SCIENTIFIC ABSTRACT KOMISSAROVA, L.N. - KOMISSARUK, A.M.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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AP4046447 At the. stoichiomcLric rdLiQ Of begir.9 to Melt. the r e - n u m V. u r C. ti an -11 T -~n n n n 5a r---v ja Kafadra nearganichas o ~-Ic~-Mlml C h em L 1 -5 b46 7 too! ~,OTIR A, L.M. ! HM-! Is V.K.,; l3irpnr oxidea in thg syst~%r Zrl'Ll ~ttf. AN NeOT'91 Eau* 11-54 J1 165- T 7539-6 EvTW/ (C /E M (t /F_VP (b) TJP(c) JD/JG/1'.13 0 5 ACC.NR: AP50 5782 SOURCE CODE: TJR/0363/65/001/009/149311497 AUTHOR: va-, _,_,1$,jMen'kov, A. A.; Vasillyeva, L. M. .1 wam ORG: Moscow State Univerailx-im. M. V. Lomonosova (Moskovdkiy goauda.'ratveft-0- nyy universitet) i TITLE: Properties of scandium phosphide SOURCE: 'W SSSR. Izvesti:ya.- Neorganicheskiye materialy, v. 1, no. 9, 1965, 1493-1497 TOPIC TAGS: phosphide, 'scandium compound, corrosion resista nce, physical chemistry property ABSTRACT: Scandium phosphide Was obtained by direct reaction of metallic scandium an red phosphorous. The substances were mixed in powder form'in a d quartz ampoule. A table shows the detailed temperature conditions used for the, reaction. The resulting fine black powder was analyzed for scandium and phospho- rous. The articlegives a diagram of the analytical apparatus and the results or, analysis in tabular form. X-ray analysis was.done by the powder method. The x-ray photos were taken with a RKD-88 camera with filtered copper irradiation. Card 112 UDC:546.6331181.1 L 7539-66 ACC NR: AP51025782. The scandium - hosphide. obtained had a crystal structure of the sodium chloride p type with a 5. 3020. -005 M Z=4.- Its density at 20C was 3. 33 grams/cm3. The compound was thermally stable during heating in a high vacuum (10-4 mm Hg,). It underwent no polymorphic transtions in the interval from 20 to 1500C and did not melt up to 2000 C. HoweverS during heating above '000 C, even in a high vacuum, the surface of the sample oxidized with the ormation of scandium' phos- phate. In air, scandium phosphAde begins to oxid;ze oticeably above 350C. A sample held in air at 1200 C to constant weight, increases in weight by 7916 X-ray analysis of the oxidized sample shows the lines characteristic of anhydrous ScP04(scandium phosphate) with the parameters a=6. 576:L0. 003A, c=5. 7954: 0. 005A. The chemical resistance of scandium phosphide was investigated in water, acids (HCI,' H2904J. and HN03), and alkalis (2.5 and 5056 solutions of.NaOH) of different concentrations, Results are shown in a table. In general, scandium phQsphide was found to be realia, ant to water and alkaline solutions, but to be easily decomposed by acids. Orig. art. has, 2 figures and 5 tables S.11 COMIC/ SU13M DATE: MayO/ ORIG REP: 0031 .-OTH REP: 002 C42M 2/2 KOHISSAROVA, L.N. - ~-2~ .1 . The monthly rhythm. Trud[y rag. NIGKI no.6:56-59 156. I (Ibtsorology) (KMA 10s9) KDMISSARM), L-N. P - *I- ~ PNM I MW MLOrEATION 'AMOR: See table of contents TIM: Trudy Tseatrel'nogo Inatituta. prognozov (TrMmactlone of the Central Institute of ftrecasting), Nr 51,, Vaprosy dd1gosrocbnykh prognozov (Iong- -term Forecast Problms) PUB- MA: OWUNOtGorologicbeskop Izdatel'stvo, Leningrad, 1957, 150 PP-, 1,000 copies ORM. AGUCY Glavno" UPTATIenlYe 91drometecrologicheskoy sluzhby pri Sovete RDIM.- Ku skayao V. X.,-,.PjS&nVvkq&v V. D.; Tech. Ed.: Tlea.miray. 0. G., PtW,,OEM-. TUB collection of articles Is for specialists in the field of long-term weather forecasting. COMUM: MW Collection of articles analyzeo the rk-tbmicity of abiospheric proc- eafts~ #ad especiany thou originating in polar regions, and It evaluates the POSBIbUlty of using the occurrence of rbytbms In weather forecasting. Card. 1/7 sYnOPtic Patterns. There an 3 tables, 14 maps$ 2 diagrams, and 3 Sovlet references. Card 2/7 " Transactions of the Central Institute of Forecasting 387 Vitells, L. A. Solar Origin of Atmospheric Rhythms 22 The author examines the relationship between solar activity and atmoszj~heric processes and drmm the following conclusions: 1. Periods of Intensified solar activity can neither be aacribea to definite areas nor can they be con- sidered constant in their degrees of intensity. 2. Although rhythmic'changes in atmospheric processes are dependent on variations in solar activity, yet similar solar effects do not always produce identical responses in atmospheric rhytbme. The article mentions S. T. Pagava, K. V. Brodovitskiy, P. P. Predted=ddr, B. M. Rubashey (Pulkovo Observatory), M. N. Gnevyshev (Pulkovo Observatory), M. S. Eygenson, V. G. ShIahkov, and V. V. Shuleykin as the leading scientists in the field of studies of solar impact on atmospheric processes. Thera are 32 diagrams, 2 maps, and 26 references, of which 20 are Soviet, 1 Is Rmnch and 5 are in ]English. Isayev, E. A. Investigation of a Sharp Decline in 5eWerature In European USSR Comed by Certain Synoptic Processes. The author separates the occurrence of cold wayes In synoptic processes of the moderate zone of European USSR Into ultra polar., meridional and normal types and remarks on the role of the advection of cold air masses from the polar region. Card 3/7 Transactions of the Central Institute of Forecasting 387 The first chapter of the article contwlia general infornstho on the nature ok cold waves, and a nmber of anUcyclonic outbroaks traw1ling scutbmrds is analyzed. The existence of monthly rhytbmIcIty In ell tn?es of proeessed and Its application In long-term forecasts In the subject of the second part of the article. In the third part the author compiles statistical dats, on air temperature during the first six monthA of the year for Moscow, Voronezh, Pen2a, and Vologda ana he demonstrates the probability of recurrence and rhythmicity in such repetitions. The author defines the term *sharp" decline in tempera- ture as a decline of Thai average daily temperature by 50 to 100C daving cold seasons and 30 to 70C in wam seasons provided that such temperature I#se occurs within 1-2 days. The author concludes that in addition to seasonal rhytbmicity there are also monthly rhytbms of synoptic processes. The statistical data we to prove that a definite successive recurrence exists among the various types of air circulation and also in the location and dis- trIbution of baric fidlds. Consequently, the occurrence of certain types of synoptic altuatibns during a given period will allow the prediction of definite synoptic situations in the non-distant future. There are 11 tables, 14 maps, and 5 Soviet references. Card 4A Transactions of the Central Institute of Forecasting 387 Avanesova A. G., Kask L. L, and Yatlsheva G. She Occurrence of Selected Ultra- pplar Processes in Central Asia and Kazakhstan. 83 Me authors evaluate the efftacy of long-term veather forecasts based on the periodic occurrence of ultrapolar processes. The latter are traced along their meridional extent from some definite reference points in the North, i.e., the Barents Sea, Novaya Zemlya, etc. In the appendix,, 54 ultrapolar processes am analyzed and their reference localities specified. In sadition, the tabular material specifies also the occurrence of respective synaptic phenomena consequent upon tle appearance of polar air processes. The rhytboicity of recurrence Is repeated In Intervals of 3 to 5 months. There an .11 map8p 1 diagram.. and 4 tables., In adcUtion to 16 pages of tabular data in the appendix. All 7 references are Soviet. Goncharova. Yee F. Synoptic Conditions of the Exceptionally Co ld Spring of 1952 in Northern Caucasus 117 The average dally tenuperature in Maxch was 2* to 59C below the noTW and in April and May, V to 1-5*C- Similar conditions vere observed during the springs of 1945, 194o, 1933,, etc. The article analyzes these conditions. There am Card 517 monrau recurrence of conditions can be obsirve& -everY S. T. Pagava proved that there are also intermediate rhythms which repeat at intervals of 45-75 days. In the present article the author not only recBPitul- ates the work of his predecessors but also describes the nature Of such polar processes. The processes are traced from some definite reference points such as the Kara Sea$ Kolym, etc. The author explains the role of these processes card 6/7 387 synoptic forecasts and their low reliability. e appendi sYnOPtic Processes which may be similiar Th x contains data respect to their , differenti, Or reversed with 8 Soviet corresPondlDg Polar Processe J references, 5 tables, and a 9-p `4 There are 3 mapap 5 diagram, age appendix. AVAMABU: Idbrary of Congress (QC 851-IM64) Card 7/7 GC/bmd June 1958 -1 ~_ 4kk AUTHOR: Burkova, M. V. 50-2-19/22 TITLE: Some Remarks on the Paper by L.N. Komissarova "The Frequency " . , of Southern Cyclones Over Central Asia and Kazakhstan (Nekotoryye zamechaniya po rabote L.N. Komisearovoy "Povtory-, emost' yuzhnykh tsiklonov nad Sredney Aziyey i KazakhetanoW ay PERIODICAL: Meteorologiya i GidrologiYa, 1958, Nr 2, pp. 52-53 (USSR) ABSTRACT3 L.N. Komisearova treats in her work anew the problem of the origin of the southern cyclones which has been solved already a long'time ago by central asiatic synoptioians. The author determines 6 types of cyclones according to the characteristic of the regions of their origin. She determines the average positions of the frontal altitude zones for each,type and giv- es statistics on the frequency of the various types during the time from 1931 to 1951, i.e. the following typest 1) South- Aschchabad, 3) North-Caspian, and 4) Furgayek 2 -Caspian cyclones 5 cyclones of the Aral Sea and 6) Syr-darlynak ~ , cyclones. The division of the central asiatiC Bouth-cyclones into 3 main types, south-Caspian, Murgabsk, and upper- -Amudarynsk, which for long years had been subjected to an Card 1/2 examination, were completely ignored by Mrs. Komissarova. She Z~m~_ 7;~ 7n 0Some Remarks On the Paper by L.N. Romiss f Southern Cyclones over Central arOva "The Frequency Asia and Kazakhstan". 50-2-19122 AVA:ELABLE: neither tries her to the to compare the V,A. statistical data obtained by -DzhOrdzBh:aot1,snor0't00f SarymsakoV,T.A. V. A. Bu gyev, the classification criticize their ;r 9 and of cyclones inciple aerologiOal data in the - The exploitation a used for research of the Origin ofof th* iae&teP00h8nitaiaj fact Of KOmissarovat th the Cyclones literature in this 0 8 Paper. The ignorance of. to an inadequate representati see has led Mrs. Komie"rov& which have been worked out th on and to the repetition of facts There are 9 Slavic OroughlY already references. a long time. Library of Congress Card 2/2 MNM~ TSIRELINIKOVp V.I.; KONISSAROVAOL.L.N.; SPITSYNt Vikt.I., akademik Vapor density of hafnium tetrachloride at high temperatures. Dokl,AN SSM 145 noe5i1081-1084 162. (HIRA 15t8) 1. Moskovskiy gosudaretvemW universitet im.,M.V.Lomonosova. (Rafnium chloride) (Vapor density) KOROVIN, S.S.; MIROVEBKO., A.F.; REZNIK, A.M.; jq~~SSAFWVA, L.N. Extraction of hydrochloric acid and of certain elements by acetophenone, Iz7.vys.ucNzav.,- khim.i Idiim.tekh. 5 no-4:553-558- 162. (HIM 15:12) 1 1. Moskovskiy institut tonkoy khimicheakoy tekhnologii, imeni Lomonesova,, kafedra tekhnologii redkikh i rasseyannykh elementov. (Hydrochloric acid) (Acetophenone) SHATSKIYY V.M.; K014ISSAROVA, L.N.; SPITSYN Vikt, I. Precipitation of scandium hydrokde and ocandium oxalate. Zhureneorg&khim. 7 no.10:2294-2298 0 162. (MIRA 156-10) (Soandium compounds) (Precipitation (Chemistry)) YOMI'SARO)VA L. 11. met als., compounds' and alloys (rdev, April- 10,63)._:, 'SCURCE, ktomnaya ener i V 15'. 1 - 1963 266-267. h85' ACCESSION ii R' AP30 Sa metals and carbon~,'Mutu'ai: "solubility of, transitionametals. L. N. Komissarova and'others Investigation-of the'physi*cal prop-- e r t i e a o I-s-c -an-M erties o scan tm and its compounds. L. H. Kovba, V. K. Trunov, %Investigation of the composition and structure of tran-sition-metal.oxide compounds. A. P..Epik, Laws.governing*lthe change ofthe activation energy the toaction diffusion of nonmetals in refractory transition metalsi.- B. N. Oshcherin.* 'New for'mula's' for calculating,the.activation energy- of self-diffusion. The special equipment-used in the investigation of refractory.ma- ierials such as Nb, Mo-, Ta, W. and monocarbides at tem'erat'ures p above 2000-2500C.was described by A. Ye. Sheyndin .(metals)* A#'. Novitskiy (hard materials), and D. L. Timrot (all.oys and comppunds).", card 7/11 t FUSHKINA, G.ra.; KOMISSAROVA, L.N. ..................... Solubility of Sc(W03)3.4H20 and ScOH(NO3)2-3H20 in water,, in solutions of ni-tric acid, and in organic solvents. Zhur. niaorg. khim. 8 no.6t1498-1504 Je 163. (KMA 1616) 1. Mookovskiy gosudarstvannyy universitet imeni Lomonosova, kafedra neorganicheskoy khimii, . (Scandium c undo) (Nitric acid) omrsolubility) -601 Akademiya nauk SSSR. Doklady, v. 149, no. 3, 1963, 599 TEYT; The melting temperature and the thermal stability of SOF 3 as well as its interaction with MgF 2 in the molten state are investigated. The thermal stability of ScF 3 was measured by continuously weighing the samples in a temperature range from 20-10000C. A small loss of weight was already obsiffr~ ed when they _wer_e_,_heated_ to 41)00C in air. Above 6500C there is The Debye diagrams -of different losses of weight a aw'on y.,- the lines of the scandium. oxides aA Cf the fluoride, wit h no oryfluorides. The rate at which SoF becomes transformed into Sc 0 depends considerably 3 2 3 lete transformation requires 2.5 on the temDerature. At 900 aG.the comp hours, at 8000C 5.3 hours, at,7000C as long as 11 hours. The ScF melts 3 Card 1/3 4 at 1550+20 0C and undergoes &-.polymorphic transformation at 1350+200C. In the system SoF 6here is a narrow range of solid solutions between 3 2 0 anq 5 zlol~ ScF 3 whose existence is confirmed by the decrease of the polymorphic transormation ter-perature from 9600C for pure MgF to 8400C for ~2 al.'Loys containing more than 5 Mol~- ScF 3 ' Besides this, a decrease of the '.ati~ce constant of the solid phase was found if the concentration of S,-F I . 3 was increased. The SoF 5 and1the solid solution with MgF 2 formed a eutectic. The eutectic point corresponds to 34 mol57 ScF,, the melting o` tne eutectic mixture C. -h~-re f~--ures and ~!-S,DC :ATION: 1-foskovskiy gosud--rstvennyy uriversitet i.,n. Mi. V. Lomonosova (Moscow State University imeni !III. V. Lomonosov) PRESEN'~'M: Novamber 22,,1962, by V, 1. Spitsyn, Academician Card 2/3 ~j.CCESSION NR: AP4019495 S/0078/64/009/003/0603/0697 AUTHOR: Komissarova, L. N.; Wang, Ken-shih; Spitsy*n, Vikt. I.; Simanov, Yu. P. (D~ceasedi 11TLE: The La sub 2 0 sub 3-RiO sub 2 system SOURCE: Zhurnal neorg. khimti, v. 9, no. 3, 1964, 693-697 1'. TOPIC TAGS: La sub 2 0 sub 3-HfO sub 2 system, lanthanum oxide containing lz~ system, hafnium oxide containing system, phase diagram, phase transition, thermal analysis, x-ray analysis, specific electric resistance, La sub 2 Hf St sull 2 0 sub 7, structure, pyrochlore structure S ri, ABSTRACT:The phasi trans itions in the La203-HfO2 system in the 1300-2450C temperature interval were investigated by thermal and x-ray analysis and by measuring the specific electric resistance of a number of samples. A phase i diagram(fig, 1) was constructed in which the boundaries of several areas were -approximated. The formation of the,compound La2Hf2O7 and of solid solutions lord 2t C.,d AP4019503 8/0078/64/009/003/0 AUTKO-is: ?IonlkOvt A.A.; gomiggaroya 7661076? SOUROB; X-ray InvestigatIon of BoandIUM 104,40 Zhurnal n80ra- khlmllt V*q_ no*3# 1964t 766.767 T0210 TAGS: scandium 16didop preparation$ structuro,.x density ray-analysis, A3STPUCT: Anhydrous Scandium iodide Was preVared by heating a lo$ ex- cess Of metallic scandium with iodine at tooo In a quartz t" V1016t iodine va' crystallizes in a rh POZ"8 disappeared. X-ray Study eho,od ampoule un_ a = 7-939 o 002 XX ombohedral lattice With that Sol 2-85, z = the fgjlOWI (.Xz = 1/1,00202 ng ParaMetels:., quently 1. aSo 3 aMrozimartes the 0 = 20-360 h 0/a racterized by the R3 3 type atru * 0-010 -"tOrMltod by. X (C.L) Fodorov oture and COMM. -ray method:is-4170 and ykn 1131ty "Authors expre'O thanks to Z.11. grOUP, Sol. do '4 " o P is lytical laboratory for help Ill 4.63-g,2/cmj. 11OVb a~d k the X-raY ana.- table. Card 1/2 I ~ I I I I Card 2/2 NVOKOVY A.A.; KOMISSAROVA, L.N. X-ray diffraction examination of iscandium bromide. Zhur. neorg. khim. 9.no.7sl759-1760 Jl 164. (MIRA l7jQ,) KOMISSAROVA, L.N.1 POKROVSKIYp B.I. Magnesium-thermal reduction of scandium fluoride. Zhur. neorg. khim. 9 no.10:2277-2279 0 164. (MIRA 17:12) 1. Moskovskiy gooudarstvennyy universitet im. M.V. Lomonosova, Kafedra neorganicheakoy khimii. -SF A jl'~ 0 (364 0 CJ W,-i n T) V t7 t r+j V i s --a r ern, -S W I f I r ~a s PLYUSHCHEV, V.Ye.; VYURANOIIA, L.I.; KOlIrSSAROTIA, L.N. BaSic o-ApJtra".es of zirconium and h--Lfplun,. Zhur. neorg. khini. 10 no.3:643-64/6 Mr f65. (MIRA 18; 7) t /F,- T-T d 5 J ~l Z4 lo' tT a y rom tnorlum. 0-:lg art. tlas: figurpG and tab,,es. afe~,Ira neorganichesk-rw khimi! Most- -v,- ogr- ~e L; -i i SUBMITTED: ISApr64 TD 10 ENCL: - 02 SUB CODE: Card 2/5 1 22mawho"m - ~-*Mwmi-- - W ~Uar;wl l3fD 2iz~ ~ i -- 7 1 n. a o v 1k c, n L 1557-66 &V(m)/EN(n)-2 ACCESSIONUR: -AF5O22267-" UR/0363/65/001/007/LISZ/1154 AUMOR: Trunov. V. K.;Vlad1mirova, Z. A.; Kovba, L. No I' Komissareva, L. N. ry --theird sub-2 Nb sub 2 0 sub 5 system TITLE!- Dina --oxides-4ti SOURCE: AN SSSR. IzvestLyao Heorganicheakiya materialy, V., 1, no. 70-19658. 1152-1154 TOPIC TAGS: zirconium compound# ni ompound ABSTRACT: The formation of compounds in,the Zr02-Nb205 BZLtem was studied by x-ray phase analyzis. Two methods 'were used to prepare the compounds: copreci- pitation of hydroxides followed by anneatingat 1000 and 1300C, and annealing of. stoichiometric.mixtures of oxides.- Formation of the phase of variable composition Zri-nNbnOZ+n/2 was observed and Its unit cell constants were determined for various compositions. Three new phases were identified in the region rich In niobium pentoxides ZrO2-5HB?O5j ZrO2-7Nb?o5# and ZrO?-nNb 0 (5