SCIENTIFIC ABSTRACT KAZANSKAYA, I.I. - KAZANSKAYA, L.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000721310018-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 13, 2000
• Sequence Number: 18
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

137- 58- 1-667D
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 1,
p 103 (USSR)
AUTHOR: Kazanskaya, 1. 1.
TITLE: "An I .. st'iggatio, ~intoo 7tee MM~ajor Parameters of the
Process of
Rolling Round Periodic Sections on Three-high Mills (Issle-
dovaniye oanovnykh parametrov p-otsessa prokatki kruglykh
periodicheskikh profiley na trekhvalkovykh stanakh)
ABSTRACT: Bibliographic entry on the author's dissertation for the
degree of Candidate of Technical Sciences, presented to the
Tsentr. n. -i. in-t tekhnol. i mashinostr. (Central Scientific
Research Institute for Technology and Mechanical Engineering),
Moscow, 1957.
ASSOCIATION: Tsentr. n.-i. in-ttekhnol. imashinostr. (Central
Scientific Research Institute for Technology and Mechanical
Engineering), Moscow
1. Rolling mills-Mathematical analysis
Card 1/1
,i_
"711 A /V .~ A- A PHASE II BOCK EawITkTION 494-11
Smirnov, V. So; Anisiforov, V. p,; VasillchikOv) M- V.;
Granovskiy., S. P-;
Ka ~r .; MekhOv: N- V.; pobedin, I. So
'~ka~,.~ Kuzmin) As Do in the Machine -building
v masbinostroyenji (Cross Rolling
poperechnaya Prokatka 4,500 copies print0a,
Industry) Moscow, Mashgiz, 1957. 375 P-
Ed. (title page): TselikoY, A. I., Corresponding Member, USSR
Academy of
sciences, and ftirnOvi V- So,, Doctor of Technical Sciences;
professor;
Ed. (inside book): Kamnev., P. V.s Ed. of publishing House:
Leyklma) To L.;
Tech. Ed.: Sokolova) L. V.; managing Ed. of the Leuingraci Branch
of
Mashgiz: Bol'shakOv) So A-, Engineer.
INTRODUCTION
11 and hel,jcal cross-
In this book, vhich is devoted to the study of crossurstrying
rolling processes in the Soviet machinl-b"11diU6 , the ,u aulthors
discuss
principles, theory, and echnological
very sZFatematicallY and in detail the periodic
aspects of rol.1 forming Of balls and gears as well as the rolling
Of
shaped stock
Card .1/30

Cross Rolling in the Machine-building Industry 494-11
The terms cross rolling (poperechnayEt PrOkatka) and helical
crOOS rolling
(poperechno-vintovaya prokatka) require a brief explanation
here. By cross roll-
ing,, the Russians understand a rolling process in whieh. two
pexallel rolls re-
volve in the same direction, their longitudinal axes belng
parallel to the axis
of tho. work. The term helical cross rolling denotes a
rolling operation between
cone roUs, the axes of which are slightly inclined to
opposite angles, thus
producing a helical advance of the work. Die rolling in this
case is a special
type of helical cross roUing in which helically grooved rolls
are used, instead
of plain tapered ones, to produce shapes such as balls.,
rollers, annular shapes,
periodic profiles, etc. The rolling of bearing balls Is said
to have already
replaced the ball-pressing method in the USSR, increasing
productivity 2 to 7
times, and saving 10 to 25 percen4, in expensive 9-Uoy
steels. Gear rolling is
reportecl to be a current develolment project in the USSR.
Rolled gears are said
to have been successfully produced to grade 3 accurw-y with a
grade 7 to 10 sur-
face roughness. Methods for determining rolling forces,
stresses, torqueo and
power, based on modern concepts of the theory of plasticity
and strendta of
materials, are discussed, and formulas derived. AU the
methods involved in
these rolling processes are discussed with great clarity, and
case histories and
specific examples are included. According to the authors, the
mechanical
Card 2/30
1~
Cross Rolling in the Machine-bi-LidLng Tna,-stry 494-11
properties of press-forned parts cvr c%f pw.-4,-Os
mo~rjh.L-ted from periodl:: roUpd stock
are considerably higher than those made f rm 1ou-,tmt.1Ozv_l
p3 rolled stock,
not t0 mezktiOn A 20 to 30 percent saving in mete_,Jal.
The develoinent, of the theoretical. pr1=i]pO_es ", thO
teaUllv3logics:1 prxesses
of cross roUing and helical cross rolling in the USSR is said
to ha-ve been
carried On intensively since 1942. The tha,-q7 vr,.s
developed by V. S. Sm4moy
On the basis Of experiments cOndUCted at the Urallskiy
politek1xn:1aheskJy imLstitut
(UrLI POlYtecbnIc Institute) and later at the Lenin&-&JskJy
pa7,1tekbn_t__hesk:Ly
'nBtJLtut (Leningrad FOlytechnic IhBtitute), The develoPment
of ma,,,hinery &-id
egu#ftnt for cross rolling and heliqsl cross rolling ws
superfisedby
A. I. TselikOv at the TsNIITK4Bh (TSeAtraltnyy
nauchno-iseledovatellskiy institut
tekbnologii i mashinostroye-niya - Centr%l Scientific
Research Institute of
TechnO30gy and Machinery), Scme OanlUne-bL'Uding plmts, e.g.,
the GOr'XQVBkiY
e'VtOmObil'nY7 z&vOcl (GOr'l--4Y Automobile Plant), have
deveJ.oped cross-r,)1'U,1g
mills of their own desiga. The acMtetts of this book axe
I-evievied be-low.,
ebapter by chapter.
Card 3136

AUTHOR: Kazanskaya, 1. 1.
S/775/6Z/002/000/004/011
TITLE: Three-roll mills for the rolling of variable- section
rounds.
I
SOURCE: Avtomatizatsiya protsessov mashinoetroyeniya. t. Z:
Goryachaya
obrabotka metallov. Moscow, Izd-vo AN SSSR, 196Z, 166-170.
TEXT: The sole practicable process for the rolling of rounds
with longitudi-
nally varying cross-section is the cross-helical rolling
method developed under
the direction of A. I. Tselikov, corresponding member, AS
USSR. The method
saves thousands of tons of metal and is fully automatable. The
three-roll mills of
TsKBMM (Central Design Bureau for Metallurgical Machinery, now
V-NIIMetMash
or All-Union Scientific Research Institute for the Planning
and Design of Metall-
urgical Machinery) differ from other helical-rolling equipment
as follows:
(1) Three narrow conical or disk-shaped rolls operate against
an axial pull applied
to the billet, thereby exerting a deformation on a small
portion of the billet and
avoiding the usual defects engendered in cross-rolling; (2)
the roll spacing is
altered by means of 3 hydraulic cylinders actuated by a guide
-profile -follower
control. Conical rolls are used for a diametral reduction of
up to 2, disk-type rolls
serve in reductions of up to 1.6-1.7. The disk rolls simplify
the mill design, shorten
the leading end of the billet, and permit steeper transition
from one rolled diameter
Card 1/3

Three-roll mills for the rolling of variable ...
S/775/62/002/000/004/011
to another, but consume more power. The "Mark 7011 mill set up
at the MZMA is
used as a specific example. The billet is heated to
1,100-1,?OOOC, inserted into'
the inter-roll space, grasped by the puller, and
simultaneously set into rotation
by the radially approaching 3 rolls. The puller advances, and
the 3 rolls (mutually
linked to ensure concentricity of the resulting billet
rotation) are pressed together
andmoved apart in response to the guide -profile -follower
control. A pneumatically
lifted boat receives the rolled billet and, upon release and
issuance, lowers it to an
inclined table. All operations are automated. The TsKBMM
developed 6 types of
industrial mills for this type of variable -section rolling
with diameters up to 10,
20, 50, 80, 120, and 220 mm. Seven mills of the first 4 types
are engaged in actual
production work, 5 at the Kolomenskoye plant for textile
-machinery building, 1 at
the MZMA in the production of automotive semiaxles, and I at
the plant imeni
Dzerzhinskiy in Dneprodzerzhinsk. Advantages of the process:
(1) 10-3016 reduc-
tion in metal consumed per unit acceptable product (in
comparison with forging;
example illustrated: Moskvich camshaft); (2) possible
reduction in *machining time
because of reduced machining allowances; (3) reduced workload
on forging presses
and hammers; (4) improved microstructural quality, finer
grain, and higher
fatigue strength, notch toughness, and plasticity, of the
resulting shafts; (5) fle)d-
bility of equipment, since a change from one profile sequence
to another entails
merely the replacement of the profile guide raU; (6) high
productivity, with a
Card Z13

Three - roll mills for the rolling of variable . . .
S/775/62/OOZ/000/004/011
billet-delivery rate of 3-5 m/min, which corresponds to a delivery
of 65 railroad-
car axles per hr, as compared with only 50-70 axles per work shift
delivered by a
forge; (7) suitability for total automation. There are 3 figures;
no tables or
references.
ASSOCIATION: None given.
Card 3/3

KAZANSKAYA, 1,1., kand.tekhn.nauk; PANFILOV, M.G., inzh.;
~PrOLITOV, V.I.
Causes for the appearance of defects in helical-cross
rolling
of circular periodic shapes. Stal* 22 no.9:824-826 S 162.
(KRA 15:11)
1. Vseso~mznyy nauchno-isaledovatellskiy i
proyektno-konstruktorskiy
institut metallurgichemkogo mashinostroyeniya.
(Rolling (Metalwork))

DU L~ K 11! 1 . ; "A A."I , Ye I.; , I .
'ty of xylaing fro;.-, the mrface layer's of rrtir.
~'h~lr.
, I '-
- ! ';~ -!P:3)
!~:*;-,.. 3~* no.J.:2;11-2.'~2 Ja 165.
.~l -1. ,
1. teKhnologicheskiv institut imeni IA-):.aoiiosovn.

MEDVEDEVAt Ye.I.; DUDKINO M.S.; KAZANSKAYA, I.S.
Amino acid composition of some types of vegetable raw
material
not used as food. Nauoh, dokl. vya, shkoly; b1ol.
nauki no.41
140-1U 164. (KRA 17t12)
1. Rekomendovana karedroy organicheakoy khimli
Odeaskogo
tekhnologicheakogo inatituta,

EXCERPTA MM1CA Soc,14 Voi.~?/5 Radidloey 1by 195,9
822. "RIEC66NI~ION OF ;~/0'7LIOSIS IN 9'CHOOLCIIILDIIEN BY
MEANS OF FLU-
OROROENTGENOGRAPHY (Russian text) - K a z a n s k a y a L.
D. VESTNI.
HENTGENOL. RADIOL. 1956, 6 (46-50) -
720 cases of scoliosis were diagnosed among 10.000
schoolchildren from 19 schools
of Yaroslav by means of fluororoentgenography. Of those 720
cases, 325 (45.170)
were in children 7-10 yr. old. In addition to the routine
antero-posterior fluoro- i
roentgenogram of the chest, postero-anterior pictures of the
lumbo-dorsal seg-
ment of the spine were also taken, Somewhat harder rays (85
kv. . 25-30 ma.) were
used and exposurje time was 1-2 sec.. with holding of the
breath. The automatic
postural correction of functional scoliosis precluded its
diagnosis by fluororoent-
genography. The diagnosed cases were classified according to
direction, local-
ization. configuration and degree of the scoliosis, Ist
degree scoliosis.being de-
fined as deviation from the perpendicular of less than IV.
and 2nd degree more
then 10*. The f luororoentgenographic data so obtained were
found to '~ orrespond
closely to data obtained by goniometry in a group of 100
children. Fluororoentgeno-
graphy was found to be a useful procedure for the early
recognition of scoliosis
and for the control of treatment by remedial exercises.
Chair of Roentgenology and Radiology,
Yaroslav Med. IneD. and Yaroslavskoy gorodskoy
Flyurograficheakoy 8tantsi
(zav. L. D. Ka m skaya)

KAZANSKAYA. L. , Cand Biol Sci -- (diss) "Phosphorus
metabolism in
-k-k
ii~e_o~_to_g_en__esis of spring wheat." Leningrad, 1960. 17
pp; (Ministry
of Education RSFSRj Leningrad State Pedagogical Inst im A.
I. Gert-
sen); 250 Copies; price not given; (KL, 29-60, 125)

RMSKAU, L.N.
Dynamics of nucleie acids and other phosphrous-bearing compounds
in leaves of the Mamant" wheat during its ontogenic development.
Is,uch.dokl.vys.ehkoly; biol.nauki no.2:153-157 160. (MIRA 13:4)
1. Rekomendovane. kafedroy fiziologii rasteniy Laningradakogo sell-
skDkhozyay,Itve=ogo instituta.
NEW (PHOSPHORUS MIMOLISM)
-5w
a"'MitM A
T
A
me

UMSKAYA. L.N,
Using the radioisotope of phosphorus in studying
phosphorus
metabolism in the ontogeny of spring wheat (Triticum
vulgare Host).
Bot.zhure 45 no-7tlO55-1059 Jl 160. (MIRA 13:7)
lo Ioningradskiy se`l'skokhozyaystvenny7 institut, g.
Pushkin.
(Phosphorus metabolism)
(Tracers (Biology))
(wheat)

KAZANSKAYA, L.N.
Phosphorus metabolism in the ontogeny of spring
wheat. Fiziol.
rast. 7 no.2:234-237 160. (MIRA 14:5)
1. Leningrad Agricultural InstituteOL-eningrad
Pushkin.
(Wheat)
(Phosphor6a metabolism)
(Ontogeny (Botany))

KAZANSKAYA, ;Tudmila Nikolayevna. kand. biol. nauk;
YEGOROVA, A.G.,
iTe-d.-; F!~-kdkk D-,'----~e--d.'izd-va-, BELOGUaOVA,
I.A., tekhn.
P *P..q
red.
(Chemical nature and possible ways of improving the
taste m-A
flavor of bread ]Kbimi chaskaia pAroda 'L vo=ozIuVe
puti uluch-
sheniia vkus~ i aromata khleba; stenogramma dokleds,
prochitan-
nogo v LDNTP ra seminare rabotnikov khlebopekarnoi
prorVr,.hlen-
nosti. Pod red. A.G. Egorovoi. Leningradj, 1962. 50 P.
(MIRA 1599)
(Bread)

YEGOROVA, A.G.; ~~KAXA,_L.N.; LORANOVA, A.Ya.;
MELIKHOVA,
Z.V.; BESPALOVA, 1.0-0; SHCHERBACH, V.A.
(Using the new yeast and lactic acid bacteria
strains in
making tin rye bread] Prigotovlenie rzhanogo
formovogo
khleba s primeneniem novykh shtamwv
molochnokislykh bak-
terii I drozhzhei, Moskvak TSentr. in-t
nauchno-tekhn.
informataii pishchevoi promyshl., 1963. 28 p.
(MI11A 17:9)

YEGOROVAI, A.G.; KAZOISKAYA, JMIDT, Z-1 .; NA
A31ir
[flew strahis of' lacti- li~+I bat-,,oi-ia '-,V
IfjnV(-n )-T4jjja-
rationj liovye obtariq i 1:~lyxh bal:
rz'r,.arI.ykII
P.Ishclievoi yroiiyaha., J4 p.

L.N., BESPUDVA, G.I.:
sp(ii.s. red.
(Use. :)f E~quld Anterit-odlate products, ArL the
making of whoat
flour br6na] Primone-nio Llij(ik-,kh
poluCabrikatov p.-I prc),,z-
V. o
vodotv,~ pohonichurykh sor-Lciv kideba. ,ikvap
TSont.r. !T,.-t
nw,- hric. -t ek1,11, A n! rmats 13, prorrWohl.
)03. 3~1 p.
1, TRA 1 EJ,
t
I H

L 2847--66
(t)/10P T"P lj-.:, Z~
(b)
YJWIJDIWB 64 r,
ACCESSION NR: AT5022891 UR/2776/651000/04310081/0098 -evi
Shchegoleva R. P.; Reutova, H. P.; G aya, V. L.;
AUTHOR: olubeva, L. S.; Po2kaysk
_qY' vi- qr, i
Kazanskaya L. N.
TITLE: Powdered-metal stainlespehrome and chrome-nickel steels
/SOURCE: Moscow. Teentral'nyy nauchno-isoledovatel'okiy
iA-stitut cherm-nn
ak~Ptallurgii. Sbornik trudov, no. 43, 1965. Poroshkovaya
metallurgiya (Powder metal
~ 1-
, urgy), 81 8
T -
TOPIC TAGS: powder metallurgy, stainless steel, chromium
steel, nickel steel, i
corrosion resistance
ABSTRACT-. It is shown that the powders of stainless chrome
and chrome-nickel
steels in the ferritic, austenitic, and martensitic-aus
,*nitic classes, prepared
by the method of the combined reduction of metal oxideiLty
means of CaH are
suitable for the industrial fabrication of porous and compact
sheets ani'strips
by the direct method of powder rolling. The flowsheet of
production of these
powdeTs has the following sequencet raw materials -- iron
powder (carbonyl and
other types of Fe), chromium oxide (Cr203), nickel
(electrolytic, carbonyl)
card

L 2847-66
ACCESSION NR-. AT5022891
powder or NiO, Ni 0
2 3, calcium hydrido (CaH2); charge blending (2.5 br);
reduction
at 1175*C for 6-8 hr, Cr203 + 3CaH2 all 2Cr + 3CaO + 3H2;
crushing of sinter;
slaking with H 0 and pulverization; hydrocyclone treatment of
pulp; leaching --
2
0
Ca(OH)2 + 2HCl - CaCl2 + 2H2 ; washing to remove CaCl2;
centrifuging; vacuum
drying, 60-70*C. Sintered stainless isteels display high
physical properties,
which warrants recommending them for the fabrication of the
elements and devices
2
performing in aggressive media. When pressed under a pressure
of 10 t/cM and
subjected to deformation and heat treatment, powdered-metal
stainless steels are
not inferior to steels produced by the smelting method 9
regards their physical
properties and corrosion resistance. Thus, for
example,Ablorrosion tests of
5 ttainless austenits steel in. a 65% solution of boiling EN03
.vLY,h!�Bl demonstrated
the high corrosion strength of this steel, not inferior'to
that of deformed cast
steel (corrosion rate 0.1-0.16 8/m2-br). Evidently these good
qualities of pow-
dered-metal stainless steels are attributable to the low
content of impurities
in the powders prepared by the combined oxide reduction
methodo Orig. art. has:
10 figures, 9 tables.
ASSOCIATION: none
Card 2/3
7
-M
R S,

L 2847-66'--'*"
ACCESSION NR.
SUBMITTED.- 00
NO REP SOV: 007
[Cord-

ACC NRi AR6035416 SOURCE CODE: UR/0137/66/000/009/GO23/GO23
JILUIEOR: Shishkhanov, To So; Rabinovich, Ye. M.; Kudinova, K.
Go; Sariadi, F. So;
Kazanskaya, L. it.
iTITLP: Reduction of titanium-hydride with increased hydrogen
content
!SOURC*E: Ref. zh. Fietallurgiya, Abs, 9G167
IRE?. SOURCE: Sb. Proiz-vo atall i splavov i vliyaniye obrabotki
na nikh uvoystva.
T
lula. 1965. 31-35
I
I-OPIC TAGS: titanium compound,
I metal hydride, chemical reduction, hydra- 1
tion .i
ABSTRACT: Titanium powder reduced by Ca. hydride (IMTU 987-63),
titaziium sponge TG-00
produced by a maGnesium-themal process (14WU-14 no. 19-64), and
electrolytic iron
produced by the method of dissolved anodes, were all hydrated
with 11 of 99.99'/t' purity
containing < 0 0030P of 02 and < 0.2 g/m3 of mj-'sture. Tile
optimal hydration condit-on
was determined: non-ly hydration temperature 6500, soaking at
this temperature, flow'
Of H of 8m2/hr until the end of absorption, and cooling in air
at a flow of 11 < 0.5
3/h2
M r. introduction of these conditions in industry has ensured
production oF
titanium hydride with a stable hydrogen content of 3.8 - 3.98%,
and has improved the
productivity of the plant, At Shmeleva, [Translation of abstract)
SUB OODE:
Card i /i
11, 07

ACC NRt
AR.700-1851 SOURCE CODE: UR/0137/66/000/010/GO32/GO32
AUTHOR: Kudinovj, K. G. ; Kazanska n L N. ; Rabinovich, Ye. M.
Korchagin, MI. I.; -ki _y, e. N.
Mishnayevs
TITLE: Investigation of possibility of coarsening the grain size
of titanium
powder by gas absorption
SOURCE: Ref. - zh. Metallurgiya, Abs. 10G230
REF SOURCE.- Sb. Proiz-vo stali i splavov i vliyeniye obrabotki na
ikh svoystva.
Tula, 1965, 50-53
TOPIC TAGS: titanium, titanium powder, grain size, reduction
ABSTRACT: Titanium powder with a grain size of 45,zi-has the
optimum gas
absorbing capacity. In order to coarsen titanium powder by
reducing titanium
oxido with calcium, a finished powder of titanium metal with a
grain size of
10.,~4 was added to the charge as the finished crystallization
centers. By
adding up to 816 titanium powder to the charge, the yield of the
coarse-grained
fraction of the reduced titanium increases up to 48%; further
additions of titanium
C,rd 1/2
r-A
2/2
UDC: 621.762. 2.( -1:669. 295

-Inzhe
Air conditioning of capran faptoriese Vod. I san,
tekhe no~9:L6-
20 3 165, 18191),

XALZAWSKATA, Li 5 1
Basic indices of air-conditioning systems for public and
municipal
buildings. Vod. i san. takh. no.12:20-24 D 158. (MIRA
11:12)
(Public buildings--Air conditioning)
(Municipal buildings-Air conditioning)

ROMANOVSKIY, LIPMANUVICII, S.G.
Outcome of labor complicated by anomalies in its
intensity for the
mother and fetass. Vop. okh. mat. i dot. 6 no.10;58-63 0
161.
(14IRA 14: 1-1)
1. Iz kafedry akusherstva ginekologii (zav. - prof.
I.I.Yakovlev)
I Leningradskogo moditainskogo instituta imeni almdemika
I.P.Pavlova
(dir. A.I.Ivanov). -
(LABOR, COMICATIM)

!*1111*41 soot 0*0 0*0411004

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ellmlivrly frjt1&vtNI fly Ill%()#. %live

nietals (%if undye

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t

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ows, O(Scuvo 110. A F., it IIVA"V.

E&MIKIT, L.I.; KAZANSKATA. X.Te.,
Colorimetric analysis of stable diazo salts aad
solutioas. TekstiII.Prom.
12, No.11, 37 '52. (MIRA 5111)
(CA 47 ao.22:12131 '53)

1, 11 KI Y , L. T . , K C,'- KA Y A , 14 . Y2,
Sodium I~Y:'Iosulfl a
hydro3ulfita, Tql,-st. prrai. 1~, P,). 6, P,-5"
New metha~l of
I-Inathly Mqt of' RiiqF;Iri.,4 Ancessints, LibrRry of
Gougress, October 1952, Unrlw3ified.

A 'JA, M.;. BIRLEINKIJ, L.
U ZAN iKA
I
ControUiq processes of dyeing with vat dyes. Tr. from
the Russian.
p. 144
Vol. 8, no. 5, Sept./Oct. 1954
PRZEffSL *4LOKIENNICZY
I,od-z
:30: Monthly List of East European Accessions (ERAL),
LC, Vol. 5, no. 2
Fob. 1956

tl'A W,W inall-od for the avlrj,?I~a it'll '10W,
:17, 1 TI I I%. . lF.I I I I
it O~rhi,fl-w
o; lat LINt.., ziii;!1;ib (so thr w%, Asm~j
C. 1. ISU, 10!iJI ill Ill-t'l[A or I- !,7111~ i-.q re.
C-tlll fo 1vq,)Ttlsv-!!ic add oll'i ~mlillol,-~wiii,
vitili! the
ii, ~iti'ii-l tv Nal A lfwotw-l awt. tit tbt-,
izi smIJA 1") a iflown vol, (if la !~") r, e1.-Att. 4
flir, ti)-c' Ilse, r1l'.1vithin 1'!ATq7 lo 60m:11 thid
011i- IV,! 1, ill
r:~. Alipr ilir on-hr,,:! A:,; Rtxl ii
with fln~
1IN sar lircolt in -Iht -Irl- it i2
!Tt~.!. vm ~Wg. Intl t--Aj~ 1 1 isn; I
fstw Id I't iv~v. I iv! 'n, z w i t 1; it 1 1'. hr. if,
aylsili a-,lur
ti -1 by ti)t m%lilol'

ICAZANSKA'~, M.,&-
Control Iw! TAt dveing M. r Ka~an-
Pe"ald. Prom 1). 2, ~
-4(l V31 Cf.
h-The vnl-dyeing (I or 2 pliase) can he
ciontrolled by dttg. NaOlt, Nal(Soi, and thiz dye eqnc!i-. in
the leuco sola. or in the swpcoslon nod the aint. of the dv-r
on the fiber with the help of it pl-intoch-c rolorinieter, poten.
tiometric tit it sill invur.
W

N <
BELENIKIT, L.I.; DZMXAYA, M.Ye.; IDILMOV, V.S.; YUROV, S.G.
%-W"WAWAW"ft*WWW.-aW
Testing the whiteness of fabrica with a FT-1 textile
photometer.
Taket.prom. 15 no.4t43-47 Ap '55. MU 8:5)
(Photometr.v) (Textile fabrios-Testing)

VC
Y PRIKIAOr'Ko, A-F
YP
'9
240) 3 MASS I bOOX IXYLOITATION BCT/1365
L'Yov. univerartat
INAteriftlY X VsQsCyuzwgj savashch#Alys. pa spektroem*pti
t. is
.
Holskulyarnare srfIiCt:%'0"PlYA (Favors of the IM All-Union
Conference an Spsatr3stopy. Vol. li Iblecular Spectros-opy)
IL'vov) 10-wo Wrovitfo AMY-t,%. 1957. 499 P. 4 000 Goples
printed, (3orism ftzychnyy abirAyk, Vp. W)
Additional Sponsor% Agemays Akademlya nauk 333R. Xoalasija po
spektroskopli. s laxor, S.L.1 Tech. td.i Saranyuk I.V.1
Editorial Boar4i Lacylaterg, 0.3,0 Aoadqedolan (Map. 6., Deceased),
Neporent. B.S.. Dootor at Physlaal and Matheutical Sciences,
Fab*llnakly, I.L., Dootor or Physical wA mathezatiova Soleness,
Jlab.~. V.A.. D"tor of Physical wd Xithematida.1 SaLencea.
Xormit%vU, V.O., CarAldata of Too,%udoal Sciences, Ptayakir. S.M.,
CarAidato of Ft4sd4a! ayel Kathematival Science lalmovskly, L.K.,
Candidate or PhIstial &:-.J Mthertatleal Sdi.nca:: millyanahuk,
V.3..
CuAidato of Ph7sl4al P--A rial.'Amatical Salenoos and Glaubersm,
A. TO.. Cardidate or Phys-'aal and PAthavAtical Sciences.
Cam 1/30
Bobushkin, A.B., A.Y. vv&mv. and L.A. Ignat'j-9va.

Infrared
Spectroscopic Study of the Adsorption

w4 Surface Reactions or Ithyl
AM Nothyl Aloobals

an Alwilnum Wds
161
31dorov, A.N. Study of
Adsorption on Porous 02&88

by Xoana of Infrared Absorption Spostra
161
b4lanIkly. 1-1. N- X4&_A&g&A&W&_At al. Spectra-

photamistria
Study at Vat 3019
170
Sidarov. T.A.. and N.A. 3-bol-v- Isotopic Shift
In

th Intrared Spaotrm of Soria Acid, and Its

34mature
176
N. 3pqtm and
TautOvArism or Aoylated
5hernker. Yu.

HOWN00,Tal 0 ARiM 0
,
180
rostovskly. 1. Y& Yu. w. aheyn"r, and X.P.Kazarinows.

fteatrobooplo ;w; of 9-oiWarIlvarldims
183
Card

A
BBIRNIKIYI L.I.; (~ANSKATA/,M.Te.; YAVORSKIY, B.M.;
KAKMINTSKIT, V.D.
S-oectrophotometric analysis of leuco eaters (with
summary in
English). Zhur.fit:.khim.31 no.7:1564-1572 JI '57.
(MIRA 10:12)
1. Inetitut khlopcitato-bumashnoy promyghlennosti,
Moskva.
(Bliectropbotometry) (Esters)

-YjVZA, USYY
"Work in the Field of Dyestuff Absorption Spectra."
report presented at the Section on Colloid Chemistry, VIII
Mendeleyev Conference of
General and Applied Chemistry, Moscow, 16-23 March 1959-
(KoLl. Zhur. v. 21, No. 4, PP- 509-511)

BELENIKIY, L.I.; BROMEERG, T.V.; W
,LAEFAYA, M.Ye.
Spectrophotometric method'of quantitfLtive analysis
of the
interaction between dyes and textile %'fibers.
Nauch.-issl.
trudy TSNIKHBI za 1958 g2115-123- (MrRA 1611)
(Dyes and dyeing-Textile fibers) (Spectrophotometrr)

BEIENtKIY, L.I.; BROMBFRG,, T.V.;-E~ -~--Yee
Radiochemical oxidation of vatsol dyes.
Nauch.-isol.trudy
TSNIKHBI za 1958 gxl23-1" . (MIM 16 sl)
(Dyes luid dyeing-Chemistry)
z
F W -0

so,~76-32-6-5/46
j~.UTHORS Berpz3,ri, 1. V~i KaZdnskaya, N. F', lweluzova, Go B,
TITLE: A Method of the Quantitative Analysis of Cyclohexanone and
Cyclohexanol in Oxidation Products of Cyclohexane by Means
cf Infrared ~,bsorution SDectra (Metod kolichestvenaogo
analiza taiklogek8anona i tz;iklogeksanola v produktakh
okisleniya tsiklowek!:ana po s;iektrum pogloshcheniya v infra-
krasnoy oblaisti)
FERIONCAL: Zhurnal fizicheekAy khimii, 1958; Vol. 32, Nr 6, pp.1218-1225
(USSR)
ABSTRACT: A method of analysis serving in a number of kinetic investi-
gationp was developed. An infrared spectrometer of the type
IM -1 Nith automatic re,I,ording equipmen' EPP 09 and with
cuvc-Etes of special construction was used. A description
of the apparatus and a st.,hematic figure are given. By making
use of' the different intensity of the spectral banda the
analysis could be conducted in such a way as to determine
ketone and alcohol in the cHme cuvette, which is important
Card 1/3 because of t!ie small nmount of sample substance. The
determina-
s

3OV/ 76-32-6-5/46
A Method of the Quantitative Analysis of Cyclohexanone and
Cyclohexanol
in Oxidation Products of Cyclohexane by Means of Infrared
Absorption Spectra
tion of the concentration of the substances was conducted
acoording to the law by Lambert-Beer, employing the-ex-
tinction X higher concentrations of alcohol
the sampie had to be diluted. A ccmparison of the results
obtained with that of othor methods showed that the
determina-
tion is not disturbed by the presence of peroxides. On the
other hand, a ketone. is present in the rample, the cyclo-
hexanone- The presence of other oxidation products does not
disturb its determinption;. A hydration is proposed in order
to prevent an increase of the results caused by the influence
of substantial amounts of asters and acids. In order to be
able to determine the estor content, the extinction coef-
ficien' of the oarbonyl band was approximately determined,
as well as of the mono- and dicyclohexyl esters of adipic
acid. The analysis as to contents of ketones and esters in
the oxidation mixture can only be conducted at optical densi-
ties below 0,3, where the spectrAl bands separate from each
other, in case they are present simultaneously. There are
Card 2/3 5 figures, 4 tables, and 8 referenc6_a,, 4 of which
are Soviet.

SOV/ 76-32-6-5/46
Math-d of the curtitntivp ~.nalysia af Cyclohoxanone an,!
Cyclohexanol
in oxi~ltition I-Toductq of (!yrionexine b;r Mears of
Tnfrared Absorption Spectra
Voskovsk~~r gouuniveraP-et im. M. V. Imonogova
1AT Toll.
(Moscow Stnte 1Tn1.-.-er:,.1ty imeni 11~4 V,. loironosov)
J RM ITT!~':, - I-"P1D!a.,rhPr iA. 19--f,
1. Cyclohexanones-Quantitative analysis 2.
Cyclohexanols-Quanti-
tative analysis 3. Cyclohexanes--Reduction 4. Infrared
spectrum
:~rd 3/3

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KAZANSKAYA, N. F. Cand Chem Sci -- (diss) "Stu4y ofIkB
conversions of intermediate
- -1
t, J-
products during the oxidation of oyolohexane in i~ liquid
phase." MOB, 1959.
C j4"It
10 pp (Mos State Univ im M. V. Lomonosov. Chem Facii1ty.
Chair of ~1~
Kinetics), 150 copies. (KL, 41-59, 103)

5W SOV/2o-126-3-38/69
AUTHORSt Berezin, I. V., Kazanakaya, N. F.
TITLEs The Sequence of the Formation of Products in the Case
of the
Liquid Acidification of Cyclohexane in Steel Vessels (Posle-
dovatellnost' obrazovaniya produktov ~ri zliidkof-xznom okis-
lenii tailclogeksana v stallnom, sosude
PERIODICALi Doklady kkademii nauk SSSR, 1959, Vol 126, Nr 3,
PP 594 - 597 (USSR)
ABSTRACT: It is said in the introduction that the essential
part of
the products of the acidification of hydrocarbons is formed
by
the decomposition of h:ldrogen peroxide. A acheme is given of
a-possible acidification of cyclohexane in the liquid state,
after which a method is suggested for the synthesis of a
radioactive hydrogen peroxide of cyclohexyl. This method is
explained on the basis of the aforementioned scheme. The
general
radioactivity of the product is given in formula (1) as a
function of molar radioactivity, and by formula (2) the time-
dependent variation of radioactivity is given. From these
formulas, formula (5) is then developed for the rate at which
Card 1/2 the molar radioactivity of cyclohexane increases.
The experi-

The Sequence of the Formation of Products in the Case of
BOV/2o.126-3-38/69
the Liquid Acidification of Cyclohexane in Steel Vessels
ments were carried out in a steel vessel at 140 0C and at a
pressure of 10 at, and figure I shows the curve of the
products
in dependence on time. A further diagram (Fig 2) shows the
variation with respect to time of molar activity, and table
I
shows the rate of the formation of alcohol at various points
of time. Finally, the obtaining of oyolohexanyl is briefly
discussed. There are 2 figures, 1 table, and 10 references,
6 of which are Soviet.
ASSOCIATIONi Moskovskiy gosadarstyenny-y univeraitet im. M.
V. Lomonosova
(Moscow State University imeni M. V. Lomonosov)
PRESENTEDt Janaury 29, 1959, by N. N. Semenov, Academician
SUBMITTEDt January 27, 1959
Card 2/2

5(4),5(3) S 0 14' /2 0 - 13 3 //(1 2
AUTHORSi Barezin, I. V.,,_ Privalov, V. F.
TITLE: Degenerate Branching Mechaniam on Liquid-phase Oxidation
of
Cyolohexano in a Steel Containor (0 makhanizme vyrozhdennYhh
razvetvleniy pri zhidkofaznom okislenii tsiklo-eksana v
stallnom sosude)
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 126, lir 4,
pp 809-812
(USSR)
ABSTRACT: The authors investigated the oxidation process of
cyclohexanone
durin~g oxidation of cyclohexane in the liquid phase. The care-
fully purified cyclohexane was oxidized with air under a pres-
sure of 10 atmospheres at 1420, 1500 and 1570 in a steel contai-
ner. In the reaction mixture, cycloliexanone, cyclohexanol and
hydroporoxide cyclohexyl were analyzed quantitatively Ref 2).
The kinetic curves of the products of oxidation at 150 and
those of cyolohexanone are C;iven in figure 1 at all three
temperatures investigated. After a certain time cyclohexanone
was added to oxidizing cyclohexanne the former of which was
marked by radioactive carbon in the carbonyl group. Subsequently
samples of oxidized cyclohexane were taken and after precipi-
Card 1/4 tation of cyclohexanone as 2,4-dinitro pheny1hydrazone
the

Degenerate Branchina "echanism on Liquid-phase, soll 20
Oxidation of Cyclohexane in a Steel Con.tainar
specific radioactivity of the latter determined. Or the basis
of the analysis results the authors suC-est the following
mechanism for the reaction inveatit;ated- The molecules of
cyclo-
hexanone are first attacked by free cyclohex.,Jporoxide
radlcalz;,
thus causing that a hydrogen atom in 0~-Positilzl to the kcto
group of cyclohexanone ir, separated-
0
1 .