SCIENTIFIC ABSTRACT KESSEL, A.R. - KESSENIKH, A.V.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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XESSIET It I A. R, Quantum theory of transionta in paramagnetic resonance (effective spin 1, equidistant spectrum). Fiz. tvar. tela 5 no.11:3120-3129 N 163. (MIRA 16,12) 1. Fiziko-takhnicheskiy institut- AN SSM, Kazan'. f-M -@-K Ih, N' NR: L uii4jlt7 i a - e a ft L. @116Z-66 KWT(d)IZWT(l) XJP(c) WWIGG IM NK: "bMUbi9 SOURCE CODE: UR/0181/66/008/002/0387/0396 AUTHOR% Kassel' A. R.; Korchemkinp M. A. ORG: Kazan Physkotechnkallnstitute (Kazanskiy fLz1ko-tekhn1che.skiy institut) 21, :TITLE: Theory of transtente In nuclear quadrupole resonance SOURCEs Flaika tvardogo tela, v. 8, no. 2, 1966, 387-3196 iTOPIC TAGS: nuclear quadrupole resonance, spin system, nuclear resonance, multiple' order 'ABSTRACT: Equations have recently been derived for extending the phenomenological I Bloch equations to spin systems with arbitrary spectra for the case of quadrupole ;and higher multipole Interactions. These 'equations may also be applied to solid paranagnetics. The authors test these new equations on a specific spin system chosen In gueb a w@W that It has all the Unit =@ti -NMeb Fevent tM use Of the iphenosenolegical, Bloch equations. Transient W are studied to quadrupole Mosarm of neclal In solids with zigard to GFift-spift and quadrupole IMOVIRCtIGM. jW0 lWtatifts an Igposed an the ey@tpy of the crystal field nor an the directiou 1@cwd 1/2 - ------------ ACC NRs AP7011829 SOURC& COD91 UR/0079/66/036/010/1835/18 -38 AUTHORt Nesterov, L. V.; Kess*'l#q-A,-Ya- CRGs Institute of organic ard Physical Chemistry, Academy of Sciences of the USSR, VAzan# (Institut orgenichoskoy i fizicheakoy khtmit AN SSSR) TITLE: Reaction of salts of aromatic quasiphosphonium bases with ortho esters of carboxylic acids and acetals SOURCEs Zhurnal obshchey khimli, v, 36, no. 10, 1966, 1835-1838 TOPIC TAGS% acetal, carboxylic acid, organic salt, reaction mechanism, ester SUB CODE: 07 ABSTRACT: Salts of aromatic quesiphosphonium baaes were found to react with ortho esters of carboxylic acids and acetals, exchanging a phenoxy group for an alkoxy group. The reactions were conducted between methyltriphenoxyphosphonium and methyl- phenyldiphenoxyphosphonium iodides as the salts of aromntic quasiphosphonium b6ses and triethyl orthoformate, triethyl orthoacetate, and dimethylformal as the ortbo. esters and acetals. The zleaction mechanisms are discussed. The ortho eaters and 0 acetals behave as weak nucleopbille reagents in these reactions. They are in- sufficiently active to attack the neutral phospborus atom in triphenyl phosphite, Card 1/2 UDCs 547.269118+547.426.3 -- - - - - - - - - - - - - - - - - - ACC NRt LIP AP7011829 -rs and the redistribution reaction with ortho este ies, doei which does not Participate in in view Of its low nucleopbilic propert beating acetals- The ester metbYl fOrmte, even after many bouto Of gybionium iodide not react with methyltriphenOXY&O las and I table& 40035-17 orig.'art, heal, 6 formu in a sealed,.tub@ crd 2/2 MMSZLI, Y.K. ... In memory of V.I.Bobrov. Khirurgiia, Moak-7a no-4:81-82 Ap '50. (Gln 19:2) VOROI@TITMf, K.Iop inzhoner; IMSELI, ItY., inzhener; ORISHKIII, S.I., Ow inzhonor. Mechanization of tree felling, loading and hauling of lumber. Mekho trud.rab. 9 no,3t42-46 Mr '550' (MML 8:5) (Lumbering--Machinery) (Zree felling) MARKOV, L.I.j ISTOMINt G.V.;KRF.STIN, POLYANTSEV, V.A., red. [Guzeripli Logging Camp]Guzeripliskii lespromkhoz. (n.p.] TSentr. nauchno-iael, in-t mekhanizatBii i ener etiki les- noi promyshl. 1962. 5 P. IMIRA 16W (Guzeripll region-Lumbering) Oll ZOTOV, G.A.; BEREZIN, V.p.; SHALAYEV, S.A.; KESSEL19 I.V.; POLYANTSEV, V.A., red. (Olenino Logging Camp] Oleninakii lesopromkhoz. Khimki, TSentr. nauchno-isal. in-t mekhanizataii i energetiki lesnoi prompshl., 1962. 30 p (MIRA 16:4) (Olenino region--Lumberin;) KESSELI, I.V. - Preparation of chips in cutover areas# Bum,pro4. 38 no.1:30-31 Ja 163. (Woodpulp industry-Reoearch) (MIRA 16:2) VORDNITSYN, K.I.; =BL'j.I.V.; SKOTNMVA, N.V., red.; Central Scientific Research Institute on Mechanization and the @ se of Power in Lumbering]TSentrallnyi nauchno-issiedovateltakiy institut makhanizataii i energetiki lesnoi promyshlennosti. Mo- Avas 1962 ll a P' (MIRA 16:1) 1. Khimki,,1TSentialInyy nauchno-isoledovatellskiy institut mekha-' nizatoii i energetiki lesnoy promyshlennosti. (Lumbering-Machinery) XESSELI, I.V., lnzh. Lumbering machine units. Yokh.i avtom.proizv. 16 no.8151-52 Ag 162. (KRA 1519) (Lumbering-Machinery) "SUL, K. Dr nod. Leon xgaln&, 1893-1942 Chir. mars. ruchu ortop. polska 19 no.3:209-211 1954. (BIOGWM89 KalInal Leon) KICSSEL19 L.A. _"wa Using the heat from compressed air to produce distilled vater. Suggestion by L.A. Kassel'. Prom.energ. 11 no*7: 17-18 J1 156. (MLRA 9.'10) (Compressed air) (Water, Distilled) ij FV K 1 @S.-j EL Kescell, 1`- Zo - "Capacity and zoning of the Yr-,vpatoriva spa durl;i, .@s Ceneral L reccnstruction period, It Trudy ObIledin. nauch. soveta pri Upr. Yevpator. kurorta, Vol. VII, 1948, p. 7-13 SO: U-4355, 14 August 53, (Letopis 'Zhurnal Inykh Statey, No. 15, 1949.) NESSELIt N.K.; GVCHINNIKOVp E.V*j KUCHUR, Ye.S.- GALKINv P.A.1 MOLIBOSHKOp ----T d . P [Equipment and devices for assembling structural elements] Obora- dovanie i prisposobleniia dlia montazha stroitelIzUrkh konstruktoii. Minsk, Redaktsionno-izdatellskii otdel BPI im. I.V.Stalina, 1960. 48 P. (Building-Tools atd implements) (HIU 14:6) (Precast conorete construction) KESSELI., N.Ke.., dotsent,, kand.tekhn.nauk Dep&ttmeWlit Conatruction, Sbor.Wuch.trud.Bal.politekh.inst. no. 66:27-34 457& (141RA 16:9) 1. Dekani stroitellnogo fakulltota Belorueskogo politekhaichookogo instituta ijaeni Stalina. SAAKYAN, A.G.; KAZANCH-EV, M..; E--'SFL1,,. V.P. Ability of K-stroplanthin and calMun tc re.,-,ture t@,e a.-tivity n the frog's heart arrested by cortis(%nu. Farm. i toks. 26 no.2:206-220 Mr-Ap 163. (Y-,'@RA 17: 8) 1. Pyatigorskaya klinika Gosudarctv@3nnogo nauchnc-11stil-@-dr- vatellskogo ballneologicheskoPo institn+,j na Kavkaz3x-'kh Mineraltnykh Vodakh, XW=t V.P.- KUBASOVAI N.M. Aracbnodactyly (Marfan's disease)e Terapoarkhe noo8.*123-124 162. (KIRA 15s12) 1. Iz Pyutigorskoy kliniki lkltneologicheakogo instituta (dir. kand.med.nauk Ye.A. Shd=ov-Kamenslci7). (ARACHNODACTYLY) KES@Ml of the kX-irlen as a manifontaLlon of dis5eminated vancula.- difiensao Vest-ri. rtjn@. @ rild. 36 no.)@05-67 My-Ja 063, (MIRA 17:7) 1. 'f-, astrologicheskogo otdqlnnlya Pyatigorakoy klin-W Goisu- darstwinnogo ballneologich6skogo institut-i (dir. - kand. med. naulc Ye.A. Smiimov-Kamen3k@y) nit Kuvkazskah Minorallnykh Vodakh. KESSELIV fu.R. Subcapsular diphasic rupture of the liver. Zdravookhrunenie 6 no.3:58-59 MY-Jet63. (MIRA 16:11) 1. Iz Yedinetskoy rayonnoy bollnitsy (glavnyy vrach - I.A. Dimmd). PHASE I BOOK EXPLOITATION sov/3844 Kessellman, A.S. Tokarl-univereal v priborostroyenii (All-Round Lathe Operator in the Instrument Making Industry) Leningrad, Sudpromgiz., 1959. 254 p. Errata sUp inserted. 15.,300 copies printed. Scientific Ed.: N.V. Kashin; Ed.: V.S. Chiohkanova;'Teoh. Ed.: R.K. Taal. PURPOSE: This book is intended for lathe operators, machine shop foremen, and students of technical and trade schools. COVERAGE: Fundamentals of the theory of metal cutting, concepts of surface roughness and engineering measurements are given along with drawing standards used in machine building.. Modern design of cutting tools and other devices used in lathework in the Soviet Union and in other countries is described. Works of the Lenin- gradskiy politekhnicheskiy institut (Leningrad Polytechnic Insti- tute), the Institut tochnoy mekhaniki i optiki (Institute of Pre- cision Mechanics and Optics)., and the Institut aviatsionnogo pri- borostroyeniya (Institute for Aircraft Instruments) have contri- All-Round Lathe (Cont.) sov/3844 buted significantly to dev@lopments in the field of machining on lathes. No personalities are mentioned. There are 15 referencesp all Soviet. TABLE OF CONTENTSt Introduction 4 Cho I* Basic Technical Information Needed by All-Round Lathe Opera- tora 5 The concept of drawings 5 The concept of interchangeability, allowances and fits 13 The concept of surface roughness and methods of measurement 31 The concept of datum systems 38 The concept of types of production and the organizational s truc- ture of the manufaotaring process 40 The basic c oncept of measurements 42 Ch. II. Some Problems in the Theory of [Metal] Cutting General information 45 45 KESELIMAN, G.; LUKIN, N. Tower substation of precast reinforced concrete. Sell. stroi. 15 no. 2;12-13 F 161, (MIRA 14:5) 1. Nachallnik proizvodstvenno-tekhnicheskogo otde'ja Moskovskogo tresta "Seltelektrostroy" (for Kesellman). 2. Starshiy inzh. Moskovskogo tresta "Sellelektrostroy" (for Lukin). (Precast concrete nonstruction) (Electric substations) KESELIM&N, I.A., tekhnik Welding and strengthening the frame of a forging and die-stamping presse Ovar.proizv. w.7:33-34 J1 160. (MM 13t7) 1. TSentral'Mye eksperimentallzWye evarochWye masterWdye Vaeso7uznogo nauchno-iseledovatellakDgo institute. avtogennoy (Power presses-Welding) ZZ 6,11 @Wl KO Or KESSEL114AII L I.- YJIOCII, G.K. [Khoch, H.K.1 Attachment to the Clan3 27 button machine for the sewing of buttons with eyelet end. Loh, prom. no.3:77 JI-S 165. (Mim 18:9) Cases of heavy ice deposit formtion on lines in Central Asia. Blek. sta. 30 no.3:90-91 Hr 159. (MIRA 12:5) (Soviet Central Asia---Electric lines-Cold weather conditions) KBS7,L'..W1,.7L.M.i ingh. In reference to the article "Calculating intermediate supports for overhand electric power lines undpr outnge conditions." Hln1c.Rtft. 29 nn.9:8? S 158. (MIRA 11:11) (Electric linos--Polna) KIMSELIAMAN, M. Sh. Kessellman, M. Sh. - "Investigation of Conditions Providing for Increased Effectiveness of the Process of Drawing Sheet bletal.11 Min Higher Education Ukrainian SSR. Khar1kov Polytechnic Inst imeni V. I. Lenin. Mharlkov, 1956 (Dissertation for the Degree of Candidate in Technical Sciences). So: Knizhnaya Letopis', No. 10, 1956, pp 116-127 Translation from; Referativnyy zhurnal, AUTHOR: Kessellman 137-58-5-9586 Metallurqiya, 1958, Nr 5, p 107 (USSR) TITLE: The Magnitude and Nature of Pad Pressure in Deep Drawing (0 velichine i kharaktere davleniya prizhima pri 8lubokoy vytyazhke) PERIODICAL: V sb.: Progressivn. metody shtampovki i kovki. Kharlkov, Oblizdat, 1957, pp 226-231 ABSTRACT: An increase in the efficiency of deep drawing depends upon the magnitude and nature of the load on the pad. An investigation shows that the latter factor is the more important one. Pads should be applied with variable optimum force. V. F. 1. Presses--Operation 2. Metals--Processing Card 1/1 t - A 7 - 54- 1 -69 7 Z Translation front: Referafivnyy Mmi-nal, MrtalhirglyiA, 19514, Nr 1, 1) 106 (U"SSR) AUTHOR: Kessel I man, TITLE: Rational Design for a Pressure Pad (0 ratsional'noy skheme skladkoderzhatelya) PERIODICAL: Tr. Kharlkovsk. politeklin. in-ta, 1957, Vol 9, pp 149-154 ABSTRACT: An investigation with the object of determining the optimum nature of action of a pressure pad for use int* drawing of a bell-shaped detail of sheet metal. The variable stress required for the pressure pad should, it is recommended, be obtained by means of a spring-loaded, pre-compressed pad. An example of pa-d selection is presented. Y11.0. 1. Preasurs pado-Desigs Card 1/1 S/061/62/000/017/092/102 B177/B186 AUTHOR: Kest el@ mapj_X.-Y-a- E I TITLE: Investigation of tlre* wearing prbpei-tieb 'bf dap'r6ne vubjected to aliding friction PERIODICAL: Heferativnyy zhurnal, Khimiya,.no..17, 1962, 545, abstract 171,06 (In collection: Plaotmaosy v mauhinoatr. i piiborostre. Kiyev, Gootekhizdat USbR, 1961, 325 - 334) TEXT: heuultr. ar,-- quoted from research into the weak-resistance of capro@e afid into the ef6`ect of certain technological fact@ors on its hardness. The wear caused to caprone is shown to obey the laws governing abrasive wear. Thu wear-resistance.-o@ caprone is high@r than that of bronze and caut ii-ont and increases when silver graplUte is adds(!. A portable inotrument for rapidly, determining the hardnevo of oomponenta of' tiny ifliape in roconiOndod:' Abutractorlo notot Co6pluto tr@inulatlon lCard 1/1 -;2 K3SS3LIMALN. P.M. Form of the equation for the state of a real gas [with summary in Inglishle Inzh.-fix.shur. no.1:68-75 J& '59. (MIRA 12:1) lo Institut inzheneray morskogo flota, Odessa. (Gases) 24(8) SOV/170-59-5-2/18 AUTHORt Kessellmany P.M. TITLEt On the Problem of Determining the Temperature Function for the Equation of State of a Real Gas (K voprosu opredeleni@a tempera- turnoy funktaii uravneniya sostoyaniya reallnogo, PERIODICALs Inzhenerno-fizicheakiy zhurnal, 1959, Nr 5, pp 8-14 (USSR) ABSTRACT: The equation of state of a real gas, expressed in dimension- less parameters 6. PV VK and -T- ) looks as f ollove j R T-X Tj% (5. CLO + a/ -r + t3 y + a- y21 4_ r 'r-I .... where 0.,,, (LI9 (3 p 3- p of, . . v are inf inite series of the reduced density wand W is a monotonously decreasing function of reduced tempera- ture 'r& This equation is a generalization of the equation of state proposed by Professor Ya.Z. Kazavchinskiy Z_Ref 2-7. The problem of composing the equation of state is reduced therefore to the finding of several elementary volume functions cL i CL 1 9 13 1 -Coos and one temperature function y, each of which depends upon but one variable W or '7. Of these, the temperature function is Card 1/3 the most important one. Certain approximate methods for determin- SOV/170-59-5-2/18 On the Problem of Determining the Temperature Function for the Equation of State of a Real Gas ing the temperature function y are expounded in References 2 and 3- The present paper describes anotherp more accurate method of 4'-de- termination which can be used if data on thermal (PVT) and caloric values in the region of low pressures are available# The method consists in the re-writing of the equation of state in virial form, computing the values of 01 ZIr on the basis of the analysis of ex- perimental data on P,1Y, T, enthalpy and specific heat in the re- gion of low pressures;Yfinding the analytical expression for the function f(T') 2, , and finally integrating this function Ct T twice, in order tc obtain the function %@, assuming the constants of integration to be zeros. The author applies this method to de- termination of the temperature function for -water vapor, using experimental data of Keyes Z-Hof 42, Kennedy @ Rof 5-7 Havlioek and Myek9weky Z-Ref 6 of 0, Osborne J, Egerton and Callendar Z-Ref 8_/, D.L. Timrot and A.M. Sirota f'Rof 119. As a result of this determination the temperature function was found to have the Card 2/3 following forms 41 MW IV 3.rIJZ 05270 10(5) SOV/170-59-7-1/20 AUTHORS: Kazavohinskiy, Ya.Z., Kessellm TITLE; Basic Data on Specific Volume of Water and Water Vapor PERIODICAL: Inzhenerno-fizicheskiy zhurnal, 1959, Nr 7, pp 3'- 7 (USSR) ABSTRACT: The 5th International Conference on the Properties.of Water Vapor held in London in 1956 decided to perform an analysis of experimental data avail- able in order to compile International Tables of Water and Water Vapor. The present paper contains the Table of basic values of specific volumes of water and water vapor for pressures ranging from 1 to 1,000 atmospheres and temperatures from 0 to 8000C, and describes the method of its compila- tion. The coordination of experimental data in the region of vapor was carried out in three successive approximations. In the first approxima- tion, the graphical coordination of data was carried out by isochores in coordinates of 47 and T, and by Isotherms in coordinates of Cr and tO . Then, according to the data of the first graphical approximation, a simple equa- tion was composed which describes the family of straight lines, given by Formula 3. The'second approximation was carried out by deviations of A16 from the auxiliary straight lines being approximates to the actual Card 1/3 asymptotes of real isochores. Isotherms and Isochores, plotted byd(Y 05'27() Basic Data on Specific Volume of Water and Water Vapor, SOV/170-59-7-1/20 Card 2/3 were jointly coordinated. The obtained results served as a base for the final, third coordination carried out analytically by making upe of the equation of state, Formula 1. This resulted In the calculation and plotting of a now analytical network of Isochores and Isotherms, consistent in the best way with the experimental PVT-data. The coordination of data in the region of liquid water was carried out by isobars and isotherms. The data of the following investigators were laid down at the base of the present study: Kirillin, Rumyantsev, Zubarev and Ulybin jefs 2,37, Timrot ZRef V, Keyes jief 67, Kennedy with co-workers ZRefs 7,8,9,7, Keyes and Smith ZRef lQ7, Aqagat ZR-ef 117, and Osborne ZRef 1?7. The values of the Table compiled agree well with the experimental data of the above writers: over 85% of the total of 1,786 experimental points used deviate from the tabular BaOic Data on Specific Volume of Water and Water Vapor 05270 values not more SOV/170-59-7-1/2o than by 0.2%. The Table gives data on the average and maximum deviations of experimental data from the calculated basic ones. There are: 2 tables and 12 references and 1 French. .. 5 of which are Soviet, 6 English ASSOCIATTON,,, Institut inzhenerov morskogo flota (Institute Odessa. 0' Englnec-r.s), Card 3/3 5W XJMORS Zagoruchuxko, V. A.,.-KesuAllwan W-4/76-33-6-9.144 TITLEt (ka the Repro sent at lon of tha Eq%zation of State of a Real Gas ir. the Explicit Form, Kxprosed by fta Tndopend=t Variables T and v (0 predstavlenii v yavn--.iy forms uravmeniya sontoyaniya reallnogo gaza, vyrazhewjogn. oheraz nez&-A&imyy3 paromezinyya T i v@ PERMICALt Zhurzal fislobeakoy WmU, 1959, Vol 33, Nr 6, pp 1221-1229 (USSR) ABSTRACTt On the strength oil" rc-ailts obt.%in,-1 fr.).n Ln"stigations made on real gaaes (water vdPor, dioxide, methane and ethane) the possibility is mte;c,.] Va@, p.Laimn"- papar tf -& transi V..-cn of the mathomatijal of th.,' oqusllc@_n :if Ptate (ESI for real gases by the vaxial,'Lex T dal v f:p Z f@,.V,v'j t;o a zQrrerding equation axpz*ssad by tha vzriatlsa T s,-nl jprv em y(T P) J'n explicit form. RaspajtivL@. D;A%the=Mjsi_*i1 der!- ticMs are given, and it is found that lhb @,EV' with ths v&riablea T anti P [eqration (4@ repradnaes the th@srmal nnd ealoef.., propertlen of gas with the same aoovjrivjy as tha (ESI with tho 'miablaa T PAM v feriuxti= (3@ ; this holds. however, for a gmall density r=6a wL.6h is determinable by tbe &id of a eimplq vrfterlXa 'LL.:- N-61-t3r. of -the Virial. Card 1/2 OCASMOi6nta f,.>r Q34)kLd C2ffE (T&:b'_,Y 1) and W2ard HP (Table 2) 'V@ on the Repramentation of ths F4uaticri cf t)f j@ aw'Al G.'.L3 3-6-9144 A in the ExpUait Form, Erp iA by tb-i V4rlablej3 T ara girsn, -and &, ax-3 thv @,.)rrespo;idlng -s@uem lor tLe gaises under investigaidon, whi;.I oanifirm the VlAt"3ability of iiipation (4) (TabIqA 3-5) and ( P119 4). Tje @remsl tion to th--# exiDlicit fo= of the (M) ocris' *derably LiAl-I.Autez the @@-i:@.mpulatizu ze tba Lbermodynamio values in the r&ngA -.f I'aw yr,3.q:3uz,qjj tly- valLes obtained are raliable; hen.@,e, t7lb-9 -.3f t@i, thpir..P.-Aynamic prop6rtles of r6a! gav,)ij -1,3 mado p-EAb:@i. 'M az@_A 4 P tables, and 9 @. tic V111.1c.-h ejr.;@ ;3'-;"'i'A . SUBUTTEDs &'P+4mT)6r 'fc:i Card 2/2 KESSELIMANg P. M. CANo TECH SCA INVESTIGATION OF THE THERMODYNAMIC PROPERTIES OF C-OOL ANTIS OF MODERN POWER P ANTS9 ,f I- I - F moscowt 1960, ION MAIN '-Aa-UNION ORDE'A OF LA- SOR RED BANNtR SO-ITREs INST im F, Ee DZERZHIN- SKIY)o (KLI 2-61, 208). -139- f4 68841 s/o96/6o/000/04/015/021 E194/E455 AUTHORt Kessellmang P#Me, Engineer TITLE: The Equation f State of Heavy Water for the Liquid Phase PERIODICAL: Teploenergetikaj 1960, Nr 4, PP 72-73 (USSR) ABSTRACT: Considerable experimental data is now available about the thermal properties of liquid heavy water but there are no experimental data on its caloric properties. The author accordingly attempted to formulate the equation of state for the liquid phase so as to obtain reliable caloric data. Previously-published experimental work was used. The form of the equation of state used to express the p-v-T relationship was that proposed by Byron, see Eq (1). This equation is considered reliable only at temperatures below 2500C and at temperatures from 250 to 380*C it is necessary to introduce an additional term given by expression (2). Hence the final form of the equation of state is that given by Eq (3). The method of determining the coefficients entering into this equation is explained. It is Card 1/2 considered that this equation of state reliably describes 68841 'i'lle Equation Of State S/096/6 0/000/04/015/021 E194/E455 Of Heavy Water for the Liquid Phase the P-v-T relationship for liquid heavy water and may be used in drawing p detailed tables of its thermo- dynamic propertieg.u are Sovie There are 6 references, 2 of which tv 3 English and I German. VK ASSOCIATION:Od.s.kiy institut inzhenerov morzkogo flota (Odessa Institute Of Naval Engineers) Card 2/2 msnomr, P.M., insh, Thermodynamic oijilarity between ordinary and heavy water. Teploenergetika 7 no.3:83-M Mr '60. (MIRA 13:5) 1. Odeeskiy institut inshenerov morskogo flota. (water) (Deuterium oxide) 29991 S/170/61/000/012/001/011 0 rl,,9 7 3 B125/B138 AUTHORS: Kazavchinakiy, Ya. Z., Kessellman, P. M., Rabinovich, V. A. TITLE: The second virial coefficient and its extravolation for high temperatures 4 PERIODICAL: Inzhenerno-fizicheskiy zhurnal A no ' 12, 1961, 16-21 TEXT: The present paper deals with the extrapolation of the second virial coefficient well above a temperature range of interest to experiments usinE _ T the Lennard Uones Dotential. From the second virial coefficient 00 B = 2MI f (1 - e- U/kT )r2dr and from the Lennard-Jones potential 0 U(r) = 4UOE(r./r) 12 _ (r,,/r)6 I it follows that-B (2/3)n1Tr3F(z) or 0 B = b F(z), (5), for z - kT/Uo; bo - (2/3)rN3. N Avogadro number, 0 0 k = Boltzmann constant, U - U(r) potential energy of interaction between two molecules at a distance r, U. minimum potential energy, ro - distance where U. = U Eq. (5) can be written as log B log b + log F (6) and Card 1/ 3 0 0 29993. S/170/61/000/012/001/011 The second virial coefficient B125/B138 log z = log (k/U 0) + log T (7). The conformity of curves (6) and confirms the accuracy of Eq. (5) and makes it possible to calculate the potential parameters for a substance to be studied. IV 0 and k/U 0 can be used to calculate B for high temperatures with the help of Eq. (5)., The ziethod described furnishes results for monatomic gases, which agree well with theoretical and experimental values of the second virial coefficient. Eq. (5) describes experimental data for the second virial coefficient of polyatomic gaeen unsatisfactorily. The Lennard-Jones potential, therefore is also unable to describe complex molecular structures satisfactorily. By translating and rotating the coordinate system used for the experimental V@/ curve of the second virial coefficient it is possible to obtain conformity of the coordinates log B, log T, or logIFI, log z, which represent values of the experimental and theoretical curves. The usefulness of this method has been checked with NV 112, D2' 02' CO, air, C02 , and CF 4' The tempera- ture dependence of the potential parameters U 0 and b0 has to be taken into account for complex molecular structures. If UO = U 0(T) and b. = b 0(T) are known, it will be possible to calculate the values of the second virial Card 2/3 KESSELIMAN, P.M.; TABACHNIKOV) A.G. Determining the equilibrium constant for the reaction of ammonia dis- association over wide temperature and pressure ranges. Insh, -fis zhur. 5 no.10:19-25 0 162. (MliiA 15:1@) 1. Institut inzhenerov morskogo tlota, Odessa. (Chemical equilibrium) (A=onia) n zi-- 4, KAZAVCHIVSKIY, Ya.Z., prof.; KESSELTAN,.T.M., kand. tekhn. nauk; KIRIU121, V.A., akademik; RIVKIN, S.L., kand. tekhn. nauk; SYCIEV, V.V., kand. tokhn. nauk; TIMROT, D.L.# prof.; SHEYNDL111, A.Ye., prof.; SHPILIRAYN, E.E., dots.; BULIDYAYEV, N.A., tekhn. red. [Ileavy water; its thermoplorsical properties] Tiazhelaia Yoda; Toplofizicheakie avoistva. Moskva, Gosenergoizdatj 1963. 255 P. (MIRA 17:2) 1. Nauchno-isaledovatellakly Ustlt@ut vyookikh t,-r,+cratur pri Moskovskom energeticheskon Institute (for Kirillin, Sychav, Timrot, Sheyndlin, @hpillrayn). 2. Vsesoyuznyy nauchno- issledovateltskiy teplotekhnicheskiy institut imeni F.E. Dzerzhinskogo (for Rivkin). 3. Odenskiy institut inzhenerov morskogo flota (for Kazavebinokiy). 4. Odesskiy tekhnologi- cheakiy institut (for Kessellman). KESSELIMANp P.M, 0vMMwAWA"U6v Equation of rtate and the thermodynamic propertiev of wqgen. Inzh.-fiz, shwo 6 no.6:61-67 Je 163. (MIRA 1636) 1, Institut inshenerov morskogo flota, Odessa. Oxygen-Thermodynamic properties) @Zquation of state) L 1?163-63 EPF(c)/EWT(I)/EPF(o)-2/Er~IP(q)/RWT(m)/BD'I AFM/AO/ -S .- b----fir--VPu-4 JD ACC@'-'Z-13:01; 1111R. AP)004293 S/0170/63/000"/007/0043/0049 Kersollm-an, P. M.# Rabinovich. V. A. TITLE Thb-- atmi-;@ pro rMMn n _portios of disssociated hydrogen'and oxygen 50URCE: Inzhanorno-fizichoskiy zhumal, v. 6, no. 7, 1963, 43-49 TOPIC TAGS: thermodynamic property, dissociated hydrogen, dissociated oxygan. @;pocific volume, enthalpy, entropy. chemical equilibrium AD3TRACT: The article uses the theory of chem3cal equilibriuri to det@orrdne the t@.Ianccd compositions of mixtures formed in the dissociation of hydrogcn and oxygen. It calculates the thermodynamic properties of dissociated H- and 02 at 2000-4000C and 2000-3000C. respectively, and pressures of (1-500)l,05 n/cu r-. T-,;o papors by the authors in IFZh N'o- 5, 1963, gave the equations for the state of@ molecular hydrogen and oxygen (without considcr@tion of cUssociation) at 4000 and 3000C, respoctively, and pressures up to 5- 10 n/cu m. The detailed thermodynamic tables of specifio volume, enthalpy and entropy of H2 and 02 Gard 113 171.63-63 ACCIESSION NR; AP3004293 cLlculated by those oquations wore the basis for calculating tho roperties of the @mbstanco studied with consideration of thoir dissociation J(Phigh toril'Deraturos. At temperatures above 2000C, at which there iE lready a porcoutiblo dissociation, atomic hydrogen and oxygen can be regarded '2s ractically ideal gases. By the theory of chemical equilibftum, K. X)2P. P where x is the mol content of und-issociated mass in the mixture, and K K p po where Kgamma is determined by the volatility data on each component, 4ga=a for whi-ch the article givos formulas. For mixtures of the type A2 + 2A (A atom), K gamma2 , where the coefficient of activity gamma f/p. 7hus, to gamma A gamma A2 dotermine the Kp of hydrogen and Wgan dissociation reactions one has to-know KPo in dependence upon the temperature for oach of the Gubstances studied, as Catd L i7l63-63 ACCESSION NR; Aploo4293 well as the volatilities Of H2 and 0 which are found from the equations of 5tato for those components. The aut@ors regard as Justified the application of 'caagls law for calculating the properties of a mixture by the equation V i@' = ,I'I x + V2(1 - x), at the same pressure and temperature. On the basis of this and tho relationships between thermal and caloric values, the following formulas for the calculation of enthalp and entropy are obtained: i J x + j (1 - x mix 1 2 S S x + S (1 - x AR (x ln x + (1 x) In (1 - x)]. na-V 1 2 Table 1 givos mol content of molecular H and 0 in a reacting mixture (balanced compositionj at 11 temperatures between 2000 and 3000 C; table 2, the specific 7alunos ard enthalpies of dissociated H and 0 at the same temperatures. Orig. has 2 tablGs a:xl 15 numbered equations, ASSOCIArION% Institut inzhenerov morskogo flota, Odessa (Institute of Haval Engineers) SU TTED: 17jan63 DATE AC@J: 08Aug63 ENCL: 00 SUB CODE: PH NO REF $OV: 003 OTHER: 010 1-Card 3/ 3 KESSELIMAN, P.M.; TABACHNIKOV, A.G. Determining the equilibrium constant of the reaction of ammonia dissociation over a wide range of temperatures and pressures. Part 2. Inzh.-fiz, zhur, 6 no.808-81 Ag 163. (MIRA 16:10) 1. Institut inzhenorov morskogo flota, Odessa. N 4M 4 A. `2t 77 k4 02 intaracrion potential. 11 4,1 second and third viria'- L r i -an be vritten in the form: HM b.@P-(T- vq . . . . . . . . . . . . . ..... r@-, @;V lK AIR, Jr 4A ow cr- rf' rl!ty'0aze-l t1"e h.4t--D e@. -Pcl@.LK 7,-rff. s r! ME 'po -9,,n n n z,,n tirul a r 14, J,@@ 5-Ah UP f c IIT) NR3 AP5026855 SOURCE CODE: UR'/0170/65/009/004/0527/05j-2- AUTHOR: Kessellman P M - Kitlyarevskly, P. A.; Afanaslyev, M. M. 1; V ORG: Industrial Institute im. M. V. Lomonosov, Odessa (Teklinologichesk!.y institut)' @j 9 1 ;- ,- , I TITLE: The equation of state for carbon diqx@Wlin the temperature interval from 273 to 4000 K and at pressures up to 1000x105 newtons/m2 sounCE: Inzhenerno-fizicheskiy zhurnal, v. 9, no. 4, 1965, 527-532 ;zt, qq, TOPIC TAGS: thermodynamic state equation, carbon dioxide, virial coefficient ABSTRACT: The authors attempt to correlate all existing experimental material a to set up an equation of state which reflects the experimental thermal and calorific data on carbon dioxide with a high degree of accuracy. For temperatures from 273 to 800 K and pressures from 1 to 1000x105 newtons/m2, the equation consists of elementary ftuictions of the form: Pb 'P+ + Rr. .. ... . UDC:536.71 L 8939-66 ACC NR, AP6026655 The elementary functions Oto, o(2, ...have the form A ((a) aid, b, Values of the coefficients in this equation are given in a table. Analysis shows that, starting with T=770 K, at P=(1-600)xIO5 newtonstm2, two virial coefficients, B(T) and C(T) are sufficlent to set up the equation of state. The virial coefficients are determined from existing experimental data. For the region of parameters T-770 to 4000 K and P=(1-600)xIO5 newtona/m2, the equation of state was set up in the virt- al form: P0, @T- + At + As (2) whereAl =Bd..c; At-CdK2v. 'The coefficients A, and,A2 were determined analytically. Results of computer calculations according to Equations I and 2 are shown to agree well with existing experimental data. Orig. art. has 2 formulas, 3 figures, and I table SUB CODE: TD, GC/ SUBM DATA: 05Apr65/ ORIG REF: 008/ OTHjjEF: 012 C.,d2/ t H@ L 234',3-66 ENT(m)/ENP(J)/T/ETC(m)-6 NW/ RM, ACC NR: AP6010038 SOURCE CODE: UR/0170/66/010/003/0385/0. AUZIOR: Ke Litvvinov, A. So ORG: Institute of Technology im. M. V. Lomonosov, Ode3na (Tekhnologicheskiy institul flat an atmospheric TITLE: Ca3culation of the viscosity boefficient of gas mixtures pressure -SOURCE : - -Inzh-inerno-fizicheakiy -zhurnal,- v. 10i no.--3i -1966i -385-392 TOPIC TAGS: gas diffusion, atmospheric pressure, gas viscosity, constant coefficient, potential energy, gas kinetics KIKIMIA(MI: A method for calculating the viscosity of gas r3ixLures is described. It is based on the use of potential energy with variable potential parameters, formulas of the riaorous kinetic theory of gaues, and rules of combination of potential par=cters o-ij - 1/2 (ri + d-J) and tij a VE_-t&,t Fair agreement with experimen- tal data is shown. Orig. art. has: 4 figures, 15 i@rmulas, and 5 tables. (Based on authors' abstract] (Hrl SUB CODE: 32,20/ SUB14 DATE: O3Jul65/ ORIG REF: 002/ OTH M: 007/ Card 1/1 J*'V UDC: L 31326-66 EWT(j)/EWT(M)/EWP(J)/T/FTC(m)-6 IJP(C) Y'-W1jW1RM ACCESSION NR-. AP5025984 URI 0294/ 65/003/005/070010707 547. 211+547. 212:532. 13+533. 21 i AUTHOR: Kessellmin, P. M.; Chernyshev, S. K. TITLE: ;Z=@@hara__c_ -te ris tics -of'-some hydrocarbons at high tempera- tures W U I A&&@@ I SOURCE: Teplofizika vyaokikh temperatur, v. 3, no. 5, 1965, 700-707 TOPIC TAGS: hydrocarbon, ethylene, ethane, methane, gas properties, equation@ of state., it" 4 A.-.,,,k t Of JA ABSTRACT-:4 thelrbj@e he work was the simultaneous determination of the transport properties and the second and thirdvirial coefficients of methanel ethanel and 2Lhylen4over a wide temperature interval including the high temp@_r@at re re- gion. The theoretical treatment is based on the following averaged potential func- tion for intermolecular interaction: "(TrI r u i= 4a (T) P(T) M! . in whiph the potential parameters and r. (T) are not constants but are some :ar,d L 31326-66 ACCESSION NR: AP5025984 functions of the temperature. Based on data from the literature, calculated I values of the viscosity and the second and third virial coefficients for methane, ethane, and ethylene are tabulated for temperatures from 300 to 3000 K. Values of the viscosity, calculated by this method, are found to agree with experimental data within 1-21o. However, at high temperatures where experimental data on compressibility are not available, the use of the potential parameters for a spher-L ical potential found from the second virial coefficient leads to unsatisfactory re- sults; the deviation in this case between theoretical and experimental values reaches 10-1516. This is attributed to.insufficiently realistic values of the spher* Cal potential for describing the interaction of nonspherical molecules.. A compari, son of calculated and experimental values of thermal conductivity shows a devia- tion within the.experimental error (from 1-316, and only reaching 5-6% at low temperatures). Orig. art. has: 7 formulas, 4 figures, and 4 tables ASSOCIATION: Odesskiy tekhnologicheskiy in6titUt iM. M.- V. Lomonosova (Qdessa Institute of Technology) SUBMITTED: 24ju164 rok4koij; UV SUB CODE; 07120 NR REF SOV: 007 OTHER: 015 Card... 2/2 ACC NR% AP6014064 SOURCE CODE: ;AUTHOR: Kessellman. P. M. ORG:__-Odessa Technological Institute im. K. V. Lomonosov institut) UR/0294/66/004/002/01 (Odesskiy tekhnologicheskiy TITLE: Some similarity criteria for physical properties of compounds SOURCE: Teplofizika vysokikh temperatur, v. 4, no. 2, 1966, 196-201 TOPIC TAPS: 06-A res ure, high temperature technology AWa hea" I gas p ABSTRACT: T e cri e"rli@a @wichlstayb:Iish thermodynamic similarity of two compounds are studied to determine those needed to describe properties of compounds with the aid of chemical potential (with one set of parameters). The discussion is restricted to a general equation of state retaining only second and third virial coefficients (althou the range of application is wide). This approach is especially useful in high temper ture applications. Experimental data showing the second virial coefficient for sever vapors and gases in the range of 15000C are quoted. It is shown that the data for various compounds lie nearly on one universal curve. A similar situation holds for the coefficient of viscosity shown as a function of the normalized temperature. Ana- lysis shows that theoretically established criteria for thermodynamic simmilarity is supported by many experimental results and therefore these criteria can he used with Card 1/2 UDC: 530.17 + 533.1 ol, I- IL 32vU-66 ACC NRi AP6014064 % / confidence to detennine properties f gases@that are not known or difficult to estab- l.ish. Orig. art, has: 5 figures, 1 table, 7 formulas. SUB CODE: 20/ SUBM DATE: 2lMay65/ ORIG REr: oo5/ OTH RM 003 1 Card 2/2 'D@) I 1 @5 (1) SOV/115-59-10-2/29 AUTHORS - Volkonskiy, V.A., 1-o"dinov, M.A., Kessel',man' SOIN16, !Temirov3kiy, A.G'. @'C I T L E T'ne Analysic of Trr3t@-iim; nt Error Produded by Dis- crete Action InteC@-atuor,, PERIODICAL: Izmeritellnaya tekhnika, 1959, Nr 10, pp 4-6 (USSR) ABSTRACT: An instrumental miscalculation of an integrator ari- ses only when the -Pi deflection angle of the output shaft of an integrator varies from cycle to cycle and the lever which introduces the element to be in- tegrated remains in a fixed position. This variation is caused, for instance, by delayed switch-off-and- on of the counter in each integration cycle. The mis- calculation represents the difference bet,ween-Pi and the assembly average of the deflection angle -foi 'fi "-Pi '10oi The corresponding miscalculation of '8 the measured element for each integration cycle will Card 1/4 be du KA-f (1) SOV/115-59-10-2/29 The Analysis of Instrument. Error Produced by Discrete Action Inte8rators where k is the proportional coefficient between the deflection angle and the measured element. The authors further describe an experimental evaluation method of an instrumental miscalculation and of the integration error derived from this miscalculation. The integrat- ion error corresponding to a time period T) will be 16 u Ju (t) dt (2) As the assembly average of an instrumental miscalcula- tion M 4u = 0, so the assembly average of integration error derived from this miscalculation M Au is also 0. The variance of the integration error, derived from the formula (2) will be D Au g R U (t,s) dtds Card 2/4 0 til S OV/ 115 - 5- 9 - 10 - 2/2, 01 P.-odaced, by e Ana yci-i s of Instrumeni @rrcor Discrete Action integrators where R (t,s) a correlation func- u tion of instrumental miscalculation, If we admit the stability and the ergodicity of the process then T-t DA R u (Vdtd[@_-T R d (3) where Ru(1r) = Ru (0,,Z)@ The expression of a correlation connection being 'r :=. - 1 (4) u @-j S Ru (T) d1C u 0 the (3) and (4) formulare give D6 2 Tr D J (5) u U of the integration err- Thus, to determine the variance or DA we must know the variance of the instrumental Card 3/4 mis- U calculation W u and the value T U . These values The Analysis Of Instrument Error--- i SOV1115-59-10-2129 Integrators P--oduced by Discrete Action were determined experimentally for integrators produ-, ced by the Khar?kOvskiy zavod (KhaAov Plant) "Kip" and by the "Manometr" Plant, A detailed description Of this experiment is given. There are 3 graphs, 1 'tab- le and 1 Soviet reference. Card 4/4 HEMIRGVSKII, A.S.; KESSELIMAN, S.M. Nomograms for the datermination.of-the error of differeinial manometero-flowmeters. Izm. tekh. no.9:49-52 S 163. (MIRA 17:1) q7 KESSELIMAN, S.,M. Slide rule with a special runner for the determination of the basic error of differential manometers-flawmeters corresponding to state standard 372G-60. Izm. tekh. no.12-145-48 D 164. (MIRA 18:4) '2' SOURCEI Izmeriteltnaya tekhnikA, no. 8, 1965, 51-52 TOPIC TAGSi orology, automatic control, automatic control system, reliability theory, applied'Lp"S:"Ychology, human engineering, scientific conference ABSTRACr: This conference was held at the All-Union Scientific- Rpsea- * h Institute of Fptrol2gy in Leningrad, between 12 and Vi -Mai-1965, and it who' __1_RttG;2eR by - Qi@Rates representing 99 different organizations from 14 cities in the USSR. A total of 28 papers was presented and discussed at the conference with respect to tho problems arising in the evaluation of humn performRneo in the handling of various types of devices in serti- automitic control systems. The subjects to which the papers pertained in- cluded,. the I'man-machine" system from the standpoint of the place and role' of man in the control processp his potential for perforrting specified functions, wA the optimal conditions for and methods of his activity; the ,development of techniba-I means of acquisi@ion and presentation of metro- Card UDCs J54.4(063)t68l.P_ 'S ACC NRt-AP6018694- 7 logical information; the @hysiologlcal factors that must be considered in .the dosign of instrumenfs and indicators; a mithomatical model of the optimal expenditures of time by the operator at a*power-unit control panolj anol, ithe theory of reliability as applied to the human operator of control stems iptatistical methods of reliability control in the "man-automaton" system;. automatic control of the chaMes in the emotional state and attentiveness of ;the operator in the "man-machine" system; features of the perception of dif- ferent types of control-and-measurinE: indicators; factors determining-the 'Irate of data processing by the hummi operator; effectiveness of the percep- tion of visual si@nals in different tasks as a function of the density of -their layout on the control panel; certain principles of the decign of coding systems. Thn resolution adopted by the conference points out that the co- J ordination of the means and techniques of data indication with the human ipsychophksiological charactoriaUcs is a major prerequisite for perfecting ineasureme,nt apparatus6 Further, it recomManded thg drafting of a glossary of Items used in ongineering psycholoq@ rip,@2 SU13 CODE; 3.3 14, 0@ SUM DAM. rforta - Card 2/2 m t FOWND/Gonorrl rnd Spocirl Z00109YI, Insocta Abs Jour s Rof Zhur - Biala, No 61 1958, No 25815 Author 'I. KA_pQi_r.4M1Z Inst i Not Given Title I Some 11otas an the Outbrork of Proprgrtion of 1.1orsuring Worm Moths rnd on Their Control. (11okotoryya zrmochrniy-n n VSPYchkc rcz=ozhoniye soanovoi pyrdonitsy 1 0 borlbo a nay.) Or! g Pub I Lt.13 polsiti, 1956, 3o, no 4t 24-26 Abstrret i Biologiorl z3onsuros could not prevent the brooding of morsuring vlorri moths in 1955t bocruso of the incdoqurcy of work in tUrreting insootivouous birds, The worthor ccnditions in 1953-1954 worc ftvorrblo to the post. In spito of the frct thrt the density of egg-Irying in 1954 rmd 1955 wrs considcr- rbly louor thrn the density rogrrdod rs destructive, the 1@rvro crusod grort drmrge. Orrd 1 1/1 %,CLL %A J./ 4. 'M @VT@ W@. .0 "AaANZ, 8@m r,-/61/003/011/002/056 6 3) B 1021B1 38 AUTHORs Kessenil-l- 1-4-. TITLE: The effect of spin diffusion on dynamic polarization of nuclear spine PERIODICALt Fizika tverdogo tela, v. 3, no. 11, 1961, 326o - 3262 TEXTs The effect of dynamic nuclear polarization is of great interest, especially in irradiated polymers, which might be used as polarized nucle- ar targets with high proton content. In the present paper the diffusion equation 8p/at - D&p + (P 0 - p)/T1 (Bloembergen, Physica, 15, 386, 1949) is solved for polarization of nuclear spins with dynamic nuclear polariza- tion. The nuclei are assumed to interact directly with the paramagnetic centers and nuclear spin - lattice ielaxation is taken into account. D - a'/XT2 , T2 - nuclear spin-spin relaxation time, T, - opin-lattice relaxation time, 4 a numerical factor of the order of -10 1 - 102, Po thermal equilibrium of nuclear spin polarization. The system is assumed Card 1/4 3 3@1787@61/003/011/002/056 13 The effect of spin diffusion on .... B102 B138 to consist of spheres of radius R - a 4N/n around the paramagnetic centers; a is the distance between the nuclei, n the number of centers and N the number of nuclei per unit volume. For spherical symmetry the polarization p of a spherical layer with radius r the steady-state equaticn Dr a2(rp) P - Po holds. With the boundary conditions p(r) - P for ar2 TI . .3 0 r --@ m , and p(r) - PD f or r = b - a e-ar p(r) P0 + (P D -P 0) /Ar is found to be its solution. a = 1/ DT, P/Po , re,r. are the gyromagnetic ratios of electron and nucleus, respectively, P D will be the polarization for nuclei which are directly connected by interaction with the spin of a parainagnetic center in-the case of electron paramagnetic resonance saturation. The mean effective T, 3 r. polarization is found to be P - P 0 +(PD - P0) XT 10 ii 2 tn N This relation makes sense only for low concentrations n/N I . It is nG Card 2/4 I "j770 '61 1/003/011/002/056 The effect of sDin diffusion on ... XT 3 longer.applicable if R4 3 1 or f'or @on@.,untrations n/14-4 2 re -2a in solids T 24 T 1). P D depends on the kind of center. The centers can be divided into three groupst Those with pon i t ivf,., dynamic nuclear polari- zation, those with negative dynamic nuclear polarization. and inactive centers. These types of centers differ in their e.p.r. saturation condi- tions. 71ith a parameter s taking this into account, the mean value of P D is given by P D - F(te/rdspo I F is a function of' e.p.r. and of the nuclear magnetic resonance line shapes. The optimum concentration of paramagnetic centers is given by nINfv XT 2 @ The author thanks V. L. Karpov r. /1-n - for discussions. There are 6 referencesi: 1 Soviet and 5 non-Soviet. The four most recent references to English-language publications rcad as followst A.,Overhauser. Phys. Rev., 929 411, 1953. M. Abraham, M. A. H. McCousland@ F. N. H. Robinson. Phy8@ Rev. Let., 2, 4499 1959, 1, E, I, Hardeman. Philips Res. Repts., j2, 587, 1960. C.. Hwang, T. M. Sanders. Card 3/4 .. @cmmm7m@ 00 341V 3/011/002/056 The effect of spin diffusion on 3102/B138 Conference on Low Temperature Physics TorurLt,), j_ 96, 1960, ASSOCIATIONs Nauchno-issledovateliskiy fiziko-khimicheskiy institut im. L. Ya. Karpova Moskva (Phyaicochewical Scientific Research Institute imeni L. Ya. Karpov, Moicow) SUBMITTED: May 3, 1961 Card 4/4 89200 17-42' S/056/61/P40/.QO1/005/037 114 7111 ia, 131s, mm) 13102/B204 AUTHUii: -ilessenikhj A. V. TITLE: Overhauser effect and "secondary signal" in electron para- magnetic resonance PERIODICAL: Zhurnal okeparimentallnoy i teoreticheskoy fiziki, Y- 40, no. 1, 1961 j 32-33 TEXT: The author reports on studies of the relative increase of the proton pdarization in the free radical diphenyl picryl hydrazyl at room tempera- ture during the saturation of electron paramagnetic resonancei proton polarization was determined from the amplitude of the nuclear magnetic resonance signal on the screen of the oscilloscope. The studies were car- ried out on a 30 mm3 solid diphenyl picryl hydrazyl in fields of about 3300 oe. As may be seen from Fig. 1, the relative signal intensity 1/1 0 of the nuclear magnetic resonance of protons increases exponentially with the amplitude H I of the h-f magnetic field. With H 0 1.5 oe, the effect of the "emission of two quanta" (9300 and 14 Mc/sec) in electron paramagnetic resonance, which has already been described by Winter, could also be ob- Card 1/3 S/056/61/040/001/005/037 Overhauser effect and ... B102/B204 served. This effect occurs with the simultaneous action of an electro- magnetic radiation having the frequencyto upon the system of electron spins in the constant magnetic field Ho and anIther radiation having the frequencV (J24 W1A = Te Ho is the condition for the occurrence of the "secondary signal" &@ (i . Fig- 3 shows an oacillogram of a signal representing a euperpositioR of a nuclear magnetic resonance signal with a peak in the H0 field, aid a "secondary signal" of the electron paramagnetic resonance at the frequency un, consisting of absorption and emission signals, which are shifted by � &) n/Te a 5 oe toward the H0field. Also the signals described in Ref- 3 are, in thacpinion of the author, a superposition of a nuclear magnetic resonance signal with a "secondary signal" of electron paramagnetic resonance in the case of a shift of the nuclear magnetic resonance signal from the maximum of the Overhauser effect. The author thanks Professor Ye. I. Kondorskiy and Ye. S. Goryunov for their collaboration. There are 3 figures and 3 references: I Soviet-bloc and 2 non-Soviet-bloc. ASSOCIATION: Moskovskiy gosudarstvennyy universitet (Moscow State Univer- sity) Overhauaer effect and ... 11; SUBMITTED1 July St 1960 89200 3/056/61/040/001/005/037 B102IB204 Legend to Fig--'31 a) nuclear ma, superposition of a @metio res peak) by a Onance Signal (central "Sevondary ai6-n,,l,, of paramagnetic res6nance (outer pea electron 2.5 00. ks), b) "secondary signal" of electron Paramagnetic resonance, 2.2 Oe. Fig- 3 Card 313 S/139/62/000/001/024/032 E039/E435 AUTHOR: Kessenilsh-. A.Y.- TITLE, The investigation of dynamic polarization of nuclear spin in free radicals PERIODICAL: Izvestiya vysshikh uchcbnylch zavedeniy. Fizika. no,l, 1962, 144-150 TEXTi At the present time much attention is given to improved methods of investigating dynamic polarization of nuclear spin (D.P.N.). An increasing nuclear magnetic resonance (N.M.R.) signal is observed with saturated electron paramagnetic resonance (E.P.R.), which was predicted for the first time by A. Overhausero- .4 The increase in N.M.R. (A) by the Overhauser effect is given by Ye I(I + 1) A I + f s 71, S(.15 4 where S are the electron and yn, I are defined in detail has been investigated Card l/ 3 Syromagnetic relation and spin of the for the nucleus. The other coefficients in the original paper. The D.P.N. effect previously for solutions of paramagnetic ionx.:@,.., ji S/139/62/000/001/024/03 The investigation of dynamic E039/E435 and free radicals in low and high fields. In the study of paramagnetic salts, crystals and pure free radicals with short relaxation times there are difficulties because of the necessity -k k of obtaining large amplitude fields and conducting away the heat produced in the sample. In this paper dynamic rolarization of protrons is investigated in free radicals of diphenylpicryl- hydrazyl (D.F.P.H.) at room temperature and for fields of 3300 toL,'----i 31100 oersteds. The sample of D.F.P.H., consisting of 30 to 50 mm3 of powder scaled in a teflon ampule, is placed with a coil- inside a resonator situated between the poles of a large electro- magnet with a stabilized current supply. The frequency for E.P.R. is in the range 9300 to 9400 Mc/s and for N.M.R. 14.0 to 14.2 Mc/s. Results are recorded photographically from an oscilloscope. The increase in the N.M.R. signal A for protons. in D.F.P.H. is shown to be a function of the intensity of the magnetic field F11 in the resonator; the experimental points falling an a curve given by -4@ (5) A 1 + 70 2 1 + 10-1-H CardC@3,; S/139/62/000/001/024/032@.,.- The invesfigation of dynamic ... E039/E435 The narrowing of N.M.R. lines with saturated E.P.R. was studied 'A and can be used as a direct measure of s - the saturation factor for E.P.R. Acknowledgments are expressed to Professor Ye.I.Kondorskiy for proposing the experimental arrangement. There are 4 figures. ASSOCIATION: Moskovskiy gosuniversitet imeni M.V.Lomonosova (Moscow State University Imeni M.V.Lomonosov) SUBMITTED: June 28, 1961 'A 47 Card 3/3 i/lei/63/005/002/009/051 B104/BI86 AUTHOR5s Keseenikh_LAM; _I* p Lushchikov# V. Isp Manenkovq As Asp and Taran, Yu. V. TITLEt Proton polarimation-in irradiated polythene PERIODICAM Fizika Vverdogo telat T, 50 no6 2# 1963p 443 454 TEXTs The aim is to find materials suitable for polarized proton targetst i and to investigate'the physical ptopertiss of irradiated polythens. To this end the atudies-of dynamic polai@ization in high-density polythene irradiated with fast protons (Ve Is Lushohikovp As As YAnenkovp Yu* V, Tar0l, FFT, 3t 3503t ig6i) -were continued, The dynamlo nuclear polarization vai measured at 77v 4o2 and t,60K in a magnetic field OfAJ3400 00 using a device described in a provi6u# paper. The 17sq-6 mm test pieces were plaC6,1k. in the coil of an autodyne n.m.r pickup, with the axis of the coil per . .1 .)..'-, pendicular to the long side of the resonatof. H oscillations with a 102 frequejoy of 9440 MO/S were set up in the resonator. The dynamic polariza-: @iop factor of the protons was determined from the amplification factor of the n.mars, signal at saturated eeptro of the free radicals formed when the Card 1/3 3/181/63/005/002/009/051 Proton polarization,ifi...- B104/BI66. polythene was irradiated. -ftesultas In the He temperature range, the dross. relaxation under oonditiona of non-uniform e.p.r. line broadening plays an important part in the dynamic polarization of the nuclei. This can be used to explain the increase in the broadening of the dynamic nuclear polarina.. tion maxima as the temperature decreases# and the fact that the dynamic, , polarization factor does not depend on temperature. The time dependence -of the n.m.r. lines is described as the sum of two exponents with relaxation times of TI and T 20 The hualear relaxation .depends lineaily on T I.. and T 21 this result being contrary to theoretical predictions (0. B. Leifsonj, 0. D. Jeffries, Phys, Rev., 122p 1781t, 1961). It is Pxplained on' the assumption that the action zone *of the. paramagnetic- centers is equalized at the expense of fast spin diffusion. The`dynamio polarization coefficient dbpends linearly on the molecular weight of the initial material. There, are 6 figures. ASSOCIATIONt-Fisiohookiy inatitut imb' P. N. Lebedeva AN 6SSR (Pkysios -Institute imeni P. N. Lebedev AS USSR)j Nsuohno-ieBleidovitol@k* fiziko-k4aWheakiy inatitut im. L.Ya. Kerpova, Moskva,,. (Soientif4#,MsAooohemioal Research Institute imeni. L. Ya. Karjpvp Moscow) Card 2/3 M@E 77@ A 7-777777 T-A Proton Polarization iis 8 Y16 VW5/C@2/009/05 I BIOW186 SMITTEN.. August 6t 1962 Card 313. W S/i8l/63/005/004/02a/04T B102/BW @UTHORSs Kessenikh, A. V.# and Hanenkov, A. A. tITLEt-- Dynamic polarization of nuclei in the case of saturation of non-uniform e.p.r. line broadening PERIODICALs Fizika tverdogo tela, v. 5, no. 4, 1965, 1143 - 1146 TEXTs Since cross relaxation between spin transitions plays a role in the case of saturation of non-uniform e.p.r. line broadening, it may be assujned.@ that this will also affect dy-namic polarization of nuclei which is due to saturation of forbidden e.p.r. transitions (FTT, 5, 4459 1963). An exact solution to the problem of saturation of non-uniform e.p.r. line broadening is very complex when crous relaxation has to be taken into account; there- fore the authors have developed an approximate method allowing of qualitative oomparison. with experiment.. On the basis Of a henoaenological model using Portia' approximation (PhIs. Rev. 104, 564 , 19 56@ a qualitative theory of tempgrature and concentration dependences of dynamic nuclear polarization is developed which takes account of cross relaxation. Tha cal- culations are made for nuclei 11IthII,w,1/2,and.eaturation of the mignetio resonance of the electron spine (S 1/2). The optimum oonditiona for Card 1/3 m - - -------- -- s/ 6 i/63/005/064/028/047- Dynamic polarization oCnuclei... siw/BW dynamic polarization are disoussedi they have to be known for a proper choice of a suitable polarized nuclear target. The theory was found to be qualitatively applicable to La 2M83 (NO 3)12 24R20 (Phys. Rev. 122, 17el, 1961) and irradiated polyethylene at helium t&peratures. The experimental- data on proton polarization at 4-20K in these substances show that the dynamic polarization coefficient ij passes through a maximum when the tem- perature of the concentration of paramagnetic centers is varied; the dis- tance between the extrema of I as a function of the magnetic field increases monotonically with decreasing temperature and increasing concentration of the paramagnetic centera (in the present case Ce3+ in 0.1 - 1% ooncentra- tions). The theoretical result, namely that the extrema. of 7? will arise at the lower temperatures the lower the concentration of the centers, is not yet verified experimentally but appears reasonable. Deviation& from the theory may arise in the case of extraneous relaxation or croaa relaxation between allowed and forbidden transitions. ASSOCIATIONs Fizicheakiy inatitut im. PO N. Lebedeva AN SSSR (Physics Insti- tute imeni P. N. Labedev AS USSR)j Fiziko-khi=ioheskiy institut im. L. Ya. Karpova Moskva (Physicochemical Institute imeni L. Ya. Karpov, Moscow) Card 2/3 KESSEUM, A.V, .Use of methyl dichlorooilane in determining the resolving power of nuclear magnetic resonance spectrometers. Opt. i spektr. 14-no.2; 315-316 F 163. (MIRA 16.5) (Silane-Spectra) (Nuclear magnetic resonance and relaxation) IMWENIM A V - LUSHCHIKOV, V.I.; MAONKOV, A.A.; TARAN, Yu.V. Polarization of protons in irradiated polyethylenes. Fize tver, tela 5 no.2:1+43-/4f4 F 163. (MIRA16'5) I 1. Fizicheskiy institut imeni P.N.Lebedeva AN SSSR i Hauchno-issledovatellskly fiziko-khimichaskiy institut imeni L.Ya,Karpova, 14opkva. (Polymers, Effedt of radiation on) (Protons) MSERKH, A.V.; MANEMKOV., A.A. Dynamic polarization of nuclei by the saturation of nonunifomly broadened Unes of ele4on paramFgnetic resonance. Fis.tver. tela 5 no.4:1143-lU6 AP 163. (MM 1614) 1. Fizicheokiy institut imeni P.N.Labedeva A.N SSSR i Fiziko- khimichesiiy in5titut imeni L.Ya.Karpova.. Moskva. (Polarization (Nuclear pbyBico)) (Paramagnetic resonance and relaxation) L 6' ENP(J)/EPF(c)/W(mN./B93 AFFTC/A30 Pc-h/Pr-h AP3001284 S/0181/63/005/006/1640/1642 ACCESSION NR: V. OR.S: Kesscnikh 'A. V.. Lushchikov, V. I.; Manenkov, A. A.; Taran, Yu' UM ------ A TITLE: Relaxation and dynamic polarization of protons in 2@@lyethy@lenes(500, URCE: Fizika tverdogo-tela, v. 5,,no. 6. 1963, 1640-1642 so proton, dynamic polarization, spin diffusion, nuclear magnetic TOPIC TAGS: resonance, polyethylene, molecular weight, ultra-high frequency ABSTRACT: The authors started with data from V. 1. Lushchikov A. A. Manenkov, and Yu. V. Taran (M, 3, 3503, 1961) and A. V. Kesseni;ch, V. i. Lushchikov, A. A. Hanenkov, and Yu. V. Taran (FWT, 41 433, 1963) concerning the dependence of dynamic polarization in polyethylenes on the average molecular weight. They ex- larization to be about 60 when the molecular pacted the coefficignt of dynamic po weight was 2.3 x 100. To test this view and to refine the results of the cited papers, th made this study on several samples of polyet!VVlene.b2 2 C P. )AY deutrons.\1) Measurements were made on a setup described in the first of the above papers, at 77, 4,2, and 1.6K. These experiments have shown that within the limits bf experimental accuracy the resolution of dynamtc polarization at ultra-high- frequency output and restoration of nuclear polarization after removal of nuclear- Card L 17999-63 ACCESSION NR: AP3001284 1'2gnetic-resonance saturation are described by eMponents with identical value of the Lime Of nuclear relaxation. This indicates that the theory of spin diffusion (G. R. Khutsishviii (ZhETF 42, 1311, 1962)) is equally applicable to dynamic f'o larization. The measured values of dynamic polarization proved to be smaller than expected and the authors ascribe the difficulty of demonstrating dependence i Of this property on molecular weight to peculiarities in the technology Of pre. j paring the samples. "In conclusion the authors thank B. I. Kokorev for his aid in the work and they thank V. L. Karpov cf interesting discussi,3"n-S. P Doctor of Chemic-a-1 Sciences, for a number i thanks to T. I. Terekhov and They also take this opportunity to express their Cf one sam Yu. P. Yy*tskiy for determining the molecular weight- fiame sampleleo, and 1q, A' SlOvOkhOtOV for studying the infrared spectrum of the Orig. art. ha-6-1-=tablet i ASSOCIATION: Fiziko-khimichaskiy institut im. L. Ya. Karpoval Moscow and Chemical Institute) SUBMITTED: 2!Jan63 DATE ACQ: 01JU163 EXCL: 00 SUB CODE; PH, MA NO RKF SOV.;- 003 OTHER: 001 C(,srd 2/2 -in" s/olBi/64/006/003/0827/0830 ACCESSION, Nin Apw19845 A!jTH0-,jiS: Kossenildi; A. V-@' jqanenkov, 1,. h,; pyatnitskjyj G. I. TITLZ: Discussion of experimental data on dynamic polarization of protons in irradiated po3,,rothylenes SOUXE; Fizi1ta tvardogo tela, v. 6, no. 3, 1964) 827-830 TOPIC,2AGGS: poLirizatign,'polyethylone, d1tra high froquency irradiations magnetic resonance, magnetic property ABSTRACT: Tile authors have investigated samples of polyethylene of hiph density.. I containing 1016 - 1019 crr3 polyene radicals: CH2-(CH)2,.j_l-I_R2, where M >2. Studies -were made at 77, 4.2, and 1.6K. The frequency of the ultra-hic;h-frequency generator was kept constant, but the magnetic field was varied, and the intensity of tl.ie nuclear magnetic resonance siGnal was measured in its relation to the magnetic field. It W@Ls assumed that the relations between the probabilities of different spin transitions, during ultra-high-frequency irradiation of paramagnetic centers with irregularly okpandod elootron para@zagneti* Card. 1/2 AG C;ESSIC)I@ NR; APhoi@8@5 resonance lines are determined equilibrium within the s by tile relations among ra pin system and dy"ar"c POlarization of protons oqu';ilibriwn of tes Of establishing witIl increaso in InagnOtic -field, reach a minimum sPin with the lattice. The (Passing threugh was fOlInd-to decline very ra.Addly (norlative values) zero) i then increase V rapidly decline again with further increase in -fields reach a In&xeix7r'ILLM'j - Theorotical values were found to Corr .1 and then values in values of rqtCn Ospond closely to theoretical V Otic fiOld Whoro UlO minin aluOs Of I the Iiinimum and zimxk IuMs and maximums,occueXPOrimental tile ex@)C'rirj 111m , The authors point Proved to be nur j, but the 'Ontal values lerica3 r U _jy wi@llin the framework ' greater than 4@ it Of thd model they ,,,,Yout that it is Possible to cor vrans4 ion saturation on electron Polari" j qute, calculations. Orig. lation the -effect of co,,nbinatioll spin I icIl cannot genwallY be neglected art- has: 2 fi6m@es 2 wI-L -@S&DUP'Ti0i'l.. ri,L,,-O-" and 3 formiUs. chemical In:;,;itute).k1liMichesiciy institut M. L. ya..Karpovas XOSCOW (Phys co_ SIP-' p63 02Se, DATS' ACQ: 331-lar64 su-@ C()'r'-w: SS, MICL: ()o NO RL"q, SOV: 004 003 Card 2/2 OTHM: All:KSANDROV, I.V.; KESSENIKH, A.V. Theory of spin-lattice relaxation of polymer radicals in a solid. Fiz. tver. tela 6 no. 4:1006-1012 Ap 164. (MIRA 17:6) 1. Nauchno-isaledavatellskiy fiziko-khimichoskiy in3titut imeni Karpova, Moskva. P,f ROM Me. KESSENIKII, Alckjandr VJ.-,.dlrJrovj.,+,; FAYINDOYIN!, IJI.) re.i. [Nuclear magnetic resonance) J;.deri@,ri magm.trly-I rezo- ., I nans. Vloskva, lzd-vo "Znanii3,11 1965. 31 T). v zliizni, nauke ' tokhrilke. IX Serila: Fi--Iva - Matematika. Astronomiia, nc..5) (?-'LflA 18:2) Y ALF, V' @Vlr)!@OVY 1. . 'L .@RSSFKKHA Isotropic auporfirn Interaction and spin-lattice relaxation of radicals In Uie Bolld phase. Part 4. Teoret. I akaper. kh1m. 1 no.2s221-228 YX- AP 06 5. (MIRA 18i7) 1@ In-,titut khlmicheskoy fiziki AN SSSR, Moskva I Nauchno-lasledovatellskiy f1z'1ko-kh1micheskiy institut imeni L.Ya.Karpova, Moskva. -777777