SCIENTIFIC ABSTRACT KATORZHNOV, N.D. - KATRUS, O.A.
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CIA-RDP86-00513R000721120011-6
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RIF
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S
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100
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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3/183/6,x/000/001/001/004
B101/B186
AUTHORS- Sheyn, T., I., &atorz*hnov, N. D., Kudryavtse,v,.G. I.
TITLE: Fraotional~compositiqh of polyamides synthesized at an
interface under. static conditions
PERIODICAL: Khimiabeekiye voloknal no. 11 196~0 17-19
TEXT: A film formed at the interface of sebaoyl diohloride dissolved in
chloro benzene and hexamethylene diamins dissolved in water oontaining
NaRCO This was drawn out without mixing the solutions, and its
3~
fractional composition was tooted. Polymers with a degree of polymeriza-
tion (DP) between 87 and 143 were obtained by changing the concentration
of the sebacyl dichloride from 8,to 10% by weight,,and that of the hexa-
methylene diamine from 1 to 5% by weight. Comparison-with the fractional
composition of polycaprolactam pol.ymerized in the melt showed that the
DP covers a wider range on interfacial polymerization than on melt
polymerization, but the fractions-with a DP of 50T200 predominate in
both polymers, The interfacially polymerized polymer is characterized
by.fractions with DP up to 600, but the content of highly polymerized
Card 1/2
0/001/001/
)/183/63/00 004
Fractional composition of polyamidee ... B101/B186 .
fraction (DP>200) is only 18-19%. The maximum on the differential curve
lies at lower DP for the interfacial polymer than for polydaprolaotam.
Similar results were obtained by comparing the interfacial polymer with
polyhexamethylene adipic amide,produoed..by thermal polymerization of AR
salt.. P.olyhexamethylene adipic-amido'had an average DF of164. 'with a-
maximum at--DP-105, thile t,he.respective values for the interfacial
polymer were 143,and 75- Conclusion: Interfacial polymerization at first
proceeds irreversibly at a rate.oorresponding to the range of ionic
reactions, go that no secondary reactions occur. After formation of a-.
--monomolecular layer, the,rate of polymerization depends on monomer a
diffusion through the layer. Due to the changes.in concentration, the
rate of diffusion finally becomes commensurate with the rate of termin'a-
ti n. The
0 polymer chains formed in the last stage therefore dif4W:.;.-.
fer 13~6m,thosd formed initially. There are 2 figures.
ASSOCIATION:. VNIIV
SUBMITTED:, -March 41 1969
Card 2/2
s/oai/63/ooo/ooi/o6i/o6i
B144fB166
AUTHORS: X&t!j ~hnov ~pN._R. p voitelev p Yu e. A.., Biber B. L.
TITLE: Rapid imethod for differentiating-polyamide fibers
PERIODICAL: Referativnyy zhurnal. Khimiyal-no it 19639 5660 abstract
iT295 (Tekstilln. prom-at', no. 8, 1962, 72-77)
TEXT: Improved schemes and rapid methods are suggested for determining all
known-polyamide fibers (including Enant and Pelaigon), based on
analyzing their solubility in different solvents, Methods are
recommended for the qualitative and quantitative determination of
Caprone and Anid fibers mixed with cotton, wool and viscose staple fibers.
~bstraoterls note: Complete translation.]
Card 1/1
VOITELET, Yu. A., alldsbiy nauchnyy sotrudnik;-UTQW.OOV, N. D.
Quantitative analysis of synthetic heterochain fibgro. Tekst.
prom. 23 no.3:72-80 Mr 163. (MIRA 16:4)
1. Vessoyusnyy nauchno-iseledovatel'Bkiy inatitut iskusst-
vennykh volokon (VNIIV) (for Voitelev). 2. VaelmlInik
laboratorii Vaesayuznogo nauchno-issledovatel'skogo instituta
iskasstvennykh volokon (for Katorshnov).
(Synthetic fibers)
(Chemistryl Analytical-Quantitative)
KAT,ORZIRIOV, Pikol VOITELEV, Yuriy Aronovich;
VERBITSKAYA, Ye.M.,, red.; PYATNITSKIY, V.N.., tekhn.red.
[Identification of synthetic fibers; qualitative and
quantitative analysis of syntbWc fibers-in the textile
7o inftetry] Raspoznavanie khimichaskikh volokon; kaebes-
Lvennyl i kolichestvennyi arelizy khi;aicheskikh volokon
v tekstillnoi promyshlennosti. ..Monkva, Gizlegprpm, 1963.
107 p. (MIRA 16:12)
(Textile fibers, Synthetic-Analysis)
KLIMVA, V.S.; KATOtIZHNOV,,. N.D.; KUDkYOTSEV, G T.; BEWEASTNOV, AN.
Rapid method for the simultaneous determination of the honoi*r and
moisture content of pblycaprolactam. Khim.volok no.6:64-65 163.
(MIRA 1731)
1. Vsesoyuznyy nauchno-issledovateltakiy institut iskusstvannogo vo-
lokna.
KATOR711NOV N.D.; V01TELLV, Yu.A.; PROSYANIK, Yu.V.
- 2 - .. .
Regulator3 of the molecular wei~iit of polycaprolactam and action
mechanism. Khim. volok. no.6:23-26 164.
(14111A 18:1),
1. Vaesoyuznyy nauchrio-issledovatellskiy inatitut iv~,uBstvenriogo
volokna.
YEGORMI, Yu.A., YAKI;POIJ, KATOHZIINCV~ l).D.
Maniifw~tlire of pipos vith a grijill. Khim. vollok,
no.41-..67-68 164. (.MIRA '~S-4)
1. V,2asoy-uzllyy In,-,tLtiit
voloknn.
KATORZHNOV,, MZMA, Ye,F.i LAZUTKII'll'i, T.F.
SrlldY~ng the contlinuovs proces5 of the Production of poly-
CLI-proll-av. Khi-,n. volok. 165. OCIRA 18%8)
1. 3esoyuzzyy npii--hno-ia,.,;Iedcvatellrikiv instittif. Aski--sstvennogc
v c. kr a ,
SAJO[IJOVSKIY. N.L.; YKVSTHATOV, Y.F.; SHIRNOTA. L.A.; KATOV, V.I.
Evaluation of the wear resistance of tread rubbers through
the testing of tires in actual service. Kauch.i rez. 19
no.1:10-15 Ja 160. NIRk~ 13:5)
i
1. 11auchno-issledovatel'skly Institut shinnoy -romynblennost.l.
(Tires. Rubber--Tooting)
Y
MS~M/Optics - Optical Methods of Analysis. Instruments. K-7
Abe Jour Referat Zbur Fiz"Lka, No 5, 1957, 13107
Author Katov, Ye.I.
Inst
Title Spectral Investigation of the Interaction of Benzidine
with the Surfaces of Bentonite, Alumo-Silica-Gel, and
Silica-Gel.
Orig Pub : Optika i spektroskopiya, 1956, 1, No 4, 500-5o6
Abstract : The absorption of adsorbed molecules of benzidine and of
their transformation products an the surfaces of bentonite,
alumo-silica-gel, and silica-gel in tho region of 2500 --
10,000 A was measured in diffusely reflected light with a
SF-4 spectrophotometer. Several types of interactions bet-
ween benzidine and the surfaces of the adsorbents were ob-
served:. (1) Physical adsorption (maximum of absorption at
300 A). (2) Forms,104on of an intermediate ion fH_2N 06HO
06H4)-W~27+ (maxim 4500, 76oo, and 8500 A) upon
Card 1/2
KATOVSKIr., 1. [Katouskj, 1.] (Vchtmroye otdeleniye Gorki,
Mfiiislavskogo rayolinj
A letter carrier. Rab. i sial. 39 no.9s8 S 163.
(WRA 16 -11)
KATOWSKI, ~ao, mgr.
Undertone in* the prognostic index of the freight market. Tech
gosp morska llno.3:74-75 161.
1. Wyzsza Szkola Ekonomiczna, Sopot.
XATRAXOVA, 0. S.
'";
Method of paraffin therapy. Mod. sestra. Moskva No.1:31-32 Jan 521,
(CLHL 21-4)
1. Nurse. 2. Of the Sanatorium Iment Semashko of the Therapeutic
Sanitary Administration, Ministry of Pablic Health Ukrainian SSR.
KATRANI)ZHIEV, 1.
Investigation on antagonistic effect of Bacterium bulgaricum and
Streptococcus thermophilus on Mycobacterium tuberculosis. Izv. mikrob.
inst., Sofia 2:117-145 1951 (CLML 21:3)
1. Doctor, Specialist of the Main Veterinary Hygiene and Control
Institute, Sofia*'
KATRANDZHIEV, Kosta, D-r., starshi nauchen sutrudnik
Activity and variability of Bacterium bulgaricum and Streptococcus
tharmophilue in cultures invarious tOMDeratures. Izv.mikrob.imet.,
Sofia 5:3ul-378 1954.
1. Pri N. 1. V. Kh. K.' r. - Sonia.
(LACTOBACILLUS,
bulgaricus, eff. of temperature on activity & variabil-
ity)
(LACTOBACILLUS,
thermophilus, aff. of themperature on activity & vari-
ability)
KATRANDZHIEV.. K.
"Microbiologiaal studies of raw cow's milk in the berdika Milk Combine." I~T-t-
IZVESTIIA. SERIIA EKSPERIMENTAL4A BIOLOGIIA I MITSINA,, Sofiiap Bulgaria,
No. 2. 1957.
Monthly List of East European Accessions Index (EEAI).. The Librsa7 of
Congress, Volume 8. No. 8. August 1959.
Unclassified
Ff?Atl 1) 7HIE-V
BLMGARIA / Microbiology, Sanitary Microbiology. F-4
Abs Jour: Ref Zhur-Biol., No 16, 1958, 72053.
;,uthor "atrandzhiyev, K.; lotov, Y.; Ikonoraov, L.; Tod-
orov, -jj--
Inst :Not giv;n.
Title :Comparative Morobiological Investigation of
Cowl s Hilk.
Orig Pub: Solskostop. misol, 1957, 2, No 10, 630-633.
i,bstract: No abstract.
Card 1/1
BULGARIA
.fAffiliation not givenI
Dr Kosta KATRAIIDZIIIEV
IlImpressions of th,2 Zooprophytactic Experiments). InstiLlItes ir the
Regions of Lazio and Toscana in ltaly."
Sofia, Voterivarna Sbirka., Vol 39, No 11, 19621 pp 24-26.
Abstract; be5cription of the study and research activity of the
institutes in question, -mainly of the central institute in Ro-me-Cappanole
directed by Prof. Zavalli. Names and tasks of principal investigators
are listed with brief coments. Photograph of building, architectural
plan of virology laboratory.
DESHKOI Yu.I.; KREYEM., M.B.; MAKHNOVIGH, A.T.; KA-IWI I G.
red-.TSBZR=EVT,-N.V.,
tekbn.
spetsored.; TABMINA, M.A,p tekhn.
red.;TMIKMAfYe.L.., tekhn.red.
Naterials,on accident prevention and industrial hygiene in
the building materials industry]Sbornik matorialov po tekh-
nike bezopasnosti i proizvodstvenuoi sanitarii v promysh-
lennosti stroitellrqkh materialov. Yoskva, Gosstroiizdat,
1962. 634 p. (MIRA 15:3-1)
(Building materials industry-Hygionic aspects)
XATRANOVA, X.Ee, vrach
A remarkable case of compensatory adaptability in a blind man vithout
hands* Ofto,2hur, 13 no.5:303-306 158 (MMA 11: 10)
I* Is Ukrainskogo teentrallnogo nauchno-isaledovateliskogo instituta
ekspertizy tradosposobnosti i organizataii truda invalidov,'
(BLIM-PRIMING, M WRITIM STSTM)
(AKKrMS--PMABILITAR ION, XTC.)
SHIATEN, S-P.; KATRANOVA, K.V.
Otogenous psychoses. Voot..oto-rin. 17 no.5.'44-47 S-0 155.
OILRA 9 % 2)
1. Iz Vinnitskoy polkhiatricheskoy bollnitsy iment A.I. Tushchanko
(konsulltant oto-laringolog B.P. Shlayen, saveduyushchava
psikhlatricheskim otdoleniyem X.V. Katranova)
(PSYCHOSES, etiology and pathogenesis,
ear dis.)
MR, diseases,
causing psychoses)
ACCESSIM NR: AR4015141 S/0124/63/000/012/VO53/VO55
SOURCE. RZh. Mokhanikaj, Abs. 1ZV410
AUTHOR. Natranovap L.A*
TITLE: The determination of critical stresses for a noncentrally stressed -bar
from the condition of local. loss of stability
CITED SOURCE: Nauchn. tr. Lordn .gr. losotekhn. akad., vy*p. 102, 1963', z57-264
TCPIC TAGS: critical stress. non-central comprossions local stability loss#
stability loss
TRANSLATION: To test the stability of the elements of a non-oontrally stressed
fl-bar, the authorused the energy method along the length of the bar botwoon
diaphragms. The stress-strain diagram of the material in the intermediate sea-
tion between the proportionality limit crn and the yield point O~ follows a second,'
degree parabola. It is assumed that the packets of vertical shoots in the cross
sections between diaphragms in the transverse direction bond as cubic parabolas,
the packets of horizontal shoots in the transverse direction bond in one or two
Card 1/2
ACCESSION NR: AR4015141
half-waves, while the potential energy of banding deformation of each of the
In
side corners is determined as for the bar. By 64gating the potential energy of
all the elements to the work of longitudinal for6es with the loss of stability,
the author obtains':an oquation which est6lishefthe dependence of the critical
stress 6, on the length of the half-wave S, Tdl.find the least value of the
k-o
critical'Strossp the author reconmends the construction of a supplementary.d.-
P . kp
graph., Q*X* Chuvikiiie
DATE ACQ; 3lDoc63.: EXCL: 00
SUB CODE: PH,
FITRANUSKHOV, T.
Katrarmakhov, T. Amtomiia na durvoto; uchebnik za I kurs na gorskite tekhaikumi.
Sofiya (Narodna prosveta) 1952. 104 p. (AnatorW of wood; a textbook for the first
course of schools of forestry.)
SOs MOlMW LIST OF EAST EUROPEAN ACCESSIONS, L. C.0 VOL. 3, NO. 1, Jan. 195.4, Uncl.
K!,mVUSTTxOVp -
"Gorsko zakonoznanie za V kurs (VIII 1,:1.) np. Cors'din tokirm1kimn. Sofiya
(Narodna irmsveta) 1,954'. 16C' P. (Legislation on forestry; a testbook for t1he fifth
course in the teclmicql. scbools of forestry.)"
-4
SOt East European, L. C. Vol. 2, No. 12, Dec. 1953
I'A T R ANI)SHKOIV,A, N.
STO-1 Mlifff.
of trjxOjjja!;mcsis. Akusb, ginek. (Sofija) 4 no-4:258-266
165.
1. Nauchno-iz slad ovate I ski Institut po &kusherstvo I ginekologiia,
.'-,'cfiia (direktor: doc. E. Svetc6lavova).
KATPW,'USIIY,OVA. V. DOTSEVA, S.
Some studies on UtriuJai:--i~ r,f tl.e gmitaliu. Plwtifi. ginuk,
(Sofiia) 4 no.lz/+')-53 165.
1. llauc~mo-izsledovatolshi institu-11- po 6-nsheistvo i gir,(-kc--
(Direkior: dots. Br. Papazor).
KATRAYFVA, A.G.
Disorder of depth vision in schizophrenia. Trudy Gos.nauch.-issl.
inst.psikh. 27:101-107 161. (MIRA 15:10)
1. TSentrallnyy nauchno-issledovatellskiy institut sudebnoy
psikhiatrii imeni V.P.Serbskogo. Dlr. dotsent G.V.Morozov,
1-ye otdeleniye Nauchnyy rukovoditell prof. S.F.Semenov.
iSCHIZOPHRENIA) (VISION)
; f,
11,
of e'cp1h percept,lor, in schizophrenia patlonts,
wrobl. tv,O. ps.il%b. no.13sI36-14) 162s (mr.RA 18i9)
c3untry BULGARIA
C C. tor Chemical Techn
Pood Thch-,sbry ology. Chenic-al Pvoducts (FS-rt 3).
Abs. Jour. Rof Zhur-.Mi.-Lu, 1959, ITO 7, 2521b.7
Author Katrayn,.!.
Inf."t Itut.
T Itl Introduction of a New Technique in the Cannl-ng
ind,astry of Rumania
OriG Pub. Ml-lardt- PrWl-st, 3.9-58, 7, No 3, 10-1-222
Jkbstract No abstraot.
Card:
p-
KATREG inzh.; KLIMKGVSKAYA, S.S.p tekhn.
I-
Austenite electrodes with decreased toxicity. Svar, proizv. no.9:
28 S 165. MIRA 18;9)
1. Kharikovskiy zavod transportnogo mashinostroyeniya im.
A.A.Malysheva.
SEMIYENKO, N.Ye., inah.; KATRECHKO.. V.1., inzh.; YMOKIMOV, K.K.p inzh.;
LIMARENKO, D.G.,- -
Utilization of'the slag crust from welding fluxes in automatic
welding. Svar. proizv. no.4:31-33 Ap 163. .(W.RA 16:5)
1. Zavod transportnogo mashinostroyeniya im. Malysheva.
(Electric welding) (Flux (Ybtallurgy))
KAnYAM,Xj~6ABAT'YB,, F.., ptitsevod (Ybnpel'ye, Frantaiya); AXOPOVA, X.P.
Ltrans~atorl
Practices in changing some hereditary characters; some interestIng
obGervations made on domestic fowl after the transfusion of blo6d
frvin a different breed. Agrobiologiia nO.1:10,rp~-107 Ja-F "63,
WIRA 160)
1. RukovoditQll tekhnicheskoy laboratorii pri Oblastnoy
veterinarno 1 boratorii, Mionpellye Frantsiya (for Katrefazh).
(Heredity~ a (4~Dod-Transfusionj (Poultry-Physiology)
LIBOR, A.P., doktor geologo-minerolOgichookikh nauk; YAPIYAVTSITA.A.T.;
WaRMKO, A.Y., redaktor.
Mat st6nes can tellj 0 chem rdiskazyvalut kamni. Moskva, Goo. izd-vo
takhniko-teoretichookoi lit-ry. 1953. 53 p. (Nauchno-popullarnaia
biblioteka, no.65) A 7:7)
(Geology)
KATRENKO, Dmitriy k1gkonvich, alIRNYAGINA, Alekoandra Andreyevma,*
M-TANTS, I.L., akademik, nauchro7 red.; KOR14IWVA) M.I.p
red.; SHIKINI S.T., tekbno red.
[Science outstrips fancyl.Nauka* obgoniaiushchaia mechtu. Ito-
.skvap Izd-vo VTsSPS Profizdat, 1961. 204 P. (MIRR 15:1)
(Syntbatic products)
VEDERNIKOVPMikhail I-vanovich; RUDOY, Ivan Vasillyevich; KATRENKO D A
nauchnyy red. ; LYAKHOVETSKAYA, T. Ye.,, red. A. M.
tekhn. red. . --t.1
[operator of compressor and pumping machinery in the chemical
industry] Mashinist kompressornykh i nasosnykh ustanovok khi-
micheskoi promyshlennosti. Moskva, Proftekhizdat, 1963. Y74 P.
(MIRA 16:9)
(Chemical machinery) (Compressors) (Pumping machinery)
KU2NET!56
_V, Vladimir Ivanovich; ARBIJZOV, A.Ye,p akademik, otv, red,;
KATMKO, D.A.., red.
[Advames in the field of oata3yti'c' bi~ganic synthesis]
Razvitie kata~iticheskogo organicheskogo sinteza. Mo-
skvap Naukap 1964. 433 p. (MIRA 17s12)
USIX, Gavriil YevtikhiyevichfUsyk, ME.), kand. sellkhoz. nauk;
BUZANOV, I.F., akademik, red.; KATRENKO K A . red.;
POMTSKAYA, L.A.[Pototalka,
(Biological principles underlying the cultivation pactices
for tomatoes In Podolia] Biologichni osnovy agrotekbniky
pomidoriv na Podilli. Kyiv, Derzhsillhospvydav URSR, 1962.
103 P. (MIRA 16:4)
1. Vsesoyaznaya akademiya sellskokhozyaystvennykh Siauk im.
M.Lenina (for Buzanov).
(Podolia-Tomatoes)
BUGDTSKIY, Aleksey Andreyevich(bjh~talkyi,, O.A.], kand. ekon. nauk;
ROMANENKOO I.N., prof.,, otv, red.; KATRENK01 K.A-, red.;
LAPCHENKO, K.P., tekhn. red.
[Production coat of grain on collective and state"4w in
the steppe zone of the Ukraine; statistical economic studies]
Sobivartist' vyrobnytstva zerna v kolhospakh i radhospakh
atepu URSR; statystyko-ekonomichne doalidzhennia. Kyiv, Der-
zhoilho-spvydav URSR, 1962. '129 p. (MIRA 160)
1. Chlen-korrespondent Vsesoyuznoy akademii sellskokhozyay3tyen-
nykh nauk imeni V.Z[.Lenina (for Romaneako).
(Ukrain~--Grain-Economic.aspects)
VOLISKIY, V.G.[VolIs'Ryi, V.H.], kand. sellkhoz. nauk, red.;
LISIY, G.B.[Lysyi, H.B.1, red.; UMEVEO, K.A., red.
[Specialization of agriculture in Gli~aM District;
western forest-steppe] Spet5ializatsiia sillskoho hos-
podarstva v Hlinianolkorm raioni; zalchidnyi bisostep.
Kyiv, Derzhsillhospvydav URfft, 1962. 159 P.
(1,1IRA 17:9)
1. Naukovo-doslidW instytut zeir-lerobstva i tvarynnytstva
zalchidn.vkh rayoniv URSR.
YUKH1MCHUK, F.P.[IUkhymchuk F P ], otv. red.; VISHINSKIY, O.M.
1Vys1Vns11qi, O.M. , red.: GOLOMBA, R.A.(Holombap R.A.31
red DMITRENKO, P.O.[Drqirenko, P.O.], red.; IL'YASHENKO,
M.GlIlliashenko, M.H.], red.; KOLOBOV, O.M., red.; -
KUKSIN, M.V., red.; LAZURSKIY, O.V.[Lazurs'kyi, O.V.), red.;
POPOV, F.A , red.; SAMBUR, G.M.[Sambur, H.M.], red.;
SAMTSEVICH: S.A.(Samtaevych, S.A.], red.; FEDOROVA, N.A., red.;
KATRENKO, K.A., red.
[Fertilizers and cultivation practices] Dobryva ta agrotekh-
nika. Kyivp Urozhai., 3.964. 16o p. (MIRA 17:12)
1. Kiev* Ukrainslkyi naukovo-doslidrqi instytut zemlerobstva.
BUCHIVSKIT, Ivan Yevatafiyevich; AgpiKO., -Yo.. A., red.; VIDOPYAK,
A.P., tekhn. red.
[Climate of the Ukraine in the past, present and future]
Klimat Ukrairy v proshlor., nastoiashchem i budushchem.
Kiev, Gossellkhozizdat UM, 1963. 307 p. (MIRA 17:2)
YJI'MiGH, A., avlatsil, Goroy Sovetakngo Soyuna, vcy;~nnyy
pervngo k2aeoa
Sh.ft at attantion --,- In.-trument flying. Air. i Rosme 4,8 ro,01:51-56
S 165. (MIRA 18:8)
KURBATOV, 111ya Dititriyevich;
SMGEYEVA, V.S., red.
[Business accounting practice within individual production
units of a collective fann] Praktika vnutrikolkhoznogo
khozrascheta. Moskva, Kolos, 1965. 189 p.
(MIRA 18:9)
vv
FTRJ cl;,. -1
ROZENBLAT, Gr!gorly, Boxisov,icb;.PODPRUZHIIIKU,-,'.., Vasiliy Ivanovich;
KICHKIN,-Viktor Vasillyevich; LOBAW04 Mikhail Petrovich;
KATRICH,, Aleksandr'Nikoleyevich; ZAVOZIN, L.P... ved. red.
[The USB--2m high-speed plow] Bystrokhodnaia strugovaia usta-
novka USB-2m. Moskva, Nedra~ 1965. 136 p. (113RA 18:8)
24904 S/18 611003100610011031
B102 V201
pe ;/*0 B
AUTHORSs Katrich, G. A. and Sarboy, 0. G.
TITLE:- Photoelectron emission by gold and chromium
PERIODICAL: Fizika tverdogo tela, v. 3t no. 6, ig6i, 1629 - 1637
TEXT: By way of an introduction, a very detailed discussion is offered on
some papers by Thomas, Mayor et al,. (H. Thomas, Zs. f. Phys, 147, 4, 395,
1957; H. Mayer, R. Nossek, H. Thomas. J. Phys. Rad. E, 204, 1956;
H. Mayer, H. Thomas. Zs. f. Phys., 147, 4, 419, 1957; A. Ebel. Zs. f. Phys.,
1471 49 465v 1957; S. Methfessel, Zs. f. Phys., 147, 4, 1957), which
contain reports on the photoelectron emission of potassium films; the
abovementioned authors have stated that photoelectron emissioz, Jn this metal
is of the volume type. The correctness of such a conclusion ap:.,e,.irs, how-
ever, to be dubious, and the problem of the nature of photoelectron emis-
aion cannot yet be considered as being definitely solved. The authors of
the present paper have therefore again studied the phenomenon of photoelec-
tron emission. They chose gold and chromium for their purpoces, because the
excitation energy of "plasmons" in these metals is considerr--bly higher
Card 1/4
24904 S/181/61/003/006/001/031
Photoelectron emission ... B1C2/B201
(> 20 ev) than the energy of photoelectrons in the spectral reCiQri concerne'--'
Photocurront:,. as a function of thickness were measured t.,L (_ ifferent light
wavelengths by an apparatus which is shown in Fig. 3. The film cf variable
thicknesses that were submitted to investiGation were sputtered onto a. mo-
bile quartz base (2) by a spherical vaporizer (1). The base could be either
arranged above the BaO vaporizer (5) or in front of the uviol glass w3rdows
(4) (for 11he purpose of photoelectric or optical measurement.-3). T'~'. fi In
was adjusted to the desired position by means of ruler (6) and iyO':cator (31
The residual gas pressure in the tube could be kept at 3 - 5-10- mm Hg by
the diffussion pump (7) and the barium getter (8). Both apparatus an~! :~,eth-
od have been repeatedly described elsewhere (cf. also C. "': 0 0 1. '_' ,. W.
k1lison. Phys. Rev. U, 247, 1950) Pure surfaces of the metal,.; concerned
were obtained by sputtering films upon metallic bagkings (tungsten7 or tan-
talum); here, the maximum pressures were at 5-10- (Au) and 3-10- mm Hg (Cr)
The effect of adsorbed BaO was examined first. The volt-ampere character-
istics obtained showed the maximum change of the thermo-electronic work funo-
tion, that depended on BaO adsorption, to be about 3.2 - 3.4 ev for gold and
2.8 ev for chromium. The effect of BaO adsorbed an Au and Cr films was
Card 2/4
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Photoelectron emission ... B102/B201
considerable in some cases; the effect was not- restricted upon the work.
function. In case of thicker BaO coatA'ngs on 1w films the characteristics
had fully'the appearance of J3aO characteriatict-.. For gold, the'quantum
yield of photoemission was larger compared with a pure metal surface even
with a reduced work function for hvw5ev. The vork functions of pure metal
surfaces amount to 5.1 (Au) and 4.4 ev (Cr), the work functioni for an
optimum BaO adsorption on the,film amount to 1,8 and 1#7 ev, respectively.
A study of the photocurrent as a iunctioh of thickneg; showed the gold
photoeleotrons to come from a depth