SCIENTIFIC ABSTRACT ISACHENKOV, Y. - ISAGULYESIA, V.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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WTI! -1111~~11 ------ ISACHENK07,Y-F. I., PIKWOVNIKOV, R. V. Deformations (Mechanics) "'Effect of the speed of deformation on the process of stam-ping parts from steel sheet.', Vest. mash. 32 no. 5, 1952. 9. 'Monthly List of Russian Accessions. Library of Congress, October 19536 Unclassified. 2 ISAGINNKOV~ Yeygeniy jvenoyt,,U, ksncl.tekhn.nauk; SVMWV. H.I.j kand.tekhn. --04-WW", -r 64 i'j hi- 2'4'f &NOVSKlY, V.P., dots&, kand.tekhn*rAUk' reda~t*or; KAPT IISKIY, Ye.F., redaktor izd-ve; SOKOLOVA, L.T., teldin.red. Ellew extrusion methods] Novye sposoby shtampovki-vytiazhki. Pod obshchei red. V.P.Romnovskogo. Moskva, Gos.nsuchno-tekbn.izd-'wo mehinostrolt.lit-rY. 1955. 50 P. (Bibliotechts shtampovshchits, no.4) (Xxtrusion process) (MIRA 11:2) AUiHOR: solozonov, M. SOV/24-58-4-36/39 TITIZ: Application of Technological IA.,briicants and Special Coatings During Shaping of Metals by Applying Pressure (Primeneni,ye tekhnologicheskikh smazok i s etsiallnvkh pokrytiy pri obrabotke metallov davleniyeZ Conference at tne Institute for Mechanical Engineering of the Ac.Sc. USSR (Soveshchaniye v Institute mashino- vedeniya Akademii nauk SSSR) PERIODICAL: Izvestiya Akademii Kauk SSSR, Otdeleniye Tekhnicheskikh Nauk, 1958, Nr 4, P 153 (USSR) ABSTRACT: The conference was held in December, 195?. The following papers were read: "General Relations and the Mechanism of Operation of Lubricants During Shaping of Metals by Applying Pressure" by V.I. Likhtman, S.Ya. Veyler (Institut fizicheskoy khimii AN SSSR - Institute of Physical Chemistry of the Ac.Se.USSR); "Applicat lon of Principles of the Hydrodynamic Theory to the Proce'ss of Cold Stamping" by Te.I. Isachenkov (NIAT); "New Stamping Ltibricants for Deep__a_n_UPirtre-al&i,1y for Very Deep Drawing of Components made of Sheet Steel" by M.A. Silltsova (Gorlkovskiy avtozavod - Gorlkiy Automobile Works); "Lubricants for Stamping Sheet of Steel and of Cardl/4 Various Alloysn by Yu.P. Davydov (VIAM); SOV/24-58-4-36/39 Ap~lication of Technological Lubricants and Special Coatings During Shaping of Metals by Applying Pressure Conference at the Institutefor Nechanicial Engineering of t .he Ac.Se.USSR 'New Lubricants for Wire Drawing" by A.G. Smirnova (TsNIICbNR1FBT); "In7estigation of Technological . Lubricants Applied for Hot Stamping of Metal Components* by S.A. Dovnar (Minskiy Politekhnicheskiy institut im. I.V. Stalina - Minsk Polytechnical Institute imeni - I.V. Stalin); "Investigation and Testing of Certain, Technological Lubricants and Methods of Applying these on the Dies of Pressos During Hot Stamping of Aluminium Alloysn by B.M. Shor (TaNIITfWh); "Lubricants Used.in Shaping of Metal by Pressure" by Ye-B. 7.huravskiy (Aviatsionnyy zavod - Aviation Works). The data given in the individual papers show the increasing use of liquid, paste and solid technological lubricants and special coatings in highly efficient-processes:of shaping metals by applying pressure in the production of complicated components from various heavy and light non-ferrous alloys. The undertakings of the chemical Card2/4 and the oil industries have so far not organised the SOV/24-58-4-36/39 Application of Technological Lubricants and Special Coatings During,Shaping of Metals by Applying Pressure Conference at the Institute for Mechanical Engineering of the Ac.Sc.USSR production of the appropriate lubricants and the instrument industry does not produce instruments for determining the main parameters of these lubricants. So far, investigations by individual institutes of the Ac.8e.USSR on technological lubricants have not been carried out on a sufficiently large scale and have not been adequately cc--ordinated. The same ~applies to other institutes. S. Ya. Veyler (Institut fizicheskoy khimii AN SSSR - Institute of Physical Chemistry of the Ac.Sc.SSSR)t reported on work in the field of lubricants for cold stamping. Since the result of this work is little known, it was proposed to devote to it a specially convened: extended semins at the Institute of Mechanical Engineering of the Ac.8c.USSR. Co-ordination was urged of the research work in the use of lubricants for shaping of metals by pressure and this Car d3/4 SOV/24-58-4-36/39 A~plfcation of Technological Lubricants and Special Coatings During Shaping of Metals by Applying Pressure Conference at the Institute for Mechanical Engineering of the Ac.Sc.USSR task should be undertaken by the Laboratoriya obrabotki metallov davleniyem Instituta mashinovedeniya AN SSSR (Laboratory for Shaping of Metals by Pressure of the Institute of Mechanical Engineering of the Ac.Sc.USSR). The importance was pointed out of putting onto the market instruments for determining the main parameters. of lubricants and also of automatic'equipment for coating dies with technological lubricants. It is necessary to work out standard specifications for technological . lubricants and also recipes and methods of analysisof such lubricants and to increase the manufacture by the industry of standard technological lubricants. At regular intervals, symposia should be published on technological lubricants and special coatings used in the shaping of metals by applying pressure. Card 4/4 25(1,5) PHASE I BOOK EXPLOITATION SOV/2294 Moscow. Dom nauchno-tekhnicheskoy propagandy Imeni FeE. Dzerzhinskogo Novoye v tekhnologil vysokoproizvoditellnoy listovoy shtampovki; sbornik trudov konferentsii (New JF~eatur'es In the Methods of High-productivity Sheet Metal Stampingj Collection of Confer- ence Transactions) Moscow, MashgIz. 1959* 228 p. 8,000 copies printed* Sponsoring Agency3 Obahohestvo po rapprostraneniyu politicheskikh i 'nauchnykh znan:Ly RSFSR9 Resp. Ed,: V,Te Meshcherin, Doctor of Technical Sciences, Professor; Eds*: V9D* Golovlev, Candidate of Technical Sciences, Docent, and Ye#Ne Lanskoy, Candidate of Technical Sciences, Docent; Ed, of Publishing Houses GoNo Sokolev; Teche Bd*i B*I* Model'; Managing Ed* for Literature on Heavy Machine Building (Mashgiz): S.'ra. Golovin, Engineer. PURPOSE: This collection of papers is intended for engineers and tedhnialans in sheet metal stampinge It may also be useful to card 1A New Features (Cont.~) . SOV/2294 students of vuzes and tekhnikumse COVERAGE: This collection deals with the design and features of some current problems in sheet metal stamping& Also discussed are processing methods still in the experimental stage. Several articles deal with the mechanization and automation of stamping processes and describe recently developed methods, such as explosion forming, the use of automatic rotary transfer lines, and press blocking with the use of radioactive is,ot 'opes. No personalities are mentioned* References follow several of the articles. TABLE OF CONTENTS: Preface 3 Meshcherin, V*To,[Doator of Technical Sciences, Professor, Stankoinstrumental"hyy institut, Moskva (Moscow Machine Tool and Instrument Institute]. Basic Manufacturing Problems of the Hear Future .5 ,. 1. IX -4i Card 2/9 New Features (Cont.) SOV/2294 The author discusses labor productivity, shapes of work- pieces, the materials used, stamping operations and techni- que, production lines, working speed, and the correct meaning of basic operational times Pikhtovnikov, R.V. [Doctor of Technical Sciences, Professor, Khar,kovskiy aviatsionnyy institut(Kharlkov Aircraft Institute)]. Use of an Explosive Wave for Drawing and Forming Medium and Large Parts in Small-scale Production 22 The author discusses experimental fabrication of shallow dish-type parts of an explosive wave caused by gunpowder, gasoline, or natural gas. Koshkin, L.N. [Candidate of Technical Sciences]. New Possitilities in the Development of Sheet Metal Stamping in Connection With the Use of Automatic Rotary Transfer Machines 31 Mechanical and hydraulic rotary transfer machines are described. The flexibility of these machines allows facility of control, inclusion of chemical and heat treat- ment in the process, and smooth transition into fully auto- niatic lines. Card 3/9 New Features (Cont.) SOV/2294 Freydlin, A.Ya- (Candidate of Technical Sciences, Gorlkovskiy avtozavad (Gor,kiy Motor Vehicle Plant)]. Problem of Increasing the Number of Strokes on Presses 2~9 The influence of the speed of deformation on properties of.metals is mentioned, and the effect of the working speed on the behavior of metals during cutting and forming operations is discussed. Information on the characteristics and design of different types of presses Is presented. _L~ ~~, (Candidate of Technical Sciences]. Bages-for Zelection of Lubricahts for High-productivity Sheet Metal Forming 67 The influence of friction forces on the course of the forming process is explained. Distribution of stresses and, its relation to lubrication is described. The use of hydrodynamic (wedge film] lubrication is discussed; formulas for forces and stresses in the drawing process are derived; and the effect of temperature increases on the viscosity of lubricants is treated. Card 4A New Features (Cont.) SOV/2294 Gorbunov, M.N. (Candidate of Technical ~5ciences, Docent, Aviatsionno-tekhnologicheskiy institut, Moskva~-(Novcow Aviation Technology Institute)]. $ignificance of Local Heating of Blanks In Ipereasing the Productivity of Sheet Metal Stamping Distribution of stresses and temperatures during local hea:ting in the deformed zone of tabular workpieces is analyzed. Formulasare presented. Solovtzov, S.S. (Engineer, Zavod imeni Sema3hkoMoBkva (Moscow Plant imani Semashko)). Significance of Tubular Blanks and Local Preheating in Reducing Main-hours in Forming Operations 106 -Advantages of using tubular blanks in making thin- walled shell-type parts by reducing and bulging operations are discussed. Local preheating for bulging is accomplished by heating the punch*, -Special features and the Effl-ciency of this method are also discussed. Mikhalenko, F.F., [Candidate of Technical Sciences, Docent, Card 5/9 New Features (Cont.) SOV/2294 Politekhnicheskiy institut, g. Gor,kiy (Gor'kiy Poly- technical Institute)). Special Features of Blanking With an Increased Numbt~r of Strokes 131 The author describes research done on this nrocess in the cold-stamping department'of the "Trud" plant and the laboratory of the Department of Machinery - and Metal Forming, GPI imeni A.A* Zhdanov. A.A. Samoylov, depart- ment head, and N.S. Gilevich, process engineer, took part in the investigations made at the "Trud" Plant, and K.V. Semenov, Candidate of Technical Sciences, parti- cipated in the work done at GPI. The article describes changes in punch and die dimensions and clearances in relation to changes in the number df-stroke's'per minute and-the number of parts cut out. dptimum clearances, nd.nimum resistances, bunching forces and energy consumpL fion at various working speeds are discussed. Card 6/9 New Features (Cont.) SOV/2294 Artes, A.E. [Engineer, Moscow Machine Tool and Instrument Institute]. Press Blocking With the Use of Radioactive Isotopes 148 The article presents information an the use of beta- radiation to stop presses in processes where two or 'more blanks are being fed, and on the principle of operation and the description of a beta-ray electronic relay- Suggestions for placing the emitter and receiver are given, and safety measures are discussed. Artem'yev, S.I. lEngineer, Goikiy Motor Vehicle Plant). New Features in the Automation of Sheet Motal Stamping at the GoAiy Motor Vehicle Plant 160 The article discusses devices for automatic removal of formed parts from the press, devices for automatic feed- ing of sheet metal into the die, and devices for complete automation of the forming process. Card 7/9 New Features (Cont4) SOV/2294 Nikblayev,-V.V., And-%'-V-* Sore-kin (Avtozavdd ivii6ni OW 'Vehl Likhacheva,:MoskvA '(M66~,~-,-:Ikotb*w *I-w-Plant imoni'Likha- chev Experience of 'the Motor Vehicle Plant imeni Likhachev ''with High-prodilict~iVity'~Progres4ive''Di6l: Sets. 169 Compound,, coinbinat:L6n:,,Ahd- progressive die~sets with rectilinear and eircuilar'f6edink-'m~otion,of'blanks, are described. Mechanization of feeding and removal of .stamped parts-an&-ickap:tArei discussed-.'* Filina, - I. S. Erkginee~-k, - Z a-vod "Krasnaya Zairya ",'Leningrad (1~~iugrad: PRed' Sunrise` Plant,) Transfer Machine f or Mixing Contact Springs 199 Arrangenient-and-6peration, of imiversal:transfei. machine:for making springs for-flat'relays iiAesctibed. Reductibnsin costs, time, tnd.-man-hours are iftown.- Card 8/9 PHASE I BOOK EXPWITATION sov/4961 kkademiya nank SSSR. Institut mashinovedeniya Tekhnologicheskiy s=zki dlya obrabotki metallov davleniyem (Industrial Lubri- cants Used in Pressworldng of Metals) Moscow, ftshgiz, 1960. 96 P. 5POOO copies printed. Sponsoring Agency: Institut duhinovedeniya Akadezii nauk SSSR. Ed.: A. V. Korolev, Candidate of Technical Sciences; Ed. of Pablishing House: G. N. Soboleva; Tech. Ed.: L. P. Gordeyeva; Managing Ed. for Literature on Heavy Machine Building: S. Ya. Golovin., Engineer. PURPOSE: This collection of articles is intended for scientific and technical pers6nrkl., production engineers.. and students in schools of higher technical education and teklinila COVM=e. The book contains articles analyzing the researchon industrial lubricants used in pressworking of metals conducted by various institutes and plant laboratories. It is stated that these lubricants improve the metal- forming process and increase the wear resistance of tools (dies), thereby Industrial imbricants Used (Cont.) SOV/4961 increasing the quantity and quality of production. Also included are papers discussed at an All-Union convention on industrial lubricants held under the auspices of the Komissiya po tekhnologii mashinostroyeniya Inscituta mashino- vedenlya. AN SWR (Commission for Machine -Building Processes of the Institute of Science of Machines, AS USSR). No personalities are mentioned. References accompany some articles and are all Soviet. TAME OF CONTEWS: _-jeoghtnkov, e. 1. Application of Principles of the Hydrodynamic Lubrication Theory to Stamping Processes 3 Korolevp A. V. On the Problem of Testing Industrial Lubricants Used in Cold Stamping of Sheet Steel 15 Davydor.. Yu. P. Friction and Lubrication in Stamping Sheet Steel and Alloys 24 S/137/6 1/000/tO b"PA43,: Translation from: Beferativnyy zhurnal, Metallurgiya,1961 No-1, P* 11,;#.1b155 AUTHOR: Isachenkov, Ye.I. ................... TTTIE: The Application of Principles of.the-Hydrodynamical Theoryof Lub- rication to Cold Press-Forming Processes PERIODICAL: V sb.: "Tekhnol. smazki dlya obrabotki metallov davleniyem,, Mos- cow, Mashgiz, 1960, pp. 3 14 TEXT: The author discusses factors influencing the meciianical*efteict -of lubricants, intensifiers and extensifiers of external friction Experiments AM described an Investigating the influence of viscosity on the lubricating effect of greases at high contact pressures. Increasing viscosity first reduces thaztress during extrusion and, after having attained optimum reduction, increases again the stress. Optimum viscosity of the lubricant decreases with a higher extrusion speed and depends on the pressure between the blank and the extrusion rib of the die. When evaluating the lubricant, thermostability must be taken into account Card 1/2 PHASE I BOOK EXPLOITATION SOV / 6161 Isachenkov, Yevgeniy Ivanovich Shtampovka detaley iz nerzhaveyushchey stali (Stamping of Stainless SteelIParts). Moscow, Mashgiz, 1962. 53 p. (Bibliotechka shtampovshchika, vyp. 9). Errata slip inserted. 9, 000 copies printed. Ed. (Title page): V. P. Romanovskiy, Candidate of Technical Sciences; Ed. - V. Ye. Nedorezov, Candidate of Technical Sciences; Ed. of Publishing House: G. N. Kurepina; Tech. Ed.: A. A. Bardina; Managing Ed. for Literature on Machine -Building Technology (Mashgiz): Leningrad Depart- ment, Mashgiz-, Ye. P. Naumov, Engineer. PURPOSE: This booklet is intended for engineering personnel of stamping shops and industrial planning institutes. COVERAGE: Technological fundamentals of stamping parts from stainless steel sheets are discussed, and various types of dies and special devices are described. No personalities are mentioned. Card 1/3 Stamping of Stainless Steel Parts There are-8.referenceil: 7 Soviet,, and I English. TABLE OF CONTENTS: Ch. 1. Basic Information on Stainless Steel 1. Classification and physico-mechanical properties of stainless steel 2. Specifications for stainless steels used for cold stamping Ch. H. Blanking of Stainless Steel Sheets Ch. III. Forming of Stainless Steel Parts 3. Bending with metal dies ' 4. Bending and forming with rubber die 5. Forming with metal dies 6. Forming of the sheet hlank with rubber, hydraulic, or gas punch and a rigid die Card 2/3 SOV/6161 3 3 8 11 13 16 16 27 Stamping of Stainless Steel Parts SO V / 6161 7. Forming from three-dimensional preforms with elastic, hydraulic, or gas punch 8. Forming with elastic or hydraulic die and a rigid punch with flange clamping Ch. IV. Prospects for improving the Process of Cold-St-amping Stainless Steel in Machine Building Bibliography AVAILABLE: Library of Congress SUBJECT: Metals and Metallurgy 37 46 51 55 DV/wb/mas Card 313 2-5-63 , PHASE I BOOK EXPLOITATION SOV/6300. Isachenkov, Ye. 1. Shtampovka rezinoy i zhidkost'yu (Rubber and Liquid~ Die Forming)- Moscvv, Mashgiz, 1962. 327 p. Errata slip inserted. 6200 copies printed. Reviewer: V. T. Meshcherin, Doctor of Technical Sciences, Professor Ed. of Publishing House: Yu. L. Markiz; Tech. Ed.: G. V. Smirnova; Managing Ed. for Literature on Hot-Working of Metals: S. Ya. Golovin. Candidate of Technical Sciences. PURPOSE: This book is intended for engineering personnel of machine-build- ing plants and scientific research institutes. It may also be useful to stu- dents at schools of higher technical education. COVERAGE: The book reviews the basic -principles and engineering prospects of rubber and liquid die forming processes, used in machine building fo r- M~ -a,i -las ng~par-is-,fro-m nefirsheet'.' t also e:~vlaihs the P Inciples of, sifyink sheet-parts and the various productions processes.~ No personali-; ties are mentioned. There are 64 references. 42 Soviet, 20 English, ana, German J -ig o d titboi m' -BlOVE38" F orniii C radiallly-o-corru. a im AS t ilbe and flie.rubbor Under t~eii s Ii., punch e c ondit.1 n P compr .;i*e u to'Ahe frictio n X bre es ,, ~c,~nm , approx Iihat ei, I! r . eaveiv, x;0S s c~) fthe tub e material.. irl o:zc 0 04 1 :tile, yi old* st iis~ malres~ th%6:,, pr o c esa particlila':~ly owjj~gl~to jt~s simpli-li Lnd -hljh~',~ lalitY of t, surfv,,-~e: % 1 6 ~inished,product odd q of~ work-ha'rdening b degree sur hae- aybr'-'Winiiii~-.xe uc 16W" r.46-~~,qacektedlby, t 6, thoAul;ia tpiA46h L -~vall thic ess nereazes x-ri increasing-`~t wall --tii!6kness -~I~idreasing-vxscqs. LtYl of ~:-Inereaslng ---speed,- v. process. --th'O i1Pr,,qijsttre: pereasp th s. ; onta,~t,~~:4,6tv pun ci h,6rj6:*- I -:anaT~'tho;- d T c n ricip k L 23054-66 EW,T(d)/E4T(m)/EWP(w)/..7NP(C)/EWP(V)/T/E',VP(i~)/t'iYP(k)/EWP(h)/E;IVP(I)~/ ACC NR: A?5028993 ETC(m)-6 ~jD/ItW/Dj - sOURCS CODE: UR/0182/65/000/009/000:t/qOO8 AUTHOR: IsacheBMx,,Aea.,j Mishunin, V.-~ A. ORG: none C TITLE: Prospects for intensifying the processes.of '014 prii~sing 191 SGUr,,CE-. Kuzuechno-shtampovachn ye 55 1.~8 ibizvodstvoi noo 9. 'C MIM cold'forging, .metal predsin Ig lubri tj extrusiba p~asti it terial can C YF =A re e rc deforma. tion metallurgic a a h ~ABSTMM Despite its great promise the cold-pressing (extr6ii0n)1* proceal S41:1 is employed on an ade4uate.'scale,inMachine building, Wixticularry, fabrica-! o4 parts from high-strength nonfWrrous and ferrous alloys~ Thii~problem can be resolved, by accomplishing the followXag'tasks- 1. i Davelopmen't'.of a' h~drodynami !Au~- Iricating-regime and the eltminationlof the considerable ener' ~, lqsaes~ due, to jil%ing. u 9 1 .1 1.- 'Th,e hydrodynamic theory of frictidnMakespossible a sufficiently complete.desdrLption of the basic. patterns of the effects accompanying various condition oficold f 0*8 as 4 !2. uniform propagation throughout the blank of the conditions~ 'of flowage arisiq in ithe surface,layer of the blank during foraing; this.is aecampllshe4~b~ compreigirig the blank so that the hydrostatic pressure in the zones of freie-floF~age.of the, lml.t_:~ erial.would be c. ensurate with the deformation resistance ot the viaterial of the Card -112 UDC::621.983.1 ISACi0NKOV, YE. K.; PIKHTOVNIKOV, R. V. Sheet Metal 'Work Effee't of the 8pped of deformation on the process of stamping parts from steel sheet, Vest. mash., 32, No. 5, 1952. 9. Monthly List of Russian Accessions, Library of Congress, October 1996. Unclassified. 2 ,"~-JgGLKI,y i..,,Qpza). ,.,Aj~ Using slide rules in computation lessons. Hat. v shkole ne.6:54-61 N~--D '58. (KM 11:12) (Slide rule) ISACHKIN, B.Ya. (Penza) Solving quadratic equations with the slide rule. Pat. v shkole no.3:61-63 Mr-Js '59. (NIRA 12:9) (Iquations, quadratic) (Slide rule) KOUTOROVICH, P.G.; KUPLUTOV, V.A. (Sverdlovsk); GUTMAN, A.Ya. (Moskva); DEYNEGA, A.V. (Kiyev); ISACHEIN, B.Ya. (Penza); IIETRDNINA, N.G. (Tambov); P0140MAREV, -SERYANOV, D.P. (Xormunl- Shevchenkovskly, Gherkaoskaya obl.);-KOLIEDV. A.1F. (Kalinin); SHM, Ya.A. (Moskva); IVANOV, M.I. (,Tula) Discussion of the now mathematics curricula. Vat. v sbkole noj: 4-20 N7-Je 159. (MIRA 12:9) (Mathematics) ISACRIM, B.Ya. (Penza) lessons on calculation with the aid of the slide rule In the 10th grade* 11at. v shkole no.5:35-41 5-0 159. (MPA 33:2) (Slide rtae) 3:SAC-HKIN,-B.Ya. (Penza); MALININ, V.V. (Loningrad)l BOGDANOV, I.M.1 SWOVSWAP F.V.,, obahchostyenMy metodint; ASMMV, K. (Baku) ties In grades 9 to 11 of eveniM *'aft 'roo =~smcahools of general education, Mat, v (stagg'sredr)"Le shkole no.3:57-59 MY-Je 163, (MM 16:7) 1. Inspektor po shkolam rabochey solodeshi Nalininskogo r1yons. MOskv7 (for Bogdanov). (yethematice-Study and teaching) BUSITA; V.T.; POP, 0.; VASIMSCU, I.; TOPGIU, Vl.; POPIAN, R.; CUCURUZ, L.; ALEXAMMOU, R.; ZAGSON, I.; SON, G.; GRAVGVSCHI, V.; ZIMMMI. L; FITARAU, A. Clinical study of levtoopirosis. Stud. cercet. inframicrob 101, IUL~W. 8 no.2:259-280 i957. 1. Comminicare presentata la Institutul do inframicrobiolokis, &I Aca4emiei R.P.IL in sedinta, din 5 marts 1956, (LVTOBPIRMIS pathol. & epidemiol. of.L. pomona. 1% canicols & Other, leptospiral infect. in Ruwania, case reports & rqvivw), TOSADNOV, P. P. Fishing Implements and Appliances Drop hamner with head for driving in seine stakes. Ryb. khoz., 28, No. 6p la""2. 9. lonthly List of Russian Accessions, Library of Congress, 950. Un'claissifted. 1, ISAD07, P. M. 2. USSR (6oo), 4. Iron - Analysis 76 Opxlitativo detection of iron in ores and minerals by menne of trituraticn. Ymch. biul Lon un. No. 30 1952. 9. Monthl List of Russian Accessions, Library of Congress, April 1953,.Lincl. SO V/118-58-1, 2-50/17 AUTHORS: Glotov, V.V., Lysenko, M.A., Parshina, Sokolova, N.A., Isads~~a _Z.A.9 Engineers TI"LEt The Economical Effectiveness of a Centralized Electric.Power Supply for Lumbering Sites (Ekonomidheskaya effektiv-aost-1 tsentralizovannogo elektrosnabzheniya na. lesozagotovsakh) PERIODICAL: Mekhanizatsiya trudoyemkikh i tyazhelykh rabotj 1958,, Nr 12, pp 29 - 35 (USSR) ABSTRACT: The article deals in detail with the calculation of the operational expenses at lumbering sites,,using electrio power instead of oil driven engines. The research leads to the conclusion that under definite conditions, the'electri- fication of the lumbering industry proves to be economically more efficient as compared with the.utilization of oil-fuel- led mechanisms. There are 7 tables, and 1 graph. Card 1/1 GULMOT. R.G.; U7XO, G.I.; ZOTOT, A.M.; Tu.A.; SRXrXM, A.Ta.; TSLWINUO M.P.; UWJMWO. I.L., red.; BAKMYAROW, A.. takhn.red. Dashkaut: concise reference back] Tasbkont; kratkil,sprayfichnit. lsd.2*o dop. 246*80, GosAnd-va lVabskskoll M, 1958. 1" p. (MW 131: (Tashkent-%Ittobooks) BOIADZIUWA, M.; MILEV, M.; ISM, Iv. Experience with the preparation of complexes in the form of dry extracts and tablets. 11. Naueb. tr. vissh. med. inst. Sofia 39 no.'.5: 133-138 '60. 1. Predstavena ot prof. T. Trandaftlov, rukovoditel na Natedrata p9: tokbnologiia na lekarstvenits foral i galenovi:preparati. (TABLETS) (PHARMACY) BOIADZHIEVA, M.; MILEV, M.; ISAEV, Iv. Experience with the prep"tion of complexes in the form of liquid extracts, dry concentrates and tablets. I. Nauch. tr. vissh. med. inst. Sofia 39 no,5:139-143 160, 1. Bredstavena ot prof. T. Trandafilov, rukovoditel na Katedrata po tokbnologiia na lakaretvenite formi i galenovi preparati. (HU'RKACY) (TABIETS) Iv.; BOIADZHIEVJI, M. Production of galenic and neo-galenic preparations and experience with the isolation of active substances from Leonurus cardiam, Nauch. tr. vissh. med. inst. Sofia 39 no.5:145-152 260. 1. Predetavena ot prof. T. Trandafilov, rukovoditel na Natedrata 06 tekhnolagiia na lekarstvanite formi i galenovi preparati. (PLANTS NEDICINIAL) ISAEV, Iv.; BOIADZHIEVA, M.; MILEV, M. Production of tablets of Leonurus cardiaca alone and in combination with nealeovasan, phanylurea and other drugs. Nauch. tr. viveh. mod. inst. Sofia 41 no.4:33-37 '62. 1. Pradstavena ot prof. d-r T. Trandafilov. ANTICONVULSARTS) (ANTiHrFERTENsivE:AGF.NTS) %PNOTICS AND SEDATIVES) (PLUITS, KEDICINAL) FASKOV, D.; ZHELIAZKOV, D.; ISAEV,_Iv.,- BOIADZHIEVA, M.; MILEV, M. Production and pharmacological analyain of a purified Digitalis ambigua eardfac preparation. Nauch. tr. viesh. mod. inst. Sofia 41 no.4:39-50 162. 1. Predstavens. ot prof. P. Nikolov. (DIGITALIS GLYCOSIDES) ISAEVA, M. First step toward inventiveness. Nauka i 'Uekh x mladezh 13 no.12:8-9 D 161. i I - I ISA13ALIY3VA, H.H, wa 6AA"~'~Ai i,., -m ftnicillin for treating progressive paralysis. Trudy Inst.kraev.pat. AN ZosakhoSSR 1:123-132 152. (MIRA 20:2) OUICILLU) (PARALYSIS) I . -U-07221n67 ArC-M-,-W?6026502 SOURCE CODE: YU/0002/66/000/004/0209/021ii, -'?e AUTHOR- Inagulianc, V. I. (Academician; Professor); Desukki, A. ORG: Moscow Institute for Oil and Gasoline Cheii-stry. Moscow (Moskovski institut za naftu i petrokiEMUT- TITLE: PolymerizatiAof certain unsaturated hydrocarbons in presence of cation exchange resins SOURCE: Kemija u industriji, no. 4, 1966, 209-213 TOPIC TAGS: ion exchange resin, hydrocarbon, unsaturated hydrocarbon, polymerization, catalytic polymerization, polyisobutylene I ABSTRACT: The article is a translation of a lecture given in September of 1965 which dealt with the polymerization of tertiary unsaturated hydrocarbons in presence of cation exchange KU-2 resins. The polymerization of Lsobytylenceliand isoamylene yields generally unsaturated dimers and trimers, whereas the polpnerizition of OL-methystyrene and its homologues yields mostly saturated dimers with some unsaturated trimers. ' Optimum conditions for polymerization are given, and it is shown that a-methylstyrene and its homologues show differing tendencies toward polymerization. The pol~meriza- tion of p,a-dimethylstyrene, p-ethyl-a-methylstyrene, and p-isopropyl-a-methylstyrene in presence of cation exchangers has been studied for the first time as was the Card 1/2 UDC: 661,715.3,095,264 L 07227-67 NR: AP6026502 copolymerization reaction of a-methylenstyrenelith isobutylene and isoamylenes. Compounds were identified by infrared and-ultraviolet rays. Orig. art. has: 7 tables and 2 figures. SUB CODE: 07/ SUBM-DATE: none /CQ!Grd 2 MI ~~m POFG. N.F. ;-- 1 JAG111,011,1. I. Using metal s!ipporls in ,io-f't grovsi. Ndu~h. KNIUI n0.143153- 162 164. (MIRA 18t./,) ' m YERSHOV, V.Z. (lErshov, V.Z.); ISAGULOVA, O.Z .. [14#iulava, O.Z.] Jurasi3ic sediments overlying the coal-bearing layer of the Lvov- Volyn' Carboniferous and "terials on their stage. Visnyk Llviv.un. Ser.geol no.l:';l-24 t62. (MM,16:-,7) 4vov-Volyn Basin--Geology, Stratigraphic) ISAGULOVA, Te.Z. Hystrichospheridia in Jurassic deposits of the Lvov-Volynt Coal Basin. -Dokl, AN.SSSR 148 no.5:1.156-n5a r 163. (KU~A 16:3) 1. LIvovskij gosudarstvonnyy universitet in. Ivana Franko. Predsta#leno akademikom V.N.Sukachevya (Lvov-Volynt BasM441sobotany) ISIIGUILOV~-'- Yfj.Z. Palynological characteristics of Middle Jurassic sediments in the southwestern margin of the Russian Platiorm and Carpathian piedmont fault. Vest. LIvov. un. Ser. geol. no.2: 36-40 164. 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At) 4141* W 'vita ( 'vNiurvis, stru IOIJ .. tj till lite etillistion 4 It I I vmlw~ WIPle) me verl little Jillefrilt Itoin M 111d 42 Inill, Isn't "SiAl - ill ACTrillivin with M. ir'lill =00 . . . , &0 tinvilliv. lite title ~S. elletr'let E, ,IV vrcv little 111 'rill- V44111r, .4 1. oblaillell litevi.-tistv t.-(~ I e I I., 11,1%-J~41-1 ".toy ."t its.. let rill fl.ont to .110 Ow 1.0110-4 it - 400 , 13 imi till the pult.il if lite trA.-mm,,. thm. Ili Ill; 0 Ad site WN'. 1 1-1 OW 1--411111101 11-1. 111 "611111 1.,2" 1) Irill.lint plit"tieitliv I'llimt fil .1 How ~V,frm Ifi,fv Ott, eqn.11j.. 0 0 .1141.1- - Pot 7 a file I.-I 1.4t- 1. 1, 1 1. .11 1 Ill 1 1 .1 1 00 0 Ir.4 f'oke it file in m1l. It. 0 00 th.- .1dit'l ... 11, ... I., ~ 1, - it., "i" I ... I It, 7 ' 4I.W. Alut till- lasitir %,Il.tr 111 1) - list i4 hKinil. At 4 , 11 . with 1;0 0 it .4. - (k. 'rite emnocte kinctit- "juati-an ,4t, see be written down tilt C.1ch It"le"t not the hassik of t1w getwirld "puttinis (it.. r,.i. 37, 2w) ; e.m., faw the aystent with - ' ..,mlict, f .104P.M I- 1!( 1. 1. JAIAll kill v. it i. ; - , I : . till 41,13 m 11 (.41 feett lisle .4 It. 7.1 I YN At lift, 411,40 Alto it A .1 tat it 01-1, ' _- . I I . . . .. - ' -, ~ -, " ~ ,_. ", , , _d_- - j -11 t I # a s 5 u a 41, to is X a it a It It 01 W f I 1k ; 111 1 114 Alm I 1 0 4 ill IN all 4 3 '111 9 *;W0 e 00000 0 00 0 0 0 0 0 0 00 00 0 0 0 0 0 0 0 00 0 . 0 M - ..:- - ~. ~ I - - I ci-, , ~-u ~ ~.L- A ~ , ~ . ~ . ;x% c--)j4~,L0 ISAGIILYAHTS~ G. V., KEYER, N. P., FLDTTCK. B. V. Ethanes Preparation of acetylene and ethane tagged by radiocarbon C 14. Dokl. AN SSSR 85F No. 5, 1952. Radioactive acetylene was prepd from barium carbide C.Tft C14. and Water. Radioactive etbane was prapd from the tagged acetylene by nesias of hydm- genation over a Ili catalyst at room t4mp. Submitted by Acad A. N. Frum 12 Jurt 52. 239TI3 9. Monthly List of Russian Accessions, Library of Congress, December 1114 Utclassifiedo IL8 - - 1-1-U! i TI Z- I, G . 'Vt. and 1ID7U;ON, B. V. Ethane Tagged 5b. ~o Obshch, Xhimii. "Preparatiop af'Ac~et,lene and "E 4th Izd-vp Ail 1% ---t., Vol 2, pp 1566-11,69, 1953 ,Veveloped a laboratory method for the preparation of acetylene tagged with CJ-4. Method consists of heating radioactive barium carbonate with magnesium to prodice radioactive barium carbide. The barium carbide then yields radioactive acetylene when treated wiht water, and the acetylene can be hydrogenated over a nickel catalyst to give radioactive ethane. (RZhKhim, No 22, 1954) Sum. No. 681, 7 Get 55 IS.~ GULU-ETIPS G. V. ; KEMR and KTITI~21MY, B. 11. Preparetion of Acetylene and Ethane Tagged with Rndio,':ictive Cvrbon C14-p Pac,e 1566, Sbornik st~-,,tey po obshchey khindi (Collection of Papers on General Chend-stry), Vol II, Moscow-Leningrad, 1953, paZes 1680-1686. Inst of Physical Chenistry, Acad Sci USSR ISAGULYANTS, G. V. --11- Aue, -53- USSR/Chemistry - Isotopes "The Preparation of Caproic Acid TaUed with Radioactive C14 In the Carboxyl Group,:" G.V. Isagulyants, Ye.,4- Pndreyev, and N.A. Ko-solapova DAN SSSR, Vol 91. No 5. PP 11*-1124 Using the Grignard reaction prepd caproic acid having C14 in the ca"oxyl group. Reacted amyl-N&bromide wit)i C1402 prepd from B&C140 3- Yield of caproic acid was 91% of theoretical. Presented 'by Acad A.N. Frumkin 13 Jun 53. ~266TS ISA6-ULYANTS, PHASE I BOOK EXPLOITATION .1181 Akademiya, nauk SSSR. Inbtitut fiziche6ko khimii Problemy kinetiki kkatalizaalt).Ix.- tzotopy v katalize-(Proble43 of Kinetics and Catalydis. I'd q.- isotopes in Catalysis) Nos'c'ols' lzd.;-vo AN SSSR, 195T.. ~442,P- 3,500 copies printed. Edse RoginskiyS'Z.., Ifinoigradovi,, O.M Keyer, N.P. and Yanovskiy, M.I., Corresponding Members, USSR Academy of Sciences; Ed. of Publishing House: Va.s.seroerg, V.E. PURPOSE% This book Is for specisAistsiinterested In the theoretical and_pzntctical problems of the a Ipplication of Isotopes in catalysis. COVERAGE: This collection of articles forms volume 9 of "The Problems of Kinetics and CatAlybis.*!- Most of the.:papers were reeented~at the f. p Conference on Isotopes.in Catalysis which took place in Moscow.. March 31 - April 5, 1956-. Scientists from the Academy of Sciences of Card 1/34 3. Problems of Kinetics and Catalysis (Cont.) 1181 of the USSR, the Ukrainian Academy of Sciences, institutes of' the chemical and petroleum industries, and several vuzes took nart. Scientists from the six people's republics China, 0DR, Poland, Czechoslovakia, Hungary and Rumania also participaied. Thia conference was the first of its sort not only in the Soviet Union, but internationally. Several articles which could not be included in the program of the conference are given iin the text. Each article has figures, tables, and a bibliography. TABLE OF CONTENTS: From the editor 3 Roginskiy, S.Z* Isotopes-in Catalysis 5 PART I. CATALYTIC REACTIONS OF HYDROGEN Voyevodakly, V.V.. Mechanism of the Homogeneous and Heterogeneous Homolytic Deuterium Rxchange Card 2/36 Problems of Kinetics and Catalysis (Cont.) 1181 Balandin, A.A., Neyman, M.B.., Bogdanova, 0 K.,,_jLaj;ulyants,, G.V., Shcheglovaj A.P., Popov, Ye, I. Tagged-at;m Study o-r-T"- Dehydrogenation of Butane - Butylene Mixtures Avdeyenko, M.A., Boreskov, G.K., Slinlko, M.G. Catalytic Activity of Metals in Relation to the Homomolecular Isotopic Exchange of Hydrogen Golovina, O.A. Rogirniiy, S.Z.,, .5akharov, M.M... Eydus,. Ya.T., v ains in the Dokukina ., Ye. S. Stu y of the Role of Plane Ch Synthesis of Hydrocarbons from CO and H2 Tverdovskiy, I.P., Tupitsyn, I.F. Study of the Nickel-Boride Catalyst 'Discussion: R#Xha-Burshteyn G.K. Bdiseskov Card 3/24 45 61 76 84 91 '.92 ~ t - F ;~ I - - 'r" ..4- ~ --- , - . IJAGUIIYAMI~;' U. V., G. "'T'A=", it. i.-.'- - -.1 .-. _. 1?~ z ItApplication of radio-carbon in investiCating the mechanism of consecutive reactions of butane-butylene-divinyl," a paper submitted at the International Conference on Pedioisotopes in Scientific research, Paris, 9-20 Sep 57. BALANDIN, A.A.; XBTMAH, H.B.; BOGDANOU. O.K.; ISAGULTARTS, G.V*_L'_.__ SHCOGLOVA. A.P.; POPOV, Te.l. Process of carbon dioxide formation-As obtalving divinyl from butane-butylens mixtures. lsv.AN SSSR.Otd.khIm.sauk.no.3:270-278 Nr '57. (MM 10:5) 1.1netitut organicheskoy khlmli im. N.D. ZellaskDgo Akadsidl-vaWc SSSR I Institut khtmicheskoy fisiki Akademll nauk SSSR- (Girbou dioxide) MUM) (ftlAyleno) A G, Z7 V/ BAIANDINO A.A.; NITW, H.B.; BOOMNOVA. 0.K.; A,P,; POPOTO Dehydrogenation of butane - butylens mIxtures Probl. kln. I kat. 9w45-60 157. 69hydrogenation) ISAGULYANTS. G.V.; SHCMLOVA,, usivg taMd atoms. (xm nol (Butane) laAG',ULW-i$o G.T. Distmesion. Probl. k1n. i kat. 9:215-216 157. (KIRIL 11:3) (Dehyftogenation) (Datane) (Ratylons) BAIANDINJ. A. A., XB B0GKj1_NOVAY 0. K., ISAGULYANTS. G. V., mynu, Yu. V-, and POPOV, Ye. (Inst. of Organic Chem. AS USSR.) "Investigation of the Mechrism of Successive Reactions Butane-Butylene-M-vlnyl by Using Radioactive Carbon C1 fl P. 52. isotopes and Radiation In Chmistry, Collection or -japers of 2nd All-Union Sci. Tech. Cour. on Use of Radioactive and Stable Isotopes find Radiation in National BconopW and.Scieuce., Moscow, lad-vo AN SM,190, 3iftp. Tble volume publiskied the reports of the Chadetry Sectlan of tbi 2nd jW Sci Tech Coof on Use of Radioactive and Stable Isotopes and Radlatlon in Science and the National ZcmcnW, sponsored by Aced Sci UBSR and Main Admin for Utilization of Atomic ikergy under Council of NInlisters UMM Hoscow 4-12 Apr 1957. / 5-,q 6 &~ 4 VAA.) -/:S- J~;, ~/, AUTHORS: Balandin, A. A., Bogdanova, 0. K., 62-1--J/29 Neyman, 1,1. B.) Popov, Ye. I. TITLE: The Application of Radioactive Carbon in the Comparison Between the Dehydrogenation Velocities of Butane and Butylene (Primenaniya radiouglaroda dlya sravneniya skorostay degidrogenizatsii butana i butilena). PERIODICAL: Izve~!tiya AN SSSR Weleniye Khimichealcikh N.auk, 1958, :Nr 1, pp~, 18-23 (USSR) ABSTRACT: The investigation (with the application of C14) was carried out by means of a special catalyst under conditions especi- ally favorable for the obtaining of divinyl. Since it,turned out that divinyl can be formed from butylene and that:butane cannot be transfo=ed into divinyl, it was.cancluded that the, reaction (d-ivinyl from butane) passes only through the-st agi' of the formation an~i dosorption of butylene. Therefo.re the desorption of butylene cannot be a final stage of the;entire reaction. The authors report on the carrying out of the 'in- vestiCation: The correlation between the dohydrogenition velocity of butane and butylene in divinyl at the chr-onium catalyst was found by means of computLtiona,-corrasponding Card 1/2 to the experimental data obtained already before. It was The Apl,lication of Radioactive Carbon in th(., ConpiLrisor- 62-1-4/29 Between the Dehydroganation Velocities of Butane and Butylene shown that the ratio of the velocities of the dehydroaen- ation. of butane in butylone and of butane in divinyl is for both catalysts of the same order and corresponds to the .,riLtio 20:1. In the experiments with chromium catalysts the irolocity ratio in the formation of divinyl from butane I ~ corresponded to 1:1000 and in the experiments with an alumo- chromium catalyst to 1:25, Furthermore it was confirmod-that the formation of divinyl from butane takes place over the. stage,of the formation of butylene. It was shown that the- constants (in the denominator of the kinetic equation of de- hydrogenation) represent aduorption~o'oeffioionts. There are 6 fioure 4 tables, and 5 references, 4 of which are Slavic. ASSOCIATION: Institute of Organic Chemistry imeni N.- D.. Zelinskiy AS USSR (Inatitut vf6anicheskoy khimii imeni N. D. Zelinskogo Aka'demii nauk- SSSR). SUBMITTED: January 4, 1957 2. Butylene-Dehydrogenation (;a:;-d 2/2 -3.','~Cifbon- isotopes '(Radi6active)-Applications 4. Chromim Catalyst-Applications 6- V AUTHOIRS: /3alandin, 1k. A., Isagulyants, G. V., Popov, Ye, 1.,62-2-18/28 Derbentsev, 'Cu. L., Vino:~radov, S. L. TITLE- The Application of Radioactive Carbon for the Invectigation of the Dehydration Mechanism of Ethyl Alcohol Over Aluminum Oxide (Primeneniye radiougleroda dlya.issledovaniya mek.han- izma degidratsii etilovogo spirta nad oki3lyu alyuminiya). PERIODICAL: Izvestiya AN SSSR Otdelerdye Xhimicheskikh Nau1c, 1958, Nr 2, pp. 233-235 (USSR). The problem of the above-mentioned de]Wdration mechanism.has long been discussed in publications. Various authors.assume that the formation of ethylene takes place over thesta6e, of the formation of the diethyl ether. Others, however, think that ethylene and ethers form as a result of 2 independent parallel reactions. For the purpose of solving this problem the authors performed the dehydration of ethylone alcohol. with addition of diethyl ether. See formulae (2),(3),(4). A:3 the final result of the performed reactions showed, alcohol, ether and ethylene possess a spicific radioactivity (see figure 1). The authors determined: the dehydration velocity Card 1/2 of ethyl alcohol and ether in ethalene as well as the ,-ommon The Application of Rad-ioactive Carbon for the Investigation 62-2-18/28 of the Dehydration Mecbanism of Ethyl Alcohol Over Aluminum Oxide. conversion of alcohol and ether over alumintun oxide at 3000 C. they found that ethylene forms in two differett ways: directly from alcohol, and over ether. There are 2 figures, 1 table, and 8 references, 6 of which are Slavic. ASSOCIATION: Institute for Organic Chemistry All USSR imeni N.D. Zelinskiy. (Institut organicheskoy khimii imeni N.D. Zelinskogo kkademii nauk SSSR). SUBMLITTED: September 21, 1957 AVAILABLE; Library of Congress 1. Carbon Isotopes (Radioactive)-Applications 2, Ethawl- D61Wdration 3. Aluninm oxide-Applicatiom Card 2/2 ,50) AUTHORS: Balandin, A. A., Isagulyants, G. V. SOV162-58-11-5/26 .TITLEt Dehydrogenation of Soma Hydroaromatic Hydrocarbons on Chromium Catalyst (Degidrogenizatsiya nekotorykh gidroaromaticheskikh uglevodorodov nad khromovym ketalizatorom) PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheakikh nauk, 1958, Nr 11, pp 1303-1309 (USSR) ABSTRACT: In the present paper the authors especially tried to establish equal conditions of reaction for various hydrocarbons. For this reason the data determined may be compared qualitatively as well as quantitatively with each other. The authors applied the running-thru method. The general scheme of the appairatus corresponded to a similar scheme described in referen ce 1. The catalyst was produced according to the method described in reference 4. Its activity was constant and was controlled after dehydrogenation of cyclohexane.,Dehydrogenation of cyclohexane, Dekalin, methyl cyclohexanel 1,3-dimethyl cyclo- hexane, Tetralin, 2-methyl-5,6,7,8-te:tr&hydro naphthalene:was investigated on the chromium catalyst. The 4 compounds Card 1/3 mentioned last were investigated for the first time. The Dehydragenation of Some Hydroaromatic Hydrocarbons SO lr//~-'52-58- 11 -5/26 on a Chromium Catalyst activation energies of cyclohexane, methyl cyclohexane, 1;3-dimethyl cyclohexane, Tetralin, and methyl Tetraltr, were determined on the chromium oxide. The.hydrocarbone similar in structure - cyclohexane, methyl. cyclohexante, dimethyl cyclohexane, and Dekalin - are characterized ty similar constants of the Arrhenius equation which, however, do not agree. The occurrence of methyl groups in the cyclo- hexane ring slightly reduces these constants. At high temperatures this leads to a considerable difference in dehydrogenation velocity. Tetralin and methyl Tetralin can be dehydrogenated at a greater number of active places than cyclohexane and its homologs. Dehydrogenation is in this case characterized by greater constants of the Arrhenius equation. For the dehydrogenation of all hydrocarbons mentioned the factors of the exponential functions are logarithmically dependent on the activation energy. The distribution constant is the same in all cases. There are 7 figures, 10 tables, and 5 references, 3 of which are Soviet. Card 2/3 .Dehydrogenation of Some Hydroaromatic Hydrocarbons SOV/62-58-11-5/26 on a Chromium Catalyst ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii nauk SSSR (Institute of Organic Chemistry imeni N. D. Zelinskiy of the Academy of SciencesUSSR) SUBMITTED: May 14P 1957 s/.cal/62/000/001/007)'067 B156/B101 AUTHORS: Minachev, Kh. M. Isagulyants, G. V., Kondratlyev, D. A. TITLE: Investigation of the poisoning of a platinum catalyst, in reforming conditions, by thiophene containing the radio- active isotope S35 PERIODICALt Referativnly zhurnal. Khimiya, no. 1, 1962, 75-74, abatraci 1B540 (Sb. "Khimiya seraorgan. soyedineniy, soderzhashchikhoya v neft-akii i nefteproduktakh, v. 4". M., Gostot)tekhizdikt, 1961, 160-165) TEXT: The general laws for the poisoning of platinized Al 20 3 conta.infjng %6' Pt by thiophene labeled with radioactive sulfur, when dehydrogenat'"ng cyclohexane in a floa system at an H 2 pressure of 20 atm and a temperature of 4500C, are studied. Radiochemical analysis enabled the sulfur content of the catalyst to be determined, this varying between 0.063 and 0.14~* according to the concentration of thiophene in the initial mixture. The activity of Card 1/2 B/081/62/000/001/007/'067 Investigation of the poisoning ... B156/B101 the cptalyst decreases linearly as its sulfur content is increased. The process of regeneration of the catalyst is accompanied by the removal of sulfur from it, but full activity is restored when the catalyst still contains -40',- of the sulfur which it contained before regeneration begans [Abstracter's note: Complete translation.] Card 2/2 33491 S/195/61/002/005/016/o27 S71190 E030/Ei8.5 AUTHORS& Isagulyants, G.V.l__and Balandint A.A. TITLE: The use of radiocarbon (C14) in studying the mechawism: of parallel-consecutive catalytic processes PERIODICAL: Kinetika i kataliz, v.2, no-5, 1961, 737-;740 TEXT: The use of radiocarbon is proposed to determine the stages and proces s of forming products in parallel-c6neecutive reactions, the general scheme of which is represented bys W A W W\2 C 3 where A is the initial product, B and C the products formed during the process. Three'typical cases aris*t for &'reaction rate W2 0, C is formed consecutively from A with*B an inter- mediate; for W3 f-se 0, B and C are formed from A in parallel but Card 1/ 5 33491 The use of radiocarbon (C14) S/195/61/002/005/Oi6/o27, E030/EI85 independent of each other; and when all the rates are commensurable, C is a product of a consecutive-parallel reaction. The formulae for the rates Vi aret dp C2 d, C-L Wl dz (a Ta C3(dy/d-t) + (y - a)(dC3/dT) dC3. W3 W2 _(F7 W3; where mo p, y are the OL specific activities and Cl, C2'j C? th-a concentrations of A, B, Cl respectively-, T is,the contac tim-S. The authors were able to observe the above discussed.cases in, many processes by adding to the initial product A a small quantity of B or C marked with C-14 and determining the changes, in concentration and specific radioactivity in relation to ~ contact time. one of these processes was that of thA decompo- sition of ethyl alcohol investigated by the authors together with Ye.l. Popov and Yu.I. Derbentsev (Ref.3s Izv. AN SSSR, otd.khim. n., 1958, 233). The decomposition was carried out in the Card 2/ 5 33491 The use of radiocarbon (C14) s/iq5/6i/oo2/oo5/oi6/027 E030/EI85 temperature range 275 - 400 OC with aluminium oxide as catalyst. It occurs in two directionss into ethylene and Into ethyl ether. At the lower temperatures, decomposition into ethylene was much slower than the dehydration reaction (reversible) into ethyl ether. An the temperature rose, the decompositi6n rate.of ethyl alcohol into ethylene rose until at 400 OC it b4came comparable with that of the ether reaction. Thus, the concentrations of both alcohol and ether show maxima. As the temperature rises.the' ether maximum is produced not only by the direct alcohol-ethylene reaction, but also by decomposition of the ether to ethylene. At 400 OC where there is 100% conversion to ethylene, 80% of the ethylene is produced from the alcohol and 20% from the ether. The dehydrogenation of cyclohexane to cyclohexene and to benzene is another similar process (Ref.53 Yu.1. Derbentsev, A.A. Betlanding G.V. Isagulyants, Kinetika i kataliz,. v.2, 741, 1961). A pare consecutive process occurs in the dehydrogenation of butane-butene mixtures on chromium catalysts. Both the butane and butenes are converted directly to butadiene, the conversion rate from butane boing about 3 times faster than from butene. Card 3/5 33491 The use of radiocarbon (C.14) .... s/.195/61/002/005/016/027 E030/EJL85, An unexpectedly interesting'syttem is the decomposition of isopropyl alcohol on a vanadium trioxide catalyst. The catalyst was obtain*d by passing hydrogen over the trioxide at 4170. The genoral scheme possible.ins. H2 ~H20 (113 H60 4 C3H7OH, C H 3- H2\1. H C H/I _/ 2 Sy using radioactive propylene (up to 29 000 impu*/mizi on BaCO3.)) and by separating propane, propylenso and the catalysa.te, and determining their activities, it was shown that propylene in not converted to isopropyl alcohol at 3150, and that propane is formed, not from propylene, but from the isopropyl alcohol. There are I table and 10 references$ 8 Sovlet.-bloc and~2 non- Soviet-bloc. The English language references read as followal. Ref.8.- V.J. Komarevsky, J.Amer.Chem.Soc..j V.69, 238,1947. Card 4/5 3 3L- 9 2 S/195/61/002/005/017/027 E030/El85 AUTHORSs Derbentsev, Yu. I. I Ba landint A. A. , and Isagulydnt s oll~ V. TITLE. Investigation of the role of cyclohexene in the heterogeneous catalytic dehydrogenation of cyclohexane, using radiocarbon PERIODICAL: Kinetika i kataliz, v.21 no-5, 1961, 741-747 TEXT3 The dehydrogenation of cyclohexane on chromia and rhenium catalysts has been studied, using C14. Chromia was chosen as an oxide catalyst, favourable for doublet dehydrogenatio .n.,, and rhenium as a metallic catalyst suitable for a sextet dehydrogena- tion, where the conversion rate of cyclohexene by this process..L'S negligible. The chromium oxide in' 2-4m pellets was obtained from. ammonium bichromate. Before every experiment the rhenium catalyst., prepared by the method previously described (Ref.81 A.A. Balandin, Ye.I. Karpeyskaya, A.A. Tolstopyatova, Zh. fi.z. khimii, v-33. 2471, 1959) was kept for one hour in hydrogen at 480 OC. A continuous flow reactor was used, with varying initial concentrations of cyclahexane (obtained by hydrogenation of benzol), Card 1/3 33492 Investigation of the role of s/195161/002/005/017/027 E030/E185 benzol,-and marked cyclohelcene (ActivitY 470 pulieA/minute mg BaC03) obtained from C" marked phenol. The Cat&lysates were analysed.chromatographically on a 7m long spiral column of diatomaceous earth, of which the first half was impregnated with dinonylphthalata, and the second half with dio:;tylsebacatei othi~ outlet from the column was led either to a thermal conductivity detector or for quantitative analysis to a bubbler with obaryta water,, in order to obtain ba rium carbonate. The radioacAivity of targets made from this carbonate was measured with an end window counter, and samples taken after 15 min. on the chromia catalyst, benzole was formed by a parallel-consecutive processi- conversion of cyclohexane into benzole is 1.5 times faster than the conversion of cyclohexene~~ a considerable part being formed from adsorbed and desorbed cyclohexone and it is obviously a doublet.mechanism of dehydrogenation. on the rhenium catalyst, there is no consecutive process at all and cyelohexane is converted directly into benzole by a sextet mechanism.. The differing behaviour on the two types of catalyst is striking-,, on chromia it is dehydrogenated to benzole, but on rhenium -it is Card 2/3 ISAGULYANTSp G.V.; BALAUDINO A.A.v akademik; POPOV, Yo-1. ------- Deteruiination of relativo adsorption coefficients by isotopic dilution. Dokl. AN SSSR 139 no.1:139-141 JI 161. (MIRA 14:7) (Adsorption) (Radioactive tracers) ZAMUffCHZVAI I. I.X--LUGUTAI!T~ ~G. V.; BAIANDIN,, A. A. IfomtIon of ethane during deeomposition of ethyl alcohol on titaniiiii dioxide, Isy. AN SM* Otd. khta. nauk no.1:179-180 163. (NMA 16: 1) 1. Institut organicheskoy Wadi in. N. D. Zelinskogo AN SSSR. Octhane) (]Bttql alcohol) M~ ISAGULYANTS, G.V.t RYASHAIJISEVA, M.A.; DERBSITSIEV, Yu.I.; hIRIACH7, Kh.?,4.; MM7=- A.A. Role of cyclohexene in the dehydrol-ation and isomerization of cyclohexane under conditions of reforming. Neftekbi-Pa 1, no.2o.229-235 Vb7-AP'64 (M I P-k 17 18) 1. Institut organicheskoy khimii AN SSSR imeni Zelinskogo. ISAGULYA~~...~.V.-, BALANDIN, A.A.; POPOV, Ye.I.; DERBENTSEV,. Yu.I. (Moscow) C14 tracer study of the dehydration mechanism of ethyl alcohol on aluminum oxide. Zhur. fiz. kbim. 38 no.1:20-27 Ja164. (MIRA 17:2) 1. Institut organicheskoy khimii imeni N.D. Zelinskogo AN SSSR. DEREENTSEV, Yu.I.; MARKOVY M.A.; ISAGULYANTS, G.V.; MINACHEV, Kh.M.; BALANDIN, A.A., akademik; FrInIma-La - e SHGHUKINA, O.K. Mechanism of cyclohexane dehydrogenation over holmium oxide studied with the use of radiocarbon C14. Dokl. AN SSSR 155 no.1:128-131 Mr 164. (MIRA 17W 1. Institut organicheskoy khimii Im. N.D.Zelinakogo AN SSSR. ISAGULYANTS, G.V.; DERBENTSET, Yu.I.; KLABUNOVSKIY., Ye.I.; BALAND111, A.A. -...... ~, Mechanism underlying the catalytic dehydration of 2-butanol on the surface of aluminum oxide. Izv. AN SSSR. Ser. khim. no.6:985-990 Je 164. (MIRA 17:11) 1. Institut organicheskoy khimii im. N.D. Zelinskogo AN MR. E RYASHENTSEVA, M.A.; DERBENTSEV, Yu.I., MINACHEV, Kh.M.; BALANDIN, A.A. Mechanism of cyclane isomerization on bifunctional catalysts. Izv. AN SSSR. Ser. khim. no.8tl555-1556 Ag 164. (MIRA 17v9) 1. Institut organicheakoy khinii im. N.D. Zelinskogo AN SSSR. V.S.; GUDKOV7 B.S.; 1~-ACMLYAWII'S, lknife,-tation of a bifunctional character of 'N' surfaco In catalytic conviw3ions of e.vc-lohexana, S'SR. ~ - r, i, - 1 ;er. il"I -~A t Organ, mm 13,11GITLYANTS, G.V.,- FOIIARWA, Ya.N.; DAI-ANDHII, A.A., Dehydrcgenation methanism ot c:yclane:3. Delaydrogenation of me tlWlc,,yclrhexane or, an califdy~~it. Dokl. AN SISSR 164 no.6.'1307-131.0 0 165. (ViJRA 1.8: 10) 1. Instlitul. orgardeheskoy kleml-,- im. AN SSSR. a 0 0 0 0 0 0 0 0 0 0 6 04 0-6 j:-41 18 -0 0 0 0 0 0 0 * 0 41 0 49 (v- 9 0 0 0-4-0-4-0-0-4 0-0-0 a -0 0 4 * j A I A r 1 a f v r6 z9 , 30 It 32 a 14 1$ m s is AD It 14 35 I Ii is 14 ly t - - - 41 of " 4 t4 t 124 00 ~ 1) j&jAjWLVAXfX AND SMOSUSGIN V. ads ID astieddebro . . . , ---m"r was umd as O j90D a Ski 11W4 " 96 m r , ZMAWOVKU. Zkw. prW n. k ). 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