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SCIENTIFIC ABSTRACT KHITAROV, N.I. - KHITRIK, I.S.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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VINOGRADOV, A.F., akademik, otv. red,j BAUNOV, V.I., red.; BARSUKOVl V.L., red.; BEUS, A.A., red.; VALYASHKG,.M.G., red.; GERASIMOVSKIYy V.L. red.; KORZHINSKIY, D.S., red,; RONOV, A.B.,, red.;ITUGARINOV,-A.I., red.; AHITAROV N I red. SHCHERBINA, V.V., red.; TARASOV, L.S., red.-lzid-va; DOROKHINA, I.N., tekhn. red. (Chemistry of the earth's crust]Khimila zemnoi kory; trudy. Moskva, Izd-vo Akad.nauk. Vol.l. 1963. 430 p. (MIRA 16:3) lt Geokhimicheskays konferentsiyai poovyashchennaya stoletiyu so dnya rozhdeniya-4kademika V.I.Vernadikogo, Moscow,1963. (Geoebemistry) KHITAROV N.I.; RTZHENKOx BX; IEBEDEV, Ye.B. Determination Of the electric conductivity of the solutions of sodium carbonate and bicarbonate under hydrothermal conditions. Geokhimiia no.lt4L.47 Ja 163. (MIRA 16:9) 1. Vernadsky Institute of Geochemistry and Analytical Chemistry., Academy of Sciences, U.S.S.R.t MOOGOW.- (Sodium carbonate-Electric properties) PUGIN., V.A.; CHZHAO BIX(Chao Ping] (Kitayakaya Narodnaya Respubiika); SLUTSKIY, A.B. interrelations,- of andaluiite, cyanite, and.sillimanite under the conditions of.-xo4erate.tdmperat1ures and pressures. GookhWia no.3:;@19-228 W 163. (HIRA .16:9) 1. Vernadaky Institute of--G.eochemistry and Analytical Chemistry, Academy of Sciences, U.S.S.R., Moscow. (Andalusite) (Sillimanite) (Cyanite) ON- NO W H @7111MIW "Nopl,ir'sm 4@ ikIM2637 OOM 16 A 0 q TITLEt Chdractartittes at Ove tq@ep VDIMS of the eArgh'-s arms baetif cm Certaill 4*ta v t ry o f the eart h',t 1964, .16-40 i r@,h cruat, ttedimentary rf)ck, continental, cr,ist ';OnrPkd dig- rxnal@ gr ad ienL C- 'rhe alternatton of acdimentary rocks by remelting to aza-mined with zei;sure, depth , temperature at start of ine'ting, and water conteint. I& ni pressure with depth of the sediments nnr1r,@-i-Kiv f!frecls 'he drop i. ne.,iling temperature but only r,) a cortain ',v@' -i @ i -I @a,,uE conEent in Ene material. After ccvmpnrinR the geological, i-it' experimental data, t1he autvior 'e M-1 zu, 'ft ellinination co: non: nugenoiLy of the C,d L 236b8-65 AC(731@10N AT11002637 crr3t and that the most-probable values of t:he grgdier@ c-xcpe@! '2-15 in @heir nature, a r 1, 1 p1.1 should be corrulat" to t rar mpper- nf 7 ri-, ! 01 V I C -Lions that preveiled durIng the i .. At ce r ta in 1 eve app rec i ab 1 a @iiiaL cuu id heve the mapmttc melt A,- 1@ @)r- A IT (')N - Institut geokhimit i analitiche@koy khimif im, V. T. Vernedgkogo ry a-d @!n@il !cn 1 t; --r ES SUMIRNOV, V.I.$! akademikp red-p* YMIAKOV, N.P.s red.; DOLGOV, Yu.A,, red,; SOKOLOV, G,A,: red.; KHITAROV, N.I.2 red. [Mineralog !Ical the rmometry and barometry] R n,@j-63ogicheskaia termometriia i barometriia. Moskvas Nauka, 1965. 327 p.@ (MIRA .18-5) 1. Akademiya nauk SSSR. Nauchnyy Sov6t PO rudoobrazovaniyu. KADIKJ A.A. @N,I, Effect of pressure on the masstransfer between a magmatic melt and the water of external media, Geokhimiia no,5*507-518 My. 165,. 18 39) .10 Institut geolkhimli i analiticheskoy khimli imeni Vernadekogo AN SSSR, Moskva, Kya* KITITAROV, N.I.; SLUTSKIYp A. Ba Effect of pressure on the malting teniperatures of albite and basalt according to data of electroccnductivity measurement. GeoAlmiia, not 12*.1395-1403 D 165 (min 19 ti) 10 Institut geokhimii i artalitichaskol k' 'xII Imni V.I. Vernad- skogo AIT'SSSIZ, Moskva. Subnitted Auguat 25, 1965. ME .ACC" NRt _'@V 06361C SOURCE GODE: UR/0007/66/000/009/1132/lUC AUTHORzo @Khitai-dv,' go X# ORG: n TITLE:. Information on'recent experimental work on deep-seated processes SOURCE: :Geokhimiya.. no. 9# 1966, 3-132-3-140 TOPIC TAGS: mineralogy, petrology, thermodynamics ABSTRACT: 'Thepapers presented at the-annual symposium on deep-qeated. processes can be subdivided into the following five sections: I :physicochemical characteristics of natural processes under conditions ;of elevated temperatures and pressures taking place in the presence. lof water; 2 - synthesis of min6rals under hydrothermal conditions; -3 - research on water-free melts@ 4 - instruments and methods; 5.- properties of materials and transiormation at high temperatures 'and pressures and summaries of researclk conducted at certain Anstitutes. The lecturea which fall in the fifth section. of "Properties of materials. and transformations under high -pressures. and temperatures" are. sum- marized.below. Card 1/14 I 61 464@_Nk,_AP760106 The annual symposium of experimentalists, whose work is asso- .ciated with deep-seated processes, was held on 15-16 February 1966 try and Analytical Chemistry im. V. 1. .at the Institute of Geochemis Vernadskiy, Acadepy of Sciences USSR. The symposium dealt with -the research performed in 1965 and ongoing investigations. 'Some of the scientific research institutions which participated in the symposium' were: Institute of Geochemistry and Analytical Chemistry AS USSR (GEOXhl), Institute of Physics of.the Earth AS USSR (IFZ), Institute 1 of Physics of High Pressures AS USSR (IFVD), Institute of General and Ino'rganic Chemistry'AS.USSR (IONKh), All-Union Scientific Re- search Institute for the Synthesis of Mineral Raw Materials (VNIISIMS). Moscow State University (MGU), All-Union Scientific Research Institute! of Geology (VSE 'GEI), Institute of Geology and Geophysics, Siberian Branch AS'USSR (IGG), Institute of'Geology of Mineral Deposits, Pdtr;ography, Mineralogy and Geoc'@emlstry AS USSR (IGEM),. All- Union Institute of Mineral Raw Materials (VIMS), Institute of Crystal- -lography AS USSR (1K), State Institute of Nitrogen Industry AS USSR (GIAP), Institute of,Geochemistry, Siberian-Branch AS USSR (IGS). Institute of Mineralogy, Geochemistry and.Crystallography of Rare Elements AS USSR (ImGRE), the Moscow All-Union Scientific,Rese.,i@ch Institute, of,Ph iotechnical and Radiotechnical Measurements ys cord 2/14 ACC NRi AP7003016 (VNIIPTRI) and the Siberian Branch In Novosibirsk, Kharkov Agri- cultural Institute im. Dokuchayev, Institute of inorganic Chemistry, 1 Siberian Branch AS USSR (IONKhS), and Institute of Geological Sciences !'AS Kazakh SSR. 7he specific heats of andalusite and sillimanite at temperatures up 'to 120WC were measured by the thermal- analysis method. The specific heat of serpentine at temperatures between 100 and 5OWC was determined for the first time. The specific heats of granite, basalt, -peridotite (52-0/6 serpentization). and serpentinite :zontaining 92-% .6erpentine were also determined. -Results oMe measurements show.. at atthe temperatures; investigated Wicific heats of ultra- basic rocks are abnormally high owing to the presence of serpentine. The heat of dehydration of serpentine measured by thermal analysis was in agreement with that computed from thermodynamic data (V. Ya. L.eonidov, GEOKhl). A new modification of,titanium dioidde (T2029), which is meta- stable under normal conditions, was, -obtained as a result of an in- vestigation of the stability of ruU16 under high pressures (40 to 120.kbar)' and temperatures (400 to 150(f C). Too methods used were such as to Card 3/14 ACC NRs A.P7003016 -.take into ac -count the presence of water acting as a mineralizing agent in the operating chamber during the entire experiment. As a result.of the investigation of the TiO 211 Modification, it was established that the new phase has the structure of the cr -Pb 2 0 type (orthorhombic, .cell, space group D PbcO with the lattice constants of the unit rh cell A = 4. 531 :h 0. 001, A, b - 5.498 :t 0. 00 1 A, @c - 4. 900 t 0. 00 1 A. .The x-ray density is equal to 4. 35 g1cm 1; the' increase in density at polymorphic transformation la equal to 30/6. An inverse transition into .the common form of rutile was accomplished by heating the TiO II 2 powder at 60(r C for four hours (N. A. Bendelian, S. V. Popova, L. F. Vereshchagin, IFVD). Methods for the investigation of elastic and electrical properties of rocks under high pressures have been developed in the section on the physical properties of rocks of the Institute of Physics of the Earth, Academy of Sciences USSR. In investigating the velocities of longi- tudinal and shear elastic waves, as well as the electrical resistivity and dielectric constant of the rock samples under the pressure of Aeveral thousands kg/cm2, apparatus with "nitrogen gis-its ihe* pressure- .transmitting medium are'used. A hydrostatic hydraulid apparatus .uded in experiments'@@iformed ader pressures up to 10 kbar. At c,rj 4/14 @ACC NIR" AP7003016 .pressures up to 40 kbar, -the velocities of elastic waves can be deter- 'mined at quasi-hydrostatic pressures, where the samples in thin lead envelopes ar6 placed into a chamber of a piston- in -cylinder apparatus. The electrical properti@s of thin waters are investigated under pres- sures, up to 40 kbar and temperatures u -to 6001 C (M. P. Volarovich, p Alkali-basalt End andesite-basalt glasses have been obtained from a quenched melt held for 2 hours at a temperatu-re of 1300* C and pressures of 1, 5, .10, 15, and 25 kbar.* During the experiments the melt' absorbed water given off by a tale-py-i-ophyllite pressure- Maximum water content transmitting medium at high temperatures. , of the melt was 4%. Absorption of water resulted in the increase of n and d of the glasses. 'The prese.nce of OH. and H'2 0 in the melt and the increase in the importance of hydroxyl-at increasing pressures. was inferred from the infrared observations Mi. S. Genshaft, ;V@ V. Nasedkin,,Yu. N. Ryabinin, IPZ).. Phase diagrams of.sulfur, selenium, and iodine at pressures @4up -to -45, 000-50, 000 kg/cm7. and temperatures up to 7000C were .investig@tted. The melting curves'of these substances were de-' Card 5/14 _kCCNR: AP7003016 termined at pressures up to 10, 000 kg/cm@l ina.hydrostatic ex- 'ternally heated bomb and in a sealed capsule. The pressure was measured with great accuracy by means of a manganin manometer. :The melting was deternined from the change'in.the volume of the 2 :-substance. Phase dihgrams at pressures in excess of 10, 000 kg/cm were determined in a cube anvil device. Calibration was made from -the discontinuities in@electrical resistivity of Bi and TI. The melting curve of sulfur has a peal@ at 16, 000 kg/eml and 3 10*C and. a,triple, 2 point at 19, 000. kg/cm and 29P*C, The presence.of. a new phase Aransition in sulfur at 2(rC and 23, 000 kgIcm was determined from the compressibiliiy.of the sample. Under, a pressure of 40, 000 kg'/crn2, 'the sulfur melted at 450'C. A maximum of the melting curve of Se 2 -was observed at 50, 000 kg/cm and 6MC. - These data agree with 'those of C. Susse and R. - Epain (60, 000 kg /CM2 and --640* C). The .:meliing curve of iodine at pressuzles up to 48, OOO.kg/crnF and a temperature of 6560C increased, monotonically with increasing pressure (Ye. Yu. Tonkov, L Xe.- Paukov, D. S., Marinskiy, V=TRI). The electrical co@ducti@ity of and basalt was, investigate-' at'high 'pressures and temperatu,res"..-, The data f9T-, quartz obtained in Card '6/14 ACC NRi AP7003016 M_ ii @@ide -range of temperatures confirm the presence of a minimu ' in !the resistance -pressure curve. With increasing temperatures the ;minirfturri is shiftea toward lower pressures. Owing to the exponential dependence of electrical conductivity on temperature, an accurate 'measurement of the, temperature, and especially of its gradient in the sample, is of - great importance. The errors in the measurement of the temperature caused by the loss cf. heat through the thermo- '.couple were evaluated by comparing the differdnce in-measurements 'obtained- using three Pt-PtRh thermocouples of different diameters, .with their junctions in the high-pressure chamber. Results of measurement have s'hown that, at T1, 200*C and P - 28, 000 atM , the error for thermocouple s with d0. 3 mm was 40* C (A. B. Slutskiy, Gj3Khl). Alkali igneous'rocks. from the Kola Peninsula, having high i.electrical conductivity and low activation -energy under atmospheric conditions, exhibit a change in electrical resistivity of one-two orders of magnitude at pressures up to 20, 000 kg/cm? and tempera- ,tures up to 7000C.- The electrical resistivity of alkali :rocks decreases less rapidly with increasing nepheline cortent and a Idecr.easing aegirite content, and vice versa. With an Increase in ipijessure, the,appearance of..a new type-of electrical conduc#vityj@. Card-VA- AC'C" Nkt_--AP7003016 'shifted toward the lower temperatures. In addition to an increase in !electrical resistivity when the pres,sure is increased from the atmos- pheric pressure to 20, 000 kg/cm the activation energy also de- :creases from 0.76 to 0.42 ev, and the pre-exponential factor decreases from 10-4 to 6 x 10-4 ohm-1cm-1. Thus, in alkali rocks the decrease in electrical resistivity with pressure is the result of a decrease in the width of the forbidden band. Thus, when computing the distribution of temperatures with,depth fromi electrical conductivity, it is necessary to take into account the effect of pressure on the electric conductivity of rocks (A. T. Bondarenko, IFZ). In the carbon-nickel system, a new phase of carbon penetration into nickel may be obtained at pressures of 16-20 kbar and temperaturew of the order of 1, 500"C. The new phase is represented by elongated. laminated crystals about 0. 1-mm long, and consists of 1276 C and 88% Ni. This product is easily soluble in hydrochloric and nitric acids and is easily oxidized by atmospheric qxygen at 5000C. Its The new phase has a face-centered Ispecific graNity is 10 g/CM,3 ,,,cubic lattice with the lattice constant a = 3. 533 :L 0. 005 k. These 'investigations indicate-the possibility of existence of a nickel carbide 4compound (Ni (I. V.,Nikollskaya, Ya. A. Kalashnikov, Ye. 4C3)' :Fekli,chev, L. F. Vereihchagin, IFVD). ACC NRs AP7003016-- E)iper'ir@ents oh.aillcali basalts at high, temperatures and pressures between 5-10 kbar in the'presence of water have shown that the order of crystallization of the,minerals with decreasing temperature is as follows: n agnetite,'monoclinal pyroxene, plagioclase, garnet, rand biotite, I'n the range of pressures of 20-25 kbar, the order of crystallization is as follows: magnetite, monoclinal pyroxene, .',garnet, and amphib'ole. A simultaneous crystailization of plagioclase 1 and garnet has been observed at a pressure of about 15 kbar. Abrupt ,changes in (@mperature 4nd pressure are instrumental in causing considerable fractionation of the crys;Zallizing melt. As a result of @this, it is possible to obtain more acidic derivatives, corresponding to diorite; grandodiorite, and garnet (Yu. S. Genshaft, V. V. Nasedkin, Yu., N. Ryabinin, V. P. Petrov, IFZ, IGEM). At temperatures up to 6700-C, two types of variations of electrical 1@resistivity versus pressure wer.e observed in quartz, microcline, inepheline, and aegirite as pressure was increased up to a maximum ;of 20, 000 kg/cm2. A 50% decrease in elt-.,ctrical'resistivity of quartz monocrystals was noted when the -pressure along UE optical axis was changed. Card 9/14 At@ NR, iF_7_66_S6f6- resistivity minimum which shifted toward.the lower pre s@res ,at higher temperatures was observed in measurements performed- in nepheline along the optical axis, in quartz perpendicular to the optical axis.and in microcline along the cleavage. Only increasing resistivit -was observed in nephqline at,670*C. . Evidently, the increase in resistivity., with pressure is associated with a decreaso in mobility of charge A carriers (E. Y. Parkhomenko, A. M., Bondarenko, IFZ). Experimental data' were used in computing the relationship between density and the velocities of elastic longitudinal waves in rockb from central'Kazakhstan. Correlation curves were -.obtained under atmos- pheric conditions., as well as under pressures of.1, 4, 6, and JO kbar. A linear relationship between the velocities of longitudinal waves and the bulk density'was' observed for all pressures. The 'correl ition .fact6rs'vary from 0. 85 to. 0. 89. The. coefficients of the, linea: equation -depend on the valu6 ..of -the, corilnw,4 pressure. 'The: constant te*rM Wag 1@ _ r - a ea. With no d gat vebut rapt ly approached ze. o..a nig!,er pres ur -increased pr@ssures the,s.lope of the -curves ',Jended asymptotically Ao a con8t@nt valpeof 2.42 atpreaburesih ex-c-oss of 10 kbar (M. P. Volarovith, A. - K., Kurskeyev, 1. _ S; Tomislievskaya, If' L. Tuzov.- I S. M. Uraiayev, IFV,..GINKaz)._.-."1 .Card ACC NRt AP7003016 The dedarb Iz ki on ation,process, Yider.high lithostatic pressures was investigated using smith$onite_6nd mat!nesium dioxide (inert, substance). Comparison of the differential heatinj curies obtained at atmospheric pressure, at 1800 atm; and.zitl 0. 000 atm shows a decrease. in the endothermic peaks on the.thermograms and shifting of Ahe initial inflecti on point toward. higher temperatures, as the pressures are increaseld.. -,These changes were attributed mainly to an; increase in the specific)heat with increasing pressures, as well as to a decrease in the@ disassociation reaction rate. Additional experiments lead to the . conclusion; that'the'decrease in the disassoci- ation reaction rate under.pressure occurs in the areas of grain con- tact. Under a pressure.,bf 10, 000 atm, theAlsassociation reaction does*Pot proceed to the end even.in-the presence of large overheating. 'At the same time, the pressure of P02 considerably in excess of the load pressure. rnay occur . in. the pores adjacent, to the undecomposed. grains. An approximate;thermodynitmice-valuation of the influence' of .pressure on the heat effect was performed. It was determined that -the maximum possible decrease of the thermal effect at 10, 000 at-M ;can reach 15116 (G. T. Ostapanko, VNIISIMS). j..ACC NRs AP70030161 'Usinga piston gage. The experiments. have shown that for cesium' 'AV - 0. - The. resitIts of e"xp'er'iments with cesium can be represented by the folloiwing'6quation for the change in volume: T AV 0.0125-0.066 log (-!M!i- ------- 'fo@,the melting c-@rV6, V(K) 302.9,+ 193 x jr3 x P + 0.593 x. 10-6 X.p2. Correspondingly, for. mercury, 3 AV (4:). - 0;0025@ 0.00205 x log ( T 9 .234.29 T 1-1,77 P 38.993 ?(V. -S. Bogdanov-, VNIIFTRI) The interrelationship be@xeen elastic and electrical properties of rocks was investigated by conducting simultaneous measurement of longitudinal waves and.'electrical resistivity in samples of moist porous sedimentary rocks.under high hydrostatic pressures up to '3000 kg/cm2. Carb .onaceous rocks and sandstones with porosities between'6 and 2016 and rn@oisture content between 1.8 and L5% were investigated. It,was'est.ablished t6t.the velocity of. elastic wavep Card 13/14 A.CC NRt AP7003016 Rnd the electrical resistivity had their* smallest values in samples "With the highest porosity. With'increasing pressures the velocity in such samples increased considerably, while the electrical re - sistivity increased only @slightly. The small increase in electrical resistivity with pressure was attributed to the. high moisture content of the highly porous rocki (Mi. P. Volarovich, Ye. I. Bayuk, K. P_ ,Valeyev, IFZ). Spectral investigations at high pressures were conducted in an apparatus, which includes a 30-ton hydraulic press, a high- .pressure chamber, an optical system with a mirror illuminator, a mondchromator and phot0elettric device. The phase transformations of the first and second kind were studied in benzene and ammonium ichloride. Crystallization of certain fluids (CHCL3, C 6 H6 and its derivatives) under compression and the effect of pressure on the dynamics of the crystalline lattices Of C 6H6 and NH 4 CI were investi- gated. and a relationship vas established between the changes in frequencies of lattice vibrations of the optical branch and'the lattice constants of the crystals, The effect of pressure on the frequencies .'of intrinsic vibrations-of ihe NH + cationin NH.CI was investigatee CPSB; '' v*- 2, no. jjj SUB CCDE: 080 20 SUBM DATHI none Cc-rd 14114- KHITAffAN#.M.G*t uchitell P876'Ological training of students for farm work, Blol.* shko;O n0*6159.62 039, 1, (MA 13:3) BrednVaya shkola KO*78 g.govosibirska, (Agriculture-4tudy and teaching) KHTTEITKOV, Grigoriy Georgiyevich. All-Union, Sci Res Tnst of Horse-Breeding. Acadenic degree of Doctor of Agricultural Sciences, based on his defense, 24 December 1954, in the Council of the Moscow Veterinary Academy, of his diesertation'enti- tled: "Experiment in the Improvement of Saddle Horses in the USSR.". Academic degree and/or titlet Doctor of Sciences SO: Decisions of VAX, List no, 15, 25 June 55, Byulleten' MVO SSSR,, No. 15, Aug 56, M0.800wt PP. 41-24, Uncl. JPPS/NY-537 USSR/Farm Animals - Horsed Abs Jour : Ref Zhur Biol-, No 15, 1958, 69244 Author : Khitenkov, G. Inst Title : Achievements of Soviet Hippology Puring 40 Years. Orig Pub : KoneVodstvo,'1957, No 11) 9-15 Abstract No abstract Card 1/1 RWOZIN, G.K.; mpmoy, M.Yu., Icand. seI'sIwkhozyajyotyanrqkh nauk; 14WOTJL, A.A.. kamd. eel IskokhmaystvanzWkh nauk; W9'j-WSVAp T.Te; TOW.LYLTBOYs B.A..' kind. oel.IskokhozMotvennykh nauk; PWAVTSVI .P.N., d9ktor eel tskok.hox*yst-Tenmykh nauk; LITOYOMMO, G*R*,, kod, sellskokhmaystysuafth nauk-, KOLMOT, G,.H*; IOYR, K.Sh.; IffIVAWMO"---- --A4.#.ddktor eel 'gkokhoxy&ystvenr*i& nauk; DaMIYAN, G.G. doktor sellskokhotMetvanulkh *uk,,, IVANOTA, A.A.; ROMT, A.P,; AMYSKIY, I.P.1,SPIRIDONOve A.L., ksud. sslIskokhozM'stvennykh nauk: ZHMXOT G ;'WNj1KOV, N.A.o red IVA@WTAq AOX red.-, ZUBRILINAO Z.P., .G., tekhn. red. [Idonomics and orga#zation of stockbreeding on collective farim] Nkonomika i organizateiia zhivotuo@odstva4v kolkhozakh. Moskva, Goo. izd-vo sellkhos.' lit-ry, 1958. 550 p. (MIRA Ilt7) (Stock and stockbreeding) IVANOVA, Z.-J.. kandidatvetertuarafth nauk; XHITBNMA -L.P. uladshly -nauchnyy notrudalk. Anduo-atabrine treatment of mcnisilasis In sheep. Veterin&rll& no.11:58 N 153. (MBA 6 11) 1. Gosud"stvsnW nauchno-kantrollay Institut veterinarafth preparboy Winisterstva sellskogo khosyaystva I sagotovok MR. K H i v - 1 1. P. S/064/61/000/007/004/005 B124/B206 AUTHORSs Chekhov, 0. B., Anokhin, V. W., Shekun, B. N., Khiterer, R.Z. TITLE1 Investigation of hydrodynamic processes in a pseudo-diluted solid-partiole layer under high pressure .BERIODICALs Xhimicheskaya promyshlennost', no. 7, 1961, 48 50 TEXTs The hydrodynamics of pseudd-diluted solid-particle layers-were investigated at 1-300 kg/cm2 and 2'5-300C with a stoiohionetrio gas mixture used.for the synthesis of ammonia* Coke particles of good electrical con- ductivity and metallic needle--'b6_nd lazella -s-haped filinge were used as solid phase. The critical rate velocity,of the gas.-mixtuxe and the height of the pseudo-diluted solid-particle layer during the process were deter- mined. The gas mixture was purified of steam, oil droplets.and other impurities, and ducted into a vertical, cylindrical high-pressure column with an inner diameter of 25 mm which contained the solid-partiole,layer. The mixture was then throttled to atmospheric pressure and its consumption was measured with a rheometer. The transition of the solid-particle layer into the pseudo-diluted state, which corresponded to the critical gas Card 1/9 Investigation of... V24/B206 velocity@ was brought about by.. closing the-..oircuit Abcve the solid- n electric contact which touched the la er after particle layer there was a the beginning of the expansionana thuslolosed the circuit. The second electric contact was connected to the housing of the:high-pressure columns For the determination -of the keight. of the paeudo-d.i.l,-4ted.solid-pa-rtidie'* ..layers,-:th-e distanoe-of'the'upper surface of,the atetionitry layer from the electric contact in the high-pressure column.was varied.; The determina- tion results obtained during opening were practically equal to thosoob- tained during 010'sing of the circuit. The experimental results obtained for the critical gas velocities were treated according to the method pro- posed in Ref. I (A, I. Rychkovt N. k. Shakhova, IFZh, No. 9t 92 (1959)) for determining the critical 'gas''velocities -at various temperatures and atmospheric pres Is ure @Ref.'@?s 0. M. Todes, A. K. Bondareva, Khim. nauka i prom., L,. No. 2 (1957 )- First, the critical gas velocity(a or (in m/sec) at atmospheric pressure was'determined experimentally, this value being a, function of the mean particle diameter d and the density of the mean particles, under absolutely equal conditions. Prom the known value ca or) the equivalent diameter d of the pores in the layer (in n) was calculated e Card 219 S/064/61/000,1007/004/005 Investigation.ofeet B124/B206 2 2 from the equation d 0 8c) g.l/4P-r.?g)_ de (73YO) ..lAp%g) .01.1 e or 0 ox 9 (1), where o is the gas velocity related to the total column diameter, or the density of the,gas, 1 the height-of the stationary solidI-particle t g layerp AP the pressure,,differenee, e the porosity of the stationari solid- 0 particle layer, g the gravitational acceleration and V "The kinematic viscosity of the gas. The critioal velocity. of.. the gas at any pressure was det"orminedl rom the equivalent -diameter by the- f ollowing equations j 1) for laminar Ponditions ,at Re