SCIENTIFIC ABSTRACT KHANALIYEV, N.M. - KHANANASHVILI, L.M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000721720018-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 18
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

KHANAK, E.
Providing the Hungarian Cotton Industry with Spare Parts. Leka Promishlenost
(Light Industry),, #12:35'-Dec. 1955

301 KHA AT-TYEV, N.M.
State of the excretory disintoxAation processes and the degree of
hemoconcentration in patients witkh burns tr4ted with novocaine-
furacillin-pyoctnnin solution. Izv. AN Azerb. SSR. Ser. biol. i
med. nauk no.3:95-100 163. (MIRA 16s6)
(Burns and scalds) (Pharmacology)

KEWIANTROY, A. R.
Tissue therapy of hearing disorders, Test. otorinolar., Moskva 14
no. 1:37-39 May-Juno 1952. (CM 22:4)
1. Candidate Medical Sciences. 2. Of the Clinic for Diseases of
the 1hr, Throat. and Nose (Head - Prof. D. I. Zimant), Rostov Medical
Institute.

~ i i ~ 'k : '., "I w 0 7. , A . ~ L .
Otoscl,-~rosis
Fene.,;trAt.iori In otwjcler-al-dJ- V-t. oto-rin. 14 no. /~, 1~)5,--,.
Monthly List, of Russian Acce:3sions, Library of 1loveiaber 195,!. U:,MAL-IFL~D

KWAMIWV, A.R., datoont
Fenestration of the ear labyrinth. Vest.oto-rin 17 no.3:34-39
my-Je 155. (HLRA 8:9)
1. Iz kafedry bolesnay lkha,gorla i nosa Rostovskogo-na-donu
meditsinakogn instituta.
(FENISMTION
technic)

KWAMIROVI A. R. Doc: Med Sci -- (diss) "The Surgical Restorati,*,oix
of Hearing, in. Otosclerosis Patients." Len., 195T. 28 pp 20
C~-
(Min of Health. RSFSR, Len. Sanitary-jHygiemr4- bleaical Inst) ,
250 copies (KL, 19~-571 88)

N
XHAIIAMIROV, A.R.,
doktor med.nauk
Skin plastic surgery in tympnnoplni3ty [vith summai7 in Bnglishl.
Vestooto-rIne 20 no.3:42-44 S-0 158 (MIRA 11:12)
l8 Iz kafedry bolezney ukha, gorla i nosa.(zav. A.R. Ehanamirov)
Goeudnretvennogo maditainskogo inAtituta, Rostov-na-Donu;
(EAR. MIDDIZ, surgery,
tympanople,aty with skin segment fror. Pxternal epr fold
(RUB))
(BAR, '-vXVW-AL, surgery
akin flap from posteior nurimilnr fold in tympanoplasty,
technic (Rus))

KMAKMOVv A.R.
Nov variation of non-free graft in tymWoplasty. Vest.otorin.
22 noo3s6l..64 MY-Je 160. (IKERA 13:10)
(TYWANIC KMRANE--SURGM)

KHkUMIROV, i.R., prof. (Rostov-na-Donu)
-----63R-a--e-r-v-a-tive tympanoplasty. Zhur. ush., nos. i gorl. bol. 21 nc.l:
15-19 Ju-F 161. (EAR--SURGM) (MIRA 14:6)

KHMAMOV,, A.R.j, prof* (Rovtov-na-Donu)
- - I------ -.. - -,-,
New international anatcmical terminology in otorldnolaryngology,
Vestn. otorinolaring. 25 no.30-16 163 (MIM 17 21)

KHANWIIROV, A.R., prof.
Classification of tympanosclerosis. Zhur.ush., nos. i gorl. bol.
24 nn.5:30-31 S-0 164. (MIRA 18:3)
1. Kafedra otolaringologil Rontovskogo meditsin3kogo instituta.

FC)TLAy ALAKOV,
mny."nomjy, L.K. P
-:r 1,~eq j,.n tne milll-
&I'd ulJ3 Of Olngle-aYIO Dlgr.ctl" fj
-lelcLruno 10
metor band, Radiotekll, c

KHANAMIROVA, A.A.
Investigating the association of germanium vith an organic
mass of coal. Trudy IGI 21:88-98 163. (MIRA 16:11)

S/l7l/6l/ol4/oo6/003/00=
E075/E136
AUTHORSj Manvelyan, M.G., Khanamiryan,. A~A
Bakhchisaraytoeve7. -S.A-.9 Mkrtchyanv N,T., and
Taliashviliq B,A.
TITLE~i Removal of silicon from pure potassium aluminate
solutions
PERIODICALo Akademiya nauk Armyanskoy SSR. Izvestiya,
Khimicheskiye nauki, v.14, no.6, 1961, 537-549
TEXT3 The object of the present work was to study the effe-~t
of factors such as temperature, exposure and caustic modulus of
original solution on the removal of silicon from pure potassium
aluminate solutions~ The apparatus used was a stainless steel
autoclave fitted with a stirrer and a heating jacket. The
solutions composed of potassium aluminate and potassium silicate
were heated at various temperatures (150-225 OC) for 1 to 10 hours
It was found that the increasing temperature leads to a better
degree of separation of silicon from the aluminate solutions,
The addition of A203 (2.0-20.0 g1t ) to the solution did not
increase the degree of separation. The addition of lime gave a
Card 1/2
Removal of silicon from pure S/171/61/014/Orj6/003/00-5
E075/E136
considerable increase in the separation afficiency via the
formation of calcium silicate. The optimal conditions for the.
removal of silicon from the solutions are as followsi
a) temperature 200 OC, treatment I hour, Cao added 15,0
aca,jst = L22 (to obtain alumina of V"l (G1) grade containing
O~121; S102), b) temperature 200 OC, treatment 0.5 hours, CaO
added 20.0 g/litre., a,aust.= 1,22 (to obtain alumina of GI gradp
-11% S1023; z) temperature 200 OC, treatment 2 hcur.3.
containing 0
CaO added 15.0 g/litreq acaust = 1.18 (to obtain alumina of highe.-
purity than the grade *1'0 (Go) containing 0.06% Si02)-
d) temperature 200 OC9 treatment 2 hours, CaO 20.0
= 1.19 (to obtain alumina of higher parity than grade GL,
containing 0,.025% SiO2). The proportion of A120-21 in -.he
solutions pre:;ipitating out under the above conditions :.s :~f tle
order of 8.77-!l,,66%. There are 4 figures and 6 tables,
ASSOCIATIONR Institut khimii Sovnarkhoza ArmSSR
(Chemistry Institute, Sovnarkhoz Arm,SSR)
SUBMITTED; July !55., 196L
Card 2/2

MANVETYAN, M.G., KHANAMIRYAN, A.A.i NIKWOSYAN, B.V.,q STEPANYAN, M.G. - I
Use of ubite slime as an active additive especially for desiliconizing
potassium aluminate solutions. TSvet. met. 37 no.9143-46 S 164.
(MIRA 180)
. r:;" j -,- z,-'
. u-!~, 1 -.1 ,
~a~ -- - I - . -
,~ - I " . -71 -

xHANAwRYAN, Kh.M.
Polarographic study of the catalytic decomposition of hydrogen
peroxide In homogeneous alcohol-aqueous solutions. Izv. AN Arm.
SSR. Khim.nauki 18 no,lt6-9 165,,
(MIRA 1815)
1, Arrrqanskiy nauchno-issledovatellskiy institut vinogradarstva,
vinodeliya i plodovodstva.

DZHANPOLADYAN, L.M.; KWMURYAN, Kh.M.; ABRANYAll, A.G., red.
(Polarographic methods for the analysis of brandy and
winel Poliarograficheskie metody analiza konliakov i
vin. Erevan, In-t nauchno-tekhn. informatsii, 1962.
10 P. (MLiA 17:3)

KHANLKIRYAN., S.A.
The 6586 centerless interral grinding machine. Biul,tekh.-ekon.
inform. w.8:45-47 161. (MMA 14:8)
(Grinding machinee)

MANVELYAN, M.G.; KHANAMIHW,-A..&.,* BAHCHISARAYTSEVA, S.A.;
TALIASHVILI, B.A.; MERTCHYAN, N.T.
Deeiliconizing pure potassium aluminate solutions.
TSvet. met. 35 no.,745-5i n 162. (MIRA 15:11)
(Potassium aluminate)

MAMLIAN, M.G.; KWAMIRYAN A.A.; MK.RTCHYANp N.T.; BAKHOHISARAYTSEVAO S.A.;
. TALIZ;4~~~ - -
Desi3laonization of pure potassium aluminate solutione,in presenos
of chemical-Sdditiven0TSvet. not. 35 no.11%66-74 N 162;
(KIRA 15S11)
(Potassium, aluminate) (Bilioon)

KHANANASHVILI, L. M. Cand Chem Sci -- (diss) "Interaction Between
A~
Tetraalkoxy- and Alkylalkoxy-Silanes and 4XXXV Their Derivatives
and Certain Inorganic Compounds," moo) 1957. 12 pp 23 cm-
(Min of Higher Education USSR, Mos Order of Lenin Chemicotechnolo-
gical Inst im D. I. Mendeleyev), 120 copiesA (KL, 26-57, 105)
- 22 -

7P7--
g4
Pf
Ap itll-Vl 11-W

KRESHKOV, A.P.; MTSHLTATIVA, L.T.;,jMANLNAM1VIL1V"1.X1
Interaction of tatraallcoiyeilanse and their derivatives with
several olasses of inorganic compounds. Trudy MMI uo,24*.333-
347 '57. (MIRA llt6)
(Silane) Otrdroxides)
4,

THARANASHVILI, L.M.1 KTSHLTATXVA, L.T.; MIKHAT V, B.M.; SHKOLINYY, V.Ye.
gum
Iffect of the aqueous solutions of sodium aluminates on
alk3rlakoxysilanes. Zhur,prikl.khim, 30.no.2:263-271 F '57.
(Mb" 10:5)
l.Kafedra analiticheskoy khimii Moskovskogo khimiko-takhnologichaskogo
instituta imeni D.I. Mendeleyeva.
(Sodium aluminates) (Silane)

KHANANASHVILI, L.H.
Producing na;i-nilicate materials b7 combining silicon organic
compounds with certain inorganic compounds. Soob. All Gruz. SSR
20 no. 3:307-314 Mr 158. (MIRA 11.7)
1. AN GruzSSR, Otdolenlye takhnichaskikh nauk, Thilict. Predetavleno
skademikon R.I.Agladze.
(Bilicatos)

T l? T,:: '--),nt h as i- of Orfr- no!~ J 1 icon (_~x i-:1 I)GI,"I" v Fr,,:- r, 1,;n.I -
(Polucheniye kremneorjr-_nichCP'7-_--Ii o*z,.si.-oy~jI-'in,~n_Jy iz -.,-.ino-
s-ilanov) I. Syntheuis cj~ tlu ron
A,-nyl -.minoiil=ncc "hich -'I-orn iikyl-chlorc-
silanes (I: Foluchcniye r_1kila1'kcksisi),:z!ov iL Llkilfrenil-
~minosilanov, sinteziv,,ye,,.,i,,'-rh
O"MIT I-
X "ILL: Zhurnf~l obshehe-y ;:h--r.:,' , )58, 7.)1. 28, N-~ 6, up. 211'~--!I,
( us --R )
AB"TRACT: ".,ith the further develo,,ment of tht: chemistry of organosi-Ii-
con compounds their prv-.ctic.,1 exploitc-tion has ~-e well. in-
creased. The alkyl-alkoxy sill.nes are uoe,j in the
of the iriodificaton of virious of inor;-nnic i-nd or-
ganic compounds t-M oc. Zemiprorluots fortthc. s,,nt~11c:7i! of vic
high-molecular organouilicon compoun(la (!-,'ef 1). Tiv- f*jll,,)7,in,,-,
syntheris methods of tho~-e compounds aro known 17-c'm nublicct-
tions: 1) .'lkylrution of tho alkox.v !!i1ancs or hr-logen alkoxy-
silanes with the aid of orrano7inc comDounds .nd mr-tallic
bard 1/3 ,,odium ('Ref 2) (2 `3,chemeij. 2) tion of +he -iilLn2!~

~51 Do
L ri un(:~- Irom ().P
synthesis of Organosilicor Ox--copo - - I
the Alkyl-Alkoxy Silones 2rom "hich Obt-,J-n,~A
2rom Allqyl-Chlorosilane2
or halogen -ith Vn~-- vAJ
poun'~,q or or).ranc1itj-.iwii 7"
(2 Schemec). -ubrtitution of ti-, in Ll'-yl
by f.11:oxy f-cou 'w~ in ti,: e~.-e o:: rci-4,~n o, ~.!C.-)1101" 4.11 tv.-,
p.r.,esence of lit,hium-, soditm--, --,nti rubi lium al-co-
holate (1 c'ehe-v' 1). 4) 'Ahe.-Ific of the alkyl ~tt
Thn2e m 7: hortcominCs. Cul',', t;
,:~.,oncmic tholigh the 1)2-,r, luc. tion
Courth method c;.ii be --ijed , I
of product!~ is accom-nn-Jed by io,-c;n,!:-.ry :,e-cticn~ . 'Thc .-A!'horv
.vorked out e now nynthesie methoi~ ,-,f T~-e P-
It consists in the transforn--tion of the o -c*- lord- -ilanen
with aniline with sub3eouent tre:)trient --ilh the -1-coholo of
the produced alkyl-phenyl ,.rAno (bofli reac+irm
cesses are giv~,n in the Ecl:uane,Z (0, ,, ~ nf, (b)). The -for
the scheme (a) :mounted. to 100 f-0-- the 2-ClICTIC (b) to
Ivrd 2/3 80 95 c'. Th,;rc -re 12 "Cvi
n~
KA

Synthevis of Or~ranoeilicon Oxycamnovn!~,, -rom
the Alkyl.-Alkoxy Pilanes 'From Alkyl-1henvi -!-Aiic!,~
F.rom Alkyl-Chlorovilanes
LT P?,, I ~11' JulY 10, 1957
'lard 3/3

MSHKOV, A.P.; MIKHAYLENKO, Yu.Ya.; MYSHLYAYLVA, L.V.; EHAIIANASHVILI, L.M.
Investigating the products of the reaction of some silicon organic
compounds with water-alkaline solutions of nluminatea, stnnnates, and
plumbites by means of infrared absorption spectroscopy. Zhur.prikl.
khim- 31 no.11:1746-1749 N 158. (MIRA 12:2)
(Silicon organic compoundB--Spectra)
(Spectrum analysis)

-)(0)
AUTHORS: Kreshkov, A., P.,j Keuhishyan, T.. IT, SOV/72 59-4-3/21
Ilyshlyayeva, L,. V.,,- Khananaahvili, L. X,
TITLE: Investigation and Application of Synthetic Organic Silicates
(Issledovaniye i primeneniye inkusstvennykh organicheskikh
silikatov)
PERIODICAL: Steklo i keramika, 1959: Nr 4., PP 11-14 (USSR)
ABSTRACT: The theoretical bases of the formation of organic silicates are
shown in the papers by A. P. Kreshkov, A. N, Chivikova, V. A,
Matveyev, G. 14~ Nessonovav IT,, L, Darashkevich (Ref 1),. The
syntbot1c silicates have a number of valuable properties.
good adhesion to glass., metal, asbestos.., tissues, and abrasives,
They may be used for the production of films for glass and
metal which do not break in !-.eating and they are also highly
acid...proof. The products which are obtained on the basis of
alkylalkoxy-silanes are characterized by a good solubility in
water. Their aqueous solutiens are used as hydrophobic im-
pregnations of building material, A,. P. Kreshkov, L- V~ Mysh-
lyayeva., L. Ms Khananashvili (Ref 2) carried out their spec:-
trum and X-ray structural analyses as well as the micro-
Card 1/2 crystallosaopic investigation Since it is possible to use

Investigation and Application of Synthetic Organi^. SOV/72-59-4-3/21
Silicatc:s
the obtained products as glues and coatings at high tempera-
tures their behaviour in heatinf, was thermoUaphically in,
vestigated., Por this purpose the self-recording pyrometer of
the Academi--,ian N.. S. Kurnakov was used as well as the
torsion balanoe of the U.-type, In those investigations the
authors refer to the papers by L~ M, Khananashvili, L. V,
1~yshlyayeva: -1J, A14, Mikhalev. V.. Ye., Shkollnyy (Ref 3)_ Thq
chaia;~teriatics of the prcdu,,,ts are Given in the tabled On
figures 1 -, 3~ 5., and 6 the beatIng curves of the products
4, and ' the
1, 2, 5, and 06 are plotted and on figures 2 1
cur-.res of weight in heating of the products 1. 2, and 6 are
given, The crystallo-optical investigatiors were performed
on the basis of the paper by D, S. Belyankin, V. Vc Lapinj
N, A, Toropov (Ref 4), As may be seen from the copyrights of
A,, P, Xxeshkov., L. V. Myshlyayeva, L_ M, Khananashvili (Ref 5)
the hitherto used skin glue which is a shorta.-e-good,, way be
replaced by a glue on the basis of synthetic silicates for the
gluing of tissues to grinding disks, The products obtained may
be used in various fields of building and silic ate material industry.
Card 212 There are 7 figures, I table,, and 6 Soviet references.,

83820
22- 0 5
AUTHORS:
TITLE:
PERIODICAL:
pp. 719-727
5/190/60/002/005/010/015
B004/Bo67
Andrianov, K. A,, ~hananashvili, L. M,, Konopchenko, Yu-F.
Synthesis of Eight-membered Mixed Organocyclosilaxar~2ej and
Their Polymerization\\
Vysokomolekulyarnyye soyedineni-ya, 1960, Vol. 2, Nc. 5,
TEXT: The authors cohydrolyzed t7io bifunctional organosilicon compounds,
m(CH ) Sicl +nRR'SiCl +(m+n)H 0 t. CH ) SiOjm [RR'SiO +2(m6n)HC1. By
3 2 2 2 2 3 2 1-1 n
,chydrolyzing dime thyld ichlorosilane and methylviny1dichlorosilarle they
obtained heptamettiylvinylcyclotetrasiloxane (1); hexamethy1divinylcyclo-
'.etrasiloxane (2); pen tame thy! trivi nyl cyclo tetra a i loxane, and by cohydro
lyz,-ng dimethyldichlorosilane with dietliyldichlorosilane they obtained
tiex~imethyldiethylcyclotetrasiloxane W. Furthermore, by cohydrclyzing
dimethyldichioroailane with phenylethyldiethoxygilane, hexamethylethyl
phenylcyclotetrasiloxane (5) was obtained; and by hydrclyzing methylvinyl
dichlorosilane in an acid medium, tetramethyltetravinylcyclotetrasilcxan,~
(6) was obtained. The yields were about 80%. The compounds were analyzed
by Z"'. M. Kuptsova. Their molecular weight and the bromine number of the
Card 15-

83820
Synthesis of Eight-membered Mixed Organocyclo- 3/190/60/002/r,05/010/01'r,
siloxanes and Their Polymerization B004/BO67
sompounds containing vinyl groups were determined. N, P, Gashnikova tcok
the infrared spectra. Fig. 1 shows the infrared spect-r-a -of ~lj and (5)~
The physical data of the compounds are given in Table 1. The authors poly-
merized compounds (1) - (6) by means of potassium hydroxide at 130 0C, and
studied the influence exerted by the various radicals on the cour3e. of
polymerization. Table 2 gives the results for (5) on variation of the KOH
concentration between 0.5 and 1-5%. With 0,5~a KOH the yield was 771.31PII';
with 1,5~o KOH it was 91-5~o, with decreasing viscosity. Fig. 2shews the
volume change in the polymerization of (5). The largest decrease in vclume
was observed with 0.5% KOH, Hence, the other compounds were polymer4Zed
by means of 0.5% KOH (Fig- 3). The experimental data are given in Table 3,
According to their influence on the polymerization coefficient., the ail.
oxang groups can be classified into the following series:
11".HC H C H C
\Si > 5 2,,~, S 1 5 2--,,, i.-,
H3C.~' H5C2"', 'I-, > H5 C61-,
There -ire 3 figures, 3 tables, and 9 references: 2 Soviet. US, I BritiE~h,
and 1 Japanese..
Cr,rd 2/3
Y~

S/07Y60/030/04/68/080
D B001 B01 1
AUTHORSt Kreshkov,.A. P-9 My Khananashvili, L. M.
TITLEs Investigations in the Field of Aminosilanes, Ij~ Methods of
Synthesizing Some Totraalkoxy Silanes'l
PERIODICALt Zhurnal obshchey khiwii, 1960, Vol- 309 110- 41 PP- 1347-1350
TEXT: The authors discuos the traditional methods of synthesizing tetre-
alkoxy silanes (Refs, 1-7).. AccordinL; to Ref- 4, the ternary mixture
Si(OC11 )4- Cff 3011-11CI boils at 69'. These components react with one. another
in two stagest 1) by reaction of 11C1 with the alcohol, under fcrm,Ition n.1'
methyl chloride and water, 2) by the hydrolysiri of erter by means of Wie
separated water until the precipitate nSiO 2 mll20 is formed. On analyzinG the
reaction products with a lower boiling temperature than that of SiOR0131 the
rtiithors- found them to contain considerable cuo,ntitio,; of tetraalkoxy cilaneo
,-nd alcoliol.-The change in the composition of low-boilinC fractions with
temperature is represented in the form of a triangular diagram in the cc-
ordinates Si(OR) 4-CH 3OH-HC1. Analytical and graphical data were similar for
Card 1/3
InveetiCations in the Field of Aminosilanes. S/079/60/030/04/68/080
II. Methods of Synthesizing Some Tetraalkoxy BOO1/B011
Silanes
acme syntheses, which fact made it Possible for this diae:.-am to be used for
the quick determination of the composition of the mixture by way of de-
termining gne component (HC1). Processes were investigated which take plar.,e
in the oyntheois of totraalkoxy ailanos. It wan found tll&t come ester of
orthosilicic acid can be obtained in much better yields by a compleme a
treatment of the side products as are obtained in the eBterification ntary
Sicl with
4' A new method of synthesizing tetraalkoxy silLnes wa~ worked out by
reactinC; chlorosilanes with different amines with a subsequent alcoholic treat-
ment of the resulting amino'silaness
SiCl4 + 6R11112 ~ Si(1111R)4+ 4RNH 2' Rcl ;Si(NHR)4+ 4R'OH
---> Si(ORI) 4 + 4RNH 2 (R = CH3! C 6 H5t CH3 C6H 4)'
There are 1 figure and 14 references, 12 of which are Soviet,
ASSOCIATION:, Moskovskiy khimiko-tekhnologicheskiy institut imeni D. I,
Mendeleyeva (Moscow Institute of Chemical Technology imeni
D. I. Mendeleyev)
Card 213

25040
S/062/61/001/006/002/010
B118/B220
AUTHORt Andrianov, K. A., Vasillyeva, T. V.)
and Khananashvili, L. M.
TITLEt Condenuation of methyl phoophinic ncid
with--.~/_ , c..) -- die thoxy- dime thyl siloxanvo
PERIODICALs Akademiya nauk SSSR. Izvestiya.
Otdeleniye khimicheskikh nauk, v. !, no, 61 1961, 1030-1035
TEXT: The present paper deals with the condensation of d.,, o,-)-diethoxy-
dimethyl siloxanes with methyl phosphinic acid. This reattion proved to
be an easy method of synthesizing the mixed organo-silicon phosphoruo
compounds resulting primarily in the formation of cyclic, not high-polymer
compounds. An increase of the distance between the alkoxy groups in
o(_ , (',,, -die thoxy -dime thyl siloxanes does not altei- the direction of the
reaction. In any case, the reaction proceeds according to the following
equation

Condensation of methyl phosphinic ...
HO 0
C H 0[(CH si61 H P
2 5 3)2 J2 5
HO CH3
25040
S/062/61/001/006/002/010
B118/B220
CIf7 0
2C H 011 ('CH ) si~ln PO
5 5 3 21
(n.1-5)
In the case of condennation of methyl phosphinic acid witho~,( ...-~-diethoxy-
' 11 0 C(CH ) Si C If . with
dimethyl siloxanes of the general formula C I
2 5 3 2 n C_ 5.
n = 1 to 5, it has been established that the siloxane bond does no' split
if n.:-7,4. In this case, the cyclic -compounds formed contain as mLny
dimethyl siloxane groups as the initial cj -die thoxy-dim~Ahyl siloxane.
Thus, on condensation of methyl phosphinic acid with a-, 0.'~- -diethoxy-
dimethyl siloxane, the following compounds have been separatedt hexamethyl
cyclomethyl phosphinoxy-trisiloxane if n - 3, and octamethyl cyclomethyl
phosphinoxy-tetrasiloxane, if n - 4. On condensation of methyl phosphinic
acid with V-, c,) -die thoxy -dime thyl siloxane, tetramethyl cyclomethyl
phosphinoxy-disiloxane is fcrmed if n - 2. Conderiqation of methyl
phosphinic acid with dimethyl diethoxy silane results in tetramethyl
Card 2/ 4

25o4o
S/062/61/001/006/002/010
Condenoation of mothyl phosphinic-, B118/3220
cyclodi (methyl, phosphinoxy) disiloxane. On condensation of methyl
phosphinic acid with 'IC, 6) -diethoxy-dimethyl silo,.-ane, the siloxane bend
splits to form hexamethyl cyclomethyl phosphinoxy --.rigiloxane if n
whereby only a rinall of decameth-il, oyclc~metli-`
siloxane is separ;Aed. T he reoti 1 t i n 6 0 oL r I o.;o, , V 1V (: ~) L~ t! I i I ia 10 L! ki I S, t I I I alt; 1
in vacuo are hydrolyzed alrea-Ay atrno.-;phoric inoi!;ture. I n fra
absorption opectra(besides the
the composition and structure ,-~f hex~imet?;'A cyc1om(.th,,,-1 rhosi.hinoxy-
trisilo.-~ane, t,.-tramethyl phosjh1noxY-diSil0XanU, Und fk~tr--,moth';-1 cjfclo.~:l
(methyl phosphinoxy)di.siIo-.:ane., The bands characte.i-,~tic of thc. i-rCL.PZ:
CH3; Si-CH3; P = 0; and were dutected iri ,pectra,. 'Pile
spectra of hexamethyl cyciomt,thyl tetv,.,a&thyl
cyclodi(methjl phosj)hinoxj)di:;ilcxaiie, tetramethyl hos~,hirioxy-
P I
disiloxe-ne show absorption batid, of the 1,roups Si-O-r alld, Si-O-~31 I n
order to c ..nf i rai the s true tui-e o f hexamv th - I!
., cyclon.%Lh I phosphinoxy-
trisiloxane, tetramethyl, cjclomethyl phosphinoxydi.,;i1c,-.irc, and tetramethyl.
di(methyl pIlosphinoxy)disiloxane. the,;e compounds tu a
hydrolytic ,iecomposition. The water dectroys I~tTter accovdil,.g to
Card 3/ 4
"'iA,, Mr

Cond,risatio:i of mcItiji
t e 1"t llowi vj- :-(Iuaf i
25U --c
I
(c1!
3
This lvyarul-eio n r-y - pr:) A!, h.
for takiaA t1lie pr--A-r~ oi' *i :;,ri ;;n.-1%- -t; -0 r, r-
5 f i~-!) "e3 3 t ubL es nor,-';--vi, *:"!-)c re! -,-~rc- -et. r,..,:e
c"1 1 3 e
291 b ( 1 ~1~4 9
ASiOCIATION: Ins ti t D Vnkuy Ki. 1 -11 telklli-, -A C-L,
Lomonor,v,! (1031-ItUtf -,i- 'Fl;ie Ciiei.'A i
S11 51AITTED: July 6.
Card 4/4

S/07 61/016/006/006/006
B106YB147
AUTHORS: Andrianov, K. A., Khananashvili, L. M., and Vasillyeva, T.V.
. ...................
TITLE: Methods for determining phosphorus in phosphorus silicon-
compounds
PERIODICAL: Zhurnal analiticheskoy khimii, v. 16, no. 6, 1961, 738-739
TEXTz The authors suggest a simple method for determining phosphorus in
phospho-organosilicon compounds with the structure
[R Sio] Por,0 which is based on their hydrolysis:
2 L n I "N CH3
0"
[R P + H
2S'O] 20 [R2S'O]n + CH3P(0H)0
L
0 CH3
Card 1/1

S/07 61/016/006/006/006
Methods for determining B1o6YB147
?I
R3SiO-P-O-SiR 3+ H20 ----) CH 3P(OH)2 + R3Si-O-SiR3
0.2-0 CH3
.3 g of the substance is dissolved in water and subjected to
hydrolysis for 4-5 hr. When heated to 800C complete hydrolysis is
already achieved after 30-40 min. The alkyl phosphinic acid is titrated
by analkali 0.1 N in the presence of thymol phthalein (pH 9.4-10.6).
Compounds of the general formula
CH ) SiO].P 0 were analyzed by the above method (n - 1, 2y 3). In
k
3 2 LoJ CH3
all cases, the results were in good agreement with the results expected
from the formula. Deviations of parallel determinations amounted to
0.2-0.3ci'o. There are 2 tables.
ASSOCIATION: Moskovskiy institut tonkoy khimicheskoy tekhnologii im.
M~ V. Lomonosova (Moscow Institute of Fine Chemical
Technology imeni It. V. Lomonosov)
SUBMITT D: July 6, 1960
Card 2

$144
S/079/61 031/001/018/025
BOO1;fBO616
AUTFORS: Andrianov, K. A., Zhdanov, A. A.,_Khananashvift, L. M., and
Shapatin, A. S.
TITLE: Reactions of Aluminum Isopropylate With Some Organo-
phosphorus Compounds
PERIODICAL: Zhurnal obshchey khimii, 1961, Vol. 31, No. 1, pp. 224 - 228
TEXT: The authors studied the reaction of aluminum isopropylate with the
acid chlorides of methyl-m-cresoxy phosphinic acid and dimethyl phosphinic
acid, in order to use them as initial products for the synthesis of
polymers with inorganic molecular chains. One of the initial organo-
phosphorus compounds, the acid chloride of methyl-m-cresoxy phosphinic
acid, was obtained by reaction of methyl phosphinic acid dichloride with
m-cresol at 120 - 1400C, 0 Cl
I[/
CH3Li 2 + m - CH 3C6H4OH )CH 3P OC 6H4CH3 M+ Ecl (1)
Card 1/3

89484
Reactions of Aluminum I8opropylate With Some 8107916,11031100110181025
Organophosphorus Compounds BOOI/BO66
As by-product, considerable quantities of di-m-cresyl ester of methyl
phosphinic acid are formed. Higher excess of the dichloride of methyl
phosphinic acid gives a large yield of the chloride of methyl-m-cresoxy
phosphinic acid and a low yield of the afore-mentioned by-product. The
reaction of the chloride of mothyl-m-cresoxy-phosphinic acid with
aluminum isopropylate was expected to proceed according to the following
equation: 0
?, " Cl 11 'QH3
CH3; \ OC6H4CH 3-m+ Al(OC3H7- i90)3 ---+i-C3H7C1 + (i-C3H70)2 Al-O-P\ OC6H4CH 3-m
However, in addition to isopropyl chloride, also the isopropyl-m-cresyl
ester was separated which is indicative of side reactions. At an elevated
reaction temperature (140 - 2000C) still more complicated compounds
resulted, which renders the separation of individual reaction products
very difficult. To confirm the assumption on the course of reaction,
tris(methyl-m-cresoxy-phosphinoxy)aluminum was synthesized. The reaction
was carried out at 90 - 1000C to avoid separation of the cresoxy group.
Under these conditions, tris(methyl-m-cresoxy-pliosphinoxy)aluminum
resulted in a yield Of'59 %, isopropylchloride in a yield of 67 %, which
Card 2/3
Reactions of Aluminum Isopropylate With Some
Organophcaphorus Compounds
8144
S/079/61/031/001/018/025
BOO1/BO66
confirmed the predicted course of reaction. The reaction of dimethyl
phosphinic acid with aluminum isopropylate takes place according to
equati8n (5): 0
(CH 3)2 6 + (i-C 3H70)3Al )(i-C3H70)2A1-0-P11(0H 3)2 + '_C3H 7OH.
This is confirmed by a nearly quantitative separation of isopropyl alcohol
(99 %). According to ultimate analysis, the product distilling from the
reaction mass at 1640C corresponds to dimethyl-phosphinoxy-(diisopropyl)
aluminum which is conta 'minated. The vitreous, colorless product is soluble
in common aromatic solvents. G. B. Ravich and I. F. Manucharova are
thanked for their cooperation. There are 1 figure and 10 referencest
4 Soviet, 2 British, 2 German, and 1 Czechoslovakian.
ASSOCIATION: Moskovskiy institut tonkoy khimicheskoy tekhnologii
(Moscow Institute of Fine Chemical Technology)
SUBMITTED: February 20, 1960
Card 3/3

88485
5/079/61/031/001/019/025
15-Slitj 2U5 BOO1/BO66
AUTHORS: Andrianov, K. A.,.Khananashvili, Kazakovaq A. A.,
and Ivanov, A. A.
TITLE: Synthesis of Poly(phenoxy-methyl-phosphinoxy) Aluminum Oxanes
PERIODICAL: Zhurnal obshchey khimii, 1961, Vol. 31, No. 1, pp. 228 - 231
TEXT: Following their papers of Refs. I and 2, and in view of Ref- 3, the
authors now studied the syntheses of some organophosphorus-aluminum com-
pounds and tried to convert them to polymers with a principal chain of
aluminum oxanes. The synthesis of these organophosphorus-aluminum com-
pounds was made by esterification of the acid chloride of methyl phos-
phinic acid with phenol, combined with a reaction of the resultant methyl-
phenoxy phosphinic acid chloride with aluminum-n-butylate, according to
the equation: CH3
/C1 /C1 Al(OC4H9)3,
CH P 0 +C H OH CH I(C H Al - 0 -P/=O + C Hocl
3 \ 6 5 3r - v 4 90)2 4
Cl OC6H5 M (II) 0C 6H 5 (111)
Card 1/3

Synthesis of Poly(ptienoxy-methyl-phosl)iiinoxy)
Aluminum Oxanes
$8485
S/07 61/orl/Or)1/019/025
BOOlNo66 -)
Compound (I), hitherto not yet described, was separated in pure condition
by distillation of the reaction products (26.2 %). The low yield is due to
the formation of compound CH 3PONC 6H 5)2 and, presumably, of a mixture of
condensation products of the organophosphorus compounds present. The yield
of butyl chloride was 58 %. The reaction carried out at 80 - 900C yields
phenoxymethyl-phosphinoxy-dibutoxy aluminum (II). Elevated temperatures
give compounds insoluble in organic solvents. The viscosity of the product
of the hydrolysis of compound (II) rapidly increases. This hydrolysis
probably givess
C4H90 -Al -0 -Al- 0 The increase in viscosity depends on the water
quantity applied, it is most pronounced at the
beginning reaction. The hydrolytiis products
CH, separated from the solution are solid compounds
~Pj = 0 CH3P= 0 soluble in butyl alcohol. A study of the thermo-
Oc6H5 L 6H5 mechanical properties of the hydrolysis products
reveals that an increase on the water quantity in the above hydrolysis
does not affect the flow temperature of the polymer con3iderably, but
somewhat decreases the interval between the temperaturessof vitrification
Card 2/3

Synthesis of Poly(phenoxy-methyl-phosphinoxy) S/079/61/031/001/0101/025
Aluminum Oxanes B001/B066
and of flow. Evaporation of the polymer solution on a solid surface gave
brittle films. There are 2 figures and 3 references: 2 Soviet and I German.
ASSOCIATION: Moskovskiy institut tonkoy khimicheskoy tekhnologii
(Moscow Institute of Fine Chemical Technology)
SUBMITTED: February 20, 1960
Card 3/3

3/062/62/0oo/oo6/oO6/0O8
B117/B101
AUTHORS: Tsitsishvili, G. V., Bagratishvili, G. D., Andrianovt K. A*9
Khananaahvili, L. M., and Kantariya, M. L.
-----------------------------
TITLE': Study of infrared spectra of cyclic organosiloxanes
PERIODICAL: Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no. 6, 1962, 1014 - 1019
':;XT: Infrared spectra of octamethyl cyclotetrasiloxane (I), trimethyl
triphenyl cyclotrisil6xane (III), tetramethyl tetraphenyl cyclotetrasilox-
ane (IV), and 6 cycloorganotetrasiloxanes with methyl, ethyl, ethoxyl,
butoxyl, phenyl, vinyl, and nitrile groups were investigated. The infrared
spectra of (I), (M), and (IV) agreed with those described in the litera-
ture. The spectra of the other 8 cycloorganotetrasiloxanes were obtained
for the first time. Stretching vibrations of the Si-OvSi group w6re de-
termined for all organotetrasiloxanes in the form of broad, very intense
loao-1089 cm-1 tJ;
bandsl the positions of these were constant and scarcely V -,
effected by the character and number of the substituents. 1he correspond-:--
ing band of the trimers appears at 1020 cm-1 and is less intense. The
Card 1/3

3/062/62/000/006/006/00.8
~Jtudy of infrared spectra ... B117/B101
bands corresponding to the stretching vibrations.of the CH-CH group were
lound for compounds with 1 to 3 vinyl groups at 1596 cm -thgy became
more intense with increasing number of these groups. The lower frequency
of stretching vibrations of the C-C bond is due to the strong effect of
the Si atom on the vinyl group. This effect is greater than that of the
conjuFate phenyl ring, and is commensurable with the effect of conjugate;
C__
%. or C-0 bonds. The bands of the vinyl group found at 959 and 1006 cm,
originate in uneven deformation vibrations of the CH bond in -CH 2 and -CH.
The intensity of these bands grows proportionally with the number of vinyl
~~roupa. Bands corresponding to stretching vibrations of the Si-C 6H5 group
%-;ere found at 1434 cm-1for organocyclosiloxanes with phenyl groups. The
1034 cm-1 band ascribed to the Si-C 6H5 group by L. Spialter, D. S. Pries ts V
C. Harris (J. Amer. Chem. 800- 77, 6227 (1955))' is masked by the vibra-
tiona of the si-O-di aroupt it iLppears distinatly in trimara onlyt 3tretah.
ing. vibrations of the SiICH and SI(CH ) groups were observe4 inalli.cyclo-
3 1 3 2 -1
organosiloxanos in the form of broad bands at 1258-12 3 cm . Banda at
96o and 1010 cm-1 were found for theethyl radical bound to silicon corres-
Card 2/3
M

3/19 62/004/004/015/019
B1 17YB1 38
AUTHORS Andrianovt K. A., Khananashvili. L. M., Belenlkaya, I. S.
TITLE- Synthesis and polymerization of dimethyl cyclosilozanes with
silsesquioxane bonds
PERIODICAL: Vysokomolekulyarnyye soyedineniya, V. 4, no. 4, 1962, 591-595i
TEXT% Bi- and tricyclic compounds of the dimethyl miloxano series with
0
silsesquioxane bonds - 0 - Si""' were obtained by hydrolysis nnd con-
____0
densation of hexamethyl ethyl cyclotetrasiloxane and totramethyl diethyl
cyclotetrasilorane. The hydrolysis of the hydrogen-containing cyclotatra-
uiloxanes synthetized by the method described in flef. 3 (N. N. Sokolov, Zh.
obahchey khimii, 22, 248, 1959) was carried out in alkaline medium (caustic
soda) at room temperature, and the condensation in acid nedium (hydrochloric'
acid, DH 5) at 40-450C. The following substances were obtainedt
bis-(h~xamethyl ethyl cyclotetrasiloxanyl)oxide (1) (Si 8016H 46 09, boiling
point 135-1470%fO'/1-2 mm HG) and a ~rioyclio compound (II) with the atructureil
Card 1/3

B/190/62/004/004/015/019
Synthesis and polymerization... B117/BI38
0 COIS 0 C'11' 0 o
0 0 1, 0 0 V11' 0 0
(ClIsh (CI[3)1 (C113),
(Si C H 0 boilirg point 240-250OC/2'10-.2 mm Hg). Both compounds;are
12 24 68 14'
readily soluble in benzene, toluene and ethyl alcohol. They easily poly-
merize at room temperature (in toluene solution in the pre3ence Of 0-3%, KOH)'~
(1) producing an insoluble polymer after 93 hr and (II) after 20-5 hr. The
reactivity increases with a higher number of allsesquioxane links in the
chain. The-stronger reactivity of silsesquioxane bonds as; compared with
siloxane bonds is probably connected with the fact that the silicon atom
bonded with three oxygen atoms is more electropoeitive and the attack of
these bonds gets more effective during the:;aotion of nualeophilio reagents.
There are 2 figures and 1 table.
Card 2/3

37b3*7
8/190/62/004/005/013/026
B110/B108
AUTHORS: Andrianov, K. A., Vasillyeva, T. V., Khananaahvilit L. M.
TITLE: Polymerization of dimethyl cyclomethyl phosphinoxysiloxanee
PERIODICAL: Vyaokomolekulyarnyye aoyedineniya, v. 4, no- 5, 1962, 708 -713
TEXT: An attempt was made to polymerize inorganic cycles containing
silicon, oxygen, and phosphorus, and to copolymerize them with octamethyl
cyclotetrasiloxane. Tetramethyl cyclometh,,1 phosphinoxydisiloxane and
hexamethyl cyclomethyl phosphinoxytriailoxane were polymerized with H 2 soV
dichloroanhydride of methyl phosphinic acid, tin chloride, and KOH. The
slight increase in viscosity indicated that polymerization was very poor .
The thermal copolymerization of octamethyl cyclotetrasiloxane with tetra-
methyl cyclodi(methylphosphinoxy)disiloxane proceeded slowly while forming
low-molecular products. In addition, the copolymerization of octamethy!
cyclotetrasiloxane with tetramethyl cyclomethyl phosphinoxydisiloxane or
tetramethyl cyclodi(methylphosphinoxy)disiloxane was studied at Si;P
ratios of 6:1, 21:1, 42:1, 101:11 201:1, and 301t1 in the presence of
water-The amounts of water were sufficient for the hydrolysis of
Card (1
E, 1A
T
-'s~ ,,A
_;.~~ - ~ `3 ' - '_U'A AIN
V" A

3/19 62/004/005/013/026
Polymerization of dimethyl .... B110YB108
dimethyl cyclomethyl phosphinoxysiloxane. Two of the resultant polymers
were.liquid, and three wore olastomers with (n) equal to 0.100, 0.202,
0.448 and with molecular weights of 12,590; 37,150; 125,900, respectively.
At a ratio of Si to P - 21:1 and at a temperature of 1000C, polymerization
takes place within the first six hours. At Si:P - 421l, the rate of Poly-
merization is temperature-dependent. The resulting transparent polymers,
which are soluble in organic compounds, become dull, insoluble, and 'elas-
tic on standing in air. The structuralization, which is irreversible
after 60 min, is attributed to the formation of a hydrogen bonds
0
-P-011 .......... 0
.1 1
C11 - Si - CIIS
.. I
A built-up system is formed if the polymer chain contains several methyl
phoophine groups. The resultant intermolecular forces cannot be removed
evcn by boiling in polar solvents for 30 hrs. The structuralized polymer
exhibits an infrared absorption band at 1600 - 1700 cm- 1. A study of the'
Card 2/3

ANDRIANOV, K.A.; MANANASHVILI, L.M.; BELEIIIKAYA, I.S.
Synthesis and polymerization of dimethyleyclosiloxanes with
siluesquiaxanic bonds. Vysokom.soed. 4 no.4:591-50.5 Ap 162.
(MIRA 15:5)
1. Moskovskiy institut tonkoy khimicheskoy tokhnologii L-leni
Lomonosova.
(Silicon organic compounds)
(Pol-ymerization)

S/079/62/032/010/008/008
D2147D307
AUTHORS: Andrianov, K.A.p Khaydukt Ionelp Khan4nashvilip L.Me,
and Nekhayeva, N.I.
TITLE: The synthesis of dimethylcyclosilthioxanes
PERIODICAL: Zhurnal obahchey 4imiip v, 32,.no, 10, 1962, 3447
.TEXT: A description of the synthesis of two examples of a hitherto
unknown class of compounds: cyclosilthioxanes. The treatment of
1,3-dichlorotetramethyldisiloxane with H 2S in the presence of pyri-
dine gave a crystalline compound (b. range 116-122 0C/2 mm HG; m.p.
38-420C). Prom the quantitative analysis of this*compound and from
ir, which showed the presence of Si-O-Si, Si-S-Si.and Si-CH 3 ~,onds,
the structure was found to be (CH 3)2 M 0 Si(CH 3)2S Si(CH 3)20 S'
70H -1. Under similar conOitions 1,5-dich'loro-hexamethyltr.1%.siloxa-
372S
ne gave-a colorless# transparent li uid (b. ran&e 1'70-172.50C) the
structure of'which was shown to be ~CH,121 Si(CH ~ SSi(CH
)2 3 2 3)20
Card 1/2

The synthesis of ... 9/079 62/032/010/oo8/008
A"OCIATION.- Moskovskiy institut tonko D214YD307
imeni 14&V. Lomonosova (MOY khimicheskoy tekhnologii
cal Technology 'imeni M.,V. sLcomwonnossovit)ute Of Fine Chemi-
SUBMITTED: May 20, 1962
Card 212

TSITSISHVILI, G.V.; BAGRATISHVILI, G.D.; ANDRIANOV, K.A.; KHMT iASffYIU,-,
L.M.; KANTARIYA, M.L.
Infrared spectra of cyclic organosiloxanes. Izv.AN SSSR.Otd._ .
khim.nauk no.61-1014-1019 162. (KRA 15t8)
1. Institut khimii im. P.G.Helikishvil-i All Gruzinskoy M i
Institut tonkoy khimicheskoy tekhnologii Im. M.V.Lomonosova.
(Silicon organic compounds-Spectra)

TSITSISHVILI) G.V.; BAGRATISHVILI) G.D.; AMRIANOV) K,A.;
Y"ARIYA, M.L.
Infrared spectra of cyclic organosilazanes. Izv.AN SSSR.Otd.khim.
nauk no.7:3.197-U98 J1 162. (KM 15:7)
1. Institut kbimii im. P.G.MLllkishvili AN Gruzinskoy SSR i
Inatitut tonkoy khimicheskoy tekhnologii im. M.Lommiosova.
(M.1azanes-Spectra)

S/079/62/032/007/005/007
1032/1232
AUTHORS: Andriyanov. K. A., Vasil'yeva T. V., Nudelman Z. N., KhananAsh ., Kochetkova,
ZflLj4,ffi
A. C. and Cherednikova, A. G,
TITLE: Dime thyl-t in-d ichloride; its synthesis and a study of its reaction with disodium salts of
dimethyl-siloxanes.
PERIODICAL: Zliurnal obshchei khimii, v. 32, no. 7, 1962, 2307-2311
TEXT: Reaction of methyl chloride with stannous chloride in the presence of spongy metallic copper gives
dimethyl-lin-dichloride (1) and methyl-tin-trichloride (11) accordi ng to the scheme
2SnO + 2CH3Cl - (CH3)2SnCI2 + Sn02,
2SnO + 3CH3CI - CHAnC13 + Sn02 + CH3CH3.
The reaction takes place between 250'and 350*C, the yield of the process and the ratio between I and Ilinthe
reaction product are temperature dependent. At 250*C mainly dimethyl-tin-dichloride is formcd.The reaction
of dimcthyl tin-dichlorides and diethyl-tin-dichlorides with disodium, salts of dinwthyl-sitoxanes gives polymer
pioducts the molecular weight of which exceeds 3000. There is I figure and 3 tables. The English-language
reference (8] reads: E. Rochow, Sff~ith, J. Am. Chem. Soc., 75- 4103 (1953).
SUBMITTED: July 5, 1961
Card 1/1

ANDRI"OV, K.A.; KUYDUK, Ionel; KHAKAUSHVILI, L.M.; REKRAYEVA, N.I.
Synthesis of dimethyleyelosilthioxane. Zhur.ob.khim.
32 no,100447 0 162. (MIRA 15:11)
1. Moskovskiy institut tonkoy khimicheskoy takhnologii
imeni. M.V. Lomonosova.
(Silicon organic compounds)
(Oxathiana)

ANDRXANOVP K.A.; pIKHOVOV - - '- `~
[Ran En-tsg]; 3' V-S-1 KHAMAN
KHANI S'- -4TIUA L.
. Shu_,, " KHANI Ent_
HYdrol,vtlc f~ TSM
no a t a bl.U ty I
12:25-27 )162. 0r PolyOrganoborosilOxanes. plast.
Siloxan8s (Boron (massy
org&n'c comPounds) (gydrolysls) MMA 16:1)

AhDRIANOV., K.A.; VASILUVA, T.V.; NUDEL114AN., Z.N.; L-M-;
KOCHETKOVA., A.S.; CHERONIKOVA,, A.G.
Preparation of dimethyl tin dichloride and study of its reaction
with disodium salts of dimetbylsiloxanes. Zhur.ob.khim. 32
no.7:2307-2311 Jl 162. (KM 15:7)
(Tin
) (Siloxanes)
organic compound

ANDRIAMOV) K. Ao; KHANAMASHVI-L-Ii, L. PM,.; x1jul ENj
TIKHoNOV -r- -- -TSz
I , a. ElHan En-ts,.];
Reaction Of dimetVIdichloms,
khi,m. 32 no.12 lane with iron Oxide. Zhjr
'3951-3952 D 162. (MIRA 16;1) * Ob.
I, HOakovski3r Institut
M* V* LOMOnOsova, tonko3r khimicheskoy tekbnolg,, imeni
(S'lane) (Iron Oxides)

anj, 5jji.(rp-Tgg_njr pr,j~n.1rotlianeS w!Lr R
P.- ,~,y~oVIippqivq ~Hpiprr,,,rialp. Yld~
I- V ul)~m-nullokii I V-arr v
is ox` A
Ap
44''k'.
on
-pg: ZA
IL -

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-or icm fj of
i1 propertles of these (-,)mpoundB wi5re then tziveatigat~od B v ic sa mi
-r ~ivi M, I

1-M
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ft 35;t
gg

IF% r R F 'I i
~~,M, 0 N 'TR A T 4
Zcu ~"~71
al
tp r A I s- 1 oct-Rmo 0~ y!
letTlaKis- fnexa-
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404 rox
--Yd YYBU
t 40 t %a 46:
t, 112
lu
91 ------
10.80 1
lot
4%A,,Ocfro;ff$o
Y.- 7 --~_E -~777
-' ;,-E,
7777

ABRILNOV, K.A.; KRANANASHVILI,-L.Mv; TIKHONCIV, V.S.;
KUN1-SftMY-UY-[H-an Shu- ],- KMNI-ENI-TSZE (Ilan En-tsg]
,YU
Polyorganoborouiloxanes. Flazt.massy no.1:21-25 163. (MIRA 16-.2)
(Boron organic compoundB)
(Polymers) (Silmcanes)

L 17C~63:!�~ EJ,P(j )/EPF(c )/EWT(M)/BDS S/062/63/000/004/009/0?9
A S D Pc-4/ilr-4 R,%Vwoj
I., Khananashv
AUTHCR: ApdrjAnoy, qv Ili ]I., and
PIpyag1pa A.
TITLE; On the condensation ofo( , 0 -dihydroxymeth s
,ylsiloxane with 1,
3-ftacato-1, 3-dimethyl-1,
PERIODICAL; Akademiya nauk SSSR. Izvestiya. Otdoleniye khimichaskikh ran*.
no. 4, 1963, 651-654
TEXT: The synthesis of-linear polymers by the reaction of polycondensa-
tion of oligomers of the dimethylsiloxane type with Vie hydroxyl groups at the
and of chains with ollgomers containing the acetate groups, for example, 1, 3-
diacetoxy-1. 3-dimethyl-1, 3-dipharqldisiloxane was of interest to the authors.
The reaction of alpha, omega-dichloromethylphanylsiloxanes with acetic anhy-
dride was studied and several alpha, omoga-dlacotoxymothylphorqlsilo=nos were
synthes-ized. The condensation between alpha, omega-dihydroxyo--tamethyltetrasi-
loxano and 1,3-cUacetoxy-l. 3-diphonyldisl2ozane was conducted. The p0lYmer
formed has a higher vitrification temperature (-550) than the polymer based on
Card 1/2
M2f- ~--M

-S/06-*163/000/004,1009102Z
On the condensatio n of .....
heptamethylphonyloyclotatrasilo=ne (-?00). There are 2 figures. The 2
Enilish-language references read as foUaws: W. H. Davdt. J. F. Hyde, J. Amer
Chem. Soc., 74, 386 (1952); P. George, L. Sommer, F. Whitmore, J. Amer. Chem.
Soo-, 75. 1583 (1953).
ASSOCIATIONt Institut toz&oy khimicheskoy tekhnologii im. M, V. Lanonosova
(Institute of Fine Chemical Technology imeni M, V, Lomonosov)
SU&%C=
a 15,
Card 2/2

ACCESSION NROO AP3000233 8/0062/63/000/0()5/0948/0950
AUTHOR: Andrianov,, Ke Aq Khqduko lonel; Khananashvili,, L. M.; Intarev, M. B.
TITLE: Synthesis of vinyl derivatives of cycloaila anes
SOURCE: AN SSSR. Izvestlyao Otdeleniye khimicheakikh naukj, no. 5. 1963, 948450
'TOPIC TAGS: si2.azanesp silanes,, vinyl derivatives,, coammonolysis
ABSTRACT: Trimethvltr-4.vinyloyclotrisilA ans and -betramethyltatravinyloyclotat.~~
,silazane were obtained by reacting methylvinyldichlorosilane with gaseous ammm-da
in benzene. Coammonol7sis of methylviny1dichlorosilans with dimeth,71dichloros;Uane
.yielded two six-memberod cyclic derivatives and one eight-merabered cyclic derkra-
tive. Coammonolysie of methylvinyldichloroai Ian with diethy1dichlorosJ I ane rv.--
sulted in the formation of six-membered cyclic derivatives only. The seven syn-
thqsized compounds were identified by means of elemental analysis and through deterr
mination of molecular weights$ molar refractive indices and infrared 5pectra.
Physical constants of the seven compounds are oumarized in.-,& table. Origo ar'w.
has: 5 formulas and I table*
.ASSOCIATIMI: Mbskovslki~ institut, tonkoy khimicheskoy tekhnologii ime K. V9
law~%~a (Hoacow Institute of Me'Chemical Technology)
Card

:ACC=Iom-s~. ---
"1"'TTZ): 29Dec62
SUB COI)s: CU DATZ ACQ: Wun63 ENCL: 00
OTHM: 003
TCcrd

L 11062-63- FPF(c) /Fwp(j) lowp(lowr (m) /Bro-AMr, --PM/MAY/
ACCESSION M: AP30.01449 W/J~/J(; S/0074/63/032/005/0539/0589
AUTHOR: Andrianov. K. A.; Xhayduk, I.; Khananashvili, L. M. I )
'10
TITLE-. Inorganic cyclic silico compounds and their organic derivatives
SOURCE% Uspekhi khimii, v. j2. 2.5, 1963, 339-589
TOPIC TAGSi heterocyclic, functional aMca.group reaction, hamofunctional con-
densation reaction, haterofunational condens&tion reaction, reaction of siloxane
bond rupture, organic radical, separation reaction, the silica atom; mixed cyclic
silicon compounds, polycylio compounds, polymers.
ABSTRACT: This article summarizsthe orks dedicated to the chemistry of in-
Qreanig evelic silicoh-compounds ncluXg the works of 1962. For the conve-
ni6nce of study, these-compoun0viere broken into hcmocyclic compounds composed
of silica atoms only of the formula - [R sub 2 Sil sub n. This group includes
cyclotetrasilanes and cyclohexasilanes. Cyclohexasilanes are more stable than
cyclotetrasilanies since the stress on the ring of the first is mnallor. Hetero-
cyclic compounds have heteroatoms of 0, K, S, and So in place of silica atoms.
Ydxed cycles are obtained when a portion of the conjugated ilica atoms are re-
placed with P, B, or others. Cycles containing conjugatedfatems of 0, N, and 3
are more stable than homogeneous cycles since the later has lower electroneg&-
Cord
--------------

L 1106-2-63
ACCESSION NR: AP3001449
tivity. Cyclosiloxanes have a general iormula [R sub 2 SiO] sub n and contain frm
3 tQ-12 SiO groups 'per cycle. After the formation of the cycle, the free valences
of silica can be replaced vith inorganic groups (R = Cl, Be. OH or __O sup
or organic groaps (R = aryl, alkyl), or other functional groups. The inorganic
cyclosilicatos are found in the anionic forms of 1i sub 3 0 sub 9 sup 6-, SiO sub
12 sup 8-, and Si sub 6 0 sub 18 sup 12-6. The organic cyclosilanes containing two
organic radicals attached directly to the silica atom can be prepared by the fol-
lowing reactions: functional silica group reaction with substances capable of gi-
ving off oxygen (water, alcohols, ketones, others, metal oxides, etc.). The most
important method in this reaction is the hydrolysis of functional silica groups.
Homofunctional condensation react:Lon is promoted by heating, pressure, and cataly-
tic reaction of acids or bases. Heterofunctional condensation reaction is promo-
ted by heating in the presence of Friedel-Crafts catalyst reaction. The reaction
of siloxane bond rupture and the reaction' of separation of the organic radical from
the silica atom are also disc,4ssed. A great number of reforences are included co-
vering the structure and physical and chemical properties of organocyclosiloxanes.
A detailed illustration of the folloiting reactions are also presented: ruptu f
cycles, formation of oligomers, telomers, regrouping, formation of polymers~n:c_
trophylic reagents, co-polymerizatioh of cycles, and chemical transformati in
the organic radical. Cyclosilaxanes containing SiN bonds in the cycle are pro-
sently found in 2, 3, or 4 SiN groups. Organocyclic silazanes are stable at high
Card 2/y.
- - - - - - - - - - - -... . . . . . . . . . . . . . . . . ... . . . . . . . . . . . . . . .
7
Z,
2

L 11062-63
ACCESSION Nit: AP3001449
temperatures; however, they hydrolize in water. Cyclosilthianes contain 2, 3, or
4 SiS groups and have 4-, 6-, and 8- group cycles. Cyclosilselanes-in its cycles
contained si~lica and selenium. At the ~Pesent only two pr,-,ducts are known. a dimer
=d!.Ia trimer with a cyclic structure. Both compounis are unstable. The mixed
cyclic silicon compounds are transitional Pompounds *between brganocycliesiloxanes
and-other inorganiccycles. The-oxygen-in-the cycle can-be ~artlysubstituted by-
N, S, and from cyclosilatoxanes and cyclosilthioxanes. Silica can be partly subs-
tituted by B. Al. P, Ti. Ar, and Sb forming mixed organocycloelemental-siloxanes.
All these reactions are illustrated in the original article 2nd their physical and
chemical properties explained. Polycyclic compounds of silica are also classified
into homo- and hetero- compounds. Thus'the cyclic silica structures of inorganic
elements present a number of specific properties sharply distinguished-from the
cyclic organic compounds. The high reaptiv-ity of the inorganic cyclic compounds
containing silica in relation to nucleophy~ic and electrophylic reagents is typical
for all cyclic compounds. This distinguishes them from the organic carbocyclic
compounds and opens a great possibility for their utilization in various syntheses
of polymers. Orig. art. has: 0 figures, 0 tables and 0 graphs.
ASSOCIATIOM ---none
Card
------------ - -------------
------------- --------------------

1(j6-( )11-63 A"
S/079/63/033/004/008/010
AUTHOR: Andrianov K A Kurakov, G.A., Khananushvili,
- E - -LVI.
- - -----------
Lomonosova, T.A,
TITLE: Reaction of reamination of bis(diethyla.Tino)-
derivative silanes'land octamethylcyclotetrasilazane
nes 11
PERIODICAL: Zhurnal obshchey khimii, v. 33, no. 4, 1963,
1294-1299
TEXT: The compounds of bis(diethylamino)methylsilane,
bis(diethylamino)ethylsilane, diethylaminophenylaminoethylsilane,
and bis(phenylamino)ethylsilane, of which the first two have not
been described previously in published literature, are synthesized.
These compounds are liquids which evaporate in a vacuum without
decomposing and are easily hydrolyzed in air. They react with
benzidine to form_pojZEers_ hich are solids at room temperature.
Card 1/2
T

1066-3-6-3 S/079/63/033/004/008/010
Reaction of rearination of...
The properties of these polymers are studied and are given in
a table. It is shown that the reamination of bis(diethylamino)-
ethylsilane by aniline takes place without the displacement- of
a hydrogen atom from the silicon to the am-ino group.
ASSOCIATION: filoskovskiy institut tonkoy khimicheskoy tekhnologii
imeni M.V. Lomonosova (Moscavi Institute of
Fine Chemical Technology imeni M.V. Lornonosov)
SUBYITTED: r,7iay 29t 1962
ke-
Ca-rd 2/2

ANDRIANOV., K.A.; KURAKOV, G.A.; KHANANASHVILI, L.M.
Interaction of glycide ethers of phenols with organochlorosilanes.
Zhur. ob. khim. 33 tio.8:2634-2638 Ag 163. (MIRA 16:11)
1. Moskovskly institut tonkoy khImicheskoy teklinologii.

1
7 WP(J)APF(c)/tWT-(m)/'bDS ASD Fc-4/Pr-4
156-63 RWdW1r1r.L
i,ACCESSION NR: AP3006831 S/0079/63/033/008/2790/27910
:,AUTHOR: Andrianov, K. A.; Khayduk, Ionel; Khananashvili, L. M.'
It
~,TITLE; New inorganic heterocyclic comB - t
ound risildiazox
016RCE: Zhurnal obahchey khimii. v. 33. no. 8, 1963, 2790-2791
~-TOPIC TAGS: heterocyclic compounds, inorganic heterocyclic com-
P,
ounds, trisildiazoxanes, 3,5-diaza-l-oxacyclohexasilane, tri-
~sildiazoxane synthesis, synthesis, ammonolysis, dichlorotetra-
.mathylsiloxana, dichlorodimethylsilane, 2,4,6-hexamethyl-3,5---
'diaza-l-oxacyclohexasilane, 2,4,6-hexamethyl-3,j-diaza-l-oxa-
Cyclohexasilane property, property
~ABSTRACT: 2,4,6-Hexamethyl-3,5-diaza-l-oxacyclohexasilane (1),
the first representative of a new class of inorganic heterocyclic
Icompounds- trisildiazoxanes (sic] - has been synthesized by a;n-
Imonolysis of dichlorotetramethylsiloxane (II) with dichlorodimethyl-
silane (III) in liquid ammonia. An equimolar mixture of II and III
dissolved in toluene war, added dropwise to liquid ammonia. After
C,ard 1/2
gig-
A,

L 17156-6)
ACCESSION NR: AP3006831
completion of the reaction excess ammonia and toluene were removed:
:by heating and distillation, respectively. Compound I precipitated
:from the reartion mixture as needle-shaped colorless crystals which',
after recrystallization from petroleum either, had a melting point
of 46-47C. The yield of I was 28.9%. Other 3,5-diaza-l-oxacyclo-~
hexasilane derivatives are being prepared. Orig. art. has: 1
formula.
ASSOCIjkTION: Moskovskiy institut tonkoy khimicheskoy tekhnologii
imeni Lomonosova (Moscow Institute of Fine Chemical Technology)
SUBMITTED: 15Mar63 DATE ACQ: 30Sep63 ENCL: 00
SUB CODE: CH NO REF SOV: 001 OTHER: 001
(;ard 2/2
&Ma
ggtv.
a, 6~v
ii-49,101 :- -
-A; 34
Fi- W~ g~

L 127og..63 9dP(J)/XPF(c)/EWT(M)/5DS ASD/ESD-3 Pc-4/Pr-4 RMI!rWIMAY
ACCESSION NR: AP3000299 810029163115010011009310095
AMHOR: Andrianov. K. A. (Corresponding Member, AN SSSR); Khayduk, _ Ionel;
Khananastvili, L. M.
laz
TITLE: Structure of unsaturated derivatives of cyclotrisi__. ane
SOURCE: AN SSSR. Doklady, v. 150, no. 1, 19630 93-95
TOPIC TA1.19: silanes? silazanes, cow=onolysis, conjugation, amonolysis
ABSTRACT: Ungaturated derivatives of trisilazue het-ero-cycle vare prelpared for the
f1r.it t-ln-- through a=wnolysiB of tt--tk7lvinyldiclx7--orisilare or of
vith in tenzf;ms. Trimmthyl-tr`
-tdny1zyc1-)trLitlazane and verz isolated
ul;-.m of Co'x=.orolyais of
ailane, vit'li trtbylrinyldizhlor-:)sil,,tr-a pan tanettv,-I~ri raylcyUotrin I las-in- Id
~,t.~iyl.,Iiv"tnyley~.-lotrioilazwir.-. FkAyklicul Properties of the four cwz")u!
slwrmariv~!d in a table., Klemental analyeis and molezmlar *,qe'Lght jleterminatic,n;4 n,)n-
firr.m:~~d th.,~ ccaTo3ition of the synthasized Infra:-,cd and ulltra vi ~,l 1~ t
spectra provided additional infoxmation altout tha stmct~-izL of wn-;aturated derltra--
'tivt-3 of cyclosilazina- A;xthar conm-luled on t!~- b3zis of ultraviolet spec'm that,
there, i:3 no conjugation of the vinyl groups through th3 inorgenic h'aterozyc'le Si
Card 1/2

L 12709-63
kcassm NH.- AP3000299
sub 3 H sub 3 but the QUIUSIU-0DAS outside the nucleus and jimited to inter-
wtion between the sili,-.on atom and the vinyl group. orig. art. hss-. 2 f4-"-e3,
I formula and 3 tables.
ASSOCIATION: Moskavskiy Institut tonkoy khtinicheskoy tekhnologii im. M. V.
Lomonosova (Moscow Institute of Fine Chemical Technology)
sumnuD: o6Feb63 DAT3 AcQ; iojun63 ERCL; 00
so CMB: CH NOW SOV: 003 07M: 002
Card 2/2
--- ------- ......... --------- ------

AND.RIANOVY K.A.; MARFENKOVAI G.P.; KHA?IANASHVILI, L.M.; SHAPATIN, A.S.
Synthesis of organophosphinoxyaluminoxanodimethylsilcocane
alastomers. Vysokom. soed. 5 no.10:1552-1557 0 163.
(MIRA 17:1)
1,, Institut tonkoy khimicheskoy tekhnologii, imeni Lomonosova.

ANDRIANOV, K.A.; KHAYDUK., Ionel,- KHANANASHVILI, L.M.
Now eight-membered cyclosilazoxanes. Izv4.' AN SSSR. Ser.khim.
no,9:1701-1702 S 163, (MIRA 16:9)
1. Institut tonkoy khimicheskoy tekhnologii im. M.V.Lomonosova.
(Silicon organic compounds)

ACCESSION NR: AP4018161 S/0191164/000/003/.0_020/0022~
AUTHOR: Andrianov, K. A.;_N4ananashvili, L. M.; Varlamov, A. V.;
T ikhonov, V. s.
TITLE: Synthesis of borosilOxane Oligomers and their stability to hydrolysis
SOURCE: Plasticheskiye massy*, no. 3, 1964'20-22
TOPIC TAGS: borosiloxane, 0119omer, borosiloxane ollgome~ hydrolytic stabili-
ty, hydrolysis, phenylaminomethyl group
ABSTRACT: Borosiloxane oligomers containing phenylaminomethyl group at the
Si atom were synthesized from suitable proportions of triacetoxyboron and me-
thylphenylaminometh.vldiethoxysilane:[ ;ti, ar, -C Hs C
CHO- 8_0
C14, H, CH,
NH Lo AN;H NH 0
Ccrd-1/2
~H, 3
J_N 4H, H& 4H.

ACCESSION NR: AP4018161
CH3 :- CH,
CH,COO- -B-0-~1-0- -q)ig (C1iC00),B-0-~1-0-B(0C0CH3),
Lo N, H
~,H
IV
The oligomers in which the number of phenylaminomethyl groups is equal to
the number of B atoms in the mo.,~cule (compound III) or are greater than the
number of B atoms (I and 11) are stable to hydrolysis; the oligomer in which the
number of B atoms exceeds the number of phenylaminomethyl groups (IV) is
hydrolytically unstable. "Han En-tse took part in the experimental work".
Orig. art. has: 1 table, 1 figure and 4 formulae.
ASSOCIATION: None
SUBMITTED: 00 DATE ACQ: 27AIar64 ENCL: 00
SUE CODE: CH NO REF SOV: 002 OTHER: 001
Cord 2/ 2_

ACCESSION NRI
AP4043319 S/0191/64/000/008/0013/0016
AUTIJORs Andrianov, K. A.; Khananashvilij.L. M.; Kochetkovq A. S.
TITLE: Synthesis and condensation of organo(hydroxyalkoxy)eitanes
SOURCEt Plasticheskiye massy*, no. 8, 1964, 13-16
TOPIC TAGS: silane, organotria(hydroxyalkoxy)oilane, transesterifl-
cation
ABSTRACT: A study has been made of the synthesis, properties, and
polycondensation of the following organotris(hydroxyalkoxy)silanest
methyl-, ethyl-, or plienyl-tria(Z-hydroxyothoxy)silone, or ethyl-
or phenyl-trio(4-hydrozybutoxy)silana. These silones were prepared'i
'bytransesterificationof methyl-, ethyl-, of phenyl- tris(ethoxy)- '.
silane with the appropriate glycol. The organotris(hydroxyalkoxy)'- i
silanes can be polycondensed alone to the polymers or with dimethyl
tereplithalate or tolylene diisocyanate to the copolymers. The
preparative conditions, chemical structureg and some physical,,
thermomechanical, and electrical properties of the polymers and
copolymers are dLecuseeds For exampla,,the polymer produced from
Card
1/2

ACqESSION NRt AP4043319
PlienyltrLo(4-hydroxybutoxy).silane will not flow at temperatures
below 300C. The polymers and copolymers can be cast in molds to
produce various artLiclese Orig*. arte hael 4 figurest 4 formulas..
and.3 tabless
ASSOCIATIONt none
SUDHITTEDI 00 ATD PRESS: '3080
ENCLi 00
SUB CODE 1. Ici 00 NO*REF SOVi 001 'OTHERt 001
'Card 212

ANDRIANOV, K.A.; KURAKOV, G.A.; KWARASIIVILI, L.M.
Rea-tion of 1.3-dioxolme with organochlorosilanes. IZ7. AN
SWR Ser. khim. no.l2s22.43-2245 D 164 (MIRA 18z1)
1. Moskovskiy institut tankoy khimicheakoy tekbnologii imeni
Lamcnosova.

ACCESSION NR: AP4022962 6/0079/64/034/003/0912/0914
AUTHOR% Andrianov, K. A.; Khayduk, Ionel; KhananAshvili, L. Mo
TITLE: The formation of polycyclosilasanes during ammonolysis of dLmethyl-
dichlorosilane
SOURCE: Zhurnal obahchey khimii, v. 34. no. 3, 1964, 912-914
TOPIC TACS: polycyclosilazane, ammonolysis, dimethyldichlorosilane, dodecane
methylbicyclo 3comw4 hexacyclpentagane, diaminosilatane
ABSTRACT: Dodecane methylbicyclo (3.4) hexacylpentazone and the polymer
(C113)jSj-N-Si(C113)2-N11
HN SI(CIYX JI(CI13)2
(C113),S1-N_ SI(C1134-6
together with hexamethylcyclotrisilazane and octamethyleyclotatrasilazane were
i obtained while carrying out the reaction of dimethyidichlorosilane with ammonia
in benzene solution at a temperature not exceeding 30 C. A study of this reaction
indicated that the composition of ammonolysia products depends on the operating
Card 1/4

ACCESSION NR: AP4022962
conditions of the synthesis, If the reaction is carried out with subsequent
heating of products and no separation of ammonium chloride, a bicyclic compound
with low yield forms. If the product of ammonolysis is heated after separation
of amonium chloride, the yield of the bicyclLc compound and the polymer increases,
significantly. It is interesting to note that ammonia separation is observed in
the process of heating the product of the dimethyldichlorosilane ammonolysis 11
reaction. While the gaseous ammonia takes effect on the dimethyldichlorosilane,-,
the reaction occurs not only with monocycliccompounds forming, but also with
linear diaminosilazanes H2N;(R SiNH) - R Si - M12. The latter are much more
0j low n I
likely to form in condition temperature ammonolysis. This confirms the
fact that during heating of products of ammonolyaLs, ammonia is always separated,;
This can develop only as a result of condensation of the amino groups in tha
silicon atoms or as a result of transamination:
imBI-N111 + 11IN-Sim' --'* =51-NII-Sim + N113
+ HIN-Sla -9, z3gl-N-Shs + NHj
Card 2/4

ACCESSION NR: AP4022962
Consequently, the formation of a bicyclic compound and of polymers obtained
during the reaction of dimethyldichlorosilane with ammonia may be explained by
the following reactions:
11,Si-Nit
I1XSj-N-SIR%7-NH
IINI bins Allis
-Nut
n3li-NII RISI-NH
1IN-SIR,-NII 11251-N-51111-NII
R'SI JIR2+ IIjN-H2S1NII5IR2-NII' ZML 11~ Sills ilins
IIN-BIAX-All AIR$
Card 3/4 Litt

ACCESSION NR: AP4022962
S S1
IW/ '\Nil \N-8111s.-Nus
R, Ins-
nA Ins
\N)
If
St\,
\N1 '_ SIR,-
\N1
n C11"
The composition of the polymer being formed does not correspond to the product
of simple ammonalysis [R2SiNH]. as might be expected. Its composition
[T18Si4N3H I x indicates that it is a product of conversion which occurs in the
second stage of the reaction. Orig. art. has, 00
ASSOCIATION: Moskovskly institut tonkoy khimicheakoy tekhnologii iment
M. V. Lomonosova (Moscow Inatitute of Fine Chernical Technology)
SUBMITTED: 04Jan83 DATE ACQ: 15Apr64 ENCLi 00
SUB CODE: GC NO REF SOV: 001 OTHER: 002
Card 4/4

~/1684/169
ACCESSION URI AP4037060 S10079/64/034/005 5
AUTHOR: And*rianov, Ko Ael Kur4kovo Go As; K6py*lov, V. M.1
KhananashvL 11 -: j -L. M.
TITLE: New synthesis method for mothylbromosilanes and methylbromo-i
chlorosilanes
SOURCEt Zhurnal obahchey khimii, v. 34, no* 5j 19640 1684-1685
TOPIC TAGS: mothylbromooLlane, methylbromochlorostlene, trimethylbr;_
mosilans, dimethylchlorobromosilans
ABSTRACT: TrLmethylbromosilane and dLmothylchlorobromooLlane ha'fe
been prepared by-treatment of trimethylchloroallane or'dimethyl-
dichlorosilane with hydrogen bromide in the presence of anhydrous
Fecl or iron filings* Either IlDt gas or IlBr generated.by the
reaclion of bromine with naphthalene or tttralefie can be used.
Boiling points of the products are 79-OOC and 93-94C, respectivelys
This work was done at the Moscow Institute of Fine Chemical Technology.
1/2
Card' -77
0:AR
7A

0 vg a c t q v
-Aaae

i e t
e r-,

v 1
13 c 0 w , (1 5 t i I- u t e 7 , 7 , ,
. 1~ ,

The addition reactions -f di-, -m.
rogen on hpat inlZ try I go- 200(-
L, 'ijr-ni the
'W'.4
zO

I N~"27-65
ACC-FSS10N NR: AP4047325
N - phenylaziridinyl derivatives, probably via the t rii:tn1 in,- i -mf-diate. Corn-
the alkenyl group in the beta-pr)-3 t i t s n
-nt,;~ thp 5-1 atom is more
3 (cy(- 1
reff"acliofjii were
he N M. R 3 Pe 1: t r -1 M,
nh'--Aineri Th - 7, u t h o ~- s ),a,, f-, -
n spectra. Orig, art. nas r m kdl R
JAT ION: Moi3kovg1ciy inBtitut tonkoy khim~rhez~ K, I V o K LT 1 M,
c- ow institute of Fine Che n-i i r.i.
I ~f Nlay64
DE- GC, OC
NO REF SOV (101 YFHF."~ ()()I

.77-
I Mcs klovskiy j. r1.; t.L ta t '10
ot;
I'mor'J's Ova.
TZ,

ENT (m /EPF ( 0/EWP j pc-4/Pr-4
L~2 121-6~
ACCOM31ON N'R: AP5003Q,62 _;,")077 /65 /,),~5/ry)1/0103/01.06
k'- Andrianov, A. jidcro7, i H. Nikitina, J. ~L
71i
, _r , 3vnthesis of organic cyclosiloxane,zk contairurig unsaturated groups at the
11~con ai".
J
SUI F-C E tthurnal obshchey khinii, r. 35, no. 1, 1965, 1~3-106
1,
L I ~j 3 tsilicon, siloxane, cyclot-3trajiloxano, t;,rirogen, viayl, mechanical
prop,~.rty
A-PSMACT & Conpounds containing various numbers of allyl groups at the silicon atom
in elAt-ma-ember aM six-mmber si-IGxane rings artl cyclotetrasilloxane containing
h-rL-,;i~en and 71nyl fp-oups at various silicon al~v)cui were EyntreFiLed. 3inultaneous
-irc ilygis of methallyl dichlorsilaxano ane otherlc
:r, elds sti -imember and eight--(nemt;,3r qro-dn by
Card