ~6)
y.l = xl "a
1+a13 3+a23x3
al3 ~x2 /x.3) ~ (7)
y2 xl + a x2 .~_
1+a13x3 23x3
(8)
y3 ~ ~, ~:, y ~ 4_, y2
that binary or ternary
7`he autho~~s yon~c.lude from Eqs ~ (1) ~;o (3) lbutene_1
sty:m isoprene o 2~methy
P~zeo~t~ropes are absent. from the sy
-meth lbute;ne~-2~~ although this is in d~s~uxellesnt63~t5~it(1949)
sknd 2 y pnn� Sae.., Se:i~. Hr
~Einding of M~ L4:cat (Raf a ?
'.Che yali.dity of the findings of the ~esultslowhichuwillsbeautilized
.confirmed by pr:i~t:i.c~r~.~, .in
IuIU.~. ~.LCUt11~)oxlel]'~ -~y;; tc~ttl,~
conclusio~z, i-t is stated that tY.u, proposed expressions
can be u;~e(i st3.tisfac~arily for e,~:pr(:;ssill~ Lhf. lrlutual
depelldenc;e of the ec~uilibriuln eoul~~ositions of phases
in sys~tenls W1~t~1 any number o:f col~~ponent;~ allci any deY;ree
of approximation, Obv:iously,, tllt~ hillier th~a required
accuracy tYle 1~~r~(~.r will be -tYle z~urabcr of cor~stal~ts of
the used expressions (serie;a) . TYIe practical iznportarl.ce
of the ~lel.'e ~;ivez~. expression is that it reduces the
number of ~~-~'~ ~,~ .m;=;i1ts ~Y~h:ich ~~.re required for character-
1%~iI1F, f.~.i.';, ,. '' � ' , ~IiO,~'v' Uf th� i;0.ilstt~IltS~ ~'lIlil lIl
2-ir~cle~~ : , .. ;~._L ;,:~~~ ~;onst,arlts, can be derived
from ?~i.t~. - 1~. ~,:,_ t~;sitl.el.,zblc~ advantage of the
prc,'p~~.~e-i _ !,~ ~~t, :i c~~n al._;o be ~:tpplied for
y >,~ ~~ ~ ~, , ~~ are, real .
5 stf:..il,~ s .i! ~ .c::~i1 ~ C.
Them: ,+_~'~~ ', ,~,' s,oi',~renco.c X111 of ~�Jhicl'~ are
A~3~~OCTATICN : I~:u f- ~ ' -~ r,~ ie , V,y~.~oY~~a s :~o is chelllicl~o-
ter.hl~.a:i~f, '_.~ , t. - . { ~.~,:>li,~.
str~~~~~aci ;,v -;1 ~,0 1~t~ ~_,,1i~t~~ble
~.- extended ~;;a ~ ~~~~~ ,
the cxpre s~ ion is , , , ., ~ uili urium
for dete~~'minir_~ the mutual ~~~ " _ . it}Z anz, number
COill'~C~s1~~ io.?1S Of 1?h