SCIENTIFIC ABSTRACT KHMELNITSKIY, L. I. - KHMELNITSKIY, R. A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000722110017-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 17
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT


j
USSR/Chemistry Reduction
Card
Autbora luryev, Yu. X., and Mmelinitskiy, L. 1.
Title Catalytic reduction.of nitrobenzene under the effect of hydrocarbons and
alcohols
Periodical Zhur. 0b. Khim., 24, Ed. 6, 994 - 998, June 1954
Abstract The reaction of nitrobenzene with fi-butane and butene miytures at 450 -
11 - with ni-bu - __
550% as well"as utyl alcohol at 4501, in the presence of chro-
rd.un, oxide deposited on ablmlinwm oxide is described. The nitrobenaene
betcomes rartially reduced into aniline and partially reverts in unchanged
f ci= . The forzation of diphenyl, as result of ammonia cleavage f r)m,
arAline wider the effect of hydrogen in the presPnce of the oxidizLng
agent, is explained. Experiments showed that nitrobenzene prevent3 hydro-
gen attach-ment to the pbenir.1 radical and stabilization takes n1ace only in
diphenyl. Eighteen references: 1-USSR, 17-USA, Engl.ish and German, Tabie.
Institution The State University, Mosccrd
Submitted January 28, 1954

I - t ~... " '', ".. "r.,

A"TUORS: Novikov, S. S., Khmellnitakiy, L I SOV/79-28-8,.64/66-
Lebedev, 0. V.
TITLE; Decomposition Reactions of N 20 With Organic Compounds
(V,2&imodeyotviye N 04.: organiiheskimi soyedineniyami). 1.
Investigation of tKe nditions for the Reaction of N 21) 4
With Benzaldoxime; Combination of the Products and the
Reaction Equation (I.Izuehanive usloviy reaktsii'N 0
benzaltdoksimom, sootav produkto,v i uravneniye reaKii':'L)
PERIODICAL: Zhurnal obahchey khimii, MS. Vol.28, Nr 8,
pp. 2296 - 23o2 (USSR)
ABSTRACT: Investigated were.the influence of the molar ratio,
the concentration, the method of mixing the reagents, sind
the nature of the solvent upon the course of the reaction
between N2 0 and benzaldoxime under cooling with ice.
In considering all these factors the highest phenyldini.tro-
methane yield obtained was 43% of the theoretical yield..
All the combinations of the products of the reaction be,tween
N20 .and benzaldoxime which form under various conditic-is
Card 1/3 weri determined qualitatively and quantitatively. It was

Decomposition Reactions of N 0 With Organic Compounds. SOV/79-28-8-64/66
I. Invistigation of the Conditions for the Reaction of N 20 With Benzal-
doxime; Combination of the Products and the Reaction Equation
found that nitrogen is produced in this reaction. Equatioris
were proposed which indicate the formation of phenyldi-
nitromethane and benzaldehyde by the reaction of N 20
with the sodium salt of benzaldoxime. The experimenth
results are given in table 1, and the following conclusions
can be dr. awn from them: with about a 1:1 ratio of N 204
to benzaldehyde in the solvent only pheny1dinitromethane
and benzaldehyde are formed; with-a 0,5'1 ratio tf these
reagents in the solvent the main produoi is 3,4-diphenyl
furoxan (46%), while lesser amounts of phenyldinitromethazie
(4%) and benzaldehyde (9%) also form. By carrying out the
reaction without solvent the aldehyde is formed almost
quantitatively (93%). Figures 1 and 2 indicate the dependence
of the yield of phenyldinitro6ethane upon the factors indJ.cated
here. There are 3 figures* 2 tables, and 11 references, 3 of
which are Soviet.
Card 2/3

Debomposition Reaction: of N 0 With Organic Compounds. BOV/79-28-0-6:4/66
I; Investigation of th Conditions for the Reaotion of N 0 With Benzip, 1-
2
doxime; Combination of the Products and.the Reaction Equation
ASSOCIATION: Institut orgahicheskoy khimii Akademii nauk SSSR (Instit ute
of Organic.Chemistry ?AS USSR)
SUBMITTED December 31P 1957
Card 3/3

-4 ~ -1 - ~-_- I: - -- - -.-, - - ~ - ~~ ~ -1 -------- :~ - , . I
i~ R-11.,

A6THORS: jQ=e1initakiy, L. 1-3 Novikov, S. S., SOV/79-28-CI-65/60'
TITLE: The Decomposition Reactions of Nitrogen Dioxide With Organic
Compounds (Vzaimodeystviye N 204 a organicheskimi soye6ineniyami)
II. The Reaction of N 0 *With Aci-Phenylnitromethane emd Its
2 4
Salts (II. Reaktaiya N 204 a atai.-fenilnitrometanom i yego so-11yu)
PERIODICAL; Zhurnal obehohey khimii$ 1958s Vol- 28, Nr 8,
pp. 2303 - 2304 (USSR)
ABSTRACT: In the course of investigations on the decomposition vemotion
between nitrogen dioxide and benzaldoxime and its salts,
which leads to the formation of phenyldinitromethane, the
authors found it necessary to study more closely the reaction
between N 0 and aci-phenylnitromethane and its salts. In the
literaturi 4 the statement is made without further d&ta that
"the aci form of phenylnitromethane enters into reaction
especially easily with nitrogen dioxide" (Ref 1). The ex-
perimente of the authors showed that* analogous to other
Card 1/3 aliphatio-aromatic compounds (Ref 1), th .e.reaction of V 204

The Decomposition Reactions of Nitrogen Dioxide With SOV/79-28-8..65/66.
,Organic Compounds. II. The Reaction of N With Aci-Phenylnitromethitne
and Its Salts 204
with aci-phenylnitromethane and its salt.-produces the expected
phenyldinitromethane;
N 2 04-, N 204
CH H CH - NOONa - C H CH (NO C a CH - MOH
6 5 6 5 2)2 6 5
The maximum yield of phenyldinilromethane van 44,5% baced
on the aci-phenylnitromethELne, and 28% based on the salt.
The reaction went in solution, and although it resembled,
externally the reaction between nitrogen dioxide and benzal-
doxime and its salts, it required much less heating than
this reaction. The results and the conditions of the ex-
periment with aci-phenylnitromethane are indicated in table 1,
while those for the sodium'sal". of pheny1nitromethane are
given in table 2. There are 2 tables and 2 references,
which are Soviet.
ASSOCIATION: Institut organicheskoy khimii Akademi.i nauk SSSR (Institute
Card 2/3 of Organic ChemistryAS USSR)

- ----- ----
The Decomposition Reactions Of Kitrogen.Dioxide With sov/79-24'1-8-65/66
Organic Compounds! II. The Reaction of N 0 With Aci-Phenylnitromothane
and Its Salts 2 4
SUBMITTED: December 319 1957
Card 3/3

AUTHORS: Novikov, S. S.9 Lebedev, 0, V*, SOV/19-28..8-66/66
Khmellnitakiyp L. L, Yegorov, Yu. P.
TITLE: Decomposition Reactions of Nitrogen Dioxide and Organic
Compounds (Vzaimodoystviya N 20 4a organicheskimi soyodineniyami)
III. Decomposition Reaction of N 20 Wtth Salts of the
Aliphatic Nitro Compounds (III. Yzaimodi stviye H20 4 a
solyami alifaticheskikh nitrosoyedineniy~
PERIODICAL: Zhurnal obehahey khimii, 1958, Vol. 28, Nr 8,
PP- 9305 - 2307 (USSR)
ABSTRACT: In contrast to the reactions of the aromatic oximes and
the ary1nitromethane salts with N 0 producing dinitro
compounds, the reaction of the alipgatic oximes with.nitrogen
dioxide produces nitrosonitro compounds. Thus, for example
acetoxin and N20 4 react to form propylpseudonitrole (Ref 3~
(CH 3),C(;O)(N0,)- Analogous to the course of the rev~tion
between the oximes and the nitro compounds of the aromatic
series, it is to be expected that the aliphatic series would
react in the same way, i.e. that the salte of the aliphatic
Card 1/3 nitro compounds must react with N 204 to give nitrosonitro

Decomposition Reactions of Nitrogen Dioxide and Organic SOY/79-28!.s-66/66
Compounds. III. Decomposition Reaction of N2 0 4t. th Salto of the A:Liphatio
Nitro Compounds
compounds. In the work re~ported in this paper this h;~potheBia
was tested using the alkali salts of the following OiDMpounds:
2-nitropropane; ethylnitroacetatel and 1,1-dinitroethane.
Thus.propylpseudonitrile was obtained by the reaction between
the sodium salt of 2-nitropropane and N 0 (reaction diagram-4)-
In'the reaction of the sodium salt of nithacetate with
N'O the ethyl eater-of nitrooximeaoetic acid was farmed
(KAgram 2). In the reaction betWeen the potassium salt of
1,1-dinitroethane and N 04 ethylnitrolic acid was prDdUCed;
in this reaction a labife intermediate producto' a ni-troso
compound, formed (Diagram 3). Contrary to expectation, only
the nitromalonic acid ester separated out quantitatively
in the reaction between N 0 and the potassium salt of
nitromalonic acid ester.',gpictral analysis showed that this
anomaly resulted from the fact that the potassium formed the
salt not at the nitro group, but at the carbonyl group. There
Card 2/3 are 4 references, 1 of which is Soviet.

Decomposition Reactions of Nitrogen Dioxide and Organic 80V/79-28~-8-66/66
Compounds. III. Decomppsition ReVtion of N 0 With Salts of thc Aliphatic
Nitro Compounds .2 4
ASSOCIATION: Inatitut arganicheakoy khimii Akademii nauk SSSR (Institute
of Organic Chemistry,AS USSR)
SUBMITTED: December 310 1957
Card 3/3

84653
S/062/60/000/010/lDO6/018
B015/B064
A3 6 (9
AUTHORS; Nqvikov, Q. $.I 101mellnitskiXp L. I,,,, and Lebedev~ 0. V..
TITLE: Reaction of N20A With Organic Compounds. Information 4.
Conversion of tn Nitromethyl Group Into the Trinitromethyl
Group
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheski kh nauk,
1960, No. 10, PP. 1783-1786
TEXT: The authors showed by experiments that a reaction of m-nitro-
benzonitrolic acidlwith an N204 excess (in dichloro ethane at 5-0---600C)
yields M-nitrophenyl trinitromethane.%86% yield). Herefrom it is
concluded that aryl nitrolio aoids are formed as intermediate products
in the formation of aryl trinitromethanes from salts of aryl nitro-
.methanes under the action Of N204- On this basis it was possible to
establish reaction conditions that permit an essential increase in the
yield of aryl trinitromethanee obtained from aryl nitromethane salts. The
method -19 based on the addition Of N204 in two portions: Tho firat portion
Card 1/3

84853
Reaction Of N204 With Organic Compounds. S/062/60/000/010/()06/018
Information 4. Conversion of.the B015/BO64
Nitromethyl Group Into the Trinitromethyl
Group
is added under conditions warranting a maximum yield of nitrolic aoid,
and the second portion is added under the optimum conditions for the
conversion of nitrolic acid to.aryl trinitromethane. Thus, a 58-6011
yield of m-nitrophenyl trinitromethane could be attained, and the
p-nitro;henyl trinitromethane hitherto not described could be obtained.
-Thd--l-att-er-eiih---b-e-d-oft-Ve-fte(I under-tKe- "OiVnof
solution, into p-nitrophonyl dinitromethane which has hitherto been
unknown. The conversion of the nitromethyl group into the trinitrogiethyl
group can-also be assumed to take place under the formation of the
dinitromethyl group (intermediate stage). In the present investigation,
also the salt of m-nitrophenyl dinitromethane was found to give
derivatives of trinitromethyl. A formation of the aci-form of aryls
dinitromethane as an intermediate stage in the formation reaction of the
trinitromethyl derivative from the nitromethyl derivativo could nott be
establishedp while in the normal form the aryl dinitromethanes do rj~ot
react with N204. The individual methods of synthesis are described.'
Card 2/3

5/062/60/000/oll/Dog/016
B013/B078
AUTHORS: Jhmeltnitskiy, L. I., Novikov, S. 3.9 Lebedev, 0. V.
TITLE: Reaction of N 204 With Organic Compounds- 5. Aryl Nitrolic~
Acids, Preparation of Aryl Nitro Methanes From Themt
Single-stage Synthesis of Aryl Nitro Methanes From Aryl
Aldoximea
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheakl'kh
nauk, 19601 No. 11p pp. 2019 - 2025
TEXT: The investigation of aryl nitrolic acids as well as of the methods
of preparation of aryl nitro methanes is continued in this paper. A new-
method of preparation of aryl nitrolic acid a through the action of' N204
on aryl nitro methane salts has been found. It was shown that aryl nitro-
lie acids may exist in two types which differ according to their ;hysical
and some chemical properties. The formation of one or the other type as
well as both types simultaneously depends on the method of preparation.
These phenomena were thoroughly investigated in the case of p-nitro
Card 1A

Reaction of X204 With Organic Compounds. S/062/6O/OOO/O11/ooq,/o16
5. Aryl Nitrolic Acids, Preparation of Azy2 B013/BO78.
Nitro Methanes From Them, Single-stage Synthesis of Aryl Nitro
Methanen From Aryl Aldoximes
benznitrolic acid. Type (1) is a pale-yellow substance with a melting
point at 600-610C (under decomposition). It is easily soluble in
alkalis and alkali carbonate solutions. (I) forma, when acidifying a so-
lution of p-nitrophen I nitro methane potassium salt and -nitrate'vith
oxalic acid. Type (II~ is an almost colorless crystalline substance with
a melting point at 520-530C- In alkalis or alkali carbonate solutions it
is immediately converted into a high meltable produot without passing
into solution. It forms under the action of N 0 upon a suspension of
2 4
p-nitrophenyl nitro methane potassium salt in ether. By the action of
0-5 M N204 upon the ether solution of p-nitro benzaldoxime t here forms
an almost inseparable mixture from both forms. When applying the f:Lrst
mentioned two methods, m-nitro.benznitrolic acid will.only be obtained
in type (I). From the oxime it will be separated like p-chloro benir.-
nitrolic acid as a mixture of both forms. With a repeated recrysta:Lliza-
tion of the mixture of (I) and (II) of p-chloro benznitrolic acid one
Card 2/4

Reaction of N 0 With Organic Compounds. S/062/60/000/011/009/016
2 4 B013/BO?8
5. Aryl Nitrolic Acids, Preparation of Aryl
Nitro Methanes From Them,.Single-Btage Synthesis of Aryl
Nitro Nothanes From Aryl Aldoximes
obtains type (11) with a melting point at 78 0- 79 00. Type (1) was,obtained
by acidification of the alkaline mixture solution after,this had,been
filtered off from the decomposition products of (ji). o-nitro ber,zal-
doxime with N 204 gives rise to type (I) only. The existence of two types
of aryl nitrolic acids can be explained by syn-anti-isomerism. Melting '
points of the obtains& aryl nitrolic acids and thei-r benzoyl derivatives
are mentioned in the*table. The conversion of nitrolic acid into aryl
nitro methane in the presence of N 204 was investiga ted with:p-chloro-,
o-nitro-., and.p-nitro benznitrolic.acids. p-ohloro--and p-nitro benz
nitrolic acids (I and II) with N 0 give rise-to respective aryl nit;o
2 4
methanes in good yields. o-nitrophenyl trinitro methane could not be ob-
tained by the action of $204 upon o-nitro benznitrolic acid..Basod on
findings, the method of a single-stage synthesis of aryl nitro m6thanes
from aryl aldoximes was developed. It consists in adding N20 4 tv"Lee.
Card ~/4

Reaction of N 204With Organic Compounds. s/o62/6d/ooo/oii/oo9/Oi,6
5. Aryl Nitrolic Acids, Preparation of Aryl B013/BO76
Nitro Methanes Fxom Themy single-stage Synthesis of Aryl
Nitro Methanes From Aryl Aldoximes
The first portilon is added under the condition that it guarantees'!the
maximum yield of nitrolio acid. The addition of the second portion' takes
place under the optimum conditions for the,oonversion of nittolio.aoid
into aryl nitto methane. There are I table and 6 references: 3 Soviet
ASSOCIATIM Inetitut organioheekoy khimii im. N.,D. Zelinakogo
Akademii nauk SSBR (Institute of Organic Chemistry iinenil
N. D. Zelinskiy of the Academy of Sciences USSR)
SUBMITTED: May 27, 1959
Card 4/4

MMLIN:ETSW
S.S.; LEBEDEV, OV.
Interaction betweem-1201, and. arganic-compour,.da. Report lo.6.-
AryInitronitrosoisethaneiA and meehaniam o-f the reaction between
N204 and aromatic compounds containing an acinitro or isonitroslii
group in the Bide chain. Izv." SUR Otdkhiin.nauk no.3:477-402
mr 61, (KM 144)
1* Institut organicheakoy khinii imeni N.D.Zelinakogo AN SSSR.
(YAthen (Nitrogen oxide)

KHMEWNITSKIY, LOI.- ISMEV,-OV.,- SLOVhISKIY,,-VOlvj MVIKOV, Soso
Reactions of N 0 with organic compounds. Repdrt Not 7: Syn,-antt
isomerism of Xf nitrolio acido,, Izv,AN SSSR Otd.khim.nauk no&4:
678-683 AP 161. (HPA 3.4 14)
1, Institut orga-aicheokoy kbi-li im, N.D.Zelinskogo.AN.BSSR,
(Nitrogen oxide) (Nitrolic acid)

KHML.INITSKIY, L.I.; NOVIKOVA, T.S.; NOVIKOVI S.S.
Oxidation of aromatic amines by trMuoroperacatic acid.
lzv.AN WSR.M.Mim.nauk no.3016-517 Mr 162. (KIRA 1513)
1. Institut organichesko kbixii im N.D.Zelinskogo AN SSSR.
(Amineof (Paroxya;etic acid)

NOVIKOV ;Jil-.FLlNlVSi(llY NOVIKOVA F.S.
w rriethods of nitratjor, by a mixture of nltr~c acid and acetic
it A ~
S
awhydride, Izv..All 33SR Ser. khi-m. no.l.:103-11.0 165.
(1-11IRA 18:2)
1. Institut orgunicleskoy lchlmli 1m. N.r,;$ Zelinskogo AN SSSR.

SOLOVIDW, V.P.; KONYArEV, G.A.; ROVIKOV, KIDIFLINITSKI7, L.I.;
NOVIKOVAy T.S.
Antimicrobial activity of nitrofurans with oimple subrtitutes..
Farm. i toks. 29 no.3.316-120 My-je 165. (MIRA 18: C)
1. Otdel kbimioterapil (Zav. - prof. A.M. Chernykh) i otdel po
vyyavleni5,u fiziologicheskikli aktivnykh veshchestv (zav. - kn-nd.
med. nauk Yu.I..Vikhlyayev) Instituta fannakologii i Ithimio-
terapli A1,21 SSSR i otdel orfanicheskogo sinteva (zav. - prof.
S.S. Novikov) Instituta organiche!3koy klilmll imoid N.D. Zelinskogo
AN SSSR, Moskva..

SOURCE-CODE: UR:/0413/661000/016100
0569 35/0036
INVENTOR: Lebedev, 0. V.; Yepishina, L. V.; Sevostlyanova, V. V.,' Novikova, Ta S.;
Khmel'nit*A;~iyl . S.
Novikov, S
ORG: none
'TtTLE: Preparation of 2-nitro derivatives of imidazole. Class-120 No. 184858
.[announced by Institute of Organic Chemistry im. N. D. Zeliniskiy (Institut organir
cheskoy khimii))
SOURCE:* Izobreteniya, promyshlennyye obraztsy', tovarnyye znaki, no..16, 196,59 35-36
TOPIC TAGS: imidazole nitro derivative, methylfomylimidazole oxime, nitrogen
.tetroxide
j, imidep org~Lnic n1tro, compound, organic oxime
.ABSTRACT; -In the proposed method, 2-nitro derivatives of imidazole are prepaired
by treatment of 4-methyl-5-formylimidazole oxime with nitrogen
tetroxide at 2-30C in absolute acetonitrile with further heating
at 1470% and'isolation of the product by known methods.
[VA-50; CBE No. 111
SUB CODE: 07/ SUBM DATE: 24Mar65/
I Card 1/1 UnCs 547,781.5.07

Translation from: Referativnyy zhurnal, Geologiya, 1957, Nr 10,1
p 256 (USSR)
AUTHORS: Samoylovskly, M. Bog Ivanov, P. S.,_Khmellnit~~'
L. Ya.
TITLE: Composite Mine Supports From Centrifugally-Cast
Elements (Sbornaya krepl iz tsentrifugirovannykh
elemen tov)
PERIODICAL: Shakhtnoye str-vo, 1957, Nr 1, pp 24-26
ABSTRACT: For reinforcing the principal mine workings (horizontal
and inclined), supports of reinforced concrete are used.0,
made of general-purpose fluted slabs by the VNIIOMS
(?).. Such supports, having industrialized the
reinforcing process, have shortened the working time
and dispersal time of materials and have Increased the
productive labor of gallery and stope operations. The
use of the centrifuge in producing support plates
Card 1/2 called for a change in the construction of supports

Composite Aline Supports From Centrifug4lly-Cast (Cont.)
from the general-purpose fluted slabs to shells, The castlng-iNrms
of the shells are made from general-purpose elements of the shell
supports, being part of a thin..cylinder with walls 40 mm thick having
a round attached insert and a basal bearing plate (shoe), The
attached insert of the elements of the support secures favorable
conditions for working, The technology of manufacturing the thin-
shell supports is described briefly. For the manufacture of these
supports and the attached Insert.s, brand 400 concrete lis used;
brand 200 is used for the basal plate, Typical sections for the
reinforced concrete supports made of tt)a jelements of the thin-shell
members were designed by the VNIIMShS '; I., in cooperation with, the
Yuzhgiproshakht (The Southern Stati Institute for the Design and
Planning of.Mine Construction in the Coal Industry).
Card 2/2 V, V. 2,hukov

KHMILINITSKIY, L.A., inzh.; rVANOV, P.S.,inzh.
Some problems of designing an4 using sectional rainforcel-conar"to
elements of mine supporte Kroplo goro vyr. ugoll . shakht no* 1:75-
89 157. (MIRA 11:7)
1. VaesoyusW imiuchno-Isaledovatel'skly institut organivetaii I
makhaaftateii shakhtnoge stroitallitva..
(Mine timbering)
(Reinforced concrete construction)

KEKSLI f;.,lush.; IVANOT. P.S., insh.; KONMVA. V.F.. insh.;
!7inx h.
]Prestressed-reinforced UPIP slab supports made by concreting
mmohinerye Xrople gore vyro ugoll shakht no* 1:163-167 157,
(KIRA 11:71)
1. Voesovuznyy nauchno-issladovatel'skiy Institut orgenizateii 1.
makhantratsii sbakbtnogo stroitalletva.
(Mine timbering)
(Reinforced concrete construction)

ZHUROV, E.M., insh.; KMMINITSKIT, L.Ta., inzh.
Sectional reinforced concrete linings for inclined abafte. Kreple
gor, vyr. ugoll. efiekht no. 1:188-202 157, (HIRA 11:7)
1. Vaeaoyuznyy nauchno-iseledovateVsKy inatitut organizateii i
mekhanizateit shakhtnogo stroltalletva.
(Shaft sinki
(Mine timberM
(Reinforced concrete constructions)

IMLINITSKIT, L,Ya.; BONDAMM, v.l4.: IvAiny, p.S.; DUDED9 V.P.
Utiversal reinforced concrete element. Gor. shur. no.lot3l
0 1-58. (MIRL IWO
(Reinforced concrete oonstruction-Patents)

AICLIZIEN, L.Ye.; BWOZDOV. I.A.; MILO. V.Ye.; TERESHKIN, F.R. Prinimili
uchastiye: MWAUT, F.R.; BHRRMWOT, N.V.; Bpn" V.A.; VWUMVSKIX,
'E.N.; DUDKO, V.P.; IMMOV, V.S.; PUGIN, Ye.V.; DUKALOT. H.F.:
IVANOV, P.S.; XONAIMA. V.7.; HORIN, H.L: HOGILKO, A.P.; PANCMMO.
A.I.; PCKALYMOV. S.N.; PRIKHODIKO, N.D.; RUBIN, I.A.; SIDOWED,
P.A.- TYUTYUNIX, Ya.l.; IUMINITSKIT, Lja.; BOHM, V.I.; MLVTSOV,
A.T.: LOMIN, V.D.; red.izd-li-a;
B=ililA, Z.A., takhn.red.
(Types of mine cross motion] Tipovys pachanUrer Vornykh vyrabotok.
Hoskva Gos.nauchno-tekhnAzd-vo lit-ry po gornomu delu. VolA; -
(Cross section of mines supported by a sectional reinforced-cont~rate
lining of UBP-11 panels for 1-, 2- and )-ton railroad care] Sechanlia
vyrabotok. zakraplannykh abornoi zhelazobatonnoi krepliu iz plill
URP-II, dlis l-, 2- 1 3-totnykh vagonstok. 1960. 278 P.
(HIM 13:12)
1. Khar1kov. Gosudarstvannyy proyaktnyv institut Yuzhgiproshakhit.
(Mina timbaring)

KHMELIKMKIY., L.Ye.j STETSYUKv V.Aop insh.
Use *f hoUov blocks in deep-#*& amring installation. Transp.,
atroi. 15 w.9:20-22 0 1659 (MMA 18111)
1-0 Chommorniiproyekt (for Statsyuk)o

S/094/61/000/001/006/007
E073/E335
AUTHOR: Khm-Q2!m1t&kiY-,k--Le Ze
TITLEt Problems of Economics of Electrical Energy in
Electric Steel Smelting
PERIODICAL: Promyshlennaya energetika, 19�11, No. 1,
Pp. 55 - 57
TEXT% The Energosbyt of Sverdlovenergo, jointly with
the Urallskiy Dom tekhitiki (Ural House of Engineering), held
a course on rational utilisation of electricity in electric
steel smelting in 'February,1960. Personnel of the Sverdlov,
Chelyabinsk and Permak sovnarkhoz participated in these
courses,
Candidate of Technical Sciences Docent A.I. Kholodov of the
Urallakiy politekhnicheakiy institut (Ural Polytechnical
Institute) imeni. S.M. Kirova dealt in detail with the slag
formation in acidic electric furnaces in his paper on
"Physical and Chemical Bases of the Acidic Process of
Electri Smelting of Steel".
Card 05

S/o94/61/ooo/oOl/006/007
E073/E335
Problems of Economics of Electrical Energy in Electric
Steel Smelting
The Steel Metallurgy Department of UPI commenced thestudy
of the physical and chemical properties of acidic slag,
paying particular attention to the solubility of Si02 in
steel-smelting slag, the fusion temperature, viscosity and
activity of oxides in it.
A.1. Kholodov pointed outtm great economy of smelting in
siectr*c furnaces with acidic lining and the necessity for a
changeover for a large number of.steels from basic furnaces
to acidic ones.
L.A. Volkova, Senior Engineer of the steel laboratory of
Uralmashzavod, lectured on using oxygen blast in electric
steel smelting.
The electrometallurgists, V.K. Balbyshev, Ya.M. Dolginov
and N.T. Khochunskiy, lectured on experience gained with
accelerated smelting in acidic and basic electric furnaces.
Card 2/5

s/oq4/6i/poo/ooi/oo6/oO7
E073/E335
Problems of Economics of Electrical Energy in Electric
Steel'Smelting
The Sverdlov Works (Chief Foreman N.T. Khochunakiy)
carried out a great deal of work on modernisation of a
5-ton furnace, as a result of which its capacity increased
to 7-to 7.5 tons.
On the initiative of S.Ya. Barin a new method of lining
wall& of electric smelting furnaces with a plastic mass
was developed. As a result of using it, the 3active volumol
of a 6-3-ton furnace increased by 2 to 2.5 m so that the
average weight of the heat could be increased to 7.3 tons.
Details of applying this lining are given. Great economies
were achieved by using this lining.
Candidate of Technical Sciences M.V. Belyayev gave a
review of existing types of automatic control of arc steel
smelting furnaces.
Candidates of Technical Sciences Docent M.G. Rezin and
Engineer Ya,L Drobinin presented an interesting lecture
Card 3/5

S/094/61/000/001/oo6/007
E073/E335
Problems of Economics of Electrical Energy in Electric
Steel Smelting
on the electromagnetic mixer to be installed in the electric
furnaces of the Verkh-Isetsk Work.s...This electromagnetic
mixer is based on the same principle an the operation of an
asyncbronous motor. However, the jacket under the bottom of
the furnace must be made of nonmagnetic steel. As a result
of using such a method of mixing, the duration of the smelting
can be reduced to 10-15 min and an electricity saving of
one million kWh can be achieved.
Various methods of standardising the specific consumptionof
electricity were discussed.
Candidate of Technical Scidhces A.I. Kholodov, in his papeir
on rational operation of electric are furnaces, drew attention
to the importance of correct choice of the transformer rat.ing.
Replacement of a 2500 kVA transformer of an 8-ton furnace by
a 3500 kVA transformer enabled increasing the average load!Lng
of the furnace by 12 tons and reducing the power consumption
Card 4/5

Conforenro on ap..,!
of
pa-ior distribution in Svardlov~ql~ j"'c-l-,onarg, 16 41
16,1. .4 (,malu~
(;Ivei-dlovek.Provlnca--4Cleotric poinix. distribution)

KHMELINITSKIY, L.Z.
Seminar on the efficient use of electric power in metal rolling. Pr om.
energ. 18 no,9r46-47 S 163. (KIRA. 16#10)

- -
~ I
"Questions without Answer"
F Uncl
bditairmUs Rabotniki 86-1414, 21 Oct 1955, Pl

in TsIly
Now process for cracking beavy petroleum residues (from
'"Petroleum Ingineeri" July, Aserb.neft,khos. 35
no.4:28 Ap 156. (Wak 9: Ito)
(Cracking process)

WHWLINITSKIY, M.D. [Khmoltnytolkyi, H.O.1; SHEVCHENKO, V.N.
Milking parlor in a summer camp. Makh. sill. hoop. 14 no.7t22 J1
163. (MIRA 17!12)
:1 Glavnyy Inzh. Donetskogo trasta molwhnykh sovkhozov (for Mid-
nitakiy). 2. Glavnyy in7h. zovkhoza "Kermonchik" (for Shevehanko).

KHMINITSKIL-FIN,
25970 111"1 1 hl 0 15tiin6n6nii Stand~rtnykch Stallnykh Zubov Fri
~sostovidnom-Prot6zirovanii.' Sbornik Nauch. Rabot Leclieb. Uchrezhdeniy
Mosk. Voiren.'Okro Gor'Kiyj 1948, S. 357.
Sm Takzho No. 25996
SO: Letorial Zhurnal Statey, No. 30, Moscow, 1948

A.; Klp(~LMITSKIY, M-Z-
SOLOVKOV, A.K*; BEZRYADNOVP -40 -.. . - I
Du.rabilitl of the crown after 944 ..m1tinge. Motallurg lo no.3,1):20-21
0 165, (14TRk, IWO
1. Ashinskiy mtallurgichaskiy,zavodo

MMINITSKIYv N,L.
Attachment for machining ba-n tracks of tuPing gear rings.
Stan, i instr, 32 no-4:39-40 AP 161. (MIRK 14:3)
(Lathes-Attachments)

EVELI sLUIALL,-, - I
ostr,oitell nosI2.22:
Attacbment for machiming ball tracks- Maoh'n (14IRA 14:32)
D 161.
(Lethes-4ttachmOnts)

PILIMMHTEIN, I.D.; MM'NnSKAUm N.Ye..
SANDOMMKIYt D.M.;
memo of finely dispOrood susPensiono. jKauch.
Gelation Of latex by (minL, 14:6)
i rez. 20 no.7-.5-8 ji 161.
1. Mookovskiy institut tonkoy khimicheakoy tekbnologii imeni,
KS.Lomonosovat (Latex) (Suspennions.(ChemistrY)']

XMLIATSKIT. 0.1.-, 111,11IN, X.A.
Tamors of arterio-yonone.anastomoses, Vest,van.i ders'. no.2:5&-57
Xr-Ap 1549 (MLRA 7:4)
1. Is kafedry patologichaskoy anatoxil Zaningradekogo gosudatatirannogo
institute dlya usovershenstvoraniya vrachey.
.(Arteries--Tumors) (Vains-Taxors)

KHMILINITSKIT, O.K. (Loulagrad)
Solitary neurinomp in tba abdominal cavity. Arkh.pat, 16 noas,44-71
Ja-Mr 154.
I.-It kafedry patologichookoy aAatoult (savadVashchly - profesilor
F.T.Sipovskiy) Laningradekogo institute, usoversbanstyowmiya vrOichey
Im, Wove. (direktor - professor N.N.Mlshtfic). (Abdomsu-Tumol,~s)

EMLINITSKIYI O.x,
Theories of the causes of death in Cases of extensive thermal burns.
Dokl.AN Tadsh..SSR no-14:11-57 155.. (MM, 96-9)
I.Kafedra pataloglebaskay anstomij-Loningradsksgo instituts. usever-
6honstyevanlya vrachey iment B.H.Ureva. Prodstarlono Inatitiltom
soilegii i parailtologlilmoni skadmaika, Pavloyokogs AN Tadshikskey
SSR. (MM AND $CALM)

fy) to T-S V I
GIMUY, 8.8*, professor; BLIVOY, N.I., prefessorl BAUNINA, V.S.,
handidat maditsinakikh asukl
professorl XSMJ~,M# if
BRIGINNIll of Odi seditainskikh naukg BOTIO, kandidat
mditsinskikh nauk; DYSTROYA. T.Y., Imadidat neditalbakikh natikI
TIASOVA, Z.A., Undidat seditainskikh unk-. ANTIPISA, A.N.0 naachM7
sotradvik
Petr Vasillevich 31ponkil. #rkhtpoto 18 no.8:131-132 056. (MIRA 10:2)
I., Deystyltelinyy chalu ANN SSU (for Girgolov)o 2. Direktor
Institute usavershenstvayantys, vrachey Iment B.K.Xirova (for MlinoT).
3o Direktor Imuchno-issledovatellskago institute trarmatologil. t
ortopedil (for Belakina)
tOUlOnIll, IPSTS VASILISVICBk

X9ML'jjZM.1Tm O.K., dotsent
Gastric fistula In a patient with tuberculous spondy.itio. Probl.
tube 34 no*6 supplonent%42 N-D 656. (MLPA 10:2)
1, Is Imfedry patologichaskoy anstomli (says prof, PJ981povekly)
laningradekogo gosudaretyancogo instituta usovershenstyovaniya
vrachey imani Kirov&.
(Unnux-TUMCULOSIS) (PISTUIA)

XHKRLI NITSKIY 0 x doteent (leningred, Muchnoy per., d.1. kv.57);
9MM-1 kand.medonauk
Glomus tumors CwIth summar7 in Ingli0h]. Vest.khir. 79 no,B,.B:L-86
Ag '57. (ML lotio)
1. Iz kafedry patologichaskoy anatomii (zav. - prof. P.V.Sipovskiy)
baningradekogo gosudarstvannogo ordena lanina institute usovershen-
stvovantya vrachey im. B.M.Kirova i bollnitay laningradakogo savocla
OBollshavik* (nacho maditsinsko-sanitarney chasti - V.A.Tvaredze)
(GLOMANGIOU
clin* aspects, pathol. & management)

CHISTOVICH, A.11. prof.; KHMINITSKIY. O.K., dotsent
Work of :he Leningrad Pathoanatomical Society in 2956. Arkh.
Pat. 20 no.11:90-93 158. (RIBA 12:8)
1e Prodeedatel' Laningradekogo obahchestva patologonnatomov
(for Chiatovich). 2. Sekretar' Leningradekogo obahchestva
iNLtoloanstomov, (for Mmllnitskiy).
(PATHOAMTOHICAL SOCIETIES)

CE[IST"Im, A.N., prvf,~; XKMELINITSKIT, 0.1o, dotes
Work of the LeniWad SocietY Of PathOauatOmists in 1957. Ar.kh.
(MIRA
pat. 21 no 1:78-83 1506 12:1)
I., predso"tell Leubgradskogo obghchegtva patologoauatomov (for
Chistovich)s 2e Sekretarl LeningradskDgo obshchestva patologoana--
tomov (for Umallnitskly).
(IMMINGRAD-PATEIOANATOMICAL SOCIETIES)

KMMINITSnT, O.K. (LeWmgrad)
Pathological anatomical changea in vesceral candidiesis. Arkbi,
pat* no*3:20-27 162e (MIRA 15;3)
1, Iz kafedry pa tologicheskoy anatomii (zav. - prof. P.V. Siptyv-
skiy) i kafecIry mikrobiologii (2av. - zaslushennyy deyatell
nauki prof. P,Nm, Kashkin) laningradekogo ordena lenina lwtitiata
usoversbenstvovaniya vrachey imeni S.M. Kirova.
(MMMIASIS)

KHMELINITSKIT, Oleg Konstantinovicb; KOKUSHINA, T.Y.,,red.;
MA67A, T.I., tekhn. red.
[Pathomorphogenesis of visceral.candidiasis] Patomorfoge- I.
nez vistserallnogo hendidoza. +,eningrad, Medgiz, 1963. 100 1).
(MI RA 16: 11)
(MDNILIASIS) -

KHMELIKITSKIYj O.K., dotsent (Leningrad)
Visceral mycosee in man. Arkh. pat. 24 no.9%3-12 162.
(MRA 17; 4)
1. Iz kafedry patologichoskoy anatomii (zav. - prof. P.Ve It
Sipovskiy) i kafedry mikrobiologii (zav. - zasluzhenny-.-
deyatell nauki prof, P.N. Kashkin)'Len'ingradskogo ordena
Lenina instituta usovershenstvovaniya vrachey imeni S.M.
Kirova (dir. dotsent S.N. Polikarpov).

MIMINITSKIY Pe ordinator
.*Now-
Result of treatment of soleroderta, with lidase; Veetodem,', i
van. 32 no.W66-68 jiAg 158 (MMA 11:10)
(SCIMROIMRMA. ther.
hyaInronidase prep; (Run))
(Hy=MONIDASR, ther.
solerodema (Rus))

TM F-M)OPT rw Omni ftj I" Chokig%7
S""M st Cb-%I-UY WA Cb,.d~l or pbo",
p6l. by AGO. W. ~, WAMBOW
be 14 obvm am"O.4 swoon.
R-0 LXOWW~w

5W SO/20-127-2-42/70
AUTHORS: Polyakoval A. A., Ziminaj K. I., Petrovp AoA*f
Khmelinits Ak6,
TITLEt Mass Spectra and Structure of Vinyl Acetylene Hydrocarbone
PERIODICAL: Doklady Akademii nauk SSSR, 19599 Vol 127, Nr 2, pp 306-388
(USSR)
ABSTRACT: Investigations Of relations existing between physical-
properties influencing structure and reactivity supply data
for infrared spectra (Ref 2), Haman spectra (Ref 3)p'and dipole
moments (Ref 4). Results obtained from investigatione with the
US-1 mass spectrograph are reported here. The mass slectra of
vinyl aoetyl and of its three monomethyl derivatives were taken.
Results are specified in table 1. Maximum intensity 4i L 13
exhibited by the molecular ion. The most.intense spltt ions are
produced by the rupture of the C-H bond* Split ions produced by
compg-unds.
the rupture of the C-C bond are not typical of these,
,
Unlike piperylene and isoprene$ the introduction of it methyl
radical decreases but little the stability of the molecular ion,
The normal chain isomers differ from isopropyl acetylene by a

2
d 1 Ion)
greater intensity of the peak 63 (05H+3-
Car
/

Mass Spectra and Structure of Vinyl Acetylene Hydrocarbons SOV/20-127-2-42/70
A striking fact is that the greatest stability is exhibited
by those split ions which have conjugate bonds. It would be
interesting to compare these properties with data concerning
the kinetics of the ion reactions of vinyl acetylenes.:
Unfortunatelyl there are no such data available in publications.
There are i table and 6 references, 5 of which are Soviet.
ASSOCIATIONs Vsesovuznyy nauchno-isoledovatellskiy inatitut po pererabot-ke
nefti I gaza i polucheniyu iskusstvennogo zhidkogo topliva
(All-Union Soientific Research Institute for Petroleum an& Gas
Refining and Production of Synthetic Liquid Fuels)
PRESENTED: March 26# 19599 by B. A* Arbuzov, Academician
SUBMITTED: March 21, 1959
Card 2/2

3, 35 e'(-, 9
AUTIIOA',!S:. PolyInkova, A. A., Ziminn, K, A., ret,~oj-. A.. A.
Khmel. rlitslriy R. A.
TI"I'LE: maos Spectra of
PERIODICAL:
ABST13ACT:
Card 1/1~
ZY11A.11"11 ob,;hchoy 10-11mil, Vol 30, Nr 3,
PP 91.L~-918 (USSR)
The ,uass 3pectra the following
stludiL~d. andd
The resul,ts of this work are given in Table A. rho stnbllit~
of the ion molecule dccreaoes and that ot' ion
increwoes with the increaso of alkyl radical, Among ion
I'm L-,jji (! i i t aformed with the rupture ot C - C hond tlbo
4- +
following types of ions prodo.-Anate: C 11 11 911- 3 ~ Cn11 211-5
a co
and C 11 A rupture of' bond to n',
11H2 n -'( 11 2n-11
system is, characteriotic for higher vinylalkylacetylenes.
Carbon-carbon bond (to conjugated syoto~i) is' leos ztable
to electron bombardment, The ions of the type G 11 1-1 2n-4+

Mass Spectra oJ' Vinylalkylacetylenes 78281
SOV/79-30-3-35/69
can originate as a result of* rearrangement proccases
related to hydrogen migration For C5116 + i t w i 11 b e
There, is I table; zind ret'ovem-en, Soviet,
U.S. Tho U.S. rofV7(_%ricc In: Amovicall PlAvoletim Ilintitute
Re:~ea-rcll, Project, 41[, Mws s -Spec t ral data, 14. Y.
SUBMITTED:
Card 2/4
March 28, 1959

n1able A Of Vit-ly'
A$5 A N t
C%( 3- CAC -C 114_cl~ c"v I

13 C111 1.3
14 cly 1.2
v, cll .I . i .)o 1 9.3
+ 3j, 1.4
N 7,8
8.3 78.2
.8 CI H 4' 0.5
36 C.
j 1
5 1
7
~
.
.
37 C, 11 f ~1. 1 1 !1.5
1 4A - 5.4
314 4:3111+
2") 17.0 9.1 9.7 0.1
3" c3ly 0.~ 10.5 1 W.0 48.,,
41 cj1'. 0.6 - 23.7 12.2
4 1ClIf 1.8 1 67.1 63.8
L.c - 1A 3.0 9.4

- 33.3 48.8
2.8
1:1.0 k0
Al C.41121i
10.0
2 G
12.5
7.0
I "'A 1.2 17.0 27.7
( 27.0
C., I In 16,!, 1 i's

Cily
5.5
2.4 3.7
2.4 11.3 23.1
C, 11 2,0 V.7
cjy 0.7 Co

70(-3
A it, 'J)

C I I -c X-CIWAt

W c-,
litC 12.0
'

5
18 21.4 2.
1
. 7
65 COW 39 0 .6.7
j".; C,ly Imo zil.A
1,7 4. S

7 NA
77

(7,11117"
81 C411.1
8 1 38.0

!14

lot
22.5
(kg cill
121C
Card 4/4

3/079J60/030/04/417/080
BOOI/BOO2
AUTHORSt Zimina, K. I.,,.Polyko a, A* L., K.hmellnitskiy,.R.
Obolentsev, A. D.
TITLEs Hass-spectroastrio Investigation of Some Homologs of
Thiophanel
PERIODICALs Zhurnal obehohey khimii, 1960, Vol. 30, No. 4, pp. 1V;4-1268
TEXTs Only a small number of reports on the mass spectra of sulfur com-
pounds had been hitherto published. Detailed investigations were only
carried out with respect to a series of thiophonsel whose spectroscopic
data were, as expeotedg similar to those of alkyl benzenes (Ref. 2),. In thf/
present paper the results of mass-spectrometrio investigations of homo-
logous d-alkylthiophanes exhibiting radicals of normal structure (C,,, - 06)
wereAssoribed. The spectrometric investigation by means of the alroady
earlier (Ref. 3) modified mass spectrometer NO-1 (U5-1) is described in
detail. The distribution of the mass intensities in the spectra, tho
values of the relative sensitivity, and the dependence of these values on
Card 1/2

Mass-spectrometrio Investigation of Some Romologe S/079/60/030/04/47/080
of Thiophane 3001/B002
the molecular weight were determined. The complete ionization was computed.
It was shown that an Identification of the structures, and a qualitativo
analysis of a-alkylthiophane mixtures is possible, The accuracy of 3he
quantitative analysis of the mixtures is relatively 10 -15%. The daia given,
are partly provided by the Veesoyuznyy nauohno-isaledovateltakiy inotitut
neftyanoy promyshlennosti, (All-Union Soi6htifio Research Institute of
Petroleum Industry). There ai-e 3 figures, 2 tableep and 5 referencea, I of
which are Soviet.
SUBMITTEDt March 280 1959
Card 2/2

5/07~/60/030/009/018/022/XX
BOO1 B066
AUTHORS: Polyakova, A. A., Zimina, K. I., Petrov, A, A., and
Khmellnitakiy, R. A.
TITLE: Mass Speotra and Btruo7ure of Some Allene Hydrooarbpns
PERIODICAL: Zhurnal obshchey khimii, 1960, Vol. 30, No. 9,
pp. 2977 - 2983
TEXT: Following the articles of Refs. 1 - 3 on the interaction of
molecules of unsaturated compounds with electrons and on the
correlation between their structure and their mass spectra, the
authors investigated the mass spectra of some allenes (2,3- and
3,4-dienes) on a MC-1,(MS-1) mass spectrograph in order to deternine
the effect of t~W-p*cs_i_tTon of the double bonds upon the main form!Ltion
of these or those ions in the electron collision, as well as to
compare these data with the characteristic mass spectroscopic proper-
ties of other hydrocarbons. Ions formed by cleavage of the C-C bonds
Card 1/3

Mass Spectra and Structure of Some 5/07 60/03C)/009/018/()22/XX
Allene Hydrocarbons BOOlYBO66
predominate in the mass spectra of the allenes. Ions formed by
dissociation of the C - H bonds are less intense. There are two maxima
for the ions 0 H4 and C R4 on the distribution curve of ion intensi-
3 x 5
ties in alleneb, like in tKe 1,3-dienes. In addition to the general
rules mentioned, the mass spectra of two allene types (2,3- and -
3,4-dienes) are characterized by some peculiarities which are depen-
dent on the structure. The mass spectra of six allene hydrocarbons are
described: octadiene-2,3, ootadione-3,4, 7-methyl ootadiene-2,3,
7-methyl ootadlene 3,4, 7,7-dimethyl octadiene-3,4, and deoadiene-3,4-
In the spectra of all 3,4-dienes, except 7,7-dimethyl octadiene-3,4,
the peak 67 of the mass ahows the maximum intensity, and in tte
spectra of the 20-dienes, the peak 68 of the mass. In the case of
7,7-dimethyl octadieneg the peak assigned to the ion C H+ shows the
4 9 .
maximum intensity. The second maximum corresponds in all cases tqt
the ione C H+ a An attempt is made to explain the origin of the most
3 x
intense ions with respect to their structure. To confirm the formation
Card 2/3

Mass Spectra and Structure of Some S/079/60/030/009/018/02',?/XX
Allene Hydrocarbons B001JB066
pechanism assumed for the split ions, the ionization curves and
potentials were investigated. Sensitivity and complete ionization
of all allenes studied were determined, and the degree of ionization
was found to be dependent on the hydrocarbon structure. There are
3 figures, 2 tables, and 9 references: 5 Soviet and 4 71S~
ASSOCIATION: Vaesoyuznyy nauchno-issledovatellskiy institut po
pererabotke nefti i gaza
Leningradskiy tekhnologicheskiy institut imeni Lensoveta/-'
(All-Union Scientific Research Institute for the
Processing of Oil and Gas)
(keningrad Tech--,io1-o-gT-c-aFTn-stitute imeni Lensovet)
SUBMITTED., September 12, 1959
Card 3/3

84688
11711. 041 S/020/60/134/004/013,1023
B016/BO60
AUTHORS: Polyakova, A. A , Zimina, K. I., Petrov, A.--., and
Khmellnitskiy,_R. A.
TITLE: Ma88 Spectr4qand Structure of Silicon-containin ~Vinyl
Acetylenes
PERIODICAL, Doklady Akademii nauk SSSR, 1960, Vol. '134, No. 4,,
pp. 833 - 835
TEXT; The authors havet.1wevLous"
.wproved (Reft. 1), by studying mass spectra of
vinyl acetyleneland its analogs, the interdependence between the intensities
of the molecular ion and some split-off ions, on the one hand, and the
structure of the hydrocarbons, on the other. The pre8ent work was conducted
to examine the mass spectra of four enin-silicon hydrocarbons: 1-trimethyl-
-silyl-buten-3-ine-I M, 1-trimethyl-silil-3-methyl-buten-3-ine-I (II),
1-trimethyl-ailyl-penten-3-ine-1 (III), and 1--triethyl-8ilyl-buten-3-ine.-1
(IV). In contrast with vinyl acetylene hydrocarbons, the process of dis-
sociative ionization of their silicon-containing derivatives is exclusively
selective (Table 1). Under the action of an elect'ronic impact,the MDlecule
Card 1/3

Mass Spectra and Structure of Silicon-, S/020/66/134/004/013/023
-containing-Vinyl Acetylenes N B016/BO60
of (1) mainly undergoes the dissociation of a single methyl.radical. While
the molecular ion with mass 124 has the highest intensity, 48% of thoi total
ion current falls to the ion with mass 109. The further dissociation,,gives
rise to silicon-containing ions with masses 93, 83, 81, 79, 69, 55, Und
intensities from 3 to 15%. This'dissociation takes place by the succio~ssive
spIlitting off of CH-, CH.-, or CH3 groups. There can be nodoubt about_the
presence of silicon in these ionso The dissociation of the two closelit
related homologs of M, naLmely,(II) and (III), proceeds along a sil~ilar
pattern. In both these homologs, the most resisittant ions were found ;to, be
those with mass 123 which result from the splitting of the methyl railical
from the molecular ion. In the case of (II) and (III), the further Us-
sociation is even less distinctly marked than in the case of (1). 68 - 71%
of the total intensity.of ions falls to ions with mass 123. (CH3)3 Sit ions
with Mass 73 are the most intensive in the spectrum of the saturated analog
of (1), viz., trimethyl butyl silane. The splitting-off of methyl groups
takes~place to a much lower extent. The ions representing this direction of
dissor:iation in.the spectrum are (CH 3)2 Si*H ions with mass 59. The remain-
ing ions in the spectrum of trimethyl butyl silane have a very low
Card 213

KHMEL'NITSKIY, R. A.
Cand Chem Sci - (diss) "Mass-spectrometric method of analyzing
gasolines." Moscow, 1961. 16 pp; (Academy of Sciences USSIR, Inst
of Petrochemical Synthesis); number of copies not given; price
not given; bibliograp4 at end of text; (KL, 6-61 sup, 200)

OBOIMMV, ROD.) POLUKOVAV A6AO; MMINITSIM, R.Ab
tr, ot nom thiopbum homologoo Xhim,sera.-i azotorgIogi(wd., ood,
V,neftei neft~prodo 3881m92 1606 (MAL 3.4t6)
1
js6B0YuzAYY n&u*hno-"mUdomtejlsk;Ly.jw;bj
0,-7 tut, PO pareraboift
gas*. j Pau6joniyu- iskmitismogo shidk6go toIxufto
(thicybone"peatra)

315h
61/000/022/001/C'76
08YB
C) B102 B108
AUTHORS: Zimina, K. I., Obolentsev, R4. Dtp Folyakoval A. A.,
Khmelinitakiy, R. A.
TITLE: Mass spectra of some homologs of thiophane
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 22, 1961, 12-13,
abstract 22B72 (Sb. "Khimiya sera-i azotorgan. soyedineniy,
soderzhashchikheya v neftyakh i nefteproduktakh", Ufa, v. 3,
1960, 81-92
TEXT; The mass spectra of a-alkyl thiophanee with radicals of normal
structure from C, to C6 were studied by means of an MC-1 (95-1) mass
spectrometer. Total ionization caused by 70-ev electrons was studied as
dependent on the molecular weight of the substance investigated: It is
shown that the total quantity of molecules and fragmentary ions increases
linearlY with increasing molecular weight. The total ionization value
measured for thiophenes makes it possible to carry out an analysis of the
structural groups of heterocyclic compounds. The ionization potentia.13
of thiophanes were determined approximately. They were found to decrease
Card 1/2

31516
8/08Y 1/000/022/001/076
mass spectra of some homologs ... B102 B108
(from 9.5 ey for C1 to 8 9v for C6) v'th increasing length of the chain of
the alkyl radical. The mass speotra of the alkyl thiophanes were all
characterized by the presence of an intense peak at the mass 87 whiah
permits identifying these compounds. [Abstracter's note: Complete
tranalation.1
Card 2/2

FOLYAKOVA,, A.A.j ZIMINA,, K.I.; PETROV, A.A.; KHMLINITSXIY, R.A.
Mass-spectra and structure of organio compounds. Part 5:
Mass-spectra of enyna hydrocarbons vith a tertiary butyl
radical at multiple bonds. Izv, VY~. ucbeb. zav.; khim,
i khim,, takh- 4 to. 21321-324 161. (MIRA Us 5)
I# Vsesoyuznyy nauchno-issledovatellakiy institut po pereabo*W9
neftl i gaza i Leningradakiy tekhnologichookiy institut im.
Lensoveta. Kafedra organiq#oskoy khimii.
(Hydro'earbons---Spectra)

YJMJINITSKRI R.Aj ZIKM K.I.; POLYAKOVA A.A.
Mass opectrum.Vuayvis of ganolinee, Ehim,i masel 6
no*6;55- 60 it 161, (JURA 34s7)
le Vaeooyuznyy nauahzko-iseledovatel'skiy institut po pererabo%~ke
nefti i gaza i polucheniyu iskusstvennogo zhidkogo topliva.
(Gasoline-Spectra)

POLYAWVAS A.A.1 MMINITM=,, RA.
eft4a% regularities in Mass opoctra. of nomowinso Zbur.obo
khime- 33. zo,,224099-4060 D~ 16L. (KML 15:2)
Mos "trovetry):

POLMOVA
A.A:; KMINITS131p R,A,
Man spectrum aw3jois of five-mmbered and air.-membered naphthona
bydrocarbons in gasolines. Zhur.priki-kbim. 34 noo7sl569-1512 J3,
161. (KMIL .14A)
(Hydrocarbons-Speatra) (Gasoline)

PMM, L*S*; KUSLINITSKIYp R.A.; WIFARUMs NeYas
Mass spectra of some dodecane isomers* Neftekbimla 2 nool:IL-13
Ja-F 162. (MM 15:5)
1, Institut neftekbimichookogo sinteza AN SSSR.
(Dodecano-Speotra)

m e. i w., ~"-Yjf g a A, f m
POLYAKOVA) A.A*; 10-IELINITSKIY R.A.
Mass spectrometry method for determining paraffinic hydrocarbons
of normal and branched Khim.i tekh.topl.i masel T
no.8:70-3.of cover Ag 162. (MIRA 3.5t8)
1. Vsesoyuznyy nauchw-issledovateliskiy institut.po pererab-olke
nefti i gazov i poluoheniyujakusstvennogo zhidkogo topliva.
(Paraffins) (Mass spectrometry)

PnIMKOI, V.W.; pMINITSKIlp R.A.
The. UXP-UKU equipmwt for automatic control of cage hoists@'Muls
tokh.-Okon.inform.Goo.imuch.-Jesl.inst.nauch.i tekh.infom, D('w,lt
10-U 163. 1 (Km l6t2)
(RIne boisting) (Electronic control)

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VEFY(p)j 1~1~ AS ?a-4/Pr-4 RM/W
L IZ977
ACCESSUOU VR, AT3002350 s/2513/63/01
ALMD
R
A~.A-) RmZrOv, A. J%
TI 711-1, .Mass-spactroma~xjc Smay3is Of Silica-con-tainimg vinyj:~jc tylenes
SCURCEI AN SSSR, Komiasiya 12 =411-,tcheslwy
Oreanjoijaakiy Anmjjz., 40p.490 Is T~Udy*, v- 13, 196.1.
MPIC TAG-9: apectrometry, S"'ca, Viny'lucetYlOnO) &-UtYl radical, vinyl ra~Llcal,
ABSTRACT- M- stu4 of meAa-speatra o:r - silim-containing v I - t I n
1that the p inY aCe y e es shcved
-Mcesp of their ionjc dissociation is M"y selective. 7rds rasult3
in the formation of a muLU groUD t3f characteristic ions which nay be util. !zed
in tl,,e identification and quantitative analysis of tthe a]-kylsilybutenenes. 'Mhe
invest-Igated m s-spectra covered the folloving compounds: trimethylisopr~penyl-
acet
,ylen~-lsilane, trL--thyl=l)enylacet,,,Ienylailane, triethylvinylacetyler,
Silare, dimethyl,,Inylace~%,ylenylailane and metIVIvinyld:ivinylacetylen.,,,Isllaia.
In ~LU the invest4gated materials, the maxim= peak was found at the sil-,
after aL'