SCIENTIFIC ABSTRACT KONDRATYEVA, A. P. - KONDRATYEVA, I.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000824220005-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: December 30, 2016
• Document Release Date: June 19, 2000
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

A,
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KORDRATIYNVA, A.F.; BRUNS, B.P.
Rate of Inactivation of phonozymethylpenicillin (T) and benzyl-
penicillin (G) in an acid medium. Med.prom. 11 no.12:30-34 D ~57.
(NIRA 11:2)
1. Yeeacquanyy nouchno-lealedovatellskiy Institut antibiottkov.
(FIVICILLIN)

KONDRATIYEVA,, A.F.- VAKULENKOp N.A.; TEBYAKINA,, A.Ye.,- BRUNS, B.F.
Kinetics of the Inactivation of erythromycin in aqueous solutions.
Antibiotiki 6 no.6:541-54-7 Je '61. (MIRA 15:1)
1. Vsesoyaznyy nauchno-issledovatel'skiy institut antibiotikov.
(ERYTHROMYCIN)

K010RATIYEVA, A.P.; BRUNS9 B.F.
Resistance of erythromycin in aqueous solutions. Antibiotiki 7 no.6s
53.1-514 Je 162. (MIRA 15-5)
(ERYTHROMYCIN)
TEBYAKINA, A.Ye.i RABINOVICH, M.S.; ZHDANOVICH, Yu.V.- STRUKOV, I.T.;
KONDRATTYEVA.-A.P.; BUYANOIISYAYA, I.S.; SHNEYERSON, A.M.;
Gk-GN,,S-kAAp DRUZHININA, Ye.N.
Alpha-aminobenzylpenicillin (aspicillin) and its microbiological
studies. Antibiotiki 9 no.5:.;~6,-392 I-Ty 164. (MIRA 18:2)
1. Vsesoyuznyy nauchno-issledovatellskiy institut antibiotikov,
Moskva.

FATEYEVAJ. M.N.; PROSTYAKOV, K.M.; TUZHILIN) S.A.; KONDRATIYEVA, P.;
POLEKHOVA, T.M,
Determination fat assimilation in gastrointestinal diseas(s by
means of 1131 trioleate glycerin. Med.rad. 10 no.3:11-16 Mr 165.
(MIRA 18:6)
1. Inst'Liut meditsinskoy radiologii (dir. - daystvitellnyy chlen
AMN SSSR prof. G.A.7-edgenidze) AIMN SSSR i klinika lechebnogo
pitaniya (dir. - prof. I.S.Savoshchenko) instituta pitaniya fil-91
SSSR, Mbskva.

KOITDR& I Y-b7A, A. S.
"Heat Loss in Heating Appliances Made of Smooth Pipes." Thesis for degree of Cand.
Technical Sai. Sub 25 Jun 49, Moscow Order of the Labor Red Banner Engineering Construction
Inst.1meni V. V. Kuybyshev.
Sumnary 82, 18 Dee 52, Di2sertatloas Presented for Dggrees in Sciellce and Entri-neering la
Moecow in 1942, From Vecherrvaa Ho&ya, Jan-Dee 1949

# A* S*
RT-1566 (Thermal conductivity of the-snow cover and physical processes caused
by the tenperature gradient) Teploprovodnost' snegovogo pokxova i fizichesIde
protsessy, proiskhodiashchie v nem pod v1iianien. temperaturnogo gradienta. Fages
14-28of:
MIKO-NEKHANIMESKIE SVOISTVA SNEGA I IhH ISPOL I ZOVANIE V AERODROMIM I DOROZIDIGI
STROITMISTVE lbscoV-LeniWad, 1945. 66 pages.

"The Heat Conductivity of Snow layers and the Physical Processes Occurring In Snow
Under the Influence of Temperature Changes," 1952.

KRAGEI.9KIYI I. V.; SHAKOV, A. A.; and KONDRATYEVA,, A. S.
KONDRATYEVA, A. S.
"On Increasing The Density of Snov By Compressionj" 1952.

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A Ewa" flat me SKMWM istaffulan of tjW aulakiols
of hVissom. 1. L. Stakaro, and
rrody lidoweats. W,skokbool. 116. 16,
. 7-MOM11);
Zooll&. 190. U. M.-The poWbility dirchnically
frevolikoll; the saw from Miter luisin". by rkviro-liall9mi. 6
wolIartmetal
;-t~tmmt twys" ow the Cif-CIA4 ilt tiorl"1.
SMAN& arvitmodsle In The coillontle conawtotacut to-
gethoir wilb ollwr cations M, Ca. Mg) ON malic anti
cifFiC WWO *"Mulsit in the annale crompattratent.. The
&WW& can be towd as an inioartiWole, the flmr whkili hs*
heeft kft4 team tAtt,-r ptincipk* (Pfutel" uWanct) can
lie uIled allibler few fimmil of as a raw material few adliviref.
The conallikoss of disiNs (choice of mentbrane. clafrent
Mfength. timit rvquifed) aM the courw of aim dialysis
with time) are diwautd, M. G. Moo"
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I-TAKARO, I. L.: INN-DRAMNA. A. V.
Vegetable Gardening
Pre-sowing treatment of seeds for vegetable crops. Sad i og. No. 2, 1953.
Monthly List of.Russian Accessions, Library of Cowgress, June 19n. UNCLASSIFIED.

MAKARO, I.L.; KOIMRATvYEVA, A.V.; TALIOVA, V.N., red.; TRUKHINA,
O.N.,q Vj~.
[Increasing the productivity of vegetable seeds] Povyshenie,
produktivnosti semian ovoshchzWkh kul'tur. Moskva., Sellkhoz-
izdat, 1962. 197 p. (MIRA 15:6)
(Vegetables) (Seeds)

KHRGIAN, A.Kh.; KUZNETSOV, G.I.; KONDItATIYEVA, A.V.; NASILOV,
D.I., otv. red.; VERSTAK, ---: ,
[Collection of articles] Sbornik statei. Moskva)
Nauka. No,8, 2965, 89 P. (MIRA 180)
1. Akademiya nauk MR. Mezbduvedomstvenn~y -k-ofizicheskiy
komitet. II razdel progrennW MGG. Meteorolohiya.

05693-67
ACC NR, AF6024~99 SOUK& CODES "20t&M69[0027dj62/638
AUTHOR: Yevotroplyev, 1. K. Sondratlyevas B. S.; Petrovsklyt G.
............
OROS none
TITLES Nature of the conductivity of beryllium fluoride-bass glass a
9g? 77
SCURMS AN SSSR. Dokladyt v. 169, no. 2p 1 1, 382-384
TOPIC TAGS2 glass, beryllium compound,, fluorides cesium compoundp electric
vns
ABSTRAM In order to deternlrA the t of current carriers in glass containing 80
mole % beryll1w fluoride arid 20 sale Kessium fluoridep a method was used in which
the conductivity measured directly was.compared to the-conductivity calculated by
means of Einstein's eauation from diffusion coefficients determined with the aid of
the radioisotope Cs 37. ginsteings equation relating ionic diffusion with electrical;
conductivity is X /D = X(se)2/ cg IT, i,
whWe X Is the con&wtivityp D the diffusion ooefficientp N the Sumber of Ions per c0
of'?glassp s the valence or the noving iong e the electronic chs
j - !jrg and a a miltlyll-
capon factor equal to 0.i:!&1, The conductivity provided by Ca Ions Is
XCs - 1.8 x 10-13NCsDC~/0.4 T.
L 05693-67
ACC NR, AP6024399
0
Comparison of cq)erlmental conductii
,~:V values with those calculated with the asswq)-
tion of transfer of electricity by Cs ions in cesium fluoboryllate glasses indicates
that the contribution of the cationic component of the conduction In negligibly small
(of the order to 1-2%). CaqmLrison of this result with data reported in the litera-
ture leads to the conclusion that the conduction in berAllum fluorlde-base glasses Is]
anionic in character. The paper was presented by Academician Tereninp A, V.# 4 Nov
65o Orig. art...hass 3 f1goeso I table and 2 fonmlaa.
SUB COIZI fi/ SMK DAM 280vW/ MM RVI 011/ OTH Wo 002

KONDRATIYBVA, D. (Ulnin).
~Mun-Vscbmm'.2 coast 3 (1930 leir.
(I;MA IOW
1. Antronamichookly'saktor AioL"zdi jui~k Letviyokoy SSR, R.J&.
(Comte--1930)

MAKAROV, V.N.;,NONDRAT1YEVAt-D.N.; TARAIFETS, V.I.
Mineralogy of supergene chlorito- `om shales of the
Yakovlevo deposit in the Kure' Magnetic Anomly. Sbor.nauch.
trud. KGIU no. 21:39-47 163. (MIRA 17%7)

MARTYNENYO, L.I.; MAKAHOV, V.N.; KUMETSAVA, M.N.; SOVA,14.G.;
TAFANETS, V.I.; DOMIM, D.S.; KONDRATlYPI -A, D. N.
Association of minerals in the group of iron oxides in rocks
and ores of tile Yakovlevo deposit in the Kursk Magne4-ic Anomaly.
Sbor.nauch.trud. KGRI no. 21:29-36 163. (YJRA l7t7)

MARTYMENKO, L.I.; ZINTSOVA, Ye.S.; MAKAROV, V.N-; KUZNETSOVA, M.N.;
KONDIRATIYEVA, D.N.;SOVA, N.G.; TARANETS, V.I.; DOMAREV,D.S.
Stratigraphy of the iron ore complex in the Yakovlevo deposit.
Sbor.nauch.trud.KGRI no. 21t24-29 163. (MIRA 17:7)

1,14KAROV, V.N. [Makarov, V.M.); KONDRATIRE-TA, D.N. [Kondrat'leva, D.M.)
Alteration of tourmaline in the weathering ourface of the Yakoviev
iron ore deposit in the Kursk Magnetic Anomaly. Dap. AN URSR na.l:
84,87 165. (14114 18.' 2)
1. Kr2Lvorozhskiy gornorudxVj institut. Predstavleno akadamikom
Ali UIcrSSR V.G. Bondavchukom (Boadarchuk, V.H.].

Ye.l.; KONDRAT'Y11VA, G.B.; OVCHMIZOVA. M.P.
Survival of the causative agents of dysentery on Tarious objects
in foci of infection. Mmr.mikrobIol.epId.1 tmmn. no-3:14-18 Mr
'55. (MIRA 8:7)
1. Is mikrobtologichaskoy laboratorii (say. prof. L.G.Peretts)
Sverdlovskogo Instituta apidemiologii. mtkrobiologit I giglyany
(dir. G.F.Bogdanov) I sanitarno-spidentologichaskoy stantsit
Sverdlovskoy oblasti (glevrqy vrach V.N.Bykova),,
(SHIMLA,
dymenterias, survival In various objects)

XMTIYXVA, VA.; IODNMATOY31TA, G.P.; MMOVA, S.D.
I--
Transformat non Of ~fata ~tyul~aro_organlxmz. Report lb.l: Decompo-
sition of fats during the process of dealtrification. ldkro-
biologila 29 no.1:8549 Ja-F ,6o. (KMA 13-5)
1. Yeasoyusnyy nawbuo-looledovatellakly goologorasvedochuyy
neftyanoy Inatitut, Noskm.
(ACMNDUCTIR ustab. )
(FATS wtab. I

MEKHTIYEVA, V.L.; KONDRATIYEVA, G.F.; 1=OVA, S.B.
Transformation of fatty substances under the influence'of micro-
organiarx.. Part 2: Study of nonsaponifying substances in experiments
on microbial decompositi6n of fats. Mikrobiologiia 29 rio.2:209-
214 Mr-Ap 160. (MIRA 14:7)
1. Vsesoyiiznyy nauchno-ionledovatello4y~~geologorazvedochnyy
neftyanoy institut,, Moskva.
(PATS) (BACTERIA 1. DENTIFUYIEG)

KOM)ROOM4VA, G.F..; GORSKAU, V.I.
Treating diphyllobothriants at home. Ned.paras. i paraz.bol.
28 no.2:236 Mr-Ap 139. (MIRA 12:6)
1. Is letonekoy re"blikanskoy sanitarno-opidemiologichookoy
Stanteii. (TAPINORKS)

KONDATIMA, G. P.
"An Approach to the Epidemiology of Diphyllobothriasis in the Estonian SSR."
Tenth Conference on Parasitological Problems and DiseaneB with Natural
Reservoirs, 22-29 October 1959, Vol. 11, Publishing House of Academy of
Sciences, USSR, Moscow-Leningrad, 1959.
Republic Sanitation and 4idemiology Station (Tallin)

ENTELISI, S.G.; KONDRATIYEVA, G.P.; CHIRKOVt N-M-
Kinetics and mechanism of the initial stage of the polycondensation
of ter.ephthaloyl chloride with ethylene glycols Part 1: Relation
~between the reaction rate and the polarity of the mddium. Vyookome
aced. 3 no*1044-1053 J3. 161. (MRA 14:6)
1. Inatitut L-bludcheskoy fiziki AN $SR.
(Terephtbaloyl chloride) (Ethylene glycol) (polymerization)

ENTELIS, S.G.; XONDRAT'YEVA, G.P.; CHIRKOV, N.M.
Kinetics a"d mechanism of tha initial stage of polycondensation
of terephthalyl chloride with etbylpnp vIvool. Part 2: Tempera-
ture dependence of the reactior rate. VTsokot...
soed. 5 no.8:11.70-1175 Ag '61. MIRA 14:9)
1. Institut khimicheskoy fiziki AN SSSR.
(Terephthaloyl chloride) (Etbylene glycol)

KONDRATIYEVA. G.P.
Some problems in the epidemiology of diphy3-lobothriasis in
Estonia. Mad.parez.,i puraz.bol. 30 no.1295-98 Ja7161.
le Iz latcnskoy rempbulikanakay sanitarmo-epidemiologichookoy
stantaii (glavrq7 vrach L*M* Stepanova),
(ESTONIA-TAPEWOFM)

KaTMATtYEVAI, G. S., Candidate Pharmaceut Sol (diss) -- "A study of the microbal
insemination of tabletized pharaceutical prpparations". Moscow, 1959- 13 pp,
(First Moscow order of Lenin Med Inst im 1. M. Sechenov), 200 copies (EL, No 23..
1959, 174)

ZAVIYALOV, S.I.; KOND-RATIYEVA, G.V.; KUDRYAVTSEVA, L.F.
New path in the synthesis of steroid compounds. Izv.AN SSSR Otd.
khim.nauk no.3-.529-530 W 161. (MIU 14:4)
1. Institut organicheskoylthim" izeni N.D.Zeliwkogo AN SSSR.
(Steroids)

ZAVIYALOVI S.I.~ KOND!~LTIUEVA 0 V KUDRUVTSEVA, L.F.
Nov metbo' for the synthesis of steroid compounds. Mod. prooi 10
no.2s56-57 F 161. (MIRL 142))
,9v kbimli imeni N.D.Zelinakogo AN SSSR.
I* Institut, arra
ST&

ZAVIYALOVY S.I.j KONDRATIYEVA- r.-V-S KORYAVTSEVA, L,F,
,4-Dicarbonyl compounds. Part 12t Carrying out the nucleophilic
reactions of dihydroresorcinol and its derivatives in solvents
of low polarity. Zhur. ob. khim. 31 no. 110695-3700 N 1619
(MMA 14: 11)
1, Institut organicheskoy Ichimii imeni N.D. Zelinskogo Akademii
nauk SSSR*
(Resoroinol)

KONDRATIYEVA, G.V,; KUDRYAVTSEVA, L.F.; ZAVIYALOV, S.I.
Syntheois of 2,6-dimethyl-2-cyano-5-(p-methoxyphonyl)-l-
cyclohexanone. Zhur. ob. khim. 31 no. n:3621-3626 N 161.
(MIRA 14:3.1)
1. Institut organichaskoy khimii imeni N.D. Zelinskogo AN SSSR.
(Cyclohexanone)
I

ZAVIYALOV, S.I.; KQFW~YLIV *-GJ-
-Dicarbororl compounds. Phrt 15: Chemical properties of
P3-d.ichloro-lp3-cyc1ohexsdiene and its derivatives. Zhur.
f
ob.khim. 31 no.12s3987-3991 D 161. (KMA 1522)
1, InstMt organicheskoy khimii 4momi N.D.Zelinskogo AN SSSR.
(Cyalohmmd-I one)

ZAVIYALOV, S.I.; KONDRATIYEVAp_qoVj,--., -
Chemistry of dihydroresoreinol., Report Noo5s Chemioal proportion
and enol others of dihydroresoroinol and its derivatives. Izv.AN
SM Otd.khim.nauk no,8:1429-1434 Ag 160. (Km 15:5)
I* Inatitut organicheskoy Ichim'i im, N.D.Zolinokogo AN =R.
(Hosorcinol) (Inols)

KONDRATIYEVAI, G.V.; KOGAII., G.A.; ZAVIYALOV,, S.I.
-~~-D~icarbo~nyl compounds. Report No,18: Cheadcal properties
of methylene-bi&-Mydroresorcinol and methylene-bis-dimedon.
Izv.AN SSSR.Otd.khim.nauk no*8:3.441-1447 Ag 162. (MM 15:8)
1. Institut organichaskoy Ichimii im. N.D.Zelinskogo AN SSSR. ~
(Resorcinol) (Cyclohexanedions)

KONDRATIYEVAP G.V.; KUDRYAVTSEVA, L.F.; ZAVIYALOV, S.I.
Synthe'sis of trans-&methyl-5-(p-metboxyphanyl)-l-hydrindanone.
Izv.AN SM.Otd.kh:Lm.nax* no.3:526-527 Mr 162. (MIRA 150)
1. Inistititit organicheskoy khimii im. N.D.Zelinskogo AN SSSR.
(Indanone)

ZAVIYALOV, S.I.; KONDRATIMA, G.V.; GUNAR, V.I.
Synthesis of dibenzofuran derivatives. Izv. AN SSSR Ser. khim.
no.3-1:2086-2087 N 164 (MIRA 18.-1)
1. Institut organicheskoy khimii N.D. Zelinskogo Ali' SSSR.

- ----- - - - -- - ---- -- -- - - - - -
KONDRATIYEVA. G.V.: KOGAN, G.A.; FADEYEVA, T.M.; ZAV'YALOV, S.I.
et
~ -Dicarbonyl compounds. Report No.21: Dissimilarity in chemical
'behxvior of 2-methyl-'L,3-cyclopentadienone and 2-methyldihydrore-
aozcinol. IzvoAll SSSR.8-er.kbim. no.9:10'48-1653 S 164. (MIRA 17110)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR.

KONDRATIYEVA, G.V.; ZAVIYALOV9 S.I.
Reaction of cyclic -diketones with acetoacetamides. Izv. AN
I SSSR. Ser. khim. no,#.lOsl9O9 0 164. (KRA 17s12)
1. Institut organicheskoy khimii im. N.D. Zelinskogo AN SSSR.

TO KARSKAI A I K04,1D Pit I - YIEVA u Ir.
injury to the DNA st-ruct,,ura under the inf.Luence of ISrg-~: dt,'Se'~3
.f a . vitro. Radlobiologila 4 no.3:35,'-.359 "64.
c
i ~alrpDIR rays in
11. fnat.itut b1ologl.cheskoy fiz-4ki. All SSSR.. ?-Ioskva~

Iu. K. Inrlev, 1111. G. Voron-ov, I. P. Gragerov and G. Ia. Kondratli--,va., The reaction
of od-bromo-furanidine v,,ith the Grignard Reavents. I. p. 1M4
The tetra-hydro-furane-li-rl-ides in which'a 'M;logen rtcm is in a /-4 position
to an ox-y-en aton, reacts with the Grignard reagent to fM-,~ v-tzry siuggisl~ly ::,.:Lxed
magnesitvi-organic com,~ounds urlhich for t~e most t-.,vzrt ratim-n-.e vit!,. the opZnin-
of the c.cle into 0.V 74-tmmibmAed T-xlr,.~-v~
,:.-nd re&ct in !~,,-xt -'n tl,e nr1r7:!r:1 ti L;
The Lc-,m~*,nosov St!,tt- Univer!5ity in Iloscow, 11ol-Aer of Vie Lenin Cv:-.-er
The Zcjinnkii 1-0). of OrCUnic Chom., Seitemb;n, 22, 19-7
4f
SO: Journal of Generzil Clpe,,z.istry (US6R) 28, (80) No. 10 (1')~+8):

Pts
1. K. Vur'cv. G. Ya. Kondrit'ma, and S. N. l"nov
1. -'W-FMMV--Sr 'JY.(kdJ.
V. tAXIWnCNMV . A . O;Ziw). POU.
Sauk S.S.S.S. 72, W-601W.-bitsityl oxide with CI
SIMI in AftO (Butimm and G&Uup. C.A. 42, '017aL
pvt 46% of the 3W&m#, m. 66'. 5 g. o( whk' Ii. iftyAimd.
witim 21) 1. C40. 2u S. cuo. it) s. Fe filings, and 25 s. Ph#-
Nil. and the distillate wadimil mh 2 NX21001. XAfSOS.
alui HoO. gave 7670 13j. 94'. mV 1.4:17, 1,
dO* O-WOM# whk inkic "Itphide it yitklo the idduct.
only with CaO.N&,CO,. with volid NuOlf, ar with 44)~,',
N&011. only MetCO (4044%) is obt;ihml and no lurAn
deriv. in deig"ed. C.. 161. Ku~latvff

YU',IIYI"V, YU. K.; U, YAO 1- 1.
Furanidines
Simultaneous catalytic dehydration of 2, 5-dialkylam 2, 2, 5, 5-tetrELalkylfuranidines
with hydrogen sulfide. Uch. zap. Mosk. un., No. 132, 1950. '
Monthl List of Russian Lecessions., Library of Congress, October 1952. UNCLASSIFIED.

mad 2.54-
11111 rAHMe
P. A. AlAiMs. mrA A. A.
Dffhd INV Zhw. m/mAd Khoo.
C~m ). n.
"I" ptopd. by the Ockmard touto ftv~m
iclfiffi~:7 MW by *bydmbm of the Wed. bw
i W. wV MM, 4r Omt3; R.M.54we-D hvnokg (n).
prm"pd.Wmfwly.br7"e.*VI.4W.4:40,MI2. SkDi-
AM44 (M) WAS oraa Od= .
mM ZrIdd.
do lk
IS 1) by .W 1*11 tdbmmd b
_y42.8g. EtCHO
Pvwe b, 1190, sy IA dit 0.11M. hydrorm&W
owarpt to 2 bi 101.&4.0* mV 1 W2
it al. = I "k - "in":
l(olir.'b, Mlt tili,41213, (11*
0 It
at 26% 0 34&wh*: 0-
1. , Ar O.fi~7; at 1~9.,
aml al 4w. Pre at =I about
F 'I JA%"*
as bw
.10 1 smilarty, M at
330* -- li
term %?Iwo than can-
;iQ ev
a- lea N
lot" km w%M mw ablikind'
:,.LX"a nodwoo* p- With
otbw p I - doWaN by Moan p whick eppear
to lave
as wd " mm dbm.
G. M. Kowlew

Y'M'Y'v7' YU-. K.-, &NDRATIYEVA, -G-.- YA.-, A. 1.
Heterocyclic compounds
Part 36. Conversion of L. B.1-dimetbylfuran and L.B.1-dimethylfuranidine to
corresponding nitrogen-and sulfur-containing heterocyclic compounds. Zhur. ob.
khim. 2-2(84) No. 3, 1952
Laboratoriya Organicheskoy Kbimii im. fi. D.
Zelinskogo Moskovskogo Ordene Lenine Gosudarstvennogo Universiteta. 2
S09 Moe. List of Russian Accessions, Library of Congress, August 195.1, Uncl-

ec Compovin ft~] Ayi::;~2'
of si'~-
or, bydio'genation
,"Catalytic Dehydrog"tion of l;4-Rndoxocyclohex&w.
and 1,4-dibxr-:YcloiexA'ne-:in a Hydrogen Sulfide At-
mosphere," Ia. K. Turlye~v, G'. Ya.. Kondrat.ljreva, ,
Ye. P. Smyslova)'lLtib of .'Org Chem imeni N.. D. Zelin
sk-ty, Moscow Stwte:~U
"Zhur Obshch Kh-Im!'-Vol XXIII, No 4 pp 694-696
When 1,4-endoyozyclohexane ir,-'introduced into an
H~S atm over A-20 3 at 2750 dehydrogenation of the
oxide takes place and cycl6hexadiene-1,3 is formed.
Catal~rtic deiydrogenitioi~of 1,4-dioxycyclohexane
in'&n H2S atm, over AlpO7' also proceeds 'Only
224T49
to cyclohexadiene-1,3. The sulfur comp corres-
ponding to 1,4-endoxQcyclohexane, 1,4-endothiocy-
clohexane is not formed by either of the 2 above
substances under the conditionsof the reactions
~;U4T,49

The cjtt&l
I 4.dihyrdr of e an
y
rl- . C,
AbA.
t!va and r. p.
ugu.g mtrani..~ti.o
S- C.A. 47,2714d.
10, 1954
JL-L. it
:anic Cjj,~mjqtry

IYEVAJ
- ----------
Transformations of 3-1-dlm&thvJfn;;"
-,*,;
Kkint. 23, 8444J(1953); cf. CA. 46, 1J177b.-AfesC(CJV)-
CII(CN)CO,Ej.b.152-(l',xl 1.4-Woix I.M80,hydrulYzed
with IICI gave 11(~CCAfCsClljCOjFl, 75%, m. 1-19411',
which with EtOll-11CI gave 02% di-FJ rskr, ba 101', #1,7
1.49-33, dw 0.9936. reduced with Na-EtOil to 63% :.2-di-
mejAAI,4-bula%cdivl. b, 117*, nl~' 1.4513, d. 0.0739, Thk
(9-29.)wA 04g. powd.aluminositicatecal~lyst hmll,,l ils n
distil. gpp. to 180-90' gavt 95C, 3,74iondky1frootthrine-
(1), fh&4 OF-9*, nV 1'.4121, dr OW-IM ). I (MA X.) trl-44f
nt,rr AljO, in a HtS atm. at 350* at 10 dfole.4/min. gave 7:1()f?
4' hyl A ka bw 144-5- 4"" 11. 1111-171
Nus atm. at =10 "VC 4 1
MAJ., Ala 1.4.'Wil, r1w, 0,94'.rl
313, WrIP111110114" 011111-4
6. M. 1, r,-4al?f;fr

bA, and 3-t-49
yrroUdR~.-
Mt,-- J4.- d "y' aTZ-.-

catall* h-=-,fuwwion
92-2 ~A-,
Fl,
H-S
~Tllt - th e I
q"4tra~
m-c-,
theLa"
by 1vurtial ~atn~ c.- cy
lc-~Ctiom ir. t!;-- h,~

1:01111P,T IYEILL.4 G. Ya.
Dissertation: "Catalytic Conversion of Homolorues of Tetrr-h.,drcf--=- f-mmanl --r the Presence
I
of Almimba Oydde." Cand Chem "ci, Moscow Order of' Lenin Sta'Qe '17 '~'. ',(. Lcmoncsov,
.;o
22 I-lay 54. VecherrVaya Z.'Oskva, M scow, 13 May 54-
SO: SUM, 284, 26 Nov 1954

171 -/1
r
p Y'6-
III)WIRLD, Robert C - LUTSMMO, I.F. (translator]; KCCHMCTp N-K-s'
[translatoA ?O*L'STATA, T.P. [transutorb ummATimmA, G.A.
(travAlatorl; TOR171T. TUSK., professor, rmummiur U-NOWFT'go N.T.0
rodaktor;.GMWIXOTA, Ye,g., tokknichookly redaktor
(Boteroeyclic compowds] Geterotalklichookle soadinenifte Perevod
s angl4skoge I.I.Intseike, I dr. Pod redaktalel W.K.Wrieva.
Moskva, Izd-vo inostmnnol lit-ry. Tol.2. 1954. 432 p. (Mm 7:10)
(Heterocyclic compowAs)

MWIM. R.; WCHff]ODV,'N.K.[ translator]; LUTSXNKO, I.F.Ctransiatorl;
NOCUTIMA. G.U.Ctranslatorl; TURITU. Tu.K., professor. redaktor;
OWM . Mowe# relaktor; GMWIMVA, U.S.. tekhnichaskly ro&aktor
[Hatercocyclic compounds. Translated from the Inglishl Geterotmikli-
chaskie,soodine'nita. Pbd red* R.Illderfilda. Perevod a anglitskogo
N.K.Kochatkova,*I.P.Lutsenko, G.U.Ionlratlevol. Pod red. MI.
XUrteva. Koskva, Izd-vo inostrannoi lit-ry. Vol-3- 1954. 357 P.
(Heterocyclic compounds) (MM 8:4)

K4
MBRiGhemistry Catalytic, conversion$*
Card 1/1 Pub. 151 -33/42. ,
Authors Yuryev, Yu. Ks, and Kondratyeva, G. Ya.
egg '7
Title Conversion of 3,4--odimsthylfuranidins into 3,4-dimathylthiophane and
into 3-,4-dimethylpyrrolydine. Part 42.-
POri6d1cal j, Zhur. obl. khim. 24/9, 1645-1648o Sep 1954
Abstract t- The.corriersion. of 3i4-dimathylfuranidine, in which both Methyl groups
are in beta position at in the case of 30-dJ*ethy1furanidina, into-
homologous compounds of,the thiophane and pyrrolidine series,, is de
scribed. It was found that the conditions of catalytic conversion of
o.Vgen-containing heterocycles into cycles with other hetero-atoms are
the most,favorable for the conversion of dimethk1furanidine., The'zm-
logy in the be'havior of these isomeric gamm-oxides cohfirms the assu:rp-
tion that the all(~l �ubstitutes at the beta-0--atom of the furahidine
cycle have little or no effect on the coftversioii process. Six.refer-
ences: 5-USSR and l-GezT,= (1886-1953).
Institution - State University, Moscow
Submitted v March 17, 1954

air -;L
Robert Go; REMY, 0. A., [translator] ; WTSBUKO, I.F.
~~V,41 [ translator] ;KDCRVM6V, N.K. [translator] ;KOIIDTRAT 'TWA. G.Ta.
[trans lator];YURI TXY , Tu.K., professor, re ~;r-, ~SJwA6VO,,,,IuS
redaktorl OGANDZNMVA, N.A., redaktor; GERASIMOVA,Ye.S.,
tekhnichodkly rodaktor.
[Heterocyclic compounde.Translated from the 'Anglishl Geterotel-
klicbeekie soadinenlia. Perevod a anglitskogo O.A.Reutova, i dr.
Pod red. Iu.K.Iurl,eva. Moskva, Izd-vo inostrannoi lit-ry, Vol.
4. 1955. 538 p. (HLRA 8:11)
(Heterocyclic compounds)

-
-k
1

-
ti
Al
------------ r-,r7 a-,Tr-f-,r K.

I!
xt'
e7l 71~ltf-ll
FM

-L
! - 1
-4 f
t , "!
;,~ri~ f,:
IV I-

-- . ~ :; i.~t-l~~ll,~~~~,g~t-.iL----a:t2Es,-,-mRrigK~~~ rl-i~;zra4~rwn,~~~;.~,"~K;L4-~tIf 1-1
~ I . I - .-, -~l -i' " - 1.
.I,- i ,-, L r - - - - - -- -
.I
!h.,c;j,il. -,:, 4 ;: ,:~ ~.: - ,l-- . ~. . . -

IJSSR/Optics Opectroscopy. K-6
Abs Jour Referat Zhux" Fizika, No 3, 1957, 7854
Author Akishin, P.A., Rambidi, N.G., ICorobiXsyna, I.K.
Kondrat'yeva, G.Ya., Yur'yeva, Yu-K.
Title Raman'- Sp-ei-ciiii of ffeterocyclic Compounds. II.
Orig Pub : Vestn. Mosk. un-ta, 1955, No 12, 103-108
Abstract : Raman spectra were obtained with a photometric estimate
of the intensity of the lines of the following compounds:
furan A 3-dihydrofuran, tetrahydrofuran, 2,2,5,5-t-etra-
hiety1furanide, 'en~ 2-dl-*hyd--opyrane,tetrahydropy-rane, and
1.4-dioxane. Comparison of the spectra and of -the litera-
ture data made it possible to establish the characteris-
tic frequencies of fully symmetrical oscillations of these
cycles. The integral intensities and the widths of the
lines were measured for these frequencies. It was esta-
blist.-Led that the intensity of the band reduces regularly
upon transition from -the Gofter to tile harder cycle:
Card 1/2 - 79 -
USSR/Optics Spectroscopy. K-6
Abs jour Referat Zhur - Fizika, No 3, 1957, 7854
'the cyclohexane 801 (250 units), tetrahydropyrane 816
(242) dioxane 835 (223), and the value of the frequency,
in accordance with the theory, increases. For six-term
cycles the width of the linea remains within the experi-
mental accuracy constant, and for five-term lines it di-
minishes with the hardness of the cycle. The intensity
of the C = C -frequencies in the spectra of the investi-
gated compounds is close to the values obtained for the
isolated C_-C bonds of the alkanes and cyclanes.
Card 2/2 - 80 -

YUR I YEV, Yu. K. ; !O'NDIIAT.#Y:BVA,, .. G. Y&.
Catalytic conversions of heterocyclic compound@. ftrt 47. Mecha-
ni,sm of the caUlytic,dehydpation of 2,2,S.5-tetramethy1furanidine.
4 Zhur.5)b,.k#im. 26 no.1:275-2?9 Ja 156.' Oa-RA 9:5)
1. Moskovskiy gosudarstvannyy universitet.
I(Do W ration (Chemistry)) (Puran)

K VAI

Distri 4E4-JAE3dAE2c(j)
V
icondk-nsation of boxaclop of elc dnhv
drWe. G. Ya- Kmidrat'cva. ~
,
!
=awles witb di=lophi!" M
C.Ra schis. do. not give the crpected ca-doxe derivs. of tetra-
hydrapyridlr.e Suits but the Substituted
A-Ppwently tLe umial mec_u=is,- ol dieW
b whicb rc&rfM'Y'-M~rctdiatc*-- to
vvc cinchomaurde acid. Condensation of the f~~Ilowmg
n-o tes with makk anhydri& vave tlic ccn-~spczdiag
ciachrmcm!z atld dezirs.: M-. 2,54, aad
c=z_zle. 2:.5.i-trLu-_thytax=lc arld 1_~~thy'4,5-ttr&-
nwhylenzosazoU. Tht y0d3, m.p., of t-l-, mpec!ive adds
aiiii the m.p. of the aphYdridei pbWmd with IIA Tzar as

j 1,47q, z.,%- ~0:1_i

Mal

f

AUTHORSs Kazanskiy, B. A.v
Bele0ka a, A. P.,
Pavlova) P. S.
Sterligov, 0. D.t
Kondratlyeva, G. Ta.p
62-11-20/29
TITLEs Determination of the Unsaturation of Isopentane-180prOZOw
Isoanylene Mixtures According to Bromonetric Methods.
(Opredeleniye noprodellnosti izopentan-isopren-
izoamilenovykh smesey bromometrichookini matodami).
PERIODICALs Izvestiya AN SSSRq Otdolenio Xhimicheakikh Naukt 1957,
Nr 11. pt., 1399-1400 (U33R)
ABSTRACTs Here,a relative evaluation of the oxactneso of the methods
of bromomotricalldetermination of the unsaturAtion and the
selection of the .most useful method for the analysis of the
isopentan*-deby4r&tion catalyeates Is brought. Ixamini
the bromometric methods of 1. W. Rgeenaund (reference
G. D. Gall Porn L (reference 2) and Virabyants with artificial
mixtures show ed that in dependence of the composition of the
isopentans~-isoprone-isoam,ylono mixtures the exactness of the
determination of the total unsaturation according to the
methods of Rosenaund and Gal*pern can vary absolutely from
Card 1/2 1 to 3 When introducing correcting coefficients the
Card 2/2

JNJ D,01 I
AUTHORSi Kazanskiy, B. A., Sterligov, 0. D., 75-1-23/26
Belen'kaya, A. F.) Kondratlyeva, G. Yal., Pavlova, P. S.
- -------- ----
TITLE: Brorometric Methods of Determining Unsaturated Hydro-
carbons in Isopentane-Isoprdne-Isoamvlene Mixtures
(Opredeleniye nepredellnosti izopentan - izopren -
izoamilenovykh smesey bromometri;heskimi metodami)
PERIODICAL: Zhurnal Analiticheskoy Khimii, 19581 Vol. 13, Nr 1, pp 134-141,
(USSR)
ABSTRACT: In the catalytic dehydrogenation of isopentane a mixture of
5 oomponente forms - the initial product, 3 isopentenes and
isoprene. The quantitative relation of the components depends
on the reaction conditions. In'the present paper the relia-
bility of the three bromimetric methods - according to
Rosenmund (Reference 3)9 Gallpern (Reference 5) and Vyrabiants
(Reference 6) is examined. This control was investigated in
pure C -hydrocarbons and also in various artificial mixtures
of iso;entane with isopentenes and isoprene shich differed il~
the number of components and also in their concentration. It-
Card 1/5 became evident that the method according to Vyrabiants is not

75-1-23/26
Bromometric Methods of Determining Unsaturated Hydrocarbons in Isopentane-
Isoprene-Isoamylene Mixtures
suitable for an analysis of such mixtures I because the error
assumes different values and attains up to 7 - 8 % (absolute).
The results obtained according to Rosenmund and Gallpern conv
firm the fact that the accuracy of the determination of double
bonds depends on the structure of the hydrocarbons and on the
composition of the mixture% 2-methyl-butene(2) and 3-methyl-
butene(l) without difficulty absorb 1 bromine molecule on
bromination. 2-methyl-butene(l) and isoprene consume more
than I bromine molecule and therefore yield too high results,
relative to a double bond, in the determination according to
Rosenmund and Gallpern. The analysis of mixtures with 3 or 4
components, but without isoprene, showed an average absolute
error of the determination of the olefines of + 1 %. On addi-
tion of isoprene to the mixtures with 3 components the ab-
solute error increases to + 3 %. The analysis of mixtures with
5 components showed that t7he absolute error in the case of an'
isoprene content up to 20 % in the method according to Rosen-
mund on the average amounts to + 3 % and according to the
Card 2/5 method by Gallpern -2 %. As the averaae error in the

75-1-23/26
Bromometric Methods of Determining Unsaturated Hydrocarbons in Iso-
pentane-Isoprene-Isoamylene Mixtures
determination of the total number of double bonds in
mixtures of 5 components according to both methods has a
systematic natureq it can be taken into account by the intro-
duction of a corresponding coefficient (in the case of an
isoprene content up to 20 1%). It was shown that the values
for the total number of double bonds which were once de-
termined according to Roserimund and once according to
Gallpern practically coincide after the introduction of a
correction coefficient. As the method of bromination only
makes possible a sum determination for alkenes and dienesq
the content of monoolefines can only be determined from the
difference between the total number of double bonds and the
content of dienee. In the present case an appropriate cor-
rection which takes into account the content of isoprene must
therefore be applied to the bromimetric results for determin-
ing the content of isopentenes. For the determination of iso-
prene the photometric method according to Robey and Wiese
(Reference 17) was employed which is well applicable in the
Card 3/5 presence of monoolefines, but also of some dienes. The average

75-1-23/26
Bromometric Method of Determining Unsaturated Hydrocarbons in
Isopentane-Isoprene-Isoamylene Mixtures
Card 4/5
error of this determination is less than 1 % (absolute).
Determination takes 1 1/2 hours, which time can be shortened
in series determinations to 20 minutes for one determination.
When the concentration of isoprene in isopentane-isoprene-
isopentene mixtures has been determined in this manner, the
content of isopentenes (P) can be calculated according to the
formula P - a.Pl-b. P is the found total number of double
bonds in the mixture, b is the concentration of isoprene in
the mixture and a is the correction coefficient. In the method
according to Rosenmund a - 0,96 and in the method according
to Gallpern a = 1,04. All performed tests are exactly de-
scribed. During the elaboration of this method a short
article by Timofeyeva and collaborators (Reference 18) on the
same problem was published. In this article a correction co-
efficient is introduced in the final formula of the calcul-
ation which only takea into account the error produced by the
inexact bromination of isoprene.

75-1-23/26
Bromometric Methods of Determining Unsaturated Hydrocarbons in
Isopentane-Isoprone-Iooam.vlene Mixtures
There are I figuret 5 tables, and 21 references, 15 of
which are Slavic.
ASSOCIATION: Institute for Organic Chemistry im. N.D. Ze3.tnskiy, AS USSR,
Moscow (Institut organicheskoy khimii im.
N.D.Zelinskogo AN SSSR, Moskva)
SUBMITTED: April 8, 1957
AVAILABLE: Library of Congress
1. Hydrocarbons - Determination
Card 5/5

50)
AUTHOR: --Kondratlyeva, G. Ya. SOV/62-59-3-15/37
TITLE: Diene Condensation of Oxazole Homologues With Maleic Acid and
Its Anhydride (Diyenovaya kondensatsiya gomologov oksazola s
maleinovoy kislotoy i yeye angidridom)
PERIODICAL: Izvestiya. Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 3, pp 464-490 (USSR)
ABSTRACT: In the present paper the condensation of oxazole homologues
with maleic anhydride and maleic acid was investigated. It
was found that the reaction proceeds according to the ordinary
scheme of diene synthesis under the formation of substituted
cinchomeronic.acids (pyridine-dicar'--oxylic acids-04)). The
reaction investigated is one of a rare modification of Diels'
synthesis if a nitrogen-containing system is used as diene
component. In the reaction with maleic anhydride the system
C=C-N=C re-presents the properties of the conjugated chain
C---C-C=C. If the ordinary carbon-containing dienes form in
thin.case cyclohexane derivatives, the G---C-IT==C dienes are
transformed into analo-ous compounds of the tetrahydropyridine
series. By condensation of the oxazoles with maleic anhydride
Card 1/2 and maleic acid 2,6-dimethyl and the 2,5-dimethyl-I

Diene Condensation of Oxazole Homoloo-ues With SOV/62-59-3-15/37
Maleic Acid and Its Anhydride
5,6-dimethyl-I 2,5,6-trimethyl-j and 2-methyl-5,6-tetramethylene-
cinchomeronic acid previously not described were obtained
(Table). Usually the yield is high and fluctuates (with the
exception of 2-methyl-5,6-tetramethylene-cinchomeronic acid)
between 50-85 'i6 of the theory. The substances are sufficiently
pure already after elution with water and acetone. The small
yields of cinchomeronic acids from oxazoles and maleic acid
might be due to the salt formation taking place at the same
time. The structure of the adducts was determined by the
example of the 2,6-dimethyleinchomeronic acid which was ob-
tained by synthesis also from ethoxalyl acetone and amino-
croton ester according to the method of Mumm and Hueneke
(Ref 7), There are 1 figure, 1 table, and 9 references.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D. Zelin-
skiy of the Academy of Sciences, USSR)
SUBMITTED: June 8, 1957
Card 2/2

S/595/60/000/000/006/014
E196/13435
AUTHORS: Kazanskiy, B.A~o Sterligovq O.D.2 Belenlkaya,
Kondrattyevag G.Ya.
TITLE% Catalytic dehydrogenation of isopentane
SOURCE: Vsesoyuznoye soveshchaniye po khimicheskoy pererabotke
neftyanykh uglevodorodov v poluprodukty dlya sinteza
volokon i plasticheskikh mass. Baku, 1957, Baku, Izd-
vo AN Azerb.SSR, 1960, 207-218
TEXT: Due to the lack of published information, the
authors investigated the process of dehydrogenation of isopentane,
which yields as the intermediate product isoamylenes, and, as the
final product, isoprene, the monomer of synthetic rubber, The
chrome-alumina catalyst K-544 was used, This catalyst, developed
by M. N. Marushkin of 1OKh AN SSSR, proved suitable for dehydro.-
genation of n-butane and propane; it is highly active chemically
and has a high mechanical strength. All experiments were
conducted in the following manner: fresh or reactivated catalyst
in portions of 20 cM3 was heated in a quartz tube to the reaction
temperature in a current of air. The air was then purged by
nitrogen and isopentane was introduced in the tube, The liquid
Card 1/5
Catalytic dehydrogenation S/595/60/000/000/006/oi4
E196/E435
reaction products were condensed by cooling with solid carbon V
dioxides noncondensibles were collected in a gasholder. The
unsaturated hydrocarbons in-the condensate were estimated
bromometrically by the Rosenmund and Halpern methodsu isoprene was
separately determined by Weighing its adduct with maleic anhydride
or colorimetrically by the method of R~ F_ Robey and H,VJftese, The
catalyst was regenerated after each run by passing a current of air
fo.r one hour at the x*eaction tempe,,ture~ Exper3.ments have shown
that during hourly working cycles in the temperature range 500 to
575-OC and that of space velocities 0.3 to 4,2 hr-1, the activity
of the catalyst increased with temperature., reaching a maximum at
550-C, maintained independently of the space velocity ill tha ranye
0.7 to,2.6 hr-1, Under those conditions the cRtalYsate from
isopentane contained UP to 58lat of unsaturated hydrocarbons, the
Yield of the latter being 45 to 49% on total Isopentane and 70 to
90% 011 the decoillposed isoPentano, The Productivity of tile,
catalyst sharply increased with temperature, reaching the
OptimumIvaluev about 700 g C H ~/?khr at 5500C and space velocity
2.6 hr'- 5 10
Card 2/5 Thus 550*C was the best operatilig r,,jjl~ c)f this ~.atalj,,4t..

S/595/6o/ooo/ooo/006/014
Catalytic dbhydrogenation goo E196/E435
w S
The noncondensible gas/'Of'ound to consist largely of hydrogen with
some methane-. The liquid products were analysed for the
individual unsaturated components by means of gas chromatography
and light scattering;ftresults are given in Table 1. Analytical
difficulties in the estimation of the unsaturated components by
means of the Raman scattering s ectra are discussedo They arise
from the fact that the 1640 cm-' line of isoprene is 12 timeB more
intensive than the 1642 cm-illine of 3-methylbutene.-I. The
masking effect of Isoprene is therefore very strong and :L-t tend3
to affect even the 1651 cm-1 line of 2-methylbutene-1. In the
chemical determination of total unsaturatlon of the catalysate,
the Rosenmund,method,was found'to give high values -while the'.
Halpern method gave low values, The correction factors which
had to be applied were 0.96 and 1.0.4 respectively. Academicians
N.D.Zelinakiy, A.A.Balandin, B4A.Kazanskiy, Corresponding Member,
AS USSR N.I,Shuykin, Yu,G.Mamedaliyev as well as V.T.Aleksanyan,
Kh.Sterln of Komissiya po spektroskopii AN SSSR (Commission on
Spectroscopy AS USSR) and CandidAte of Chemical Sciences, Headlof
Gazovaya laboratoriya (Gas Laboratory) of VNIGNI 16INP SSSR are
mentioned in the paper. There are 9 figures, 6 tables and
Card', 3/F

S/595/60/000/000/006/014
Catalytic dehydragenation E196/E435
Unsaturated components in catalysate W1W Table L,
Fraction 20- 38" -500- 525' 550"
Total unsaturation
Isoprene
2-methylbutene-2
2-methylbutene-1
3-methylbutene-I
18.6
0.4
10
5
3
41.6
1.5
15
15
3
52~2
4.2
20/25;1
15/301~
5/35'
xThe analysis was carried out before separation of dienes
in the fraction 20-380,
Card 5/5

68813
54-3.) S7 J 100 S/020/60/131/01/026/060
AUTHORS: Kondratlyeva. G.-Ya.. B011/B006
M-anClizhi-khen
11, P" ` I , 11s: Reaction of Pyridine-3t4-dicarboxylic Acids With Hydrazine
and Aniline
1111"',11 UDICAL: Doklady Akadejaii nauk SSSR# 1960, Vol 131, Nr 1, PP 94-97
(USSR)
ABSTRACT: The authors describe the condensation of the pyridine-394-
dicarboxylic acidu which they prepared previously (Rof i) with
hydrazine nnd aniline. The presence of two adjacent carbo.:yl
groups.in these acids rakes the fornetion of various types of
derivatives In like this, the main reaction
path is detcr;.-.inc0 properties of the reactants.
Dihydrazidec, cyclic or K-aninoinides of the
acid II (nee scheme) (Refs 2-5) nay be formed. TLe authors
proved that 5,6-dimethyl-, 2,6-dimethyl-, and 5-hydroxy-2-
r'-ethYI-.-),,'!-i0i'10-3,4-dic~~rboxylic -acids are converted to cyclic
livdrazi.~dcs (I)yrido-(3t4)-pyridazinediones) I in yields of
Card 1/3 60-80516 on heatinG shortly wiih hydrazine*. With 2,5,6-trimethyl-

68813
Renction of Pyridine-3,4-dicarboxylic Acids 8/02P/60/131/01/ 026/o6o
With Illydrazine and Aniline Doll/BC06
pyridine-3t4-dicarboxylic acidq hydrazino forms the 11-anino-
imide of acid II. The 2,5-dimethylDyridine-3,4-dicarboxylic
acid, in which the COOH- groups are blocked by CH -groups in
3
the same mannerl reacts with hydrazine to, give 'the hf-tminq-
and v. small quantity of the hydrazijq, IL.;* On lo*rK-k~r
heatill'i, the hyCrivide~ yield increa.-en to 6(,,,,, th of
the aninoi;:iido. Tho,,,Iatter is ivomorizod rorc r,-.---idly,b-v un-
reacted hydrz?-zino.
'Ve 5 -hy droxy -2 -1,-;0 thy 1~ly ri (line - 3,
carboxylic acid however, on trcatnont with hydrz.--zina X, s
L;ivL,
only the hydrazide IIv. The noLit otable derivatives of pyridine-
3 jli~Ltjicarboxylic acids are the cyclic hydrzizidess 1. U,-in,~:, the
Y.yC.)?v.%ido Id as an c-canple, it was I;rovcd th,%t it is ferried as
fflIcI product of.tho reactions betwoon hydrrtzino and the acid,
ac.,vc1l as the araide and 11-plionylimide of' the latter. The
hydrazide Ia vac obtained in hit;h yields by rezetion of
hydrazzine with the free ac id or its dicnilide, dimethyl-, and
nonomothyl esters. The 'cyclic hydrl-'zidor; are slichtly colored,
Cf,.-re, 2/3 I1i,,,4i-re1tin,1,, m1botnTiceri wIUch :-.-ro insoluble in or!-,Pnic solvent'69

AUTHORS: Kondratlyeva, G.Ya.j and
TITLE: Academician Boris Aleksaadrovich
70th birthday)
PERIODICAL: Zhurnal obshchey khimii,
S/07 61/031/005/001/002
D222YD304
Mikhaylova, Ye. A.
Kazanakiy (On his
v. 31, no.5, 1961,1407-1416
TEXT: This article is a survey of the scientific work of B.
A. Kazanakiy, who completed his studies at Moscow University in
1918, specializing in chemistry. He began his scientific career
at this University and is still working there. Acquiring a docto-
rate of,Chemical Sciences and becoming a Professor in 1935, he sub-
sequently became Assistant Head of the Kafedra khimii nefti(Oil
Chemistry Department) and held the post of Head from 1950 to 1960.
Also since 1935 B*A. Kazanskiy has been actively engaged at the
Laboratoriya kataliticheskogo sinteza ( Laboratory of Catalytic
Synthesis) which he established himself of the Institut organiche-
skoy khimii Akademii nauk SSSR ( Institute of Organic Chemistry
of the Academy of Scienc-es, USSR). In 1946 he was elected member
Card 1/10
Academician Boris Aleksandrovich . . .
S/079/61/031/005/001/002
D222/D304
of the Academy of Sciences and he is a member of the International
Bureau of the Union of Pure and Applied Chemistry. The main.area
of Kazanskiy's scientific work is catalytic synthesis and theoata-
lytic transformation of hydrocarbons. He discovered a specific
paraffine-dehydration reaction which leads to the formation of aro-
matic hydrocarbons, C dehydrocyclization. Only such aliphatic
hydrocarbons which cNtain at least 6 carbons in their straight
chain undergo this reaction; the structure of obtained benzene ho-
'logues denoting that of the original compound. Substituted ali-
m
oL
cyclic compounds can also enter this reaction. By dehydrocycli-
zation of hexane and heptane, benzene and toluene are formed; by
using higher paraffine homologues a whole series of aromatic com-
pounds can be obtained. The reaction mechanism is a two step one:
paraffine - alkylcyclohexane - alkylbenzene. This was discovered
by investigating the aromatization of hydrocarbons which contain a
quaternary carbon atom, the structure of which does not permit di-
rect formation of aromatic compounds; such paraffines ( e.g. 3.3 -
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Academician Boris Aleksandrovich . . .
dimethylhexane) submitted to catalytic cyclization form a mixtu-
re of 1.1 dialkyloyclohexanes and of aromatic compounds of lesser
molecular weight. Platinized coal is the standard catalyst for
this reaction, but after many investigations Kazanskiy discovered
several other contacts: e.g6 with an aluminium chromium catalyst
activated with potassium She yield of toluene from heptane amounts
to 70% at 51500 : at 550 C the same amount of benzene is formed.
Platinized coal also promotes cyclization of paraffines with 5 or
more carbon straight chains and that of alkylocyclic compounds
with side chains. in this case, other catalysts are ineffective.
The cyclization of n-hexane and n-octane gives (at 3100C) 10% of
pentanaphtanes. It is difficult to cyclicize n-pentane while sub-
stituted paraffines undergo the reaction more easily, e.g. iso-
octane is converted to 1.1,3 - trimethyleyclopentane with a yield
of 25-32%. Benzene homologues and alkylocylanes form bicyclohydro-
carbons, e.g. propylbenzene is converted to indan and propylcydo-
pentane into cis-pentalan. The activation energy in parafftne ae-
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Academician Boris Aleksandrovich . . .
hydrocyclization equals 20 Kal/mol and in the case of alkylobenze-
nes cyclization - 27.Kal/mol. Kazanskiy also studied the hydrati-
on reactions of unsaturated hydrocarbons. He proved that the vel-
ocity and selectivity of the hydrogen addition to double bonds de-
pend not only on the olefine structure but on the properties of the
catalyst as well. -When platinum catalysts are used, the hydrogen
absorption is lowered if phenyl groups are present in the olefine
molecules, the effect being reversed in the case of palladium and
nickel catalysts. Similar phenomena are observed in the hydrati-
on of dienes with conjugated double bonds. Yet another type of
reaction t&kes place when a hydration process is effected by hydr-
ogen ~' in statu naBeendill obtained by the decomposition of double
ammonium salts of calcium, strontium, barium and lithium. In the
case of benzene hydration two double bonds are saturated and com-
pounds of the cyclohexane series are obtained. By this method ali-
phatic dienes with conjugated and non-conjugated double bonds are
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Academician Boris Aleksandrovich
also hydrated, as well as mono-olefines, the latter showing a lower
reaction velocity, It is a two step ionic reaction:
1) >C = 0 >+ 2e -4> ce - Ce > ; 2) > Ce - Ce + 2H+--4 >CH - CH
because the reaction velocity is inversely proportional to the evo-
lution of H2 and to the acidity of the reaction solution. Another
group of Kazanskiy's investigations consists in the study of small
cyclic hydrocarbons with 3-4 carbon links, their synthesis and the-
ir catalytic transformations; he first obtained many new compounds
of the cyclobutane series and work6d out an improved method of
pure cyclopropane preparation, which should start shortly in the
production scale. f-Abstract 1
USSR on an industrial - ers note: The me
thod is not described_/. Hydrocarbons of the cyclopropane series
easily absorb an H2 molecule and are converted to paraffiness two
independent reactions taking place: 1) the actual hydrogenolysis
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Academician Boris Aleksandrovich
of cyclopropane with its isomerization to an olefine and 2) the
subsequent hydrogenation of the unsaturated compound into a satu-
rated one. By choosing appropriate contacts, the two reactions
may be separated, palladium black being the specific catalyst for
the isomerization reaction. With this catalyst the tempgrature of
reaction depends on the type of catalyst carrier, temperatures ran-
ging as follows: on silica gel it is 20C, on alumina gel - 500C9
on KieBelguhr - 1200C, on pumice - 1750C, and on coal - 2000C.
Cyclopropanes with unsaturated side chains are more easily iso-
merized than alkyleyelopropanes. The reactivity of aryl deri-
vatives depends on the conjugation of the phenyl and cyclopropa-
ne rings. The isomerizationof paraffines, obtained from alkyl
cyclobutaries requires very a:dtive contacts and temperatures above
2000C, but cyclobutanes with unsaturated side chains undergofoome-
rization as easily as alkyl cyclop-ropanes. Substituted alkyl-
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S/079/61/031/005/001/002
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Academician Boris Aleksandrovich ;,.- -.
cyclopenlanes are even less reactive and their reactivity decre-
ases with the number of added alkyl groups. The fission of the
cyclopropane ring during hydration most often takes place betwe-
en the second and third link atoms. This peculiarity of ring
fission was used by Kazanskiy for selecting.suitable catalysts
in his method of gasoline analy'sers., CAbstracte?B note: Method
not describeg. The hydrogenolys 'is of bicyclo ( 19 1,.2) hep-
tane and its final conversion into 2,4 - dimethylpentane has pro-
ved that it is a true member of the cyclopentane and not (.as was
thought) of the cyclohexane series, Kazanskiy also investigated
the hydrogenolysis and dehydration of alicyclic hydrocarbons
with 6 - 10 carbon lift; platinized coal in the absence of hydro-
gen ewases the transformation of these compounds either into aro-
matic or bicyclic ones: e.g. methylcyclooctane is converted at
3200C into toluene, dime 'thylayclo octane - into m-xylene; cyclo-
octane on a ferro-platinum catalyst at 3200C splits off H2 and
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Academician Boris Aleksandrovich
forms cis-pentalan with a yield of 75% on an aluminium chromium
contact. Besides this compound, ethylbenzene and xylenes are for-
med; with nickel on a Kieselguhr catalysti cyclo-octane is con-
verted at 2000C into n-octane followed by its isomerization into
alicyclic-compounds with-7, 6, and 5 carbon links. Cyclonane is
converted by transannular dehydration ( at 3000C over platinized
coal) first into indan.and finally into alkylbenzenes. Kazans-
kiy and his scientific co-workers made a great contribution to the
synthesis of hydrocarbons of high chemical purity; these were ne-
eded as standards for spectra tables. Z_ AbstracteA note: Chara-
cteristice of.spectra not given2. Many of these compounds have
been obtained for the first time and special synthesis and puri-
fication methods being worked out for those which were already
known. The authors cite some examples of newly prepared compounds
such asg dialkylhemsubstituted cyclopentanes and cyclohexaneB
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S/079/61/031/005/001/002
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Academician Boris Aleksandrovich . . .
and some complicated bicyclic and tricyclic hydrocarbons; Ipure cis
and trans lsomerB-Of I , 4 --dimethyl - 2 - ethylcyclopentane; 19
29 3 trimethylcyclopentane and a series of 19 2 - disubutituted
cyclohexaneB. Kazanakiy was the first to introduce into Soviet
oil research laboratories new equipment.and analytical methods su-
ch as high efficiency rectifying columns; absorption chromatogra-
phy on silica gel including a gas liquid one ; dehydrogenocatalysis
for the selective dehydrogenation of alicyclic compounds; the use
of combined scattered light spectra determinations. At present
these analytical methods are used for'the composition study of gas-
olines, obtained by direct oil distillation and cracking processes.
By means of these methods 36 gasolines ( from direct distillatio'n)
were determined in oils.from Azerbaydzhan Bashkiriya, Kazakhstan,
RSFSR, Tatariya, Turkmeniya, Uzbekbtan and Communist China as well
as the composition of the ligroin petrol fractions, the precise
Card 9/10

KONDRATIYEVA, G.Ya.; WAN CHZHI-KHEN (Huang Chih-h;ng]
Reaction of alkyl- and alkoxyoxazoleo with maleic acid imide.
Dokl. AN SSSR 141 no.3:628-631 N 161. (MMA I/+: U)
1. Institut organichemkoy khimii im. N.D.1 Zelinskogo AN SSSR.
Predstavleno akademikom B.A. Kazanskim.
((bmzole) (Maleic acid)

KONDRATIYEU, G.Ya.; KHUAN CHZHI-IGIEN (Huang Chih-heng]
-----------
Reaction of 5-alkoxyoxasple with maleic anhydride. Dokl.
AN SSSR Al to-4:8,61-864 D 161. (MIRA 14:11)
1. Institut organicheskaylehlTnii im, N.D. Zelinskogo AN SSSR.
Predstavleno dkademikom B.A. Kazanskim.
(Oxazole) (Maleic anbydride)

KORDRATIUVA, G.Ya.; KHUN CHZHI-MN [Hwmg Chih-hOng]
Imides of pyridinedicarbooglic acids*
199-201 JA 162.
(Pyridinedicarbo"de)
Zhur.prikl.khim.
35 nool:
(KEPA Ifl)
-k- .

KONDRAT'YEVA, G.Ya.; KRUAN CHZHI-YJiEN [Huang Ghih-b~ngjj
Oxazole derivatives in diene synthesis. Dokl. AN SSSR 142 no.3:
593-595 Ja 162. (MIRA 15:1)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR.
Predstavleno akademikom B.A.Kazanskim.
(Oxazole) (Olefins)

KOXDRAT I nVA, G. ~a.; KHUAjj CMU
_,M,
V [R .. ~,W Chlh"ha,j
Synthesis
nO*7:2348-2of
som subOtituted oxazoles. Zhuroob.khlm,
35~ 'n I li~ 0 32
(O,Xaz..I.) (au .15:7)

"UAN "22fl-KHEN fjj,~~ Chlh_Wgl; KONDRATIYEVA a y
- ~,-, ~Ua-
SYnthesis of 6-mqt4.vl-'
lzv.AN SSSR.Otd.khim. -"-OVPyrldlne-3,4-dlcarbojVUc
1. Izatitut organi nauk no.3$525-526 . r62.
Cheskoy
khWi 'M' "-D-Zolinskogo
(pyridi"ed"arbOV1-ic acid)
acid.
(KRA 15:3)
AU S_qMG

FONDRAT'YEVA) G.Ya.;
F-f[IIIIN CIEHI-KIIEN (Ijuang Qjh-leng]
Reaction of oxazoistj with acrylic a0l.d. Dokj. AN SSSR 164 no,4:816-
819 0 165, (MA .18&10)
lo Institut organicheskoy khimi-t im. N.D.Zol.l.nskopo AN SSSR. Sub.
mitted February 22, 1965.

L,.--, C--~ /V z~
f I u
Translation from: Referativnyy zhurnal, Geologiya, 1957, Nr 7,
p 82 (USSR)
AUTHORS: Kondratfyeval I, A., Kholodov, V. N.
TITLE: Som~ePec~uliar
the Formation of Dolomitic Rocks
in the Durkestan Series of the Paleogene of Fergana
(0 nekotorykh osobennostyakh obrazovaniya dolomitovykh
porod tarkestanskogo yarusa paleogena Fergany)
PERIODICAL: V sb: Vopr. mineralogii osadoch. obrazovaniy, Nr 2,
Llvov, L'vovsk. un-t, 1955, pp 219-222
ABSTRACT: A significant persistence of layers of dolLMite along
the strike in the Turkestan series of Ferganat as well
as an observed direct relation between content of alas-
tic material and quantity of dolomite in the rocks, has
led to the hypothesis that the magnesium salts in the
sediments were deposited syngenetically. The following
varieties of dolomite are distinguished texturally:
1) organic, 2) organic-oolitic, 3) oolitic, 4) with
Card 1/2 relict textures, and 5) finely crystalline. Each of
Some Peculiarities in the Formation (Cont.)
15-57-7-9315
these textures corresponds to a definite dolomite content. The
greater the content of dolomite, the greater role recrystalliza-
tion has played, leading to relict and finely crystalline tex-
tures. The intensity of secondary processes is determined by
the percent of the dolomite content occurring originally in the
sediment
Card 2/2 0. 1. Zelenova

H, I YL- !'/7j
V -j-, /I/.
KHOLCDOV. V.N.; K014AROVA. G.V.; KONI)RATIYXVA, I.A.
The effect of simultaneous folding and sediment deposition an the
carberAte-forming process: Article 1, Role of tectonic structures
in the formation of facies characteristics of carbonates. IsvJI
SSSR.Ser.geol.21 no.11:39-60 N156, lon)
1. Institut geologil rudnykh mestoroshdaniy petrografii, mineralegil
I gookhimii Akademil vxuk SSSR. Moskva.
(CPAonat*s, (Minerklogy)) (Geology, Structural)

T_
USSR/Geology 3.1-4-3/23
AUTHORt Kholodovq V.N., Komarovat G.B. and Kondratlyeva I.A.
TITLE: "About the Influence of Consedimental Folding Process on the
Formation of Carbonates." (0 vliyanii konsedimentatsionnoy sklad-
chatosti na protasse karbonatoobrazovaniya)
Article 2. "Interrelation of Dolomitization and the Develoz)ment
of Antiollqal Structures". (Svyas' dolomitoobrazovaniya, z
vitiyez antiklinallnykh strul-tur),
PERIODICAM "Izveetiya Akademii Nauk SSSR11, Serlya Geologicheekaya, 1957,4,~,
# 4, pp 33-42, (USSR).
ABSTnCT: In this article are published the results of the second part
of & study dealing with the application of a structural facies
analysis at the lithological research of carboniferous Paleo-
gone deposits at Fergana. The spatial sequence of the diagnetic
dolomitization from the preceding stages is hereby established.
Studies of carboniferous rocks of the l,thorizon of the Alay
layer at the Paleogene strata showed th at the first stage of
rock forming consedimental folding strongly affected the chemi-
cal composition and the structural properties of sediments.
Card 1/6 Changes of the composition and the structure of sediments are
11--4-3/23
TITLE: "About the Influence of Consedimental Folding Process on the
Formation of- Carbonates." (0 vliyanii konsedimentatsionnoy sklad-
chatosti na proteese karbonatoobrazovaniya)
Article 2. "Interrelation of Dolomitizption nn.1 thf- Development
of Antiolinal Structures", (Svyazl dolomitodbrazovaniya. 9 raz-
vitiyom antiklinallnykh atruktur).
Card 2/6
identified by a complielted joining process of fold formation
and by hydrodynamics. he ever present tendency to smooth
elevations on the bottom create more or less distinct diffe-
rences on various sections of the same stratum with a subse-
quent forming of certain facies. In due course, the phase of
accumulation of carboniferous sediments on the bottom of the
basin is not within the realm of influence of consedimental
tectonics. Due to set sequenceaq several diagenetic and epi-
genetic changes occur within the boundaries of the facies plans,
for which the conditions have already been prepared during the
preceding phase. Dolomitization is such a follow-up process
which will be examined in the following studies. The existing
relation between the profile of the bottom of the Alay basin
and the distribution of average contents of CaMg(CO 3)2 was
stated in the preceding article. It was noted that the consti-
tuent parts of the dolomites combined well with the components

11-4-3/23
TITLEs "About the Influence of Consedimental Folding Process on the
Formation of Carbonates." (0 vliyanii konsedimentatsionnoy sklad-
chatosti na protsess karbonatoobrazovaniya)
Article 2. "Interrelation of Dolomitization and the Development
of Anticlinal Struc4ures". (Svyazf dolomitoobrazovaniya a
razvitiyem antiklinallnykh struktur).
organic matter was available in small quantities, and dolomite,
when organic substances were present in large quantities. While
the process of dolomitization depends on the basic concentration
of magnesium saltat the distribution in the basin is governed by
the antiolinal structure, therefore the diagenetic and even the
epigenetic forming of dolomites is interconnected with consedi-
mental folding, and evidencing a certain regularity of this
process. Embedded dolomites can be subdivided in 3 groups, close-
ly related with each other genetically: 1) Interpersed dolomites
in limestones: 2) Lenses in calcareous dolomites. 3) Layers
of calcareous dolomites and dolomites.
The main object of these studies was to show that consedimental
folding affected the chemical composition and the structural
properties considerably during the process of sedimentation.
The article contains I chart, 1 table, I diagram and 5 photo-
Card 5/b graphs.

32-4-3/23
TITLEs "About the Trfluence of Consediment&l Folding Process on the
Formation of Carbonates." (0 vliyanii konsedimentatsionnoy
skladchatonti na prozieses karbonatoobramvaniya)
Article 2. "Interrelation of Dolomitization and the Development
of Antiolinal Structures". (Svyazl dolomitoobrazovaniya s
razvitiyem antiklinallnykh struktur).
The bibligoraphy lists 19 references# of which 18 are Slavic
(Russian).
ASSOCIATIONt Geologic Institute of Metal Deposits, Petrography, Mineralogy,
and Geochemistry of the Academy of Sciences, USSR, Moskva.
PRESENTED BYt
SUINITTEDt February 23! 1956
AVAILABLE: At the Library of Congress.
Card 6/6

KHOLODOVO V.N.; LAITSIN, NOMMOVA, G.V.; KONDWT-Y-EVA, I.A.
Epipenetic 7ones In uranium ore deposits in oil-bearing ca-r-bonite
rocks. lzy.All SSSR. Ser.geol. 26 no.11:50-63 N 161.
(1111PLA 14:10)
1. Institut geologii rudnykh mestorozhdeniy, petrografii, minpralo-
gli i geokhimili AN SSSR Moskva
. (uranium oreO (Rock;, Carbonate)

01 11-6
L o 6 EPA (8)-?'/EWT WILW(a) -2/T/W(t)/LPWP(b)/VdA (C) 0
PU_4
lp
T
_IJPc WVH/ES/JD/WW/JG
AK5014982 BOOK EXPLOITATION UR/553.061046.79
Batulin. So G.g Golovin. YE. A.; Zelenova, 0. 1.; Kashirteava.. No #6
Komarov4. Go V.; Kondratlyevs, 1. A.1 Lialtsin. A. K.j ?erelluas.
~1.;Si~ndendoVa, V. Do; Chernikov, At A.; ShmarLovich. TZ, me
Exogenous epigenatic deposits of uriniual formation conditions'
(Ekzonennyye epLgensticheskiye mestoroxhdamiya urana; usloviya
obrazovantya). Moscov, Atomizdat, 1965. 321 p. illus.. biblie..
Errata slip inserted. 1100 copies printed.
TOPIC TAGSt deposit formation, epigenetic theory. oxodiajenstie
deposit, surface urnalum,accumulation, uranium bituminous depositq
uranium deposit, uranium, nuclear fuel. q,
':PURPOSE.7AND COVERAGE: This book is Lntanded-for readers
in the geology of ore deposits, in particular for those concerned
vith atomic rev materials, and also for students of higher~educa-
tion institutions. In the book, for the first time in Soviet aad
foreign literatures, the spigenstic theory of uranium-deposit I . -:.1.I
formation ii,expounded. Hany Soviet and f4ireLga source mater1ale

rL-
65
;82
have'been used in thin book. and some of the Investigations
carried out by the present authors'ara published in this book for
the first time. Several nat4a of Soviet scientists working to
this field are mentioned. V. A. Uspenskiy collaborated on Ch. 1,
and H. A. Visalkina on Ch. 111. The authors tha
dedeased, Corresponding Member Academy of Sciences USSR, 4nd
F. 1. Vollfson, D. C. Sapothaikov V. 1. Gersaimovskly M T'
Stralki , Q. S. gritsayanko, and 1. P. Kushoarev, Doctor@ of
Geologico-mindralogic Sciencell V, 1# Danchey, Candidate of Cosa
logico-Hineralogic Science olokovzkh, There are
c:: and N. As V
about 11 pages of refs n of wVrch about 314 are Soviet$
TABLE OF CONTENTS libridgedlo
Introduction --i, 4
Ch. 1*
Ch. 11.
Zp1genstic processes in..hyporgene a zone -9
Chemistry and drystallochanistr of uranium compounds-

AH5014982
Chi 111. Associations of nonoxidized uranium mLearale I*
apigianstic deposits, -1- 37
Ch. IV. Uranium twourface and ground water@ 46
Chi V. Uranium In stratal water# -- 57
ch. V1.1 classification of exogamous uranium deposits 83
Ch. VIZ. Nzodiagenstic deposits (Type 5i -- 113
Ch., VIII. Deposits of Oxygenous shoot oxidation (Type 6) 133
Ch. IX. Deposits of oxygen-fro* oxLdatton.(Type 7). Deposits Lai.
all-boating carbonate rocks -- 160
Cho X6 UrsoLum-bLtuaLsous depooLts is sommetamorl
rocks 213

i , -- - - -.-- - --- - -- - - I -
I
- I
I
I

BATULD', S.G.; GOLOV111, Ye.A.; ZELENOVA) 0.1.; KASHIRTSEVA, M.F.;
KOMAROVA, G.V.; 4~Ll;LR~AT,IYEVA, I.A.; LISITSIN, A.K.;
PERELIMAN, A.I., doktor geol~-miner. nauk; SIDELINIKOVA, V.D.;
CHERNIKOV, A.A.; SHMARIOVICH, Ye.M.; MURADOVA, A.A., red.
[Exogenetic epigene uranium deposits; conditions governing
their formation) Ekzogennye epigeneticheskie mestorozhdeniia
urana; usloviia obrazovaniia. [By] S.G.Batulin i dr. Moskval
Atomizdat, 1965. 323 P. (MIRA 18:5)