SCIENTIFIC ABSTRACT KARPACHEV, PAVEL SPIRIDONOVICH - KARPACHEVA, S.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000720820003-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 13, 2000
• Sequence Number: 3
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

ARMIPOV, Nikolay Nikolayevich; MIPACE.:W. Pavel Sr)iridonovich:
1-MZ-ELI, Mal-s Vil&aYlovich, dokto-r-TgEhh. nauk, pr-or;--;
PLEEVAKO, Nikolay Alekseyevich; ZAYU-C1,TGV=Y, A.D., do-ktor
tekhn. nauk, prof., retsenzent; ZOLGT-01*, V.I., inzh., retsen-
zent: ZYBD4'-, V.P., doktor tekhn. nauk, retsenzent, KAPUST111,
I.I., doktor tekbn. nauk, prof., retsenzent; KOZLOV, B.A.,
inzh., retsenzent; POFOV, S.E., doktor teklm. nau1c, prof.,
retsenzent; EPPEL', S.S., kand. tekhn.nauk-, dots., retsen-
zent; VE-1AYEVA, T.F., red.; SHVEETSOV, S.V., tekhn. red.
[Basic processes, machinerj, and apparaiuo of light industry]
Osnovnye protsessy, masi-diV j. aparaty leglkoi promyshlermosti.
r
LBy] N.N.Arkhipov i dr, Moskva, Izd-vo nauchno-tekhn. lit-ry
RSFSR, 1961. 491 P. (Industry) (MIRA 15:2)

- - 4
ARKHIPOV, N.N.; AARUGHU,_PS,; MATZELI, M.M., doktor tekhn. nauk,
prof.; PLEVAKO, N.A.; UDODOVSKIY, A.N.j kand.-tekhn. nauk,
retsenzent; RYZHOVA, L.P., red. izd-va; ELIKIND, V.D.,
tekhn. red.
(Fundamentals of the design and construction of standard
machines and devices for light industry) Osnovy konstrui-
rovaniia i rascheta tipovykh mashin i apparatov legkoi
promyshlennosti. (Byl N.N.Arkhipbv i dr. Pod red. M.M.
Maizelia. Moskva, Mashgiz, 1963. 599 P. (MIRA 16:7)
(Machinery--Design and construction
(Instruments)

A
Lek-hil. Prof.; CH-L"17"I'l, .:,47
P.s . I imml .
"'fect cC mechanical ac', ions (.,n 01--~ n,
in tannin tanning. Ilauch.
1. Kafedrn. teldnologi-i kozhi 1-
instituta legkoy promyshlenno:3ti.
)!I:r
;-"n .
,-~ticr t~ C enc t! -a! on
Wi III i I

KARF:,.Gll-r,N, Fawl Spiridonovl-h; 1-faks
uOlktor tekhn.naukprof.; FLEVAKO, Nikolay Alekseyevlch;
C111--kUll", Fetr Petrovion; 7Wl'OllCffKCjVSKIY, A.D~q d0ktor
toklin.nauk.prof., retsenzerit; 7,01PTOV, V.I., Inzh.,
re r.3enzent
and a-~paratii~i fcr the
limi t'il.11" nw,"t-l-i'lLd ~.wslt;lny i i-pponLy pro-
(ir. Mit,,,.1-;~-, Legkui~a
r)9 1.) .

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lite 1~01 ctiniti,4941 of 14.1
1A 111WnStat'l. Its 111,- 1.41,
Nld lort4l. While MU41tAIII. alt An%J A K h'
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1%( NWI ~% nni"tant In-camer it rrdtk" the in 1). eif lite 1wh ao,l at th' "'ne
dilutt% the KCI control. whwh 6 helpful in keeping K mit id %IS. 0 111
tit a 1,411 -mic clectrOyliv b4th itur Own.

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molten Wts. S. XtIrpaclicy. A. Slitminixig
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ollorallkaya. J. Pkvs.'Ckjvc. (U. S. S. R.) S.
IW4).-Thc 3ystem kCl-MLClj was ~tudkd at
The ckc. cond. at All temps. falls as the
mtent h itterrawd fruits 0 to 30 motes f-o, then
const. and 12111 rapidly alwve 80 moles ':~. Th,-
)Inpn. Cit." %hows maxittis at 3.1 arld Y) moles ' 4 "S 0
The dutibir salts _KCL.%fgcl awl KCI.%Igcl w,,

CLASSIFICATION
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Ask-ILA MIOLLURGICAL LITIOATWE CLAIWICATION
via".
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INTERNAL FRICTION AND ELECTRICAL CON~,UCTIVITY
IN THE KC L EM F FYM SALTS. S. V.
IMirvachey . 0. StrombeEg. indV. N. PodchalAM.
-Ti-anilated from Zhur, Obshchel 1(him. 11517-27(1935).
l8r. (AEC-tr-023)
In the interval of temperatures from 400 to OW, the
electrical conductivity and internal friction coefficient for
the system of fused salts KCI-LICI was investigated. On
the basis of the results obtained it Is shown thAt direct
application of Stokes law for describing the movement of
separate tons within the tuned salt is Inadmisalbte. (auth)

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Of tM Cutmt-POWnILW cunw of fusftl KCI + IACI =00

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with and Without stbling.-- R. R. 'a

jL&I..ILA MITALLUROCAL LITIVATUIll CLAIVOKATION

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ft
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S. Ksqmvhcv atki A. Stralittliffil. J. P4 .V, (_A- I I
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KARPACHEV
"On the Work of S. Pletenev and V. Rozov, "Cathode PolRrization during the
Electrolysis of Molten Substances"; Zhur. Fiz. Khim., 12, No. 1, 1939.
Report U-1613, 3 Jan. 19,52

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I

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k , .wit,fol, thm th,

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- Poo
ing t
At hotiv jk)Ltr izat ion 1, [lot V-413d. Cf.K.J11,11 "Atorit,
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Solutims of meUdUo cadmium in molten o:
IS chlorides. S. KARPArsciin and A. STMORRER41 (.1.
09 f1k.". Chrin, 11tow" * 1030,13,397 -4M). -Tlip 1wilen
go
0 J 1 ini of a C Plectrtwip In a polution of (A in n nuiltro
tuixturv of (MCI KVI, aml NaCl nt 71 )'IA given bv
1 R = const. - 2-4j11Tj-'F) log [WI. indicating that t lie
C41 it; diseolved as single stow. Tlie solubility of
(V in snixtum-s of the above chlocid" has liven
deduml fn)tn r.iu.f. nkeasumnients. thp rraultp bring
ciinflrntotl lky dimvt deterwination. 11.41.
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KARrACII-EV, S. , STROI,TEM, A.
"On SolutiDns of Metallic Cadmium in Molten Chlorides"; Zhur. Fiz. Khim; 13,
No. 3, 10,39; Ural Physico-Tech. Insti., Lab. of Electrochem., Sverdlovsk;
Rcd 28 Jul. 1938.-
Report U-1613, 3 Jan. 1952

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Karpachev, S. lYn'lld and R. loftlAll. J. PAP. Chm.
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Aud
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phrmimena arr fAArrvvd. I'm low v. & the cutPA
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o
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A
(~ M111-ber
A. &S, GI0SP,-IhptI- d4ca on the dectro.
d.
capIUM V*qml" ww tm mrfwe icuslum cd TI-Hg
Una--s 00m4. frm 0 to to TI mW dimWvvd In mol-
Sea KCI "d ucs ore Vivo%, M tablet arA 2 Op. The
mantm IS which the curva (w vubus "Wns. Ile with
ispmt to ow anothier to skman this @&me as for Aq. Owns.
W Ibid I 7640M). C. A. S3, 569111). In the to=
of* Z;bq I the pottatimis at the umx, of the
he
a( the coma., wbm~.&
The
potentIat rehire in the m--. d the rite. espilivy curyt for
metals disedved In nuAten KCI-UCI wv-. Hg, 0.1. So.
().23; MO.47: Z5.0.65; TI,0-65; andCd.0.63,
P. It. Rathnisun-i
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;my-Th.-iuumj IXOTS in
y of
Fusedgalts.
un,xim, and mercury-tWhum sIIqI In fused eleetrolvtel we"' 'Wert"ine'l.
00 [it the tin ritic allovs. the cum, A wing interfacial te.winn ILV a function of
wittv"ition It," a 'ruinimum. Theocu!.Vvs for ali'v3p air
verv imilar ti) thom, ObWnmI in ailurtius wilutions tit- Frunikin wA Gor-
:0 det'Lli,l (Z. IIA!iIiIIII. CAM.. 1922S. 138, 4,11). The sig.nifican-vol' thin* rt-Ault
68v in tite theory of vIcetroexpillarity is diwusseI-N. 11. V.
00
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oil
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ONOCItiff APO Off"411116 wot#
ches, wid R. Ionian. J. PAYS. CAM. (U. 8.1 RITZ
--1493t7t")~Tbe relkatim bet ~&!Aofb
C electrode vid the cwA=. c of =a1tri.7 liquid saft
(RY'/P)Ioc. c. It is sh"a
0 0 is ghm by 8
tW Li dinolved in 3adttd alts tsists in its at.
as the complex W 1.6". B. C. P. A.
go
0 .00
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go Loll CA WJO+Akl
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bell
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It It It U Is If It4it 11 at a If Ais-V-a-it! X It 11 UM H b Ir a X 41 it Q 0 a a
T-J-M IV jM
Is
00
!-00
00 00
of
0 Ali
ON SOIATTIONS OF METAIZ (CAMMM) IN FUSED SALTS. (IZVFST- '00
6,(l) 43-413-(IaRussian) An 113weatiga tion
AKAD NAUK S.S.S.R. IM, (fit) -00
00 vma carried out at determine carbon-electrode potentials as functions of .00
0c tl~,,o concentration of metallic cadmium dies lved in fused mixtures of
atiom- X* 9
ptita asium, sodium, and cadmium chloridese It Is shown t:.at t he rel
oonst. lrCv-W*A. =00
ship found abya the thermodynamic law: E
2? re*
00 Zoo
00 ,v
go
zoo
so*
tie
t'"
19*
--W
a ow 0 1 if h -j a -it
P 101, ai an grit 'Catt Itu"404 00
0 0 * 0 a OLO 0 * 0 9 0 0 0 0 0 S * 0 0 0 0 0 9 Ole 0 ~S 0 0 a 0 0 0 0 (P 9 0
~0-1461000 00.000 * 0 0 0 0 0 0 * 0 0 * 4 o 0 0 Ole 6 00 - 0 0 0 0 0 0 Q 0 a6

1-1-,r0419";
0 00 0 0 0 0 0 0 0 0 0 0 0 0 004 0
IL r a FI- 10*1 1,--- ri-GILL-l HiMl CC W U
I A 4 1 a r I # 4 it 11 Is W U k 17 4 W a a a )f
-of!
iio *0 Sir*
oil majon huxorviolij S3 0 a 0
I L tj ~ 0 -41-P t-A
ts
*0 Investigation of Ilectrocapillary Phenomena on Various Liquid -00

0
Oil Metals. S. Korpatochoff and A. Stoomberg (Act& Physloodhim, U.N.S.Se -00
1942, 16s (5/6) C. &be., 1943, 37, 3322).-Cf. 9. and S., A -410
81" ibid., 1940, 12, 5231 Not. Abs., 1941, 8, 342. El9otrocappillary cu- -so
;W rves for silver, antimony, biwouth, cluminium, gallium, and t*Uurl= a**
were obtained,, using fused sixturoo of KCl+LICl of outectio cimpos.
09
itica as the olm~irolyts. A table Is given for the potentials of
the mxlm of the cilectrocapillary curves against the load *loot- C-00
rods for the e6tals studied. In a number of can*# the p.d.s at the
aaxixa of the eleatrocappllary curves for different astala coincide
with the p.d. between the" setals at their points of sero change 2 too
in aqueous solutions. Such agpeatent Is not found for silver. Ize:
0
A 1 05 1, ADITALLuorKAL L1119kUllf CL114SWICATION
awl
T- T-
U IN 49
Ot HW is I I& An 1 1 CW 0 X 0 1 ill Ill '4 a 0 >
0 94, 0 0, as 0 0 0 o as 0 0 0 0 o a 0 a 'a 0 0 0 0 0 a 0 0 a 0 * 0 * a 0 0 0 0
0 * 0 0 as i 0 00 00 as 0 0 * 0 0 0 0 Is 6 0 6 0 j * 9 as o o 0 a * 0 so 0 o a 0 is o *
ts* 0
1110 0

6olat of ksd In its WWI chlodic t.,chev, A. Sttom-
berg. and E. Jordan lCompt. rend. .4c4J!Y1sraT1.`,_RSS.. 1942. W.
101-1041.-Froto measurements of the potential o( a C cl~trWc
in a solution of Ph in fused PbCl, at 700' as a functsun of the concri.
of the mttaL it is concluded that the 110 Kom into solution a., a
univalent positive ion. The solubility of 11b in 1,K),,at 700* is
0.0417%. 11 1. IV.

KARPACIIEV, S - , OMOI-TERG, A.
Mbr. Lab of Electrochemistry, Ural Affiliate of the Acad. of Sci., USSR; (-1941-)
"The Contact Difference of Potentials Between Mercury and an Imalgam of Thalliun"
Zhur. Fiz. Ehim. Vol 17, No. 1, 1943
BR-52059019

4W
04
11 U 11 M to N 11 to it 4 It a D1 is' It P 1
&_rate NA a
4
Pecre.r'll .0t.
00 a
11 11 U 0 0 b U I I oleo
-1- .1 tA, L-1 A.
0
.1 AkV &I. C*PJffj
-~710
Measurement of the Capacity of the Secondary Electrical Layer on
the Alloy Vuda
0 3;)X hove N. Ladygin, and V. Zykov (7hur. Fit.
xhilu., 1943.. ( . 8-70.-(In Russian.) A study was made of the cap-
&city of the secondary layer on liquid and solid Vuda (bismuth 50.1.
land 24.P. tim 14.2, cadmium 10.6 wt.%; M-P,~71"C) at 'Various values
or the elpotrm~,- potential. It is shown that in regions wharv tr4o sur-
a face of the mott. In negatively charged, the capacity is 15 and 20,ar./
am.2 on liquid a~% solid alboy. respectively. - N#P.V.
U
I~vt
S'voraloysk .5+,J4 U. ;m. G
LIURATLAI CLA%iWKA11QU I z
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as
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Ell
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d maws. S.
h, Acad. Ski.

1 11 Chiron. (U.S.S.R.) 21,
1 00

t'.NM't2(l04"Wn RuW&n).- curTrnt I tvtvw~'l a
&
'""I C41 W 111411will cat ht*lr a 11.1 wit 14 1 wom'f oil a n'.]- 1'.
-
votiswo of ItI I ono. till dejW11.16 on the v-4k&gr I 4p 0
poed to the cell according to I ~ kj(V + V,) and i - Art
(V + Vt) for the 2 anodes. From tbew measimentents
6
di&rence V, - III Is caw. It is O-M W. for liquid
Z
/
and solid Pb at 300% 0.42 Y. for solid So and solid P~)
at room temp., iwd OM. 0.M, and 0.46 v. for liquid
*
coo
Sc-Pb at W. HIM (W). and SAWfl (420
). rc~j,
The cotil "tial diffeirroce 1'. - V, Is slino"t equal
= 00
to the di
bctwttn the 1xitentials coitespandbil to
the clee"irwapitlary max. of thm metab In molten clectr-
The e.m.f. of a cell is V. - Vg plus the potential%
P.n. he diffavnce betvrmn the clectroirce ~cn. in ih, a0c
cril an', the conciti. co"nponding to electroca y 1113x,
r"it
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CoItchn, m tures of cryolite mild
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0 0 0 Ole 0 0 0 0 6 0 0 0 0 60 go a 0
0 4k 41LA 0 0 9 * 0 0
L -

MM/Chemistry Amalgam, Tin ATr 1948
Chemistry Blectrocapillarlty
CV
~~"Reawwoh' an the Meatric Capillary Phenomenon in
~O-Amftlgsms of Tin and Bie=th," S.V. ZarpwAST, V.P.
Kochergin, Ye.F. Iordam, Zlectrochem Lab, Ural
Affiliate, Arad Sol U , Sverdlovakp 6, IU~
"Zbur Flz Rhim' Vol IM, No 4
Blectrocapillary phanomencn Sams of tIn
evidence minimum surface termion, while ammlgams
of bismuth evidence maxim= surface tensica. Can-
duoted. studier todetemminethe alastiolty of mer=7
vapcra an subject -slgams at temperatures of
67T22
UM/Chemistry - Amalgam, Tin (Contd) Apr 1948
4200. ftimitted. 23 Jul 1947.
67TM
V)

Esrr-acht:~v. -.n-' P.11guev, S., DeterminAtIon -)f the tr-ansfcr numinbez-:3 of catIon axyl
anion in 942
The t.-,ip0IItn- m.jn~-,cvs oC the cation ani AiAon An
ii,,easwed -..:itL and -.Ath,-)A a :~o~-ous diaphramn. Values for- the t.-ansfei- nun',-cro of
,hC :~Tld anion .here o'.tained in an Interval of 0.1-0.2 and 0.9-0.e. resrectively;
that _33, the Aobi'lty of th,-, cation in rnelted ~.ea! chlo,.-Irle is :,-.,,~ch r,:r..A.Iei- hin
thA O'L t'fe ajl~,On.
The U aL Braiich f of Sci. , U'.%i
_1~_. jolarn-1

USSR/Chemistry - Electrocapillarity Aug 49
Tin Alloys
~Isearch on the Electrocapillary Fhenomena of
Alloys of Tin With Gold and Bismuth With Tel lurium,
S - Kerpachev, E. Rodigins., Lab of Electrochem, Inst
of Chem and Metal, Sverdlovs)P, Ural Affiliate, Acad
Sci USSR , 51 pP
"Zhur Fiz Mlin!' Vol XXIII, No 8
Research on both these types of alloys in -Clie flui!!
state indicates a pronounced minimum of surface ten-
sion. Aided by the theory of A. Zhukhovitskiy, ex-
amined maximum and minimum surface tensions of binary
metallic alloys vith relation to c on boundaries
67/49TI2
OM/Chemistry - Electrocapillarity (Contd) Aug 49
of -the two components of the alloys and their satur
rated vapors. Positive and negative deviatibno, I'm
the behavior of alloys in contrast vith ideal -,%61u-
tions predict vn-yimum and minimt='~.extremes, rebpe6-
tively. In the equation for the surface tensions
0t pure components, the extreme.alvays lies at the
m6lar fraction 0-5- Submitte& 27 Sep 48.
67LJL9T22

WSR/Fby5ics - contact Potential 3.1 Sep 49
Hetals - Yerzury
4
Contact Potential Differences Between Liquid
Mercury and Solid Lead and Thallium," S. Karpach-ov,
M.,Smirnov, Inst Phys of Metals, 'Ural Affilliate,
Acad Sci USSR, 4 Pp
'~Dok Ak Nauk SSSR" Vol LXVIII, No 2
Obtained an average value of 0.4417~volt, in three
i~xperiments, az the contact potential, difference
between liquid mercury and solid lead. This is
vexy close to potential difference bet4een -points'
of zero charge of mercury and lead in water
3/5OT81
USSR/Physics - Contact Potential 1.1 Sep 49
(Contd)
solutions. Obtained an average value of 0.533
volt for contact potential difference between
Uquid mercu=y and solid thalliun, which is also
fairly close to value (0-59 volt) for,potential
difference between points of zero'charge of liquid
mercury and solid tballiua. Submitted by Acad
A. N. Frumkin 8 Jul 49.
3/5Or8l
rA
K-)

KARPACIIEV, S. V.
r. p
t: L;
i t
14 :4-7q,~ 'f 3)
2 3",

681'!2
0 0 SOV/20-1 29-6-39/ /6 9
AUTHORS: Pal1guyev, So F., Karpachevf S. V., Yushina, L. D,
TITLE: An Electrochemical Chain With a Solid Electrolyte']
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 12), 1jr 6, PP 133)-1542
(USSR)
ABSTRACT: The authors investigated the temperature dependence of the olec-
tromotive'force of the chain Ag/AgBr solid /Br,C in tiio recicn
25-4210. The electrochemical cell consisted of presiod s-Alver
bromide, to the one and of which a silver wire and to the other
a carbon rod is attached. The entire cell was in a bromine
atmosphere. Figure 1 gives the measured emf of the cell 0in de-
pendence on temperature. The values between 110 and 421 lie
on a straight line, for which an empirical equation is solo up.
Extrapolation to the melting point 4340 of the AgBr giveo an
emf of 0,8033 v, which is in good agreement with the values
given in reference 5 for liquid Aglir (0.9056 v", confirms
the correctness of meaourements,aM points out thai. in solid
AgBr electric conductivity near nolting point has ionic char-
acter. The occurrence of electron ccnductivity in a '-_romi-i:a
Card 1/2 atmosphere is proven by the fact that the ion transfer number,

681,12
An Electrochemical Chain With a Solid Electrolyte SOV/20-121--6-39/631
for Ag+ at 200 was between 0.03 and 0.05, and at 93 0 between
0.06 and 0.11, whereas that for Br-' was zero, On the basis
of the thermodynamics of irreversible processes the concentra.
tion gradient of Br dissolved in solid A,Br and, thus, the
gradient of the holes was calculated and the transfer
number of the holes was found to be zero for the temFerature
0
interval of from 100 to 434 . The authors thanIk Academician
A. N. Frumkin for the evaluation of their work. There are 1
figure and 8 references, 1 of which is Soviet,
ASSOCIATIO'LIT: Institut elektrokhimii Ural'skogo filiala Akademii nauk SSSR
(IAZt--it-Wt--EL of Electrochemistry of the Ural Pranch of the
Academy of Sciences, USSR)
PRESENTED: July 16, 1959, by A. N. Frumkin, Academician
SUBMIT7'ED: July 15, 1959
Card 2/2

5/631/60/000/001/009/014
B110/B102
A11THORS: Karpachev, S. V., Voroblyev, G. V.
TITLE: Electrical conductivity of molten alkali-metal carbonates.
I. The system Na 2C0 3-K2CO3
SOURCE: Elektrokhimiya rasplavlennykh solevykh i tverdykh elektrolitav,
no. 1, ig6o, 61 - 64
TEXT: The authors studied the electrical conductivity of molten carbonates
of the system Na2CO 3-K2CO3 between 700 and 1000 0C. The end of an alundum
tube (inner diameter: -0.4 cm; wall thickness: 0.15 - 0 20 cm was provided
with cylindrical Pt electrodes with a surface area of_;.5 am - O-5-mm
Pt wires were used for curr?nt supply. At an electrode spacing of
4,0 - 5.0 cm, a 40 - 50 cm- cell was obtained, which was set by screws to
an immersion depth of the upper electrode of 0.5 cm. The measuring
arrangement consisted of an a-c bridge and a cathode-ray oscilloscope
which was used as zero indicator. The conductivity was measured between
1000 - 5000 cps. The results were extrapolated to infinite frequency;
Card 1/3

01651160100C)1001/0091014
Electrical condtictivity of ... B110/B102
R = g(l/R) (R = resistance, f = a-c frequency) is linear. The alundum
tube remained unchanged during B-hr melting of Na 2CO3and K 2CO3 at 900 0C
in a CO2 atmosphere. The crucible with the alundum tube containing the
melt was put into a metal block and then heated. The temperature was
measured with a Pt-PtRh thermocouple. The tem erature was kept constant
with an accuracy of 1 - 2 0C (measuring error, P+ 3%). The temperature
dependences of the electrical conductivities are straight lines which
are almost parallel, since the temperature coefficients of the conductivity
of pure, molten Na 2C03 and K2CO3 are similar. The curve of conductivity
versus comnosition first ascends glowly when Na 2C03 is added (with 40 - 4Y-
of Na2 CO3a has changed only by Of and then rapidly up to the value of
pure Na2CO 3' The dependence of equivalent conductivity on composition is
more complex: on melting with 50 mole% of Na 2 CO3a distinct minimum is
observed. This indicates that the interaction between 111a 2CO3 and K2 CO3
in melts reduces the conductivity and causes a densit. maximum at 4r' iole'
Card 2/3

S/631/60/000/001/009/014
"lectrical conductivity of ... B110/B102
Co_ There are 2 filglures and 7 references: 1 Soviet and 6 non-
o f Kc:
Soviet 'Niv three roferences to EnClish-languare publicntions read ac
follo,iis: E. Gorin, 11. L. Recht. Amer. Soc. i'llech. Engrs, 1958, A-200; A.
Reisman. J. Amer. Chem. Soc., 81, n07, 1959; -1. R. Van Artsdalen, J. 5.
Yaffe. J. Phys. Chem., 59, 11C,_1955-
Card 3/3

KARPACIIEV, S.V.; PALIGUYEV, S.F.
Electrunotive forces of eleictrochemical cells with soiid
electrolytes. Trudy Inst.elektrokh:Lm.UFAN SSSR no.1:79-89
16o. (MIRA 15:2)
(Electa-omotive force)
(Eloctrolytes)

29413
S/061/61/000/0171/01.3/!66
2V 213 0 116 01 'Y B102/B158
AUTHORS- Karpachev, S. V,,, Pallguyev, S. F.,
TITLE: Electromotive forces of electrochemical circuits with soliq
electrolytes. II. Coexistence of n-type and D-type
conductivity in the electrolyte
PERIODICAL. Referativnyy zhurnal. Khimiya, no. 17~ 1961, 67, abstract
176495 (Tr, in-ta elektrokhimii., Urallskiy fil. AN SSSR,
no,, 1, 1960, 91-96)
TEXT- An expression is derived for the emf of a galvanic cell
A/A z2 XZ JIX 9 C,A (A - metal of val ency z i I X - metal loid of val ency z2~
C -carbon electrode, A Z2' XZ1 -salt or oxide) taking account of ionic,
n-type, and p-type conductivity. It is shown that if n-type and p-type
conductivity are due to dissolution of the metal or the trietalloid in the
solid electrolyte the emf of the circuits under consideration may, under
certain conditions,be approximately the same as its thermodynamic value,.
[Abstracter,s note: Complete translation.) bX1
Card 1/1

AUTHORS; Karpachev, S.
TITLE, Electromotive
possessing electron
29104
S/081/61/000/017/014/!66
B102/B138
V., Pallguyev, S. F.
forces of circuits with solid electrolytes
besides ion conductivity
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 17, 1961, 67-68, abstract
176496 (Tr. In-ta elektrokhimii. Urallskiy fil. AN SSSR,
no. 1, 1960, 97-100)
TEXT: The effect of n-type conductivit on emf is considered for the
electrochemical circuit Br',C/AgBr(solid~/Ag as an example. It is shown
that E= E0 (1-t), where E is the total emf, E 0 the emf without n-type
conductivity, and t the number of electron transitions into the electrolyte.
The efficiency of this kind of cell is described by the ratio:
(('--t)/(i-t (Ag) ))100, if the efficiency of a cell without n-type
conductivity is taken as 100 %. When current is obtained from the element,
the Br distribution along the electrolyte changes, and the efficiency
increases. LAbstracter's note: Complete translation,j IK
Card 1/1

S.F.
Functioning of a primary cell vith a solid electrolyte
having both ionic and electron conductivity. Trudy InsL.
el.ektrokhim.UFAN SSSR no.1:101-103 160. (I-IIIUL 15:2)
(Electric condUctivity)

PALIGUIEV; S.F.; -KARFACHEVI Sjj YUSHINA, L.D.
R7oblem of measuring the decomposition voltage of solid
electrolyte solutions. Trudy Ins t. elektroldhim. Ur- AN SSSR
ni).1:105-3-10 160. - (14IRA 15:2)
(Solutions, Solid)
(Electromotive force)

S/076/60/034/'05/22/038
B010/BO02
AUTHORS: Karpachev, S. V.9 Karasik, E. M.
TITLE. On the Heats of Fusion of Some Inorganic Salts
PERIODICAL: Zhurnal fizicheskoy khimii, 1960, Vol. 34, No. 5,
PP- 1072-1076
TEXT. Proceeding from the concept of a salt melt as a crystal with a
large number of lattice defects, the authors calculated the latent heat
of fusion of some alkali halides (Table, results) by using Oriani's
method of calculation (Ref- 4). The total change in entropy during the
fusion process was represented as the sum from the change in entropy,
caused by an increase in volume, and the change in entropy, caused by
the increase in the degree of disorder on the fusion of the salt. The
valusa of the latent heats of fusion calculated from this change in the
entire entropy in the fusioz~ process were compared with the corresponding
experimental values taken from the manual by E. V. Britske, A. S.
Kapustinskiy, and others (Ref. '11), and a aatisfactory agreement was
found (Table). Frenkell is m6ntioned. There are 1 table and 12 references;
2 Soviet, 1 German, 6 American, 2 English, and 1 Japanese.
Caxd 1/2

On the HeatB of PuBion of Some Inorganic S/076/60/034/05/22/038
Salts BO1O/BOO2
ASSOCIATION: Urallskiy gosudars"vennyy universitet im. A~ M. Gcr'kc,6-,0I :"/I
Sverdlovsk I!'.
(7.ral State University imeni A. M. Gorlkiy, Sverdlevsk) -j ,
SUBMITTEDz July 199 1958
Card 2/2

S/'020/6o/133/02/41/o68
P'OO4/Bo64
AUTHORS: Karpacha, -S-V., Pal'guyev, S. F.
On the Operation of oltaie Col Wi th It
TITLE EL V Solid
Electrolyte Having a Mixed Conductivity
PERIODICAL: Doklady Akademii nauk SSSR, 196o, Vol. 133, No. 2,
pp. 396 - 398
TEXT: The authors investigated the effect upon the power of a voltaic
cell of the electron conductivitykf a solid electrolytelexisting along
with the ionic conductivity. The calculations were made from a sample
cell with silver bromide as a solid electrolyte: Ag I AgEir ) Br 2) C. The
gaseous bromine should dissolve in AgBr and thus produce an electron
conductivity of the p-type. On the condition that the bromine diffuses
as far as the silver electrode and its concentration in the electrolyte
is determined by the diffusion process only, the equations for the emf,
the electron and hole transfer, the resistance of the electrolyte, and
for th6 efficiency W 0 without electron conductivity and for W with
electron conductivity were derived (11). Equation (11) shows that in
16,
Card 1/2

M '312
S /0 2 00 / 13 14 / 0 0 50 2 00 2 3
I Ll BOO4/.B064
AUTHORS Pal,Cuyav, S. F., Karva,71iev- S. V.. Ne uyn- i n , AD -
and Volchenkova, Z,
TITLE: Transition From Electron to Ion Conductivity aq a Function
of the Composition of Solid Solutions of Oxides
PERIODICAL. Doklady Akademii nauk SSSR, !960, Vol. 134. No. 5,
PP. 1138-1141
TEXT: Tile authors wanted t study the influence of calcium oxide upon
the electrical conductivit f solid solutions of cerium'and zirconium
c x _i d ~T.==n c -4 -
e !;Fe solid so-Iut-Jon O.75CeO, 0.25ZrO. has the highest ~cn
ductivi-~y (Ref, 1), it was used as initial substance CaO was added in
varying amouncs; addition of CaO of up to 40 mole5 resulted in the
fcrmation of sctlid solutions. The i)reparation cf fhe saim.;)Ies was alrefidy
desc.ribed in Ref. 1. The relative electron and ion cGnductivitieF were
determined by 1he solid electrolyte emf method at temperatures ranging
0 0
from r-00 to 1000 C, and herefrom the activation energy %as computed.
It was found that -ion conductivity Increases with an increase in tempera-
Card 1/4

84832
Tranjition Frou Electron to Ion Conductivity S/020/60/1,34/005/020/022,
as a Function cf the Composition of Solid B004/Bo64
Solutions of Oxides
ture, reaching a maximum at 750 C. C. Only electron conductivity is found
in the system CeO 2 __ Zro2; the addition of CaO diminishes the total con-
duct-lvity with a minimum at apprcximately 6 mole's CaO; the maximum is
reached at 40 moIe%CaO,wbmtbe conductivity is nearly 100~ ion-ic -and
approximately equal to the electron conductivity of the CeO 2 - ZrO2 system.
The experiments were carried out with two electrolytic chains.
Pi,)O~ I solid electrolyte 1 0 (Pt). The cell of this chain is solhemati-
Pi p
cali'y shown in Fig. 1. The sample placed in a quartz tube betAeen plati-
num electrodes was at both ends in contact with oxygen of different
preosures (PI = 1.0, p 0.2 atm). b) Me', Me;(O) 15olid electrolytel
2
IM-3"(0), Me". This cell operated in vacuum w thcut addition of gaseous
1~xygen. The partial pressure of 0 was determined frcm :he disscciation
pressure of the oxides (mixtures of Fe and FeO, Cu and Cu 20), and ranged
rom !0_7 C 110 ,25 atm. The electron and icri conductivities were determin-
f r o m E + E E is the measured emil; t. , t the avera-e
Card 2/4

8032
Transition From Electron to Ion Conductivity S/020/60/134/00";/020/023
as a Function of 1;he Composition of Soli,1 B004//BO64
Solutions of Oxides
4ransference numbers of electrons and holes, resoectivGly, E the thermo-
0
dynamic value of the emf: E0 = (RT/4F)~In(j; 2/P! Table 1 lists the ex-
perimental data. Fig. 2 shows conductivity and AE at 1000 0C as a function
of the CaO content. With rising CaO content in the system
CeO 2 - ZrO 2 - CaO, the authors found a steady transition from electron
to icn conductivity. This effect %as not observed in the Systems
CeO 2 - CaO ard ZrO 2 -CaO. The authors give the folloiing explanation:
~4 + 3+
As a result of partial reduction of Ce to Ce , first an intense elec..
tron conductivity occurs in the system CeO 2 - Zro 2' Increasing addition
of CaO inhibits thio reduction more and more, and the ion conductivity
caused by oxygen ions takes the place of electron conductivity, A decrease
of conductivity in aamples containing over 40 mole% CaO is attributed to
the accumulation of free CaO not converted into a solid solution. There
are 1 figure, 2 tables, and 9 reforencea: 5 Sovlet, 3 US, and I Germari,
Card 3/4

(DP 9
-7r
V
AUTHORS
TITLE
SOURCE
S/631'161'10000)2iCi I j;0 I
1003/1203
Filyayev, A T., Pal'guyev, S F., and Karpachev. S V.
Investigation of electrode polarization in solid electrolytes
Akademi 'va nauk SSSR. Ural'skiy fiflial. Institut clektrokhimii rrudy, no 2. 1961,
Elekt.rokhimiya casplavlcnnykh solevykh i tverdykh elcktrolitov 199-209
TEXT~ There are indications in the literature that the conductivity at elevated temperatures in a solid
electrolyte COnSiStiDg Of 15 rnole % CaO and 85 mole % of ZrOj is almost entirely ionic and suppobedly duc
to the movement ofoxygen ions.The polarization ofthcCO -f CO,(P0 [solid clectiolyteO 15 CaO 0 85Zr0jj
0,(Pt) cell was measured by a device containing a potentiometer or an oscilloscope The oxygcn c1ccuodt
was used as [lie reference t.-lectrode, because it is not readily polarized. The relationship betwLen the anodic
polarization of the CO-CO2 electrode and the polarizing current density is expressed by the equation
p = q 4 b - log i, where t i-- 2 3 - RTIF for both anodic and caLhodic polarization. Oscillographic me~~urc-
ments show that, after the current is cut off, the polarization decreases so slowly that it can be C01tediv
measured by means of a:a oscillograph. This is probable due to changes in concentrations caused by in
hibition of diffusion or of chemical procesws There are 9 figures and 4 tables
Card 1/1

c.t--/on?/007' 15
10
2~ 0 P'. 2
AUTHORSa Y-;sh!r_a, L, D, Pal,F~_iyE:v, S, 7~, an4 Karpacng-.-, S, V.
TITLED S- udy of el a ~, tro -,,he in ic a. _-~a 11 z-; wi h 5 -~.l id i,: 15~ _- t,- (1-1yteg
I. Tempera*ure depend;~n-& -)f -hi~ force of
the %sll Ag ( AgB--(.e) I B:--,, r'
PERIODICAL! Zhurnal fizicheskoy kh,_Li1.'-, ? '96-1 342 - 349
TF,XTs In the -ourse of the work an:!;;, -h- authors measured
the emf of the deli mentioned ~.n -,he 7,; lt- -.n ~hL rar.6ii froin r~,om tempe-
rature to 421 0 I'd .ThE, test results werE i-,b-,a*rt--d wi-.h a U-shaDed glass
tubej into whooe onp bend, which serv--~d uz:~ ~-n~ gaseous bro-
mine was Introdaced and draw-, off ors ~hr-- ourfa,-,e. The con-
tact with the b_-ominc E-lectrode in 1!if~ -abi~ wale abou', by a solde-
red platinum wire. The bromine 'LtSti_' WaE 6 of spectrally
pure carbon anc6 the elec-.rolyte a --.yl'_nder prr_--sst~d fr.,~m AgBz~ The emf of
the cell was measured with a hligh-resiqthrl~'.~ of the type
c, 9 zer
NIM-1 (PPTV-1), equipped witr. an-N-9z.1". izri.-anrrre- - a a o
Card 1/5

Study of el9ctrochcmi:.a_" ceils R
instrument. Th~ accuracy vas o7c-r
110 0Ci and abou-r. ai-i ar lower ttmpera'-;r~,6. Mea~,,'Irement resul-.5 at
different tt)-mperarkirt.,2 are v F;ea T'-Mpera~-Alre
range from 110 to 4210C * ''hc- pon~'.-~ --,--~ht?d ty were upon
a straight line, whose equation Was ~.ozivei emD*.r'_-aIIy with the aid of
the least squares ni~_-thodz E I , 15 n.00,7 v (1)t
at temperatures Icwr- than. 110
were not an a straight !!.ne~ A_:crd~ng S.'s -,-m,. j. H.
Hildebrand, J. Amer. Chem, So,:., ',650~ 9~rj c~mf -~f the ~_ell with
wb~~-_- -h- -ne a-_-rd-,n,'- to Eq.
liquid AgBr amounts
(1) is 0.8033 v~ By thermodvnami~~ uI at ma,l-.- cn the basis of da-
ta by A. F. Kapu!~tinskiy (Ref. 8,., neorganiches-
kikh veshl-hestv" (,fherrrall sonetan~~ .47
1949) 0.9904 v was found f~,r ht? Qmf a, "5 ' in i i k)04q v was -)b
tained from EQ, TheBe data prc-:E~ ~ha* I.illir- -XISIS Dract-J--ally no
Card 2/5

89573
3/076/61/035/002/007/015
Study of electrochemical cells B124/B201
electron conductivity in AgBr in the temperature range from 420 to 1000C.
To find out whethex the electrical conductivity of solid AgBr was of an
electronic nature, the authors measured the transfer numbers of the ions
in solid AgBr in b:~omine (vapor pressure - 168 mm Hg) at room temperature
and 930C, the abovo described device being used for this purpose also.
The electrolyte plates used were pressed by a special equipment between
the carbon electrodes. The electrolysis current at 200C was 0-5 to 1.2 ma
and at 930C it was 1.0 to 5.0 ma. The dissolution of bromine in solid
AgBr causes an electron conductivity to appear. The electron conductivity
arising in solid AgBr in connection with the bromine dissolution is caused
by the motion of positively charged holes in the electric field. Ag- and
Br ions and positively charged holes were found in solid AgBr. The mean
value of the hole-transfer number is calculated from eauation
t Ag 1/(,Ag _,,Br) (11) (where denotes the potential of
0 ~r to dl'Br) Br Br kk Br Ag Br
atomic bromine in bromine vapors around the Br-electrode, Nr andUBr the
chemical potential of atomic bromine, dissolved in the crystal around the
Card 3/5

8 9 557 3
S/076/61/035/002/007/015
Study of electrochemical cells ... B124/B201
Ag- and Br-electrode. respectively; t 0 is proportional to the concentra-
tion of atomic bromine dissolved in AgBrs to - kc Br* The relation
to - [k(c Br - cAg)] /[1n (,Br cAg)j.The relation t.-t"/ln(c Br/cAg) (12)
Br Br' BV Br 0 Br Br
is derived, where t" is the hole-transfer number in AgBr saturated with
0 Br
bromine at a bromine vapor pressure of 170 mm Hg, and c Br is the concen-
tration of dissolved bromine in the immediate neighborhood of the Br eled'-
Br Ag
trode; c Br >~ cBr. It may be stated in this connection that if the solid
salt saturated with a metalloid practically exhibits only an electron con-
ductivity, this will not become manifest at very low concentrations of
dissolved solid metalloid salt near the metal electrode when measuring the
emf; the same holds for dissolution in a solid metal salt.
There are 1 figure and 10 references: 2 Soviet-bloc and 8 non-Soviet-
bloc. A reference to English language publications reads as followst
D. L. Hildebrand, W. R. Kramer, R. A. Mac Donald, D, R. Still, J. Amer.
Chem. Soc., 8-0, 4129, 1958.
ASSOCIATIONs Institut elektrokhimii, Sverdlovsk
Card 4/5 (Institute of Electrochemistry, Sverdlovsk)

Study of electrochemical cells
L' v
SUBMITTEDt MaY 30t 1959
Legend to Fig. 1i Temperature
dependence of the
AgjAgBr(so1)YBr 2 1 0 oelli
1) data obtained from the
present work; 2') data cal-
culated on the basis of paper
Ref. 3: C. Wagner, Z. phys. 465
Chem., 3-2, 447, 1936.
OY~73
B/076/61/035/002/007/015
B124/B201
TOMUePaTypltalt BRUNCHMOCT16 gena, Ag jAgDr(-rz) Br2,C:
Aannue "ACTO"kelk WOM: 2 - Aftunue, paccwTau-
OWO na OCHODaIIIIII Pa6OTU 131
12

--, r.7 06
S1020161114 I /GG2/020/027
Polarization of some gas ... 2101/B147
which could be(;o,-ie constant (measurement with a Pt-Ptith -.hermocou-olel
1.
The resistance of the electrolyte was measured with an a-Q bridge
0
(3000 cps). At the experimental temperature3 900, 1-000, and 11000C, it
was 23-90, 7.93, and 3.80 ohms, respeczively. A linear relationsh'.;-
e c Q71
found between current density and the measured at the 1 ctr
The resistanCES of the electrolyte calculated from the slo.-e o f th--~
straight line showed only sliGht diverc-~-nces from. t-- values measured
directly. Ac~2ordingly, no overvoltaEc- orcurred at thQ 02 electrode. T e.-4
a Pt,O electrode was exchanged for a Ptj CO + CO electrode
2 (cell IT
which produced a noticeable emf , so tl-at nu ex-c-rnal current a,Durce cas
necessar:i. km-perage was chan[;ed by means )f a resistance box. The
anodic polar'.zation of the CC electrode around a flow of '06 vc'!,-,~
of CC + 34 v~)l~/- of C02 streamed, t.-,as then :;,.easur---,!. P-ire ox-yl-en strea-
around the 0. electrcde. The anodic uvervolta.~,) was determinc-d -f'rou:
r% = E - Ir - IR (1). absclute value of anodic overvoltage;
0 k
EO = equilibrium value of ermf; I = amperage; r = resistance of electr,:If-cz
IR = potential drop in the external circuilt. For all of 4.--,e thre---
temperatures, the linear function ij = a +- b i was
pressed in VCIM'2). Since- t-,7cj 1--urticipate in the ano'dic.
Card 2/4

Polarization of some gas ...
of the CO electrode, b - 2-3RT/2Fa
values are given:
9000C 10000C
b 0.21,:8 0.250
a 0.45 0-51
a 1-0E8 0-953
is writter
11000C
0.26o
0.52
o.866
30706
S1/020/61 /141/002/020/027
:-I
~ 01 /31, 47
For a, b, a the following
At low amperae-es, the measurement values deviated considerably from
linearity. This was ascribed to the polarization countercurrent. The
following equations are written:
4 +- 4
I K exp(,%F/RT) (3); i = K exp(-,%F/RT) (4); i i + i (5)-
At high overvoltage, ?=i, at low overvoltage Eq. (5) is valid. i is the
current measured. By using Eq. (4),:*L' was calculated for the measuring
points deviating from linearity at low overvoltage, and, by taking 1t into
account7 complate linearity could be achieved also for these measuring
points. At the CO electrode, a considerable overvoltage (nL = o.6 v)
occurred. Thui3, the electrodic reaction is inhibited in spite oil the high
temperature. Further studies are necessary t-o explain this effect. TkIere
Card 3/4

KARPACHEVY S,V.; FILLYAYEV, A.T.; PALIGUYEV, S.F.
Anodic polarization in solid electroly-tes. Trudy Inst. elektro-
k1lim. UFAN SSSR no.3.-161-164 162. (MIFLA 16:6)
(Electrolytes) (Polarizatio~(Electricity))

FILTAYEV,, A.T.; KARPAGB__, S V.; FALIGUYEV,.S.F.
.__ . ~V
Capacitance of a double electric layer in solid electrolytes.
Dokl. AN SSSR 149 no.4:909-910 AP 163. (MIRA 160)
1. Institut elektrokhimii Urallskogo filiala AN SSSR. Predstavleno
akademikom A.N.Frumkinym.
(Fused salts-Electric properties)

KARPACHEV, S. V.; FILYAYF.V, A. T.; PALGMV, S. F.
OPolarization of Oxygen Platinum Electrodes in a 0085 Zr02 0015 CaO
Solid Electrolyte.*
Report presented at the 14th meeting CITCE, Intl. Comm. of Ele&chemical
Thermodynamics and Kinetics, Moscow, 19-25 Aug 63-
Ural Institute of Electrochemistry, Academy of Sciences of U.S.S.R.

1. 4982-66 EVI-P(e)/F-PA(s.)-21F-Vil'(m)./EPF(c) ~VIP(I)/EFF(n)-2/EPA(w)-:,/EYIP(t)/EWP(bi'~
AGO NR: AP5025351 SOURCE CODE: UR/0131/65/ooo/o.10/00
40/0042
S V"~ lieuYmiu
AUTHOR: Ovchinnikov, Yu. Mq KarYach0v, A. Do; Paliguyev So F-
-ORG"; Institute of ElectrochemistrY, Urals Branch, LN
qSSR (Institut
e oktrokhimii UFAN SSSR)
TITLE: Penetration of dxygen In ceramics having a zirconium dioxide base
SOURCEs. Ogneupory, no. 16, 1A, 40-42
TOPIC TAGSt ceramic product,, gas diffusion, oxygen, carton mon d a n,
oxi a rgo
titanium
ABSTRACT; The authors describe.an experiment of ol(Ygen diffusion through ceramit-
having a composition of 0.85'ZrO2 0,15 CaO, in the temperature range of 600-9000C.
The flow of oxygen that diffused.through the walls of the test tubes was measured
with argon and titanium. A.test was also carried out to determine the Renetration
of carbon monoxide at a temperature of 9000C. It was less than 4 1V*Jcm/seo.
1/2 UDCs 661,883
Card

OVCHINNIKOV Yu.M.; KPRPACHEV. S.V.: PALIGUYEV, S.F.; ZHDANOVA, G.M.; NEUMIN,
.9
A*Dq
Kinetics of the reduction by carbon monoxide of solid solutions
based on cerium dioxide. Elektrokhimiia I no.10:1296-1201 0 165.
(MIRA 18:10)
1. Institut elektrokhimii Ural'skogo filiala AN SSSR.

VM031YEV, P1114,14- uv-rv , 6,1- ~; - -x - 71 'SI.V.
V 1" 7 Of uVJl t" -:L-" *~',5 ', - m~ In 1. 1'r-4:v . 1 a
n. r., i;" 4.,) ( oi.,(p '. ., --, -,-I )
OL~h,e- Vii-no UFAN 0~~C, ~'. c I .i, ? I

0MUNNIKOV, KARPACHH, A.Ij "
0
Oxygen permoalAll-Ity of certw.,,rn an a 7,rr), bito f% ,0, g -~j t, ~ q , 0.- y -,r..
no.10-.40-43 165. ll~ Okl"Vk 1q,10"
1. Institut elok-trokhimAi UrRIllkotTo ?'illnlti AN

LOL19-66 WT [m
ACC NRi AP6015014
"JD
SOURCE CODE: IJR/0364/66/002/005/0617/061'j
AUMOR: Karpachav, S. V.; Filyayev, A. T.
ORG: institute of ElectrochemistEy, Ural Affiliate, AcadeTy of ScieTices~SSSR,
Sverdlovsk (Institut ciektrokhimii Urallskogo filiala Akademii nauk SSSR)
TITLE: Some specific features of the behavior of gas electrodel in contact with a
solid electrolyte
SOURCE: Elektrokhimiya, v. 2, no. 5, 1966, 617-619
TOPIC TAGS: zirconium compound, calcium oxide, solid solution, electrolyte, platinum
electrode potential, cathode polarization
ABSTRACT: Th46uthors meas d th acity of the electric double layer in the solid
pfe e cap
solution 0.852ZrO2'O.l5CaO i~ order to refine the data obtained earlier and to use the,'
method of capz~c-ity measurement for studying the behavior of gas electrodeq in contact
with a solid electrolyte. Platinm electrodes were employed and the capacity and re- i
sistance of the electric double layer were measured (at a frequency of 100 Kc) as func
tions of the electrode potential. Pretreatment of the electrode with anodic current
decreased the electrode capacity. This is attribitted to a decrease in the contact
area between the electrolyte and the electrode, caused by the disrupting action of thea,
oxygen escaping from the electrode, as indicated by a rise of the ohmic resistance and:
UDC: 541.135.4
Card 1/2

14
ACC NR, AP60f!~d
drop of the anodic polarization of the electrode following the pretreatment, A sub- 1
stantially weaker effect in the range of high cathodic polarizations may be due to I
the appearance of electron conduction. The data indicate that a compact platinum eled
trode does not have a constant working surface. The capacity values obtained are noti
absolute, since the true area of contact between the electrode and the electrolyte is
not known* Origo arts has; 2 figures,
SUB CODE: 07/ SUBM DATE: 19Feb65/ ORIG REF: 006
2/2-

L 38369-66 EVIT(m)/T 'D5
ACC NRt AT6021374 ( A
SOURCE GODEt W/2631/65/m/oOM169/ol7h
AUTHOR3 ftlyayev, A,_T..,- KarpacheV, S. V. ; Pal I Mv, S. F.
ORO: nono4'-N,
TITLE: Study of the'polgrization~d,f the oxygen clectrodelin a solid electrolyte
SOURCE: AN SSSR. Ur lWo Institut elektrokhimii. Trudy, no. 7, 1965. Xlek-
al I s!S~j
trokhimijr raspIavlenhyRn solevyRa I tv'erdykh 91_e1;Eo"=ov; termodinamika i kinetika
elektrodnykh protsessov (Electrochemistry of fused salts and solid electrolytes;
thermodynamics and kinetics of electrode processes), 169-174
TOPIC,TAGSt electric polarization, oxygen, platinumt, zirconima compound, calcium
compoundp electric impedance., electrode
ABSTWWT: Continuing their investigation of electrode polarization in solid electro-
lytes, the authors studied the polarization of the platinum oxygen electrode as a
function of current density in the solid solution O-85ZrO2'O-15cao- The anodic po-
larization was determined from oscillograms of the electrode potential drop with time
after the polarizing current was switched off. At relatively low polarizations., the
current dependence of the polarization obeyed Tafel Is equation, A 0 - a + b, log i,
where b - 1*3 2o3 RT * It is'shown that this value of the coefficient is compatible,
2F_
with the slow discharge theox7. The impedance of the electrode - electrolyte- inter-

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u R 4v -0 is *a A I a ow o 3, -41 4, i
0 to It a If a if It R it If Of A 1 !1%
a 0 a 0 0 0 0 a 0 0 0 0 0 0 0 * 0:41 0 0 0 0 0 0 0 0 0 0 0
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D,,~~!r:tmgem,ent .f c)mp*-,8nar-ityP-Tld conjutraticii in cry:~tal--
f--,rmung Dokl. AllT SSSR 16.0 no.3:650-653 Ja 165.
(,,,Tq
1, A18-3)
1~ in~-.tD.ut- sjmt,~zq- lm. A.V. Tol)ch~yeva
AN SSSR., Submitted -juLy 14, i,)6-/.

79'
.51 v2/31 04
U T 0:1 S Volkbv, D. I., Pshenichkin, ?. A., Kar-pzichevc-, U. 2.
T 1 T Temnarature dependence of -che maj3nctic of
man~anese-coi),.Ier alloys
Zhurnal eksoerimentallnoy iteoretic~es.:oy fiziki, v. 4'
no. 2(8), 19062, 370 375
T'-~-.~ '-'*,e -,ia-netic properties of Cu-.,In alloys sho,,-T the
causes of rhich have so far not been fully clarified. Thu 3 t ~- 'I C C
(T) between 77 and 12500.K for Mn concentrations fro.-A 5.76 - ~1-2' U-~
~'.:eansurements were made by the weighin.7method. The -,Ilo-,rs -~,Ore fu--ed in an
evacuated h-f furnace. At loy, temDeratures, all alloys s-o,.-.- an anzi-
ferromagnetic t~anstition ("Neel point 9 N) ; ON lies the deeper, the -'o-.-:er
the '-:-,i content; from 50';f L,n uP'.'.ard, it remains cons,~ant at abou-C 150
The course of the curves (T) showing a iminimum at Q., de.,,ends on t.,-,e
.,:n content: uP -.0 175', they are linear between 9,, and t1he ze-l-Winj
Card 1/2

S/L' 56/62/043/,~32/0021/05
Temperature dependence of the ... B102/ii1G,'
as from 22,~) bet,.,,een 9and room "emocrature. T'noy a ZalienT -~Oint-
N
room temaperature, and Co on linearly up to the point. -T- e
inclination of these straight lines is the jreat~.:.-, tlie h-46-'ner t',e
concentration. Resistivity maxima occur at these critic-~!
I -1loys containi-nS 82. ~ and 91 . .1 atj4 L:n s,.o-., an abt-.or:..u-' Of
ro,,-,,s rith the temoerature. The experimentz~l z esult-- car, '30
b3e assuming that conduction electrons participute in 'che exchan-a i rv~ E:-, -
action. There are 5 figures.
AS SO'. , '. ' : ... j
-IA"10% "osicovslkiy C-osudarstvennyy universitet (Losco'.-. U-':,*-!.-~~f!31-~-,)
SUB""ITTED: January 8, 1962
Card 2/2

i -,Axacterua
S-c ence

4 w
46
A -u- ~) I M
PINE
-A -
b6l
606 0d
a i
'I k_hii'd N k- `ti6'
SOURCE;: At
#r ya-, c es aya,~~
~.Topic' afte . 'ra
ensat
ST YS
e t I le -i6fd ihiU a t
.,e .. :.~ "I I . . ll-,,,~ - " -,AL'.
p.,
tp 'i
o y as c ccwp
-
uct--,-,o -,-.;po4,.con ensat o
d
iu
-~'d amino leculat! oud".1 .'64 iwit
V6
~-.~acceptor~:r
a i s
The ~~il 41'" the xeslgti~,i
ibhz-of.',t e'br
uc
A t
e--Ir-o'sist'iv*'It~'~;~ia:~,'bh' .-as~4~ftnct dn~.
fi
.T gi

AC Ssi 01
SUB. -CODE i"

m ole.cules pe~,, I

.7A

KAUACHEVA, S.M., doktor khimich. nauk; CHEMARIN, N.G., karid.tekhn.nauk;
inzh.; ZAKHAPOV, Ye.I., inzh.; DEVY-ATKIN, V.I., inzh.;
HDANOV7 B.V., inzh.
Study of the operation of a pulsating e7traction sieve plate
column. Khim. i neft. mashinostr. no.1:2.1,-27 Ja 165.
(MIRA 18-3)

MOM,
ba # W is a 'if" A
A LIIAL-M p a N 11 . - I
U*V I A -I ~ 1A OL 1
A*
0 0
Fumace for tks
KarP&chc'm -A, V-
U39.1-WO, Aug. 31,1938. A furnacr for the
triptliack by cracking hydrocarbon gases d
jn~jt gases consists of two chambees; with Indiv
boxes and a refractory checker work: In one the
is heated aW in the other the mixt. is cracked.
00 butruers In the nx)f of the second chamber bri
surface combust" in thr checker wnrk M ft,,rh
0

0 U 0 11 V 4 4 Q " 0
11 -
6 1
-

i. of
with
fire 40*
gag

i
=0 0
s
oll
bout
roo
T. t
I
a**
00
'W11 q
0-1 1; 1
'00
'00
06 it
so
t%
A I a. A L A 41TAL'XIMICAL UtERAMNIE CLASSIPICATIC.
too
00 t!! Iola., C- is( ~r
I T I I
U U 0 0 v I IN 61 9 d3 4 3 6 V
to 0 o 010 0 4 0 100 0 0 0 0 0 0 0 0 :0 0 0 0 0 * 0 0 0 0 0 * 0 0 * 0 0 0 0
*T~o I
o:ooooiooooooo

0 0 * 0 0 0
0 0 01 --0-.# 0 0,4 * 0, 0 0 0 0 0 0 0 0 0
9 13 n LI U is is is ty is to a 21 12 a 34 n a 17 a 30 31 37 33 34 u x v x x AD
'A 0'
v v I I M-W~ 41 41 41 0
4j- 1 1.-JL-
os C"'m
a Oc I I t.0 C f, f S 41
00 !f:
00 2 -00
*f cub" black. S. M-
oo I Cd6uums (cc th
Irm &.Rkbbe (U. S. S. R.) No.
C"Su
00 I%Ac*lcg. the thcru-, and
Auc" of catboa black from
B. z KwIlich
00 j
00 0
0 So 0
00
coo
'00
tto
1._Ala ~A_ SCTALLUWCK&t U71147141 CWW IKAT-CA
we 0
it *I- too
0 u &V 00 At OR 2, a, a, t, U, -mi, s a 0, 0 4 1 v IN 2 a -01 1 T..
it I
0 0 IV 0 0 0 0 * 0 0 0 0 01 0~41 0 a 0 0 0 0 0
o0 :Is 0 000 00 0 * 6 41 At 0 0 At 0 0 01 0 * 0 * SAL - -

17' - Ar
" 0 0 0 6
f 1-,!R 7
0
:
"

!6*41 000
0 8944960
r
0000000040
0
r
9999
9
'
1, 1% M I_1, 11 :J to 14 It
, 1, it I
Y ? M,
y a #I to 41 a
a
,,*
itill
; I i
t! t
1h
to ,
.
'
o
v
00
1

Rolcovecy of carbon black In cArbon-bl&ck plants. S.M.
1 .00

so x Ka ch and V. .
1. Gwittralov. Cajulchome axd
,P,;
x
S
N
7
51
5
A
R
R
) 1940 .-so

0 -
,,
,
.
o.
.
.
.
n initallatiou
.
,
ilo
f Cl
K
l
l
ll
th
l
k l
fil
i
h
0 d
so a i
io
tect
ti
ut
crivintiv o
ac
it
iur,ow
ia
t
fife lino Inary ort"Iti; tif I fie jai In it %virilbl.- t -w4,hrt, J'hr
C bluk-iiiio-ews rum
from the lurnave
-4%,e% tlitou
h (ti

00 .
e
1
S
wiriablwr where it is co,4M to LU) -70' 4nd ul4m It-wing the
-so
scrublit-ir the vritoter-qatd. mist. 14 mixtril with it portion
of the gai cistning directly front the fornare. The mittrd

00 Kaws tire thus adpistcd at a tornip. t-f 140 1.741 and then

411 0 J
fort.
-rd through the bug fillers. Thr miit. (4 C lilack atul
Water Settling In the worublirr Is ra%dy lumilkil. Nlost e(
'
h
l
ff
d
h
l I
to 0
00
06 ri
net
t
e water is dra
gin
e C Nat
l, can lie dri,,l in
t
the wirublier l;Y %hurling WT thr wat,f and fusmitj in a co 0
stresmu of hot g~wa. BY inaintaininir tl,c ump. Imfor,
1'
fi
00
the bag
lters at 121
the nw6ture in tlt~ final pt.1-t
was 0.33%. 11. Z. Katuich 2
00
so

Igo*

&JETALLURGICAL LITER&TURE CLASSIFICATIC01 I
Z-
~ too 0
xv~ 1- I.;w

t Sencial -A
Cv
"
0
is, 6.
4 4 . MCI to I KA
I
~

0
g go o 0 0

a 0 0 0 0 40 * 0 0 e 6 0 :
0 0 0
0 s, Ir
0 0 0 a a 0 a 6 a a 0 0 9 : : a ,
0 0 0 a 4 0 0 ow 0 0 a 0 4
O 0
: : :1 : : : 0

A
Oil
'ygen" " Indledurf In lislotoge"O"
M Kaf lachen arA A. ~11. Rcmn. Voililstly AW. Ndai
S.-iST. TI* (slit of 0111cKw-
I-m-Al"I 411" Ilse rat'lly-t fly the eqchimiffire 111VOIss + MO14
JsIIs1'*144IIIV-li44IVsI In 3 fr1WtflM4, 1,S) file-
Iss"r timit'liql"'I .4 111 IAI 40,1. PINII.. 41114110. It 'I'allor,
(6) mi'lation 14 C( I on *Ali, is ) 'ItISY11111164114 10011 oll
Crit), M + AWN M~~ tw on lusofin, fit all 3 miles untitr
thre VIN1111041914, fly 11, Ifelm, no the lls() ifiledly Pruilutrof
in rtact6,114 4 and 1, fir that 9111,111441 fly talwilsm) oillob fit
of the CO, prosiuc"I in reaction 6. Whereas IrworpmV
tim -( 011 fly thr above exchange iv emy. jorsto pankWarly
I.-I (rqutt. m4rhef tit I wv.) with Nlln(h. the exchange
, ~, 0 M011 , I I/" (k-,- I. M014 At fma Ilkin RX), was f
~.Oy, ,.Akvrwu), ex(VI)t on Nltlth~ The Isinto. of W-
incorporated in the vatalysts were. (a) In quarts, 5. in
gling, FCA. and dunite. I+-IT -y/g., (b) 167-251) -r1g. too
data for C). In all 3 reactions, siginificatit amts. of 014
were found in the products. That this RION is formed -
prinurily. not by the wconday exchanp MOJI + RIO'%
waildemonstrated hypammiltor Ifroommecatal"t.whkii
rrsulted only In very ilight enrichnietit In O'll. It follow%
that fruction a (at 4tX")O*. time of contact 0.6 me.) In- 1111
volves direct participation of The catalyst which andertion
AltstmOna reductim by fit and reasidstion by Ot. Th.-
,otmt applies to mcilort b (at 2110-21W)", time of Contact
IA-4.0 -m.), ritchangr between btn% and CO, takes -
I~U,v at aA 4- to V"I'. with Air tially at stout 2W.
Vtw react"i c (34'0-47.0% (fine of contart 0.&" mv.1,
direct participathm of the cutalym was denzatmirated by
colsurwilson Clf thtd. of 11,0 prMilce'l III p,&RAW V. I
with 011-entiche'l and nonenrimil.0 Catalls-lb. 12) Z, I
C-StAlysto were fountl His" 11) 1XIII)II, the IrtmS. (di
I )IS, In I he Wile "r-l" (If
IfOll + 'A OV ;71 111001 1- rl I
,4clivitietax In MIC 'nil ran be
-atalyred In 3 waya. either by a "Itt,drale" "whAllitm
whPitill III" nirl4l "Ithle "till 160's And the g-
ijitills hy,11%)SIA10 V�d14114- W, With Oil, 'K he
An .. allyliTn" l1whallimit Ifil'.1vtfill (mumli'm ml -1,
.4, olmeVol with 41 Cuo.,,Ijalyo, Intelivskled
14fiff.. by tr1w.1104 Uthl"Will
for the 111011 + MOA illid
With Itto, This Passivat"I ctuslyst still rel"Al-V41 Arlivis
in the exchange d; it aho Proved to have 2 high Activate"
4claitlition caluk,ity for Ot. This trPr tof Pureir ad~wls-
live rxelmnior cutAysto. invislyinit no rhern ImPlIrl lion
at the CAtA)Ylt. 6. hOWtVTI`, not general. It, Ilarimt.,
it could am be Irealissid with MnOj which always is Itself
9 iuvolvrd In a cosen, -reution - ?Ano# is also co"wracte"ad
by & very low setivatico enctly for d. 7 kcal./mole as
against M for CUO. N. Than
01
r.4-

ogyv, a"", bt-..n " "UIYAU I" wata
Tap" NI X 6'. slid k. M. R-en. VokWY
.1 kad: rW-;71-7 szsoilw); 'I. C.A. 44, qlTe.-
Na . .. .. - I
tat oackles Ato and
Iltate, .1 .,hanx- III oll bet.ectl me difeetior, 3.11011 +
b`Ah ill the forward -0011 by
ig, + ll,w, &fill Ill tile reverse dif
ul- cAkitent in the it3itial and tile re-
ef%% 11.). On a ~:rp, 1j)"i. + AIM
acled Iy) (by the to N, vA on p-anutated
W-, contact on active AIA- MttC
tile i3 charactertmi by a sharp sIGwtng (town
cuo. the excit; a qualli-equil. and
with pro~grrmlng _At,,., resulting 'in
ce,,satkit,.of further exchange at 8 conai4crallte
!4actical In of Olt between the
16tanct from the truc equil. disttibutkul
- With tizing te P., the rate of ex-
,,,Ll,lc still the val-ll conu-4
still the quiMi-equil. . clowr to the
change . of excitlivige .4 (ratio
true equil Thus, on MAI. the degm
il-, in -, per a. 0- AM of its
vi the actual riersl, ontc1l. 44 U And Will was Z), 30,
,quit conell.) attzi~cd at -2to)", 400, hod in W)
and V:i was r" -
rest).. alld At im", A
colallilt-tely 114td. with Ou in 1) 111111. at
MoO, wits Active contact. Cuo. A - 45', at
With the lc-t IiAlilln Of the contact time
(in Cr,01 If" of the pej~ts by 2
a I
to 2.3 still If a 11clitattoll
I tt I'll 1.1 h. 111.11 t . IIAIIA, I lin'l III, iMl 1.6 1-
.1; Consequently. diflUN1,01 I% not (Ate-drtil. The c-,atiom
of the exchange at a callsidrralde dWance froni the rqud~ I.
L-1111411k4l by t6 khwiLl 1",,tude.Av J tl--..t-i
with only plart tol the 0 Atiattil of [tic owille estuh1v ol %.
chinge. In the lwk exchatile. all the excvsq 03ittitt-luced
was given up. i.e. the back exchange procredi to coniple.
tinit. However, only the 01, introduo-d III tile "tile. oc at a
I Ywer temp., was given tip in the back exchange; thin. ff"
14
111roduccil Into the inhIr at 411)* wax not onvapirtely al,vt
up At WK)". but only at 44N)*. Activat"i cticig" I.- cal 1.
front the recilwocal times uccr_~ary to attaiu a st .1 of
were: active AIO,, A - 5, ~0
:0)"; E - 1.75. 1.
kcal./mole; ignited A]rO,. A - 2. 4l7;, F - 2.9. 4.8; CrA
+ AIA, A m 4, 10~;. E ~ 2.3, 11.0 kcid.irnole. The in.
crease of E with A is very nearly linear, as in Activated ad.
ion on uniformly betirrogetatints surfacts. The same
k2tic equation. dAldr - ie-OA. where r - length of
time of treatment, applies to both Activated WISKI)tiOll AtId
to Olt exchange. This is demonstrated by tile linearity of
A as a function of tile. in forward and III Imck exchange oil
active MO& and on C
ai oltr~Ztlitkll
2
r
topk exchange and act plau,ildr .111 ac.
count of the large sp. surface area of the o%idei
sq. m. '9.); one cc. III the oxide can be rrpfr~csitrd by a film
about, w,
I nim. thin, all(] difluiioti across such a filut would
require t"lly 14) 1 mv., as cottillaral with tile dtiratlint 14 Oil,
eXPIN, Of ~119) 11111). Oil the 0thVf 1141111. d(AiVAlt4I 111110111-
ti,in involvell Ill.. line unit. of hulk -rptillu. N. I hot.

UstbitAp bAitterg"
Oxidto and UqWd w#W1 likohol,
Auid le-
MVI"A-,6 R 11M and A. M. Rotten
y A Zed"rasub S:S,. J.-Kaw
is, 79. 2W-42(19,50), d. C.A:
1110M)AWeld backez we forward Mae + 1410to - mole
dululge(1110 +HOn,,%ION+ 10+
Uquidifft0andmeWolid"Sto.at. H 0)
werv obeer"red with A CrA.AhOj talyiet temp..
(a dehydration tal ) CA
yst , "live Zito (ghte, Udye AhOg
catalyst), and 524 As delelydrittion
Xd; the rates of exchange an lower
I' witie H-0 VZP t higher, t.X , a.
iquid 1110. The oxides . a Prelftice Olf
excle"It P&Wbly eTwently all- hydi'llitts. and the
Proceeds Ovtr foreseallm and decomien. Oll
hydrai to Shnilar exchienav was also observed between the
M oxidn anti liquid HtOll or AcOll; this I% taken to
inged
icate "Vate (Ormati(An with thew. oxides even at foom
'elop. Nck exchange twtween a tagged oxide and ga-irms
of wild obs"ll,rd. with %inCh At its low as 704W, CaCU~
At 360% V#00 fit AM'. and isith natural ductile at W)".
The "3ult with MnO, 6 in condicl with I'Alorits WA. 34,
2Z173) who found beginning exchange onl)r at 3MI. On
CuO, exchange L- uniniiiakible at R)O*. arAin in conflict
%iih M.'sconclasimi of af~rncr of nit r%chantie. Kineticallv.
the anti. cxchaogrd, Aith ritlicr 11,0 vatetv or jr-A.-ou, 01.
6 prol,orfionAl to the log of tiller; at the %duse stage. CX.
change with 0, is lower Than with 11,0 vapor. In a flow
.Item, the exchange is detectable only with outruriently long
-
contact tittles T; thus, between CuO and Ifff) Y;apor or Ot.
the min. r required is 3.4 and 7.6 we., rmp. Itispossible
that over very locis times, 0" exchange between in oxide
4 ' kt be etertable even at rmu ttrup.; the well-
an am wou d
known difference of the Old content of natural water and air
might be due to sueb an excheingt between CaCOI aud air.
The qu"tion whether traces of IIP in the oxide am nect*-
dairy fur the Old exchange between It and 01 (or air) is still
open. P41lurt by VAIJUS111CID 41111 Turovskil (VA. 44
71310 to det"t exchAnsv at VW on Met% dried at W
may be due to either the drying or rlde to partial didiewn.
to %InA which could be tantamount to kedes of J%W The
If the cittalyik activity
of an uxlele Is cleamtettlerd by the lowest temp. at which it
Is able to catalyze it" milelation, the order of activities of
Mn(h (rum t6sup.). VA &nit CUO
of-
coincideee with the order of mchange o(Ota with (h
The tau tk- act I Ity of are 0141C ~olr .16dation is, cotiw-
quen fly, irliked wlyth file M011111tv All lid 0, 14. The)-

MMICb0datry - catalysts 21 NOV 51
0278921 Exchange Between Alcoba Vapors and DWw-
azziian Catal7sts'" S. Karpachava.. ~- _RoZen
"Dok Ak WwA SM" Vol No 3, Pr 425P W
Zz prev ou vork it was shmm that the 018 in ac-
tive oxides in capable fj exchange vith water vapor
and certain liquids. 01 was introduced into the
catalyst (A120 ). Alcoholic vapors lst at 2000,
and then at E20 were passed over the ca.Wyst- The
oxygen was exchanged from the catalyst to the alco-
h4ic vapoas 2-3 times faster than in the came of
vILter. At the lower temp, the exchange passed
through 2 stages: 2.st there vas a decona of the
ale a's a result of the formtion of alcoholates;
then a decompn of the alcoholates back into the
Cri
products .(ale and A120 S' -4 lar expts
at W 20'iinp
were carried out over abromalindnm
and zim ozide. Dehydration resulted from the Ist
2j, and dehydrogenation from the 3d. It Is airbain
that all catalysts used form intermediate conSdo
vith ale, whether there in debydraticm or not.
2AT19