SCIENTIFIC ABSTRACT KONK, V. - KONKIN, A.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000824310005-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: December 30, 2016
• Document Release Date: June 19, 2000
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

KONK, Vladimir, inz., architekt; WENCL, Zdenek, inz.
A new air station in Ruzyne. Letecky obzor 6 no.7:194-195
162.

KONIKAY Ye.; BEKMAN, V.
Abroad. Avt.transp. 41 no-10:52-58 0 163. (MIRA 16slO)
1. Zamestitell predsedatelya Glavnogo pravleniya professionallnogo
soyuza rabochi" transporta i dorog Pollskoy Narodnoy Respubliki
(for Kon'ka),

___ KONKABOEV, YS.K,
Working and free tims-of miners in the Karaganda Basin and ways
of its efficient us during the period of the large scale build-
ing of oommunistd Nauch. trudy KNIUI n0.14:530-543 164. (MIRA 18W

XONxkSfwAUv, 0. X.
r
Popular razakh geographical terms. Isv.AN XiLsakh.MM.S*r.g~og.no-3:
151. (KM 10: 2)
(geograph.-Tervittioloff )
(XLskah langmap-Glossaries, vocatularies, etc.)

. K
G.; AUMKIROT, Zh.
Brief Russian-Kazakh terminological dlationar7 of physical geography
[in &saktk with summmT In Russian]. Test, AN Kazakh. SSR 14 no.3:
50-63 Mr 158. (KIM 11:5)
(ftelcal geography-Dictionaries)
(Huslan lan~-Dictioriaries-razakh)

IT
ABMIAKMNOT, A.A., kand.filolog.neuk; DOMIDZZ,.G.I.. kand.filolog.nauk;
KARKrSfflffA, Dzh.Kh., inzh.-kirtograf;.,_,K,MMASECUM..G.K.,P kand.
geograf.nouk; ROROXIXA. Z.P., tekhn.red.
[Instructions for the Russian transcription of geographical name
in the Kazakh S.S.R.] Instraktotia po rueskol peredsche geogra-
ficheskikh naivanii Kazakhakoi SSR. Alma-Ata. lad-vo Akad.nauk
Kazakhskol SM. 1959. 13 P. (MIRA 13:2)
1. Russia (1923- U.S.S.R.) Glavnoys upravleniye geodesii i
kartografli.
(Kazakhstan--games. Oeographical)

KONKASHPAYEV. Gali Ronkashpayevich; GLADYSHEVA, Ye.N., otv. red.;
9MWWVA, M.A., red.i KHUDYAKOV, A.G., tekhn. red.
[Dictionary of Kazakh geographical names] Slovarl kazakh-
skikh geograficheskikh nazvanil. Alma-Ata, lzd-vo AN
Kazakh. SSR, 1963. 184 p. (MIRA 16:11)
(Kazakhstan-Geography-Dictionaries) .''I

G. KONKASUAYEV.
Ekonomicheskaya Geografiya Kazakhakoy SSR (by)
M.Sh. Yarmukhamedov (1) 0. Konkashpayev. Alma-Ata,
Kamakhakoye Uchpe#giz, 1960.
87 P. Illus-P MaPs.
Title and Text in Ka2akh.
"Uchebnoye Posobiye Dlya 9 Klasea.11

KONKASHPAYEV, G.K.
Some difficult ot understand geographical names in Kazakhstan.
Trudy otd. geog. AN Kazakh, SSR no.9:240-243 162. (KRk 15:6)
(Kazakhatan-Names, Geographical)

A
ML
pro~~
i, U~'d ft~ the iu,! mom~,r
77

Koniuv, n.
"Question on simplifying and improvin.c, the accountiri, system.11
p. 1 (Otchetnost I Kontrol, Vol. 6, no. 12, 1957, Sofiia, Bulgaria.)
Monthly Index of East Euzopean Accessions (YMI) LC, Vol. 7, No. 6, June 1958.

KONKILEV, N.
Increased labor productivity, and decreased cost price in the
V. Kolarov Plant ror High-#bltage Equipment and the Troyan Plant
for Small Electric Engines. Mashinostroene 11 no-7/8:53~-54 Jl-19
162.

KONKIN.A.
Sports mastery Is growing. Kryl.rod. 6 n0-9:9 S'35- (MMA 8:11)
(Mordovla--P~wachutists--Compatitions)

85-58-1-9/28
AUTHOR: Yonkin A. (parawk)
TITLE: The Vocation of Alexander Pankov (Prizvaniye Aleksandra
Pankova)
PERIODICAL: Kryllya i.odiny, 1958, Nr pp 10-11 (USSR)
ABSTRACT: This is a biographical sketch of Alexander Pankov, sports-
man-parachutist and instructor, former student at the
Gomel' River Tekhnikum and Gomel' Aeroclub.
AVAILABLE: Library of Congress
Card 1/1

-- . KOIjI~Iff,-,A....(Saransk)
Vhere are all the clubs? Irrl.rod. n no.1:23 Ja '60. 4
j
(KIU 13:5)
(Saransk-Airplanes-mMels)

HELKINP A.; BORISOV, A.; GENIN,, B.; GUSLITSER, I.; GRUZDEV, V.; DICH,S.;
DUSEYEVA, Te.; YEGOROVA.. A.; ZAK, S.; KAZYMVp A.; KRUPENNIKOVA.Te.,-
KONKIN.-L,- MOGILEVSKITq Ye.; FAISHVER, A.; SHELXOV, G.;
CHICHIMIANI, A.; CHUGUNOV, K.; SHIFRINp L~; TUNOVICH., E.
Sergei Alekseevich Tairov. Khim.volok. no.3279 162 '
ZMIRA 16:2)
(Tairov, Sergei Alekseevich)

.1 KONKIN, A.
To hero-stratostat pilots, Kryl. rod. 24 no.8:36 Ag 163,
(MIRA 16:8)
(Balloon ascenbions)

AGRANOVSKIY, I.; ARANOVICH, B.; BELYAYEVA, V.; BOLISHAKOV, A.; GRUZDEV
V.; LICH I
p S.; ZELENTSOV, I.; KONKINP A.; LEVIT, R.; MIKHAnGVP
N.; MOGILEVSKIY, Ye.; SERKOVy'A.-;' S'MELKOV, G.; SNETKOV, N.;
SOROKIN, Ya.; SHIFRIN, L.
In memory of Vladimir Sergeevich Smurovp 1897-1965. Khim.
volok. no.208 165. (MIRA l8s6)
USSR/Farm &I-J-MIS - 0,~n~:ral Probjini.
Abe Jour 'LLI= - Biol-p NO 1-~)~ 191, " 33275
Author
Inst Aijia-Ata Institute 0~ ','Ooioa and Votarinary H I
Title 'rho Dev.-,lopment of Aniriial Husbandry nnd Feedin,-
,;.ii %-,tona Situatad DoWuii 13A ana Karntal
Or"Ir: P,,.b -,'lb. nauclin. tr. obshch3st-v.-~~Icon. kafedr
14-100
zoovc:-U-. :ix-ta,411-ma-k-a, 1957,
Abstract Do abstract.
Card 1/1

- Cand-. Tec h.-I'Vie- ---- -- --- ---
Dissertation: "Development of a New Method for Separating Cellulose from Wbod.11 IbIlco'd
Textile inst. 23 Oct 47.
SO: Vechernyaya Moskva, Oct, 1947 (Project #17836)

-comparlium d es"Wok"M andullms aid
A. Z. A. Rallovie.
Zhur. Pri&W. Khi;*.:'(rNftft:!x-) 2S. W-44
(1111W.-Tior say. of VYLW speciawas in 4M. alkalies Is
much higher Our; in that of ckgrAded cvlktkw hydrate;
I The xylan opeckriens t v Tgd. from straw by 24w.
hollin wkb FW, thm wkb 81=011 in an atm. of N
or Mus. ., ;W? . foizwlf fly ,. 0( WON a" Wit-
~` Islintion AcOlf; the product contained 3.2% UeO
.iusd 41-44%`oOgIl groups and was a dense gmyr~&!. Its
tM211111tut with CIO, (04%) at 1&-301 for " &y9 ft-
moved ftsidual livin. vrkh consequent goin. will repptu.
as the above. Tbr alkab soly. is explalued by a -- cl
Primary IW thsin groups Its sylaw and a kmv total no,
of Off groupa, in comptroon whit w1julm; thin rww.
fin InterrhAn If-bond fornusiou. Nitration of Plylan
(46% llN0# 43~ Hs!n, and I'M PA ruixt. (cw 2-9
bre. at G-2)~ ;;,~c 92-830 yi,-Ms of nil"Mykane t
.102-10.9% N. Le.. replacewnt a( I.#M1 Oil units 90=n:
sail: the products Were incompirtely VA. in cellulose
Ditrate solvents (111M solo. In MrCO. for examilk).
A Ac,0-AcOII, with pyridirw. 1r.
celt'll ion by Ac.
I(% , or ILPO. catalysts. 'of 1-4 hn. at 30-140 the."
at 7(t-) prCXWdS nRWh (Alftf th.,n the rcActiocu wftb
cellulow. iro,wr. Aero alone at 140* Catift-2 P&"iAl
acrtyLation; Nin. of ll#S0. 1,.Ads to ignificant hydrall
I'L., hut lf.1`04 ur-M 16th Ar.0-AcOll mists. is Most
'1W1ljI;n,t(Wy 1_ X;qjjjg tfw)",, yihis of di-tllxyLM.
Almot Withotit hycifoly'sk; th~ Pro,10" is sol. in IM"als
for compttl! CCtylAtM MlU:01W (CliCil. Clio"). is
Insol. ill f%a Aeration at loins. of xylan in CVPCAN-
Monium soln. or h'; NaOll at 25- M%Ultz in Pr
o2wation, as ii ill,- caw with ctiltdo- hydrate. ISM a
print-iry Oil gtoup I, not ru-cciviry for th6 degmilatiOn.
NI, KM)6pm

BUYMOVA, #.K.; VDWRADOTA, L.M.; ROGOVIN. Z.A.
Iffect of the composition and structure of monoses snd aglucons on
the resistance of glucosidei to the action of acids. Soob.o navah.
rab.chl.VIHO no-3--l-5 153. (MMA 10: 10)
I (4dralyals) (Glucosides)

XORKIN, A.A.; KRYWVA. R.A.; ROGOVIN. Z.A.
Effect of intermolecular interaction on the resistance of the gluco-
side bond in a cellulose macromolecule, to the action of hydrolyzing
reagents. Xoll.zhur. 15 no.4:246-251 '53. (KLRA 6:8)
,-.-' I' 1 11 ;- -11
1. Mookovskiy tekstillnyy inatitut. Kafedra iskusstvennogo voilo-kna.
.(Cellulose) (Ikvdrolysis)

Eff,~, .f nn:.- , I . I - I I
~ ~ij!,: lt-3,! !T: ',1 1. '. I ~ - !- - - ~ 7 : I . .. .-
1, :-v .11 1 -1. 2 ,~, 1, .., . I
~ :1.1 - -- - . - ?~ ~"-- I .- - -.-.
I .! ;: 1; t . .. - c - i ,
I

~h na. les Ed
IM kat vt M, (1)
C dellpffimtka
VA&L floui (150 C.) WIG 0 140, W'670
Crow and Befto I it pentasaw, and 26.i%
is a I xMt. oficoatc. HCI catalyst Was
vwkm teMP& Wd for Various times, am the
T
rip v!pd., washed vM I and with hot FW. driod. and am-
lzmed. The Orate wo toucd. is wow at IM-400 to lrj,-
20% 11 aud a total wilds of 30-40 the dark sirup washed
AAO.aaddriedat 100*."
0.10%. and
Ai i di coUCII. ot 6.ft, OMS, 0.05. =d
_hfttCd r" OA hr. at 1W* the pulp yield (M) was 57.3.
'41.3,40.9. mud 40.5%: ;~~Idse In pulp 78A0. 78.00.
77Xi5,%tnd7T.I5%;UktqqtpI9.5 1.43,410,andl.03%;
Wtosans (V) im pulp 434,3.34. 1.40. md 1.40; Cu no.
of Pulp 0.6g. 1.45, IM. and 0.67: the yield of It from
the I ext. (ai % of the total U dismWed (VU)) was 83.50.
and 93.90. For a HO'Concu.-of 0.05%,
and 1800'&t,1.9, 15.aadgOnatu., %11143.8,43.2.41A.
T" JW4O9!%TVW-S W-S
2.4. LV~Q 1.2. F. V, 9-0 330. 2M. 1.54. ad 1.49,
VE U1, 0-70AZO. and 1.00; 89.5, 89.5. 00.0. and W.9;
andAiree of polymerlatim of pulp ~-, MO, 5W, and 416.
At iw- -ITO IBD- and 0.2% act, aad at 160 and 180* and
Y1 igM was 43.5,40.3,40.0.55.3. and 40.9.
ifid % H fn 3.792.7,4,2. 1.4-7. " 1.4. 'to a
study cg the tifeertl I an cellolbse, it suffite pulp (VM)
87.3% IV# V1 IJ. suad a cuprawmmituu,viscosity Stuff 5%. MeLCO CO-5%. =d MesCO + W%'iflo. 00~-
:5%; mmdded X wms-.sol. in Acuff. dio~ 1Wf( I
M 'i Ivi Mopa" at I Conea.) W= heated 30 mia. NaOH solo., C4%N,- and 1, whm=s X dried;af 100 di~'$
at ISV w1th I cwtg. OASOIEECI, 0.05% HCI and 0.05% solved with coaskeraMe difficulty. The catfiehydrate
NEW. ad 0.134% ff",a- the [U-(b..d ;~X2
VM) was 834. 904, aA 412; %W conteat of undded X was 5.6%. zaade up of 312% g"(01
68.0. 77.1, ead 72.8:' ~ 11
Vt 0.40.0.4D, =d O.W; ad M 89.7,44.0. and 48.2-mt(H- sans and 2.49% heuiwm; X pVtd. from AtOW wit I
tcantzdaedl%carhohydrate. UpovitrratmeatcWKwitts
Pavm. When wood was hydrolyzed 2 hrs. at 1000 with a , 5% soin. of I(M,. it bcame jaso(. in 1. Acuff p(lou,
1% w1n. of HCS (too im wt. 21%. and pdyzeeftaddes di*- I-'andI%NaOHso1n. For
wEved 18-1%%. at whkh 7-617* wts pentasaus and it- 0.02,0.05, aud 0.05% and exto. times of 3M
12% bevacuts. with Wk change im U coutent). washed, =d 4 min..,the VU was 93.96. 9U-88, 83. MA 8V3.5, ami
dried. aud hexted I hr. at 1606 with I without ,Myst, g8 5%. the % ()H j. X S.79, 10.1 . I 1 10
9 o 54 ifa, m
5S% of the U was ds*Avcd; 00 11 Was Muoved from tu!-
";i i 1,40; ind the % OW W1,14.7.-.15^ (4.4. a
hydrolrad wood. and It is assumed that during hydrotyns, _ Mp. rhe O&je contenj Q( -&-d X I I Q'v1,'
bouds am got bKwew & PLtct O'n aad the hydrolywd of -i pptd, 3 times froM AcOH IuVaMA X I
effuldsm Mral thmin M could be solveat fmc-
damfcd.* MR + 10% RIO, dissotred 70% X. anhyd. ~ MaOff 9'ala, 17%. and of x Irciled'with 5% 13%.
10* Let= K=vs;

I'MIMT A -A.,
The comittee on ftain Prime (of the Comil of Ministers UGO) in the fields of
science and inventions announces that the following scient1fic vortsj, popular scien-
tific books, end textbooks havo been submitted for competition for Stolin Prize& for
the Yeare 1952 and 1953- (~gn!aM Wturs, *neov, No. 22-40.. 20 Feb - 3 Apr 1954)
Nam
TIUS of work
*almted ?L
Rogovin Z.A.
Shory'rina, N.N.
Konkin, A.A.
"Cheml-stry of Cellulose
Pnd Associated Com-
pounds"
Moscow Textile Institute
SO! W-306a, 7 July 1954

tire
I w 4::,~ was
e I a mmtytlttw of cellulost ill -i
~k~ .1 t~i~efyL-A,tlo io" 1.
n the p.rtW ~rw,i -4 ir.-':
pha.,"- Th~ tff~z, ,I th,
i lctlluk~ and t tir
also stedied. "A If

cl (bt rule -,f
lill('1~1~0.'oxy;.41u)ose, alzinic. and pe~,ta

a 1.~

fb~
~ - v -- f-, - - ~ , -, - - , z:,
-.I?! n,

lure ai fargad ftie E,
rT-
,U
'
'elementar unit on
StabilUty ot acecal UaLdge Ld molecuf;i:
d dt- mad palyeacOaddes, & A, Rogovia, A. A. Kankinj
and Yu- KAZZ;W;WR~-
' . .
K4tatz
t reak al; Spdrabrolli, Akda". Ivas(k S.S.S.R'.
OWL Khirx. Xamk 1955, ~ S'21-32, cf.-, C.A. 49. 0209f;1.1
foltowi-ig abstr.-Replacetuent, of the I-CHO group by
C()4f( gre-atly stabilizes thc acelat listkage to fiydialyils in
"balic saln. Wt!(~ in the elinsition dLvs not chanlL the
Istabil(Cr of aretal tow"d acidg, but 1,"karboxyhdatl
undcr all couditious. Ab.

=,,c- of the pcitwxrv 110 group mduc~s hydrolytic statit
ifity
-
~
reetl
if
a
!u
l1
k
of
H
SO

.
u
ca. (
Le
a
,
c
C
, aq,
4 g
y
reduces the rAte of hydmlyiis, G. M. Katulappli.

KONKIN.A.A.
Science In the serviceof Industry. Te-k-st.prom.15 no.10:6-8 0'55.
(MLRA 8:12)
1. Nimchnyy rukoyodltell Yeasoyusnogo nfmchno-imeledovatel'skago
instituts iskusStVGUnOgO Tolokna
(Textile fibers, Synthetic)

K 0 N N
USSR/Chemical Technology -Chemical Products and Their Application. Wood Chemistry
Products. Cellulose and Its Manufacture. Paper., 1-23
Abst Journalt lWarat Zhur - Xhint4st io 19, 1956t 63349
Authort Konkin,, A. A.., Kaplaup fi. I*,, Rogovin., Z. A.
Institution: None 7e r/4 6
, L5
Titlet Comparative Investigations of the Rate of Hydroly3-is of Xylan and.
Cellulose
Original
Periodical: Zh. prikl, kbimii, 1955, 28., No 7) 729-734
Abstract: Rate of xylan hydrolysis in a homogeneous medium is about 4 times and
in a heterogeneous-medium 70 times higher than that of cellulose. The
principal factor that determimes the higher rate of xylan hydrolysis,
as compared with cellulose in a heterogeneous medium is not the.com-
position of the elemental units but the different physical structure
of these polysaccharides which determines the difference in intensity
of intermolecular interaction.
Card 1/1

UXJR/Chcn,~c:~l T,:chnology. Clicride.--:1 Product3 1-26
cnd Thoir Applicctjon--,S)ynthct-f.c fibcrs.
14
:.ba Jour: Rcf Zhu a, No 3, 19'57, loo'
111.1thor 1--o and lCudry-vtscv, G. I.
Inst N-ot--gTv-c-T-~
Titlc The Phy5lcochcnical Pronertics of 3-mthotic Fibcrs
Ori.- Pub: TcIcstilln. prom-st, 1c9:555, No G, 9-111
Abstract; A survcy with a bi,-)lJ.ogr-,phy covcring 7 itcms.
Cnrd 1/1

MwU

2nd 6
'wlz
h~
tem
"
n'w
Ii
ht - I
d
p.,
of
y.
~g
g
g
And an

USMANOV, A.N.;XMWAYfS, J.&.;&HJWAJaN, X.M.;BWCSWVSKrY. B.M.;
SIMTM. S.X.; WPOWITSXAU. T.A.,; RWOF3. 2.
In owmory of A.A. ptz"Meev; obltyaryo thureab.khin*2.6 noellx~.224-
3226 N 9560 Ow lbli)
(streplkhow, Aleksandr.Aleksandrovich. 1912-1955)

FAKSHYAR, A.B., doktor tokha.usuk. red.; MIKIN. A.A., doktor tekhasnaukq
red.; XUXIII, G-U.. doktor Te.M.. red.;
K&DMAY, L.Ta., takhn.red.: rOGAN. V.V., tekhn.red.
[Handbook of analytical control in the manufacturing of artificial
and synthetic fibers] Spravochnik po analiticheekomu kontrollu v
prot2vodetva iskusstvennykh i sintaticheskikh volokon. Kook", Go$.
nouchno-tekhnoizd-vo lit-ry pe legkol proarahl., 3.957, 565 p.
(MM 11:2)
(Textile industry-4biality control)

IM'"Y71T, A. A. 'Joc Tech Sci -- (di~-) U,e
Or 4QL.A,
in cellulose and zbo othcr rol'.'sacebaricles undr- nf, -Ict4en of hydrol zinp,
,0 19"t. N7 '0 e
I . \21 cm. (Yill'plli~hnr ''d tl~fll. l' s TP tij... -,r,,stjtut4,,),
120 co-:Ans
Qa-,

,ORIN, A.A.; KOTINA. V.Ye.; DXKINA. N.V.
Bffect of the scale factor on the properties of man-made fibers,
Tekst. prom, 17 noo8t2O-23 Ag 157. (K18A 10tg)
(Textile fibers, Mrnthetic--Testing)

---- I,",, i
-- --- - -
KAJ4.1 6A-,j;and. tekhn. rauk; PNTUXHOY, B.V., kand. tekhn. nauk.
Production of dacrou fibers in the U.S.S.R. Takst. prom. IS no.I:
15-16 A '58. (MIRA IIr2)
(Textile fibers. Synthetic)

FINKILISHTXYN, T,Ao; NIKOLATWAO U.S.; KONOYAWYA, Ye.M.; KORKIN, A.A.
VXRIITXMMDYAO T.P.
Cellulose grinding on a vlbra.tor7 will. Tekst. prom. 18 no.2,.16-19
F 158. WRA 13:3)
(Cellulose)

MOTOPINA, A.T. - KONKIN, A.A.
r,
Effect of temperature on strength and lengthening of chemical
fibers. Taket. prom. 18 no. 7:18-26 Jl.'58. (MIRA 11:7)
(Textile fibers, Synthetic)

KONKIN, A.A.; RYMASHBVSKAYA, Yu.A.
lanthogenation of the cellulose preparations. Zhur.prikl. khim.
31 w.3:459-V5 Mr 158. WRA 11:4)
(Cellulose xanthates)

76-32-4-26/43
AUTHORS: Konkin, A. A., Shigorin, D. N., ITovikova, L. 1.
TITLE: The Infrared Absorption Spectra of Monosaccharides and
Polysaccharides ( Infrakrasnyye spektry pogloshcheniya mono- i
polisakharidov)
PERIODICAL: Zhurnal Fizicheakoy Khimii, 1958, Vol. 32, Nr 4,
PP. 894 - 903 (USSR)
ABSTRACT: As an introduction the present paper explains the possibilities
of the types of hydrogen bindings in mono- and polysaccharides
and mentiones two basic types. It is pointed out that the
investigations carried out hitherto by means of infrared
spectroscopy for the purpose of determinin- the types of hydro-
gen binding by observing the position and diffusion of spectral
bands of the OH-group of polysaccharides are insufficient. The
present experiments deal with the investigations of mono- and
polysaccharides as well as of polyatomic alcohols, rith compa-
risons of the spectra being carried out to solve the problem
Card 113 of the function of the absorption spectrum of the hydroxyl

76-32-4-26/43
The Infrared Absorption Spectra of Monosaccharides and Folysaccharides
groups on their geometri-cal distribution within the molecules
The measurements were carried out by means of atAKC-11
spectrometer with a Nernst rod as source of radiation; the
results obtained are shown on tables and graphically as well.
Among other it was observed that in d-Clucoses anrl d-xyloses
both types of hydrogen binding are existing (I. -0-H .... 0-H....O-H
and II. -0-H ... 0-11). The spectrum of d-galactosis shows two
strong low-frequency bands 3120 and 3206 cm-1 which points at
the presence of a greater number of bindings of type I. In the
rest of the monosaccharides, on the other hand, also character-
istic phenomena were observed, the explanation of which needs
detailed structural investigations. The investieations of poly-
atomic alcohols showed that, for instance, a difference bet-
ween mannite and xylite consists of the fact that the latter
has more bindings of type I. Based on the spectral analyses of
polysaccharides the energies of hydrogen bindinEs were deter-
mined and a closer classification of the relative intensity of
Card 2/3 intermolecular interactions was carried out. The energy changed

76-32-4-.26/43
The Infrared Absorption Spectra-of Monosaccharides and Folysaccharides
4 - 6 kcal., the highest value having been obtained with
cellulose..As final conclusion the change of energy of
the intermolecular interaction is given as follows:
cellulose's amyloais~ xylan~ lamirarine7 galactan. There are
6 figures, 2 tables and 12 references, 5 of which are Soviet.
SUBMITTED: January 8, 1957
AVAILABLE: Library-of Congress
1. Monosaccharides--Spectrogtaphic analysis 2. Polysaccharides
--Spectrographic analysis 3. Polyatomie alcohols--Spectrographic
analysis 4. Infrared spectroscopy-Applications
Card 3/3

KONKIM, A.A.I:BIRGER, G.Ye.; GRUZIW, V.A.; PACSHM. A.B.; TSTIMOVA,
red.; =PAX, Ye.G., takhn.red.
CSynthstic f1berej ZhImicheskie volokna. Moskva, Gos,nauchno-
tekhn.Izd-vo khlm,llt-ry, 1959, 50 p, (XIU 13:2)
Tea'so"yl'us*~n'j~*P"naiiil6o-lssle'd-ovatellakly instit-ut Iskusetvannogo
volokna.
(Textile fibers, Synthatio)

18U
11 1 -11
X4
it
Ajai Is
-Ii
'A aw
Jog
AA
it
43
jai
Ila I
lag

SMOVA , A. T. ;-KONKIII, A.A.; KOTOMINA. I.N.
Preparation of extra-strong viscose cord. Khim.volok. no.l:
15-21 '59. (MIRA 12:8)
1. Vaesoyuznvv muchno-teeledovatellskiy Inotitut takusetyan-
nago volokna.
(Rayon)

14MEL'BA1314. D.I.; XONKIN A.A.
Bffect of the polydisperse state of cellulose on the physical
and mechanical properties of viscose fibers. Report No.l.
Xhim.volok. no.1:22-26 '59. (MIRA 12:8)
1. Vaesoyuznyv nauchno-iseledovatellskiy inBtitut Iskusetvan-
nogo volokna jqe1lulose) (Rayon)

SRUKA-WVA. Ya.A. ~ XONKIN. A.A.
Kinetics of Cuprammonimia fAber swellinge
sav.; tekh.tekst.prav. no.1:141-147 '59.
In water. lzv.vye.ucbeb.
(MIR& 12:6)
1. Moskovskly tokstillWy Institut.
(Rayon-Testing) (Textile chemiatr7)

FZT1JKHOV, B V - KOWIN A.A
=1 '7
Technology of the manufacture of the polyester fiber "lavsar'
Xhim. volok. no.2:11-16 '59. - (?URA 12:9)
l.Vseso7wWy i~auchno-insledovatel'ekiy institut iskumstvennogo
volokna.
(Rayon)

?4ANIZLIB&UMO D.I.* MMIT A*A , S.HULTATIEDVA, N.V.
~09,09~6,,
Zffect of polydisPerse state of cellulose on the physical
and.mechantIcal properties of viscose fiber. Part 2.
Xhim. volok. no.2:35-W '50. (KIRA 12:9)
ijoesoyusnyy nauchno-Issledovatel'skly institut iskusstvennogo
volokna.
(Cellulose) (Rayon)

MANDELIBAUM. D.I.; KOHMKIM. A.A
#0 Moftaw
Iffect of the natural structure of cellulose on the physical and
mechanical properties of viscose fiber. Khim.volok. n0-3:23-26
'59. (MIRA 12:11)
1. VsesoyusMy nauchno-lealedovatellakly institut iskuastvennogo
volokna (VNIIV).
(Cellulose) (Rayon)

AREA 'SKIT, D.N.; ROGOVIN. Z.A.;_.~~~
Iffect of the concentration and nature of the acids and sulfate*
used on the ap:ed:of saponification of cellulose x th te.
An;9 '13: 2)
&1m.volok. n .4 23-26 159. N
lo Vessoymmsyy nauchno-looledovatellakly InstItut inkmestvonnogo
volokna i Hookovskly tekstilln" Institut.
(Cellulose xanthate)

SZKOV, A.?.,- KDEKIN, A.A.; EMKIM. 1.I.; SHUMNA, YO.V.
Surface phenomena occurring In the system viscose - spinnerst -
precipitation bath. Zhin.volok. no.5:31-33 '59. (KM 13:4)
1. Vessayurgy n&uebzo-issl*dov*tel'GldY Inatitut Iskusetvennogo
volokn-a (VNIIV)o
(Viscose) (Plap4) (Owqac* chemistry)

ARKHANGILISKIT, DAO; ROGOVIN. Z.A.';--XONKIII. A.A.
Bffect ofthe composition of the percipItation baths on the
swelling of viscose fiber. Xhin.volok. no.5:36-38 159.
(MIRA 13:4)
1. Voesoy=Wy.nauchno-looledovatellakly institut Iskusetyennogo
volckna (VVIIT) i Haskevskiy tekstilInyy institut (HTI).
0"*Cose) (Rayon)
4j,

15M S/1 Fi 3, /59/00c/06/002/027
AUTHORS: Serkov, A. T.~, Shevchenko. A. S~7 B004/i/B'007
Kotomina., I,, I., Kankin, A.
TITLE: The Application of-Surface-active Substances in the Production
of Viscose Fiber"
PERIODICAL, XhimicheskiY volakna~ 1959, Nr 6, pp 3~.i! 0,9510,
ABSTRACT: The present paper ia based mainly on Vlostern publications, the
data of which haveg in some cases, been chacked by the.authorat
own experiments. The quality-improving effect produced by sur-
face-active substances is pointed out (increase in the strength
of vincose-oord by 50-7(Yla). -Th-9 conception of a surface,-active
substance (modifier) iz defined and i'-,j mode of operation,is
explained., There follows a survey of the application of such
modifiers in the mercerizationg xanthlogenation, and spiming
of viscose-solutionn, Mention is made of the investigation car-
ried out by Ye~ M. Lev of the emulsification of carbon disul-
phide by qebac--c acids (Fig 1), where the most atable emulsion
is obtained by m9ans of sebacio acids with 5 to 7 C-atoms. Fig-
uren ? and 3 show the offect of Rarol viacf) 30 upon the rate
of filtrhtion and the clearnese of' the visco8e,. Table 1 in this
Card 113 connection gives the results obtained by L, !31oed, H. Rauch

The Application of Strfaae-aotive Subatances in the I~ro- 3/1,33/59/000/06/OWM
duotion of Viscose Fibers B004/13007
and K. Goatze (Ref 1). The influence exerted by the modifiers
upon the elimination of air from the viscooe is disausned,
oxyethylated aliphatic amines give leas stable foam than sul-
phurized sebacic acids and oxyethylized alcohols. Tables 2
and 3 mention Western reaull.8 (Refs 1, 2) concerning the nec-
essary additions of modifiers and their effect upon keeping
the spinnerets clean. Figures 4 to 7 3how the effeat of the
concentration of H so ZnSO Ila so and of modifiers upon
2 4# 4P 2 41
the adhesion of the viecoee to the spinnereta a-,cording to ref-
erence 11, which was confirmed by experiments carried out by
the authors. Table 4 shows various modifiers of ~.,Yestern origin
(aminesi quaternary ammonium compounds; polyoxyethyl derivatives)P
which are used for the purpose of obtaining strong viscose fibers.
Table 5, figure a show the exparimental results obtained by
the authors, according to which amines with to 9 C-atoms'~ ive
particularly homogeneous fibers which swell only little in
'water. Table 6 shown the effect prod-oced by the Oxyethyl-grOUp
Card 2/3 content of the modifier upon the properti~)u of the fiber (Ref 16~

The Application of Surface-active Substances in S/183/59/000/06/002/027
the Production of Viscose Fibers B004/BO07
Table 7 and figure 9 show the dependence of the effect produced
by cyclopropane on the concentration of the coagulating
bath (Ref 16). There are 9 figures, 7 tableag-and.18 references,
6 of which are Soviet.
ASSOCIATION: VNIIV - Veesoyuznyy nauohno-iseledovatellskiy institut
iskusstvennogo volokna
(All-Union Scientific Research Institute for Synthetic Fibers)
Card 3/3

15(4)
AUTHORS: -Sych, L. S., Kozlov, V. I., B004/11007
A. Aq
Petukhov, B. V., Konkin,
_
TITLE: The Utilization of Polymer-waste of the Production of Lavea
Fiber
PERIODICAL: Khimicheskiy volokna, 1959, Nr 6, PP 12-14 (USSR)
ABSTRACT: Among the waste in the production of the Lavsan fiberg a poly-
ester f1bAr, the hanks of'the godet wheals may be utiliz"u
witnout any special chemical treatment. They are disentangled
on a device shown in figure 1, out up into rayon fiber, and
are used as filling medium for upholstered goods and winter
clothing. The larger part of the waste (rosinified polymer,
waste products of the apinneretay torn fibere) mustg howeverp
be decomposed to the initial product (dimethyl-terephthalate).
The authors mention respective English patents (Refs 1, 2)
and also their attempts at decomposing the polymer by hydro-
ly8is in water or lye and by means of methanol. In water (7
Card 1/3 partB by weight corresponding to one part by weight of polymer)

The Utilization Of POlymer-waate of the Production S/1p, 59/000/06/003/027
of Lavean Fiber B004YB007
decomposition takes place at 20 to 23.atm within.an.bour, at
15 atm within 5 hours. The precipitated terephthalio acid is
filtered off, disaolved and reprecIpitated, and again.-methyl-
ated. In 5 to,7% 1Ta0H (7--to 6 parts by weight corresponding to
I part by weight polymer) decomposition at 9 to 10 atm.takee
place within I to 2 hours (Table 1).,The quantity af-re-obtain-
ad terephthalate depends on the shape and the size of-the
waste products. Decomposition by means of mothanal.is-Aspeoial-
ly reoommendedg because methanol is a waste produc -Of.Lavean
production', dirdctly forms dimet4yl terephthqlatelland there-
fore requires no further ch~cals (Table 2) The dimetbyl
terephthalate,~isld depends on the molecular weight-of.the
olymer (-Fig and on the catalyst used in.itB synthesid
~potassiumantimonyl tartrate, calcium acetate, zinc acetate,
figure 3). The authors recommend 2 to 3 parts by weight of
methanol corresponding to I part by weight of polymer, 26 to
27 atm, duration of reaction 3 to 6 h. There are 4 figuresq
Card 2/3 2 tables, and 2 referenaeso

KONKIN, K.A.- ROGOVIN, Z.A.-
Role of molecular interaction in the hydrolysis of polyeaccha-
rides In a heterogeneous medium. Tysokom,soad. 1 no.2:177-182
7 '59- (HIM 12:10)
1. VaesWuzmyy nanchno-issledovatel'skiy institut iskusstvennogo
volokna.
(Polysaccharides) (Hydrolysis)

BUTANDVA,
~qN~s
Rate of oxidation of polys"charldes In a homoginecum medl=.
Tymolms. soed. 1 noo6z889-893 ja 159. (Km 12:10)
l.Vessoyusnyy nauchm.-Iseledovatellskly institut iskunstyennogo
volokna. -
(Palreacchardles), (Oxidation)

MOTORIVA, A.V,; XOPKIN, A.A.
Iffect of the medium on modifications in the mechanical properties
of synthetic fibers during thermal treatment. Tekst. prom. 19 ne.6:
52-55 Je '59. (Textile fibers, Synthetic) (MIRA 12:9)

50) SOV/80-32-4-26/47
AUTHORS- Konkin, A.A. and Rogovin, Z.A.
TITLE: The Principal Regularities in the Hydrolysis of Polysaccharides
in Homogeneous and Heterogeneous Media (oar-ovnyye zakonomernosti
gidroliza polisakharidov v gomogennoy i geterogennoy sredakh)
PERIODICAL: Zhurnal prikladnoy khimii, 1959, Vol 32, Nr 4, PP 852-857 (USSR)
ABSTRAM. The present paper represents t-he 73rd communication from the
series of investigations tnto the structure and properties Of
cellulose, and the 12th communication from the series of
investigations into the process of hydrolysic of polysaccharidee.
The authors discuss certain general regularities in the hydrolysis
of polysaccharides in homogeneous and heterogeneous media and cite
the data on the correlation of hydrolysis rates of polysaccharides,
disaccharides and "monozid"s under various conditions in a table.
The conclusions drawn by the authors from their own experiments
and from literature data are as foilcws~ 1~ The ace-tal bonds of
polysaccharides differ insignificantly in resistance to the action
of hydrolyzing agents, As far as relative resistance of acetal
Card 1/3 bonds to the action of ae~ids is concernedg the polysaacharides can

SOV/80-32-4-26/47
The Principal Regularities in the Hydrolysis of Folysaccharides in Homogeneous and
Heterogeneous Media
be arranged in the following series of decreasing resistances chitin>
cellulose)galactan>mannan~laminarin)xylan)amylose; 2. The resistance
of acetal bonds with respect to the action of hydrolyzing agents does
riot depend, as a riile, on a degree of polymerization of polyeacchari-
des; 3. The hydrolysis rate of polysaccharides in a heterogeneous
medium is determined by their physical structure which, in its turn,
depends on the peculiarities in the structure and composition of
macromolecules. According to the relative rate of hydrolysis in a
heterogeneous medium, the polysaccharides can be arranged in the
following sequence; Calactan>laminarin,7xylan;,amylose)mannan),cellulose)-
chitin.
There is 1 table and 11 references, 9 of which are Soviet, 1 English
Card 2/3 and I Danish.

SOV/'80/32-4-26/47
The Principal Regularities in the Hydrolysis of Polysaccharides in Homogeneous and
Heterogeneous Media
ASSOCIATION: Vsesoyuznyy nauchno-isoledovatellskiy institut i.skul3stvennogo volokna
(All-Union Scientific Research Institute of, S;rxt~_et-ia Fiber)
SUBMITTED: December 2'1, 1957
Card 3/3

5(3,4) sov/8o-32-5-26/52
AUTHOF.S. Konkin, A.A., Shu"lova, Ye.A.
TITLE; On the Role of Diffusion izi the Hydrolysis of Polysaccharides in an
Heterogeneous Medium. Com=nication 13.
PERIODI,CAL: Zhurnal prikladnoy lehimid, 19559, 7,1`ol 32, Nr 3, PP 1076-lo8o (usm)
ABSTRACT: The study of difPjaio., i processes has a great significance for the
hydrolysis of polyeaeoharides by weak solutions of acids. The energy
of activation of the hydrolytic raaction foizid by the authors has the
value of 26-30 kcal/mcie.whieh is oharact'aristic for chemical pro-
cesses. The chemical reaction rate increases faster with the tempera-
ture than the diffusion rate. Ito activation energy is nearly the
same for polysacaharides in a homogeneous or a heterogeneous medium
and for monooldes and disaccliarides In a homogeneous medium. The
energy is therefore independent of the molecular weight, the compoai-
tion, the structure.'of the ele.Tvatary link and of the macromolecule.
The activation energy in the hydrolysis of polysaccharides arises
from the rupture of the acetal bond. The diffusion of water into
cellulose was studied in viscoae morofiber of 400-800,~w in diameter.
Card.1/2 Diff'usion was determined by the degree of swelling, which was in-

SOV/80-32-5-26/52
On the, Role of Diffusion in the Hydrolysis -of Polysaccharides in an Heterogeneous
Medium. Communication 13.
vestigated_at'.17, 27 and.3706. The energy of.activation was-determined
by the graphic methodas 7,800 cal/mole. This value-is considerably
below that of the hydrolysis of the acetal bond. The diffusion.of the
hydrolyzing agent has no effect an the reaction r 'ate of-the hydrolysis
of polysaccharldes. Sharkov has shown that the rate of hydrolysis of
cellulose does not depend an the duration of the preliminary soaking.
in diluted.acid.
There are: 5 tables, 1 set of graphs and 7 references, 6 of which are
Soviet and l.-English.
ASSOCIATION: Vsesoyuznyy nauchno-issledovatellskiy institut Iskusstvennogo volokna
(All-Union Scientific Research Institute of Artificial Fiber)
SUE1MITTEDt December 31, 1957
Card 2/2

5.(3) SOV/BO-32-5-27/52
AUMORS;;- Nov.1kova, L.I., Xonkin', A.A.
The Effect -of-the'.Condentration of Acids on the Rate of the Hydrolysis
of Folysacoharldes.4 . Communi-3ation 14.
PERIODICALv Zhurnal prikladnoy khImli, 1959, Vol 32, Nr 5,. pp 1081-1085 (USSR),
ABSMIACT-v The. acet&I bond iA..~ow- ~and--WZ)i-moleaular compounds is resiatant to
the action of wat~i. Its.:rupture is ao'cielerated by catalysts, like
.acids, the-activity ofwhich'ia datexmined by their degree.of dis-
soclation. Z~eltukhin,- KorolIkov ar-d autrkov found the. the rate ~of
hydrolysis is'proportional. to the concentration of the acid /Wer 47.
The -hydrolysis of celloblose, cellulose, laminarin obtained Trom -
Laminaria SaQcharina_i. and VIan_prIl ei from straw according to
konkin's and RogovinIs method /Ref Fis investigated here.-Sulfuric
acid of the concentration 15.77 - 50.9K, and hydrochloric acid of
L04 - 22 *4% were used as hydrolyzing reagents. The rate of lydrolysis
Of cellobiose increases faster thaa the concentration of the acids.
A doubled concentration increase raises the hydrolysis rate 10*,times,
in'laminarin even: 15,,times. . A three-fold increase- of the hydrochloric
Card IIR aAd concentration -increases the hydrolysis rate of: xylan. 40 times. The

50) SOV/80-32-5-47/52
AUTHORS: Petukhov, B.V., Konkin A A
TITLE: The Combination of the Reactions of Reesterification and Polycondensa-
tion In the Synthesis of Polyethyleneterephthalate
PERIODICAL: Zhurnal prikladnoy khimii, 1959, Vol 32, Nr 5, pp 1171-1173 (USSR)
ABSTRACT: Polyethyleneterephthalate is the base of the polyester fiber "lavean!'.
It is produced by the reesterification of the dimethyl ether of the -
terephthalic acid and etkylene glycol to diglycol ether, and the poly-
condensation of the latter to polyethyleneterephthalate. Ethylene gly-
col is used in the quantity of more than two moles per one mole of di-
ethyl ether. Experiments were made to use less than two moles in the
reaction. For this purpose 0.05% of zinc acetate was used as a cata-
lyst. The yield was approximately the same as in the ratio 2.5 : 1.
The products obtained had a sufficiently high molecular weight, which
could not be expected, if the unreacted methoxy-groups had blocked the
ends of the chain. The formed ethyleneglycol remains in the sphere of
reaction due to the increasing viscosity and the ratio may be therefore
Card 1/2 less than 2 : 1.

SOV/80-32-5-47/52
The Combination of the Reactions of Reesterification and Polycon-densation in the Syn-
thesis of Polyethyleneterephthalate
There are: 1 diagram, I graph, 1 table and 2 references, I of which is
Scviet and 1 E%glish.
ASJOCIATION: Vsesoyuznyy nauchno-issledovatel'skiy institut iskusstvemogo volokna
(All-Union Scientific Research Lnstitute of Artificial Fiber)
SUBDUTTED: january 20, 1958
Card 2/2

t /~__s
S_YY0
B/183/60/000/03/04/007
3020/B054
82$63
AUTHORSs Qeller, A. 1,, Konkin, A. A.# Kjagkov, . A.
TITLEx Fractional Composition of Polyethylene Terepbthalatel
PERIODICAL: Khimicheskiye voloknav 19609 No. 3, pp. 10-12
TEXTt It is known that not only the mean molecular weight of the
polymer but also its polydisperaity exert an influence on the properties
of artificial fibers. The greater the inhomogeneity of the polymer
with respect to the molecular weight, the more irregular are the
physico-mechanical properties of the fiber obtained. Polyester forma-
tion and determination of polydispersity of various polyesters was
investigated by V. V.-Korshak and co-workers. Papers by E.. Turska-
Kusmierz, T. Skuarski (Refs- 4, 5), and F. Rybnika'f (Ref. 6) were
concerned with the study of the composition of polyethylene fractions.
In the present investigation, the authors studied the change in poly-
dispersity of a polyester resin in polycondensation and repeated melt-
ing. The type of change in the composition of polyethylene terephthalate
fractions was investigated by the authors under consideration of
Card 1/3

Fraotiaj,~tl Compocition --ir S/18 6o/ooO/03/04/007
Terephthalate B020YB054
82063,
conditions of the technological process which condu'oted on a semi-
industrial scale. This procese.was briefly described in the paper,by
B. V. Petukhov and A. A. Konkin (Ref. 9). A method of fractionating
polyet*lene torephthalate from 1% solutions in a phenol - chloro-
benzene mixture (10) by means of benzine precipitation was studied.
The character of the position of the differential distribution curves
(Fig. 1) for two parallel experiments shows a fully satisfactory
reproducibility of the results obtained in fractionating. The polyester
resin kLavaan\7is produced via two basic stages - trans-esterification and
polycondensation. Data on the polymer composition in the individual
reaction stages are graphically shown in Figs. 2 and 3 under consideration
of the change in polydispersity and chain growth in polycondensation of
Lavsan. The content of low-molecular fractions in the individual resin
samples of Lavsan is shown in the table. The differential distribution
curves of the molecular weight of the resin before and after repeated
melting are shown in Fig- 4. The character of the differential curves
shows that the molecular weight of polyethylene terephthalate slightly
decreases in repeated melting. The polydispersity of the resin changes
only little. Besides, the authors found a distinct tendency to an incresse
Card 2/3 1~

0
3/163/60/000/003/011/016/XX
B004/BO67
AUTHORS: Serkov, A. T., Konkin, A. A., Solov'yeva, N, I., ay~-'
Fedorova, ff-.N.
TITLE: Study of Drawi .ng in Spinning Viscose~Fibers
PERIODICAL: Khimicheskiye volokna, 1960, No. 3, PP. 31-33
TEXT: The authq~rs point to the great importance of plasticizing drawing
to the strength\of viscose fibers. They attempted to determine the condii.
tions un&e-rwhich maximum drawing can be attained. In the present paper
they describe their study of the effect of the v. CS2 content of residual
xanthogenate in the fibers and its structure in the freshly spun state an
the capability of being drawn. The effect of residual xanthogenate was
studied by increasing the distance between the spinneret and the point
where drawing sets in from 1 to 15 m- In this conneotion,yCS 2 decreased
from 11.0 to 6.0. Nevertheless, no changes were observed in the maximum
drawing and in the mechanical properties of the fiber. In a second test
Card 1/2

NOMN, A.A.; RMSMUU, Th.A.; SUMUTIMVA, N.Y.
Chemical heterogetwity of cellulose xmnthsteir. KUm.volok. no.4:
23-26 160. (MM - 13: 10)
1. VassoyusW nauchno-Issledovatellakiy institut iskusstvannogo
volokha.
(Cellulose xanthate)

S118316010001004100910141XX
B004/BO75
AUTHORS: Shevohenko, A. S., Konkin, A. A., Serkov, A. T,,
TITLE: Effect of Amines on the Spinning Process of Viscose Fiber
PERIODICAL: Khimioheskiye volokna, 1960, No. 4, pp.27-30
TEXT: In the introduction the authors state that the effect of various
modifiers which are added to the viscose to improve the structure of the
fiber has so far not been studied. Therefore, they attempted to study the
effect of amines on the formation of the viscose fiber. They used 1) mono..
amines', i.e., a) a mixture of C7-C9 amineaq b) a mixture of C 13-C15 aminee,\
0) cyclohexylamine, and d) monoethanolamine; 2) secondary amines: diethyl -
amino; 3) tertiary amines: triethylamine, and 4) polyamifies: a) diethylone
triamine, b) triethylene tetra&mine. They studied the effect of these amines
on the ripeninj of viscose, the degree y of esterification of the xanthate,
viscosity, and the decomposition rate of xanthate in the precipitating bath.
All experiments were made with the same viscose: content of a-cellulose:
6.3%, alkali 6.3%, degree of ripening 9.5-10-5, admixture of 2% amine
referred to a-cellulose. Composition of the precipitating bath 100 g/1 H 2so 49
Card 1/3

Effect of Amines on the Spinning Process of S/183/60/000/004/009/014/XX
Viscose Fiber B004/BO75
100 g/1 ZnSO 49 240-260 g1l Na2so 41 temperature 450C. Neutralization was
made in a second bath with 60 g/1 NaHCO 3 and 200 g11 Na2so 4~ The xan"hate
content in the fiber and its swelling power were then determined by the
known method of Ref- 5, and the Biruoture of its cross section was studied.
The following results were obtained: diethylamine and monoethanolamine ex-
erted no or almost no influence on the precipitation process, Cyclohexyl-
amino, diethylenetriamine, and triethylene tetraamine proved to be effective
modifiers. They delayed the precipitation process so that the fiber contain-
ed by 2-5 to 3 times more xanthate. The cross section of the fiber was
homogeneous, its swelling power was reduced from 130-135% to ao.-85%. The
effect of oyclohoxylamine waa examined in the pilot plant by means of
* spinning frame of type nH-300-w~ (PH-300-IZ). A rayon cord fiber with
* 34-36 km breaking length was obtained. Hence cyclohexylamine was recom-
mended as modifier in spinning viscose fiber. The surface tension of via-
ccse was not influenced by amines. No chemical interaction has as yet been
observed between amines and xanthate. The authors, however, assume the ac--
tion of trithiocarbonates since in their absence cyclohexylamine does
not essentially influence the decomposition of xanthate. There are 10
fig-area, 1 table, and 7 references: 3 Soviet, 6 US, 2 Austrian, 1 Belgian,
5 Brit~sh, 2 French, 1 German, and 1 Swiss.
Card 2/3

KLMLIBM. D-1--, XONKIN, A.A.; VISiMYAIMVA, K.N.
Connection between the submicroscopic structure of natural and
regenerated celluloseoXhim.voloko no-5:31-33 0" ) -- - ~.'
(NIBA 13:12)
1. VsesoyuzWy M-achno-iseledovatel'skiy im9titut Iskusetyennogo,
volokna (for Yawdel'baum, lomkin). 2. Leningradskiy teketillrjy
institut imed Itrova (for VishAyakova).
(Cellulose) (viscose)

KAYTZL', B.B. (Kithel. B.B.); SEKSTON, U.R. [Saxton, W.R.l: MRGAN Dzh.Te.
[Norgan, J.B*.]; TITKW, Dzh. [Witkamp, T.1'. KATVIMA, Te.l.
Ctranslatorl*,KOlMM4--At&j red.
Spinning of high-tenacity rayon from 100 per cent wood pulp. Xhim.
volok.,no.5-.71-77 l6o. (KIRA 13:12)
(Rayon) * (Woodpulp)

SHWCHNIZO, A.S,; KOWIN, A.A.; MKOV. A.T.
Bffect of bydroxyetlWlated amines on thr process of spinning
wincose fiber. Khim. volok. no. 6:28-30 060. (MIRA 13:12)
1. Tsesoyusnyy nauchno-iseledovatollskiy institut iskusetvannogo
volokna.
(Rayon spinning) (Amines)

a K KIN, Alukundr Arsanoxaxiwu IBTRGU, Goorgiy Yefimovich; DMUNOTI, A.S.@
red*; WVCM=O9 YGoToo takhn,rode
[Miracle fibers] Cbudesnye Tolokna. Nookvs, Ixd-vo 'ftaniO#4
1961. 43 p. (Tsesolusnos obahchostvo po rosprostranonift foll-
t.4,chookikh 1 nouchnykh zwnil. Sor.10, 16olodezhnalai A0.5).
MM 14:3)
(TeztIls f1bem Synthetic)

311831611000100110021006
B101/B205
AUTHORS: Konkin, A. A., Rogovina, A. A., Birger, G. Ye.
TITLE: Present stage and prospects of tire cord production
PERIODICAL: Khimicheskiye volokna, no. 1, 1961, 3-14
TEXT: This is a review of publications on the production of tire cord,
which bases primarily on Western literature. In the Soviet Union, tire cord
is productVfrom cotton, viscose and caprone fibers. As the Seven-year Plan
(1959-1965) provides for a substantial increase of the production of viscose
cord (2.8 times) and capronecord (22 times), 91% of all tire cord will be
made from synthetic fibers in 1965. The review is divided into five sec-
tions: 1) Achievements in the field of viscose and polyamide cord produc-
tion. This section bases chiefly on Western literature. 2) Physicomechani -
cal properties of viscoser caprone, and nylon cord. Besides several Western
publications, mention is made of a paper by V. A. Kargin and a paper by
M. B. Lytkina, Ye. Ya. Yaminskaya, V. F. Yevstratov, and Ye. V. Troshkina
on impact tests: BX (M) cord withstood 50 impacts, cord "Super-super",
129, and caprone cord, 850. The optimum modulus and elongation have not yet
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8/183J61/000/001/002/006
Present stage and ... BIOI/B205
been determined. Tests made by A. V. Motorinat A. A. Konkin, N. V.
Mikhaylov,and others confirmed that the behavior of polyamide heated in an
inert atmosphere differs from that heated in air, 3) Brief analysis of
data on the testing and practical use of tires made from different types of
cord. It is noted that the NIIShP (Scientific Research Insidtute, of the Tire
Industry) has made several tests of tirea which showed that caprone cord is
best suited for the purpose. This is ascribed to the poor quality of
viscose cord- 4) Technical and economic data on the use of viscose and
polyamide cord. This section deals with an investigati6ncarried out by
VNIIV (All-Union Scientific Research Institute of Synthetic Fibers) in
cooperation with the Scientific Research Institute of the Tire Industry, in
the course of which the highly stable cord no. 5.45/2/1 was compared with
caprone cord no. 10.7/2/1. Both types were assumed to have a lifetime of
63,000 km. When putting the cost of viscose cord as 100%, the following
figures are obtained for caprone cord:
Capital cost
Creation of the raw-material basis .............. 138
Production of raw material and fiber ............ 142
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S/183/61/000/001/002/006
Present stage and ... B101/B205
Production of cord referred to a distance of
1000 km covered by the tire ....................... 96.7
Expenditure of work needed to produce the
cord tissue ....................................... 116
Prime Cost
Raw material ...................................... 216
Cord tissue ....................................... 181
Cord and rubber (per 1000 km) ..................... 101.8
The costs for sulfate cellulose and caprolactam were taken from planning
figures. Aocording to estimates of GIAP ~State Design and Scientific Re-
search Institute of the Nitrogen Industry and of the All-Union Scientific
Research Institute of Synthetic Fibers, the corresponding figures for anide
fiber are 107% and 12W4, respectively, when putting capital cost and prime
cost of caprone cord fiber as 100%. The high price is due to the costs of
AP("AG") salt. According to I. Ye. Krichevskiy and N. P. Fedorenko, -a price
cut'is possible by using non-aromatic starting materials, such as furfurol
and butadiene- 5) Prospects of the use of other fibers in the production
of tire cord. Reference is made to Western data on polyester, polyvinyl
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S/183/61/000/001/002/006
Present stage and B101/B205
alcohol, polypropylene, and polyurethane fibers. The authors state that
further research work would be necessary. They recommend caprone cord for
the production of truck tires, and viscose cord for automobile tires. The
development of caprone cord production intended in the Soviet Union does
not exclude the production of nylon cord. V. L. Biderman and P. Kh.
Drozhzhin are mentioned. There are 5 figures, 10 tables, and 53 referencem
17 Soviet-bloc and 34 non-Soviet-bloc.
ASSOCIATION: MT1 (Moscow Textile Institute): A. A. Konkin VNIIV (All-
Union Scientific Research Institute of Synthetic Fiber):
A. A. Rogovina, G. Ye. Birger
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S/182 ~61~000/005/003/003
B1O1FB11O
AUTHORS: Wu Jung-jai, Rogovin, Z. A., Konkin, A. A.
TITLEs Grafting of polyacrylic acid on polypropylene fibers
PERIODICAL: Khimicb.eskiye volokna, no- 5, 1961, 18 - 20
TEXTs The present paper deals with the dimination of the disadvantages
of pure polypropylene fiber (PPF): hydrophobic nature, poor colorability,
slipperiness, and unpleasant "cold" feel. For this purpose, grafting of
polyacrylic acid (PAA) on previously oxidized PPF was studied. PPF no. 35
of the VNIIV containing 6~ of amorphous, 6% of stereoblock, and 8Tj;') of
isotactic fraction was used. Oxidation was carried out by means of-atmos-
pheric oxygen at 1000C. The initial PPF had a breaking length of 37.4 km,
an elongation of 32~o. After 48 hr oxidation, the PPF contained 0.01(Yi~ of
hydroperoxide groups (HPOG) at a breaking length of 33.4 km and a 2&1~i
elongation. After 96 hr, the HPOG content was 0.031~o, breaking length:
21.9 km, elongation: 14-7%- PPP cxidized for 48 hr was used for further
experiments. Grafting of acrylic acid on oxidized PPF was conducted in
sealed ampuls with a 50A1 aqueous solution of the acid in argon atmosphere.
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Grafting of polyacrylic ...
27567
S/183/61/000/005/003/003
BIOI/B110
The content of carboxyl groups in the grafted polymer was analytically
determined after removal (washing-out) of the homopolymer (PAA). After
7 hr grafting, the following data were determineds with a 0 ;007d/- HPOG
content at 650C, no COOH groups had formed in the FPF, at 80 C, PPF con-
tained 3.5% COOH. The data for 0.010% HPOG aret 650C, 3-0% COOH; 800C,
4.15 COOH; for 0.031% HPOGz 650C, 10.7% COOH; 800C, 17-Y/o' COOH. The reac-
tion time exerted an effect upon the content of COOH groups. This content
waa 2.3% after 3 hr grafting at 80001 breaking length of PPF: 31.0 km,
elongations 24-9~a'. After 10 hr grafting, the COOH content was 14-04,
breaking lengths 27.8 km, elongations 23.0%. To inhibit the formation of
the PAA homopolymer, crystalline FeSO 4'7H2 0 was added as reducing agent in
amounts equivalent to the HPOG content in PPF. The following data were
found:
Time of temperature, content of GOOR breaking elongation, %
grafting, hri Oc groups, % I length, kmi
3 80 3.7 27.2 22-3
49 21 1-5 31.4 24.2
121 1 21 10-7 27-0 24.8
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2
7 67
8
S/1 6-1/000/005/003/003
Grafting of polyacrylic... B101 B110
1?B
In the presence of FeS04' grafting has to take place-in inert gas atmos-
phere, since in the presence of 02s the Fs2+ ions act as catalys-ts in the
oxidative destruction of polypropylene. Inhibition of the formation of
homopolymeric PAA was confirmed by the fact that grafted PPF was soluble
in acetone (in which PAA is insoluble) without turbidity in the presence
of FeSO 4* Modified PPF was colorable by basic dyes. With a relative
atmospheric moisture of 55.8%, PPF containing 8.2~o"COOH adsorbed 0.25~ of
the moisturet PPF containing 12.3~ COOKs however# adsorbed 0.73%. There
are 2 figures, 4 tables, and 8 referencest 3 Soviet and 5 non-Soviet
The. four references tc English-lanSua%~`ublications read as follows:
G. Natta, J. Polymer Sci., U9 685 (19 1 D. J. Metz an& R. B. Meavolian,
J. Polymer Soi., 16, 345 (1955)1 R. J. Orr,:H. Levevne, Williams, J. Am.
Chem. S00., 22, 3M (1957); R. Urwin, J. Polymer Sci., ZZ, 580 (1958).
ASSOCIATIONs MT1
Card 3/3

KONKIN, A.A.; SEITOV, A.T.
Structure.of.cellulose. Vysokom.soad. 3-no.10:1610-i6:13 0 161. .1.
Oma 14: 9)
1. Nauchno-iosledovatellskiy institvt iskusstvennogo volol-ma.
(cellulose)

SEMOV) A.T.; KONKIN. A.A.1 KOTOMINAp I.N.; SOLOV'YEVAj N.I.
Effect of the atructure of freshly formd viscose fiber od
Btresses during spinning,. Khimsvoloks noo5:34p..37 161*
(MIRA .14: 10)
1. Voesoyuznyy nauchno-issledovatelinkiy institut iskusstvennogo
vol6kna.
(Rayon Bpinning)

DRUMININA, T.V.; ANDRICHENKO, ru.D.; XONKIN, A.A.; ROGOVIN, Z.A.
Process of polyethylem fiber formation. Khimvolok. no.2:17-20
162. .(MMA 15:4)
1, Moskovskiy tokati3.IxWy iwtitut.
(Folptbylene)

BORISOV, A.; BIMERj Go; VOLKOV# A.; DICH., So; DUSEMA~ Yee LKONKI_&_~A.Aq ~
WMO A.; MIKHAYLOV, No; MOGEMSM, Yee; PM%M, A.;
ROGOVINO Z,; SERKOVp A.; S.HIMIN., L.
On the 6ft birthday of an honored worker. Khim.volok. no.2:79
162. 1(Grundev,, 'Familli Alekoesvichs 1902-) . (KIRL 15:4)

NOVIKOWAI L.I.; KOMM, A.A.; SHULYATIKOVAy N.V.
Effect of the de&ee of substitution of cellulose xanthate
on the supermolecular structure of cord fiber. Kbimovolok
no.4 347-51 162. OMA 15:8)
1. Vaesoyusnyy nauchno-iseled6vatelfskiy institut iskusstvemnogo
volokna (for Novikcrwa,, ShLa7atikova). 2. Moskovskiy tekstilInyy
institut (for Konkin).
(Cellulose ZLnthate) (payon)

NIKOLAEYVA, N.S.; KONKIN, A.A.
*Polynosi" (ce3-lulose hydrate) fibers. Khim.volok. no-5:5-15
162. (MIRA 15:11)
1. Vsesoyuznyy nauchno-isoledovatellskiy institut
iskusstvennogo volckna (for Nikolayeva). 2. MookovskiT
tokstilinyy institut, (for Konkin).
(Cellulose) (Rayon)
I

SHBVCHENKO, A.S.; KOMCIN, A.A.; SERKOV, A.T.
Possibility of producing complex compounds with modifying
agents during the process of viscose fiber formation.
Khim.volok. no.5:27-30 162. (MIRA 15:11)
1. Voesoyuznyy nauchno-iseledovateltakiy institut
iskusstvemogo volokna (for Shevchenko). 2. MoskovsId-
tekstilInyy institut (for Konkin). 3. Gosudarstvennyy
komitet kbimicheskoy promyshlennosti pri Sovote Miniatrov
,SWR (for Serkov).
(viscose)
(Complex compounds)