SCIENTIFIC ABSTRACT KHITAROV, N.I. - KHITRIK, I.S.
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CIA-RDP86-00513R000722020010-7
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S
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100
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Publication Date:
December 31, 1967
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SCIENTIFIC ABSTRACT
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VINOGRADOV, A.F., akademik, otv. red,j BAUNOV, V.I., red.; BARSUKOVl
V.L., red.; BEUS, A.A., red.; VALYASHKG,.M.G., red.;
GERASIMOVSKIYy V.L. red.; KORZHINSKIY, D.S., red,; RONOV,
A.B.,, red.;ITUGARINOV,-A.I., red.; AHITAROV N I red.
SHCHERBINA, V.V., red.; TARASOV, L.S., red.-lzid-va; DOROKHINA,
I.N., tekhn. red.
(Chemistry of the earth's crust]Khimila zemnoi kory; trudy.
Moskva, Izd-vo Akad.nauk. Vol.l. 1963. 430 p. (MIRA 16:3)
lt Geokhimicheskays konferentsiyai poovyashchennaya stoletiyu
so dnya rozhdeniya-4kademika V.I.Vernadikogo, Moscow,1963.
(Geoebemistry)
KHITAROV N.I.; RTZHENKOx BX; IEBEDEV, Ye.B.
Determination Of the electric conductivity of the solutions of
sodium carbonate and bicarbonate under hydrothermal conditions.
Geokhimiia no.lt4L.47 Ja 163. (MIRA 16:9)
1. Vernadsky Institute of Geochemistry and Analytical Chemistry.,
Academy of Sciences, U.S.S.R.t MOOGOW.-
(Sodium carbonate-Electric properties)
PUGIN., V.A.; CHZHAO BIX(Chao Ping] (Kitayakaya Narodnaya
Respubiika); SLUTSKIY, A.B.
interrelations,- of andaluiite, cyanite, and.sillimanite under the
conditions of.-xo4erate.tdmperat1ures and pressures. GookhWia
no.3:;@19-228 W 163. (HIRA .16:9)
1. Vernadaky Institute of--G.eochemistry and Analytical Chemistry,
Academy of Sciences, U.S.S.R., Moscow.
(Andalusite) (Sillimanite) (Cyanite)
ON-
NO
W
H
@7111MIW "Nopl,ir'sm
4@
ikIM2637 OOM 16 A 0 q
TITLEt Chdractartittes at Ove tq@ep VDIMS of the eArgh'-s arms baetif cm Certaill
4*ta
v t ry o f the eart h',t
1964, .16-40
i r@,h cruat, ttedimentary rf)ck, continental, cr,ist ';OnrPkd dig-
rxnal@ gr ad ienL
C- 'rhe alternatton of acdimentary rocks by remelting to aza-mined with
zei;sure, depth , temperature at start of ine'ting, and water conteint.
I& ni pressure with depth of the sediments nnr1r,@-i-Kiv f!frecls 'he drop
i. ne.,iling temperature but only r,) a cortain ',v@' -i @ i -I
@a,,uE conEent in Ene material. After ccvmpnrinR the geological,
i-it' experimental data, t1he autvior
'e
M-1 zu, 'ft ellinination co: non: nugenoiLy of the
C,d
L 236b8-65
AC(731@10N AT11002637
crr3t and that the most-probable values of t:he grgdier@
c-xcpe@! '2-15
in @heir nature, a r 1, 1 p1.1
should be corrulat" to t rar mpper-
nf 7 ri-, ! 01 V I C
-Lions that preveiled durIng the i ..
At ce r ta in 1 eve app rec i ab 1 a @iiiaL cuu id heve
the mapmttc melt
A,- 1@ @)r- A IT (')N -
Institut geokhimit i analitiche@koy khimif im, V. T. Vernedgkogo
ry a-d @!n@il !cn 1 t; --r
ES
SUMIRNOV, V.I.$! akademikp red-p* YMIAKOV, N.P.s red.; DOLGOV, Yu.A,,
red,; SOKOLOV, G,A,: red.; KHITAROV, N.I.2 red.
[Mineralog !Ical the
rmometry and barometry] R n,@j-63ogicheskaia
termometriia i barometriia. Moskvas Nauka, 1965. 327 p.@
(MIRA .18-5)
1. Akademiya nauk SSSR. Nauchnyy Sov6t PO rudoobrazovaniyu.
KADIKJ A.A. @N,I,
Effect of pressure on the masstransfer between a magmatic melt
and the water of external media, Geokhimiia no,5*507-518 My.
165,. 18 39)
.10 Institut geolkhimli i analiticheskoy khimli imeni Vernadekogo
AN SSSR, Moskva,
Kya*
KITITAROV, N.I.; SLUTSKIYp A. Ba
Effect of pressure on the malting teniperatures of albite and
basalt according to data of electroccnductivity measurement.
GeoAlmiia, not 12*.1395-1403 D 165 (min 19 ti)
10 Institut geokhimii i artalitichaskol k' 'xII Imni V.I. Vernad-
skogo AIT'SSSIZ, Moskva. Subnitted Auguat 25, 1965.
ME
.ACC" NRt _'@V 06361C SOURCE GODE: UR/0007/66/000/009/1132/lUC
AUTHORzo @Khitai-dv,' go X#
ORG: n
TITLE:. Information on'recent experimental work on deep-seated processes
SOURCE: :Geokhimiya.. no. 9# 1966, 3-132-3-140
TOPIC TAGS: mineralogy, petrology, thermodynamics
ABSTRACT: 'Thepapers presented at the-annual symposium on deep-qeated.
processes can be subdivided into the following five sections: I
:physicochemical characteristics of natural processes under conditions
;of elevated temperatures and pressures taking place in the presence.
lof water; 2 - synthesis of min6rals under hydrothermal conditions;
-3 - research on water-free melts@ 4 - instruments and methods; 5.-
properties of materials and transiormation at high temperatures 'and
pressures and summaries of researclk conducted at certain Anstitutes.
The lecturea which fall in the fifth section. of "Properties of materials.
and transformations under high -pressures. and temperatures" are. sum-
marized.below.
Card 1/14
I
61
464@_Nk,_AP760106
The annual symposium of experimentalists, whose work is asso-
.ciated with deep-seated processes, was held on 15-16 February 1966
try and Analytical Chemistry im. V. 1.
.at the Institute of Geochemis
Vernadskiy, Acadepy of Sciences USSR. The symposium dealt with
-the research performed in 1965 and ongoing investigations. 'Some of
the scientific research institutions which participated in the symposium'
were: Institute of Geochemistry and Analytical Chemistry AS USSR
(GEOXhl), Institute of Physics of.the Earth AS USSR (IFZ), Institute 1
of Physics of High Pressures AS USSR (IFVD), Institute of General
and Ino'rganic Chemistry'AS.USSR (IONKh), All-Union Scientific Re-
search Institute for the Synthesis of Mineral Raw Materials (VNIISIMS).
Moscow State University (MGU), All-Union Scientific Research Institute!
of Geology (VSE 'GEI), Institute of Geology and Geophysics, Siberian
Branch AS'USSR (IGG), Institute of'Geology of Mineral Deposits,
Pdtr;ography, Mineralogy and Geoc'@emlstry AS USSR (IGEM),. All-
Union Institute of Mineral Raw Materials (VIMS), Institute of Crystal-
-lography AS USSR (1K), State Institute of Nitrogen Industry AS USSR
(GIAP), Institute of,Geochemistry, Siberian-Branch AS USSR (IGS).
Institute of Mineralogy, Geochemistry and.Crystallography of Rare
Elements AS USSR (ImGRE), the Moscow All-Union Scientific,Rese.,i@ch
Institute, of,Ph iotechnical and Radiotechnical Measurements
ys
cord 2/14
ACC NRi AP7003016
(VNIIPTRI) and the Siberian Branch In Novosibirsk, Kharkov Agri-
cultural Institute im. Dokuchayev, Institute of inorganic Chemistry,
1 Siberian Branch AS USSR (IONKhS), and Institute of Geological Sciences
!'AS Kazakh SSR.
7he specific heats of andalusite and sillimanite at temperatures up
'to 120WC were measured by the thermal- analysis method. The specific
heat of serpentine at temperatures between 100 and 5OWC was
determined for the first time. The specific heats of granite, basalt,
-peridotite (52-0/6 serpentization). and serpentinite :zontaining 92-%
.6erpentine were also determined. -Results oMe measurements show..
at atthe temperatures; investigated Wicific heats of ultra-
basic rocks are abnormally high owing to the presence of serpentine.
The heat of dehydration of serpentine measured by thermal analysis
was in agreement with that computed from thermodynamic data (V. Ya.
L.eonidov, GEOKhl).
A new modification of,titanium dioidde (T2029), which is meta-
stable under normal conditions, was, -obtained as a result of an in-
vestigation of the stability of ruU16 under high pressures (40 to 120.kbar)'
and temperatures (400 to 150(f C). Too methods used were such as to
Card 3/14
ACC NRs A.P7003016
-.take into ac -count the presence of water acting as a mineralizing agent
in the operating chamber during the entire experiment. As a result.of
the investigation of the TiO 211 Modification, it was established that
the new phase has the structure of the cr -Pb 2 0 type (orthorhombic,
.cell, space group D PbcO with the lattice constants of the unit
rh
cell A = 4. 531 :h 0. 001, A, b - 5.498 :t 0. 00 1 A, @c - 4. 900 t 0. 00 1 A.
.The x-ray density is equal to 4. 35 g1cm 1; the' increase in density at
polymorphic transformation la equal to 30/6. An inverse transition into
.the common form of rutile was accomplished by heating the TiO II
2
powder at 60(r C for four hours (N. A. Bendelian, S. V. Popova,
L. F. Vereshchagin, IFVD).
Methods for the investigation of elastic and electrical properties
of rocks under high pressures have been developed in the section on the
physical properties of rocks of the Institute of Physics of the Earth,
Academy of Sciences USSR. In investigating the velocities of longi-
tudinal and shear elastic waves, as well as the electrical resistivity
and dielectric constant of the rock samples under the pressure of
Aeveral thousands kg/cm2, apparatus with "nitrogen gis-its ihe* pressure-
.transmitting medium are'used. A hydrostatic hydraulid apparatus
.uded in experiments'@@iformed ader pressures up to 10 kbar. At
c,rj 4/14
@ACC NIR" AP7003016
.pressures up to 40 kbar, -the velocities of elastic waves can be deter-
'mined at quasi-hydrostatic pressures, where the samples in thin lead
envelopes ar6 placed into a chamber of a piston- in -cylinder apparatus.
The electrical properti@s of thin waters are investigated under pres-
sures, up to 40 kbar and temperatures u -to 6001 C (M. P. Volarovich,
p
Alkali-basalt End andesite-basalt glasses have been obtained from
a quenched melt held for 2 hours at a temperatu-re of 1300* C and
pressures of 1, 5, .10, 15, and 25 kbar.* During the experiments
the melt' absorbed water given off by a tale-py-i-ophyllite pressure-
Maximum water content
transmitting medium at high temperatures.
,
of the melt was 4%. Absorption of water resulted in the increase of
n and d of the glasses. 'The prese.nce of OH. and H'2 0 in the melt and
the increase in the importance of hydroxyl-at increasing pressures.
was inferred from the infrared observations Mi. S. Genshaft,
;V@ V. Nasedkin,,Yu. N. Ryabinin, IPZ)..
Phase diagrams of.sulfur, selenium, and iodine at pressures
@4up -to -45, 000-50, 000 kg/cm7. and temperatures up to 7000C were
.investig@tted. The melting curves'of these substances were de-'
Card 5/14
_kCCNR: AP7003016
termined at pressures up to 10, 000 kg/cm@l ina.hydrostatic ex-
'ternally heated bomb and in a sealed capsule. The pressure was
measured with great accuracy by means of a manganin manometer.
:The melting was deternined from the change'in.the volume of the
2
:-substance. Phase dihgrams at pressures in excess of 10, 000 kg/cm
were determined in a cube anvil device. Calibration was made from
-the discontinuities in@electrical resistivity of Bi and TI. The melting
curve of sulfur has a peal@ at 16, 000 kg/eml and 3 10*C and. a,triple,
2
point at 19, 000. kg/cm and 29P*C, The presence.of. a new phase
Aransition in sulfur at 2(rC and 23, 000 kgIcm was determined from
the compressibiliiy.of the sample. Under, a pressure of 40, 000 kg'/crn2,
'the
sulfur melted at 450'C. A maximum of the melting curve of Se
2
-was observed at 50, 000 kg/cm and 6MC. - These data agree with
'those of C. Susse and R. - Epain (60, 000 kg /CM2 and --640* C). The
.:meliing curve of iodine at pressuzles up to 48, OOO.kg/crnF and a
temperature of 6560C increased, monotonically with increasing
pressure (Ye. Yu. Tonkov, L Xe.- Paukov, D. S., Marinskiy,
V=TRI).
The electrical co@ducti@ity of and basalt was, investigate-'
at'high 'pressures and temperatu,res"..-, The data f9T-,
quartz obtained in
Card '6/14
ACC NRi AP7003016
M_
ii @@ide -range of temperatures confirm the presence of a minimu ' in
!the resistance -pressure curve. With increasing temperatures the
;minirfturri is shiftea toward lower pressures. Owing to the exponential
dependence of electrical conductivity on temperature, an accurate
'measurement of the, temperature, and especially of its gradient in the
sample, is of - great importance. The errors in the measurement of
the temperature caused by the loss cf. heat through the thermo-
'.couple were evaluated by comparing the differdnce in-measurements
'obtained- using three Pt-PtRh thermocouples of different diameters,
.with their junctions in the high-pressure chamber. Results of
measurement have s'hown that, at T1, 200*C and P - 28, 000 atM ,
the error for thermocouple s with d0. 3 mm was 40* C (A. B. Slutskiy,
Gj3Khl).
Alkali igneous'rocks. from the Kola Peninsula, having high
i.electrical conductivity and low activation -energy under atmospheric
conditions, exhibit a change in electrical resistivity of one-two
orders of magnitude at pressures up to 20, 000 kg/cm? and tempera-
,tures up to 7000C.- The electrical resistivity of alkali
:rocks decreases less rapidly with increasing nepheline cortent and a
Idecr.easing aegirite content, and vice versa. With an Increase in
ipijessure, the,appearance of..a new type-of electrical conduc#vityj@.
Card-VA-
AC'C" Nkt_--AP7003016
'shifted toward the lower temperatures. In addition to an increase in
!electrical resistivity when the pres,sure is increased from the atmos-
pheric pressure to 20, 000 kg/cm the activation energy also de-
:creases from 0.76 to 0.42 ev, and the pre-exponential factor decreases
from 10-4 to 6 x 10-4 ohm-1cm-1. Thus, in alkali rocks the decrease
in electrical resistivity with pressure is the result of a decrease in
the width of the forbidden band. Thus, when computing the distribution
of temperatures with,depth fromi electrical conductivity, it is necessary
to take into account the effect of pressure on the electric conductivity
of rocks (A. T. Bondarenko, IFZ).
In the carbon-nickel system, a new phase of carbon penetration
into nickel may be obtained at pressures of 16-20 kbar and temperaturew
of the order of 1, 500"C. The new phase is represented by elongated.
laminated crystals about 0. 1-mm long, and consists of 1276 C and
88% Ni. This product is easily soluble in hydrochloric and nitric
acids and is easily oxidized by atmospheric qxygen at 5000C. Its
The new phase has a face-centered
Ispecific graNity is 10 g/CM,3
,,,cubic lattice with the lattice constant a = 3. 533 :L 0. 005 k. These
'investigations indicate-the possibility of existence of a nickel carbide
4compound (Ni (I. V.,Nikollskaya, Ya. A. Kalashnikov, Ye.
4C3)'
:Fekli,chev, L. F. Vereihchagin, IFVD).
ACC NRs AP7003016--
E)iper'ir@ents oh.aillcali basalts at high, temperatures and pressures
between 5-10 kbar in the'presence of water have shown that the
order of crystallization of the,minerals with decreasing temperature
is as follows: n agnetite,'monoclinal pyroxene, plagioclase, garnet,
rand biotite, I'n the range of pressures of 20-25 kbar, the order of
crystallization is as follows: magnetite, monoclinal pyroxene,
.',garnet, and amphib'ole. A simultaneous crystailization of plagioclase
1
and garnet has been observed at a pressure of about 15 kbar. Abrupt
,changes in (@mperature 4nd pressure are instrumental in causing
considerable fractionation of the crys;Zallizing melt. As a result of
@this, it is possible to obtain more acidic derivatives, corresponding
to diorite; grandodiorite, and garnet (Yu. S. Genshaft, V. V.
Nasedkin, Yu., N. Ryabinin, V. P. Petrov, IFZ, IGEM).
At temperatures up to 6700-C, two types of variations of electrical
1@resistivity versus pressure wer.e observed in quartz, microcline,
inepheline, and aegirite as pressure was increased up to a maximum
;of 20, 000 kg/cm2. A 50% decrease in elt-.,ctrical'resistivity of
quartz monocrystals was noted when the -pressure along UE optical
axis was changed.
Card 9/14
At@ NR, iF_7_66_S6f6-
resistivity minimum which shifted toward.the lower pre s@res
,at higher temperatures was observed in measurements performed- in
nepheline along the optical axis, in quartz perpendicular to the optical
axis.and in microcline along the cleavage. Only increasing resistivit
-was observed in nephqline at,670*C. . Evidently, the increase in resistivity.,
with pressure is associated with a decreaso in mobility of charge A
carriers (E. Y. Parkhomenko, A. M., Bondarenko, IFZ).
Experimental data' were used in computing the relationship between
density and the velocities of elastic longitudinal waves in rockb from
central'Kazakhstan. Correlation curves were -.obtained under atmos-
pheric conditions., as well as under pressures of.1, 4, 6, and JO kbar.
A linear relationship between the velocities of longitudinal waves and
the bulk density'was' observed for all pressures. The 'correl ition
.fact6rs'vary from 0. 85 to. 0. 89. The. coefficients of the, linea: equation
-depend on the valu6 ..of -the, corilnw,4 pressure. 'The: constant te*rM Wag
1@ _ r - a ea. With
no d
gat vebut rapt ly approached ze. o..a nig!,er pres ur
-increased pr@ssures the,s.lope of the -curves ',Jended asymptotically
Ao a con8t@nt valpeof 2.42 atpreaburesih ex-c-oss of 10 kbar (M. P.
Volarovith, A. - K., Kurskeyev, 1. _ S; Tomislievskaya, If' L. Tuzov.- I
S. M. Uraiayev, IFV,..GINKaz)._.-."1
.Card
ACC NRt AP7003016
The dedarb Iz ki
on ation,process, Yider.high lithostatic pressures
was investigated using smith$onite_6nd mat!nesium dioxide (inert,
substance). Comparison of the differential heatinj curies obtained
at atmospheric pressure, at 1800 atm; and.zitl 0. 000 atm shows a
decrease. in the endothermic peaks on the.thermograms and shifting of
Ahe initial inflecti
on point toward. higher temperatures, as the
pressures are increaseld.. -,These changes were attributed mainly to an;
increase in the specific)heat with increasing pressures, as well
as to a decrease in the@ disassociation reaction rate. Additional
experiments lead to the . conclusion; that'the'decrease in the disassoci-
ation reaction rate under.pressure occurs in the areas of grain con-
tact. Under a pressure.,bf 10, 000 atm, theAlsassociation reaction
does*Pot proceed to the end even.in-the presence of large overheating.
'At the same time, the pressure of P02 considerably in excess of
the load pressure. rnay occur . in. the pores adjacent, to the undecomposed.
grains. An approximate;thermodynitmice-valuation of the influence' of
.pressure on the heat effect was performed. It was determined that
-the maximum possible decrease of the thermal effect at 10, 000 at-M
;can reach 15116 (G. T. Ostapanko, VNIISIMS).
j..ACC
NRs AP70030161
'Usinga piston gage. The experiments. have shown that for cesium'
'AV - 0. - The. resitIts of e"xp'er'iments with cesium can be represented
by the folloiwing'6quation for the change in volume:
T
AV 0.0125-0.066 log (-!M!i- -------
'fo@,the melting c-@rV6,
V(K) 302.9,+ 193 x jr3 x P + 0.593 x. 10-6 X.p2.
Correspondingly, for. mercury,
3
AV (4:). - 0;0025@ 0.00205 x log ( T
9 .234.29
T 1-1,77
P 38.993
?(V. -S. Bogdanov-, VNIIFTRI)
The interrelationship be@xeen elastic and electrical properties
of rocks was investigated by conducting simultaneous measurement
of longitudinal waves and.'electrical resistivity in samples of moist
porous sedimentary rocks.under high hydrostatic pressures up to
'3000 kg/cm2. Carb .onaceous rocks and sandstones with porosities
between'6 and 2016 and rn@oisture content between 1.8 and L5% were
investigated. It,was'est.ablished t6t.the velocity of. elastic wavep
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A.CC NRt AP7003016
Rnd the electrical resistivity had their* smallest values in samples
"With the highest porosity. With'increasing pressures the velocity
in such samples increased considerably, while the electrical re -
sistivity increased only @slightly. The small increase in electrical
resistivity with pressure was attributed to the. high moisture content
of the highly porous rocki (Mi. P. Volarovich, Ye. I. Bayuk, K. P_
,Valeyev, IFZ).
Spectral investigations at high pressures were conducted in an
apparatus, which includes a 30-ton hydraulic press, a high-
.pressure chamber, an optical system with a mirror illuminator, a
mondchromator and phot0elettric device. The phase transformations
of the first and second kind were studied in benzene and ammonium
ichloride. Crystallization of certain fluids (CHCL3, C 6 H6 and
its derivatives) under compression and the effect of pressure on the
dynamics of the crystalline lattices Of C 6H6 and NH 4 CI were investi-
gated. and a relationship vas established between the changes in
frequencies of lattice vibrations of the optical branch and'the lattice
constants of the crystals, The effect of pressure on the frequencies
.'of intrinsic vibrations-of ihe NH + cationin NH.CI was investigatee
CPSB; '' v*- 2, no. jjj
SUB CCDE: 080 20 SUBM DATHI none
Cc-rd 14114-
KHITAffAN#.M.G*t uchitell
P876'Ological training of students for farm work, Blol.*
shko;O n0*6159.62 039, 1,
(MA 13:3)
BrednVaya shkola KO*78 g.govosibirska,
(Agriculture-4tudy and teaching)
KHTTEITKOV, Grigoriy Georgiyevich.
All-Union, Sci Res Tnst of Horse-Breeding. Acadenic degree of Doctor
of Agricultural Sciences, based on his defense, 24 December 1954, in
the Council of the Moscow Veterinary Academy, of his diesertation'enti-
tled: "Experiment in the Improvement of Saddle Horses in the USSR.".
Academic degree and/or titlet Doctor of Sciences
SO: Decisions of VAX, List no, 15, 25 June 55, Byulleten' MVO SSSR,,
No. 15, Aug 56, M0.800wt PP. 41-24, Uncl. JPPS/NY-537
USSR/Farm Animals - Horsed
Abs Jour : Ref Zhur Biol-, No 15, 1958, 69244
Author : Khitenkov, G.
Inst
Title : Achievements of Soviet Hippology Puring 40 Years.
Orig Pub : KoneVodstvo,'1957, No 11) 9-15
Abstract No abstract
Card 1/1
RWOZIN, G.K.; mpmoy, M.Yu., Icand. seI'sIwkhozyajyotyanrqkh nauk; 14WOTJL,
A.A.. kamd. eel IskokhmaystvanzWkh nauk; W9'j-WSVAp T.Te;
TOW.LYLTBOYs B.A..' kind. oel.IskokhozMotvennykh nauk; PWAVTSVI
.P.N., d9ktor eel tskok.hox*yst-Tenmykh nauk; LITOYOMMO, G*R*,, kod,
sellskokhmaystysuafth nauk-, KOLMOT, G,.H*; IOYR, K.Sh.; IffIVAWMO"----
--A4.#.ddktor eel 'gkokhoxy&ystvenr*i& nauk; DaMIYAN, G.G. doktor
sellskokhotMetvanulkh *uk,,, IVANOTA, A.A.; ROMT, A.P,; AMYSKIY,
I.P.1,SPIRIDONOve A.L., ksud. sslIskokhozM'stvennykh nauk: ZHMXOT
G
;'WNj1KOV, N.A.o red IVA@WTAq AOX red.-, ZUBRILINAO Z.P.,
.G.,
tekhn. red.
[Idonomics and orga#zation of stockbreeding on collective farim]
Nkonomika i organizateiia zhivotuo@odstva4v kolkhozakh. Moskva,
Goo. izd-vo sellkhos.' lit-ry, 1958. 550 p. (MIRA Ilt7)
(Stock and stockbreeding)
IVANOVA, Z.-J.. kandidatvetertuarafth nauk; XHITBNMA -L.P. uladshly
-nauchnyy notrudalk.
Anduo-atabrine treatment of mcnisilasis In sheep. Veterin&rll&
no.11:58 N 153. (MBA 6 11)
1. Gosud"stvsnW nauchno-kantrollay Institut veterinarafth
preparboy Winisterstva sellskogo khosyaystva I sagotovok MR.
K H i v - 1 1. P.
S/064/61/000/007/004/005
B124/B206
AUTHORSs Chekhov, 0. B., Anokhin, V. W., Shekun, B. N., Khiterer, R.Z.
TITLE1 Investigation of hydrodynamic processes in a pseudo-diluted
solid-partiole layer under high pressure
.BERIODICALs Xhimicheskaya promyshlennost', no. 7, 1961, 48 50
TEXTs The hydrodynamics of pseudd-diluted solid-particle layers-were
investigated at 1-300 kg/cm2 and 2'5-300C with a stoiohionetrio gas mixture
used.for the synthesis of ammonia* Coke particles of good electrical con-
ductivity and metallic needle--'b6_nd lazella -s-haped filinge were used as
solid phase. The critical rate velocity,of the gas.-mixtuxe and the height
of the pseudo-diluted solid-particle layer during the process were deter-
mined. The gas mixture was purified of steam, oil droplets.and other
impurities, and ducted into a vertical, cylindrical high-pressure column
with an inner diameter of 25 mm which contained the solid-partiole,layer.
The mixture was then throttled to atmospheric pressure and its consumption
was measured with a rheometer. The transition of the solid-particle layer
into the pseudo-diluted state, which corresponded to the critical gas
Card 1/9
Investigation of... V24/B206
velocity@ was brought about by.. closing the-..oircuit Abcve the solid-
n electric contact which touched the la er after
particle layer there was a
the beginning of the expansionana thuslolosed the circuit. The second
electric contact was connected to the housing of the:high-pressure columns
For the determination -of the keight. of the paeudo-d.i.l,-4ted.solid-pa-rtidie'*
..layers,-:th-e distanoe-of'the'upper surface of,the atetionitry layer from the
electric contact in the high-pressure column.was varied.; The determina-
tion results obtained during opening were practically equal to thosoob-
tained during 010'sing of the circuit. The experimental results obtained
for the critical gas velocities were treated according to the method pro-
posed in Ref. I (A, I. Rychkovt N. k. Shakhova, IFZh, No. 9t 92 (1959))
for determining the critical 'gas''velocities -at various temperatures and
atmospheric pres Is ure @Ref.'@?s 0. M. Todes, A. K. Bondareva, Khim. nauka i
prom., L,. No. 2 (1957 )- First, the critical gas velocity(a or (in m/sec)
at atmospheric pressure was'determined experimentally, this value being a,
function of the mean particle diameter d and the density of the
mean
particles, under absolutely equal conditions. Prom the known value ca
or)
the equivalent diameter d of the pores in the layer (in n) was calculated
e
Card 219
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Investigation.ofeet B124/B206
2 2
from the equation d 0 8c) g.l/4P-r.?g)_ de (73YO) ..lAp%g) .01.1
e or 0 ox 9
(1), where o is the gas velocity related to the total column diameter,
or
the density of the,gas, 1 the height-of the stationary solidI-particle
t
g
layerp AP the pressure,,differenee, e the porosity of the stationari solid-
0
particle layer, g the gravitational acceleration and V "The kinematic
viscosity of the gas. The critioal velocity. of.. the gas at any pressure
was det"orminedl rom the equivalent -diameter by the- f ollowing equations j
1) for laminar Ponditions ,at Re