SCIENTIFIC ABSTRACT KHAZANOV, YE.I. - KHAZANOVA, N.YE.

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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

KHAZANOVI Ye.I.1 SHULITSp B.V.
Kinetics and mechanism of the reduction of Jimenite and
titanium-magnetite by car'bon at gintering tamperatures.
Titan i ego splavy no,5:8.5-94 161. (MIRA 15:2)
(Titanium oros)
(ore drossing)

S/200/61/000/011/003/005
D202/D304
AUT HORS,. Khazano Ye. 1. and Shullts, B.V.
TITLE: Reduction of titanomaguetite by sintering with a solid
reducing agent
PERIODICAL: Akademiya nauk SSSR. Sibirskoye otdeleni.ye. Izvestiyaj
no. 11, 1961, 98,402
TEXTi In the present. work the authors studied the reduction of synthetic
titanomagnetite on samples obtained by the fusion of pure Fe203and TiO2
in a~ atmosphere of Wo They found that by sintering this mixturs at
1200 , only ilmenite was formed. Fusion at 1500'C yielded a product con-
sisting of two distinct phases: that of ilmenite and that of titanonagne-
tite. Only the last phase was magnetic and its chemical composition was
as follows: M2 TiO 2 =4.89, Fe203 = 63.44, FeO = 30A, Fe ~ 0.22.
X-ray crystallographic data showed it to be similar to those of the na-
tural mineral. Its chemical analysis was performed by %.I. Kapustina,
Card 1/2

S/200/61/000/011/003/005
Reduction of titanomagnetite D202/D304
and its X--ray examination by S.A. Stakheyeva, This magnet-fe portion of
the fusion product was used by the authors for their experiments by
heating the product with pure charcoal in the temperature range 1000 -
13000C. It was found that at 'Lower temperatures, up to 1100 0C, mostly
iron oxides wert reduced2 the rnduction of t1tantxii oxide being very
slight. With rising temperature the rate of iron oxide reduction was
lowered owing to the formation of anosov%te. It follows that for indus-
trial purposes the reduction of ferrotitan~7 ~or,-fntrates t4hould be
carried out at possibly low temperatures. The authors proposs a follow-
ing scheme for the reduction process: (Fe 304- FeO.TiO2; FeO.TiO2)+ C =
mFeO.nTiO2 p~T-.'203+ Fe 4 CO., the ratios m . n :, p depending on tempera-
ture. These conclusions were checked on ne'ural ores. An addition of
20% soda facilitated the oxide reduction. Inere are 4 figuresq 2 tables
and 13 Soviet-bloc references.
ASSOCIATION,,, Vogtochno-Sibirakkiy filial sibirskege otdelen'-ya AN SSSR,
Irkutsk (East Siberian Branch of the Siherian Department
AS USSR, Irkutsk)
SUBMITTKU:. September 14, 1960 Card 2/2

KHAZAROV, Ye.I.
Processing alkaline aluninosilicate and other alumina-bearing
rocks by sintaring granulated mixturos. Izv.Sib.otd.AN SSSR
no.1203-63 161, (HIRA 150)
1. Yostochno-Sibirskiy filial Sibirskogo otdeleniya AN SSSR, Irkutsk.
(Alumimmi,metallurgy)

Y'. (I
I" tc,r :f
c.;;. q -,Tl
!nr. 11"i+
AN

KHAZA P 10010
Complex treatment of alkali alumosilicates and other Aluminer-bearing
mineralos Trudy Vost,-Sib., file AN SSSR no*43:7-21 162,
(MIBA 16&3)
(Iluminum oxido (Alkali metal alumonisilicates)

KMANOV, Ye.I.1, KHMPINA, A.F.
7-
Temperature rarge for the sintering of alkali aln silicate cb=ge
mixtures. Trudy Vost.-Sib. fJ-I. AN SSSR no-43:22-35 '(42- (MRA 160)
(Alkali metal ahmi silicates) (Sintering)

JHAZANOV, Ye.I.; SHUSHLYANNIMA, ZA; HUYUPIMS A.F.; KUZIIUNAP G.V.
Industrial assaying of feldspar rocks as a raw material for the pro-
duction of alumina* Trudy Vost,,-Sib. fil. AN SSSR no.43:36-39 162.
(MMA 16:3)
(F.Dldopar-Testing) (Aluminum oxide)

- KHAZANOV, Ye.I.; OTTOp D.D.
Irmestigating the procaBs of granulating a2kali alumosilicate charge
ndittures, Trudy Vost.-Sib. fil. AN SSSR no-43:40-54 162. (M,RA 16:3)
(Alkali metal aluminosilicates) (Ore dresaing)

KHAZANOV~ I&J.; GALKOV., A.S.
TAboratory equipment for modeling theaintering process of alunina...,
bearing charge mixtures. Trudy Vost.-Sib. fil. AN SSSR n0-43-55-58
162. - (MIRA, 1633)
-I:- (Sintering-Models) (Aliminum oxidoe)

GALKOVS SHMHLYANNIKOVA, E.M.
Distribution of water-ooluble alkalies in sinter cakes of nepbollne-
oodium-calcium charge mixtures. Trudy Voot.-Sib. fil. AN SSSR no*43t
59-62 162. ' I (HIBA 16:3)
(Nephelite) (Sintering-Testing)

KUZIMBA, G.V.1 YHLYUPINA,, A.F,; KHAZANOV, rtf.L, SHISHUARNINOVAp F.*N.;
Pr4niml ucbastiye GALKOW,-f.-S-.-
Nepheline rocks of the Buryat A.S.S.R. are a possible raw material for
the production of alumina. Trudy Voot,-Sib. fil. AN SSSR no-43:63-68
162. (KU?A 16:3)
(B"t-Mongolia-Rephelite) (Aluminum oxideq, '

KHAZA.NOV, 18-1.; KUZIflINA,, G.V.;' 8"I'AMIEVA, S.A.; SHULITS, B.V.
------ -
Changes in the phase composition of clays during heating In.s. neutral
atmosphere in the presence of a solid reducing agent. Trudy Vost,-Sib.
file AN SBSR no*43:69-76 IE2. (MIRA 160)
(Alumimim oxide) (clay) (Phase rule and equilibrium)

KHAUNOV Ye Ii KUZIMLNAo G.V.; DONTSOVA) S.GIP
Changes in the phase composition of an alumina-kaolin charge mixture
in the process of charge-reoiotance melting of fused silicon and
aluminum. Trudy Vost.-Sib. fil. AN SSSR no.43:7-1-81 162. (MIRA 16:3)
(Alilminum-Electrometallurgy) (Slag) (Phase rule and equilibrium)

KHAMIOVO Y90014.
I PhyoicooheOical principles and now data on the experimental investigation
of the carbothermic method of preparing magnesium in tt~s vacuum. Trudy
Voote-Sib., fil. AN SSSR no*4305.~Ill 162, (KIRL 16:3)
um-Blectrometallu'r'97)-
(Magnet
--(Vacuum -metallurgy)

KHAZANOVj YesIti; SAYONOVA) Ye#G*;. STAKUTEVA, S.A.- KUZIMINAI G.V.
0
~ Interaction of aluminum carbide and magnesium oxide. Trudy Vosto-Sib.
fil, All SSSR no*43:112-128 162. (HIRA 16s3)
(Aluminum carbide) (Magnesium oxide)

SAPONOVA,, Ye.G.;-KHAZANOV, Ye.l.
Compovition of filtration revidueee Trudy Voste-sib, filo AN S43R
no.43029-141 162. (MIRA 16'3)
(Tailing (Metallurgy)-Analysis) (Electrometallurgy-By-I)roducts)

KRAZkNGVj Ye.I.; SAFONOVAj, Ye.G.; VRUBLEVSKAYA,, I.A.
Composition and properties of dolomites from the Irkatsk Province.
Trudy Voot,-Sib, fil* AN SSSR no.43:142-153 162. OCRA 16:3)
(Irkatsk Province--Dolomitee-.~-Analysis)

YM7ANOVp Ye,I.j SAFONOVAs Ye,Ge
Industrial testing of dolomites form deposits in the Irkutsk Provinces
Trudy Vost,-Sib, fil, AN 35SR no.43t154~-157 162, (MIRA 160)
(Irkutsk Province-Dolomites-Testing)

, 'V , . . .1
I I . I . 11 .

DROBOT., N.M.; KHAZMOVP le.l.
Method of measuring electric conductivity for the study of sint-d-ring
processes in alumina--adntaining mixtures. Izv. SO AN SSSR no.7
Ser.khim.nauk no.204-61 163. (MIRA 16:10)
1. Institut nefte- I uglekhimichaskogo sinteza Sibirskogo otdoledya
AN SSSR, Irkatsk.

S.A'. Kui-fMIPIA; Ga.
KPUZANOT 11'~-,)'Qj ~IM!Iff-TEVAt Y
fiu -,:,I onIbeLween t4 odi Lm-eluminat~3 and dl-AlcIum sihcatao
,,liar. prIU.xhim, 38 no.6t!381-1383 Je 165a f
kvim Isao)

KHfizANOV1.Y.s.T..; SHISHLYANNIKOVAj E.M.g RMX;HMO, Z.1.
Simultaneous complex treatment of alumina-,ontaining high2y farTouep
al)rali alumi-noellicates. TSvet.met, 38 no*7:58--62 JI 165*
(MIRA IS ~ 8)

OUJINTSEV, Valldemar Ivanovich; YAKD-';UK, Vitaliy Zak~zrovich;
KHAZANOV, Yevgeniy Kharitorovich; BRYZGAIC;A, N.., red.;
VELICHKOY N.p tekhn. red.
(Using large blocks in the installation of piping for
industrial and sanitary systems] Montazh ukrupnenzWmi
blokami truboprovodov sanitarno-tekhnicheskikh sistem.
Kiev, Gosstroiizdat USSR., 1963. 55 p. (MIRA 17:1)

ODVIIITSEV, Valldemar Ivanovicb; YJIAMCLV-,-2D2goui7-Klw-rJl-oaqA-c-b-,*-
YAYIMUX, Vitaliy Zakharovicb; KOWIDAM, red.;
LEUSHCIMUKO, N.L.9 tekhn. rod.
[Production of half-finished pipe units for sanitary
engineering systems of buildings]Proizvodstvo trubozagoto-
vok sanitarno-tekhnicheskikb z;istem zdanii. Kiev, Gos-
stroiizdat, USSR, 1962. 45 1). (MIRA 15:8)
(Sanitary engineering) (pipe)

LWANOV, Ya*N.y inzh.; BOGOSLMKIY, S.G., inzh.
Efficient utill*tion of mustard seeds. Musl,-zhir, prom. 29
no.6:7-8 Je 163. (~MU 16:7)
1, GosucIBrstvonnyy institut po proyektirovariiyu masloboynoy.,
zhirovoy, mylovarennoy.. parfyumernoy i margarinovoy promyshlen-
nosti.
(Mustard seed)

KHA7ANOVI yu., inzh-ekonomist
Traveling goods. Hest.prom.i khud-prorwo. 3 no.12s28 0 162.
(HIPA 1W)
(Siberia, W estern-Indus trial organization)

BYC!IKGV, S.M.; KIIAZANOVA A I --
-A,"
Tnteraction of chondromueoprotein and Oiondrol~,-
insulfate A with polymyxin M. Vop.nrd.kiiin. 1.1 no.S~
11-17 S-0 165. (MIRA 19SI)
1. Laboratoriya Ministerstva zdravookhran-~njya SSSR, Mo3kva.
Submitted April 9, 1964.

tinsL .4fla-4-1.4-7
"'a n0-19111 ~'n A
(MRA 18,-6)
T n
!3 'a rs v!~,,

BYCICKOV, S.H.; ZBARSKIY, I.B.; KUW.'OVA. A.I.; P014111A, V.A.
4
,-~. ~;,.z I
Mucopopyeaccharides and mucoproteins metabolism in cell nuclei.
Dok1ndy Akad. nauk SSSR 76 no.1:99-101 1 MaY 1951. (CUS 20:9)
1. First Moacow Medical In3titute. 2. Presentea by Academician
A.D, Speranakiy 23 January 1951.

BYCHKOV, S.M.; KRAZANOVA, A.1,
- -------
Interaction of streptorqcin with chondroltin sulfate and
chondromucoprotein. Vop. med. khIm.'q no.1348-5~ Ja-F '61.
(KIRA 17:6)
1. Laboratorlya Ministerstva zdravookhraneniya 333R, Moskva.

MOGILEVSKIY, Ye.14.; KHAZANGVA~ A.S.; FINGER, G.G.
Formation of viscose silk by a continuous process at hi h speed.
Xhim.volok. no-5143-46 161. ~~MRA 14:10)
1. VBesoyuznyy nauchno-iorleeovatellskiy institut inkuastvennogo
volokne*
(Rayon)

VASILOYEV, Yu.S., dots., kand. tokhn. hauk; VELINER, M.A., dots.,
kand. tekhn. nauk; GINDUS, D.O., inzh.; GOM"CIIEVSK.TY,
N.I., dots., kand. tekhn. nauk; GROICV, A.I., inzh.;
DOMANSKIY, L.K., inzh.; ISATEV, Yu.M., inzh.; KULESS, H.P.,
dots., kand. tekhn. nauk; ICKBLEV, B.N., dots., kand.
tekhn. nauk; IVROZOV, A.A., prof., doktor tekhn. nauk
(deceased); NALIMOV, SaMop at* nauchn. sotr.j, kand. tekhn.
nauk; REZNIKOVSKIY, A.Sh., kand. tekhn. nauk; SVANIDZE, G.G.,
doktor tekhn. nauk; TARAVAYEV, A.V., dots., kand. tekhn. nauk;
KHAZANOVA,-A.Z., inzh.; CHERNYATIN, I.A., at. nauchn.
86-tr., kand. tekhn, nauk; SHCHAVELEV, D.S., prof., doktor
tekhn. nauk; YAGODIN, N.N., at. nauchn. sotr., kand. tekhn.
nauk; LEONOVA, B.I.,, red.
(Utilization of water power) IspolIzovanie vodnoi energii.
Mookva, Energiia, 1965. 563 p. (MIRA 19:1)'

KLINGFRT, Nikolay Vasil 1,,,ovich; KHOMARIN, Anatolly Kharitonovich;
KIMMOU, A.2,, inzh.t rettenzont
[Steel p1pellneg and oclijahzing, reservolro of hydrooleo-tric
power stationil St-a3tnye truboprovody i urzivnitellriye re-
zervuary g1droe"lektrIcheskikh stantsii. MosRvat Enprglia,
1965. 207 p. (KTIU, 180)
1. I.eyAnCr1A.9knya proyiktiio-.konstmiktor-kal.,~t konflora
"Gldrostallproycktl'

I", KHAZANOVA, D.. Inch.
For the increase in the coefficient of powor. Prom.konp.
14 no-2:12-13 7 160. (HIJUL 13'.5)
1. Proyektno-konstruktorskaye byuro Mosob1promnoveta.
(Electric capacitors)

ROZ11,,,9iK1Y, L.B. (Rozynalkyi, L.B.1; BIC:IiKOVS'KIY, V-111. (afchkovs1kyi,VqV.]
KHAZANOVA, D. Yu.
Intestinal pneumatooiw in childron.Ped.lakush. i gin. 25
no.1:23-25 163. (1,11RA 16:5)
1, Kafedra dityachikh Jnf*tsiyn*h klivorob (zav.-dotoeut S.M.
Gavalov (S.M.Havalov]), Kririetkogo medichnogo ftstitut-A frektor
dotsent S.I.Georgiyovolkiy [S.I.Heorhiievsll~ytl) ta patalogo-
anatomichne viddilennya 4-1 mislkoi likarni (golovniy likar
Ya.I.Vidershayn).
(114TESTI1,23-DISHASES) (CHILDREII-DISEASES)

I- MZANOVA, G.(Chelyabinskaya oblast'); PLATONOTA, N. (Chelyabinakaya oblast')
Improve,the procedure for rel-jotering the staff. Fin.SSSR 19 no-8:76I
Ag 058. (MIR& 11:9)
1. Zaveduyushchly Kopoyskim gorfinotdolom (for Khazanova); 2. Starshiy
inspektor po shtatan Kopayekogo gorflnotdala (for Platonova).
(Wages--Accounting)

Z[fEVNOVATYYO A.I.; Prinimali uchastiyet.KHAZANOVA 1,V.,; KUZUECREMKOV, I.G.;
-
CHUKHONTSEV, V.P.; SHENBERG, G.F.
Agitation flowsheet In the leaching of alumina-bearing calcine with
the use of hydrocy~lones as main apparatuses for separating the pulp.
TSvet. met. 36 no.100-53 Ja 163. (K7n 160)
(Leaching) (Ahmina)

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15 (6)
SOY/101-59-51-4/11
AUTHORS: Illina, N. V., Vlasov, I. I., Khazanova, Kh. A., and
Shadrina, M. N.
TITLE, On the Use of Light-Weight Refractories for Lining Rotary
Kilns
PERIODICAL: Tsement, 1959, Nr 5, PP 9 - 13 (USSR)
ABSTRACT: The authors state that in the early days of the cement
industry the lining of kilns was considered exclusively as a
protection of the kiln body against the effect of high temper-
atures. Consequently any fire resistant material was accept-
able. The increase in the productivity of kilns has led to
more requirements on the qualities of the lining. The
physico-chemical process varies in depending upon the thermal
conditions in the burning zones of the kiln. To reduce
thermal losses, or to save as much as possible of the heat for
the burning process, a suitable lining material must te used
for insulation purposes. For years this matter has been rais-
ed by various authors. Higb-porous fire-resistant chamotte
Card 1/5 refractory insulation bricks were used for lining kilns in

SOV/101-59-5-4/11
On the Use of Light-Weight Refractories for Lining Rotary Kilns
the U. S., England, Puerto Rico. Compared with the light-
weight refractory material produced at the BorovichskAy
kombinat "Krasnyy keramik" (II.Krasnyy Keramik" Borovichi
Combine), it shows better thermo-insulation properties, a
smaller volumetric weight, with a mechanical strength of 30
kg/sq cm. on the other hand the Borovichi light-weight re-
fractory material has better mechanical resistance,which is
for compressive strength 45 to 80 kg/sq cm for class A mater-
ial, and 30 to 45 kglsq cm for class B material. Due to the
lower content of alumina, the fire resistance of the foreign
material is 16900 against 17500 of the Borovichi light-
weight refractories. Table I shows comparative data on the
materials originated from the General Refractories Com-pany
and the "Krasnyy Keramik" Borovichi Combine, classes A and B.
The Borovichi light-weight refractory bricks were first
tried in the lining of a rotary kiln at the Pikalevskiy
tsementnyy zavod (Pikalevo Cement Plant). The bricks used
belonged to class B (GOST 5040 - 58). Their compressive
strength was within the limits of 35 - 42 kg/sq cm (average
Card 2/5 38 kg/sq cm), porosity 52% and volumetric weight 1.26 g/cu cm.

C-0
~; V/101-519-5-4/11
On the Use of Light-Weight Refractories for LinJng Rotary Kilne
During a thermal stability test, the material resisted more
than 25 heat variations within the 8500C heat limit and
intermediate water cooling. The fluxing action between
clinker and lining bricks was also tried at a maximum
termperature of 12500 for light-weight refractory lining,
followed by a severe trial at a temperature of 15000- A
photograph (Figure 1) shows bricks prior to and after the
trial. No erosion was found in the lining after the first
of the above trials. In a second test, after one hour of
exposure to the effects of a heat of 1,5000C, the lining
bricks were affected by the raw mixture to a depth ranging
between 1 and 5 mm. Examination of the junction between
two zonal linings made of Ts-l and Ts-2 chamotte bricks,
and light-weight lining adjacent to the latter without
temperature compensations seams, revealed deterioration in
the light-weight refractory bricks. At the junction borders
the bricks became friable, and a 2 mm wide gap appeared at
the junction. Cracks were visible 70 to 80 ca inward from
the junction. Photograph 2 shows junctions at the cold
Card 3/5 side (left) and at the hot side of the kiln (right).

SOV/101-59-5-4/11
On the Use of Light-Weight Refractories for Lining Rotary Kilns
After 6 months of successful operation of a kiln lined with
light-weight refractories, the temperatures of the kiln
body were measured. In the tested zone, the temperature
was 180 - 1950 and in the zones lined with usual chamotte
refractory bricks, the temperature was 2350 at the hot
side of junction and 2200 at the cold side. Heat losses for
1 sq m of the tested surface was 2430 kcal/sq m per hour,
or 69% of the heat losses of the sections lined with chamotte
refractories was found to be 3540 kcal/sq m per hour.
Consequently, use of the light-weight chamotte with a volumet-
ric weight of 1.9 g/ccm for lining will result in a 30% re-
duction of heat losses due to conduction through the lining.
The author concludes that the first experience in lining the
burning zone in the rotary kiln at the Pikalevo Cement Plant
has shown that the qualities of the domestic fire-resistant
material are not inferior ' to material of foreign origin,
in relation to fire resistance, strength, thermal resistance
and the flux between the clinker and bricks. The author
recommends that in another test the trial zone be lined
Card 4/5 with class A light-weight refractory bricks over a length

SOV/101-59-5-4/11
On the Use of Light-Weight Pefractories for Lining Rotary Kilns
of 20 m. The brick3 should be laid on a chamotte-clay
mixture. Precautions must be taken to exclude the possibility
of a longitudinal displacement of the lining.
There are 2' sets of photographs, 1 table and 5 references
3 of which are Englishp 1 German and 1 Soviet
Card 5/5

ILIINA, N.V.j KIIAZAW)VA, M.A.
-------- --.
Wear of aluminum silicate refractories in the lining of a
rotary cement-roasting kill. Trudy Giprotsoment no.24%92-
102 162. (MM 16s4)
(Aluminum silicates) (Kilns, Rotqry)

MAMMA,, L.Ye.
ReIntion of acquired resistnnee to nntiblotics nnd bneterlophnge to
variability of properties of nnthopenic stnnhylococci. Zhur.
mikrobiol.mDid. i immun. 28 no.12:61-65 D 157. WIRA 11:4)
1. IZ MDakovskogo nauchno-iseledovntellskogo institutn vAktsin I
syvorotok im. 1.1. Mechnikova.'
(MICROCOCCUS PYOGMS,
acquired resist. to antibiotics & bactertophnge, eff. on
variability (Rua)
(ANTIBIOTICS, effects,
on Hicrococcuo Pyogenesis, eff. of acquired resist. on
variability (Rua)
(DACTERIOPHAGE,
Hicrococcoun pyogenes acquired resint., off. on vnrinbility
(Rua)

,KHAZANOVA, L.Ye.
Bacteriological properties of blood sera in typhoid and para-
typhoid fever. Zhur. mikrobial., e~id. i imun. 41 no.10:111-
116 164. (MIRA 18:5)
1. Moskovskiy institut vaktsin i syvorotok imeni Yechnikova.

KILZA!:0VA, N. yo I
"Gas-Vapor Solution.,; at High Pressures".
Zhur Fiz, Khim., 12, No. 1, 1939. Nitrogen
Institute, 1,:o:3coi7. Rcd. 3 June 193";
Report U-1613, 3 Jan. 1952

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4hiul. UASS., IM, to.
MW application of the Gibbill-I)SItOn 6W, tbV [A'Wi*-
RAMW Me. SI-141 vq1tatiollo of P44440 (4) PAO-valvour
"Mtk""49 high jwQA9UrVA I&MOCUSM41. (44tiftoftentm
must pxWmW jbmr~jw I"Ittiftew (11 IMW 14t (Ovin 0
uW pa "utiatt. A thAvetl equattim viialifes
-
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00-1 r valour itt
4-14-0tow"110 lheiiiry f(W milutionit of jW
00 .411 lum-poW Itad limp lKvn devriolimi isivii sit ctit4stiott hit&
*0 ir, Ix" tfeviv"I which sgrms with data for m4ut"ss of
9i
U IIjO vatimus in vmriou* pawm%. AiA lievewurr inermov,
- the- mal. firaction of vapour In the Xam Ikh-w tiecreamu
tit a inin, tral, mul then hienmm*. An eijtmfit~o
0
Obtailting at 01101 t1kin, 116111
It&* beca rivoil but t6tA txmitirming it siv likekill
It. If:
2,
i
J! WALLUN6KAL L1TfSA1U4q Ct4%%,fKA11QO
ft f, 4; 11 11 11 1 A6 A I I) ftj 0 X,
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00
too
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ve 0
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tie
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too
to!

KHAZANOVA4N8YE8 600
1. ITICREVSKIY, T. R.; KIIAZAN(?VA, tj_,_ Ye.
2. USSP WO)
"The Amonin Content In Conpressed Hydrogen and Nitrogen in Fquilibriwn With
Liquid Amronla," Zhur. Piz. nim, 13, No. 11, 1939. Yoscow, Chemical-
Technolorical Inst. imeni D. 1. Mendeleyev. Received 15 Feb. 1939.
9. 4W Report IT-1615, 3 Jan. 1952.

T 1~, ttt lot t
14
IA. a It

so -09
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R, Kfi,.
rv,klf an't NWI
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ph
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so

is*
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1& 90 1& ILA AM
- ... 1.61 .1.
ffiftecensum 01 I= by Nolecalu Nik%w 1A
Ekh Prealum 1, Kritchevsky and NJUQU&
10110'. (Aeta Phyxi(whitniva IT.H.S.M. 1946 -t1l.
*it. ave'ralculated
1, 1). 187). The authorro h
on thrrmodynamical grounds that thoequilibrium'.
pnwure of nitnWn in the system Fe (i phaw)--
Fe, N(y' -phase) -N, at 41k C. is rquxl 14) .0.180
aim. and not ACIA) atm. As obtained in a simplified
calculation by P. Emmett, S. liendricks, anti
8. Brunnuer.-c. o.
00; s,
I L A&I fAL I UnrK &L LIVIRAV"I CLAsISPICAm.
Val;
-T-
J u Vs 4v 10 is' 'w 0 1 w Ow 0 a 4 4 It
10 11tvit Ioo( a it it 9 4 a 4x t4 IM KO A I 1~t-k dew
0 0
Vo
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I too
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goo
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too

-If T If W, 10.
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j;j
a Vapor prea-
a w" of US ad am at N's pm-
WAM t~hft hfthwto (d, e
EWmKtt al., C.A. 34, 2M) tkl AA-
Outried tvlkwl or p"fid Sam to he valu at ettsetmell
Illah pre"Me" WW the wivit the 4d14 Plaw" awl tho
fqw, dt
-woo U4 06 wo to top"
%Mto tuft "PALOMM4 "a not M4,14. The Nktaaq
&w.) at M4 am (mw: a phaw + r
as equa. pmesum r* 0
obaw + Pit. z1val 3000 and 27W as MI. +
lqt. 3" at W aid MW M 6M"; + -e'+ N3100at
W and 3MO at 3014; ad a + + T,. 4000 as 5w*
And I (witusuble) a act". ~L qtatern"T point
woe tested b
V beading Ft. of Come. 114% of Awl~
"A 1.4mal r.O. Pw. NN in N at sz-wl
and M atm. do R is The folAl phase
obtak" Yaw k"Caddy do *at 44 delalle effect of
pf"We at d dwWom of lmtkg cotald be &twttd ' Pre:
'Colewwww"Ovinaeued the cm
vio" "C!,C!~ N
tent up to 3.1 m. It is act bwwu wky aitriding stopped 4900
belom r-hl- wqWL. In -avermem, w" caksm.. the Y' too
pbaw Is I P t (9-can) Ott 473* at 2WO abm~ but only
the * Plid-ft is Sound alt 3370 atm. TW Snake &pacing
of %be 7 Pbaft dwwtd Uml b was m(4. witts N. too
f. J~ Rikes-Alml
T!AL &IMAT11611 Ct"WICt"Oll
111*W 42wi9v
*Nasal 009 a" All
AV 10 All; .611 Ica ;J, V I v a
ZIL
j
a 0 0 0 da 0 0 0 0 0 0 9,

Jun
nigh Pressures
adoes
"Device for the zlgh-prosGpra Compressing of
Gas$" D. S. Talklis, N. E. Xhazano'va, State
last of Nitrogen Ind, 2 pp
"Zavod lab" Vol XV, No 6
Industry frequentlv reqiilres large amounts of.
very pure gas compressed tinder high presaureo.~
Describes a amiple apparatuu de7eloped to fill
this need. It Is capable cf compressing no up
to 720 atm. Advantagda are many, Iticluding:
(1) ability to vork vith small amounts of eA8.
OW
7MR/Phystoo (Contd) Jun
(2) no contact between lubrication oil eLhd
gas, thus insuring as parity; and (3) Pressure.
which in obtainable it; limited only by size
.and strength of apparatus.

--l L ~ I - - ,
. . - 7~
1 -; . ..,- I ,
, . - z , ~
. .
. ~ ~,: - - " I 1 4
. . !-.w. . .,:

1. R. Kricher.1vil and N. E, fousA.
Of IN Irtre nitrklecl at X3, AM. 450. and 0i
.r.t`M".=UfT in Nifs-11, mists, The NIII Content
froging fiam 33 to 6317c. The nittidine fvActkm %top;x,,I
llff~ftf (~OMPICtfjy &$ X IIMJII"l .1; CtIntent In tile Fe %,ji
ltppccwbrd. the final N majent ImTeming with inm4w in
(1) 2Vff, + 2SPe - WroN + :111j, And (2)
WroN 2xVe + Np. RrAction (t) is Iinjitej by rate .(
diffusim of N dwmgh Fe and Ve nitrides. Itud bcczu~ 4
the iow rate of diffusion tbrough Fe nitrid" the rrmt~m
slows do" as the nitmts increaft Uslif t 1 11, b-tween ibe
2 reactitons Is altainrd. H. 1~t. Rxtbmann

Tko MUI&
KUmm&"DV=j AW.,
too. tocid. h (of tite reactim (lot
0 - N)lVr*M - 12mAo - w)l t.N + Nu whe" Ft.N Is
the ud F%N 60wrobaw,wait caW. (tow existius
datalo.hr -11h. ovelecols cA KI . and for sbe roaction of Ve imi.
trWm wkh If*. The valoes obtakwd fw kv K wvfv - 400'
5.610, 41101 GJA W &4911840e 6.433, &Awl &X). i.m.
it? cosibitoin t" vww With data an 4hp fulacily fle Nq.
41. M$ j _P AM QqUR. Whit dW 0- a4d -Y-PhASOO At 4M)-
H.W.R.

cj'#~n. AL't,...
'Xnwltroto~
r r MO ottil, ~o
et~-"'Innfj from -1 lf~ 1-:
kg &-'4

M
.
MI
-d
-- -n,c,tlrlt,d " f, - .. -
- ~ - - - -- -..,
C-101-11 i_ i.,- , i o- -.,

-Y,
_-, 1q, - I 't" - It/ ,d --

t-, J~ -7- -_i I- ~ -, '~ -(~; , &1 , \ft/?' .
KRICHEVSKIY,I.R.; KHAZAITOVA,N.Ye.; LIHSHITS,L.R.
Dilatometry oi binary liquid systems in the critical region.
Zhur.fiz.khim. 29 no-3:547-557 Kr '55. (KLR& 8-7)
(Dilatometry) (Systems (Chemistry)) (Liquids')

fill w_'iio C~'
If,
rtv;
th,
lh, 1~' kv,
-it Ilia,
if '.I P 'i
2r.

In~l -irrccen intiustry
r 3,o- n.. ed b Acridf-!,~17i~;n N. Fri I r I
rg

JUL.
v
USSR/Fhyvical. Chemiitry Thornorh-arsioitry 33-6
USSR/1'hyvical
Equ.libriom. Tay,-,I_(,.ochL-aIca3_ Tliasu Transitioll-'
I ~.
Ab s Jo ur Ref(-;rat 71var - -:11irliYaj NO 2s 1-957P 3""0
Author Krichevskiy LP. IgIalaEova Njo.
Titlt! Foruation of Mists at Ifigh Pressu,,,_-3
Orig Pub Zh, tekha- fiziki, 1956, e,6, No 2, 1,0~2-429
Abstract A procedure has been worked out for icothc-eral ercation
of oversaturation duzing formation of mist at LZ-tji pres-
sures, which is based ol, utilization of the phenomenon
of rininum solubility of liquid in gas. Included is a
layout of a unit for tile investigation if the conditions
of Liist '~Grrmtion at hi4i presuures, and the procedure of
utilizinG it is described, Investi_r~ated wure the syctems
bu~ izene-nitroren, n, e-thanol-nitrogen, Cr,'3-4-nitrogen, at
preosure of -..- 900 atm, There was a ttainud a sharp lowe-
rine of critical overcaturation, in comparison with the
atnespheric pressure, which is, qualitativ-21y, in accord
Card 1/2 - 66 -

-~*/l 7 1
AUTHORS: Krichevskiy, I.P. , Khazanova, N.Ye. , Linshits, L.P. 76-12-1607
TITLE: Liquia-Vapor-Equilibrium in the Benzene-Uethanol-Systet at Hlgb
?ressures (Ramoveslye zhidkost-par v sisteme-benzol-metanol pri
vyaoklich davlaniyakh).
FMODICAL: Zhurnal Fizicheskoy Khimii, 1957, Vol- 31, Nr 12, PP-2710-2716 (USSR)
ABSTRACT: The lirdting curves of the liquid-vapor-equilibrium in the system of
benzeno-methanol at various oomponitions and temperatures from 1500 C
lip to the critical temperature wera investigated by means of the
method of soldered ampules. The volumes of the benzene-mathanol-ayo-
tem were measured at the limiting rurve3 of the liquid-vapor-equillb-
rim. The investigated mixtures contained 16.7, 34.9, 5o.6, 63.4
and 83.1 percentage by weight of benzene. The critical temperatures
and volume-values were found for each of these mixtures and the orit-
ical t-.x- and v-t curves were dra7m. v - is the molar volume of the
mixture: of a given composition, x - benzene content in percentage by
weight. The critical t-x-ourve has a minimum which in observed with
systems Ath steadily boiling mixtures under maximm vapor-pressure,
These systems usually have such a minimum at the vapor-phase-line
of the v-x-limiting curves. It is shown that the limiting curves
Card 1/4 occupy the whole range of the ooq)osition of the mixture at tempera-

MqHA-Vanor-Bquilibrium in the Bermena-Uethanol-System 76-12-16/27
at High Preamirea
tures below the temperature of the minimum at the critical curve
(238.5) and that with all temperatures for which diagrams were plotted,
they have minim at the vapor-phase-line. At temperatures above the
temperature-minium at the critical curve, the limiting curves embraoa
only a part of the compositions adjacent to the axis of pure benzene
and show critical points. It is shown that in the v-x-diagram for
the bemene-methanol-diagram at 2400 C (critical temperature of me-
thanol) only one field of the heterogeneous equilibrium was detex%.
mined, instead of the two expected. In the case of a further inorvase
of temperature, this field embraces the reducing interval of compo-
sition. The minim at the vapor-phase-line of the Y-x-limiting
curves indicate the presence of aceotropes in the system. The ooWo-
sition of the minim= coincides with that below the maxiamm vapor-
pressure only then, if said when the vapor-phase follows the laws of
the ideal gazes. It was assumed that the investigated mixture follows
these laws and moreover the data available in literature on the oom-
position of aceotrope mixtures were applied for this system at tem-
Peratures up to 1310 0 [Ref. 7] . The curves for the dependence of
Card 2/4

ti.ouid-Wkioor-Equilibrium in the Benzene-Methanol-Syntem 76-12-16/27
at HIgh Pressures
the Isoiling temperature of the aceotrope on its composition were
drawn upon these bases. At a benzene content of 17 percentages by
weightt and 238.50 C the t-x-curve of the aceotrope attains the
critical t-x-curve immediately in the proximity of the minimilm point.
The data P-v-t for the bomene-methanol-system in reference Is and
the here obtained data for cmputing the pressures at equilibrium
for three mixture-campo3itions we've applied and the critical P-x-
and P-t-our7es were drawn. The P-v-limiting curves for the three mix-
tures ivere constructed from the here cbtained data for the volumes
of the phases with the investigated system at the limiting curve at
various temperatures and compositions, as well as according to the
data of reference 1. (Mixtures with 54.2, 70.9 and Q3.0 percentage
by weight of benzene at 1500, 2000. 250v and 3000 C). Tho critical
P-t-curve was drawn according to the values for the critical para-
meters of pure berzene, methanol, and the three mixtures, as well as
according to the data on the temperature-minimm at the critical
curve for this system. This curve differs from those desoribed in
the references 8 and 9. It is shown that Ath the benzena-mathanol-
Card 3/4 system the relation set up there is not observed: the component with

Liouid-V-"or-Equilibrium in the Benzene-Methawl-System 76-12-16127
at High Pressures
the least critical temperature (methanol) has the highest critical
pressure. On the other hand, benzene shon at higher critical tem-
peratures the lowest critical pressure. Finally, also the P-x-iso-
therms for the liquid-pbase at 1500 to 2200 C, and isothenn for
the liquid- and vapor phase at 2400 and 2500 0 were constructed.
There are 8 figures, 2 tables, and 9 references, 2 of which are
Slavic.
ASSOCIATION: Institute of Nitrogen Industry, Moscow (Institut azotnoy
pranyahlormosti, Moskva).
SUBMITTED: September 17, 1956
kVAUMLE: Library of Congress
Card 'A

AUTHORSt Krichevskiy, I. R., Khazanova, N. Ye., 2o-119-5-37/59
Linshits, L. R.
TITLEt Diffusion Within the Critical Range of Ternary Solutions
(Diffuziya v kriticheskoy oblasti troynykh rastvorov)
FERIODICALt Dokla0y Lkademii Nauk SSSR# 1958, Vol- 119, Nr 5,
PP- 975-977 (USSR)
ABSTRA.CT% The aim of the present work is restricted to the solu-
tion of the main problem, namely the clear determination
of the problem, whether a noticeab 'le enrichment of the
solution with the third component occurs (playing the
part of a small addition to the binary system) in the
critical range because of molecular diffusion. The inve-
stigation of the diffusion in ternary solutions was for
various reasons carried out by the example of the tri-
methylamine-water system with an addition of a small
amount of butylamine. The investigation was carried out
by means of the method of capillaries (about r,-2mm dia-
meter and about *, 40 mm length). The experimental
Card 1/3 lasted 50-go hours. The thermal stabiliting was accurate
Diffusion Within the Critical Range of Ternary 2o-119-5-37/59
Solutions
to an error of,~. 0,050C. The investigation of the diffu-
sion in the ternary mixture is always carried out with
solutions of the same ratio butylamines triethylamine
(abouti--~_ 104), and always at the same temperature of
180C. In order to reach exact results a great gradient
of the concentrations of the diffusing component was
selected for the investigations. The following can be
seen from the data mentioned in 2 tabless The diffusion
coefficient of the butylamine is of the same order within
the critical range and in diluted solutions. The little
smaller value of the diffusion coefficient in diluted
solutions is explained by their small viscosity as com-
pared to concentrated solutions. Thus the diffusion ve-
locity of butylamine does not decrease within the criti-
cal range while the diffusion velocity of triethylamine
within this range strongly decreases. However, diluted
solutions the diffusion coefficient of triethylamine has
the same order as the diffusion coefficient ot butylamine.
According to the theoretical conditions the nystem was en-
Card 2/3 riched with butylamine. The ratio butylaminct *1 : 6,

24(8) T al~cy~ 6
A'ksdCmlY& Mauk 333R. Ct:jcl--',-a kn.-rjc~ds"kh nauk
Termodinamika I atroyanlya rastvarou; trtjI7 moveahchanlya...
Mormodynandca ".3tructure of Solutlon3; TramactlOn3 Of the
Conference Hold January 27-30, 1958) m3dow, lzd-vo AN S33R,
1959. 295 9. 3.000 copies printed.
24. : X. 1. Shakhparcnov, Doctor or Chemical Sciences; Ed. of Publishing
flaw"I X. 0. Yagorovj Tech. Md.; T. V. Polyakova.
PVJMN=s This book Is lztondod for physicists, chemiets, and
chmalmal engineers.
'COVEMMEt This collection of papers-was originally presented at the
Coriforense an Thermodynamic* and Structure of Solutions sponsored
by the Section of Chemical scianc** or the Academy or sciences,
assa, aw the Department of Chemistry of Moscow state UniveMity,
and be12 in Moscow an Janus" ZT-30, 1958. Officers of the
listed In tht_ rortrLTd A list of other reports
but not I.Oludia- IiC Uff*-W0V--
020 given. Among the problZa treated in this work are:
elactrolytia solutions, ultrasonic =Asurcmant, d1olectrid
mA thermodynamic properties of various mixtures, spectro-
sonnin aa&lvats. &to- References accom,pa" Individual articles.
36
Skrlml-Y--r- Fluctuation or Inergy In solutions god Their
-9 Mtias to~daat Capacity 43
and V. Z. MLE'Adeb. Molecular Theory at
11 Z
:A 48
1. 1L. ad X. Yet Kh-X=vS, Cfttloal Fhe a"
M
1
-I
1MV Ntu Sr-'-
1 49
T- P- Study of the critioai states or Individual
omod of Their XLxtures With the Aid of L*"93onLa
Methods 56
and A. A,_f2LlZ2XA- rhass Transitions In
F-Elassirication
simple Systems and Thirr 67
U" of 'Uttrosoula Measurements in the
3olutlons 72

,l
and 9. 1. Zmaborak. Tts"formation of
Er-
pe. into RaGAZOO OPOO sj~j HO=Z"trQp*&
Almary dat=za
T9
1tamakla-&-y- And A. 0. MoracheymX-y- ApPLIcabillty or
-
Lonov&Uv-o and Tema" solutions ST
)C and Rolation of Thermo-
-
-
tursted and Nearly Saturated Ternary
la
4yuouLa Properties or
Solutions, to Their ComposItlon 93
Thermc~lynsalo Propartlos or Water in
Wolutlons of 1160trolytes 97
of kleatrolytod In xon&quoous
W.-itions ICP5
Xvano~* Thermodynamic Proper-
'
;~ yt-,
r mcnaz"ous Solutions
Ila
r1ov, 9. A., V. A. Kronor r. X rctsyna, and To. V.Titov.
Study Or tzw JLrf'Ot Of 3-1-6418 an ibe Strength or Aolds by
Mean& Of CPtlcal Nothads 122
X2)n5LD*1X-A-Z- DI5&*Oi&tIOn of Aside &W Complex Compounds
Aiid Methods of studying it 126
ChaAge in Thenoodynomic ?motions In
or ions in solutions 133
Ther1mod7namloa of o&q%cc=pj*=sO Z40
Study or Pxnjoa J;~aaum or Solvent In
Aqu&0" Ulazlens of lloctrolyt4a 144
Interactions Or r=tOA Wlth Malsoulas (Water.
Af-
-2AA1
.
. 152 At

r5 ( 4 1)
AUTHORS. K~-icheyakiy7 1. R.,_Kha-.arov-, 1j. Yq~ SCV/76-33-7-7/440
Taekhanakaya, Yu. V., Linshits, L, R.
T I T LE. C:itical Phenomena in the Systim Hexampthylcne Imine - Watr-7~t
T. Equilibrium Lim!tln~, Curv,.i of Liq-jid - Fear the
PERIODICAL; Zhu--r-nal fizicheskoy k1iiinii, 15159, Vol 331; 11:- 7, I)p 1104 - 1491
(USSR)
L B 3T 1? i'~ C TFrow th-.~ data of the olassi,--,al theory ~n the
7,ia new thermodynar-io relatfons ?an b!~ obtaln,3d (Refs 1 3) wni:,h
the ccurse of the liraiting ourue ( 'LC) near the
pz,int (CP) with th? jumpaof the d~-rivatil~Os -,,' acne p-rop2rtaes
durinj tliq transition of zhe system !rcm the hor.,:,ec~neoua to. th-~
1--steroCenecus state. In-previous papez~s (Refs 4-6) 1-t waa f-olind
for twc- systems by the method of the lump of the derivati--rc-
U
(9 Irld t )P;T of the course .~f the (Lv') -,,eax 'lie ~sri'ical point
that th? limiting curves of 'hese systems are ser,--ond-degree
pa.-abolas. In rontinuation. of these irives--igattons ths auth~ra
ax-alyzed the system hexamethylene tmiia watRr -'II~. Tl,ey
13 nvestigated the course of the (LC) (Fig 1 Table n,~ar The

Critical Phenomena Jn the System Hexamethylene SOV/76-33-7--7/40
!mine Water. I. Equilibrium Limiting Curve of
Liquid Liquid Near the Critical Point
(CP), the partial and total vapor pressure, the spe.-Afic weight,
thO Tefractive index, the viscosity,. and the diffusion ~oeffi-
cients within the wide range of temperature and composition.
Investigations were carried out near the lower (cp) at 66.90c
and 22.5 wt% (1) by means of a gravimotric dilatometer (Refall-
14) (Fig 1) which was contained in a thermostat. The authors
investigated six systems with a hexamethylene imine content
of 13-7, 20-1, 24-32i 27.6, 31-4, and 35.6 wt% at various tem-
peratures (Table 2). On the basis cf the results of the spe-
cifit- -volumes; volume-temperature curves were plotted. and
herefrom the authors calculated the derivatives (9-/)t)p on
"he (LC) for the heteroeeneoua and the homogeneous range as
well as the jumps of the derivatives at the point of intersecticn
of the (LC). Results showed that the jump of -,he derivativ.~
kav/Ot)p,X attains a limit in the critical point, and thus the
(LC) is a second-degree parabola near the (CP)~ In (Refs 18-20).,
the -:umps of c and (Dv/at)p of some binary solutions atri
Ca~d 2/3 1; P,x .7.

Cziti~:ai Phenomena in the System Hexamethylene SOV/76~-33-7-7/40
Imine Water. 1. Equilibrium Limiting Curve of
Liquid Liquid Near the Critical Point
the Jumps of cV of several pure vibstarwas were Investigated,
bind it was found that these jumps always attain limits in Vic-
(CP). It is therefore assumed that the (LC) cf the liqu` -d -
liquid and of the 11.quid .- wapor in the s,rsterrs under i
.Lgation is a rjecond.-degree parabola. near the (CP). There arz-~
5 figures., 2 tables, and 211 referen~.es, 14 of which are Soviit.
ASSOCIATION; Goaadazetvennyy institut azotnoy proayshlerno!iti (State Insti-
tute for Nitrogen Industry)
SUBMITTED; Septembem 11., 1957
Card

1-~ (4) JOV/76,
AUTHORS: Khazanova, It. Ye., Linshita, L. R. (Moacow)
TITLE: Critical Phenomena 'in the System 11examethylenimine - Water
II. Some Physicochemical Properties of the System Hexanetbylen-
imine - Water
PERIODICAL: Zhurnal fizicheskoy khimii, 1959, Vol 33), Nr 8, pr, 1811-1812
(USSR)
ABSTRACT: In the course of the investigations of the critical phenomena
in the system hexametbylenimine (I) - water (II) it became
necessary to determine a series of physicochem4cal proper-
ties of this system as well. The specific weight of the
system M - II) was aeterm'ned for compositions of 4 - 441/~
by weight of M at temperatures between 13 and 650C (Table 1).
The measurements were made with a double capillary -)ycno-
motor, the meniscus readings were taken by means of a
cathetometer, The viscosities of the systern W - (II) vere
measured by mean8 of a Heppler viscosimeter for temperatures
between 0 arid 66 C (Table 2)... The refractive index was
measured by a 0refractometer RLU for temperatures ranCing
Card-474-2- from 10 to 50 0 (Table 3). There are 5 tables and 2 ,.')oviet
'refey-evices.

1A '? r
FlIME I BCOX EeLOITATICT S011/5469
Sovor,hchaniyc po kritichc3kim yavlcni:~ L'z i flyuktuatclyam v
rastvorakh. Moocow, 1960.
Krltichoalci.ya yavlonlya i flyuktuatuii v rartvor-,'-:h; trudy
yanvarl 19GO r, (Ci-Itical rliuna--ona and Pluo-
tuat!,= in Solution3; TranuactIona of the Confortnico,
January 1960) noscow, Izd-vo kI 5,3311, 1960. 190 p. 2,500
copic;i printod.
Spown,oring Agonoie3t AllcadmAya nault COSR. Otdoleniyo khir"i-
chauklkh nauk. Noskov3kiy go3udarjtvcnnyy universitot Im.
N. V. Lonono3ova. j(hirAchesIrly falmlltot.
Responsible Ed.: 14. 1. Shalthparonov, Doctor of Chemical
Sciennea, Professor; Ed. of Publichln~ House: E. S. DraMinov;
Tech. Ed.s 3. G. TikhomiroVa.
PURPOSE 1 Thia collection of articles I* intended for scientific
personnel concerned vrith chcmiatry, physics, and heat power
engineering.
Card 1/9

Critical Phenomna and Fluctuationa SOV151,69
CWrt--'V-GE i' The book contaira 24 of ' he 206 reports read at the
Conference o-n Critical ?honomnna and Pluctuationa in -Iolut-Ion3
organizcd by the Chemical DIvI51on of 1.*ozco-,t Stato Univraroity,
jdnu~,r-j 26-28, 196o. The reportz contaln reculta of Inve3ti-
gations carried out in recent ycara by Soviet phycicist""-,
ehenlz3ta, anil heat power enOin"--zo. ILe Orz;anizinz Cc-,-.-,Uttee
of the Conference v;a3 co-,rnpoocd of Profe3oor Kh. I. 1,7-irdiz~-nov,
A. Z. Golik, 1. R. Krichevakiy (Chairnan), V. X. Sczenchenko,
A. V. StoronRin, 1. Z. Fii3hor, and 11. 1. Shakhparonov (Doputy
Chairman). References accompany individual artiolea.
12ABLE OF CONT04TS:
Forrword
Am.irkhanov, Kh. I., A. M. Kerimov, and B. 0. Alibekov (Lab-
oratoriya molelcalyarnoy fiziki, Dagentanskiy filial All SSSII
Laboratory of M22ecular Ph~alcsp DagoDtan Branch, AS USSR].
Thermophysical Properties bf Matter at Critical Temperature
Card 2/9
3
5

Critical Phenomena and Fluctuations sov/5469
X.,.hadov, Ya. Yu., and 11. 1. Shr0eInnaro-nov (Laboratoriya riziko-
khimii raztvc-rovj Khird-CII-eddy ':0o':oV3!:iy rozudarot-
v-~-~nyy univercitet im. 11. V. Lo.-ic-lozova -- Lr-borator-y of
th~ Physical Chemistry of S61utlons, Chcmiotrj Divizion, ;oscoa
State Untverrity imcni I.I. V. Lomonooov). Dielectric Pronorties
of Solutions In a Suporhigh Frcquency ConcentrAtion
Flu3tuationa
B,aridze, D. R., and Il. I. Shakhnaronov (Laborator-j of Physi-
cal Cha-zilstry of Sol`u~_i=, &EC:,iLz-!!TDivioion, Z:oncov State
University imeni I.I. V. Lomonooov]. LIr~'it Scattering in Solu-
tl=3 Having a Critical Stratification Point
Vuka, M. F., and L. I. Linnyanzckiy (Laboratoriya molelculyarnay
optiki, Fizicheskly fakulltet, Loningradoltiy gonudar3tvonnyl
univor3itot im, A. A, Zhdanova -- L~boratoj of .olccular
Optics, 2hysics Division, Leningrad State Univer3ity Imcni
A. A. ZhJanovl. Intermolecular Interaction and Light Seat-
toring ip Solutions of Pyridine ando(- Piaolino In Water
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Critical Phenomena and Fluctuations sov/5469
Zat3epinu, L. P., and P1. 1. Shndinironov (Laboratox-y of the
Phy3ical Choml3tvj of 36`1u--tiona, Diviaion, 1*0jeow
State Un.Lvor3lty Imcni 11. V. Lomonocov). Rayleirh 14ght
scattering in flitrobenzeno -- Cyclohexane and Ethyl Alchol
- Diethylamine Solutions
Knoinov, R. M., and M. 1. Shaldinarono-v [Laboratory of the
.st 0'r A -_ -0 E
Physical ChenJ ry -3-oliNfondi ffc.-,if6try Divicion, Voccovi
State UnIveraity Imeni M. V. Lorionosov). DielectrIc Proper-
tiC3 of Soluti.ons in Elcotrow,,metic Fields of the .1,1111imetric
Band and Conce!ntration Fluctuations
Kriahevskiy, 1. R., and 1!. Ye. Khazanova (Laboratoriya vycoRikh
davleniy.. GIAP -- Laborai-o-r-y-o-F-Tff-g~-~j~e-ni3ure [Studical, Ioa-
cow StatJ Design and Planning Scientific Research Inatitute of
the Nitrogen Industry]. Diffunion of Liquid and Ganeous Solu-
tions in the Critical Region
3P
37
45
Krichevskiy, 1. R., and YU. V. Tockhanakaya [Laboratory of
Card 4/9

Critical Phenomena and Fluctuations Sov/5469
"If.h-Pro azure [Studical, GIAP]. Kinotica of HotoroSencous
Frocalazon in tho Critical 11,77_rion
Kriclv~vokly, 1. R., 14. Yo. Kh yn, and L. R. Llnohlts [Lab-
orator,j oC High IGIAX) , Liqvid-V,,;,r
(jullibrium In the Critical Rt.,Olon of Liquid-Syotci Zf;ratl-
fleation
Lo-.-,iova, N. N, andff'I* S1,,'I-hn rolov Elhbor~tory of the
PhY31cal Chomictry or S-Olutioli-, Hvision, Illoccow
St,tc Univeraity Imcni e1. V. Lo-onosov]. Permittivity and
iliolccuhnr Struoturo of SolutIon3
L. V., and 1.1. 1. Ih_,1!,1,,,)nmnov ELaboratory of tho
rhyZical Chnmistry Of h:.d6ti-j Divicion, 11,loacow
Stato Univoraity Inoni 14. V. Lo;ionoaovj. I'ain 3tructura of
tho Lino of Rayloigh LiCht ScattorinG in Solutiono
M,okhov, 11. V., and Ya. M. Lablzovzkiy [Kafedra dc7orimontallnoy
fiziki)Dnopropetrovokly goaudarstvonrU univeroltot --,Dopart-
Card V9

Critical Fhcnomcna and Fluctuationa S0715469
r;.,-nt of Fcmorlmcntal Phynics, rnn,.)ropotrov3!,. 3tato Univoralty).
1=.-Gtication or Dm3lty Vluctu,~tic_-m In "thor and B~n,.;,;no
on X-Ray Scattering at Narro-a Aw.Clc3 81
pAr",,-.-nt of F-mcririr.,ntal
hw, 11. V., ond I. V. Klmh (D.-,
P11-olco, Dnopropotro-vok St-ato U.Av,.)r.,A'-yj Variation In tho
of Conc,.,.atration Fluctuationa in ~!,,)Iatlox-hlp to Tc-n-
-p,ur,~tur.q amt Conamitration in Binary Liquid Sy~;tc-_-3 kkiving
an. upp~ar Critical Diooolvin_r? TL~:;p~:.mtura 89
111o2.drov, V. F., B. 1. Mallyanov ond N. 0. Ohir',,ovich
:;!siy oblaotnoy pcdagogichr~Ldy inctitut -- Pcd?,-'o,,~ical In3ti-
tullo of tho I,lc:;co,,., Oblanst]. Hyporsonic Lnvostivatior. in
C._~;c.nic Liquido at Const,,xt D:naity In tho Vicinity oL tho
Critical Stato 93
Pott, L. A. Ninokiy losotc!chnJ.Ch03kiy institut -- Minck'
Forcotnj En-inooring In:3titutol. Concorning tho Diffunion in-
tho Critical Stratification Region 102
Card 619

30
Critical Phenomma and Fluctuationsk sov/5469
Roolichina, G. P. (Laboratorlya molckulyarnoy fi.-Aki, V-Izi-
chenkiy falcul'tat, Xlyovakiy gcsudarntvennrj univeroltet In.
T. G. Shavchenko -- ' ..Laboratory of Noleaular Phyalco, Divi-
sion of Ohyoics, Kiyev State University ineni T. 0. ShcvchcnRo]
Investigation of Fluctuations in Solutions by the Method of
Licht Scattering
Skripov, V. P. (Laboratorlya molekulyarnoy fiziki,Ural1s1ciy'
rolitckhnicho31tiy inatitut im. S. M. 111irova -- Laboratury of
1:olocular nlyalca, Ural Polytechnic Institute imeni S. 14.
Kirov). Special Structural Features of Ratter in the Vicin-
ity of the Critical Point and Transfer Phenomena
Skripov, V. P., and Yu. D. Kolpakov (Laboratory of Yolecular
Physics, Ural Polytochnic institute imeni S. M. Kircr, and
the Laboratoriya teplofizikiUral'skiy filial All SSSA --
Thermophysics Laboratory, Ural Branch, AS USSR]. Light Seat-
toring in Carbon Dioxide along Pre- and Pont-Critical Isotherms
A
[Inatitut neftekhimichenkogo sinteza AN SSSR
SmIrnov B
109
117
126
--
'
'
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30
Cr~.tical Phenomena and Fluctuations sov/5469
Inntitute of Petrochemical Synthesis, AS USSR (Moscow]) Visual
Observations in the Critical neg4 on 137
richer, 1. Z., nnd V. K. Prolchoronlco. Concerning the Fluct-
uations of Coordination Numbers in Liquids 142
Finhcr, 1. Z. (Bclo:un;~dF Gonudarstvennyy Univcr~.Ltat -- Balo-
runuian State University (M-nak)] Correlation Analysia of the
Critical Point 148
,pAlIqDai~qpov 4.1. (I.-Ix-ratcvy of thu R*nlcal Chemistry of Solu-
,_j,_
tiona, Ohcrmiati~r_Dlvision, Moscow State University imeni It. V.
Lo-monooov]. Fluctuations in Solutions 151
Shimanskaya, Y.). T., and A. Z. Golik [Laboratory of Molecular
Phyoica, Physics Division, Kiyev State University Imeni T. 0.
Shevchenko), Investigation of the Critical State, Liquid-
Vapor, of SolulAons by Topler's Method 161
Card 8/9

'Critical rhenomena and Fluctuations Z011/5469
Shimanakaya, Ye. T., Yu. I; Shimanakiy, and A. Z. Golik (Lab-
oratory of Molecular Physics, Division of Physics, Myov
State University imeni T. 0. Shevchanko]. Investigation of
the Critical State of Pure Substances by Tepler's Method
Resolution of-the Conference on Critical Phenomena and Fluc-
tuations in Solutions
AVAILA13LE: Library of Congress (qD545.S73)

171
189

J?/dVk1jw
10-28-61
Card 9/9

3/170/60/003/010/020/023x
B019/BO54
AUTHORS: Krichevskiy, I. R., Khazanova,.-N. Ye., Linshits, L. R.
TITLE: Diffuaion of Gases Near the Critical Point
PERIODICAL: Inzhenerno-fizicbeskiy zhurnal, 1960, Vol. 3, No. 10,
Pp. 117-118
TEXT: In the introduction, the authors point out that it is very dif-
ficult to investigate the molecular diffusion of gases near the criticF.1
point. They observed visually the diffusion of iodine in carbon dioxide.
Iodine pressed Into tablets and carbon dioxide were introduced into thick-
walled glass ampoules. The diffusion of iodine in carbon dioxide causes
a discoloration of carbon dioxide, and thus the diffusion of iodine in
liquid and gaseous carbon dioxide was inveStigated. In this way, a dif-
fusion coefficient of 1*10-5 cm2 /sea at 20 C was determined in liquid
carbonic acid. Prom the results obtained, the authors conclude that the
diffusion coefficient near the critical point is smaller than
1.10- 6arm 2/ sea, and that the diffusion coefficient near the critical
Card 1/2

Diffusion of Gases Near the Critical Point S/170/60/003/010/020/023X
B019/BO54
point Is reduced by at least three orders of magnitude. There are 4 ref-
erences: 2 Soviet and 2 Scandinavian.
ASSOCIATION: GosudEtretvennyy institut azotnoy promyshlennouti,
g. 11of1kva
(Stato Institute of the Nitrogen_Industry, Moscow)
SUBMI'TTED: April 187 1960
Card 2/2

KRICHZVSKIT, I.R.; KHAZAHOVA, N.Te.~ TSIKKANSKILU, Yu.T. (Moscow)
Critical phenomena in the system hexametlWlenimine -
water. Part 3: Diffusion in the vicinity of the criti-
calpoint. Zhur.fizekhim, 34 no.6:1250-1254 Je 160.
(MM 13:7)
1. Institut axotnoy -protyeblemosti.
(HexametbVlenimns) (Diffusion) (Critical point)

S/076/60/054/008/018/0-39/XX
B015/3063
AUTHORSs Krichevskiy, 1. R., Fba-zanova. N. Ye-.-,
TITLEa Critical Phenomena in he HexametMleniminq Water System.
IV. ~7otal Vapor Pressure -!
PERIODICALt Zhurnal fizicheskoy khimii, 1960, Vol. 34, No. 8,
PP- '1702 - 1705
TEM The c-itical isotherm of total pressure above binary solutl a li~e'k
on
the isotheriis of the chemical potential'and partial pressure, exhibits
an almost horizontal section in which the vapor pressure is practically
independent of the composition of the solutior. This effect of %he
critical point also extends to the homogeneous region, in a wide range of
composition and temperature. The authors studied the thermodynamics of
binary solutions near the critical point in -the hexamethy.lenimine - irater
system, which has its lower critical point at 68.10C and 24.8 percent by
weight of hexamethylenimine (Ref.2). In doing so, they measured the total
vapor pressure above the solutions with 5-55 percent by weight of hexa-
methylenimine from 40 0 to 740C by the isotheniscope method. The latter has
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Critical Phenomena in the Hexamethylenimine - S/076/60/034/008/0*18/(139/XX
Water System. IV. Total Vapor Pressure B010063
been developed by Bmith and Rensies ~'.'j .~mer.Chem.Soc., 32, 1412, V910) and
is described here. Both instrument and method were checked by determining
the vapor pressure of bidistilled v%ter. The measurement error of the
total vapor pressure above solutior.5 of dit.'ferent compositions is
indicated a,-) being 0.10 - 0.20 mm 1-g. The values obtained from the diagram
logP w f(l/T) were interpolated for integral temperature valuea and
tabulated (Table 1). From this the '~ - f(x) diagram was drawn and the
limiting curve was plotted therein, the data on the liquid - liquid
equilibrium in the system concerned being derived from Ref.2. The P .. gx)~L
diagram (Fig.3) shows zhat the effect of the critical point extends over a
wide range of temperature and composition. A thermodynamic interpretation
of the data given here will be offered in a later report. There are
3 figureal 2 tables, and 4 referencess 2 Soviet, I U22, and I German.
ASSOCIATIONt Inetitut azotnoy promyshlennosti Moskva (Institute of the
Nitrogen Industry, Moscow)
SUB14ITTED% September 26, 1958
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S/076/60/034/009/025/041XX
B020/BO56
AUTHORS: Krichevskiy, I. R., !haz Ye., and Linshits, L. R.
TITLE: Critical Phenomena in the System Hexamethylene !mine - Water.
V. Partial Pressures of the Components
PERIODICAL: Zhurnal fizicheskoy khimii, 1960, Vol. 34, No. 9,
pp. 1920 - 1927 V/
TEXT: For the purpose of explaining the characteristics of the behavior
of a substance in the critical point and the effect produced by these
characteristics upon the behavior of a substance near the critical point,
it is first necessary to determine the dependence of the chemical potential
of the component upon the composition of the mixture in these regions. For
the temperature dependence of the differentials of isothermal and isobaric
lines upon the partial pressures of the components from the composition in
the critical point of the binary solution the equatiuns
(3/3T)(BP [(P1 N (RT 2)jj(B2jj/3N2)P (26) and
1)/(aN2)'P,T] PIN2;k k 2,k)/ k 2 T,k
Card 1/4

Critical Phenomena in the System Hexamethylene S/07 60/034/009/025/041XX
Imine - Water. V. Partial Pressures of the B020YB056
Components
(3/~T) (aP P N /RT 2),(32 H/3N 2) (27)
2l6N2)1),T]P,N2k 2,k I,k k 2 IP,T,k
are derived, where k is the index of the critical phase. The partial
pressures of the components in the critical range of the binary solution
were investigated in the system hexamethylene imine - water -with a lower
critical point at 68.10 and 24.8 % by weight of hexamethylene imine
(Ref- 5). The investigation was carried out by means of the dynamic method,
where only the equilibrium composition of the liquid and of the vapcr was
determined. The total vapor pressure over the solutions was separately
determined (Ref. 6). The equilibrium is established only slowly near the
critical point of a binary system, and therefore particular care was taken
in order that the saturators be used effectively. Helium was the carrier
gas. A scheme of the arrangement is given in Fig. 1. The equilibrium in
the system hexamethylene imine - water was measured in solutions with five
different compositions at 50-0, 62.1, and 67.60. From the equilibrium
compositions of the vapor- and liquid phases, the partial pressures of the
components were determined (the partial pressures of hexamethylene.-imine
Card 2/4

Critical Phenomena in the System Hexamethylene S/076V60/034/009/025/041XX
Imine - Water. V. Partial Pressures of the B020/ 13056
Components
are given in Fig. 2). The proportionality of the partial pressure of the
components with concentration holds only for diluted solutions (with 3 -- 4%
by weight of hexamethyleno imine).. At temperatures near critical one, the
partial pressure of hexamethylene imine from a concentration of about 8%
onward remains constant within a broad range of compositions. At 500, the
partial pressure within the range of this composition increases somewhat
with concentration, but its dependence of composition remains very low,
which fully corresponds to the conditions given in the thermodynamic equa-
tions (26) and (27). In solution concentrations near the critical one,
the composition of the gaseous phase changes only little with temperature.
The temperature dependence P2 /p, j'or three ternary systems is shown in
Fig- 3: triethyl amine - water, phenol - water, and hexamethylene imine
water, from which it may be seen ,;hat this function converges to zero.
when approaching the critical temperature. Between evaporation and the
solution heats of the components nt the critical point, a relation is
obtained, which does not follow f:.-om the general thermodynamics of the
critical state, namely
'AR 1,ev 2,ev - A111,k,sol - 6H 2,k,sol'
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Critical Phenomena in the System Hi~xamethylene 3/076/60/034/009/025/041XX
Imine - Water. V. Partial Pressurea of the B020/BO56
Components
T~here are 3 figures, I table, and S) references: 6 Soviet, I US, and
2 German.
ASSOCIATION: Gosudarstvennyy institut azotnoy promyshlennosti, Moskva
(State institute of the Nitrogen Industry, Moscow)
SUBMITTED: Nov-ember 12, 1958
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84625
S/076/60/034/010/002/022
5~47'm X101,50 12.1-S *41 3015/B064
AUTHORS; Krichevskiy, 1. R., Khazanova, N. Ye.., isvetlova, G_ M.1
TDece-ased), a;7d--
TITLE: Total Vapor Pressure Over the Solutions of.Triethyl
Amine - Water in the Critical Range
PERIODICAL: Zhurn Ia\1 fizicheskoy khimii, '1960, Vol. 347 No. 10,
pp. 2-j60 - 2166
TEXT: Investigations of the total vapor pressure over binary solu-
tions in the vicinity of the critical point are interesting for two
reasons. On the one hand, it is important to establish according to
which laws a distribution of the critical phenomena In the homogeneous
region takes place, on the other hand, it is important to study the
problem of jumps of the intensive quantities when intersecting the
limiting curve both in the critical point and at a distance from it,
the importance of this has already been stressed by the authors of
the present paper (Ref. 1). For the mentioned reasons the authors
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84625
Total Vapor Pressure Over the
Solutions of Triethyl Amine -
Water in the Critical Range
S/076J60/034/010/002/022
-BO15/BO64
investigated the critical parameters for the equilibrium liquid -
liquid in the system triethyl amine - water. For this purpose spp--~al-
ly p-arified triethyl amine was used (specific weight at
250C - 0.72345 g/cm 39 refractive index at 25 0C nD - 1.398).
The vapor pressure of triethyl amine was determined (Table 3) and the
total pressure of vapor over the system A. ziethyl amine - water in the
temperature range of from 100 tc 250C (Fig. 2) and the limiting curve
for the equilibrium of the system inv,~,qtigated, i.e. tht~ rr-ti.-al
solution temperature (Table 4, Yig~ 1). As may be seen from Fig. 2..
tha iaosteric c-arve of the solution w�th a -Lomposition -,'csr to that
of the critical (30-56 wt% triethyl amine) passea contlnUCU31Y over
intc) the limiting courve, while the curves for the solutJons with
different compositions form an angle with zhe equilibrJum curve. The
experimental values and the calculated ones show that the derivation
of the values of the total. pressure according to temperature
Ptotal' A T)N
2
Card 2/7

Total Vapor Pressure Over the
Solutions of Triethyl Amine
Water in the Critical Range
84625
3/076/60/034/010/002/r,22
B015/BO64
an well as the derivations of the other intensive values show no jump
on intereecting the limiting curve at the critical point. This coinci-
dence of the experimental and calculated data confirms the accuracy
of the theoretical assumptions. From Diagram logP - f(l/T) (Fig. 2)
the values for the total pressure over the solution were interpolated
for inte ral values of temperature (Table 5), the P - x diagram
plotted ~Fig- 3), the limiting curve drawn, and thus, the values of
the vapor pressures on the boundary line ob 'tained (Table 6). Fig. 3
shows that at concentrations close to the critical point a slight
dependence of the total vapor preasure over the solutions on the
concentration is to be tobserveLd I in the wide temperature range.
Thid corresponds fully to the thermodynamic characteristics of the
.behavior of substances-in the vicinity oV the critical point. D. Mayer
and V. F. 'Alekeeyov are mentioned.There are 3 figures, 6 tablesp
and 11 ieferences: 7 Soviet, 2 British, I German, 1 French.
Card 3/7

84625

Temne 6 Rannewme. Temnel)a
06 Ablaell"a.
MR. Am PT. cy. TIM AA PT. B01
i 13,&9" 36,7 40,M Tmj.
1 18,07 4815 60M 292,&
13.50 62,8 70, 12) M5.15
27,57 76,6 89,4" 760 0
32,20 94,9,

HOMICHTPalmn Temnepa- aRIVIVIttle. Tpown Temliops. Asonetiffe,
!,TpnmnnxmlfHS, TIP&, AL64 PT. VPtIDTNnA-
Millis TICR. PT.j t
?
%

-
1 cl. ,
% am. .
c
7
7~7 i4 0 78 7 0.9 0 '6 57,~
8:9 22:0 10:4
"
" 23,2 1814 56,8
M4 20,0 62,6 30,0 18,35 50.7
o
59 32,2- to,33* 56,00

Card 4/7