SCIENTIFIC ABSTRACT KLABUNOVSKIY, YE.I. - KLABUSAY, L.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000722930005-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 18, 2001
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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"Dle AssymetrIshe Xotnlyve,," a paper presented at tl* Internatioal
Symposium an the Origin of Life, Wmcov,, 19-24 Aug 1957.

CT
----------------------

n"MOVSKITt YO.Le IMUU"t Walchesifth nauk.
Organic 0041rots-."line ths stor*60pocifle action of Ousyms.
I this. nauka I pro*. 2 no.21197-202 157, (mm IoW
(2urms) (catalysts) (Stersochealstry)

gA
WTHOR SAUNDIN AoA. X*a'b*r af the Academy, KLADUKOVSKIY TO.I. PA - P50
TITLZ On the Stsrooohealstry of Cesslytia Active Complexes
(0 sterookhtmil, katalitiahoski akttvnykh kospleksoy -Russian)
MIODICAL Doklady Akad*ali Sank SSSR# 19570 Vol 113, Nr 30 PP 585-561 (038s)
Received 6/1957 @ Reviewed 7/1957
ABSTRACT With reference to the author's work in D. 1956# Vol iloi Ir 4t the
present paper explains the process of reaction. For-thle purpose
the hydrogealsation of the camp6und (1) Is carried out,
*
4
*1
6'
6w
601)
dlh
8
d
6
(1
(
(
-
-
1) to 2t3-
1 5
1 5
#
t
71
0
5
5
) (5#
)
y
:o
tribeasoobia (gg2 2 -oatadisn-5.7-dlon-10#4'. Rydrojesisation
yala
j
j
was carried out at 45 and an atmospheric pressure &bay* the as-
talyger In freshly distilled dioxant (peroxides are lacking). The
experimental method and the production of the catalyttr.le des*6
bad In Di 19569 Vol iio, Ir 41 Investigation showed that the sub-
Otanee obtained to the product Ills It 21 3't4't5't61- bezahydro-
(2001#61)(%61 50p6ft) (?#as 5"4# 6-11- 1ribezoebicycla-(20102)-
oot&di*n-5# 1-dion-11#44. This eamPaund has as Yet not be** 40scri-
bed In publication*, In pure form these are yellow crystals with a
saltine point at 182 - 30o This pxoduct showed no reaction to ohin-
old* structurog did not react to an elefine compound# formed so pb*-
nylurethan** and did not react to saleinashydrido.On the aassesion
of the reaction with 2A-dinitrophanylbydraclno the produm (III)
Card 1/2 gave a **11-arystallising mono-2.4-Ainitropheny1hydrasove with a

ASSOCIATION
PRESZXTZD BY
SUMITTED
AVAILABLE
Card 2,2
On the Sterooobesistry of Catalytic Active Complexes, ?A - 3150
melting point at 185 - 80. The sultiplot theory sakes it possibl*
to construct stersochomical models of aotlv* complexes of the in.
vestigatod reactions. The structure of such models to described.
(With 2 illustrations and 6 citations from Slavio publications).
Institute for Orgwdo Chemistry "N.DoZolInskiyO of the Academy of
Science of the MAX
4#io.i956
Library of Congress

Y6- -L
Balandin, As As, KlabunovsklyLlyet It, Fozins$ 62-1-3/29
M.P., Ullyanovao Od
TITLEs ThermocheJoal Detection of the EnerGios of Compounds
(Tormokhiaiahookoye opredoleniyo onergiy s%yazoy). Report It
The Znargles of'tho Com;ounds Sn - C In Totramethyl and
Tetrltetbyl Tin (Sooblohzheniye 1. Energli sryazoy Sn - C v
totrazotil., I to)raotilolove)
PERIODICALs Izv,-stiya AN SSSH Otdo3snip LhImicheskikbi Waukt 2958j Ir It
pp 12-17 OUR)
ABSTRACTs
C ard 1A
The dots, in @techntcal literature conoerning the energies of:
compounds (used in the computation of the adsorption potent-
Iola of the catalysts) are Insufficient* Above all no vubli.
cation gives concrete data on the anarelea of the compounds
CtH#CgN with elements belonging tc the composition of the
most important catalysts. Therefor* It wao important to start
a systematical Investigation of the compound energies n*coss-
ary for the catalysis also by thermo-chezical ways In the press
sont.paper the authorn report on the detection of the com-
bustion heat of tetramethyl- and tetreathyl-ting the hsat@
formationfrox element and tho energies of the compound.
Sn - C (tables 1 and 2 The found data give more preoiss

The-rmooliemical Detection of the Energies of Compounds 62-1-3/29
Report lo The Energies of the Compounds Sn - C In Teta@amothyl and
Tqtraothyl Tin
rules governing the homologous series than do those hitherto
found by researobam Turtharmoro it was shown that the app-
lied calorimetric methods can also be used for the detection
of the combustion heat of the Imotal-or unto compounds with
rather grreat prsaisenoss.(Tables 36#61, Furthermore each in-
vestigated compound demands a special approach to the methods
of its dombustion# and therefore it is nooeseary to carry out
numerous preliminary experiment*. Furthermore the spectrum of
the combination dispersion of tetraothyl-tin was detected for
the first time. There are 6 tables and 24 reforences, 7 of
which are Slavice

ASSOCIAVONt Institute of Organic-Chemistry Imoni No Do Zelinskly,
AS USSR and State University Imant M. V. Lomonosov,,Moscow
(Inatitut organicheskoy khimii Imeni go Do Zelinskogo Akadvail.

Card 2/2 nauk SSSR I koskovskiy gosudarstvennyy univeraltet Imoni Mo Vs
Lomonocova)

,.~1-4";",~"xotnlorrtnia-,eompounde-Combustion 2, Ctapounds-Enera mesuressat
3. Ctlorimotord -Applications 4, TatramettWI-tin-Thermochadstry
5. Tetra sttw1-tin-ThG=fthsMistz7

5/7
TITL@'@: Tho qlArIttition of 1,Aaamates by of :Acorption

F@;RIOI)I(IAL:
,965 (11-joa)
UnpLkht khInti, 19,510 701. 27, Nr 8, pp. c" 4 9 -
AF%TRACT: Tho prenent sirtiole rwfnl@,, U, Is with th*n different wires of
tho (jistribution or the rcconatoe of the al,-6r--
tion mothod) tn t!ynth,@tic @-,nd niturAl trio rydrorbentLl
thich ccy.be of ort-onla or tnorgAntc orij:tn. The detoratna-
tion zethod of Tneemato dlotribution bw@rd on the f orant ion
of Ahacton compounin CioYedineni.l?., vklywc-henlyr-) tnkes a
prominent rlucco Tha first nection of tha artieln -1caln with
the dictribution o!' thc rricomateL, un,ler the influcnce of the
opticully native roly,@nts in the trconl ch,iptor %1,ify -@uthor
diacuoupoo the diatribution of the race#-atca by nny=ctria
nd4orptlon. The lulter trkcc placcc Ather b-, tho diatribution
of the rneemntoi on the synthatic @Arorbont a?
by mouo.l n&O the no-mmetric adeoriA.1,jo cn wtun-11, flsy:!,,-c-trtc
ndvorbentv. In the preatnt case the adearii-4.1on an c1bunin or
on curbohydratoa in coneorneds Thin ad4orption method on natural
Csird 1/3 disymmet,ric ndn'orbentn la discunced in dtltail (Rffl ,1-68).

`7A
Tho Diotritution or aacemates by UenAn of the Adcorpti,,,in
The third chuptor do als with the dietribiallon of tbj@ ructeater.,
b- morinn of the formation of adhesion com;,ntind@i (fo-1011hrnly
All.nicheniya). -It Is strenned th-r-A the rot-, -A17, itircovored
4uthod ot the ritconsto distribution (bnvei on tho direct
itlectivo cryatullivition of the ndherior eomrcunl.-) V1 of
grc@At theoretical und practicul in:;ort,3iat_. In thin chsptf-r
Loome rapoes dealing with this topic ore diecusned-JUfa 69-76)#
In thoAlourth chapter tho uuthor, diccurcen th@ rccomote Ala-
tribution on oyttoftlly.active quartz. A nuzb"r of )-arern
Aeoling with tho asv=etrid adsorption on quartz bre dircussei
Oford 77-81)# game or which are dealing with the ronlitation
of the colootive adsorption of silioio:acid siparated from
1IvJng aniral organiva,(Refe 85, 86). The si?orptian vethoda
given for t@o distribution of the racomatea prove their In-
creasing ImPortance for.preparative enj analytict-I Phemiatry,
'The use of synthetic dlaymmatric ainorbents saeon to off-@r
the bent prospoots an In a number of co"es they re=it Vie
complete distribution of the racomater, A recently
methoi aloo attracted great attention: The alutributioll Of
.racomto amino eciAn on prper celluloves There aro 6 tablun
Card 2/3 ain,f 87 @4oforencos, 5 of which are toviet.

5.3400
AUTHORSs
TITLEs
PERIODICAL:
ABSTRACT:
Card 1/3
77076
sov/62-59-12-2o/43
Nazarov, 1. N., Kravchenkoo N. A., Kiabunovskiyj Ye. I.
Concerning the Catalytic Synthesis or looprene, Based on
Gaseous Hydrocarbons. Communication 1. The Study or
Possibility Isoprene Synthesis from Acetylene
Izvestiya Akademii nauk SSSR. Otdele-iiye khimicheskikh
nauk, 19591 Hr 12, pp, 2171-2176 (USSA)
Several catalysts were tested for the condensation or
acetylene with propy@ene At Atmospheric pressure. Pure
catalysts without support were inactive. The following
supported catalysts were used. (1) Fe 0 + moo /Qi02'
2 3 Y
Silica gel was impregnated with an aqueous solution of
ammonium molybdate. The excess solution was removed.
Silica gel was dried at 1100 and was boiled in a 5%
solution or Fe(No 3)30 for 10 minutes, dried and calcinated
at 5500. The catalysts 2-7 were prepared similarly. (2)
coo + moo ISi02- (3) SnO + MoO SiO2. (4) TiO + MoOvaio,,,.
.0 -

Concerning the Catalytic Synthesis or 77076
Isoprene, Based on Gaseous Hydrocarbons. sov/62-59-12-2o/43
Communication 1. The Study or Possibility
Isoorene Synthesis rrom Acetylene
(5) CUO + M003/3102- (6) mgo + moo3/sio2. (7) cao +
4. M003/SiO2. The catalysts: (8) MoO3/ASCv (10) W03/ASCP
(11) TIO + W03/ASCj (12) W03 + TIO/ASC were prepared
with aluminum-silicate catalyst (ASC). Beside the
above catalysts, (9) WO /GiOV (13) CaO/SiO., and ASC
. 3Y 11
were also tested. Condensation of acetylene with propylene
over above catalysts was carried out at 350-4500 forming
mootely@aromatic hydrocarbons in 3.6 to 63.6% yield
(benzene,s toluene, o-., m-,, and p-xylenes). The forma-
tion or isoprene and pipez"jlene was not observed. A. E.
Agronomov took part in this work. There are 3 tables;
and 8 rererenceso 2 Oerman, 2 Frenchs 3 U.S., 1 U.K.t
The 4 U.S. and U.K. references are; C. H. Holder, N. J.
Craufordj U S. Pat. 2388916 (13., 11; 1945)i94B; -We 4atieV.,
,Card 2/3 H. Pdnes'# @.,s, . P a t ., 2410445 (25# 11, 2

Concerning the Catalytic Synthesis of 77076
Isoprene, Based on Gaseous Hydrocarbons. sov/62-59-1@2-20/43
Communication 1. The Study of Possibility
Isoprene Synthesis from Acetylene
It. Plaueon, J. A, Vielle, U.K. Pat 156116 (30, 12, 1920);
Chem..Abstrs. 15, 1727 (1921).
ASSOCIATION: Zelinskiy Institute of Organic Chemistry, Academy or
Sciencesj USSR (Institut organichoskoy khimii imeni No Do
Zelinskogo Akademli nauk SSSR)
SUBMITTED: May 7, 1958
Card 3/3

6bdoi
BOY/76-33-11-17/47
AUTILORSt Balandinp Ao A*,# Klabunovsklyp Yto I*
TITLts t1o i0f the Meahaniss of Catalysisl
yesti
4tersoobesioal
In
-
-
gm
Pnioxcn, Zhurnal fisiobeskoy kbisii, 1959# Vol 33t Ir lit PP 2460-2484
(USSR)
ABSTRACTs The catalytic hydrogenation of several tryptic*ne derivatives
was carried out with nickel# as theme hav* a complicated
sterio configuration and,theroforo they do not adjust th*&-
S&SilyLtO the catalyst surfaeop vhich readers then
suitable for this study (fro& the viewpoint of the multiplet
theory)* The application of storsoahenical principles iogether
with those of the multiplet, theory permits the recording of
models of intermediary active complexes (Pigs 2#3)* It was
shown that# despite aoupUcated configuration of the original
substances which prevent the laying on a plane catalyst Sur-
facet hydroStnation-occurs already at 450 and I atze Therefore
the catalysis occurs on the elevations of the catalyst# besides
hollows where the protruding volsoule parts deposit in the.
hollows* The models of the compounds investigated permit
Card 1/2 evaluation of the depth of these hollows with a minims of

66862
BOV/76-33-11-17/47
Stereochomioal Investigation of the Xeohanism of Catalysis
307 1 and a maxinum vidth of 4A L Thust a sethod is obtained
for the dotermizationdf the idororelief of the catalyst our-
face., There are,3 figures-and 9 referenoest 6 of uhiah a"
SOVI*tO
ASSOCUTIONs Akademlys n&uk,SSSR.,Ins,tItut organicheekoy khinil in@ No D& Z*-
linskojo, (Aaadsm of $OIsAO*s,#.US3R# Insti.tute of Organlo
,-Ch9r4.#trY Imeal so Do zelinally)

AUTHORS# Salanding A#A#t Aoadealotano SOY/90-127-3-21/71
Klobun etrovi Tuals
TITLEs guration n err stions In Stersoopooifio Catalysis
1010
9:1,
PMIODICAL# J)okl&dy Akawdi naak SSSR,, 1959# Vol 127,11r 3t
pp, 557 - 560 (USSR)
ABSTRACIs The sultiplet theory of catalysis shows the existence of
a certain structural homology between the reacting molecule
-and the fine structure of thecatalyst surface, Theme
relations were investigated by several examples of the
heterogeneous catalyst* (Rate 1-3)- Henceforth they have
.to be investigated in the field of asymnetric micro-
heterogeneous catalysts# sinoo.the principles of the
structural and energy oorr*spondenoo of the imItiplet
theory was also applied to fernentativ* catalysis (Rofs 4-00
The effectivity or the stereosp*olfio catalysis depends on
the degre**of the structural correepondoua*. Therefore it
is*of interest to onlargo the knowledge about reactions
Card 1 3 catalysel by staro-heterogeneous asymmotrio catalysts

Configuration Interrelations in Sterecopooific Catalysts BOT/20-127-3-21/71
(ferment samples),'Skita catalyst (colloidal platinum or
palladium with gus aratio as protective colloid) was chosen
.88 such (Rat 7), The** catalysts were produced according
to reference 9 which was altered according to reference 10#
Pbenyl- &a O&vnaphthyl- glyoxylic sold* were ohoeen to
Initial compounds whichdovelop oxy-scids with a considtr-
able optic activity asnelyt mandeli'O &old and Q&-nApht1.q1-
e1yoollio &aid, Theos, tun In opposite directions but belong
to the same configuration series, figure I shows kinetic
curves of the hydrogenation phsAyl-glyoxylic said And of
the dioxins In coordinaUss reaction rate versus - time
and rats versus - degree of transformation. Table I shows
results of characteristic experiments with regard to the
optical activity. The comparatively high value of the specific
optic activity of the developed diasine Is striklzgo The
results obtained show certain configuration interrelations
between ths@catalyst and the reacting molecules. In the
cases invoitigat4d thi. protective colloid (gua &rabic) does
not toovi to act as asymetric carrier$ nor as optically
active solvent. The asymmotria carrier chosen by the authors,
Card 213 ban a selective effect during oatalyals, since it favors Us,

Configuration Interrelations-In Stersospeolfic Catalysts, BOT/20-127-3-21/11
development of an "Id with a D-configuratton* The above
results prove & great configuration correspondow between
the &symmetric catalyst (rather the &symmetric carrier) sad
the spatial structure of the r#aoting molecule (lot 13) o
Speoial experiments proved that the protective colloid also
tots to asymetrio ouvior (also Ref 2). The results
obtained finally prove that the metal particle to not In
the solyato cover of the sicellet but immediately contests
the &symmetric molecule of the protective colloid, the sourse.
,of an asymetrio adsorption and:of such a catalysts thus
become possiblesIbre are I figure# I tablet sad 13
referenesso 11 of which are Soviet*
ASSOCIATIONt lAotitut organiobeskoy kbixii In, N,D@ Zolinskogo Aksdomit
nauk 8881
(Instit4to for organic Chouistry Lasni N@D,. Zelin .skir of the.
Acadeny'of Sciences$ USSR
SUBMiTTED, May lot 1959
Card 3/3

5,( SOY/20-129-1.28/64
AUTHORSt Balandin, A. A., Academioten, Ela@bjnovakiy, *10. 1.
TITLEj Steroooheefoal Investigation of Active Centers of the Catalyst
PERIODICALs Daklady Akademil nook $$SRO 1959, Vol 129, Nr 1,
PP 102 104 (USSR)
ABSTRACTs Conclusions on the stricture of the catalytically active osta-
lyst surface are rendered possible.by the investigation of the
catelysisof molecules with complicated configurstion, It the
size and structure of the reacting molecules is varied, the
absolute dimensions of centers protruding:from this surface
and their statistical distrib4tion can be determined.- Thus
-hydrogenation of the tryptio (I)
anthrylone-g"#100)-cycloboxone-2-dione-1,4) isof interest
see.Dis ram). (1) *as synthesized by condensation of trjYptio
quinone III) with anthraeone by boiling it for 5 hoire in on-
hydrous othylbonzeno. The constants and transfortations of (1)
(Rof 2),are shown;0(1) was hydrated araer nor@zal atmospheric
preavire and at 4 , ovPr the nickel catalyst skeloton in freshly
distilled dioxans free from poroxidn (setr Ditgran). The by0roo
Card 1/5 ganation product (IV) was recrystallizod. Its melt"Ing point to

Stersochomical Investigation of Active Centers SOVI/20-129-1-2a/64
of the Catalyst
2210 its smpirlo formula 0 1 0 ?'gar@ Ishows the varia-
34 24 2
tion in the hydrogenation rato,of (1) depending on the reso-
tion process# as well as the hydrogenation ojrv* of tryptio
quinon*4 The investigation of the stractaroo of (I) and (IV)
is difficult, Ifor this reason# apparently$ the analysis ro-
sults devists from the theoretical values. Yu. P. Yogorov
plotted the infro-rad spectra* They shoved an ethylene bond
in the case of (1) which is missing in the hydrogenation pro-
duct (IV). Moreover. the frequencies typical of the 0-11 bond
or# missing In the a octrum of (IV). gone# it appear's that no
isomerization or (Iy@ to a disnediol (V) took place. Hydro.
#$nation of (1) seems to lead to the formation of di4dro-
diketont (IV) without 'byoproduots. Figare 2 gives a schematic
rorosontation of the position of the 20100410 of compound
(I on the surfs** of the catalyst. In connection with the
hydrogenation of each a compound only plorar orientation of
the oyalahaxonedione ring on this s4rfaae event to be possible.
The h:ight of an active center on the surface where hydrogens.
Card 2/3 tio f (1) t skso place to determined from the true sea V*f

6648L
Stersochemical Investigation of Active Centers SoV12o- 12 9 .1 -26164
of the Catalyst
the model of the active complex. The fact that this reaction
takes place at all (although at a low rote) indicates that
the height mentioned amounts to at least 3.171. The alto of
.the active center surface can be approximately estimated on
account of the 41stinco between the ceso positions on the model
(fig 2). it cannot amount to more than 4.0 Ro The sterooohomi-
cal model of the Intermediate complex discussed hors differs
considerably from the hydrogenation of tryptic quinono Invos-
tigated previously* The number of active centers is considerably
reduced due to the surface orientation of the molecule and the
staiio hindrance of the reactionj hence the low rate of reaction.
There are 2 figures and 2 references, I of *hich is, Soviet.
ASSOCIATIONo Inatitut organiohtskoy khImifim. N. D. Zolinakogo Akademli
nauk SSSR (Institute of Organic Chemistry izeni N. @D. Zolinskly
of the Academy of Sciences, USSR)
SUBMITTUs 4uly 9, 1959
Card

PHASE I BOOK SULDITMON SOV/4289
Klabunovskiyp Yovgoniy Ivinovich
Asimmetriaheskiy sintoz trilrSynthosis) Moscow
Ooskh'm'zdat# 1960. 29 p. Errata slip inserted, 4,000
ooplos printed#
Zd.: 2. 1. Budovskiyj Tech. Ed.t Yo. 0. Shpak.
PURPOSEt This book Is Intended for students in advanced courses,
aspirants, and scientists working in organic chemistry, bio-
ahomIstry, and biophysics,, - it *4 be usod as a handbook and
methodological guide In &symmetric synthesis.
COVLUORt The book contains a comprehensive review of material
on,"=trla synthesis, being based on data published through
1958 of 1959. Catalysis and the resolution of race-
mates by fh"etaation of physical agents are also discussed.
There are 9 figures, 33 tables, and 763 references: 75 Sovioto
306 Inglisho 51 French, 16 Swiss,, and 315 German. No person-
alitios are mentioned*
card l/S

Asymmetric Synthesis 3OV/4289
@TABLE OF CONTINTSt
Introduction
Conditions for Accomplishing Asywmtrio Synthesis 9
Partial Asymmetric Synthesis 13
Attempts at synthesizing asymmetria cy"ohydrins I
Asymmetric condensations B
Asymmetric condensation without separation of the
asymmetrization reagent 18
Asymmetric condensation with separation of the asymmetri-
zation reagent from the reaction products 19
Asymmetric synthesis by partial decomposition of the inter-
mediate oompounds (Nankwald.synthesis) 25
Afiymmstri@ synthesis by addition of a symmetric reagent to
unsaturated optically active compounds 30
Asymmetric reduction of eaters or unsaturated or keto
acids 30
Asymmetric synthesis of amino aoide 35
Card 2/6

Asymmetric Oynthesis SOV/4289
AmyMmAst 0 synthesis by hydroxylation of eaters of opti-
cally,adtive alcohols and unsaturated saide 39
Inner'soleGulU asymmetric synthesis by addition at a
dopble bond with subsequent destruction of the asymmetri-
sation center 39
Asymmetric synthesis.with the aid of organomstallio oompounds,io
Asym"trio Induction
Asymmdtric conversions of complex compounds
Stereospedific Catalysis 90
optically inactive stereospeolfic catalysis 90
Fermonta%ive &symmetric catalysis 94
Yermontative asymmetrio oyanohydr1n syntbesis of hydroxy
nitriles and hydroxy acids 97
Asymmotricsynthemis by the action of oarboligaso

As
ymmetria phytoahem1cal reduction of ozo compounds 201
symetrio synthesis by the action of Oketoalldomutane.0
A
aldokotomutase,, or glyoxalasel
I 103 i
Biochemical asymmetric synthesis by the action of as-
partaso
7be asymmetrization effect of oarboxylaso 107
Card 3/6

AsymmstrIo Synthesis SOVA289
Asymmetric W thesis with the aid of organic catalysts which
reproduce the stereospeaiflo effect of ferments
The asymmetrization effect of an optically active solvent 109
Asymmetric resolution of rac*mates 109
Asymmetric synthesis ill
Dissymmotrio slarohoterogonsous catalysts 113
Asymmetric resolution of racomates over alarohotero-
geneous eatalysts 123
luoroheterogra4tous catalytic &symmetric synthesis 222
Dissymmetria hiterogeneous catalysts 134
Catalysts bupd on a dissymmetric carrier lJT
The meahanism of asymmetric heterogeneops oatelysis 1 5
Absolute Photochemical Asymmetric Synthesis 149
trio photochemical resolution of racematos
Any 252
r
ttempts to accomplish the photochemical asymmetric res-
olution of racemates 151
Asymmetric resolution of racemia complex compounds .
155
Asymmetric photochemical resolution of racenio organic
compounds 156
Card 4/6

Asymmetric Synthesis SOV/4289
Absolute amymMtri* photochemical synthesis 160
Absolute Destructive Asymmetric Synthesis 16T-,
separation of racematas by the effect or an optically activo
solvent 16T
Separation of racemates by asymmetric adsorption 160
Separation of racouates on synthotia stereospecific,
adsorbents 170
.Separation-of raosmates by asymetrio adsorption on
natural dissymmetria adsorbents 275
.Separation of racemates by the formation of Inclusion
compounds 288
Separation of racomates on optically active quartz 194
separation of raae"t,se by spontaneous crystallization 199
Selective crystallization in an optically active solvent 199
Selective crystallization of a radomate, Induced by a
crystal antipode or an Isomorphic crystal 201,
Spontaneous crystallization 204
The importance or asymmetric synthesis preparative purposes 206
Card 5/6

78067
-sov/62-6o-i-13/37
AUTHORS: Nazarovj 1. N., Klabunovskiyj Ye. I., Kravchenko,. N. A.
TITLE: of Isoprene Prom Gasequa Hydro-
.carbons.. It. Synthesis of Isoprene Prom Propylene
PERIODICkL: Izvestlya Akademli nauk. Otdeleniye khtmicheskikh
naukp:1960, Mr li PP 73-79 (USSR).
ABSTRACT @Technical propylene was dimerized to 2-methyl-2-penteqe.
The alumina-silica catalyst, containing small amounts
of oxides of magnesium, copper, and iron, was treated
with solutions o*r aluminum sulfate or titanium sulfate.
0
The yield of dimer, at 300-360 and atmospheric pressurep
was 38.7% of the polymeric reaction products.. The
.dimler was converted into isopmne in a quartz tube. at 7500)
r 0 0.09.13ec, 306 mm, in 17.7% yield (the ratio,
nitrogen carriert dimer was 1:0.33). There are 3
tables; 15 references,.1 U.K., 4 Soviet, 10 UOS. The
Card 1/2 5 most recent U.S, @rarerences are.* U.S. Patents

Catalytical Syntbwsla of Isoprene '(8067
From Gaseous Hydrocarbons. 11 sov/62-60-1-13/37
2404056 (1946); 2446619 (1948); 2507864 (1950); 2410688
2476512 (!949).
ASSOCIATION: N, D, Zelinskiy Institute or Organic Chemistry of
the Academy of Sciences of the.USSR:(Institut
organicheskoy khtmil Imeni N. D. Zelinakogo Akademii
nauk SSSR)
SUBMITTED: May 70 1958
Card 2/2

/60/001/001/007/007
8/195
2015/B060
AUTHORs Klabunovskirt YO. 1.
TITLEs All-Union Conference on Train Catalysis In Moscow
PERIODICALs Kinstiks, I katalisp 1960t Vol. Is go. is pp. 172-175
TE(Ts The First Ysesayusnays, konferentelys, po, organichaskomu katallau
(All-Union Confelenot onArstania Catalyoll) was hold in Moscow from
November 16 to 20j 1959a It had been organized on the Initiative of the
Vchenyy sovet po problems "Isuchniya asnovy podbora ketalizatorov"
(Scientists# Council for the Problem of the "Scientific Basis of'the
Selection of Catalysts") by the Inatitut organicheskoy khImli AN SSSR
(institute of Orasnic Cbexistry of the AS CSSR)q the Fiziko-khtmichaskir
institut is# Le Yas Karpova trnystooonemicai institute imeni L. Ya. Karoov)..]
and the khIsloheskly fakulltot XQU (Department of Chemistry of the USU).
Since the Cosudarstvennyy Xomitet Sov*t& Kinistrov SSSR o Wall (SjpA_*
Committee for Chemistry of the Counall of Ministers USSR5 Intended to holi-__
a conference on tsoS al catalysts at the same time# the two conferences
were combined. An attendance of 600 persons at the plenary meetings heard
Card 1/6

ill-Union Conference on Organic Catalysis S/195;'60/00i/001/007/001
In Moscow B015/BO6.0
sight.leatures on theoretical problems of organic catalysis and ton
lectures on technical catalysts. The other 140 lectures war* dolivorod in
six sectional 0 investigation of,cat4lystal 2) polymortzationl and con.
. y
donastion resotionel 3) Isomerisation- and alkylation reactionsi Ohydroo,
gonatLon-j dOydroganWon-, and dehy4roo olitation*rosational 5) hydratim.,
dehydration-# and hydrolytIc reactions$ 65 oxidation- and halogenation
reactions* The Conference was opened by Academician V. A. Taxanotty *ho
mentioned the research work done on organic catalysis, In the present
report, the following Soviet lectures and lecturers arv mentioned
(contents are briefly Indicatod)s Academician A. A, Balandin (10rh An-im)
"Structure of Molecules and Reaotivity"I So Z, Rogin kT,`y-RFZ' Ab U.4-jdj
with a lecture on the theory of catalysis r. V21#X!W= (IFKb A@MSR)
.on the "electron factors" in the kinetics of heterogeneous reactional.
A* So Torenin and L. ROY** (@qu nfrared spectra of the catalyst
M on I
urfacoj.W4 P. Kayer 1IFKh AS US R) on the effect of olocCronia interaction
:n the activation ani Sy of abomosorptioal So L. KIpersan and 1.H#k&Yy4?!!t
(10D AS USSR) on the determination of the binding onoriji Yo.f--WT-P%qV-_-
novsviy OOKh AS U3010 on the determination of the absolute conficuration
of wvAooulesj H. A, Landau and V. V. Shchokin (IMS AS USSR) on some.
Card 2/6

All-Union Conference on Organic Catalysis V195/60/001/0001/00VW7
in Moscow B015iBO60
rules governing catalytic activity, Reprdin the lectures delivered at
the sections, the following namos'ars mentioned$ section Is V.V.VoyoV6dIft
skiyl,IA_L Kasanskly Yu. I* Poohorskaja (IXhF AS VS3It)j S._i7RoCInskiy+
X", Ygoovski 0 V oalkeYM L. I&. Margolis (IrKh AS 1USSR)i
o Is Laynerp No -M, &AM 0 gratevetestobrabotkp V. Patrik*yov
V Ituso C-70 VI&SONO
AS U33 ) 0 No MAL io-T(MI go To Ruso
inh As VkrSS!)I A, As 51 n n (IOD AS USSR), 0 D. I-XmbArfiirIx,,
5n
No Ivanovskayal L. Y%. Wokronvot
(physicoo ealoal institute ImenI L. Ya, xerpov) 0. V. Zpacroy
V, Is Vladistrovs, 0, aVinogradova (IM AS.USSR)j A* go u Inshto"
anIt
IOKh AS U11 1 4 V4 Uganova, To Ye. Shakhova A. Too P kovs, (VE-11
Neftekbia)l Kh. F. Tnaaheilpt 0. V.Ms_&m7XWWj Do A* KondraVyo-V
--I-.-D-s RoshdostyanskU& (10 H - V. Antipina,
Kh AS USSR)j Kh AS VESIT, F.
@MIOSU)j 9, P, Vakslaovaq To Z, Vasserberg t AS USSR)j 06 VO Krylovi
Yet A* fikins, (I Kh AS U7W_._So_otIon-f,;B. A. Krentsolq A. V. Topchi7ey'.
IMS AS USSR)l Ch. So Karryyovp,,G. go Panchonko% So V. Alitshulor
HM I OP - 1 00 go V01,00 Is Oglobli&__(G__ro-MI);
IN- T_ U@ n1lblel
To. To Eydus (IOKh As USSR)- As No bashk1rov- Yu- B. X!gan; YUoB# Kryukor,
so We Laktav (Ixxhs As OSSA I B. A. bolono P. U. Adr V)j A.V, Top-*
Card 3/6

All-Union Conference on Organio.Catalyste SA95160/001/001/007/007
In Moscow B015/B060
ohlyevo go TSUV Dultriyeva (101b I OF Is. I. M. OubkIn&).
Section 31 L-0, A I# Shuykin, T. S. Shokorashvili (IKh AS
OruzSSR)l I go Bursn@nq a. A. Barkhan (VIII Reftakhis)l
M. 1. 1yokin, M. B# lansk I II Neftekb1m)l Me O._0on1kb*rg 1. is jL4_*fU-
waste (Ts 0
kly- --N-o&$ @ Kazanalt4v SSR); No B# Turoys-rolyak, 1, X*.__$gsn1nA.
11 11 s. is
1. Shuyvi"t 1. ps Bel AS USSR)j 0. V. ftno
SU Lj@& (j0Kb henkov#
go Islas it T kiUh I rp G. T M OubkIna) 1 W., V. Rudenkp p Y
Polyak tMSU)j R6 M. Lagidso (1Xb AS Oru%SSR)j So 0* MoPkanovitfilArAWS
bSSR). Most of the 19-o-Vurse we ad at
390tion.4t &so hers bys - A- AAAI#ban. 91 1. Temkin (Phyrionnhomminal
T"atitilto Imo"i Lo Ya. Or imv)-l A* Ta, Rosovskly, V. To Rchokint Tqo_.&@
okrovskays (INOW Ab USSR3 I I, a 9. Kachkine, 0. K. Torgskov, 0.71. LVIIN-vat-4v
Phyalooohomical Institute Imenl Ls Ta@ Karpov);-Do V. Sokollakly wf. UL
ID AS_XasUj)j A. A. Ponomarev, N,_Z. Xaslonnikova- Alaklas
isaratovskiy 6000 -univervit*t - A&ratoy jW* University)l X.A, VaNZ2mins,
As As Balandinj Sol Choplivo (10D AS USSR and
Chzhao-lan't'K. P. Lavrovskly# A. L. Hosentail (IWWS-As Us D. A.-
Bol'shokove I* Ya. T-vuEzayoy (NIIU SK)l 1. L. ftidshte-vil (Giprokauc
V- 3.:A1176Vj A- P- Kaulmova, sr.-r-. Kyazimav Ter-Sarkisov (IMM
Card 4/6

'All-Union Conference on OrsaniO Catalysis 60/001/001/007/007
in Moscow aom/Bo6o
IS IsSSR)j Yeo I# X&rpsysk#y#j A. A. Tolstovyatois, M. A. Rumy*at#o*!,A#
Kh.@M. Minacheyt Yo A# terapoat IFNSR) six 71ectures on dehydro-
oyolisation - Be A* lasanskly# A. L. Libersan.@%` -11 oxonfatIf
tOEO X* Ot tortoT-4101h AS'USSR and
A. Ze Dorofi$gh nskly, Ao V. (IKh AS iru 31 _,rQ ULLY, korup
OroxNII)j Kh,. I. Arsehidse 0 SSSR)j KL-S-, 9#10n Ya,,P*S
(Aserb.in-t neftemali - AserbaldijhaD Ingtituts of Zetrolians gheal-IlAry)l _
K, A. XrulpennIkova, (X&ss,kh#gos.un-t - Kazakh State Univorgity)l 10 lectures
were delivered at Section 5S YO. M. PIS-Fu-no-va-, 0. X. Boreskov, T,A,Dv1vfkO
(Physioaahesioal, Institute Imeni Lo yao Karpov)l Tu. K. Bakabi A- 1.
0911bebt v 7. T41MI04ft (Pbysloothemical Institute la*ni L. ;a. KarpovT
feint
As M# . Isagulyants (INKh I OP 1z.,Gubk1n&)1
Rabove as 0. - A# Rasuvaj a *@ To It Ind isnova$ LJ4_j=t (IFKh AS USSR)j
Vk-B-shloshevskiyj A,,A, Tolatopyatova MSU)j V. Ia. jakwohl a 20
footures-ware 3slivered at Section 61 ju. D, Xer"Of B. . voldalre
(VNII.Sertakh1m)l 1, 1. Povoyal Yes To* Vorsell I V. W.'
Millman (lKh V3? At SSR)j L, Ia. Margolis V. Ia. Rubanikl A._oG*ra
Ir.1 -7*--rios (MI oftekbia)
gorin I?Xh AS UkrSS1)j B. L. Moldavskly, Y
V. A. Slavinskayat 8, A. 01114r, 1. 1. Idffe (109h AS L&tSS1)f M.I.Teskino
N. V. Kulfkova kPhylercoosvnfcar, latvf"t@ *nrT-. Y.. X v); L. Ia.
Card 5/6

All-Union Conference on Organic Catalysts S1295. %0/001/001/007A-07
in.Hosoow BO 155060.
Margolist I, Kh, Yanikoyall 00 V., Isayevo V. ao Lindo (Inh AS USSR)j
Os P, Kornoychukp V, A# koytere P* Usbakova (IFKh S,UkrSSB)# K. V,
Kilmova, Ac_1#_TjGhohqnkog I - I. Iorfe k1tOPIK).,?robl4z% of tschnical
catalysis *or# disou-0mi-eW at the final Plan& ma'ating. Among tho leoturors
wares Oe to boraskov and V.*,, S. Chesslon (Ph 01000hezIcal Institute Imanl
L.;Ts. Zorpov)l V. A: Royter (IFXh AS UkrSsall U. 0. Slin3ko (Inlatitut
katalize, 80 AN HIM - Institute of Catalysis of the so As USSR
Vallkovskiy (MITKbT)i 1. 1. Torre JHIO 1 0. U. Todes (VIT"V
V. E. Aeror (NIISS)l X. V. Shumilovskly ( RI). In the course of the 170n-.
ferencet sever=& organ measures fo-bo taken for the Intorsiflea.
tion of work in@ the field of aqWo and toohnical Patslysis were agraa4 ui,.-n
.82ong with theDnecessity of a r*ferono* work lt4iostlng tto applicatlo.:b
and properties of the principal catalysts, It was deeldod to hold anAll-
Union Conference on.testing methods of Industrial oatalysti for hoacgotecua
and oxidation catalysis in the near future. The foundaticn of the InstItut
kataliza Sibirskogo otdol#hlya 0 SSSR (I"tituto of Catalysis of Ith't
'Siberian Department of the Al USSR) in NOVO sibirsk-iwas noted with natla-
faOtIont and so was thi public on of the now periodical "Xinetilke. i katalle.
SUBMITTED: December 1%, 1959
card 6/6

------------------
candidate of 8/030/60/000/02/031/040
Chemical Polonces B00812008
TITLE# Problems of the Org&41* Catal sis@
L
MIODICALs Yestaik Ak&d&Sii ZSVJC $SSj 1960, Ir 2, 109-111 (OB81)
ABSTROTs this Is a report an the lot k1loUsion Conference on the Organic
CIA41:8141 hold in Mocov tros I*-v*nbsr 16 to 10. Ii w" convened
V7 @4 t Out orlsolahookoy Wall Akadeviii sauk OUR (IRA tj
hasiot 4f, %be Academy of Solegoos USSR) jolifly with
f Orsanio'c ry
---Trio 11auchao-1441440VAtO 'Okly Miko-khIMIGhOlkly LOStitut In&
L. Ta. W#61ra (Scientific Mdoo-ohoulool Research Institute
Iasi- LQ @ X6 9, UE LOVT-and the kbialabOokly fakulltet Nookovskogo
universitsts, apartment of Chemistry of Mosog!- WvvrelAY),
About 600:dologates.ottanded the Conference-& 160 lectures were
hold altogether# 18 of then in plenary sessions, 8 of the letter
dealt with theoretical probless of organic catalysis and 10 with
toohnio&2 catalysis. Th* ranalaing lectures dealt with the
investigation results of catalysts and with various reactioraso
The Conference was opened by 3-,---A. Itasavokly. A. A. Ulundi*
reported in his looturs, an t1w corrolatio-a-betw;;n ts; ity
and the structure of the molecules and gave a survey of various
card 1/13 catalytic rosotional, starting from the sultiplot theory,

problems of the Organic Catalysis 8/030/60/000/02/031/040
BOOS/BOOS
8', ago lost k1Z_ reported on electron mechanism In organic Chemistry.
P, I. Tallkonghtay reported on the relative content of chealoally
adsorbed substances on:tbo surface of sodoonduoto". Aj 1" Tors"11
and 21 arted on the investigation at Abe surface of
oxidative AT,%V-611,2111a catalysts by somm of 11-spoctra of adsorbed
2014culess X# P. 14yer 4 sit with the Influence of the
reciprocation on the activating energy, q# Lo-lipegIlLast I* JL*
Vsyydo reported-on be computation of the activating energies
the hydrogesolysis of astbYlenineland fivo-senbered cycleG* TO* to
Slatumovskly reported on the possibility.of applying the
atereospecific catalysts on quarts-catalysts for the determination
of the absolute configuration of noleaul"o Is the coast of a
discussion# X. A., Landau reported on the rules in the catalytic
16 tivitiss of a MSer _0? catalysts discovered by bin and To 10
3 k1u., QeXt Voresk2X and To So Chosslova report*& an
production Methods of Industrtal oaMysts. T. A. Ralter dealt
with the methods and standardization of the testing of astalystao
Is Go R elk* reports& on contact apparatus. 1. 3, Fallkova
And jgdV reported on lootbormlo coniaiwass im@
#j., IWO, ppe,
glad computation Seth ds for the processes takinS piece 40ithis the
Card 2/3 diffusion range* Is 1. Shumilovsk!z dftlt with the automation ot.

Problems at the organic Catalysis 8/03OJ60/000/02/0)1/040
.100013008
catalytic process", the Conference opprov#d th& activity of the
Sovet po nbuohas *#novam podbora katellsasoroy (council of
Scientific Fundamental* at the Catalyst 20206tion) and-exprossed
the wish to Intensity largely the work in the field of technical,
extallsis. It was rosomasuded to sonoontrat* the production at
catalysts In several works and to establish their moll equippot
work #actions* the necessity to publish a catalog at the &*at
Important catalysts product to the YXS1 was pointed out In ths
resoluktax, It was @ found suit&*2o to belt ) All-Uniou Meetings
In the near futures these are to deal with'testInS methods tar
ladvAtrial catalysts and the homogeneous and oxidative catalysts#
card

61062 6010001OV611004
80049DOC6
AUTOMSs Balandin. guys I*# If#
119=-Ad .42Z
0
TITUs Thermooh4mlool Determination of Combustion seats of
20ftZI.Pyridineland 2-Tinyl Pyridine
PnIODICALt lavestlya Akodeall n&uk Son, Otdolonlye khiaiob*skikh
naukq 1960# NO- St PP* 784-786
..TXXTs The purpose of the present paper was to obtain thersochomical data
for the calculation of the thersoahemical-equilibriumva. .'he "tal3rtio
dobidroffenotlon' of 06BOY5 --6951CROCH 20 the experiments were
oarried out in & now calorimeter designed by J6 Ooops ot &I* (let, 1)*
Combustion took place In a tomb, calorimeter developed at the Torml-
ahoska,ys, laboratoriya Lae To IN Luginins, Nag (Thermal Lolboratory.1mani
1. P.-Lusinin of Moscow State University). The measuring toohniqu* is
described in a paper by So Me Skuratov at &I, (Ref* The oaloriflo
Card 1/3

Beats of 2-2thyl r7ridine and 2-TI#yVPyrIdins MZA066
value of the cAl6r1SOt*r-,N*std&:v&s determined with an adearaol of
0"03
0*02 por,osm b 800S.,oUbinsolo &014 supplied br Tsesojusay7
na,uchno-Issiodovatel's I too D. L Nendolsym
% titut astroloo
Y, fig
(I VMOV" eat I* *search lastituts of Netrolo" 180al D. 10
Nondeloyev) -Because of Us easy polymerlsablIlty or 2-vivyl pyridinst
.--Us substances investigated wste@prepsr*4 Ims4lat*ly before ocabostiono
distilled$ and filled4nto:ampulse Special attention was paid to the
purity of the eutstandes.-2-othyl pyridins was obtained by hydrogenation
of 2-yinyl pyridinep whloh:rssulted from condensation ofa-plooline
with parefonaldshyde W tram. dehydration of the resultant alcohol on
alkali* the physical data of boti substances are compared to Table-I
with data available In publiostions, When calculating the combustion
boat (at 2500)9 all corrections necessary were considered (Regnault-
Pfaundler-19sov forsulat correction according to Be We Washburnp Isfe 14),
Table 2 gives the f2llowiag data for the two substanasse beat of con-
bustion, chaw AV-7 of enthalpy on combustion with molecular
liquid
oxygen at i ats to form 0021 1201 and X2# The formation beat of ethyl
pyridin* was found to be 0669 kosl/mols and that of 2-vinyl pyridins
Card 2/3

PATRIX3ffV,p T.T.1 DAIAOIN. AaA.. akodomikI.17ABUM"NIT. To..I.: NUMSM.
Yu.8,1 RWIMYA. 0&1.
SolectivIty towards optical Isomers of adoorbouts fromed In Me
presence of bacteria,, Vold.0 SM 1132 no.4:860-852 is 160,
Oau 3:5
I* Institut organichsokoy thiall is* N.D.Zollnekoge Akadoult nauk
(Adoorbou to) (Isomers)

8/195/61/002/001/001/006
SIOI/Z216
AUTHORS: Balanding At A.# Klabunovskiyo Ye. I.
TITLE, Steria position of &toast and catalysis (on the occasion.
of the 1004h birthday of No Do Zolinskly)
PERIODICAL: Kinottka I katalizi v, 29 no. It 1961g 3-8
.TEXT: On the occasion of the 100th anniversary of N# Do Zollnsklyos
birthday# the authors give a survey of probloss of catalysis and
siorsoohemistry# which had boon studied by Zolinskiy and further
investigated by his successors, Zolinakiy "do detailed investigations
of the stersoisomerion of derivatives of di- and tribasio organic &aide,
and studied the optical activation of crystallization of dimethyl
dihydroxy Slutarto uid, Basing on stersochouloal oonelderationst
Zolinskiylrrivod st,the following concept of heterogeneous catalysis:
"The deformation of molecules ooours,under the Influence of the force
field present on the-aotive surface of the oatalyett this force field
Influencing the configuration of particles and rendering them ready to
Interact From this concept# A. A. Balandin developed his multi lot
Card 1/3

-

I
A

,

0

'ANrIKj LA.) IMAOMMI Y LOPATIHO B.V.1 PETUKHOV# V.A.
BAIAXDIHj A.A.1
Synthesis &W transformations of dihydrodioxotribanzotriptycerse
Isy. AN SUR Ur. Mix. no.7tl260-1267 JI 064.
(MIM 1718)
1. Institut orgwdobeekay khlndi imenl Zelinskogo AN US&
IMME

ACCESMON MR
A@rl"'FIOR: 2aabunoyakLy, a.
TITZ: WIoally activi Z=@_rsltftsed on' e'e'tem of--M QUU and itaconig-
acids
SM= VysokowlakulywUM 4Qy*UUenU%# v6, no 39&, IW-142
TOPIC TAGSt,a,cwt*rj usermolmajUr cheadstry, polymarizatAca, opUa Vr0V6rW#,.:".
optic Lothod
clymers, (#)-pot y-2-mthyl butylusths"71&
AAVMCT Optically aativ* p to
(-)-PQl-/=thylfteth&cry1mt*, and (#)-Po1y-dL-(2-mthylbu@.y1) Uscomate
synthasised by the polymerization of the corresponding optically
active ester* of matbacrylta and itaconic acids. The optically settva
@*Iymara were synthesized by free-radical polymerLzatLon (eatslyzad bry
banzoyl peroxide), anionic Voly=erizatLon (catalyz*4 by phany1magnesium
6romida). and thirvol polymrixatLon (by heating to 2000). Their prorpertLea:
'pnLng point. specific cotatLon, and intrinsic viscosity) va" Lftvaati-@@
jste6@ Mis polarosistric watbod vas shown to be suit"lo for the study AU
Card 1/2 06

7 -
4
Acassrox ml
pol)zerisation klnetLcs, using the polyw*rLsstL*n ot (0-2-mathylbutil
moth&cL-ylat* as an exAmple, Relationships were faun4 between the specific
cotatiqn *o4 the ttma, d*Sree of polymovisati6a, &ad aolocular weight.
OrIg. art. h"., I CbrwAl&p k gmpMp I table.
ASSOCIATIONo lustitut orgonlolmokoy khlati in. N. D. Zollaskago AX SM
(institute of Orovaie ChisaLltryo AX MM)
snxrrm t o3oo43 1=1 00 SM OMM I oc', OP
10 REF M 003 018 im
Cwr,d 2/2

ISAGULYANTSP O.V.,j MRMMZV, Tuol.j KIABUMOVSKZY, Te.Z.; SAWDIV, A.A.
Mechanism underlying the catalytic dehydration of 2-butavol
on the surface of aluminum aides Isv. AN SSSR. Ser. khIx.
no.6085-W Js 164, (MIRA Vill)
1. Institut organichookay khi*.U im. N.D. ZelWkogo AN SM.

XLABMVSKIYO Ye.1.1 AXTlXo LoV,; BALANDIN# A.A.
Polarographlo reducUon of dihydrodio"tribensotrypticens
in dimethy1formaidd, lay* AN SMR. Sor. khis. no.StI412-
U16 Ag 164, (MM 17S9)
1, Inatitut org&Moh*xkol khWi is. N.D. Zelinskogo All SSSR.

IALUMIX, A,A,.t MAkEDZADE, R.Yu.j ANTIK, L.Y.;
I;i!Ao
DepmWenes of polarop*phla charea tarl a ties on the stmoture
of quinoass of Lbe,triptycons verlos, lav. AX SSSR, Ser. Min,
no.&1554 Ag 164i (MIRA I?tg)
1, Infititut orgwacheskay khisli Is. K.D* Zolinskogo AN SSSR,

KLADUIIOV$Krrg U,Z,; -'HVArtTSW#' M.1.1 PETROV, Yu.1.
IppIleation ef optIcal rotatory dispersion In the study of th* strub.-
ture of aptIcally acti" polymers. Vy9okcmsoed* 6 no.9sl579-1584 S
164. (MIRA 17110)
It Inatitut arganichoskay Wait Smad Zeliaskogo.

I @ . I! @ @ v. -.,-
77"l-alm 7-77, 71:;;? @- ., !- @.

betvOi Ago #k"" is cv6wa
L Kisbukil, "d U
"MO O'natuiri ILIG11- CAL-COW. COVIVA-2t-0-104 Mod.
'Var. Ma. Vigil, USS&PA. a pAkuk. It. tt";'CimxIt.4j-
IU14 th* *4kv^Wk-I lwtkld
d"Wiek ir rm ra q*%Ai @vd. (ii-
0 V a 'd ftj) lw,*% wl-lmar@i for I j da" to cumes
'd 410 NIP 1-ir -1
C-4 11'.. &Jpf-k.' .4 'iyw bv qwt'Ajm.
'mIII-jpvTmI' w'(tV'j."v -*1 &.4 .
"Am@%Ivm C%f vid-ryl," r4.. Nh R,
.Ulf I IfU1111-31. IKAI
n1flifimM Im-1444) by r,&v

t tho f-F
-I
4 44 Ji @,l pw.17 t
it foolol S3 hw,rm@j ( ), r 1, it@ I- J
hr-mip vil, Aut,41mi 1@.,rjp w.i-l 'i. A-
kttM, 4 1"t L,, -J- -i
if ju
Awlaw C24f", wort t f(vome4 C@ Allow .k4. P@-
*Ikuhflk (0.3 I.,dw wt
m t,4n i he t mrA CT-t
MAN jw%vkA** (cmu by , I'D, IPAh dr,f WAV to
camlikuwL.61:71" %kn&A" VVVILWAat fl*AjIJ - 7.7 1)
IWAIA

4 , . I

a

A

AwfuKV-1- I TMTSLT# 1.1 ILI me
Coutribution'tO the Sool-also of spreading f"tor aativity,
,dorlpts mod*$ Brno 27 soo3-4l6l-69 1954o
L 2 to Ititani klidlW a farmtolo ustavu lok. fake v Olowouelo
Prednostat prof, Mr, PUklI KUDP JoLenfeld.,
(WAMROEMASIO' offset@
on spreading@ usehanles of sation in rabbits)

7-1 Lz.1 r-PIT If-IT

-rN -IT -@L-l

% flu
law ba or
-
dmFn, wAe4.,$hm4w
0
0
'
M
OM MOM jS
tWbbW"
04 scout*

Im *v* "0 aw low keAbdog sows.
.00%OVU JAPILO XA&* &V*T WAMOW& VsMOUGS
All ImGf44*#

kit

HOW
.

itz
ll
a

if tylowemise and
ener$wlitat arthritis I first assmaisation.
Tailro Jokbi Proo I soj4dW253 Apt 55.
1. 3 1, vulirsiklinOW a far makelo glakeho ustavu Iskareks foultr
T pr6f WDr P. Wd, OlIr J. lonfold
Olowmat fter, Ingermm 10,
off, of 2640st ML & NON-sis
-maphtbrIamise In rate
(11"Wil xm2wes amell
N,Jl-'bii(2.;triahlor6otbrl)-2-saphtbyl&"So &
triGbIftetbrIodso on exper. arthritis in "to
Noil-tio(2-obloroo%tWl)-2-papbtlwlanlao, off. es'exper,
Arthrisis I& role,

Weabaulss of anti-r1he-atic effect of nitrogen mustuds
Valtr. Isk., Mrso Ino.M843-850 Nov 55.
11 1 farmkologickelho ust&vu a L vultral klinOw Isk. take
PU v Oloamol$ produstat so ste do@* Wro Jo Unfold, prote
WDr. P. takt, Mr. L. Ift,l 016mows Plarlingerova 10.
WIMOU RMAnds therspostic use.)
offocts,
on eswe rbam. artbritlej
(AMM2181 RMUTOIDI aperimental#
off, at nitrogen wistarda')

MATUT, K.,; VADUSAYs lo.9; nOUTIL, N.
?be role of vessels and serves in "ti4alurosidass sativitre
Acts, made hund* 7 no,3-41279-285 1955-
Is lot depatmost of qadiotae &jA the department of pbarmscology..
PAII61W University medical school# Olomono,'Asochoolowakta*
(11YALM(MbAUs antagonist$,
off#$ role of norwoo A blood vessels)
(MWWS Err=. PIWOL010a.
anti-braluronidass action, role In off. at various
(CARDIOVASCUIAR MMM9 pbqotology,
some)

el

A,i

o
*an*
"4
"4 Z'
t
uwir,
goo
*S*jk 04
94
k onarA
MWIP4 a"
T?* Ott, fmm C.
the It "kas
ft" -bed
olvix ot aw" to samw*vt
lir- W.'d
ft os @
two$
loadsYs. laddr-
dwifts
04:2 =11 a
L (po kS,
WM 3
OL
hiamma
ot
r In
-
Wro*Lwm Skew to oft "o.
imp" Of

. 494
k
*
hit%* &&*"WtQwuw
I .@'

.,- .1-1:i@
Cjro@, -W
60 mWUsmd by the
IN im" i
@

swrm
4@M

. -g

C=WWAKWpharmcojoa. Todcology. 2harapeutic Drugs of BUY
mtIc Origin
ad jour t %f Zhur - giolep go lip 1958, No 52036
Author t tanfold J,j KIAWSAY L,
Inst :
TLtjo I Mwnidase
C.-ig pub f voyan..004. Zh. 1936, No lo 94
V
,%bstvact % Moniduse: (1), a protein preparation from bull's tostieles
ressessof byalurooldwo activity. I-a holxWWWO finely
growd pouder of light yellow color 18 rGOOMOnded,for ex-
ternal application In ulcers and Dupurtren contractunsp
dhrordo Indolent ulcorsp etas It to a"nistered daily
for periods -of 1,5.6D days according to tbo effects 20
do" of adtAnistered I Is deterrAned by the am of the lesiont
I is spread on a sterila pad of Fuze* molstoned by a ster-
ile solution and to applied to the lesion; the 1puza to COV-
ered vith wax paper$ 2110 aftl1nistration of I Is coatruLa-
dicated in tuberculosis wA mlignant twors.-- D.A. Bystrolotov
Card 1 1/1
aw"O iwy oxicalo pifforent PrOrArations
PhArmagolow 0 T or . . .
g. N,,. 56767
12
ti,,a of
flaming art the Vscro
me* of Trialstoreth) on of the secbectifM Of
iThe oids, (The Prob, r
Active 11.0XIster 01061)
Acti6ft in 11hou"t - 21 ^0-124 1075-1081
:vni-tri Lokarst", 19* Val.
urine Of-
zo. in th
Yateroids 1,8
hot is
of '-a% .(Patio
r*
Ini 0
n a;,x as Of
at
I a 91 4i . wil , t 10 a roSressivg pallor
or _,tciliti with v
othylsow (11 aw to ilor content Of 11-oxisterolds
thrWe lod $0 a ouch . atrols. -Me duration Of
in the urine than it, the Cal of
of II.Oxygtoroide in
the
eightened *%art, hours, but only 2 hours
the COUtrolgrouP was 48 created admin'strat ton" of
toontal SrOUP4 Upon I f ll.oxyst*roids `0
its effects On,tbo o%crotion 0

g(MOMMAKWHumn WA Animl Physiology - Nmeral Problems V.1
Cz
Abe Jbur Ref thur B1014) So 2p. 1958) 8240
Author L. pod Trzavsky, K.
Inst
Title The Role'of #A* Spleen in amoral Replation
Orig P Ub Vnitral lakarstvi, 106p 2p No llp, 967-9U
Abstract A revisw Of the nev clinical and cgerimental data an tho
intox oft MA on the in-
vml secretory activity of the spi
terroUtionship between the spleen end certain g3axd of
Internal secretion (thyroid$. sq;rarenal &M pituitary
gums.)
Bibliographyl 26 titlese
ftrd 1/1

Abe Jour i Pa tZ
hor - Kole) So 110 IPO) 00 71068
.
Author i tenteld J U4usa L.; N%Ua&4 JS
Inst I a
Title UU-Neftfaitattafts

Orig Pub i (Wskosli 4*sibl 4) 1"6., 15), No 2i: 2.31-234

Abstract i BtOPOVWI.@ (8)a--VMc& ls,,usod
todrAW,trostboAt Of, &&-k 4 was adidnistared to Odnea
pip in a dosa of 0.25 kS na 3 *XUr 26 day-op
a 20 percent solutionor atawl 011c. (M) van tweated
intmPeriUmaW, ft a dos* of 1 100 is., (at the and of
the experiment) 2.@.WIOO g) to the soas antasUp ocas to
2 weeks during 73:days. Tvo veeks &tUr. tba last Injection
of V., a tdotologia oxmAnstion vas *treated. Mocovered
veres InJuries at the Uvor berivescalAr Infiltratesp Is-
crossed s4idopidlia, of the liver c*Us, wsrotic foci vith
, Interst,lual,
proliferstion.,wA Won)) Iddasys (bypermia
.
and perivascular Infiltratas)p and lwgs (in 50 percent of
C4rd'. 1 V,2
@rof-t,*IAIO 4.0 f- /C WPS ro z. of IC kO - 9,w VIO 4 0IC
wx-mv 4r, ?m

=CHMMAXWMarmoology Toxicology Various prepmmtions. V
Abe Jow i Rof 2hur Kol.,p So 4,, 1959, 18731
Author i Kroutil, M.# EeLfflm L.
Inst I a
Title i Pharsnoolo& Action of mconic Acid wA its Derivatives
Orig Pub i Ceskoslo farrAa#, 1956, 1b 4; 226-230
Abstract i Meconle sold and others of moconle sold and meconyl-ures
do not Pooduc* an effect an isolated intestines.
Mwnyl-ursa (1) mA moconylth (rr) Induce a short.
YOUM
tim increase of the intestinal tonum of rabbit vith a
decrease of the contraction acplitude. The investigated
substances did not affect isolated utem. I wA o"Le
ally 11 postponed the beginning of convulsions in toads
In Introduction of strychnine. I In doses of 1 Goa
decreases Ahe blood pressure by 8-10%j In doses of 10
m&/kS by 50%j the effect is of short duration. Il Lndu-
coo a short-Ume Lnereare of blood poessure in a dose of
Card 1/2

Fharmwology - Toxicology - Various Proparatlors, V
Abe jour I jet thur ALol. 0 So 40 1"9, 18731
L 209 - to 40 Of the Initial one, In doses of 30 mg/kg -
-
'00 10-15%, In Animals Vith blood Presswe dearaued by
mmm of bloodUttings borth preparations In intramm
I
mtroduction In doses of up to 5 m#kg considerably in-
irease the blood prossurs. LA. Frolovs
Card 9/2

11;yfi t@ f RME

waso tA wilm 'A wup MAS.% to stwrtmeow bru rats
0 w 'T @U t(@o-.g -i
ltt@. ftri@ -4 -,4 14* -1 1-, 1, 7h, 'P-@ t t-t, .44
"ATTVtw" 1@hllwed thAA At i"I . - "- ,
ARti (-J@ jTt-ltjr,pf,t Wag qjq,.,J-f@@
t-'t
".d It
nO Pf"IrKi Ein tht 11 All

ff VEM. -Y

Problaw of llathal3@,y Inflaumtloud UO
Abe Jour i But Z11ur - Bid U.) 21) lZ0,0 0)62
Author Trnavoky, V..$ Sittajoa
q4 Klabusay,,. Le

II, aI ad f tWt4ltift on tA* Cam* of zxwiumv@ml

OrIC; Pub Vaitral Ukarstvij. 1953s 4., No 2j. 99-1030
Abstract t In ratep After d*Uvor,,,, inrImmation vus producod by fu-
:troeuction of forvaldlce;yco into tho poriarthric ro5ioz,
In a chronic courso of inam;.mtiono no diffm%nitintion.
was notod betwom nursuw, amA uon-=#IM anwals. Li
acuto inflacmUm, Cia courio of the -proca-3a to ozelor in
mlrvill@; MA savoro in Artificial tandnatio-4 :r 3AC-
tatiwt# Tho nost awworo courso of inflmmatim vu'd@;oor-
vod vith introduation of liropionato tastostomia into 4to
orticolds (1) VA42. rCe.UC*Cj
orLmdaus Socration or 11-o:qc
Card 1/2

DOUM.1o; ULIM,jo; XUBMAY114
Souroplegice and horeme In Um treatmat of burns, Aota. chir,
U0021,113,0239 19398
Xedical b8partmosto General Hospital In Ostrava (Cs*ctmlo-
wakia). ;&Sotors J. Cora$ No A, I Tho Jum Unit of the Depart-
sent of Surceryo General Dwpital Is Ostravas Diroctors K,
TYPOTAWSMA
IIUIMM thor.)
ULUMVICO A32VICUL tbsr,)
HOWOM tbor.

MUCXKS 14i,julwo L.
lboro"od levels of antidlurotio hormone In serum and of aldostorone
In urlas In Wno* 0eek4yelole 9 no.2s181-182 Xr 160.
Is lateral oUsleal a oddeleal pro Isebu popalesych 01to Ostrava.
Im "tab)
A%M2U= uriso
VASOPM81% tlood@
i