SCIENTIFIC ABSTRACT FR:HAJOS, E. TO:HAJNAL, T.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000617800027-6
• Release Decision: RIF
• Original Classification: U
• Document Page Count: 99
• Document Creation Date: November 2, 2016
• Sequence Number: 27
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTR

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APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000617800027-6

APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000617800027-6

APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000617800027-6

APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000617800027-6

APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000617800027-6

APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000617800027-6

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APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000617800027-6

l,(AJO Endre, ,~r� ; LEL~K, Imre, dr.
Osseous metastases in utArine cancer. Ma~�v. rad ol. 7 no.l:
51-54 Jan 55.
1. A Budapeati Orvostudomanyi Fgyete~~n Hont~enklinika~anak
kozl9menye (Igazgatn~ Ratkoczy, Nando dr. egyet, tanar).
(UTERUS, neoplasms,
metac~tases to bones.)
(BONES, neoplasms,
metastases from uterus.)
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APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000617800027-6

APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000617800027-6

APPROVED FOR RELEASE: 06/23/'1'1: CIA-RDP86-005'1380006'17800027-6
C U ~ ~C j ~/ ~. iJ ~.. ~ ~ ` ~./ - 1 1 1 U 1 J iJ l i 1. l I J .+. ~ a... as v .. .. u ......� .. ~
Csrd ~/~I
.~ `%
/ ~;'
HUNGARY / Or~aY-~c Chemi~tr~~,--�~-Natur~a-~ ~Ot~~~~~1nas unu u�-a
Abs Jour: Ref Zhur~-P~l1im~.y~, ido ~,, 159, 2~(~2~~
Avstrect: (t~:~:il~llE~n;~~.aet;;~~;lo;;y)-1-~u1�oi~~xr~~,~t~e, ~,raeld ~i?~,
rn~~ 2U5-2(~G , the reactio~y wit~l Iz gives ery-
thr�o-1-(p-nitro hei`!yl}-2-acetarnido--3-(trl-
phenylmethylo::y~-l-~ro,aanol, yield 90 ~, mp
2U3~; the fo1].owin~ products have been obtained
from, the latter.. (a) refluxin~; for 2 hr�s with
5~ HC1 dives eryti~ro-l-(Y~-nitroprlenyl)-2-am~.~~o-
1,"?-propat~edlol, yieJ.d 5~3.5~; (b) i:,reatment
witi~ i0C1~ followed by hydrolysis ;~f the o,.azol~~
formed gi~~es threo-~--(P-nitro,~'rieny:l)-~--arnzr~o-1;3-
pro~;ane iol, yield 65p. F'or Comrnunicat~.on V see
RZhKhim, 1,'a~, 15~~+5� -- L� ~~hal;hn~~vslcly
Card ~I/~
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PPROVE~
IiUNG~1RY / Organic Chei7~i~stry--Nai:,~~~ral comho~inrls and G--3
Abs Jour : Ref 'ui~ur-ki~irni~~a; No v, 1~5;, 27~~2~
Abstract : (L. P�i. Long and H � D . Troutma~r:, J Ames Cher
Soc, "Tl, 2~~ i ~ (19'9) in additio:~ to thx~eo-
III -and er�yrhro-l-~p-r.itrov;ienyl)-2-acetamide-
1,3-~r�o~:atzed:~ol (1V), gives 2,~1-dimei;hyl-~-
(~-nitrophenyl)-o.tazole (V)� The z~ollowing
reac t;iar~ chc-.Ic~ is ,~ro;~osed . :t(afl �-~ 1-(p-nit's :~;~h-�
enyl) -?_ -ac e tar,,i c3o-2 -pro1~en~~~ -1-one Vr) (1~'~ -
ar�r�angernent) --~1-( -r.itr~ophenyl)-2-acetar~ido-
1-gr�opanone (r~educ~ion) -'~1-(n-ritr'Gphenyll-?-
acetami.do t sic) -1-hydro~:ypro ane (c:yc lizacion) ~
V. The above reaction sche~i;e is confirmed by
tilE~ synthesis of V from V:~ (see also t~ZhT~l.a,
�,:.
~.?~7, 63651)� The mother liquor remaining a~uei
tl,e ,7enar�ation of ZSI and IV (froi~i 200 gms S)
~~~3 i'wa;.~o~~~�at,cc3 t~~ Ali~~tr-e:~,~, t:h~~ ~ e;;ic!�c ~c r e-
Gard 2
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}ttJNG/11tY / ~)i~;frAi:ir~ (.;lic.ml,~ti~y- clr_+i;~~r�Fi L r.r~-+ip~rtr~~Jts ar;c) ~J-�.3
t~~,~;,:� syni;hetac ar,a?o~r~
~~,
Abs Jour : ~~e ~' Zilur�-i~h~rr.~:tya, i o ~~ , . - ,
A._ and Trollonltsch, J.
Author� Ha;~os,
I~1st Hun~al~~a�an Acadec,ry of ~.i~;nce
Title : I,~vesti~;a~cion' ~:i Ft'hae~h~~nsaD~~x,in l; 'theot~eei~c~v'in
~c;o1. VI. ~~de
[ -P~nndorf ] r~cductson of 1-.~-Nitr�oph~nyl-2-
Ace ~ar:~:~do-~ -Hydro;:y_1-Pr ~pa~rone
Orig Pub: Acta Chun Arad ~~~-1 Huns 16. rjo lI, 1l~1-166
(158) (in German w~! th :~~nglish and Russian s~?,~-
mar ies )
Abstract ~ Ti1e reduction of 1-(1~-r1 cro~liei~yl ] -2--ace'can-ldo-
3-hydro.~;~-1-,~xopanone (T) by the action of (::so-
C3H ~� )3!~l (II) by the nieerv~e�in (Ponndor~f ] n-ethod
Caxd 1/~I
~; >
~ ~- J
APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000617800027-6

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APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000617800027-6

PPROVE~, FOR REL
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Ref Zht~r-h:i~.~n, 19~?, '~7b1;.~) }:TI was obtainer:.
[HC, yl.eld ~';;~, m�p. 17~-1~0~ i;c~ecoi~~osit~on;
.from alcohol-ether )~ , and f roe: Ls-`.rT, V?3: �,~'3
o}~t~.ined, with ~ie?.d of y~~~, T~,~p. 3.~.~~1.~~.~o
{aecompos~.tlc~r.}, I~jn t35� (~ '., l~-o:~ane);
T-~C, yie:lc3 ~9 0, m�n. ].7~~.--~.?5`~ t ;~'c~mpesit~:~n;
'".rom al~'oro.-.-~dt~lier), ~~~P -18`'` (c ~_'; z n. ~ic~.~
0. ~~ g. of VI:C in :- 0 ml. of ab,aclu~f;P tetra- I
i~yc~rofua~an i~ rr~ixc~~1 1'or ~'c~ur iic~urs at abr~ut ,
Or' wl.i~l~ a.3.~ p>� o!' F~;u~;~carou.~ T~~.1' ur~d n.'`~~ ~r,
o~' 95~ NaBH4, left s itancl ~.n~ ~'ox~ ~.}you i, 1.~' hour:,
APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000617800027-6

PPROVED OR.RELEASE~:~QfJ23/11: CIA-RDP86-00513
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~.~~:~ i,r~ar ~ T,,s-~: is heatad foie r~ra hcat~r !a:ii;h .~ rel. of ~ ny
cony d. HC.1_ (a~aoui~ ],UQ�) , anct L~-y I i:~ sepc.t~~. tad out
1a'iY,l~ th{:~ acatat;e a.~ :;oda.luu, w~F~.h yi.e;l.d of 56;n,
m.p. ~0~-.20i~o (de;omposluien), [,~~J �38� (c ~.; ,
1 n. HCl?. .HCI gas (-~lo�, one hour) is passed
through ~-~ solution of 1.2lt. g. ~~f r s�.x ix~i iQ mi
of absol~Ite ~.~coho:l., saturated with HC1 f ar~d c
L -V is separated out, with JriE~ad of 83~, m.p.
:1~!}.-x.25� (1'rc~u w~.tc~r ~, [:x~ D -r~ ~b (c 1; ~.icohol)o
Ana~,ogously, from 0-a~ath~l-thrEjo-~-phen~'lsarine;
r , :: x/1.1. c
I
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PPROVED FOR RELEASE: 06/23/1_
c, ~iuZtx~;~ G
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~~~;3~,r~~,,~ 235r~36� (uecompasi~yon), ~~~~ +8� ~r 1; ~Cla~
contd. CH3~H); from tho mother I:ir~uox^, tha ti3alt o1
17g wI is sc:rsra~ced out, with yj.~1c} a~' 7b~, ri.p.
1zbw127� (c~ecompasit:~on; ~['rom ague ~u~ CI~I 4H) ,
~
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(c 1; ~0`N
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FJaO}i at about 2C~o, she sa?.t a:^e tr:~nsfa;~7~c?d, ;

� � ~ ~.n:to L I, with ;~ ie~.d of 81}~`~
re spect3. Je.Ly s- ~a~
~
�
(clacom~osition}, ~�G~IJ+~.3
!a %; '
rr,.n. 191--1c}2
~ r is
U.1 n. ~taOH) anti D~�~ T, m. P . 1 !~)~-191 (dc,: om}~o-
sit:I.on), ~~`~n ~~.3� (c 2; a.l n. ZYaoI~). 1c:. az' '�
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PPROVEQ FOR RELEASE: 06 - - -

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1 ~.~ ~~~ r~~.:: ;, of X,i (8 hours with :=' n . ?iCl a t ~bo~at 1.00�~ }
VI is ob~ainod, ~�3.tki yiel.cl Gf ~~~, m.p. 134-
18~� (decompoa:l!:,~on~. A :~Ulut ic~n of ~~~3$ ox' ,
vx in I..9 m1.. 01' 1 n. IvaOx ys a,;:it~.tc~ci for 7.5
minutes at ~bolii; 0� with t~.38 mle of (C"r13C0j20;s
b~ ac~.di.~'~.cat3.on wit~i I~C7., i is precipitated, j
wif;xl iel~i of f~6. ~~. 8.1.x.8 r;.
y of T ~.n~? 1?.~. ~;.
f 01' anhydrous IV are dissolved 3r: alb ml. o.f'

boill.ng GIi30H; aftor chi1~ in6 ,
, urucine salt of ,
Ls-~I is precipitated, with y'f eld of 87.5, m.p

i
G - 96 -_
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PPROVED FOR RELEASE: 06/23/11:

U ~t.~11ti~~J

1h. ~. ~' ,~r
i ~ ~~E~ ~:::~.~.� ~ F'':ya 'w ~, is"~, :sta. 1~51~5

C;x~l-; 1~~, j
~ ~?~~~tr~ ~. ; :into 300 r~. of ice, axic~ 7~ g. o~ NaHCG~ arv
1g, _
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'cunt~d. i~ off
11..33 F~.� , ~.~.
i~dded, ~itY~ y~ia~.~1 at
1~2� (From ~lcoho].) . ,~r~1o~;oug1;; , by n~.trat +an
of ~, ?'~I is o'ntained, Frith ~ricld cf 33.5, m.p~
0
G
~
(f~�om f~q~~~ous a1^c~hol.) . ~ of V ara
121.-? 2~
i.9 m7.. of 1 n. N~~OH a~:~e ha:zt',ed I'c~r 1K minutes
~~t ~i~nut 100� anc~ by f~cidiz".~.cauiun kith con- ~
centrated HC1, I is p.rec ip:~ toted, with yield ,
of 8?.r~, m.p. 209-21~ao (ropracipltation from

I
i 10~ N~~-~CO~ with 1 r.. IiCI) , Dy sananii'icatior~
F
APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000617800027-6

PPROVED FOR RELEASE: 06/23/11:

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t, ~;;~t,r'a::~t, ; a~,i~J.s. 20 g. of hy~~r. ochloi~3c1~; (~iC ~ o.f VTT~~,
cont ~ c'~. 5a r~r1. of Cif C~ai~ ~tnc~ 3a m~.. ~f CH~CQC1 are
hc~.t;c~c~ ~oz, onf; hour r.~t ~~C~n, w:I.rl~ 'lu;.~ yi.a~ ci a1'
IiC; of ~~, m.p. :l.bl~--1'j0� (c3c~cortrosi~.or.). ~0 g.
of }~G o1' y"ITT are i.~v~le~i for one t1c~ux~ with ?cJ~7
znl. of (CII~Ct?)~,a c~..i~l ~atlr~~d lrxto ;ra~;er, w~.ti~
a r. ~
~ 173-171. (x om
y~.e1d of ~~.C~.�. 3 g� of ~., m.p.
' e~.coholl. 1.2 �~. of }iC of IX are ad~ec': to 1.~8
} :n,.Q Uof Mor~oa:~trated H1~'fl3 (far 15 m~nutes,
_1~ ), r,ii~.ed far 30 minutes at -~10 y p~~ured
Y,,- ~ t~./11
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PPROVE~ FOR RELEASE: 06/23/11: CJA-R~P8~-
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tr, I. Bq an ana:Lo~ous me th.r~d, ~ of 0-meti~,~'I- i
threo-- ~-p:x�rglsPx~~ne (X1.I) , throl~~h 0-metl~;,Yl f
dE,riv'ativE}s of Z and ~rTI (XI~T ax.d X~C:V), i;~ f
t;ransi ormAd into throc~~l-P~-r~3.trnphen~l-l-MCA--
thaxy--2-aminopro~anol"3 (fir) ~~nce the con~'i-
~uratlons o1' L. -trITI end off' L -(---)-i;hreon~.r:e
are ~.dent~~ea1 ~Voglar, h. , He~v. ch~.ni. acta, 4
1r~0, 33, 21.~.Z), tha t,ransi'orm,at~.ans d.escribe~~
present ~ new conf'irr~r>.tion ax' the s;;ez~eoche-
rr;icA1. bo.iti be tureen I~~ anci the na~tlaral. ~nino ,
i
3/11
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PPROVED, ~O,~~RELEAS~:~g6/23/11: CIA-RDP
- I

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~ ~. 15 ~r~,^^. ~ and ~ of X;s-VT (~I:i) . S i:; :,yn~hesi~:ed from
ct~ntld. ~~~ of thrco-�iMphunylscrinc (VI?.i} b~ t~cetyla-~ r
t:~on t;o 0�ac ~ t;~~. c' ~~~~ ~.~P~~ t ivc (IBC) , k:~.cb a.f tar
r~I.tra~.-.ion :i~ re~~rran~;Qd in an a1~cal.ino med~.tuu
in V :end i~ theia axia~.ued t;o ~. ,kt,ather mo-
i,2~.od c>f synt~ ha s iz in.g ~: c on:s i s t a in file tran::s- (1
i'orzn~~t3.on of. VI]:I inti~ O,N--discct~,yl. deriva.}ive y
~X), n~.tz~31~:~an cif X tc- ~ of O,Iti-d:inccityl~ i
'�11rco--~ -p-n1.fi.rop~~E~nylE~arin~- (XI ), sapGnif is ~- I
pion of the lattor to VT and acety~.ot;ion o.f Vr ~
~
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~~u~t 1'Y
~
~~-� ,,ry
u ~ : Iiinr C~tY " 1
:organic G'hhMi:~try. Idat;oral gubatarces anc~
.
, 'I71o3.r 5y'nthot~.c Analn~;n ~.,r ;
i~5
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\~J~,f�G1 J.l tip '
iox~s Concerning Chloramphon~icol. V.
: lavesti~at
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l~:[1 ~'['1.C't~C~-4"`~"~I~~.'~x`t?j.)r1i3t1~1.$t'?'iI1E3
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E lari~; ~~~ t~. ., ~ i
~ A,r to ch3.m. t;c sd . ~c:te~.~t. hunK. , 1.95 ~ ~.�,

~.~~7t}f sodium acctttit~: ~wl~icri V is p.r~:l~ared 1'rorrt IV and
neat isolated}, gave Ds-(-)-lp-iiitrophenyl-2-acetatnido-
-3-hydroxypropanone-1 (Vx) (1.79 tams of QI from 3
~.�aras of IV), m. p. 14)-151�C., ~]D -~.8�(� ~; alcohol).
This compound is ec.sily .racem:i.ed, even at ?_0�C., by the
action of sodium acetate in acetic acid, and thus, from
1.62 ~Yrams of VI, 1.5 grtu~s o.f throe-l-p-nitr~~phi:nyl-2-
-accta~~.ido-3-diliydroxypronaiie (VII) was prept.red~ ~a. p.
14f3-149�C. One grad of V7 iu pyr.lciisic gave G.~ ~~'ax~
of VxI, m. p. 167-1G~�C. (ilecot:ipos~s) .
tmen 4.7 Baas of VI wtss reduced (ticcording to tiie
Card 1E/`z
~~
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HUNW~.RY/Organic Chemistry ~ Natural Compounds s,ncl Their G:
.>yntheitc Ant-:1�gs.
Abs Jour Fief Lllur - Khirn:iyt+., No lei, 195f3, 5411 j
..hyrlroxy-2-t~tuido-3-.acetohydroh-yproptinc (III ), rn. p.
:1.01+-1i)~�C., L `~~1'la -'(C'(c ,~, jlY~, tillc~~~lol). I11.1C'.i' i.lli.>
1?roduct was heatod oil a water bath, a melting point cif
:1.32-134oC. was obtained.
~nc~ oxiiltttioll oi' j~.7 E;rnant+ oi' IIT. w.Fth M~:1 C.r,,O, ~�~ a~ `~`_~ kxeld ~ q~l` slaps; Its d3a>or-
p ie ~ ryryy ('( a
t w~i~' ~t ~' '~F ~{ ~ #~t1 di ~-~ ~~ ~QAI iF4~i ~t~'t` r ! ..
g3~~ ~;~~~ ~~ ~~ ~~F, N t : ~,~ aft ; ~; ~8~ !l ;frp tt t~to:�ligbt~ pCtr,
~~ ~ r~ ~J~ ~ ~ ~ ~, r ,~ ~'' ' ~ ~~ ~sa~ ; ~`hC'~LVaioltia~ farm is cca ~arts~ into tl~~ t~f~laer~me cin~; '
;~r~ i~~~ ~~ t;,+ ~+~ ., ~ t~tur'::t~Y _ a~~tt~u wat+.t fiath,.'~oih�tunn~;ca ~ tic, _
J:t.. ,. ~~ :~(1-~W~ ~~3.} ~ ~ ~ ' ~~dl~ ~'.b~ ~z~~t~ , ,~ yrith I1f J~I~CO. ivea n�~-1~ ~ .. ~~` ,
r~ y R y~ P ~'`
~,`~~.~~'`~ f~~r ~'~ t ~'~ ~ ~~-~~~E~C~?~~e~tt~ 7t3%b~ p~~~I~1't~ri~~0~# ia,t~e ~, " ,' `
3 ~'`3 = ~ x, ~ ~~- ' ~ , W �:At is?ta' Ica~cmlz+~-:I1~ weir .upaue~ess{u1. .. ~~
~~, s [tt~~~ ~ � , ~ ~ rt~ .ky jZb ~ bl~:AcQ ~Aat~~pa cfl~ ~pltt~ a!~{at~u_l~(~~py~ ~ ?a .,
~~f rtt~~t')( f~[d ~~a 4~`~ ~ ti97}ft~ s d. ~.~~~~~~~~ iii" ~~~ 1~, lAtl'ti T~F.t,i.Y"1 ~$ i~"~`t _4~ '{
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t1Ei tlh~h ~ ' ~i~'~ ~~f ~~ ` r ' ~ e ~ ` fl ` t ~~ ~ ~.x~' ~"~sj~~ r"a ~ z a~1V,fl~ ~+tt~ththa0~-~t~~erl~ptttt-~ 2M~zitai by tp~.t'hpkstion r~it3~ ~i~f r,rd
flit zvn,~ ntErnteci,. deuc~tylatecit and dctttct�~
X; l~'rotlt ttto r~rsaita It i~ edident that ~rztrtar;ut
t~uyi~-mC#haxv-~-brotarpropiarr?c acld :(yfilV' j ~ r.i
tii~ster~aist+tttoxta atititta dc~~1v+, aitho.tgh ~l nt=. >~; ,~
-iy #tltve tits same ~tfigurnt{on. It !a sgggeated in a previous x~per and in this
article: idicate that such effects should be taken into consideration, The
resuiLs also suggest tha~:, so;~e trace elements play a role in the effect.
Tn these e:~.peri~enis the effect of g-radiation was dealt with but it is likely
t'rat conta:~:in.~nts ~:mittinr a-rays may also have be~:n involved. The problem
can not br coi:sicl